4.4 biogas reactors for treatment 2010-09-05
TRANSCRIPT
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4.4 Biogas – a way to solve sanitation
problems
H o w m u c h b i o g a s c a n b e p r o d u c e d f r o m
e x c r e t a a n d b i o m a s s ? H o w s a f e i s t h e p r o c e s s a n d i t s s l u d g e ? ?
Learning objectives: to know about the
fundamental processes in biogas production,
and get an overview of biogas generation in
the world
Anaerobic
fermentation
is a natural
andunavoidable
process
Jam-Olof Drangert, Linköping university, Sweden
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pying on !ature –
"hat can we learn from cows?
Inlet OutletBiogas digester
Cows convert biodegradable plants and water to
milk, cow dung and urine – and gases
Pedro Kraemer, BOD!, "ndia
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# new look at the cow – and bull
Inlet
Outlet
Biogas digester
The Biogas Plant
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# biogas plant operates though
anaerobic digestion of organic material
The Biogas Plant
InletOutlet
Biogas digester
Biogas
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$ntegrating biogas in agriculture
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ome examples of biogas plants
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"here is biogas technology applied?
#pproximate numbers of biogas units in selected countries%
&ountry !o of units 'olume ()** m+
&hina ),***,*** x*
$ndia -in **4 +,/**,*** ?
!epal -in **0 **,*** ?'ietnam, 1hailand, 1an2ania,Bangladesh, Burundi, Bra2il
x,***
+,4** -**/
in 3ermany
enya, 5exico, &uba, 3uyana x** ?
5orocco, 3hana, 6imbabwe,!icaragua, 7amaica, Bolivia x*
8, !9, ,1hailand,
##$ of all systems do not use pumps, agitator, and %eating
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#vailable human excreta in $ndia compared
to the need of fertiliser
Dry org. matter (DS) 9, t!day "itrogen (N) #$, t!day
%&osp&orus (P2O5) $, t!day
%otassium (K 2O) ', t!dayCarbon (C) '$, t!day
Calcium (CaO) $, t!day
%otential biogas $ mil m'
day
… oras a
resource
Excreta viewedas waste:
Faeces $, tons!day
Urine #,, m'!day
!:;:% <
=
6
>
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lurry application in agriculture
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nergy balance – for composting and digestion
Aerobic conversion (composting ):
C6 H12 O6 + 6O2 6 CO2 +6 H2 O
∆* +', k-!mol
Anaerobic conversion (digestion):
C6 H
12 O
6 + 2H
2 O 3 CO
2 + 3CH
4 + 2H
2O
∆* + $ k-!mol
Burning of biogas:
2CH4+ 6O2 CO2 + 6 H2 O
∆ * +',/$ k-!mol Pedro Kraemer, BOD!, "ndia
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Biogas appliances
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Biochemical process of anaerobic
fermentation@digestion
ce!ogenic
bac!eria
Fer"en!a!i#e
bac!eria
$e!%anogenic
bac!eria
Organic &as!e
Carbo%'ra!es
Fa!s
Pro!ein
a!er
*ac!eria
"ass
H2 , CO2 ace!ic aci
*ac!eria
"ass
$e!%an
+ CO2
*ac!eria
"ass
Pro-ionic aci
*.!'ric acico%os,
O!%er
co"-onen!s
H2 , CO2,
ace!ic aci
Step 1:Hydrolysis + Acidogenesis Step 2 :
Acetogenesis Step 3:Methanogenesis
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"hat parameters affect anaerobic digestion?
The most imortant determinants of good livingconditions for anaerobic bacteria and therefore efficient
gas roduction! are :
– 1emperature
– >etention 1ime
– pH:level
– &arbon@!itrogen ratio -&@! ratio
– ;roportion of dry matter in substrate A suitable viscosity – #gitation -mixing of the substrate
"f any one of these determinants is outside accetablerange! the digestion may be inhibited
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ubstrate temperature in the digester
#ommon temerature ranges for bacteria%
;sychrophillic bacteria below *o&
5esophillic bacteria * – 4*o&
1hermophillic bacteria above 4*o&
#naerobic fermentation can work in an ambienttemperature between +o& and 0*o& and, if colder,
the reactor has to be insulated and@or heated.
5ethane production is very sensitive to changes in
temerature Pedro Kraemer, BOD!, "ndia
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Biogas production with continuous feeding
Hydraulic retention time in days
9itres of
biogasper litre
of slurry
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)*
*
+*
C* )** )C*
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pH –value is crucial for a good result
$timal roduction when H %&' ( %&)
$nhibition -due to acids if pH D /.
$nhibition -due to ammonia if pH ( 0./
-H is a cen!ra -ara"e!er /or con!roing !%e anaerobic -rocess
8eviation from the optimum range results in%
9ower gas yield
$nferior gas Euality Pedro Kraemer, BOD!, "ndia
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&@! ratio is important
Microorganisms need * nitrogen, and# carbon, for their metabolism
Methanogenic organisms refer a
#-* ratio of between .':. and )':.
>ecommendation%
5ix different substrates
! must not be too low, or else
shortage of nutrient
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!itrogen inhibition
"f * concentration is too high -(),0** mg@l of !H4:!and pH is high, then
growth of bacteria is inhibited due to
toxicity caused by high levels of -uncharged ammonia
5ethanogens, however, are able of adapt to
C,*** : 0,*** mg@l of !H4:! given the pre:reEuisitethat the uncharged ammonia -!H+ controlled by pH
level does not exceed **:+** mg@l
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&hanges in dry matter -85 concentration
inside the digester
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Behaviour of the substrate inside the digester
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tirring the substrate
/tirring imroves the efficiency of digestion by:
>emoving metabolites -gas removal
Bringing fresh material in contact with bacteria
>educing scum formation and sedimentation
;reventing temperature gradients in the digester
#voiding the formation of blind spots -short cuts
However! excessive stirring disturbs the symbioticrelationshi between the different bacteria secies
imple biogas units normally do not have
mechanical stirring devises Pedro Kraemer, BOD!, "ndia
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fficiency of a biogas unit
"nut:
. 0g of dry 123, cattle dung will roduce )&2 04h -rule of thumb
. 0g dry .''3, matter can generate )&2-'&12 5 )&67 04h
/lurry contains .'3 dry matter! thus . litre can generate '&)67 04h
. litre slurry )%o#! 1' days retention, releases )% litre biogas
. m7 of biogas can generate 6 04h rule of thumb,
/o! . lit of slurry generates '&')%86 5 '&.6) 04h
#ctual k"h
;otential k"hfficiency A
*.)/
*./A A *./
/F efficiency and the other +GF energy remains in the slurry
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&heck:list
if gas production is lower than expected
#hec0 9esonse
$s pH (0.C ? =es #dd water and take pH after
one hour
!o
1oo much feed or of
skewed composition?
1emperature fallen? =es
=es
1ry to insulate digester,
less feed, heat substrate.
"ait one day
#dd lime -acute action
and wait one day
!o
$s pH D /.G ?
#dd urine or ash -kg@m+ and
wait ) day
=es
Drangert & Ejlertsson, Linkoping university, Sweden
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;rinciples for design and construction
as collector:
: fixed dome! or
: floating dome
&ontinuous feeding
or batch feeding
urther
treatment or
direct use
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ixed:dome biogas digester
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).
;
slurry
7
BirdIs
eye view
.)
7;
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loating:drum unit with water:Jacket
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#naerobic filter -off:plot system
gas manhole
inflow
scum
outflow
filter mass
grill
sludge
sedimentation tank filter tanks
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#naerobic baffled reactor Off-plot system
gas
manholes
m outflow
ge
sedimentation inoculation of fresh wastewater with active sludge final settler
#naerobic Baffled >eactor
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toilet sectionshower
section
anaerobic baffled
reactor
waste:
water
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;ublic toilet with hidden treatment unit
# bli t il t ith bi di t
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# public toilet with a biogas digester
Jan-Olof Drangert, Linköping &niversity, Sweden
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5aterial flows in the toilet complex
Toilet units
< showers
=aece
s
>rine
Bio?digester
>rine
drying?bed
9iEuid
urine
aeces washwater
#blution
water
lush
9iEuid fertili2er
comost
9iEuid urine
aeces
$rganic waste9ainwater
roundwater
recharge
biogas
oil conditioner Krine powder
lurry
Aerobic
ond
lurry
ystem border