y:eia-projectson-going projectslion tapeslion tapes...

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315th meeting of SEAC-Gujarat, Dated 01.12.2016

Page 1 of 108

Minutes of the 315th meeting of the State Level Expert Appraisal Committee held on

01/12/2016 at Committee Room, Gujarat Pollution Control Board, Gandhinagar.

The 315th meeting of the State Level Expert Appraisal Committee (SEAC) was held on 1st

December, 2016 at Committee Room, Gujarat Pollution Control Board, Gandhinagar. Following

members attended the meeting:

1. Shri T. P. Singh, Chairman, SEAC.

2. Shri V. C. Soni, Vice Chairman, SEAC.

3. Shri R. J. Shah, Member, SEAC.

4. Dr. V. K. Jain, Member, SEAC.

5. Shri Rajesh Shah, Member, SEAC.

The agenda of TOR/Scoping/Category 8 (a) cases and Appraisal cases was taken up. Twelve (12)

cases of TOR/Scoping/Category 8 (a) and thirteen (13) cases of Appraisal was taken up. The

applicants made presentations on the activities to be carried out along with other details furnished in

the Form-1 / Form-1A, EIA report and other reports.

1. High Rise Building Project 2 FP 123

R.S. No.: 54/2+54/3, O.P.No: 27/B1, F.P.No: 123, T.P.S.No: 7, (Anjana), Ta: Choryasi, Dist. Surat

Appraisal case

The project was earlier taken up in meeting of SEAC dated 09/8/16. During the meeting held on

09/08/2016, after detailed discussion on various aspects of the project it was decided to appraise the

project further only after submission of the following:

1. Copy of permission obtained from concerned competent authority for the proposed FSI.

2. Base line status of the existing traffic, impact on it due to the project activities (prior to construction,

during construction and at full site operation), carrying capacity of the existing roads and details of

traffic management in and outside the project during construction and operation phase of the project.

3. Copy of permission obtained from Airports Authority of India for the proposed building height.

4. Location of the proposed STP on the layout plan.

5. Minimum fire water requirement for the proposed project based on the fire study.

6. Type of activities to be carried out in the proposed commercial units. Notarized undertaking stating

that no any kind of manufacturing activity shall be allowed in the commercial units of the proposed

project and they will not sold / allot any commercial unit for storage of chemicals, flammable

substances, explosives, fire crackers or any other material of hazardous characteristics.

7. Perspective view of the building(s) to be constructed along with the materials used such as fibers,

glass, etc. on the facades or external walls and the impacts thereof on the nearby buildings /

residents due to heat island effect and emissions from the air conditioning systems.

8. E waste management plan.

9. Details of mechanical parking to be provided (also including its operation, maintenance, energy

consumption, appointing trained personnel’s etc.) in the basement along with the feasibility of

providing mechanical parking considering the basement height.

10. Details on ventilation, lighting arrangements and CO sensors to be provided in the basements.

Details on provision to be made for natural lighting & ventilation in the proposed commercial units.

11. Detailed plan for loading / unloading of goods, movement plan, space designated for it, parking area

designated for trucks/tempo etc.

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Typewritten Text

Annexure-1

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Typewritten Text

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Page 62 of 108

The above mentioned project specific TORs/additional TORs and the model TORs available in the

MoEF’s sector specific EIA Manual for Synthetic Organic Chemical industry shall be considered as

generic TORs for preparation of the EIA report in addition to all the relevant information as per the

generic structure of EIA given in Appendix III in the EIA Notification, 2006. The project shall be

appraised on receipt of the final EIA report.

Validity of ToR:

• The ToRs prescribed for the project will be valid for a period of three years for submission of

EIA & EMP report accordingly, ToR will lapse after 30/11/2019.

• The period of validity could be extended for a maximum period of one year provided an

application is made by the applicant to the Regulatory Authority, at least three months before

the expiry of valid period together with an updated Form-I, based on proper justification and

also recommendation of the SEAC.

12 M/s: Lion Tapes Pvt. Ltd. Plot No:293 GIDC-Chitra Estate Dist: Bhavnagar

Appraisal

Project / Activity No.: 5(f)

Project status: New

Chronology of EC Process:

• This project proposed by M/s: Lion Tapes Pvt. Ltd. (herein after Project Proponent – PP) has

submitted Application vide their letter dated 16/01/2013.

• The project proponent was called for presentation and discussion in the meeting of SEAC held

on 12/03/2013.

• During the meeting, the committee informed the project proponent that as per the report on

"Comprehensive Environmental Assessment of Industrial Clusters", CEPI scores of Chitra -

Bhavnagar was above 70 and hence considered as critically polluted. The proponent was also

informed that the MoEF has imposed temporary restrictions on consideration of developmental

projects in such clusters / areas vide their Office Memorandum dated 13/01/2010 and hence

the proposed project can’t be considered as it is situated in Chitra - Bhavnagar having CEPI

score above 70. At this, the project proponent presented that as per the latest assessment

done recently, CEPI score of Chitra – Bhavnagar is less than 70 and hence their application

should be considered. However, the committee decided not to reconsider the project as new

report on CEPI score is not yet published. It was decided to consider this project only after

verifying that CEPI score of Chitra – Bhavnagar is less than 70.

• The project proponent was again called for presentation and discussion in the meeting of

SEAC held on 24/06/2014.

• During the meeting, the project proponent requested for categorizing the project as B2 and to

exempt them from carrying out detailed EIA study which was not considered by the committee

and the project proponent was asked to include the additional TORs for the EIA study to be

done covering 5 km radial distance from the boundary of the project.

• EIA Report prepared by M/s: Precitech Laboratories Pvt. Ltd., Vapi was submitted by project

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Page 63 of 108

proponent vide dated 09/11/2015.

• PP was called for presentation in the SEAC meeting dated 22/12/2015.

• During the meeting dated 22/12/2015, Committee noted that the site of the proposed project is

located within the Chitra GIDC, where all the industrial units are of Inorganic chemical nature.

On asking about the waste water treatment and disposal, PP informed that they will treat the

entire effluent within premises and send it to disposal pipeline of GIDC Chitra which ultimately

leads to Arabian Sea. Committee was of the view that Organic Chemical industries having high

organic load containing effluent shall not be allowed to discharge in this industrial estate. After

detailed deliberation, Committee asked to change the proposal and go for complete zero liquid

discharge (ZLD). Considering the above facts, it was unanimously decided to consider the

project for appraisal only after submission of revised proposal with complete zero liquid

discharge (ZLD) system.

• PP submitted corrigendum to the EIA report considering Revised proposal with complete zero

liquid discharge (ZLD) system vide their letter no. Nil dated on 27/10/2015.

Project / Activity Details:

This is a proposed unit applied for manufacturing of following Dye & Dye Intermediates.

Sr.No. Name of Products Quantity MT/Month

1. Fast Red B Base 40

2. Fast Bordeaux GP Base 20

3. Fast MNPT (Red G) Base 10

4. Fast Red 3GL Base 5

5. Fast Scarlet R Base 10

6. Fast Yellow GC Base 5

7. Fast Orange GC Base 5

8. Fast Red RC Base 5

Total 100

The proposed production activity falls in the project activity 5(f) as per the Schedule of EIA

Notification, 2006 as amended from time to time.

Capital cost of the project is Rs.3.54 Crores. Total plot area of the proposed project is 4,389.67 sq.

m including green belt area 710 sq. m. Fresh Water requirement of 42.5 KL/day will be met through

GIDC water supply system. Industrial effluent generation will be 29.5 KL/day which will be treated

in the proposed onsite ETP and will be discharged through common pipeline of GIDC. Wood

briquette will be used as fuel in Thermic Fluid heater (2 lac Kcal/hr.) and HSD will be used fuel in

the proposed D.G. Set (31.25 KVA). Bag filter will be provided as APCM to Thermic Fluid heater.

ETP waste, process waste, discarded containers/bags and recovered solvent are the hazardous

waste to be generated from the proposed production.

Observations/Discussions:

Technical presentation made during the meeting by project proponent. The baseline environmental

quality has been assessed for various components of the environment viz. air, noise, water,

biological and socioeconomic aspects. The baseline environmental study has been conducted for

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Page 64 of 108

the study area of 5 km radial distance from project site for the period October 2014 to December

2014. Ambient Air Quality monitoring was carried out for PM10, PM2.5, SO2, NOx, and VOC at Six

locations, including the project site. Values conform to the prescribed standards for Ambient Air

Quality. The incremental Ground Level Concentration (GLC) has been computed using ISCST – 3

model. The resultant concentrations are within the NAAQS. While discussing about the treatability

for treatment of waste water to be generated, PP informed that they have proposed segregation of

industrial effluent at source and Zero Liquid Discharge status will be maintained. Upon asking

about the adequacy of the proposed treatment facilities, PP could not reply satisfactorily. In-

process distillation will be carried out to recover spent solvent. Committee asked to submit

adequacy certificate with qualitative analysis of the each waste stream. Sodium acetate solution

(217 MT/Month) and spent Acetic acid (234 MT/Month) will be generated as waste streams from

the manufacturing process. Sodium acetate will be used in Benzyl Acetate manufacturing & spent

Acetic acid will be used in Manganese acetate manufacturing. However actual consumers have not

been identified. After detailed discussion on the matter, It was decided to consider the project only

after submission of the following:

1. A detailed effluent treatability study vis-a-vis the adequacy and efficacy of the treatment

facilities proposed for the waste water to be generated. Give stage wise reduction of main

parameters. Certificate from Schedule I auditor for complete Zero Liquid Discharge.

2. Management of Sodium acetate solution and spent Acetic acid as per the Hazardous and

other Wastes (Management and Transboundary Movement) Rules, 2016.

13 SIA/GJ/IND2/11094/2016 M/s: Anagha Chem Pvt. Ltd. Plot no. D/2/CH-318, Phase-II, Dahej GIDC Estate, Ta.: Vagra, Dist.: Bharuch

Appraisal


Project status: Existing

Chronology of EC Process:


• M/s: Anagha Chem Pvt. Ltd (herein after Project Proponent – PP) has submitted online

proposal vide no. SIA/GJ/IND2/11094/2015 dated 16/04/2016 for EC amendment.

• PP was called for presentation in the SEAC meeting dated 29/06/2016.

• During the meeting dated 29/06/2016, while discussing about the justification for change in fuel

and capacity of the Boiler, PP informed that the Natural gas pipeline is not available in area. PP

could not justify properly about the change in capacity of the Boiler. Total fuel (Bio-Coal)

consumption for the 3 TPH Boiler will be 600 Kg/hr. PP has proposed MDC followed by Bag

filter as APCM. After detailed discussion on the matter, It was decided to consider the project

only after submission of the following: (1) Detailed justification for proposed change in fuel

along with the supporting documents. (2) Technical Justification for change in capacity of the

Boiler from 0.3 TPH to 3 TPH. (3) Give above mentioned justification with regard to earlier EIA

report. (4) Specific details on (i) Type, quantity and quality (CV, Sulphur content, Ash content,

etc,) of coal to be used (iii) Flue gas emission details (iv) Air pollution Control Measures along

with its adequacy to achieve the GPCB Norms. (v) List the sources of fugitive emission from

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Page 108 of 108

ADDITIONAL AGENDA

1. Letter of Shri Bharat S. Dave dtd 14/11/2016 regarding illegitimate allotment of

quarry permits and operation of lease without obtaining Environmental Clearance

regardiing.

The aforementioned letter was received by this office on 16/11/2016 and it was deliberated

in the meeting. After referring to the letter of Shri B.S.Dave dated 14/11/2016, committee

unanimously decided to inform Shri B.S.Dave with a copy to Commissioner, Geology and

mining stating that it is mandatory to obtain Environment Clearance for mining project. It was

also mentioned to inform that for river bed mining proposal, it is required by the concerned

geologist to submit project details along with details of lease whether it is located in dry river

bed and it is not an instream mining. Upon submission of details with validation of concerned

district geologist, river bed mining proposal is recommended to SEIAA for grant of

environment clearance.

Meeting ended with thanks to the Chair and the Members.

--------------------------------

Minutes approved by:

1. Shri T. P. Singh, Chairman, SEAC.

2. Shri V. C. Soni, Vice Chairman, SEAC.

3. Shri R. J. Shah, Member, SEAC.

4. Dr. V. K. Jain. Member, SEAC.

5. Shri Rajesh Shah, Member, SEAC.

HBHAI PATEL EDUCATION SOCIETY'S

a)b)c)

AT. ISROLI, PO. AFWA, TAL. BARDOLI, DIST. SURAT PIN.394620P h one : 92280008 67, 02622-290933, F ax: 02622-29 I 411

E-mai I : [email protected] . Website; wwvv.fetr.ac. i n

Ref. No.: FETR/CHED|ELCD0IT/}J lL Date : o7to3t2ot7

Adequacy Certificate from Environ AuditorThe Environmental Management System Adequacy Certificate

The environmental Audit Scheme was introduced by the Gujarat High court vide lts Orders

dated. 20112196 & l3l3/97 and modified vide order dated.16/9199. We are appointed by the

GPCB Gandhinagar as recognized Auditor for ScheduleJ industries for compliance of the

directions of the Hon. High Court in that matter & have carried out study of quantity/quality ofeffluents (wastewater + solid hazardous waste) of;

lWs. LION-TAPES PVT. LTDLocated at: PLOT NO 293, GIDC CHITRA ESTATE, BHAVNAGAR, GUJARATManufacturing products as under:

Product Details:-

LIST OF PROPOSED PRODUCTS AIID PRODUCTION CAPACITY

LIST OF RAW.MATERIALS AND ITS CONSUMPTION.

FAGULTY OF EilGI}IEEHilG TECHilOLOGY AilD RESEARCH

Sr. No Name of the Products Quantity (MT/IvIonth)

I Fast Red B Base 40.02 FastBordeaux GP Base 20.03 FaStMNPT (Red G) Base 10.04 Fast Red 3GL Base 5.05 Fast Scarlet R Base 10.06 FastYellow GC Base 5.07 Fast Orange GC Base 5.08 Fast Red RC Base 5.0

Total 100.0

S. No. Name of the product Raw material Requirement(Mra{)

1Fast Red B Base & Fast Scarlet RBase

,l^--sG.."x

Ortho Anisidine 38Acetic Anhydride 32Nitric Acid 36Methylene Di-chloride 6

Snhadrrlo-'l Fnvirnr

/iG'#,Ie

frH#.{ Nodar centre For sooken rurd#spd,pfPJ{)F !rGPCB Approved Mumbai.

eia8

Typewritten Text

Annexure-2

S. No. Name of the product Raw material Requirement(MT/fvr)

Sulphuric Acid 2Sodium Hydroxide 27

2 Fast Bordeaux GP Base

Para Anisidine l7Acetic Anhydride t6Acetic Acid l6Nitric Acid 26Methylene Di-chloride 2Sodium Hydroxide 7

3 Fast MNPT (Red G) Base

Para Toluidine IAcetic Anhydride 9Acetic Acid 9Nitric Acid I4Methylene Di-chloride 2Sodium Hydroxide 4

4 Fast Red 3GL Base

Para Chloro Aniline 5Acetic Anhydride 4Acetic Acid 4Nihic Acid 6Methylene Di-chloride 1

Sodium Hydroxide 2

5 Fast Yellow GC BaseOrtho Chloro Aniline 5Hydrochloric Acid 5

Sodium Chloride 2

6 Fast Orange GC BaseMeta Chloro Aniline 5

Hydrochloric Acid 5Sodium Chloride )

7 Fast Red RC BaseEgq 3{4 Chloro-Ortho-Anisidine) 5

Hydrochloric Acid 5Sodium Chloride 2

Details of lvlanufacturing Process & Mass Balance : As per Annexure - I

Page2 of26

r'-*\

As per the direction of Hon'ble High Court in Environmental Audit Scheme and based on

literature survey, site visit of the industry, we certify that the Environmental Management

System proposed by this industry for the proposed products is adequate to achieve thequantity/quality of effluents (Wastewater + Solid and hazardous waste) as specified/required by

ConsentsArlotifications of GPCB, Gandhinagar for following quantity of effluents.

d) WATER CONSUMPTTON & EFFLUENT GENERATTON (KL/DAY)

o Water consumption:

Sr.

No.Particular

Water consumption

(KL/Day)

I Domestic 1.5

2 Gardening 4.0

aJ Industrial

Process 0.0*

Boiler 5.4

Washing 4.0

Cooling 6.1

Total Industrial 15.5

4 Total (1+2+3) 21.0

* The fresh water consumption in process unit will be zero because only recycled water(35.4 KL/Day) will be used.

o Effluent generation:

Sr.

No.Particular

Water consumption

(KL/Day)

I Domestic 1.3

2 Gardening 0.0

3 Industrial

Process 33.5

Boiler 1.8

Washing 4.0

Page 3 of26

Cooling 0.7

Total Industrial 40

4 Total (1+2+3) 41.3

Note:

finally mixed with industrial effluent.

MEE system. MEE condensate shall be recycled back to process. Salt from MEE shall be

dispose off into TSDF.

Details of effluent Treatment Plant

Water Balance Diagram

: As Per Annexure - II

: As Per Annexure - III

ADEQUACY OF EFFLUENT TREATMENT PLAIIT

(Nitration Stream)

Flow:16.1 KLlday (Effluent from Nitration Stage).

(Hvdrolvsis Stream)

Flow: 9.3 Kl/day (Effluent from Hydrolysis Stage).

Test Parameters Results of treatabilitv studvInitial After neutralization &,

Carbon TreatmentCondensate Water

Recovered afterEvaporation

pH 4.8 7.8 7.9

SS 650 ms/L 72ms,lL 32 ms,LTDS 20330 ms.lL 30362mslL l48ms.LCOD 13325 ms/L 9054me/L 67 ms/LBOD 3012ms,/L 1770ms/L 24 ms,/L

Test

Parameters'

Results of treatability study

Initial After neutralization &Carbon Treatment

Condensate WaterRecovered after

Evaporation

Page 4 of26

pH 8.s 7.6 7.5

SS 445 mglL 6lmgll aSmglL

TDS 28332mglL 29383 mgtL 168 mg/L

COD 9313 mglL 6476mglL 89mglL

BOD 2232mglL t662mg/L 33mglL

(Washine & othef Stream)

FIow: 14.6 Kl/day @flluent from Washing & others).

CONCLUSION:

Overall Remarks:

Looking to all above points, it is concluded that the proposed Effluent treatment system will be adequate

with respect to waste water treatment & zero liquid discharge system for proposed project.

Test

Parameters'

Results of treatability study (Stream from Washing & others)

Initial After neutralization &Carbon Treatment

Condensate Water

Recovered afterEvaporation

pH 7.1 7.4 7.2

SS 318 mg/L a6mglL 34mglLTDS 7643 mglL 7978mgll- 173 mglL

COD 1265 mglL 876mglL 65 mglLBOD 358m{L 266mgtL 26 mglL

Page 5 of26

e) Hazardous Waste:

Type of waste Source 4ry. Mode of disposaU reuse Category

Ilazardous Waste

Used oil Maintenance l0 Liter/IVlonth Collection, storage and reused aslubricant in plant machinerv

5.1

ETPSludge ETP 2.80MT/lvlonth

Storage, transportation anddisposal to the TSDF

35.3

Evaporation salts MEE 3.20MT/IVIonth

Storage, transportation anddisposal to the TSDF

3s.3

Salts (mainly inform of SodiumNitrate fromnitration andsodium acetatefrom Hvdrolvsis)

MEE 19.0MT/Month

Collection, Storage & sent toactual users or disposal to theTSDF

35.3

Discardedcontainers/ bags

Raw materialstorage

Approximately0.5 MT/\tfonth

Collection, Storage & sale toactual users or authorizedrecycler.

33.3

Spent Carbon ETP 4.0 MT/IVIonth Collection, Storage &disposal tocommon incineration facilifu

Spent Acid (AceticAcid)

Process 17.0MT/IVIonth

Collection, Storage & Reused asRM or sold out to actual users.

D2

Non-Hazardous Waste

Fly Ash Utility 1.5 MT/IVIonth Collection, Storage, & given tofarmer as rnanure

Page 6 of26

]E

FACULTY OF ENGINEERINGTECHNOLOGY AI\DRESEARCH,ISROLI-AFWA,BARI}OLI.

There will be no discharge of the indushial effluent from the manufacturing process and other ancillary

industrial operations.

This certificate is subject to automatic iancellation in case of any change in product profile/capacity,

quantlty & quantity of eflluents (Water + Solid) and effrciency of EMS equipment.

DATE: 0710312017 AUDIT TEAM MEMBERS

1. Dr. Jaydeep lV[.parad, Ph.D. (Chemical)

X;fi,'8:,, fun---2. Mr. Nevil J. Shakwala, M.Tech. (Env.)

*ib"-

Member,Audit Cell

3. Dr. Amish B.Member,Audit Cell

M.! .f,)af,a)*lqr

-tr{Patel, Ph.D. (Chemistry)

J#4. Miss. Krina B. Mistry, M.Sc. (Chemistry)

Member,Audit Cell

, {,.

ffi@

PageT of26

ANNEXURE - I

1) Fast Red B Base & F'ast Scarlet R Base

Ortho anisidine is acetylated with acetic anhydride in the acetylation reactor, after the completion ofthe reaction that mass is to be transferred for recovery of Acetic acid. Then reaction mass is takeninto nitration vessel where it is mixed with MDC, and concentrated Nitric acid is slowly added to it.

After completion of this process the mass is washed with water and further distilled in distillationunit for recovery of MDC. After the recovery of MDC the mass is transferred in to neutch filter andwater is separated from reaction mass. Washing water collected from neutch filter is to be senttowards ETP for treatment purpose.

After that the reaction mass is to be gradually added into the solution of caustic soda flakes andwater at maintained temperature for hydrolysis purpose. After completion of reaction the mass istransferred it to neutch filter and waste water as filtrate is to be sent towards ETP for treatment ,

purpose. Fast Red B Base & Fast Scarlet R Base is separated with dilute Sulphuric acid where FastScarlet R Base dissolved in it & Fast Red B Base collected as a residue after neutralization will getFast Scarlet R Base both are dried, pulverized & packed.

Page 8 of26

].ffiBfiTi fl*! ,: ..

... 1, l

.1..1-

..6 , r,t.

.i

Pasit9,ffi26

Material Balance:

Iilataifrl $r*incc ForRcd E $a:* & Fat$cari*t R $a:r.tAll Valucr in KG!

0rfixoAnisidinBAqett{ Anhyd*de

Areti{ A${X,90%

fi{nNitiis Acd {S&Ya}

t*iathylenp $chiorideFfsshWster

Freeh Water

WstsrT*ETF

M*dlylene Diehh:riule(g*%l Flscot WEBUgsd in 9{@xtEst{h

Evrlp.Loxs {tySC}}TdLi* EIP

*latrrT*ETF

&{}p. l"q6s

lAfatfrts ETF

WslsrTcWathi{rg

t565!+15q{i

132735_>

:rlss----.F

3ffi

2f25--+

2fios

E1

frerh Water

C*u*lic &da Flsl$es*$qrd* Y!,ster ir*m Yua$hi*g

20ss

$0*

E:I

r*

c1

Fregh Wai*r

t{?*r{s696}Fr8sh WsI6r

$r*ah W*tqr

C*usrlc Flfikes

fr66h.Wst8r lay€rlo#TP *&71-*******'*

Hios L{s$ 34

cl

frv*p. Loes 1*0

E4SrFGDBsA#10m

F&sTSEABLEThEASE

t68

Page 10 of26

2) Fast Bordeaux GP Base

Para Anisidine is acetylated with acetic anhydride in the acetylation reactor, after the completion ofthe reaction that mass is transferred for recovery of Acetic acid. Then reaction mass is to be taken

into nitration vessel where it is mixed with MDC and concentrated Nitric acid is slowly added to it.

After completion of this process the mass is washed with water and further distilled in distillationunit for recovery of MDC. After the recovery of MDC the mass is transferred in to neutch filter and

water is separated from reaction mass. Washing water collected from neutch filter is to be sent

towards ETP for treatment purpose.

After that the reaction mass is gradually added into the solution of caustic soda flakes and water at

maintained temperature for hydrolysis purpose. After completion of reaction the mass is transferred

it to neutch filter, waste water as filtrate is to be sent towards ETP for treatrnent purpose and solidpart of the mass is further washed, dried &pulverized to get final product Fast Bordeaux GP Base.

Chemical Reaction:

Bordeaux GP

NHC@H3CH3CO\ MDC ,\+ P--* ll .l +cH3cd \/

H3CO

Acetic Anhydride

102.08

cH3cooH

Fara Anisidine

{23.15

trHCocH3,4-V+

HsCO

165.19

Nitration-----+

+ Heo

t-lNo3

63 210.18 18

l!HCOCH3

-(Il -l + NaoH

\y'No, --------*Hydrolysis 'Noz + CH3C@Na

82.03

Sodium Acehte

ocH3

210.18 39.99

HsCO

't 68. 15

Bordaaux GP

##191-dt, rsroifiF / [ic,: itflvs.CI{'r,.l'xi".i"r1, lp

t-h*-%? Page 11 of26

r3I'!

lll

Material Balance:

tilalerial E.alarec For F.isI Bord@ux GP Bce.(All Vduos in l(G)

P.ila l\hisidins.i-{cetiG:AhhydrideRscorsr Acr1ic Acid (S96)

8{8

Ra9w6r Ac*ic Acid 99,67€3.recyclo4f2 sale.

Evo.Loss (AcetieAcid)

1?2.5

t0

qon.Iftdc.Add (60%)Metrylene Dichlorida

Fresh Waler

12723392

2oih MetMenp DibhloridsRbUsed:in Next:Batch

IJIL tO ETP

WatEr To ETP

Evop- Loes

3256

2737 lE1

1fi)0 ---- E2

'\100

3283 + Cr

2e/JO

'2&

Frt€sh Watbr

Sosium Fidio(ideReqtdoWabr frodr Washin g(Fresh 544 + Recyd.d 2000)

Fresh'Watar

To ETP

Water ToWadring

; Evop. Loss

Fast Bordraur,GP 9!!a{0m

Page12 of26

3) Fast MNPT (Red G) Base

Conversion of Para Toludine to Meta Nitro Para Toludine is carried out in three stages namely

Acetylation, Nitration and Hydrolysis. In Acetylation, Para Toludine is acetylated with Acetic

Anhydride and Acetic Acid to obtain Acetylated Para Toludine. After theAcetylation reaction the

mass is furttrer distilled for recovery of Acetic Acid. The Nitration of Acetylated Para Toluidine and

MDC as a solvent is done'with Concentrated Nitric Acid and Sodium Nitrite as a Catalyst.

MDC is then recovered from Nitro mass and after the recovery of MDC Nitro mass is further

hydrolysed with Caustic Flakes to get Meta Nitro Para Toluidine. Then MNPT is further purified,

centrifuged, dried, blended and pulverized.

Chemical Reaction:

MNPT

NH.A'[)HsG

+CH.CO-\

.o/cH3GO,

Acelic Anhydride

'to2,oB

MDC

-iF.

NHCoC

-'\-[ :-t-'\-VYHac

1 4S.1 A

H3

+ cH3eooH

60.05

Par€ Tol,uidine

'r o7.1 5

NHCOCH3

1All I -r

HaC

149.18

HN()3

63:01

Nitration

--_--.

tHcocH3

[ )^,^--7 rrv2cHs

134.1A

+ Hzo

1A

NHCOCH3

e>*.,CH:

1 94.1 8

+ _____-____>

Hydrolysis

NH.t'

e>'".,HeC

MNPT

152.15

+ CH3COONa

Sodium A.cetate

a2.0339.99

6ffiY/ t"t: lsroli'\'fr /- A^t: lsroli'\ rP(r- / pr: Afwa, \'o I To, Barcoti, I 7

:l\Pin-3e4620/d

Page 13 of26

Material Balance:

t rtrrlel Brlanea For',MNPT,{Rcrl Gl,BCrc.{AIl Vatucs ln KG)

Para'Tolljl.dinoAcsti.c4nhydrideRecover Acitic Acrd

Recover Acetic Acid92.95%' 13188 1 8 recycle 500 sale ,

Ro.Loss (Acetic Acid) 10

Nilric Acid198%lMethylene Eichloride

Fresh Wat€r

Fresh Wgter

Caustic SodaFlalecWater

{Fresh 118'l + Recycledl0oo)

Fresh Water

Mefiylene Dichiorid6Reused in Next Batch

MLIo,EfPwater Io.ETP.

Evopr Loss

h,ater To EfP

WaterToWashing

Evop, Los6,

4364,

1250 ----------r..811000 ----------l E2

100

4218. l C1

2000

637

l$:N.P,T1000

. {,.

Page14 of26

4) Fast Red 3GL Base

Para Chloro Aniline is acetylated with Acetic Anhydride in presence of Acetic acid and after

completion of addition of Acetic Anhydride, mass is fiansferred to distillation reactor to recover

Spent Acetic Acid. After flaking, Aceto product is collected & transferred into nitration vessel withMDCand slow addition of dilute Nitric Acid at required temperature. After completion of nitrationprocess, reaction mass is transfer into distillation vessel for recovery of MDC a.nd then is transferred

into neutch filter. Filtrate is drained out to ETP after washing and reaction mass is transfered into

hydrolysis reactor with caustic soda flake and water. The mass is further filter waste water as filtrateis to be sent towards ETP for treatment purpose and solid mass is further purified by washing and

drying to get Finished Product - Fast Red 3GL Base.

Chemical Reaction:

Fted 3rt.'l-

NH: IIHCoCH3I - CHOCO )

fa> + -""-> 5 fi- -F cH3cooHcH3co Y uo.oscr PlAccticAfihvdride .r6(i.6o

para, chttro Anitine 1A2,AS127.57

trHcocH3a.lCI:

169.60

hrHcocH3

,t'YozYCI

Nitra.tiohH,N()3 '------""">

63-02

ryHCocH3/./\-N02il -t

Gl21:4.6O

-t Hzo

1a

-+- NaoH #Hydr{jYsis

+ cH3GooNa

Seclium ;A{retate

a203:214;60 39:99 Red:3GL

172.s6

#ffiW

Page 15 of26

Material Balance:

Material lialance For Fast Red GL Base.(All Values in KG)

Phra ChlcoiAnilineecetiglnfry*iaeRecover Acitic Acid

Acefic Abid 99cA 12,,

r0

763 recyde 462 sale.

.Loss,(Acetic Aeid)

Nitric Acid (60",6)

MeSrylene Didrloride

Fre$r Urhter Metftylene DichloridoReused in N*t Batch

3256

1585 +E1

'1,000 +E2

100

3283 +Cl

:2000

N1

FreSr llUiiter

Sosiuni HydroxideWater(Fr66h 544 + Recycled 2000)

Fresh Whter

ML to ETP

Water To ETF

Evop.rloss

Water To ETP

To Wa$ing

Ev6p: Loss

F.ast,Red GL,Easemm

Page 16 of26

5) F'ast Yellow GC BaseIn the Reactor water and add Hydrochloric acid (32%) are mixed properly and OrthoChloro Aniline

is added at specific temperature and time. The mass is stirredfor I hour and after that sodium

chloride is added to precipitate of Yellow GC Base from water.

The whole mass is centrifuged for separation of water. Water from centrifuged stage is partially

reused in next batch and rest is diverted to ETP. Wet cake of product is further dried to obtain final

product

Chemical Reaction:

lllHz# $H2.HClCl H2gl

+HCl*CI

ortho chtorp..Anitine. Hydrothloric,Acid ortho Chlom Aniline Hvdrochloride

127.5 36.4 164.03

Material Balance:

fthtetial Bahifce For FaEt YellowG0 Base{All\Ialues in KG}

0rtto'Chloro Aniline 1

Hel32% 1

Nast

Recy.ele V\hter 1

:

f+ 1000 Recycle in next batch

14141It+ 414 To EfP

FastYellowG0 Base,

ud-\'O*LE

Pagel7 of26

r

6) Fast Orange GC BaseIn the Reactor water and add Hydrochloric acid(32%) are mixed properly and Meta Chloro Aniline

is added at specific temperature and time. The mass is stined for t hour and after that sodium

chloride is added to precipitate of Fast Orange GC Base from water.



product.

Chemical Reaction:

Material Balance:

l)JHz

0 + HCIHzo_1.

CI

Meta Chloro Aniline

127.5

l.lydrochloric Acid

36.4

Meta Chloro: Al iline Hydrochloride

164.03

Matef-ial Bal&nae FoI Fast OrangeGG Bess(All VsIuEs in KG)

Meta ehbro.AnilineHoi 32%NaclRecydeWater

1000 Reoyelein,nextbatoh

414 ToEIP

-

Page 18 of26

I ,,7

7) Fast Red RC BaseIn the Reactor water and add Hydrochloric acid (32Y) are mixed properly and Red R (1 Chloro 4

Amino Toluidine) is added at specific temperature and time. The mass is stirred for I hour and after

that sodium chloride is added to precipitation of fast red RC Base from water.



product

Chemical Reaction:

#ocH3 + HCr

HrO--f

CI

Red R Flhkes

123..15

HydrochloriCAcid

36.4

Red RC Base

194.05

Material Balance:

l,Jlaterial'Balanee For Fast Red RO,Base.{Atl Valueg:in' KG)

Red Rr-Jd3a%Nac!Reclcle Water

1000- ReClrclein'n4{,ttatch

414 To tIP

Page19 of26

ANNEXURE - II

Details of Effluent Treatment Plant

Total 4I.3KLD wastewater will be generated from proposed project bifurcated as domestic

wastewater @1.3 KLD & industrial wastewater @ 40.0 KLD. Industrial wastewater includes

wastewater from plant washing @ 4.0 KLD, cooling tower blow-down @ 0.7 I<LD,

wastewater from boiler @1.8 KLD & water arrives from [email protected] KLD.

The domestic wastewater will be disposed off through Septic tank/ soak pit. The industrial

effluent will be segregated in 3 streams as

1) Water from Nitration stage (16.1 KLD)2) Water from Hydrolysis stage (9'3 KLD)3) Water from washing & others - (14.6 KLD)

The entire three stream will be separately collected ln collection tank and given separate

primary treatment as per its characteristics. After primary and tertiary treatment, treated water

from each stream will be separately evaporated in evaporator. Condensate water recovered

from evaporator will be reused in manufacturing process.

Effluent Treatment Scheme for Water from Nitration stage

The entire effluent from the nitration process will be collected in separate collection tank.

Then effluent will be neutralized with NaOH up to pH value 7.5 -8.0. After neutralization,

e{fluent will be filtered in filter press and clear effluent will be given tertiary treatment with

activated carbonand clear effluent will be sent for evaporation. Condensate water from

evaporator will be reused in the process. Based on the effluent quality sodium nitrate salt will

be generated as evaporation salt which will be sold out to actual users or sent to TSDF site.

Sludge from primary treatment will be sent to TSDF site for disposal.

Units of Effluent Treatment Plant (for treatment of Nitration Stage water)

Note: Multiple effedt evaporator will be used as a cemmon facilities for all streams.

400 mm Dia.

1.5 m Height.

Page20 of26

1. Collection TankFLOW: 16.1 KL/DAY (Nitration Stream)

in multi effective evaporation unit to achieve Zero

2. Neutralization Tank

3. Nutsch Filter

4. Carbon Column

Aftbr primary treatment,

discharge.

Req. HRT- 12 Hrs.

Provided HRT - 23.8 Fhs.

It will be adequate

Installing of this tank isto collect effluent whichis coming from the

Installing of this tank isto Neutralize theeffluent.

Req.HRT-2FIrs.Provided HRT - 7.5 Hrs.

Nutschfi lter is typicallyused to dewater settled

sludge from plants.

is being a continuous process and waterill not being stored and sent for other

t Thus it will be adequate for said

Capacity req. - 0.67 m3/hr.Capacrty Provided -2.4 m3ltnIt will be adequate

Activatedcarboncolumnis used inthe treatment of effluentas a frnal polishingstage. In these stage thesuspended solids, COD,BOD and color will beremoved.

5. HoldingTank

Holding tank is used forcollecting the clarifiedwater from carboncolumn.

Req. HRT-6Provided HRT - 23.8

It will be adequate

it will further feed

Page2l of26

Effluent Treatment Scheme for Water from Hvdrolvsis stage

The entire effluent from the Hydrolysis process will be collected in separate collection tank

Then effluent will be acidified with Acetic acid up to 6 pH and after that the effluent will

neutralized with NaOH up to pH value 7.5 -8.0. After neutralization, effluent will be filtered

in filter press and clear effluent will be given tertiary treatment with activated carbonand

clear effluent will be sent for evaporation. Condensate water from evaporator will be reused

in the process. Based on the effluent quality sodium acetate salt will be generated as

evaporation salt which will be sold out to actual users or sent to TSDF site. Sludge from

primary treatment will be sent to TSDF site for disposal'

Units of Effluent Treatment Plant (for treatment of Hydrolysis Stage water)

Name of the unit Quantity Capacity

Collection Tank I 10m

Neutralization Tank I 5m'

Nutsch Filter I 5.0 m'

Carbon Column 2 400 mm Dia.

1.5 m Height.

Holding Tank I 10m

MEE I 40 Kl/day

Note : Multiple effect evaporator will be common for all streams.

FLOW: 9.3 KL/DAY (Hydrolysis Stream)


t. Collection Tank

Req. HRT- 12 Hrs.

Provided HRT- 25.8 Hrs.

It will be adequate


Req. HRT-2 Hrs.

Provided HRT - 12.9 F{rs.


3. Nutsch Filter

Page22 of26

4. Carbon Column

HoldingTank

After primary treatment, it will further feed in multi effective evaporation unit to achieve Zero

discharge.

Effluent Treatment Scheme for Water from washing and others

The entire effluent from the water and others will be collected in separate collection tank.

Then effluent will acidified with alum up to 6 pH and after that the effluent will neutralized

with NaOH up to pH value 7.5 -8.0. After neutralization, effluent will be filtered in filterpress and clear effluent will be given tertiary treatment with activated carbonand clear

effluent will be sent for evaporation. Condensate water from evaporator will be reused in the

process. Sludge from primary treatment along with evaporation salt will be sent to TSDF site

for disposal.

Units of Eflluent Treatment Plant (for treatment of Washing & others water)


Collection Tank "l 15 m'

Page23

being a continuous process and waternot being stored and sent for other

Thus it will be adequate for said

Nutschfilter is typicallyused to dewater settled

sludge from plants.

2 2.4m3/br Activatedcarboncolumnis used inthe treatment of effluentas a final polishingstage. In these stage thesuspended solids, COD,BOD and color will beremoved.

Capacrty req. - 0.38 m3flt.Capacrty Provided -2.4 m3lltr.It will be adequate

Req. HRT-6Provided HRT - 23.8

It will be adequate

Holding tank is used forcollecting the clarifiedwater from carboncolumn.

of26


Neutralization Tank I 5m'Filter press 24" x24" I 24x24Carbon Column I 400 mm Dia.

1.5 m Height.

Holding Tank I 15m

MEE I 40KUday

FLOW: 14.61<L{DAY (Washing & others)

1. Collection Tank


Req. HRT- 12 Hrs.

Provided HRT- 24.6Hrs.It will be adequate


3. Filter press

4. Carbon Column


Req. HRT-2 Hrs.Provided HRT- 8.2 Hrs.will be adeouate

24" x24" Req. capacity - l4.6Kl-lday.Provided capacity - 40 KLlday

Activatedcarboncolumnis used inthe treatment of effluentas a final polishingstage. In these stage thesuspended solids, COD,BOD and color will beremoved.

Capacity req. - 0.60 m3/hr.Capacity Provided -2.4 m3/hr.It will be adequate

Page24 of26

IloldingTank

Note: Condensate recover from the MEE will be further reused in manufacturing process.

ETP Diagram.

MEE DETAILS.

Req. HRT-6Provided HRT- 23.8

Itwill be

Holding tank is used forcollecting the clarified waterfrom carbon column.

For Nitrrtian Stream (t5.1 XtO)

{uld€IlsetEi€use inProrcss SodiunSallsold

out lo s{tual users d sentto TSDF

co{rdefisste fi€ure inProc€ss sodiun Salt sold

out to actrial us€rs or sPnttoTSSF

For W*hing & other Stream (ltt.6 KtDl

condensate ReuseinProcess s.lt to TSDF

€arbon €otru*u

{zl4{X}mmOit.

15 mr$ t*eight

For Hydrolysir Stream {s.l t<to}

{aIbon colurirn

{1}4Bo mm DiB.

1.5mm HeiBht

Page25 of26

lqtt1

ANNEXURE - III

Water Balance Diagram (in KLD)

FrGEh llllater21.s

To reptic Tankt.3

Water Balance Diagram Stream wise (in KLD)

lffater

21"8

f€aJi-;nil]

+*SludEe lo ,l-oB*es & SaH

TSDF

Page26 of26

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Annexure-3 Acceptance letter for disposal of hazardous and incinerable waste

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