10781 outline remediation strategy report rev...
TRANSCRIPT
Intégral Géotechnique
Persimmon Homes East Wales PHASE 7, FORMER AVESTA STEELWORKS, SEBASTOPOL Reclamation & Remediation Strategy Report Rev B 10781/TD/12/RRSR/RevB
Integral Géotechnique
CLIENT: Persimmon Homes East Wales
PROJECT: Phase 7, Former Avesta Steelworks, Sebastopol
TITLE: Reclamation & Remediation Strategy Report RevB
JOB NO: 10781
DOCUMENT REF: 10781/TD/12/RRSR/RevB
Revision Purpose Description Originated Reviewed Authorised Date
0 Final TD RB HP Feb ‘12
A Final RB TD HP Nov ‘12
B Final RB TD HP Jan ‘13
Geotechnical Engineers:
Intégral Géotechnique (Wales) Limited
Integral House
7 Beddau Way
Castlegate Business Park
Caerphilly
CF83 2AX
Tel: 029 2080 7991
Fax: 029 2086 2176
CONTENTS
1.0 INTRODUCTION
1.1 General
1.2 Proposed Development
2.0 BACKGROUND
2.1 Site Location and Description
2.2 Available Site Investigation Data
2.3 Conceptual Site Model
2.4 Site Specific Risk Assessment
3.0 OUTLINE RECLAMATION AND REMEDIATION STRATEGY
4.0 RECLAMATION AND REMEDIATION IMPLEMENTATION
4.1 Objectives
4.2 Methodology
4.3 Operations
5.0 RECLAMATION AND REMEDIATION VERIFICATION and VALIDATION
5.1 Report Objectives
5.2 Remediation Verification Methodology and Data Gathering Requirements
5.3 Validation
APPENDICES
Appendix A Environment Agency Correspondence
Appendix B Risk Assessment Results & Model Settings
Appendix C Soil Guideline Values for Capping Materials
Appendix D Concrete Cap Design
Appendix E Leachate Remedial Targets
FIGURES
Figure 1 Site Location
Figure 2 Site Phasing Plan
Figure 3 Proposed Development Layout
Figure 4 Existing Shaft and Pit Location Plan - School Site Overlay
Figure 5A Existing Shaft and Pit Sections – General Overlay
Figure 5B Existing Shaft and Pit Sections – Long Sections
Figure 5C Steelworks Processing Locations
Figure 6 Conceptual Model
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1.0 INTRODUCTION
1.1 GENERAL
Under a planning agreement with Torfaen County Borough Council, Persimmon Homes
East Wales are preparing a part of the site, Phase 7, of the Former Avesta Steelworks,
Sebastopol, near Cwmbran, see Figure 1.
Phase 7 is currently allocated for a school, Phases 5 and 6 are currently being
redeveloped for residential use.
Intégral Géotechnique (Wales) Limited have been appointed by Persimmon Homes as
the Geotechnical Engineers to design and prepare a reclamation and remediation
strategy for the Phase 7 works to be carried out at the site. The phasing of the site
remediation/reclamation works is illustrated on Figure 2.
The remediation strategy has been designed based on the findings of a Desk Study
(Reference 9201/HP/05) dated July 2005, and subsequent Site Investigation Reports
Reference 9201/RB/06, 10677/RB/10/FR dated December 2006 and 10677/RB/10/SI
dated November 2010 respectively. The site investigation dated December 2006 also
referenced a number of other investigations that have been carried out across the site.
These reports form the basis of the following Reclamation and Remediation Strategy
Report produced by Intégral Géotechnique (Wales).
In order to gain a full and detailed appraisal of the site, this Report should be read in
conjunction with the previous reports listed above.
Intégral Géotechnique (Wales) Limited have also been appointed by Persimmon Homes
East Wales as the Geotechnical Engineers to supervise and validate the implementation
of the previously agreed reclamation and remediation works for the Phase 5 and 6 areas
of the development, as discussed in our Outline Remediation Strategy Report No.
10677/HP/10/RSR dated December 2010.
The following Reports prepared by Intégral Géotechnique (Wales) Limited as a result of
the supervision, testing and execution of the reclamation and remediation works carried
out to date in accordance with the Outline Remediation Strategy have been submitted to
the regulators; 10620/TD/10 Phase 5 Remediation and Reclamation Validation Report
dated October 2010 and 10781/TD/11/VAL6a/RevB Phase 6A Former Avesta
Steelworks, Sebastopol dated September 2012.
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1.0 INTRODUCTION (CONTINUED)
During the Phase 6 reclamation works, groundwater and soils remediation and validation
was undertaken by a specialist sub-contractor and reported separately. Reference
should be made to the Former Avesta Steelworks, Sebastopol, Groundwater Validation
Report, Reference 10781/RB/11/GW, dated December 2011, prepared by Intégral
Géotechnique (Wales) Limited, which includes a copy of the sub-contractors validation
report. It should be noted that this groundwater validation report covers the entire Avesta
2 site, i.e. Phases 5, 6 and 7 in their entirety.
The Groundwater Validation Report, ref: 10781/RB/11/GW has also been submitted to
the Planning Department of the Torfaen County Borough Council for approval by the
Local Authority’s Environmental Health Department and the Environment Agency.
It is intended to prepare a reclaimed plateau, at or about the existing site levels, to a
standard suitable for raft/pad foundations with a minimum depth clear of obstructions of
2m, with residual contamination levels suitable for routine subsequent capping works.
Completion works for the development, such as filling to final levels, building works,
infrastructure and externals including sourcing and placing of clean inert soils to soft
landscape areas will be by others with a requirement for independent third party
supervision and validation.
1.2 PROPOSED DEVELOPMENT
The proposed development scheme for Phase 7 of the Avesta steelworks site comprises
a school building, associated roads and parking and external sports/play facilities across
the whole of the Phase 7 area, the proposed layout of which is shown on Figure 3.
However, the planned reclamation works are designed to render the site suitable for
either the above scheme, or alternatively, residential development with soft finished
gardens suitable for vegetable growth and consumption.
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2.0 BACKGROUND
2.1 SITE LOCATION AND DESCRIPTION
The site is located in Sebastopol, approximately 3.0km south-south-east of Pontypool at a
National Grid Reference of ST 296 981, see Figure 1.
The greater Avesta 2 site is roughly rectangular in shape and occupies an area of
approximately 25 acres. The boundaries of the site are defined by recently remediated
development land formerly the northern extent of the steelworks to the north, open lower
lying ground and a gas meter house to the south. Avondale Road, Station Road, a
footpath and cycle track lie to the west and the Newport to Abergavenny railway line to
the east.
The Phase 5 area to the south of Phase 6, previously a landfill facility for steelworks
waste such as slag, has been the subject of large scale remediation and reclamation
works carried out and validated by Intégral Géotechnique between March 2010 and
October 2010 and is now under residential development.
Phases 6 and 7 areas of the site were predominantly developed as the Panteg Sheet and
Galvanising Works with various railway sidings serving the works. The Phase 7 area of
the works contained a number of deep pits in which steel was rolled. The locations of the
known shafts and pits were surveyed by Daren Oliver Civil Engineering Services prior to
infilling. See Figures 4, 5A and 5B for the known layouts and sections. Parts of the
galvanising works and acid baths were also present in this area of the site. The main
former processing areas of the site are shown in Figure 5C.
The northern boundary of the Phase 6 area is that defined by the boundary of the
residential housing site and the proposed primary school. Phase 6, at the time of writing,
is partially reclaimed with Phase 6A validated by Intégral Géotechnique, currently under
development by Persimmon Homes.
Phase 7 remediation/reclamation area of the Avesta development comprises the northern
part of Avesta 2, see Figure 2 and 3.
The majority of the Phase 7 area of the site is situated on relatively level ground at an
approximate existing elevation of 89m AOD. The plateau area falls via an embankment
to the eastern site boundary. The eastern boundary level, at its lowest, is set at
approximately 86m AOD.
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2.1 SITE LOCATION AND DESCRIPTION (CONTINUED)
At the time of the Phase 6/7 Site Investigation (reports 10677/RB/10/FR and
10677/RB/10/SI) the site was principally cleared of buildings associated with the former
production of steel products at the site. The demolition works having taken place in the
summer and autumn of 2010
The ground slabs to building and external hard standings were in place at the time of the
investigation. The pits and shafts associated with the steelworks were previously filled
with crushed demolition rubble in order to leave the site surface in a safe condition.
Prior to the temporary backfilling of the pits and shafts the concrete surfaces were
cleaned of residual oil contamination (which had built up since the earlier cleansing works
undertaken by Egan Waste) by Redwood Environmental.
2.2 AVAILABLE SITE INVESTIGATION DATA
Detailed site investigations have been carried out by Intégral Géotechnique. Four reports
have been prepared on behalf of Persimmon Homes:-
Intégral Géotechnique Outo Kumpu Panteg Steelworks, Sebastopol, Cwmbran – Avesta
2 Desk Study Report Ref 9201/HP/05 dated July 2005.
Intégral Géotechnique Outo Kumpu Panteg Steelworks, Griffithstown – Avesta 2 Site
Investigation Report No. 9201/RB/06 dated December 2006.
Intégral Géotechnique Avesta Phase 6 & 7 Preliminary Factual Report
No. 10677/RB/10/FR dated October 2010.
Intégral Géotechnique Outo Kumpu Panteg Steelworks, Griffithstown – Phase 6 and 7
Site Investigation Report No. 10677/RB/10/SI dated November
2010.
Soil Conditions Summary
A summary of the ground conditions encountered across the site during the site
investigation works is presented below in Table 1.
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2.2 AVAILABLE SITE INVESTIGATION DATA (CONTINUED)
TABLE 1 : SUMMARY OF GROUND CONDITIONS
Depth (m) Stratum
From To
G.L. 0.2/0.5 MADE GROUND: Reinforced concrete.
G.L./0.5 0.3/6.8 MADE GROUND: Very loose to loose/loose/medium dense
black/greyish brown/brown/dark brown gravelly sand of ash
with fragments of brick, slag, concrete and occasional clinker,
steel, timber, wire rope, occasional pockets of sandy clay.
0.3/6.8 3.8/8.2 Soft/firm/stiff grey/greyish yellow/reddish brown/mottled light
grey slightly sandy, slightly gravelly silty CLAY with
occasional cobbles. Gravel is sub angular to sub rounded
fine to coarse of sandstone, siltstone, mudstone and quartz.
Cobbles are sub angular of sandstone and quartz.
3.8/8.2 5.9/10.6 Medium dense, becoming dense reddish brown sandy sub
angular to sub rounded fine to coarse GRAVEL of sandstone,
siltstone and quartzite with occasional sub angular to sub
rounded cobbles of sandstone and quartzite.
Or
Medium dense to dense reddish brown gravelly SAND with
occasional cobbles. Gravel is sub angular to sub rounded
fine to coarse of sandstone, quartzite and siltstone. Cobbles
are sub angular to sub rounded of sandstone and quartzite.
5.9/10.6 >8.4/>16.0 Very weak to weak reddish brown MUDSTONE. Distinctly
weathered.
A number of shallow obstructions were encountered within the top 2m of made ground,
comprising concrete and brick floors, pits, brickwalls, foundations and culverts. A number
of redundant cables were also encountered, within cable ducts running through the made
ground. Large diameter (400mm) metal pipes were encountered in the western part of
the site (TP7(10)), running approximately north-south.
The site is known to be underlain by several culverts at varying depths. These culverts
themselves being a potential conduit for hydrocarbon contamination.
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2.2 AVAILABLE SITE INVESTIGATION DATA (CONTINUED)
The sides of excavations were mostly stable. Localised collapse occurred within the
made ground due to the removal of obstructions such as brick or concrete.
Shallow perched water was generally not encountered within the made ground in the trial
pits excavated across the site. A seepage was encountered at 1.8m depth in TP7(3) at
the base of the made ground, but a consistent perched water body was not encountered.
Groundwater was encountered within both the alluvial gravel deposits and in the
underlying bedrock. Alluvial groundwater was encountered within the boreholes at a
depth of between 3.5m and 8.2m below existing ground level. A bedrock aquifer was
encountered at a depth of typically 7.0m to 9.7m below existing ground level.
Our previous Site Investigation Reports No.9201/RB/06 and 10677/RB/10/SI identified
elevations of both metalliferous, polyaromatic hydrocarbons (PAH), petroleum
hydrocarbons (TPH), and PCB contaminants in the made ground deposits, with some
TPH and trichloroethene being identified within the alluvial groundwater at the site, which
would require remedial works in order to render the site acceptable for residential
development.
It should be noted that visual and olfactory evidence of the presence of hydrocarbon
contamination was typically not identified within the made ground deposits across the
site.
It is considered, given the nature of the shallow made ground present that relatively low
level contamination comprising metals and PAH will be wide spread with localised TPH
hot spots associated with the industrial processes undertaken at the site including the
transmission of lubricating oils and solvents.
The made ground materials are considered to be leachable however no significant
perched water body was encountered beneath the site. Alluvial groundwater was found
to contain some elevated concentrations of TPH, and trichloroethene (and its degradation
products). However the underlying bedrock aquifer did not appear to be significantly
impacted.
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2.2 AVAILABLE SITE INVESTIGATION DATA (CONTINUED)
As previously stated, during the Phase 6 reclamation works groundwater and soils
remediation and validation was undertaken by a specialist sub-contractor and reported
separately. Reference should be made to the Former Avesta Steelworks, Sebastopol,
Groundwater Validation Report (Reference 10781/RB/11/GW) dated December 2011,
which includes a copy of the sub-contractors validation report. This report validates
groundwater remediation for the entire Avesta 2 site, i.e. Phases 5, 6 and 7.
Note that the free phase hydrocarbon contamination reported at BH7(4) and BH6(2) in
our Site Investigation Report reference 10677/RB/10/SI of November 2010 has been
remediated and its validation included in the Subcontractor’s Validation Report.
For full details of the ground conditions at the site, reference should be made to the
engineering logs presented in Appendices A and B of our Preliminary Factual Report Ref.
10677/RB/10/FR dated October 2010.
2.3 CONCEPTUAL SITE MODEL
Based on the results of the contamination testing of the made ground and underlying
groundwater, the following potential contaminant sources were identified within the
shallow made ground and/or the underlying groundwater:
Metals/Inorganic (soils);
Polyaromatic Hydrocarbons (PAH) (soils);
Petroleum Hydrocarbons, VPH/EPH (soils and groundwater);
Polychlorinated Biphenyls, PCBs (soils); and
Chlorinated Hydrocarbons (groundwater).
The potential active pathways by which future end users (residents) and the wider
environment could be affected by the contaminant sources are listed below:
1.Dermal contact with soil and/or soil derived dust;
2.Ingestion of soil and/or soil attached to home-grown produce;
3.Ingestion of home-grown produce;
4.Inhalation of soil derived dust;
5.Inhalation of vapours – indoor and outdoor air (from soil and groundwater);
6.Migration of contaminants from made ground to groundwater; and
7.Transportation of contaminants within groundwater
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2.3 CONCEPTUAL SITE MODEL (CONTINUED)
It should be noted that although potential risks to groundwater (6 & 7 above) have been
identified above, these have been assessed, remediated and validated to the approval of
the regulators as detailed in our Groundwater Validation Report Ref. 10781/RB/11/GW
dated December 2011. Copies of correspondence from the EA are presented in
Appendix A.
A conceptual site model showing the contaminant sources and potentially active pollutant
pathways are shown on Figure 6.
The remediation works to be carried out at the site have been designed to address the
identified potentially active contaminant pathways (1-5) listed above and shown on
Figure 6.
2.4 SITE SPECIFIC RISK ASSESSMENT
A site specific risk assessment has been carried out to determine remediation criteria to
be applied during the remediation works. The risk assessment has been undertaken
assuming a residential end use, since this is considered the most conservative. All soft
landscaped areas are proposed to be capped by a minimum thickness of 600mm of clean
imported subsoil and topsoil resulting in a number of the potential pathways (1-4)
identified above in Section 2.3 being broken.
A risk assessment for the remaining active pathways, i.e. the inhalation of vapours from
soil and groundwater to indoor and outdoor air, Item 5 above, has been carried out by
using both the UK compliant CLEA Model and the RISC 5 modelling software package to
assess any residual risk to end users. The RISC 5 model has been edited to be UK
compliant by changing a number of input parameters to those used within the CLEA
Model, such as body weight, exposure duration, and typical building properties. The
contaminant toxicity has also been altered to be reflective of the use of reference doses
and tolerable daily intakes used within the CLEA Model. RISC 5 utilises the Johnson and
Ettinger model for indoor vapour intrusion, and the volatile emission rates calculated by
the unsaturated zone model for outdoor vapour exposure. A copy of the results and
model inputs and outputs are presented in Appendix B. The summary table also includes
maximum soil and groundwater concentrations recorded as part of the site investigation
works across the Phase 7 site area.
Comparison of the maximum soil and groundwater concentrations to the derived site
specific vapour inhalation screening values indicates that there are no elevated
concentrations, with the exception of trichloroethene in groundwater via the indoor air
vapour inhalation pathway.
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2.4 SITE SPECIFIC RISK ASSESSMENT (CONTINUED)
The risk assessment concludes that there would be no risk to end users from outdoor
vapour exposure providing no free phase hydrocarbon contamination was present within
the underlying soils and/or groundwater. Groundwater remediation to remove free phase
hydrocarbon contamination has been completed to the satisfaction of the Environment
Agency. Therefore, it is concluded that there is no residual risk to human health from
exposure to outdoor vapours from soil or groundwater. The results indicate a slight risk
via inhalation of indoor vapours and hence it is recommended that all buildings are
constructed to include a suitable vapour resistant membrane.
Based on the findings of the site specific risk assessment, and comparison to the post
remediation groundwater monitoring results, no further treatment of groundwater is
considered necessary.
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3.0 OUTLINE RECLAMATION AND REMEDIATION STRATEGY
Following various stages of investigation at Avesta (2) and after due consultations with
the Regulators, including the Environmental Health Department of Torfaen County
Borough Council and the Environment Agency, Intégral Géotechnique (Wales) Limited
prepared an Outline Remediation Strategy Report for Phases 5 and 6. The report was
considered by all parties and approved by the Regulators subject to the satisfactory
execution and validation of the works.
Under the following reclamation strategy it is proposed to prepare Phase 7 to the same
standards as Phases 5 and 6.
An earlier contract for demolition of the old steelworks buildings and superstructures was
carried out in 2008/2009 leaving behind internal and external concrete slabs, pits,
basements and other sub-structures.
Phase 7 reclamation works are intended to deal with those parts of the former steelworks
present below ground level as described above and as currently undertaken for Phases 5
and 6.
The top 2.0m of the pre-remediation made ground strata, but locally deepened to 4/5m to
remove where possible deeper basements and other sub-structures, will be excavated. If
original ground is encountered at less than 2m the general reduced dig will be terminated
on original ground. The arisings from the reduced dig will be screened to remove
unacceptable materials, such as timber and metal. Oversize material such as concrete
will be crushed to an acceptable size. The processed materials will be stockpiled for
subsequent re-use. During the excavation routine, sampling and testing for metals, semi-
metals, EPH/VPH and asbestos will be undertaken in order to successfully segregate
contaminated soils for on-site treatment.
A number of reinforced concrete pits, up to 16m deep and 3 to 4m in diameter, are known
to be present within the old steelworks buildings. As part of the earlier demolition contract
all known pits were backfilled with crushed concrete. During these works it is proposed to
reduce the deep pit walls by at least 4m below finished remediated plateau level and cap
the pits with a reinforced concrete transfer slab.
Potential materials affected by organic contamination such as petroleum
hydrocarbons/oils could be encountered, if so then these will be set aside for bio-
remediation.
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3.0 OUTLINE RECLAMATION AND REMEDIATION STRATEGY (CONTINUED)
Once the exposed formation has been approved, the reduced formation will need to be
brought up to the required remediation/reclamation levels with the processed site won
materials. Any shortfall should be made up with imported inert granular material. This
approved material will be compacted in layers and in accordance with the Department of
Transport (DTp) Specification for Highway Works.
Any localised perched groundwater encountered within the made ground materials would
need to be pumped out and removed off site. In this instance, permission would need to
be obtained from Welsh Water and the Environment Agency (EA) to discharge to a foul
sewer. Alternatively, the water could be treated prior to discharge to a surface water
sewer, again with permission from Welsh Water and the EA. Minor pockets of perched
water would be pumped and soaked into the site formation away from the excavation.
Following the groundwater remediation undertaken in conjunction with the Phase 6
remediation work, it is considered that other than localised pockets of unforeseen
perched contaminated groundwater, the site does not pose a risk to the wider
ecology/environment.
Redundant sewers found to contain contamination will be carefully cleaned prior to
excavation and removal. Live sewers may also be encountered which require cleaning
before, if necessary, diverting to newly constructed sewers.
Currently an oil arrestment plant is located at the far south-eastern corner of the Former
Avesta Steelworks connecting existing sewers and watercourses to Railway Stream
before exiting the site and joining the Afon llwyd some 200m south of the site. This
facility, which previously served as part of the environmental management of the
steelworks, has recently been refurbished and will be actively maintained as part of the
reclamation and remediation works.
During all works, groundwater monitoring will be undertaken from the existing network of
boundary monitoring wells. Additionally, monitoring will be continued of the upstream and
downstream organic compound concentrations within the Railway Stream.
Upon completion of the reclamation and remediation works, all remnant redundant
sewers and culverts from the site to the Railway stream will be disconnected.
Once the final culvert is removed, the oil arrestment plant will no longer treat waters from
the site and will be decommissioned.
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3.0 OUTLINE RECLAMATION AND REMEDIATION STRATEGY (CONTINUED)
The risk to future occupiers is considered to be from dermal contact and/or ingestion of
the made ground materials encountered beneath the old factory buildings. The final
remediation will have to break this potential pathway between source (made ground),
pathway (dermal contact and/or ingestion, dust inhalation) and receptors (future
occupiers).
The current gas risk assessment for the site indicates gas Characteristic Situation 1
which, in accordance with CIRIA 665, does not require any special precautions.
However, post remediation gas monitoring and risk assessment is proposed which will
provide finalised advice on residual ground gas risk remedial measures which may be
required.
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4.0 RECLAMATION AND REMEDIATION IMPLEMENTATION
4.1 OBJECTIVES
A remediation strategy is required in order to translate the findings and recommendations
as defined in the Site Investigation Report into a clear set of activities for the site.
The main objective of the proposed reclamation and remediation works is to render the
site suitable for use as a primary school. The required reclamation and remediation
activities defined by our Site Investigation Report Ref No. 10677/RB/10/SI in order to
achieve this objective are as follows:
To provide an engineered formation free from obstructions to a depth of at least
2m from the underside of foundations and suitable for the construction of
concrete raft type foundations/floor slabs. The site is to be returned to a level of
approximately 89.27m AOD;
Source removal by excavation and ex-situ remediation to the agreed site specific
remediation criteria of removal/treatment of all free phase hydrocarbon impacted
soils that may present a risk to human health via the inhalation of vapours;
Break any potential pathway between proposed site end users and made ground
deposits; and,
Removal of all redundant sewers and culverts.
4.2 METHODOLOGY
The removal of existing made ground material to typically 2m depth, locally up to
4/5m, followed by selection of suitable structural fill materials placed in a
controlled engineered manner (suitable layers, compacted to DTp Standards)
should ensure a prepared formation suitable for shallow services and an
appropriately designed reinforced concrete raft type foundation with a
characteristic applied working load of 50kN/m2 (average of less than 30kN/m2),
bearing onto the prepared remediated plateau.
Materials excavated from the site will be subject to screening and processing to
remove any unacceptable materials such as concrete, timber, etc. Granular
materials will be subject to crushing to a suitable grade (6F2) prior to materials
being approved for re-use at the site. All surplus deleterious and in-situ soft
materials will removed off-site. All acceptable excavated materials for re-use will
be stockpiled on site. The processing, sorting, crushing and removal of
unacceptable materials will result in a uniform/more consistent material suitable
for re-engineering.
Stockpiled suitable materials will be placed in layers and well compacted in
accordance with department of transport (DTp) Specification for Highway Works.
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4.0 RECLAMATION AND REMEDIATION IMPLEMENTATION (CONTINUED)
A potential exposure pathway has been identified in proposed soft landscaped
areas. Remediation is therefore required to sever the link between site end users
and made ground proven to be statistically contaminated with metalliferous,
polyaromatic hydrocarbon, petroleum hydrocarbons, and PCB contaminants.
Therefore, a capping system will be required in soft landscaping areas. The
capping system is to comprise a minimum of 600mm of imported clean inert
materials conforming to the DEFRA soil guideline values for residential
development with gardens. Depending on the results of validation testing on the
remediated plateau, a geotextile anti-dig/marker horizon, such as Terram Hi-Vis
Geotextile, or similar, should be placed between the remediated plateau and the
clean capping layer. A copy of the soil guideline values for residential
development with gardens to be used when screening the capping materials is
presented in Appendix C.
Any gross contamination identified outside of structures below 2m depth will be
excavated as best as reasonably practicable. Locally, excavations will be
extended to 4/5m depth to deal with residual obstructions and contaminated soils.
Structures/obstructions will be broken out and excavated to typically 4/5m depth.
Residual deep structures that remain will be capped by a concrete cap. Details of
the concrete cap design are presented in Appendix D.
As appropriate, quantitative risk assessments will be made and for those
contaminants of concern (COC), Generic Soil Assessment Criteria (GSACs) will
be established using the CLEA software version 1.06 for human health.
Remediation of contaminated soil shall comply with the derived GSACs. These
GSACs shall be agreed with the regulators, including the Local Authority’s
Environmental Health Officers and the Environment Agency.
Remediated soils will also need to meet the leachate remedial targets defined in
the Site Investigation Report ref. 10677/RB/10/SI, in order to ensure the
protection of groundwater quality. Provided that these remedial targets are met,
the potential risk to groundwater quality is deemed to be low. A copy of the
leachate remedial targets is presented in Appendix E.
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4.2 METHODOLOGY (CONTINUED)
Pending post remediation gas monitoring and risk assessment it is recommended
that the slab construction to building structures should allow for gas Characteristic
Situation 2 in accordance with CIRIA 665. Based on the results of the risk
assessment, and the past contaminative history, it is recommended all buildings
benefit from a suitable vapour resistant membrane. The use of a foil backed
vapour membrane, such as a Monarflex Reflex Super vapour barrier, or similar
equivalent, is recommended, with under floor venting. All joints and penetrations
of the floor slab should be sealed. The results of the risk assessment carried out
using the Johnson and Ettinger model for subsurface vapour intrusion indicate
that there is no residual risk to end users provided that a vapour barrier is
constructed within all buildings.
Reinforced concrete cast in situ floor slab (suspended, non-suspended or raft)
with at least 1200 g DPM.
Ground and surface water monitoring will be undertaken during the remediation
works to Phase 7 to verify conditions and provide reassurance that no adverse
effects arose because of the activities
Maintenance of the oil arrestment facility.
The site will be deemed remediated by the following active remedial measures:
Re-engineering of existing made ground materials.
Cleaning and removal of redundant sewers and culverts.
Capping of proposed landscaped areas with a clean and suitable engineered
cover system.
Localised remediation of hydrocarbon contaminated soils using bioremediation.
Incorporation of ground gas membranes within the construction of the proposed
buildings pending post remediation gas monitoring
Ground and surface water monitoring shows no adverse effects
Review of the methodologies will be a continuing process and subject to findings of the
proposed validation works, and if necessary quantitative risk assessments. The review of
these risk assessments will form the basis for any additional remedial works which may
be required.
PHASE 7 FORMER AVESTA STEELWORKS, SEBASTOPOL 10781/TD/12/RRSR/REV A
INTÉGRAL GÉOTECHNIQUE (WALES) LIMITED PAGE 16
4.3 OPERATIONS
The works in the Phase 7 area are to be undertaken as one operation. It is likely that
Persimmon Homes will appoint a specialist contractor experienced in brownfield
reclamation/remediation to undertake these works. The remediation works will be
undertaken under the supervision of Intégral Géotechnique (Wales) Limited.
Site preparation and operational constraints will be covered in the contractors method
statements, copies of which will be provided when available. These should include the
contractors proposals for controls and monitoring of dust, noise, vibrations and odour.
Site procedures for managing the remedial works in a manner that will not cause pollution
to controlled waters will be covered in the contractors method statements which will be
submitted in discharge of the Conditions of Planning.
The proposed remediation works required in the area of Phase 7 will be controlled by the
appropriate mobile treatment license held by the remediation contractor. The conditions
imposed under the planning process will be considered adequate to control the works.
Groundwater monitoring will to be undertaken during the construction phase to verify
conditions and provide reassurance that no adverse effects arose because of the
activities.
Should significant changes in groundwater quality be monitored during the remedial
works, such as the detection of free phase hydrocarbons, then further assessment will be
required in order to address the causes of such changes and the requirements, if any, for
remedial works. In any case a contingency plan will be in place for implementing the
following if deemed necessary, such as:
Groundwater encountered during the reclamation and remediation works that requires
treatment, will be pumped out and either treated on site before discharge under an
appropriate consent or tankered off site for subsequent treatment and disposal at a
suitable licensed facility.
Section 5 of this report gives details of the Verification Plan and Monitoring requirements
for the remediation and reclamation works.
PHASE 7 FORMER AVESTA STEELWORKS, SEBASTOPOL 10781/TD/12/RRSR/REV A
INTÉGRAL GÉOTECHNIQUE (WALES) LIMITED PAGE 17
5.0 RECLAMATION AND REMEDIATION VERIFICATION AND VALIDATION
5.1 REPORT OBJECTIVES
A remediation validation report is required to detail the data gathering requirements
necessary to demonstrate that the works meet the site remediation criteria.
5.2 REMEDIATION VERIFICATION METHODOLOGY AND DATA GATHERING REQUIREMENTS:
The reclaimed plateau will be verified by the following measures:
Re-engineering works:
Plate bearing tests and/or dynamic probing, typically at 25m centres, of the
prepared plateau.
Contamination:
Localised hydrocarbon bio-remediation will be confirmed by validation testing
upon completion of the remedial works to ensure that the agreed target level
is achieved and that the soil is suitable for re-use. This could be either a total
soil concentration or a leachate concentration, depending on which is
confirmed to be the risk driving pathway.
Grid sampling, typically at approximately 25m centres, of the prepared
plateau for laboratory chemical analysis (MCERTS), to comprise near surface
samples at approximately 0.00-0.50m and at depth, approximately 1.00-
1.50m, post analysis samples will be retained for 28 days. Samples that fail
the risk assessments for the site will in the first instance be re-tested. If on
re-test the sample still fails further risk assessments will be undertaken to
determine the appropriate action, such as the use of an anti-dig layer, in-
situ/ex-situ treatment or removal from site to a suitably licenced landfill facility
and replacement with clean imported fill.
Monitoring and analysis of groundwater and surface water conditions will be
required to assess the level of risk to controlled waters during site
reclamation works. Further assessment of the risks can be undertaken using
the Environment Agency P20 model, if required. Validation reports of this
data will be provided.
Incorporation of ground gas resistant membranes to be included within the
construction of the proposed buildings, subject to post remediation gas
monitoring and risk assessment. Post remediation gas monitoring will be
carried out in accordance with the requirements of CIRIA C682 and CIRIA
C665, as appropriate, and will include methane, oxygen, carbon dioxide and
volatile organic compounds.
PHASE 7 FORMER AVESTA STEELWORKS, SEBASTOPOL 10781/TD/12/RRSR/REV A
INTÉGRAL GÉOTECHNIQUE (WALES) LIMITED PAGE 18
5.3 VALIDATION:
The development will not be complete, in accordance with the reclamation
strategy for the site, until placement of the final 600mm (minimum thickness)
capping soils to soft finished areas. In order to validate these works a series
of hand dug pits will be excavated to confirm an adequate thickness of inert
soils are in place, a photographic record will be kept. The capping system is
to comprise imported clean inert materials conforming to the DEFRA soil
guideline values for residential development with gardens. Samples of
topsoil and subsoil will be taken for laboratory analysis, as above, at the rate
of approximately one in every five gardens.
Monitoring and validation of the final 600mm capping is typically late in works, usually on
a plot by plot basis and will be maintained until the completion of the development.
Reporting of the clean capping to garden areas will be submitted independently of the
reclamation works.
APPENDIX A
ENVIRONMENT AGENCY CORRESPONDENCE
APPENDIX B
RISK ASSESSMENT RESULTS &
MODEL SETTINGS
Avesta IG Screening ValuesIndoor Outdoor Inhalation of Vapours
10677
Indoor Vapour Outdoor Vapour Max Concentration Indoor Vapour Outdoor Vapour Max Concentrationmg/kg mg/kg mg/kg mg/l mg/l mg/l
TPH Aliphatic C5-C6 1.13E+02 4.80E+06 2.70E-01 20 >Sat 6.03E-01TPH Aliphatic C6-C8 3.72E+02 8.70E+06 3.00E-01 >Sat >Sat 1.70E+00TPH Aliphatic C8-C10 1.09E+02 1.14E+06 1.90E-01 0.44 >Sat <0.01TPH Aliphatic C10-C12 5.57E+02 2.57E+06 7.90E+00 0.28 >Sat 1.30E-02TPH Aliphatic C12-C16 4.69E+03 7.45E+06 1.00E+03 0.07 >Sat 6.20E-02TPH Aliphatic C16-C35 6.34E+13 6.34E+13 6.70E+03 >Sat >Sat 2.16E+00TPH Aliphatic C35-C44 6.34E+13 6.34E+13 1.90E+02 - - 2.20E-02TPH Aromatic C5-C7 1.04E+00 1.11E+04 1.20E-02 - - <0.01TPH Aromatic C7-C8 3.14E+03 1.93E+07 1.20E-02 53 >Sat <0.01TPH Aromatic C8-C10 1.94E+02 6.89E+05 0.00E+00 15 >Sat <0.01TPH Aromatic C10-C12 1.07E+03 1.62E+06 2.20E+00 >Sat >Sat <0.01TPH Aromatic C12-C16 1.19E+04 5.38E+06 2.90E+01 >Sat >Sat 4.70E-02TPH Aromatic C16-C21 NR NR 4.80E+02 >Sat >Sat 4.92E-01TPH Aromatic C21-C35 NR NR 3.60E+02 >Sat >Sat 4.37E-01TPH Aromatic C35-C40 NR NR 1.10E+02 - - <0.01Acenaphthene 2.05E+04 3.20E+07 3.70E-01 - - <0.00001Acenaphthylene 1.92E+04 3.05E+07 1.70E+00 - - 1.10E-05Anthracene 6.48E+05 3.60E+08 4.70E+00 - - 2.90E-05Benz[a]anthracene 4.61E+01 2.64E+03 1.00E+01 - - <0.00001Benzo[a]pyrene 1.46E+02 5.21E+02 7.20E+00 - - <0.00001Benzo[b]fluoranthene 7.35E+02 3.38E+03 1.50E+01 - - <0.00001Benzo[ghi]perylene 1.36E+04 4.35E+04 7.10E+00 - - <0.00001Benzo[k]fluoranthene 1.70E+03 5.62E+03 4.10E+00 - - <0.00001Chrysene 3.54E+02 3.35E+03 1.30E+01 - - <0.00001Dibenz[ah]anthracene 6.59E+01 5.83E+02 1.30E+00 - - <0.00001Fluoranthene 1.70E+05 3.09E+07 4.60E+01 - - 5.20E-05Fluorene 2.58E+04 2.85E+07 1.70E+00 - - 1.71E-04Indeno[123-cd]pyrene 3.67E+02 1.88E+03 9.20E+00 - - <0.00001Naphthalene 9.28E+00 7.55E+04 1.30E+00 0.88 >Sat 2.51E-04Phenanthrene 3.03E+04 1.53E+07 4.90E+01 >Sat >Sat 1.70E-05Pyrene 3.89E+05 7.03E+07 1.60E+01 - - 6.00E-05Phenol 2.47E+03 1.13E+06 8.50E-01 >Sat >Sat 5.00E-03Trichloroethene 5.11E-01 4.79E+04 1.60E-02 0.54 >Sat 1.88E+001,2-Dichloroethane 1.60E-02 1.27E+03 <0.0058 - - <0.001Vinyl Chloride 1.07E-03 5.05E+02 <0.0058 0.035 230 9.70E-03Cis-1,2 Dichloroethene 3.93E-01 4.22E+04 7.70E-03 >Sat >Sat 3.01E+00
>Sat - Saturated concentration has been exceeded.
DeterminandSoil Groundwater
Integral Geotechnique)
CLEA v1.06 Software PAH & VOCs INDOOR VAPOUR
CLEA Software Version 1.06 Page 1 of 5
Report generated
Report title
Created by
BASIC SETTINGS
Land Use Residential with homegrown produce
Building Small terraced houseReceptor Female (res) Start age class 1 End age class 6 Exposure Duration 6 yearsSoil Sandy loam
Exposure Pathways Direct soil and dust ingestion Dermal contact with indoor dust Inhalation of indoor dust Consumption of homegrown produce Dermal contact with soil Inhalation of soil dust Soil attached to homegrown produce Inhalation of indoor vapour
Inhalation of outdoor vapour
Avesta
RB at Integral Geotechnique
03/07/2012
CLEA v1.06 Software PAH & VOCs INDOOR VAPOUR
CLEA Software Version 1.06 Report generated Page 2 of 5
Land Use
Exposure Frequencies (days yr-1) Occupation Periods (hr day-1)
Age Class
1 180 180 180 180 365 365 23.0 1.0 0.06 1.00 0.102 365 365 365 365 365 365 23.0 1.0 0.06 1.00 0.103 365 365 365 365 365 365 23.0 1.0 0.06 1.00 0.104 365 365 365 365 365 365 23.0 1.0 0.06 1.00 0.105 365 365 365 365 365 365 19.0 1.0 0.06 1.00 0.106 365 365 365 365 365 365 19.0 1.0 0.06 1.00 0.107 0 0 0 0 0 0 0.0 0.0 0.00 0.00 0.008 0 0 0 0 0 0 0.0 0.0 0.00 0.00 0.009 0 0 0 0 0 0 0.0 0.0 0.00 0.00 0.0010 0 0 0 0 0 0 0.0 0.0 0.00 0.00 0.0011 0 0 0 0 0 0 0.0 0.0 0.00 0.00 0.0012 0 0 0 0 0 0 0.0 0.0 0.00 0.00 0.0013 0 0 0 0 0 0 0.0 0.0 0.00 0.00 0.0014 0 0 0 0 0 0 0.0 0.0 0.00 0.00 0.0015 0 0 0 0 0 0 0.0 0.0 0.00 0.00 0.0016 0 0 0 0 0 0 0.0 0.0 0.00 0.00 0.0017 0 0 0 0 0 0 0.0 0.0 0.00 0.00 0.0018 0 0 0 0 0 0 0.0 0.0 0.00 0.00 0.00
3-Jul-12
Dire
ct s
oil i
nges
tion
rate
(g
day
-1)
Inha
latio
n of
dus
t an
d va
pour
, ind
oor
Inha
latio
n of
dus
t an
d va
pour
, out
door
Residential with homegrown produce
Soil to skin adherence factors (mg cm2)
Indo
or
Out
door
Indo
ors
Dire
ct s
oil i
nges
tion
Con
sum
ptio
n of
ho
meg
row
n pr
oduc
e
Der
mal
con
tact
with
in
door
dus
t
Der
mal
con
tact
with
so
il
Out
door
s
CLEA v1.06 Software PAH & VOCs INDOOR VAPOUR
CLEA Software Version 1.06 Report generated Page 3 of 5
Receptor Female (res)
Max exposed skin factor Consumption rates (g FW kg-1 BW day-1)
Age Class
1 5.60 0.7 8.5 0.32 0.26 3.43E-01 7.12 10.69 16.03 1.83 2.23 3.822 9.80 0.8 13.3 0.33 0.26 4.84E-01 6.85 3.30 5.46 3.96 0.54 11.963 12.70 0.9 12.7 0.32 0.25 5.82E-01 6.85 3.30 5.46 3.96 0.54 11.964 15.10 0.9 12.2 0.35 0.28 6.36E-01 6.85 3.30 5.46 3.96 0.54 11.965 16.90 1.0 12.2 0.35 0.28 7.04E-01 3.74 1.77 3.38 1.85 0.16 4.266 19.70 1.1 12.2 0.33 0.26 7.94E-01 3.74 1.77 3.38 1.85 0.16 4.267 22.10 1.2 12.4 0.22 0.15 8.73E-01 3.74 1.77 3.38 1.85 0.16 4.268 25.30 1.2 12.4 0.22 0.15 9.36E-01 3.74 1.77 3.38 1.85 0.16 4.269 27.50 1.3 12.4 0.22 0.15 1.01E+00 3.74 1.77 3.38 1.85 0.16 4.26
10 31.40 1.3 12.4 0.22 0.15 1.08E+00 3.74 1.77 3.38 1.85 0.16 4.2611 35.70 1.4 12.4 0.22 0.14 1.19E+00 3.74 1.77 3.38 1.85 0.16 4.2612 41.30 1.4 13.4 0.22 0.14 1.29E+00 3.74 1.77 3.38 1.85 0.16 4.2613 47.20 1.5 13.4 0.22 0.14 1.42E+00 3.74 1.77 3.38 1.85 0.16 4.2614 51.20 1.6 13.4 0.22 0.14 1.52E+00 3.74 1.77 3.38 1.85 0.16 4.2615 56.70 1.6 13.4 0.21 0.14 1.60E+00 3.74 1.77 3.38 1.85 0.16 4.2616 59.00 1.6 13.4 0.21 0.14 1.63E+00 3.74 1.77 3.38 1.85 0.16 4.2617 70.00 1.6 14.8 0.33 0.27 1.78E+00 2.94 1.40 1.79 1.61 0.22 2.9718 70.90 1.6 12.0 0.33 0.27 1.80E+00 2.94 1.40 1.79 1.61 0.22 2.97
Shr
ub fr
uit
Tree
frui
t
Roo
t veg
etab
les
Bod
y w
eigh
t (kg
)
3-Jul-12
Tube
r veg
etab
les
Her
bace
ous
fruit
Inha
latio
n ra
te
(m3 d
ay-1
)
Gre
en v
eget
able
s
Indo
or (m
2 m-2
)
Bod
y he
ight
(m)
Out
door
(m2 m
-2)
Tota
l ski
n ar
ea
(m2 )
CLEA v1.06 Software PAH & VOCs INDOOR VAPOUR
CLEA Software Version 1.06 Report generated Page 4 of 5
Building Small terraced house Soil Sandy loam
2.80E+01 5.30E-015.00E-01 2.00E-01
4.80E+00 3.30E-01
0.00E+00 1.20E-01
3.10E+00 3.56E-031.50E-01 3.20E-01
1.21E+00
5.00E+01 Threshold value of wind speed at 10m (m s-1) 7.20E+00Empirical function (Fx) for dust model (dimensionless) 1.22E+00
2.83E+02
7.00E+006.00E+003.48E-02
5.12E-014.75E-086.42E-013.05E-08
3-Jul-12
Pressure difference (soil to enclosed space, Pa)
4.23E+02Floor crack area (cm2)
Foundation thickness (m)
Living space height (below ground, m)
Building footprint (m2)Living space air exchange rate (hr-1)
Living space height (above ground, m)
Dust loading factor (μg m-3)
Ambient soil temperature (K)
Residual soil water content (cm3 cm-3)
Saturated hydraulic conductivity (cm s-1)
Porosity, Total (cm3 cm-3)Porosity, Air-Filled (cm3 cm-3)
Porosity, Water-Filled (cm3 cm-3)
van Genuchten shape parameter m (dimensionless)
Bulk density (g cm-3)
Effective total fluid saturation (unitless)
Relative soil air permeability (unitless)Intrinsic soil permeability (cm2)
Effective air permeability (cm2)
Soil pHSoil Organic Matter content (%)
Fraction of organic carbon (g g-1)
CLEA v1.06 Software PAH & VOCs INDOOR VAPOUR
CLEA Software Version 1.06 Report generated Page 5 of 5
Soil - Vapour Model Air Dispersion Model
0 Mean annual windspeed at 10m (m s-1) 5.00Depth to top of source (beneath building) (cm) 65 2400.00
Default soil gas ingress rate? Yes 0.00
2.50E+01 Fraction of site cover (m2 m-2) 0.75
1.87E+04 * Air dispersion factor in g m-2 s-1 per kg m-3
Averaging time surface emissions (yr) 6Finite vapour source model? NoThickness of contaminated layer (cm) 200
Soil - Plant ModelAverage High
g DW g-1 FW dimensionless g g-1 DW dimensionless0.096 0.05 0.33 1.00E-03 2.00E-010.103 0.06 0.40 1.00E-03 1.00E+000.210 0.02 0.13 1.00E-03 1.00E+000.058 0.06 0.40 1.00E-03 6.00E-010.166 0.09 0.60 1.00E-03 6.00E-010.157 0.04 0.27 1.00E-03 6.00E-01
Gardener type Average
Dry weight conversion factor
Preparation correction factor
Soil gas ingress rate (cm3 s-1)
Depth to top of source (no building) (cm)
Air dispersion factor at height of 1.6m *
3-Jul-12
Building ventilation rate (cm3 s-1)
Tree fruitShrub fruit
Green vegetablesRoot vegetablesTuber vegetables
Air dispersion factor at height of 0.8m *
Herbaceous fruit
Soil loading factor
Homegrown fraction
CLEA v1.06 Software PAH & VOCs OUTDOOR VAPOUR
CLEA Software Version 1.06 Page 1 of 5
Report generated
Report title
Created by
BASIC SETTINGS
Land Use Residential with homegrown produce
Building Small terraced houseReceptor Female (res) Start age class 1 End age class 6 Exposure Duration 6 yearsSoil Sandy loam
Exposure Pathways Direct soil and dust ingestion Dermal contact with indoor dust Inhalation of indoor dust Consumption of homegrown produce Dermal contact with soil Inhalation of soil dust Soil attached to homegrown produce Inhalation of indoor vapour
Inhalation of outdoor vapour
Avesta
RB at Integral Geotechnique
03/07/2012
CLEA v1.06 Software PAH & VOCs OUTDOOR VAPOUR
CLEA Software Version 1.06 Report generated Page 2 of 5
Land Use
Exposure Frequencies (days yr-1) Occupation Periods (hr day-1)
Age Class
1 180 180 180 180 365 365 23.0 1.0 0.06 1.00 0.102 365 365 365 365 365 365 23.0 1.0 0.06 1.00 0.103 365 365 365 365 365 365 23.0 1.0 0.06 1.00 0.104 365 365 365 365 365 365 23.0 1.0 0.06 1.00 0.105 365 365 365 365 365 365 19.0 1.0 0.06 1.00 0.106 365 365 365 365 365 365 19.0 1.0 0.06 1.00 0.107 0 0 0 0 0 0 0.0 0.0 0.00 0.00 0.008 0 0 0 0 0 0 0.0 0.0 0.00 0.00 0.009 0 0 0 0 0 0 0.0 0.0 0.00 0.00 0.0010 0 0 0 0 0 0 0.0 0.0 0.00 0.00 0.0011 0 0 0 0 0 0 0.0 0.0 0.00 0.00 0.0012 0 0 0 0 0 0 0.0 0.0 0.00 0.00 0.0013 0 0 0 0 0 0 0.0 0.0 0.00 0.00 0.0014 0 0 0 0 0 0 0.0 0.0 0.00 0.00 0.0015 0 0 0 0 0 0 0.0 0.0 0.00 0.00 0.0016 0 0 0 0 0 0 0.0 0.0 0.00 0.00 0.0017 0 0 0 0 0 0 0.0 0.0 0.00 0.00 0.0018 0 0 0 0 0 0 0.0 0.0 0.00 0.00 0.00
3-Jul-12
Dire
ct s
oil i
nges
tion
rate
(g
day
-1)
Inha
latio
n of
dus
t an
d va
pour
, ind
oor
Inha
latio
n of
dus
t an
d va
pour
, out
door
Residential with homegrown produce
Soil to skin adherence factors (mg cm2)
Indo
or
Out
door
Indo
ors
Dire
ct s
oil i
nges
tion
Con
sum
ptio
n of
ho
meg
row
n pr
oduc
e
Der
mal
con
tact
with
in
door
dus
t
Der
mal
con
tact
with
so
il
Out
door
s
CLEA v1.06 Software PAH & VOCs OUTDOOR VAPOUR
CLEA Software Version 1.06 Report generated Page 3 of 5
Receptor Female (res)
Max exposed skin factor Consumption rates (g FW kg-1 BW day-1)
Age Class
1 5.60 0.7 8.5 0.32 0.26 3.43E-01 7.12 10.69 16.03 1.83 2.23 3.822 9.80 0.8 13.3 0.33 0.26 4.84E-01 6.85 3.30 5.46 3.96 0.54 11.963 12.70 0.9 12.7 0.32 0.25 5.82E-01 6.85 3.30 5.46 3.96 0.54 11.964 15.10 0.9 12.2 0.35 0.28 6.36E-01 6.85 3.30 5.46 3.96 0.54 11.965 16.90 1.0 12.2 0.35 0.28 7.04E-01 3.74 1.77 3.38 1.85 0.16 4.266 19.70 1.1 12.2 0.33 0.26 7.94E-01 3.74 1.77 3.38 1.85 0.16 4.267 22.10 1.2 12.4 0.22 0.15 8.73E-01 3.74 1.77 3.38 1.85 0.16 4.268 25.30 1.2 12.4 0.22 0.15 9.36E-01 3.74 1.77 3.38 1.85 0.16 4.269 27.50 1.3 12.4 0.22 0.15 1.01E+00 3.74 1.77 3.38 1.85 0.16 4.26
10 31.40 1.3 12.4 0.22 0.15 1.08E+00 3.74 1.77 3.38 1.85 0.16 4.2611 35.70 1.4 12.4 0.22 0.14 1.19E+00 3.74 1.77 3.38 1.85 0.16 4.2612 41.30 1.4 13.4 0.22 0.14 1.29E+00 3.74 1.77 3.38 1.85 0.16 4.2613 47.20 1.5 13.4 0.22 0.14 1.42E+00 3.74 1.77 3.38 1.85 0.16 4.2614 51.20 1.6 13.4 0.22 0.14 1.52E+00 3.74 1.77 3.38 1.85 0.16 4.2615 56.70 1.6 13.4 0.21 0.14 1.60E+00 3.74 1.77 3.38 1.85 0.16 4.2616 59.00 1.6 13.4 0.21 0.14 1.63E+00 3.74 1.77 3.38 1.85 0.16 4.2617 70.00 1.6 14.8 0.33 0.27 1.78E+00 2.94 1.40 1.79 1.61 0.22 2.9718 70.90 1.6 12.0 0.33 0.27 1.80E+00 2.94 1.40 1.79 1.61 0.22 2.97
Shr
ub fr
uit
Tree
frui
t
Roo
t veg
etab
les
Bod
y w
eigh
t (kg
)
3-Jul-12
Tube
r veg
etab
les
Her
bace
ous
fruit
Inha
latio
n ra
te
(m3 d
ay-1
)
Gre
en v
eget
able
s
Indo
or (m
2 m-2
)
Bod
y he
ight
(m)
Out
door
(m2 m
-2)
Tota
l ski
n ar
ea
(m2 )
CLEA v1.06 Software PAH & VOCs OUTDOOR VAPOUR
CLEA Software Version 1.06 Report generated Page 4 of 5
Building Small terraced house Soil Sandy loam
2.80E+01 5.30E-015.00E-01 2.00E-01
4.80E+00 3.30E-01
0.00E+00 1.20E-01
3.10E+00 3.56E-031.50E-01 3.20E-01
1.21E+00
5.00E+01 Threshold value of wind speed at 10m (m s-1) 7.20E+00Empirical function (Fx) for dust model (dimensionless) 1.22E+00
2.83E+02
7.00E+006.00E+003.48E-02
5.12E-014.75E-086.42E-013.05E-08
3-Jul-12
Pressure difference (soil to enclosed space, Pa)
4.23E+02Floor crack area (cm2)
Foundation thickness (m)
Living space height (below ground, m)
Building footprint (m2)Living space air exchange rate (hr-1)
Living space height (above ground, m)
Dust loading factor (μg m-3)
Ambient soil temperature (K)
Residual soil water content (cm3 cm-3)
Saturated hydraulic conductivity (cm s-1)
Porosity, Total (cm3 cm-3)Porosity, Air-Filled (cm3 cm-3)
Porosity, Water-Filled (cm3 cm-3)
van Genuchten shape parameter m (dimensionless)
Bulk density (g cm-3)
Effective total fluid saturation (unitless)
Relative soil air permeability (unitless)Intrinsic soil permeability (cm2)
Effective air permeability (cm2)
Soil pHSoil Organic Matter content (%)
Fraction of organic carbon (g g-1)
CLEA v1.06 Software PAH & VOCs OUTDOOR VAPOUR
CLEA Software Version 1.06 Report generated Page 5 of 5
Soil - Vapour Model Air Dispersion Model
0 Mean annual windspeed at 10m (m s-1) 5.00Depth to top of source (beneath building) (cm) 65 2400.00
Default soil gas ingress rate? Yes 0.00
2.50E+01 Fraction of site cover (m2 m-2) 0.75
1.87E+04 * Air dispersion factor in g m-2 s-1 per kg m-3
Averaging time surface emissions (yr) 6Finite vapour source model? NoThickness of contaminated layer (cm) 200
Soil - Plant ModelAverage High
g DW g-1 FW dimensionless g g-1 DW dimensionless0.096 0.05 0.33 1.00E-03 2.00E-010.103 0.06 0.40 1.00E-03 1.00E+000.210 0.02 0.13 1.00E-03 1.00E+000.058 0.06 0.40 1.00E-03 6.00E-010.166 0.09 0.60 1.00E-03 6.00E-010.157 0.04 0.27 1.00E-03 6.00E-01
Gardener type Average
Dry weight conversion factor
Preparation correction factor
Soil gas ingress rate (cm3 s-1)
Depth to top of source (no building) (cm)
Air dispersion factor at height of 1.6m *
3-Jul-12
Building ventilation rate (cm3 s-1)
Tree fruitShrub fruit
Green vegetablesRoot vegetablesTuber vegetables
Air dispersion factor at height of 0.8m *
Herbaceous fruit
Soil loading factor
Homegrown fraction
CLEA v1.06 Software VPH EPH INDOOR VAPOUR
CLEA Software Version 1.06 Page 1 of 5
Report generated
Report title
Created by
BASIC SETTINGS
Land Use Residential with homegrown produce
Building Small terraced houseReceptor Female (res) Start age class 1 End age class 6 Exposure Duration 6 yearsSoil Sandy loam
Exposure Pathways Direct soil and dust ingestion Dermal contact with indoor dust Inhalation of indoor dust Consumption of homegrown produce Dermal contact with soil Inhalation of soil dust Soil attached to homegrown produce Inhalation of indoor vapour
Inhalation of outdoor vapour
03/07/2012
Avesta TPH
RB at Integral Geotechnique
CLEA v1.06 Software VPH EPH INDOOR VAPOUR
CLEA Software Version 1.06 Report generated Page 2 of 5
Land Use
Exposure Frequencies (days yr-1) Occupation Periods (hr day-1)
Age Class
1 180 180 180 180 365 365 23.0 1.0 0.06 1.00 0.102 365 365 365 365 365 365 23.0 1.0 0.06 1.00 0.103 365 365 365 365 365 365 23.0 1.0 0.06 1.00 0.104 365 365 365 365 365 365 23.0 1.0 0.06 1.00 0.105 365 365 365 365 365 365 19.0 1.0 0.06 1.00 0.106 365 365 365 365 365 365 19.0 1.0 0.06 1.00 0.107 0 0 0 0 0 0 0.0 0.0 0.00 0.00 0.008 0 0 0 0 0 0 0.0 0.0 0.00 0.00 0.009 0 0 0 0 0 0 0.0 0.0 0.00 0.00 0.0010 0 0 0 0 0 0 0.0 0.0 0.00 0.00 0.0011 0 0 0 0 0 0 0.0 0.0 0.00 0.00 0.0012 0 0 0 0 0 0 0.0 0.0 0.00 0.00 0.0013 0 0 0 0 0 0 0.0 0.0 0.00 0.00 0.0014 0 0 0 0 0 0 0.0 0.0 0.00 0.00 0.0015 0 0 0 0 0 0 0.0 0.0 0.00 0.00 0.0016 0 0 0 0 0 0 0.0 0.0 0.00 0.00 0.0017 0 0 0 0 0 0 0.0 0.0 0.00 0.00 0.0018 0 0 0 0 0 0 0.0 0.0 0.00 0.00 0.00
Indo
ors
Dire
ct s
oil i
nges
tion
Con
sum
ptio
n of
ho
meg
row
n pr
oduc
e
Der
mal
con
tact
with
in
door
dus
t
Der
mal
con
tact
with
so
il
Out
door
s
Out
door
Indo
or
Residential with homegrown produce
Dire
ct s
oil i
nges
tion
rate
(g
day
-1)
Inha
latio
n of
dus
t an
d va
pour
, ind
oor
Inha
latio
n of
dus
t an
d va
pour
, out
door
Soil to skin adherence factors (mg cm2)
3-Jul-12
CLEA v1.06 Software VPH EPH INDOOR VAPOUR
CLEA Software Version 1.06 Report generated Page 3 of 5
Receptor Female (res)
Max exposed skin factor Consumption rates (g FW kg-1 BW day-1)
Age Class
1 5.60 0.7 8.5 0.32 0.26 3.43E-01 7.12 10.69 16.03 1.83 2.23 3.822 9.80 0.8 13.3 0.33 0.26 4.84E-01 6.85 3.30 5.46 3.96 0.54 11.963 12.70 0.9 12.7 0.32 0.25 5.82E-01 6.85 3.30 5.46 3.96 0.54 11.964 15.10 0.9 12.2 0.35 0.28 6.36E-01 6.85 3.30 5.46 3.96 0.54 11.965 16.90 1.0 12.2 0.35 0.28 7.04E-01 3.74 1.77 3.38 1.85 0.16 4.266 19.70 1.1 12.2 0.33 0.26 7.94E-01 3.74 1.77 3.38 1.85 0.16 4.267 22.10 1.2 12.4 0.22 0.15 8.73E-01 3.74 1.77 3.38 1.85 0.16 4.268 25.30 1.2 12.4 0.22 0.15 9.36E-01 3.74 1.77 3.38 1.85 0.16 4.269 27.50 1.3 12.4 0.22 0.15 1.01E+00 3.74 1.77 3.38 1.85 0.16 4.26
10 31.40 1.3 12.4 0.22 0.15 1.08E+00 3.74 1.77 3.38 1.85 0.16 4.2611 35.70 1.4 12.4 0.22 0.14 1.19E+00 3.74 1.77 3.38 1.85 0.16 4.2612 41.30 1.4 13.4 0.22 0.14 1.29E+00 3.74 1.77 3.38 1.85 0.16 4.2613 47.20 1.5 13.4 0.22 0.14 1.42E+00 3.74 1.77 3.38 1.85 0.16 4.2614 51.20 1.6 13.4 0.22 0.14 1.52E+00 3.74 1.77 3.38 1.85 0.16 4.2615 56.70 1.6 13.4 0.21 0.14 1.60E+00 3.74 1.77 3.38 1.85 0.16 4.2616 59.00 1.6 13.4 0.21 0.14 1.63E+00 3.74 1.77 3.38 1.85 0.16 4.2617 70.00 1.6 14.8 0.33 0.27 1.78E+00 2.94 1.40 1.79 1.61 0.22 2.9718 70.90 1.6 12.0 0.33 0.27 1.80E+00 2.94 1.40 1.79 1.61 0.22 2.97
Out
door
(m2 m
-2)
Tota
l ski
n ar
ea
(m2 )
Gre
en v
eget
able
s
Indo
or (m
2 m-2
)
Bod
y he
ight
(m)
Tube
r veg
etab
les
Her
bace
ous
fruit
Inha
latio
n ra
te
(m3 d
ay-1
)
3-Jul-12
Shr
ub fr
uit
Tree
frui
t
Roo
t veg
etab
les
Bod
y w
eigh
t (kg
)
CLEA v1.06 Software VPH EPH INDOOR VAPOUR
CLEA Software Version 1.06 Report generated Page 4 of 5
Building Small terraced house Soil Sandy loam
2.80E+01 5.30E-015.00E-01 2.00E-01
4.80E+00 3.30E-01
0.00E+00 1.20E-01
3.10E+00 3.56E-031.50E-01 3.20E-01
1.21E+00
5.00E+01 Threshold value of wind speed at 10m (m s-1) 7.20E+00Empirical function (Fx) for dust model (dimensionless) 1.22E+00
2.83E+02
7.00E+006.00E+003.48E-02
5.12E-014.75E-086.42E-013.05E-08Effective air permeability (cm2)
Soil pHSoil Organic Matter content (%)
Fraction of organic carbon (g g-1)
Bulk density (g cm-3)
Effective total fluid saturation (unitless)
Relative soil air permeability (unitless)Intrinsic soil permeability (cm2)
Ambient soil temperature (K)
Residual soil water content (cm3 cm-3)
Saturated hydraulic conductivity (cm s-1)
Porosity, Total (cm3 cm-3)Porosity, Air-Filled (cm3 cm-3)
Porosity, Water-Filled (cm3 cm-3)
van Genuchten shape parameter m (dimensionless)
Dust loading factor (μg m-3)
4.23E+02Floor crack area (cm2)
Foundation thickness (m)
Living space height (below ground, m)
Building footprint (m2)Living space air exchange rate (hr-1)
Pressure difference (soil to enclosed space, Pa)
Living space height (above ground, m)
3-Jul-12
CLEA v1.06 Software VPH EPH INDOOR VAPOUR
CLEA Software Version 1.06 Report generated Page 5 of 5
Soil - Vapour Model Air Dispersion Model
0 Mean annual windspeed at 10m (m s-1) 5.00Depth to top of source (beneath building) (cm) 65 2400.00
Default soil gas ingress rate? Yes 0.00
2.50E+01 Fraction of site cover (m2 m-2) 0.75
1.87E+04 * Air dispersion factor in g m-2 s-1 per kg m-3
Averaging time surface emissions (yr) 6Finite vapour source model? NoThickness of contaminated layer (cm) 200
Soil - Plant ModelAverage High
g DW g-1 FW dimensionless g g-1 DW dimensionless0.096 0.05 0.33 1.00E-03 2.00E-010.103 0.06 0.40 1.00E-03 1.00E+000.210 0.02 0.13 1.00E-03 1.00E+000.058 0.06 0.40 1.00E-03 6.00E-010.166 0.09 0.60 1.00E-03 6.00E-010.157 0.04 0.27 1.00E-03 6.00E-01
Gardener type Average
Air dispersion factor at height of 0.8m *
Herbaceous fruit
Soil loading factor
Homegrown fraction
Tree fruitShrub fruit
Green vegetablesRoot vegetablesTuber vegetables
3-Jul-12
Building ventilation rate (cm3 s-1)
Depth to top of source (no building) (cm)
Air dispersion factor at height of 1.6m *
Soil gas ingress rate (cm3 s-1)
Preparation correction factor
Dry weight conversion factor
CLEA v1.06 Software VPH EPH OUTDOOR VAPOUR
CLEA Software Version 1.06 Page 1 of 5
Report generated
Report title
Created by
BASIC SETTINGS
Land Use Residential with homegrown produce
Building Small terraced houseReceptor Female (res) Start age class 1 End age class 6 Exposure Duration 6 yearsSoil Sandy loam
Exposure Pathways Direct soil and dust ingestion Dermal contact with indoor dust Inhalation of indoor dust Consumption of homegrown produce Dermal contact with soil Inhalation of soil dust Soil attached to homegrown produce Inhalation of indoor vapour
Inhalation of outdoor vapour
03/07/2012
Avesta TPH
RB at Integral Geotechnique
CLEA v1.06 Software VPH EPH OUTDOOR VAPOUR
CLEA Software Version 1.06 Report generated Page 2 of 5
Land Use
Exposure Frequencies (days yr-1) Occupation Periods (hr day-1)
Age Class
1 180 180 180 180 365 365 23.0 1.0 0.06 1.00 0.102 365 365 365 365 365 365 23.0 1.0 0.06 1.00 0.103 365 365 365 365 365 365 23.0 1.0 0.06 1.00 0.104 365 365 365 365 365 365 23.0 1.0 0.06 1.00 0.105 365 365 365 365 365 365 19.0 1.0 0.06 1.00 0.106 365 365 365 365 365 365 19.0 1.0 0.06 1.00 0.107 0 0 0 0 0 0 0.0 0.0 0.00 0.00 0.008 0 0 0 0 0 0 0.0 0.0 0.00 0.00 0.009 0 0 0 0 0 0 0.0 0.0 0.00 0.00 0.0010 0 0 0 0 0 0 0.0 0.0 0.00 0.00 0.0011 0 0 0 0 0 0 0.0 0.0 0.00 0.00 0.0012 0 0 0 0 0 0 0.0 0.0 0.00 0.00 0.0013 0 0 0 0 0 0 0.0 0.0 0.00 0.00 0.0014 0 0 0 0 0 0 0.0 0.0 0.00 0.00 0.0015 0 0 0 0 0 0 0.0 0.0 0.00 0.00 0.0016 0 0 0 0 0 0 0.0 0.0 0.00 0.00 0.0017 0 0 0 0 0 0 0.0 0.0 0.00 0.00 0.0018 0 0 0 0 0 0 0.0 0.0 0.00 0.00 0.00
Indo
ors
Dire
ct s
oil i
nges
tion
Con
sum
ptio
n of
ho
meg
row
n pr
oduc
e
Der
mal
con
tact
with
in
door
dus
t
Der
mal
con
tact
with
so
il
Out
door
s
Out
door
Indo
or
Residential with homegrown produce
Dire
ct s
oil i
nges
tion
rate
(g
day
-1)
Inha
latio
n of
dus
t an
d va
pour
, ind
oor
Inha
latio
n of
dus
t an
d va
pour
, out
door
Soil to skin adherence factors (mg cm2)
3-Jul-12
CLEA v1.06 Software VPH EPH OUTDOOR VAPOUR
CLEA Software Version 1.06 Report generated Page 3 of 5
Receptor Female (res)
Max exposed skin factor Consumption rates (g FW kg-1 BW day-1)
Age Class
1 5.60 0.7 8.5 0.32 0.26 3.43E-01 7.12 10.69 16.03 1.83 2.23 3.822 9.80 0.8 13.3 0.33 0.26 4.84E-01 6.85 3.30 5.46 3.96 0.54 11.963 12.70 0.9 12.7 0.32 0.25 5.82E-01 6.85 3.30 5.46 3.96 0.54 11.964 15.10 0.9 12.2 0.35 0.28 6.36E-01 6.85 3.30 5.46 3.96 0.54 11.965 16.90 1.0 12.2 0.35 0.28 7.04E-01 3.74 1.77 3.38 1.85 0.16 4.266 19.70 1.1 12.2 0.33 0.26 7.94E-01 3.74 1.77 3.38 1.85 0.16 4.267 22.10 1.2 12.4 0.22 0.15 8.73E-01 3.74 1.77 3.38 1.85 0.16 4.268 25.30 1.2 12.4 0.22 0.15 9.36E-01 3.74 1.77 3.38 1.85 0.16 4.269 27.50 1.3 12.4 0.22 0.15 1.01E+00 3.74 1.77 3.38 1.85 0.16 4.26
10 31.40 1.3 12.4 0.22 0.15 1.08E+00 3.74 1.77 3.38 1.85 0.16 4.2611 35.70 1.4 12.4 0.22 0.14 1.19E+00 3.74 1.77 3.38 1.85 0.16 4.2612 41.30 1.4 13.4 0.22 0.14 1.29E+00 3.74 1.77 3.38 1.85 0.16 4.2613 47.20 1.5 13.4 0.22 0.14 1.42E+00 3.74 1.77 3.38 1.85 0.16 4.2614 51.20 1.6 13.4 0.22 0.14 1.52E+00 3.74 1.77 3.38 1.85 0.16 4.2615 56.70 1.6 13.4 0.21 0.14 1.60E+00 3.74 1.77 3.38 1.85 0.16 4.2616 59.00 1.6 13.4 0.21 0.14 1.63E+00 3.74 1.77 3.38 1.85 0.16 4.2617 70.00 1.6 14.8 0.33 0.27 1.78E+00 2.94 1.40 1.79 1.61 0.22 2.9718 70.90 1.6 12.0 0.33 0.27 1.80E+00 2.94 1.40 1.79 1.61 0.22 2.97
Out
door
(m2 m
-2)
Tota
l ski
n ar
ea
(m2 )
Gre
en v
eget
able
s
Indo
or (m
2 m-2
)
Bod
y he
ight
(m)
Tube
r veg
etab
les
Her
bace
ous
fruit
Inha
latio
n ra
te
(m3 d
ay-1
)
3-Jul-12
Shr
ub fr
uit
Tree
frui
t
Roo
t veg
etab
les
Bod
y w
eigh
t (kg
)
CLEA v1.06 Software VPH EPH OUTDOOR VAPOUR
CLEA Software Version 1.06 Report generated Page 4 of 5
Building Small terraced house Soil Sandy loam
2.80E+01 5.30E-015.00E-01 2.00E-01
4.80E+00 3.30E-01
0.00E+00 1.20E-01
3.10E+00 3.56E-031.50E-01 3.20E-01
1.21E+00
5.00E+01 Threshold value of wind speed at 10m (m s-1) 7.20E+00Empirical function (Fx) for dust model (dimensionless) 1.22E+00
2.83E+02
7.00E+006.00E+003.48E-02
5.12E-014.75E-086.42E-013.05E-08Effective air permeability (cm2)
Soil pHSoil Organic Matter content (%)
Fraction of organic carbon (g g-1)
Bulk density (g cm-3)
Effective total fluid saturation (unitless)
Relative soil air permeability (unitless)Intrinsic soil permeability (cm2)
Ambient soil temperature (K)
Residual soil water content (cm3 cm-3)
Saturated hydraulic conductivity (cm s-1)
Porosity, Total (cm3 cm-3)Porosity, Air-Filled (cm3 cm-3)
Porosity, Water-Filled (cm3 cm-3)
van Genuchten shape parameter m (dimensionless)
Dust loading factor (μg m-3)
4.23E+02Floor crack area (cm2)
Foundation thickness (m)
Living space height (below ground, m)
Building footprint (m2)Living space air exchange rate (hr-1)
Pressure difference (soil to enclosed space, Pa)
Living space height (above ground, m)
3-Jul-12
CLEA v1.06 Software VPH EPH OUTDOOR VAPOUR
CLEA Software Version 1.06 Report generated Page 5 of 5
Soil - Vapour Model Air Dispersion Model
0 Mean annual windspeed at 10m (m s-1) 5.00Depth to top of source (beneath building) (cm) 65 2400.00
Default soil gas ingress rate? Yes 0.00
2.50E+01 Fraction of site cover (m2 m-2) 0.75
1.87E+04 * Air dispersion factor in g m-2 s-1 per kg m-3
Averaging time surface emissions (yr) 6Finite vapour source model? NoThickness of contaminated layer (cm) 200
Soil - Plant ModelAverage High
g DW g-1 FW dimensionless g g-1 DW dimensionless0.096 0.05 0.33 1.00E-03 2.00E-010.103 0.06 0.40 1.00E-03 1.00E+000.210 0.02 0.13 1.00E-03 1.00E+000.058 0.06 0.40 1.00E-03 6.00E-010.166 0.09 0.60 1.00E-03 6.00E-010.157 0.04 0.27 1.00E-03 6.00E-01
Gardener type Average
Air dispersion factor at height of 0.8m *
Herbaceous fruit
Soil loading factor
Homegrown fraction
Tree fruitShrub fruit
Green vegetablesRoot vegetablesTuber vegetables
3-Jul-12
Building ventilation rate (cm3 s-1)
Depth to top of source (no building) (cm)
Air dispersion factor at height of 1.6m *
Soil gas ingress rate (cm3 s-1)
Preparation correction factor
Dry weight conversion factor
CLEA v1.06 Software PAH & VOCs OUTDOOR VAPOUR
CLEA Software Version 1.06 Page 1 of 11
Report generated
Report title
Created by
RESULTS
Avesta
RB at Integral Geotechnique
03-Jul-12
CLEA v1.06 Software PAH & VOCs OUTDOOR VAPOUR
CLEA Software Version 1.06 Report generated Page 2 of 11
Assessment Criterion (mg kg-1) Ratio of ADE to HCV 50% rule?
oral inhalation combined oral inhalation combined Oral Inhal
1 Acenaphthene NR 3.20E+07 3.20E+07 0.00 1.00 1.00 3.36E+02 (sol) No No2 Acenaphthylene NR 3.05E+07 3.05E+07 0.00 1.00 1.00 5.06E+02 (sol) No No3 Anthracene NR 3.60E+08 3.60E+08 0.00 1.00 1.00 6.96E+00 (vap) No No4 Benz[a]anthracene NR 2.64E+03 2.64E+03 0.00 1.00 1.00 1.03E+01 (sol) No No5 Benzo[a]pyrene NR 5.21E+02 5.21E+02 0.00 1.00 1.00 5.46E+00 (vap) No No6 Benzo[b]fluoranthene NR 3.38E+03 3.38E+03 0.00 1.00 1.00 7.29E+00 (sol) No No7 Benzo[ghi]perylene NR 4.35E+04 4.35E+04 0.00 1.00 1.00 9.23E-02 (vap) No No8 Benzo[k]fluoranthene NR 5.62E+03 5.62E+03 0.00 1.00 1.00 4.12E+00 (sol) No No9 Chrysene NR 3.35E+03 3.35E+03 0.00 1.00 1.00 2.64E+00 (vap) No No
10 Dibenz[ah]anthracene NR 5.83E+02 5.83E+02 0.00 1.00 1.00 2.36E-02 (vap) No No11 Fluoranthene NR 3.09E+07 3.09E+07 0.00 1.00 1.00 1.13E+02 (vap) No No12 Fluorene NR 2.85E+07 2.85E+07 0.00 1.00 1.00 1.83E+02 (sol) No No13 Indeno[123-cd]pyrene NR 1.88E+03 1.88E+03 0.00 1.00 1.00 3.68E-01 (vap) No No14 Naphthalene NR 7.55E+04 7.55E+04 0.00 1.00 1.00 4.32E+02 (sol) No No15 Phenanthrene NR 1.53E+07 1.53E+07 0.00 1.00 1.00 2.14E+02 (sol) No No16 Pyrene NR 7.03E+07 7.03E+07 0.00 1.00 1.00 1.32E+01 (vap) No No17 Phenol NR 1.13E+06 1.13E+06 0.00 1.00 1.00 1.74E+05 (vap) No No18 Trichloroethene NR 4.79E+04 4.79E+04 0.00 1.00 1.00 7.14E+03 (vap) No No19 1,2-Dichloroethane NR 1.27E+03 1.27E+03 0.00 1.00 1.00 8.43E+03 (sol) No No20 Chloroethene (Vinyl Chloride) NR 5.05E+02 5.05E+02 0.00 1.00 1.00 2.69E+03 (sol) No No
3-Jul-12
Saturation Limit (mg kg-1)
CLEA v1.06 Software PAH & VOCs OUTDOOR VAPOUR
CLEA Software Version 1.06 Report generated Page 3 of 11
Assessment Criterion (mg kg-1) Ratio of ADE to HCV 50% rule?
oral inhalation combined oral inhalation combined Oral Inhal
21 Cis 1,2 Dichloroethene 4.22E+04 NR NR 1.00 NR NR 1.29E+04 (sol) No No222324252627282930
3-Jul-12
Saturation Limit (mg kg-1)
CLEA v1.06 Software PAH & VOCs OUTDOOR VAPOUR
CLEA Software Version 1.06 Report generated Page 4 of 11
Soil Distribution Media Concentrations
% % % % mg kg-1 mg m-3 mg kg-1 mg m-3 mg m-3 mg m-3 mg m-3 mg m-3 mg kg-1 FW mg kg-1 FW mg kg-1 FW mg kg-1 FW mg kg-1 FW mg kg-1 FW
1 Acenaphthene 99.7 0.3 0.0 100.0 3.20E+07 2.97E+05 NA NA NA NA 1.43E+00 0.00E+00 NA NA NA NA NA NA2 Acenaphthylene 99.6 0.4 0.0 100.0 3.05E+07 2.72E+05 NA NA NA NA 1.43E+00 0.00E+00 NA NA NA NA NA NA3 Anthracene 99.9 0.1 0.0 100.0 3.60E+08 3.33E+05 NA NA NA NA 7.17E+00 0.00E+00 NA NA NA NA NA NA4 Benz[a]anthracene 100.0 0.0 0.0 100.0 2.64E+03 3.09E-02 NA NA NA NA 1.15E-05 0.00E+00 NA NA NA NA NA NA
5 Benzo[a]pyrene 100.0 0.0 0.0 100.0 5.21E+02 2.05E-04 NA NA NA NA 1.67E-06 0.00E+00 NA NA NA NA NA NA
6 Benzo[b]fluoranthene 100.0 0.0 0.0 100.0 3.38E+03 1.90E-03 NA NA NA NA 1.20E-05 0.00E+00 NA NA NA NA NA NA
7 Benzo[ghi]perylene 100.0 0.0 0.0 100.0 4.35E+04 8.57E-03 NA NA NA NA 7.65E-05 0.00E+00 NA NA NA NA NA NA
8 Benzo[k]fluoranthene 100.0 0.0 0.0 100.0 5.62E+03 1.90E-03 NA NA NA NA 1.67E-05 0.00E+00 NA NA NA NA NA NA
9 Chrysene 100.0 0.0 0.0 100.0 3.35E+03 5.57E-03 NA NA NA NA 1.67E-05 0.00E+00 NA NA NA NA NA NA10 Dibenz[ah]anthracene 100.0 0.0 0.0 100.0 5.83E+02 4.86E-04 NA NA NA NA 1.51E-06 0.00E+00 NA NA NA NA NA NA11 Fluoranthene 100.0 0.0 0.0 100.0 3.09E+07 3.07E+03 NA NA NA NA 2.99E-01 0.00E+00 NA NA NA NA NA NA12 Fluorene 99.7 0.3 0.0 100.0 2.85E+07 1.19E+05 NA NA NA NA 9.56E-01 0.00E+00 NA NA NA NA NA NA13 Indeno[123-cd]pyrene 100.0 0.0 0.0 100.0 1.88E+03 1.27E-03 NA NA NA NA 7.17E-06 0.00E+00 NA NA NA NA NA NA14 Naphthalene 98.8 1.2 0.0 100.0 7.55E+04 2.20E+04 NA NA NA NA 1.65E-02 0.00E+00 NA NA NA NA NA NA15 Phenanthrene 99.9 0.1 0.0 100.0 1.53E+07 1.15E+04 NA NA NA NA 2.98E-01 0.00E+00 NA NA NA NA NA NA16 Pyrene 100.0 0.0 0.0 100.0 7.03E+07 7.02E+03 NA NA NA NA 7.17E-01 0.00E+00 NA NA NA NA NA NA17 Phenol 91.4 8.6 0.0 100.0 1.13E+06 2.98E+03 NA NA NA NA 1.81E-01 0.00E+00 NA NA NA NA NA NA18 Trichloroethene 94.2 5.2 0.6 100.0 4.79E+04 1.72E+06 NA NA NA NA 1.24E-01 0.00E+00 NA NA NA NA NA NA19 1,2-Dichloroethane 71.5 28.1 0.4 100.0 1.27E+03 3.12E+04 NA NA NA NA 2.87E-03 0.00E+00 NA NA NA NA NA NA20 Chloroethene (Vinyl Chloride) 59.3 28.0 12.7 100.0 5.05E+02 3.87E+05 NA NA NA NA 7.17E-03 0.00E+00 NA NA NA NA NA NA
Tube
r ve
geta
bles
Gre
en
vege
tabl
es
Roo
t ve
geta
bles
Indo
or
Vapo
ur
Out
door
va
pour
at
0.8m
Out
door
va
pour
at
1.6m
Soil
gas
Out
door
dus
t at
0.8
m
Out
door
dus
t at
1.6
m
3-Jul-12
Soil
Indo
or D
ust
Sor
bed
Dis
solv
ed
Vap
our
Tota
l
Her
bace
ous
fruit
Shru
b fru
it
Tree
frui
t
CLEA v1.06 Software PAH & VOCs OUTDOOR VAPOUR
CLEA Software Version 1.06 Report generated Page 5 of 11
Soil Distribution Media Concentrations
% % % % mg kg-1 mg m-3 mg kg-1 mg m-3 mg m-3 mg m-3 mg m-3 mg m-3 mg kg-1 FW mg kg-1 FW mg kg-1 FW mg kg-1 FW mg kg-1 FW mg kg-1 FW
21 Cis 1,2 Dichloroethene 83.3 16.0 0.7 100.0 4.22E+04 1.85E+06 NA NA NA NA 1.29E-01 0.00E+00 NA NA NA NA NA NA222324252627282930
3-Jul-12
Sor
bed
Dis
solv
ed
Vap
our
Tota
l
Soil
Indo
or
Vapo
ur
Indo
or D
ust
Soil
gas
Out
door
dus
t at
0.8
m
Out
door
dus
t at
1.6
m
Out
door
va
pour
at
0.8m
Out
door
va
pour
at
1.6m
Gre
en
vege
tabl
es
Roo
t ve
geta
bles
Tube
r ve
geta
bles
Her
bace
ous
fruit
Shru
b fru
it
Tree
frui
t
CLEA v1.06 Software PAH & VOCs OUTDOOR VAPOUR
CLEA Software Version 1.06 Report generated Page 6 of 11
Average Daily Exposure (mg kg-1 bw day-1) Distribution by Pathway (%)
1 Acenaphthene 0.00E+00 0.00E+00 0.00E+00 0.00E+00 6.00E-02 5.51E-05 1.52E-06 0.00 0.00 0.00 0.00 0.00 100.00 0.00 0.002 Acenaphthylene 0.00E+00 0.00E+00 0.00E+00 0.00E+00 6.00E-02 7.88E-06 6.67E-07 0.00 0.00 0.00 0.00 0.00 100.00 0.00 0.003 Anthracene 0.00E+00 0.00E+00 0.00E+00 0.00E+00 3.00E-01 4.50E-06 2.49E-06 0.00 0.00 0.00 0.00 0.00 100.00 0.00 0.004 Benz[a]anthracene 0.00E+00 0.00E+00 0.00E+00 0.00E+00 4.80E-07 0.00E+00 0.00E+00 0.00 0.00 0.00 0.00 0.00 100.00 0.00 0.00
5 Benzo[a]pyrene 0.00E+00 0.00E+00 0.00E+00 0.00E+00 7.00E-08 0.00E+00 0.00E+00 0.00 0.00 0.00 0.00 0.00 100.00 0.00 0.00
6 Benzo[b]fluoranthene 0.00E+00 0.00E+00 0.00E+00 0.00E+00 5.00E-07 0.00E+00 0.00E+00 0.00 0.00 0.00 0.00 0.00 100.00 0.00 0.00
7 Benzo[ghi]perylene 0.00E+00 0.00E+00 0.00E+00 0.00E+00 3.20E-06 0.00E+00 0.00E+00 0.00 0.00 0.00 0.00 0.00 100.00 0.00 0.00
8 Benzo[k]fluoranthene 0.00E+00 0.00E+00 0.00E+00 0.00E+00 7.00E-07 0.00E+00 0.00E+00 0.00 0.00 0.00 0.00 0.00 100.00 0.00 0.00
9 Chrysene 0.00E+00 0.00E+00 0.00E+00 0.00E+00 7.00E-07 0.00E+00 0.00E+00 0.00 0.00 0.00 0.00 0.00 100.00 0.00 0.0010 Dibenz[ah]anthracene 0.00E+00 0.00E+00 0.00E+00 0.00E+00 6.30E-08 0.00E+00 0.00E+00 0.00 0.00 0.00 0.00 0.00 100.00 0.00 0.0011 Fluoranthene 0.00E+00 0.00E+00 0.00E+00 0.00E+00 1.25E-02 1.97E-05 5.09E-06 0.00 0.00 0.00 0.00 0.00 99.96 0.00 0.0412 Fluorene 0.00E+00 0.00E+00 0.00E+00 0.00E+00 4.00E-02 3.32E-05 5.82E-06 0.00 0.00 0.00 0.00 0.00 99.99 0.00 0.0113 Indeno[123-cd]pyrene 0.00E+00 0.00E+00 0.00E+00 0.00E+00 3.00E-07 0.00E+00 0.00E+00 0.00 0.00 0.00 0.00 0.00 100.00 0.00 0.0014 Naphthalene 0.00E+00 0.00E+00 0.00E+00 0.00E+00 6.90E-04 3.94E-04 1.70E-04 0.00 0.00 0.00 0.00 0.00 80.26 0.00 19.7415 Phenanthrene 0.00E+00 0.00E+00 0.00E+00 0.00E+00 1.25E-02 8.66E-05 3.14E-05 0.00 0.00 0.00 0.00 0.00 99.75 0.00 0.2516 Pyrene 0.00E+00 0.00E+00 0.00E+00 0.00E+00 3.00E-02 2.42E-05 3.94E-06 0.00 0.00 0.00 0.00 0.00 99.99 0.00 0.0117 Phenol 0.00E+00 0.00E+00 0.00E+00 0.00E+00 7.58E-03 1.97E-02 2.42E-03 0.00 0.00 0.00 0.00 0.00 75.75 0.00 24.2518 Trichloroethene 0.00E+00 0.00E+00 0.00E+00 0.00E+00 5.20E-03 0.00E+00 0.00E+00 0.00 0.00 0.00 0.00 0.00 100.00 0.00 0.0019 1,2-Dichloroethane 0.00E+00 0.00E+00 0.00E+00 0.00E+00 1.20E-04 0.00E+00 0.00E+00 0.00 0.00 0.00 0.00 0.00 100.00 0.00 0.0020 Chloroethene (Vinyl Chloride) 0.00E+00 0.00E+00 0.00E+00 0.00E+00 3.00E-04 0.00E+00 0.00E+00 0.00 0.00 0.00 0.00 0.00 100.00 0.00 0.00
Inha
latio
n of
vap
our
Back
grou
nd (o
ral)
Back
grou
nd (o
ral)
Back
grou
nd
(inha
latio
n)
Inha
latio
n of
vap
our
(indo
or)
Dire
ct s
oil i
nges
tion
Con
sum
ptio
n of
ho
meg
row
n pr
oduc
e an
d at
tach
ed s
oil
Der
mal
con
tact
with
so
il an
d du
st
Inha
latio
n of
dus
t
3-Jul-12
Con
sum
ptio
n of
ho
meg
row
n pr
oduc
e an
d at
tach
ed s
oil
Der
mal
con
tact
with
so
il an
d du
st
Inha
latio
n of
dus
t
Back
grou
nd
(inha
latio
n)
Dire
ct s
oil i
nges
tion
Inha
latio
n of
vap
our
(out
door
)
CLEA v1.06 Software PAH & VOCs OUTDOOR VAPOUR
CLEA Software Version 1.06 Report generated Page 7 of 11
Average Daily Exposure (mg kg-1 bw day-1) Distribution by Pathway (%)
21 Cis 1,2 Dichloroethene 0.00E+00 0.00E+00 0.00E+00 0.00E+00 5.41E-03 2.25E-04 3.64E-04 0.00 0.00 0.00 0.00 0.00 90.19 9.81 0.00222324252627282930
3-Jul-12
Dire
ct s
oil i
nges
tion
Con
sum
ptio
n of
ho
meg
row
n pr
oduc
e an
d at
tach
ed s
oil
Der
mal
con
tact
with
so
il an
d du
st
Inha
latio
n of
dus
t
Inha
latio
n of
vap
our
Back
grou
nd (o
ral)
Back
grou
nd
(inha
latio
n)
Dire
ct s
oil i
nges
tion
Con
sum
ptio
n of
ho
meg
row
n pr
oduc
e
Der
mal
con
tact
with
so
il an
d du
st
Inha
latio
n of
dus
t
Inha
latio
n of
vap
our
(indo
or)
Back
grou
nd (o
ral)
Back
grou
nd
(inha
latio
n)
Inha
latio
n of
vap
our
(out
door
)
CLEA v1.06 Software PAH & VOCs OUTDOOR VAPOUR
CLEA Software Version 1.06 Report generated Page 8 of 11
1 Acenaphthene TDI 60 TDI 60 0.98 0.025 7.59E-04 5.85E-06 4.70E-10 3.37 4.03 0.13 0.5 1 1 12 Acenaphthylene TDI 60 TDI 60 0.14 0.011 5.68E-04 5.97E-06 4.82E-10 3.26 3.91 0.13 0.5 1 1 13 Anthracene TDI 300 TDI 300 0.08 0.041 1.81E-04 5.36E-06 4.36E-10 3.75 4.5 0.13 0.5 1 1 14 Benz[a]anthracene ID 0.138 ID 0.00048 NR NR 3.16E-05 4.60E-06 3.80E-10 4.89 5.91 0.13 0.5 1 1 1
5 Benzo[a]pyrene ID 0.02 ID 0.00007 NR NR 1.76E-06 4.38E-06 3.67E-10 5.11 6.18 0.13 0.5 1 1 1
6 Benzo[b]fluoranthene ID 0.142 ID 0.0005 NR NR 2.05E-06 4.36E-06 3.62E-10 5.02 6.08 0.13 0.5 1 1 1
7 Benzo[ghi]perylene ID 0.909 ID 0.0032 NR NR 2.86E-06 4.22E-06 3.56E-10 5.62 6.81 0.13 0.5 1 1 1
8 Benzo[k]fluoranthene ID 0.2 ID 0.0007 NR NR 1.74E-06 4.36E-06 3.62E-10 5.17 6.26 0.13 0.5 1 1 1
9 Chrysene ID 0.2 ID 0.0007 NR NR 3.18E-06 4.57E-06 3.77E-10 4.74 5.73 0.13 0.5 1 1 110 Dibenz[ah]anthracene ID 0.018 ID 0.000063 NR NR 5.40E-06 4.08E-06 3.40E-10 5.27 6.38 0.13 0.5 1 1 111 Fluoranthene TDI 12.5 TDI 12.5 0.35 0.084 6.29E-05 5.01E-06 4.11E-10 4.26 5.13 0.13 0.5 1 1 112 Fluorene TDI 40 TDI 40 0.59 0.096 4.12E-04 5.58E-06 4.47E-10 3.45 4.13 0.13 0.5 1 1 113 Indeno[123-cd]pyrene ID 0.086 ID 0.0003 NR NR 2.05E-06 4.17E-06 3.51E-10 4.94 5.97 0.13 0.5 1 1 114 Naphthalene TDI 20 TDI 0.86 7 2.8 6.62E-03 6.52E-06 5.16E-10 2.81 3.34 0.13 0.5 1 1 115 Phenanthrene TDI 12.5 TDI 12.5 1.54 0.518 1.43E-04 5.34E-06 4.32E-10 3.74 4.5 0.13 0.5 1 1 116 Pyrene TDI 30 TDI 30 0.43 0.065 5.64E-05 5.01E-06 4.15E-10 4.21 5.08 0.13 0.5 1 1 117 Phenol TDI 700 TDI 10 350 40 8.35E-06 7.90E-06 6.36E-10 1.92 1.48 0.3 0.5 1 1 118 Trichloroethene ID 5.2 ID 5.2 NR NR 1.87E-01 7.91E-06 6.23E-10 2.15 2.53 0.1 0.5 1 1 119 1,2-Dichloroethane ID 0.12 ID 0.12 NR NR 2.38E-02 8.60E-06 6.74E-10 1.3 1.48 0.1 0.5 1 1 120 Chloroethene (Vinyl Chloride) ID 0.014 ID 0.3 NR NR 7.47E-01 1.11E-05 8.34E-10 1.22 1.38 0.1 0.5 1 1 1
Rel
ativ
e bi
oava
ilabi
lity
via
soil
inge
stio
n (u
nitle
ss)
3-Jul-12
Ora
l Hea
lth C
riter
ia V
alue
(μ
g kg
-1 B
W d
ay-1
)
Inha
latio
n M
ean
Dai
ly In
take
(μ
g da
y-1)
log
K oc (
cm3 g
-1)
log
K ow (d
imen
sion
less
)
Coe
ffici
ent o
f Diff
usio
n in
Wat
er
(m2 s
-1)
Inha
latio
n H
ealth
Crit
eria
Val
ue
(μg
kg-1
BW
day
-1)
Ora
l Mea
n D
aily
Inta
ke
(μ
g da
y-1)
Air-
wat
er p
artit
ion
coef
ficie
nt
(Kaw
) (c
m3 c
m-3
)
Coe
ffici
ent o
f Diff
usio
n in
Air
(m2
s-1)
Rel
ativ
e bi
oava
ilabi
lity
via
dust
in
hala
tion
(uni
tless
)
Der
mal
Abs
orpt
ion
Frac
tion
(dim
ensi
onle
ss)
Soil-
to-d
ust t
rans
port
fact
or
(g
g-1 D
W)
Sub-
surfa
ce s
oil t
o in
door
air
corr
ectio
n fa
ctor
(d
imen
sion
less
)
CLEA v1.06 Software PAH & VOCs OUTDOOR VAPOUR
CLEA Software Version 1.06 Report generated Page 9 of 11
21 Cis 1,2 Dichloroethene TDI 6 NR 0 4 6 7.46E-02 9.02E-06 7.08E-10 1.61 1.86 0.1 0.5 1 1 1222324252627282930
Rel
ativ
e bi
oava
ilabi
lity
via
soil
inge
stio
n (u
nitle
ss)
Rel
ativ
e bi
oava
ilabi
lity
via
dust
in
hala
tion
(uni
tless
)
Coe
ffici
ent o
f Diff
usio
n in
Wat
er
(m2 s
-1)
log
K oc (
cm3 g
-1)
log
K ow (d
imen
sion
less
)
Der
mal
Abs
orpt
ion
Frac
tion
(dim
ensi
onle
ss)
3-Jul-12
Soil-
to-d
ust t
rans
port
fact
or
(g
g-1 D
W)
Inha
latio
n M
ean
Dai
ly In
take
(μ
g da
y-1)
Air-
wat
er p
artit
ion
coef
ficie
nt
(Kaw
) (c
m3 c
m-3
)
Coe
ffici
ent o
f Diff
usio
n in
Air
(m2
s-1)
Ora
l Hea
lth C
riter
ia V
alue
(μ
g kg
-1 B
W d
ay-1
)
Inha
latio
n H
ealth
Crit
eria
Val
ue
(μg
kg-1
BW
day
-1)
Ora
l Mea
n D
aily
Inta
ke
(μ
g da
y-1)
Sub-
surfa
ce s
oil t
o in
door
air
corr
ectio
n fa
ctor
(d
imen
sion
less
)
CLEA v1.06 Software PAH & VOCs OUTDOOR VAPOUR
CLEA Software Version 1.06 Report generated Page 10 of 11
1 Acenaphthene 8.16E+01 7.37E-02 4.11E+00 model model model model model model2 Acenaphthylene 6.33E+01 7.08E-02 7.95E+00 model model model model model model3 Anthracene 1.96E+02 8.49E-05 5.60E-02 model model model model model model4 Benz[a]anthracene 2.70E+03 1.24E-06 3.80E-03 model model model model model model
5 Benzo[a]pyrene 4.48E+03 2.00E-08 3.80E-03 model model model model model model
6 Benzo[b]fluoranthene 3.64E+03 6.34E-08 2.00E-03 model model model model model model
7 Benzo[ghi]perylene 1.45E+04 1.55E-10 2.64E-04 model model model model model model
8 Benzo[k]fluoranthene 5.15E+03 1.64E-08 8.00E-04 model model model model model model
9 Chrysene 1.91E+03 4.52E-08 2.00E-03 model model model model model model10 Dibenz[ah]anthracene 6.48E+03 1.66E-10 6.00E-04 model model model model model model11 Fluoranthene 6.33E+02 1.31E-04 2.30E-01 model model model model model model12 Fluorene 9.81E+01 1.56E-02 1.86E+00 model model model model model model13 Indeno[123-cd]pyrene 3.03E+03 2.12E-09 2.00E-04 model model model model model model14 Naphthalene 2.25E+01 2.31E+00 1.90E+01 model model model model model model15 Phenanthrene 1.91E+02 2.82E-03 1.12E+00 model model model model model model16 Pyrene 5.64E+02 1.53E-05 1.30E-01 model model model model model model17 Phenol 2.89E+00 1.15E+01 8.41E+04 model model model 0.00E+00 0.00E+00 model18 Trichloroethene 4.92E+00 4.58E+03 1.37E+03 model model model model model model19 1,2-Dichloroethane 6.94E-01 4.92E+03 8.68E+03 model model model model model model20 Chloroethene (Vinyl Chloride) 5.78E-01 2.20E+05 2.76E+03 model model model model model model
Wat
er s
olub
ility
(mg
L-1)
Soil-
to-p
lant
con
cent
ratio
n fa
ctor
fo
r her
bace
ous
fruit
(m
g g-1
plan
t DW
or F
W b
asis
ove
r mg
g-1 D
W s
oil)
Soil-
to-p
lant
con
cent
ratio
n fa
ctor
fo
r shr
ub fr
uit
(m
g g-1
pla
nt D
W o
r FW
bas
is
over
mg
g-1 D
W s
oil)
Soil-
to-p
lant
con
cent
ratio
n fa
ctor
fo
r tre
e fru
it
(
mg
g-1
plan
t DW
or F
W b
asis
ove
r mg
g-1 D
W s
oil)
Soil-
to-p
lant
con
cent
ratio
n fa
ctor
fo
r tub
er v
eget
able
s
(mg
g-1
plan
t DW
or F
W b
asis
ove
r mg
g-1 D
W s
oil)
Soil-
to-p
lant
con
cent
ratio
n fa
ctor
fo
r roo
t veg
etab
les
(m
g g-1
plan
t DW
or F
W b
asis
ove
r mg
g-1 D
W s
oil)
Soil-
to-p
lant
con
cent
ratio
n fa
ctor
fo
r gre
en v
eget
able
s (m
g g-1
plan
t DW
or F
W b
asis
ove
r mg
g-1 D
W s
oil)
3-Jul-12
Soil-
to-w
ater
par
titio
n co
effic
ient
(c
m3 g
-1)
Vapo
ur p
ress
ure
(Pa)
CLEA v1.06 Software PAH & VOCs OUTDOOR VAPOUR
CLEA Software Version 1.06 Report generated Page 11 of 11
21 Cis 1,2 Dichloroethene 1.42E+00 1.37E+04 7.55E+03 Model Model Model Model Model Model222324252627282930
Soil-
to-p
lant
con
cent
ratio
n fa
ctor
fo
r her
bace
ous
fruit
(m
g g-1
plan
t DW
or F
W b
asis
ove
r mg
g-1 D
W s
oil)
Soil-
to-p
lant
con
cent
ratio
n fa
ctor
fo
r shr
ub fr
uit
(mg
g-1 p
lant
DW
or F
W b
asis
ov
er m
g g-1
DW
soi
l)
Soil-
to-p
lant
con
cent
ratio
n fa
ctor
fo
r tre
e fru
it
(
mg
g-1
plan
t DW
or F
W b
asis
ove
r mg
g-1 D
W s
oil)
3-Jul-12
Soil-
to-p
lant
con
cent
ratio
n fa
ctor
fo
r roo
t veg
etab
les
(m
g g-1
plan
t DW
or F
W b
asis
ove
r mg
g-1 D
W s
oil)
Vapo
ur p
ress
ure
(Pa)
Wat
er s
olub
ility
(mg
L-1)
Soil-
to-p
lant
con
cent
ratio
n fa
ctor
fo
r gre
en v
eget
able
s (m
g g-1
plan
t DW
or F
W b
asis
ove
r mg
g-1 D
W s
oil)
Soil-
to-w
ater
par
titio
n co
effic
ient
(c
m3 g
-1)
Soil-
to-p
lant
con
cent
ratio
n fa
ctor
fo
r tub
er v
eget
able
s
(mg
g-1
plan
t DW
or F
W b
asis
ove
r mg
g-1 D
W s
oil)
CLEA v1.06 Software VPH EPH OUTDOOR VAPOUR
CLEA Software Version 1.06 Page 1 of 11
Report generated
Report title
Created by
RESULTS
03-Jul-12
Avesta TPH
RB at Integral Geotechnique
CLEA v1.06 Software VPH EPH OUTDOOR VAPOUR
CLEA Software Version 1.06 Report generated Page 2 of 11
Assessment Criterion (mg kg-1) Ratio of ADE to HCV 50% rule?
oral inhalation combined oral inhalation combined Oral Inhal
1 TPH Aliphatic C5-C6 NR 4.80E+06 4.80E+06 0.00 1.00 1.00 1.15E+03 (sol) Yes Yes2 TPH Aliphatic C6-C8 NR 8.70E+06 8.70E+06 0.00 1.00 1.00 7.36E+02 (sol) Yes Yes3 TPH Aliphatic C8-C10 NR 1.14E+06 1.14E+06 0.00 1.00 1.00 4.51E+02 (vap) Yes Yes4 TPH Aliphatic C10-C12 NR 2.57E+06 2.57E+06 0.00 1.00 1.00 1.86E+02 (vap) Yes Yes5 TPH Aliphatic C12-C16 NR 7.45E+06 7.45E+06 0.00 1.00 1.00 1.42E+02 (sol) Yes Yes6 TPH Aliphatic C16-C35 NR 6.34E+13 6.34E+13 0.00 0.00 0.00 5.09E+01 (sol) Yes No7 TPH Aliphatic C35-C44 NR 6.34E+13 6.34E+13 0.00 0.00 0.00 5.09E+01 (sol) Yes No8 TPH Aromatic C5-C7 NR 1.11E+04 1.11E+04 0.00 1.00 1.00 4.71E+03 (sol) No No9 TPH Aromatic C7-C8 NR 1.93E+07 1.93E+07 0.00 1.00 1.00 4.36E+03 (vap) No No
10 TPH Aromatic C8-C10 NR 6.89E+05 6.89E+05 0.00 1.00 1.00 3.58E+03 (vap) Yes Yes11 TPH Aromatic C10-C12 NR 1.62E+06 1.62E+06 0.00 1.00 1.00 2.15E+03 (sol) Yes Yes12 TPH Aromatic C12-C16 NR 5.38E+06 5.38E+06 0.00 1.00 1.00 1.00E+03 (sol) Yes Yes13 TPH Aromatic C16-C21 NR NR NR 0.00 0.00 0.00 3.21E+02 (vap) Yes No14 TPH Aromatic C21-C35 NR NR NR 0.00 0.00 0.00 2.90E+01 (sol) Yes No15 TPH Aromatic C35-C40 NR NR NR 0.00 0.00 0.00 2.90E+01 (sol) Yes No1617181920
3-Jul-12
Saturation Limit (mg kg-1)
CLEA v1.06 Software VPH EPH OUTDOOR VAPOUR
CLEA Software Version 1.06 Report generated Page 3 of 11
Assessment Criterion (mg kg-1) Ratio of ADE to HCV 50% rule?
oral inhalation combined oral inhalation combined Oral Inhal
21222324252627282930
Saturation Limit (mg kg-1)
3-Jul-12
CLEA v1.06 Software VPH EPH OUTDOOR VAPOUR
CLEA Software Version 1.06 Report generated Page 4 of 11
Soil Distribution Media Concentrations
% % % % mg kg-1 mg m-3 mg kg-1 mg m-3 mg m-3 mg m-3 mg m-3 mg m-3 mg kg-1 FW mg kg-1 FW mg kg-1 FW mg kg-1 FW mg kg-1 FW mg kg-1 FW
1 TPH Aliphatic C5-C6 88.3 0.9 10.8 100.0 4.80E+06 3.15E+09 NA NA NA NA 5.98E+01 0.00E+00 NA NA NA NA NA NA2 TPH Aliphatic C6-C8 96.5 0.2 3.3 100.0 8.70E+06 1.73E+09 NA NA NA NA 5.98E+01 0.00E+00 NA NA NA NA NA NA3 TPH Aliphatic C8-C10 99.3 0.0 0.6 100.0 1.14E+06 4.46E+07 NA NA NA NA 3.47E+00 0.00E+00 NA NA NA NA NA NA4 TPH Aliphatic C10-C12 99.9 0.0 0.1 100.0 2.57E+06 1.98E+07 NA NA NA NA 3.47E+00 0.00E+00 NA NA NA NA NA NA
5 TPH Aliphatic C12-C16 100.0 0.0 0.0 100.0 7.45E+06 6.81E+06 NA NA NA NA 3.47E+00 0.00E+00 NA NA NA NA NA NA
6 TPH Aliphatic C16-C35 100.0 0.0 0.0 100.0 6.34E+13 3.39E+12 NA NA NA NA 7.13E+06 0.00E+00 NA NA NA NA NA NA
7 TPH Aliphatic C35-C44 100.0 0.0 0.0 100.0 6.34E+13 3.39E+12 NA NA NA NA 7.13E+06 0.00E+00 NA NA NA NA NA NA
8 TPH Aromatic C5-C7 89.0 10.3 0.7 100.0 1.11E+04 4.86E+05 NA NA NA NA 3.35E-02 0.00E+00 NA NA NA NA NA NA
9 TPH Aromatic C7-C8 96.1 3.7 0.3 100.0 1.93E+07 3.00E+08 NA NA NA NA 3.27E+01 0.00E+00 NA NA NA NA NA NA10 TPH Aromatic C8-C10 99.4 0.5 0.1 100.0 6.89E+05 3.14E+06 NA NA NA NA 7.17E-01 0.00E+00 NA NA NA NA NA NA11 TPH Aromatic C10-C12 99.7 0.3 0.0 100.0 1.62E+06 1.33E+06 NA NA NA NA 7.17E-01 0.00E+00 NA NA NA NA NA NA12 TPH Aromatic C12-C16 99.8 0.2 0.0 100.0 5.38E+06 3.88E+05 NA NA NA NA 7.17E-01 0.00E+00 NA NA NA NA NA NA13 TPH Aromatic C16-C21 99.9 0.1 0.0 100.0 -3.36E-10 -4.74E-13 NA NA NA NA -8.15E-18 0.00E+00 NA NA NA NA NA NA14 TPH Aromatic C21-C35 100.0 0.0 0.0 100.0 -3.36E-10 -1.90E-15 NA NA NA NA -1.84E-18 0.00E+00 NA NA NA NA NA NA15 TPH Aromatic C35-C40 100.0 0.0 0.0 100.0 -3.36E-10 -1.90E-15 NA NA NA NA -1.84E-18 0.00E+00 NA NA NA NA NA NA1617181920
Her
bace
ous
fruit
Shru
b fru
it
Tree
frui
t
3-Jul-12
Soil
Indo
or D
ust
Sor
bed
Dis
solv
ed
Vap
our
Tota
l
Gre
en
vege
tabl
es
Roo
t ve
geta
bles
Indo
or
Vapo
ur
Out
door
va
pour
at
0.8m
Out
door
va
pour
at
1.6m
Soil
gas
Out
door
dus
t at
0.8
m
Out
door
dus
t at
1.6
m
Tube
r ve
geta
bles
CLEA v1.06 Software VPH EPH OUTDOOR VAPOUR
CLEA Software Version 1.06 Report generated Page 5 of 11
Soil Distribution Media Concentrations
% % % % mg kg-1 mg m-3 mg kg-1 mg m-3 mg m-3 mg m-3 mg m-3 mg m-3 mg kg-1 FW mg kg-1 FW mg kg-1 FW mg kg-1 FW mg kg-1 FW mg kg-1 FW
21222324252627282930
Her
bace
ous
fruit
Shru
b fru
it
Tree
frui
t
Out
door
va
pour
at
0.8m
Out
door
va
pour
at
1.6m
Gre
en
vege
tabl
es
Roo
t ve
geta
bles
Tube
r ve
geta
bles
Indo
or
Vapo
ur
Indo
or D
ust
Soil
gas
Out
door
dus
t at
0.8
m
Out
door
dus
t at
1.6
m
Soil
3-Jul-12
Sor
bed
Dis
solv
ed
Vap
our
Tota
l
CLEA v1.06 Software VPH EPH OUTDOOR VAPOUR
CLEA Software Version 1.06 Report generated Page 6 of 11
Average Daily Exposure (mg kg-1 bw day-1) Distribution by Pathway (%)
1 TPH Aliphatic C5-C6 0.00E+00 0.00E+00 0.00E+00 0.00E+00 2.50E+00 5.62E+95 6.06E+95 0.00 0.00 0.00 0.00 0.00 50.00 0.00 50.002 TPH Aliphatic C6-C8 0.00E+00 0.00E+00 0.00E+00 0.00E+00 2.50E+00 5.62E+95 6.06E+95 0.00 0.00 0.00 0.00 0.00 50.00 0.00 50.003 TPH Aliphatic C8-C10 0.00E+00 0.00E+00 0.00E+00 0.00E+00 1.45E-01 5.62E+95 6.06E+95 0.00 0.00 0.00 0.00 0.00 50.00 0.00 50.004 TPH Aliphatic C10-C12 0.00E+00 0.00E+00 0.00E+00 0.00E+00 1.45E-01 5.62E+95 6.06E+95 0.00 0.00 0.00 0.00 0.00 50.00 0.00 50.00
5 TPH Aliphatic C12-C16 0.00E+00 0.00E+00 0.00E+00 0.00E+00 1.45E-01 5.62E+95 6.06E+95 0.00 0.00 0.00 0.00 0.00 50.00 0.00 50.00
6 TPH Aliphatic C16-C35 0.00E+00 0.00E+00 0.00E+00 0.00E+00 2.98E+05 5.62E+95 0.00E+00 0.00 0.00 0.00 0.00 0.00 100.00 0.00 0.00
7 TPH Aliphatic C35-C44 0.00E+00 0.00E+00 0.00E+00 0.00E+00 2.98E+05 5.62E+95 0.00E+00 0.00 0.00 0.00 0.00 0.00 100.00 0.00 0.00
8 TPH Aromatic C5-C7 0.00E+00 0.00E+00 0.00E+00 0.00E+00 1.40E-03 1.69E-04 1.21E-02 0.00 0.00 0.00 0.00 0.00 100.00 0.00 0.00
9 TPH Aromatic C7-C8 0.00E+00 0.00E+00 0.00E+00 0.00E+00 1.37E+00 5.63E-04 3.15E-02 0.00 0.00 0.00 0.00 0.00 97.75 0.00 2.2510 TPH Aromatic C8-C10 0.00E+00 0.00E+00 0.00E+00 0.00E+00 3.00E-02 5.62E+95 6.06E+95 0.00 0.00 0.00 0.00 0.00 50.00 0.00 50.0011 TPH Aromatic C10-C12 0.00E+00 0.00E+00 0.00E+00 0.00E+00 3.00E-02 5.62E+95 6.06E+95 0.00 0.00 0.00 0.00 0.00 50.00 0.00 50.0012 TPH Aromatic C12-C16 0.00E+00 0.00E+00 0.00E+00 0.00E+00 3.00E-02 5.62E+95 6.06E+95 0.00 0.00 0.00 0.00 0.00 50.00 0.00 50.0013 TPH Aromatic C16-C21 0.00E+00 0.00E+00 0.00E+00 0.00E+00 -3.41E-19 5.62E+95 0.00E+00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.0014 TPH Aromatic C21-C35 0.00E+00 0.00E+00 0.00E+00 0.00E+00 -7.68E-20 5.62E+95 0.00E+00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.0015 TPH Aromatic C35-C40 0.00E+00 0.00E+00 0.00E+00 0.00E+00 -7.68E-20 5.62E+95 0.00E+00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.001617181920
Inha
latio
n of
vap
our
(out
door
)
3-Jul-12
Con
sum
ptio
n of
ho
meg
row
n pr
oduc
e an
d at
tach
ed s
oil
Der
mal
con
tact
with
so
il an
d du
st
Inha
latio
n of
dus
t
Back
grou
nd
(inha
latio
n)
Dire
ct s
oil i
nges
tion
Back
grou
nd (o
ral)
Back
grou
nd
(inha
latio
n)
Inha
latio
n of
vap
our
(indo
or)
Dire
ct s
oil i
nges
tion
Con
sum
ptio
n of
ho
meg
row
n pr
oduc
e an
d at
tach
ed s
oil
Der
mal
con
tact
with
so
il an
d du
st
Inha
latio
n of
dus
t
Inha
latio
n of
vap
our
Back
grou
nd (o
ral)
CLEA v1.06 Software VPH EPH OUTDOOR VAPOUR
CLEA Software Version 1.06 Report generated Page 7 of 11
Average Daily Exposure (mg kg-1 bw day-1) Distribution by Pathway (%)
21222324252627282930
Inha
latio
n of
vap
our
(out
door
)
Con
sum
ptio
n of
ho
meg
row
n pr
oduc
e
Der
mal
con
tact
with
so
il an
d du
st
Inha
latio
n of
dus
t
Inha
latio
n of
vap
our
(indo
or)
Back
grou
nd (o
ral)
Back
grou
nd
(inha
latio
n)
3-Jul-12
Dire
ct s
oil i
nges
tion
Con
sum
ptio
n of
ho
meg
row
n pr
oduc
e an
d at
tach
ed s
oil
Der
mal
con
tact
with
so
il an
d du
st
Inha
latio
n of
dus
t
Inha
latio
n of
vap
our
Back
grou
nd (o
ral)
Back
grou
nd
(inha
latio
n)
Dire
ct s
oil i
nges
tion
CLEA v1.06 Software VPH EPH OUTDOOR VAPOUR
CLEA Software Version 1.06 Report generated Page 8 of 11
1 TPH Aliphatic C5-C6 TDI 5000 TDI 5000 9.99E+99 9.99E+99 2.10E+01 1.00E-05 1.00E-09 2.91 3.31 0.1 0.5 10 1 12 TPH Aliphatic C6-C8 TDI 5000 TDI 5000 9.99E+99 9.99E+99 2.73E+01 1.00E-05 1.00E-09 3.58 4.13 0.1 0.5 10 1 13 TPH Aliphatic C8-C10 TDI 100 TDI 290 9.99E+99 9.99E+99 4.15E+01 1.00E-05 1.00E-09 4.48 5.22 0.1 0.5 10 1 14 TPH Aliphatic C10-C12 TDI 100 TDI 290 9.99E+99 9.99E+99 6.44E+01 1.00E-05 1.00E-09 5.38 6.3 0.1 0.5 10 1 1
5 TPH Aliphatic C12-C16 TDI 100 TDI 290 9.99E+99 9.99E+99 1.71E+02 1.00E-05 1.00E-09 6.73 7.94 0.1 0.5 10 1 1
6 TPH Aliphatic C16-C35 TDI 2000 TDI 9E+99 9.99E+99 0 1.07E+03 1.00E-05 1.00E-09 8.76 10.39 0.1 0.5 10 1 1
7 TPH Aliphatic C35-C44 TDI 2000 TDI 9E+99 9.99E+99 0 1.07E+03 1.00E-05 1.00E-09 8.76 10.39 0.1 0.5 10 1 1
8 TPH Aromatic C5-C7 ID 0.29 ID 1.4 3 200 1.16E-01 8.77E-06 6.64E-10 1.83 2.13 0.1 0.5 10 1 1
9 TPH Aromatic C7-C8 TDI 223 TDI 1400 10 520 1.15E-01 7.78E-06 5.88E-10 2.31 2.73 0.1 0.5 10 1 110 TPH Aromatic C8-C10 TDI 40 TDI 60 9.99E+99 9.99E+99 2.53E-01 1.00E-05 1.00E-09 3.2 3.69 0.1 0.5 10 1 111 TPH Aromatic C10-C12 TDI 40 TDI 60 9.99E+99 9.99E+99 7.22E-02 1.00E-05 1.00E-09 3.4 3.93 0.1 0.5 10 1 112 TPH Aromatic C12-C16 TDI 40 TDI 60 9.99E+99 9.99E+99 1.26E-02 1.00E-05 1.00E-09 3.7 4.29 0.1 0.5 10 1 113 TPH Aromatic C16-C21 TDI 30 TDI 9E+99 9.99E+99 0 6.95E-04 1.00E-05 1.00E-09 4.15 4.82 0.1 0.5 10 1 114 TPH Aromatic C21-C35 TDI 30 TDI 9E+99 9.99E+99 0 2.48E-05 1.00E-05 1.00E-09 5.1 5.95 0.1 0.5 10 1 115 TPH Aromatic C35-C40 TDI 30 TDI 9E+99 9.99E+99 0 2.48E-05 1.00E-05 1.00E-09 5.1 5.95 0.1 0.5 10 1 11617181920
Sub-
surfa
ce s
oil t
o in
door
air
corr
ectio
n fa
ctor
(d
imen
sion
less
)
Der
mal
Abs
orpt
ion
Frac
tion
(dim
ensi
onle
ss)
Soil-
to-d
ust t
rans
port
fact
or
(g
g-1 D
W)
Rel
ativ
e bi
oava
ilabi
lity
via
dust
in
hala
tion
(uni
tless
)
log
K oc (
cm3 g
-1)
log
K ow (d
imen
sion
less
)
Coe
ffici
ent o
f Diff
usio
n in
Wat
er
(m2 s
-1)
Inha
latio
n H
ealth
Crit
eria
Val
ue
(μg
kg-1
BW
day
-1)
Ora
l Mea
n D
aily
Inta
ke
(μ
g da
y-1)
Air-
wat
er p
artit
ion
coef
ficie
nt
(Kaw
) (c
m3 c
m-3
)
Coe
ffici
ent o
f Diff
usio
n in
Air
(m2
s-1)
3-Jul-12
Ora
l Hea
lth C
riter
ia V
alue
(μ
g kg
-1 B
W d
ay-1
)
Inha
latio
n M
ean
Dai
ly In
take
(μ
g da
y-1)
Rel
ativ
e bi
oava
ilabi
lity
via
soil
inge
stio
n (u
nitle
ss)
CLEA v1.06 Software VPH EPH OUTDOOR VAPOUR
CLEA Software Version 1.06 Report generated Page 9 of 11
21222324252627282930
Sub-
surfa
ce s
oil t
o in
door
air
corr
ectio
n fa
ctor
(d
imen
sion
less
)
Ora
l Hea
lth C
riter
ia V
alue
(μ
g kg
-1 B
W d
ay-1
)
Inha
latio
n H
ealth
Crit
eria
Val
ue
(μg
kg-1
BW
day
-1)
Ora
l Mea
n D
aily
Inta
ke
(μ
g da
y-1)
Inha
latio
n M
ean
Dai
ly In
take
(μ
g da
y-1)
Air-
wat
er p
artit
ion
coef
ficie
nt
(Kaw
) (c
m3 c
m-3
)
Coe
ffici
ent o
f Diff
usio
n in
Air
(m2
s-1)
3-Jul-12
Soil-
to-d
ust t
rans
port
fact
or
(g
g-1 D
W)
Rel
ativ
e bi
oava
ilabi
lity
via
soil
inge
stio
n (u
nitle
ss)
Rel
ativ
e bi
oava
ilabi
lity
via
dust
in
hala
tion
(uni
tless
)
Coe
ffici
ent o
f Diff
usio
n in
Wat
er
(m2 s
-1)
log
K oc (
cm3 g
-1)
log
K ow (d
imen
sion
less
)
Der
mal
Abs
orpt
ion
Frac
tion
(dim
ensi
onle
ss)
CLEA v1.06 Software VPH EPH OUTDOOR VAPOUR
CLEA Software Version 1.06 Report generated Page 10 of 11
1 TPH Aliphatic C5-C6 2.83E+01 2.19E+04 3.59E+01 model model model model model model2 TPH Aliphatic C6-C8 1.32E+02 3.45E+03 5.37E+00 model model model model model model3 TPH Aliphatic C8-C10 1.05E+03 3.20E+02 4.27E-01 model model model model model model4 TPH Aliphatic C10-C12 8.35E+03 2.11E+01 3.39E-02 model model model model model model
5 TPH Aliphatic C12-C16 1.87E+05 1.53E+00 7.59E-04 model model model model model model
6 TPH Aliphatic C16-C35 2.00E+07 2.38E-02 2.54E-06 model model model model model model
7 TPH Aliphatic C35-C44 2.00E+07 2.38E-02 2.54E-06 model model model model model model
8 TPH Aromatic C5-C7 2.35E+00 6.24E+03 1.78E+03 model model model model model model
9 TPH Aromatic C7-C8 7.11E+00 1.73E+03 5.90E+02 model model model model model model10 TPH Aromatic C8-C10 5.52E+01 3.20E+02 6.46E+01 model model model model model model11 TPH Aromatic C10-C12 8.74E+01 3.21E+01 2.45E+01 model model model model model model12 TPH Aromatic C12-C16 1.74E+02 1.14E+00 5.75E+00 model model model model model model13 TPH Aromatic C16-C21 4.92E+02 5.62E-03 6.53E-01 model model model model model model14 TPH Aromatic C21-C35 4.38E+03 1.61E-06 6.61E-03 model model model model model model15 TPH Aromatic C35-C40 4.38E+03 1.61E-06 6.61E-03 model model model model model model1617181920
Vapo
ur p
ress
ure
(Pa)
Soil-
to-w
ater
par
titio
n co
effic
ient
(c
m3 g
-1)
3-Jul-12
Wat
er s
olub
ility
(mg
L-1)
Soil-
to-p
lant
con
cent
ratio
n fa
ctor
fo
r her
bace
ous
fruit
(m
g g-1
plan
t DW
or F
W b
asis
ove
r mg
g-1 D
W s
oil)
Soil-
to-p
lant
con
cent
ratio
n fa
ctor
fo
r shr
ub fr
uit
(m
g g-1
pla
nt D
W o
r FW
bas
is
over
mg
g-1 D
W s
oil)
Soil-
to-p
lant
con
cent
ratio
n fa
ctor
fo
r tre
e fru
it
(
mg
g-1
plan
t DW
or F
W b
asis
ove
r mg
g-1 D
W s
oil)
Soil-
to-p
lant
con
cent
ratio
n fa
ctor
fo
r tub
er v
eget
able
s
(mg
g-1
plan
t DW
or F
W b
asis
ove
r mg
g-1 D
W s
oil)
Soil-
to-p
lant
con
cent
ratio
n fa
ctor
fo
r roo
t veg
etab
les
(m
g g-1
plan
t DW
or F
W b
asis
ove
r mg
g-1 D
W s
oil)
Soil-
to-p
lant
con
cent
ratio
n fa
ctor
fo
r gre
en v
eget
able
s (m
g g-1
plan
t DW
or F
W b
asis
ove
r mg
g-1 D
W s
oil)
CLEA v1.06 Software VPH EPH OUTDOOR VAPOUR
CLEA Software Version 1.06 Report generated Page 11 of 11
21222324252627282930
Soil-
to-p
lant
con
cent
ratio
n fa
ctor
fo
r gre
en v
eget
able
s (m
g g-1
plan
t DW
or F
W b
asis
ove
r mg
g-1 D
W s
oil)
Soil-
to-w
ater
par
titio
n co
effic
ient
(c
m3 g
-1)
Soil-
to-p
lant
con
cent
ratio
n fa
ctor
fo
r tub
er v
eget
able
s
(mg
g-1
plan
t DW
or F
W b
asis
ove
r mg
g-1 D
W s
oil)
Soil-
to-p
lant
con
cent
ratio
n fa
ctor
fo
r her
bace
ous
fruit
(m
g g-1
plan
t DW
or F
W b
asis
ove
r mg
g-1 D
W s
oil)
Soil-
to-p
lant
con
cent
ratio
n fa
ctor
fo
r shr
ub fr
uit
(mg
g-1 p
lant
DW
or F
W b
asis
ov
er m
g g-1
DW
soi
l)
Soil-
to-p
lant
con
cent
ratio
n fa
ctor
fo
r tre
e fru
it
(
mg
g-1
plan
t DW
or F
W b
asis
ove
r mg
g-1 D
W s
oil)
3-Jul-12
Soil-
to-p
lant
con
cent
ratio
n fa
ctor
fo
r roo
t veg
etab
les
(m
g g-1
plan
t DW
or F
W b
asis
ove
r mg
g-1 D
W s
oil)
Vapo
ur p
ress
ure
(Pa)
Wat
er s
olub
ility
(mg
L-1)
CLEA v1.06 Software PAH & VOCs INDOOR VAPOUR
CLEA Software Version 1.06 Page 1 of 11
Report generated
Report title
Created by
RESULTS
Avesta
RB at Integral Geotechnique
03-Jul-12
CLEA v1.06 Software PAH & VOCs INDOOR VAPOUR
CLEA Software Version 1.06 Report generated Page 2 of 11
Assessment Criterion (mg kg-1) Ratio of ADE to HCV 50% rule?
oral inhalation combined oral inhalation combined Oral Inhal
1 Acenaphthene NR 2.05E+04 2.05E+04 0.00 1.00 1.00 3.36E+02 (sol) No No2 Acenaphthylene NR 1.92E+04 1.92E+04 0.00 1.00 1.00 5.06E+02 (sol) No No3 Anthracene NR 6.48E+05 6.48E+05 0.00 1.00 1.00 6.96E+00 (vap) No No4 Benz[a]anthracene NR 4.61E+01 4.61E+01 0.00 1.00 1.00 1.03E+01 (sol) No No5 Benzo[a]pyrene NR 1.46E+02 1.46E+02 0.00 1.00 1.00 5.46E+00 (vap) No No6 Benzo[b]fluoranthene NR 7.35E+02 7.35E+02 0.00 1.00 1.00 7.29E+00 (sol) No No7 Benzo[ghi]perylene NR 1.36E+04 1.36E+04 0.00 1.00 1.00 9.23E-02 (vap) No No8 Benzo[k]fluoranthene NR 1.70E+03 1.70E+03 0.00 1.00 1.00 4.12E+00 (sol) No No9 Chrysene NR 3.54E+02 3.54E+02 0.00 1.00 1.00 2.64E+00 (vap) No No
10 Dibenz[ah]anthracene NR 6.59E+01 6.59E+01 0.00 1.00 1.00 2.36E-02 (vap) No No11 Fluoranthene NR 1.70E+05 1.70E+05 0.00 1.00 1.00 1.13E+02 (vap) No No12 Fluorene NR 2.58E+04 2.58E+04 0.00 1.00 1.00 1.83E+02 (sol) No No13 Indeno[123-cd]pyrene NR 3.67E+02 3.67E+02 0.00 1.00 1.00 3.68E-01 (vap) No No14 Naphthalene NR 9.28E+00 9.28E+00 0.00 1.00 1.00 4.32E+02 (sol) No No15 Phenanthrene NR 3.03E+04 3.03E+04 0.00 1.00 1.00 2.14E+02 (sol) No No16 Pyrene NR 3.89E+05 3.89E+05 0.00 1.00 1.00 1.32E+01 (vap) No No17 Phenol NR 2.47E+03 2.47E+03 0.00 1.00 1.00 1.74E+05 (vap) No No18 Trichloroethene NR 5.11E-01 5.11E-01 0.00 1.00 1.00 7.14E+03 (vap) No No19 1,2-Dichloroethane NR 1.60E-02 1.60E-02 0.00 1.00 1.00 8.43E+03 (sol) No No20 Chloroethene (Vinyl Chloride) NR 1.07E-03 1.07E-03 0.00 1.00 1.00 2.69E+03 (sol) No No
3-Jul-12
Saturation Limit (mg kg-1)
CLEA v1.06 Software PAH & VOCs INDOOR VAPOUR
CLEA Software Version 1.06 Report generated Page 3 of 11
Assessment Criterion (mg kg-1) Ratio of ADE to HCV 50% rule?
oral inhalation combined oral inhalation combined Oral Inhal
21 Cis 1,2 Dichloroethene 3.93E-01 NR NR 1.00 NR NR 1.29E+04 (sol) No No222324252627282930
3-Jul-12
Saturation Limit (mg kg-1)
CLEA v1.06 Software PAH & VOCs INDOOR VAPOUR
CLEA Software Version 1.06 Report generated Page 4 of 11
Soil Distribution Media Concentrations
% % % % mg kg-1 mg m-3 mg kg-1 mg m-3 mg m-3 mg m-3 mg m-3 mg m-3 mg kg-1 FW mg kg-1 FW mg kg-1 FW mg kg-1 FW mg kg-1 FW mg kg-1 FW
1 Acenaphthene 99.7 0.3 0.0 100.0 2.05E+04 1.90E+02 NA NA NA 6.49E-02 NA NA NA NA NA NA NA NA2 Acenaphthylene 99.6 0.4 0.0 100.0 1.92E+04 1.72E+02 NA NA NA 6.49E-02 NA NA NA NA NA NA NA NA3 Anthracene 99.9 0.1 0.0 100.0 6.48E+05 5.98E+02 NA NA NA 3.24E-01 NA NA NA NA NA NA NA NA4 Benz[a]anthracene 100.0 0.0 0.0 100.0 4.61E+01 5.39E-04 NA NA NA 5.19E-07 NA NA NA NA NA NA NA NA
5 Benzo[a]pyrene 100.0 0.0 0.0 100.0 1.46E+02 5.74E-05 NA NA NA 7.57E-08 NA NA NA NA NA NA NA NA
6 Benzo[b]fluoranthene 100.0 0.0 0.0 100.0 7.35E+02 4.14E-04 NA NA NA 5.41E-07 NA NA NA NA NA NA NA NA
7 Benzo[ghi]perylene 100.0 0.0 0.0 100.0 1.36E+04 2.69E-03 NA NA NA 3.46E-06 NA NA NA NA NA NA NA NA
8 Benzo[k]fluoranthene 100.0 0.0 0.0 100.0 1.70E+03 5.74E-04 NA NA NA 7.57E-07 NA NA NA NA NA NA NA NA
9 Chrysene 100.0 0.0 0.0 100.0 3.54E+02 5.89E-04 NA NA NA 7.57E-07 NA NA NA NA NA NA NA NA10 Dibenz[ah]anthracene 100.0 0.0 0.0 100.0 6.59E+01 5.49E-05 NA NA NA 6.81E-08 NA NA NA NA NA NA NA NA11 Fluoranthene 100.0 0.0 0.0 100.0 1.70E+05 1.69E+01 NA NA NA 1.35E-02 NA NA NA NA NA NA NA NA12 Fluorene 99.7 0.3 0.0 100.0 2.58E+04 1.08E+02 NA NA NA 4.32E-02 NA NA NA NA NA NA NA NA13 Indeno[123-cd]pyrene 100.0 0.0 0.0 100.0 3.67E+02 2.49E-04 NA NA NA 3.24E-07 NA NA NA NA NA NA NA NA14 Naphthalene 98.8 1.2 0.0 100.0 9.28E+00 2.70E+00 NA NA NA 7.46E-04 NA NA NA NA NA NA NA NA15 Phenanthrene 99.9 0.1 0.0 100.0 3.03E+04 2.26E+01 NA NA NA 1.35E-02 NA NA NA NA NA NA NA NA16 Pyrene 100.0 0.0 0.0 100.0 3.89E+05 3.89E+01 NA NA NA 3.24E-02 NA NA NA NA NA NA NA NA17 Phenol 91.4 8.6 0.0 100.0 2.47E+03 6.51E+00 NA NA NA 8.19E-03 NA NA NA NA NA NA NA NA18 Trichloroethene 94.2 5.2 0.6 100.0 5.11E-01 1.83E+01 NA NA NA 5.62E-03 NA NA NA NA NA NA NA NA19 1,2-Dichloroethane 71.5 28.1 0.4 100.0 1.60E-02 3.92E-01 NA NA NA 1.30E-04 NA NA NA NA NA NA NA NA20 Chloroethene (Vinyl Chloride) 59.3 28.0 12.7 100.0 1.07E-03 8.24E-01 NA NA NA 3.24E-04 NA NA NA NA NA NA NA NA
Tube
r ve
geta
bles
Gre
en
vege
tabl
es
Roo
t ve
geta
bles
Indo
or
Vapo
ur
Out
door
va
pour
at
0.8m
Out
door
va
pour
at
1.6m
Soil
gas
Out
door
dus
t at
0.8
m
Out
door
dus
t at
1.6
m
3-Jul-12
Soil
Indo
or D
ust
Sor
bed
Dis
solv
ed
Vap
our
Tota
l
Her
bace
ous
fruit
Shru
b fru
it
Tree
frui
t
CLEA v1.06 Software PAH & VOCs INDOOR VAPOUR
CLEA Software Version 1.06 Report generated Page 5 of 11
Soil Distribution Media Concentrations
% % % % mg kg-1 mg m-3 mg kg-1 mg m-3 mg m-3 mg m-3 mg m-3 mg m-3 mg kg-1 FW mg kg-1 FW mg kg-1 FW mg kg-1 FW mg kg-1 FW mg kg-1 FW
21 Cis 1,2 Dichloroethene 83.3 16.0 0.7 100.0 3.93E-01 1.72E+01 NA NA NA 5.85E-03 NA NA NA NA NA NA NA NA222324252627282930
3-Jul-12
Sor
bed
Dis
solv
ed
Vap
our
Tota
l
Soil
Indo
or
Vapo
ur
Indo
or D
ust
Soil
gas
Out
door
dus
t at
0.8
m
Out
door
dus
t at
1.6
m
Out
door
va
pour
at
0.8m
Out
door
va
pour
at
1.6m
Gre
en
vege
tabl
es
Roo
t ve
geta
bles
Tube
r ve
geta
bles
Her
bace
ous
fruit
Shru
b fru
it
Tree
frui
t
CLEA v1.06 Software PAH & VOCs INDOOR VAPOUR
CLEA Software Version 1.06 Report generated Page 6 of 11
Average Daily Exposure (mg kg-1 bw day-1) Distribution by Pathway (%)
1 Acenaphthene 0.00E+00 0.00E+00 0.00E+00 0.00E+00 6.00E-02 5.51E-05 1.52E-06 0.00 0.00 0.00 0.00 100.00 0.00 0.00 0.002 Acenaphthylene 0.00E+00 0.00E+00 0.00E+00 0.00E+00 6.00E-02 7.88E-06 6.67E-07 0.00 0.00 0.00 0.00 100.00 0.00 0.00 0.003 Anthracene 0.00E+00 0.00E+00 0.00E+00 0.00E+00 3.00E-01 4.50E-06 2.49E-06 0.00 0.00 0.00 0.00 100.00 0.00 0.00 0.004 Benz[a]anthracene 0.00E+00 0.00E+00 0.00E+00 0.00E+00 4.80E-07 0.00E+00 0.00E+00 0.00 0.00 0.00 0.00 100.00 0.00 0.00 0.00
5 Benzo[a]pyrene 0.00E+00 0.00E+00 0.00E+00 0.00E+00 7.00E-08 0.00E+00 0.00E+00 0.00 0.00 0.00 0.00 100.00 0.00 0.00 0.00
6 Benzo[b]fluoranthene 0.00E+00 0.00E+00 0.00E+00 0.00E+00 5.00E-07 0.00E+00 0.00E+00 0.00 0.00 0.00 0.00 100.00 0.00 0.00 0.00
7 Benzo[ghi]perylene 0.00E+00 0.00E+00 0.00E+00 0.00E+00 3.20E-06 0.00E+00 0.00E+00 0.00 0.00 0.00 0.00 100.00 0.00 0.00 0.00
8 Benzo[k]fluoranthene 0.00E+00 0.00E+00 0.00E+00 0.00E+00 7.00E-07 0.00E+00 0.00E+00 0.00 0.00 0.00 0.00 100.00 0.00 0.00 0.00
9 Chrysene 0.00E+00 0.00E+00 0.00E+00 0.00E+00 7.00E-07 0.00E+00 0.00E+00 0.00 0.00 0.00 0.00 100.00 0.00 0.00 0.0010 Dibenz[ah]anthracene 0.00E+00 0.00E+00 0.00E+00 0.00E+00 6.30E-08 0.00E+00 0.00E+00 0.00 0.00 0.00 0.00 100.00 0.00 0.00 0.0011 Fluoranthene 0.00E+00 0.00E+00 0.00E+00 0.00E+00 1.25E-02 1.97E-05 5.09E-06 0.00 0.00 0.00 0.00 99.96 0.00 0.00 0.0412 Fluorene 0.00E+00 0.00E+00 0.00E+00 0.00E+00 4.00E-02 3.32E-05 5.82E-06 0.00 0.00 0.00 0.00 99.99 0.00 0.00 0.0113 Indeno[123-cd]pyrene 0.00E+00 0.00E+00 0.00E+00 0.00E+00 3.00E-07 0.00E+00 0.00E+00 0.00 0.00 0.00 0.00 100.00 0.00 0.00 0.0014 Naphthalene 0.00E+00 0.00E+00 0.00E+00 0.00E+00 6.90E-04 3.94E-04 1.70E-04 0.00 0.00 0.00 0.00 80.26 0.00 0.00 19.7415 Phenanthrene 0.00E+00 0.00E+00 0.00E+00 0.00E+00 1.25E-02 8.66E-05 3.14E-05 0.00 0.00 0.00 0.00 99.75 0.00 0.00 0.2516 Pyrene 0.00E+00 0.00E+00 0.00E+00 0.00E+00 3.00E-02 2.42E-05 3.94E-06 0.00 0.00 0.00 0.00 99.99 0.00 0.00 0.0117 Phenol 0.00E+00 0.00E+00 0.00E+00 0.00E+00 7.58E-03 1.97E-02 2.42E-03 0.00 0.00 0.00 0.00 75.75 0.00 0.00 24.2518 Trichloroethene 0.00E+00 0.00E+00 0.00E+00 0.00E+00 5.20E-03 0.00E+00 0.00E+00 0.00 0.00 0.00 0.00 100.00 0.00 0.00 0.0019 1,2-Dichloroethane 0.00E+00 0.00E+00 0.00E+00 0.00E+00 1.20E-04 0.00E+00 0.00E+00 0.00 0.00 0.00 0.00 100.00 0.00 0.00 0.0020 Chloroethene (Vinyl Chloride) 0.00E+00 0.00E+00 0.00E+00 0.00E+00 3.00E-04 0.00E+00 0.00E+00 0.00 0.00 0.00 0.00 100.00 0.00 0.00 0.00
Inha
latio
n of
vap
our
Back
grou
nd (o
ral)
Back
grou
nd (o
ral)
Back
grou
nd
(inha
latio
n)
Inha
latio
n of
vap
our
(indo
or)
Dire
ct s
oil i
nges
tion
Con
sum
ptio
n of
ho
meg
row
n pr
oduc
e an
d at
tach
ed s
oil
Der
mal
con
tact
with
so
il an
d du
st
Inha
latio
n of
dus
t
3-Jul-12
Con
sum
ptio
n of
ho
meg
row
n pr
oduc
e an
d at
tach
ed s
oil
Der
mal
con
tact
with
so
il an
d du
st
Inha
latio
n of
dus
t
Back
grou
nd
(inha
latio
n)
Dire
ct s
oil i
nges
tion
Inha
latio
n of
vap
our
(out
door
)
CLEA v1.06 Software PAH & VOCs INDOOR VAPOUR
CLEA Software Version 1.06 Report generated Page 7 of 11
Average Daily Exposure (mg kg-1 bw day-1) Distribution by Pathway (%)
21 Cis 1,2 Dichloroethene 0.00E+00 0.00E+00 0.00E+00 0.00E+00 5.41E-03 2.25E-04 3.64E-04 0.00 0.00 0.00 0.00 90.19 0.00 9.81 0.00222324252627282930
3-Jul-12
Dire
ct s
oil i
nges
tion
Con
sum
ptio
n of
ho
meg
row
n pr
oduc
e an
d at
tach
ed s
oil
Der
mal
con
tact
with
so
il an
d du
st
Inha
latio
n of
dus
t
Inha
latio
n of
vap
our
Back
grou
nd (o
ral)
Back
grou
nd
(inha
latio
n)
Dire
ct s
oil i
nges
tion
Con
sum
ptio
n of
ho
meg
row
n pr
oduc
e
Der
mal
con
tact
with
so
il an
d du
st
Inha
latio
n of
dus
t
Inha
latio
n of
vap
our
(indo
or)
Back
grou
nd (o
ral)
Back
grou
nd
(inha
latio
n)
Inha
latio
n of
vap
our
(out
door
)
CLEA v1.06 Software PAH & VOCs INDOOR VAPOUR
CLEA Software Version 1.06 Report generated Page 8 of 11
1 Acenaphthene TDI 60 TDI 60 0.98 0.025 7.59E-04 5.85E-06 4.70E-10 3.37 4.03 0.13 0.5 1 1 12 Acenaphthylene TDI 60 TDI 60 0.14 0.011 5.68E-04 5.97E-06 4.82E-10 3.26 3.91 0.13 0.5 1 1 13 Anthracene TDI 300 TDI 300 0.08 0.041 1.81E-04 5.36E-06 4.36E-10 3.75 4.5 0.13 0.5 1 1 14 Benz[a]anthracene ID 0.138 ID 0.00048 NR NR 3.16E-05 4.60E-06 3.80E-10 4.89 5.91 0.13 0.5 1 1 1
5 Benzo[a]pyrene ID 0.02 ID 0.00007 NR NR 1.76E-06 4.38E-06 3.67E-10 5.11 6.18 0.13 0.5 1 1 1
6 Benzo[b]fluoranthene ID 0.142 ID 0.0005 NR NR 2.05E-06 4.36E-06 3.62E-10 5.02 6.08 0.13 0.5 1 1 1
7 Benzo[ghi]perylene ID 0.909 ID 0.0032 NR NR 2.86E-06 4.22E-06 3.56E-10 5.62 6.81 0.13 0.5 1 1 1
8 Benzo[k]fluoranthene ID 0.2 ID 0.0007 NR NR 1.74E-06 4.36E-06 3.62E-10 5.17 6.26 0.13 0.5 1 1 1
9 Chrysene ID 0.2 ID 0.0007 NR NR 3.18E-06 4.57E-06 3.77E-10 4.74 5.73 0.13 0.5 1 1 110 Dibenz[ah]anthracene ID 0.018 ID 0.000063 NR NR 5.40E-06 4.08E-06 3.40E-10 5.27 6.38 0.13 0.5 1 1 111 Fluoranthene TDI 12.5 TDI 12.5 0.35 0.084 6.29E-05 5.01E-06 4.11E-10 4.26 5.13 0.13 0.5 1 1 112 Fluorene TDI 40 TDI 40 0.59 0.096 4.12E-04 5.58E-06 4.47E-10 3.45 4.13 0.13 0.5 1 1 113 Indeno[123-cd]pyrene ID 0.086 ID 0.0003 NR NR 2.05E-06 4.17E-06 3.51E-10 4.94 5.97 0.13 0.5 1 1 114 Naphthalene TDI 20 TDI 0.86 7 2.8 6.62E-03 6.52E-06 5.16E-10 2.81 3.34 0.13 0.5 1 1 115 Phenanthrene TDI 12.5 TDI 12.5 1.54 0.518 1.43E-04 5.34E-06 4.32E-10 3.74 4.5 0.13 0.5 1 1 116 Pyrene TDI 30 TDI 30 0.43 0.065 5.64E-05 5.01E-06 4.15E-10 4.21 5.08 0.13 0.5 1 1 117 Phenol TDI 700 TDI 10 350 40 8.35E-06 7.90E-06 6.36E-10 1.92 1.48 0.3 0.5 1 1 118 Trichloroethene ID 5.2 ID 5.2 NR NR 1.87E-01 7.91E-06 6.23E-10 2.15 2.53 0.1 0.5 1 1 119 1,2-Dichloroethane ID 0.12 ID 0.12 NR NR 2.38E-02 8.60E-06 6.74E-10 1.3 1.48 0.1 0.5 1 1 120 Chloroethene (Vinyl Chloride) ID 0.014 ID 0.3 NR NR 7.47E-01 1.11E-05 8.34E-10 1.22 1.38 0.1 0.5 1 1 1
Rel
ativ
e bi
oava
ilabi
lity
via
soil
inge
stio
n (u
nitle
ss)
3-Jul-12
Ora
l Hea
lth C
riter
ia V
alue
(μ
g kg
-1 B
W d
ay-1
)
Inha
latio
n M
ean
Dai
ly In
take
(μ
g da
y-1)
log
K oc (
cm3 g
-1)
log
K ow (d
imen
sion
less
)
Coe
ffici
ent o
f Diff
usio
n in
Wat
er
(m2 s
-1)
Inha
latio
n H
ealth
Crit
eria
Val
ue
(μg
kg-1
BW
day
-1)
Ora
l Mea
n D
aily
Inta
ke
(μ
g da
y-1)
Air-
wat
er p
artit
ion
coef
ficie
nt
(Kaw
) (c
m3 c
m-3
)
Coe
ffici
ent o
f Diff
usio
n in
Air
(m2
s-1)
Rel
ativ
e bi
oava
ilabi
lity
via
dust
in
hala
tion
(uni
tless
)
Der
mal
Abs
orpt
ion
Frac
tion
(dim
ensi
onle
ss)
Soil-
to-d
ust t
rans
port
fact
or
(g
g-1 D
W)
Sub-
surfa
ce s
oil t
o in
door
air
corr
ectio
n fa
ctor
(d
imen
sion
less
)
CLEA v1.06 Software PAH & VOCs INDOOR VAPOUR
CLEA Software Version 1.06 Report generated Page 9 of 11
21 Cis 1,2 Dichloroethene TDI 6 NR 0 4 6 7.46E-02 9.02E-06 7.08E-10 1.61 1.86 0.1 0.5 1 1 1222324252627282930
Rel
ativ
e bi
oava
ilabi
lity
via
soil
inge
stio
n (u
nitle
ss)
Rel
ativ
e bi
oava
ilabi
lity
via
dust
in
hala
tion
(uni
tless
)
Coe
ffici
ent o
f Diff
usio
n in
Wat
er
(m2 s
-1)
log
K oc (
cm3 g
-1)
log
K ow (d
imen
sion
less
)
Der
mal
Abs
orpt
ion
Frac
tion
(dim
ensi
onle
ss)
3-Jul-12
Soil-
to-d
ust t
rans
port
fact
or
(g
g-1 D
W)
Inha
latio
n M
ean
Dai
ly In
take
(μ
g da
y-1)
Air-
wat
er p
artit
ion
coef
ficie
nt
(Kaw
) (c
m3 c
m-3
)
Coe
ffici
ent o
f Diff
usio
n in
Air
(m2
s-1)
Ora
l Hea
lth C
riter
ia V
alue
(μ
g kg
-1 B
W d
ay-1
)
Inha
latio
n H
ealth
Crit
eria
Val
ue
(μg
kg-1
BW
day
-1)
Ora
l Mea
n D
aily
Inta
ke
(μ
g da
y-1)
Sub-
surfa
ce s
oil t
o in
door
air
corr
ectio
n fa
ctor
(d
imen
sion
less
)
CLEA v1.06 Software PAH & VOCs INDOOR VAPOUR
CLEA Software Version 1.06 Report generated Page 10 of 11
1 Acenaphthene 8.16E+01 7.37E-02 4.11E+00 model model model model model model2 Acenaphthylene 6.33E+01 7.08E-02 7.95E+00 model model model model model model3 Anthracene 1.96E+02 8.49E-05 5.60E-02 model model model model model model4 Benz[a]anthracene 2.70E+03 1.24E-06 3.80E-03 model model model model model model
5 Benzo[a]pyrene 4.48E+03 2.00E-08 3.80E-03 model model model model model model
6 Benzo[b]fluoranthene 3.64E+03 6.34E-08 2.00E-03 model model model model model model
7 Benzo[ghi]perylene 1.45E+04 1.55E-10 2.64E-04 model model model model model model
8 Benzo[k]fluoranthene 5.15E+03 1.64E-08 8.00E-04 model model model model model model
9 Chrysene 1.91E+03 4.52E-08 2.00E-03 model model model model model model10 Dibenz[ah]anthracene 6.48E+03 1.66E-10 6.00E-04 model model model model model model11 Fluoranthene 6.33E+02 1.31E-04 2.30E-01 model model model model model model12 Fluorene 9.81E+01 1.56E-02 1.86E+00 model model model model model model13 Indeno[123-cd]pyrene 3.03E+03 2.12E-09 2.00E-04 model model model model model model14 Naphthalene 2.25E+01 2.31E+00 1.90E+01 model model model model model model15 Phenanthrene 1.91E+02 2.82E-03 1.12E+00 model model model model model model16 Pyrene 5.64E+02 1.53E-05 1.30E-01 model model model model model model17 Phenol 2.89E+00 1.15E+01 8.41E+04 model model model 0.00E+00 0.00E+00 model18 Trichloroethene 4.92E+00 4.58E+03 1.37E+03 model model model model model model19 1,2-Dichloroethane 6.94E-01 4.92E+03 8.68E+03 model model model model model model20 Chloroethene (Vinyl Chloride) 5.78E-01 2.20E+05 2.76E+03 model model model model model model
Wat
er s
olub
ility
(mg
L-1)
Soil-
to-p
lant
con
cent
ratio
n fa
ctor
fo
r her
bace
ous
fruit
(m
g g-1
plan
t DW
or F
W b
asis
ove
r mg
g-1 D
W s
oil)
Soil-
to-p
lant
con
cent
ratio
n fa
ctor
fo
r shr
ub fr
uit
(m
g g-1
pla
nt D
W o
r FW
bas
is
over
mg
g-1 D
W s
oil)
Soil-
to-p
lant
con
cent
ratio
n fa
ctor
fo
r tre
e fru
it
(
mg
g-1
plan
t DW
or F
W b
asis
ove
r mg
g-1 D
W s
oil)
Soil-
to-p
lant
con
cent
ratio
n fa
ctor
fo
r tub
er v
eget
able
s
(mg
g-1
plan
t DW
or F
W b
asis
ove
r mg
g-1 D
W s
oil)
Soil-
to-p
lant
con
cent
ratio
n fa
ctor
fo
r roo
t veg
etab
les
(m
g g-1
plan
t DW
or F
W b
asis
ove
r mg
g-1 D
W s
oil)
Soil-
to-p
lant
con
cent
ratio
n fa
ctor
fo
r gre
en v
eget
able
s (m
g g-1
plan
t DW
or F
W b
asis
ove
r mg
g-1 D
W s
oil)
3-Jul-12
Soil-
to-w
ater
par
titio
n co
effic
ient
(c
m3 g
-1)
Vapo
ur p
ress
ure
(Pa)
CLEA v1.06 Software PAH & VOCs INDOOR VAPOUR
CLEA Software Version 1.06 Report generated Page 11 of 11
21 Cis 1,2 Dichloroethene 1.42E+00 1.37E+04 7.55E+03 Model Model Model Model Model Model222324252627282930
Soil-
to-p
lant
con
cent
ratio
n fa
ctor
fo
r her
bace
ous
fruit
(m
g g-1
plan
t DW
or F
W b
asis
ove
r mg
g-1 D
W s
oil)
Soil-
to-p
lant
con
cent
ratio
n fa
ctor
fo
r shr
ub fr
uit
(mg
g-1 p
lant
DW
or F
W b
asis
ov
er m
g g-1
DW
soi
l)
Soil-
to-p
lant
con
cent
ratio
n fa
ctor
fo
r tre
e fru
it
(
mg
g-1
plan
t DW
or F
W b
asis
ove
r mg
g-1 D
W s
oil)
3-Jul-12
Soil-
to-p
lant
con
cent
ratio
n fa
ctor
fo
r roo
t veg
etab
les
(m
g g-1
plan
t DW
or F
W b
asis
ove
r mg
g-1 D
W s
oil)
Vapo
ur p
ress
ure
(Pa)
Wat
er s
olub
ility
(mg
L-1)
Soil-
to-p
lant
con
cent
ratio
n fa
ctor
fo
r gre
en v
eget
able
s (m
g g-1
plan
t DW
or F
W b
asis
ove
r mg
g-1 D
W s
oil)
Soil-
to-w
ater
par
titio
n co
effic
ient
(c
m3 g
-1)
Soil-
to-p
lant
con
cent
ratio
n fa
ctor
fo
r tub
er v
eget
able
s
(mg
g-1
plan
t DW
or F
W b
asis
ove
r mg
g-1 D
W s
oil)
CLEA v1.06 Software VPH EPH INDOOR VAPOUR
CLEA Software Version 1.06 Page 1 of 11
Report generated
Report title
Created by
RESULTS
03-Jul-12
Avesta TPH
RB at Integral Geotechnique
CLEA v1.06 Software VPH EPH INDOOR VAPOUR
CLEA Software Version 1.06 Report generated Page 2 of 11
Assessment Criterion (mg kg-1) Ratio of ADE to HCV 50% rule?
oral inhalation combined oral inhalation combined Oral Inhal
1 TPH Aliphatic C5-C6 NR 1.13E+02 1.13E+02 0.00 1.00 1.00 1.15E+03 (sol) Yes Yes2 TPH Aliphatic C6-C8 NR 3.72E+02 3.72E+02 0.00 1.00 1.00 7.36E+02 (sol) Yes Yes3 TPH Aliphatic C8-C10 NR 1.09E+02 1.09E+02 0.00 1.00 1.00 4.51E+02 (vap) Yes Yes4 TPH Aliphatic C10-C12 NR 5.57E+02 5.57E+02 0.00 1.00 1.00 1.86E+02 (vap) Yes Yes5 TPH Aliphatic C12-C16 NR 4.69E+03 4.69E+03 0.00 1.00 1.00 1.42E+02 (sol) Yes Yes6 TPH Aliphatic C16-C35 NR 6.34E+13 6.34E+13 0.00 0.00 0.00 5.09E+01 (sol) Yes No7 TPH Aliphatic C35-C44 NR 6.34E+13 6.34E+13 0.00 0.00 0.00 5.09E+01 (sol) Yes No8 TPH Aromatic C5-C7 NR 1.04E+00 1.04E+00 0.00 1.00 1.00 4.71E+03 (sol) No No9 TPH Aromatic C7-C8 NR 3.14E+03 3.14E+03 0.00 1.00 1.00 4.36E+03 (vap) No No
10 TPH Aromatic C8-C10 NR 1.94E+02 1.94E+02 0.00 1.00 1.00 3.58E+03 (vap) Yes Yes11 TPH Aromatic C10-C12 NR 1.07E+03 1.07E+03 0.00 1.00 1.00 2.15E+03 (sol) Yes Yes12 TPH Aromatic C12-C16 NR 1.19E+04 1.19E+04 0.00 1.00 1.00 1.00E+03 (sol) Yes Yes13 TPH Aromatic C16-C21 NR NR NR 0.00 0.00 0.00 3.21E+02 (vap) Yes No14 TPH Aromatic C21-C35 NR NR NR 0.00 0.00 0.00 2.90E+01 (sol) Yes No15 TPH Aromatic C35-C40 NR NR NR 0.00 0.00 0.00 2.90E+01 (sol) Yes No1617181920
3-Jul-12
Saturation Limit (mg kg-1)
CLEA v1.06 Software VPH EPH INDOOR VAPOUR
CLEA Software Version 1.06 Report generated Page 3 of 11
Assessment Criterion (mg kg-1) Ratio of ADE to HCV 50% rule?
oral inhalation combined oral inhalation combined Oral Inhal
21222324252627282930
Saturation Limit (mg kg-1)
3-Jul-12
CLEA v1.06 Software VPH EPH INDOOR VAPOUR
CLEA Software Version 1.06 Report generated Page 4 of 11
Soil Distribution Media Concentrations
% % % % mg kg-1 mg m-3 mg kg-1 mg m-3 mg m-3 mg m-3 mg m-3 mg m-3 mg kg-1 FW mg kg-1 FW mg kg-1 FW mg kg-1 FW mg kg-1 FW mg kg-1 FW
1 TPH Aliphatic C5-C6 88.3 0.9 10.8 100.0 1.13E+02 7.40E+04 NA NA NA 2.70E+00 NA NA NA NA NA NA NA NA2 TPH Aliphatic C6-C8 96.5 0.2 3.3 100.0 3.72E+02 7.40E+04 NA NA NA 2.70E+00 NA NA NA NA NA NA NA NA3 TPH Aliphatic C8-C10 99.3 0.0 0.6 100.0 1.09E+02 4.29E+03 NA NA NA 1.57E-01 NA NA NA NA NA NA NA NA4 TPH Aliphatic C10-C12 99.9 0.0 0.1 100.0 5.57E+02 4.29E+03 NA NA NA 1.57E-01 NA NA NA NA NA NA NA NA
5 TPH Aliphatic C12-C16 100.0 0.0 0.0 100.0 4.69E+03 4.29E+03 NA NA NA 1.57E-01 NA NA NA NA NA NA NA NA
6 TPH Aliphatic C16-C35 100.0 0.0 0.0 100.0 6.34E+13 3.39E+12 NA NA NA 1.24E+08 NA NA NA NA NA NA NA NA
7 TPH Aliphatic C35-C44 100.0 0.0 0.0 100.0 6.34E+13 3.39E+12 NA NA NA 1.24E+08 NA NA NA NA NA NA NA NA
8 TPH Aromatic C5-C7 89.0 10.3 0.7 100.0 1.04E+00 4.55E+01 NA NA NA 1.51E-03 NA NA NA NA NA NA NA NA
9 TPH Aromatic C7-C8 96.1 3.7 0.3 100.0 3.14E+03 4.88E+04 NA NA NA 1.48E+00 NA NA NA NA NA NA NA NA10 TPH Aromatic C8-C10 99.4 0.5 0.1 100.0 1.94E+02 8.86E+02 NA NA NA 3.24E-02 NA NA NA NA NA NA NA NA11 TPH Aromatic C10-C12 99.7 0.3 0.0 100.0 1.07E+03 8.83E+02 NA NA NA 3.24E-02 NA NA NA NA NA NA NA NA12 TPH Aromatic C12-C16 99.8 0.2 0.0 100.0 1.19E+04 8.62E+02 NA NA NA 3.24E-02 NA NA NA NA NA NA NA NA13 TPH Aromatic C16-C21 99.9 0.1 0.0 100.0 -3.36E-10 -4.74E-13 NA NA NA -2.53E-17 NA NA NA NA NA NA NA NA14 TPH Aromatic C21-C35 100.0 0.0 0.0 100.0 -3.36E-10 -1.90E-15 NA NA NA -2.27E-19 NA NA NA NA NA NA NA NA15 TPH Aromatic C35-C40 100.0 0.0 0.0 100.0 -3.36E-10 -1.90E-15 NA NA NA -2.27E-19 NA NA NA NA NA NA NA NA1617181920
Her
bace
ous
fruit
Shru
b fru
it
Tree
frui
t
3-Jul-12
Soil
Indo
or D
ust
Sor
bed
Dis
solv
ed
Vap
our
Tota
l
Gre
en
vege
tabl
es
Roo
t ve
geta
bles
Indo
or
Vapo
ur
Out
door
va
pour
at
0.8m
Out
door
va
pour
at
1.6m
Soil
gas
Out
door
dus
t at
0.8
m
Out
door
dus
t at
1.6
m
Tube
r ve
geta
bles
CLEA v1.06 Software VPH EPH INDOOR VAPOUR
CLEA Software Version 1.06 Report generated Page 5 of 11
Soil Distribution Media Concentrations
% % % % mg kg-1 mg m-3 mg kg-1 mg m-3 mg m-3 mg m-3 mg m-3 mg m-3 mg kg-1 FW mg kg-1 FW mg kg-1 FW mg kg-1 FW mg kg-1 FW mg kg-1 FW
21222324252627282930
Her
bace
ous
fruit
Shru
b fru
it
Tree
frui
t
Out
door
va
pour
at
0.8m
Out
door
va
pour
at
1.6m
Gre
en
vege
tabl
es
Roo
t ve
geta
bles
Tube
r ve
geta
bles
Indo
or
Vapo
ur
Indo
or D
ust
Soil
gas
Out
door
dus
t at
0.8
m
Out
door
dus
t at
1.6
m
Soil
3-Jul-12
Sor
bed
Dis
solv
ed
Vap
our
Tota
l
CLEA v1.06 Software VPH EPH INDOOR VAPOUR
CLEA Software Version 1.06 Report generated Page 6 of 11
Average Daily Exposure (mg kg-1 bw day-1) Distribution by Pathway (%)
1 TPH Aliphatic C5-C6 0.00E+00 0.00E+00 0.00E+00 0.00E+00 2.50E+00 5.62E+95 6.06E+95 0.00 0.00 0.00 0.00 50.00 0.00 0.00 50.002 TPH Aliphatic C6-C8 0.00E+00 0.00E+00 0.00E+00 0.00E+00 2.50E+00 5.62E+95 6.06E+95 0.00 0.00 0.00 0.00 50.00 0.00 0.00 50.003 TPH Aliphatic C8-C10 0.00E+00 0.00E+00 0.00E+00 0.00E+00 1.45E-01 5.62E+95 6.06E+95 0.00 0.00 0.00 0.00 50.00 0.00 0.00 50.004 TPH Aliphatic C10-C12 0.00E+00 0.00E+00 0.00E+00 0.00E+00 1.45E-01 5.62E+95 6.06E+95 0.00 0.00 0.00 0.00 50.00 0.00 0.00 50.00
5 TPH Aliphatic C12-C16 0.00E+00 0.00E+00 0.00E+00 0.00E+00 1.45E-01 5.62E+95 6.06E+95 0.00 0.00 0.00 0.00 50.00 0.00 0.00 50.00
6 TPH Aliphatic C16-C35 0.00E+00 0.00E+00 0.00E+00 0.00E+00 1.14E+08 5.62E+95 0.00E+00 0.00 0.00 0.00 0.00 100.00 0.00 0.00 0.00
7 TPH Aliphatic C35-C44 0.00E+00 0.00E+00 0.00E+00 0.00E+00 1.14E+08 5.62E+95 0.00E+00 0.00 0.00 0.00 0.00 100.00 0.00 0.00 0.00
8 TPH Aromatic C5-C7 0.00E+00 0.00E+00 0.00E+00 0.00E+00 1.40E-03 1.69E-04 1.21E-02 0.00 0.00 0.00 0.00 100.00 0.00 0.00 0.00
9 TPH Aromatic C7-C8 0.00E+00 0.00E+00 0.00E+00 0.00E+00 1.37E+00 5.63E-04 3.15E-02 0.00 0.00 0.00 0.00 97.75 0.00 0.00 2.2510 TPH Aromatic C8-C10 0.00E+00 0.00E+00 0.00E+00 0.00E+00 3.00E-02 5.62E+95 6.06E+95 0.00 0.00 0.00 0.00 50.00 0.00 0.00 50.0011 TPH Aromatic C10-C12 0.00E+00 0.00E+00 0.00E+00 0.00E+00 3.00E-02 5.62E+95 6.06E+95 0.00 0.00 0.00 0.00 50.00 0.00 0.00 50.0012 TPH Aromatic C12-C16 0.00E+00 0.00E+00 0.00E+00 0.00E+00 3.00E-02 5.62E+95 6.06E+95 0.00 0.00 0.00 0.00 50.00 0.00 0.00 50.0013 TPH Aromatic C16-C21 0.00E+00 0.00E+00 0.00E+00 0.00E+00 -2.34E-17 5.62E+95 0.00E+00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.0014 TPH Aromatic C21-C35 0.00E+00 0.00E+00 0.00E+00 0.00E+00 -2.10E-19 5.62E+95 0.00E+00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.0015 TPH Aromatic C35-C40 0.00E+00 0.00E+00 0.00E+00 0.00E+00 -2.10E-19 5.62E+95 0.00E+00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.001617181920
Inha
latio
n of
vap
our
(out
door
)
3-Jul-12
Con
sum
ptio
n of
ho
meg
row
n pr
oduc
e an
d at
tach
ed s
oil
Der
mal
con
tact
with
so
il an
d du
st
Inha
latio
n of
dus
t
Back
grou
nd
(inha
latio
n)
Dire
ct s
oil i
nges
tion
Back
grou
nd (o
ral)
Back
grou
nd
(inha
latio
n)
Inha
latio
n of
vap
our
(indo
or)
Dire
ct s
oil i
nges
tion
Con
sum
ptio
n of
ho
meg
row
n pr
oduc
e an
d at
tach
ed s
oil
Der
mal
con
tact
with
so
il an
d du
st
Inha
latio
n of
dus
t
Inha
latio
n of
vap
our
Back
grou
nd (o
ral)
CLEA v1.06 Software VPH EPH INDOOR VAPOUR
CLEA Software Version 1.06 Report generated Page 7 of 11
Average Daily Exposure (mg kg-1 bw day-1) Distribution by Pathway (%)
21222324252627282930
Inha
latio
n of
vap
our
(out
door
)
Con
sum
ptio
n of
ho
meg
row
n pr
oduc
e
Der
mal
con
tact
with
so
il an
d du
st
Inha
latio
n of
dus
t
Inha
latio
n of
vap
our
(indo
or)
Back
grou
nd (o
ral)
Back
grou
nd
(inha
latio
n)
3-Jul-12
Dire
ct s
oil i
nges
tion
Con
sum
ptio
n of
ho
meg
row
n pr
oduc
e an
d at
tach
ed s
oil
Der
mal
con
tact
with
so
il an
d du
st
Inha
latio
n of
dus
t
Inha
latio
n of
vap
our
Back
grou
nd (o
ral)
Back
grou
nd
(inha
latio
n)
Dire
ct s
oil i
nges
tion
CLEA v1.06 Software VPH EPH INDOOR VAPOUR
CLEA Software Version 1.06 Report generated Page 8 of 11
1 TPH Aliphatic C5-C6 TDI 5000 TDI 5000 9.99E+99 9.99E+99 2.10E+01 1.00E-05 1.00E-09 2.91 3.31 0.1 0.5 10 1 12 TPH Aliphatic C6-C8 TDI 5000 TDI 5000 9.99E+99 9.99E+99 2.73E+01 1.00E-05 1.00E-09 3.58 4.13 0.1 0.5 10 1 13 TPH Aliphatic C8-C10 TDI 100 TDI 290 9.99E+99 9.99E+99 4.15E+01 1.00E-05 1.00E-09 4.48 5.22 0.1 0.5 10 1 14 TPH Aliphatic C10-C12 TDI 100 TDI 290 9.99E+99 9.99E+99 6.44E+01 1.00E-05 1.00E-09 5.38 6.3 0.1 0.5 10 1 1
5 TPH Aliphatic C12-C16 TDI 100 TDI 290 9.99E+99 9.99E+99 1.71E+02 1.00E-05 1.00E-09 6.73 7.94 0.1 0.5 10 1 1
6 TPH Aliphatic C16-C35 TDI 2000 TDI 9E+99 9.99E+99 0 1.07E+03 1.00E-05 1.00E-09 8.76 10.39 0.1 0.5 10 1 1
7 TPH Aliphatic C35-C44 TDI 2000 TDI 9E+99 9.99E+99 0 1.07E+03 1.00E-05 1.00E-09 8.76 10.39 0.1 0.5 10 1 1
8 TPH Aromatic C5-C7 ID 0.29 ID 1.4 3 200 1.16E-01 8.77E-06 6.64E-10 1.83 2.13 0.1 0.5 10 1 1
9 TPH Aromatic C7-C8 TDI 223 TDI 1400 10 520 1.15E-01 7.78E-06 5.88E-10 2.31 2.73 0.1 0.5 10 1 110 TPH Aromatic C8-C10 TDI 40 TDI 60 9.99E+99 9.99E+99 2.53E-01 1.00E-05 1.00E-09 3.2 3.69 0.1 0.5 10 1 111 TPH Aromatic C10-C12 TDI 40 TDI 60 9.99E+99 9.99E+99 7.22E-02 1.00E-05 1.00E-09 3.4 3.93 0.1 0.5 10 1 112 TPH Aromatic C12-C16 TDI 40 TDI 60 9.99E+99 9.99E+99 1.26E-02 1.00E-05 1.00E-09 3.7 4.29 0.1 0.5 10 1 113 TPH Aromatic C16-C21 TDI 30 TDI 9E+99 9.99E+99 0 6.95E-04 1.00E-05 1.00E-09 4.15 4.82 0.1 0.5 10 1 114 TPH Aromatic C21-C35 TDI 30 TDI 9E+99 9.99E+99 0 2.48E-05 1.00E-05 1.00E-09 5.1 5.95 0.1 0.5 10 1 115 TPH Aromatic C35-C40 TDI 30 TDI 9E+99 9.99E+99 0 2.48E-05 1.00E-05 1.00E-09 5.1 5.95 0.1 0.5 10 1 11617181920
Sub-
surfa
ce s
oil t
o in
door
air
corr
ectio
n fa
ctor
(d
imen
sion
less
)
Der
mal
Abs
orpt
ion
Frac
tion
(dim
ensi
onle
ss)
Soil-
to-d
ust t
rans
port
fact
or
(g
g-1 D
W)
Rel
ativ
e bi
oava
ilabi
lity
via
dust
in
hala
tion
(uni
tless
)
log
K oc (
cm3 g
-1)
log
K ow (d
imen
sion
less
)
Coe
ffici
ent o
f Diff
usio
n in
Wat
er
(m2 s
-1)
Inha
latio
n H
ealth
Crit
eria
Val
ue
(μg
kg-1
BW
day
-1)
Ora
l Mea
n D
aily
Inta
ke
(μ
g da
y-1)
Air-
wat
er p
artit
ion
coef
ficie
nt
(Kaw
) (c
m3 c
m-3
)
Coe
ffici
ent o
f Diff
usio
n in
Air
(m2
s-1)
3-Jul-12
Ora
l Hea
lth C
riter
ia V
alue
(μ
g kg
-1 B
W d
ay-1
)
Inha
latio
n M
ean
Dai
ly In
take
(μ
g da
y-1)
Rel
ativ
e bi
oava
ilabi
lity
via
soil
inge
stio
n (u
nitle
ss)
CLEA v1.06 Software VPH EPH INDOOR VAPOUR
CLEA Software Version 1.06 Report generated Page 9 of 11
21222324252627282930
Sub-
surfa
ce s
oil t
o in
door
air
corr
ectio
n fa
ctor
(d
imen
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CLEA v1.06 Software VPH EPH INDOOR VAPOUR
CLEA Software Version 1.06 Report generated Page 10 of 11
1 TPH Aliphatic C5-C6 2.83E+01 2.19E+04 3.59E+01 model model model model model model2 TPH Aliphatic C6-C8 1.32E+02 3.45E+03 5.37E+00 model model model model model model3 TPH Aliphatic C8-C10 1.05E+03 3.20E+02 4.27E-01 model model model model model model4 TPH Aliphatic C10-C12 8.35E+03 2.11E+01 3.39E-02 model model model model model model
5 TPH Aliphatic C12-C16 1.87E+05 1.53E+00 7.59E-04 model model model model model model
6 TPH Aliphatic C16-C35 2.00E+07 2.38E-02 2.54E-06 model model model model model model
7 TPH Aliphatic C35-C44 2.00E+07 2.38E-02 2.54E-06 model model model model model model
8 TPH Aromatic C5-C7 2.35E+00 6.24E+03 1.78E+03 model model model model model model
9 TPH Aromatic C7-C8 7.11E+00 1.73E+03 5.90E+02 model model model model model model10 TPH Aromatic C8-C10 5.52E+01 3.20E+02 6.46E+01 model model model model model model11 TPH Aromatic C10-C12 8.74E+01 3.21E+01 2.45E+01 model model model model model model12 TPH Aromatic C12-C16 1.74E+02 1.14E+00 5.75E+00 model model model model model model13 TPH Aromatic C16-C21 4.92E+02 5.62E-03 6.53E-01 model model model model model model14 TPH Aromatic C21-C35 4.38E+03 1.61E-06 6.61E-03 model model model model model model15 TPH Aromatic C35-C40 4.38E+03 1.61E-06 6.61E-03 model model model model model model1617181920
Vapo
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CLEA v1.06 Software VPH EPH INDOOR VAPOUR
CLEA Software Version 1.06 Report generated Page 11 of 11
21222324252627282930
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Vapo
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Wat
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olub
ility
(mg
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Summary of Input Data for Risk CalculationDescription:
Date: 07-02-2012
08:36:12
Receptors:Child Resident - Mean
Routes:Inhalation of Indoor Air
Chemicals: Dichloroethylene (cis 1,2)NaphthalenePhenolPhenanthreneTPH Aliphatic C5-6TPH Aliphatic C6-8TPH Aliphatic C8-10TPH Aliphatic C10-12TPH Aliphatic C12-16TPH Aliphatic C16-35TPH Aromatic C7-8TPH Aromatic C8-10TPH Aromatic C10-12TPH Aromatic C12-16TPH Aromatic C16-21TPH Aromatic C21-35Trichloroethylene (TCE)Vinyl Chloride
Exposure Parameters
Exposure Pathway UnitsChild Resident -
MeanBody weight kg 11.1Averaging time for carcinogens yr 6Exposure duration yr 6
Inhalation of Indoor Air UnitsChild Resident -
MeanExposure frequency for indoor air events/yr 350Time indoors hr/d 19.6Inhalation rate indoors m3/hr 0.35
Slope Factors and Reference Doses
Chemical UnitsDichloroethyle
ne (cis 1,2)Naphthalene Phenol Phenanthrene
TPH Aliphatic C5-6
TPH Aliphatic C6-8
TPH Aliphatic C8-10
TPH Aliphatic C10-12
TPH Aliphatic C12-16
TPH Aliphatic C16-35
TPH Aromatic C7-8
TPH Aromatic C8-10
TPH Aromatic C10-12
TPH Aromatic C12-16
TPH Aromatic C16-21
TPH Aromatic C21-35
Trichloroethylene (TCE)
Vinyl Chloride
Unit risk factor 1/(ug/m3) ND 3.40E-05 ND ND ND ND ND ND ND ND ND ND ND ND ND ND 2.00E-06 8.80E-06Reference Concentration mg/m3 ND 3.00E-03 0.2 ND 18.4 18.4 1 1 1 ND 0.4 0.2 0.2 0.2 ND ND ND 0.1
Exposure Point Concentrations for Modeled MediaObtained from Fate and Transport Output
For carcinogenic risk, concentrations are averaged over the exposure duration (ED).For non-carcinogenic risk, concentrations are averaged over the minimum of 7 years or the ED.
Modeled Concentrations for Indoor Air Exposure Point Concentration for Carcinogens
Receptor DescriptionExposure Duration
Dichloroethylene (cis 1,2)
Naphthalene Phenol PhenanthreneTPH Aliphatic
C5-6TPH Aliphatic
C6-8TPH Aliphatic
C8-10TPH Aliphatic
C10-12TPH Aliphatic
C12-16TPH Aliphatic
C16-35TPH Aromatic
C7-8TPH Aromatic
C8-10TPH Aromatic
C10-12TPH Aromatic
C12-16TPH Aromatic
C16-21TPH Aromatic
C21-35Trichloroethyle
ne (TCE)Vinyl Chloride
yr mg/m3 mg/m3 mg/m3 mg/m3 mg/m3 mg/m3 mg/m3 mg/m3 mg/m3 mg/m3 mg/m3 mg/m3 mg/m3 mg/m3 mg/m3 mg/m3 mg/m3 mg/m3 CarcinogensChild Resident - Mean 6.00E+00 3.25E+01 3.69E-04 4.44E-02 3.23E-05 2.31E+01 9.52E+00 1.26E+00 1.26E+00 1.26E+00 5.65E-04 5.02E-01 2.51E-01 1.20E-01 1.09E-02 3.06E-04 1.74E-07 6.28E-03 1.43E-03
Modeled Concentrations for Indoor Air Exposure Point Concentration for Non-Carcinogens
Receptor DescriptionExposure Duration
Dichloroethylene (cis 1,2)
Naphthalene Phenol PhenanthreneTPH Aliphatic
C5-6TPH Aliphatic
C6-8TPH Aliphatic
C8-10TPH Aliphatic
C10-12TPH Aliphatic
C12-16TPH Aliphatic
C16-35TPH Aromatic
C7-8TPH Aromatic
C8-10TPH Aromatic
C10-12TPH Aromatic
C12-16TPH Aromatic
C16-21TPH Aromatic
C21-35Trichloroethyle
ne (TCE)Vinyl Chloride
yr mg/m3 mg/m3 mg/m3 mg/m3 mg/m3 mg/m3 mg/m3 mg/m3 mg/m3 mg/m3 mg/m3 mg/m3 mg/m3 mg/m3 mg/m3 mg/m3 mg/m3 mg/m3 Non-CarcinogensChild Resident - Mean 6.00E+00 3.25E+01 3.69E-04 4.44E-02 3.23E-05 2.31E+01 9.52E+00 1.26E+00 1.26E+00 1.26E+00 5.65E-04 5.02E-01 2.51E-01 1.20E-01 1.09E-02 3.06E-04 1.74E-07 6.28E-03 1.43E-03
Summary of Clean-up Levels
Dissolved Phase Groundwater Source The receptor considered is: Child Resident - Mean
Exposure pathways depending on this source:Inhalation of Indoor Air
Site-Specific Target Levels (SSTLs) for Dissolved Phase Groundwater Source
SSTLOriginal Source
Concentration
Chemical Solubility
[mg/l] [mg/l] [mg/l]Dichloroethylene (cis 1,2) 7.6E+03 3.1E+00 7.550E+03** Naphthalene 8.8E-01 1.5E-02 1.9E+01Phenol 8.4E+04 5.0E-03 8.410E+04** Phenanthrene 1.1E+00 3.8E-01 1.100E+00** TPH Aliphatic C5-6 2.0E+01 5.0E-02 3.6E+01TPH Aliphatic C6-8 5.4E+00 1.0E+00 5.370E+00** TPH Aliphatic C8-10 4.4E-01 1.0E+01 4.3E-01TPH Aliphatic C10-12 2.8E-01 2.0E+01 3.4E-02TPH Aliphatic C12-16 6.7E-02 1.2E+02 7.6E-04TPH Aliphatic C16-35 2.5E-06 5.2E+02 2.540E-06** TPH Aromatic C7-8 5.3E+01 5.0E-02 5.9E+02TPH Aromatic C8-10 1.5E+01 1.4E+00 6.5E+01TPH Aromatic C10-12 2.5E+01 4.5E+00 2.450E+01** TPH Aromatic C12-16 5.8E+00 7.0E+01 5.750E+00** TPH Aromatic C16-21 6.5E-01 5.7E+01 6.530E-01** TPH Aromatic C21-35 6.6E-03 1.8E+02 6.610E-03** Trichloroethylene (TCE) 5.4E-01 1.0E+01 1.4E+03Vinyl Chloride 3.5E-02 9.7E-02 1.1E+03
Summary of Input Data for Risk CalculationDescription:
Date: 07-02-2012
08:36:12
Receptors:Child Resident - Mean
Routes:Inhalation of Outdoor Air
Chemicals: Dichloroethylene (cis 1,2)NaphthalenePhenolPhenanthreneTPH Aliphatic C5-6TPH Aliphatic C6-8TPH Aliphatic C8-10TPH Aliphatic C10-12TPH Aliphatic C12-16TPH Aliphatic C16-35TPH Aromatic C7-8TPH Aromatic C8-10TPH Aromatic C10-12TPH Aromatic C12-16TPH Aromatic C16-21TPH Aromatic C21-35Trichloroethylene (TCE)Vinyl Chloride
Exposure Parameters
Exposure Pathway UnitsChild Resident -
MeanBody weight kg 11.1Averaging time for carcinogens yr 6Exposure duration yr 6
Inhalation of Outdoor Air UnitsChild Resident -
MeanExposure frequency for outdoor air events/yr 365Time outdoors hr/d 1Inhalation rate outdoors m3/hr 7.29
Slope Factors and Reference Doses
Chemical UnitsDichloroethyle
ne (cis 1,2)Naphthalene Phenol Phenanthrene
TPH Aliphatic C5-6
TPH Aliphatic C6-8
TPH Aliphatic C8-10
TPH Aliphatic C10-12
TPH Aliphatic C12-16
TPH Aliphatic C16-35
TPH Aromatic C7-8
TPH Aromatic C8-10
TPH Aromatic C10-12
TPH Aromatic C12-16
TPH Aromatic C16-21
TPH Aromatic C21-35
Trichloroethylene (TCE)
Vinyl Chloride
Unit risk factor 1/(ug/m3) ND 3.40E-05 ND ND ND ND ND ND ND ND ND ND ND ND ND ND 2.00E-06 8.80E-06Reference Concentration mg/m3 ND 3.00E-03 0.2 ND 18.4 18.4 1 1 1 ND 0.4 0.2 0.2 0.2 ND ND ND 0.1
Exposure Point Concentrations for Modeled MediaObtained from Fate and Transport Output
For carcinogenic risk, concentrations are averaged over the exposure duration (ED).For non-carcinogenic risk, concentrations are averaged over the minimum of 7 years or the ED.
Modeled Concentrations for Outdoor Air Exposure Point Concentration for Carcinogens
Receptor DescriptionExposure Duration
Dichloroethylene (cis 1,2)
Naphthalene Phenol PhenanthreneTPH Aliphatic
C5-6TPH Aliphatic
C6-8TPH Aliphatic
C8-10TPH Aliphatic
C10-12TPH Aliphatic
C12-16TPH Aliphatic
C16-35TPH Aromatic
C7-8TPH Aromatic
C8-10TPH Aromatic
C10-12TPH Aromatic
C12-16TPH Aromatic
C16-21TPH Aromatic
C21-35Trichloroethyle
ne (TCE)Vinyl Chloride
yr mg/m3 mg/m3 mg/m3 mg/m3 mg/m3 mg/m3 mg/m3 mg/m3 mg/m3 mg/m3 mg/m3 mg/m3 mg/m3 mg/m3 mg/m3 mg/m3 mg/m3 mg/m3 CarcinogensChild Resident - Mean 6.00E+00 9.32E-02 2.59E-05 2.75E-04 1.57E-07 1.19E-01 2.67E-02 3.41E-03 4.29E-04 3.99E-05 1.58E-06 1.57E-02 3.12E-03 3.42E-04 3.21E-05 1.02E-06 9.16E-10 4.49E-02 2.68E-02
Modeled Concentrations for Outdoor Air Exposure Point Concentration for Non-Carcinogens
Receptor DescriptionExposure Duration
Dichloroethylene (cis 1,2)
Naphthalene Phenol PhenanthreneTPH Aliphatic
C5-6TPH Aliphatic
C6-8TPH Aliphatic
C8-10TPH Aliphatic
C10-12TPH Aliphatic
C12-16TPH Aliphatic
C16-35TPH Aromatic
C7-8TPH Aromatic
C8-10TPH Aromatic
C10-12TPH Aromatic
C12-16TPH Aromatic
C16-21TPH Aromatic
C21-35Trichloroethyle
ne (TCE)Vinyl Chloride
yr mg/m3 mg/m3 mg/m3 mg/m3 mg/m3 mg/m3 mg/m3 mg/m3 mg/m3 mg/m3 mg/m3 mg/m3 mg/m3 mg/m3 mg/m3 mg/m3 mg/m3 mg/m3 Non-CarcinogensChild Resident - Mean 6.00E+00 9.32E-02 2.59E-05 2.75E-04 1.57E-07 1.19E-01 2.67E-02 3.41E-03 4.29E-04 3.99E-05 1.58E-06 1.57E-02 3.12E-03 3.42E-04 3.21E-05 1.02E-06 9.16E-10 4.49E-02 2.68E-02
Summary of Clean-up Levels
Dissolved Phase Groundwater Source The receptor considered is: Child Resident - Mean
Exposure pathways depending on this source:Inhalation of Outdoor Air
Site-Specific Target Levels (SSTLs) for Dissolved Phase Groundwater Source
SSTLOriginal Source
Concentration
Chemical Solubility
[mg/l] [mg/l] [mg/l]Dichloroethylene (cis 1,2) 7.6E+03 3.1E+00 7.550E+03** Naphthalene 1.9E+01 1.5E-02 1.900E+01** Phenol 8.4E+04 5.0E-03 8.410E+04** Phenanthrene 1.1E+00 3.8E-01 1.100E+00** TPH Aliphatic C5-6 3.6E+01 5.0E-02 3.590E+01** TPH Aliphatic C6-8 5.4E+00 1.0E+00 5.370E+00** TPH Aliphatic C8-10 4.3E-01 1.0E+01 4.270E-01** TPH Aliphatic C10-12 3.4E-02 2.0E+01 3.390E-02** TPH Aliphatic C12-16 7.6E-04 1.2E+02 7.600E-04** TPH Aliphatic C16-35 2.5E-06 5.2E+02 2.540E-06** TPH Aromatic C7-8 5.9E+02 5.0E-02 5.900E+02** TPH Aromatic C8-10 6.5E+01 1.4E+00 6.490E+01** TPH Aromatic C10-12 2.5E+01 4.5E+00 2.450E+01** TPH Aromatic C12-16 5.8E+00 7.0E+01 5.750E+00** TPH Aromatic C16-21 6.5E-01 5.7E+01 6.530E-01** TPH Aromatic C21-35 6.6E-03 1.8E+02 6.610E-03** Trichloroethylene (TCE) 1.4E+03 1.0E+01 1.370E+03** Vinyl Chloride 2.3E+02 9.7E-02 1.1E+03
APPENDIX C
SOIL GUIDELINE VALUES FOR CAPPING MATERIALS
10781 Avesta Phase 7 Soil Screening Criteria Values
(mg/kg)Beryllium 51 LQMBoron 291 LQMCadmium 10 SGVChromium (III) 3,000 LQMChromium (VI) 4.3 LQMCopper 2,330 LQMLead 450 SGVMercury 1 SGVNickel 130 SGVVanadium 75 LQMZinc 3,750 LQMArsenic 32 SGVCyanide 34 ATRISKSelenium 350 SGVAcenaphthene 1,000 LQMAcenaphthylene 850 LQMAnthracene 9,200 LQMBenzo(a)anthracene 5.9 LQMBenzo(a)pyrene 1 LQMBenzo(b)fluoranthene 7 LQMBenzo(ghi)perylene 47 LQMBenzo(k)fluoranthene 10 LQMChrysene 9.3 LQMDibenzo(ah)anthracene 0.9 LQMFluoranthene 670 LQMFluorene 780 LQMIndeno(123cd)pyrene 4.2 LQMNaphthalene 8.7 LQMPhenanthrene 380 LQMPyrene 1,600 LQMTPH Screen <100 Based on LQM GAC for Aliphatic C5-C6
DeterminandScreening Criteria Value
Source
SGV
LQM
ATRISK
EA Soil Guideline Value
Land Quality Management/Chartered Institute of Environmental Health Generic Assessment Criteria for Human Health Risk Assessment
Atkins ATRISKsoil Soil Screening Values
Integral Geotechnique (Wales) Limited
APPENDIX D
CONCRETE CAP DESIGN
APPENDIX E
LEACHATE REMEDIAL TARGETS
10781 Avesta Phase 7 Leachate Remedial Targets
Leachate Remedial Target
mg/l
Chromium 0.467
Copper 0.0934
Nickel 0.187
Vanadium 0.561
Zinc 0.701
Arsenic 0.0934
Selenium 0.0934
Determinand
Integral Geotechnique (Wales) Limited
FIGURES
Scale = 1:25000
Integral House7 Beddau WayCastlegate Business ParkCaerphillyCF83 2AXTel: 029 2080 7991Fax: 029 2086 2176
FIGURE 1 - SITE LOCATION Integral Géotechnique
FORMER AVESTA STEELWORKS, PONTYPOOL
NORTH
SITE LOCATION
FIGURE 2 - SITE LAYOUT, PHASINGIntegral House7 Beddau WayCastlegate Business ParkCaerphillyCF83 2AXTel: 029 2080 7991Fax: 029 2086 2176
AVESTA STEELWORKS, PANTEG
IntegralGéotechnique
NOT TO SCALE
PHASE 7
PHASE 6PHASE 5
Integral House7 Beddau WayCastlegate Business ParkCaerphillyCF83 2AXTel: 029 2080 7991Fax: 029 2086 2176
FIGURE 3 - SCHOOL SITE LAYOUT Integral Géotechnique
AVESTA STEELWORKS, PANTEG
NORTH
NOT TO SCALE
FIGURE 4 - SCHOOL SITE LAYOUT with PIT OVERLAY Integral House7 Beddau WayCastlegate Business ParkCaerphillyCF83 2AXTel: 029 2080 7991Fax: 029 2086 2176
AVESTA STEELWORKS, PANTEG
IntegralGéotechnique
NOT TO SCALE
PITCHMUGA
SCHOOL
PHASE 6 PHASE 7
PHASE 5
FIGURE 5A - PITS AND SHAFTS OVERLAYIntegral House7 Beddau WayCastlegate Business ParkCaerphillyCF83 2AXTel: 029 2080 7991Fax: 029 2086 2176
AVESTA STEELWORKS, PANTEG
IntegralGéotechnique
NOT TO SCALE
FIGURE 5B - PITS AND SHAFTS, LONG SECTIONSIntegral House7 Beddau WayCastlegate Business ParkCaerphillyCF83 2AXTel: 029 2080 7991Fax: 029 2086 2176
AVESTA STEELWORKS, PANTEG
IntegralGéotechnique
NOT TO SCALE
FIGURE 6 - CROSS SECTIONAL CONCEPTUAL MODELIntegral House7 Beddau WayCastlegate Business ParkCaerphillyCF83 2AXTel: 029 2080 7991Fax: 029 2086 2176FORMER AVESTA STEELWORKS, PONTYPOOL
Integral Géotechnique
CONCRETE SLAB, PITS, BASEMENTS, DUCTS, ETC (indicative only)
MADE GROUND
GRAVELLY CLAY - RIVER TERRACE DEPOSITS
SANDY GRAVEL - RIVER TERRACE DEPOSITS
WEATHERED MUDSTONE
GROUNDWATER - GRAVEL AQUIFER
GROUNDWATER - BEDROCK AQUIFER
NW SE
25m BGL
0m BGL
5m BGL
10m BGL
15m BGL
20m BGL
POTENTIAL ORGANIC CONTAMINATION ASSOCIATED WITH STEELWORKS MACHINERY (OILS/SOLVENTS)
POTENTIAL MIGRATION OF CONTAMINANTS
POTENTIAL CONTAMINANT PLUME
CONTAMINATION NOTES:
1. HYDROCARBON CONTAMINATION (OIL/SOLVENTS) LOCALLY ASSOCIATED WITH FORMER STEELWORKS MACHINERY PITS/SUMPS, ETC, NOT WIDESPREAD ACROSS THE SITE.
2. SEVERAL SMALL LOCALISED GROUNDWATER PLUMES RATHER THAN ONE LARGE PLUME
Contaminant Pathways
P1 Inhalation of soil dust or vapours P5 Direct contact with Made Ground - Construction Materials Durability P2 Dermal contact with soil P6 Migration and accumulation of gas in enclosed spacesP3 Ingestion of soil/soil on home-grown produce P7 Migration to groundwaterP4 Inhalation of vapours (indoor/outdoor air) P8 Transportation in groundwater
DNAPL
LNAPLLNAPL
P4P5, P6
P4 P4
P1, P2P3, P4
P3
P8
P8
P7
P7