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14.1 Structure of the Atom In order to understand atoms, we need to understand the idea of electric charge. We know of two different kinds of electric charge and we call them positive and negative.

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14.1 Electric charge in matter We say an object is electrically neutral when its total electric charge is zero.

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14.1 An early model In 1897 English physicist J. J. Thomson discovered that electricity passing through a gas caused the gas to give off particles that were too small to be atoms. These negative particles were eventually called electrons.

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14.1 The nuclear model In 1911, Ernest Rutherford, Hans Geiger, and Ernest Marsden did a clever experiment to test Thomsons model. We now know that every atom has a tiny nucleus, which contains more than 99% of the atoms mass.

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14.1 Inside an atom The mass of the nucleus determines the mass of an atom because protons and neutrons are much larger and more massive than electrons. In fact, a proton is 1,836 times heavier than an electron.

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14.1 Force inside atoms Electrons are bound to the nucleus by the attractive force between electrons (-) and protons (+).

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14.1 Force inside atoms What holds the nucleus together? There is another force that is even stronger than the electric force. We call it the strong nuclear force.

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14.1 How atoms of various elements are different The atoms of different elements contain different numbers of protons in the nucleus. Because the number of protons is so important, it is called the atomic number.

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14.1 How atoms of various elements are different Isotopes are atoms of the same element that have different numbers of neutrons. The mass number of an isotope tells you the number of protons plus the number of neutrons. How are these carbon isotopes different?

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14.1 Radioactivity Almost all elements have one or more isotopes that are stable. Stable means the nucleus stays together. Carbon-14 is radioactive because it has an unstable nucleus.

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Solving Problems How many neutrons are present in an aluminum atom that has an atomic number of 13 and a mass number of 27?

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1.Looking for: number of neutrons in aluminum-27 2.Given atomic no. = 13; mass no. = 27 3.Relationships: Periodic table says atomic no. = proton no. protons + neutrons = mass no. 4.Solution neutrons = mass no. protons neutrons = 27 13 = 14 Solving Problems

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14.2 Electrons in the atom Each different element has its own characteristic pattern of colors called a spectrum. The colors of clothes, paint, and everything else around you come from this property of elements to emit or absorb light of only certain colors.

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14.2 Electrons in atoms Each individual color in a spectrum is called a spectral line because each color appears as a line in a spectroscope. A spectroscope is a device that spreads light into its different colors.

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14.2 Bohr model of the atom Danish physicist Neils Bohr proposed the concept of energy levels to explain the spectrum of hydrogen. When an electron moves from a higher energy level to a lower one, the atom gives up the energy difference between the two levels. The energy comes out as different colors of light.

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14.2 The quantum theory Quantum theory says that when things get very small, like the size of an atom, matter and energy do not obey Newtons laws or other laws of classical physics.

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14.2 The quantum theory According to quantum theory, particles the size of electrons are fundamentally different An electron appears in a wave-like cloud and has no definite position.

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14.2 The quantum theory The work of German physicist Werner Heisenberg (19011976) led to Heisenbergs uncertainty principle. The uncertainty principle explains why a particles position, momentum or energy can never be precisely determined. The uncertainty principle exists because measuring any variable disturbs the others in an unpredictable way.

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14.2 The uncertainty principle

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14.2 Electrons and energy levels In the current model of the atom, we think of the electrons as moving around the nucleus in an area called an electron cloud. The energy levels occur because electrons in the cloud are at different average distances from the nucleus.

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14.2 Rules for energy levels Inside an atom, electrons always obey these rules: 1.The energy of an electron must match one of the energy levels in the atom. 2.Each energy level can hold only a certain number of electrons, and no more. 3.As electrons are added to an atom, they settle into the lowest unfilled energy level.

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14.2 Models of energy levels While Bohrs model of electron energy levels explained atomic spectra and the periodic behavior of the elements, it was incomplete. Energy levels are predicted by quantum mechanics, the branch of physics that deals with the microscopic world of atoms.

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14.2 Energy levels In the Bohr model of the atom, the first energy level can accept up to two electrons. The second and third energy levels hold up to eight electrons each. The fourth and fifth energy levels hold 18 electrons.

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