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Data File: >S1240::A6 Quant Output File: ~S124U::U1Name: 100687 HSLSU2flisc: HP'?97U-1 MbiUI384 OCCIDENTAL 100U-1ML 1-15 NGLi B ! L# <yUuant Time: 910125 16:06 Quant ID File: ID_8XA::UTInjected at: 9l012b lb:U7 Last Calibration: 91U125 13:30

Compound No: 72Compound Name: bi3t2-EthyIhexy1)phthalateScan Number: 2617Retention Time: 33.11 mm.Uuant Ion: 149.0Area: 101754Concentration: 19 . b5 ug/Lq-va1ue: 93

SEHT70L&TILE ORGANICS ANALYSIS DATA SHEETTENTAlrXVfiLx IDENTIFIED COMPOUNDS | \

.ab Name: A** i-M Contract: Kt-W™- \ / 7

.ab Code: ' $0*4' Case No.: &/?/ SAS No.: SDG No.: ^. • ... ... ,.„.,__latrix: (soil/water) k/ft'S" Lab Sample ID: /04££7 ^

jample wt/vol: b*AO (q/nL) *L Lab File ID: >5/ZV

evel: (low/med) t-6*v Date Received: I fa l<3 f

\ Moisture: not dec. / /£ dec. Date Extracted: tfa/f'

Ixtraction: (SepF/Cont/Sonc) S?/*** Date Analyzed: y^-yf/

5PC Cleanup: (Y/N) ^ pH: Dilution Factor: />d

CONCENTRATION UNITS:Number TICs found: / (ug/L or ug/Kg) y /L

CAS NUMBER

1.2.3.4.5.6.7.8 .Q

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BR307325

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Sample: 100687 HSLSU2 Operator: USER2 REG. GRP. 1/25/91 15:07Misc : HP'5970-1 MSU384 OCCIDENTAL 1000-1HL 1-15 NGG BTL# 5Sys . #: 1 MS model: 70 StJ/HU rev.: 1A ALS # : 0

Hethod file: H625SU Tuning file: MTMSD1 No. of extra records: 2Source temp.: 0 Analyzer temp.: 280 Transfer line temp. : 0

Chromatographic temperatures : 40. 300. 0. 0. 0.Chromatographic times, mm. : 4.0 31.0 0.0 0.0 0 . 0 . "^ ""*"Chromatographic rate, deg/min: 10.0 0.0 0.0 0.0 0.0

>S1240 100687 HSLSU2 HP5970-1 MSU384 OCCIDENTAL 1000-ltlL 1-

35.0 I 500.0 CLP TICUpc-lope: .20 Area Reject: 40764. Max Peaks: 1 Bunching:Dnslope: 0.00 Results File IS1240 Sorted by Time/Area INT

Peak R.T. first max last peak raw corr. corr. % offt mm. scan scan scan height area area % max. total

1 16.65 1022 1028 1032 250257 526364 525873 100.00 100.000

Sum of corrected areas! 525873.

Summary of Unknowns PBfl Library Search and Quant itat ion

Retention UnknownStandard Concentration Area Time Window

1 40.0 407639. 13.61 6.02 - 15.262 40.0 531216. 16.92 15.26 - 19.293 40.0 684529. 21.66 .. 19.29 - 23.644 40.0 726589. 25.62 "23.64 - 29.495 40.0 647192. 33.36 29.49 - 37.456 40.0 561406. 41.53 37.45 - 57.01

1'* ' Dilution Factor = 1.00 U dilf = 1.00riethod called for 1000.000 g or mL This sample was 1000.OUO g or mL

Lorrection Factor = 1.00

Cone Int StdUnknown Concentration = _ _ _ _ _ _ _ _ _ _ _ _ _ * Area Unknown * Correction Factor

Area Int Std

7:34 PM FRI., 25 JAN., 1991

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J7 101 H9 131133

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UNKNOWN #,1AREA = 525873.0 TENTATIVE CONCENTRATION IS 40.00

1. Ethanol, 2-C2-butoxyethoxy)- (8CI9CI) 162 C8H18032. Ethanol, 1-C2-butoxyethoxy)- 19CI) 162 C8H18O33. Butane, 1-methoxy- (9CI) 88 C5H1204. 2-Hexanol CSCI9CIJ 102 C6H14U5. 2-Propanol, 1-chloro- (8CI9Cn 94 C3H7C106. Propanoic acid, 2-hydroxy-, methyl ester, 1.+-.)- t9 104 C4H8O3

CI )

Sample file: >S1240 Spectrum #: 1028search speed: 1 T i l t i n g option: N No. of ion ranges searched: 41

Prob. CAS # CON # ROOT K DK ^rLG TILT X CON C_l R_1U

1. 69 112345 6643 "8IGD8 81 19 0 0 67 35 262. 53 54446785 9148 "B1GDB 66 23 0 0 46 39 193. 47* 628284 332 "BIGD8 35 46 0 0 82 37 17 364. 36* 626937 ,352 "BIGDB 38 42 2 0 100 32 12 195. 36* 127004 350 "BIGDB 38 51 2 0 100 r?6. 36* 2155308 150 "BIGDB 27 51 0 0 76 ft K

IB EPA SAMPLE NO.SEMIVOLATILE ORGANICS ANALYSIS DATA SHEET ______________,

I II 100768 |

Lab Name: BCM LABS Contract: OCCIDENTAL I____________I

b Code: BCM Case No.: 38191 SAS No.: SDG No.:

Matrix: (soil/water) SOIL ~ Lab Sample ID: 100768

Sample wt/vol: 10 (g/mL) g Lab File ID: >D2863

Level: (low/med) LOW Date Received: 1/10/91

% Moisture: not dec. 47 % dec. —- Date Extracted: 1/13/91

Extraction: (Sepf/Cont/Sonc) Sonc Date Analyzed: 1/23/91

GPC Cleanup: (Y/N) N pH: Dilution Factor: 3.0

CONCENTRATION UNITS:CAS NO. COMPOUND (ug/L or ug/Kg) ug/Kg Q

108-95-2 ——— -111-44-4 ——— -95-57-8 — ——541-73-1 —— -106-46-7 — —100-51-6 ————Q S_ SO — 1 —95-48-7 ————39638-32-9 —106-44-5 — —621-64-7 —— -67-72-1 —— —98-95—3 —— —78-59-1 — ——88-75_-b- ——— -105-67-9 — —65-85-0 —————111 Q 1 1

120-83-2 — —1 •) n Q o i _91-20-3 —— —106-47-8 —— -87-68-3 —— —59-50 7 — - ——91-57-6 —— —77-47 4 —— -88-06-2 — ——95-95-4 — ——91-58-7 -— —88-74-4 —— —131-11-3 — —208-96-8 — —606-20-2 ————

——— Phenol——— bis f 2-Chloroethyl ) Ether- ——— 2:-Chlorophenol——— 1 P 3-Dichlorobenzene——— 1 f 4-Dichlorobenzene——— Benzyl alcohol

-— -bisl 2'-cTfl6roisopropyl ) ether_— — 4-Methylphenol— — N-Nitroso-Di-n-propylamine _——— Hexachloroethane——— Nitrobenzene——— Isophorone— --2-Nitrophenol——— 2 f 4-Dimethylphenol——— Benzoic acid——— bis ( 2-Chloroethoxy Vmethane- —— 2 r 4-Dichlorophenol—— -1 f 2 , 4-Trichlorobenzene——— Naphthalene— ---4-Chloroaniline—— -Hexachlorobutadiene—— --4-Chloro-3-methylphenol——— 2-Methylnaphthalene

I-I /~\ v ~» ^™* T i"i T— f*> r* i 7 r* 1 f\ ir\tst i*> t- -^ i*^ T n KI o

——— 2 , 4 , 6-Trichloropheriol- ——— 2 f 4 f 5-Trichlorophenol——— 2-Chloronaphthalene— , — 2-Nitroaniline——— Dime thy Iphthalate——— AcenaphtKylene——— 2r 6-Dinitrotoluene

1900.1900 .1900 .1900 .1900.1900.1900.1900.1900.1900.1900.1900 .1900 .1900.1900.1900.9500 .1900 .1900.1900.1900.1900.1900.1900 .1900.1900 .1900 .9500.1900.9500.1900.1900.1900.

UUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUU

FORM I SV-1 .. ••• o 1/87 Rev.

Continuing Calibration CheckHSL Compounds

Case No: Calibration Date: 01/21/91

Contractor: BO1 LABS ' Tine: 17:41

Contract No: Laboratory ID: >D2833

Instrument ID: HP5970-1 Initial Calibration Date: fll/21/91e

ninimm RF for SPCC is 0.05 fexiMM X Oiff for CCC is 25*_Compound RF RF XOiff CCC SPCC

N-Nitrosodi«ethyi8Bii» .84333 .77599 7.982-Fluorophenol SA 1.16112 1.14546 1.35Phenol-d6 SA 1.47881 1.45037 1.92Phenol 1.57617 1.54873 1.74 •bts(2-Chloroethyi)ether 1.66932 1.72710 3.462-Chiorophenol 1.34674 1.34494 .131,3-Oichlorobenzene 1.39181 1.43780 3.301,4-Dichlorobenzene 1.36730 1.44991 6.04 *Benzyl alcohol .82991 .71943 13.311,2-Dichlorobenzena 1.34661 1.43210 6.352-Methylphenol 1.14076 1.10463 3.17bis(2-Chloroisopropyl)ether 2.52852 2.69030 6.404-tlethylphenol 1.15575 1.20061 3.88K-Nitroso-di-n-propylaiine 1.09519 1.05088 4.05 ««Hexachloroethane .65230 .68103 4.40Nitrobenzene-d5 S8 .41577 .42447 2.09Nitrobenzene .41019 .42473 3.54Isophorone .82256 .86007 4.562-Nitrophenol .22559 .21552 4.46 *2,4-OiMthylphenol .31899 .36176 13.41Benzoic acid .16697 .19896 19.16bis(2-Chloroethoxy)Mthane .50073 .54664 9.172,4-Dichlorophenol .29931 .32354 8.10 *1,2,4-Trichlorobenzene .30840 .33876 9.84Naphthalene .89473 .99902 11.664-Chloroaniline .31678 .18503 41.59Hexachlorobutadiene .17022 .18534 8.88 *4-Chloro-3-iethylphenol .32722 .34647 5.88 *2-Hethylnaphthalene .57976 .64559 11.35Hexachlorocyclopentadiene .28037 .28573 1.91 **2,4,6-Trichlorophenol .37547 .37141 1.08 *2,4,5-Trichlorophenol .38564 .41103 6.58

RF - Response Factor froi daily standard file at 50.00 ug/L

RF - Average Response Factor from Initial Calibration For* UI

XOiff - IK Difference froi original average or curve

CCC - Calibration Check Compounds (*) SPCC - Systei Performance Check Compounds (**)

For* UII Page 1 of 3

Dmtinuing Calibration CheckHSL Conpounds


Contractor: BCH LABS • Time: 17:41

Contract No: Laboratory ID: >02833

Instrument ID: HP5970-1 Initial Calibration Date:

RF for SPCC is 0.05 Haxinui % Diff for CCC is 25X

Coipound R? RF XOiff CCC SPCC

2-Chloronaphthalene 1.06099 1.14437 7.862-Fluorobiphenyl SB 1.16113 1.24475 7.202-Nitroaniline .46607 .45858 1.61Diaethylphthalate 1.32087 1.38967 5.21Acenaphthylene 1.69196 1.84090 8.803-Nitroaniline .05729 .03606 37.06Acenaphthene 1.017641.13380 11.42 «2,4-Oinitrophenol .13161 .12135 7.80 »*4-Nitrophenol .12793 .11948 6.61 ** (Cone-50.00)Dibenzofuran 1.33180 1.47079 10.442,4-Oinitrotoluene .40366 .42821 6.082,6-Oinitrotoluene .36121 .34703 3.92 'Diethylphthalate 1.35471 1.47025 8.534-Chlorophenyl-phenylether .57618 .61747 7.17Fluorene 1.12934 1.22877 8.804-Nitroaniline .16816 .22135 31.632,4,6-Tribroraophenol SA .20009 .18779 6.154,6-Dinitro-2-iethylphenol .15629 .15119 3.27N-Nitrosodiphenyta»ine (1) .45656 .39924 12.56 »4-Bromophenyl-phenylether .22624 .23400 3.43Hexachlorobenzene .26384 .28278 7.18Pentachlorophenol .13948 .11328 18.78 *Phenanthrene 1.01834 1.09977 8.00Anthracene 1.01906 1.15952 13.781,2-Diphenylhydrazine .92292 1.00847 9.27Di-n-butylphthalate 1.30304 1.67945 28.89Fluoranthene 1.06937 1.24391 16.32 *Pyrene 1.47233 1.50518 2.23Benzidine .01778 .01433 19.41 (Conc«50.00)Terphenyl-dl4 SB .93733 1.00268 6.97Butylbenzylphthalate .80997 .84728 4.613,3'-Dichlorobenzidine .17005 .17895 5.23

RF - Response Factor froi daily standard file at 50.00 ug/L

RF - Average Response Factor fro* Initial Calibration For* Ul

XDiff - % Difference froi original average or curve

CCC - Calibration Check Compounds (») SPCC - Syste* Perforiance Check Coapounds («*) QOQ&29

Foni UII Page 2 of 3



Contractor: BCM LABS • Tiie: 17:41

Contract No: Laboratory ID: >D2833

Instrument ID: HP5970-1 Initial Calibration Date: •&&&»: S-2T-9/usniniium R for SPCC is 0.05 rtaximu* X Oiff for CCC is 25X r 4, ' •-•

1 '*' '•' *'

Compound RF RF XDiff CCC SPCC

Benzo(a)anthraceneChrysenebis(2-Ethyihexyl )phthalateOi-n-octylphthalateBenzo(b ) f 1 uorantheneBenzo (k ) f luorantheneBenzo(a)pyreneIndeno ( 1 ,2 ,3-cd )pyreneDtbenz(a,h)anthraceneBenzo(g,h, i )perylene

1.10974 1.135491.00139 1.045621.03177 1.226892.13713 2.188741.23327 1.175721.13462 1.130831.08155 1.07686.97961 1.07804.82025 .90977.81894 .91400

•MM***

2.324.4218.912.414.67.33.43

10.0510.9111.61

RF - Response Factor fro* daily standard file at 50.00 ug/L

RF - Average Response Factor fro* Initial Calibration For* UI

XDiff - X Difference froi original average or curve

CCC - Calibration Check Compounds (•) SPCC - Systei Performance Check Compounds (**)

For* UII Page 3 of 3

.. i.

•

QUANT REPORT

Jperator ID: EAG Quant Rev: 6 Quant Time: 910121 18:39Output File: /XD2833::D1 Injected at: 910121 17:41Data File: >D2833:':D4 Dilution Factor: 1.00000Name: 50 PPM SNA STDMisc: 1UL INJ (5-36-3) BTL* 1

ID File: ID_BXA::QTTitle: HP SNA StandardsLast Calibration: 910121 11:20

Compound R.T. Scan* Area Cone Units q

1) *l,4-Dichlorobenzene-d4 IS 13.66 739 90839 40.00 ug/L 962) N-Nitrosodimethylamine 7.24 121 88113 50.07 ug/L 883) 2-Fluorophenol SA 10.57 442 130066 51.61 ug/L 964) Phenol-d6 SA 12.75 651 164688 51.38 ug/L 955.) Phenol 12.78 654 175856 50.04 ug/L 966) bis(2-Chloroethyl)ether 13.00 675 196110 51.06 ug/L 9971 2-Chlorophenol 13.21 695 152716 50.63 ug/L 988) 1,3-Dichiorobenzene 13.58 731 163260 50.83 ug/L 999) 1,4-Dichlorobenzene 13.71 743 164636 51.25 ug/L 9710) Benzyl alcohol 13.99 770 81690 48.28 ug/L, 841) 1,2-Dichlorobenzene 14.18 789 162613 51.54 ug/L 942) 2-Methylphenol 14.27 797 125429 49.14 ug/L 93•5) bis(2-Chloroisopropyl )ether 14.38 808 305480 48.85 ug/L 934) 4-Methylphenol 14.62 831 136328 53.22 ug/L 91

I1?) N-Ni troso-di-n-propylamme 14.73 841 119326 47.40 ug/L 9416) Hexachloroethane 15.00 867 77330 49.85 ug/L 91I.-3) *Naphthalene-d8 IS 16.98 1057 321920 40.00 ug/L 9818) Nitrobenzene-d5 SB 15.11 878 170806 53.85 ug/L 79IV) Nitrobenzene " 15.15 882 170912 52.51 ug/L 94"20) Isophorone 15.75 939 346092 52.59 ug/L 9421) 2-Nitrophenol 15.99 962 86725M 43.44 ug/L 9522) 2,4-Dimethylphenol 16.01 964 145571 54.91 ug/L 932?) Benzoic acid 16.24 986 80063 61.39 ug/L 9724) bis(2-Chloroethoxy)methane 16.26 988 219969 53.45 ug/L 9521?) 2,4-Dichlorophenol 16.59 1020 130194 54.28 ug/L 8926) 1,2,4-Trichlorobenzene 16.85 1045 136318 52.76 ug/L 9427) Naphthalene ' 17.04 1063 402006 53.15 ug/L 9828) 4-Chloroani1 me 17.17 1075 74455 74.27 ug/L 9929) Hexachlorobutadiene 17.49 1106 74580 53.76 ug/L 9630) 4-Chloro-3-methylphenol 18.36 1190 139421 52.78 ug/L 9231) 2-Methylnaphthalene 18.86 1238 259784 54.29 ug/L 9732) *Acenaphthene-dlO IS 21.73 1513 180487 40.00 ug/L 9673) Hexachiorocyclopentadiene 19.47 1296 64463 52.22 ug/L 9934) 2,4,6-Tnchlorophenol 19.65 1313 83794 51.53 ug/L 933«) 2 ,4,5-Trict-florop'henal 19.75 1323 92731 54.71 ug/L 9936) 2-Chloronaphthalene 20.18 1364 258180 53.52 ug/L 95) 2-Fluorobiphenyl SB 19.84 1332 280826 54.39 ug/L 94) 2-Nitroaniline 20.45 1390 103459 60.60 ug/L 86

9) Dimethylphthalate 20.95 1438 313521 53.39 ug/L 9940) Acenaphthylene 21.32 1474 415324 53.97 ug/L 9441) 3-Nitroaniline 21.56 1497 8135 65.30 ug/L 7942) Acenaphthene 21.81 1521 255796 53.92 ug/L 9743) 2,4-Dinitrophenol 21.81 1521 M j ff f$ 3 if 3 • 45 "9/Le -omjo jA

Compound R.T. Scan* Area Cone Units

44) 4-Nitrophenol 21.90 1529 26955 65.83 ug/L 9445) Dibenzofuran ' 22.23 1561 331823 54.34 ug/L 9746) 2,4-Dinitrotoluene 22.22 1560 96609 53.69 ug/L 9347) 2,6-Dinitrotoluene 21.16 1458 78293 52.79 ug/L 9448) Diethylphthalate 22.82 1618 331702 53.26 ug/L 9149) 4-Chlorophenyl-phenylether 23.09 1643 139306 52.42 ug/L 9450) Fluorene 23.17 1651 277221 52.90 ug/L 9151) 4-Nitroaniline 23.23 1657 49939 84.76 ug/L 9552) 2,4,6-Tribromophenol SA23.85 1716 42366 53.64 ug/L 9853) *Phenanthrene-dlO IS 25.70 1894 279996 40.00 ug/L 9354) 4,6-Dinitro-2-methylphenol 23.33 1666 52914 50.46 ug/L 9855) N-Nitrosodiphenylamine (1) 23.40 1673 139732 55.66 ug/L 9656) 4-Bromophenyl-phenylether 24.40 1769 81898 54.15 ug/L 9157) Hexachlorobenzene 24.88 1815 98973 53.26 ug/L 9658) Pentachlorophenol 25.32 1857 39647 46.92 ug/L 9859) Phenanthrene 25.77 1900 384914 52.58 ug/L 9660) Anthracene 25.89 1912 405825 56.12 ug/L 9861) 1,2-Diphenylhydrazme 23.51 1684 352960 53.47 ug/L 9362) Di-n-butylphthalate 27.14 2032 587799 54.76 ug/L 9663) Fluoranthene 28.99 2210 435361 53.78 ug/L 9264) *Chrysene-dl2 IS 33.53 2645 229665 40.00 ug/L 95.65) Pyrene 29.63 2271 432108 46.15 ug/L .£566) Benzidme 29.23 2233 4114M 94.69 ug/L67) Terphenyl-dl4 SB 29.90 2297 287852 48.52 ug/L68) Butylbenzylphthalate 31.24 2425 243237 46.54 ug/L 9069) 3,3 '-Dichlorobenzidme 33.23 2616 51373 75.29 ug/L 9270) Benzo(a)anthracene 33.46 2638 325977 51.87 ug/L 9771) Chrysene 33.63 2655 300177 52.42 ug/L 9872) bis(2-Ethylhexyl)phthalate 33.25 2618 352216 47.35 ug/L 93,75) *P«rylene-dl2 IS 41.91 3450 203704 40.00 ug/L 9874) Di-n-octylphthalate 36.13 2895 557319 45.21 ug/L 10075) BenzoCb)fluoranthene 39.17 3187 299373 48.86 ug/L 9576) Benzo(k)fluoranthene 39.32 3201 287944 48.96 ug/L 997-7) Benzo(a)pyrene 41.49 3410 274201 52.32 ug/L 8778) Indeno(l,2,3-cd)pyrene 52.30 4448 274501 68.04 ug/L 6279) Dibenz(a,h)anthracene 52.44 4461 231656 70.15 ug/L 8380) Benzo(g,h,iJperylene 55.48 4753 232733 68.29 ug/L 82

* Compound is ISTD

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Data File: >D2833::D4 Quant Output File: /SD2833::D1Name: 50 PPM SNA STDMTSC: 1UL INJ (5-36-3) BTL* 1

Id F i1e: ID_BXA::QTTitle: HP SNA StandardsLast Calibration: 910121 11:20

Operator ID: EAGQuant Time: 910121 18:39Injected at: 910121 17:41

000833HR307336



Contractor: BO1 LflBS Time: U9:16

Contract No: Laboratory 10: >S1234

Instrument ID: HH5970-1 Initial Calibration Date: 01/21/91

Ilinimun RF for SPCC is 0.05 Kaximum % Diff for CCC is 25S

Compound RF RF Miff CCC SPCC

N-Nitrosodimethylamne .82647 .77915 5.722-Fluorophenol Sft 1.03523 1.068/6 3.24Phenol-d6 Sfl 1.36620 1.41)055 2.51Phenol 1.47523 1.520U2 3.U4 *bist2-Chloroethyl)ether 1.39761 1.48158 6.012-Chlorophenol 1.27553 1.32574 3.941,3-Dichlorobenzene 1.35358 1.48497 9.711,4-Dichlorobenzene 1.34U1H 1.49543 11.58 *Benzyl alcohol .80435 .33562 3.891,2-Dichlorobenzene 1.328/6 1.44815 8.982-Hethylphenol 1.09879 1.17383 6.83bis(2-Chloroisopropyl)ether 2.57363 2.61749 l./'fl4-nethylphenol 1.14078 1.20216 5.38N-Nitroso-di-n-propylaaine 1.14314 1.15273 .84 »»Hexachloroethane .66953 .,'3658 18.02Nitrcbenzene-d5 SB .41617 .4U87? 1.78Nitrobenzene .41501 .41193 .74Isophorone .83512 .81766 2.1192-Nitrophenol .24692 .22501 8.88 *2,4-01 methyl phenol .31492 .J4>1!8 H.94Senzoic acid .13210 .19106 44.63b;sr2-Di!oroethoxy>methane .48388 .48/1)8 .662,4-Oichlorophenol .32150 .32964 2.53 *1,2,4-InchIorobenzene .34467 .37139 /.75Naphthalene .92082 .98498 6.974-Chloroanihne .28657 .29159 1.75Hexachlorobutadiene .24009 .25942 8.05 *i-Chloro-3-methylpnenol .33685 .35420 5.15 *2-Hethy[naphthalene .59739 .66202 10.82Hexachlorocyclopentadiene .45257 .46925 3.69 **:,.*,6-iricn!oropnenol .;b'ol2 .,lV8o2 3.29 *2,4,5-lrichlorophenol .38876 .42283 d.76

KF - Kesponse Factor from daily standard File at Sfl.UU ug/L

Rh - ftwerage Response Factor froai Initial Calibration Form Ul

SUiff - % Difference froa original average or curve

CCC - Calibration Check Compounds (*) SPCC - Systei Performance Check Compounds (»*) QGOS70

FormUll Page 1 of 3 AR307337


No: Calibration Date: 01/25/91

Contractor: BCM LABS Time: 09:16

Contract No: Laboratory ID: >S1234

Instrument ID: HP597Q-1 Initial Calibration Date: 01/21/91

rtiniBua RF for SPCC is 0.05 tlaxiMii % Oiff for CCC is 25X

Conpound R? RF XOiff CCC SPCC

2-Chloronaphthalene 1.00594 1.07748 7.112-Fluorobiphenyl SB 1.12960 1.19435 5.732-Nitroanihne .40092 .41557 3.65Uimethylphthalate 1.29933 1.40127 7.85ftcenaphthylene 1.61403 1.77309 9.853-Nitroanihne .05256 .06059 15.28ftcenaphthene .97889 1.06878 9.18 *2,4-lhnitrophenol .15496 .18768 21.11 **4-Nitrophenol .14353 .17238 20.10 " -(Conc=50.0U)Oibenzofuran 1.34270 1.48362 10.50

«tnitrotoluene .39863 .43619 9.42mitrotoluene .35291 .36131 2.38ylphthalate 1.37315 1.53581 11.85

4-CMorophenyl-phenylether .62366 .71232 14.22Fluorene 1.11383 1.25417 12.604-Nitroanihne .17169 .19008 10.712,4,6-rnbromophenoi Sft .29037 .34233 17.904,6-Oinitro-2-methy[phenol .17420 .17243 1.02N-Nitrosodiphenylamine (1) .36333 .36660 .90 *4-brcmophenyl-phenylether .25277 .25131 .58Hexachlorobenzene .33655 .32928 2.16Pentachlorophenol .16559 720667 24.81 *Phenanthrene .98413 1.04711 6.40finthracene .98333 1.09207 11.061,2-Diphenylhydrazine .31918 .81538 .46Ui-n-butylphthalate 1.39022 1.43552 3.26Flucranthene " 1.11366 1.32140 18.65 *Pyrene 1.26983 1.18923 6.35Benzidine .00669 .01021 52.68 (Conc=5fl.OO)!erphenyl-dl4 SB .93098 .93368 .29c^ty.senzyiphthalate .65937 .5916U 10^233,3''-Qichlorobenzidine .17791 .18283 2.77

KF - Response Factor from daily standard file at 50.00 ug/L

- ftverage Response Factor from Initial Calibration Form Ul

XUiff - % Difference from original average or curve

- Calibration Check Compounds (*) SPCC - System Performance Check Compounds (**) r\nr\c~i-*OOOOVl

Forn" UII Page 2 of 3



Contractor: BCM LflBS Time: 09:16

Contract No: Laboratory ID: >S1234

Instrument ID: HP5970-1 Initial Calibration Date: 01/21/91

Minimum RF for SPCC is 0.05 Haximui X Diff for CCC is 25X

Compound R? RF XOiff CCC SPCC

Benzota)anthracene 1.07260 1.07060 .19Chrysene .96529 .98567 2.11tns(2-Ethylhexyl)phthalate .92017 .81888 11.01Ui-n-octylphthalate 1.71093 1.43157 16.33 *8enzolb)f luoranthene 1.14814 1.18699 3.38Benzotk)fluoranthene 1.04926 1.37239 2.206enzo(a)pyrene 1.02714 1.02945 .23 *Indeno(l,2,3-cd)pyrene 1.10535 1.04227 5.71Dibenz(a,h)anthracene .93775 .39599 4.45Benzotg,h,i)perylene .95611 .3891)3 7.02

SF - Response Factor from daily stanoard file at 5U.UO ug/L

RF - flverage Response Factor from Initial Calibration Form Ul

tthff - X Difference froa original average or curve

CCC - Calibration Check Compounds (») SPCC - System Performance Check Compounds (**) QQQ872

Form Ul 1 Page 3 of 3 SR307339

iSPTr

QUANT REPORT

irator ID: USLR2 IJuant Kev: 6 yuant !'i rne : 910125 10:15Liutput F i l e : 'SS1234::O1 . " Injected at: 910125 09:16Data r" i 1 e: ">S1234::A6 - Dilution Factor: 1.00000r-J.Bn.s: 5!J-PPI"I B'NA S'l U .._. . - --- - - - _-riisc: 1UL INJ (5-36-3) - , 1. . _ .. . . ' ". " " .-. B ! L# 1

ID F i ie : ID_BXfl: : iJT """ """" " _. " .".T i t l e : HP "SNA Standards,Last Calibration: 910124 10:03

Compound Ff. T. Scan# Area Cone Units q

1) * 1 ,4-DichIorobenzene-d4 IS 13.60 738 72570 4U.OO ug/L 942) N-Ni t rosod imethy lamme 7.21 120 70679 49.30 ug/L 953) 2-f-"luoropheno 1 "~" " SA 10.52 440 " 96950 51.25 ug/L 98•4) r'henol-d6 SA 12.68 649 127047 49.72 ug/L 955) Phenol - -- - - 12.72 653 137885 48.77 ug/L 96o) D is C2-Lh loroejhy 1 Jether 12.95 675 134398 50.17 ug/L 997) 2-iJn'loroph'enbT"""" 13.15 694 120261 50.72 ug/L 9785 1,3-Dichlorobenzene 13.52 730 134/05 51.53 ug/L 939) 1,4-Dichlorobenzene 13.64 742 135654 50.29 ug/L 9710) Benzyl alcohol ;._ . 13.92 769 75301 50.65 ug/L 87

i ,2-Dichlorobenzene ' 14.12 78« "13136V 50.91 ug/L 932-HethyIpheno1 14.20 796 106481 50.17 ug/L 38b ist2-Ch loroi sop rop"y"U ether "" 14.33 803 237439 51.14 ug.-L 914-riethy Ipheno 1 ' 14.57 831 109051 50. o3 ug/L 91

15.' fi-N i t roso-d i -n-p ropy 1 am i ne " 14.63 842 104567 51.50 ug/L 9716) ,-iexach 1 o roe t hane 14.94 " 867 66317 ^2.08 ug/L 9517? *r:.3ph tha lene-.dB - - -IS 16.92 1U58 280739 40.00 ug/L 9918; :<i t robenzene-d5' • SB 15.04 "377" 143446 " 51.47 ug/L 76

r;;trobenzene - .:_... 15.10 882 144556 50.09 ug<-L 94liophorone 15.70 941J 236935 ^1.81 ug/L 94

21.' 2 M i t r o p h e n o l ~ 15.92 9o2 "78960 41 . 65 ug--L 9222) . 2,4-L)imethylphenoi " 15.94 964 120394 52.20 ug/L 9323 ' 'bonzoic acid __ 16.18 987 67048 5JO . 23 ug/L 9224i -_ is, '. 2-Lh loroethox^yTrneThane 16.20 989 . 170927 50.95 ug/L 952cr i 2 ,4-Dich lorophenoi. 16.54 1U21 115677 51.78 ug/L 3326) 1,2,4- I" rich lorobenzene 16". 79" 1046 130331 50.48 ug/L 9727.i N.-jphtha lene . _ . . ... 16.98 1064 345654 51.16 ug/L 9928 J -*-Lh loroani 1 me - -17.09 1074 102326 46 . /I ug/L 992>J ' -?... acn lorobutad lene 17.43 1107 91035 53.50 ug/L 9730 J -.-!_!-, loro-3-methy Ipheno 1 13.30 1191 124296 I?2.ii6 ug/L 93; 1 > J riethylnaphtha'lene . 18.79 1239 232317 51.04 ug/L 96.2; - -.-enaph t. hene-d 10 • - : IS 21.66 1515 135'-: 6 4 4U.-U ug/L 9933; Haxachlorocyc1 open tadlene 19.41 1298 109021 50.61 ug/L 9934; 2 ,4,6- l"r ich'lorophenol " " 19.57 1314 92653 51.22 ug/L 9335;- 2 ,4 /;. - i r ich loropheno"1" 19.68 1324 98236 51.5^ ug/L 97363 2-Ch loronaphthalene - 20.11 1366 250330 ^1.81 ug/L 95

2 rluorobipheny1 SB 19.78 1334 2/7484 50.39 ug/L 922-Hitroani1 me 20.38 1392 96550 50.67 ug/L 331 imejthy iphtha late - - - - - ..__2'J". 39 1441 325557 52.94 ug/L 99

40) Acenaphthylene 21.25 1476 411943 50.34 ug/L 9341) 3-Nit roani1 me 21.48 1498 14076 46.62 ug/L 8842) Acenaphthene ~ 21.75 1524 248309 52. QOOQ CS4>; 2 ,4-Umi tropheno 1 ~"~" 21.74 1523 43603 51.9V u

V '' M l

Compound " H. I'. Bcan^ Area Lone Units

44) 4-Nitropheno1 21.81 1530 40050 53.49 ug/L45") DibehzoFuran 22.17 1564 344689 51.36 ug/L46) 2 ,4-Dm i t roto Tuene . 22.15 1562 101339 50.41 ug/L47) 2 ,6-Dmi t roto luene 21.10 1461 83943 52.57 ug/L->3) Die thy Iphtha late 22.76 1621 356315" 51.26 ug/L49) 4-ChlorophenyT-phenyTether "23.02 1646 165493 52.56 ug/L50) Fluorene 23.10 1654 291381 51.69 ug/L51) 4-Ni t roam 1 me 23.12 1656 44161 45.65 ug/L52) 2,4,6-Tnbromopheno1 SA 23.77 1719 79534 51.86 ug/L53) *Phenanthrene-dl"0 IS 25 . 62 1897 349136 40.00 ug/L54) 4,6-0mitro-2-methyIpheno1 23.26 1669 75252 48.31 ug/L55) N-Ni t rosod ipheny larnme CD 23.33 16/6 159990 51.46 ug/L56) 4-Bromophenyl-phenylether 24.32 1772 109678 46.46 ug/L571 Hexachlorobenzene 24.SI 1819 143706 45.19 ug/L58) Pentachlorophenoi 25.23 1359 90194M 51.50 ug/L59 ' Phenanthrene """ 25.69 1904 45697S 49.41 ug/LoO) Anthracene 25.31 1915 476599 51.17 ug/L61) 1,2-DiphenyIhydrazme 23.45 1688 355846 49.58 ug/L62) Ui-n-butyIphthalate 27.06 2036 626483 46.94 ug/L63) Fluoranthene 28.91 2214 576685 49.00 ug/L64) *!2hrysene-dl2 IS 33.38 2644 399987 40.00 ug/L65) Pyrene 29.54 2275 594597 48.15 ug/L66) Benzidme 29.12 2234 5104 42.60 ug/L67) Terpheny 1-d 14.. -- SB 29.81 2301 466825 47.21 ug/L68) Butylbenzyiphthalate 31.14 2429 295789 47.02 ug/L6^ .! J ,3 '-Uich lorobenz id me 33.05 2613 91412 51.01 ug/L70) Benzo (.a )anthracene 33.29 2636 535283 49.29 ug/L71,' Lhrysene - 33.48 2654 492818 49.49 ug/L72) b is 12-t.thy Ihexy 1 )phtha late 33.11 2619 409428 50.0/ ug/L77; *!-•.•? ry i ene-d 12. . IS 41.56 3433 357541 40.00 ug/L"'4) LJi-n-octy Iphtha late 35.95 2892 639805 48.83 ug/L'5' b.::nzo ib .U lucranthene 38.33 3175 530495 49.35 ug/L."'6) Be nzo(k)f luoranthene 39.04 3190 479277 46.47 ug/L

B'-nzc Ca jpyrene"" "" 41.15 3393 460039 49.26 ug/L. o ) Ir.deno C 1 ,2 ,3-cd Jpyrene 51.65 4406 465319M 47.92 ug/L79,' L-ibenz ta ,h )anthracene 51.81 4422 4U0443 ^8.14 ug/L30) BenzoCg,h,i)perylene 54.76 4706 397332 48.13 ug/L

•* Lornpound is IS ID

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Data F i Te : >' S12 3 4 : : A6""" U'u an t Uu't p u t File: /SS12 3 4 : : U1Name: 50 HHfl BNA BIDHisc: 1UL 1N.J (.5-36-3) _. . B! L# 1

1 d h i 1 e : i D_BXA : : UJ Ti i t l e : HP BNA St an"d"a"rds - "Last Calibration: 910124 10:03

Operator ID: UShH2 . "Quant i i r n e : 91 u 125 ..10:15Injected at: 910125 09:16

3830731*2 °°087S

rF"iT""".-u£2£5 r?7.r-19S.7 amu.50"(3 DFTPP 1UL INJI tlPI 328 33Q 343 358 368

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1UL IH-J Scan 3*1fia ISO. NRn 10.55 min.

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50 100 153 200 258 388 350 480

GC/MS PERFORMANCE STANDARD

Deca f luorotriphenylphospine (DFTPP)

* Relative AbundanceIon Abundance Base Appropriate

m/z Criteria Peak Peak Status

51 30-60* of mass 198 55.09 55.09 Ok68 Less than 2* of mass 69 0.00 0.00 Ok69 (reference only) 63.26 63.26 'Ok "70 Less than 2* of mass 69 .27 .42 Ok127 40-60* of mass 198 46.37 46.37 Ok197 Less than 1* of mass 198 0.00 0.00 ...Ok,198 Base peak, 100* relative abundance 100.00 100.00 ^Bk199 5-9* of mass 198 6.42 6.42 Ok275 10-30* of mass 198 20.65 20.65 Ok565 Greater than 1* of mass 198 2.00 2.00 Ok441 0-100* of mass 443 8.94 76.29 Ok442 Greater than 40* of mass 198 60.85 60.35 Ok443 17-23* of mass 442 11.72 19.27 Ok

Injection Date: 01/21/91Injection Time: 09:23

Data File: >D2825Scan: 341

000907

F'lGP :•' TAB

D2B2? 5QNG DFTPP 1UL INJ-"'41 NRM

f - i l e : :•• 02825 "Scan #: "" 341 Retn. time: 10.55

m/s. Int. m/z Int. m/z Int. m/z Int. m/z Int.

37.00 .287 94.00 .347 152.15 .155 203.05 .591 276.95 1.41038.00 .859 95.00 .226 153.05 .674 204.05 2.784 277.95 .22339.00 5.627 96.00 .348 154.05 .511 205.05 4.788 281.05 .19840.00 .927 98.00 3.457 155.05 1.161 206.05 19.948 283.05 .18741.00 .591 99.00 2.803 156.05 1.821 207.05 3.185 235.05 .3044.5.10 .452 100.00 .348 157.05 .345 208.05 .632 293.05 .24044.00 .726 101.00 1.758 157.95 .365 209.05 .285 296.05 4.45144.VO .263 103.00 .596 159.05 .301 211.05 .772 297.05 .66850.00 13.991 104.00 1^.115 159.95 . .715 212.05. .116 303.05 .6295 L . U U 55. 094 "105. 00 'i .137? 161,05 .900 215. Of" .226 304. U5 .17952.00 2.710 107.00 12.694 162.05 .315 216.V5 5.441 314.05 .22757.GQ .215 108.00 T._918 162.85 .104 218.05 .736 315.05 .47755.00' .543 110700 31.2U5 16.4.05 .151 221.U5 6.926 321.05 .12956.00 1.826 111.00 4.156 164..95 . .795 223.05 1.270 323.05 1.567.57. UO 4.399" 112.00 .497 166.05 ' .665 224.05 11.231 324.05 .2515.'7.0Q .190 '117. 00 _~H,581 167.05.." 4/076 225.05 2.718 327.05 .31460.90 .673 117.90 . oU9 168.05 1.719 227.05 4.318 331.95 .10062. t'lj .641 122.00 .547 "168. 95 ...271 228.05 .587 3:?4.05 .92463. 'JO 2.02? 123.00 1.391" i?0.75 .220 229.05 " .974 ?35.05 .20964.i:!l .262 123.90 ".~6"34 172.05 .419 231.05 .394 341.05 .22365.:.'0 . *65 125.00 ..- 6 173.05 .471 235.05 .317 346. 05 .339t.'.i'J .198 127.05" 46.374 173'. 95 .899 237.05" .322 352.05 .51069.00 63.262 128.05 .< . 742 175.05 1.521 239.05 .143 ?53 . 05 .332"".i.UU" .268 129.05 .I* . <-^3 175.95 .552 241.05' .231 354.05 .4997l.UO .158 130.05 1.647 177.05 . .850 242.05 .544 355.05 .215"'•.'JO" 2.062 131.05 " .229' 179. 05 ...3,130 243.05 .671 364.95 2.00474.00. 4.448 132/05 .169 180.05 2.029 244.05 - 9.228 365.95 .279."->.U!J 7.553 "rJ279~'r~ . 19'6 iyi.05 .944 245.05, 1.267 ?72.05 .947"6.10 2.514 "134. ii5 "".439 131.95 .104 246.05 1.619 373.05 .169""7.OU 4?. 026 135.05 1.626 164.05 .215 2-46.95" .290 383.10 .270•'9.00.. 3.. 262 136.05 ".508 135.05 1.520 2-47.95 .114 J-90.10 .1337*.'.Mr 5.124 137.05 .oOl 186.05 11.766 248.95... .343 401.10 .174••30.'JO 2.578 138.U5 "7 146 187.05 3.113 253 . U5 .191 -402.10 .398o L . !.'!.!- -il.803 178.95 .114 188.05 .381'255. 05 4.2.. 083 4U3.10 .560

1.1121 L 40.115" .274 189.05 .656 256.05 5.966 404.00 .163.93? 1.41.!.'15 V'7 1?9 'j^l.O^ .780 •I"'-7.0c; .496 421.10 .340.102 142.05 .-359 192.05 .976 258.05 2.193 422.10 .402

y^ . U :.' . 728 143 . 05 . ?6 0 193 .05 1. 041 259 . 05 . . 295 423 .10 3 . 526i-rib.uO .886 146.15 .397 194.05 .177 265.05 .828 424.10 .743y.-'.UU ..375 147. tl^ 1.J17 196.05 5.256 265.95 .140 441.Ill 8.94488.00 .130 148.05"" 2.186 197.95 100.000 273.05 1.327 442.10 60.853'-•I.UU .386 149.05 ,516 198.95 6.416. 274.05 3.640 443.10 11.724'32.!JO .723 151.05 .367 199.95 .381 275 . U5 20.646 444.10 1.016V5.00 57113 151/65 .227 201.35 .56? 276.05 2.840

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% Relative Abundanceon Hbundance Base Appropriatem/z Criteria Peak Peak Status

51 30-60* of mass 198 55.07 55.07 Ok68 Less than 2* of mass 69 0.00 0.00 OR.69 (reference only) 64.36 64.36 Ok "•-'Q Less than 2* of mass 69 .35 .55 Ok127 40-60% of mass 198 44.93 44.93 Ok1V7 Less than 1* of mass 198 0.00 0.00198 Base peak, 100* relative abundance 100.00 100.00IV* 5-9* of mass 198 6.73 6.73 Ok275 10-30% of mass 198 20.48 20.48 Ok/t5 Greater than 1* of mass 198 1.82 1.82 Ok441 0-100% of mass 443 8.74 79.57 Ok-4-,i Greater than 40* of mass 198 56.04 56.04 Ok•*4/. 17-23% of mass 442 10.98 19.60 Ok


Data FiIs: >D2832Scan: 338

000909

«l

.,GR : FAB

!..'2S32 50NG DFTPP 1UL I N J338 NRM

Fi le:. >D2832 Scan #: ?38 Retn. time: 10.50

m/z Int. m/z Int. m/z Int. m/z Int. m/z Int.

35.90 .163 93.90 .364 151.05 .297 199.05 6.725 265.05 .87437.00 . .186 96.10 .301 151.75 .261 200.05 .443 271.05 .15438.00 .800 98.00 3.498 153.05 .641 201.45 .591 273.05 1.28639.00 5.553 99.00 2.919 154.05 .521 203.05 .519 274.05 3.57340.00 .718 100.00 .310 155.05 1.113 204.05 2.984 275.05 20.48341.00 .333 101.00 1.948 156.05 1.598 205.05 4.851 276.05 2.52443.00 .286 102.10 .163 157.15 .428 206.05 20.217 277.05 1.39544.00 .664 103.00" .661 158.05 .382 207.05 2.884 277.95 .20945.00 .334 104.00 1.110 159.05 .337 208.05 .752 233.05 .15149.00 .452 105.00 1.052 160.05 .679 209.05 .260 293.05 .37450.00 14.093 107.00 12.448 161.05 .950 211.05 .722 296.05 4.51751.QU 55.066 108.00 1.924 162.05 .266 214.95 .252 297.05 .664•52.00 2.715 110.00 30.767 164.05 .181 216.05 .522 301.95 .09855.00 .394 111.00 4.277 165.05 . .728 2.17.05 5.566 303.05 .53356.00 1.708 112.00 .486 166.05 .573 218.05 .650 '314.15 .195.57.00 3.979 116.10 .735 167.05 3.906 221.05 6.673 31.5.05 .50958.00 .204 117.00 3.548 168.05 1.648 223.05 1.140 316.05 .30059.00 .1-31 118.00 .539 169.05 .248 224.05 10.804 321.05 .14861.00 .633 119.00 .137 170.15 .137 225.n5 2.635 723.05 1.64762.00 .688 120.00 .131 170.85 .124 227.05 4.053 324.05 .23663.00 2.096 122.00" .925 172.05"' .319 228.05 .592 326.95 .257oa.iu .270 123.00 1.276 173.05 .527 229.05 .779 327.85 .12265.00"""., .382 124". 00 .567 174.05 , .758 229.95 .125 333.05 .15567.10 .137 125.00 .724 175.05 1.332 231.05 .395 334.05 .98069.00 64.363 127.05 44.934 176.15 .628 234.05 .294 341.05 .2257I3.00 .354 128.05 3.455 177.05 .786 235.U1? .279 345.95 .34277.10 .'cl85 129.05 19.892 178.05 .315 236.15 .161 352.05 .35774. ui.l 4,2o2 130.05 1.562 179.05 3.282 237.05 .288 353.15 .32475.UO 7.H07 131.05 .282 180.05 1.835 240.05 .169 354.15 .43676. LU 2.400 131.95 .118 181.09 1.040 240.95 .252 365.05 1.81977.'jo 46.963 132.25 " .125 184.05 .282 242.05 .601 765.95 .246"H.UO 3.258 134.05 .503 185.05 1.629 244.05 9.084 372.05 .74679.'JO""_ 3.336 135.05 1.384 136.05 11.101 245.05 1.265 373.05 .19480.00 .2.373 136.135 .525 187.05 3.176 246.05 1.529 383.10 .172Sl. i J U - 3.436 137.05 .767 188.15 .351 247.05 .376 402.10 .382?2.0!! .947 137.85. ". .188 189.05" "" .604 249.0? .373 403. 10 .49793. ','.0 , . 8"B9 140.95 1.896 "191.05 " .733 253.05 .222 421.10 .370:?•:•. CI.T .592 142.05 .885 192.05 .967 255.05 41.473 423.10 3.15886 . M 0 .313 143 . 05 .. 471 193 . U5 1. 046 256.05 6 . 082 424 . 2 0 . 528:-'-'. O'J . .421 145.Q5 ".158 194.05 .173 257.05 .504 441.20 8.73988.00 .182 146.05 .339 195.05 .236 258.05 2.105 442.10 56.0451.00" .838 147.05 1.138 196.05 3.048 259.05 .324 443.10 10.983

92.130 .;;33 148.05 2.260 198.05 100.000 263.95 .115 444.10 .93795.00 4.926 149.05 .451

flR3073i*6 00091°

% Relative AbundanceIon abundance Base Appropriatem/z Criteria Peak Peak Status

51 3U-6UX of mass 198 58.44 58.44 Ok68 Less than 2% of mass 69 0.00 0.00 Ok69 (reference only) 67.17 67.17 Ok70 Less than 2X of mass 69 .31 .45 Ok127 40-60X of mass 198 47.34 47.34 Ok197 Less than IX of mass 198 0.00 0.00 Ok198 Base peak, 100X relative abundance 100.00 100.00 Ok199 5-9X Of mass 198 6.79 6.79 Ok275 10-3QJS of mass 198 19.76 19.76 Ok365 Greater than IX of mass 198 1.60 1.60 Ok441 0-100X of mass 443 7.93 85.19 Ok442 Greater than 40X of mass 198 50.34 50.34 Ok443 17-23X of mass 442 9.31 18.49 Ok


Data File: >D2852Scan: 326

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File: >D2852 Scan *: 326 Retn. time: 10.41

m/z Int. m/z Int. m/z Int. m/z Int. m/z Int.

38.00 1.039 100.00 .294 156.05 1.845 201.05 .265 274.05 3.34339.00 5.631 101.00 1.961 157.05 .476 201.55 .538 275.05 19.76040.00 .749 103.00 .628 158.05 .352 203.05 .673 276.05 2.70444.00 .578 104.00 1.202 158.95 .268 204.05 2.655 277.05 1.35044.90 .212 105.00 .912 160.05 .709 205.05 4.624 278.05 .23950.00 14.588 107.00 13.202 161.05 .976 206.05 19.807 284.05 .12051.00 58.443 108.00 2.015 162.05 .273 207.05 2.919 285.15 .20952.00 3.105 110.00 32.626 164.25 .114 208.05 .717 293.05 .30452.90 .183 111.00 4.365 165.05 .734209.05 .214296.05 4.2235*.00 .268 112.00 .526 166.05 .688 210.95 .801 297.05 .56756.00 1.714 116.00 .834 167.U5 4.168 215.05 .276 303.05 .49657.00 4.151 117.00 8.765 168.05 1.606 216.95 5.121 304.05 .13158.00 .140 118.00 .676 169.05 .342 218.05 .666 314.05 .19461.00 .746 122.00 .822 169.95 .108 221.05 6.886 315.05 .49462.00 .676 123.00 1.473 171.05 '.201 223.05 1.148 316.05 .293-3.00 2.208 124.00 .578 172.05 .372 224.05 10.665 321.05 .1634.00 .276 125.00 .702 173.05 .483 225.05 2.983 323.05 1.450

"65.00 1.068 127.05 47.340 174.05 .901 227.05 3.988 327.05 .27869.00 67.167 128.05 3.537 175.05 1.484 228.05 .534 334.05 .8147U.OO .305 129.05 20.229 176.15 .483 229.05 .827 335.05 .31973.10 .346 130.05 1.777 177.05 .779 231.05 .360 340.95 .15974.00 4.621 131.05 .345 178.95 3.188 235.05 .316 346.05 .25375.00 8.274 132.15 .110 180.05 2.103 237.05 .300 352.05 .39876.10 2.879 134.05 .557 181.05 .920 239.05 .194 353.05 .28177.00 49.097 135.05 1.466 182.05 .140 241.05 .214 354.05 .48273.00". 3.008 136.05 .575 184.15 .252 242.05 .502 365.05 1.59579.00 3.306 137.05 .744 185.05 1.668 244.05 8.771 365.95 .2208U.OO 2.623 137.85 .130 186.05 11.499 245.05 1.119 372.05 .73881.00 3.762 140.05 .252 187.U5 2.974 246.05 1.543 372.95 .146BV.QQ .973 141.05 2.205 188.15 .285 247.05 .284 383.10 .24983.00 .892 142.05 .814 189.05 .673 249.05 .329 402.10 .2648^.00 .624 143.05 .543 189.95 .124 253.05 .172 403.10 .42786.00 .814 146.05 .403 191.05 .337 255.05 40.020 421.10 .307e.'.OU .436 147.05 1.065 192.05 .996 256.05 5.699 422.10 .34587.90 .191 148.05 2.109 193.05 .836 257.05 .430 423.10 2.92791.00 .792 149.05 .503 195.05 .236 258.05 1.961 424.10 .60192.DO .782 151.15 .345 196.05 3.290 259.05 .293 441.20 7.9289.-5.00 4.972 153.05. .738 198.05 100.000 265.05 .878 442.10 50.34294.00 .351 153.95' .464 198.95 6.794 272.15 .098 443.10 9.3069B.UU 3.644 155.05 1.132 200.05 .435 273.05 1.246 444.10 .91499.00 3.055

IB EPA SAMPLE NO.SEMIVOLATILE ORGANICS ANALYSIS DATA SHEET _____________ ,

I 100617Lab Name: BCM LABS Contract: OCCIDENTAL I

Lab Code: BCM Case No.: 38191 SAS No.: SDG No.:

Matrix: (soil/water) 'WATER Lab Sample ID: 100617

Sample wt/vol: 1000 (g/mL) ml Lab File ID: >D2780


% Moisture: not dec. 100% dec. —— Date Extracted: 1/13/91

Extraction: (Sepf/Cont/Sonc) Sepf Date Analyzed: 1/17/91


CONCENTRATION UNITS:CAS NO. COMPOUND (ug/L or ug/Kg) ug/L Q

I108-95-2———————Phenol _________________I 10.

10.10.10.10.10.10.10.10.10.10.10.

111-44-4———————bis ( 2-Chloroethyl) Ether____95-57-8————————2-Chlorophenol____________541-73-1 ——————— 1, 3-Dichlorobenzene________106-46-7———————1,4-Dichlorobenzene________100-51-6———————Benzyl alcohol_____________9 5-50-1————————1, 2-Dichlorobenzene________95-48-7————————2-Methylphenol_____________39638-32-9—————bis( 2-chloroisopropyl) ether_106-44-5———————4-Methylphenol_____________621-64-7——————N-Nitroso-Di-n-propylamine_67-72-1———————Hexachloroethane__________98-95-3———————Nitrobenzene______________I 10 .78-59-1————————Isophorone________________I 10.

10.10.50.10.10.10.10.10.10.10.10.10.10.50.10.50.10.10.10.

88-75-5————————2-Nitrophenol______________105-67-9———————2 , 4-Dimethylphenol_________65-85-0————————Benzoic acid______________111-91-1———————bis ( 2-Chloroethoxy)methane_120-83-2———————2 ,4-Dichlorophenol_________120-82-1—-—————1, 2 ,4-Trichlorobenzene_____91-20-3 —-—————Naphthalene_______________106-47-8———————4-Chloroaniline___________87-68-3———————Hexachlorobutadiene_______59-50-7———————4-Chloro-3-methy Ipheno 1____91-57-6————————2-Methylnaphthalene.77-47-4————————Hexachlorocyclopentadiene.88-06-2———————2,4 , 6-Trichlorophenol____9 5-95-4————————2 , 4, 5-Trichlorophenol____91-58-7———————2-Chloronaphthalene_____88-74-4————————2-Nitroaniline__________131-11-3——:————Dime thy Iphthalate_208-9 6-8——————Acenaphthy lene___606-20-2———————2 , 6-Dinitrotoluene_

UUUUUUUUUUUUUUUUUUUuuuuuuuuuuuuuu

FORM I SV-1 1/87 Rev.000930

1C EPA SAMPLE NO.SEMIVOLATILE ORGANICS ANALYSIS DATA SHEET ____ .

100617b Name: BCM LABS Contract: OCCIDENTAL I

b Code: BCM Case No.: 38191 SAS No.: SDG No.:

Matrix: (soil/water) • WATER Lab Sample ID: 100617

Sample wt/vol: 1000 (g/mL) ml Lab File ID: >D2780


% Moisture: not dec. 100% dec. :—— Date Extracted: 1/13/91




99-09-2 ——————— 3-Nitroaniline.83-32-9———————Acenaphthene__51-28-5———————2 , 4-Dinitrophenol_100-02-7——————4-Nitrophenol___132-64-9———————Dibenzofuran____121-14-2———————2 , 4-Dinitrotoluene_84-66-2————————Diethylphthalate__7005-72-3——————4-Chloropheny1-phenylether__86-73-7———————Fluorene ________________

50,10,50,50,10,10,10,10,10,

100-01-6———————4-Nitroaniline____________| 50 ,534-52-1———————4, 6-Dinitro-2-methylphenol_| 50,86-30-6———-———N-Nitrosodiphenylamine (1)_| 10,101-55-3———————4-Bromophenyl-phenylether__| 10 ,118-74-1———————Hexachlorobenzene__________I 10 ,87-86-5————————Pentachlorophenol__________I 50 ,85-01-8———————Phenanthrene______________I 10 ,120-12-7———————Anthracene________________I 10,84-74-2————————Di-n-butylphthalate________| 10 ,206-44-0———————Fluoranthene______________I 10 ,129-00-0———————Pyrene ________________ 10.

10.20,10,10.10,10.10.10.10.10.10.10.50.

85-68-7———————Butylbenzylphthalate_______91-94-1———————3 , 3 ' -Dichlorobenzidine_____56-55-3———————Benzo (a) anthracene_________218-01-9———————Chrysene ________________117-81-7-——————bis(2-Ethylhexyl)phthalate_117-84-0———————Di-n-octylphthalate________205-99-2———————Benzo (b) f luoranthene_______207-08-9———————Benzo(k)f luoranthene_______50-32-8————————Benzo (a )pyrene____________193-39-5———————Indeno( 1,2, 3-cd)pyrene_____5 3-70-3———————Dibenz (a, h) anthracene______191-24-2———————Benzo (g,h, i Jperylene_______92-87-5————————Benzidine_________________

UUUUUUuuUuuuuuuuuuuuuuuuuuuuuuuuu

(1) - Cannot be separated from Diphenylamine

FORM i sv-2 flR3Q7350 1/87 Rev-

II^

Operator ID: EAG Quant Rev: 6 Quant Time: 910117 02:43Output Fife: ~D2780::D1 Injected at: 910117 01:40Data Fi l e : >D278Q::D4 Dilution Factor: 1.00000Name: 100617 HSLSU2Misc: 1UL INJ MSU0380B 30GR/1ML BTL# 7

ID F i1e: ID_BXA::QTTitle: HP SNA StandardsLast Calibration: 910116 18:26

Compound R.T. Scanfc Area Cone

1) *l,4-Dichlorobenzene-d4 IS 13.82 750 824883) 2-Fluorophenol SA 10.75 455 188337At Phenol-d6 SA 12.89 661 23687017) *Naphthalene-d8 IS 17.14 1070 29339418) Nitrobenzene-d5 SB 15.26 889 12117732) *Acenaphthene-dlO IS 21.90 1528 16190537) 2-Fluorobiphenyl SB 20.01 1346 20983252) 2,4,6-Tribromophenol SA 24.03 1733 5300753) *Phenanthrene-dlO IS 25.88 1911 23218364) *Chrysene-dl2 IS 33.82 2672 14572667) Terphenyl-dl4 SB 30.08 2314 20075073) *Perylene-dl2 IS 42.47 3502 102405

* Compound is ISTD

flR30735l 000932

rci ION nHROMOTORRBHl - i l s >0278e 35.0-500.8 amu. 188617 HSLSVS 1UL INJ HSW03888 386i TIC '

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; 3 Fil-e: !D_8XA::"QT .' - t i e : HH BMA Standards_2st Calioration: 910116 13:26

• -.era tor ! U : EAGQuant Time: 910117 02:43:-jectsd at - : 910117 01:41)

000933

___ IF EPA SAMPLE NO.SEHT7DL&TIIZ. ORSAKICS ANALYSIS DATA SHEET

IDENTIFIED COMPOUNDS

Lab Name:_____W1 L™________ contract; Oca

Lab code: '&M Case No.: 3JVW SAS No.: ______ SDG No.:

Matrix: (soil/water) h*** Lab Sample ID:

Sample wt/vol: V66 (g/mLl ' Lab File ID: >J>J-720

Level: (low/med) L*» Date Received: _

* Moisture: not dec. 4**# dec.____ Date Extracted:

Extraction: (SepF/Cont/Sonc) 5 Date Analyzed: __

GPC Cleanup: (Y/N)_// pH:___ Dilution Factor:

. CONCENTRATION UNITS:Nmacer TICs found: ^ (ug/L or ug/Kg)

CAS NUMBER

1. /V/7f72.3.4.5.6./ .

8.Q m10.i_i12 .12.14 .15.15.17.IS.19.20.21.22.t- -. .

24 .25.25.27.28.29.30.

COMPOUND NAME

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Method die: M625SU Tuning f i l e : NTf1SD4 No. of extra records: •?bource temp.: Q Analyzer ternp.: 230 Transfer line temp. : 0 "

Chromatographic temperatures : 40. 300. 0. 0. 0.Chromatographic times, mm. : 4.0 31.0 0.0 0.0 0.0Chromatographic rate, deg/min: 10.0 0.0 0.0 0.0 0.'0

HJ2-J80 100617 HSLSU2 1UL INJ MSU0380B 30GR/1ML35. 0 I 500.0 CLP TIC

i J p s i o p e : ' .20 Area Reject: 28299. flax Peaks: 6 Bunching: 1Dnslopc: 0?00 Results F i l e 102730 Sorted by Time/Area [NT

P=ak R.T. first max last peak raw corr. corr. X of__* _™ln- scan s<=an scan height area area « max. total

L 8.B8 270 275 2SB ."_ 27166 77914 72395 2.23 1.901; I''.1 312 51-7 329 25575 87065 79432 2.45 2.087

'•V8 369 -31 ?85 715960 3247350 3240363 100.00 85.HE£ Li-63 ^^^ ^0 551 95429 238708 233116 7.19 6

li.^9 617 r,22 o29 18094 45346 41497 1.29 1

I.1.1?! 714 721 729 57817 144382 1400V? 4.32 3.680

Sum of corrected areas: 3806886.= i ~

Nummary o 1- Unknowns. PBM Library Search and Guan t i t a t i on

Retention Unknown'-tandard Concentration Area Time Window

1 ~n!.0 512971. 13.82 6.03 - 15.48- "-U.O "" " 638431. 17.14 15.48 - L9.52> ----»IJ.U 722854. 21.90 19.52 - 2?. 894 40.0 630727. 25.88 23.89 - 29.85"• - -41,1.0 421103. 33.82 29. a1? - 3H. 146 40.0 282991. 42.47 38.14 - 61.04

1 ' D i l u t a o n Factor = " 1'iOO " U d i l f = " 1.00"='-HC.S r a i l e d t-or ! !JO'J .-ULiiJ g or mL This sample was 1000.000 g or mL

1 j r-«;_C-t t on h".=jctor = l.UO

Lone Int StdL'nknown Concentration = _____ — — _ — _ * Area Unknown * Correction Factor

ttrea Int Std

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File >D2780 188617 HSLSBpk fib 6563.

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FilA >BI6DB 3-PerBpk flb 9999.

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File >BI6DB 2-P«iBpk flb 9999.

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1 60 67 77

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9884 95 .' 101

59 69 79 80 99 109

ttene, 2,3-di«cthyl- <8CI955 83

69 ^«._ 63 / 77

275»in.

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98 t84 91 / 99 fc

50 " 60 ' ' "70 ' 80 "'""90" ' 100

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51 63 67 ??^ i 1 ' { ^

<8CI9CI> Scan0.00

84 91 1Q0

50 60 70 30 90 100

5593Min.

UNKNOWN #,1AREA = 72385.00 TENTATIUE CONCENTRATION IS 6.00

1. 3-Penten-2-one, 4-methyl- C8CI9CI1 98 C6H1002. 2-Pentene, 2,3-0ime thy 1- (801901) 98 C7H14?. Cyclopropane, 1 , 1 ,2 ,2- t e tirarnethy 1 - (8CI9CI) 98 C7H1Aa. 2-Pentene, 5 ,4-d ime t hy 1 - , (£)- "(8CI9CU 98.C7H14?. 2-Pentene, A,4-dlmethyI-,• CZ)- (8CI9CI) 98 C7H146. 3-Penten-2-one, 3-mcthyl- f8CI9CI) 98 C6H100

Sample f i l e : >02780 Spectrum ft: 275:.earch speed: 1 T i l t i n g option: N No. of ion ranges searched: 41

Prob. CAS # CON ft ROOT K DK ftFLG TILT % CON C__I R_IU

1. . 37* 141797 8486 "BIGDB 66 32 2 0 66 3 632. 78* 1U574375 S516 "BIGDB 45 56 3 0 90 5 55J-. 70* 4127473 5593 "BIGDB 4? 54 2 0 92 7 42 194. 52* 4914925 5596 "BIGDB 34 62 3 0 90 20 20 135. 51* 762630 5590 "BIGDB 44 48 2 0 90 21 22 236. 47* 565628 3488 "BIGDB 56 36

ftBpk flb 999°. -.„ - SUB 9.31 min.

4o

1 45 58 69 -•» " ?* 87' .-•*' fhr

48 60 C3 108 120

File .-BI60B 1,3-Oioxolane. c-methvl- (3CI9CI) Scan 1335Bpk fib 9999. . ' 0.60 mm.

i 343

£3l.i ,1.1

45~"" 5S 0f 69^ 86

~*~.

.

97 89 fr"" - — •"" *" Tf

40 60 ' 80 100

File >BI6DB 3-Pentanone, l ,5-dim«thoxy- <9CI> Scan 11368Bpk fib 9999. 0.08 min.

45

J S5 ,5,9 7-j_ 83 5 - 99

40 60 30 180 120

File.-SieDB 1-Butanol, 4-mstnoxv- <3CI9CI> Scan 1309Bpk flb 9999. ' 0.88 rain.

45

} 44 •3B/ 1 X O »i s? E

/ . . i , , , , , . i i , , i i , . , , , i i ,r a43 60 S3 103 123

rt*s>

UNKNOWN ft, 2AREA = ?*432.00 TENTATIUE CONCENTRATION IS 6.00

1. i ,3-0 lox-o lane , 2-meth.yl- (SCI9CI) 88 C4H8022. 7-Hentanone. 1", 5-d ime t hoxy- (VCI) 146 C7H1403.; . i-eutanoi, 4-methow- <aCI9CI) 104 C5H1202**. stjtancLic acid, 3-ch'loro- '. 9CI) 122 C4H7C1O2"r . H.-etic acid, 1-me t hy 1 e.thy 1 ester (9CI) 102 C5H10026. Ethanol, 2- ' 2-am i noe t nox v l- (.8CI9CI) 105 C4H11NQ2

Sample f i l e : > 02 780 " "5jpe~c t r u m ft: 317••earcn spe^d-' 1 T i l t m q -ption: N No. of icm ranges searched: 49

Prnb. CAS" ft CUM ft ROOT K OK ftFLG TILT % CON C_I R_IU

1. 28* 497267 1335 "BIGDB 20 53 1 0 38 40 10 142. -J5 53005188 11368" "BIGDB 36 37 2 0 25 48 7 123. 25 111320 1309 "BIGDB 35 40 2 .0 25 48 7 124. 25* 1951128 6665 "BIGDB 26 78 3 0 69 44 8 135. 25 108214 2031 "BIGDB= 43 36 1 0 74 48 7 15c.. 24 929066 °6 "BIGDB 33

Bpk fib £60594.43

i"j 39

•> I ^V 1 .:.o 40File ,BI6DBBpk 8b 9?99.

43

I" - ,30 48

File >BIGDB Hydro!Bpk flb 9999.

, 43j 31 39oi, /, , r-n.i, , ,

30 40

~ile -BIGDBBpk fib 9999.

43-i PQ\ -/ 39 .

oiH!,,,,^,!,,,30 40

1t

SUB 9.98??

51 63 69" 73 83 93 J 01 103

53 63 70 SO 90 108 118

»in .

t-0

2-ProD*none <9CI) Scan 12310.08 min.

58 __ F•N. 59 tI--- h-

50 60 70 88 99 100 110

3«roxide, 1 ,1-dinethy lethyl <9CI) Scan 15910.00 min.

59

50 60 73 89 E

58 fc0 73 88 90 180 110

Butane -.SCI9CI) Scan0.00

50 58 59' ^^ -— '50 £0 73 30 90 108 110

1234mih .

L

'if',' ••.'•

UNKNOWN ft,3JEA = 7240363. TENTrtTIUt' CONCENTRATION IS 250.00

1. 'J-Propanone '9CI) 58 C3H60_. Hydrcperoxide , 1 , 1-dimethy 1 ethyl (9CI) 90 C4H1002?. Butane '8CI9CI) 53 C4H10-*. .-Butanone, ': -hyo ro ...y->-me t hy 1- 18CI9CI) 10 2 C5H10025. p-opane, 2-methy1-2-'1-methylethoxy)- <9CI; 116 C7H16Q

e r i l e : '1)2780 Spectrum ft: 381Search speed: 1 T i l t i n g option: N No. of ion ranges searched! 40

P-ob. CAb ft C'JN ft ROOT K DK ftKLG TILT % CON C_I R_IU

L. 27* 67*41 1231 "BIGDB 21 50 0 G 81 44 8 152. 25 75912 1591 "BIGDB 38 42 2 0 69 44

25* 106978 1234 "BIGDB 23 56 1 0 67 49A. 15* 115220 1644 "BIGDB 27 54 1 0 53 59 35. 11 17348593 1692 "BIGDB 37 44 2 0 51 64 2 12

000940AR307359

^3pk fib 9999.

K48

File ;BIGDBBpk flb 9999.as

38 83

68 30-

43 ? 73

48 ' 60 ' 80'

Tile >BISDBBpk fib 9999.

J,f If

SUB

f.7 181 133 168

100 ' 120 ' 140 ' 160 ' 188

1,3-Oioxan* <9CI>

87181

100 ' 120 ' 148 ' 160 ' 189

1,4-Dioxane, dimethyl- <9CI>87

59 f* f J? \ 114 16

« i • i • i • i • i • i •48 68 89

File .'BIGDBBpk flb 9999.

j 31

Silai

43 x- 85

40 68 80

100 ' 128 ' 148 ' 168 ' 180

ie, tetraathyl- <8CI9CI)

J7 115

| 116 144

108 120 148 168 188

11.63 min.

I200

Scan 66118.00 min.

, J.£09 '

Scan 66790.00 min.

,; J.200

Scan 67920.80 min.

200

UNKNOUN ft,4AREA = 233116.0 TENTATIVE CONCENTRATION IS 18.00

1. 1,3-Dioxane (9CI) 88 C4HS022. 1,4-Dioxane, dimethyl- (9CI) " " "". 116 C6H12023. Si lane, tetraethyl- C8CI9CI) 144 C3H20S1-4. bilane, triethyl- f. 8CI9CIii 116 C6H16S15. Propane, 2-methy1-1-propoxy- (9CI) 116 C7H16Q6. CyclohexanoI, 3,5-dimethoxy-, stereoisomer CUAN8CI) 160 C8H1603

Sample f i l e : ^02780 ~ Spectrum ft: 540Search •speed: 1 T i l t i n g option: N No. of ion ranges searched: 43

Prob. COS ft CON ft ROOT K OK ftFLG TILT \ CON C_I R_IU

1. 29* 505226 6611 "BIGDB 21 70 0 0 25 36 10 15f2. 25 25136554 6679 "BIGDB 33 35 1 0 18 47 7 123. 25* 631367 6792 "BIGDB 20 37 1 0 18 47 7 144. 25* 617867 6613 "BIGDB 21 39 1 0 12 47 7 145. 25* 15268492 6600 "BIGDB 33 53 2 0 72 47 7 166. 25* 30363838 6749 "BIGDB 29 54 2 0 14 47 7 14

flR307360 000941

File ,02738Bpk fib 9999.

-jj 39

40

File ;BIGDBBpk fib 9999.

188617 HSL3V2 1UL INJ MSU0388B 38SR/1HL Scan 622SUB 12.49 min.

5(

« I-" \\

37 38 0 130. m ~.-* ~ *

68 ' ''80 '''"'£00' '"'120'"' "148 "'"'160

^E

, i , [a180

3-Pentanone, 2-m«ihvl- <8CI9CI) Scan 98538.30 min.

57

"1 29r' ...: J. • ? * 1 O t Ay- as j 0 10140 68 '• 89 "' 100 ••'"i.e •' 149 ' 169- '

File >BI6DBBpk flb 9999.

29r,,48

File 'BieDBBok fib 9999.

™

-m-'-e1)8

Propanoic acid, ethenyl ester <9CI> Scan 12949.88 min.

57

J3 73 86 188 108

60 80 100 120 140 160JL180

2-Butanone, 3 ,3-dimethyl- (8CI9CI) Scan 98858.00 min.

57

48

J-|

10873 85 95-> 181

60 38 100 128 140 160

-

:180

UNKNOUN ft,5- 41497.00 TENTATIUE CONCENTRATION IS 3.00

i. 3-Pentanone, 2-methyl- (8CI9CI) 100 C6H120J. Propanoic acid, ethenyl ester (9CI) 100 C5H8023. 2-Butanone,- ?,?-dimethyl- (8CI9CI) 100 C6H120-». Isobutyl ether (8CI) 130 C8H1805. 2-Butanone, 1-Cacety1oxy )- f9CI). 130 C6H10Q3

Sample f i l e : >D2780 Spectrum ft: 622Search speed: 1 Tilting option: N No. of ion ranges searched: 43

Prob. CAS ft CON ft ROOT K DK ftFLG TILT K CON C_I R_IU

1. 52* 565695 9053 "BIGDB 30 55 1 0 73 18 20 162. 37* 105384 1204 "BIGDB 22 63 1 0 119 30 143. 20* 75973 9085 "BIGDB 31 55 2 0 61 51 5•j.. 11* 628557 6583 "BIGDB 23 49 1 0 60 61 25. 11* 1575571 1218 "BIGDB 20 63 2 0 51 63 2 13

16

tflR30736P00942

<

^

rFi 1«=Bpk

rileBpk

Fi leBpk

,

fib 9999. SUB 13.51*rO

j 55 58 7Q *? 97O1 • r- ^ -^ -{•- , '

40 ' 60 S3 ' 138 ' 128 ' 140

>BIGDB 2-Butanol. 3-mathvl-, acetate (8CI9CI> Scanf i b 9999. . . . 0>0043

| 29 55 fil 70 37 1±s lge0-k" T||,. i / [. ,1 / -""

40 ' 60 ' 88 ' 100 ' 128 ' 140

>BI6DB 1-Butanol, 2-wethyl-, acetate <8CI9CI> Scanfib 9999. 0.00

j 29 85 61 78 87 ±el leg 115 130

40 ' 'fe'0 ' ' ' ' ' s'fl ' 100 ' 120 ' 148

.•BIGDB 2-Butanoi, 3-bromo-, acetate C8CI9CIJ Sc»nflb 9999. 0.90

43

1 ' .. 87j 33 ^ 61 73 79 93 107 115 134 138

40 60 SO 100 120 140

min.

6594rain .

6647min.

I6764mm.

F

.*-' rr.»,r»*rt« .*,, C.,"'".—.'-- .g|SL;:;.

•' 3SSSS»-.-'.

UNKNOWN ft,6AREA = 140093.0 TENTATIUE CONCENTRATION IS 11.00

1. 2-Butanol, 3-methyl-, acetate C8CI9CI) 130 C7H14022. 1-Butanol, 2-methyl-, acetate (8CI9CU 130 C7H14O27. T-Butanol, ?-bromo-, acetate (8CI9CH 1^4 C6HllBr024. Butanoic acid, 2-e t hy 1-3-oxo-, methyl ester '.9CI; 144 C7H12Q3

'-ample f i l e : .-D2780 Spectrum ft: 721Search speed: 1 T i l t i n g option: N No. of ion ranges searched: 43

Proa. CAS ft CON ft ROOT K OK ftFLG TILT "?« CON C_I R_IU

1. 58* 5343964 6594 "BIGDB 43 32 2 0 88 16 25 232. K2* 624419 6647 "BIGDB 32 49 2 0 96 16 20 16

26 5798812 6764 "BIGDB 40 34 2 0 43 45 8 1425* 51756082 6701 "BIGDB 27 65 2 Q 58 47 _ 7 14

flR307362 °°°943

IB EPA SAMPLE NO.SEMIVOLATILE ORGANICS ANALYSIS DATA SHEET _____________.

I II SV BLK #4 |

Lab Name: BCM LABS Contract: OCCIDENTAL I_______

Lab Code: BCM Case No.: 38191 SAS No.: SDG No.:

Matrix: (soil/water) WATER Lab Sample ID: 100679

Sample wt/vol: 1000 (g/mL) ml Lab File ID: >S1228

Level: (low/med) LOW Date Received: N/A




CONCENTRATION UNITS:CAS NO. COMPOUND . (ug/L or ug/Kg) ug/L Q

I108-95-2———————Phenol __________________\ 10,111-44-4——————bis( 2-Chloroethyl)Ether,____| 1095-57-8———————2-Chlorophenol_____________I 10 ,

111-91-1——————bis ( 2-Chloroethoxy)methane_120-83-2 ——————— 2,4-Dichlorophenol________120-82-1 —————— i, 2 , 4-Trichlorobenzene_91-20-3———————Naphthalene__________106-47-8 —————— 4-Chloroaniline______87-68-3———————Hexachlorobutadiene___59-50-7————————4-Chloro-3-methylphenol.91-57-6 ———————— 2-Methylnaphthalene__77-47-4———————Hexachlorocyclopentadiene.88-06-2 ———————— 2,4,6-Trichlorophenol____95-95-4 ———————— 2,4, 5-Trichlorophenol____91-58-7 ——————— 2-Chloronaphthalene_____88-74-4 ——————— 2-Nitroaniline__________131-11-3——————Dimethylphthalate_______208-96-8——:———Acenaphthylene.606-20-2——————2 , 6-Dinitrotoluene

10.10.10.10.10.10.10.50.10.50.10.10.10.

UUu

541-73-1 —————— 1, 3-Dichlorobenzene ________ | 10. U106-46-7 —————— 1,4-Dichlorobenzene ________ | 10. U100-51-6 ——————— Benzyl alcohol ____________ | 10. U95-50-1 ———————— 1,2-Dichlorobenzene ________ | 10. I U95-48-7 ———————— 2-Methylphenol __________ I 10. I U39638-32-9 ————— bis ( 2-chloroisopropyl ) ether_| 10. I U106-44-5 ————— - — 4-Methylphenol _____________ | 10. I U621-64-7 —————— N-Nitroso-Di-n-propylamine _ | 10. I U67-72-1 ——————— Hexachloroethane __________ | 10. I U98-95-3 ———————— Nitrobenzene ____________ \ 10. I U78-59-1 ——————— Isophorone ______________ \ 10. I U88-75-5 ———————— 2-Nitrophenol ______________ | 10. I U105-67-9 ——————— 2,4-Dimethylphenol _______ I 10. I U65-85-0 ———————— Benzole acid _______________ | 50. I U

10. | U10. | U10. I U

uuuuuuuuuuuuu

FORM I SV-1 1/87 Rev.AR307363 000983

1C EPA SAMPLE.NO.SEMIVOLATILE ORGANICS ANALYSIS DATA SHEET _______________.

I II SV BLK # 4 |

Lab Name: BCM LABS Contract: OCCIDENTAL I____________I

ab Code: BCM Case No.: 38191 SAS No.: SDG No.:


Sample wt/vol: 1000 (g/mL) ml Lab File ID: >S1228






99-09-2 ———— •o o "j o a51 O Q C1 — 28 — 5 ————— •100-02-7 ———— •132-64-9 ———— •121-14-2 ———— •84-66-2 ————— •7005-72-3 ——— -86-73-7 ————— -100-01-6 ———— -534-52-1 ———— -86-30-6 ————— -101-55-3 ———— -118-74-1— —— -87-86-5 ————— -o c n * Q

120-12-7 ———— -84-74-2 ————— -206-44-0 ———— -129-00-0 ———— -8C £. Q ~7

91 Q A 1

56-55-3 ———— -21 p n 1 Q117-81-7 ———— -117-84-0 ———— -205-99-2 ————207-08-9 ———— -50-32-8 —————193-33-5 ———— -53-70-3 ————— -191-24-2 ———— -92-87-5 —————

——— 3-Nitroaniline——— Acenaohthene——— 2 . 4-Dinitrophenol—— 4-Nitrophenol——— Dibenzofuran——— 2 . 4-Dinitrotoluene——— Diethvlphthalate——— 4-Chlorophenyl-phenylether _——— Fluor ene——— 4-Ni troani line——— 4 , 6-Dinitro-2-methylphenol _——— N-Nitrosodiphenylamine (1) _——— 4-Bromophenyl-phenylether __——— Hexachlorobenzene——— Pentachlorophenol- —— Phenanthrene——— Anthracene- —— Di-n-butylphthalate- — :-F luoranthene• —— Pyrene- —— Butylbenzylphthalate• —— 3 . 3 ' -Dichlorobenzidine——— Benzo ( a ) anthracene

N^H^ J hJOllW

- —— bis(2-Ethylhexyl)phthalate _——— Di-n-octylphthalate——— Benzo f b ) f luoranthene——— Benzo f k 1 f luoranthene——— Benzo ( a ) pyrene——— Indenof 1 f 2 r 3-cdl pyrene——— Dibenz ( a f h ) anthracene——— Benzo ( g r h r i ) pery lene——— Benzidine

50.10.50.50.10.10.10.10.10.50.50.10.10.10.50.10.10.10.10.10.10.20.10.10.11.10.10.10.10.10.10.10.50.

Uuuuuuuuu

• uuuuuuuuuuuuuuuuuuuuuuu

( 1 ) - Cannot be separated from Diphenylamine

FORM I SV-2 SDOflTOri 1/87 Rev.000984

REPORT

Ljperator LU: UbtK' Uuant Kev: 6 quant lime: V1U124 17:34«utput h i i e : Asi228::01 Injected at: 91U124 16:36

fliac: 1LIL INJ MbU0384B lUUOHL/iriL OCCIDENTAL. B i L* 7

ID Fi la: ID_BXfl::QTTitle: HP 8»*»-StanciardsLast Calibration: 910124 10:03 *. -

Compound R. r. Scan* Area Cone Units"— 7q

!_or.-.pound 13 I

AR307365000985

.c IS 13-69 74A- 68790 4U.OO- ---Fluorophcnol SA 10. 6U 44^ 106SS1 59.60 ug/L.£° 98^*) Phenol -d6 S« 12.75 6S3 81339 33.5fe! ug/U// 93

,., ) Naphthalene-da 1317.01 1U65 58709 40 . UU ug/LIT- 99;."; ^^ltr°°enz=ne-d^ SB 15.13 883 77113 30.02 ugXL>d" 78\^\ Wcenaphthene-dlQ IS 21.75 1523 163581 40. UU ug/L 93~-J --Huorobiphenyl SB 19.87 1341 169777 34.33 ug/L<^ 95^JJ ^,4,6- Iribromophenol b« .3.87 1723 138427 W.^l ug/L ^ 89,?> »Hhenanthrene-diU IS 25. 73 19U7 323682 40. 00 ug/L 98

Ui-n-butylphthatate _?ilg —— iHWJ ————— **trt- —————— rrrr- ug/L_6-*) -Lnrysene-di. IS 33. 52 266U 298056 4!J . UU ug/Lox) Ierphenyl-dl4 SB 29. 91 2311 365626 4V . 0^ u|/L•^-, bial2-tthylhexyl J p h t h a l a t e 33.25 2654 68154 ll.ia<jg/L 96.si *Heryiene-dl2 1S41.B* 3464 2693^4 AU.UOug/L 97

'• • -»•»•• -••« .*TS* •"* V „ *Sa"

TQTOl IQH CHRQHOTOBPOMila >S1229

12 16 20 24 ' 29 ' 32 ' 36 ' 40 ' 4§4 ' Vd ' '.2 ' ',6

Data File: >S122S::«6 Quant Output File: ~S1228::U1Name: 100679 HSLSU2Hisc: 1UL INJ MbU10384B 1UOOML/1ML OCCIDENTAL B TL* 7

Id File: ID_BX«::QTT t t l e : HP BNft StandardsLast Calibration: V1U124 10:03

Uperator ID: USLR2Quant Time: 910124 17:34Injected at: 91U124 16:36

flR307366 000986

STaHOBRD SPgCTRUrt

aooooon57/I

ioo167 IOOOOH

I j 216 r | j

IOO

8AWLE SPECTRUM CBAOCBROUNO SUBTRACTED >

Fil« >S1228 148.7-149.7SUB 3£~. 19 min.

149 I I 20000H

•-- . «t» i- 33.as Bin.^

soooof57f •^ p 4vTr*r r r . i

r

i-" «,1 /

-1»

97 279 :, >

SAHPLE SPECTRUM <UNALTEREDJ

BBpk

80000-

33.25 -in.

57/ 113

l.JJ-.^r!' i " L : '

h-100

*T*"100r T

33.2

Fil« >S1228 166.7-16?.7

- 'i'*'

4000H

_______ ________ li-.1-. -H.-S-\ —-IOO 200 33.2

Fii« >siaea 273.9-279.9aooo-

1000-

33.2

Data File: >S1228::fl6 Quant Output File: ~S1228::O1Name: 100679 HSLSU2Hisc: 1UL INJ nSU0384B lUOOHL/inL OCCIDENTAL BTL# 7Uuant Time: 910124 \7ii4 Quant ID File: ID_BX«::UTInjected at: 910124 16:36 Last Calibration: 910124 10:03

Compound No: 72Compound Name: b i sC2-tthyIhexy1)phthalateScan Number: 2634Retention Time: 33.25 mm.Quant Ion: 149.0ftrea: 68154Concentration: 11.18 ug/Lq-value: 96

5R307367 000987

IT EPX

Lab Name: , contract:

Lab Code: Case No.: JJVflP SAS No.: _____ SDG No.:

Matrix: ( soil/water )_J^f^ Lab Sample ID:

Sample wt/vol: /. ^^ (q/mL) Lab File ID: >

Level: (low/metl) ^ Data Received:^

* Moisture: not dec;. / % dec. _____ Date- Extracteds

Extraction: (SepF/Cont/Sonc*- /SW* Dat-uAnalyzeds

<3PC Cleanup: (Y/N) J pH:____ Dilution Factor:

COHCEHTKATION UNITS:Number TICs found: ____^ (ug/L .or ug/Kg)

CAS NUMBER

1.2. ' 6 7* V3.4.5.6.7.a.9.10.11.12.12. %14.15.15.17.la.19.20.21.22.23.24.25.26.27.28.29.30.

COMPOUND NAME:

//Ax yUrf/VV

"

RT-

/i.77~2/.t>£~

EST. CONC_

.4 .

QrAu~

sv-TicftR307368 OOO388 1/87

.1.- data f i l e header from : >S1223

'Sample: 1006^9 HSLSU2 ' Operator: USER2 REG. GRP. 1X24/9116:36•ii-c ^. iU_ INJ MbUJ0384B 1'JUUML/lflL OCCIDENTAL BTL* 7^yo. ,r. i ns modei. ,.u SLJXHUJ rev>. Ifl ftLg . Q

TUning Mle' "T"SD1 N°' o¥ e*tra records: 2Analyzer temp.: 230 Transfer line temp. : 0

Chromatographic temperatures : 40. 300. 0. 0 0Chromatographic times, mm. : 4.0 31.0 0.0 0.0 Q.O '' -i~i-hromatographic rate, degXmin: 10.0 0.0 _0.0 O.Q 0.0 ..-•'

S1228 100679 HSLSU2 1UL INJ MSU03848 10UOML/1ML OCCIDENTAL?^

35. 01 500.Q CLP TIC

n'nS ^ea Ke]ect: 42724« "•« Peaks: 2 Bunching: 1Q.QQ Reaults File IS1223 Sorted by Time/Area INT

Peak R.T. flrat max last peflk paw copp_ cQrr> ^ Qf

--- __!!l"l SCa" scan scan height area area % max. tota

'?\ 1Q32 1U37 1U48 214791 430120 428976. b^ 1^09 iu,3 1516 52858 102521 102521 23.90 2:

Sum of corrected areas: 531497.

ummary of Unknowns Pbn Library Search and Quant i tat ion

standard

•ii-4

U

6

Concen t ra

4U.40.AU .4U.4U.JO.

t i on

J0LIU00

Area

427236.565683.732265.766619.763847.662284.

Retent ionT ime

13.6V17. Ul21.7525 . 7333.5241.35

UnknownWindow

6. UU -15T35 -19.38 -23.74 -29.62 -37.69 -

lb.3519.3823.7429.6237.6957.02

M" d i l u t i o n Kactor = i.UU U d l l f 3 1<00..e.hoa c a l l e d Kor IQUO.UUO g or mL This sample was 10UU.UUU g or mL

•-cr rec't i on " Factor - i.UU

Cone Int StdVnur.cun Concentration = -———————————— » Area Unknown * Correction Factor

«rea Int Std

2:4b ftfl FRi., 2b JAN., 19

flfi307369 °00989

i File ;S.

i1 H360000-

.1i 323COO-

-

230000--

240000-

20000O-.

leOOOO-

120000-

owwOO-

-

r-J\

-0-

-4UOOO-

1

L22S 35.0-600.0400

*j»u. 100679 HSLSV2 1UL INJ MSU0384B 100011ROC TIC

800 | 1200 t 1300 s , 2000 f 2400

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flR30737l»

\TRILLILJM,

DATA VALIDATION FOR OCCIDENTAL CHEMICAL PLANTPOTTSTOWN, PENNSYLVANIA SITE

ORGANIC DATA:Pesticide/FCB

Order Numbers 37933, 38191, 38298, and 38542

Chemical Analyses Performed by:BCM Laboratory

FOR

Occidental Chemical CompanyNiagara Falls, NY

BY

Trillium, Inc.7A Grace's Drive

Coatesville, Pennsylvania 19320

June 20, 1991

AR307375

v TRILL1UM,NCEXECUTIVE SUMMARY

Validation of the pesticide/PCB data prepared by the BCMLaboratory for 10 sediment/soil samples from the OccidentalChemical Plant Site in Pottstown, Pennsylvania, has been completedaccording to EPA's "Functional Guidelines for Evaluating OrganicsAnalyses (2/88)", with modifications specified by EPA Region III.These data were reported under laboratory Order Numbers 37933,38191, 38298, and 38542. The following field samples were analyzedfor this parameter:

Sample Number Lab ID OrderOXY-SR-3-2-SED 037121 37933Field Rinsate Blank 037122 37933

• OXY-SW-1-SED 100608 38191Rinse Blank 100616 38191OXY-SW-10-SED 100768 38191Rinse Blank 100770 38191

OXY-B-1-SED 101067 38298•OXY-CLSO-1-SED 101068 38298Field Rinsate Blank 101072 38298-OXY-SR-4-2-SED 102117 38298•OXY-SR-1-3-SED 102120 38298.Field Rinsate Blank 102122 38298

OXY-FBG-1-S 102674 38542OXY-PGB-1-S 102675 38542OXY-PGB-1A-S 102676 38542

Because of the relatively small number of field samples andthe fact that samples from more than one order were run under thesame standard series in several cases, the four data packages werereviewed and ax-e being reported together, as a single set of data.

Analyses were performed according to the USEPA ContractLaboratory Program (CLP) 2/88 Statement of Work. According to thisprotocol, results of sample analyses are reported by the laboratoryas either qualified or unqualified. Unqualified results mean thatthe reported values may be used without reservations. Variousqualifier codes are used by the laboratory (per CLP procedures) todenote specific information regarding the analytical results.

During the validation process, laboratory-qualified andunqualified data are verified against all available supportingdocumentation. Based on this evaluation, qualifier codes may beadded, deleted, or modified by the data validator. Final validatedresults are, therefore, either qualified or unqualified.Unqualified results still mean that the reported values may be usedwithout reservation. Validator-qualified results are annotated

TRILLIUM,with the following codes in accordance with the Region Ill-modifiedFunctional Guidelines:

U = Not detected. The associated number indicates approximatesample concentration necessary to be detected.

B = Not detected substantially above the level reported inlaboratory or field blanks.

R = Unreliable result. Analyte may or may not be present inthe sample. Supporting data necessary to confirm result.

N = Tentative identification. Consider present. Specialmethods may be needed to confirm its presence or absencein future sampling efforts.

J = Analyte present. Reported value may not be accurate orprecise.

K = Analyte present. Reported value may be biased high.Actual value is expected to be lower.

L = Analyte present. Reported value may be biased low.Actual value is expected to be higher.

UJ = Not detected. Quantitation limit may be inaccurate orimprecise.

UL = Not detected. Quantitation limit is probably higher.

These codes are recorded on the Data Summary Sheets, containedin Attachment G of this validation report, to qualify the resultsas appropriate according to the review of the data package.

A considerable number of errors were found in all four of thedata packages, particularly with respect to the standards analyses.These will be discussed in the following sections of this report,rather than listing them here. Ultimately, they were found to havelittle or no adverse effect on the validity of the reportedresults. However, it must be emphasized that the quality of thedocumentation is also very important; these packages would notstand up well to a review that was based on general accuracy,rather than technical validity, or a review that focused on theability of the lab to correctly and consistently report sampleresults and supporting data.

No pesticides were confirmed to be present in any of thesediment, soil, or field rinse samples. A small amount of Aroclor-1254 was found in two samples, one sediment and one soil. Bothresults are below the Contract Required Quantitation Limit (CRQL),and are therefore qualified as estimated " J". A second columnconfirmation is available for only the soil sample, although in

AR307377

TRILLIUM,both cases the pattern matches closely with the Aroclor-1254standard run in that series. These results should be used withcaution.

Due to re-extractions, two field rinse blanks were held beyondthe holding time limit of 7 days; all results for these samples aretherefore qualified as estimated, "J" or "UJ". Three sedimentswere also re-extracted more than 7 days after collection, howeverthe water holding time criterion is not directly applicable tosolid samples; no qualifiers were applied in these cases.

Details of the validation findings and conclusions withrespect to the pesticide/PCB data are provided in the followingsections of this report:

I. Holding TimesII. Pesticides Instrument Performance

III. Calibration1. Initial2. Analytical Sequence3. Continuing

IV. BlanksV. Surrogate RecoveryVI. Matrix Spike/Matrix Spike Duplicate

VII. Field DuplicatesVIII. Compound IdentificationIX. Compound Quantitation and Reported Detection LimitsX. Overall Assessment

I. Holding Times

The 7 sediment and 3 soil samples that were analyzed forpesticides and PCBs were collected on 12/27/90, 1/8/91, 1/10/91,1/15/91, 1/18/91, and 1/28/91. All samples and associated rinseblanks were initially extracted no more than 7 days aftercollection, the established holding time. Three of the sedimentsrequired re-extraction which was performed 11 or 15 days aftercollection. No qualifiers are applied because the holding timecriterion is specific to water samples only; Region III protocoldoes not allow application of the water criterion to solid samples.

Two field rinsate blanks (lab #037122 and #101072) alsorequired re-extraction, performed 15 days after each was collected.Results for both of these samples are qualified as estimated, "UJ",per the validation guidelines.

\ TRILLIUM1NC.Cold storage of the samples from the time of collection until

analysis (or at least until arrival at the laboratory) is notdocumented on the chain-of-custody forms. Samples (and extracts)must be refrigerated (i.e., stored at 4 degrees C) according to 40CFR 136. Cold storage is a form of preservation and must bedocumented, or the assumption must be made that it was notperformed. No qualifiers are applied on this basis in this casedue to the same-day delivery of samples to the laboratory. It isassumed that the samples were properly stored once at the lab.

The Case Narrative for Order #38191 contains several errors;a copy of page 2 from the narrative is provided as Attachment A.Extraction dates are listed as 1/18 and 1/23 for the sediment andwater samples, respectively. These are actually the analysis dates;extraction was performed on 1/11 and 1/14, respectively. Also, 2of the spike recoveries listed are incorrect, and the first samplenumber listed in the spike recovery table is incomplete.

General problems with the chain-of-custody documentation arethe same as previously discussed in the validation reports for thevolatile and semivolatile data (dated June 7, 1991); these issuesare therefore not repeated here.

II. Pesticides Instrument Performance

Four criteria are evaluated to ensure that adequateChromatographic resolution and instrument sensitivity were achievedduring the analyses. These include: (1) DOT Retention Time; (2)Retention Time Windows; (3) DDT/Endrin Breakdown Check; and (4)Dibutylchlorendate (DEC) Surrogate"Retention Time Check.

The 10 soil/sediment samples and associated QC samples wereanalyzed under a total of 6 Standard Series, all performed on thesame Gas Chromatograph (GC) system using a split injection thatallowed essentially simultaneous primary and confirming analyses ondifferent columns. The 6 series are identified as follows:

1. Series 1/10-12/91; GC Channels 8, 9; Order #379332. Series 1/17-20/91; GC Channel 8; Orders #37933, 381913. Series 1/22-24/91, GC Channel 8; Orders #38191, 382984. Series 1/25-28/91; GC Channels 8, 9; Order #382985. Series 1/29-2/1/91; GC Channels 8,9; Orders #38298, 385426. Series 2/4-6/91; GC Channels 8,9; Order 38542

The order numbers indicate where the samples associated with eachseries are reported. It is noted that confirmation column runs (onGC channel 9) are not reported for the second and third serieslisted above, although for the third series, Form 8D-Linearity andBreakdown Summary and the raw data for the channel 9 standards werefound in the package for order #38298 only.

AR3Q7379

TRILLIUM1NCThe DDT retention time was well beyond the 12 minute

requirement; all runs were made on wide-bore capillary column, withDDT eluting at approximately 23-25 minutes.

Calculation of breakdown for DDT and Endrin in the EVALBstandards was not done consistently by the laboratory, and couldnot, in all cases, be reproduced. Attachment B contains severalexamples. In the first 2 runs provided, endrin aldehyde (EA) andendrin ketone (EK) peaks are correctly identified and used inbreakdown calculations. In the next 3 example runs, the peaklabelled by the data system as endosulfan sulfate (ESS) has beenused in the breakdown calculation; EA and EK are either not presentor much smaller. In the next example, EK was excluded from thecalculation even though a peak clearly within the retention timewindow for EK is present and integrated. In the last example, all3 peaks for EA, ESS, and EK are very obvious, and larger thanusual; the quant report shows manual areas that are lower thanthose integrated by the datasystem. The reported breakdown wascalculated from these lower areas.

Some of the observed errors or inconsistencies in breakdowncalculations resulted in higher than actual values being reported,and others in lower than actual values; several were reported,correctly, well above the 20% QC limit. Recalculation of all thebreakdowns was outside the scope of this review and therefore wasnot performed. Based on a review of the sample chromatograms, itwas verified that no DDT, Endrin, or related breakdown productswere confirmed at reportable levels in any of the samples,therefore the breakdown calculations have no real effect of thevalidity of this set of results. They do indicate a need forimprovement in laboratory practice with respect to this activity.

Stability of standard retention times throughout each 72-hourseries is evaluated through the use of retention time windows,established at the start of each series and recorded on Form 9.The retention time of each "continuing" standard analyte is alsorecorded on Form 9 and compared to the windows. Findings for eachseries are as follows:

Series 1/10-12: All continuing standard retention times wereinside the established windows.

Series 1/17-20: Retention times in all continuing standardswere later than the established windows, or just inside; atthe end of the series, the retention times were as much as 0.6minutes later than the window. It is noted that the rawdata and Form 9 for INDB2 on 1/18 at 20:08 was not provided;this continuing standard was run immediately after sedimentsample OXY-SW-10-SED, which contained numerous peaks. Theidentification of beta-BHC, gamma-BHC, and aldrin peaks inINDB5 on 1/20 at 08:42 is incorrect. The elution order usedby the lab is correct for GC channel 9, but this run is on GC

AR3Q7380

x TRILL!UM,Ncchannel 8. A corrected copy of the raw data and Form 9 isprovided in Attachment C. Using the correct retention times,the standards are still later than the windows but at leastconsistently so.

Series 1/22-24; This is a short series, as reported here,with only 1 continuing standard, INDA2 on 1/24, in addition tothe series ending INDA and INDB runs. All retention times arelater than the established windows, by 0.3-0.6 minutes in theending standards.The ending INDB run on 1/24 at 16:05 islisted as "INDA5" on Form 8E and Form 9, and the raw data ismislabelled but hand-corrected to read "INDB" with no initialsor date. Most crucially, the lab has identified the peaks inthe standard-and recorded them on Form 9-as the compoundscontained in the INDA mix. As a result, retention timesappear to vary inconsistently when compared with the windows.A corrected copy of Form 9 is provided in Attachment D. Usingthe correct retention times, the standards are still laterthan the windows, but at least consistently so.

Series 1/25-28: All continuing standard retention times arejust within the established windows or slightly late on GCchannel 8. The retention time for endrin in INDB5 on 1/28 at04:20 is incorrectly recorded as 24.00 on Form 9; the correctretention time is 24.84. No retention time windows areprovided for the GC channel 9 standards. Instead, thereference retention time from the initial INDA and INDB runsis listed as both the "From" and "To" times. Continuingstandard retention times match the reference times veryclosely, in most cases within 0.1 minute. The retention timefor methoxychlor on channel 9 is incorrectly listed as 26.24on Form 9; the correct time is 25.81 (26.24 is the DECretention time).

Series 1/29-2/1; All continuing retention times are withinthe established windows on both channels, with the singleexception of INDB2 on 1/30 at 19:25 on channel 8. In thiscase, the retention times are just within the windows orslightly late.

Series 2/4-6; All continuing retention times are within theestablished windows on channel 9. On channel 8, the firstINDA continuing standard is within the established windows,but all subsequent runs are later than the windows by 0.3-0.5minutes. On Form 9 for INDB4 on 2/6 at 23:03 on channel 8both dieldrin and DDT are listed with a retention time of23.88; dieldrin is not in the INDB standard mix, and should bedeleted from this form.

Retention time stability within a series is also monitored bywatching the shift of the DEC surrogate retention time in everystandard and sample run; the Percent Difference (%D) between the

flR30738l

TRILL1UM1NCDEC retention time in the first EVALA run of the series and thecurrent run is recorded on Form 8E, which also serves as a run logsince it identifies, in chronological sequence, all the runsperformed in each series. Findings with respect to this QCindicator generally parallel the findings with respect to thestandard retention time windows, as follows:

Series 1/10-12; %D is well below the 1.5% limit for wide-borecapillary columns for all runs on both channels.

Series 1/17-20; %D steadily increases throughout the series,reaching 3.3% with the ending INDA and INDB runs. The lastrun for a reported OXY sample was early in the series,however; at the time of this run, the %D was, at 1.3%, stillwithin the QC limit.

Series 1/22-24: %D again steadily increases, to 2.5% in theINDA and INDB runs at the end. The last OXY sample %D is1.0%, and all runs up to that point are within the QC limit.

Series 1/25-28; %D is much more consistent here throughoutthe series on both channels. On channel 8, the last OXYsample run has a %D of 1.6, the highest value of any run inthe series. On channel 9, all OXY samples and standards have%D less than 0.5.

Series 1/29-2/1: Three OXY QC samples have %D of 1.7 onchannel 8; all other pertinent runs are well within the limit.On channel 9, all series runs are within the 1.5% limit.

Series 2/4-6; %D is okay through all OXY sample analyses onchannel 8, but increases to 2.9% towards the end of theseries. On channel 9, all pertinent runs are okay.

Because qualitative identification of target analytes insamples is based entirely on matching retention times, it iscritical that stable retention times be maintained in standard runsthroughout the analysis series. Shifts such as those identifiedhere could cause misidentifications, including false negatives andfalse positives, if sample data are not carefully interpreted. Inthis case, careful review of the sample chromatograms verified thatno misidentifications were reported by the laboratory, thereforethe findings outside of QC limits cited above have no real effecton the validity of the reported results.

It is noted that the order in which the standard raw data ispresented in the data packages makes validation with respect toeach series extremely difficult. Instead of arranging the EVALAfrom each applicable series followed by all the EVALB's, followedby all EVALC's, etc., it is recommended that the laboratory compileall the standards for each series in chronological order, before

7

HR3073S2

TRILLIUM,.,proceeding with the next series. While there is no CLP requirementspecifying the order to be used, a series-based format should provemore straightforward for both assembly and review of the datapackages.

III. Calibration

1. Linearity. The Percent Relative Standard Deviation (%RSD)for aldrin, endrin, DDT and DBG was less than 10% in all reportedseries except for DDT in the following: Series 1/25-28, GC Channel9; Series 1/29-2/1, GC Channel 9; and Series 2/4-6, GC Channel 9.In each case, a 3-point curve for DDT was performed as required.%RSD calculations could not be reproduced for aldrin and DDT inSeries 1/10-12, GC Channel 9, and for endrin in Series 1/29-2/1, GCChannel 9. In both these series, results were quantitated from theChannel 9 data. See Section IX below for further discussion.

2. Analytical Sequence. The number and order of standardruns in each series is satisfactory. In Series 2/4-6, however, itwas observed that the "paired" analyses on channels 8 and 9 did nothave identical Injection times. Per conversation with R.Allessandro of the BCM Laboratory, the simultaneous injectionsystem utilized on the GC can be programmed to inject an aliquotfrom the same vial simultaneously on each channel (thus generatingpaired runs with identical injection times), or to inject analiquot from different vials on each of the channels (thusgenerating "offset" paired runs). The same phenomenon was noticedin Series 1/22-24, since the raw data for channel 9 was provided inone of the data packages, even though it apparently was not meantto be reported. This has no affect on the technical validity ofthe data, but it is very confusing. It is also hard to imagine ascenario where you would want to offset the sample injections onthe two channels. A brief explanation from the lab-ideally in theCase Narrative-would have been helpful.

3. Continuing. CLP requires that the calibration factor (CF)for each standard be within 15% of the initial series CF forquantitation, and within 20% for confirmation. It is impossible totell from the Form 9's provided in these data packages which column(or channel) data was used for quantitation vs. confirmationbecause every standard on both channels is identified as being usedfor quantitation, i.e. a "Y" is recorded in the "Quant-Y/N" column.Further, many %D values in excess of 15% and 20% were found inevery series. (Note: Where compounds were misidentified by thelab, as discussed above, corrected CF's were used for calculationof %D; corrected values are contained in Attachments C and D.) Inaddition, several errors and omissions were found:

HR3Q7383

v TRILLlUlVLc,.INDB2 1/26 21:11(9)-ESS not on Form 9; CF=1851550, %D=35.9.INDB2 1/30 19:25(8)-DDT not on Form 9; CF=1137000, %D=19.0.INDA2 1/30,09:38(9)-%D for DDT=l.o%, not 70.4% as reported.INDA4 2/06 22:18(8)-%D for DDT=14.6%, not 113.9%.INDB4 2/06 23:03(8)-%D for DDT=9.2%, not 247.6%

-%D for DDE=5.9%, not 43.3%

In INDB4, 2/6 at 23:03 on channel 9, it appears from thechromatogram that the system integration may be in error, and atleast partly responsible for the very high %D values reported (forESS and gamma-chlordane in particular); see chromatogram inAttachment E. No manual areas were generated by the lab for thisstandard.

The %D values in excess of the 15% and 20% limits are toonumerous to list here (all may be found on the Form 9's in eachdata package, with corrections as noted above); their effect on thevalidity of the reported data is discussed further in Sections IXand X of this report.

IV. Blanks

Laboratory method blanks (MB) were reported for each matrix(solid and water) and for each extraction batch containing reportedOXY sample results. All MB results were below CRQL's for allpesticide and PCB target analytes. Some unknown peaks not matchingany target compound retention times were observed in most of theblanks, and were also seen in several samples. This is not aproblem. A peak identified as ESS by the datasystem in severalruns was confirmed by GC/MS to be bis(2-ethylhexyl)phthalate, andis also seen in several of the blanks.

A copy of the Form I and chromatogram for each MB is providedin Attachment F, for reference, as required by Region III.

V. Surrogate Recovery

All surrogate recoveries are within the advisory limits of 24-154% for water and 20-150% for soil as prescribed in the 2/88 CLPStatement of Work. The Form 2's for soil samples in the datapackages incorrectly indicate limits of 24-150%, causing therecovery for 1 sediment sample, at 22%, to appear "out".

Two sediment samples were re-extracted due to no surrogaterecovery in the original analyses. On re-extraction, recoveriesfor DBC in OXY-SR-4-2-SED and OXY-SR-1-3-SED were still low, butwithin limits at 22% and 36%. Only the re-extract data is(correctly) reported.

\ TRILLIUIVLc.VI. Matrix Spike/Matrix Spike Duplicates

A matrix spike/matrix spike duplicate (MS/MSD) pair wasprocessed with each batch for both matrices (water and solid).Labelling of the MS/MSD's is confusing: the waters are simply"SPK" and "DUP", while the solids (for which field samples wereused) are referred to as their own assigned lab numbers (e.g.,100618 and 100619) or as the original sample's lab number with asuffix of MS or MSD (e.g., 100608MS and 100608MSD) . Neither one isincorrect, but more consistency would be very helpful in followingwhat has been done.

Most of the percent recovery (%R) and relative percentdifference (RPD) values were within limits; the followingexceptions are noted:

SPK, Batch GCW586: %R for gamma-BHC 50% (QC 56-123%)%R for dieldrin 26% (QC 52-126%)

DUP, Batch GCW586: %R for gamma-BHC 48%%R for dieldrin 28%

100608MS, Batch GCS582: %R for DDT 147% (QC 23-134%)

DUP, Batch GCW602: All 6 RPD's high, at 22-32% (QC 15-27%)%R for dieldrin 46%

SPK, Batch GCW602: %R for gamma-BHC 46%%R for dieldrin 36%

SPK, Batch GCW593: %R for gamma-BHC 45%%R for dieldrin 22%

DUP, Batch GCW593: %R for gamma-BHC 55% RPD 20% (QC 15%)%R for dieldrin 32% RPD 37% (QC 18%)

102674MSD, Batch GCS614: %R for gamma-BHC 131% (QC 46-127)%R for DDT 163% (QC 12-134%)

SPK, Batch GCW610: %R gamma-BHC 125%

None of these results has any adverse effect on the technicalvalidity of the sample results as reported.

VII. Field Duplicates

Samples OXY-PGB-1-S and OXY-PGB-1A-S were prepared as fieldduplicates. No positive target compound results were obtained forcomparison. Percent moisture is very comparable, at 20 and 17%,respectively. Visual examination of the chromatograms for thesesamples also shows considerable similarity.

10

AR3Q7385

\ TRILLIUM,VIII. Compound Identification

Where data from both channels 8 and 9 are available forreview, there is no question that compound identifications arecorrectly made by the laboratory. In the cases of 2 sedimentsamples, however, only data from channel 8 is provided. Both ofthese samples (OXY-SW-1-SED and OXY-SW-10-SED) are very dirty,showing numerous peaks and high baselines, which make analyteidentifications based only on retention times both difficult andtentative.

In the case of OXY-SW-1-SED (lab #100608), I agree with thelab's tentative identification of gamma-BHC, aldrin, and DDT peakson the chromatogram, but believe that peaks at the retention timesfor ODD and EK are also present. None of these are above theCRQL's, and are therefore not reported. However, this sample wasrun in Series 1/17-20, where the DBC retention shift increasedsteadily from start to finish; it is therefore possible that we arenot making the best possible comparisons with respect to analyteretention times in the sample and series standards. A confirmationrun would go a long way toward ensuring either that no analytepeaks were missed, or that the tentatively identified analytes werenot actually present at all.

Sample OXY-SW-io-SED (lab #100768) is also a "dirty" sample,with numerous peaks and a sharp baseline rise. Based on patternmatching to the series Aroclor standards, this sample was found tocontain a small amount of Aroclor 1254, but no confirmation of thisresult is provided. Because of the pattern identification inaddition to retention time matching, the result is reported evenwithout a confirmation run (as an estimated value), but the datawould be more supportable if confirmation were available.

Many of the sample and field rinse blank samples contained noidentifiable target analytes in the primary analyses but are stillreported with a paired confirmation run. Since it is known thatthe lab was using a simultaneous injection technique for theanalyses, make both analyses would be automatically available afterinjection. It is therefore unclear why no confirmation data isavailable for some of the reported analyses, the 2 sedimentsdiscussed above in particular. An explanation of this apparentinconsistency in the Case Narrative(s) would be helpful.

IX. Compound Ouantitation and Reported Detection Limits

All reported quantitation limits correctly account for samplevolumes less than 1000 ml in some of the rinse blanks (recorded asdilution factors on the Data Summary Forms) and for % moisture inthe solid samples.

From the DBC surrogate recovery values reported on Form 2 ineach package, it can be surmised which of the 2 channel analyses

11

flR3Q7386

\TRILLIUM(where both are available) was used by the lab to quantitate thereported results. For Series 1/17-20 and Series 1/22-24, where noconfirmation run (channel 9) data were reported, data from channel8 were consistently used for the DBC calculations. For Series1/10-12 and Series 1/25-28, all associated runs were calculatedfrom the channel 9 data. For Series 2/4-6, channel 8 results wereconsistently used. In Series 1/29-2/1, however, channel 9 data wasused except for 2 rinse blank runs, lab #102678 and #101072, wherethe channel 8 data was used.

It is not immediately obvious why channel 8 or 9 was selectedfor quantitation in any of the series, since problems were notedwith retention time windows, DBC shifts, and CF %D values in datafrom both channels in all of the series. Since no targetpesticides were confirmed in any of the samples, it doesn't makemuch difference which one was used in this case; the results wouldstill be the same. Aroclor 1254 was confirmed in one sample (OXY-FBG-l-S) and reported unconfirmed in a second sample (OXY-SW-10-SED) ; both results were correctly reported from the channel 8 data.

It is good practice to be consistent about which run is usedfor quantitation within each series. This was not the case forSeries 1/29-2/1. Here, it appears that the lab used whichever rungave the best DBC recovery for each sample:

%R DBC %R DBCSample Number Channel 8 . Channel 9

OXY-SR-4-2-SED (102117) 3.1% 22% *OXY-SR-1-3-SED (102120) 6.1% 36% *Rinse Blank (102678) 37% * 24%Rinse Blank (101072) 77% * 57%

The "*" values are the ones reported on Form 2 in each case. Forthe rinse blanks, both %R values are within the QC limits; if thechannel 9 results had been reported, quantitation within the serieswould have been consistent, as the QC samples and MB were alsoquantitated using channel 9. The channel 8 recoveries for thesediments are obviously below the QC limits; this is probablyattributable to the sample matrix, however, since these are re-extracted samples in which the original runs had no recovery ofDBC. While the reported results are not wrong, the procedures usedfor quantitation could make the data more difficult to support.

X. Overall Assessment

While the reported results in this case are ultimately notadversely affected, significant quality problems were observed inthe presentation of the data package itself and in the validity ofthe series standards for quantitation.

The errors and omissions in the data are discussed at lengthin the preceding sections of this report, and will not be repeated

12

HR3G7387

TRILLIUM™,here. They suggest a need for more (or perhaps simply morecareful) review of the summary forms in particular before releaseof the data.

Two issues related to the standards are of primary concern:(1) the shifting retention times make qualitative identification ofanalytes extremely difficult, especially in "dirty" samples; and(2) CF's that vary by more than 15% (or 20%) indicate a significantchange in how the instrument is responding to the analytes, andmake any quantitations that are performed estimates, at best. Infact, CLP requires that when the 15 and 20% criteria for CF's arenot met that the series be terminated until acceptable results areobtained. The lab consistently used CF's from the initial standardA and B runs in each series for quantitation. A sample run 24-36hours into the series, where a continuing A or B standard showsCF's varying by 30% or more, cannot be accurately quantitated usingthe initial CF values. Note that determining that no analytes arepresent above the CRQL's is a form of quantitation.

In most of the samples in this case, no analytes werequalitatively identified in either of the available runs. In theone sample where very low levels (well below the CRQL) of 3pesticides were identified, they were not confirmed and aretherefore not reported. The two Aroclor 1254 results that arereported are already estimated since they are below the CRQL. Hadthere been any confirmed positive results for this set of samples,most would have been qualified as estimated and some may have beenrejected based on the continuing standard results.

Pesticide/PCB data for these samples were considered valid asreported with the following exceptions and modifications:

All results for 2 field rinse blanks (lab #037122 and #101072)are qualified as estimated "UJ" due to missed holding times.

The Aroclor 1254 result for OXY-SW-1O-SED is qualified asestimated "J*" as the value is below the CRQL and has not beenconfirmed on a second column.

13

flR307388

TRILLIUM INC.

ATTACHMENT A

Case Narrative, Order 38191Page 2

HR3G7389

GC-EXTRACTABLES! BCM ! Occidental Chemical

Form III " ~

—time trip blank filled at laboratory not documented—no sample type (composite or grab) listed for trip blank

Soil samples and associated QC samples extracted in batch GCS582 on1/18/91 within the 10 day CLP extraction holding time. Rinse blanks wereextracted in batch GCW586 on 1/23/91. All samples were analyzed withinthe 40 day post-extraction holding time.

Based on screening by extract color, soil samples were initially run at a1:5 dilution. Samples were re-analyzed at no dilution. Only theundiluted runs were reported. These straight rerun samples were given an"RE" suffix.

Sample 100768RE's arochlor 1254 hit was not confirmed. Arochlor'sconcentration is estimated as it is under the quantitation limit.

is(2-ethylhexyl)phthalate [BEH] was found to coelute with endosulfanIfate. This was confirmed by GC/MS. Tentative endosulfan sulfate ine rinse blank hits were therefore discounted as BEH.

All RPDs fell within acceptable limits.

The following spike recoveries fell outside of QC limits:

Sample Compound Recovery QC Limit

10061 4,4'-DDT 147 23-134%DI spike lindane 40 56-123%

" dieldrin 26 52-126%DI spike dup lindane 46 56-123%

" dieldrin 28 ' 52-126%

Release of the data contained in this hard copy data package has beenauthorized by the Laboratory Director as verified ..by the followingsignature. • //

Laboratory Director

flR307390 °00005

\TRILLIUM INC.

ATTACHMENT B

EXAMPLES: Endrin Breakdown CalculationsEVALB Chromatograms

GC Channel 8

^307391

HLT1 LftHUKftI UKltb K«port - litNlt nedium_flrea rorind

: LUPLb Keport No : lUb.UlLXU.uriN SHH6UB 5UP1 HY U.^nn MlbtU~ SILILR Page I•LÎIIJ iniN bc/niN, wtxj IUHIN uti ^ÛL INJ vûu

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Instrument : rtUL_H Application ! Loop

\:.f> t cu 1 at \or> : hvternalblU Uuan t i t at i on : WreaUnits

W«-.ult t - i l e : /Uttltt/tXIK«L!b/KtbULI /I U12212U . Khb

Wim l i m n : J6.UU Htnutes Injected on ixled Jan 25. 1VV1 5:56:*2U am

I- i I c s /Lift I «XtX t KttC I S/i=hUUtNUh./iDfc.UL:Lhl_U122y l_b . SLU

t e : I/ 2U bottle no. : 2U

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bample Name : tU«Ub2 Wsport No :1/3.Uli..ui_unN UW6UW ->un HY u.^nn hustu biLiLft Hagc 1

IL. in IN û/niN 2/ u luniN ut i. ULH I LL LUMHIJUNUbjilKljntNl IWttUUK >7AU 'J LIL INJ. UUL.

Hook/Hage :

Heû Processor : bien i e nu 11 i l eve l : i-a ise

Instrument : POL_b Mnp I \cat\on : Loop

Lalculation : txternaiblU Uuantitation : OreaUnits

Weûlt I- lie : /UR I «/tX I KttlJ I b/KtbUL I / I Ul'2l7l_5 . H?tb

Kun l i m n : 56. UU nmutes. Injected on bat Jan 26. 1W1 /JIJllUU am

Sequence K i l e : /IJ« I tt/hX I W«L I b/btUUtNIJt/btULLP_U I'- y 1_H . btU

e: I/ '25 b o t t l e no. : 25

nin — rtr HU 1*1 \ o t h Kt- _UnUnouin1. "71111 lit+ m . iUU 2.655t-U/

Wet-WlUl Non Ke t Ul i n rtbs Non We+-'-wiiJ Ident LevelU . II U 1 . <? U U.U U 1 . *> U 1 U U U . U U

'l.Ul-'-act bmp-«mt Std-«mt X Hur\ty In] Un I WatlOL.UUUUt»U2 U.UUUUt*UU l.UUUUt+UU 1LIU.UUU l.llllll

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S a m l e Name : tv«Lb2 Weport No :Ub6UB 5un bY u.'sjnn Mjbtu blLlUtt Page 'i

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.2/.JAV tndosulfan sulVate<iH ."? 1.^ ~ibijt«.»lr:n lorendat. o>^

AR307395000351

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•/! /. 2^ i -LI ion -su i »^nb 111 v I c n\l orendate

BCM LABORATORIES Report - GENIE Medium_Area Form

Sample Name : EUALB3 • Report No :185.00UMN DB608 30M BY 0.53MM FUSED SILICA Page 1

IMIN 5C/MIN 275C lOHIN DET 350C INJ 250CCLP TCL COMPOUNDS

INSTRUMENT TRACOR 540 1UL INJ. UOL.

Book/Page : 1016/25

Peak Processor : Genie Multilevel : False

Instrument : ADC_8 Application : Loop

Calculation : ExternalSTD Quantitation: AreaUnits

Result File : /DATA/EXTRACTS/RESULT/I 0125135.RES

Run Time : 36.02 Minutes Injected on Sat Jan 26, 1991 4:41:21 pm

Sequence File: /DATA/EXTRACTS/SEQUENCE/SEU.CLP_012591_8 . SEQ

Subseq/Sample: I/ 35 Bottle no. : 55

Threshold Min-Ar _ Pkwidth RF_Unknown2.0 1 . 5 0 0 0 E + 0 3 . 1 0 0 2.6^3E-U7

Ref Udw Abs Ref-RTU Non Ref Win Abs Non Ref-RTU Ident Level*0.00 1.50 0.00 1.50 . 1000.00

1-Fact Smp-Amt Std-Amt X Purity Inj Uo 1 Ratiol.OOOOE+02 O.OOOOE+00 l.OOOOE+UO 100.UUO 1.000

Run Status : RunStatusQK

Timed Events Time Events Logic Uaiue EventUpdate1 .05 ResetBLAi1Ua1 ley EventOn -1.00 False2 .10 AutoSolvent EventOff -1.00 False

Pktt RT ID-tm PeakUidth Area Code AMOUNT Name1 1.61 #1.55 .1065 2594188BB 5.U048E+U1 SOLVENT FRUNT2 2.12 .0779 18691BB 4.92ly£-033 2.36 .0418 13639BB 3.5916E-034 IB.46 IB.29 .1260 18205BB 1.698UE-02 Aldrin5 24.79 24.63 .1238 21388BB 2.038UE-U2 Endrin6 26.37 26.15 .1374 38256BB 3.6579E-02 4,4'-OUT7 27.54 27.23 .1771 3489GB 2.4266E-02 Endosulf-an sulf-ate8 28.72 #28.37 .1882 . 118473BB 1.0246E-01 Dibutyich1orendate

Total Area : 2826328 Total AMOUNT : 50.257

Report Time : Sat Jan 26, 1991 5:18:09 pmhod : /DATA/EXTRACTS/METHOD/MTHCLP_012591_8 . nTHn h


Sample Name : EVALB3 Report No : 189". 00COLUMN DB608 30M BY 0.55MM FUSED SILICA ________ Page 2————— . . ________

SOLvENT FRONT

_18.459 Aldrin

\ — — — — _24.786 Endrin

====————————— _26.374 4,4'-DDT_27.543 Endosulfan sulfate

_2b . 722. Uibutylch lorendate

flR307399000374


Name : EUALB Report No : 226. 00DB608 30M BY 0.53MM FUSED SILICA Page 1

150C 1M1N 5C/MIN 275C 10MIN UET 35UC INJ 25UCALL CLP TCL COMPOUNDSINSTRUMENT TRACOR 540 1UL INJ. UUL.

Book/Page : 1016/33


Instrument : AUC_B Application : Loop


Result File : /DATA/EXTRACTS/RESULT/ I 0129102 . RtS

Kun Time : 36.00 Minutes Injected on Tue Jan 29, lyyi 12:37:52 pm

Sequence F i 1 e : /DA TA/EXTRACTS/SEQUtNCE/SEQCLP_0 12V9 1_8 . SEQ


Threshold Min-Ar Pkwidth Kh_Unknown2.0 1.5000E+03 .100- 2.655E-U7

Udw Abs Ref-RFLJ Non Ref LJin Abs Non Ref-RTtJ Ident LevelO.UO 1.50 O.UO 1.50 1UUO.UU

% Oil-Fact Smp-Amt Std-Amt X Purity Inj Uo 1 Ratiol.UUUOE+02 O.OOOOE+UO l.OUOOE+UO 1UO.OUO l.UUO

Run Status : ExcessNegat i ve

Timed Events Time Events Logic Ualue EventUpdate1 .05 ResetBLAl lUal ley Event On • -1.00 False2 .10 AutoSolvent EventOff -l.UO False

RT ID-tm PeaklJidth Area Code AMUUN I Name1 1.72 #1.53 .0095 202055BB 3.8V81E+00 SOLUEN T FRUNT2 2.16 .0516 6347BB 1.6712E-03.3 18.68 .1290 i=*-23683BB 6 . 2366E-03ff V J — ',.* 21.12 21.21 .1688 119105BB 7.6147E-02' g^mnu Cli 1 u i Ooiie &*5 21.94 21. ?6 7.6741 310890BB 2.3454E-U1 EinJuoul Tun-I ^ '6 25.00 24.96 .1249 =^22453Bb 2. D4B4E-02 4", 4 ' -UUtT A-l uyK7 26.59 26.63 .1309 -= -40487BB 3 . 2807E-02 g 'EncTriii Al duhygu8 27.77 .1839 5162B8 1.3593E-039 28.98 .1994 134306BB 3 . 5367E-02 & fo C10 32.25 .2313 1628BB 4.285BE-04

75.08 .1822 4888BB 1.2871E-Q3

tal Area : 871001 Total AMOUNT : 4.308

Report Time : Tue Jan 29, 1991 1:14:48 pi-Method : /DATA/EXTRACTS/METHOD/MTHCLP_012591_8.MTH kQ^ni!

OOO144


Sample Name : EUALB Report No :226.0UCOLUMN DB608 30M BY 0.53MM FUSED SILICA ____ Page 2

SOLUENT FRONT

_18.677

\ _21.121 gamma-Chlordane... _21.938 Endosulfan I

_24.997 4,4'-OUU

•_26.59U Endrin Aldehydec

<*r

fo

SCtl-LABOR A TORIES Report - GENIE Medium_Area Form

Sample Name : EUALB2 Report No :247.00COLUMN DB608 3OH BY 0.53MM FUSED'SILICA Page 115UC 1M1N 5C/M1N 275C 10M1N DET 35UC INJ 25UCALL CLP TCL COMPOUNDSSTRUMENT TRACOR 540 1UL 1NJ. UOL.

ook/Page : 1016/33

Peak Processor : Genie Mu l t i l e v e l : False

Instrument : ADC_.8 Application : Loop


Result File : /DATA/EXTRACTS/RESULT/IU129123.RES

Run Time : 36.02 Minutes Injected on Wed Jan 3U, 1991 5:U7:55 am

Sequence File: /DArA/EXTRACTS/SEQUENCE/SEQCLP_U12991_8.SEQ


Threshold Min-Ar Pkwidth R(-_Unknown2.0 1.5000E+03 .100 2.633E-U7

Ref Udui Abs Ref-RFU Non Ref LJin Abs Non Ref-RlU Ident Level0.00 1.50 O.UO 1.50 1UUO.UU

Oil-Fact Smp-Amt Std-Amt S Purity Inj vol RatioOOOOE+02 O.OOOOE+00 l.OOOOE+UO 100.UUO 1.000

Run Status : RunStatusOK

Timed Events Time Events Logic Ualue EventUpdate1 .05 ResetBLAlIvalley EventOn -1.00 False2 .10 AutoSolvent EventUff -l.UO h'alse

Pk# RT ID-tm PeakUidth Area Code AMOUNT Name1 1.77 #1.53 .1110 34y7486bB 6.7767E+U1 SOLUE.NT FRUNT2 2.23 . U523 4749Bb 1.25U7E-033 18.87 18.77 .1194 2561V88 2.17b4E-U2 Al d r i n4 25.20 25.08 .1230 22522BB 2.U393E-02 Endrin5 26.82 26.69 .1382 39693bB 4.1125E-U2 4,4'-UDT6 28.02 27.83 .1795 6122BB 3.653UE-05 Endosuifan suifate7 29.26 #29.U9 .1842 123717BB 1.1341E-U1 DibutyIch1orendateb 32.65 .2434 166UBB 4.372UE-04

Total flrea : 3721569 Total «ntJUNT : 67.V69

Report Time : Ued Jan 30, 1991 5:44:59 amnet hod : /DATA/EXTRACTS/METHOD/MTHCLP_U12591_8.nIH

AR307U02000354

LABORATORIES Report - GfcLNlE Medium_Area Form

Sample Name : EUALB2 Report No :247.UOCOLUMN DB608 3DM BY 0.53MM FUSED SILICA Page 2

1

FRONT_ 2.229

f

18.865 Aldrin

f

•5————""——•~—— 25.199 Endrin

_26.817 4,4'-DDF

_28.02l Endosulfan sulfate_29.261 D'lbutylch lorendate

*1_32.647 ==>

000355


Sample Name : EUALB4 Report No :166.00COLUMN SPB608 30M BY 0.53MM FUSED SILICA Paqe 1150C 1MIN 5C/MIN 275C 10M1N DET 350C INJ 250CALL CLP TCL COMPOUNDS -INSTRUMENT TRACQR 540 3UL INJ. UOL.

Book/Paqe : E1016/




Result File : /DATA/EXTRACTS/RESULT/1 0109209.RES

Run Time : 36.00 Minutes Injected on Fri Jan 11, 1991 7:14:12 pm

Sequence; File: /DATA/EXTRACTS/SEQUENCE/SEQCLP_011191_8.SEQ

Subseq/Samp le: I/ 9 Bottle no. '. 9

Threshold Min-Ar Pkwidth RF_Unknown2.0 1.5000E+03 .100 2.633E-07

Ref Udw Abs Ref-RTU Non Ref Win Abs Non Ref-RTU Ident Level0.00 1.00 0.00 1.00 1000.00

% Oil-Fact Smp-Amt Std-Amt X Purity Inj Uo1 Ratiol.OOOOE+02 O.OOOOE>00 l.OOOOE+00 100.000 1.000

Run Status : EndOffBase 1ineSiqnaIQverload

Timed Events Time Events Loqic Ualue EventUpdate1 .05 ResetBLAlIvalley EventOn -1.00 False2 .1U WutoSolvent EventOff -1.00 False

PM. RT ID-tm PeakUidth Area Code AMOUNT Name1 .14 .1850 14400PH 3.7921E-032 1.21 #.56 .1)337 16949512GB 7. 1489E+G1 - SOLUENT FRONT3 16.55 16.57 .0857 36125BB 2.0637E-02 Aldrin4 18.54 .2551 14263BB 3.7559E-03? 22.85 22.36 ' .0876 23529BB 2.5886E-02 Endrin6 24.47 24.48 .0813 52091BB 4.7831E-U2 4,4'-DDT7 24.83 24.84 .0943 ?2.7J -46Jj?ee 4. 1341E-03 Endrin Aldehyde3 25.55 25.J2 .0976 ' 6534BB 4.6341E-G3 EmKrycil fan "Srri Pate9 26.48 26.49 .0976 168579BB 1.2603E-01 DibutvIchlorendate10 28.82 28.87 .1145 ~<'j&io . 67BB 2.4235E-03 Cndr in .ir.etane11 35.46 .AA13 "5 17305BB 4.5570E-03


Report Time : Fri Jan 11, 1991 7:51:46 pmMethod : /DATA/EXTRACTS/METHQD/MTHCLP_010991_8 .MTH


Sample Name : EUALB4 Report No :16jCOLUMN 5PB608 70M BY 0.53MM FUSED SILICA___________ Paqj

-————————=== . 143 |___________________ I1 ' • ' SOLVENTj FRONT

..\.t

*

f

ri

\\

Aldri

18.540

?l

<rt<V ________________ 'r """"" EndrinC

Endrin AldehydeEndosulfan sulfate

U1DDtylchlor sndate

i '-DDT

Endrin Ketone..

TRILL1UM INC.

ATTACHMENT C

Corrected Standard:INDB5, Series 1/17-20/91

39433

9PESTICIDE/PCB STANDARDS SUMMARY

Lab Name: BCM Contract:

Lab Code: BCM Case No.: SAS No.: SDG No.: S582B

Instrument ID: 0008 GC Column ID: CAP

COMPOUND

alpha-BHCbeta-BHCdelta-BHC __ rgamma-BHC (LiHeptachlorAldrinKept. EpoxideEndosulfan IDieldrin4,4' -DDE ____EndrinEndosulfan II4,4' -ODD ____Endo. sulfate4,4' -DDTMethoxychlorEndrin ketonea. Chlordaneg. Chlordane-ToxapheneAroclor-1016Aroclor— 1221Aroclor-1232Aroclor-1242Aroclor-1248Aroclor-1254Aroclor-1260

DATE(S) OF FROM: 1/17/91ANALYSIS TO: 1/18/91TIME(S) OF FROM: 18:46ANALYSIS TO: 1:14

RT

11.9313.8715.3713.5414.8416.1618.4219.7820.9820.7522.4223.1122.9024.8524.0327.6828.1519.7119.0723.2014.9610.9214.9816.2517.5920.4722.41

FWlh

FROM

11.8113.7415.2113.4014.6916.0018.2419.5820.7720.5422.1922.8822.6724.6023.7927.4127.8619.5218.8822.9714.8110.8114.8316.0917.4120.2722.19

.TtDOW

TO

12.0514.0115.5213.6814.9916.3318.6119.9821.1920.9622.6423.3423.1225.1024.2727.9628.4319.9119.2623.4315.1111.0315.1316.4117.7720.6722.63

CALIBRATIONFACTOR

916600.647750.815500.830900.1077400.952700.1087650.1097000.972750.874200.650750.945200.654550.802750.687625.423460.1166150.1158600.1101600.51172.257052.78012.116786.269992.172348.224530.247696.

DATE OF ANALYSIS 1/20/91TIME OF ANALYSIS 8:42EPA SAMPLE NO.(STANDARD) INDB 5

RT

12.63lo.io/;ic.-03-y'

H-rS-8-A

21.4923.20

23.6625.66

29.3320.4819.85

1

CALIBRATIONFACTOR

964500.•SB W T"ff&.•/O 903 0-ffO .

43 7004UJT

9.89000.722100.

770400.950250.

1312300.1235800.1226650.

1

QNTY/N

YYYYYYYYYYYYYYYYYYYYYYYYYYY

%D

5.2•3 -rB•t n niSrTi fjf

• DO.P

13.111.0

17.718.4

.06.711.4

—————

%D must be less than, or equal to 15.0% for quantitation, and less thanor equal to 20.0% for confirmation.

Note: Determining that no compounds were found above the CRQL is a form ofquantitation, and therefore at least one column must meet the 15.0% criteria.

For nulticonponent analytes, the largest single peak that is characteristicof the component should be used to establish retention time and %D.Identification of such analytes is based primarily on pattern recognition.

page X of f 000063, /0_ _/ A. FORM IX PEST 1/87 Rev.

o n *J !. r» -

J U . V 7 J


Sample Name : INDB? Report No : 85.00COLUMN SPB608 30M BY 0.53MM FUSED SILICA Page 1150C 1MIN 5C/M1N 275C 10MIN DET 350C ING 250CALL CLP TCL COMPOUNDSINSTRUMENT TRACOR 540 3UL INJ. UOL.

Book/Page :


Instrument

Caleulat ion

Result File

Run Time

Sequence File

Subaeq/Somple

ADC_8 Application : Loop

ExternalSTD Quantitat ions AreaUnits

/DATA/EXTRACTS/RESULTV10117323.RES

36.00 Minutes Injected on Sun Jan 20, 1991 8:42:07 am

/DATAXEXTRACTS/SEQUENCE/'SEQCLP_011991_8. SEQ

I/ 23 Bottle no. : 23


Ref Uldw Abs Ref-RTU Non Ref Uin Abs Non Ref-RTU Ident Level0.00 1.50 0.00 1.50 1000.00

% Oil-Fact Smp-Amt Std-Amt % Purity Inj Uol Ratiol.OOOOE+02 O.OOOOE+00 l.OOOOE+00 100.000 1.000

Run Status : RunStatusOKEndOf fBaae i ine

Timed Events Time Events Logic Ualue EventUpdate1 .05 ResetBLAl lUal ley Event On -1.00 False2 .10 AutoSolvent EventOff -1.00 False

Pk* RT ID-tm PeakUidth Area Code AMOUNT Name1 1.32 *.56 .0858 850995BB 4.0525E+00 SOLVENT FRONT2 12.63 .1147«<-e>HC, 2445BB 23 14.58 .1136fe-BWc. 1_4101BB 3 .4 16.10 16.16 .1171S-B.VC. 17873BS 1.S760E-02 -5 16.93 .1343 Aldfin 19917BB 5 . 2447E-03a6 19.85 19.78 .1397 , 24533BB 2.2364E-02 ErrdOSUlfan7 20.48 20.75 .1422 C*j 24716BB 2.8272E-02 4-r4'8 21.49 .1247 <A|8nV 19780BB 5.2087E-03 OD 99 23.20 23.11 .1412 14442BB 1.52BOE-02 EHdujulFan II10 23.66 .1249 30816BB 8 . 1148E-03 DC) C)11 25.18 .1339 1565BB 4. 1215E-04-S?®- .112 25.66 25.96 .1387 38010BB 4.9617E-02 DVhntyl rh lepenrlatabncio-13 26.83 .1763 91262BB 2. 4032E-0214 29.33 .2019 52492BB 1.3S23E-0215 30.69 .6978 1515BB 3.9887E-04 '/


Report Time s Sun Jan 20, 1991 9:18:51 am "*"BCM LABORATORIES Report - GENIE Medium_Area Form

ftR3Q7l4G8

name : inuB? report NO : 09. uuCOLUMN SPB608 30t1 BY 0.53MM FUSED SILICA P«9» 2Method : XOATftXEXTRACTSXMETHODxMTHCLP_011991_8.MTH

000250

ftR307»*09

BCM LABORATORIES Report - GENIE Modium_Ar«a Form

Sample Name : INDB5 Report No : 89.00COLUMN SPB608 30M BY 0.53MM FUSED SILICA Page 3

SOLVENT

.581-AfcUrc- fc-

FRONT

10

mdate

:>6.830

000251

flR3Q7l.iO

TRILLIUM INC.

ATTACHMENT D

Corrected Standard:IND B, Series 1/22-24/91


Name: BCM Contract:

Lab Code: BCM Case No.: SAS No.: SDG No.: W586


<COMPOUND

alpha-BHCbeta-BHCdelta-BHCgamma-BHC (LiHep.tachlor __AldrinKept. EpoxideEndosulfan I_^LeldrinB4 ' -DDEIRdrinEndosulfan II4,4' -ODDEndo. sulfate4,4' -DDTMethoxychlor_Endrin ketonea. Chlordaneg. ChlordaneToxapheneAroclor-1016Aroclor-1221Aroclor-1232Aroclor-1242Aroclor-1248Aroclor-1254Aroclor-1260


RT

13.1615.1316.6414.8516.1617.5119.7821.1622.3722.0423.7924.4924.2026.2825.3629.5530.2421.0520.4124.6016.2613.0616.2516.2718.8820.6924.47

FWI*

FROM

13.0314.9816.4814.7016.0017.3419.5820.9522.1521.8223.5524.2423.9626.0225.1129.2529.9320.8420.2024.3516.1012.9316.0916.1118.6920.4824.23

i

IT.DOW

TO

13.3015.2816.8115.0016.3217.6919.9821.3722.6022.2624.0.324.7324.4426.5525.6229.8430.5421.2620.6124.8516.4213.1916.4116.4319.0720.9024.71

CALIBRATIONFACTOR

811200.629850.814250.771500.1043400.931000.1045700.1070700.946450.881200.626800.944200.689175.1176375.731825.441790.1249000.1118550.1109800.57516.288640.60546.135884.269352.183468.320990.287706.

DATE CTIME CEPA SA(STANE

RT

l6-b 1/?. /*f

1-7.1418.01£. \J . S .&

-1 55,

Xx. 55"34,33.

** A •— | 1— t-ZH • J -i.34. ? 1Hto<?3-S4.71-31.0031- 0$Si- 6<*ao. °\ &•

F ANALYSIS 1/24/91F ANALYSIS 16:05JMPLE NO.7iT?n\ TMPiTl

CALIBRATIONFACTOR

5°) 00 SO-$ 1 0 IffO'1100100.-010800.789650.1055700.1100300.•054400.-

3 f&jtlS'! f £of-J.

?*/30SZ>«/ //SU)? .7-43050.-3-26575..

1 16$ 3<fo*16 SS1 CTD.

^* -Vijcjjo " , ..\i.5°& \A-\

QNTY/N

YYYYYYYYYYYYYYYYYYYYY

i YYYYYY

%D

(s-1($*2>o.tj-

•Ci 3 . 0i* i^ i j15.2

3.040.£~^ r~—T3U . J

5". 5"

2 G . i30-?0 .9

—A3-

Under QNT Y/N: enter Y if quantitation was performed, N if not performed.%D must be less than or equal to 15.0% for" quantitation, and less thanor equal to 20.0% for confirmation.

Note: Determining that no compounds were found above the CRQL is a form ofantitation, and therefore at least one column must meet the 15.0% criteria

r multicomponent analytes, the largest single peak that is characteristicof the component should be used to establish retention tine and %D.Identification of such analytes is based primarily on pattern recognition.

page 3 of 3" ' • " -- FORM IX PEST

BCM i ftBQRftTORIES Report - GENIE Medium Area Form-J-K/D B

Sample Name i POP 6 0 eH=€fc—i 0 0 n ML 10ML CHER/OCC) Report No : 147. 00COLUMN DB608 3DM BY 0.53MM FUSED SILICA Page 1150C 1MIN 5C/MIN 275C 10MIN DET 350C INJ 250CALL CLP TCL COMPOUNDSINSTRUMENT TRACOR 540 1UL INJ.

Book/Page : E1016/27 GCU602KLH 1/23


Instrument : AUC_8 Application : Loop

Calculation : ExternalSTD Quantitat:on: AreaUnits

Result File : /DATA/EXTRACTS/RESULT/ I 0122219.RES

Run Time : 36.00 Minutes Injected on Thu Jan 24, 1991 4:05:25 pm

Sequence File: /DATA/EXTRACTS/SEQUENCE/SEQCLP_012391_8.SEQ


Threshold Min-Ar Pkwidth RF-_Unknown2.0 1.5000E+03 .100 2.6.J3E-U7

Ref Udw Abs Ref-RTU Non Ref Uin Abs Non Ref-RTU Ident Level0.00 1.00 0.00 1.00 1000.00

% Oil-Fact Smp-Amt Std-Amt H Purity Inj Oo1 Ratiol.OOOOE + 03 • O.OOOOE + 00 l.OOOOE+00 100.UUO 1.000

Run Status : RunStatusOK

Timed Events Time Events Logic Uaiue EventUpdate1 .05 ResetBLAllUalley EventUn -1.00 False2 .10 AutoSolvent EventOff -1.00 False

Pk# RT ID-tm PeakUidth Area Code AMUUNI Name1 1.50 #.56 .0947 543131BB 8..9001E + 00 SOLUENT FRUNT2 1.99 .0659 14856BB 3.9120E-023 2.21 .0396 11357BB 2.9906E-024 13.64 .1014 7556BB 1.9897E-025 15.61 .1122 11801BB 3.1075E-026 17.14 .1056 16216BB 4.2702E-027 18.01 .1261 15793BB 4.1588E-028 20.92 21.05 .1315 21114BB 1.8876E-01 aipha-Chlordane9 21.56 .1362 22166BB 5.8370E-U210 22.55 22.37 .1175 17088BB 1.8054E-01 Dieldrin11 24.32 24.20 .1252 14915BB 2.1642E-U1 4,4'-UDD12 24.71 24.49 .1241 29722BB 3.1479E-01 Endosulfan II13 26.87 .1516 44483BB 1.1714E-0114 28.11 .1822 90951BB 2.3950E-0115 31.08 .2445 65315BB 1.7200E-0116 32.38 1.0693 5815BB 1.5313E-02


Report Time : Thu Jan 24, 1991 4:42:20 pm OCQiftS3CM LABORATORIES *eoort - GENIE neaium_Area Form

Lu^wt ii. u/oouo .vuii 01 u . v.. i u i r LJOCOJ ox»_Ac.n , royeMethod : /DATAxEXTRACTS/METHOD/MTHCLP_012291_8.nTH

BCM LABORATORIES Report - GENIE Medium_Area FormZ7WO-? ______.

Sample Name : DUP 600TCL IDOOML-iailL: (HER/OCC) Report No : 147.00COLUMN DB608 30M BY 0.53MM FUSED SILICA Page 3

SOLVENT FRONT

_17.142_18.012

_20.921 alpha-Chlordane_21.558

_22.547 Dieldrin

Endosulfan II

_26.873

_31.084

TRILLIUM INC.

ATTACHMENT E

Chromatogram: INDB4, 2/6/91, 23:03GC Channel 9

SOI LABORATORIES Report - GENIE Medium_Area rorm

Sample Name : Report No :317.00COLUMN OB-1701 30H BY 0.53MM FUSED SILICA Page 2

_ 1.547 SOLUENF FRONT

_12.190 alpha-BHC

_1£.55>2 Aldrin_16.594 beta-HHU

_17.460 delta-BHL

Endrin

_22.793 4,4'-DUD

ibutyIch_1S ,'i/? tndrin ketone

HR307M7000308

\ TRILLIUIVLINC.

ATTACHMENT F

Method Blank Results


•t NoPage 2

(ocofc-r • s--- — ~~~~-Sample Name : 1006-1-.2. TCL608 30G-10MVJ1BLK S582 >COLUMN SPB608 30M BY 0.53MM FUSED SILICA•r

| SOLVENT

X

I'r* 5.377f

\L .... ... -• •y^ F1.

1t1

ft^F I

t11 . . . .\...

\\\P=- 25.193

t\

1

*1

| flRSO; - r - - —

Report No :Pa

FRONT.702

\ 1^O GLxW 1 S

63. : t

' . 118

snda t e

U 1 9 oooz

ID EPA SAMPLE NOPESTICIDE ORGANICS ANALYSIS DATA SHEET


Lab Code: BCM Case No.: 37933 SAS No.: SDG No.: S582B

Matrix: (soil/water) SOIL Lab Sample ID: 100067MB

Sample wt/vol: 30. (g/mL) G Lab File ID: 10117115

Level: (low/med) LOW Date Received: O/ O/ 0

% Moisture: not dec. 0. dec. 0. Date Extracted: 1/11/91

Extraction: (SepF/Cont/Sonc) SONG Date Analyzed: 1/18/91

GPC Cleanup: (Y/N) N pH: .0 Dilution Factor: 1.00

CONCENTRATION UNITS:CAS NO. COMPOUND (ug/L or ug/Kg) UG/KG Q

3 19-84-6 ——— alpha-BHC

319-86-8 ———— delta-BHC58-89-9 ———— gamma-BHC (Lindane)76-4 4-8 ———— Heptachlor309-00-2 ——— Aldrin1024-57-3 ——— Heptachlor epoxide959-98-8 ———— Endosulfan I60-57-1 ——— Dieldrin72-55-9 ———— 4 , 4 ' -DDE72-20-8 ——— Endrin

33213-65-9 ———— Endosulfan II72-54-8 ———— 4 , 4 ' -ODD

1031-07-8 ———— Endosulfan sulfate— t \J £. J ~J H f H LJU ±

72-43-5 ——— Methoxychlor53494-70-5 ———— Endrin ketone5103-71-9 ———— alpha-Chlordane5103-74-2 ———— gamma-Chlordane8001-35-2 ———— Toxaphene12674-11-2 ———— Aroclor-101611104-28-2 ———— Aroclor-122111141-16-5 ——— Aroclor-123253469-21-9 ———— Aroclor-124212672-29-6 ———— Aroclor-124811097-69-1 ———— Aroclor-125411096-82-5 ———— Aroclor-1260

. u

. u• u. u. u• \J

. u

. u16.16.16.16.16.16.16.80.16.80.80.160.80.on

O U .OU .Q no U •

160.160.

UUUUUUuuuuuuuuuuuuuuuuuuuuu

O002SO

FORM I PEST ,.,,--/ *20 1/8?

3T

ID . EPA SAMPLE NO.PESTICIDE ORGANICS ANALYSIS DATA SHEET _____ _____

Lab Name: BCM Contract:100617

Lab Code: BCM Case No.: 38191 SAS No.: SDG No.: S582A



Level; (low/med) LOW Date Received: 0 / 0 / 0





3 19-84-6 ———— alpha-BHC

319-86-8 ———— delta-BHC58-89-9 ——— gamma-BHC (Lindane)76-44-8 ——— Heptachlor

3 09-00-2 ———— Aldrin1024-57-3 ———— Heptachlor epoxide959-98-8 ———— Endosulfan I60-57-1 ——— -Dieldrin72-55-9-— — 4 , 4 ' -DDE7 2-20-8 ———— Endrin


103 1-07-8 ——— Endosulfan sulf ate50-29-3 ———— 4 , 4 ' -DDT72-43 -5 ——— Methoxychlor

53494-70-5 ———— Endrin ketone5103-71-9 ———— alpha-Chlordane5103-74-2 ———— gamma-Chlordane8001-35-2 ———— Toxaphene12674-11-2 ————— Aroclor-101611104-28-2 ———— Aroclor- 12 2111141-16-5 ———— Aroclor-123253469-21-9 ———— Aroclor-124212672-29-6 ———— Aroclor- 12 4 811097-69-1 ———— Aroclor-125411096-82-5 ———— Aroclor-1260

i ———— - ————————————————————————— - ———————————

. u

. u8.0• U• u• u* u• u

16.16.

• 16.16.16.16.16.80.16.a n80.160.

Q n80.80.Q n160.160.

UUUUUUUUUUUUUuuuuuuuuuuuuuu

AR307U2IFORM I PEST 000"™ "? 1/87 Tlev.


No : 21.01Paqe ^

. FRONT1.702

Dibutvichlorfcndate

llS

,O/~>O" ~-r>

ID EPA SAMPLE NO.PESTICIDE ORGANICS ANALYSIS DATA SHEET

rab Name: BCM Contract:101073

Lab Code: BCM Case No.: 38298 SAS No.: SDG No.: S592


Sample wt/vol: 30. (g/mL) G Lab File ID:j)(oi25H8

Level: (low/med) LOW Date Received: O/ o/ 0

% Moisture: not dec. 0. dec. 0. Date Extracted: -i/13/91-| |r?n (

Extraction: (SepF/Cont/Sonc) -S-epf-5cM/£ Date Analyzed: 1/26/91PQKAiiiht



319-84-6 ———— alpha-BHC

58-89-9 ———— gamma-BHC (Lindane)76-44-8 ———— Heptachlor209-00-2 ———— Aldrin1024-57-3 ———— Heptachlor epoxide

60-57-1 ———— Dieldrin72-55-9 ———— 4 , 4 ' -DDE72-20-8 ———— Endrin

33213-65-9 ———— Endosulfan II72-54-8 ————— 4 , 4 ' -ODD

1031-07-8 ———— Endosulfan sulfate50-29-3 ———— 4 , 4 ' -DDT72-43-5 ———— Methoxychlor

~ 3 ''.04 -7 0-5 ———— Endrin ketone.103-71-9 ———— alpha-Chlordane-.103-74-2 ———— gamma -Chlordane"001-35-2 ———— ToxapheneP. 07 4 -11-2 ———— Aroclor- 10 161104-28-2 ———— Aroclor- 12 21ll-l 1-16-5 ———— Aroclor-1222,3 -.6 9-2 1-9 ———— Aroclor- 12 4 22 C7 2 -2 9-6 ——— -Aroclor- 12 4 8

1 1007-69-1 ———— Aroclor-125411096-82-5 ———— Aroclor- 12 60

8.08.08.08.08.08.08.08.0-16.16.16.16.16.16.16.80.16.80.80.160.80.80.80.80.80.160.160.

i

UUuuuuuuuuuuuuuuuuuuuuuuuuu

AR307U23FORM I PEST _ 00

HUM LWbUWftlLIWItS Hfeport - yhNlh Mad J um__«rea Horm

Sample N«m« : IIJIU/JMH 6UUILL ^uy-lUML b^VVi Keport No :16H.U1l.-MI.UMN UH6UO >UM «Y U.^nn 1-USh.U biLlLA . Page '2

m \• i

SULUtNl HWUNI

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=- 6.

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BEH

ii

_ •> *>. u » u

iIiiiiii

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6UH.UI. ,.IU-lUni- ^ No :V2 / . 01uH-i/ui jun WY LI.^^HM HubbU SILIUA

ML'.HLUrVU-m-XYLb.Nb

i r l u . A* 1 1 I T . /j : ~ O O-A. d~ iff

\

I i\ ii \i ? liS.^fS* t-i»T^ — HMIj

N.

ID EPA SAMPLE NO.PESTICIDE ORGANICS ANALYSIS DATA SHEET _____________


Lab Code: BCM Case No.: 3829> SAS No.: SDG No.: S614A3«2.t* <M

Matrix: (soil/water) SOIL ***** Lab Sample ID: 102145MB

Sample wt/vol: 30. (g/mL) G Lab File ID: J0129202





CONCENTRATION UNITS:GAS NO. COMPOUND (ug/L or ug/Kg) UG/KG Q

319-85-7 ———— beta-BHC

58-89-9 ———— gamma-BHC (Lindane)76-44-8 ———— Heptachlor309-00-2 ——— Aldrin1024-57-3 ———— Heptachlor epoxide959-98-8 ———— Endosulfan I60-57-1 ——— Dieldrin72-55-9 ———— 4 , 4 ' -DDE72-20-8 ———— Endrin


1031-07-8 ———— Endosulfan sulfate50-29-3 ———— 4 , 4 ' -DDT7 2-43-5 ——— Methoxychlor

53494-70-5 ———— Endrin' ketone5103-71-9 ———— alpha-Chlordane5103-74-2 ———— garama-Chlordane8001-35-2 ———— Toxaphene12674-11-2 ———— Aroclor-101611104-28-2 ———— Aroclor-122111141-16-5 ———— Aroclor-123253469-21-9 ———— Aroclor-124212672-29-6 ———— Aroclor-124811097-69-1 ———— Aroclor-125411096-82-5 ———— Aroclor-1260

8.08.08.08.08.08.08.08.016.16.16.16.16.16.16.80.16.80.80.160.80.80.80.80.80.

160.160.

UUUUUUuuuuu .uuuuuuuuuuuuuuuu

FORM I PEST 1/87 Rev

HUM LAHUWAI Uh» 1 tb Kftport - l^tNlh Medium_«rea rorm

: 'llJV-lA'ynU 6Ub *IJI»-1UML S61<4 UU Weport No : V.'2.l.iLILUMN DB-1/111 .5UM BY U.f^nn HUbtU blULR Hage '2

\{

i

I X——==^======—————_ tt.SV/. 2. . A ..-» . b- I b. I kttLHLUKU-m-XYLt...Nfc.I .• '

i ijjjii

'16.6111

000468

oun UHBUKHI UKie.3 rteporc - ta&rt.c. neaiuot^i-iroa rarm

Sampie Nama : 102145MB 608 306-10MV S614") CU Report No :268.00COLUMN DB608 30M BY 0.53MM FUSED .SILICR——^ Page 3

T7>65 SOLVENT ER' ss **

_ 4.311

-!•iff52

_11.403

_16.143 gamma-BHC (Lindane)

_17.505 Heptachlor

_18.880 Aldrin

_23.751 Dieldrin

J25.192 Endrin

__26.812 4,4'-DOT1 Fan sulfate

^ ^gyTTUB UibutyIchlorendate

00047 3 07U 28

ID EPA SAMPLE NO.PESTICIDE ORGANICS ANALYSIS DATA SHEET __

Name: BCM Contract:/02679

Lab Code: BCM Case No. :_ 38542 SAS No.: SDG No.: S614



Level: (low/med) LOW Date Received: C/ o/ 0


Extraction: (SepF/Cont/Sonc) SONG Date Analyzed: 2/ 5/91



319-84-6————alpha-BHC319-85-7————beta-BHC319-86-8————delta-BHC58-89-9————gamma-BHC (Lindane)76-44-8————Heptachlor309-00-2————Aldrin1024-57-3————Heptachlor epoxide959-98-8————Endosulfan I60-57-1———Dieldrin72-55-9————4 , 4 ' -DDE72-20-8————Endrin

33213-65-9————Endosulfan II72-54-8 ———— 4f4'-DDD

1031-07-8————Endosulfan sulfate50-29-3 ————4 , 4 ' -DDT72-43-5———Methoxychlor

53494-70-5————Endrin ketone5103-71-9————alpha-Chlordane5103-74-2————gamma-Chlordane8001-35-2————Toxaphene12674-11-2————Aroclor-101611104-28-2————Aroclor-122111141-16-5————Aroclor-123 253469-21-9————Aroclor-124212672-29-6————Aroclor-12 4 811097-69-1————Aroclor-12 5 411096-82-5————Aroclor-1260

8.08.08.08.08.08.08.08.016.16.16.16.16.IS.16.80.16.80.80.

160.80.80.30.80.80.

160.160.

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FORM I PEST i87 Rev.00032O

HUH l_«HUK« I UK 1 t-a Keport - Ufc-N t h. Hed l um_«r ea harm

6UBIUL .*ULi-lUML LaL-bbi* Keport No :_>1/.U1'JULUMN UH6UH ^IJH UY IJ.'y^MM hUbtU blLlL« Hage 2aii•tiiiiii

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bULUtNl KKU

lA.b .o-1 h. IWftLHLLIKU-.n-XYLh.Nb.

00324


Lab Name: BCM Contract:MBLANK

Lab Code: BCM Case No.: 37933 SAS No.: SDG No.: W575B

Matrix: (soil/water) WATER Lab Sample ID: MBLANK

Sample wt/vol: 1000. (g/mL)ML Lab File ID: J0109205


% Moisture: not dec. 100. dec. 0. Date Extracted: -M/27/DO //?//// ' StoW-

Extraction: (SepF/Cont/Sonc) SEPF Date Analyzed: 1/11/91

3PC Cleanup: (Y/N) N pH: .0 Dilution Factor: 1.00

CONCENTRATION UNITS:GAS NO. COMPOUND (ug/L or ug/Kg) UG/L Q

319-84-6 ———— alpha-BHC3 19-85-7 ———— beta-BHC

58-89-9 ———— gamma-BHC (Lindane)76-44-8 ———— Heptachlor

3 09-00-2 ———— Aldrin1024-57-3 ———— Heptachlor epoxide959-98-8 ———— Endosulfan I60-57-1 ———— Dieldrin/ £• ••/ «/ -/ -I f -I ULJl*t

72-20-8 ———— Endrin33213-65-9 ——— Endosulfan II

72-54-8 ———— 4 , 4 ' -ODD1031-07-8 ———— Endosulfan sulfate

v ^ V S A . ^ w ' tf** LJ1-/JL

72-43-5 ———— Methoxychlor53494-70-5 ———— Endrin ketone5103-71-9 ———— alpha-Chlordane5103-74-2 ———— gamma-Chlordane8001-35-2 ———— Toxaphene12674-11-2 ———— Aroclor-101611104-28-2 ———— Aroclor-122111141-16-5 ———— Aroclor-123253469-21-9 ———— Aroclor-124212672-29-6 ———— Aroclor-124811097-69-1 ———— Aroclor-125411096-82-5 ———— Aroclor-1260

.050

.050

.050

.050

.050

.050

.050

.050

.100

.100

.100

.100

.100

.100

.100.50.100.50.501.0.50.50.50.50.501.01.0

UUuuuuuuuuuuuuuuuuuuuuuuuuu

000253

FORM I PEST AR3G7^32 1/87 Rev-

BCM LABORATORIES Report - GENIE Medium_Area t-orm

Sample Name : MBLK 608PS 1000ML-1UML HsAfeU. Sb Report No sloSCOLUMN DB-1701. 30M BY 0.53MM FUSED SILlLft Haqe—————————— _ ———— _ ———————— _ —————————— j

.420

SULOfc-N T

rf" 3.395.

.f.f 2 ,4,5 ,6-TETRACHLORU-m-XYLENEfL ______________ ""'r..f' 1U.082

.if- 13.VUJ-

.I .Irif- 17.491\

...<\\\

. \ 4, 4 '-DDT^ 23.677\

25.107_ 7 c; _ c; — .— - • • • •

26.52-2) 27.169r 27.801

Dibu t v Ich lore

AR307^33

FRUN I

da t e

OD025S


Sample Name : MBLK 608PS 1000ML-10ML £ni^\n S -S" Report No : 162COLUMN SPB608 30M BY 0.53MM FUSED SILICA Paq

SOLVENT | FRONT

-ODDndosu1.an II

Endosulran sulfate

trrtrd t vi chlortndate

.

?...j\

ID EPA SAMPLE NO.PESTICIDE ORGANICS ANALYSIS DATA SHEET ___

Name: BCM • Contract:MBLANK



Sample wt/vol: 1000. (g/mL)ML Lab File ID: 10122115

Level: (low/med) LOW Date Received: O/ 0/0

% Moisture: not dec.100. dec. 0. Date Extracted: 1/14/91


GPC Cleanup: (Y/N) N pH: .0 - Dilution Factor: i.oo

CONCENTRATION UNITS:CAS NO. COMPOUND (ug/L or ug/Kg) UG/L Q

*}T f\ _Q A _ f. -„ — . T wiV. — . TTITT^

319-85-7 ———— beta-BHC319-86-8 ———— delta-BHC58-89-9 ——— gamma-BHC (Lindane)76-44-8 ———— Heptachlor309-00-2. ——— Aldrin1024-57-3 ———— Heptachlor epoxide959-98-8 ———— Endosulfan I60-57-1 ———— Dieldrin/ . *J W -/ *T f *T UU±1

72-20-8 ———— Endrin33213-65-9 ———— Endosulfan II

72-54-8 ———— 4 , 4 ' -ODD1031-07-8 ———— Endosulfan sulfate50-29-3 ———— 4 , 4 ' -DDT72-43-5 ——— Methoxychlor

53494-70-5 ——— Endrin ketone5103-71-9 ———— alpha-Chlordane5103-74-2 ———— gamma-Chlordane8001-35-2 ———— Toxaphene12674-11-2 ———— Aroclor-101611104-28-2 ———— Aroclor-122111141-16-5 ———— Aroclor-123253469-21-9 ———— Aroclor-124212672-29-6 ———— Aroclor-124811097-69-1 ———— Aroclor-125411096-82-5 ———— Aroclor-1260

.050

.050

.050

.050

.050

.050

.050

.050

.100

.100

.100' .100.100.100.100.50.100.50.501.0.50.50.50.50en. ..J w

1.01.0

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nr>0™ flR307i*35FORM I PEST UUUjLtui 1/87 Rev.

HUM LHHLIKtt 11JK l tb Keport - LJtNlfc. Medium_Area rorm

Sampl*. N»me : MHLK 6UH lUUUML-lUMl^JJ5B6i^) Keport NoULILUMN bHH6U8 ^UM HY U.'J.JMM l-UbfcU LTCET"''' _______ Page '2

I 5 .-.....— • —— -———• - -• -- —— ————————————————————————- i

i ) ii i______________________;__________ ii • _____ _______i bULUtNl j FKIJN1j ' • •._.__———————————— j

i /-J==r vf:9/' 6 ii f - i O CL -> S - 3

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K n d n » u 1 f a n s u 1 f a t e II

======——— Uibut v I ch I orentia te

i ii i

0001S5


Name: BCM _ Contract:MBLANK

Lab Code: BCM Case No.: fyffl SAS No-: SDG No-: W602




% Moisture: not dec.100. dec. 0. Date Extracted: -1/23/01 //23/9/




319-84-6 ———— alpha-BHC319-85-7 ———— beta-BHCTTQ Q £ Q ^«T4--i QU.O

58-89-9 ———— gamma-BHC (Lindane)76-44-8 ——— Heptachlor

3 09-00-2 ——— Aldrin1024-57-3 ———— Heptachlor epoxide959-98-8 ——— Endosulfan I60-57-1 ———— Dieldrin/ f. ~J mj J *T f T LJLS^j

72-20-8 ———— Endrin33213-65-9 ———— Endosulfan II

/ -C. W "T U ** f "» WJU/.L/

1031-07-8 ———— Endosulfan sulfate~J \J £. J ^ -I f T WL./..I.

72-43-5 ——— Methoxychlor53494-70-5 ———— Endrin ketone5103-71-9 ——— alpha-Chlordane5103-74-2 ———— gamma-Chlordane8001-35-2 ———— Toxaphene .12674-11-2 ———— Aroclor-101611104-28-2 ———— Aroclor- 12 2111141-16-5 ———— Aroclor-123253469-21-9 ———— Aroclor-124212672-29-6 ———— Aroclor-124811097-69-1 ———— Aroclor-125411096-82-5 ———— Aroclor-1260

.050

.050

.050

.050

.050

.050

.050

.050

.100

.100

.100

.100

. 100

.100

.100.50.100.50.501.0.50.50• ~j \j.50.501.01.0

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00046FORM I PEST fosjm


Sample Name : MBLK 608TCL 1000ML-10ML (HER/OCC) Report No :183.00COLUMN DB608 30M BY 0.53MM FUSED SILICA Page 2

r— S. 17R

_18.315 Atdrin

_32.20b

_ 2.651

' ,J

,4/.>,i!j- ILlkACHLURO-m-XYLh.NE

butylch lorendate

0004G3

HL:M LttHUKftlUKltS Keport - LitN 11 Medium_«rea rorm

: MHLK 6UH.LL 1UUUML-1UML CHtK/ULL. Heport No :14..UUr.HLLIMN Ub-l/Ul ^UM UY U . -OMM F-UbhU a 1 LI LA __ ______ _ .

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000465

ID EPA SAMPLE NO.PESTICIDE ORGANICS ANALYSIS DATA SHEET ________


Lab Code: BCM Case No.: SAS No.: SDG No.: W617B




% Moisture: not dec.100. dec. 0. Date Extracted: 1/30/91 , ///?nf

Extraction: (SepF/Cont/Sonc) SEPF Date Analyzed: 2/ 1/91



319-84-6 ———— alpha-BHC3 19-8 5-7 ———— beta-BHC

58-89-9 ———— gamma-BHC (Lindane)76-44-8 ———— Heptachlor3 09-00-2 ——— Aldrin1024-57-3 ———— Heptachlor epoxide959-98-8 ———— Endosulfan I60-57-1 —— "—Dieldrin/ £. ~i -J 3 H f *t ULJC**? *> *. f\ O T"*l-»«_ T fl -1 M

33213-65-9 ——— Endosulfan II72-54-8 ———— 4 , 4 ' -ODD

1031-07-8 ———— Endosulfan sulfate^ \J f. ^ *T 7 *T LJLJ .L

7 2-43-5 ———— Methoxychlor53494-70-5 ———— Endrin ketone5103-71-9 ———— alpha-Chlordane5103-74-2 ———— gamma-Chlordane8001-35-2 ———— Toxaphene12674-11-2 ——— Aroclor-101611104-28-2 ———— Aroclor-122111141-16-5 ———— Aroclor-123253469-21-9 ———— Aroclor-124212672-29-6 ———— Aroclor-124811097-69-1 ———— Aroclor-125411096-82-5 ———— Aroclor-1260

.050

.050

.050

.050

.050

.050

.050

.050

.100

.100

.100

.100

.100

.ioo

.100.50

. .100.50.501.0.50.50.50.50Kn. *j \j1.01.0

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AR3071.1.0FORM I PEST 000471 1/87 Rev-

BL41 I_HBUKH I UK i c.9 Report - ucutic. rieaium_nraa ruriu

Sample Name : MBLK 608 lOOOML-lOML. W617RST Report. No :278.00COLUMN OB60B 30t1 BY 0.53MM FUSED .SILICA Page 2

21 SOLVENT FRONT_ 2.800

16.d80

_18.642 Aldrin

_20.601

_27.45,7_Endcin Aldehyde— _27.92t> EndosuIFan sulfate===M**~~ 7? .132 Dibuty 1 ch lo renda t e

000473

HUM LAHLIKttl UK 1 tb Kepor_t - UtN 11 Medium_«rea Form

I*. N*rrm : MHLK MIH .1 imuni.,- 1IJMI.. /W6'!L7K±i \^) Keport No : V .> / . U ULIULUHN l.H-i/'Ul 3 MM HY U.^MM F UbtU b 1 L 1 LA~~ — ' — —— — - Hage 2

j ____ ._. ______ ———————————————— — _ 1 . faV 1 SULUtNl FKIINIi . *~-~ ~- _•;

_ •>• i|w"1DO:

661.A.1? .o- I t IKALHLUKLI-m-XYL.tNt

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OG0475flR307H2

ID EPA SAMPLE NO.PESTICIDE ORGANICS ANALYSIS DATA SHEET _____

b Name: BCM Contract:MBLANK

Lab Code: BCM Case No.: 3<£SVc2_ SAS No. : SDG No.: W610



Level: (low/med) . LOW . Date Receivedf O/ O/ 0





319-84-6319-85-7319-86-858-89-976-44-8309-00-21024-57-3959-98-860-57-172-55-972-20-8

33213-65-972-54-8

1031-07-850-29-372-43-5

53494-70-55103-71-95103-74-28001-35-212674-11-211104-28-211141-16-553469-21-912672-29-611097-69-111096-82-5

^ . »^w nu/™1

———— gamma-BHC (Lindane)———— Heptachlor———— Aldrin———— Heptachlor epoxide——— Endosulfan I——— Dieldrin

*T / LJLJl*

———— Endosulfan II———— 4,4/-DDD———— Endosulfan sulfate

** f ** LJU ±

———— Methoxychlor——— Endrin ketone———— alpha-Chlordane———— gamma-Chlordane———— Toxaphene———— Aroclor- 10 16———— Aroclor- 12 21———— Aroclor- 12 3 2———— Aroclor-1242——— Aroclor- 124 8———— Aroclor- 12 5 4——— Aroclor-12 60

.050

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.050

.050

.050

.050

.050

.050

. 100

. 100

. 100

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.100.50

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FORM I PEST

BCn LABORATORIES Report - GENIE Mediun»_Ar«a-Form

Sample NBMV : MBLK 608 1000ML-10ML U610 Report No :260;.00"COLUHN DB608 30H BY 0.53W1 FUSED SILICft ____ Page- 2

SOLVENT FRONT_. 2.899

. 3O

is.-40

_17.088

_11.525

_20.800 Heptachlor epoxide

22.628 Endosulfan aulfate

lorendate

14.26 .1416 '2/fc.H 6.2U6Ht-U->16._>y 16.66 . 181V ^ 66UH 1 . XAAVt-U-iV.6.16 *V6,,.21 . iV^y liyHUUHH y.^W-ih-Ul Uibuty ten lorendate

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314

TRILLJUM INC.

ATTACHMENT G

Data Summary Forms

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Attachment H

HR3071.50


Name: BCM Contract:/00608 RE


Matrix: (soil/water) SOIL Lab Sample ID: 100608


Level: (low/med) LOW Date Received: I/ 9/91

% Moisture: not dec. 52. dec. 0. Date Extracted: l/11/91




319-84-6————alpha-BHC319-85-7————beta-BHC319-86-8————delta-BHC58-89-9———gamma-BHC (Lindane)76-44-8———Heptachlor309-00-2———Aldrin1024-57-3————Heptachlor epoxide959-98-8————Endosulfan I60-57-1————Dieldrin72-55-9————4 , 4 ' -DDE72-20-8————Endrin

33213-65-9————Endosulfan II72-54-8————4 , 4 ' -ODD

1031-07-8————Endosulfan sulfate50-29-3————4 , 4 ' -DDT72-43-5————Methoxychlor

53494-70-5————Endrin Jcetone5103-71-9————alpha-Chlordane5103-74-2————gamma-Chlordane8001-35-2————Toxaphene12674-11-2————Aroclor-101611104-28-2————Aroclor-122111141-16-5————Aroclor-123253469-21-9————Aroclor-124212672-29-6————Aroclor-124811097-69-1————Aroclor-125411096-82-5————Aroclor-1260

50.50.50.50.50.50.50.50.100.100.100.100.100.100.100.500.100.500.500.1000.500.500.500.500.500.1000.1000.


FORM i PEST f-rtrinn-? 1/87 Rev


Name: BCM Contract:100616

Lab Code: BCM Case No.: 38191 SAS No.: SDG No.: W586








319-84-6————alpha-BHC319-85-7————beta-BHC319-86-8————delta-BHC58-89-9————gamma-BHC (Lindane)76-44-8————Heptachlor309-00-2————Aldrin1024-57-3————Heptachlor epoxide959-98-8————Endosulfan I60-57-1————Dieldrin72-55-9 ———— 4 , 4 ' -DDE72-20-8————Endrin


1031-07-8————Endosulfan sulfate50-29-3————4 , 4 ' -DDT72-43-5————Methoxychlor

53494-70-5————Endrin ketone5103-71-9————alpha-Chlordane5103-74-2————gamma-Chlordane8001-35-2————Toxaphene12674-11-2————Aroclor-101611104-28-2————Aroclor-122111141-16-5————Aroclor-123253469-21-9-———Aroclor-124212672-29-6————Aroclor-124811097-69-1————Aroclor-125411096-82-5————Aroclor-1260

.058

.058

.058

.058

.058

.058

.058

.058.12. 12.12. 12.12.12.12.58.12.58.581.2.58.58.58. 58.581.21.2

UUUUUUUUUUUUUUUUUUUUUUUUuuu

FORM I PEST



Lab Code: BCM Case No.: 38191 SAS No.: SDG No.: S582A

Matrix: (soil/water) SOIL ' Lab Sample ID: 100617MB


Level: (low/med) LOW Date Received: O/ 0/0





T 1 Q — P A— fi_ __

319-85-7 ——

76-44-8 ——

1024-57-3 ——

60-57-1 — -72-55-9 ——

33213-65-9 ——72-54-8 — -

1031-07-8 — -FT r\ o o *^

• — alpha-BHC• — beta-BHC

d G _L U cl D Jtl L*• — gamma-BHC (Lindane)- — Heptachlor—— Aldrin—— Heptachlor epoxide—— Endosulfan I—— Dieldrin—— 4 A i —nnp-Iff LJUU

—— Endrin—— Endosulfan II—— 4, 4 '-ODD—— Endosulfan sulfate

A At T\T\m

72-43-5 ———— MethoxychlorFTI/^O *7 1 ™ ("I ..

Ui.lU.jL. Ail JVC L.U11C:

—— alpha-Chlordane

8001-35-2 ———— ToxapheneXZD/*r JLi £.

11141-16-5 — •^3469 21-9 —— -f ~J *•* Nj —S 4- J- — /

1 O £ *7 O O Q_i.r

11097-69-1 — •11096-82-5 — •

t\i- UOXUX. XUXU

—— Aroclor-1221—— Aroclor- 12 3 2—— Aroclor- 12 4 2—— Aroclor-1248—— Aroclor-1254—— Aroclor-1260

8.08.08.08.08.08. 08.08.016.16.16.16.16.16.16.80.16.80.80.160.80.80.80.80.80.160.160.

UUUUUUUUUUUUUUUUUuuuuuuuuuu

9009FORM I PEST --•»«


Name: BCM Contract:100768 RE


Matrix: (soil/water) SOIL Lab Sample ID: 100768


Level: (low/med) LOW " " Date Received: 1/10/91




CONCENTRATION UNITS:GAS NO. COMPOUND (ug/L or Ug/Kg) UG/KG Q

319-84-6————alpha-BHC319-85-7————beta-BHC319-86-8————delta-BHC58-89-9————gamma-BHC (Lindane)76-44-8————Heptachlor309-00-2————Aldrin1024-57-3————Heptachlor epoxide959-98-8————Endosulfan I60-57-1————Dieldrin72-55-9 ————— 4 , 4 ' -DDE72-20-8————Endrin


.1031-07-8————Endosulfan sulfate50-29-3 ———— 4 , 4 ' -DDT72-43-5————Methoxychlor

53494-70-5————Endrin ketone5103-71-9————alpha-Chlordane5103-74-2————gamma-Chlordane8001-35-2————Toxaphene12674-11-2—————Aroclor-101611104-28-2————Aroclor-122111141-16-5————Aroclor-123253469-21-9————ArocIbr-124212672-29-6————Aroclor-124811097-69-1————Aroclor-125411096-82-5————Aroclor-1260

46.46.46.46.46.46.46.46.92.92.92.92.92.92.92.460.92.

460.460.920.460.460.460.460.460.740.920.

UUUUUUUUUuuuuuuuuuuuuuuuuJu

FORM I PEST 000010 fifj JO H'S 1+











319-84-6 ——"31 Q_QR_'7._.__

C.QWQQ_Q___

309-00-2 — -1024-57-3 — -

60-57-1 — -7.5-55-9 ——* £. *j *j **T) ~ On — Q— — .

33213-65-9 — •72-54-8 — -

1031-07-8 — •50-29-3 — •79—4.3 — 15 —— .i fj ~r ™/ — '

53494-70-5 — •5103-71-9 — •51 03-74-7 — •<uf .1. \J -*J f £-

8001-35-2 — •12674-11-2 — •11104-28-2 —11141-16-5 —5346Q— ? 1 — Q ——•~s -s ~z \j -* £—,-»* ~J

12672-29-6 —11097-69-1 —11096-82-5 —

- — alpha-BHC• — beta-BHC- — delta-BHC—— gamma-BHC (Lindane)—— Heptachlor—— Aldrin—— Heptachlor epoxide—— Endosulfan I—— Dieldrin__ 4 4 / — nnp-* f *± iJLJi-j

—— Endrin—— Endosulfan II—— 4 4. i nnn*T • ** LJ LJ LJ

—— Endosulfan sulfate•T f *t _L_/_L^ J.

—— Methoxychlor—— Endrin ketone—— alpha-Chlordane—— gamma-Chlordane.._. vj-?tci£jiifc-ijris—— Aroclor-1016—— Aroclor-1221—— Aroclor-1232—— Aroclor- 12 4 2—— Aroclor-1248

J i. V.'V .J-lM'.UJ. .' T

— -Aroclor-1260

.050

.050

.050

.050

.050

.050

.050

.050

.100

.100

.100

.100

.100

.100

.100.50

.100.50.501.0.50.50.50.50.501.01.0 '

UUUUUUUUuuuuuuuuuuuuuuuuuuu

FORM I PEST 000011

Attachment I

AR3G7t_56

BCtl Laboratory Analytical Data Package

Laboratory Division10 Gravers Road

Norristoun, Pfl 19101 | .I

Lab. Cert, ft •• HJ 77175 |: Pfl 16-007 I

iI

III

LOCUTION SIMPLE ID BCH No. LOCftTION SftHPLE

•sOXY-SU-1-SED 100608

RINSE ELflNKDUP 100608 100618 SPIKE 100608

OXV-SU-10-SEB 100768 RINSE ELftNK

This case includes the following packages:

GC/flS UolatilesGC/NS Seni-Uolatiles

Itetalstticro

UetChenGC

This is the package for this case.

Data Packaae audited bv Iff'. '"/2% -wC*" tfi<t

Data Package

Client: OCCIDENTAL CHEIHCflL

Project No.: 00-1061-13

Project tlanager:

Order: 38191

ID ECU No. LOCATION SIMPLE ID ECtl No.

100616 METHOD BLANK 100617100619

100770

BCn Subcontractor

[V/ [ ][vT C ][v/ [ 1[ ], MI1// C 1

'4 Date £/}/

000001

BCM

Section 3

Surrogate Recovery Form

000012 JSR3Q7.58

2EWATER PESTICIDE SURROGATE RECOVERY

(Name: BCM Contract:


1234567891011121314151617181920212223242526272.82930

EPASAMPLE NO.

MBLKSPKDUPMSPIKE100616100770

SI(DBC)#

495453545755

OTHER

ADVISORYQC LIMITS

SI (DBC) = Dibutylchlorendate (24-154)

# Column to be used to flag recovery values

* Values outside of contract required QC limits

D Surrogates diluted out

page 1 of 1M II PEST-I ft ROT 7*59

2FSOIL PESTICIDE SURROGATE RECOVERY



Level:(low/med) LOW

12

* 3»456789101112131415161718192021222324252627282930

EPASAMPLE NO.

100617/00608 RE/00608MS REf00608MSDRE100768 RE

SI(DBC)#

7870979578

OTHER

ADVISORYQC LIMITS

si (DBC) = Dibutylchlorendate (24-150)

# Column to be used to flag recovery values

* Values outside of contract required QC limits

D Surrogates diluted out

page 1 of l - ' OOOQ14,000.4

BCM

Section 4

Matrix Spike/Spike Duplicate Form

000015ftR307U6l

WATER PESTICIDE MATRIX SPIKE/MATRIX" SPIKE" DUPLICATE RECOVER!

Lab Name; 13oM ____' Contract: ______

Lab Code: ______ Case No.: _____ SAS No.: _____ SDG No.:

Matrix Spike ,- EPA Sample No.: DX (L/ATErR

COMPOUND

gamma— BHC ( Lindane )HeptachlorAldrinDieldrinEndrin4,4' -DDT

SPIKEADDED(ug/L)0-3L0.3L0-^k

o-f5r>.<=(o -S

1|CC11i11111

SAMPLE |>NCENTRATIONI(ug/L)0-Q0-00.0o.oo..-oft.o

MSCONCENTRATI

(ug/L). to. L4?i89 15,*fl-33-

1ON|

1—— 1-

111111|

MS. | QC.%-• \WOTS

SEC- *| REC.

50 -|56-123&0 140-131lO \ 40-120ab (52-126& \ 56-121bM- 138-127

I

COMPOUND

gamma-BHC (Lindane)HeptachlorAldrinDieldrinEndrin4,4' -DDT

SPIKEADDED(ug/L)0- 20.3k

MSDCONCENTRATION

(ug/L).CQ6• IS

ft.JJ- . /?o -.5 .Ifc-.S .3:7'O. t5 .30

MSD |%REC #

1% | QC LIMITSRPD «| RPD | REC.

H8>)4H 4 ! IS 1 56-123^«528J*-7-(CC-'

1 1

ft I 20 140-13.1& 1 22, 140-120^r j 18 J52-126$ \ 21 156-121S 1 27 138-127

1 1

# Column to be used to flag recovery and RPD values with an asterisk

* Values outside of QC limits

RPD; O out of 6 outside limitsSpike Recovery; If ou't of f . outside limits

COMMENTS:

eooois RR307U62

3FSOIL PESTICIDE MATRIX SPIKE/MATRIX SPIKE DUPLICATE RECOVERY

Name: BCM Contract:


Matrix Spike - EPA Sample No.: 100608 Level:(low/med) LOW

00

COMPOUND


SPIKEADDED(UG/KG)

41.6741.6741.67104.17104.17104.17

SAMPLECONCENTRATION

(UG/KG)

16.11.00

11.23.00.00

9.47

MSCONCENTRATION

(UG/KG)

61.5536.1653.37108.89104.49162.39

MS%

REC #

10987101105100147 *

QCLIMITSREC.

46-12735-13034-13231-13442-13923-134

COMPOUND


SPIKEADDED(UG/KG)

41.6741.6741.67104.17104.17104.17

MSDCONCENTRATION

(UG/KG)

55.2434.8657.5787.3585.31144.81

MSD%

REC #

94841118482130

%RPD #

1549

222012

QC L]RPD

503143384550

CMITSREC.

46-12735-13034-13231-13442-13923-134

# Column to be used to flag recovery and RPD values with an asterisk

* Values outside of QC limits

RPD: 0 out of 6 outside limitsSpike Recovery: 1 out of 12 outside limits

COMMENTS:

FORM III PEST-2 1/87 Rev.

000017 AR307U63

BCM

Section 5

Method Blanks

000018

4CPESTICIDE METHOD BLANK SUMMARY

: BCM Contract:

BCM Case No.: SAS No.: SDG No.: W586

Lab Sample ID: MBLANK Lab File ID: 10122115

Matrix: (soil/water) WATER Level: (low/med) LOW

Date Extracted: 1/14/91 Extraction: (SepF/Cont/Sonc) SEPF

Date Analyzed (1): 1/23/91 Date Analyzed (2):/<f23/91

Time Analyzed (1) : 0:01 Time Analyze£x<2): 2:10

Instrument ID (1): 0008 Instrujnefit ID (2): 0009

GC Column ID (1) : CAP pe'Column ID (2) : CAP

THIS METHOD BLANK APPLIES TO THE FOLLOWING SAMPLES, MS AND MSD:

1234567B91011121314151617181920212223242526

EPASAMPLE NO.

SPKDUPMSPIKE100616100770

LABSAMPLE ID

SPKDUPMSPIKE100616100770

DATEANALYZED 1

1/23/911/23/911/23/911/23/911/23/91

DATEANALYZED 2

1/23/9/1/23//11/237911A/3/913-723/91

1

Comments:

page 1 of 1FORM IV PEST 000019 1/87 Rev-

BR307U65











3T Q O A £.

31 Q __Q £T _Q _

76-44-8 ——309-00-2 ——1024-57-3 ——

60-57-1 ——1 C-> *J *J — /

"7*5 Or- — Q-._-

T T *> 1 O /r F* *"*

1031-07-8 — -rr n *"> o *

• — alpha-BHC• — beta-BHC• — delta-BHC• — gamma-BHC (Lindane)• — Heptachlor• — Aldrin• — Heptachlor epoxide• — Endosulfan I- — Dieldrin

•T f ".C W-Urj^

—— Endrin—— Endosulfan II—— A. A ' — nnn*T , "X UULJ

—— Endosulfan sulfateA At TM"MT1

72-43-5 ——— Methoxychlor53494-70-5 ——— Endrin ketone5103-71-9 ———— alpha-Chlordane5103-74-2 ——— gamma-Chlordane8001-35-2 ——— Toxaphene

X<£ O / *x XX ^

11104-28-2 — -11141-16-5 — •53469-21-9 — •12672-29-6 — •11097-69-1 —11096-82-5 —

/iJ. (_H_O.WJ. J.UJ.O

—— Aroclor-1221—— Aroclor- 12 3 2—— Aroclor- 12 4 2—— Aroclor-1248

AX UwXwX X.£> «> *±

—— Aroclor-1260

.050

.050

.050

.050

.050

.050

.050

.050

.100

.100

.100

.100

.100

. 100

.100.50

.100.50.501.0.50.50.50.50.501.01.0

UUUuuuuuuuuuuuuuuuuuuuuuuuu

m

4CPESTICIDE METHOD BLANK SUMMARY

BCM Contract:

BCM Case No.: 38191 SAS No.: SDG No.: S582

Lab Sample ID: 100617MB Lab File ID: 10117115

Matrix: (soil/water) SOIL Level:(low/med) LOW

Date Extracted: 1/11/91 Extraction: (SepF/Cont/Sonc) SONC

Date Analyzed (1) : 1/18/91 Date Analyzed (2) : -1/10/Dl

rime Analyzed (1): 2:40 Time Analyzed (2): -a i 4y

Instrument ID (1): 0008 Instrument ID (2):-0000"

1C Column ID (1): CAP GC Column ID (2) : .jCAP~

THIS METHOD BLANK APPLIES TO THE FOLLOWING SAMPLES, MS AND MSD:

1>2>34567891011121314151617181920212223242526

EPASAMPLE NO.

/00608 RE.00608MS RE/00608MSDRE100768 RE

LABSAMPLE ID

10060810060fSPK100618DUP100768

DATEANALYZED 1

X / XO / y X1/18/911/18/911 / 1 Q /Q 1

DATEANALYZED 2

-ZfttfVT-

"L / 18 791

ts:

age 1 of 1FORM IV PEST 1/87 Rev.

OQQQZ1

ID . EPA SAMPLE NO.PESTICIDE ORGANICS ANALYSIS DATA SHEET


~~gjlLab Code: BCM Case No.: 38191 SAS No.: SDG No.: S582A





Extraction: (SepF/Cont/Sonc) SONG Date Analyzed: 1/18/91*



319-84-6 ——-3 T Q Q C_"7 _

76-44-8 ——j U . 7 U U - £ ""*•*

1024-57-3 ——

60-57-1 — -^ ^ rt72-55—9 — •-

33213-65-9 — -72-54-8 — -

1031-07-8 — -FT f\ O _"l "

• — alpha-BHC• — beta-BHC. — delta-BHC• — gamma-BHC (Lindane)• — Heptachlor

•C-IX\*LX -1.11

—— Heptachlor epoxide—— Endosulfan I—— Dieldrin

f *± LJLJLi

—— Endrin—— Endosulfan II

f ** ULJLJ

—— Endosulfan sulfateA At r\T\m

72-43-5 ———— Methoxychlor53494-70-5 ———— Endrin ketone5103-71-9 ———— alpha-Chlordane5103-74-2 ——— garama-Chlordane8001-35-2 ——— Toxaphene

11104-28-2 — •11141-16-5 — •53469-21-9 — •12672-29-6 — •11097-69-1 —11096-82-5 —

rij. WV_JLV_<JL j.uxo—— Aroclor-1221—— Aroclor-1232—— Aroclor-1242—— Aroclor-1248

f J- wwXVJJL «U*» *J *t

—— Aroclor-1260

8.08.08.08.08.08.08.08.016.16.16.16.16.16.16.80.16.80.80.

160.80.80.80.30.80.

160.160.

UUUUUUUUUUUUUUUuuuuuuuuuuuu

0000 2FORM I PEST

BCM

Section 6

Internal Standards Summary Forms

HR3071.69


Name: BCM Contract:/00608 RE

ib Code: BCM Case No.: 38191 SAS No.: SDG No.: S582

.trix: (soil/water) SOIL Lab Sample ID: 100608

imple wt/vol: 10. (g/mL) G Lab File ID: 10117202

>vel: (low/med) LOW Date Received: I/ 9/91

Moisture: not dec. 52. dec. 0. Date Extracted: 1/11/91

:traction: (SepF/Cont/Sonc) SONG Date Analyzed: 1/18/91

'C Cleanup: (Y/N) N pH: .0 Dilution Factor: 1.00


319-84-6————alpha-BHC319-85-7————beta-BHC319-86-8————delta-BHC58-89-9————gamma-BHC (Lindane)76-44-8————Heptachlor309-00-2————Aldrin1024-57-3————Heptachlor epoxide959-98-8————Endosulfan I60-57-1————Dieldrin72-55-9————4 , 4 ' -DDE72-20-8————Endrin

33213-65-9————Endosulfan II72-54-8————4 , 4 '-ODD

1031-07-8————Endosulfan sulfate50-29-3————4 , 4 ' -DDT72-43 -5 ————Methoxychlor

53494-70-5————Endrin ketone5103-71-9————alpha-Chlordane5103-74-2————gamma-Chlordane8001-35-2————Toxaphene12674-11-2————Aroclor-101611104-28-2————Aroclor-122111141-16-5————Aroclor-123253469-21-9————Aroclor-124212672-29-6————Aroclor-124811097-69-1————Aroclor-125411096-82-5————Aroclor-1260

50.50.50.50.

' 50.50.50.50.100.100.100.100.100.100.100.500.100.500.500.1000.500.500.500.500.500.1000.1000.


FORM I PEST

BCM LABORATORIES Report - GENIE fled ium_Area Form

Sample Name : 100608.TCL608 10G-10ML Report No : 40.01COLUMN SPB608 30M BY 0.53MM FUSED SILICA Paqe 1l Hl 1MIN 5C/MIN 275C iOMIN DET 350C INJ 250Cf PtLP TCL COMPOUNDS 'INSTRUMENT TRACOR 540 3UL INJ. UOL.

Book/Page : E1016/21 OXYCHEM GCS582NGG 1/11 ORDER 38191

Peak Processor : Genie M u l t i l e v e l : False



Result F i l e : /DATA/EXTRACTS/RESULT/I 0117202.RES


Sequence File: /DATA/EXTRACTS/SEQUENCE/SEQCLP_011891_8.SEQ

Subseq/Sample: 1/2 _ Bottle no. : 2

Threshold Min-Ar Pkwidth RF_Unknown2.0 1.5000E+03 .100 2.633E-U7

Pef Udw ttbs Ref-PTUI Non Ref Win Abs Non Ref-RTU) Ident LevelkO . 0 0 1.50 0.00 1.50 1000.00

act , Smp-Amt Std-Amt % Purity Inj Uo1 Ratio1 . OOOOE+05J O.OOOOE+00 l.OOOOE+00 100.000 1.000

Pun Status : EndOffBase 1 ineS i qna 1 Over 1 oad ""

'irned Events Time Events Loqic Ualue EventUpdate1 .05 ResetBLAllUalley EventOn -1.00 False2 .10 AutoSolvent EventOff -1.00 False

PHt PT ID-tm PeakUidth Area Code AMOUNT Name1 1.29 #.56 .1274 63966304GB 3.0461E+05 SOLUENT FRONT2 1.67 .0296 5334BB 1.4045E+00

1.97 .0751 22302BB 5.8728E+004 2.77 .0907 4885BB 1.2864E+00

' r- 4.01 .1365 16508BB 4.3471E + 006 4.85 .1037 4129BB 1.0874E+00•=" 5.09 .1021 23039BB 6.0669E+00r ?.^7 .1186 " 100584BB 2.6487E+01v 6.12 .1075 " 5750BB 1.5141E+0010 6.34 .1179 17273BB 4.5486E+00:. i -.71 ,.1238 6694BB 1.7628E + 0012 7.01 7.07 .1253 23904BB 4.5872E + 00 2-

^.60 .-1148 783639BB 2.0636E+029.24 .1107 124305BB 3.2734E+01

10.17 .0847 1580BB 4.1601E-0116 10.38 .1299 10476BB 2.7587E+00

flR307lt7


Sample Name : 100608 TCL608 10G-10ML Report No : 40.01COLUMN SPB608 30M BY 0.53MM FUSED SILICA Paqe 2Pk# RT ID-tm PeakWidth Area Code AMOUNT Name17 10.88 .1197 34444BB 9.0702E+0018 11.21 .1155 2996BB 7.8907E-0119 11.76 11.93 .1498 2287BB 2.4948E+00 a ipha-BHC-20 12.34 .1331 2464BB 6.4898E-0121 12.67 .1253 4861BB 1.2800E+0022 13.02 .1165 386088 1.0164E+0023 13.36 13.54 .1717 10714BB 1.2895E+01 e^-rmia-BMC (Lindtfne)24 13.71 13.87 .1708 6424BB 9.9166E+00 buta DI 1C L-fnc J—25 14.47 .1172 2119BB 5.5810E-01"6 15.81 .1553 13442BB 3.5398E+002,- 16.24 16.16 .1316 1889BB 1.9832E+00 H l d n i n28 16.50 .1507 5137BB 1.3 527E+00 k IcUnn29 17.09 .1117 8958BB 2.3589E+0030 17.57 .1512 9891BB 2.6047E+0031 17.86 .1097 2223BB 5.8536E-0132 18.53 18.42 .1498 5323BB 4.8942E + 00 Hoptaohlei—epuXide33 19.54 19.71 .1350 1669BB 1.4403E+00 T I p h n - f i l i l u i Uaim34 20.10 .1032 1553BB 4.0882E-01s1? 20.56 20.75 .1885 6497BB 7.4312E + 00 4-p»'-DDE36 21.17 20.98 .1415 3923BB 4.0326E + 00 D i ei 1 d i- i n37 21.58 .1501 3217BB 8.4726E-0138 22.34 22.42 .1353 24298BB 3.7338E+01 End r i n39 23.15 23.11 .1382 2784BB 2.9456E + 00 Endy L.U 1 Pan 1140 24.40 24.39 .1090 3126BB 6.3008E-t-01 Fnri'Ti-i 1 Fan fii.l Fntr T)\) \41 25.08 .1956 308815BB 8.1321E+0142 26.24 25.96 .1746 53811BB 7.0244E+01 DibutyIch1orendate 7~3 27.19 .1626 1832BB 4.8248E-0144 28.63 .2724 J26051BB 6.8602E + 00-5 29.13 .1725 "1833BB 4.8269E-01^6 29.46 .2215 3041BB 8.0074E-01-7 30.49 .2418 17279BB 4.5501E+00^8 30.86 .2429 3127BB 8.2357E-01-9 74.42 .6754 ' 28107BB 7.4016E+00

'otal -rea : 65724696 Total AMOUNT : 305261.900

Keport Time : Sat Jan 19, 1991 4:21:34 pmMethoq : /DATA/EXTRACTS/METHOD/MTHCLP 011791 8.MTH

0000 7 flR307.72


Sample Name : 100608 TCL608 10G-10ML Report No : 40.01COLUMN SPB608 30M BY 0.53MM FUSED SILICA Page 3

I _ .II

SOLUENT

'5.473l417 6.340

2 ,4,5 ,6-TETRACHLORO-m-:

10-879a Ipha-BHC

I = — - T , 'gamma-BHC (.Lindane)gamtr d "•

Heptachlor epoxide

alpha-Chlordane20.100

4,4'-DDEDieldrin21.578

FRONT

:YLENE'.599

.238

jindpsu 1 f an sulfate— ———' 2'?. 078

,.>——— D 1 bu tylch lorondate27.190

28.631

30.86I0'495

34.418











319-84-6————alpha-BHC319-85-7————beta-BHC319-86-8————delta-BHC58-89-9————gamma-BHC (Lindane)76-44-8————Heptachlor309-00-2————Aldrin1024-57-3————Heptachlor epoxide959-98-8————Endosulfan I60-57-1————Dieldrin72-55-9 ————— 4 ,4'-DDE72-20-8————Endrin

33213-65-9————Endosulfan II72-54-8 ————— 4 , 4 ' -ODD

1031-07-8————Endosulfan sulfate50-29-3————4, 4'-DDT72-43-5————Methoxychlor

53494-70-5————Endrin ketone5103-71-9————alpha-Chlordane5103-74-2————gamma-Chlordane8001-35-2————Toxaphene12674-11-2————Aroclor-101611104-28-2————Aroclor-122111141-16-5————Aroclor-123253469-21-9————Aroclor-124212672-29-6———-Aroclor-124811097-69-1————Aroclor-125411096-82-5————Aroclor-1260

.058

.058

.058

.058

.058

.058

.058

.058.12. 12.12.12.12.12.12.58.12.58.581.2.58.58.58. 58.581.21.2

UUUUUUUUUUUUuuuuuuuuuuuuuuu

FORM i PEST ecoo ..9 /.R3WW-

HUM LAHUWf. I LIK l tb Keport - UStNlt Med ium_f=»rea l-orin

Samp I .» NMme : 1UU616 6Ubll.:i_ B6UML.-1UML W7B6 Weport No :1U/.U'1LULUMN ^HH6ua J.IJH HY u.^nn i-ubtu aiLiLA Page l

J H I N '.L/MIN 2/^L -j.uniNL. ut i ^->uu INJ.i H M:L IJUMHUUNIJS|f,intNi IKttL'.UK ^4U 3UL INJ.

Honk/Hage : .

Heak Hrocessor : Lien i e __ Hu 11 i level : t-aise

Instrument : «l)U_H Application : Loop

Ca l c u l a t i o n : ., tx t erna I S I U _ Uuan t i t a t l on : AreaUnits

W.j!.,u I t Hil.?. : /Uttl A/tXI WrtU I b/H*tSUL I / I U 1221IV . Wtb

Wun l i m e : 36.LIU Minute-, Injected nn Wed Jan 2> . 1VV1 2'. <? 5'. 2\.\ am

Sequence r i I e : /UA I A/hX I K"«l_; I b/btUUhNLh/btULLr'_U122Vl_B .

le: I/ JV dottle no. : I

ihrf.sholrt ntn-«r Hkwidth W'2. . U 1 . "?UUUt+U3 _ ._ .1UU '2

wer uirtui «bs Kef-KIU Non Kef Win Abs Non Kef-WIUl Ident Leue IU.UII I.UU U.I.I I! I.UU lUULI.UU

bimp-Amt btd-Amt % Purity Ini Uo 1 KatioU. U. Utlllt* Hll 1 . UUULIt-HlU 1UU.UUU l.UMU

btatus : tndl.lt'ftiase I i neSi ana 1Uverload

i i m.»d h vp-.n t s I ime tven t s Log i c Ua 1 ue tv^en t Up da t e'I . U*> WesetHLA 1 1 Ua 1 1 ey hyentLIn -l^UU halse'I . lU Wutobo I vent tventtJtf -I.UU halse

Hkifc ..I JU-tm HeakUlid t h ttrea Lode «MUUN I NameL :i...>U *."36 .1UU1? bU4VUV6Ubhi V.62UBt+U2 SULUtN I H..UNI2 IU.2/ *1U.26 .ILILIII 1/UV41HH >.B144t-Ul 2 . 4 . <y__. 6- I t I WttLHLUWU-m-XYL

A V6.IV V6.^B .14/V 44yVHB 4.U4>Ht-Ul tHfedn.su I I'an T.II 1 >•' a t-o•? V6.t>A . ibB6 yviuvBb v.oiv/'t-uvi6 V/.^V dk^/.4V .IB'93 4V/6/HH . 6 . 66^yt-Ul U i bu t y 1 ch 1 o renda t e

l o t a l «rea : b U/-2/6 //! lotal AMUUN I : V6^

I i me : Uled Jan 23. iVVl i : yy : I .> pm: /I.)A I A/tX I WAU I b/Mt I Hl.JU/M I HLLH_U 122 V1_BH . H I H

000030 SR307U5

BUM LAHUKAIUKltb Keport - bJtNlt Madium_Area rorm

B Nwrne : 1UU616 6UHHJL B6UML-lUnL W7H6 Keport No :1U7.U1;LILUMN SPB6U8 .^UM HY U.'.OMM t-ustu SILILA Page 2

.';'>r

\\\\\V

i bULUtNl j V-KUNIi

.6- I t I KRL:HLLIHU-m-KYLtNt

/6"7 I

r..._ l- n rt o s i j l f a n sulfate

Uibutylchlorendateji

000031«"» f,

i/£


BCM Contract:100617

tb Code: BCM Case No.: 38191 SAS No.: SDG No.: S582A

itrix: (soil/water) SOIL Lab Sample ID: 100617MB

tmple wt/vol: 30. (g/mL) G Lab File ID: 10117115

3vel: (low/med) LlOW Date Received: O/ O/ 0


itraction: (SepF/Cont/Sonc) SONG Date Analyzed: 1/18/91

Cleanup: (Y/N) N pH: .0 Dilution Factor: 1.00


319-84-6————alpha-BHC319-85-7————beta-BHC319-86-8————delta-BHC58-89-9————gamma-BHC (Lindane)76-44-8————Heptachlor309-00-2————Aldrin1024-57-3————Heptachlor epoxide959-98-8————Endosulfan I60-57-1————Dieldrin72-55-9 ————— 4, 4'-DDE72-20-8————Endrin


1031-07-8————Endosulfan sulfate50-29-3—————4,4'-DDT72-43-5————Methoxychlor

53494-70-5————Endrin ketone5103-71-9————alpha-Chlordane5103-74-2————gamma-Chlordane8001-35-2————Toxaphene12674-11-2————Aroclor-101611104-28-2————Aroclor-122111141-16-5————Aroclor-123253469-21-9———Aroclor-124212672-29-6————Aroclor-124811097-69-1————Aroclor-125411096-82-5————Aroclor-1260

8.08.08.08.08.08.08.08.016.16.16.16.16.16.16.80.16.80.80.160.80.80.80.80.80.160.160.

UUUUUUUUUUUUUUUUUUUUuuuuuuu

000032

FOEMIPEST

BCM LABORATORIES Report - GENIE Medium_Area Form'i:-C?0 6 7

Sample Name : 100617 TCL608 30G-10ML MBLK S582 Report No : 21.01COLUMN SPB608 30M BY 0.53MM FUSED SILICA Paqe 1150C 1MIN 5C/MIN 275C 10M1N DET 350C INJ 250CALL CLP TCL COMPOUNDSINSTRUMENT TRACOR 540 3UL INJ. UQL.

Book/Paqe : 10016/19 BATCH GSC582 1/11 NGG OCCIDENTAL




Result File : /DATA/EXTRACTS/RESULT/I 0117115 . RES

Run Time : 36.00 Minutes Injected on Fri Jan 18, 1991 2:40:03 am

Sequence File: /DATA/EXTRACTS/SEQUENCE/SEQCLP_01179 1_8 . SEQ


Threshold Min-Ar Pkwidth RF_Unknown2.0 1.5000E+U3 .100 2.633E-U7

Ref Uldw Abs Ref-RTU Non Ref Win Abs Non Ref-RTW Ident Level0.00 1.00 0.00 1.00 1000.00

% Oil-Fact Smp-Amt Std-Amt \ Purity In] Uo1 Ratio3.3333E+04 O.OOOOE-t-00 l.OOOOE+00 100.000 1.000

Run Status : EndOffBase 1 ineSiqna1 Over load

Timed Events Time Events Loqic Ualue EventUpdate1 .05 ResetBLAllUalley EventOn -1.00 False2 .10 AutoSolvent EventOff -1.00 False

Pk# RT ID-tm PeakUidth Area Code AMOUNT Name1 1.25 #.56 .1111 55811576GB 8.8593E+04 SULUENT FRONT2 1.70 .0857 33109BB 2.9062E+003 1.93 .0412 3581BB 3.1431E-014 5.38 .1142 2242BB 1.9680E-01? 9.12 .1018 144969BB 1.2725E+016 25.19 .1538 7018BB 6.1598E-017 26.07 25.96 .1732 59685BB 2.5970E+01 DibutyIch1orendate


Report Time : Fri Jan 18, 1991 8:59:58 amMethod : /DATtt/EXTRACTS/METHOD/MTHCLP_011791_8 . MTH

000033


Sample Name : 100617 TCL608 30G-10ML MBLK S582 Report No : 21.01COLUMN SPB608 30M BY 0.53MM FUSED SILICA Paqe 2

————————|I

I SOLVENT[FRONT——! (..702

. 118

DibutvIchlor nda t e

000034AR307l*79


b Name: BCM Contract:100768 RE

b Code: BCM Case No.: 38191 SAS No.: SDG No.: S582

rrix: (soil/water) SOIL Lab Sample ID: 100768

mple wt/vol: 10. (g/mL) G Lab File ID: 10117205

vel: (low/med) LOW Date Received: 1/10/91


traction: (SepF/Cont/Sonc) SONG Date Analyzed: 1/18/91

C Cleanup: (Y/N) N pH: .0 Dilution Factor: 1.00


319-84-6————alpha-BHC3 19-85-7————beta-BHC319-86-8————delta-BHC58-89-9————gamma-BHC (Lindane)76-44-8————Heptachlor309-00-2————Aldrin1024-57-3————Heptachlor epoxide959-98-8————Endosulfan I60-57-1————Dieldrin72-55-9 ———— 4 , 4 ' -DDE72-20-8————Endrin

33213-65-9————Endosulfan II72-54-8 ———— 4, 4'-ODD


53494-70-5————Endrin ketone5103-71-9————alpha-Chlordane5103-74-2————gamma-Chlordane8001-35-2———-Toxaphene12674-11-2————Aroclor-101611104-28-2—i—Aroclor-122111141-16-5————Aroclor-1232C2-.65-21-9-----Arocior-124212672-29-6————Aroclor-12 4811097-69-1————Aroclor-125411096-82-5————Aroclor-1260

46.46.46.46.

• 46.46.46.46.92.92.92.92.92.92.92.

460.92.

460.460.920.460.460.460.460.460.740.920.

UUUUUUUUUUUUUUUUUUUUuuuuuJu

009035FORM I PEST 1/87 Rev.

AR307I.8Q


Sample Name : 100768 TCL608 10G-10ML Report No : 43.01COLUMN SPB608 30M BY 0.53MM FUSED SILICA Page 1tlM IN 5C/MIN 275C 10MIN DET 350C INJ 250C

CLP TCL COMPOUNDSRUMENT TRACOR 540 3UL INJ. UOL.

Book/Page : E1016/21 OXYCHEM GCS582NGG 1/11 ORDER 38191




Result File : /DATA/EXTRACTS/RESULT/ 1 0117205 . RES


Sequence File: /DATA/EXTRACTS/SEQUENCE/SEQCLP_011891_8 . SEQ

Subseq/Samp le : I/ 5 Bottle no. : 5


Pef Udw Abs Ref-RTW Non Ref Win Abs Non Ref-RTU) Ident Level.00 1.50 0.00 1.50 1000.00

Smp-Amt Std-Amt % Purity In] Uo 1 Ratiol.OOOOE+05 0. OOOOE+00 l.OOOOE+00 100.000 1.000

Pun Status : S igna lOver load

Timed Events Time Events Logic Ualue EventUpdate1 .05 ResetBLAl lUal ley EventOn -1.00 False2 .10 AutoSolvent EventOff -1.00 False

Pktf RT ID-tm PeakWidth Area Code AMOUNT Name1 1.30 #.56 .1275 64025848GB 3.0490E+05 SOLUENT FRONT2 1.69 .0275 5595BB 1.4734E+003 1.99 .0506 6495BB 1.7103E+00* 5.51 .1134 56974BB 1.5003E+015 5.74 .0993 1648BB 4.3389E-01t> 6.37 .1246 10740BB 2.8282E + 007 6.74 .1157 4290B8 1.129BE+008 6.97 7.07 .1228 3354BB 6.4364E-01 .2,^,^,6 TETR(?iCI ILORO-5 ~.o3 .1382 5084BB 1.3389E+00

10 9.28 .1015 172234BB 4.5355E+0111 10.18 .1633 5258BB 1.3846E-t-0012 10. 90 .1281 "" 1644BB 4.3296E-0113 11.24 .1293 2342BB 6.1673E-0114 13.93 13.87 .1245 1550BB 2.3930E+00•14.52 .1308 3195BB 8.4145E-01

15.23 15.37 .1589 2049BB 2.5126E+0016.52 .1151 7403BB 1.9496E+00

OOS03S5tR307l*8l


Sample Name : 100768 TCL608 10G-10ML Report No : 43.01COLUMN SPB608 30M BY 0 . 53MM FUSED SILICA Page 2Pk# RT ID-tm PeakUlidth Area Code AMOUNT Name18 17.82 .1396 4503BB 1.1858E+0019 18.30 18.42 .1301 4678BB 4.3008E+00 hioptaohlur opujride20 18.82 .1109 6775BB 1.7841E+0021 19.11 19.07 .1335 5867BB 5.3263E+00 gamma Chlordane22 19.39 .1246 17494BB 4.6067E+0023 19.63 19.71 .1299 16831BB 1.4527E+01 a24 19.90 19.78 .1293 6764BB 6.1663E+00 Endosulfan I25 20.69 20.75 .1783 10952BB 1.2527E + 01 4Tzf126 20.98 20.98 .1157 6077BB 6.2475E+00 Dieldrin27 21.22 .1334 10119BB 2.6647E+0028 21.64 .1487 33051BB 8.7035E-t-0029 22.07 .1348 19257BB 5.0711E+0030 22.32 22.42 .1180 11854BB 1.8216E+01 Endrin31 22.62 22.90 .1370 16916BB 2.5844E+01 4 4-"— ©OD32 23.39 23.11 .1307 4528BB 4.7906E+00 BlClu^u I^uu II33 23.72 .1020 4664BB 1.2282E+0034 23.92 24.03 .0995 3601BB 5.2369E + 00 4p4'35 24.27 24.37 .1806 30553BB 4.3952E+01 Endrin Aldehyde36 25.13 .1697 47662B8 1.2551E+0137 25.37 .0956 2580BB 6.7946E-0138 26.07 25.96 .0989 3536BB 4.6161E+00 Dibut y Ich lorendat e39 26.30 .1474 59779BB 1.5742E+01^/40 27.31 .1513 2327BB 6.1276E-0141 29.16 .2253 3236BB 8.5205E-0142 30.42 .2106 7164BB 1.8865E+0043 32.30 .2428 10014BB 2.6370E+00


Report Time : Sat Jan 19, 1991 4:35:36 pmMethod : /DATA/EXTRACTS/METHOD/MTHCLP 011791 8 . MTH

000037


Sample Name : 100768 TCL608 10G-10ML Report No : 43.0120LUMN SPB608 30M BY 0F53MM FUSED SILICA Page 3

SOLUENT1.

5.738 5'506.371

2 , $ ; 57S- TETRACHLORO-m-XYLENE7.633

10.176

1D'.?Ii5

beta-BHC14.520

delta-BHC

16.522

17.818Heptachlor epoxide

8 . 81£. . ,"=th Iordane0.Endosu14nk4'TDDE

1721.637

FRONT

.283

25.125Endrin Aldehyd

000038 ftR307i,83


ab Name: BCM Contract:100770

ab Code: BCM Case No.: 38191 SAS No.: SDG No.: W586

atrix: (soil/water) WATER Lab Sample ID: 100770

ample wt/vol: 1000. (g/mL)ML Lab File ID: 10122121

avel: (low/med) LOW Date Received: 1/10/91

Moisture: not dec.100. dec. 0. Date Extracted: 1/14/91

•ctraction: (SepF/Cont/Sonc) SEPF Date Analyzed: 1/23/91

?C Cleanup: (Y/N) N pH: .0 Dilution Factor: 1.00


319-84-6————alpha-BHC• 319-85-7————beta-BHC319-86-8————delta-BHC58-89-9————gamma-BHC (Lindane)76-44-8————Heptachlor309-00-2————Aldrin1024-57-3————Heptachlor epoxide959-98-8————Endosulfan I60-57-1————Dieldrin72-55-9————4 , 4 ' -DDE72-20-8————Endrin

33213-65-9————Endosulfan II72-54-8 ———— 4 , 4 ' -ODD


53494-70-5————-Endrin ketone5103-71-9————alpha-Chlordane5103-74-2————gamma-Chlordane8001-35-2———Toxaphene12674-11-2————Aroclor-101611104-28-2————Aroclor-122111141-16-5————Aroclor-123253469-21-9————Aroclor-12 4 212672-29-6————Aroclor-124811097-69-1————Aroclor-125411096-82-5————Aroclor-1260

.050

.050

.050

.050

.050

.050

.050

.050

.100

.100

.100

.100

.100

.100

.100.50.100.50.501.0.50.50.50.50.501.01.0

UUUUUUuuuuuuuuuuuuuuuuuuuuu

FORM I PEST 000039

Hi^n L.HWUKW MJK i e.s Kepnrr - USC.IN 11 nen ium_»-iri3«> rorm

fi N..mt» : 1UU/VU 6118 ILL 1UUUML-iUML U1_>H6 Keport No :1UV.U1r.UI IJMN bHH6U« 3UM HY U.'sJMM HJStL) b IL i UA Page 1•j'.iii: IMIN -7U/M1N 2/"?i; IUMIN uti 5«?uL LNJ«U_ LLH IUL UJMHUUNI.S,

I WttULIK "7AU JUL INJ. ULIL..

Hrnc.»ft»nr : Irienie M u l t i l e v e l : raise

Instrument : AIJL_B _ Application : Loop

Laic til at inn : txternalSlU LJuan t 11 a t i on : Area Units

We»ult I- i t e : /UA I ft/fcX I K«i: I b/Kt.bUL I / I U'L22 121 . Kb.S

K'nn l i m e : 56 . \\2 Hinutes Injected on Wed Jan 23. lyyi <4:iy":'2'l am

S-.niif.ncR H v Le: /Oft I tt/hX I WftlJ I S/ShULJfc.NI.:fc./Sfc.ULLH_J) 1229 1_B . StU

le: I/ -21 _. : _ Hot tie no. : 21

Min-«r Hkwidth .«;.-_Unknownl..>UUUtt-U5 . 1UU X-6>->t-U.>

Wet- Ulrtui «bs, Wef-WIUI Non Kef Win Abs Non K*f-KIUI Ident Level1 I . I I U I.UU U.UU I.UU 1UUU.IIU

Smp-«mt Std-Amt % Hurity Ini Uo1 KatioII. U. IIU LI lit+ 111) 1. U.UUUt-Hlll 1UU.OUU 1 . U U U

•Status : tnflUf f Hase I i neSignalUv«r t o « d

iimp.d hvents l i m e hvcnts Logic Ua lue h.ventUpdate'J . LI1? W«»e t Bl. p 1 | U.. 1 1 ev hven t Un -I.UU Halse•/. . 1U Autobolvent tventUff -L.UU halse

^UJt k I lL)-tm HeakUlidth Wrea Lode ftHUUN I Name! L.^U *. 6 . 1J.4AH '224W2 2 ti -• . 686y t+U2 bULUtN I H KUN I

.- UJ.'^B #11.1.26 .11.110. 1J..S1B/HH V.^'s-^Vh-Ul 2 .4."? .6- I t IKAUHLUKU-m-XYLA I'-./B . iyuy IBBBHH•7 V6.22 26.2H -16BB 5

/ V/.6V; Jtv/.^y .LB/6 A/3/yHB b , 4*5 . *h-U'i U i bu t y t ch 1 o renda t e

i n t a l rtrea : 226V /V2U lotal AMUUN I :

^:A1:^/ pmtWthnd : /UA I A/tX I KALI^b/Mh .J HUU/M I HuL.H_l) I'/I V 1_BK. M I H

•:».*• >

I-HCSUKM i urr i c.S3 report - istMic. neoium_Hrea rorm

Samp Ie Nam« : 1UU//U 6UBIUL 1UUUML-LUML U^«6 Keport No :1UV.U1l.:iJLUMN bHH6UB 3UM HY U.-^MM MJbhU S1L1 LA ' Hage '2

! ! . ii L_ __' _ _ !I . . .._....._ """"j bULUfcN I I r KUNIl -._,———-———————— ———————————————— j

. a . •> . b- I L I KRCHLUKU-m-KYLhNh

ib.//y

_triieluau 1 I'an ^u t I'ate

Uibutylch torendateiji

I (JOG(m RB.307U86

000052


ab Name: BCM Contract:101068

ab Code: BCM Case No.: 38298 SAS No.: SDG No.: S592

atrix: (soil/water) SOIL Lab Sample ID: 101068

ample wt/vol: 10. (g/mL) G Lab File ID:J 0125124

evel: (low/med) LOW Date Received: 1/15/91


xtraction: (SepF/Cont/Sonc) SEPF Date Analyzed: 1/26/91

PC Cleanup: (Y/N) N pH: .0 Dilution Factor: 1.00


319-84-6————alpha-BHC319-85-7————beta-BHC319-86-8————delta-BHC58-89-9————gamma-BHC (Lindane)76-44-8————Heptachlor309-00-2————Aldrin1024-57-3————Heptachlor epoxide959-98-8————Endosulfan I60-57-1————Dieldrin72-55-9————4 , 4 ' -DDE72-20-8————Endrin


1031-07-8————Endosulfan sulfate50-29-3 ———— 4 , 4 ' -DDT72-43-5————Methoxychlor

53494-70-5————Endrin ketone5103-71-9————alpha-Chlordane5103-74-2————gamma-Chlordane8001-35-2————Toxaphene12674-11-2————Aroclor-101611104-28-2————Aroclor-122111141-16-5————Aroclor-123253469-21-9————Aroclor-12 4 212672-29-6————Aroclor-124811097-69-1————Aroclor-125411096-82-5————Aroclor-1260

39.39.39.39.39.39.39.39.79.79.79.79.79.79.79.390.79.390.390.790.390.390.390.290.390.790.790.

UUUUUUUUUUUUUUUUUUuuuuuuuuu

FORM I PEST O'n0013 1/87 Rev-

AR307I*88 I

BUM LAHUK.A I UK 1 tS Keport - L.tN 1 1 Medium_Area rorm

Sample Name : 1U1U6«»W 6UHILL 1ULJ-1UML bby* Keport No :UULIJMN IJB6UB J.UM BY IJ.^^MM 1-UStU b 1 L I LA Page 1l^ni.; iniN Û/MJN 2/t>L 1LIMJN Ut I .^bLIL INJ 2.>UU«I..L ULH J UL IJUMHtJUNUa• I KUMhN I I KrtlJUK ÂU 1IJL i NJ . UIJL.

••</

Hroressor : L-ienie •- - M u l t i l e v e l : i-alse

Instrument : AIJL_B ... -- — - — • -- Application : Loop

i:aJculation : txtern<BlblU Uuan t i t a t i on : rtreaUnits

Kesult h i i e : /U« l A/tX I K«IJ I b/KtbUL I / I UI'21? 124 . Khb

Kun l i m e : >6.UU Hinutes Injected on bat Jan 26. lyy'i /:-46:UU am

Sequence H . le: /U« I «/tX I KAIJ I b'/bbUUhNlJt/btUUL.-'_U12 <?V 1_B . btU

p 1 e : 'i / 24 Uottle no. : 24

Ihri-snold Min-«r Hkwidth KI-_Unk nown2.11 l.t>UUUt+U^ .1LIU 2

Ket-KIW Non Kef Ulin Abs Non Kef-KIUI Ident LevelU . Ll U 1 . -7 U U . LID 1 . •? U 1 U U U . U U

Uil-Hact Hmp-«mt btd-Amt X Hu r \ t y Ini Uo 1 KatioU.ULIUUt + UU 1. ULIUUhf U U 1UU.UUU 1 . U U U

sâflJS : KunS ttndUf t'BasR I me

* Ii me hven t s Log i c Ua t ue tven t Up da t ei .LI1? KesetHLAl 1 Ua I ley tventUn . -I.UU - Halse<^ . HJ «u to bo I vent hventUtf -I.UU Halse

at h. i iU-tm Heaki.Uidth ftrea Lode PHULIN I NameL 1.6U itl.^3 . UA1. y ^ByB^^Hb /.b'Û/t +•!.).> bULUtN I I- KUN I2 2.2/ . LI^BA _>yyyutiti

f> A.yy -UBU6 ^^ljy«H 6.UBIJ"7h-Ul6 ^.3/ .Li/By ^BJJUHB l.UUb^t + UU/ 6.// . 1U16 'J^^yHB 17.B6BAt-UiH /.Ul .1U6A 16yilBB 4.4*?Liyh-Ulw 4. 'IV -

II . L H . y i itLU.yi .UyiJ-i lia^lÛBH 2 . ÛVt+Ul 2 .4 ..> .6- I t I KAUHLUKU-m-XYL12 1 1 . /2 .I1? /A Â«?ldB 6.A-7>2h-Lll

« . y 6 .?tr.- U 16.U4'7Ut-Ul

. IB .11UJ>4 l.»y6BB A

.tO 16. y^ .2B/6 - VU/BHB 6

000014

HUH LAHUKRMjKltb Keport - y tN 1 t Medium_Area rorm

bampje Name : 1U1U6BM«~6UH I UL lUli-lUML b^y^ Keport No :i/A.UlIJULIJMN MH6UB >UM BY U .«?:.MM HJbtU H I L 1 UA Page —2^k# Kl lU-tm Heakuiidth Area Uode AMUUN I Name1 ' 'IB.2/ lB.2y . 1A/1 iy?BBB 1 . B261k.-H.il) ft.id.MiT'•IB ly.LIB .16U> 1-76J.BB 4.11^./t-LHl.y 23. A/ 23.lti .'L2V6 '^IJ.>IJBB 1 . /6 43 t-t- U U U'le t UTl n2\S 24.44 24.63 . liyy -^LI/ABB l.y/61t + UU Lndi" i P '21 V-6.'^v ' 6. I1? .1/6/ 33V2UU 3.'243lk. + UU 4-.U' -UUI22 26. V6 .166/ I3/263BU 3 . 6 1 46t+ U 1 '2^ 2/.'>y 2/.2.-> .1^1.11 4y23BB 3.A23Bt-t-Ul L ni In -| 1 1 I ran c u J_T_iLo

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l o t a l ttrea : B2BA6y l o t a l AMUUN I : //UA.U/1?

Keport lime : bat Jan 26. lyyi B:4B:21 amMethod : /U«l A/tX I KAIJ I b/Mt IHUU/MIHULH U12'?yi B.MIH

000015 AR307 .90

BUM LAHUWft » UK 1 hS Keport - ytNlt Medium_Area Form

Sample Name : lUlU6HI«t*-6U« I LL lU^-lUML b>?y2 Keport No :ULILUMN UB6LIB .HIM BY U.^MM hUShU S1L1LA Hage 3

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BUM L«HIJK« I UK I tb Keport - IstN I h Medium_Area t-orm

e Name : 1 Lll U6BMU. 6UB I L:L 1 LI Ii- 1 LI ML bby2 Keport No :'133.U'lUIJLIJMN UB-1/IJ1 ..UM BY U .-1? *MM I- UbtU b I L 1 LA Page 1i mii: .MIN L/MIN ,2/"?i_: I U M I N ut i ^^uu INJ 2*?ULAI..I. LLH ILL LUMHIJUNIJbi NS I KI.IMfc N I I KttlJLIK '•'All -MIL i NJ . UI.IL .

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/UA I tt/tX I K«l_: I b/KtbUL I /J U 12 .> 12 A . Khb

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000047

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Sample Name : lUlU6HBt4 6MBIi:L 1 UL-J-UIML b^>y2 Keport NO|-.»n.UMN UH-i/lil >tJM BY IJ.^MM HJbhU blLlLA HageHk# Kl )L)-tm Hi-akUlidth Area Uoae AMUUN I NameI/ 'll.v.-. . L2U1 ^liyHBB 1. . _}A2bh+LHj.IB ll.^B ..12Ay .?61 ABB y.17l62h-Ul_LV !V.A/ . I 6AA 222.7BB ^ . B1? A'lfc - I.I'I

12.yil .Jl/ll 22A?HB "7 . y LI66b-LI "iIA./.. l,A.6r. . J rSB1? 6AA'IBB A, 12 IJ2b + ll II I \i*9-f m f> h TO r <

V'V I H. II1? .2UU1? ^.?y?BB 1 . A2LI.7h-H.lU2? 211. IKS 2IJ.IJ1. . 'I yj.2 -U62BB 2 . B2 AlJt HI IJ ^ . •!» ' -UUL—•/•A yi.l.J..i y|J.A^ .J6.?.^ .'/'J..HB b . k76AAb-H.ILI LOT11 U'r'tiUHrl.1; 'j late-"-> VI. n1? . 12 .>y - VIIA.HB ^ . 5/HBb-LH

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COOO.W

•=>*mple Name : 1U1LI6HW-* 6UBILIL '1 Lll=;-'l IIML WyVV? Keport No 1133.U1ULIJMN UB-L/IJ1 >IJM BY \).*?3nn hUbhU b IL1 LA Page 3

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, 2.626

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"X VA.6A)-i bndrin Aldehk.de

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0000=19

UUANI HhHUKi

Ub£K2 - ,_.. Juant Kev: 6 ijuant l i m e : V1U2U1 LIB: 23•'Sbl31.j: :D1 " - Injected at: V1U2U1 U/:2/>~bl3'lV : : A6" "" U i i u t i on I-ac t or : 1 U U U . U U U

e : 1U1U6B 6UBTCL ."c: 1UL INJ GLbUS92 1 ULik "."rUTTL" - BiLftiJ

f - i l e : iD_BXA::Uir . .___le: HH BNA Standardst La 1 i b r a t i o n : V1U 13 1 1 a : 2 3

Compound H. I . Scan.. ftrea Lcnc Units q

*1 ,4-Uich lorobenzene-dA lb 13.41 /"1V 6/f-"?2 4SJ.UU ug/L VA~Naph tha Iene-d8 .13 16./'I 1U3B 2^266-2 ^U.iJU ug/L W*Acenaphthene-dlU . lb 21.AA lAV1? 1662A6 AiJ.U'J ug/L VV?*Hhenan threne-dlU .... 1S"2"!?.^B IB.-'6 2V8//U 4U.'JU ug/L VAPhenan t h rene -. 2t.AA I'clo2 - - 1216 i,.-"" .'J'r1 uq/L V L)Anthracene - - '2^ .,44 iHtl2 11I16 1/2. IB ug/L V3

*Lhrysene-dl2 - IS 33.UU .2611 1/2424 4U.UU ug/L VoPyrene - .. ."- ~. . 29 .2S 2252' 1541 223.44 ug/L /6b is t'2-£thy Ihexy 1 . phtha late 32.7B 2^yiJ l/y3/ 46/B.V2 ug/L V/

*Pery Iene-dl2 lb 4U.B2 3364 134428 4U.UU ug/L V/'Di-n-octylphtha late 3"?. 66 2B6/ 1113 1B6.S/ ug/L 1UU

u n d i s 1S I U

r.HF>nMOTnfii?ptiFil* >S131? 35.0-500.0 3.XU. 1.01063 60STCL 1111.. TN..I fiogofjq? 1 on

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Oata I- l i e : >S131V::A6 " Uuant Uutput File: '"bl31V::Ulr-.ame: 1U1U6B 6USTCLHi so: 1UL INJ GLbU^yi 1UUK./1UML B!L#13

i d K i 1 e : 1 D_BXA : : U|TI i t l e : HH BNA StandardsLast Calibration: yiU131 lid: 23

Uperator ID: UbhR2"Uuant lime: V1U2U1 UB:23injected at: 9 1 U 2 0 1 U / : 2 /

000051 «R307i,96

^ »J I* ti ^ BTiiO.3 itvjCpk^lB C56C55.

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.StlPLE: SPECTRUMFile .£1319 101Bpk fib 1990.

OOQQ-j

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PPH BNH STD Scan" 1834*~» »r» ir -**•< .. ; .-../ «_>,_' U- W • V «-' Ml 1 1 1 •

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80 94 160 1-"•--- ii-. i .1 .t . i.ii .SO ISO 160

Fiis '>?131? 177.7-178.7 '

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Data i - i i e : >b!3iy: :A6 _ __Ljuajn t Uutput r i l e : "Sl3iy::UlDame: 1U106B 6U8TCL " ^ =Misc: 1UL INJ GCSU592 " "1UGR/1UML HUuant l i m e : yiU2Ul UB: 23 Uuant 1U r i l e : 1 U_t!XA: : LJ IInjected at: 91U201 07:27 Last C a l i b r a t i o n : 91U131 IB:23

Compound No: byCompound Name: PhenanthreneScan Number: TBB2retention Time: 25". 43 rrfi n . " ~"Uuant Ion: I/a.UAr e a: 1216Concentration: I/1?. 2V ug/Lq-value: 9 U . . " „ , , . . .

000052

EFEREriCE 3Ti.NuMRD SFECTRufl-~i i e >5i JL03 160 PPrl BN'H S i 0 Scan i.546 iDpk flb 259102. SUB 25.15 ,v,ir. .

1 7R— • - ii f \•* r~l v v

30000 O-' ~J rt _™ 151 266 t

I-LJ... ...j_~i.J __ ——— "Ii. _ .1 "'•Li-,

100 SOO

OMPI E spF^TRim < RQntc-fif-niiND suBTRonTtrn. .•" i 1 s 'S131? lO^'^SS 608TCL ?c n 1882iok fib 598. *""" ^ sTlfi" """ 25.44 min.

173

1 f t100400-1 „„ Li 33 Ri i^ r

1 X -' ,1— " i-rur. 1 1 l_n

100 £00

AMPLE SPECTRUM CU«flLTERED>- l i e ^tioly I'Jl'.'bS oOSTCL Scan laSc:3pk' fib 1990. £5.44 min.

1SS£000-) "~~ j-100

j-j 44 SO 1«* [J, -- -' ;"". i : .i i ., . ij

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r i l o •>«;1'.1« 177 7-171. -7

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40- /\ f \- I \\ .

1 • •!-•—( — r •,--—.— f r2?5 .40

""File ->S1319 175. 7-176. 7

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'H / \A. ^ i / ',.. / V \'•^ , • • ' ' • 1 • ' • -£o .40

i

Oat3 F i l e : >S1319:":A6 Uuant Uutput F i l e : "vbi3iy::L?lname: 1U1U6B 6UBTLLMisc: 1LJL INJ GLSU592 1UUR/10ML " ' " . BIL..13-,uar, t iirne: 91U2'J1 :j'd :~2"3" ~~ _ Uuant ID I - l i e : 1U_BXA: : U!'injected at: 91U2U1 U/:27 " Cast Calibration: 9 ID 131 IB:23

_Grnpound tlo : 6U_ompound Mame: Anthracenezcan Number: 1BB2^ctention Time: 25 . 44 mi n".Juant Ion: 1/8.0A r e a: 1216Concentration: 1/2.IB ug/Lq-va 1 ue: 93 - . __

000053AR307U98

^ ^ '•"51103 -160 PPM BHfi SiD . Scan ££'0i1 ' ^•b £54904. GUB CO. 04 r,-, i;-,.

pnnnnrvi•! 7* .01 £00

150 -~-i _~~~ '-

100 POO

3PFOTRIIM < BOnKfiRnilNp SIIRTRflDTFn .

0-"=

Fiis ->S1319 -101068 60STCL Sc sp £252Bok fib 615. * "SUB"" " 29.27 min.

20c " ' I-I r'" . -'" (-100J

40oJ .. - .J [ !1 73 9b . ,„193 I PR? I I-l . •• x4? i ._ lJ ^-- ; . ^ t i --t- I

0-1 .,'..'. . * ? . . . . j ....'' , ' . . . . , . . .'"-O j100 £00 I

iuu.fa-iui.fa

1 ,1 i

IflHPLE SPECTRUM gj^LTTgCD .__ _ _ __ [File --S1319——99 .7-100 .7Tile .S1319 101068" tToST'cL ~~£can"~F25a | |

^lb •>46. £9.£7 min.| orj ;--i|55'7 I I " " . M I

1'-"-"-1 \ r100! i 1 ,' \ I\ 44 ,1 £S1 t 1 1 4CH i' \ I^ s- 96 14'? l?jl| --.). |j j | \ |

.iii . .1 £ .^ J i l l Ih. I i .. / \ I

Ua t a F i l e : > b 1519 : : A6 Uuant'Uutput F i l e : "SS1319 : : U1r.^rne: I'Jl U6B 6 UB I LLflisc: 1LJL INJ GCiiQy92 1U UK/ID ML . " tIiC.,13Uuant l i m e : 9102111 UB.-J23" - Uuant 1U h i i e : 1 U_UXR: : U IInjected at: 91U2U1 U/":"2/ " Cast C a l i b r a t i o n : 9IU131 IB : 23

Compound No: 65Compound r-.ame: Pyrenebean Number: 2252'- e t e n t i o n T i me : 29. 2 / rn.i n .Uuant Ion: 2U2.UArea: 1541 . . . . - - - -Concentration: 223.44 ug/Cq-^a iue : 76 -~ - - "

000054

Fi "ia ".i.103 160 PPH SNin STD Scan CD". -p — i. o u ~ino/r/-er r>,in *"i i r» ,. ; .L» p r. n u t_ u 7 D O *j • •_> »j u •_• i_ . j. .' tn i. > • *

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16

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File !'S131? 101068 608TCL Scan 2590BpU fib 5560." "" SUB"' 32.73 mm.

149

unnJ f r"10°~ ~ ~ \ 5 f ] n^^'l~/ 11- i , £,3,7 i.'. v .

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Ifit1Fl.E SPECTRUM: (U.lflLTERED. I Fi ie ;>£lo!9——£7i .Sr£7J_,9 IFile ,-£1319 101068 608TCL - - Scan £5901 | I IBpk fib 5707. __ 3£.78 ro in . j bUU^ ^ i •

149 i

j I 1-100) 4UI.I

4000-) 57j / 113. 1 I J * . .-'

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Data Fi l e : >S'l319::tt6 - Uuant Uutput I- l i e : "'=;i319 : : UlName: 1U1U6B 6U8TCLr.isc: 1CIL INJ GCS0592 .1UUH/1UML ~ " fclJu a n t V i me : 9 1 U 2 ill "U B : 2 3~" " Uuant 1 U h i i e : , U_oXft : : U Iinjected at: 91U201 07:27" Last Calibration: 9 1 U13 1 IB: 'Jj>

Compound No: /2Compound Name: b i s (. 2-fc.t hy 1 hexy i . ph t ha 1 a t ebean Number: 2590'-' e t e n t i o n T i rne : 32.78 rn i n .Uuant Ion: 149.0-irea: 1/B37Concen t ra t i on : 46/8 . '92 ug/La -va1ue: 97

000055

I.R3G75QG

. c. o i M i* u M rs. u ore. u i r. u 11 _™___„_________._ ^ ^ . . . _—rrr—--.. _..-—nn————z————__ . . i—i r i . 0 -).c;i T-I Qc ^ V-1 J- x v it-1-1 r i" n f. N M ^ i u '- c an £.' t. .31 i • - - - ------C p ^ WE) u_ • J i i' O i • O!_' D •-' "^ • '_• «_• m I i"i • i

149 . i j-1 '"""; ~" " ' - (..« ' ' - - -1EOOOOCH ; ri'""J I CUVH . . . .J ! I | : J ; ', / i' '13 ' 167 £61 ^-. 390 r I i \ i .1 w1' i t

n •-^- . , . , .TOO £00

l\ft )\/ Il'i J V 'in i ' i

. SPFCTRIIM .RQr:k'RRnii(.n s -r j ie >Si?19 101063 60STCL Sc an £86? i I 140-i | ]Bok ftb £03. 31 iR 35.66 ruin. I I • J i

143 || ..J /„ ^i 26" -

i 195 "-1 331-i. i / i " -.in n. . i 11 MI ,ir , jnJIM 1 1 1 ^ I ^.^.1! ,\ ,', ', . , , ,',', ,l, p , , J .^ , , , ,1-0 J

100 £00 300

r.PMF'LE SPECTRUM (. L>„.,L. i c.n c.u_/ ,File >S1319 101068 608TCL _- Scan £367i . | j|Bpk fib ££09. 35.66 mm. I J

£07 - -'-" '-

"i { tb 1 7 [ 341.i.i i r'. • ., . * I f . 1 ."-"'."?','; .".'.'. .'. ..'!'.'.'. ... .. . ,'.'... . . .' .'. . . . .""-'

II2CHJ

Jl

Uata File: >~Bl3TyT: Fi6 Uuant LJutput H i l e : /'1bl319::UlName: 1U1U6B 6UBTLL"Misc: 1CIC INJ GCSO'592 "" IIIGR/TOML B!L*13Uiuant .ime: 91U2CT1 OB:23_.._ ..LJuant 1U 1 - i l e : i U_=:Xr.: : U !injected at: 91U201 07.: 2 / Cast' Ca 1 i b r a t i on : . 9 i U 13 1 IB: 23

Compound No: 74 -Compound Name: Di-n-octy1phtha 1 ateScan Number: 2B67He t e n t i o n T i me : 3 5 . 6 6 rn i n .Quant ion: 149.0ft r e a: 1113Concentration: 136.B7 ug/Cq-va iue : 100 ~ " ~ - ' "- " - •

000056ftR30750i

000057HR3075Q2

BCM

Standards Data

000058

8DPESTICIDE EVALUATION STANDARDS SUMMARY

. Name: BCM Contract:

a Code: BCM Case No.: 38191 SAS No.: SDG No.: S582A

strument ID: 0008 GC Column ID: CAP

;es of Analyses: 1/17/91 to 1/20/91

Evaluation Check for Linearity

PESTICIDE

AldrinEndrin4,4' -DDTDBC

CALIBRATIONFACTOREVAL MIX A

896400.855100.732500.869780.

CALIBRATIONFACTOREVAL MIX B

907500.919650.752150.886070.

CALIBRATIONFACTOREVAL MIX C

1027575.875400.788300.935565.

%RSD(</ =10.0%)

7.73.73.73.8

(1) If > 10.0% RSD, plot a standard curve and determine the ngfor each sample in that set from the curve.

Evaluation Check for 4,4'-DDT/Endrin Breakdown(percent breakdown expressed as total degradation)

1234567891011121314

INITIALEVAL MIX BEVAL MIX BEVAL MIX BEVAL MIX BEVAL MIX BEVAL MIX BEVAL MIX B

DATEANALYZED

1/17/911/18/911/18/911/18/911/19/911/19/911/20/91

TIMEANALYZED

17:206:15

14:5115:50

0:2621:13

5:50

ENDRIN

17.8715.5417.4915.9418.0819.8217.62

4,4' -DDT

.00

. 00

.00

.00

.00

.00

.00

COMBINED(2)

7.636.487.276.477.538.147.09

(2) See Form instructions.

000059

(i)

8DPESTICIDE EVALUATION STANDARDS SUMMARY

e: BCM Contract:

,ab Code: BCM Case No.: SAS No.: SDG No.: W586

instrument ID: 0008 GC Column ID: CAP

>ates of Analyses: 1/22/91 to 1/24/91

Evaluation Check for Linearity

PESTICIDE

AldrinEndrin4,4' -DDTDBC

CALIBRATIONFACTOREVAL MIX A

882900.842300.831400.1058320.

CALIBRATIONFACTOREVAL MIX B

953450.841950.792725.1060550.

CALIBRATIONFACTOREVAL MIX C

993125.888850.862700.1103290.

%RSD(</ =10.0%)

5.93.14.22.4

(1) If > 10.0% RSD, plot a standard curve and determine the ngfor each sample in that set from the curve.

Evaluation Check for 4,4'-DDT/Endrin Breakdown(percent breakdown expressed as total degradation)

1234567891011121314

INITIALEVAL MIX BEVAL MIX B

DATEANALYZED

1/22/911/23/91

TIMEANALYZED

13:583:36

ENDRIN

16.8919.75

4, 4 '-DDT

.00

.00

COMBINED(2)

6.587.70

2) See Form instructions.

009GGO

d)

HR307505

8EPESTICIDE EVALUATION STANDARDS SUMMARY

Evaluation of Retention Time Shift for Dibutylchlorendate




Dates of Analyses: 1/17/91 to 1/20/91

V. 1

v2v3v4v5. 6. 7* 8v 9.,10'11./12,13

- 14151617

V1819202122

V23V24-,25.26--27728-/ 29303132333435363738

EPASAMPLE NO.

EVALAEVALBEVALCINDAINDBTOXAPHEAR1016AR1221AR1232AR1242AR1248AR1254

. AR1260100617ZZZZZZZZZZZZZZZEVALBZZZZZZZZZZZZZZZZZZZZINDA2 —EVALBEVALB

/ 00608 RE. 00608MS RE/ 00608MSDRE100768 REINDB2ZZZZZZZZZZZZZZZZZZZZEVALBZZZZZZZZZZZZZZZ

LAB SAMPLEID

100617MB100069SPK100068DU37121

100608100619SPK100618DUP100768

100608100608SPK100618DUP100768

MBLANKSPKDUP100616

100770100687100638

DATEANALYZED

1/17/911/17/911/17/911/17/911/17/911/17/911/17/911/17/911/17/911/17/911/17/911/18/911/18/911/18/911/18/911/18/911/18/911/18/911/18/911/18/911/18/911/18/911/18/911/18/911/18/911/18/911/18/911/18/911/18/911/18/911/18/911/18/911/18/911/18/911/19/911/19/911/19/911/19/91

TIMEANALYZED

16:3717:2018:0318:4619:2920:1220:5521:3822:2123:0423:470:301:142:403:234:064:496:156:587:418:249:07

10:3314:5115:5016:3317:1617:5918:4220:0820:5121:3422:1723:430:261: 101:532:36

%D

.0

.1

.0

.0

.0

.0

.1

. 1

.2

.2

.2

.3

.4

.4

.5

.4

.5

.6

.6

.6

.7

.7

.71.01.11.01.21.21.31.31.31.41.41.41.51.51.51.6

*

i

* Values outside of QC limits (2.0% for packed columns,0.3% for capillary columns)

page l of 2 nnnric* SDOmcncAR3Q/DQ6



• Name: BCM Contract:

Code: BCM Case No.: 38191 SAS No.: SDG No.: S582



1234567891011121314151617181920212223724V2526272829303132333435363738

EPASAMPLE NO.

ZZZZZZZZZZINDA3ZZZZZZZZZZINDA4INDB4ZZZZZZZZZZZZZZZZZZZZZZZZZEVALBZZZZZZZZZZZZZZZINDA5ZZZZZZZZZZZZZZZEVALBZZZZZZZZZZINDA6 —INDB5 -

LAB SAMPLEID

100819100821

100823100825

MBLKSPKDUPMSPK100830

101072101254101073MB

MSPK101067101068

101074DUP101075SPK

DATEANALYZED

1/19/911/19/911/19/911/19/911/19/911/19/911/19/911/19/911/19/911/19/911/19/911/19/911/19/911/19/911/19/911/20/911/20/911/20/911/20/911/20/911/20/911/20/911/20/911/20/911/20/91

TIMEANALYZED

3:194:024:455:286:117:37

16:0217:3818:2119:0419:4720:3021:1321:5622:390:051:313:404:245:075:506:337:167:598:42

%D

1.61.61.61.61.71.72.22.52.22.2.0

2.52.72.62.72.82.9.0

3.03.23.23.23.33.33.3

*

****

******

*******


flR3075







/ 1, 2v 3V 4. 5v 6~ 7> 8v 9. 10. 11. 12• 13~ 1415

, 16. 17. 18v 19., 202122. 23242526

•J21-,2829303132333435363738

EPASAMPLE NO.

EVALAEVALBEVALCINDAINDBTOXAPHEAR1016AR1221AR1232AR1242AR1248AR1254AR1260MBLKSPKDUPMSPIKE100616EVALB100770ZZZZZZZZZZINDA2 —ZZZZZZZZZZZZZZZINDA4 —INDA5 ~Tmn n-

LAB SAMPLEID

MBLKSPKDUPMSPIKE100616

100770MBLANKSPK

DUPMSPIKE101072

t

DATEANALYZED

1/22/911/22/911/22/911/22/911/22/911/22/911/22/911/22/911/22/911/22/911/22/911/22/911/22/911/23/911/23/911/23/911/23/911/23/911/23/911/23/911/23/911/23/911/23/911/23/911/23/911/23/911/24/911/24/91i /aW^H—— Ij^l f _

TIMEANALYZED

13:1513:5814:4115:5616:3917:2218:0519:0019:4320:2621:0921:5222:350:010:441:272:102:533:364:196:287:117:548:509:33

11:2515:2016:05

%D

.0

.0

.1

.3

.2

.4

.5

.4

.4

.4

.4

.5

.7

.6

.6

.7

.6

.6

.7

.7

.7

.8

.7

.91.01.02.52.5

*

**


page 1 of 1&R3Q7508


«Name: BCM Contract:

Code: BCM Case No.: SAS No.: SDG No.: S582


COMPOUND

alpha-BHCbeta-BHCdelta-BHCgamma-BHC (LiHeptachlorAldrinHept. EpoxideEndosulfan I_Dieldrin4, 4 '-DDEfcdrinHfdosulfan II4 ,4 '-ODDEndo. sulfate4,4' -DDTMethoxychlorEndrin ketonea. Chlordaneg. ChlordaneToxapheneAroclor-1016Aroclor-1221Aroclor-1232Aroclor-1242Aroclor-1248Aroclor-1254Aroclor-1260


RT

11.9313.8715.3713.5414.8416.1618.42-19.7820.9820.7522.4223.1122.9024.8524.0327.6828.1519.7119.0723.2014.9610.9214.9816.2517.5921.6422.41

FWIIv

FROM

11.8113.7415.2113.4014.6916.0018.2419.5820.7720.5422.1922.8822.6724.6023.7927.4127.8619.5218.8822.9714.8110.8114.8316.0917.4121.4222.19

.Tmow

TO

12.0514.0115.5213.6814.9916.3218.6119.9821. 1920.9622.6423.3423 . 1225.1024.2727.9628.4319.9119.2623.4315. 1111.0315.1316.4117.7721.8622.63

CALIBRATIONFACTOR

916600.647750.815500.830900.1077400.952700.1087650.1097000.972750.874200.650750.945200.654550.802750.687625.423460.1166150.1158600.1101600.51172.257052.78012.116786.269992.172348.299976.247696.

DATE OF ANALYSIS 1/18/91TIME OF ANALYSIS 10:33EPA SAMPLE NO.(STANDARD) INDA2

RT

13.7415.0416.3518.6219.9921.18

23.29

24.2127.92

CALIBRATIONFACTOR

785000.1026950.910700.1028050.1062000.932800.

865450.

687925.448225.

QNTY/N


%D

5.54.74.45. 53.24. 1

8.4

.05.8

Under QNT Y/N: enter Y if quantitation was performed, N if not performed.%D must be less than or equal to 15.0% for quantitation, and less thanor equal to 20.0% for confirmation.

Note: Determining that no compounds were found above the CRQL is a form ofquantitation, and therefore at least one column must: meet the 15.0% criteria.

multicomponent analytes, the largest single peak that is characteristicthe component should be used to establish retention time and %D.entification of such analytes is based primarily on pattern recognition.

page 1 of & _. «r.«~~-- FORM IX PEST C-.JOU-.b4 a p O n Y§7n Bev'



Lab Code: BCM Case No.: SAS No.: SDG No.: S582


COMPOUND

alpha-BHCbeta-BHCdelta-BHCgamma-BHC (LiHeptachlorAldrinHept. EpoxideEndosulfan IDieldrin4, 4 '-DDEEndrinEndosulfan II4, 4 '-ODDEndo. sulfate4, 4 '-DDTMethoxychlorEndrin ketonea . Chlordaneg. ChlordaneToxapheneAroclor-1016Aroclor-1221Aroclor-1232_Aroclor-1242Aroclor-1248_Aroclor-1254Aroclor-1260_


RT

11.9313.8715.3713.5414.8416.1618.4219.7820.9820.7522.4223.1122.9024.8524.0327.6828.1519.7119.0723.2014.9610.9214.9816.2517.5921.6422.41

F.m

FROM

11.8113.7415.2113.4014.6916.0018.2419.5820.7720.5422.1922.8822.6724.6023.7927.4127.8619.5218.8822.9714.8110.8114.8316.0917.4121.4222.19

IT[DOW

TO

12.0514.0115.5213.6814.9916.3218.6119.9821.1920.9622.6423.3423.1225.1024.2727.9628.4319.9119.2623.4315.1111.0315.1316.4117.7721.8622.63

CALIBRATIONFACTOR

916600.647750.815500.830900.1077400.952700.1087650.1097000.972750.874200.650750.945200.654550.802750.687625.423460.1166150.1158600.1101600.51172.257052.78012.116786.269992.172348.299976.247696.


RT

14.2815.6016.9419.2220.5821.80

23.92

24.8028.73

CALIBRATIONFACTOR

864400.1119350.993000.1155700.1124450.1001200.

978700.

785500.514285.

QNTY/N


%D

4.03.94.26.32.52.9

3~!j

14.221.4



For multicomponent analytes, the largest single peak that is characteristic,of the component should be used to establish retention time and %D.Identification of such analytes is based primarily on pattern recognition.

page jf of pJL J FORM IX PEST non-f^8i7OOOOS5 AR3075I



Code: BCM Case No.: SAS No.: SDG No.: S582


•Lao

*

<

COMPOUND

alpha-BHCbeta-BHCdelta-BHCgamma-BHC (LiHeptachlorAldrinKept. EpoxideEndosulfan IDieldrin4, 4 '-DDEJSndrin^kdosulfan IIPf4'-DDDEndo. sulfate4,4' -DDTMethoxychlor_Endrin ketonea. Chlordaneg. ChlordaneToxapheneAroclor-1016Aroclor-1221Aroclor-1232Aroclor-1242Aroclor-1248_Aroclor-1254Aroclor-1260_


RT

11.9313.8715.3713.5414.8416.1618.4219.7820.9820.7522.4223.1122.9024.8524.0327.6828.1519.7119.0723.2014.9610.9214.9816.2517.5921.6422.41

Fwir>

FROM

11.8113.7415.2113.4014.6916.0018.2419.5820.7720.5422.1922.8822.6724.6023.7927.4127.8619.5218.8822.9714.8110.8114.8316.0917.4121.4222.19

ITfDOW

TO

12.0514.0115.5213.6814.9916.3218.6119.9821.1920.9622.6423.3423. 1225.1024.2727.9628.4319.9119.2623.4315.1111.0315.1316.4117.7721.8622.63

CALIBRATIONFACTOR

916600.647750.815500.830900.1077400.952700.1087650.1097000.972750.874200.650750.945200.654550.802750.687625.423460.1166150.1158600.1101600.51172.257052.78012.116786.269992.172348.299976.247696.

DATE OF ANALYSIS 1/20/91TIME OF ANALYSIS 8:42EPA SAMPLE NO.(STANDARD) INDB5

RT

12.6316. 1016.93

14.58

21.4923.20

23 . 6625.66

29.3320.4819.85

CALIBRATIONFACTOR

964500.877750.985600.

700400.

989000.722100.

770400.950250.

1312300.1235800.1226650.

QNTY/N


%D

5.235.520.9"

26.5

13.111.0

17.718.4

.06.7

11.4

Under QNT Y/N: enter Y if quantitation was performed, N if not performed.%D must be less than or equal to 15.0% for quantitation, and less thanor equal to 2-0.0% for confirmation.

Note: Determining that no compounds were found above the CRQL is a form ofquantitation, and therefore at least one column must meet the 15.0% criteria,

For multicomponent analytes, the largest single peak that is characteristiccomponent should be used to establish retention time and %D.

of such analytes is based primarily on pattern recognition.

page £ of J8J J ' FORM ix PEST QOOOS6 B 1/87 Rev,

fiR3Q75 I !





COMPOUND

alpha-BHCbeta-BHCdelta-BHC __gamma-BHC (LiHeptachlorAldrinKept. EpoxideEndosulfan IDieldrin4, 4 '-DDEEndrinEndosulfan II4,4' -ODDEndo. sulfate4,4' -DDTMethoxychlor_Endrin ketoneja. Chlordaneg. ChlordaneToxaphene\roclor-1016.roclor-1221,roclor-1232

, Aroclor-1242Aroclor-1248Aroclor-1254Aroclor-1260


RT

13.1615.1316.6414.8516.1617.5119.7821.1622.3722.0423.7924.4924.2026.2825.3629.5530.2421.0520.4124.6016.2613.0616.2516.2718.8820.6924.47

EWIN

FROM

13.0314.9816.4814.7016.0017.3419.5820.9522.1521.8223.5524.2423.9626.0225.1129.2529.9320.8420.2024.3516.1012.9316.0916.1118.6920.4824.23

.TTDOW

TO

13.3015.2816.8115.0016.3217.6919.9821.3722.6022.2624.0324.7324.4426.5525.6229.8430.5421.2620.6124.8516.4213.1916.4116.4319.0720.9024.71

CALIBRATIONFACTOR

811200.629850.814250.771500.1043400.931000.1045700.1070700.946450.881200.626800.944200.689175.1176375.731825.441790.1249000.1118550.1109800.57516.288640.60546.135884.269352.183468.320990.287706.


RT

14.9216.2517.6019.8721.2622.47

24.59

25.4629.72

CALIBRATIONFACTOR

746000.1053300.914400.1040250.1067800.961700.

953425.

735000.470825.

QNTY/N


%D

3.3.9

1.8.5.3

11.0

.46.6


Note: Determining that no compounds were found above the CRQL is a form ofquantitation, and therefore at least one column must meet the 15.0% criteria,

For multicomponent analytes, the largest single peak that is characteristicof the component should be used to establish retention time and %D.Identification of such analytes is based primarily on pattern recognition.

page 1 of 3 7 OOOOS7 I

AR307512 I


lame: BCM Contract:

LaTTCode: BCM Case No.: SAS No.: SDG No.: W586


COMPOUND

alpha-BHCbeta-BHCdelta-BHC __gamma-BHC ( LiHeptachlor __AldrinHept. EpoxideEndosulfan IDieldrin_4. 4 ' -DDEj Wrinj plosulfan II4,4'-DDDEndo. sulfate4,4' -DDTMethoxychlor_Endrin ketonea. Chlordaneg. ChlordaneToxapheneAroclor-1016Aroclor-1221Aroclor-1232Aroclor-1242Aroclor-1248_Aroclor- 12 54Aroclor-1260


RT

13.1615.1316.6414.8516.1617.5119.7821.1622.3722.0423.7924.4924.2026.2825.3629.5530.2421.0520.4124.6016.2613.0616.2516.2718.8820.6924.47

FWlh

FROM

13.0314.9816.4814.7016.0017.3419.5820.9522.1521.8223.5524.2423.9626.0225.1129.2529.9320.8420.2024.3516.1012.9316.0916.1118.6920.4824.23

ITroow

TO

13.3015.2816.8115.0016.3217.6919.9821.3722.6022.2624.0324.7324.4426.5525.6229.8430.5421.2620.6124.8516.4213.1916.4116.4319.0720.9024.71

CALIBRATIONFACTOR

811200.629850.814250.771500.1043400.931000.1045700.1070700.946450.881200.626800.944200.689175.1176375.731825.441790.1249000.1118550.1109800.57516.288640.60546.135884.269352.183468.320990.287706.


RT

15.3216.6618.0120.2721.6722.88

25.00

25.8730.33

CALIBRATIONFACTOR

746400.1119200.871750.1013000.1025650.948400.

1020075.

904350.666615.

QNTY/N


%D

3.37.36.43.14.2.2

8.0

23.650.9


Note: Determining thcit no compounds were found above the CRQL is a form ofquantitation, and therefore at least one column must meet the 15.0% criteria,

multicomponent analytes, the largest single peak that is characteristiche component should be used to establish retention time and %D.

ratification of such analytes is based primarily on pattern recognition.

page 2 of 3FORM IX PEST 000068

". -"• ••'-.• •¥i :-- •-.'.••.-•• *-v*-* • - Sil ' W9

PESTICIDE /PCB STANDARDS SUMMARY




COMPOUND

alpha-BHCbeta-BHCdelta-BHC __gamma-BHC (LiHeptachlorAldrinHept. EpoxideEndosulfan IDieldrin4,4' -DDEEndrinEndosulfan II4,4' -ODDEndo. sulfate4,4' -DDTMethoxychlor_Endrin ketonea. Chlordaneg. ChlordaneToxapheneAroclor-1016Aroclor-1221Aroclor-1232Aroclor-1242Aroclor-1248Aroclor-1254Aroclor-1260


RT

13.1615.1316.6414.8516.1617.5119.7821.1622.3722.0423.7924.4924.2026.2825.3629.5530.2421.0520.4124.6016.2613.0616.2516.2718.8820.6924.47

Fwn

FROM

13.0314.9816.4814.7016.0017.3419.5820.9522.1521.8223.5524.2423.9626.0225.1129.2529.9320.8420.2024.3516.1012.9316.0916.1118.6920.4824.23

ITmow

TO

13.3015.2816.8115.0016.3217.6919.9821.3722.6022.2624.0324.7324.4426.5525.6229.8430.5421.2620.6124.8516.4213.1916.4116.4319.0720.9024.71

Under QNT Y/N: enter Y if quantitat%D must be less than or equal to 15or equal to 20.0% for confirmation.

CALIBRATIONFACTOR

811200.629850.814250.771500.1043400.931000.1045700.1070700.946450.881200.626800.944200.689175.1176375.731825.441790.1249000.1118550.1109800.57516.288640.60546.135884.269352.183468.320990.287706.


RT

15.6117.1418.0120.9221.5622.55

24.32

24.7131.08

CALIBRATIONFACTOR

1180100.810800.789650.1055700.1108300.854400.

372875.

743050.326575.

QNTY/N


%D

53.022.315.21.03.5H60. •

1.526.1

ion was performed, N if not performed.. 0% for quantitation, and less than

»


For multicomponent analytes, the largest single peak that is characteristicof the component should be used to establish retention time and %D.Identification of such analytes is based primarily on pattern recognition.

page 3 of 3 . .FORM IX PEST no«-h^« 1/87

A R 30 7511.

mooCO

AR3075I5

DATA VALIDATION REPORT FOR

OCCIDENTAL CHEMICAL CORPORATION

INORGANIC ANALYSIS DATA

Samples Collected:

1/8/91, 1/9/91, and 1/10/91

J/0)e>e 3817 ILaboratory Order No. 38191

Chemical Analyses Performed By

BCM

June 20, 1991

ByTrillium, Inc.7A Grace's Drive

Coatesville, PA 19320

TRILLIUM1NC

HR3075I6

\ TRILLIUMINC.

EXECUTIVE SUMMARY

Validation of inorganic laboratory data was conductedgenerally in conformance with the checklist in SOP No. HW-2, (SOPRevision X) , Feb 1990, "Evaluation of Metals Data for the ContractLaboratory Program (CLP)," based on SOW 7/88, Rev. 2/89 as modifiedby USEPA Region III. This checklist is intended to evaluate dataon a technical basis rather than a contract compliance basis forchemical analyses conducted under the USEPA's Contract LaboratoryProgram (CLP) and assumes that the data package is presented inaccordance with the CLP requirements. In addition, the datapackage is assumed to represent the best efforts of the laboratoryand has already been subjected to adequate and sufficient qualityreview prior to submission for validation. As stated in thelaboratory case narrative, the laboratory report was based on the3/90 SOW, and, consequently, validation procedures were modifiedsomewhat to accommodate the new guidelines.

Results of analyses are reported by the laboratory as eitherqualified or unqualified. Unqualified results mean that thereported values may be used without reservations. Qualifiedresults indicate a non-routine (with respect to CLP procedures)situation occurred during the course of analysis. Variousqualifier codes associated with the numerical results are used bythe laboratory to denote specific information regarding theanalytical results. During the process of validation, laboratoryqualified and unqualified data are verified against supportingdocumentation. Based on the supporting documentation, qualifiercodes may be atdded, deleted, or modified by the data validator.Final -results are either qualified or unqualified. Unqualifiedresults still mean that the reported values may be used withoutreservations. Validator qualified results are annotated with thecodes shown the Glossary of Data Qualifier Codes (Inorganic) inaccordance with the USEPA Region III guidelines.

This data package was poorly presented with numerousinconsistencies arising primarily from poorly documentedactivities. The data package would not be able to withstandrigorous evaluation if the form and format of the report were aprimary factor in the scrutiny. The procedures used duringanalyses and in assembling the data package tended to circumventthe purposes of requiring a CLP reporting format. The data packagesuggests a disorganized approach to conducting analyses andassembling data packages.

Specific qualifications of data are summarized in Section XII- Overall Assessment.

HR3Q7517

TRILLIUMme.

GLOSSARY OF DATA QUALIFIER CODES (INORGANIC)

CODES RELATING TO IDENTIFICATION(confidence concerning presence or absence of compounds):

U - Not detected. The associated number indicatesapproximate sample concentration necessary to bedetected.

(NO CODE) - Confirmed identification.

B - Not detected substantially above the level reported inlaboratory or field blanks.

R - Unreliable result. Analyte may or may not be present inthe sample. Supporting data necessary to confirm result.

CODES RELATED TO OUANTITATION(can be used for both positive results and sample quantitationlimits):

J - Analyte present. Reported value may not be accurate orprecise.

K - Analyte present. Reported value may be biased high.Actual value is expected to be lower.

L - Analyte present. Reported value may be biased low.Actual value is expected to be higher.

[] - Analyte present. As values approach the IDL, thequantitation may not be accurate.

UJ - Not detected, quantitation limit may be inaccurate orimprecise or imprecise.

UL - Not detected, quantitation limit is probably higher.

OTHER CODES

Q - No analytical result.

AR3Q75I8

TRILLJUM INC.

Samples validated in this report are noted below:

Date ofClient ID Lab ID Collection

OXY-SW-1-SED 100608 1/8/91OXY-SW-2-SED 100609 1/8/91OXY-SW-3-SED 100610 1/8/91OXY-SW-4-SED 100611 1/8/91OXY-SW-5-SED 100612 1/8/91OXY-SW-6-SED 100613 1/8/91OXY-SW-6A-SED 100614 1/8/91RINSE BLANK 100616 1/8/91METHOD BLANK 100617 —————DUP 100608 100618 1/8/91SPIKE 100608 100619 1/8/91OXY-SW-7-SED 100683 1/9/91OXY-SW-8-SED 100684 1/9/91OXY-SW-9-SED 100685 1/9/91RINSE BLANK 100687 1/9/91OXY-SW-10-SED 100768 1/10/91RINSE BLANK 100770 1/10/91

TRILLIUM INC.

Inorganic Data Validation

for

Occidental Chemical Corporation

Samples Collected:

1/8/91, 1/9/91, and 1/10/91

Case Narrative

This group contained thirteen soil samples including oneduplicate and one matrix spike and four aqueous samples includingone method blank and three rinse blanks. All samples were analyzedfor total TAL metals.

Samples validated in this report are noted below:

Date ofClient ID Lab ID Collection

OXY-SW-1-SED 100608 1/8/91OXY-SW-2-SED 100609 1/8/91OXY-SW-3-SED 100610 1/8/91OXY-SW-4-SED 100611 1/8/91OXY-SW-5-SED 100612 1/8/91OXY-SW-6-SED 100613 1/8/91OXY-SW-6A-SED 100614 1/8/91RINSE BLANK 100616 1/8/91METHOD BLANK 100617 —————DUP 100608 100618 1/8/91SPIKE 100608 100619 r/8/91OXY-SW-7-SED 100683 1/9/91OXY-SW-8-SED 100684 1/9/91OXY-SW-9-SED 100685 1/9/91RINSE BLANK 100687 1/9/91OXY-SW-10-SED 100768 1/10/91RINSE BLANK 100770 1/10/91

Laboratory identification numbers, instead of the clientidentification numbers, were used on the Cover Sheet as well as theForm I' s. No direct correlations can be made between theidentifications on the chains of custody and the identifications onthe Cover Sheet or Form I's as required by the CLP. Thecorrelations were present, however, on p. 1 of the data package.

AR307520

TRILLIUIVLc.

Results for the method and rinse blanks were reported on theForm I's in units of ug/L.

The Form XIV's (analytical run logs) were generally notreflective of the actual run sequences. The run logs shouldindicate all samples in the order they were analyzed with samplesthat were not pertinent to the data package lined out (or replacedby Z's). However, in this data package, the raw data indicatedthat injections were made that were not shown on the correspondingrun logs. The sample designations in the run log for.selenium for1/30/91 did not correspond to the raw data. For example, the runlog listed the ICV and ICB as ICV2 and ICB2, respectively, althoughthese samples were labeled as ICV1 and ICB1, respectively, in theraw data. Also, the GCV's and CCB's for this analytical sequencebegan with CCV7 and CCB7 according to the run log although the rawdata began with CCVl and CCBI.

The run log for lead on 1/25/91 did not correspond to thesequence of samples in the raw data.

Although raw data on pp. 238-247, pp. 264-274, pp. 331-333,pp. 342-363, and pp. 394-427 were included in the data package, thedata were not included on the run logs nor did they contain anydata pertinent to these analyses.

flR30752|

TRILUUM,NC.

The areas reviewed during validation are listed below.

CLP Inorganics Data Validation

I. Holding Times

II. Calibrations

III. Blanks

IV. ICP Interference Check Sample

V. Laboratory Control Sample

VI. Duplicate Analysis

VII. Matrix Spike

VIII. Method of Standard Additions

IX. Serial Dilution

X. Sample Verification

XI. Other QC

XII. Overall Assessment

TRILUUM INC.

I. Holding Times

All metals analyses were conducted within acceptableholding times.

II. Calibrations

The run log for lead for 1/25/91 indicated that severalstandards were analyzed that were pertinent to this run.However, the raw data indicated that the results for some ofthese standards were voided. What was used to calibrate theinstrument was not clearly identified. AA lead data werequalified estimated.

III. Blanks

No metals calibration blanks had values above the CRDL'snor less than the negative CRDL's. However, some calibrationand preparation blanks yielded concentrations greater than theIDL or less than the negative IDL.

Calibration blanks were consistently negative for arsenicand thallium. Arsenic and thallium non-detect results werequalified as biased low.

The preparation blank for cadmium yielded a negativeresponse. Cadmium non-detects were qualified as biased low.

IV. ICP Interference Check Sample

Interference check sample results were satisfactory.

V. Laboratory Control Sample

Laboratory control sample results were satisfactory.

VI. Duplicate Analysis

Duplicate analyses for metals were satisfactory.

VII. Matrix Spike

flR3.Q7523

\ TRILLIUIVU

Matrix spike recoveries were out of acceptable limits forantimony (47%), arsenic (72%), barium (139%), manganese(222%), silver (54%), vanadium (132%), and zinc (146%). Post-digest spike recoveries were satisfactory except for barium(68%). All antimony, arsenic, and silver data were qualifiedas estimated low. All positive manganese data were rejected.Positive vanadium and zinc data .were qualified as estimatedhigh. Barium data were qualified as estimated.

VIII. Method of standard Additions

No MSA analyses were conducted.

IX. Serial Dilution

Serial dilution results were out of acceptable limits forlead (30%) and nickel (16%) . The ICP results for lead andnickel were qualified as estimated.

X. Sample Verification

Calculations were performed correctly.

The matrix spike results for arsenic could not beverified in the raw data.

XI. Other QC

CRDL recoveries were out of acceptable limits for arsenic(54%, 42%, 42%), copper (71%, 61%), lead (54%(AA), 157%(ICP)),mercury (55%), selenium (131), silver (313%, 135%), and zinc(121%) . No qualifications of data were based on theserecoveries.

Post-digest spike recoveries for selenium in SW-2-SED,SW-4-SED, SW-6-SED, SW-6A-SED, SW-7-SED, SW-8-SED, andSW-9-SED were out of the acceptable limits. Selenium resultsfor these samples were qualified as biased low.

8

\TRILL1UM ,

XII. Overall Assessment

The data package itself was poorly presented withnumerous inconsistencies arising primarily from poorlydocumented activities. The data package would not be able towithstand rigorous evaluation if the form and format of thereport were a primary factor in the scrutiny. The proceduresused during analyses and in assembling the data package tendedto circumvent the purposes of requiring a CLP reportingformat.

Metals data for Laboratory Order No. 38191 wereconsidered valid with the following exceptions:

Arsenic and thallium nori-detect results were qualified asbiased low due to calibration blank readings.

AA lead data were qualified estimated due to theinability to verify calibration.

Cadmium non-detects were qualified as biased low due topreparation blank results.

All barium results were qualified estimated due to matrixspike and post-digest spike recoveries.

Due to matrix spike results, all antimony, arsenic, andsilver data were qualified as estimated low. All positivemanganese data were rejected. Positive vanadium and zinc datawere qualified as estimated high.

Selenium results in SW-2-SED, SW-4-SED, SW-6-SED,SW-6A-SED, SW-7-SED, SW-8-SED, and SW-9-SED were qualified asbiased low due to post-digest spike recoveries.

The ICP results for lead and nickel were qualified asestimated due to serial dilution comparisons.

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