4.4 biogas reactors for treatment 2010-09-05

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    4.4 Biogas – a way to solve sanitation

    problems

    H o w  m u c h  b i o g a s  c a n  b e  p r o d u c e d  f r o m  

    e x c r e t a  a n d  b i o m a s s ?  H o w  s a f e  i s  t h e  p r o c e s s  a n d  i t s  s l u d g e ? ? 

    Learning objectives: to know about the

    fundamental processes in biogas production,

    and get an overview of biogas generation in

    the world

      Anaerobic

    fermentation

    is a natural

    andunavoidable

     process

     Jam-Olof Drangert, Linköping university, Sweden

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    pying on !ature –

    "hat can we learn from cows? 

    Inlet OutletBiogas digester

    Cows convert biodegradable plants and water to

    milk, cow dung and urine – and gases

     Pedro Kraemer, BOD!, "ndia

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     # new look at the cow – and bull

    Inlet

    Outlet

    Biogas digester

    The Biogas Plant

     Pedro Kraemer, BOD!, "ndia

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     # biogas plant operates though

    anaerobic digestion of organic material

    The Biogas Plant

    InletOutlet

    Biogas digester

    Biogas

     Pedro Kraemer, BOD!, "ndia

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    $ntegrating biogas in agriculture

     Pedro Kraemer, BOD!, "ndia

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    ome examples of biogas plants

     Pedro Kraemer, BOD!, "ndia

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    "here is biogas technology applied?

     #pproximate numbers of biogas units in selected countries%

    &ountry !o of units 'olume ()** m+

    &hina ),***,*** x*

    $ndia -in **4 +,/**,*** ?

    !epal -in **0 **,*** ?'ietnam, 1hailand, 1an2ania,Bangladesh, Burundi, Bra2il

     

    x,***

     +,4** -**/

     in 3ermany

    enya, 5exico, &uba, 3uyana x** ?

    5orocco, 3hana, 6imbabwe,!icaragua, 7amaica, Bolivia   x*

    8, !9, ,1hailand,

    ##$ of all systems do not use pumps, agitator, and %eating 

     Pedro Kraemer, BOD!, "ndia

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     #vailable human excreta in $ndia compared

    to the need of fertiliser

    Dry org. matter (DS) 9, t!day "itrogen (N) #$, t!day

    %&osp&orus (P2O5) $, t!day

    %otassium (K 2O) ', t!dayCarbon (C) '$, t!day

    Calcium (CaO) $, t!day

    %otential biogas  $ mil m'

     day

      … oras a

    resource 

    Excreta viewedas waste: 

    Faeces   $, tons!day

    Urine #,, m'!day

    !:;:%  <

      =

      6

      >

     Pedro Kraemer, BOD!, "ndia

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    lurry application in agriculture 

     Pedro Kraemer, BOD!, "ndia

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    nergy balance – for composting and digestion

    Aerobic conversion (composting ): 

    C6 H12 O6 + 6O2  6 CO2  +6 H2 O

      ∆* +', k-!mol

    Anaerobic conversion (digestion):

      C6 H

    12 O

    6 + 2H

    2 O 3 CO

    2 + 3CH

    4 + 2H

    2O

      ∆* + $ k-!mol

    Burning of biogas:

      2CH4+ 6O2  CO2 + 6 H2 O

    ∆ * +',/$ k-!mol Pedro Kraemer, BOD!, "ndia

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    Biogas appliances 

     Pedro Kraemer, BOD!, "ndia

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    Biochemical process of anaerobic

    fermentation@digestion

     ce!ogenic

    bac!eria

     Fer"en!a!i#e

    bac!eria

     $e!%anogenic

    bac!eria

     Organic &as!e

     Carbo%'ra!es

    Fa!s

     Pro!ein

     a!er

      *ac!eria

      "ass 

    H2 , CO2 ace!ic aci

     

    *ac!eria

      "ass

    $e!%an

     + CO2

      *ac!eria

    "ass

    Pro-ionic aci

    *.!'ric acico%os,

    O!%er

    co"-onen!s

      H2 , CO2, 

    ace!ic aci

    Step 1:Hydrolysis + Acidogenesis Step 2 :

    Acetogenesis Step 3:Methanogenesis

     Pedro Kraemer, BOD!, "ndia

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    "hat parameters affect anaerobic digestion?

      The most imortant determinants of good livingconditions for anaerobic bacteria and therefore efficient

    gas roduction! are : 

     –  1emperature

     –  >etention 1ime

     –  pH:level

     –  &arbon@!itrogen ratio -&@! ratio

     –  ;roportion of dry matter in substrate A suitable viscosity –   #gitation -mixing of the substrate

      "f any one of these determinants is outside accetablerange! the digestion may be inhibited 

     Pedro Kraemer, BOD!, "ndia

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    ubstrate temperature in the digester 

    #ommon temerature ranges for bacteria%

    ;sychrophillic bacteria below *o&

    5esophillic bacteria * – 4*o&

    1hermophillic bacteria above 4*o&

     #naerobic fermentation can work in an ambienttemperature between +o& and 0*o& and, if colder,

    the reactor has to be insulated and@or heated.

    5ethane production is very sensitive to changes in

    temerature  Pedro Kraemer, BOD!, "ndia

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    Biogas production with continuous feeding 

    Hydraulic retention time in days

    9itres of

    biogasper litre

    of slurry

     Pedro Kraemer, BOD!, "ndia

    )*

    *

    +*

    C* )** )C*

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    pH –value is crucial for a good result

    $timal roduction when H %&' ( %&)

    $nhibition -due to acids if pH D /.

    $nhibition -due to ammonia if pH ( 0./

    -H is a cen!ra -ara"e!er /or con!roing !%e anaerobic -rocess 

    8eviation from the optimum range results in%

      9ower gas yield

      $nferior gas Euality  Pedro Kraemer, BOD!, "ndia

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    &@! ratio is important

    Microorganisms need * nitrogen, and# carbon, for their metabolism

      Methanogenic organisms refer a

    #-* ratio of between .':. and )':.

      >ecommendation%

      5ix different substrates

    ! must not be too low, or else

      shortage of nutrient

     Pedro Kraemer, BOD!, "ndia

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    !itrogen inhibition

      "f * concentration is too high -(),0** mg@l of !H4:!and pH is high, then

      growth of bacteria is inhibited due to

    toxicity caused by high levels of -uncharged ammonia

      5ethanogens, however, are able of adapt to

    C,*** : 0,*** mg@l of !H4:! given the pre:reEuisitethat the uncharged ammonia -!H+ controlled by pH

    level does not exceed **:+** mg@l

     Pedro Kraemer, BOD!, "ndia

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    &hanges in dry matter -85 concentration

    inside the digester 

     Pedro Kraemer, BOD!, "ndia

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    Behaviour of the substrate inside the digester 

     Pedro Kraemer, BOD!, "ndia

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    tirring the substrate

    /tirring imroves the efficiency of digestion by:

    >emoving metabolites -gas removal

    Bringing fresh material in contact with bacteria

    >educing scum formation and sedimentation

    ;reventing temperature gradients in the digester 

     #voiding the formation of blind spots -short cuts

    However! excessive stirring disturbs the symbioticrelationshi between the different bacteria secies

    imple biogas units normally do not have

    mechanical stirring devises Pedro Kraemer, BOD!, "ndia

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    fficiency of a biogas unit 

    "nut: 

    . 0g of dry 123, cattle dung will roduce )&2 04h -rule of thumb

    . 0g dry .''3, matter can generate )&2-'&12 5 )&67 04h

    /lurry contains .'3 dry matter! thus . litre can generate '&)67 04h

    . litre slurry )%o#! 1' days retention, releases )% litre biogas

    . m7 of biogas can generate 6 04h rule of thumb,

    /o! . lit of slurry generates '&')%86 5 '&.6) 04h

      #ctual k"h

    ;otential k"hfficiency A

    *.)/

    *./A A *./ 

    /F efficiency and the other +GF energy remains in the slurry

     Pedro Kraemer, BOD!, "ndia

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    &heck:list

    if gas production is lower than expected

    #hec0 9esonse

      $s pH (0.C ? =es #dd water and take pH after

    one hour 

    !o

    1oo much feed or of

    skewed composition?

    1emperature fallen? =es

    =es

    1ry to insulate digester,

    less feed, heat substrate.

    "ait one day

     #dd lime -acute action

    and wait one day

    !o

      $s pH D /.G ?

     #dd urine or ash -kg@m+ and

    wait ) day

    =es

    Drangert & Ejlertsson, Linkoping university, Sweden

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    ;rinciples for design and construction

    as collector:

    : fixed dome! or 

    : floating dome

    &ontinuous feeding 

    or  batch feeding

      urther

    treatment or 

      direct  use

     Pedro Kraemer, BOD!, "ndia

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    ixed:dome biogas digester 

     Pedro Kraemer, BOD!, "ndia

    ).

    ;

    slurry

    7

    BirdIs

    eye view

    .)

      7;

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    loating:drum unit with water:Jacket 

     Pedro Kraemer, BOD!, "ndia

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     #naerobic filter  -off:plot system 

    gas manhole

    inflow

    scum

    outflow

    filter mass

    grill

    sludge

    sedimentation tank filter tanks

     Pedro Kraemer, BOD!, "ndia

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     #naerobic baffled reactor  Off-plot system

    gas

    manholes

    m outflow

    ge

    sedimentation inoculation of fresh wastewater with active sludge final settler  

       #naerobic Baffled >eactor 

     Pedro Kraemer, BOD!, "ndia

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    toilet sectionshower 

    section

    anaerobic baffled

    reactor 

    waste:

    water 

     Pedro Kraemer, BOD!, "ndia

    ;ublic toilet with hidden treatment unit

    # bli t il t ith bi di t

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     # public toilet with a biogas digester 

     Jan-Olof Drangert, Linköping &niversity, Sweden

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    5aterial flows in the toilet complex

     

    Toilet units

      < showers

    =aece

    s

    >rine

      Bio?digester 

    >rine

    drying?bed

    9iEuid

    urine

     

    aeces washwater 

     #blution

      water 

     lush

    9iEuid fertili2er

      comost

    9iEuid urine

    aeces

    $rganic waste9ainwater 

    roundwater 

      recharge

     biogas

    oil conditioner Krine powder

     lurry

      Aerobic

      ond

     lurry

     ystem border