yunus.hacettepe.edu.tr › ~damlacetin › kmu392 › index_dosyalar › explosive-industry.pdf...
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Seher BALKANLI Ayşe Dilara AYDIN
Hande GÖKBAYRAK Tuğba TUNÇEL
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WHAT IS AN EXPLOSIVE?
Reactive substances
A great amount of potential energy
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HISTORY OF EXPLOSIVES
Gunpowder First it was started to use in wars in Europe. In 17th century it was used in mining
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• 1833 Henri BRACANNOT • Flammable ester
• 1846 Christian F. SCHÖNBEİN
• Nitrocellulose
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• 1846 Ascanio SOBRERO • Nitroglycerin
• Alfred B. NOBEL • Stabilized
Nitroglycerin
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• Detonation rate • Density • Particle size • Sensitivity • Resistance of water • Characteristics of flame • Shelf life • Susceptibility to freezing
PROPERTIES OF EXPLOSIVES
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TYPES OF EXPLOSIVES
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MILITARY EXPLOSIVES
The highest explosive which is not atomic Materials: RDX, TNT… etc.
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HIGH EXPLOSIVES
PRIMARY EXPLOSIVES: Sensitive to stimuli such as impact, friction, heat, static electricity, or electromagnetic radiation. Material:Hg(ONC)₂,Pb(N3)₂ trinitroresorcinate, diazodinitrophenol,tetrazine. SECONDARY EXPLOSIVES: A secondary explosive is less sensitive than a primary explosive It’s speed is higher than the speat of voice İt burns when it ignites without shock. Material: TNT, PETN, RDX.. etc
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MANUFACTURING IN EXPLOSIVES
- TNT
- NITROGLYCERIN
-NITROCELLULOSE
- RDX
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TNT: CHARACTERISTICS AND PROPERTIES
APPERANCE: -Pale yellow solid compound,odorless -Some manufactures add graphite during the production process which turns the compound gray
SENSITIVITY: -Moderately sensitive to heat;relatively insensitive to schock and friction
CHEMICAL INTERACTIONS: -Interacts with alkalis(bases) to form very sensitive explosives -Not hygroscopic
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USES:
– Primarily mines and demolition explosives
– Also used in booster explosives and missile and rocket propellants
– Military use decreased significantly after World War II
� PRECAUTIONS:
– Toxic and can be absorbed through the skin – Can irritate the eyes, skin, and respiratory system
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MANUFACTURING OF TNT
1.NITRATION STEP 2.PURIFICATION STEP 3.FINISHING STEP
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Nitration Step in TNT Production
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NITROGLYCERIN: CHARACTERISTICS AND PROPERTIES
APPERANCE: – Colorless oily liquid when pure, but turns a yellowish-brown when impure – Sweet burning smell
SENSITIVITY: – Extremely sensitive to heat, shock, and friction
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USES: – Powerful high explosive used in dynamite, blasting gelatin, smokeless powder, and cordite – Can be used with nitrocellulose in some propellants, especially for rockets and missiles
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MANUFACTURING OF NITROGLYCERIN
1.NITRATION STEP 2.NEUTRALIZATION AND WASHING 3.SEPARATION
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NITRATION REACTION IN NITROGLYCERIN PRODUCTION
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FLOW CHART FOR NITROGLYCERIN PRODUCTION
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Characteristics, Properties, and
Overview of Nitrocllulose
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• Alternate names
-Cellulose nitrate; Flash paper; Flash cotton; Flash string; Gun cotton
• Physical Properties
- White
- Cotton-like filaments
- Odorless
- Tasteless
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C6H7O2(OH)3 + 3HONO2 + H2SO4 → C6H7O2(ONO2)3 + 3H2O +H2SO4
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• Sensitivity
- Stable under normal temperature and pressure
- Shock-sensitive
• Uses
- Explosives
- Lacquers
- Celluloid
- Inks
- Propellants
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• Chemical interactions
-Soluble in a mixture of alcohol and ether
• Precaution
- Toxicity is low
- Can irritate the eyes, skin, and respiratory system
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Characteristics, Properties, and Overview of RDX
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• Alternate names
- Cyclotrimethylene-trinitramine
- Research Department Explosive
- Royal Demolition Explosive
- Cyclonite
- Hexogen
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IUPAC name 1,3,5-Trinitroperhydro-1,3,5-triazine
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Physical Properties - White or colorless crystals - Will appear red to pink in detonating cord
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Bachman Process
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• Uses
– Primarily high explosive military warheads, mines, demolition explosives, booster explosives, missiles, and rocket propellants
– Used in civilian oil well penetrators
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• Chemical interactions
– Soluble in hot acetone or hot phenol and insoluble in water
• Precaution
– Inhaling RDX dust can cause intoxication, seizure, and loss of consciousness
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PROPELLANTS FOR ROCKETS
Rocket propellants are low
explosives which consist of
fuels which include their
own oxidant or other reactant
necessary to cause the
planned reaction.
According to the principle that
forces act equally in opposite
directions.
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LIQUID PROPELLANT
Liquid propellants are those added to the combustion chamber as liquids.
Fuel and oxidizer stored in two fuel tanks and fed separately to the combustion chamber.
Large high-performance rockets use LOX/LH₂ propellants.
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SOLID PROPELLANT
Solid-fuel rocket is a rocket with a motor that uses solid propellant. Solid-fuel rockets can remain in storage for long periods, and then reliably launch on short notice.
Solid propellant=oxidizing+fuel+ binding
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Solid propellants; -simple in design -more easy stored -easy handled -easy serviced -more cheap -used in model rokets -
Liquid propellants; -more efficient -controllable -losses in fuel tanks
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For fireworks
For medical uses medicines - Fracturing
kidney and gall stones
In demolition,the quantities of explosive used
on this type of operation vary, depending on the
size, construction and location, of the structure
to be demolished.
In rocketry
USES OF EXPLOSIVES
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For avalanche control
In automotive restraint systems to inflat Airbags
In tunneling
In mining
In agriculture industry-farmers use
explosives to break up boulders, blow tree
stumps, felling trees and loosening soil.
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ECONOMY Military explosives are usually made under conditions of secrecy and no figures of output are published.
Table 1.Consumption of industrial explosives in the world
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Table.2 U.S.A Consumption by Industry in 1977
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EXPLOSIVE INDUSTRY IN TURKEY Nitrocellulose Factory
Explosive and Propellant Factory
Small Arms Ammunition Factory
Pyrotechnics Factory
Weapons Factory
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Weapon
-Small weapon
-Heavy weapon
Ammunition
-Heavy Arms Ammunition
-Small Arms Ammunition
Rocket
Explosives
PRODUCTS
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ROKETSAN
-Land Systems,Multi Barrel Rocket
-Air Defence Systems
-Naval Systems
-Precision Guided Missiles
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