a global presence - evatane · ftir astm d1238 dsc astm d1525 internal method iso 1133 iso 11357-3...

Evasin

Let’s progress together

Specialty Polyolefi ns

evatane.comlotader.comlotryl.comorevac.com

Headquarters: Arkema France420, rue d’Estienne d’Orves

92705 Colombes Cedex – FranceTel.: 33 (0)1 49 00 80 80Fax: 33 (0)1 49 00 83 96

arkema.com

Packaging • Tie layer for multilayers barrier fi lms

and extrusion lamination • Oxygen barrier layer • Sealing and Seal/Peel resins

Hot melt adhesives • EVA binder • High stability hot melt • Deep freeze hot melt adhesives

Construction • Additives for bitumen rutting resistance • Adhesive for pipe coating • Aluminum panels

Plastic compounds • Impact modifi ers for PA, PET, PBT, PPS, POM • Coupling agents for HFFR and composites • Automotive compounds • Compatibilization of recycled plastics

Automotive • Fuel tank • Sound deadening foams • Thermo adhesive fi lm

Energy • Cables compounds (LV, MV, HFFR) • Photovoltaic panels

Arkema Specialty Polyole� ns

With fi ve brands sold globally, Arkema offers the widest range of reactive and non-reactive specialty polyolefi ns:

Evatane® ethylene vinyl acetate copolymers (18-42% VA)

Lotryl® ethylene acrylate copolymers

Evasin* EVOH ethylene vinyl alcohol

Lotader® reactive polyolefi ns(up to 8% reactive group)

Orevac® T reactive EVA copolymers

Orevac® G grafted polyolefi ns (PE,PP, EVA)

Arkema Specialty Polyolefi ns are used in applications as diverse as:

Evasin* EVOH Oxygen barrier

GradesEthylene content (% mol)

Melt index (g/10min) Melting

point (°C)Crystalization

point (°C)Glass transition

point (°C)O2 Transmission Rate

(65% RH)(20°C)

Main applications190°C - 2.16 kg 210°C - 2.16 kg

EV 2951F 29 3 187 162 60 0.3 Bottles, pipes

EV 3251F 32 1.6 3.5 183 159 59 0.38 Bottles, sheets, fi lms

EV 3851F 38 1.6 3.7 173 151 54 0.71 Sheets, thermoforming, fi lms

EV 4405F 44 5.5 166 146 56 1.35 Sheets, thermoforming, shrinks, fi lms

Test method ASTM D1238 / ISO 1133 DSC ISO 11357 DSC ISO 11357 DMA ISO 11357 ASTM D3985 /

ISO 14663-2

Disclaimer: Please consult Arkema’s disclaimer regarding the use of Arkema’s products on http://www.arkema.com/en/products/product-safety/disclaimer/index.htmlRegulatory information: for information on regulatory compliance, consult your local representative.Read and understand the Material Safety Data Sheet (MSDS) before using these products.

*Evasin is a brand of Chang Chun Petrochemicals

EUROPEHeadquaters Arkema France420, rue d’Estienne d’Orves92700 ColombesFRANCETel.: (+33) 1 49 00 80 80Fax: (+33) 1 49 00 83 96

NORTH AMERICAAltuglas International100 PA Route 413Bristol, PA 19007USA Tel.: (+1) 215 826 2600

ASIAArkema Pte LtdRepresentative offi ce19th Floor, ITF Tower140/41 Silom Road,Suriyawonge Bangrak10500 B THAILAND Tel.: (+66) 2 237 62 57

SOUTH AMERICAArkema Quimica LtdaAv. Ibirapuera 20334° andar - Bairro MoemaCEP 04029 - 901 São PauloBRAZIL Tel.: (+55) 11 21 48 85 22

Depending on the grade, we offer the following packaging: 25 kg bags, 500/550 kg cardboard boxes and 1000/1100 kg big bags.

Arkema operates in more than 50 countries. For help fi nding a local representative, please consult our web sites or contact one of the following regional customer contact centers.

Production plant R&D Sales offi ce

A global presenceArkema produces more than 100 Specialty Polyolefi ns grades in four sites in Europe and one in North America and is represented in several sales offi ces in Asia, Latin America. Several of our production lines have online quality control to deliver consistent quality. ISO certifi cates are available in our web sites.

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EBA (Ethylene-Butyl Acrylate copolymer) EMA (Ethylene-Methyl Acrylate copolymer)

Ethylene - Vinyl acetate copolymers

Grades Bases

Specifi ed properties* Typical properties** Main applications

Comonomer content (%)

Melt index (g/10 min)

(190°C–2.16 kg)Melting point

(°C)Vicat softening

temp. (°C)Ring and ball

temp. (°C)HardnessShore A Hot Melt adhesives Films / Sheets Foams Cables Sound

dampening Others

18-150

17 - 19 135 - 175 88 43 102 85 Bitumen18-500 17 - 19 450 - 550 86 43 94 90 Bitumen20-20 19 - 21 17 - 23 83 46 127 89 Bitumen24-03 23 - 25 2.5 - 3.5 80 46 183 83 Bitumen28-03 26 - 28 3 - 4.5 76 41 166 82 Crude oil28-05 27 - 29 5 - 8 72 40 160 80

28-25*** 27 - 29 22 - 29 71 <40 120 75 Solar panel28-40 27 - 29 35 - 45 70 <40 106 73 Crude oil28-150 27 - 29 135 - 175 69 <40 95 71 Crude oil28-420 27 - 29 370 - 470 66 <40 84 70 Crude oil28-800 30 - 32 700 - 900 63 <40 80 60 Crude oil33-25 32 - 34 22 - 29 63 <40 119 6733-45 32 - 34 38 - 48 62 <40 107 63

33-45 PV 32 - 34 38 - 48 62 <40 107 63 Solar panel33-400 32 - 34 350 - 450 63 <40 84 6040-55 38 - 41 48 - 62 55 <40 97 5042-60 >41 65 - 85 48 <40 95 42 Ink

Test methodFTIR ASTM D1238 DSC ASTM D1525 ASTM E28 ASTM D2240

Internal method ISO 1133 ISO 11357-3 ISO 306 NF EN1238 ISO 868

* Properties routinely measured during the standard quality control procedure ** indicative average values *** Photovoltaic (PV) quality available

EVA (Ethylene-Vinyl Acetate copolymer)

evatane.com

Grades Types Base polymer

Typical Properties* Main applications

Adhesion to / A� nity withReactivity (+ medium)

(++ high)

Melt index(g/10min.)

(190°C, 2.16k)Melting point

temp. (°C)Extrusion coating /

Lamination Cast / Blown

fi lm coexPlastic modifi cation/

Coupling agent /Cables HFFR

Sheet coex Blow molding/ Tube coex

PE/EVAgrades

EVA + 3.5 75 51 PE / PET / PS / PA / EVOH18302N LLDPE ++ 1.5 123 84 Coupling agent PE / Mineral fi llers / natural fi bers18334 LLDPE + 1.0 125 101 PE / PA / EVOH18341 LLDPE ++ 1.5 121 95 Concentrate Coupling agent Concentrate Concentrate Concentrate PE / Mineral fi llers / PA/ EVOH

18342N HDPE + 3.5 125 110 PE / Epoxy primer / EVOH / 3LPE coating18362 LLDPE + 2.0 123 94 PE / PA / EVOH18507 HDPE ++ 5.0 128 - Coupling agent PE / Mineral fi llers / natural fi bers18910 LLDPE + 1.5 117 77 PE / PS / PA / EVOHIM300 VLDPE + 1.2 112 <40 Impact modifi er PAIM800 VLDPE ++ 0.5 55 <40 Impact modifi er PAOE825 LLDPE ++ 3.0 118 99 Concentrate Concentrate Concentrate Concentrate PE / PA/ EVOHOE850 LLDPE ++ 7.5 104 89 Concentrate Concentrate PE: Alu / Primed fi lms / EVOH

PPgrades

Random PP + 7.0** 143 120 PP, PA, EVOH18725N Random PP + 13** 124 - PP,PA, Epoxy, Metals18729 Homo PP + 4.5** 162 137 PE, PA, EVOH18732 Copo PP + 8.0** 134 120 PP, PA, EVOH, Alu, Epoxy18750 Homo PP + 35** 160 121 PP, PA, EVOH, Alu18751 Homo PP + 35** 160 138 PP, PA, EVOH, Alu

CA100/CA100N Homo PP 1% 10*** 167 147 Concentrate Coupling agent PP / mineral fi llers / glass & natural fi bers

Test methodFTIR ASTM D1238 DSC ASTM D1525

internal method ISO 1133 ISO 11357-3 ISO 306

Grafted polyolefi ns (LDPE, LLDPE, HDPE, VLDPE, EVA)

* Indicative average values ** Melt index (230°C, 2.16 kg) *** Melt index (190°C, 325 g)

orevac.com

Ethylene - Acrylate copolymers

Combined with Lotryl®, some masterbatches are available to enhance slip and antiblock properties.

Grades Bases

temp. (°C)Flexural modulus

(MPa)HardnessShore A/D

Hot melt adhesives

Films / Sheetscoating

Foams / Sound dampening

Modifi cation of thermoplastic polymers

Extrusion coating /

LaminationCables

18MA02

EMA Autoclave

17 - 20 2 - 3 83 53 - 50 -/2520MA08 19 - 21 7 - 9 76 46 - 20 83/-

24MA005 23 - 26 0.4 - 0.6 72 45 - 18 84/-24MA02 23 - 26 1 - 3 68 49 - 18 79/-29MA03 27 - 31 2.0 - 3.5 61 <40 175 10 75/-

2012Bestpeel

20 ** 11 ** 79 42 - 25 84/212407 24 ** 7 ** 69 <40 - 14 79/22

17BA04

EBA Autoclave

16 - 19 3.5 - 4.5 93 60 - 45 -/3228BA175 26 - 30 150 - 200 75 40 94 23 80/-30BA02 28 - 32 1.5 - 2.5 75 41 >190 <10 75/-35BA40 33 - 37 35 - 45 66 <40 110 <10 70/-35BA320 33 - 37 260 - 350 65 <40 85 <10 52/-20MA08T

EMA Tubular

19 - 21 7 - 9 97 49 - 3624MA02T 23 - 26 1 - 3 95 40 - 1729MA03T 27 - 31 2.0 - 3.5 92 <40 - 1235BA40T EBA

Tubular33 - 37 35 - 45 89 <23 134 <10

HMA high content 260 - 350 90 <23 102 <10

Test methodFTIR ASTM D1238 DSC ASTM D1525 ASTM E28 ASTM D790 ASTM D2240

Internal method ISO 1133 ISO 11357-3 ISO 306 NF EN1238 ISO 178 ISO 868EBA (Ethylene-Butyl Acrylate copolymer) EMA (Ethylene-Methyl Acrylate copolymer)

lotryl.com

Grades Reactive group

Co-monomer(%)

Reactive group (%)

LaminationThermoadhesive

fi lmsPlastic modifi cation

Coupling agentCables HFFR

Bitumen additives Others

AX8700

GMAEpoxide group

BA (25%) 8 9 72 - PET, PBT, PPS FoamsAX8750 BA (25%) 5 12 72 - PET, PBT, PPS AX8820 - 4.5 2 107 88 PET, PBT, PPS TonersAX8840 - 8 5 106 87 PET, PBT, PPS TonersAX8900 MA (24%) 8 6 65 <40 PET, PBT, PPS FoamsAX8930 MA (25%) 3 7 67 <40 PET, PBT, PPS Foams

Maleic anhydride High content

BA (6.5%) 3.6 10 105 69 Concentrate3210 BA (6%) 3.1 5 107 76 PA3410 BA (17%) 3.1 5 89 47 PA3430 MA (15%) 3.1 7 84 45 PA

LX4110 EA (5%) 3 5 105 786200 EA (6.5%) 2.8 40 102 668200 EA (6.5%) 2.8 200 100 57 Hot melt

TX8030 EA (13%) 2.8 3 95 65 Pipe coating4700

Maleic anhydrideLow content

EA (29%) 1.3 7 65 <40 PA4503 MA (20%) 0.3 8 80 454613 MA (24%) 0.3 7 98 41

T 9307Y VA (14%) 0.2 10.5 93 66

9318 VA (18.5%) 0.2 7 86 54

9304 VA (25%) 0.2 7.5 80 49

9305 VA (28%) 0.6 180 68 <40 Hot melt

Test methodFTIR FTIR ASTM D1238 DSC ASTM D1525

Int. method Int. method ISO 1133 ISO 11357-3 ISO 306MA (Methyl Acrylate) BA (Butyl Acrylate) EA (Ethyl Acrylate) VA (Vinyl Acetate)

Reactive terpolymers lotader.com orevac.com

Grades Bases

dampening Others

18-150

evatane.com

(++ high)

PE/EVAgrades

PPgrades

orevac.com

Grades Bases

Hot melt adhesives

Extrusion coating /

LaminationCables

18MA02

EMA Autoclave

17 - 20 2 - 3 83 53 - 50 -/2520MA08 19 - 21 7 - 9 76 46 - 20 83/-

24MA005 23 - 26 0.4 - 0.6 72 45 - 18 84/-24MA02 23 - 26 1 - 3 68 49 - 18 79/-29MA03 27 - 31 2.0 - 3.5 61 <40 175 10 75/-

2012Bestpeel

20 ** 11 ** 79 42 - 25 84/212407 24 ** 7 ** 69 <40 - 14 79/22

17BA04

EBA Autoclave

16 - 19 3.5 - 4.5 93 60 - 45 -/3228BA175 26 - 30 150 - 200 75 40 94 23 80/-30BA02 28 - 32 1.5 - 2.5 75 41 >190 <10 75/-35BA40 33 - 37 35 - 45 66 <40 110 <10 70/-35BA320 33 - 37 260 - 350 65 <40 85 <10 52/-20MA08T

EMA Tubular

19 - 21 7 - 9 97 49 - 3624MA02T 23 - 26 1 - 3 95 40 - 1729MA03T 27 - 31 2.0 - 3.5 92 <40 - 1235BA40T EBA

Tubular33 - 37 35 - 45 89 <23 134 <10

HMA high content 260 - 350 90 <23 102 <10

lotryl.com

Co-monomer(%)

Reactive group (%)

AX8700

GMAEpoxide group

EA (29%) 1.3 7 65 <40 PA4503 MA (20%) 0.3 8 80 454613 MA (24%) 0.3 7 98 41

T 9307Y VA (14%) 0.2 10.5 93 66

9318 VA (18.5%) 0.2 7 86 54

9304 VA (25%) 0.2 7.5 80 49

9305 VA (28%) 0.6 180 68 <40 Hot melt

Grades Bases

dampening Others

18-150

evatane.com

(++ high)

PE/EVAgrades

PPgrades

orevac.com

Grades Bases

Hot melt adhesives

Extrusion coating /

LaminationCables

18MA02

EMA Autoclave

17 - 20 2 - 3 83 53 - 50 -/2520MA08 19 - 21 7 - 9 76 46 - 20 83/-

24MA005 23 - 26 0.4 - 0.6 72 45 - 18 84/-24MA02 23 - 26 1 - 3 68 49 - 18 79/-29MA03 27 - 31 2.0 - 3.5 61 <40 175 10 75/-

2012Bestpeel

20 ** 11 ** 79 42 - 25 84/212407 24 ** 7 ** 69 <40 - 14 79/22

17BA04

EBA Autoclave

16 - 19 3.5 - 4.5 93 60 - 45 -/3228BA175 26 - 30 150 - 200 75 40 94 23 80/-30BA02 28 - 32 1.5 - 2.5 75 41 >190 <10 75/-35BA40 33 - 37 35 - 45 66 <40 110 <10 70/-35BA320 33 - 37 260 - 350 65 <40 85 <10 52/-20MA08T

EMA Tubular

19 - 21 7 - 9 97 49 - 3624MA02T 23 - 26 1 - 3 95 40 - 1729MA03T 27 - 31 2.0 - 3.5 92 <40 - 1235BA40T EBA

Tubular33 - 37 35 - 45 89 <23 134 <10

HMA high content 260 - 350 90 <23 102 <10

lotryl.com

Co-monomer(%)

Reactive group (%)

AX8700

GMAEpoxide group

EA (29%) 1.3 7 65 <40 PA4503 MA (20%) 0.3 8 80 454613 MA (24%) 0.3 7 98 41

T 9307Y VA (14%) 0.2 10.5 93 66

9318 VA (18.5%) 0.2 7 86 54

9304 VA (25%) 0.2 7.5 80 49

9305 VA (28%) 0.6 180 68 <40 Hot melt

Grades Bases

dampening Others

18-150

evatane.com

(++ high)

PE/EVAgrades

PPgrades

orevac.com

Grades Bases

Hot melt adhesives

Extrusion coating /

LaminationCables

18MA02

EMA Autoclave

17 - 20 2 - 3 83 53 - 50 -/2520MA08 19 - 21 7 - 9 76 46 - 20 83/-

24MA005 23 - 26 0.4 - 0.6 72 45 - 18 84/-24MA02 23 - 26 1 - 3 68 49 - 18 79/-29MA03 27 - 31 2.0 - 3.5 61 <40 175 10 75/-

2012Bestpeel

20 ** 11 ** 79 42 - 25 84/212407 24 ** 7 ** 69 <40 - 14 79/22

17BA04

EBA Autoclave

16 - 19 3.5 - 4.5 93 60 - 45 -/3228BA175 26 - 30 150 - 200 75 40 94 23 80/-30BA02 28 - 32 1.5 - 2.5 75 41 >190 <10 75/-35BA40 33 - 37 35 - 45 66 <40 110 <10 70/-35BA320 33 - 37 260 - 350 65 <40 85 <10 52/-20MA08T

EMA Tubular

19 - 21 7 - 9 97 49 - 3624MA02T 23 - 26 1 - 3 95 40 - 1729MA03T 27 - 31 2.0 - 3.5 92 <40 - 1235BA40T EBA

Tubular33 - 37 35 - 45 89 <23 134 <10

HMA high content 260 - 350 90 <23 102 <10

lotryl.com

Co-monomer(%)

Reactive group (%)

AX8700

GMAEpoxide group

EA (29%) 1.3 7 65 <40 PA4503 MA (20%) 0.3 8 80 454613 MA (24%) 0.3 7 98 41

T 9307Y VA (14%) 0.2 10.5 93 66

9318 VA (18.5%) 0.2 7 86 54

9304 VA (25%) 0.2 7.5 80 49

9305 VA (28%) 0.6 180 68 <40 Hot melt

Evasin

arkema.com

(65% RH)(20°C)

ISO 14663-2

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Evasin

arkema.com

(65% RH)(20°C)

ISO 14663-2

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a global presence - evatane · ftir astm d1238 dsc astm d1525 internal method iso 1133 iso 11357-3...

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