7/31/2019 1203091 MDEQ

1/15

Dear Mr. Joseph Walczak,

Enclosed is a copy of the laboratory report for the following work order(s) received by TriMatrix Laboratories:

Attn: Mr. Joseph Walczak

Lansing, MI 48909

MDEQ

525 W. Allegan St., 4th Floor North

Project: WWW Tannery, 41000451

Work Order Received Descr ipt ion

March 21, 2012

1203091 03/06/2012 Laboratory Services

This report relates only to the sample(s) as received. Test results are in compliance with the requirements of the

National Environmental Laboratory Accreditation Program (NELAP) and/or one of the following certification programs:

If you have any questions or require further information, please do not hesitate to contact me.

Sincerely,

Lisa M. Harvey

Project Chemist

Any qualification or narration of results, including sample acceptance requirements and test exceptions to the above

referenced programs, is presented in the Statement of Data Qualifications section of this report. Estimates of

analytical uncertainties and certification documents for the test results contained within this report are available upon

request.

ACLASS DoD-ELAP/ISO17025 (#ADE-1542); Arkansas DEP (#10-046-0); Florida DEP (#E87622-24); Georgia EPD

(#E87622-24); Illinois DEP (#002841); Kansas DPH (#E-10302); Kentucky DEP (#0021); Louisiana DEP

(#03068); Michigan DPH (#0034); Minnesota DPH (#367345); New York ELAP (#44950); North Carolina DNRE

(#659); Texas CEQ (#T104704495-11-1); Virginia DCLS (#1239); Wisconsin DNR (#999472650); USDA Soil

Import Permit (#P330-09-00163).

Page 1 of 15

This report shall not be reproduced, except in full, without written authorization of TriMatrix Laboratories, Inc.Individual sample results relate only to the sample tested.

5560 Corporate Exchange Court SE Grand Rapids, MI 49512 616.975.4500 Fax 616.942.7463 www.trimatrixlabs.com

7/31/2019 1203091 MDEQ

2/15

ANALYTI CAL REPORT

03/06/12 11:15

J.Walczak

1203091

Laboratory Services

SD1/ 0-12

03/06/12 17:15Soil

MDEQ

WWW Tannery, 41000451

Client:

Project:

Client Sample ID:

Lab Sample ID:

Matrix:

Work Order:

Description:

Sampled:

Sampled By:

Received:

1203091-01

Physical/ Chemical Parameters by EPA/ APHA/ ASTM Methods

DilutionFactor

QCBatchMDLRLAnalyte Unit Met hod

Date TimeAnalyzed By

AnalyticalResult

% USEPA-3550B 1203202147 0.10.1 KCSPercent Solids 03/12/12 13:10

ug/kg dry USEPA-7196A 120317914200 U 3804200 HLBChromium, Hexavalent 03/12/12 12:11

Page 2 of 15

This report shall not be reproduced, except in full, without written authorization of TriMatrix Laboratories, Inc.Individual sample results relate only to the sample tested.

5560 Corporate Exchange Court SE Grand Rapids, MI 49512 616.975.4500 Fax 616.942.7463 www.trimatrixlabs.com

7/31/2019 1203091 MDEQ

3/15

ANALYTI CAL REPORT

03/06/12 11:15

J.Walczak

1203091

Laboratory Services

SD1/ 12-24

03/06/12 17:15Soil

MDEQ

WWW Tannery, 41000451

Client:

Project:

Client Sample ID:

Lab Sample ID:

Matrix:

Work Order:

Description:

Sampled:

Sampled By:

Received:

1203091-02

Ph sical/ Chemical Parameters b EPA/ APHA/ ASTM Methods

DilutionFactor

QCBatchMDLRLAnalyte Unit Met hod

Date TimeAnalyzed By

AnalyticalResult

% USEPA-3550B 1203202177 0.10.1 KCSPercent Solids 03/12/12 13:10

ug/kg dry USEPA-7196A 120317912600 U 2302600 HLBChromium, Hexavalent 03/12/12 12:12

Page 3 of 15

This report shall not be reproduced, except in full, without written authorization of TriMatrix Laboratories, Inc.Individual sample results relate only to the sample tested.

5560 Corporate Exchange Court SE Grand Rapids, MI 49512 616.975.4500 Fax 616.942.7463 www.trimatrixlabs.com

7/31/2019 1203091 MDEQ

4/15

ANALYTI CAL REPORT

03/06/12 12:00

J.Walczak

1203091

Laboratory Services

SD2/ 0-9

03/06/12 17:15Soil

MDEQ

WWW Tannery, 41000451

Client:

Project:

Client Sample ID:

Lab Sample ID:

Matrix:

Work Order:

Description:

Sampled:

Sampled By:

Received:

1203091-03

Ph sical/ Chemical Parameters b EPA/ APHA/ ASTM Methods

DilutionFactor

QCBatchMDLRLAnalyte Unit Met hod

Date TimeAnalyzed By

AnalyticalResult

% USEPA-3550B 1203202136 0.10.1 KCSPercent Solids 03/12/12 13:10

ug/kg dry USEPA-7196A 120317915600 U 5105600 HLBChromium, Hexavalent 03/12/12 12:13

Page 4 of 15

This report shall not be reproduced, except in full, without written authorization of TriMatrix Laboratories, Inc.Individual sample results relate only to the sample tested.

5560 Corporate Exchange Court SE Grand Rapids, MI 49512 616.975.4500 Fax 616.942.7463 www.trimatrixlabs.com

7/31/2019 1203091 MDEQ

5/15

ANALYTI CAL REPORT

03/06/12 12:00

J.Walczak

1203091

Laboratory Services

SD2/ 9-15

03/06/12 17:15Soil

MDEQ

WWW Tannery, 41000451

Client:

Project:

Client Sample ID:

Lab Sample ID:

Matrix:

Work Order:

Description:

Sampled:

Sampled By:

Received:

1203091-04

Ph sical/ Chemical Parameters b EPA/ APHA/ ASTM Methods

DilutionFactor

QCBatchMDLRLAnalyte Unit Met hod

Date TimeAnalyzed By

AnalyticalResult

% USEPA-3550B 1203202155 0.10.1 KCSPercent Solids 03/12/12 13:10

ug/kg dry USEPA-7196A 120317913700 U 3303700 HLBChromium, Hexavalent 03/12/12 12:16

Page 5 of 15

This report shall not be reproduced, except in full, without written authorization of TriMatrix Laboratories, Inc.Individual sample results relate only to the sample tested.

5560 Corporate Exchange Court SE Grand Rapids, MI 49512 616.975.4500 Fax 616.942.7463 www.trimatrixlabs.com

7/31/2019 1203091 MDEQ

6/15

ANALYTI CAL REPORT

03/06/12 12:30

J.Walczak

1203091

Laboratory Services

SD3/ 0-6

03/06/12 17:15Soil

MDEQ

WWW Tannery, 41000451

Client:

Project:

Client Sample ID:

Lab Sample ID:

Matrix:

Work Order:

Description:

Sampled:

Sampled By:

Received:

1203091-05

Ph sical/ Chemical Parameters b EPA/ APHA/ ASTM Methods

DilutionFactor

QCBatchMDLRLAnalyte Unit Met hod

Date TimeAnalyzed By

AnalyticalResult

% USEPA-3550B 1203202136 0.10.1 KCSPercent Solids 03/12/12 13:10

ug/kg dry USEPA-7196A 120317915500 U 4905500 HLBChromium, Hexavalent 03/12/12 12:19

Page 6 of 15

This report shall not be reproduced, except in full, without written authorization of TriMatrix Laboratories, Inc.Individual sample results relate only to the sample tested.

5560 Corporate Exchange Court SE Grand Rapids, MI 49512 616.975.4500 Fax 616.942.7463 www.trimatrixlabs.com

7/31/2019 1203091 MDEQ

7/15

ANALYTI CAL REPORT

03/06/12 12:30

J.Walczak

1203091

Laboratory Services

SD3/ 6-28

03/06/12 17:15Soil

MDEQ

WWW Tannery, 41000451

Client:

Project:

Client Sample ID:

Lab Sample ID:

Matrix:

Work Order:

Description:

Sampled:

Sampled By:

Received:

1203091-06

Ph sical/ Chemical Parameters b EPA/ APHA/ ASTM Methods

DilutionFactor

QCBatchMDLRLAnalyte Unit Met hod

Date TimeAnalyzed By

AnalyticalResult

% USEPA-3550B 1203202137 0.10.1 KCSPercent Solids 03/12/12 13:10

ug/kg dry USEPA-7196A 120317915300* U 4805300 HLBChromium, Hexavalent 03/12/12 12:20

*See Statement of Data Qualifications

Page 7 of 15

This report shall not be reproduced, except in full, without written authorization of TriMatrix Laboratories, Inc.Individual sample results relate only to the sample tested.

5560 Corporate Exchange Court SE Grand Rapids, MI 49512 616.975.4500 Fax 616.942.7463 www.trimatrixlabs.com

7/31/2019 1203091 MDEQ

8/15

ANALYTI CAL REPORT

03/06/12 14:30

J.Walczak

1203091

Laboratory Services

SD4/ 0-14

03/06/12 17:15Soil

MDEQ

WWW Tannery, 41000451

Client:

Project:

Client Sample ID:

Lab Sample ID:

Matrix:

Work Order:

Description:

Sampled:

Sampled By:

Received:

1203091-07

Ph sical/ Chemical Parameters b EPA/ APHA/ ASTM Methods

DilutionFactor

QCBatchMDLRLAnalyte Unit Met hod

Date TimeAnalyzed By

AnalyticalResult

% USEPA-3550B 1203202147 0.10.1 KCSPercent Solids 03/12/12 13:10

ug/kg dry USEPA-7196A 12031791390 J 3604000 HLBChromi um, Hexavalent 03/12/12 12:29

Page 8 of 15

This report shall not be reproduced, except in full, without written authorization of TriMatrix Laboratories, Inc.Individual sample results relate only to the sample tested.

5560 Corporate Exchange Court SE Grand Rapids, MI 49512 616.975.4500 Fax 616.942.7463 www.trimatrixlabs.com

7/31/2019 1203091 MDEQ

9/15

ANALYTI CAL REPORT

03/06/12 15:05

J.Walczak

1203091

Laboratory Services

SD5/ 0-15

03/06/12 17:15Soil

MDEQ

WWW Tannery, 41000451

Client:

Project:

Client Sample ID:

Lab Sample ID:

Matrix:

Work Order:

Description:

Sampled:

Sampled By:

Received:

1203091-08

Ph sical/ Chemical Parameters b EPA/ APHA/ ASTM Methods

DilutionFactor

QCBatchMDLRLAnalyte Unit Met hod

Date TimeAnalyzed By

AnalyticalResult

% USEPA-3550B 1203202130 0.10.1 KCSPercent Solids 03/12/12 13:10

ug/kg dry USEPA-7196A 120317916600 U 6006600 HLBChromium, Hexavalent 03/12/12 12:31

Page 9 of 15

This report shall not be reproduced, except in full, without written authorization of TriMatrix Laboratories, Inc.Individual sample results relate only to the sample tested.

5560 Corporate Exchange Court SE Grand Rapids, MI 49512 616.975.4500 Fax 616.942.7463 www.trimatrixlabs.com

7/31/2019 1203091 MDEQ

10/15

ANALYTI CAL REPORT

03/06/12 15:05

J.Walczak

1203091

Laboratory Services

SD5/ 15-33

03/06/12 17:15Soil

MDEQ

WWW Tannery, 41000451

Client:

Project:

Client Sample ID:

Lab Sample ID:

Matrix:

Work Order:

Description:

Sampled:

Sampled By:

Received:

1203091-09

Ph sical/ Chemical Parameters b EPA/ APHA/ ASTM Methods

DilutionFactor

QCBatchMDLRLAnalyte Unit Met hod

Date TimeAnalyzed By

AnalyticalResult

% USEPA-3550B 1203202138 0.10.1 KCSPercent Solids 03/12/12 13:10

ug/kg dry USEPA-7196A 120317915200 U 4705200 HLBChromium, Hexavalent 03/12/12 12:33

Page 10 of 15

This report shall not be reproduced, except in full, without written authorization of TriMatrix Laboratories, Inc.Individual sample results relate only to the sample tested.

5560 Corporate Exchange Court SE Grand Rapids, MI 49512 616.975.4500 Fax 616.942.7463 www.trimatrixlabs.com

7/31/2019 1203091 MDEQ

11/15

ANALYTI CAL REPORT

03/06/12 15:35

J.Walczak

1203091

Laboratory Services

SD6/ 0-12

03/06/12 17:15Soil

MDEQ

WWW Tannery, 41000451

Client:

Project:

Client Sample ID:

Lab Sample ID:

Matrix:

Work Order:

Description:

Sampled:

Sampled By:

Received:

1203091-10

Ph sical/ Chemical Parameters b EPA/ APHA/ ASTM Methods

DilutionFactor

QCBatchMDLRLAnalyte Unit Met hod

Date TimeAnalyzed By

AnalyticalResult

% USEPA-3550B 1203202159 0.10.1 KCSPercent Solids 03/12/12 13:10

ug/kg dry USEPA-7196A 120317913400 U 3003400 HLBChromium, Hexavalent 03/12/12 12:34

Page 11 of 15

This report shall not be reproduced, except in full, without written authorization of TriMatrix Laboratories, Inc.Individual sample results relate only to the sample tested.

5560 Corporate Exchange Court SE Grand Rapids, MI 49512 616.975.4500 Fax 616.942.7463 www.trimatrixlabs.com

7/31/2019 1203091 MDEQ

12/15

QUALI TY CONTROL REPORT

Physical/ Chemical Parameters by EPA/ APHA/ ASTM Methods

RL MDQC Type UnitSpike

% Rec.ControlLimits RPD

RPDLimits

SampleConc.

SpikeQty. Result

Chromium, Hexavalent/USEPA-7196AAnalyte:

03/12/2012 By: HLBQC Batch: 1203179(3060A Alkaline Digestion) Analyzed:

ug/kg wet2000Method Blank U 182000

ug/kg wet40000 2072-1179237000Laboratory Control Sample 182000

ug/kg wet1800000 2072-117881580000Laboratory Control Sample 1800200000

1203091-06 [SD3/ 6-28]

ug/kg dry98300 2046-12621930Matrix Spike

7/31/2019 1203091 MDEQ

13/15

STATEMENT OF DATA QUALIFI CATI ONS

Physical/ Chemical Parameters by EPA/ APHA/ ASTM Methods

Qualification: The post-digestion spike recovery for this sample was outside the control limit. Sample matrixinterference is suspected and the reported result must be considered as estimated.

Analysis: USEPA-7196A

Sample/Analyte: 1203091-06 SD3/6-28 Chromium, Hexavalent

Qualification: The MS and/or MSD recovery was outside the control limit. The non-spiked sample result isconsidered estimated.

Analysis: USEPA-7196A

Sample/Analyte: 1203091-06 SD3/6-28 Chromium, Hexavalent

Page 13 of 15

This report shall not be reproduced, except in full, without written authorization of TriMatrix Laboratories, Inc.Individual sample results relate only to the sample tested.

5560 Corporate Exchange Court SE Grand Rapids, MI 49512 616.975.4500 Fax 616.942.7463 www.trimatrixlabs.com

7/31/2019 1203091 MDEQ

14/15

Page 14 of 15

This report shall not be reproduced, except in full, without written authorization of TriMatrix Laboratories, Inc.Individual sample results relate only to the sample tested.

5560 Corporate Exchange Court SE Grand Rapids, MI 49512 616.975.4500 Fax 616.942.7463 www.trimatrixlabs.com

7/31/2019 1203091 MDEQ

15/15

Page 15 of 15