2225 riverside dr. october 01, 2018 pace project no

#=CL#

October 01, 2018

LIMS USE: FR - DONNA LISENBYLIMS OBJECT ID: 92400475

92400475Project:Pace Project No.:

RE:

Ms. Donna LisenbyWaterkeeper Alliance180 Maiden LaneSuite 603New York, NY 10038

9/21/2018-SUT

Dear Ms. Lisenby:Enclosed are the analytical results for sample(s) received by the laboratory on September 24, 2018.The results relate only to the samples included in this report. Results reported herein conform to themost current, applicable TNI/NELAC standards and the laboratory's Quality Assurance Manual,where applicable, unless otherwise noted in the body of the report.

If you have any questions concerning this report, please feel free to contact me.

Sincerely,

Chris [email protected]

Project Manager(828)254-7176

Enclosures

cc: Larissa Liebmann, Waterkeeper Alliance

REPORT OF LABORATORY ANALYSISThis report shall not be reproduced, except in full,

without the written consent of Pace Analytical Services, LLC.

Pace Analytical Services, LLC2225 Riverside Dr.

Asheville, NC 28804(828)254-7176

of 15

#=CP#

CERTIFICATIONS

Pace Project No.:Project:

924004759/21/2018-SUT

Minnesota Certification IDs1700 Elm Street SE, Minneapolis, MN 55414-2485A2LA Certification #: 2926.01Alabama Certification #: 40770Alaska Contaminated Sites Certification #: 17-009Alaska DW Certification #: MN00064Arizona Certification #: AZ0014Arkansas DW Certification #: MN00064Arkansas WW Certification #: 88-0680California Certification #: 2929CNMI Saipan Certification #: MP0003Colorado Certification #: MN00064Connecticut Certification #: PH-0256EPA Region 8+Wyoming DW Certification #: via MN 027-053-137Florida Certification #: E87605Georgia Certification #: 959Guam EPA Certification #: MN00064Hawaii Certification #: MN00064Idaho Certification #: MN00064Illinois Certification #: 200011Indiana Certification #: C-MN-01Iowa Certification #: 368Kansas Certification #: E-10167Kentucky DW Certification #: 90062Kentucky WW Certification #: 90062Louisiana DEQ Certification #: 03086Louisiana DW Certification #: MN00064Maine Certification #: MN00064Maryland Certification #: 322Massachusetts Certification #: M-MN064Michigan Certification #: 9909

Minnesota Certification #: 027-053-137Minnesota Dept of Ag Certifcation #: via MN 027-053-137Minnesota Petrofund Certification #: 1240Mississippi Certification #: MN00064Montana Certification #: CERT0092Nebraska Certification #: NE-OS-18-06Nevada Certification #: MN00064New Hampshire Certification #: 2081New Jersey Certification #: MN002New York Certification #: 11647North Carolina DW Certification #: 27700North Carolina WW Certification #: 530North Dakota Certification #: R-036Ohio DW Certification #: 41244Ohio VAP Certification #: CL101Oklahoma Certification #: 9507Oregon NwTPH Certification #: MN300001Oregon Secondary Certification #: MN200001Pennsylvania Certification #: 68-00563Puerto Rico Certification #: MN00064South Carolina Certification #:74003001Tennessee Certification #: TN02818Texas Certification #: T104704192Utah Certification #: MN00064Virginia Certification #: 460163Washington Certification #: C486West Virginia DW Certification #: 9952 CWest Virginia DEP Certification #: 382Wisconsin Certification #: 999407970Wyoming UST Certification #: via A2LA 2926.01




Asheville, NC 28804(828)254-7176

of 15

#=SA#

SAMPLE ANALYTE COUNT


924004759/21/2018-SUT

Lab ID Sample ID MethodAnalytesReported LaboratoryAnalysts

92400475001 A EPA 200.7 3 PASI-MDM

EPA 200.8 16 PASI-MPW1

92400475002 B EPA 200.7 3 PASI-MDM

EPA 200.8 16 PASI-MTT3

92400475003 C EPA 200.7 3 PASI-MDM

EPA 200.8 16 PASI-MPW1

92400475004 BACKGROUND EPA 200.7 3 PASI-MDM

EPA 200.8 16 PASI-MTT3




Asheville, NC 28804(828)254-7176

of 15

#=AR#

ANALYTICAL RESULTS


924004759/21/2018-SUT

Sample: A Lab ID: 92400475001 Collected: 09/21/18 13:45 Received: 09/24/18 10:30 Matrix: Water

Parameters Results Units DF Prepared Analyzed CAS No. QualReport Limit

Analytical Method: EPA 200.7 Preparation Method: EPA 200.7200.7 MET ICP

Boron ND ug/L 09/27/18 13:14 7440-42-809/26/18 14:10150 1Calcium 15700 ug/L 09/27/18 13:14 7440-70-209/26/18 14:10500 1Iron 8670 ug/L 09/27/18 13:14 7439-89-609/26/18 14:1050.0 1

Analytical Method: EPA 200.8 Preparation Method: EPA 200.8200.8 MET ICPMS

Aluminum 15500 ug/L 09/26/18 16:02 7429-90-509/26/18 10:07400 20Antimony ND ug/L 09/26/18 20:19 7440-36-0 D309/26/18 10:075.0 10Arsenic 32.8 ug/L 09/26/18 16:02 7440-38-209/26/18 10:0710.0 20Barium 157 ug/L 09/26/18 16:02 7440-39-309/26/18 10:076.0 20Beryllium ND ug/L 09/26/18 20:19 7440-41-7 D309/26/18 10:072.0 10Cadmium ND ug/L 09/26/18 20:19 7440-43-9 D309/26/18 10:070.80 10Chromium 17.5 ug/L 09/26/18 16:02 7440-47-309/26/18 10:0710.0 20Cobalt 5.6 ug/L 09/26/18 20:19 7440-48-409/26/18 10:075.0 10Lead 18.7 ug/L 09/26/18 16:02 7439-92-109/26/18 10:072.0 20Lithium 20.6 ug/L 09/26/18 16:02 7439-93-209/26/18 10:0710.0 20Manganese 369 ug/L 09/26/18 16:02 7439-96-509/26/18 10:0710.0 20Molybdenum 7.6 ug/L 09/26/18 20:19 7439-98-709/26/18 10:075.0 10Selenium ND ug/L 09/26/18 20:19 7782-49-2 D309/26/18 10:075.0 10Strontium 138 ug/L 09/26/18 16:02 7440-24-609/26/18 10:0710.0 20Thallium ND ug/L 09/26/18 20:19 7440-28-0 D309/26/18 10:071.0 10Vanadium 49.8 ug/L 09/26/18 16:02 7440-62-209/26/18 10:0720.0 20

Sample: B Lab ID: 92400475002 Collected: 09/21/18 14:05 Received: 09/24/18 10:30 Matrix: Water





Aluminum 1640 ug/L 10/01/18 09:46 7429-90-509/27/18 14:2020.0 1Antimony 0.56 ug/L 10/01/18 09:46 7440-36-009/27/18 14:200.50 1Arsenic 2.8 ug/L 10/01/18 09:46 7440-38-209/27/18 14:200.50 1Barium 24.8 ug/L 10/01/18 09:46 7440-39-309/27/18 14:200.30 1Beryllium ND ug/L 10/01/18 09:46 7440-41-709/27/18 14:200.20 1Cadmium ND ug/L 10/01/18 09:46 7440-43-909/27/18 14:200.080 1Chromium 3.5 ug/L 10/01/18 09:46 7440-47-309/27/18 14:200.50 1Cobalt 0.76 ug/L 10/01/18 09:46 7440-48-409/27/18 14:200.50 1Lead 0.96 ug/L 10/01/18 09:46 7439-92-109/27/18 14:200.10 1Lithium 3.9 ug/L 10/01/18 09:46 7439-93-209/27/18 14:200.50 1Manganese 65.1 ug/L 10/01/18 09:46 7439-96-509/27/18 14:200.50 1Molybdenum 5.2 ug/L 10/01/18 09:46 7439-98-709/27/18 14:200.50 1Selenium 0.73 ug/L 10/01/18 09:46 7782-49-209/27/18 14:200.50 1


without the written consent of Pace Analytical Services, LLC.Date: 10/01/2018 04:59 PM


Asheville, NC 28804(828)254-7176

of 15

#=AR#

ANALYTICAL RESULTS


924004759/21/2018-SUT

Sample: B Lab ID: 92400475002 Collected: 09/21/18 14:05 Received: 09/24/18 10:30 Matrix: Water



Strontium 36.7 ug/L 10/01/18 09:46 7440-24-609/27/18 14:200.50 1Thallium ND ug/L 10/01/18 09:46 7440-28-009/27/18 14:200.10 1Vanadium 8.5 ug/L 10/01/18 09:46 7440-62-209/27/18 14:201.0 1

Sample: C Lab ID: 92400475003 Collected: 09/21/18 14:50 Received: 09/24/18 10:30 Matrix: Water



Boron 212 ug/L 09/27/18 13:17 7440-42-809/26/18 14:10150 1Calcium 22100 ug/L 09/27/18 13:17 7440-70-209/26/18 14:10500 1Iron 51100 ug/L 09/27/18 13:17 7439-89-609/26/18 14:1050.0 1


Aluminum 332000 ug/L 09/26/18 16:08 7429-90-509/26/18 10:07400 20Antimony ND ug/L 09/26/18 20:22 7440-36-0 D309/26/18 10:075.0 10Arsenic 710 ug/L 09/26/18 16:08 7440-38-209/26/18 10:0710.0 20Barium 3370 ug/L 09/26/18 16:08 7440-39-309/26/18 10:076.0 20Beryllium 31.0 ug/L 09/26/18 16:08 7440-41-709/26/18 10:074.0 20Cadmium 2.3 ug/L 09/26/18 16:08 7440-43-909/26/18 10:071.6 20Chromium 306 ug/L 09/26/18 16:08 7440-47-309/26/18 10:0710.0 20Cobalt 80.5 ug/L 09/26/18 16:08 7440-48-409/26/18 10:0710.0 20Lead 152 ug/L 09/26/18 16:08 7439-92-109/26/18 10:072.0 20Lithium 407 ug/L 09/26/18 16:08 7439-93-209/26/18 10:0710.0 20Manganese 1520 ug/L 09/26/18 16:08 7439-96-509/26/18 10:0710.0 20Molybdenum 15.7 ug/L 09/26/18 16:08 7439-98-709/26/18 10:0710.0 20Selenium 22.0 ug/L 09/26/18 16:08 7782-49-209/26/18 10:0710.0 20Strontium 1460 ug/L 09/26/18 16:08 7440-24-609/26/18 10:0710.0 20Thallium 7.7 ug/L 09/26/18 16:08 7440-28-009/26/18 10:072.0 20Vanadium 1130 ug/L 09/26/18 16:08 7440-62-209/26/18 10:0720.0 20

Sample: BACKGROUND Lab ID: 92400475004 Collected: 09/21/18 14:50 Received: 09/24/18 10:30 Matrix: Water





Aluminum 594 ug/L 10/01/18 09:49 7429-90-509/27/18 14:2020.0 1Antimony ND ug/L 10/01/18 09:49 7440-36-009/27/18 14:200.50 1Arsenic 0.85 ug/L 10/01/18 09:49 7440-38-209/27/18 14:200.50 1




Asheville, NC 28804(828)254-7176

of 15

#=AR#

ANALYTICAL RESULTS


924004759/21/2018-SUT

Sample: BACKGROUND Lab ID: 92400475004 Collected: 09/21/18 14:50 Received: 09/24/18 10:30 Matrix: Water



Barium 13.7 ug/L 10/01/18 09:49 7440-39-309/27/18 14:200.30 1Beryllium ND ug/L 10/01/18 09:49 7440-41-709/27/18 14:200.20 1Cadmium ND ug/L 10/01/18 09:49 7440-43-909/27/18 14:200.080 1Chromium 0.92 ug/L 10/01/18 09:49 7440-47-309/27/18 14:200.50 1Cobalt ND ug/L 10/01/18 09:49 7440-48-409/27/18 14:200.50 1Lead 0.69 ug/L 10/01/18 09:49 7439-92-109/27/18 14:200.10 1Lithium 0.64 ug/L 10/01/18 09:49 7439-93-209/27/18 14:200.50 1Manganese 68.2 ug/L 10/01/18 09:49 7439-96-509/27/18 14:200.50 1Molybdenum ND ug/L 10/01/18 09:49 7439-98-709/27/18 14:200.50 1Selenium ND ug/L 10/01/18 09:49 7782-49-209/27/18 14:200.50 1Strontium 11.2 ug/L 10/01/18 09:49 7440-24-609/27/18 14:200.50 1Thallium ND ug/L 10/01/18 09:49 7440-28-009/27/18 14:200.10 1Vanadium 2.0 ug/L 10/01/18 09:49 7440-62-209/27/18 14:201.0 1




Asheville, NC 28804(828)254-7176

of 15

#=QC#

QUALITY CONTROL DATA


924004759/21/2018-SUT

Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.

QC Batch:QC Batch Method:

Analysis Method:Analysis Description:

565395EPA 200.7

EPA 200.7200.7 MET

Associated Lab Samples: 92400475001, 92400475002, 92400475003, 92400475004

Parameter UnitsBlankResult

ReportingLimit Qualifiers

METHOD BLANK: 3067946Associated Lab Samples: 92400475001, 92400475002, 92400475003, 92400475004

Matrix: Water

Analyzed

Boron ug/L ND 150 09/27/18 13:09Calcium ug/L ND 500 09/27/18 13:09Iron ug/L ND 50.0 09/27/18 13:09

Parameter UnitsLCS

Result% RecLimits Qualifiers% RecConc.

3067947LABORATORY CONTROL SAMPLE & LCSD:LCSSpike LCSD

% Rec RPDMaxRPD

LCSDResult

3067948

Boron ug/L 9841000 98 85-115100995 1 20Calcium ug/L 1880020000 94 85-1159518900 1 20Iron ug/L 1930020000 97 85-1159819600 1 20




Asheville, NC 28804(828)254-7176

of 15

#=QC#



924004759/21/2018-SUT




565263EPA 200.8

EPA 200.8200.8 MET

Associated Lab Samples: 92400475001, 92400475003



METHOD BLANK: 3067543Associated Lab Samples: 92400475001, 92400475003

Matrix: Water

Analyzed

Aluminum ug/L ND 20.0 09/26/18 15:56Antimony ug/L ND 0.50 09/26/18 15:56Arsenic ug/L ND 0.50 09/26/18 15:56Barium ug/L ND 0.30 09/26/18 15:56Beryllium ug/L ND 0.20 09/26/18 15:56Cadmium ug/L ND 0.080 09/26/18 15:56Chromium ug/L ND 0.50 09/26/18 15:56Cobalt ug/L ND 0.50 09/26/18 15:56Lead ug/L 0.16 0.10 P809/26/18 15:56Lithium ug/L ND 0.50 09/26/18 15:56Manganese ug/L ND 0.50 09/26/18 15:56Molybdenum ug/L ND 0.50 09/26/18 15:56Selenium ug/L ND 0.50 09/26/18 15:56Strontium ug/L ND 0.50 09/26/18 15:56Thallium ug/L ND 0.10 09/26/18 15:56Vanadium ug/L ND 1.0 09/26/18 15:56

Parameter UnitsLCS


3067544LABORATORY CONTROL SAMPLE:LCSSpike

Aluminum ug/L 20802000 104 85-115Antimony ug/L 105100 105 85-115Arsenic ug/L 102100 102 85-115Barium ug/L 111100 111 85-115Beryllium ug/L 110100 110 85-115Cadmium ug/L 110100 110 85-115Chromium ug/L 110100 110 85-115Cobalt ug/L 107100 107 85-115Lead ug/L 108100 108 85-115Lithium ug/L 110100 110 85-115Manganese ug/L 108100 108 85-115Molybdenum ug/L 107100 107 85-115Selenium ug/L 112100 112 85-115Strontium ug/L 103100 103 85-115Thallium ug/L 109100 109 85-115Vanadium ug/L 105100 105 85-115




Asheville, NC 28804(828)254-7176

of 15

#=QC#



924004759/21/2018-SUT


Parameter UnitsMS

Result% RecLimits Qual% RecConc.

3067545MATRIX SPIKE & MATRIX SPIKE DUPLICATE:

MSSpikeResult

92400409001

3067546

MSDResult

MSD% Rec RPD

MSDMSSpikeConc.

Aluminum ug/L 2000 109 70-130101 62000418 2600 2440Antimony ug/L 100 106 70-130104 1100ND 106 105Arsenic ug/L 100 109 70-130102 7100ND 110 103Barium ug/L 100 116 70-130109 510019.1 135 128Beryllium ug/L 100 113 70-130107 5100ND 113 107Cadmium ug/L 100 117 70-130109 71000.097 117 109Chromium ug/L 100 115 70-130108 61001.3 117 109Cobalt ug/L 100 115 70-130107 8100ND 116 107Lead ug/L 100 112 70-130106 51001.9 114 108Lithium ug/L 100 112 70-130106 61000.63 113 107Manganese ug/L 100 112 70-130103 610035.4 147 139Molybdenum ug/L 100 110 70-130109 11001.4 111 110Selenium ug/L 100 114 70-130111 31000.50 115 112Strontium ug/L 100 112 70-130104 610031.8 144 136Thallium ug/L 100 112 70-130107 4100ND 112 107Vanadium ug/L 100 113 70-130105 8100ND 114 106




Asheville, NC 28804(828)254-7176

of 15

#=QC#



924004759/21/2018-SUT




565765EPA 200.8

EPA 200.8200.8 MET

Associated Lab Samples: 92400475002, 92400475004



METHOD BLANK: 3069564Associated Lab Samples: 92400475002, 92400475004

Matrix: Water

Analyzed

Aluminum ug/L ND 20.0 10/01/18 09:40Antimony ug/L ND 0.50 10/01/18 09:40Arsenic ug/L ND 0.50 10/01/18 09:40Barium ug/L ND 0.30 10/01/18 09:40Beryllium ug/L ND 0.20 10/01/18 09:40Cadmium ug/L ND 0.080 10/01/18 09:40Chromium ug/L ND 0.50 10/01/18 09:40Cobalt ug/L ND 0.50 10/01/18 09:40Lead ug/L ND 0.10 10/01/18 09:40Lithium ug/L ND 0.50 10/01/18 09:40Manganese ug/L ND 0.50 10/01/18 09:40Molybdenum ug/L ND 0.50 10/01/18 09:40Selenium ug/L ND 0.50 10/01/18 09:40Strontium ug/L ND 0.50 10/01/18 09:40Thallium ug/L ND 0.10 10/01/18 09:40Vanadium ug/L ND 1.0 10/01/18 09:40

Parameter UnitsLCS


3069565LABORATORY CONTROL SAMPLE & LCSD:LCSSpike LCSD

% Rec RPDMaxRPD

LCSDResult

3069647

Aluminum ug/L 18302000 91 85-115911820 0 20Antimony ug/L 98.6100 99 85-1159191.2 8 20Arsenic ug/L 89.8100 90 85-1158888.3 2 20Barium ug/L 88.4100 88 85-1158787.4 1 20Beryllium ug/L 93.1100 93 85-1159191.4 2 20Cadmium ug/L 89.9100 90 85-1158989.3 1 20Chromium ug/L 92.9100 93 85-1159392.5 0 20Cobalt ug/L 93.3100 93 85-1159393.0 0 20Lead ug/L 92.3100 92 85-1159190.5 2 20Lithium ug/L 94.1100 94 85-1159392.8 1 20Manganese ug/L 92.2100 92 85-1159292.2 0 20Molybdenum ug/L 100100 100 85-1159493.7 7 20Selenium ug/L 92.7100 93 85-1159090.0 3 20Strontium ug/L 90.7100 91 85-1159191.4 1 20Thallium ug/L 91.7100 92 85-1159089.6 2 20Vanadium ug/L 91.2100 91 85-1159191.0 0 20




Asheville, NC 28804(828)254-7176

of 15

#=QL#

QUALIFIERS


924004759/21/2018-SUT

DEFINITIONS

DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot.ND - Not Detected at or above adjusted reporting limit.TNTC - Too Numerous To CountJ - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.MDL - Adjusted Method Detection Limit.PQL - Practical Quantitation Limit.RL - Reporting Limit - The lowest concentration value that meets project requirements for quantitative data with known precision andbias for a specific analyte in a specific matrix.S - Surrogate1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte isa combined concentration.Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.LCS(D) - Laboratory Control Sample (Duplicate)MS(D) - Matrix Spike (Duplicate)DUP - Sample DuplicateRPD - Relative Percent DifferenceNC - Not Calculable.SG - Silica Gel - Clean-UpU - Indicates the compound was analyzed for, but not detected.Acid preservation may not be appropriate for 2 Chloroethylvinyl ether.A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPAMethod 8260.N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported foreach analyte is a combined concentration.Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes.TNI - The NELAC Institute.

LABORATORIES

Pace Analytical Services - MinneapolisPASI-M

BATCH QUALIFIERS

Batch: 566292A matrix spike/matrix spike duplicate was not performed for this batch due to insufficient sample volume.[M5]

ANALYTE QUALIFIERS

Sample was diluted due to the presence of high levels of non-target analytes or other matrix interference.D3Analyte was detected in the method blank. All associated samples had concentrations of at least ten times greater thanthe blank or were below the reporting limit.

P8




Asheville, NC 28804(828)254-7176

of 15

#=CR#

QUALITY CONTROL DATA CROSS REFERENCE TABLE


924004759/21/2018-SUT

Lab ID Sample ID QC Batch Method QC Batch Analytical MethodAnalyticalBatch

92400475001 565395 565598A EPA 200.7 EPA 200.792400475002 565395 565598B EPA 200.7 EPA 200.792400475003 565395 565598C EPA 200.7 EPA 200.792400475004 565395 565598BACKGROUND EPA 200.7 EPA 200.7

92400475001 565263 565453A EPA 200.8 EPA 200.8

92400475002 565765 566292B EPA 200.8 EPA 200.8

92400475003 565263 565453C EPA 200.8 EPA 200.8

92400475004 565765 566292BACKGROUND EPA 200.8 EPA 200.8




Asheville, NC 28804(828)254-7176

of 15

2225 riverside dr. october 01, 2018 pace project no

Documents