1r.2 towards an understanding of hydrogen enriched natural gas
TRANSCRIPT
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Towards an understanding of hydrogenenriched natural gas combustion inindustrial gas turbinesJENNY LARFELDT - SIEMENS INDUSTRIAL TURBOMACHINERY AB, FINSPONG
ELNA HEIMDAL NILSSON - COMBUSTION PHYSICS, LUND UNIVERISTY
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Outline
1. Hydrogen as a fuel
2. Full scale experiments at Siemens,Finspong
3. Modeling of combustion chemistry
4. Moving towards an increasedunderstanding: the way ahead
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Hydrogen (H2) as a fuel
• Future energy carrier that can buffer energyproduction capacity and energy need
• Waste gas in some industries
• Can be fed into natural gas grid
• ”Zero emission”
• Technical challenges: diffusivity, volume
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H2 combustion:Effect on combustion properties
• Increased flame speed – improved flamestability
• Increased flame temperature – risk of NOxproduction
• Decreased ignition delay time – flashback
• Increased flammability range
• High energy content
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H2 combustion:A chemical perspective
• Overall reaction: 2H2 + O2 → 2H2O
• Intermediate steps:
H2 + OH → H + H2O
H2 + O → H + OH
H + O2 → OH + O
H + HO2 → H2 + O2
→ OH + OH
Significant radical production – chain branching!
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H2 combustion:Gas turbines
• Gas turbines commonly fueled by natural gas
• H2 cofiring increase flame speed
• Risk of flash-back
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Full scale experiment:Testing in a Siemens gas turbine
• Purpose: find the maximum concentration of hydrogen in natural gasthat Siemens gas turbines SGT-700 and SGT-800 can handle withstandard combustion system and increase our knowledge on what issetting this limit
• Testing: a standard SGT-700 in Finspong with so called “single burnerfeed” of natural gas was operated with increasing amount of hydrogen
• Parameters evaluated: emissions, flame position, combustiondynamics and temperatures
• Funding: Swedish Energy Agency via the SGC AB, Siemens and Infraserv GmbH & Co.Höchst KG in Frankfurt am Main
• Report: Co-firing with hydrogen in Siemens industrial gas turbines, Mats Andersson, JennyLarfeldt and Anders Larsson, SGC rapport 2013:256
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Restricted © Siemens Industrial Turbomachinery AB 2013 All rights reserved.
Results 1(3): Stable operation at near 40 % byvolume H2 demonstrated
Based on the test Siemens
has increased the allowed
hydrogen content in the
standard SGT-700 and SGT-
800 today to 15 vol-% H2.
Jenny LarfeldtSiemens Industrial Turbomachinery AB
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Restricted © Siemens Industrial Turbomachinery AB 2013 All rights reserved.
Results 2(3): Tendency to flame shifting observedand our understanding has increased
0vol% H2 30vol% H2 60vol% H2 100vol% H2
Atmospheric
combustion
test rig
0% pilot
0vol% H2 20vol% H2 32vol% H2
In SGT-700
engine 30 MW
load
6% pilot
Jenny LarfeldtSiemens Industrial Turbomachinery AB
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Restricted © Siemens Industrial Turbomachinery AB 2013 All rights reserved.
Results 3(3): The stability of the feeding system wasnot as accurate as desired… Improvements neededfor higher hydrogen contents
Jenny LarfeldtSiemens Industrial Turbomachinery AB
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Chemical kinetics modeling:Motivation
• Detailed models increase fundamentalunderstanding but are computationallyexpensive
• Reduced models can be used forComputational Fluid Dynamics simulations
• A ”cheap” way to investigate a wide range ofparameters
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Chemical kinetics modeling:Aim
Develop a tool based on combustion simulations to enableprediction of flame speeds of gas mixture relevant for gasturbines
• This tool will enable optimization of the operation of thegas turbines at different fuel compositions, with respect tonatural gas composition and hydrogen content
• It is impossible to investigate a large enough parameterset using full scale experiments
• Up to 60% hydrogen
• Pressures up to 20 bar
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Chemical kinetics modeling:Preliminary results
• text
GRI mechanismUsed forsimulation oflaminar flamespeed
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Chemical kinetics modeling:Further work
• Evaluation of detailed kinetic models to use asbenchmark (laboratory flames)
• Evaluation of existing reduced models (laboratory flames)
• Development of understanding of high pressurechemistry; what is required for a model to work for highpressures
• Development of reduced kinetic model
• Use reduced model for simulation of gas turbines
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Future work
• Laboratory studies of flames, from laminar toturbulent, at pressures up to 20 bar
• Development of reduced chemical kineticsmechanism suitable for gas turbineconditions
• CFD modeling of gas turbines
• Improved full scale experiments
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Thank you for your attention!
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