advanced cleaning product formulations vol. 4

ADVANCED CLEANING PRODUCT FORMULATIONS

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ADVANCED CLEANING

PRODUCT

FORM U LATIO NS Volume 4

Ernest W. Flick

NOYES PUBLICATIONS Westwood, New JOrsey, U.S.A.

Copyright 0 19% by Ernest W. Flick No part of this book may be reproduced or utilized in any form or by any means. electronic or mechanical, including photocopying. recording or by any information storage and retrieval system. without permission in writing from the Publisher.

Library of Congress Catalog C u d Number: 89-30274

Printed in the United States ISBN 0-8155-1396-8

Published in the United States of America by Noyes Publications 369 Fairview Avenue Weshvood, New Jersey 07675

10 9 8 7 6 5 4 3 2 1

Library of Congress Cataloging-in-Publication Data (Revised for vo1.4)

Flick, Ernest W. Advanced cleaning produd formulations

Includes bibliographid references and index. 1. Cleaning compounds. I. Title

TP990.F56 1989 668'1 89-30274 ISBN 0-8155-1186-8 (v. 1) ISBN 0-8155-1346-1 (v. 2) ISBN 0-8155-1382-1 (v. 3) ISBN 0-8155-1396-8 (v. 4)

To

Ernie and Jeanne

and

AIIp and Barbara

and

Chris and Rachel

V

This book (Volume 4) presents more than 435 up-to-date advanced cleaning product formulations for household, industrial and automotive applications. It is the result of information received from numerous industrial companies and other organizations. The data represent selections made at no cost to, nor influence from, the makers or distributors of these materials. Only the most recent formulas have been included. All formulations are completely different than those contained in Volumes 1, 2 and 3 published earlier.

Formulation in the cleaning product industry has gradually been undergoing significant change during the past years. Raw materials costs have risen and manufacturers have been reluctant to pass along these increases. Environmental considerations have also played a part. By changing formulations to improve cost/performance characteristics, manufacturers have been able to control costs but still enhance performance. This book presents manufacturers' suggested formulations which might meet new performance criteria.

The formulations in this book are divided into the following sections and chapters, with the number of formulations indicated in ( ):

I. Household and Industrial Cleaners and Polishes 1. Bathroom Cleaners (26) 2. Dairy, Food and General Industrial Cleaners (15) 3. Degreasers (5) 4. Dishwashing Detergents (47) 5. General Purpose Cleaners (34) 6. Glass Cleaners/Polishes (25) 7. Hard Surface Cleaners (44) 8. Laundry Products (65) 9. Metal Cleaners and Polishes (22)

10. Oven, Grill and Hot Plate Cleaners (3) 11. Polishes, Coatings and Finishes (30) 12. Rinse Aids (4) 13. Rug, Floor, Carpet, Upholstery Shampoos and Cleaners (32) 14. Miscellaneous (32)

vii

Preface

viii Preface

11. Transportation Cleaners and Polishes 15. Auto Cleaners and Polishes (14) 16. Car and Truck Wash Compounds (27) 17. Whitewall Tire Cleaners (4) 18. Miscellaneous (8)

Each formula is located in the chapter which is most applicable. The reader, seeking a formula for a specific end use, should check each chapter which could possibly apply. In addition to the above, there are two other sections which will be helpful to the reader.

111. Achemical trademark section where each tradenamed raw material included in the book is listed with a chemical description and the supplier's name. The specifications which each raw material meets are included, if applicable.

IV. Main office addresses of the suppliers of trademarked raw materials.

Each formulation in the book lists the following information, as available, in the manufacturer's own words:

0

Description of end use and most outstanding properties.

The percent by weight or volume of each raw material included in the formula, rounded to a decimal figure.

Key properties of the formula, which are the features that the source considers to be more outstanding than other formulations of the same type. The formula source, which is the company or organization that supplied the formula. The secondary source may be the originating company and/or the primary source's publication title, or both. A formula number is included, if applicable.

0

The table of contents is organized in such a way as to serve as a subject index.

My fullest appreciation is expressed to the companies and organizations who supplied the original starting formulations included in this book. I also thank the suppliers of the raw materials included in these formulations, who furnished information describing their trademarked raw materials.

Newburyport, Massachusetts August 1996

Ernest W. Flick

NOTICE

To the best of our knowledge the information in this publication is accurate; however, the Publisher does not assume any responsibility or liability for the accuracy or completeness of, or consequences arising from, such information. This book is intended for informational purposes only. Mention of trade names or commercial products does not constitute endorsement or recommendation for use by the Publisher. Final determ- ination of the suitability of any information or product for use contemplated by any user, and the manner of that use, is the sole responsibility of the user. We recommend that anyone in- tending to rely on any recommendation of materials or procedures mentioned in this publication should satisfy himself as to such suitability, and that he can meet all applicable safety and health standards.

X

1 .

Contents and Subject Index

SECl'ION I HOUSEHOLD AND INDU-

CLEANERS AND POLISHES

BATHROOM CLEANERS .............................. 2 Bathtub and Faucet Cleaner ............................ 3 Bathroom Cleaner ................................... 3 Toilet Bowl Cleaner ................................. 3 Tub and Tile Cleaner ................................ 3

Thick Toilet Bowl Cleaner ............................ 4 Foamable Acid Tile Cleaner ........................... 5 Liquid Toilet Bowl Cleaner ............................ 5 Solid Automatic Toilet Bowl Cleaner Formulation . . . . . . . . . . . 6 Acid Toilet Bowl Cleaner ............................. 6 Tub. Tile and Bathroom Cleaner ........................ 6 Tile. Porcelain and Bathroom Cleaner. Acid . . . . . . . . . . . . . . . . 7 Hypochlorite Tub and Tile Cleaner and Mildew Stain

Remover ....................................... 7 Soap Scum RemoverICleaner ........................... 7 Toilet Cleaner

LiquidA ...................................... 8 Liquid B . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 8

Clear Liquid Bowl Cleaner ............................ 4

Medium Viscosity-A ............................. 8 Medium Viscosity-B ............................. 8 Medium Viscosity-A ............................. 9 Medium Viscosity-B ............................. 9 Powder ....................................... 9 Powder-B ..................................... 9

Extruded-A ................................... 10 Extruded-B ................................... 10 Cast-A ...................................... 10 Cast-B ...................................... 10

Toilet Cleaning Block

xi

xii Contents and Subject Index

2 . DAIRY. FOOD AND GENERAL INDUSTRIAL CLEANERS . . . 11

Acid Dilutable Concentrate . . . . . . . . . . . . . . . . . . . . . . . . 12 Low Cost Acid Dilutable Concentrate . . . . . . . . . . . . . . . . 12

Dairy Milkstone Remover

Dairy Pipeline Cleaner-High Alkaline Low Foam

Institutional Stainless Steel Cleaner . . . . . . . . . . . . . . . . . . . . . 13 High Pressure Cleaner for Industrial Use . . . . . . . . . . . . . . . . . 14 Cleaner for Milking Equipment . . . . . . . . . . . . . . . . . . . . . . . . 14 Cleaner for Meat Plants . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 14 Meat Packaging Plant Cleaner Concentrate . . . . . . . . . . . . . . . . 15 Steam Cleaners

Light Duty . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 16

Hypochlorite Cleaner . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 13

Medium Duty . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 16 Heavy Duty (for Oily Soils) . . . . . . . . . . . . . . . . . . . . . . . 16 General Purpose . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 16 Light Duty for Soft Metals . . . . . . . . . . . . . . . . . . . . . . . . 16 Compound . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 16

3 . DEGREASERS . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 17 d-Limonene Microemulsion Cleanermegreaser . . . . . . . . . . . . . 18 Concentrated d-Limonene Biodegradable Degreaser . . . . . . . . . 18 Solvent Degreasing . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 19

4 . DISHWASHING DETERGENTS . . . . . . . . . . . . . . . . . . . . . . . . . 20 Clear Liquid Dishwash . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 21 Non-Chlorinated Machine Dishwashing Compound. Liquid . . . . 21 Clear. Colorless Manual Dish Wash . . . . . . . . . . . . . . . . . . . . . 21

Powder for Automatic Dishwashing Machines . . . . . . . . . . . . . . 23 Dishwashing Detergent

Medium Viscosity

Dish Washing Agent . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 22

Basis Marlon A-A . . . . . . . . . . . . . . . . . . . . . . . . . . . 24 Basis Marlon A-B . . . . . . . . . . . . . . . . . . . . . . . . . . . 24 Basis Marlon AS3-A . . . . . . . . . . . . . . . . . . . . . . . . . 24 Basis Marlon AS3-B . . . . . . . . . . . . . . . . . . . . . . . . . 24 Basis Marlon PS-A . . . . . . . . . . . . . . . . . . . . . . . . . . 25 Basis Marlon PS-B . . . . . . . . . . . . . . . . . . . . . . . . . . 25 Basis Marlon Compounds-A ..................... 25 Basis Marlon Compounds-B . . . . . . . . . . . . . . . . . . . . 25

Powdered Spray Mixing Process-A . . . . . . . . . . . . . . . . . . . . . . 26 Spray Mixing Process B . . . . . . . . . . . . . . . . . . . . . . . 26 Phosphate-Free. Spray Mixing. Process A . . . . . . . . . . 26

Contents and Subject Index xiii

Phosphate.Free. Spray Mixing. Process B . . . . . . . . . . 26 40% Solids-A . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 27 40% Solids-B .............................. 27

Hand Dishwashing Liquid ............................ 27 Dish Wash w/Amine Oxide/LABS/SLES . . . . . . . . . . . . . . . . . 28 Dish Wash w/Amine Oxide/LABS/ALES . . . . . . . . . . . . . . . . . 28 Dish Wash w/Amine Oxide/LABS ...................... 28 High-Performance Hand Dish Detergent . . . . . . . . . . . . . . . . . 29 Mild Liquid Hand Dish Detergent ...................... 29 Starting Formulations for Home Machine Dishwashing

Detergents 8.7% Phosphorous(A) ............................ 30 8.7% Phosphorous(l3) ............................ 30 Nonphosphate ................................. 30

Pilot Formula #LDL-010-01 ...................... 31 Pilot Formula #LDL-013-01 ...................... 31 Pilot Formula #LDL-005-01 ...................... 31 Pilot Formula #LDL-O15-01 ...................... 31 Premium Hand Dishwash ......................... 32 Economy Hand Dishwash ......................... 32

Liquid Hand Dish Detergent . . . . . . . . . . . . . . . . . . . . . . . . . . 33 Mechanical Dishwashing Detergent. Chlorinated . . . . . . . . . . . . 34 Mechanical Dishwashing Detergent. Liquid . . . . . . . . . . . . . . . 34 Non-DDBSA Dishwashing Liquid ...................... 35 Starting Formulations for Commercial Machine

Light Duty Liquid Detergents

Dishwashing Detergents Nonchlorine/Noncaustic .......................... 36 Noncaustic . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 36 ChlorineKaustic ................................ 36

5 . GENERAL PURPOSE CLEANERS ....................... 37

Phosphate Free All Purpose Cleaner ..................... 38 Bathroom Tile Cleaner . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 38 All Purpose Cleaner . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 39 Hard-surface Cleaner ............................... 39 All-Purpose Cleaner

Cleaner-A . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 40 Cleaner-B . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 40 With Microbicidal Properties. Liquid-B . . . . . . . . . . . . . . . 40

All Purpose Cleaner ................................ 38

Liquid-A . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 41 Liquid-B . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 41 With Microbicidal Properties. Liquid-A . . . . . . . . . . . . . . . 41

xiv Contents and Subject Index

Pasty-A . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 42

With Soap. High Viscosity-A . . . . . . . . . . . . . . . . . . . . . . 42 With Soap. High Viscosity-B

Pasty-B . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 42

. . . . . . . . . . . . . . . . . . . . . . 42 D-Limonene Emulsifiable Concentrate . . . . . . . . . . . . . . . . . . . 43 D-Limonene All Purpose Cleaner . . . . . . . . . . . . . . . . . . . . . . 43 General Cleaners

Household . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 44 Alkaline Cleaner . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 44 Liquid Hand Cleaner . . . . . . . . . . . . . . . . . . . . . . . . . . . . 44 Germicidal Cleaner . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 44

High-Performance General Purpose Cleaner Concentrate . . . . . . 45 Heavy-Duty Cleaner Powder . . . . . . . . . . . . . . . . . . . . . . . . . . 45 Neutral All-Purpose Cleaner. with Pearlescence Effect

High Viscosity-A . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 46 High Viscosity-B . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 46

With Acetic Acid-A . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 46 With Acetic Acid-B . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 46

Non-Phosphate All Purpose Cleaner .................... 47 Oil Splitting General Purpose Cleaner . . . . . . . . . . . . . . . . . . . 47 Scouring Cleaner

Medium Viscosity-A . . . . . . . . . . . . . . . . . . . . . . . . . . . . 48 Medium Viscosity-B . . . . . . . . . . . . . . . . . . . . . . . . . . . . 48 Powder-A . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 48 Powder-B . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 48

All-Purpose Cleaner

6 . GLASS CLEANERSD’OLISHES . . . . . . . . . . . . . . . . . . . . . . . . . 49

For Application to Cloth . . . . . . . . . . . . . . . . . . . . . . . . . . 50 For Direct Application to Glass . . . . . . . . . . . . . . . . . . . . . 51

Anti-Fogging. Anti-Static Glass Cleaner . . . . . . . . . . . . . . . . . 52 Ammoniated Glass Cleaner . . . . . . . . . . . . . . . . . . . . . . . . . . . 52 Glass Cleaners

Ammonia . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 53 Vinegar . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 53

Antifog Composition

Glassware and Bottle Cleaners Bottle Cleaner

Alkaline-Powder . . . . . . . . . . . . . . . . . . . . . . . . . . . . 54 Acid-Powder . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 54 Acid-Liquid . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 54 Highly Alkaline . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 54

Household Window Cleaner . . . . . . . . . . . . . . . . . . . . . . . . . . 55 Premium Household Window Cleaner . . . . . . . . . . . . . . . . . . . 55

Contents and Subject Index xv

Low VOC Antistat/Cleaner for Glass .................... 56 Anti-Fog Glass Cleaner . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 56 Glass Cleaner ..................................... 56 Traditional Consumer Glass Cleaner .................... 57 Consumer Acid Glass Cleaner ......................... 57

7 . HARD SURFACE CLEANERS .......................... 58 Abrasive Cleaner-1 ................................ 59 Abrasive Cleaner-2 . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 59 Abrasive Cleaner-3 ................................ 59 Concentrated Liquid Household Hard-surface Cleaner . . . . . . . 60 All-Purpose Household Spray Cleaner . . . . . . . . . . . . . . . . . . . 60 Consumer Tile Cleaner .............................. 61 Industrial Strength Chlorine Cleaner ..................... 61 D-Limonene Hard-surface Cleaners .................... 62 d'limonene Spray Cleaner ............................ 63 d'limonene Cleaner Concentrate ....................... 63 General Purpose Hard Surface Cleaner . . . . . . . . . . . . . . . . . . . 64 Alkaline Hard Surface Cleaner ........................ 64 General Purpose Hard-surface Cleaners . . . . . . . . . . . . . . . . . . 65 Unbuilt. High-Sudsing. Hard-surface Cleaner . . . . . . . . . . . . . 65 Hard Surface Cleaner ............................... 66 Non-Abrasive Cleanser .............................. 66 Hard Surface Cleaner ............................... 66 Floor Cleaner Products .............................. 68 Rug Cleaner ...................................... 68 Plastic. Vinyl and Leather Cleaner ...................... 68 Hard Surface Cleaners .............................. 69 Tub and Tile Cleaners ............................... 69 Counter Top/Wall Cleaners

AlIPurposeType ............................... 69 Ammoniated Type .............................. 69

Hard Surface Cleaner w/Amphoteric .................... 70 Hard Surface Cleaner Concentrate

w/d'Limonene ................................. 70 Alkaline All-Purpose Cleaner Concentrate . . . . . . . . . . . . . 71 All-Purpose Alkaline Cleaner for Sponge or Spray

Application ................................. 71 High-Performance. Hard Surface Cleaners . . . . . . . . . . . . . . . . 72 Economical Pine Oil Hard-surface Cleaner . . . . . . . . . . . . . . . 72 Mild Abrasive Hard Surface Cleaner .................... 73 Non-Phosphate Household Hard-surface Cleaner . . . . . . . . . . . 74 Non-Phosphate Concentrated Household Hard-surface

Cleaner . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 74

xvi Contents and Subject Index

Pine Oil Cleaner Concentrate . . . . . . . . . . . . . . . . . . . . . . . . . . 75 Liquid Super Concentrate . . . . . . . . . . . . . . . . . . . . . . . . . . . . 75

8 . LAUNDRY PRODUCTS . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 76 Anionic/Nonionic Heavy-Duty Laundry Detergent . . . . . . . . . . 77 Nonionic/Amphoteric Heavy-Duty Laundry Liquid . . . . . . . . . . 78 Cold Water Detergent . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 79 Fine Fabric Detergent . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 79

Process-A . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 80 P~OUXS-B . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 80

Medium Viscosity-A . . . . . . . . . . . . . . . . . . . . . . . . . . . . 81 Medium Viscosity-B . . . . . . . . . . . . . . . . . . . . . . . . . . . . 81

Medium Viscosity-A . . . . . . . . . . . . . . . . . . . . . . . . . . . . 81 Medium Viscosity-B . . . . . . . . . . . . . . . . . . . . . . . . . . . . 81

Detergent for Fine Fabrics-1 . . . . . . . . . . . . . . . . . . . . . . . . . . 82 Detergent for Fine Fabrics-2 . . . . . . . . . . . . . . . . . . . . . . . . . . 82 Enzymatic Heavy-Duty Laundry Detergent Non-Phosphate Laundry Powder . . . . . . . . . . . . . . . . . . . . . . . 83 Fabric Pretreatment Spritz . . . . . . . . . . . . . . . . . . . . . . . . . . . . 84 Low VOC Pump Fabric Antistatic Spray Laundry Pre-Spotter and Stain Remover

Detergent for Colored Fabrics. Powder. Spray Mixing

Detergent for Curtains

Manual-Wash Detergent. Foaming

. . . . . . . . . . . . . . . 83

. . . . . . . . . . . . . . . . . 84

. . . . . . . . . . . . . . . . . 84

Process-1 . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 85 Pr0~ess-2 . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 85 Process-3 . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 85 Low Viscosity-A . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 86 Low Viscosity-B . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 86 Concentrate. Low Viscosity-A . . . . . . . . . . . . . . . . . . . . . 86 Concentrate. Low Viscosity-B . . . . . . . . . . . . . . . . . . . . . 86

Spray Mixing Process-A . . . . . . . . . . . . . . . . . . . . . . . . . . 87 Spray Mixing Process-B . . . . . . . . . . . . . . . . . . . . . . . . . . 87 Spray Mixing Process-A . . . . . . . . . . . . . . . . . . . . . . . . . . 88 Spray Mixing Process-B . . . . . . . . . . . . . . . . . . . . . . . . . . 88

Viscosity-A . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 88

Fabric Softener

Heavy-Duty Detergent. Powder

Liquid Heavy-Duty Detergent. Built Type. High

Heavy Duty Liquid Laundry Detergent-Type DN . . . . . . . . . . 89 Built Formulation #1 . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 89 Heavy Duty Liquid Laundry Detergent-Type TA . . . . . . . . . . 90

Heavy Duty Liquid Laundry Detergent-Type WA . . . . . . . . . . 91 Liquid Laundry Detergents . . . . . . . . . . . . . . . . . . . . . . . . . . . 90

Contents and Subject Index xvii

Built Formulation #2 ................................ 91 Liquid Heavy-Duty Detergent

Low Viscosity-A ............................... 92 Low Viscosity-B ............................... 92 Built Type. High Viscosity-B ...................... 92

Light-Duty Detergent. Powder Spray Mixing Process-A .......................... 93 Spray M i n g Process-B .......................... 93

With Incorporated Softener. Low Viscosity-A . . . . . . . . . . 93 Low VisCosity-A ............................... 94 Low Viscosity-B ............................... 94 With Incorporated Softener. Low Viscosity-B .......... 94

Industrial Laundry Two-Part Systems. Uniforms (Petroleum Greases and Oils) ........................ 95

HoteVLinen Supply (Animal and Vegetable Grease) . . . . . . . . . 95 Industrial Laundry Powder. Uniforms .................... 95 Laundry Liquids ................................... 96 "Fine Care" Fabric Detergents

Pilot Formula #LDY-OO3-01 ...................... % Pilot Formula #LDL-003-01 ...................... 96

Pilot Formula #HDL-004-01 ...................... % Pilot Formula #HDL-005-01 ...................... %

Laundry Powder Detergent ........................... 97 Industrial Laundry One-Shot Liquid .................... 97 Liquid Heavy Duty Detergent HDLD .................... 98 Liquid Detergent "FSL" A ............................ 98

Thick Bleach-2 ................................... 99 Wool Detergent

Medium Viscosity-A ........................... 100 Medium Viscosity-B ........................... 100

Liquid Light-Duty Detergent

Heavy Duty Laundry Liquids

Thick Bleach-1 ................................... 99

9 . METAL CLEANERS AND POLISHES . . . . . . . . . . . . . . . . . . . 101 Aluminum CleanerDrightener ........................ 102 Aluminum Smut Cleaner ............................ 102 Aluminum Cleaner Concentrate ....................... 103 Aluminum Wash ................................. 103 Cleaners and Cleaning Solutions ...................... 104 Metal Cleaning

Alkaline .................................... 104 Acid ....................................... 104 Paint Removal ................................ 104

xviii Contents and Subject Index

Rust Removal . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 104 Copper Cleaning . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 105

Acid . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 105 Brightening . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 105

Aluminum Aircraft-Brightener (U.S. Patent 2.687. 346) . . . . . . 105 Electrocleaner . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 106 Moderate Alkalinity. Soil Splitting Soak Cleaner . . . . . . . . . . . 106 High-Foaming Acid Scrubber ........................ 107 Acid Cleaner . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 107 Metal Cleaner and Degreaser . . . . . . . . . . . . . . . . . . . . . . . . . Thickened Clear Degreaser Concentrate . . . . . . . . . . . . . . . . . 108

Cleaner-A . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 109 Cleaner-B . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 109

Liquid-A . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 109 Liquid-B . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 109

Aluminum Cleaning

108

Stainless Steel

Silver Polish

10 . OVEN. GRILL AND HOT PLATE CLEANERS . . . . . . . . . . . . 110 Pump Spray Oven Cleaner . . . . . . . . . . . . . . . . . . . . . . . . . . 111 Caustic Oven Cleaner . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 111 Oven/Grill Cleaner . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 111

11 . POLISHES. COATINGS AND FINISHES . . . . . . . . . . . . . . . . . 112 Aerosol Furniture Polish (Carbon Dioxide Propellant) . . . . . . . 113 General Purpose Liquid Polish (Oil-in-Water Type) . . . . . . . . 113 Aerosol Furniture Polish (Hydrocarbon Propellant) . . . . . . . . . 114 Furniture Paste Wax . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 114 Detergent Resistant. Cream Cleaner Polish . . . . . . . . . . . . . . . 115 Non-Abrasive. Detergent Resistant. Glaze Emulsion . . . . . . . . 115 High Gloss. Detergent Resistant. Soft Paste Polish . . . . . . . . . 116 Detergent Resistant Cream Polish ..................... 116

For Clear Coat Finishes . . . . . . . . . . . . . . . . . . . . . . . . . 117 No Solvent . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 117 Outer Phase Oil . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 118

Non-Wax Liquid Polish (Oil-in-Water Type) . . . . . . . . . . . . 118 Liquid Furniture Polish . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 119 20% Wax Emulsion-1 . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 119 20% Was Emulsion-2 . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 119 Liquid Water-Based Glaze . . . . . . . . . . . . . . . . . . . . . . . . . . 120 Solvent Wax Glaze . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 120 Paste Polish (Oil-in-Water Type) ..................... 121

Liquid Polish

Contents and Subject Index xir

Spray-and-Wipe Polish ............................ 121 Paste Polish

Oil-in-Water Type Type-1 .................................. 122 Type-2 .................................. 122 Type-3 .................................. 123

Outer Phase Oil ............................... 123 Spray-and-Wipe Polish (Pump) ...................... 124 20% Wax Emulsion-1 ............................. 124 20% Wax Emulsion-2 ............................. 124 Spray and Wipe Type

Aerosol or Non-Aerosol (1) ...................... 125

Aerosol or Non-Aerosol (3) ...................... 125 Aerosol or Non-Aerosol (2) ...................... 125

Liquid Wax-Solvent Furniture or Floor Polish . . . . . . . . . . . . 125

12 . RINSE AIDS ....................................... 126

For Hard Water ............................... 127 For Neutral or Soft Water ........................ 127

Rinse Aid ...................................... 128

Automatic Dishwash Rinse Aid

13 . RUG. FJ.DOR, CARPET. UPHOLSTERY SHAMPOOS ANDCLEANERS ................................... 129

Liquid-A .................................... 130 Liquid-B .................................... 130

Liquid-A .................................... 130 Liquid-B .................................... 130

Dry-Foam Cleaner

Basic Floor Cleaner

Floor Cleaner. for Everyday Use

Carpet and Upholstery Cleaners

Liquid-A ................................ 131 Liquid-B ................................. 131 Powder-A ................................ 131 Powder-B ................................. 131

Carpet Shampoo. High Foam ......................... 132 Evaporative (No Rinse) Wax Stripper . . . . . . . . . . . . . . . . . . . 133 Waxed Floor Cleaner .............................. 133 Floor Cleaner .................................... 134 Floor Polish

Mor-Glo 2-457 20% Solids ...................... 135 ML-870-389 20% Solids ........................ 136

Liquid Carpet Cleaner .............................. 137

XT Contents and Subject Index

Carpet Stain Remover-Liquid . . . . . . . . . . . . . . . . . . . . . . . . 137 Carpet Cleaner/Booster.Dry. Destainer . . . . . . . . . . . . . . . . . 137 Low Cost Extraction Carpet Cleaner . . . . . . . . . . . . . . . . . . . 138

Non-Ammoniated Floor Stripper . . . . . . . . . . . . . . . . . . . . . . 139 Quarry Tile Cleaner . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 140 Low Foam Floor Cleaner . . . . . . . . . . . . . . . . . . . . . . . . . . . 140 Special-Purpose Floor Cleaner

Liquid-A . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 141

Liquid-A . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 141

Medium Cost Steam Extraction Carpet Cleaner . . . . . . . . . . . . 138 Premium. Heavy Duty Steam Extraction Carpet Cleaner . . . . . 138

Liquid-B . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 141 Wash-and-Wax Floor Cleaner

Liquid-B . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 141

14 . MISCELLANEOUS . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 142 Condensate T L Typical Formulations . . . . . . . . . . . . . . . . . . 143 All Purpose Cleaner . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 143

Dilutable Shampoo . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 143

Dishwashing Liquid . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 143 Opacified Hand Soap . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 143 d'lmonene Waterless Hand Cleaner . . . . . . . . . . . . . . . . . . . 144 Waterless Hand Cleaner . . . . . . . . . . . . . . . . . . . . . . . . . . . . 144 Dry Cleaning . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 145 Dust Control . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 146 Hand and Body Cleanser . . . . . . . . . . . . . . . . . . . . . . . . . . . . 147 Heavy Duty Degreaser . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 148 Burnishing Compound . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 148

Bubble Bath . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 143

Viscous Floor Cleaner . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 143

Corrosion Inhibiting Coating Oil-Emulsifiable . . . . . . . . . . . . 148 Heavy Duty Industrial Spray Metal Cleaner Concentrate . . . . . 149 Low Foam Hypochlorite Cleaner . . . . . . . . . . . . . . . . . . . . . . 149 Metal CleanerBrightener . . . . . . . . . . . . . . . . . . . . . . . . . . . 149

Low Foam Heavy Duty Alkaline Cleaner-A . . . . . . . . . . . . . . 150 Low Foam Heavy Duty Alkaline Cleaner-B . . . . . . . . . . . . . . 150 Paint Brush Cleaners . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 151 Steam Cleaner . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 152 Heavy Duty Industrial Spray Cleaner Concentrate . . . . . . . . . . 152

Hot Tank Stripper/Cleaner/Derster . . . . . . . . . . . . . . . . . . . . 150

High Solids Alkaline Cleaner . . . . . . . . . . . . . . . . . . . . . . . . 152 Wallpaper Removal . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 153

Contents and Subject Index m-

SECTION II TRANSPORTATION CLEANERS AND POLISHES

15 . AUTO CLEANERS AND POLISHES .................... 155 Auto Polishlcleanser. Oil in Water Emulsion . . . . . . . . . . . . . 156 Detergent Resistant Auto PolishlCleanser. Paste Wax . . . . . . . 156 Camauba Hotwax ................................. 157 Pressure Spray Truckwash ........................... 157 Detergent Resistant Auto Polish. Oil in Water Emulsion . . . . . 158 High Luster Auto Finish. Paste Wax . . . . . . . . . . . . . . . . . . . 158 High Gloss. Detergent Resistant Polish . . . . . . . . . . . . . . . . . . 159 High Gloss Auto PolishPinish ........................ 159

Spraywax ....................................... 160 Spraywax Ladder of Formulas ........................ 161

Spraywax Concentrate .............................. 160

16 . CAR AND TRUCK WASH COMPOUNDS . . . . . . . . . . . . . . . . 162 Automatic Car Wash Concentrate ..................... 163 General Purpose Car Wash .......................... 163 Auto Shampoo Concentrate .......................... 164 High Foaming Car Wash ............................ 164 Car Wash ....................................... 164 Car Wash Liquid ................................. 165 Car Wash Powder ................................. 165 Economy Truck Wash .............................. 166 Truck Wash Liquid ................................ 166 Foamy Brush Car Wash. Liquid ....................... 167 1:2 Dilutable Car Wash ............................. 167 High Oil Splitting Vehicle

Wash-A .................................... 168 Wash-B .................................... 168

Liquid Car Wash ................................. 169 Spray-On Car Wash Concentrate ...................... 169 Liquid Hi@ Pressure Coocentrate ..................... 170 Tmck Wash w/varamide A-83 ....................... 170 Liquid Tmck Wash ................................ 171 Mild Car Shampoo ................................ 172 Cgrspray CW Concentrate ........................... 172 Automotive "Wash t Wax" ......................... 172 Premium Carspray 500 Concentrate .................... 173 Standard Carspray 500 Concentrate .................... 173 Premium Carspray 700 Concentrate .................... 174 Standard Carspray 700 Concentrate .................... 174

xxii Contents and Subject Index

17 . WHITEWALL TIRE CLEANERS ....................... 175 White Wall Tire Cleaner ............................ 176 Bug Remover Concentrate ........................... 176 Whitewall Tire Cleaner Concentrate .................... 177 Whitewall Tire Cleaner Liquid ....................... 177

18 . MISCELLANEOUS .................................. 178 Automobile Windshield Cleaners ...................... 179 General Purpose Liquid Boat Polish-(l) . . . . . . . . . . . . . . . . . 180 General Purpose Liquid Boat Polish-(2) . . . . . . . . . . . . . . . . . 180 Liquid Aluminum Engine Block Cleaner . . . . . . . . . . . . . . . . 181 Foaming Engine Cleaner ............................ 181

SECTION Ilk TRADE-D RAW MATERIAIS . . . . . . . . . . . 182

SECTION N: SUPPLIERS' ADDRESSES .................... 197

Section I Household and Industrial

Cleaners and Polishes

1

1 Bathroom Cleaners

2

Bathroom Cleaners 3

Bathtub and Faucet Cleaner

I n g r e d i e n t : Percent by We1 q h t

Ammoni um hydrox ide s o l u t i o n 28% 3.2 Ce l l oso l ve so l ven t 5.0 Nonionic s u r f a c t a n t (Neodol 25-9) 6 .0 Water 65.8

L i q u i d C i t r i c Acid-50% (Haarman & Reimer Corp.) 20.0

Fragrance, dye q . s .

Mix t h e L i q u i d C i t r i c Acid-50% w i t h an equal volume o f water. S lowly add t h e ammonium hydrox ide s o l u t i o n . The n e u t r a l i z a t i o n should be done c a u t i o u s l y and under a g i t a t i o n , as t h e r e a c t i o n i s exothermic. Add Ce l l oso l ve , s u r f a c t a n t , remaining water, f ragrance and dye. The formula i s s u i t a b l e f o r a pump spray. Bathtub, s inks , f auce ts and o the r hard sur faces should be sprayed from a d i s tance o f about 10 inches. For maximum e f f e c t - iveness, t h e depos i ted c leaner f l u i d should be e f t a t work f o r a t l e a s t f i v e minutes and then r i n s e d o f f w t h water o r removed w i t h a wet c l o t h o r sponge.

SOURCE: Haarman 81 Reimer Corp.: Suggested Formu

__ Bathroom _ _ _ - ~ Cleaner

Water Sodium C i t r a t e Glucopon 425 CS Propylene Glyco l nButy1 Ether

T o i l e t B o w l Cleaner

Water Phosphoric Ac id Glucopon 425 CS

Tub 8 7 1 l e Cleaner

a t i o n

Water Sodium C i t r a t e STPP Standapol ES-2 Velvetex A0-45 Standamid KD I sop ropy l Alcohol

SOURCE: Henkel Corp., CD D i v i s i o n : S t a r t i n g Formulat ions

\"rtb 79 9 9 3

W t % 79 15 6

W t % 75

4 1

12 4 1 3

4 Advonced Cleoning Roduct Formulotions

Clear Liquid Bowl Cleaner Formula BC-0001

Mi rano l FBS Hydroch lo r ic Ac id (20Be) Water

Wt.% 3.0

20.0 77.0

Procedure

Add t h e Mi rano l FBS. Mix u n t i l un i fo rm.

Phvsi -1 P rooer t i es

Add t h e water. Slowly add t h e hyd roch lo r i c ac id , w i t h mix ing .

Appearance: C lear , l i g h t ye l l ow V i s c o s i t y : <10 cps S p e c i f i c Grav i t y : 1 -03 pH (as i s ) : <1.0

Thick T o i l e t Bowl Cleaner Formula BC-0002

Wt.% M i r a t a i ne TM 5.0 Hydroch lo r ic Ac id (20Be) Water

32.0 Q.S

Prowdu r g

add t h e M i r a t a i n e TM and mix u n t i l un i fo rm.

Phvsi G a l Prooert i es

Add t h e hyd roch lo r i c a c i d t o t h e water, w i t h s t i r r i n g . Slow

Appearance: C1 ear, ye1 1 ow 1 i qui d V i scosi t y : 1.035 cps Speci f i c Gravi t y : 1 ,037 pH (as i s ) : <1.0

Y

SOURCE: Rhone-Poulenc Sur fac tan ts & S p e c i a l t i e s : Formulas

Bathroom Cleaners 5

Foarnable A c i d T i l e Cleaner Hard Foaming Hard Surface Cleaner f o r Soap Scum Removal

I na red i e n t : Dei on i zed Water C i t r i c Ac id (50%) Mazon 98

Wt.% 87.00 10.00 3.00

pH (as i s ) : 2 .0 -2 .5 Appearance: C lear , water-whi te l i q u i d S p e c i f i c G r a v i t y : 1 . 0 1

Procedure:

above. Mix u n t i l c l e a r .

Notes : Th is fo rmula produces a copious, dense foam. It i s s u i t a b l e

f o r c lean ing soap scum from shower s t a l l t i l e s and o the r bathroom and household f i x t u r e s .

To a m ix ing vesse l , charge t h e i n g r e d i e n t s i n t h e order l i s t e d

Formula CH-105

L i a u i d T o i l e t Bowl Cleaner A L i q u i d S t a i n and Rust Remover

I n s r e d i e n t : Deionized Water Phosphoric Ac id (75%) Avanel S-70

pH (as i s ) : t1.5 Appearance: C lear , water -wh i te l i q u i d S p e c i f i c G r a v i t y : 1 .124

Wt.% 66.00 30.00

4 . 0 0

Procedure:

phosphor ic a c i d under a g i t a t i o n . Use c a u t i o n du r ing a c i d add- i t i o n t o avo id s p a t t e r i n g . When a l l o f t h e a c i d i s d isso lved, coo l t o room temperature and add t h e Avanel s u r f a c t a n t .

Notes:

i c u l a r l y e f f e c t i v e i n t h e removal o f sca le bu i l d -up and r u s t s t a i n s .

Th is m a t e r i a l may be marketed i n an approp r ia te squeeze b o t t l e t o f a c i l i t a t e "under t h e r i m " bowl c lean ing by t h e consumer.

Formula CT-101

SOURCE: Mazer Chemicals: Suggested Formulat ions

Charge t h e water t o t h e mix ing vesse l , and s low ly charge t h e

Th is fo rmu la t i on i s designed t o be used "as i s " and i s p a r t -

S o l i d Automat ic T o i l e t Bowl Cleaner Formula t ion

I n g r e d i e n t : Macol DNP 150 Incromide L90 Carbowax PEG 8000 Macol 27 Versa f lex 207 ( d r y ) Water

%- 25.0 25.0 20.0 20.0 5.0 5.0

Procedure: 1 . Me l t t h e Macol 27, Macol DNP 150, and Carbowax PEG 8000, and

2. Main ta in a temperature o f about 70C, and add t h e Incromide

3. Add water and Versa f lex 207 ( d r y ) and mix. 4 . Pour fo rmu la t i on i n t o a mold, and a l l o w t o coo l . SOURCE: Na t iona l S tarch and Chemical Co.: Reference #8069:49

mix toge the r .

L90 w h i l e mix ing .

__ A c i d T o i l e t Bowl Cleaner

Water, D . I . Hyd roch lo r i c Ac id (37%) Rewoteric AM TEG

% bv Weiaht 71 . O 27.0 2.0

B1 endi ng Procedure: Add i n g r e d i e n t s i n o rder shown and d i s s o l v e comple te ly between

each addi t i on. Typ ica l P roper t i es :

V i s c o s i t y , cps: 135 So l i ds : 1.0% pH: 2.8

SOURCE: Witco Corp.: Formula 532

Tub, T i l e and Bathroom Cleaner

Water Sodium Carbonate Tetrasodium EDTA (40%) Phosphoter ic T-C6 Nonoxynol 10

Procedure:

% bv Wei ah t 81.5 5.0 10.0 1.5 2.0

Add i n g r e d i e n t s i n o rder l i s t e d , a l l o w i n g s u f f i c i e n t t ime between a d d i t i o n s .

Th is product may be app l i ed w i t h a t r i g g e r pump o r by aeroso l . Formulat ion P roper t i es :

Phys ica l Appearance: Clear l i q u i d Cloud Po in t : 42C

SOURCE: Mona I n d u s t r i e s , I n c . : Suggested Formulat ion

6 Advanced Cleaning Roabct Formulations

Bathroom Cleaners 7

T i l e , Porcelain and Bathroom Cleaner, Acid

Water. D . 1 % by Weiqht

75.5 Rhodopol 23 0.5 Petro BAF Powder 2.0 Phosphori c Acid, 75% 12.0 Hydroxyacetic Acid, 70% 10.0 Perfume, Dye q . s . B1 endi ng Procedure :

t o mix u n t i l mater ia l th ickens. Add remaining ingredients i n order l i s t e d . If problems develop adding Rhodopol t o water, premix the Rhodopol 23 i n some isopropanol before adding t o water. Formula 529

Add Rhodopol 23 slowly t o water w i t h high speed mixing. Allow

Hypochlor i te Tub and T i l e Cleaner and Mildew S ta in Remover

% by Weiqht Water, D.I. 44.9 Sodium Hydroxide (30%) 1 . o Varox 365 1.5 Sodium Hypochlor i te (5.7%) 52.6 81 endi ng Procedure :

between each addi t i on. Typical Propert ies:

V iscos i ty , cps: 4 Sol ids: 3.8% pH: 13.5

Formula 531

Add ingredients i n order shown and d isso lve completely

Soap Scum Remover/Cleaner

% by Weiaht Water, D.I. q . s . *Bui lder Solut ion 0.20 Tetrasodi um EDTA 0.25 Rewoteric AM V 1 .oo Dowanol EB 0.50 81 ending Procedure:

Blend ingredients i n the order shown, mixing thoroughly between each add i t i on . Typical Proper t i es :

Viscos i ty , cps: 4 Sol ids: 2.0% pH: 11-12

Comments: *Bui lder Solut ion: Sodium Carbonate (Na2C03): 4%

Potassi um Hydroxide (KOH) : 3% DI Water 93%

Formula 544

SOURCE: Witco Corp.: Suggested Formulations

8 Advanced Cleaning Roabct Formulations

T o i l e t Cleaner. L iquid-A

Marl i pa l 01 3/99 Ace t i c ac id* Balance water, f ragrance, dyes tu f f

A c t i v e mat te r : 2.7%

Toi 1 e t Cleaner . L i qui d-B

Marl i pa l 01 3/99 C i t r i c a c i d Balance water, f ragrance, d y e s t u f f


To i 1 e t C1 eaner , Medi urn V i scosi t y - A

Mar laz in OL 2 M a r l i p a l 013/99 C i t r i c a c i d Na Cumene sulphonate 40 (approx.) Balance water, f ragrance, d y e s t u f f


T o i l e t Cleaner, Medi urn V i scosi tv -B

Mar laz in OL2 Marl i p a l 01 3/99 C i t r i c a c i d Phosphoric ac id , 85% KNA cumene sulphonate 40 (approx.) Balance waser, f ragrance, d y e s t u f f

A c t i v e mat te r : 2.0 * f u r t h e r p roduc ts o f Huls AG

96 3.0 6.0

t o 100

% 5.0 1 .7

t o 100

% 1.5 0 . 5 5.0 1.5

t o 100

% 1.5 0 .5 2.5 7.5 1.3

t o 100

SOURCE: Huls America, I n c . : Baslc Formulat ions o f Detergents and Cleaning Agents f o r Household Purposes

Bathroom Cleaners 9

Toi 1 e t Cleaners, Medi urn V i scosi t y - A

Marlazin 7102 Phosphoric acid, 85% Sodium c h l o r i d e Balance water, fragrance, dyes tu f f

Act ive matter: 4.0%

Toi 1 e t C l eaner . Medi urn V i scosi ty-B

Marlazin OL 2 Mar l i pa l 013/99 Acet ic Acid* KNA cumene sulphonate 40 (approx.) Balance water, fragrance, dyestuf f


Toi 1 e t Cleaner. Powder

Marlon ARL Amidosulphonic a c i d Magnesium carbonate Sodi um b i sulphate Sodium bicarbonate, fragrance, dyes tu f f


T o i l e t Cleaner. Powder-B

Marlon A 390 C i t r i c ac id Sodi um sulphate Sodium bicarbonate, fragrance, dyestuf f

Ac t i ve matter: 4.5%

96 4.0 5.0 3.5

t o 100

% 3 . 0 0 .5 6.0 3.1

t o 100

96 5 . 0

20.0 5 . 0

6 0 . 0 t o 100

% 5.0

25.0 55.0

t o 100

SOURCE: Huls America, I nc . : Basic Formulations o f Detergents and Cleaning Agents for Household Purposes

10 Advanced Cleaning Roduct Formulations

T o i l e t Cleaning Block, Extruded-A

Marlon ARL Mar l i pa l 1618/25 powder Marlamid M1618 Vest ino l C* Sodium sulphate, dyes tu f f


T o i l e t Cleaning Block. Extruded-B

Marlon ARL Marlon A390 Lipoxol 6000* Sodi um tr ipolyphosphate Fragrance Sodium sulphate, dyes tu f f


T o i l e t Cleanino Block. Cast-A

Marl i n a t 242/70 Marlon A375 Mar l i pa l 1618/25 powder Mar l i pa l 1618/40 Marlamid M 1618 L i poxol 12000* Fragrance Dyestuf f


T o i l e t Cleaning Block. Cast-B

Marl i pal 01 3/90 Mar l i pa l 1618/40 Mar l i pa l M 1618 L i poxol 12000* Fragrance Dyestuf f

Act ive matter: 79.0% * f u r t h e r products o f Huls Ag

96 40.0

4.0 6.0 4.0

t o 100

ss 40.0 30.0 8.0 1 .o 5.0

t o 100

% 3.0

13.0 30.0 24.0 15.0 10.0 4.0 1 .o

96 12.0 60.0 10.0 13.0 4.0 1 .o

SOURCE: Huls Chemical Co.: Basic Formulations o f Detergents and Cleaning Agents f o r Household Products

2. Dairy, Food and General Industrial Cleaners

11


An

Inaredi ent : Deionized Water G lyco l i c Acid (70%) Phosphoric Acid (85%) Avanel S-150

Dai ry Mi 1 kstone Remover Acid D i l u t a b l e Concentrate

Wt.% 53.40 28.60 10.00 8 . 0 0

pH (as i s ) : ~ 2 . 0 Appearance: Clear, water-white t o l i g h t - y e l l o w l i q u i d

Procedure: Charge water t o the mixing vessel and s t a r t ag i ta t i on . Under

a g i t a t i o n , charge the G lyco l i c Acid fo l lowed by the Phosphoric Acid. Charge the Phosphoric Acid s lowly t o avoid s p l a t t e r i n g . Charge t h e Avanel S-150 and cool t o room temperature. F i l l o f f .

Notes :

m i 1 kstone from dai r y equipment . Brush thoroughly, then r i nse . Formula CD-101

This formulat ion i s h igh l y e f f e c t i v e a t removing d a i r y

Use concentrat ion i s 1 /2 t o 1 ounce per ga l l on o f water.

Dairy M i 1 kstone Remover Low Cost Acid D i l u t a b l e Concentrate

Inaredi ent : Dei oni zed Water Phosphoric Acid (85%) Gluconic Acid (50%) Avanel 5-70

pH (as i s ) : < 2 . 0 Appearance: Clear, water-white l i q u i d

Wt.% 55.00 37.50

3 . 5 0 4 . 0 0

Procedure: To mixing vessel, charge the water and s t a r t a g i t a t i o n .

Slowly charge the Phosphoric Acid t o avoid s p l a t t e r i n g . Cool t o room temperature and charge the Gluconic Acid and Avanel S-70.

Notes: A lower cost s u b s t i t u t e f o r PPG/Mazers CD-101 d a i r y cleaner

formulat ion. I t r e t a i n s the general performance a t t r i b u t e s o f t he o r i g i n a l formulat ion.

Use concentrat ion i s 1/2 t o 1 ounce per ga l l on o f water. Brush thoroughly, then r i nse . Formula CD-102

SOURCE: Mazer Chemicals: Suggested Formulations

&ky, Food and General I . . Cleaners 13

D a i r y P i p e l i n e Cleaner H i g h A1 k a l i ne Low Foam Hvpoch lor i t e Cleaner

I n n r e d i en t : Deionized Water Sodium Hydroxide (50%) Avanel S-74 Sodium Cumene Su l fonate (40%) Sodium Hypoch lo r i t e (12.5%)

pH (as i s ) : 12.5-13.5 Appearance: C lea r , 1 igh t -ye1 low 1 i q u i d Speci f i c G r a v i t y : 1 . 1 5

Wt.% 52.00 20.00

2.50 1 .50 24.00

Procedure:

Hydroxide, and coo l t o l e s s than 9OF. Add t h e Avanel 5-74 and Sodium Cumene Su l fonate . Mix u n t i l c l e a r and add t h e Sodium Hypoch lo r i t e .

Notes:

a l k a l i n i t y o f common p i p e l i n e c leaners r e s u l t i n g i n a s i n g l e c lean ing system.

She l f s t a b i l i t y o f h y p o c h l o r i t e c leaners i s dependent on t h e absence o f t r a c e meta ls . Care shou ld be taken t o i n s u r e good q u a l i t y water and hypoch lo r i t e .

Formula may be ad jus ted t o use o the r commercial ly a v a i l a b l e concen t ra t i ons o f Sodium Hypoch lor i te . Absolute concen t ra t i on o f a v a i l a b l e c h l o r i n e i s 3.0%.

SOURCE: Mazer Chemicals: Formula t ion CD-103

Charge water t o mix ing vessel and s t a r t a g i t a t i o n . Add Sodium

Th is fo rmu la t i on combines a c h l o r i n e c leaner w i t h t h e h i g h

I n s t i t u t i o n a l S t a i n l e s s S tee l Cleaner

Components: Water 50% C i t r i c Ac id Burcosperse LP Dequest 2000* Burco NPS 50% 45% KOH

% by Weight 52.75 20.00

5.00 5.00 5.00

12.25

*From Monsanto o r use equ iva len t p roduc t .

Procedure: Add components i n t h e order l i s t e d . Blend u n t i l un i fo rm

between each a d d i t i o n .

SOURCE: B u r l i n g t o n Chemical Co., I n c . : Suggested Formula t ion

14 Advanced Cleaning Product Formulations

High Pressure Cleaner for I n d u s t r i a l Use L iqu id , t ransparent , a l k a l i n e

Inq red i en ts : A Genapol UD-050

Genapol UD-080 Genopur ASA KOH (85%)

B Water (ca.5OC) C Sodi ummetasi 1 i ca te x 5H20

Manufactur ing: I The components o f A a re mixed. I1 Then B i s added. I11 F i n a l l y t h e components o f C a re added

Aquamoll in 8C Powder h i g h l y conc.

2,50% 2,50% 3,00% 5.00%

67 ,00% 10,00% 10,00%

Cleaner f o r M i 1 k i n a Eaui Dment L i q u i d

Ing red ien ts : A Tetrapotassiumpyrophosphate

Sodi ummetasi 1 i c a t e x 5H20 Sodiumcarbonate

B Water C Genopur ASA

KOH (85%) D Genapol UD - 080 Manufactur ing: I One a f t e r another, t h e components o f A I 1 S t i r one a f t e r another, t h e components I11 A t l a s t D i s added.

7.00% 5,00% 3,00%

70 ,00% 5.00% 5,00% 5,00%

are added t o 8. o f c t o I.

Cleaner f o r Meat P lan ts L i q u i d

Ing red ien ts : A Tetrapotassiumpyrophosphate

B Water C Genopur ASA

KOH (65%) D Hostapur SAS 60

Genapol UD - 080 Solvent GX 5

Manufactur ing: I Add one a f t e r another, t h e components o f A t o I 1 C i s added t o I by con t inu ing s t i r r i n g . I11 A t l a s t t h e components o f D a re added.

Potassium water g las (40 Be) 5,00%

76 ,00% 3,50% 3,50% 5.00% 2,00% 3,00%

2,00%

B.

SOURCE: Hoechst Ak t i engese l l scha f t : Detergents and Cleaning Agents: Guide Formulat ions

he, Food and General Industrial Cleaners 15

Meat Packaaina Plant Cleaner Concentrate An A lka l i ne High Foaming Hypochlor i te Hard Surface Cleaner

w i t h Improved Sa l t Tolerance

Inaredi ent : Oei oni zed Water Hostapur SAS-60 Potassi um Hydroxide Tetrapotassium Pyrophosphate Mazon 98 Sodium Cumene Sul fonate (40%) Sodium Hypochlor i te (12.5%) Oei oni zed Water

Wt.% 59.20 2.50 0.90 2.10 5.00 1.30

10.00 19.00

pH (as i s ) : 12.5-13.5 Appearance: Clear- to- t ranslucent, s l i g h t l y viscous, l i g h t -

Speci f i c Grav i ty : 1 .04

Charge t h e water t o a mixing vessel and s t a r t a g i t a t i o n .

yel low l i q u i d .

Procedure:

Charge t h e Hostapur, fo l lowed by t h e Potassium Hydroxide and the Tetrapotassium Pyrophosphate. Apply cool ing and then add the Mazon 98 and t h e Sodium Cumene Sulfonate. When product i s l ess than 85 degrees F. add the Sodium Hypochlor i te and the balance o f t h e water.

Notes: This formula i s designed t o be d i l u t e d t o 3-6 ounces per

ga l l on i n hot water and t o be appl ied as a foam t o meat packing house w a l l s and other surfaces. A f t e r an appropr iate time, these surfaces should be thoroughly r insed.

Shel f s t a b i l i t y o f ch lo r i ne cleansers i s dependent upon t h e absence o f t race metals. Care should be taken t o insure good q u a l i t y water and Sodium Hypochlor i te.

Revision o f CB-102 t o provide greater s a l t to lerance.

SOURCE: PPG Indust r ies, I n c . : Formula CB-102-A

16 Advanced Cleaning Prodccct Formulations

Steam Cleaners C1 eaner-Li ght Duty

Inaredi ents : Sodi urn Metasi 1 i a te Sodi um T r i po l yphosphate Trisodium Phosphate Aerosol 22 Surfactant T r i t o n CF-10

Inqredi ents: Sodi urn Orthosi 1 i c a t e Sodium Carbonate T r i sodi urn Phosphate Aerosol 22 Surfactant T r i t o n CF-10

C l eaner-Medi urn Duty

% by Weiaht 30.0 58.0 10.0

1 .o 1 .o

% by Wei aht 33.0 20.0 44.0

1.5 1 .5 _ _

Cleaner-Heavy D u t y (For O i l y So i l s ) % by Weiaht Inaredi ents:

Aerosol 22 Surfactant 7.0 ~ ~~~

Sodium Metas i l i ca te Dowanol DE Water

Inaredients : Aerosol 0s Surfactant Soda Ash Sodi urn Hydroxide Sodium Metas i l i ca te (5H20) Sodi um T r i po l yphosphate

Cleaner-General Purpose

Use 0.5 t o 2.0 0 2 . t o 1 aa l l on o f water.

35.0 3.0

55.0

% by Weight 10.0 35.0 15.0 30.0 10.0

_ _ _ Cleaner-Lipht Duty f o r So f t Metals

Ingredients : % by Weiaht Aerosol 0s Surfactant 7.14

~ ~~~

Sodium Sesquicarbonate 92.86

Inpredients : % by Weiaht Cleaner-General Purpose

Sodi um Metasi 1 i cate

Aerosol 22 Surfactant 5.0 Water 73-78

15-20 Aerosol 0s Surfactant 2- 3

Cleaner-Compound Inaredi ents : % by Weiaht Sodi urn Hydroxide 30.0 Borax 30.0

D i sodi um Phosphate 15.0 Aerosol C-61 Surfactant 5.0

Add t h e desired amount o f cleaner t o water which has been preheated t o 140F.

SOURCE: Cytec Indus t r i es I n c . : Suggested Formulations

Soda Ash 20.0

3. Degreasers

17


d-Liaonene Microemulsion Cleaner/Desreaser

Burco TME Burco FAE d-Li monene Water

11 p a r t s 11 p a r t s 16 p a r t s 62 p a r t s

Mix i n order l i s t e d ; add water s lowlv. Product w i l l

No co-solvent i s requi red when mixed i n propror t ions given thicken, then break as water i s added.

above. Produces a c l e a r product. Burco FAE imparts corros ion resistance i n add i t i on t o emulsion cha rac te r i s t i cs .

but r a t i o s o f t he other ac t i ves must remain s i m i l a r t o the above. Exampl e :

To make a more concentrated product, l ess water can be used,

TME FAE d-Limonene Water

22 p a r t s 22 p a r t s 32 p a r t s 24 p a r t s

High a c t i v e products can reach a g e l - l i k e v i scos i t y , but can be t h i nned w i t h Isopropanol and Buty l Propyl sol v.

SOURCE: Bur l ington Chemical Co., I nc . : Suggested Formulation

Concentrated d-Limonene Biodearadable Deareaser A Natural All-Purpose Micro-Emulsion Cleaner o r Concentrate

Inaredi ent : d-Limonene. Grade M Mazclean EP Deionized Water

Wt.% 30.00 20.00 50 .00

pH (as i s ) : 9.0-10.0 Appearance: Clear, l i g h t - y e l l o w l i q u i d Spec i f i c Grav i ty : 0.97 Odor: Sweet Orange

Procedure: Charge t h e d-Limonene and Mazon 245-103 t o an apprDopriate

mixing vessel and s t a r t a g i t a t i o n . Under good ag i ta t i on , s lowly add the water and mix u n t i l s o l u t i o n i s c lea r .

Notes :

duty use, product should be sprayed "as i s " onto the o i l y substrate, fo l lowed by a water r i nse .

SOURCE: PPG Indus t r i es , Inc. : Formulation CS-101

This formulat ion may be used "as i s " o r d i l u t e d . For heavy-

Degreasers 19

Sol vent Deareasi rig

The s o l u b i l i t y o f Aerosol OT Sur fac tan t i s extremely h igh i n a l l so l ven ts used f o r degreasing. I t w i l l d i s s o l v e e a s i l y a t room temperature i n most cases. I f hea t ing i s requ i red f o r s o l u b i l i z a t i o n , t h e s o l u t i o n w i l l be s t a b l e upon r e t u r n t o room temperature.

As an example, Aerosol OT-75% i s so lub le t o over 50% a t room temperature i n carbon t e t r a c h l o r i d e , b u t naphtha so lvent requ i res heat ing . Both a re c l e a r s o l u t i o n s a t room temperature. The presence o f t h e water i n Aerosol OT-75% p o r t i o n i s an a i d i n t h e removal o f any water -so lub le p a r t i c l e s present i n t h e work be ing degreased.

Formulat ions such as: Aerosol GPG o r OT-75% High F lash Naphtha

0.5% 99.5%

can be used f o r l i g h t - d u t y c lean ing , t h e so l ven t removing t h e o i l s , waxes, e t c . and t h e Aerosol OT a i d i n g no t o n l y i n t h e pene t ra t i on o f t h e cover ing ma te r ia l , b u t a l s o i n d r a i n i n g . Th is t ype o f c leaner can be sprayed on, brushed on, o r t h e work can be immersed i n t o i t fo l l owed by a r i n s e .

Heavy-Duty Degreasing: To remove heavy l u b r i c a t i n g and p rese rva t i ve o i l s and

greases, many so l ven ts may be used t o s p e c i f i c needs. Aerosol GPG Sur fac tan t w i l l be found t o be so lub le i n a l l o f these so lvents . A t y p i c a l f o rmu la t i on used i s :

Aerosol GPG o r OT-75% Kerosene

1- 3% 97-99%

Prepara t ion i s by s imple mixing. T r i - o r t e t rach lo roe thy lene , h igh f l a s h naphtha o r o ther s u i t a b l e so l ven ts can be s u b s t i t u t e d f o r t h e kerosene.

Carbonaceous depos i t s can be removed by d i p p i n g i n formula- t i o n s such as:

Kerosene Perchloroethylene Carbon Te t rach lo r i de Cresyl i c Ac id Aerosol GPG o r OT-75%

40% 30% 16% 10%

4%

Normally, 3 g a l l o n s o f t h e above a re added t o 1 g a l l o n of water which, f l o a t i n g on t h e surface, minimizes l o s s o f so l ven t . The work t o be cleaned i s immersed i n t h e so lvent phase f o r t ime per iods o f a few minutes t o several hours, i f requ i red , t o o b t a i n c lean l i ness . Upon removal f rom t h e so lvent l aye r , and a s h o r t r i n s e i n t h e aqueous l a y e r , t h e cleaned a r t i c l e s a re r i nsed , d r i e d o r c a r r i e d on to t h e nex t opera t ion . SOURCE: Cytec I n d u s t r i e s , I nc . : Suggested Formulat ions

4. Dishwashing Detergents

20

Dishwashing Detergents 21

C1 ear L i q u i d D i shwash

W i t c o l a t e AE-3 Witco 1298 S o f t Ac id Sodi um Hydroxide, 50% W i t cona te SXS L i q u i d W i tcami de 51 95 Phosphoric Ac id Water

% by Weiqht 12.5 19.0 5.2

13.5 2.5

q.s. t o pH = 6.4-6.8 q.s. t o 100

Blending Procedure


Formula 108

B1 end i ngred i en ts i n t h e order shown, m i x i ng thorough ly

Non-Chlori na ted Machine D i shwashi na Compound, L i q u i d

% by Weight Water, D.I. 79.5 Sodi um Tr ipo lyphosphate 2.0 Versene 220, Powder 1.0 Sodium Gluconate 1 .o Sodium M e t a s i l i c a t e , Pentahydrate 7 . 0 Caust ic Soda 50% 8 .5 Pet ro ULF L i q u i d 1.0

B lend ing Procedure:


Formula 109

Blend i n g r e d i e n t s i n t h e o rde r shown, m ix ing thorough ly

Clear, Co lo r less Manual D ish Wash

Water, D.I. W i t c o l a t e ES-3 Rewoteric AM 8-14 Ethanol Sodium Ch lo r ide

% by Weiqht 57 .5 31.2

5.0 3.0 3.3



Comment :

B1 end i ngredi en ts i n t h e o rde r 1 i sted. D isso lve comple te ly

Rewoteric AM 8-14; Grease c u t t e r and foam booster .

Formula 132

SOURCE: Witco Corp.: Suggested Formulat ions


Dish Washi na Agent Clear, l i q u i d , 25% WAS

Alkanesulphonate:ethersulfate=4.1 Ingredients : A Hostapur SAS 60

B Water Genapol ZRO l i q u i d

Preservat ive Dye Perfume Hoe S 3924

Manufacturi ng : One a f t e r another, t h e components o f B are added t o A.

Tests: V i scos i t y (mPas) : 90 Cloud p o i n t : <-5C

33.36% 17.90% 47.50% 0.10% q.s. 0.20% 1.00%

Dish Washin A ent c lea r , l iquid: 2:% WAS

alkanesulphonate:ethersulphate=4.1 Ingredients : A Hostapur SAS 60

B Water Genapol ZRO l i q u i d

Preservat ive We Perfume Hoe S 3924

Manufacturing: One a f t e r another, t he components o f B are added

Tests V iscos i t y (mPas): 410 Cloud po in t : <-5C

33.30% 17.90% 44.50%

0.10% q.s. 0.20% 4.00%

t o A.

Dish Washing Aaent Clear, l i q u i d , 30% WAS

alkanesulphonate:ethersulphate=4.1 Ingredients: A Hostapur SAS 60 40.00%

Genapol ZRO l i q u i d 21.40% B Water 30.30%

Preservat i ve O . \ l O % Dye q.s. Perfume 01.20%

Manufacturing:

Tes ts : One a f t e r another, t h e components o f 0 are added t o A.

V i scos i t y (mPas): 330 Cloud po in t : <-5C

SOURCE: Hoechst Akt iengesel lschaf t : Detergents and Cleaningal Agents: Guide Formulations


Dish Washi na Agent Clear, l i q u i d , 30% WAS

alkanesulphonate:ethersulphate=4:1

I na red ien ts : A Hostapur SAS 60

Genapol ZRO l i q u i d

8 Water Preserva t ive Dye Perfume Hoe S 3924

Manufactur ing:

Tests:

One a f t e r another, t h e components o f 0 are added

V i s c o s i t y (mPas): 610 Cloud p o i n t : <-5C

Powder f o r Automatic Dishwashina Machines

40.00% 21.40%

34.30% 0.10%

q.s. 0.20% 4.00%

t o A.

I na red ien ts : A Genapol 2908

B Sodiummetasi l icate x 5H20

C Sodiumcarbonate Sodi umdichloroi socyanurate Thermphos NW

Manufactur i no:

1;. 00%

52 .00%

10.00% 2.00%

35.00%

I Spray A on 0 . I1 One a f t e r another, t h e components o f C a re added t o 1.

A p p l i c a t i o n :

SOURCE: Hoechst Ak t i engese l l scha f t : Detergents and Cleaning

1-2 g de tergent /L dishwashing l i q u o r

Agents: Guide Formulat ions

24 Advanced Cleoning Product Formulations

Dishwashing Deteraent. Medium V iscos i t v . Bas is Marlon A-A

% Marlon A 350 30.0 Marl i na t 242/70 5.7 D i o n i l OC 1 .o Na cumene sulphonate 40 1 .o Balance water, f ragrance, dyes tu f f , p rese rva t i ve ,

sodium c h l o r i d e t o 100


Dishwashing DeterQent. Medium V iscos i t v . Bas is Marlon A-B

%

Marl i na t 242/70 4.3


Marlon A 365 18.5

Balance water, f ragrance, d y e s t u f f , p rese rva t i ve ,


D i shwashi na Detergent, Medi urn V i m s i t y . B a s i s Marlon AS3-A

% Marlon AS3 10.5 Caust ic soda, 50% (approx.) 2.6 Marl i p a l 01 3/120 2.7 Balance water, f ragrance, dyes tu f f , p rese rva t i ve ,



D i shwashi n Q Detergent, Medi urn V iscos i t y . Bas4 s Marlon AS3-B

% Marlon AS3 4.5 Caust ic soda, 50% (approx.) 1.1 M a r l i n a t 242/70 4.5 Balance water, f ragrance, dyes tu f f , pe rse rva t i ve ,



SOURCE: Hu ls America, I n c . : Bas ic Formulat ions o f Detergents and Cleaning Agents f o r Household Purposes

M w h i n g Detergents 25

D i shwashi nq Detergent, Medi um V i s c o s i t y . Bas is Marlon PS-A

% Marlon PS 65 49.0

Marlamid DF 1218 3.0 Ethanol * 4.0 Balance water, f ragrance, d y e s t u f f , p rese rva t i ve ,

Marl i n a t 242/70 11 .5


A c t i v e ma t te r : 43.0%

D i shwashi ng Detergent, Medi um V iscos i t y , Bas is Marlon PS-B

% Marlon PF 40 71.3

Balance water, f ragrance, d y e s t u f f , p rese rva t i ve , Marlamid DF 1218 1 . 5


A c t i v e ma t te r : 30.0% * f u r t h e r p roduc ts o f Hu ls AG

D i shwashi ng Detergent, Medi u m V i scos t y . Bas is Marlon Compounds-A

% Marlon AFO 40 46.3 Marlamid D 1885 1 .5 Balance water, f ragrance, d y e s t u f f , p rese rva t i ve ,



D i shwashi ng Detergent , Medi um V iscos i t y , Bas is Marlon Compounds-B

% Marlon AFO 50 30 .0 Balance water, f ragrance, d y e s t u f f , p rese rva t i ve ,



SOURCE: Hu ls America, I n c . : Bas ic Formulat ions o f Detergents and Cleaning Agents for Household Purposes


D i shwashi n Q Deteraent . Powdered. SDrav M i x i na Process-A

% Marlox FK 64 1 . o Sodium t r i po l yphospha te 40.0 Sodium m e t a s i l i c a t e pentahydrate 35.0 Sodium carbonate, dehydrated 22.0 Sodium d i ch lo ro i socyanura te 2 .0

A c t i v e ma t te r : 1.0% A p p l i c a t i o n : Use 3-5 g/1 water (depending on water hardness)

D i shwashi ng Detergent, Powdered, Spray M i x i ng Process-I3

Marlox B 24/80 Sodium t r i po l yphospha te Sodium m e t a s i l i c a t e pentahydrate Sodium m e t a s i l i c a t e , dehydrated Sodium carbonate, dehydrated Sodi um d i c h l o r o i socyanurate Phosphonate HEDP, e.g. Sequion 10 Sodi um hydrox ide

A c t i v e ma t te r : 1.0 A p p l i c a t i o n : Use 3-5 g/1 water

Na 2

% 1 . o

25.0 25.0 20.0 15.0 2.0 2.0

10.0

(depending on water hardness)

D i shwashi ng Detergent, Powder, Phosphate-Free, Spray M i x i ng Process-A

Marlox MO 154 Sodi um c i t r a t e d i hydra te Sodium d i s i l i c a t e g ranu la te Po lycarboxy la te , e.g. Sokalan PA 40 g ranu la te Sodium perbora te monohydrate Tetraacetylethylenediami ne (TAED) Enzyme Esperase Sodium sesquicarbonate


% 2.5

35.0 25.0

5 . 0 15.0 4.0 2.0

t o 100

Dishwashing Detergents, Powder, Phosphate-Free, Spray M ix ing Process-I3

Marlox MO 154 Sodium carbonate, dehydrated Po lycarboxy la te , e .g . Permulsin SP Phosphonate HEDP, e .g . Sequion 10 Na 2 Sodi um metasi 1 i c a t e


% 2.0

15.0 10.0

5 . 0 t o 100



DishwashtnLDeterpent (4096 Sol ids)-A

Witconate 1260 S lu r r y W i t c o l a te LES-6OA W i tcami de 128T Water

% by W e i m 37.0 17.5

4.0 34.0

Blending Procedure:

between each add i t i on . Blend ingredients i n the order shown. mixing thoroughly

Dishwashing Deteraent (40% Sol ids)-8

W i tconate 45LX W i tconate SXS L iqu id Wi tco late LES-6OA W i tcamide 128T Water

% bv Weiqht 59.0

6.0 17.5 4.0

16.5

Blending Procedure:

between each addi t ion.

Formula 105

Blend ingredients i n the order shown. mixing thoroughly

Hand D i shwashi ng L i q u i d

W i tconate AOS Witco late S-1285C Witcamide 128T Water

% by Weiaht 60.0 10.0

4.0 26.0

Blending Procedure:

between each add i t i on .

Formula 106


Blend i ngredi ents i n the order shown, m i x i ng thorough1 y

28 Advanced Cleaning R&t Formulations

Dish Wash w/Ami ne Oxi de/LABS/SLES

Water, D . I . Witconate 30DS Varox 1770 W i t c o l a te SE-5

Blending Procedure:

between each add i t i on . Add Ethanol as needed t o Typical Proper t ies:


Formula 117

Add ingredients i n order shown and d i ss l v e

Dish Wash w / h i ne Oxi de/LABS/ALES

Water, 0.1. W i tconate 30DS Varox 1770 Witcolate LES-6OA Ethanol

% by Weiqht 62.9 13.7 5 .3

18.1

ompl e t e l y lower v i s c o s i t y .

% by Weiaht 70.0 13.8 3.1 8.2 5 .0

B1 endi ng Procedure: Add ingredients i n order shown and d isso lve completely

between each add i t i on . A c i d i f y w i t h C i t r i c Acid t o pH = 6.5. Typical Propert ies:


Formula 118

Dish Wash w/Ami ne Oxide/LABS

Water, D . I . W i tconate 30DS Varox 1770 Ethanol

% by Weiaht 69.8 20.3

4.9 5.0

Blending Procedure: Add ingredients i n order shown and d isso lve completely

between each add i t i on . Typical Propert ies:


Formula 119



High-Performance Hand Dish Detergent Formula DW-0013

Water SXS, 40 Caustic Soda, 50% Dodecylbenzene s u l f o n i c Acid Rhodapex NA-61 A 1 kami de DC-212/S Rhodacal A-246/L Rhodasurf 25-9 C i t r i c Acid (50%). t o pH 8 Ethanol SD-3A Preservat i ve Fragrance Dye

Wt.%

3.0 6.6

25.0 8.0 3.0

10.0 6.0 Q.S. 2.0 0.1

To 100

-

Procedure Add the ingredients i n the order l i s t e d w i t h mixing. Mix

u n t i l uni form a f t e r each add i t i on . C i t r i c Acid and Caustic Soda are used f o r pH adjustment. Physical ProDerties

Appearance: Clear go ld l i q u i d , dyed t o preference pH. as i s : 8 V iscos i ty : 400 cps Spec i f i c Grav i ty : 1.05

M i l d L i a u i d Hand Dish Detergent

Water Caustic Soda (50%) Dodecylbenzene s u l f o n i c ac id Miranol CS Conc. A1 kami de DC-212/S Rhodasurf 25-9 Cheel ox BF-13 C i t r i c Acid (50%). t o pH 8 Fragrance Dye

Wt.% To 100

3 12 15 3 3 0.2

Q . S . - - Procedu r e

u n t i l uni form a f t e r each addi t ion. C i t r i c ac id and caus t i c soda are used f o r pH adjustment. Dissolve the dye i n water before add i t i on . Phvsi c a l P roper t i es

Appearance: Clear go ld l i q u i d , dyed t o preference pH. as i s : 8 Spec i f i c Grav i ty : 1.04 V iscos i t y : 150 cps

Add the ingredients i n the order l i s t e d w i t h mixing. Mix

SOURCE: Rhone-Poulenc Surfactants & Spec ia l t i es : Formulas


S t a r t i n g Formula t ions f o r Home Machine Dishwashinq Detergents 8.7% Phosphorous(A)

Compounds: BASF Sur fac tan t * Sodium t r i po l yphospha te B r i t e s i 1 H24 hydrous sodium s i 1 i c a t e * * Sodium s u l f a t e Sodium carbonate Ch lo r ina ted isocyanurate*** Water

8.7% Phosphorous(B1

Coflpounds : BASF Sur fac tan t * B r i t e s i l H24 hydrous sodium s i l i c a t e * * Sodi um s u l f a t e Sodium carbonate Ch lo r ina ted isocynaurate*** Sodium t r i po l yphospha te hexahydrate

Nonphosphate

Compounds2 BASF Sur fac tan t * Sokalan PABOCL B r i t e s i l ti24 hydrous sodium s i l i c a t e * * Ch lo r ina ted t r i s o d i u m phosphate Sodium s u l f a t e Sodium carbonate Sodi um c i t r a t e d i hydra te

?4 b y W S i ¶ h _ t . 3

34 17 15 19

2 10

% -by__W!sh t 3

17 1 4 . 5 20

1 . 5 44

”/._ b Y. W!%lb t 4 . 0 2****

20 1 2 . 5 30

1 . 5 30

*P lu ron ic , P lu ra fac , and I n d u s t r o l s u r f a c t a n t **Other r a t i o s o f Si02 can be used. L i q u i d s i l i c a t e s can a l s o

be used i n p l a c e o f powders. ***Such as ACL-59.

* * * *Ac t ive

M ix ing Procedures:

gent, t h e f o l l o w i n g process i s suggested f o r t h e mix ing of raw mater i a1 s : 1 . Spray a m ix tu re o f t h e s u r f a c t a n t and water ( o r su r fac tan t ,

To achieve maximum c h l o r i n e s t a b i l i t y o f t h e formulated de te r -

water , and l i q u i d s i l i c a t e ) on to t h e phosphate b u i l d e r s , soda ash, o r m ix tu re t h e r e o f . S t i r con t inuous ly w h i l e spray ing .

w i t h s imu l - Th i s process r e s u l t s i n hyd ra t i on o f t h e bu lde rs taneous adsorp t ion o f t h e s u r f a c t a n t .

2. Add t h e ch lo r i ne -con ta in ing compound and any f i l m ix tu re and cont inue mix ing u n t i l t h e e n t i r e m i x homogeneous. A d ry , f r e e - f l o w i n g granu lar produc ob ta ined w i t h t h i s method.

SOURCE: BASF Corp.: Suggested Formulat ions

e r s t o t h e u re i s

should be

-washing Detergents 31

L i g h t Duty L i q u i d Deteraents

L i q u i d de tergents based on P i l o t Ca lso f t , Calsuds and Calfoam s u r f a c t a n t s produce safe, e f f e c t i v e suds w i t h e x c e l l e n t grease- c u t t i n g p r o p e r t i e s f o r hand dishwashing. Detergents con ta in ing Calamide C a re e s p e c i a l l y m i l d t o s e n s i t i v e sk in .

Water C a l s o f t L-60 Ca l fax DB-45 Cal foam EA-603 Calamide C C i t r i c Ac id Perfume

Ammonium Ch lo r ide Dye

Calsuds A Cal foam ES-303 Water* C i t r i c Ac id Perfume and Color

C a l s o f t L-40 Cal foam EA-603 Calamide C P i l o t SXS-40 Water* C i t r i c Ac id Perfume and Color

Calsuds CD-6 Cal foam EA-603 P i l o t SXS-40 Cal s o f t LAS-99 Water* C i t r i c Ac id Perfume and Color

P i l o t Formula #LDL-010-01

% bv Weipht 61 .OO 19.80 9.90 5.00 3.00 0.10 0.10 0.10 1 .oo

P i l o t Formula #LDL-013-01

% by Weiaht 70.00 10.00 20.00

Q.S. pH 7 Q . S .

P i 1 o t Formul a #LDL-005-01

% bv Weiaht 40.00 10.00 6.00

12.50 26.50

Q.S. pH 7 Q . S .

P i 1 o t Formula #LDL-015-01

% bv Weight 25.00 10.00 8.80 6.00

50.20 Q.S. pH 7

Q . S .

*May be o p a c i f i e d by r e p l a c i n g 1% o f water w i t h 1% l a t e x opaci f i e r . Opaci f i e r should be d i 1 u ted w i t h water be fo re a d d i t i o n .

SOURCE: P i 1 o t Chemi c a l Co. : Household C1 eaner Formul a t i on8

32 Advanced Cleaning Promcct Formulations

L i g h t Duty Liauid. Premium Hand Dishwash

Water, D . I . W i t c o l a t e SE-5 W i t cona te 1260 S1 u r r y W i tcami de 128T Pe t ro LEA L i q u i d Sodium S u l f a t e Ethanol Formal i n Perfume, Dye

% by Weight 30.2

36.7 5.0 1 .9 2.6 1 .8 0.1 q . s .

21.7


us ing C i t r i c Acid.

Typ ica l P r o p e r t i es :

Blend i n g r e d i e n t s i n t h e order l i s t e d . Ad jus t pH = 6.5-7.0

V i s c o s i t y , cps: 230 Appearance: C lear L i q u i d

Formula 113

L i g h t Duty L i q u i d

Water, D. I. W i t c o l a t e SE-5 Witconate 1260 S l u r r y W i tcami de 128T Pe t ro LEA L i q u i d Sodium S u l f a t e Sodium Ch lo r ide Formal i n Perfume, Dye

Economy Hand D i shwash

% by Weiqht 73.6 8 .3

13.5 1 .9 1 . o 0.6 1 .o 0.1 q . s .

81 ending Procedure:

us ing C i t r i c Ac id .

Typi c a l P r o p e r t i es :

Blend i n g r e d i e n t s i n t h e o rde r l i s t e d . Ad jus t pH = 6.5-7.0

V i s c o s i t y , cps: 180 Appearance: C1 ear L i qu i d

Formula 115

SOURCE: Witco Corp.: Suggested Formula t ions

LXshwashing Detergents 33

Water Caustic Soda (50%)

L i a u i d Hand D ish Detergent Formula DW-0016

Wt.% Wt.% Wt.% To 100 To 100 To 100

2.5 3.3 4.1 Dodecylbenzene sui f o n i c ac id 10 13 Rhodapex NA-61 4.5 4.5 A1 kami de DC 212/S 1 2 Cheelox BF-13 0.5 0.5 C i t r i c Acid (50%), t o pH 8 Q.S. Q . S . Sodium ch lo r i de 1 1 Fragrance - - Dye Opaci f i er (Morton ) - -

- -

16 5 3 0.5 Q.S. 1

Procedu r e Add t h e ingredients i n the order l i s t e d , w i t h mixing. Mix

u n t i l uni form a f t e r each addi t ion. C i t r i c ac id and caus t i c soda are used f o r pH adjustment. Sodium ch lo r i de b u i l d s v i s c o s i t y . Dissolve i t i n water before add i t i on .

Dissolve t h e dye i n water before add i t i on . I f o p a c i f i e r i s used, i t should be d i l u t e d w i t h water before addi t ion. A l l pH adjustments must be completed before t h e o p a c i f i e r i s added.

Phvsical ProDertieg Appearance: L iqu id, colored and opac i f i ed t o preference pH. as i s : 8

V iscos i ty : 200-400 cps Speci f i c Gravi t y : 1 .02+-0.05

pH, 1%: 7.2

SOURCE: Rhone-Poulenc Surfactants & Spec ia l t i es : Formula


Mechanical D i shwashi ng Detergent Chlor inated

Formula DW-0009

Sodium Carbonate ( L t . Density) Antarox BL-330 Sodium Tripolyphosphate. Powder Sodium Metas i l i ca te Pentahydrate Clearon CDB (FMC)

Wt.% 41 . O

2.0 34.0 20.0 3.0

Procedu rQ Add the sodium carbonate t o the mixer. Spray on t h e Antarox

EL 330. Add t h e remaining ingredients i n the order l i s t e d . Mix u n t i 1 uniform.

Phvsi ca l ProDert i eg Appearance: White, f ree- f lowing powder pH (1%): 11.2 Spec i f i c Grav i ty : 0.70

Uechani c a l D i shwashi ng DeterQent L i sui d Formula DW-0010

Igepal CO-730 Gantrez AN-149 Potassium Hydroxide (45% Act ive) Sodium S i l i c a t e (46% Act ive) Antarox BL-330 Tetrapotassium Pyrophosphate (60% Act ive) Water

Wt.% 0.5 1 . o 3.0

17.0 3.0

63.3 12.2

Proctndu r e 1. Add Gantrez AN-149 t o Igepal CO-730/water mix ture and s t i r

a t room temperature u n t i l d issolved. Heat t o 45-50C i f not t o t a l l y i n s o l u t i o n .

2. Maintain heat a t 45C and add r e s t o f ingredients i n d i v i d u a l l y .

Physical P r o m r t i eg pH (as i s ) : 13.2 pH (1%): 10.4 V iscos i t y : 1060 cps Spec i f i c Grav i ty : 1.14

SOURCE: Rhone-Poulenc Spec ia l t i es 6 Surfactants: Formulas


L i a u i d Formula DW-0008

Rhodacal A-246/L Rhodapex MA-460 Alkamide DC-212/S Sodium Xylene Su l fonate (40%) O p a c i f i e r (Morton) Water C i t r i c Ac id t o pH 6.5-7.5 Perfume and Color

Wt.% 60.0 10.0 5.0 4.0 1.0

20.0 Q . S . P.S.

Procedure 1. Charge water and sodium xylene su l fona te t o vessel equipped

w i t h a g i t a t i o n .

u n t i 1 uni form. 2. Add Rhodacal A-246/L and Rhodapex MA-360 t o vessel and mix

3. Add Alkamide DC-212/S and mix as above. 4. Ad jus t pH 6.5-7.5 w i t h c i t r i c ac id . 5. Add o p a c i f i e r ( o p t i o n a l ) , perfume and co lo ran t , as des i red .

Phys ica l P r o m r t i e s : Appearance: Clear go ld l i q u i d , dye and opac i f y t o preference. pH, as i s : 6.5-7.5 S p e c i f i c Grav i t y : 1.02-1.04 V i s c o s i t y : 200-300 cps

SOURCE: Rhone-Poulenc Sur fac tan ts EL S p e c i a l t i e s : Formula


S t a r t i n a Formulations f o r Commercial Machine Dishwashing Deteraents

Nonchlori ne/Noncaustic

BASF Surfactant* Sodium tr ipolyphosphate Sodium carbonate Sodium s u l f a t e Sodium metas i l i ca te pentahydrate Water

Noncaustic

BASF Surfactant* Sodium tr ipolyphosphate Sodium carbonate Sodium metas i l i ca te pentahydrate Chlor inated isocyanurate** Water

Ch lo r ineKaus t i c

BASF Surfactant* Sodium tr ipolyphosphate Sodium carbonate Sodium metas i l i ca te pentahydrate Chlor inated isocyanurate** Sodium hydroxide (90%) Water

*Pluronic, Plurafac, I ndus t ro l sur factant **Such as ACL-59

% by Weight 3

34 22 11 25

5

% bv Weiaht 3

31.5 20 31.5

1.5 12.5

% bv Weiqht 3

34 18 22.5

2 .5 15 5

M i x i ng Procedures : 1. Thoroughly mix the phosphate and carbonate. 2. I n a separate container, mix the sur factant and water. Next,

spray th'is l i q u i d onto the phosphate/carbonate mixture. Mix cont inuously wh i l e spraying, and continue mixing u n t i l t h e l i q u i d i s completely adsorbed and the mixture i s homogeneous.

3. Add the me tas i l i ca te , su l fa te , and/or caust ic and mix. 4. F i n a l l y , add the ch lo r i na ted cyanurate and mix thoroughly. Note:

maximum ch lo r i ne s t a b i l i t y .

SOURCE: BASF Corp.: Suggested Formulations

The mixing sequence given above i s necessary f o r maintaining

5. General Purpose Cleaners

37

38 Advanced Cleaning Roduct Formulatioiu

A1 1 Purpose Cleaner

Mackam 2CSF Tetrapotassi um Pyrophosphate T r i sodium Polyphosphate KOH (45%) Low Rosin T a l l O i l Fa t t y Acid Dei oni zed Water

Weight.% 10.0 5.0 5.0 4.0

10.0 66.0

Procedure: 1. Dissolve Tetrapotassi um Pyrophosphate and T r i sodi um Po

2. Add KOH. 3. Disperse T a l l O i l Fa t t y Acid. 4. Cool t o 50C and s lowly add Mackam 2CSF.

phosphate a t 70C.

PhosDhate Free A l l PurDose Cleaner

Sodium Metas i l i ca te Pentahydrate Mackami ne C-10 Caustic Soda (50%) Mackam 2CYSF Tetrasodium EDTA (40%) Dei oni zed Water

Y-

Weight .% 22.0 9.0 2.0 4.0 1 . o

62.0

Procedure: 1. Add Sodium Metas i l i ca te and Tetrasodium EOTA t o water and

2. Add Mackamine C-10 and Caustic Soda (50%). 3. Add Mackam 2CYSF and blend u n t i l c l e a r .

heat t o 60C.

Bathroom T i l e Cleaner

Sodium Hypochlor i te (35%) Mackamine LO Tetrasodi um EDTA Dei oni zed Water

Procedure: Add components t o water and blend u n t i l c

SOURCE: McIntyre Qroup Ltd. : Suggested Formu

Wei aht .% 4.7 5 .0 1 .o

89.3

ear.

a t i one

Water Sodi um Carbonate Tetrasodium EDTA, 40% W i t c o l a t e 7031 Sodium Ch lo r ide W i t cona te SXS L i q u i d C i t r i c Acid, 50%

A l l Purgose Cleaner

% bv Weiqht 61.2

5.0 6.0 15.0 10.8 2.0

9 .s . t o pH=11.0-11.5

Blend ing Procedure:

Typ ica l P roper t i es : V i s c o s i t y , cps: Water t h S o l i d s : 25.6% pH, as i s : 11.2

Blend i n g r e d i e n t s i n t h e order l i s t e d .

n

SOURCE: Wi tco Corp.: Formula 518

All-PurDose Cleaner

Eastman E 8 so lven t Na4EDTA* Nonionic s u r f a c t a n t * * I sop ropy l a lcoho l Water

*Tet rasod i um e t h y l enedi ami n e t e t r a c e t a t e **Such as Neodol 23-7 a lcoho l e thoxy la te

N-95 e thoxy la ted nonylphenol (Texaco).

Hard-surface Cleaner

Eastman DB so lven t An ion ic su r fac tan t * * * N a 4 EDT A* * * * Ammonium Hydroxide (28%) Water

2. 2 1

90

39%) S h e l l ) o r Su l fon

% bv Weisht 3.2 7 3 5 3

C

% bv Weiaht 7.0 1 . o 1.25 2.0 88.75

***Such as Rhodapex CO-433 (Rhone-Poulenc) ****Tetrasodium ethylenediaminetetraacetate (39%)

SOURCE: Eastman.Chemica1 Co.: Eastman EB and D0 Solvents f o r Cleaners: Suggested Formulat ions

General Purpose Cleaners 39


A1 1 -Purpose C1 eaner-A

% Marl i p a l 24/90 7.5 Methoxypropanol 6.0 Sodium carbonate 3.0 N i t r i l o t r i a c e t a t e , 40% 0 . 4 Balance water, fragrance, dyestuf f , preservat ive, sodium c h l o r i d e t o 100

Act ive matter: 7.5% V iscos i t y : L iqu id

A11-PUrDOSe C l e a n e r 4

% Mar l i pa l 1012/6 1 .o Mar l i na t 242/28 10.0 Sodium carbonate 3 . 0 Sodium c i t r a t e d ihydrate 1.5 Sodium t a r t r a t e 1.5 Balance water, fragrance, dyestuf f , preservat ive,

sodium ch lo r i de t o 100

Act ive matter: 3.8% Viscos i t y : Low

Al1-PUrDOSe Cleaner. w i t h Y ic rob ic ida l Prooert ies. Liauid-B

Marl i pa l 01 3/99 Warlazin KC 21/50 N i t r i 1 o t r i acetate, 40% Sodium carbonate Balance water, fragrance, dyes tu f f

% 8.0 5.0 0.5 3.0

t o 100


SOURCE: Huls America, Inc. : Basic Formulations o f Detergents and Cleaning Agents f o r Household Purposes


A-Jl-Purpose Cleaner, L iquid-A

Marlon PS 65 Marl i pa l 01 3/69 Coconut f a t t y a c i d C i t r i c terpene Methoxypropanol Sodium carbonate Sodium c i t r a t e d ihyd ra te Ethylenediamine te t raace ta te , 40% Balance water, f ragrance, d y e s t u f f , p rese rva t i ve


A l l -Pu_rpose C1 eaner , L i qu i d-6

Marl i pa l 01 3/69 C i t r i c terpene Methoxypropanol Sodi um carbonate C i t r i c a c i d N i t r i l o t r i a c e t a t e , 40% KNA cumene sulphonate 40 Balance water, f ragrance, dyes tu f f , p rese rva t i ve


% 3.0 1 . o 0.2 2.0 3.0 3.0 3.0 0 . 2

t o 100

'16 5 . 0 0 . 2 5 . 0 3.0 1 . o 0 . 2 1 . o

t o 100

Al l -Purpose CleaKer, w i t h - M i c r o b i c i d a l Proper t ies , L iquid-A

Marl i pa l 01 3/99 N i t r i l o t r i a c e t a t e , 40% Lonzabac 12.30 Sodium carbonate KNA cumene sulphate 40 Balance water, f ragrance, d y e s t u f f

% 7.5 2.0 3.0 3.0 2.0

t o 100


SOURCE: Huls America, I n c . : Basic Formulat ions o f Detergents and Cleaning Agents f o r Household Purposes

42 Advanced Cleaning product Formulations

All-Purpose Cleaner, Pastv-A

Marlon AS3 Caust ic soda, 50% (approx.) Marl i nat 242/28 Marl i p a l 01 3/30 Tylose CBR 10000 T i tan ium d i o x i d e Sodium c h l o r i d e (approx.) Balance water, f ragrance, p rese rva t i ve


A1 1 -Purpose Cleaner ,

Marlon PF 40 Mi l i p a l 01 3/30 Marlamid DF 1218 Tylose CBR 10000 T i tan ium d i o x i d e Sodium c h l o r i d e (approx.) Balance water, f ragrance, p rese rva t i ve


96 10.0 2.6

15.5 3.0 4.0 0.1 2.0

t o 100

Pastv-B

% 45.0

2.0 2.0 4.0 0.1 8.0

t o 100

Al l -Purpose Cleaner, W i t h Soap, High V iscos i ty -A

% Marlon PF 40 5 . 0 O l e i c a c i d 10.0 Caust ic potash, 50%* (approx.) 3.9 Potassium carbonate* 1 .o Ethylenediamine t e t r a a c e t a t e , 40% 0.2 Balance water, f ragrance, d y e s t u f f , p rese rva t i ve t o 100


Al l -Purpose Cleaner. W i t h Soap. High V iscos i tv -B

Marl i pa l 24/79 Marl i pa l 242/28 O l e i c Ac id Caust ic potash, 50%* (approx.) Sodi um c i t r a t e d i hydra te Ethylenedi amine te t raace ta te , 40% Ethanol * Balance water, f ragrance, d y e s t u f f , p rese rva t i ve


96 2.0 5 .0 8.0 3.1 1.5 0.2 1.5

t o 100

SOURCE: Hu ls America, Inc. : Basic Formulat ions o f Detergents and Cleaning Agents f o r Household Products


D-Lilnonene Emuls i f iab le Concentrate Formul a HS-0094

Component D-Li monene Rhodacal I PAM Igepal CQ-720 T r i ethanol ami ne

Wt.% 80.0 1 5 . 0

4 . 0 1 .o

Procedure

Phvsical Prooer t i es

Blend ingredients i n order l i s t e d and m i x u n t i l uniform.

Appearance: Clear, yel low l i q u i d Spec i f i c Grav i ty : 0.9 V i scos i t y : t10 cps pH, as i s : 10.0

Note: Product forms mi lky whi te emulsions when d i l u t e d w i t h water.

D-Limonene All-PurDose Cleaner Formula HS-0033

Comoonent: Water Sodium Metasilicate-Pentahydrate Miranol FBS Rhodasurf 91 -6 Cheelox BF-13 A1 kamide DC-212/M D-Li monene

Wt.% 73.5 2.0

10.0 3.5 5.0 3.0 2.0

Procedu r e Blend ingredients i n order l i s t e d and m i x u n t i l uniform.

Phvsicsl Proner t ies Appearance: S l i g h t l y hazy, yel low l i q u i d pH, as i s : 1.25 Spec i f i c Grav i ty : 1.02 V iscos i t y : <I0 cps

SOURCE: Rhone-Poulenc Surfactants 81 Specia l t ies: Formulas

44 Advanced Cleaning Rorluct Formulations

General C1 eaners

Cleaner-Household

Ins red i ents: Tetrapotassium Pyrophosphate Dodecyl benzene Sul fonate T r i ethanol ami ne S a l t Aerosol A-103 Surfactant Laur ic Diethanolamide Sodium Xylene Sul fonate

Mix a l l o f t he above together a t one time.

A1 k a l i ne Cleaner

Ins red i ents: Aerosol 0s Surfactant Sodi um Metasi 1 i cate Caustic Soda Tetrasodi um Pyrophosphate T r i sodi um Phosphate

L i a u i d Hand Cleaner

Insredients : Aerosol A-102 Surfactant Mineral O i l Coconut O i l n-Propanol o r Isopropanol Triethanolamine Germicide Water

% by Weiaht 8 . 0 4.0 4.0 2.0

7 6 . 0

% bv Wei aht 5 . 0

50.0 5.0 7 . 0

3 3 . 0

% by Weiaht 60.0 10.0

5 . 0 5 . 0 0.5 0.1

19.4

Germicidal C1 eaner

Inaredi ents: % bv Weiaht Aerosol 22, Aerosol 0s. Aerosol A-102 Surfactant

o r mix ture 10.0 Tetrapotassium Pyrophosphate 7.0 Dowicide 32 5 . 0 Isopropanol 3 . 0 Water 7 5 . 0

SOURCE: Cytec Indus t r i es Inc. : Suggested Formulations


Hiph-Performance General Purpose Cleaner Concentrate Formula HS-0038

Water STPP (Anhydrous Granular) Rhodapon UB Rhodapon BOS A1 codet HSC-1000 Butoxyethanol Miranol FBS

Procedu r e Blend ingredients i n order 1

Phvsi ca l P r o D e r t l es Appearance: Clear, l i g h t ye1 pH, as i s : 9 . 4 Spec i f i c Grav i ty : 1.06 Viscos i t y : t10 cps

sted

ow 1

and mix unt

qu id

Heavy-Dutv Cleaner Powder Formula HS-0039

Wt.% 65.0

6.0 13.0 5.0 5.0 4 . 0 2 . 0

1 uniform.

Trisodium Phosphate o r Sodium Carbonate Sodi um S i 1 i cate Rhodacal DS-10 Sodium Su l fa te Fragrance

Procedu r g

uniform.

Physical ProDerti es

Add ingredients i n order l i s t e d t o powder blender

Appearance: Whi te , f ree- f 1 owi ng powder pH, 1% Solut ion: 10.8

Wt.96 40 10 20 30

Q.S

Mix u n t i l

SOURCE: Rhone-Poulenc Surfactants & Specia l t ies: Formulas

46 Advanced Cleaning Pr&t Formulations

Neut ra l A1 1 -PurDose C1 eaner, w i t h Pear l escence High V i scosi t y - A

Marlon PS 65 Marl i nat 242/28 Marlamid DF 1218 Marlamid PG 20 Cellobond HEC l O O O O O A Balance water, f ragrance, dyes tu f f , p rese rva t i ve


E f fec t ,

96 7.5 4.5 1 .o 2.0 0.7

t o 100

Neut ra l All-PUrDOSe Cleaner, w i t h Pearlescence E f f e c t . H i ah V i scosi ty-B

M a r l i n a t OFK 30 Marl i na t 242/28 Marlamid DF 1218 Marl i pa l 24/90 Marlamid PG 20 Cellobond HEC l O O O O O A Balance water, f ragrance,


96 5.0 2.0 1 .o I .o 1 . o 0.9

dyes tu f f , p rese rva t i ve t o 100

A1l-PUrDOSe Cleaner, w i t h A c e t i c A c i d - A

M a r l i p a l 1012/6 M a r l i n a t 242/28 Sodium c i t r a t e d ihyd ra te Ace t i c ac id * Sodi um c h l o r i d e (approx. ) Balance water, f ragrance, d y e s t u f f

A c t i v e mat te r : 5.7% V i s c o s i t y : low

A11-PUrDOSe Cleaner. w i t h A c e t i c Acid-B

Marlon PS 65 Ace t i c ac id* Balance water, f ragrance, dyes tu f f

A c t i v e mat te r : 3.3% Viscos i t y : 1 i q u i d

* f u r t h e r p roduc ts o f Huls AG

96 1.5

15.0 1 .o 2.0 6.5

to 100

s6 5.0 6.0

t o 100

SOURCE: Hu ls America, Inc. : Bas ic Formulat ions o f Detergents and Cleaning Agents f o r Household Purposes


Non-PhosDhate A l l PurDose Cleaner

Components: Water 45% KOH Burcosperse AP L iqu id Sodium Xylene Sulfonates 40% Sodi um C i t r a t e Dodecylbenzene Su l fon i c Acid Burco TME Buty l Propasol Varsol o r Mineral S p i r i t s

% by Weight 77.15 0.75 3.00 3.40 1 .oo 1.75 6 . 0 0 6 . 0 0 0.95

Procedure:

between each add i t i on . Add components i n the order l i s t e d . Blend u n t i l uni form

O i l S D l i t t i n s General PurDose Cleaner

Components: Water Sodium Metas i l i ca te Pentahydrate Burco ADS-40 Burco TME Burco LAA-38 Burco EHS

% by Wei Qht 82.5

5.0 2.5 5.0 2.5 2.5

Procedure: Add components i n t h e order l i s t e d . Blend u n t i l f u l l y d iss-

olved between each addi t ion. This i s a use as i s formulat ion f o r heavy duty c leaning. For

l i g h t e r duty appl icat ions, d i l u t i o n w i t h water may be poss ib le . This formulat ion w i l l suspend o i l t o a s s i s t w i t h removal. The suspended o i l w i l l then f l o a t f o r easy removal.

SOURCE: Bu r l ington Chemical Co., I nc . : Suggested Formulations


Scouri ng Cleaner, Medi urn V i scosi tv-A

Marlon PS65 Marl i pal 01 3/30 Sodium sulphate Calcium carbonate, e.g. Durcal 40 Balance water, dyestuf f , fragrance, preservat ive


Scouring Cleaner. Medi urn V i scosi t y - B

Marlon PS 65 Mar l i pa l 013/30 Marl i nat 242/28 Sodium carbonate Calcium carbonate, e.g. Durcal 40 Balance water, dyes tu f f , fragrance, preservat ive


Scouring Cl-eaner. Powder-A

Marlon ARL Sodium carbonate, dehydrated Sodi um d i ch lo ro i socyanurate Calc i um carbonate powder (abrasive)


% 4.3 2.7 1.5

50.0 t o 100

% 3.5 3.0 2 . 0 1.5

5 0 . 0 t o 100

% 5.0 5.0 1 . o

t o 100

Scouring Cleaner, Powder-B

% Marlon ARL 5.0 Sodium carbonate, dehydrated 5.0 Sodium tr ipolyphosphate 2.0 Calcium carbonate powder (abrasive) t o 100


SOURCE: Huls America, I nc . : Basic Formulations o f Detergents and Cleaning Agents f o r Household Purposes

6. Glass Cleaners/Polishes

49


A n t i f o g Compositions f o r A p p l i c a t i o n t o C l o t h

Special w ip ing c l o t h s impregnated w i t h Aerosol OT Sur fac tan t a re used t o c lean and t o p revent fogg ing o f eye glasses, b i n - ocu la rs , goggles, eyepieces i n gas masks, and automobile, t r a i n , p lane, and boat windshields. Such w ip ing c l o t h s a re prepared by impregnat ing c o t t o n f l a n n e l w i t h Aerosol OT Sur fac tan t s o l u t i o n s fo l l owed by a run through squeeze r o l l s t o remove t h e excess 1 i quor .

a t 25% s o l i d s and one fo rmu la t i on a t 50% s o l i d s a re as f o l l o w s : Three successful f o rmu la t i ons con ta in ing Aerosol OT Sur fac tan t

Ingred ien ts -1 : Aerosol OT-75% Sur fac tan t ( l b . ) Varsol No. 2 Petroleum Solvent ( g a l . ) I sopropy l Alcohol ( g a l . ) Water ( g a l . )

I na red i ents-2 : Aerosol OT-75% Sur fac tan t ( l b . ) Varsol No. 2 Petroleum Solvent ( g a l . ) I sopropy l Alcohol ( g a l . ) Water ( g a l . )

I n ~ r e d i e n t s - 3 : Aerosol OT-75% Sur fac tan t ( l b . ) Varsol No. 2 Petroleum Solvent ( g a l . ) I sopropy l Alcohol ( g a l . ) Water (ga l . )

Inqred ien ts -4 : Aerosol OT-75% Sur fac tan t ( l b . ) Varsol No. 2 Petroleum Solvent ( g a l . ) I sopropy l Alcohol ( g a l . ) Water ( g a l . )

25% S o l u t i o n 113

15 3

19

25% S o l u t i o n 113

6 6

25

25% S o l u t i o n 113 -

8 29

50% S o l u t i o n 66

2

3 -

The so l ven ts and water a re mixed a t 80F t o 1OOF. The Aerosol OT-75% Sur fac tan t i s added s low ly w i t h cont inued mix ing . A f t e r t h e Aerosol OT has d isso lved, a l l s o l u t i o n s w i l l remain c l e a r and l i q u i d a t temperatures as low as 5OF. No scumming o f t h e sur face w i l l occur because o f evapora t ion d u r i n g a normal run o f c l o t h through t h e ba th . The s o l u t i o n s t h a t a re al lowed t o stand should be covered t o p revent l o s s o f so l ven t .

The optimum amount o f Aerosol OT Sur fac tan t t o be l e f t on t h e c l o t h i s 40-50%, based on t h e weight o f t h e c l o t h . However, a range o f 25-50% w i l l g i v e s a t i s f a c t o r y r e s u l t s .

SOURCE: Cytec I n d u s t r i e s Inc . : Suggested Formulat ions

Glass CleanerslPolishes 51

A n t i f o g Compositions f o r D i r e c t Appl icat ion t o Glass

Aerosol OT Surfactant i s used i n specia l formulat ions t h a t are appl ied d i r e c t l y t o glass surfaces t o prevent fogging under ad- verse weather condi t ions. Some o f these formulat ions g i ve dur- ab le f i l m s t h a t stand up under severe tes ts . An example o f an excel l e n t "Ant i fog" paste i s as fo l lows:

Aerosol OT-75% Surfactant Gum Tragacanth Petrolatum Water

10.7 l b . 2.0 l b . 2 . 0 l b .

85.3 l b .

Heat t h e water t o 18OF and add the Aerosol OT-75% slowly w i t h mixing. S i f t i n powdered gum tragacanth. Continue mixing u n t i l a l l gum i s dispersed, cool t o 105F, and add petrolatum.

Appl icat ion o f An t i f og Paste: Dampen t h e corner of a piece o f c l o t h w i t h paste and rub

over e n t i r e glass surface. Before f i l m becomes dry, p o l i s h we l l w i t h c lean p o r t i o n o f t he c l o t h .

A spray bomb o f An t i f og may be prepared as fo l lows:

Aerosol OT-75% Surfactant Buty l Cel losolve Solvent Propel 1 ant

10 p a r t s 10 p a r t s 80 p a r t s

Aerosol OT Surfactant may a l so be cast i n t o s t i c k form. Softening agents such as g lycer ine o r ethylene g l yco l are incorporated t o s i m p l i f y app l i ca t i on t o the glass surface. Such s t i cks , usual ly two t o fou r inches long and one-half inch i n diameter, are so ld i n k i t s f o r app l i ca t i on t o goggles, w i ndshi e l d w i pes and bthroom m i r r o r s .

SOURCE: Cytec Indus t r i es , Inc. : Suggested Formulations

52 Advonced Cleoning product FormulotiOnr

Water, D . I . Isopropanol Adogen 66 Varox 365 Emcol 4500

Anti-Foggina. An t i -S ta t i c Glass Cleaner

% bv We

Blending Procedure: Combine ingredients i n the order shown and mix thorough

I f product i s hazy, add i t i ona l Isopropanol can be used t o c l a r i f y t he so lu t i on . Gentle heat ing can be used t o f a c i l - i i t a t e mixing o f t h e Emcol 4500.

Use Ins t ruc t i ons :

sht 0.0 9.0 0.1 0.5 0.4

Y.

Apply f i n i s h e d product t o a towe l l e te (Kimwipe, e t c . ) and wipe onto t h e glass. Al low t o dry.

Product Informat Product: Varox 365 Adogen 66 Emcol 4500

This formulat

on : Bene f i t : Wetting agent, degreaser. and detergent A n t i - s t a t i c agent Wetting agent, coupler, and detergent

on presents a t h i n b a r r i e r between the water vapor ( i . e . , fog, steam, e tc . ) and the glass which w i l l prevent fogging. The a b i l i t y t o lower the surface tens ion o f t he water prevents the c l i n g i n g o f i n d i v i d u a l water d rop le ts t o the glass; t he re fo re l i g h t i s not scat tered as much as i t i s when passing through i n d i v i d u a l droplets .

Formula 708

Annoniated Glass Cleaner

Water W i t c o l a te 231 0 Buty l Cel l oso l ve Aqua Ammonia, 26 Be'

% by Weight 94.0 3.0 2.0 2.0

Blending Procedure:


Formula 704


Blend ingredients i n the order shown, mixing thoroughly

Glass CleanersfPolbhes 53

Glass C1 eaners Ammon i a

Formula GC-0017

Water Rhodacal DSB Butoxyethanol Ammonium Hydroxide (28%) Dye

Economical Heavy-Duty Wt.% Wt.%

94.60 88.70 ~~

0.15 0.30 5.00 10.00 0.25 1 .oo - -

Procedu rQ Blend ingredients i n order l i s t e d and mix u n t i l uniform.

Phvsi ca 1 Prooer t ies Appearance: Clear l i q u i d , dye t o preference pH (as i s ) : 10.5 pH (1%): 9.0 Spec i f i c Grav i t y : 0.99 V iscos i t y : t10 cps

10.8 9.7 0.99

t10 cps

G1 ass C1 eaners Vinegar

Formula GC-0018

Water Rhodacal DSB Butoxyethanol Acet ic Acid Dye

Economical Heavv-Duty Wt.% Wt.%

94.85 89.70 0.15 0.30 5.00 10.00

To pH=4 To pH=4 - - Procedu rQ

Blend ingredients i n order l i s t e d and mix u n t i l uniform.

Physical Prooer t i eg Appearance: Clear l i q u i d , dye t o preference pH (as i s ) : 4.0 4.0 pH (1%): 3.5 3.5 Speci f i c Grav i ty : 0.99 0.99 V i scosl t y : t10 cps t10 cps

SOURCE: Rhone-Poulenc Surfactants 6 Spec ia l t i e r : Formulas


Glassware and B o t t l e Cleaners B o t t l e Cleaner (Alkaline-Powder)

Inaredi ents: Aerosol OT-8 Surfactant Sodium NTA Powder Cyanamer A-100L Polyacrylamide Sodi um Metasi 1 i cate Tetrasodium Pyrophosphate

B o t t l e Cleaner (Acid-Powder)

Inaredients : Aerosol OT-0 Surfactant NTA Acid Sodium Dihydrogen Phosphate Sodium Hydrogen Su l fa te

B o t t l e Cleaner (A1 k a l i ne-Powder)

Inaredients : Aerosol 0s Surfactant Aerosol OT-8 Surfactant Sodium NTA Powder Sodi um Metasi 1 i cate Tetrasodi um Pyrophosphate

% by Weiaht 2.0

2 0 . 0 5.0 8.0

65.0

% by Weiaht 2 . 0

2 0 . 0 58.0 20.0

% bv Weiaht 5-1 0 1- 2

20.0 8.0

60-66

B o t t l e C1 eaner ( A c i d-Li qu i d)

Inaredi ents: Aerosol GPG Surfactant Phosphoric Acid (85%) NTA Acid Water

% by Weiaht 5.0

t o pH 3.0 or l e s s 20.0 75.0

B o t t l e C1 eaner (Acid-Liqui d l

Inaredi ents: Aerosol 0s Surfactant NTA Acid Phosphoric Acid (85%) Water

% bv Weight 10.0 . .

20.0 t o pH 3.0 o r l ess

70.0

B o t t l e Cleaner (Hiahly Alka l ine) % bv Weiaht I naredi ents :

Aerosol 0s Surfactant 10.0 Aerosol 22 Surfactant 2.0 Sodium NTA 20.0 Sodi um Hydroxi de ( 1 0%) 68.0 SOURCE: Cytec Indus t r i es Inc. : Suggested Formulations

Glass CleanerslPolishes 55

Water, D . I . Isopropanol Varox 365 Methyl ene B1 ue

Household Window Cleaner

% by Weight 89.3 10.0 0.7 q . s .

Blending Procedure:


Typical Proper t ies: V iscos i ty , cps: 4 Sol ids: 0.2% pH: 7.4


Formula 706

Prerni urn Household W i ndow C1 eaner

Water, D . I . Isopropanol Varox 1770 Methyl ene 81 ue

% by Weight 89.4 10.0

0 . 6 q . s .

Blending Procedure:


Typical Propert ies: V i scos i t y , cps: 4 Sol ids: 0.23% pH: 6.2


Formula 707



Low VOC An t i s ta t /C leaner f o r Glass

I n q r e d i e n t : Versaf 1 ex 7000 Isopropanol Ammonium Hydroxide (30%) Neodol 25-35 (58%) Water, Fragrance, and Prese rva t i ve

%w/w 1 . o o 5 .00 0.50 0.15

q . s .

Procedure: 1. D isso lve Versa f lex 7000 i n water. 2 . Add ammonium hydrox ide and Neodol 25-35, and mix. 3. Add isopropanol and mix. 4. Add f ragrance and p rese rva t i ve .

SOURCE: Na t iona l S tarch and Chemical Co.: Reference: #8069:32

A n t i -Fog G1 ass C1 g a s

I n q r e d i ents:_ Water Monawet MO-70R I PA

Procedure: Blend i n o rder l i s t e d and package.

% by We- 93.0

2.0 5.0

SOURCE: Mona I n d u s t r i e s , I n c . : Suggested Formula t ion

G1 ass C1 eaner

Eastman EB so l ven t I sop ropy l a lcoho l Noni on i c s u r f a c t an t * Water

% by We- 3.0 5.0 0.1

91.9

*Such as T e r g i t o l 15-S-7, Cll-C15 secondary a lcoho l e t h o x y l a t e (Union Carbide) o r Genapol 24-L-60 l i n e a r a l coho l e thoxy la te (Hoechst Celanese).

SOURCE: Eastman Chemical Co.: Eastman EB and DB So lvents f o r Cleaners: Suggested Formula t ion

Glass CleaturslPolisks 57

Trad i t i ona l Consumer Glass Cleaner Ammoni ated Anionic Non-Streaki na G1 ass C1 eaner -

Inaredi ent : Wt.% Deionized Water 94.05 2-Butoxyethanol 5.70 Avanel S-70 0.25 C . I . D i r e c t Blue #86 Q.S. Monoethanol ami ne t o pH 10.5-11.5

pH (as i s ) : 10.5-11.5 Appearance: Clear, l i g h t - b l u e l i q u i d Odor: Sweet, ethereal

Charge under a g i t a t i o n most o f t he water, t h e 2-butoxyethanol. Procedure:

and the Avanel S-70 i n t o the mixing vessel. I n a separate vessel, under ag i ta t i on , d isso lve the dye i n the balance of t h e water. Add the dye so lu t i on t o t h e batch. Adjust p H t o 10.5-11.5 w i t h Monoethanolamine. Notes :

This formulat ion incorporates a novel anionic surfactant i n t o a t r a d i t i o n a l ammoniated glass cleaner.

On prolonged storage, g l yco l ethers have been shown t o form peroxy compounds which can adversely a f f e c t t h e dyes normally used i n glass cleaners. Morpholine, Ammonia, o r other v o l a t i l e amines may be used i n place o f t he Monoethanolamine. Formula CG-101

Consumer Aci d G1 ass C1 eaner Acid Anionic Non-Streaking Glass Cleaner

Ins red i ent : Wt.% Dei oni zed Water 89.70 2-Butoxyethanol 10.00 Avanel S-70 0.30 Color Q.S. Acet ic Acid t o p H 3.5-4.0

pH (as i s ) : 3.5-4.0 Appearance: Clear 1 i q u i d Odor: Sweet, ethereal

Charge under a g i t a t i o n most o f the water, t he 2-butoxyethanol, Procedure:

and the Avanel S-70 i n t o the mixing vessel. I n a separate vessel, under ag i ta t i on , d isso lve the dye i n t h e balance o f the water. Add t h e dye so lu t i on t o t h e batch. Adjust p H t o 3.5-4.0 w i t h Acet ic Acid. Notes:

This formulat ion i s p a r t i c u l a r l y e f f e c t i v e a t removing o i l . greases and other atmospheric contaminants from glass surfaces.

On prolonged storage, g l yco l ethers have been shown t o form peroxy compounds which can adversely a f f e c t t h e dyes normally used i n glass cleaners. Dyes should be thoroughly screened f o r s h e l f s t a b i l i t y i n the f i n i s h e d product p r i o r t o adoption i n t o the f i n i shed formulat ion. Formula CG-102


7. Hard Surface Cleaners

58

Hard swface Cleaners 59

Abrasive Cleaner-1

Ina red ien ts : A Hostapur SAS 60

Genapol UD-030 B Water (40-5OC) C Preserva t ive

D C a l i b r i t e SL Tests:

Perfume

V i s c o s i t y (mPas): 1700 ( B r o o k f i e l d RVT) pH: 1 0 , O

Abrasive C1 eaner-2

1.n q red i en t s : A Hostapur SAS 60

Genapol UD-030 B Water (40-50C) C Preserva t ive

Perfume D C a l i b r i t e SL Tests:

V i s c o s i t y (mPas): 2800 ( B r o o k f i e l d RVT) pH: 1 0 , O

Abrasive C1 eaner-3

Ins red ien ts : A Hostapur SAS 60

Genapol UD-030

B Water (40-5OC)

C Preserva t ive Perfume

D C a l i b r i t e SL

4.50% 5.40%

59.00% 0.10% 0.20%

30.00%

4.50% 5.40%

49.00% 0.10% 0.20%

40.00%

4.50% 5.40%

39.00%

0.10% 0.20%

50.00%

Tests:

Manufactur ing( l ,2,3): I One a f t e r another, t h e components o f A a re added t o 0. I1 A t 30C t h e components o f C a re added t o I. I11 A t l a s t , s t i r D to 11.

any longer . Modern l i q u i d products a re based on ca lc ium carbonate.

SOURCE: Hoechst Ak t i engese l l scha f t : Detergents and Cleaning

V i s c o s i t y (mPas) : 6400 (Brookf i e l d RVT) pH: 1 0 , O O

Abrasive powders, based on s i l i c i u m dioxyde a re no t common


60 Advanced Cleaning product Forrnulaiions

Concentrated L i q u i d Household Hard-surface Cleaner P i ne O i 1 A1 1-Purpose D i l u t a b l e Concentrate

Inaredi ent : Dei oni zed Water Macol TD-12 Macol TD-3 Mazamide 80 Macol 40 Pine O i l Tetrapotassium Pyrophosphate Sodium Metas i l i ca te Pentahydrate Sodium Xylene Sul fonate (40%)

Wt.96 79.30 5.00 2.50 0.50 4.00 0.20 3.00 2.00 3.50

pH (as i s ) : 12.5-13.5 Appearance: Clear, l i g h t - y e l l o w l i q u i d Speci f i c Grav i ty : 1 .03

Procedure: Charge the water t o a mixing vessel and s t a r t a g i t a t i o n .

Charge t h e Macol TD-12, Macol TD-3. and Macol 48 and m i x u n t i l product i s c lea r and f r e e o f " f i s h eyes." Charge t h e Pine O i l and mix 5 minutes. Charge t h e remaining ingredients and mix u n t i l c l e a r . Notes:

This i s a concentrated household hard-surface cleaner designed t o be used a t a d i l u t i o n o f 1-3 ounces per ga l lon. Formula CH-103

All-PurDose Household Spray Cleaner Ready t o Use A lka l i ne Hard Surface Spray Cleaner

Ineredi ent : Dei oni zed Water Macol TD-12 Sodi um C i t r a t e Tetrapotassium Pyrophosphate Macol 48

Wt.96 95.15

1 .oo 0.25 0.60 3.00

pH (as i s ) : 9.5-10.5 Appearance: Clear, water-white l i q u i d Spec i f i c Grav i ty : 0.99

Charge the water t o a mixing vessel and s t a r t a g i t a t i o n . Procedure:

Charge t h e Macol TD-12 and mix u n t i l d issolved and f r e e o f " f i s h eyes.'' Charge the remaining ingredients and m i x u n t i l c l e a r . Notes :

This i s an al l -purpose household cleaner designed t o be used "as i s " from a spray b o t t l e . Formula CH-104


Hard Surface Cleaners 61

Consumer T i 1 e C1 eaner A Hard Surface Hypochlor i te Spray Cleaner

Inpredient : Dei oni zed Water Sodium Hydroxide (50%) Sodium Hypochlor i te (12.5%) Avanel S-70

Wt.% 81 .OO

2.00 18.00 1 .oo

pH (as i s ) : >12.5 Appearance: Clear, water-white t o l i g h t - y e l l o w l i q u i d

Charge t h e ingredients w i t h a g i t a t i o n i n t h e order l i s t e d .

This formula i s s u i t a b l e f o r pump spray app l i ca t i on . I t can

Shel f s t a b i l i t y o f ch lo r i ne cleaners i s dependent on t h e

Formula may be adjusted t o use other commercially ava i l ab le

Procedure:

Notes :

be used on shower t i l e s and l i k e surfaces.

absence o f t race metals. Care should be taken t o insure good q u a l i t y water and Sodium Hypochlor i te.

concentrat ions o f Sodium Hypochlor i te. Absolute concentrat ion o f ava i l ab le c h l o r i n e i s 2.0%. Formula CC-101

I n d u s t r i a l Strenath Chlor ine Cleaner A Hard Surface I n d u s t r i a l Strength Hypochlor i te Spray Cleaner

Inaredient : Deionized Water Sodium Hydroxide (50%) Sodium Hypochlor i te (12.5%) Avanel S-70

Wt.Sb 56 .00

3 . 0 0 40.00

1 .oo

pH (as i s ) : >12.5 Appearance: Clear, water-white t o l i gh t - ye l l ow l i q u i d Odor: Chlor ine

Procedure: Charge t h e ingredients w i t h a g i t a t i o n i n t h e order l i s t e d .

Notes : This formulat ion can be used i n high-pressure spray washing

cleaners, d i l u t e d f o r hard-surface c leaning o r used as i s f o r an enhanced consumer household bleach.

Shel f s t a b i l i t y o f ch lo r i ne cleaners i s dependent on the absence o f t race metals. Care should be taken t o insure good qua1 i t y water and Sodi um Hypochlori t e .

concentrat ions o f Sodium Hypochlorite. Absolute concentrat ion of ava i l ab le ch lo r i ne i s 5.0%. Formula CC-102 SOURCE: Mazer Chemicals: Suggested Formulations

Formula may be adjusted t o use other commercially ava i l ab le


D-Limonene Hard-surface Cleaners Formula HS-0093

D-Limonene Concentrate

Component Wt.% D-Li monene 20.0 Alcodet HSC-1000 30.0 Igepa l CO-720 30.0 Mi rano l FBS 19.0 Tr iethanolamine 1 . o Water ---

Al l -Purpose Spray C1 eaner

Type (1 :9 D i l u t i o n )

Wt.% 2.0 3.0 3.0 1.9 0 .1

90.0

Heavy-Duty Degreaser Type (1 :3 D i l u t i o n )

Wt.% 5.0 7.5 7.5 4.75 0.25

75.0

Procedu r e A. Concentrate Blend i n g r e d i e n t s i n o rder l i s t e d and mix

u n t i 1 uni form. B. SDrav Cleaner D i l u t e concent ra te 1:9 w i t h water or charge

"Vessel A" w i t h D-Limonene, Alcodet HSC-1000, and then Igepa l CQ-720. Mix u n t i l uni form. Charge a separate "Vessel B" w i t h water, t r i e thano lamine and M i rano l FBS. Mix u n t i l uni form. F i n a l l y , add t h e conten ts o f "Vessel A" t o "Vessel B" and mix u n t i l un i fo rm.

C.DeQreaSer D i l u t e concent ra te 1:3 w i t h water or b lend i n g r e d i e n t s i n t h e same manner as s p e c i f i e d i n t h e spray c leaner procedure.

Phvsi c a l P r o o e r t i es

Appearance Clear, go ld Clear, l i g h t Clear, Concentrate S w a y Cleaner DegreaSer

l i q u i d ye l l ow l i q u i d ye l l ow l i q u i d S p e c i f i c G r a v i t y 1.02 1 .oo 1 .oo V i s c o s i t y 110 cps <10 cps <10 cps pH. as i s 10.0 9.5 9.5

SOURCE: Rhone-Poulenc Sur fac tan ts & Spec ia l t l ea : Formulas


d ' l i aonene SDrav Cleaner

Phase A: Water, D . I . Tetrapotassium Pyrophosphate Sodium M e t a s i l i c a t e , Anhydrous Pet ro LBA L i q u i d W i t conate AOS

Phase B: DeSonic 9N W i tcami de 128T d ' L i monene*

% bv Weiaht

68.0 6 .0 2.0

10.0 3.0

5.0 3.0 3.0

*Sunkist Growers, I n c . o r Union Camp

Blending Procedure:

speed, add Phase B t o Phase A.

Use D i l u t i o n : use as i s .

Formula 802

Blend Phase A and Phase B separa te ly . W i t h mixer a t h igh

~- d'Lirnonene Cleaner Concentrate

Phase I: Isopropanol O l e i c Ac id Varonic K205 d ' L i monene

Phase 11: Water, D . I . Potassium Hydroxide, 87%

% by Weiaht

10.0 8.8 5.0

12.0

62.2 2.0

Blending Procedure:

I 1 ing red ien ts and mix thoroughly. Whi le mixing, add Phase I t o Phase 11.

Typ ica l P roper t i es : V i scos i t y , cps: 75 So l i ds : 13.8% pH: 10.2

Formula 808


Combine Phase I ingred ien ts and mix thorough ly . Combine Phase


General Purpose Hard Surface Cleaner

This general purpose cleaner i s a v e r s a t i l e product. The combination o f Sandoxylate SX-408 and Sandoxylate SX-424 provide excel lent surface a c t i v i t y and s o i l removal a l lowing i t t o be used i n many app l i ca t i ons .

Inaredi ents: Water Sodi urn S i 1 i cate Sodium Hydroxide (20% Solut ion) Buty l C e l l osol ve Sandoxylate SX-408 Sandoxylate SX-424 Sodium Xylene Sul fonate Drimarine Turquoise XB

% bv W t 79.9

1 .o 0.5 0.5 5.0

11.5 1.5 0.1

Procedure:

i d e (20%), Buty l Cel losolve, Sandoxylate SX-408. Sandoxylate SX-424, Sodium Xylene Sul fonate and Drimarine Turquoise XB.

Charge vessel w i t h water. Add sodium s i l i c a t e , sodium hydrox-

Suggested Use: 4 t o 6 ounces per ga l l on o f water.

SOURCE: Sandoz Chemical s Corp. : Formul a t i on HHG-11

A l k a l i n e Hard Surface Cleaner

Water, D.I. Sodium Metas i l i ca te Varami de A-83 Witconate 30DS W i tconate SXS L iqu id

% by Weiaht 34.0

8.0 12.0 40.0 6.0

Blending Procedure:

each add i t i on .

Typical Propert ies: V iscos i ty , cps: 205 Sol ids: 34.4% pH: 12.5

Add ingredients i n order shown and d isso lve completely between

SOURCE: Wltco Corp.: Formula 5 1 6


General Puroose Hard-surface Cleaners Formula HS-0034

Comoonent

Water Sodi um Metasi 1 i ca te

Pentahydrate Rhodasurf 91-6 Cheelox BF-13 Mi rano l FBS Rhodaf ac RA-600 Butoxyethanol

Solvent-Free Non-Phosphate

IYPe Wt.% 83.5

2.0 7.5 3.0 4.0 -

Solvent-Free Phosphate m Wt.% 85.5

2.0 7.5 3.0

2.0 - -

Heavy-Duty Sol vent

I Y P S Wt.% 83.0

I . o 6.0 2.0 2.0

6.0 -

Procedure

Phvsi c a l P r o o e r t i 8s

Blend i n g r e d i e n t s i n o rder l i s t e d and mix u n t i l uni form.

Appearance C1 ear, C1 ear, C1 ear,

S p e c i f i c G r a v i t y 1.035 1.012 0.994 V i s c o s i t y <I0 cps <I0 cps <I0 cps pH, as i s 12.3 11.85 12.20

It. ye l l ow water-whi te water-whi te

U n b u i l t . Hiah-Sudsina. Hard-surface Cleaner Formula HS-0036

Comoonent Water C a l s o f t F-90 Mi rano l FBS Sodi um S i 1 i c a t e Igepa l CO-710 A1 kami de DC-212/S M-Pyrol, N-methyl-2-pyrrol idone

Wt.% 79.7

5.3 3.0 5.5 1 .o 2.0 3 .5

Procedure 81 end i n g r e d i e n t s i n o rder l i s t e d and mix u n t i l un i fo rm.

TvDi c a l ProDer t i 88 Appearance: C1 ear, ye1 1 ow 1 i qu id V i s c o s i t y : t 1 0 cps pH, as i s : 9.85 S p e c i f i c Grav i t y : 1.07

SOURCE: Rhone-Poulenc Sur fac tan ts h S p e c i a l t i e s : Formulas


Hard-sur face C leaner

I n q r e d i e n t : L i q u i d C i t r i c Acid-50% (Haarman & Sodium h y d r o x i d e s o l u t i o n 50% N o n i o n i c s u r f a c t a n t (Neodol 25-9) Methy l C a r b i t o l s o l v e n t Sodi um x y l ene s u l f o n a t e Sodium carbonate P i n e o i 1 Water

Percent by Wei q h t Rei mer C o r p l - j 4 . 0

2 . 5 0 . 0 7 . 0 5 .0 3.0 0 . 3

70 .2

M i x t h e L i q u i d C i t r i c Acid-50% s o l u t i o n w i t h an equal volume o f water and n e u t r a l i z e by add ing sodium h y d r o x i d e . The neut - r a l i z a t i o n r e a c t i o n s h o u l d be done s l o w l y and c a u t i o u s l y under a g i t a t i o n , as t h e r e a c t i o n i s h i g h l y exo thermic . B lend t h e neut - r a l i z e d s o l u t i o n w i t h t h e n o n i o n i c s u r f a c t a n t , Methy l C a r b i t o l , sodium x y l e n e s u l f o n a t e and sodium carbonate . Add p i n e o i l l a s t .

M n - A b r a s i v e C l e a n s e r

I n g r ed i en t : L i q u i d C i t r i c Acid-50% (Haarman Sodium h y d r o x i d e s o l u t i o n 50% Xanthan gum Vegetab le gum (Veegum HS) Amphoter ic s u r f a c t a n t Noni o n i c s u r f a c t a n t Calc ium c a r b o n a t e (100 mesh) Water

Percent by Wet q h t & Reimer Corp. ) 6 . 0

3 .7 25.0

2 . 5 3.0 1 . 5

45.0 13.3

-~

Prepare a 1% s o l u t i o n o f xanthan gum w i t h t h e i n c l u s i o n o f a p r e s e r v a t i v e . S l o w l y add t h e v e g e t a b l e gum t o water and s t i r u n t i l t h o r o u g h l y h y d r a t e d . Add t h e c a l c i u m carbonate , f o l l o w e d by t h e amphoter ic s u r f a c t a n t , t h e n o n i o n i c s u r f a c t a n t and t h e xanthan gum s o l u t i o n .

SOURCE: Haarman 8, Reimer Corp . : Suggested F o r m u l a t i o n s

- Hard-Surf ace C leaner

Eastman DB s o l v e n t A n i o n i c s u r f a c t a n t * Na4 EDTA* * Ammoni um h y d r o x i d e (28%) Water

*Such as Rhodapex CO-433 (Rhone-Poulenc) * *Tet rasod ium ethylenediaminetetracetate (39%)

SOURCE: Eastman Chemical Co.: Suggested F o r m u l a t i o n

Yo by W t . 7 . 0 1 . o 1 .25 2 . 0

00.75


Hard-surface Cleaner Al l -Surface Bathroom Acid Type

Formula BC-0005

M-Pyrol, N-Methyl-2-Pyrrolidone (ISP) Igepal CO-630 Hydroxyethylcel l u lose Phosphori c Acid Water Perfume and co lorants may be added.

W> 3 4 .0 1 .o 0.2 9.5

85.3

Procedure 1 . D i sperse hydroxyethylcel 1 ulose i n water. 2. I n a separate vessel, mix M-pyrol, Igepal CO-630 together.

Add hydroxyethylcellulose/water mixture. 3. Add ac id and mix thoroughly.

Phvsi ca l P r w e r t i gg pH (as i s ) : 2.0 pH (1%): 2.4 V iscos i t y : 30 cps Speci f i c Grav i ty : 1 .02

--Surface Cleaner Al l -Surface Bathroom Type

Formula BC-0006

Wt.% Water 70.5 I gepal CO-630 2.5 Cheel ox NTA-Na3 20.0 Sodi um Xylene Sul fonate 5.5 Sodi um Hydroxide 1.5 Perfume and co lorants added, as desired, rep lac ing water.

Procedure 1 . Dissolve Igepal CO-630 i n water. Add Cheelox NTA-Na3. 2 . Add sodium-xylene su l fonate and sodium hydroxide, mixing we l l

Physical P r w e r t i e s pH, as i s : 12.9 pH (1%): 11.4 V i scos i t y : 10 cps Spec i f i c Grav i ty : 1.05

a f t e r each addi t ion.


68 Advanced Cleaning Product Formulotiotu

Hard Surface Cleaners

Calsuds, C a l s o f t and Calamide concentrates can be fo rmula ted t o c rea te power fu l , non-corrosive, non - f i lm ing c leaners f o r f l o o r s , woodwork, wa l l s , windows, counter tops, tubs, t i l e and s i m i l a r hard surfaces. Use l e v e l s : 1-4 oz. /gal o f water.

F l o o r Cleaner Products P i 1 o t Formula #HSC-003-01

Water Na4EDTA Ca lso f t F-90 Cal oxy l a t e N-9 B u t y l Ce l l oso l ve

Calsuds 81 TKPP P i l o t SXS-40 Water

Cal foam SLS-30 Calamide C Propyl ene G1 yco l Water

% by Weiaht 81 .OO 10.00 4.00 2.00 3.00

P i l o t Formula #HDC-003-01

% bv Weight 5.00 7.80

10.00 77.20

Rua Cleaner P i l o t Formula #CPT-003-01

% by Weiqht 40.09

4.04 20.11 35.76

P l a s t i c , V i n y l and Leather Cleaner P i l o t Formula #UPC-001-01

Ca loxy la te N-9 Dowanol D (PnB) Propyl ene G1 yco l B u t y l Ce l l oso l ve Water

SOURCE: P i l o t Chemical Co. : Household C1 eaner Formu

by Weight 10.10 5.02 2.56 1.13

81.19

a t i ons


Hard Surface Cleaners

Calsuds, C a l s o f t and Calamide concent ra tes can be fo rmula ted t o c r e a t e power fu l , non-corrosive, non - f i lm ing c leaners f o r f l o o r s , woodwork, w a l l s , windows, counter tops , t ubs , t i l e and s i m i l a r hard sur faces . Use l e v e l s : 1 -4 oz . /ga l . o f water.

Tub and T i l e Cleaners P i l o t Formula #APC-004-01

Water Versene 100 Calsuds A I sop ropy l Alcohol Propyl ene G1 yco l Pine O i 1

D-1 i monene Cal imul se PRS Ca loxy la te N-9 Water C a l s o f t L-40 P i l o t sxs-40 Calamide 0

Water TKPP Calsuds 81 P i l o t sxs-40

Water Ammonia (29%) Na4EDTA Bu ty l C e l l osol ve Calsuds 81

P i 1 o t Formula #HDC-006-01

Counter Top/Wall Cleaners P i l o t Formula #HDC-003-01

A l l Purpose Type

P i l o t Formula #HSC-008-01 Ammoniated T-

% bv Weiqht 65.00

1 . o o 25.00

5.00 3.00 1 .oo

?&by Wei a h t 30.00

5.00 5.00

26.50 16.50 10.00

7 . 0 0

% by Weight 77.20

7.80 5.00

10.00

% by Weiaht 86.50 3.00 0.50 5.00 5.00

SOURCE: P i lot Chemical Con : Household C1 eaner Formulat ions


Hard Surface Cleaner w/AmDhoteric

Water, 0.1. Sodium Carbonate Rewoteric AM KSF-40 Oowanol DPM Versene 100 Witconate SXS (40%)

% by Weinht 75.0

4.0 10.0 5.0 2.0 4.0

Blending Procedure:

each add i t i on .

Typi c a l Propert i es :


Viscos i ty , cps: 4 Sol ids: 10.2% pH: 10.8

Formula 507

Hard Surface Cleaner Concentrate w/d'Lilnonene

Phase I: Isopropanol Ole ic Acid Varonic K205 d ' L i monene Phase 11: Water, 0.1. Potassium Hydroxide (87%)

% by Weiciht

10.0 8.8 5.0

12.0

62.2 2.0

B1 endi ng Procedure :

I 1 ingredients and mix thoroughly. While mixing, add Phase I t o Phase 11.

Typical Propert ies: V iscos i ty , cps: 75 Sol ids: 13.8% pn: 10.2

Combine Phase I ingredients and mix thoroughly. Combine Phase

Formula 508


Hard Swface Cleaners 71

Hard-surface Cleaner Concentrate A lka l i ne All-Purpose Cleaner Concentrate

Inaredi ent : Deionized Water Sodium Hydroxide (50%) Tetrapotassium Pyrophosphate Sodium Metas i l i ca te Pentahydrate Avanel S-150 Sodium Cumene Sul fonate (40%)

Wt.% 76.00

2.00 12.00 1 .oo 6.00 3.00

pH (as i s ) : 10.5-11.5 Appearance: Clear, l i gh t - ye l l ow l i q u i d Spec i f i c Grav i ty : 1.13

Procedure: Charge the water t o an appropr iate mixing vessel and s t a r t

a a i t a t i o n . I n t h e sequence l i s t e d above, charge the remaining ingredients and mix u n t i l t he so lu t i on i s c lea r . Notes :

This i s a hard-surface cleaner concentrate which i s on many d i f f e r e n t s o i l s and surfaces. For concrete sur use "as i s . " For wal ls , f l o o r s , and other surfaces, d i 1O:l w i t h water. Formula CH-101

Household Hard-surface Cleaner All-Purpose A l k a l i n e Cleaner f o r Sponge o r Spray Apt

Inaredi ent : Deionized Water Sodium Laureth (3) Sul fa te Mazamide 00 Tetrapotassium Pyrophosphate Sodium Metas i l i ca te Pentahydrate Macol 40 Deionized Water, Dye, e tc .

pH (as i s ) : 12.0-13.0 Appearance: Clear, water-white l i q u i d (wi thout dye) Spec i f i c Grav i ty : 1.01

Procedure:

e f f e c t i ve aces, u te

I i ca t i on

Wt.% 80 .00

2.50 0.50 1 .oo 2.00 4.00

Q.S.

Charge the f i r s t p o r t i o n o f water t o a mixing vessel and s t a r t a g i t a t i o n . I f product i s t o be colored, d i sso l ve dye i n the reserved p o r t i o n o f the water i n a separate vessel. Charge a l l remaining ingredients , i nc lud ing t h e dye so lut ion, t o t h e mixing vessel and mix u n t i l c l ea r . Notes :

cleaner. The product may be used w i th a sponge o r may be used i n a spray b o t t l e . Formula CH-102


This formulat ion i s designed as a general purpose household


Hiah-Performance. Hard-surface Cleaners Formula HS-0035

Component

Water Sodi um Metasi 1 i cate

Miranol FBS A1 codet HSC-1 000 Cheelox BF-13 Rhodafac RA-600 Butoxyethanol

Pentahydrate

6 . 0

Solvent-Free Solvent-Free Non-Phosphate Phosphate

IYPe IYIzz Wt.% Wt.% 88.0 87.0

2.0 2.0 3.0 1 . o 4.0 4.0 3.0 3.0 - 3 .0

- -

Heavy-Duty Solvent

TYDe Wt.% 85.0

2 .0 2 . 0 3 .0 2.0 -

Procedu r e

Physical ProDert ies

Blend ingredients i n order l i s t e d and mix u n t i l uniform.

Appearance Clear, l i g h t yel low l i q u i d pH, as i s 12.6 11.5 12.55 V iscos i t y <I0 cps Speci f i c Grav i t y 0.978 1.013 1.016

<I0 cps <10 cps

Econoai c a l P i ne O i 1 Hard-surface C1 eaner Formula HS-0037

Component Pine O i l Rhodasurf 0C-840 Water

Wt.% 5 . 0

10 .0 8 5 . 0

Procedu r e 1 . Add Rhodasurf BC-840 t o p ine o i l . Mix w e l l . Heat t o approx-

imate ly 35-40C t o ob ta in homogeneous so lu t i on . 2. Add water and mix thoroughly.

Physical Prooer t ies Appearance: Clear, water-white l i q u i d pH. as i s : 3.08 Spec i f i c Grav i ty : 0.99 V iscos i t y : <10 cps



M i l d Abras ive Hard Sur face Cleaner A m i l d abras ive c leaner f o r consumer use. E f f e c t i v e on

S t a i n l e s s S t e e l , Po rce la in and o the r hard sur faces .

P a r t : I n q r e d i e n t s : A Dei on i zed Water

C a l c i t e ( t100 mesh) Mazox LDA Potass i um C i t r a t e

B C a l s o f t F-90 Deionized Water

Appearance: White pas ty 1 i qu i d p H (as i s ) : 7.0-8.0 S p e c i f i c G r a v i t y : 1.47

Procedure:

charge t h e water and s t a r t a g i t a t i o n . Do no t i n t o t h e p roduc t . Slowly add t h e C a l c i t e f o l Mazox LDA and t h e Potassium C i t r a t e .

To a m ix ing vessel w i t h sweep and scrape

Wt.% 30.00 50.00

6.70 1 .oo

3.30 9 .00

ype a g i t a t i o n , mix a i r owed by t h e

I n a separate vesse l , d i s s o l v e t h e C a l s o f t F-90 i n t h e remaining water. When comple te ly d i sso l ved , add t h e f i r s t p a r t o f t h e mix. Again avo id m ix ing excess a i r i n t o t h e system.

Notes :

I t i s a m i l d abras ive hard su r face c leaner e f f e c t i v e aga ins t mast common s o i l s . I t can be used on s t a i n l e s s s t e e l , p o r c e l a i n and o the r hard surfaces.

I n t h e manufacture o f t h i s p roduc t , ca re should be taken t o avo id m ix ing a i r i n t o t h e f i n i s h e d p roduc t . Being a pas ty l i q u i d , once a i r i s en t ra ined i n t o t h e system, i t i s d i f f i c u l t and t i m e consuming t o remove.

SOURCE: Mazer Chemicals: Formula t ion CH-109

Th is f o r m u l a t i o n i s designed t o be used as i s by t h e consumer.


Non-Phosphate Household Hard-surface Cleaner All-Purpose A l k a l i n e Cleaner f o r Sponge or Spray App l i ca t i on

Inaredi ent : INt.% Dei oni zed Water 79.75 Sodi um Laureth Su l fa te 2.50 Mazamide 80 0.50 Sodi um C i t r a t e 1.25

Macol 40 4.00 Sodium Metas i l i ca te Pentahydrate 2.00

Deionized Water, Dye, e t c . a .s . pH (as i s ) : 12.0-13.0 Appearance: Clear, water-white l i q u i d (wi thout dye) Spec i f i c Grav i ty : 1 . O l

Procedure: Charge the f i r s t p o r t i o n o f water t o a mixing vessel and

s t a r t a g i t a t i o n . I f product i s t o be colored, add the dye t o reserved p o r t i o n o f t he water i n a separate vessel. Charge a l l remaining ingredients , i nc lud ing the dye so lut ion, t o the mixing vessel and mix u n t i l c l ea r . Notes :

This formulat ion i s a non-phosphate version o f formulat ion CH-102. This formulat ion i s designed as a general purpose household c leaner. The product may be used w i t h a sponge or may be used i n a spray vessel. Formula CH-106

Won-Phosphate Concentrated Household Hard-surface Cleaner Concentrated Pine O i l All-Purpose Cleaner

Inqredi ent : Wt.% Dei oni zed Water 78.05 Macol TD-12 5.00 Macol TD-3 2.50 Mazamide 00 0.50 Macol 40 4.50 Pine O i 1 0.20 Sodi um C i t r a t e 3.75 Sodium Metas i l i ca te Pentahydrate 2.00 Sodium Xylene Sul fonate (40%) 3.50

pH (as i s ) : 12.5-13.5 Appearance: Clear, l i g h t yel low l i q u i d Spec i f i c Grav i ty : 1.02

Procedure: Charge the water t o a mixing vessel and s t a r t a g i t a t i o n .

Charge the Macol TD-12, Macol TD-3, Mazamide 80 and Macol 48 and cont inue a g i t a t i o n . Charge the Pine O i l and mix 5 minutes. Charge the remaining ingredients and mix u n t i l c l ea r and f r e e o f "f i sh eyes. I' Notes :

This formulat ion i s a non-phosphate version o f formulat ion CH-103. This i s a concentrated household hard-surface cleaner designed t o be used a t a d i l u t i o n o f 1-3 ounces per ga l lon. Formula CH-107



P i n e O i l C leaner C o n c e n t r a t e

~~ I n g r e d i en.Lsl P i n e 01 I N i n o l 11-CM Makon 12 Ammonyx LO

I s o p r o p a n o l Water, D.I.

B i o - S o f t S-100

% by W t . 20.0

9.0 5 . 0 0 . 5 2 . 0

10 .0 53.5

M i x i n g P rocedure :

w a t e r s l o w l y w h i l e under a g i t a t i o n . M i x u n t i l c l e a r .

P r o p e r t i e s :

Combine p i n e o i l , s u r f a c t a n t s and IPA. M ix u n t i l c l e a r . Add

Appearance: C l e a r y e l l o w l i q u i d Odor: P i n e V i s c o s i t y C 25C, c p s : 50 pH ( a s i s ) : 8 . 1 D e n s i t y l b s / g a l : 8 . 0 6 Freeze/Thaw ( 3 c y c l e s ) : Pass 50C oven ( 1 week): Pass

Use I n s t r u c t i o n s : D i l u t e 1-2 ozs i n t o one g a l l o n

Per formance: Gardner S t r a i g h t L i n e W a s h a b i l i t y T e s t :

Above f o r m u l a t i o n : 73.0% s o i l removed f r o m t i l e s Commercial p r o d u c t : 55.5% s o i l removed f r o m t i l e s

SOURCE: Stepan Co.: F o r m u l a t i o n No. 208

L i q u i d Super C o n c e n t r a t e

%_by Wei ght Water, D . I . 30.0 T e t r a p o t a s s i u m Pyrophosphate (60%) 25.0 B u t y l C e l l o s o l v e 5 .0 W i t c o n a t e SXS L i q u i d 10 .0 Varamide A-83 30.0

B l e n d i n g Procedure:

each add1 t i on.

T y p i c a l P r o p e r t i e s : S o l i d s : 49.0%

SOURCE: W i t c o Corp. : Formula 502

Add i n g r e d i e n t s i n o r d e r shown and d i s s o l v e c o m p l e t e l y between

8. Laundry Products

76

Anionic/Nonionic Heavy-Duty Laundry Deteraent Formula LY-0042

Water Ca lso f t F-90 Rhodasurf 25-7 Rhodacal A-246/L Sodi um C i t r a t e Br ightener Fragrance Dye

Wt.% 63

5 7

15 10

Q.S. Q.S. Q . S .

Procedu rg

a g i t a t i o n . Then, add Rhodasurf A-246/L and Calsof t F-90. Begin coo l i ng and add remaining ingredients s ing l y , w i t h a g i t a t i o n t o ob ta in uni form mixture, before making next add i t i on .

Phveical ProDert 1 ea Appearance: C1 ear 1 i quid, dyed t o preference pH. as i s : 7.4 Spec i f i c Grav i ty : 1.09 V iscos i t y : 200 cps

Heat water t o 60C. Add Rhodasurf 25-7 s lowly, w i t h moderate


Par t A Water Na C i t r a t e Calsof t F-90 l!artJ! Rhodasurf 25-7 MEA sxs Par t C Colorant Perfume Water Procedu rg

Dissolve Sodi um C i t r a t e add Ca lso f t F-90. Mix Part "B" . Add co lorant , perfume

Phvs f ca 1 Prooer t ies pH: 11.0 pH (1% Solut ion) : 9.50 Spec i f i c Grav i ty : 1.120 V iscos i t y : 75 cps

30.0 8 . 0

17.0

8 . 0 2.0 6.0

0.02-1 0.1-0.5

Q . S .

i n water by s t i r r i n g a t 45-50C and

and water. Adjust pH t o 11.0. i n the order l i s t e d . Add "A" t o llgll


Laundry Products 77



Par t A Water Na C i t r a t e Calsof t F-90

P a r t B Rhodasurf 25-7 MEA sxs

Part C Colorant Perfume Water

Wt.% 30.0 8.0 17.0

8 . 0 2.0 6 . 0

0.02-1 0.1- 0.5

Q . S .

Procedure Dissolve sodium c i t r a t e i n water by s t i r r i n g a t 45C-5OC.

add Ca lso f t F-90. Mix Part "B" i n the order l i s t e d . Add "A" t o "8" . Add co lorant , perfume and water. Adjust pH t o 11.0.

Nonionic/Amphoteric Heavy-Duty Laundry L i q u i d Formula LY-0045

Water G1 ycosi des Miranol FBS MEA Colorant Perf ume '

Wt.% Q.S.

20.0 7 . 0 2 . 0

0.02-1 0.1 -0.5

Procedure

each add i t i on . Adjust pH t o 11.0. Add the ingredients i n the order l i s t e d . M i x wel l a f t e r

Phvsi c a l P r o m r t i eg pH: 11.0 pH (1% Solut ion) : 9.50 Spec i f i c Grav i ty : 1 .lo0 Viscos i ty : 300 cps


Cold Water Deterpent JFor W o o l and De l i ca te Fabr ics)

Formula LY-0040

Water Miranol CS Conc. Rhodapex ES-2 A1 kami de DC-212 Fluorescent Whitening Agent

Wt.% 55.9 10.0 30.0

4 . 0 0.1

Procedu r Q

c l e a r .

Phvsi c a l Proner t i 8s

Add ingredients i n order l i s t e d . Heat t o 50C and mix u n t i l

Appearance: Clear, yel low l i q u i d pH. as i s : 8.16 Spec i f i c Grav i ty : 1.02 V iscos i t y : 700 cps

F i ne Fabr ic Deterpent Formula LY-0041

Rhodacal DS-10 Sodium Hexametaphosphate Sodium Bicarbonate Opt ica l Br ightener

Wt.% 32.0 30.0 38.0

P.S.

Procedu re

t o t h e blender. Mix f i v e minutes. Add the Rhodacal DS-10 w i t h mixing. Add the o p t i c a l br ightener w i t h mixing. Mix u n t i l uniform.

Phvaical Prooer t i e s

Add the sodium bicarbonate and the sodium hexametaphosphate

Appearance: White, f ree- f lowing powder pH, 1% Solut ion: 8.5


Laundry Products 79


Deteraent f o r Colored Fabr ics . Powder, Spray M ix inQ Process-A

Spray Mix : M a r l i p a l 24/939 o r 013/939 Fragrance O p t i c a l b r i g h t e n e r

B u i l d e r Mix : Z e o l i t e A Sodium m e t a s i l i c a t e pen tahyd r i t e Sodium carbonate, dehydrated Carboxymethyl c e l l u lose Po lycarboxy la te , e.g. Sokalan CP 5 powder Sodi um s u l phate 1 i gh t


% 10.0 0.2 0 . 2

35.0 5 . 0

15.0 2.0 4.0

t o 100

Detergent f o r Colored Fabr ics, Powder, Spray M j x i n ~ Pro_cess-B

Spray M i x : M a r l i p a l 24/30 Marl i p a l 24/90 Fragrance O p t i c a l b r i gh tener

B u i l d e r Mix : Marlon ARL Z e o l i t e A Sodium soap powder Sodium m e t a s i l i c a t e pentahydrate Sodium carbonate, dehydrated Po lycarboxy la te , e.g. Sokalan CP 5 powder P o l y v i n y l p y r r o l i d o n e , e.g. Sokalan HP 50 Sodium su lphate l i g h t

% 2.0 4.0 0 . 2 0 . 2

10.0 40.0

4 .0 5.0

15.0 4 . 0 2 . 0

t o 100



Detergent for Cur ta ins , Medium V i s c o s i t v - A

% M a r l i n a t DFK 30 20.0 Marl i pa l 24/70 15.0 Coconut f a t t y ac id , potassium s a l t 5.0 Ethylenedi ami ne t e t r a a c e t a t e 40 0.2 Balance water, f ragrance, d y e s t u f f , o p t i c a l b r i gh tener ,

p reserva t i ve t o 100


Detergent f o r Cur ta ins , Medium V iscos i t v -8

% Marlon PS 65 10.0 Marlox M 606/1 15.0 Ethylenediamine t e t r a a c e t a t e 40 0.2 Balance water, f ragrance, dyes tu f f , o p t i c a l b r i gh tener , p rese rva t i ve t o 100


Manual -Wash Detergent, Foaming Medi um V i scos i t y - A

% Marlon PS 65 10.0 M a r l i p a l 013/70 15.0 Marlamid DF 1218 2.5 Na cumene sulphonate, 40% 1 .o Ethanol * 1.5 Balance water, f ragrance, dyes tu f f , p reserva t ive ,



Manual-Wash Detergent. Foaming Medium V iscos i ty -B

%

Marl i na t 242/28 12.0


Marlon A 365 18.5

Balance water, f ragrance, d y e s t u f f , p rese rva t i ve ,


SOURCE: Huls America, I nc . : Basic Formulat ions o f Detergents and Cleaning Agents f o r Household Purposes

Laundry Products 81


Detergent f o r F ine Fabr ics-1 L i q u i d

I n red ien ts : i ? F a t t y a c i d (Cocos + Olein. P r i f a c 7976)

KOH (85%) H20 (40-50C)

B Hostapur SAS 60 Genapol ZRO l i q u i d Genapol UD-080

3.00% 0.60% 41.90%

23.30% 25.00%

6.00%

C C i t r i c a c i d x 1H20 0.20%

Manufactur ing: I One a f t e r another, t h e components o f B a re added t o A . I 1 A t l a s t C i s added.

Deteraent f o r F ine Fabr ics-2

m r e d i e n t s : A F a t t y a c i d (Cocos + O le in , P r i f a c 7976) 4.00%

KOH (85%) 0 . 8 0 % H20 (40-5OC) 63.00%

8 Hostapur SAS 60 Genapol UO-080

a. 00% 24.00%

C C i t r i c a c i d x 1H20 0.20%

Manufactur ing: I One a f t e r another, t h e components o f B a re added t o A. I 1 A t l a s t C i s added.

SOURCE: Hoechst Ak t i engese l l scha f t : Detergents and Cleaning Agents: Guide Formulat ions

Laundry Products 83

Enzymatic Heavy-Duty Laundry Deteraent Formula LY-0046

P a r t A Water C i t r a t e C a l s o f t F-90 P a r t Rhodasurf 25-7 M EA TEA sxs Rhodapex NA 61 P a r t C Na Formate Calcium Ch lo r ide Enzymes Co loran t Perfume Water

Wt.% 10.0

5.0 8.0

6.0 2.0 2.0 3.0 8.0

1.2 0.2 0.4

0.02-1 0.1 - 0 . 8

Q.S.

Procedure

C a l s o f t F-90. Mix Par t "B" i n t h e o r e r l i s t e d . Add "A" t o "B". Add sodium formate and ca lc ium chlOP & e. Cool t o room temper- a tu re . Add t h e enzymes. Add co lo raa t , perfume and water. Ad jus t pH t o 10.0. Phvsi c a l P r o o e r t i

pH: 10.0 pH (1% S o l u t i o n ) : 8.8 Speci f i c G r a v i t y : 1 . l o 0 V i s c o s i t y : 100 cps

D isso lve sodium c i t r a t e i n water by s t i r r i n g a t 45-5OC. add

Won-Phosphate Laundry Powder Formula LY-0048

Sodium Carbonate Igepa l CO-630 Sodi um S i 1 i ca te Sodium S u l f a t e Carboxymethyl c e l l u l ose O p t i c a l Br igh tener

Wt.% 50.0 12.0 12.0 24.5

1 .o 0 .5

Procedu r g Add t h e sodium carbonate t o t h e mixer . Spray t h e Igepa l

02-630 on to t h e sodium carbonate. Add t h e remaining i ng red ien ts i n t h e order l i s t e d . Mix u n t i l a homogeneous, f r e e - f l o w i n g product r e s u l t s . Phvsi c a l P r o m r t 1 os

Appearance: White, f r e e - f l o w i n g powder pH, 1% So lu t i on : 11.0

SOURCE: Rhone-Poulrnc Sur fac tan ta & S p e c i a l t i e s : Formulas


Fabr i c Pretreatment S p r i t z

I ng red ien ts : Neodol 25-7 Neodol 25-3 Versa f lex 207 (25%) Sodium Xylene Su l fona te (40%) EDTA, Disodium S a l t Water, Dye, Perfume, and Enzymes

Procedure: 1. Mix me l ted Neodol 25-7 and Neodol 25-3. 2. Add sodium xylene su l fona te and mix. 3. Add water and Versa f lex 207, mix, and coo l . 4. Add EDTA. dye, perfume, and enzymes.

Reference #8069:21

Low VOC Pump F a b r i c Antist-

I ns red ien ts : Versaf 1 ex 2004 (30%) Ethanol Propyl ene G1 yco l Preserva t ive , Water, and Fragrance

9.75 5.25

20.00 15.00

0.50 4.s.

%%. 5.00

10.00 0.50

Q . S .

Procedure: 1. Mix Versa f lex 2004 and water. 2. Add ethanol and mix. 3. Add p ropy l ene g l y c o l , p rese rva t i ve , and fragrance. and mix.

Reference #8069:97

SOURCE: Nat iona l S t rach and Chemical Corp.: Suggested Formula- t i o n s

Laundrv Pre-Spotter and S t a i n Remover

Water Sodium Meta S i l i c a t e (Anhydrous) Detergent Concentrate 840

% by Weiaht 83.0

2.0 15.0

Procedure:

p rese rva t i ve as requ i red.

SOURCE: Mona I n d u s t r i e s , I nc . : Suggested Formulat ion

Blend i n g r e d i e n t s i n o rder l i s t e d . Add c o l o r , f ragrance and

Fabr i c Softener-1

Ing red ien ts : A H20 (50-6OC)

B Prapagen WK

C MgC12 (10% b . w . )

D Perfume Dye

ad 100.00%

6.70%

0.10%

0.20% q . s .

Fabr i c Softener-2

Ing red ien ts : A Genamin S-250

H3P04 (1 M; 9,5% b . w . ) H 2 0 (50-60C)

8 Prapagen WK

C MgClP (10% b . w . )

D Perfume Dye

Fabr i c Softener-3

Inq red ien ts : A Genamin 5-250 0.90%

H3P04 (1 M; 9,5% b . w . ) 0.45% H20 (50-6OC) ad 100.00%

8 Prapagen WK 13.80% Po lyg l yko l 400 3.70%

C MgClZ (10% b . w . 1 1 .OO%

0 Perfume 0.60% Dye q . s .

Manufactur ing: I One a f t e r another, t h e components o f B are added t o A. I 1 A t 40C, a d j u s t t h e v i s c o s i t y w i t h C (ca. 100-150 mPas). I11 A t 30C the-components o f D a re added.

Appl i c a t i on :

SOURCE: Hoechst Ak t i engese l l scha f t : Detergents and C

1.0-2.0 g a c t i v e i ng red ien t / kg t e x t i l e


2.00% 1.00%

ad 100.00%

17.30%

3.00%

0.60% Q . S .

eani ng

Laundry Products 85

86 Advanced Cleaning Product Formulatiom

Fabr ic Softener. Low V i scosi tv-A

Mar losof t IQ 90 Balance water, fragrance, dyestuf f


Fabr ic Softener. Low V i scosi ty-B

Marlosoft IQ 90 Balance water, fragrance, dyes tu f f


% 5 . 6

t o 100

% 8.3

t o 100

Fabr ic Softener Concentrate. Low Viscosity-A

Marlosoft IQ 90 Calcium chlor ide, 25% (approx.) Balance water, fragrance, dyes tu f f

Act ive matter: 10.0% Formulation A : double concentrate

% 11.1 0.1

t o 100

Fabr ic Softener Concentrate. Low Viscosi ty-B

Mar losof t IQ 90 Calcium ch lo r i de , 25% (approx.) Balance water, fragrance, dyes tu f f

% 16.7

1.1 t o 100

Act ive matter: 15.0% Formulation 8: t r i p l e concentrate


Heavy-dutv Detergent, Powder, SDrav Y i x i n a Process-A

Spray Mix: M a r l i p a l 24/70 o r 013/70 O p t i c a l b r i gh tener Ethylenediamine te t raace ta te . 40% Fragrance

% 4.0 0.2 0 . 8 0.2

B u i l d e r M i x : Marlon ARL Sodium soap powder Z e o l i t e A Sodium m e t a s i l i c a t e pentahydrate Sodium perbora te te t rahyd ra te Te t raace ty l e thy lened i ami ne (TAED) Sodium carbonate Polycarboxylate, e.g. Sokalan CP 5 Carboxymethyl c e l l u l o s e Sodium sulphate l i g h t , enzymes


powder

8 . 0 2.8

25.0 5.0

20.0 3.0

10.0 4.0 1 .o

t o 100

Heavy-Duty Detergent. Powder, Soray M ix ing Process-8

Spray Mix: M a r l i p a l 24/70 o r 013/70 O p t i c a l b r i gh tener Ethylenediamine te t raace ta te , 40% Fragrance

% 4.0 0.2 0 . 8 0.2

B u i l d e r Mix: Marlon ARL Sodium soap powder Sodium t r i polyphosphate Sodium d i s i l i c a t e Sodi um perbora te te t rahyd ra te Tetraacetyethylenediamine (TAED) Carboxymethyl c e l l u l o s e Sodium sulphate l i g h t , enzymes

8 . 0 3.0

30.0 9.0

20.0 3.0 1 .o

t o 100


SOURCE: Huls America, I n c . : Basic Formulat ions o f Detergents and Cleaning Agents f o r Household Purposes

Laundry Products 87


Heavy-Duty Deteraent. Powder. Sprav Mix ing Process-A

Spray Mix: Mar l i pa l 013/939 o r 24/939 Fragrance Ethylenediamine te t raacetate. 40% Opt ica l br ightener

Bui lder Mix: Z e o l i t e A Sodium metas i l i ca te pentahydrate Magnesi um s i l i cate Sodium perborate te t rahydrate Tetraacetylethylenedi ami ne (TAED) Sodi um carbonate Carboxymethyl c e l l u l o s e Sodium sulphate l i g h t , enzymes


E! 10.0 0.2 1 .o 0.2

30.0 5.0 1 .o

25.0 3.0

15.0 1.5

t o 100

Heavy-Duty Deteraent. Powder. Sprav Mix ing Process-8

Spray Mix: Mar l i pa l 013/939 o r 24/939 Fragrance Opt ica l br ightener

Bui lder Mix: Sodium tr ipolyphosphate Sodi um d i s i 1 i cate Magnesi um s i 1 i cate Sodium perborate te t rahydrate Tetraacetylethylenediamine (TAED) Carboxymethyl c e l l u l o s e Sodium sulphate l i g h t , enzymes


E! 10.0 0.2 0.2

28.0 5.0 1 .o

25.0 3.0 1 .o

t o 100

L i a u i d Heavy-Duty Deteraent. B u i l t Tvoe. Hieh Viscosi ty-A

% Marlon PS 65 10.0 Mar l i pa l 013/30 5.0 1,2-Propylene g l y c o l * 5.0 C i t r i c ac id 2.0 Z e o l i t e A, 50% s l u r r y 45.0 Balance water, fragrance, dyestuf f , o p t i c a l br ightener , enzymes, preservat ive t o 100

Act ive matter: 11.5% + f u r t h e r products o f Huls AG

SOURCE: Hula America, I nc . : Basic Formulations o f Detergents and Cleaning Agents f o r Household Purposes

Heavy D u t y L i a u i d Laundry Deterqent Type DN

I n q r e d i en ts : Stepan B i o S o f t D-62 ( a n i o n i c s u r f a c t a n t ) Neodol 25-7 (non ion i c s u r f a c t a n t ) Propyl ene g l y c o l E t h y l a l coho l Sodium C i t r a t e (Haarman & Reimer) Sodium xy lene s u l f o n a t e Sodium bo ra te (borax) T r i ethanol ami ne (TEA) o r sodi um hydrox ide

Par t s by Weiqht 7.0

16.0 7 .0 5.0 5.0

10 .0 1 . o

t o pH 9 .5

D isso lve the Sodium C i t r a t e and sodium bo ra te i n approxim- a t e l y 20 m l water. Apply heat i f necessary t o d i s s o l v e . Combine t h e s u r f a c t a n t s , p ropy lene g l y c o l and e t h y l a l c o h o l . Add t h e Sodium C i t r a t e and sodium bo ra te s o l u t i o n t o t h e s u r f a c t a n t s m ix tu re . Add t h e sodium xy lene s u l f o n a t e . Ad jus t t h e pH t o 9 .5 us ing TEA o r d i l u t e sodium hydroxide. B r i n g t h e volume o f t h e m i x t u r e t o 100 m l us ing water.

I f an enzyme detergent i s des i red , t h e f o l l o w i n g should be added :

Sodium bo ra te (borax) add an a d d i t i o n a l 2 .0 Calcium c h l o r i d e 0.1 Protease 0 . 6 D isso lve t h e Sodium C i t r a t e , sodium bo ra te and ca lc ium ch lo -

r i d e i n water . Apply heat i f necessary t o d i s s o l v e . Combine the s u r f a c t a n t s , p ropy lene g l y c o l and e t h y l a l c o h o l . Add t h e Sodium C i t r a t e , sodium bo ra te and ca lc ium c h l o r i d e s o l u t i o n t o t h i s m ix tu re . Add sodium xy lene su l fona te . Ad jus t t h e pH t o 8.0 w i t h TEA o r d i l u t e sodium hydroxide. Add t h e Protease. B r i n g t h e volume o f t h e m ix tu re t o 100 m l us ing water .

The a d d i t i o n o f f ragrance, dye, o p t i c a l b r i gh tener , a n t i - r e d e p o s i t i o n agent, cor ros ium i n h i b i t o r , e t c . , i s o p t i o n a l .

SOURCE: Haarman & Reimer Corp.: Suggested Formula t ion

B u i l t Formula t ion #1

I n a r e d i en t : Water Na3NTA Na Gluconate 45% KOH 42 S i l i c a t e N G lyco l Ether Non i on i c Sur f a c t an t Amphoteric

Weight .% 68% -

1% 1%

10% 10% 5% 2% '

3%

Both t h e Amphoteric SC and t h e compe t i t i ve im idazo l i ne coupled t h e f o r m u l a t i o n together w i t h 3% o f amphoteric.

SOURCE: Tomah Products, I n c . : Suggested Formul t ion

Laundry Products 89


I nq red Neodol Neodol

Heavy Duty L i q u i d Laundry Detergent Type TA

i en ts : 25-7 (non ion i c s u r f a c t a n t ) 25-35 ( a n i o n i c s u r f a c t a n t )

Sodium l a u r y l s u l f a t e ( a n i o n i c s u r f a c t a n t ) Stepan B i o S o f t D-62 (LAS-anionic s u r f a c t a n t ) T r i ethanolami ne (TEA) Propylene g l y c o l Potassium C i t r a t e (Haarman & Reimer Corp.) E thy l a l coho l Calcium c h l o r i d e Sodium bo ra te (borax) Protease Water q .s

Pa r t s I

t o

a L ! W s h t 5.0

10.0 12.0 8.0 5.0 7.0 6.0 7.0 0 . 1 3 .0 0.6

100 p a r t s

D isso lve the Potassium C i t r a t e , ca lc ium c h l o r de and sodium bo ra te i n approximately 20 m l water. Apply heat f necessary t o d i s s o l v e . Combine t h e su r fac tan ts , TEA, propy ene g l y c o l and e t h y l a l c o h o l . Add t h e Potassium C i t r a t e , ca lc ium c h l o r i d e and sodium bo ra te s o l u t i o n . Ad jus t t h e pH of t h e s o l u t i o n t o 8 . 0 w i t h TEA o r d i l u t e sodium hydrox ide . Add t h e Protease. B r i n g t h e volume o f t h e m ix tu re t o 100 m l us ing water .

The a d d i t i o n o f f ragrance, dye, o p t i c a l b r i g h t e n e r , a n t i - redepos i t i on agent, co r ros ion agent, co r ros ion i n h i b i t o r , e t c . , i s o p t i o n a l .

SOURCE: Haarman & Reimer Corp.: Suggested Formula t ion

!&M d Laundry_ D_etergents

I n Q red j.=ts: Water Glucopon 6OOCSUP (50%) E t hano 1 Tryco l 5963

I n redients.; i a F e r Sodi um C i t r a t e Su l fo tex SXS Glucopon 6OOCSUP (50%) Ethanol S u l f o t e x 6040 S (59%)

We 1 g h t% 72 10

3 15

Weight% 32

5 5

15 5

38

Add i n t h e order l i s t e d , d i s s o l v i n g each i n g r e d i e n t com- p l e t e l y . Use moderate a g i t a t i o n and inco rpo ra te c o l o r s and f ragrances as requ i red .

SOURCE: Henkel Corp.: CD D i v i s i o n : Glucopon Sur fac tan ts : Suggested Formulat ions

Heavv Dutv L i q u i d Laundry Deterqent Type WA

I n a r e d i en ts : _ _ Pa r t s by Weiaht Stepan B i o S o f t D-62 (LAS-anionic s u r f a c t a n t ) 28.0 Neodol 25-7 (non ion i c s u r f a c t a n t ) 7 . 0 Sodium xylene s u l f o n a t e 12.0 T r i ethanolami ne (TEA) 2 .0 Sodium C i t r a t e (Haarman & Reimer Corp . ) 12.0 Water 9 , s . t o 100 p a r t s

D isso lve Sodium C i t r a t e i n approximately 20 m l water. Combine t h e su r fac tan ts , sodium xylene s u l f o n a t e and TEA. Add t h e Sodium C i t r a t e . Ad jus t t h e pH o f t h e s o l u t i o n t o 11 us ing d i l u t e sodium hydrox ide . B r i n g the volume o f t h e m ix tu re t o 100 m l us ing water.

added : I f an enzyme detergent i s des i red , t h e f o l l o w i n g should be

Sodi um bo ra te (borax) 3 . 0 Cal c i um c h l o r i d e 0.1 Propylene g l y c o l 7 . 0 Protease 0 .6 D isso lve t h e sodium bora te , ca lc ium c h l o r i d e and Sodium i

C i t r a t e water. Apply heat i f necessary t o d i s s o l v e . Combine t h e s u r f s t a n t s , sodium xylene su l fona te , TEA and propylene g l y c o l . Add t h e sodium bora te , Sodium C i t r a t e and ca lc ium c h l o r i d e s o l u t i o n t o t h i s m ix tu re . Ad jus t t h e pH t o 8 . 0 w i t h TEA o r d i l u t e sodium hydrox ide . Add t h e Protease. B r i n g t h e volume o f t h e m ix tu re t o 100 m l us ing water.

r e d e p o s i t i o n agent, co r ros ion i n h i b i t o r , e t c . , i s o p t i o n a l .

SOURCE: Haarman & Reimer Corp.: Suggested Formulat ion

The a d d i t i o n of f ragrance, dye, o p t i c a l b r i gh tener , a n t i -

B u i l t Formula t ion #2

I n a r e d i e n t : Water Na M e t a s i l i c a t e pentahydrate STPP Nonionic s u r f a c t a n t Amphoteric s u r f a c t a n t

Weight .% 7 9%

1% 10% 5% 5%

Both t h e Amphoteric SC and t h e compe t i t i ve amphoteric coupled t h e f o r m u l a t i o n together w i t h 5% o f amphoteric.

SOURCE: Tomah Products, I n c . : Suggested Formulat ion

Laundry Products 91

92 Advanced CIeaning Roduct Formulations

L i aui d Heavv-Duty Detergent. Low V i scosi t v - A

Marlon PS 65 Marl i pal 01 3/89 Caustic potash, 50% (approx.)* Coconut f a t t y a c i d T r i ethhnol ami ne R* 1.2-Propylene g l yco l * Ethanol * Phosphonate, e.g. Dequest 2060 S Sodi um formi ate* Balance water, fragrance, dyestuf f , enzymes, preservat ive


% 20.0 17.2 3.9

10.0 5.0 3.0 8.0 1.5 1 . o

o p t i c a l br ightener , t o 100

L i a u i d Heavy-Dutv Detergent. Low Viscosi tv-B

s6 Marlon PS 65 20.0 Mar l i pa l 013/129 3.9 Marlox FK 64 12.0 Caustic potash, 50% (approx.)* 3.9 Coconut f a t t y ac id 10 .0 Triethanolamine R* 5.0 1,P-Propyl ene g l yco l * 3.0 Ethanol * 8.0 Phosphonate, e.g. Dequest 2060s 1.5 Sodi urn formi ate* 1 .o Balance water, fragrance, dyes tu f f , o p t i c a l br ightener ,

enzymes, preservat ive t o 100


L i a u i d Heavy-Duty Deteraent. B u i l t Type. H i g h Viscosi tv-B

%

Marl i pa l 01 3/30 5.0 C i t r i c ac id 1 . o Z e o l i t e A, 50% s l u r r y 45.0 Balance water, fragrance, dyestuf f , o p t i c a l br ightener , enzymes, preservat ive t o 100

Marlon PS 65 10.0


* f u r t h e r products o f Huls AG


L igh t -Duty Deterqent. Powder. Spray M i x i n q Process-A

Spray Mix : M a r l i p a l 013/939 o r 24/939 Marlamid DF 1218 Fragrance

% 5.0 1.0 0 . 2

B u i l d e r Mix : Z e o l i t e A Sodi um d i s i 1 i c a t e Carboxymethyl c e l l u lose Sodium su lphate l i g h t

Post Mix: Marlon ARL


40.0 3 . 0 1 .o

34.8

15.0

L i ght-Duty Deterqent ~ Powder, Spray M i x i ng Process-€3

Spray Mix : M a r l i p a l 013/939 o r 24/939 Fragrance

% 3.0 0.2

B u i l d e r Mix : Z e o l i t e A Sodi u m d i s i 1 i c a t e Carboxymethyl c e l l u l o s e Sodium su lphate l i g h t

Post Mix : Marlon ARL

A c t i v e Ma t te r : 17.1%

45.0 5.0 1 . o

22.8

18.0

L i q u i d L igh t -Duty Detergent, w i t h Inco rpo ra ted Softener, Low V i scosi ty-A

Marl i p a l 24/99 Marlox FK 64 Mar loso f t I0 90 Ethanol * Balance water, f ragrance, d y e s t u f f

9b 15.0

5 . 0 5 . 0

10.0 t o 100

A c t i v e Ma t te r : 23.0% * f u r t h e r p roduc ts o f Huls AG

SOURCE: Huls America, I n c . : Bas ic Formulat ions o f Detergents and Cleaning Agents f o r Household Purposes

Laundry Products 93


L i Quid L i ght-Duty Detergent. Low V i scosi t y - A

Marlon PS 65 Marl i nat 242/28 Marlamid DF 1218 Coconut f a t t y a c i d Caustic potash, 50% (approx.)* Ethylenediamine te t raacetate, 40% Balance water, fragrance, dyestuf f , sodium ch lo r i de

Act ive matter: 23.5% Formulation A f o r machine-wash

% 20.0 12.0

3.0 4.0 1.4 0.2

preservat ive, t o 100

L i aui d L i ght-Duty Detergent, Low V i scosi ty-B

% Mar l i na t 242/28 40.0 Marlamid DF 1218 3.0 Marlamid PG 20 3.0 Balance water, fragrance, dyestuf f , preservat ive, sodium c h l o r i d e t o 100

Act ive matter: 16.2% Formulation B f o r manual-wash

L i q u i d Light-Duty Detergent, w i t h Incorporated Softener, Low V i scosi ty-B

Marl i p a l 24/99 Marlox FK 64 Ampholyt JB 130 Marlosoft I Q 90 Balance water, fragrance, dyes tu f f

% 5 . 0 5 . 0

25.0 5.0

t o 100


* f u r t h e r products o f Huls AG


Part A Igepal CO-660 Calsof t F-90 Water

I n d u s t r i a1 Laundry Two-Part Systems Formula LY-0052

Uniforms (Petroleum Greases and O i l s )

2 90

Part B Sodium S i l i c a t e (Si02/Na20 1.6-2.5) 100

Hotel / L i nen SUDD~Y (Ani ma1 and Vegetable Greaser

Part A Igepal CO-660 Calsof t F-90 Water

Par t B Potassi um Hydroxide (45%) STPP, TKPP o r KTPP

Sodium Carbonate Igapal CO-660 Sodi um Tripolyphosphate Sodium Metas i l i ca te Opt ica l B r i ghtener

t o t h mixer. S CO-660. Add t h e remaining ingredients i n t h Mix u n t i l uniform.

Wt.% 10

2 88

85 15

I n d u s t r i a l Laundry Powder Uniforms

Formula LY-0050

Procedure Add t h e sodi um carbona

Wt.% 5 2 . 5 15 20 12

0 . 5

ray on the Igepal order 1 i sted.

Phvsi c a l ProDert i 8s Appearance: White, f ree- f lowing powder pH, 1% Solut ion: 11.4


Laundry Products 95


Laundry L iau ids

Calsuds o r C a l s o f t based products remove ground- in d i r t and grease i n heavy f a b r i c s and g e n t l y c lean d e l i c a t e k n i t s i n c o l d water. They i n h i b i t s t a t i c bu i l d -up and p rov ide l u b r i c i t y , f u l l i n g and so f ten ing .

"Fine Care" Fabr i c Detergents P i l o t Formula ULDY-003-01

Calsuds CD-6 Cal foam ES-303 P i l o t SXS-40 Cal s o f t LAS-99 Water

Calsuds CD-6 Cal foam ES-303 P i l o t SXS-40 Cal s o f t LAS-99 Water C i t r i c Ac id Perfume and Color Preserva t ive

Water 50% NaOH D i ethanol ami ne Propylene Glyco l Cal s o f t LAS-99 Cal oxy l a t e N-9

Water 50% NaOH D i ethanol ami ne P i l o t SXS-40 C a l s o f t LAS-99 Cal oxy l a t e N-9

P i l o t Formula ULDL-003-01

Heavy Duty Laundry L iqu ids P i 1 o t Formula #HDL-004-01

P i l o t Formula #HDL-005-01

% bv Weipht 19.90 15.15 10.20 4.96

49.79

% by Weiqht 20.00 15.00 10.00 5.00

50.00 Q.S. pH 7

Q . S . Q.S.

% by Weiqht 36.60

6.40 7.00 5.00

40.00 5.00

% bv Weiqht 30.40

4.60 5.00

25.00 30.00

5.00

SOURCE: P i l o t Chemical Co. : Household C1 eaner Formul a t i ons

Laundry Powder Deteraent Formula LY-0047

Sodium Carbonate Ca lso f t F-90 Rhodapex NA-61 Rhodasurf 25-7 Sodium Metas i l i ca te Pentahydrate Sodi um Su l fa te Zeol i t e Sodi um Perborate Enzymes can be added Dye Perfume

Procedure Add t h e sodium carbonate t o t h e mixer.

pex NA-61 and the Rhodasurf 25-7. Add t h e i n t h e order l i s t e d and mix u n t i l uniform.

Wt.% 44.0 14.0 6.0 2.0 4.0

10.0 18 .0 2.0

Spray on the Rhoda- remai n i ng ingredients

Physical ProDerties Appearance: White, f ree- f lowing powder, dyed t o preference. pH, 1 % Solut ion: 11

I n d u s t r i a l Laundry One-Shot L i a u i d Formula LY-0049

Water Igepal CO-630 Igepal CO-710 Cheelox BF-13 Potassi urn Hydroxide (45%) Miranol FBS

Wt.% 69

3 3

10 10 5

Procedu r e

Phvsi c a l P rove r t i ea

Add t h e ingredients i n the order l i s t e d . Mix u n t i l uniform.

Appearance: Clear l i q u i d pH. as i s : 13.0 pH, 1% so lu t i on : 11.8 Spec i f i c Grav i ty : 1.06 V iscos i t y : <lo cps

SOURCE: Rhone-Poulenc Surfactants a Spec ia l t i es : Formulas

Laundry Products 97

98 Advanced Cleaning Product Formulafions

L i q u i d Heavy Duty Detergent HDLD Soap based

Ingredients : A Genapol OA-080

Fa t t y ac id (2/3 o l e i c , 1/3 COCO) KOH (85%) 1,2 Propyleneglycol

Water (50-6OC)

T r i sodi um-ci t r a t e x 2H20

Savi nase Alcalase Termamyl Parf um Farbs to f f

8 Tinopal CBS-X

C Hostapur SAS 60

D Ethanol

12.00% 14.00% 3.50% 5 .OO% 0.10%

39.40% 17.00% 5.00% 3.00% 0.50% 0.20% 0.30% 0.20% 0.10%

Manufacturing: I Dissolve 8 i n A . 11 One a f t e r another, t he components o f C are added t o I I11 A t 25C, the components o f D t o 11.

L i q u i d Detergent "FSL" A

I ngr ed i ent s I r- Genapol CIA-080 Fa t t y a c i d ( P r i f a c 7976) KOH (85%) T r i ethanolami ne 1.2 Propyleneglycol

8 Tinopal CBS-X Water (50-6OC)

C Hostapur SAS 60 T r i sodi um-ci r a t e x 2H20 Dequest 2066

D Ethanol Savi nase A1 c a l ase Termamyl Perf ume Dye

12.00% 14.00% 2.60% 2.00% 5.00% 0.20%

34.20% 17.00% 5.00% 4.00% 3.00% 0.50% 0.20% 0.30%

q . s . q.s .

Manufacturing: I Dissolve 8 i n A. I 1 One a f t e r another, t he components o f C are added t o I. I11 A t 25C, t h e components o f D t o I.

SOURCE: Hoechst Akt iengesel lschaf t : Detergents and Cleaning Agents: Guide Formulations

Thick Bleach-1 L i qu i d

Ingredients.; A Genaminox MY

Medialan LD NaOH (100%)

B Water

C Sodiumhypochlori te - s o l u t i o n (150 g/L a c t i v e c h l o r i n e )

D Perfume (e.g. Hypofresh)

Manufactur ing: I B i s added t o A. I 1 S t i r C t o I. I11 A t l a s t D i s added.

V i s c o s i t y ( B r o o k f i e l d RVT, sp.4, 22C, mPas): 4800

mgk Bleach-2

Ing red ien ts : A Genaminox MY

Medialan LD NaOH (100%)

B Water

C Sodiumhypochlori te - s o l u t i o n (150 g/L a c t i v e c h l o r i n e )

D Perfume (e.g. Hypofresh)

Manufacturing: I B i s added t o A. I 1 S t i r C t o 1. 111 A t l a s t D i s added.

V i s c o s i t y ( B r o o k f i e l d RVT, sp.4, 22C. mPas): 600

12.000% 2.500% 1 .OOO%

34.475%

50.000%

0.025%

6.000% 1.000% 1.000%

41.975%

50.000%

0.025%

SOURCE: Hoechst Ak t iengese l l scha f t : Detergents and Cleaning Agents: Guide Formulat ions

Laundry Products 99

100 Advanced Cleaning R&ct Formulotions

Wool DeterQent, Medium Viscosity-A

Marlon PS 65 Marl i nat 242/28 Marlamid DF 1218 Balance water. dyestuf f , fragrance, preservat ive.

sodium c h l o r i d e


Wool Detergent. Medium Viscosi ty-B

Marlon PS 65 Mar l i na t SRN 30 D i o n i l OC Balance water, dyestuf f , fragrance, preservat ive,

sodium ch lo r i de


Wool Detergent. Medi um V i scosi tv-A

Marlon AS3 Marl i nat 242/28 Ammonium hydroxide, 25% Urea Balance water, fragrance, dyestuf f , preservat ive. sodium c h l o r i d e


Wool Detergent. Medium Viscosi ty-B

Marlon A 375 Marl i nat 242/28 Marlamid DF 1218 Balance water, fragrance, dyestuf f , preservat ive, sodium c h l o r i d e


% 18.0 28.0

1 .o

t o 100

% 20.0 20.0

1 .o

t o 100

% 12.0 18.0 3.0 3.0

to 100

% 15.6 28.0

1 . o

t o 100


9. Metal Cleaners and Polishes

101

102 Advanced Cleoning Product Formulations

A l u m i nun C1 eaner/Br i shtener Ac id Cleaner for Aluminum Wheels and T r a i l e r s

Inq red i en t : Deionized Water Phosphoric Ac id (85%) C i t r i c Ac id (50%) N i t r i c Ac id (70%) Avanel S-70

Wt.% 83.00

6.00 8.00 1 .oo 2.00

pH (as i s ) : <2.0 Appearance: Clear, white-water l i q u i d

Charge t h e water t o an appropr ia te mix ing vesse l . Charge

WARNING: Use a l l manufacturer p recaut ionary s a f e t y meas-

Procedure:

remaining i ng red ien ts i n t h e order l i s t e d w h i l e con t inu ing a g i t a t i o n .

ures when hand1 i ng concentrated a c i d s o l u t i o n s .

Formula CM-101

A1 urni num Smut C1 eaner High Temperature D i l u t a b l e Ac id Concentrate

I n s r e d i en t : Dei on i zed Water C i t r i c Ac id (50%) Gluconic Ac id (50%) Avanel N-1525-90 Avanel S-70 Ammoni um B i f 1 u o r i de

Wt.% 19.00 50.00 25.00

3.00 1.50 1.50

pH (as i s ) : <2.0 Appearance: Clear, water-whi te t o l i g h t - y e l l o w l i q u i d S p e c i f i c G r a v i t y : 1 .18

Procedure: Charge t h e water and two ac ids under a g i t a t i o n . Continue

a g i t a t i o n and add t h e Avanel su r fac tan ts ; mix u n t i l d isso lved. Add Ammonium B i f l u o r i d e and mix u n t i l d isso lved.

Use D i r e c t i on8 :

Use temperature o f d i l u t i o n i s normal ly 140-15OF.

Notes: Th is formula was developed t o remove stamping o i l smut from

aluminum cans. Cans should be thorough ly r i n s e d a f t e r c lean ing

Formula CM-104

SOURCE: Mazer Chemicals: SUQQeSted Formulat ions

Use i n pressure wash a t a r a t e o f 2-4 ounces per ga l l on .

Metal Cleaners and Polishes 103

Alumcnum Cleaner Concentrate

Water Sodium M e t a s i l i c a t e (Anhydrous) Tetrapotassium Pyrophosphate (Powder) Mona NF-10

% by Weiqht 75 10 5

10

Procedure:

i n water w i t h mix ing , then add Mona NF-10.

Typ ica l P roper t i es : Appearance: Clear l i q u i d Cloud Po in t : 88C

D isso lve sodium m e t a s i l i c a t e and te t rapotass ium pyrophosphate

Recommended Use D i l u t i o n : 1 t o 4 oz /ga l .

Formula F-498

A1 umi num Wash

Water Sodium M e t a s i l i c a t e (Anhydrous) Tetrasodium Pyrophosphate (Powder) B u t y l Carbi t o 1 Mona NF-10

% by Weight 88

2 3 2 5

Procedure:

i n water, then add Bu ty l C a r b i t o l and Mona NF-10.

Typi c a l Proper t i es :

D isso lve sodium m e t a s i l i c a t e and te t rasod ium pyrophosphate

Appearance: C lear l i q u i d pH: 1 2 . 8

Recommended Use D i l u t i o n : 1 : lO w i t h water

Formula F-499

SOURCE: Mona I n d u s t r i e s , I n c . : Suggested Formulat ions

104 Advanced Cleaning R&t Formulations

Cleaners and Cleanina Solut ionq

Metal Cleani na-A1 k a l i ne

Inaredients : Aerosol 22 Surfactant Sodium Carbonate Sodi um Metasi 1 i cate Sodium Hydroxide

% by Weiaht 10.0 40.0 2 0 . 0 10.0

Grind the powders together and add t h e Aerosol 22 s lowly wh i l e gr ind ing.

Metal C1 eani na-Aci d

Inqredients : Dowanol EB Phosphoric Acid (85%) Aerosol 22 Surfactant Water

Metal C l eani na-Pai n t Removal

I ns red i ents: Aerosol C-61 Surfactant Sodium Carbonate Sodium Metas i l i ca te Sodi um Hydroxide

% by Wei aht 6.0 7 . 0 0 . 3

8 6 . 7

% by Wei aht 20.0 40.0 30.0 10.0

Grind t h e powders together and add t h e Aerosol C-61 slowly wh i l e mixing.

Metal Cleaning-Rust Removal

Ineredi ents: Aerosol 0s Surfactant Sodium B i f l u o r i d e Sodium Tetraphosphate Sodium B i s u l f i t e

% by Weight 10.0 7 5 . 0 10.0 15.0



Comer C l eani ng

Inaredients : Aerosol A-102 Surfactant Sodium Chlor ide C i t r i c Acid Eentoni t e Water

Aluminum Cleaning - A c i d

Inaredients : Phosphoric Acid (65%) Hydro f l uo r i c Acid (48%) Glac ia l Acet ic Acid Aerosol 0s Surfactant Water

A1 un i num C1 eani na-Bri ahteni ng

Ingredients : Phosphoric Acid (85%) Aerosol 22 Surfactant Aerosol 0s Surfactant Buty l Cel losolve Water

Aluminum Ai rcraf t -Br ightener (U.S.

Ingredients : Aerosol 0s Surfactant Aerosol 22 Surfactant C i t r i c Acid Arnmoni urn B i f 1 u o r i de Benzenesul f on i c Acid Phosphoric Acid (85%) Water

% bv Weiaht 2.0 5.0 5.0

22.0 66.0

% bv Wei Qht 15.0 2.0 3.0 5.0

75.0

% by Wei Qht 47.2

1 . o 1 . o

16.0 34.8

Patent 2.68Y.3461

% bv Weiaht 3.0 9.0 5.0 3.0

10.0 2.4

26.4-52.6

SOURCE: Cytec Indus t r i es Inc. : Suggested Formulatlons

lo6 Advanced Cleaning Product Formulations

E l e c t r o c l eaner

Components: Water Burco BSGH-400 Burco NPS-225 Burco TME 50% NaOH

% by Weiaht 2-0 1-4

0.75-3 0.25-1

To 100% Tota l

Basic formulat ing guidel ines: 1) Rat io o f Burco NPS-225/Burco TME should be 3/1. 2 ) The l e v e l o f Burco BSGH-400 i s p re fe rab ly equal t o the sum

3 ) The water charge should be equal t o the sum o f Burco BSGH-400,

4) Premix a l l components but NaOH. then add NaOH w i t h s t i r r i n g .

This formulat ion w i l l provide moderate foam l e v e l s and i s s u i t a b l e f o r use as an electrocleaner, food p l a n t cleaner o r o ther app l i ca t i ons where h igh caus t i c concentrates are used. For reduced foam l e v e l s as i n an a l k a l i n e spray cleaner, replace Burco NPS-225 w i t h Burco HCS-50NF.

o f Burco NPS-225 and Burco TME.

Burco NPS-225 and Burco TME.

Moderate A1 k a l i n i t y , Soi 1 So1 i t t i n a Soak Cleaner

ComDonents: Water Sodium Metas i l i ca te (Pentahydrate) Trisodium Phosphate (Crysta ls) Burco ADS-40 Burco EHS Burco TME

% bv Weiaht 70

5 10 5 5 5

Procedure: Add components i n the order l i s t e d . S t i r u n t i l homogeneous


SOURCE: Bur l ington Chemical Co., I n c . : Suggested Formulations

Metal Cleaners and Polirhes 107

Hiah-Foaming Ac id Scrubber* Formula BC-0003

Mi rano l FBS Igepa l CO 630 Sul famic Ac id G1 yco l i c (Hydroxyaceti c ) Ac id (70%) Butoxyethanol Water

Wt.% 5.0 2.0 4.0 4.0 3.0

82.0

Procedure

o lved. Add t h e remaining i ng red ien ts , w i t h mix ing . Mix u n t i l un i fo rm.

Add t h e water, su l famic and g l y c o l i c acids. Mix u n t i l d i s s -

Physical ProDer t ies Appearance: Clear l i q u i d . .

pH, as i s : 1.5 S p e c i f i c Grav i t y : 1 V i s c o s i t y : t10 cps

*Su i tab le f o r appl i c a t

Rhodafac RE-61 0 Igepa l CO-630 Phosphoric Acid, 75% Water

027

ons w i t h a t r i g g e r - t y p e sprayer.

Ac id Cleaner Formula BC-0004

Wt.% 3.0 4.0

10.0 83.0

Procedure Add phosphoric a c i d t o water and heat w i t h a g i t a t i o n t o 50C.

w i t h r a p i d bu t smooth a g i t a t i o n . Slowly b lend i n Rhodafac RE-610 and Igepa l CO-630. Once system i s completely uni form, coo l w i t h s t i r r i n g t o 40-45C, and package.

Phys ica l P r o D e r t i e a Appearance: S l i g h t l y hazy l i q u i d pH, as i s : 1.6 Speci f i c Grav i t y : 1 .03 V i s c o s i t y : 20 cps

SOURCE: Rhone-Poulenc Sur fac tan ts 8 Spec i 'a l t ies : Formulas

108 Advanced Cleaning Product Fotmulations

Metal C1 eaner and Deereaser

InQredi ents: Monoethanolamine Sodium DDBSA, 35% Sandoxylate SX 400 Sodium EDTA Water Ole ic Acid D-Li monene Buty l Cel loso lve

% bv Weight 5.0

12.0 5.0 0.5

50.5 10.0

3.0 6.0

Procedure:

add DDBSA. Mix i n Sandoxylate SX 400, and EDTA. Warm t o 50C, add the o l e i c ac id s lowly, wh i l e increas ing t h e a g i t a t i o n . When t h e o l e i c a c i d has completely reacted, add D-Limonene and Buty l Cel losolve. Cool w i t h s t i r r i n g t o 40C. B o t t l e .

Propert ies:

Charge monoethanolamine and water t o vessel. With s t i r r i n g .

pH (as i s ) : 10.0 V i scos i t y : Approx. 100 cps B rook f i e ld LVT, Spindle #2 @ 12 rpm % Sol ids: 26%

SOURCE: Sandoz Chemicals Corp.: Formulation HHG-10

Thickened Clear Deareaser Concentrate

Water, D . I . DeSonic 9N Varonic DM55 d ' L i monene

% by Weight 42.5 25.0 12 .5 20.0

Blend1 ng Procedure:

each add i t i on .





Stain less Steel Cleaner-A

Mar l i pa l KF Marlophor CS ac id Solvent BG* Balance water, fragrance, dyestuf f , preservat ive

Act ive matter: 1.0 V i scosi t y : 1 i qui d

S ta i n l ess Steel C1 eaner-B

Mar 1 i pa l 01 3/99 Aluminum oxide FPTO Isopara f f i n . e.g. Shel lso l T Balance water, fragrance, dyestuf f , preservat ive

Ac t i ve matter: 5.4 V iscos i t y : medi um Formulation B w i t h abrasive

S i l v e r Pol ish, Liauid-A

Mar l i pa l KF Thiourea Phosphoric acid, 85% Isopropanol* Balance water


S i l v e r Pol ish. Liauid-B

Marlazin L 10 Marlophor CS ac id Thiourea Phosphoric acid, 85% Balance water

% 1 . o

10.0 5.0

t o 100

% 6.0

25.0 40.0

t o 100

% 0.5 6.0 2.0 3.0

t o 100

% 1.5 5.0 2.5

20.0 t o 100



10. Oven, Grill and Hot Plate Cleaners

110

Oven, Grill and Hot Plate Cleaners 111

Pump Sprav Oven C leaner

- Ingredient; P a r t A : Vegetab le gum (Veegum T) Xanthan gum Water

-. Percent b v Wei q h t

1 .2 0 . 4

78 .9

P a r t B: L i q u i d C i t r i c Acid--50% (Haarman & Reimer Corp . ) 7 . 0 Sodium h y d r o x i d e s o l u t i o n 50% 4 .5

P a r t C : Amphoter ic s u r f a c t a n t 8 . 0

Prepare P a r t A by s l o w l y add ing v e g e t a b l e gum and xanthan gum t o t h e w a t e r . Cont inue a g i t a t i n g u n t i l smooth d i s p e r s i o n i s o b t a i n e d .

t o a separa te t a n k and n e u t r a l i z i n g i t w i t h t h e sodium h y d r o x i d e s o l u t i o n . The n e u t r a l i z a t i o n s h o u l d be done s l o w l y and c o n t i n - u o u s l y under a g i t a t i o n , as t h e r e a c t i o n i s h i g h l y exo thermic .

Prepare P a r t B ( t r i s o d i u m c i t r a t e ) by add ing t h e c i t r i c a c i d

Add P a r t B t o P a r t A, and f i n a l l y P a r t C . The f o r m u l a t i o n has t h e c o n s i s t e n c y o f a f l u i d g e l . I t may be

used i n e i t h e r warm o r c o l d ovens. The s p r a y i n g s h o u l d be done a t a d i s t a n c e o f f r o m 10 t o 15 inches . Clean by w i p i n g a f t e r a t l e a s t 10 minu tes o f r e a c t i o n t i m e . SOURCE: Haarman & Reimer Corp . : Suggested F o r m u l a t i o n

C a u s t i c Oven C1 eaner

I n g r e d i egt_s_: % b y Weight ( 1 ) K o r t h i x H 2 . 0 ( 2 ) Kelzan 0 .3 ( 3 ) De ion ized Water 8 6 . 7 ( 4 ) Sodium Hydrox ide (50%) 10.0 ( 5 ) Avanel S-74 1 . o Procedure:

Add ( 1 ) t o ( 3 ) and mix a t h i g h speed. A f t e r ( 1 ) i s w e l l d i s - persed, add (2) and ( 5 ) . Reduce speed and add ( 4 ) c a r e f u l l y and s l o w l y .

F o l l o w recommended h a n d l i n g p r a c t i c e s o f t h e s u p p l i e r s of each p r o d u c t used. SOURCE: K a o p o l i t e , I n c . : Suggested F o r m u l a t i o n

O v e n / G r i l l C leaner

Wt% Water 78 Tetrasodium EDTA 2 Sodium Hydrox ide (50%) 15 Glucopon 425 CS 5 SOURCE: Henkel Corp . , CD D i v i s i o n : Suggested F o r m u l a t i o n

11 Polishes, Coatings and Finishes

112

Polishes, Coatings and Finishes 113

Aerosol F u r n i t u r e P o l i s h (Carbon D iox ide Propel l a n t l

Mater i a1 s: Pa r t A: I sopar E Hoechst Wax A 3 CS SF 96 (100) V i s c a s i l (10,000) Span 80 P a r t 8: Water Procedure: 1.) Heat P a r t A t o 85C. 2 . ) Heat Pa r t 8 t o 70C. 3 . ) Add P a r t 8 t o P a r t A w i t h h igh shear mixing. 4.) Cool t o room temperature when homogeneous. Prepara t ion o f Aerosol : Loadi ng : P o l i s h Concentrate Carbon D iox ide

Aerosol Valve: P rec i s ion Valve P a r t Numbers:

*Th is w i l l g i v e a can pressure o f approximately

Button: Pa r t No. 01-5843 (0.020" MBFT RS) Stem: Par t No. 04-1215 (0.016") Gasket: Pa r t No. 05-0310 (BUNA) Body: Pa r t No. 07-1901 (0.080")

5.) Package i n s u i t a b l e conta iners .

Part/Wt(%)

22.5 0.5 2.3 0.5 0 .3

73.9

Part/Wt(%) 97.5

2.5* 105 p s i g .

General Purpose L i auid Pol i sh (Oil-In-Water Type)

Mater i a1 s : Part/Wt (%l P a r t A: SF 96 (350) 2.50

Hoechst Wax E 1.50 O l e i c Ac id 1.50

Par t 8: Water 70.05 Carbopol 934 0.25 Morphol i ne 1.60 Kathon CG 0.10 Par t C: I sopar M 2.00 SF 1706 1.50 P a r t D: Kaopo l i t e SF 8 . 0 0 Procedure: 1 . ) Heat Pa r t A t o 95C. (2 . ) Heat Pa r t B t o 85C. (3.) Add P a r t

A t o Pa r t 8 w i t h h igh shear mix ing . ( 4 . ) When homogeneous, coo l t o 60C and add Par t C w i t h h i g h shear mix ing . ( 5 . ) Add Par t D w i t h moderate mix ing . ( 6 . ) Cool and package i n s u i t a b l e conta iners .

V i s c a s i l (10,000) 1 .oo

Isopar M 10.00

SOURCE: GE Si14cones: Formula FP 3003/Formula AP 1000

114 Advanced Cleaning Roduct Formulatiom

Aerosol F u r n i t u r e P o l i s h IHydrocarbon ProDel lan t )

Ma te r ia l s : Pa r t A: I sopar E Hoechst Wax A3 CS S F 96 (100) V i scasi 1 ( 10,000) Span 80 Tween 81 Par t B: Water Procedure: 1 . ) Heat P a r t A t o 85C. 2 . ) Heat P a r t B t o 70C. 3 . ) Add P a r t B t o Pa r t A w i t h h igh shear mix ing . 4.) Cool t o room temperature when homogeneous. Prepara t ion o f Aerosol : i o a d i ng : P o l i s h Concentrate A 46 P rope l l an t Aerosol Valve : P rec i s i on Valve P a r t Numbers :

But ton : Par t No. 01-5843 (0.020" MBFT RS) Stem: Par t No. 04-1240 (0.024") Gasket: Pa r t No. 05-0310 (BUNA) Body: P a r t No. 07-1901 (0.080")

5. Package i n su i tab1 e conta i ners.

F u r n i t u r e P a s t e m Mater i a1 s : Par t A:

Par t / W t 1%)

14.75 0.50 2.30 0.50 0.25 0.08

81.62

Part/WtC%) 90.0 10.0

V i scasi 1 (30,000) Hoechst Wax E Hoechst Wax F Ross Micro Wax 1135/15# Ross Ozoker i te Wax 77Y Par t B: I sopar L Procedure: 1 . ) Heat Pa r t A t o 1OOC. 2.) Heat Pa r t B t o 9%. 3 . ) Add Par t 8 t o Par t A w i t h g e n t l e mixing. 4.) Cool t o 50-52C w i t h g e n t l e mix ing and pour i n t o conta iners .

A l low con ta ine rs t o coo l be fo re capping. A f l o w o f a i r across sur face o f con ta ine r w i l l improve c o o l i n g process. M u l t i p l e pour cyc les can be used f o r deep conta iners .

A l t e r n a t e Method: 1 . ) Heat P a r t A t o 100C. 2 . ) Add Par t B (unheated) s lowly w h i l e b lend ing . 3 . ) Reheat Pa r t AB u n t i l a c l e a r s o l u t i o n i s obtained. Fo l low

above procedure f rom here.

7.0 7.0 3.0 6 . 0 1 .o

76.0

SOURCE: GE Si l i cones : Formula FP 3002/Formula FP 3004

Polishes, Coatings and Finishes I15

Detergent Res is tan t . Cream Cleaner P o l i s h

I n g r e d i e n t s : % by ( 1 ) Deodori zed Kerosene ( 2 ) Hoechst Wax S (3 ) GP-7104 ( S i l i c o n e F l u i d ) ( 4 ) GP-10-1,000 c s t k (Dimethyl S i l i c o n e F l u i d ) ( 5 ) O l e i c Ac id ( 6 ) S o f t Water ( 7 ) Morphol i ne ( 8 ) S o f t Water ( 9 ) Minera l S p i r i t s (Low Odor) (10)Kaopo l i te SF

Weight 10.0

8 . 0 3 . 0 4.0 1 .o 2.4 0 .8

38.8 20.0 12.0

Procedure: Combine (1 ) through ( 5 ) and heat t o 212F w i t h low t o moderate

m ix ing . Remove heat, inc rease m ix ing and add ( 6 ) through (10) as i n s t r u c t e d below.

Heat (6 ) t o 21OF, s t i r i n ( 7 ) , then pour i n t o t h e ba tch . Heat ( 8 ) t o 210F and add t o t h e ba tch . Add ( 9 ) then (10) s low ly t o t h e batch, a l l o w i n g complete mix ing o f each.

Mix s low ly u n t i l temperature o f ba tch reaches l lOF . Package.

Formula 4-2

Non-Abrasive, Detergent Res is tan t , Glaze Emulsion

I n g r e d i e n t s : % by Weight ( A ) ( 1 ) GP-10-1,000 c s t k (Dimethyl S i l i c o n e F l u i d ) 3.0

(2) GP-7104 ( S i l i c o n e F l u i d ) 3 . 0 ( 3 ) Hoechst Wax S 1.5 ( 4 ) Carnauba Wax #3 1 . o ( 5 ) O l e i c Ac id 1 .5 ( 6 ) Minera l S p i r i t s 4.6

( B ) ( 7 ) S o f t Water (8 ) Carbopol 934 ( 9 ) Tr ie thano lamine 99%

(10) Morphol i ne

83.6 0 . 2 0 .2 1 .4

Procedure: (A) Combine (1 ) through (6 ) and heat t o 150F w i t h mix ing . ( B ) Heat ( 7 ) t o 1OOF. Wi th h i g h shear mix ing add ( 8 ) t o ( 7 ) .

Once (8) i s d i sso l ved add (9 ) and then add (10) . Add ( A ) t o ( B ) s low ly , w i t h h igh shear mix ing . Cont inue m ix ing u n t i l emulsion reaches 70F. Package.

Formula 8-1

SOURCE: Genesee Polymers Corp.: Suggested Formulat ions

I16 Advanced Cleaning Product Formulations

Hi ah G1 oss. Detereent Res is tan t . S o f t Paste Pol i sh

I nq red ien ts : ( A ) ( 1 ) Hoechst Wax OP

(2) Hoechst Wax E (3) Ozokeri t e

% bv Weight 7.0 8.0 1 .5

(B) ( 4 ) GP-7104 ( S i l i c o n e F l u i d ) 3.0 ( 5 ) GP-10-1,000 c s t k (Dimethyl S i l i c o n e F l u i d ) 3.0 (6 ) GP-10-12,500 c s t k (Dimethyl S i l i c o n e F l u i d ) 2.0 (7 ) Minera l S p i r i t s (Low Odor) 36.0 ( 8 ) Deodorized Kerosene 9.5 (9) Kaopo l i t e SF 12.0

(10) Minera l S p i r i t s (Low Odor) 18.0

Procedure: ( A ) Combine ( I ) , (2), and (3), heat t o 230F t o me l t waxes. (B) Separately mix and heat ( 4 ) , ( 5 ) , ( 6 ) , (7 ) , and (8) t o 160F.

Slowly add (B ) t o ( A ) w i t h mix ing . Temperature o f ba tch a f t e r adding (B) t o (A) should be 195F. Add (9 ) then (10) t o ba tch w i t h m ix ing . Remove heat and mix w e l l u n t i l temperature reaches 140F. Package.

Formula 5-2

Detergent Res is tan t Cream P o l i s h

Inq red i en ts : ( 1 ) Witconol 14 (2) GP-10-1,000 c s t k (Dimethyl S i l i c o n e (3) Carnauba Wax #3 (4 ) Isopar L (5) Morphol i ne (6 ) GP-7104 ( S i l i c o n e F l u i d ) (7 ) S o f t Water (8 ) Kaopo l i t e SF

% by Wei ah t 1 .5

F l u i d ) 3.0 10.0 25.0

0.4 3.1

47.1 10.0

Procedure:

t o 195F w i t h m ix ing t o me l t wax. Once wax i s melted, add ( 5 ) w i t h mix ing . Add (6 ) t o m ix tu re fo l l owed by t h e r e s t o f (41, keeping t h e temperature a t 175F. Remove from heat and mix u n t i l temperature reaches 130F. Package.

Formula 3-2

SOURCE: Genesee Polymers Corp.: Suggested FormulatSons

Combine ( I ) , (2), (3). and 50% o f (4) i n a conta iner and heat


L i q u i d P o l i s h For C lear Coat F in i shes Mater i a1 _s ; Part/Wt(%) Par t A: SF 96 (350) 3.50 Hoechst Wax S 1 .oo Hoechst Wax E 1.60 O l e i c Ac id 1.50 Isopar M 5.00 Par t 0: Water 77.75 Carbopol 934 0.20 Morphol i ne 1.60 Kathon CG 0.10 Par t C: I sopar M I .oo SF 1706 0.75 Par t D: Kaopol i t e 11 52 6.00 Procedure: 1 . ) Heat P a r t A t o 95C. 2 . ) Heat Pa r t B t o 8%. 3.) Add P a r t A t o Pa r t B w i t h h i g h shear mix ing . 4 . ) When homogeneous, coo l t o 60C and add P a r t C w i t h h igh

5 . ) Add P a r t D w i t h moderate mix ing . 6 . ) Cool and package i n s u i t a b l e conta iners .

Mater i a1 s : Part/Wt(%) Par t A: SF 96 (350) 5.00 Hoechst Wax E 1.50 O l e i c Ac id 1.50 Par t 8: Carbopol 934 0.25 Morphol i ne 1.50 Water 74.15 Kathon CG 0.10 Par t C : SF 96 (100) 2.00 SF 1706 2.00 Par t D: Kaopol i t e 11 52 7.80 Snow F loss 4.20 Procedure: 1 . ) Heat Pa r t A t o 95-IOOC. 2 . ) Heat Par t B t o 85C. 3 . ) Add Par t A t o Pa r t B w i t h h igh shear mix ing . 4 . ) When homogeneous, coo l t o 60-70C and add Par t C w i t h con t in -

5 . ) When homogeneous, reduce mix ing t o medium speed and s low ly

6.) Cool and package i n s u i t a b l e conta iners .

SOURCE: GE S i l i c o n e s : Formula APlOOl/Formula AP1002

shear m i x i ng.

L i q u i d Polish-No Solvent

ued h igh shear mix ing .

b lend i n Par t D.


L i a u i d Po l i sh (Outer Phase O i l l

Mater ia ls : Par t A: V i scas i l (10,000) W i tcamide 51 1 Tween 81 Hoechst Wax OP Ross Ozoker i te 77Y Isopar M Par t 9: Water Kaopol i t e 11 52 Kaopol i te SF Part C : Isopar L SF 1705 SF 1706 Procedure: 1.) Heat Par t A t o 90-95C. 2 . ) Heat Part B t o 80C. 3 . ) Add Par t B t o Par t A w i t h h igh shear mixing. 4 . ) When homogeneous, cool t o 50-60C and add Par t C

5 . ) Cool and package i n s u i t a b l e containers. Formula AP 1003

continued h igh shear m i x i ng.

Part/Wt (%l

1.50 1 .oo 0.15 1.30 0.20

2 0 . 0 0

55.85 4.50 4.50

6.00 3.00 2.00

w i t h

Non-Wax L i a u i d Po l i sh (Oil-Pn-Water Tvoe)

Mater i a1 s : Par t A:

Part/Wt C%l

SF 96 (350) 4.00 V i scasi 1 (10,000) 1 .oo Isopar L 11 .oo Ole ic A c i d 1.50 Part 0 : Water 65.95 Carbopol 934 0.25 Morpholine 1.70 Kathon CG 0.10 Part C: Isopar M 4.00 SF 1706 1.50 Par t D: Kaopol i t e 11 52 6.00 Snow Floss 3.00 Procedura: 1. ) Add Par t A t o Par t B w i t h h igh shear mixing. 2 . ) When AB i s homogeneous, add Part C. a lso w i th h igh shear

m i x i ng. 3 . ) Add Par t D w i t h moderate mixing u n t i l homogeneous. 4.) Package i n s u i t a b l e containers. Formula AP 1004 SOURCE: BE Sl l lconea: Suggested Formulations

M a t e r i a l s : SM 2133

20% Wax Emulsion Carbopol 934 Tr iethanolamine Water B i o c i de

sm 2135

M a t e r i a l s : P a r t A: Card is 36 Wax Hoechst Wax A3 CS O l e i c Ac id Morphol ine Par t B: Water B i o c i de


L i sui d F u r n i t u r e P o l i sh Part/Wt (%I

4.0 2.0 2.5 0 . 2 0.2

91.1 q . s

20% Wax Emulsion-1

20% Wax Emulsion-2 M a t e r i a l s : Pa r t A: Card is 36 Wax Hoechst Wax A3 CS O l e i c Ac id D i e t h y l ami noethanol (DEAE) Par t 8: Water B i oc i de

Part/Wt(%)

10.0 10.0

3.0 4.0

73.0 q . s .

Part/Wt (%)

10.0 10.0

3.0 2.5

74.5 q . s .

Prepara t ion o f Wax Emulsion: 1.) Add Card is 36 wax, Hoechst wax A3 CS, and o l e i c a c i d t o a

2.) When completely melted, add e i t h e r t h e morpholine o r DEAE u n t i l m ix tu re i s homogeneous.

3.) Add P a r t B, preheated t o 95C, s low ly s t i r r i n g t h e wax/soap mix tu re , ma in ta in ing temperature between 93 t o 98C du r ing t h i s a d d i t i o n .

4.) Continue s t i r r i n g u n t i l temperature reaches 45C. 5 . ) Cool t o room temperature. Prepara t ion o f Po l i sh : 1 . ) Add water, b ioc ide , and Carbopol 934 t o a vessel , and

2 . ) Add t r i ethanol ami ne and mix u n t i 1 homogeneous. 3 . ) Add o the r i ng red ien ts . 4 . ) Combine w i t h m i l d mixing, and when homogeneous, package

SOURCE: GE S i l i c o n e s : Formula FP 3000

vessel , and w i t h m i l d s t i r r i n g b r i n g t h e temperature up t o 96-1 OOC.

d i s s o l v e t h e Carbopol w i t h good mix ing . Warm water w i l l improve t h i s process.

i n s u i tab1 e con ta i ners.

120 Advanced Cleaning Roduct Formulatiotu

L i a u i d Water-Based Glaze

Mater i a1 s : Par t A: SF 96 (350) O l e i c Acid Hoechst Wax OP Card is 36 Wax Isopar M

Par t B: Water Carbopol 934 Morphol ine Kathon CG

Par t C: I sopar M SF 1706

Part/Wt(%)

3.50 1.50 1 .oo 1.50 6.00

82.55 0.25 1.60 0.10

1 .so 0.50

Procedure: 1 . ) Heat Pa r t A t o 95-1OOC. 2 . ) Heat P a r t B t o 90-95C. 3 . ) Add Par t A t o Pa r t B w i t h h igh shear mixing. 4.) Cool t o 60-70C and add Par t C w i t h h igh shear mixing. 5 . ) Cool w i t h cont inued moderate mix ing . 6.) Package i n s u i t a b l e conta iners . Formu la AP 1005

Sol vent Wax G l aze

M a t e r i a l s : Pa r t A: SF 96 (1000) Hoechst Wax OM Hoechst Wax F Deodorized Kerosene

Par t B: Odorless Minera l S p i r i t s SR 107

Part/Wt (%l

3.0 0.6 1.4

1 0 . 0

84.0 1 .0

Procedure: 1.) Heat P a r t A to 95C. Be sure a l l wax i s completely melted

2 . ) Add Par t B w i t h moderate mix ing . 3 . ) Continue mix ing and coo l t o room temperature. 4.) Package i n s u i t a b l e conta iners .

Formula AP 1008

SOURCE: GE S i l i c o n e s : Suggested Formulat ions

and d i spersed.


Paste Po l i sh (Oil-In-Water Type1

Part/Wt (%l Materi a1 s: Part A: Hoechst Wax S Hoechst Wax OP SF 96 (350) V i scas i l (10,000) Stear ic Acid Isopar M Isopar L Part 0: Water Morpholine Kaopol i t e 11 68 Super Floss Part C: Isopar M SF 1706 Procedure: 1 . ) Heat Part A t o 90-95C. 2.) Heat Part 8 t o 80-85C. 3.) Add Part A to Part B wi th good mixing. 4. ) When homogeneous, cool t o 60C and add Part C w i t h continued

5 . ) Cool t o s u i t a b l e pour temperature (<50C). 6.) Package i n su i tab le containers. Comments :

degree o f cool ing ava i l ab le on the f i l l i n g l i n e . With slow coo l i ng rate, t he coo l i ng cyc le must be done without covers t o prevent condensation i ns ide containers.

mixing.

The pour temperature w i l l depend on equipment and r a t e and

5.0 1 . o 4.5 2.0 1 .o 8 .0

18.0

42.8 0.7 8 .0 2.0

5 .0 2.0

Spray-And-Wipe Po l i sh

Mat e r i a1 s : SM 2109 AF 9020

Part/Wt(%) 8 . 0 0 0.05

Veegum Pro 0 . 8 0 Proxcel GXL 0.15 Kaopol i te SF 5.00 Water 86.00 Procedure: 1 . ) Add water, Proxcel GXL. and Veegum Pro t o a mixing vessel,

2.) Add Kaopol i te SF and continue mixing w i th h igh shear u n t i l

3 . ) Reduce mixing t o low t o moderate and add AF 9020 and

4 . ) Package i n su i tab le sprayable containers.

SOURCE: GE Si l icones: Formula BP 2001/Formula AP 1010

and, using h igh shear, disperse u n t i l uniform.

a uni form f i n e dispersion i s obtained.

SM 2109 emulsions. Do Not Overmix. These mater ia ls e a s i l y disperse i n a very shor t t ime per iod.

122 Advonced Cleaning Product Formulations

Paste P o l i s h (Oi l - In-Water TYDe)-(l)

Ma te r i a1 s : Part/Wt (%) Pa r t A: SF 96 (350) 4.5 V i s c a s i l (10,000) 2.0 Hoechst Wax S 5.0 Hoechst Wax OP 1 . o S t e a r i c Ac id Isopar M Isopar L Par t 0: Water Morphol ine Kaopo l i t e SF Snow F1 oss Kathon CG Par t C: I sopar M SF 1706

Mate r i a1 s : Par t A: SF 96 (350)

1 .o 8 . 0

18.0

42.7 0.7 8.0 2.0 0.1

5.0 2.0

Paste P o l i s h (Oil- In-Water Tyoe)-(Zl

Par t /Wt (%l

4 . 5 v i scas i 1 (i 0, ooo) Hoechst Wax S Hoechst Wax OP S t e a r i c Ac id Isopar M Isopar L Par t 0: Water Morphol ine Kaopo l i t e 1152 Snow F1 oss Kathon CG Par t C: I sopar M SF 1706

2.0 5.0 1 . o 1 .o 8 . 0

18.0

41.7 0.7 7.8 4.2 0.1

4.0 2.0

Procedure: 1.) Heat Par t A t o 90-95C. (2.) Heat Par t B t o 80-8512. 3.) Add Par t A t o Pa r t 0 w i t h good mix ing . (4.) When homogeneous,

6.) Pour i n t o s u i t a b l e con ta ine rs .

Comments : The pour temperature w i l l depend on equipment, r a t e and degree

o f c o o l i n g a v a i l a b l e on the f i l l i n g l i n e . Wi th slow c o o l i n g r a t e , t h e c o o l i n g c y c l e must be done w i thou t covers t o prevent condensation i n s i d e con ta ine rs . SOURCE: GE S i l i c o n e s : Formula AP 1008

coo l t o 60C and add Par t C w i t h cont inued mix ing . ( 5 . ) Cool t o s u i t a b l e pour temperature, e.g., >50C.


Paste Pol ish ( O i p Meteri a1 s: Part/Wt t % l Part A: SF 96 (350) 4.5 V i scasi 1 (10,000) 2.0 Hoechst Wax S 5.0 Hoechst Wax OP 1 . o Stear i c Acid 1 . o Isopar M 8 . 0 Isopar L 18.0 Part B: Water 42.7 Morphol i ne 0.7 Kaopol i t e 11 52 7.5 Snow Floss 2 .5 Kathon CG 0 .1 Par t C: Isopar M 5.0 SF 1706 2.0 1 . ) Heat Part A t o 90-95C. 2 . ) Heat Part 8 t o 80-85C. 3 . ) Add Par t A t o Part B w i th good mixing. 4 . ) When homogeneous, cool t o 60C and add Part C w i t h cont-

5 . ) Cool t o su i tab le pour temperature, e.g., >5OC. 6. ) Pour i n to s u i t a b l e contai ners. Comments :

The pour temperature w i l l depend on equipment, r a t e and degree o f cool ing on the f i l l i n g l i n e . With slow cool ing rate, t h e coo l i ng cyc le must be done without covers t o prevent condensation i nsi de contai ners.

Mater ia ls : Part/Wtt%) Par t A: V i scas i l (10,000) 2.50 Hoechst Wax S 1.80 Hoechst Wax E 2.00 Ross Ozokerite 77Y 0.15 Span 80 2.00 Tween 81 0.15 Isopar L 17.00 Isopar M 5.00 Part B: Water 52.40 Kaopol i t e 11 52 6.00 Snow Floss 3.00 Part C : Isopar M 2.00 SF 1705 4.00 SF 1706 2.00 1. Heat Part A t o 95C. ( 2 . ) Heat Part B t o 8OC. ( 3 . ) Add Part

B t o Par t A w i t h h igh shear mixing. (4 . ) Cool t o 60-65C and add Part C w i t h good mixing. (5.) Cool t o 55C and pour i n t o s u i t a b l e containers.

i nued m i x i ng .

Paste Po l i sh (Outer Phase O i l 2

SOURCE: GE S i l icones: Formula AP 1006(3)/AP 1007


Spray-And-Wipe P o l i s h (Pump)

Mater i a1 s 1 SM 2133 SM 2135 20% Wax Emulsion Water B i o c i de

M a t e r i a l s Pa r t A : Card is 36 Wax Hoechst Wax A3 CS O l e i c Ac id Morphol ine

Par t B: Water B i o c i de

20% Wax EmulKion-.(a

Matey ja l s : Par t A: Card is 36 Wax Hoechst Wax A3 CS O l e i c Ac id Diethylaminoethanol (DEAE)

Par t B: Water B i o c i de

Part/Wt(%) 3.0 2 . 0 2 . 5

92.5 q . s .

20% Wax .Emu 1 s i onr--l )

Sartf W t f U

10.0 10 .0

3.0 4 . 0

73.0 q . s

10.0 10.0

3 . 0 2.5

74.5 q . s .

Prepara t ion o f Wax Emulsion: 1 . ) Add Card is 36 wax, Hoechst wax A3 CS, and o l e i c a c i d t o a

vessel and, w i t h m i l d s t i r r i n g , b r i n g temperature up t o 98-1ooc.

2 . ) When comple te ly melted, add e i t h e r t h e morphol ine or DEAE u n t i l m i x t u r e i s homogeneous.

3.) Add Par t B, preheated t o 95C, s low ly s t i r r i n g t h e wax/soap m ix tu re , ma in ta in ing temperature between 93 and 9BC d u r i n g t h e a d d i t i o n .

4 . ) Cont inue s t i r r i n g u n t i l temperature reaches 45C. 5 . ) Cool t o room temperature.

Prepara t ion o f P o l i s h :

package i n s u i t a b l e con ta ine rs .

SOURCE: GE S i l i c o n e s : Formula FP 3001

Blend a l l i n g r e d i e n t s toge the r w i t h m i l d s t i r r i n g , and


Spray 8 Wipe Type-Aerosol o r Non-Aerosol(1)

Concord Co-Wax Emulsion, 12% S i 1 i cone (Union Carbide LE-461) D i s t i 11 ed Water

% by Weiaht 4.1 7.0

88.9

Spray 8 Wipe- Type-Aerosol o r Non-Aerosol(E]

Concord Co-Wax Emulsion, 12% S i l i c o n e (Union Carbide LE-461) S i l i c o n e (Union Carbide LE-462) D i s t i 11 ed Water

Weisht 7.5

12.5 2.5

77.5

Spray & Wipe Type-Aerosol o r Non-Aerosol(3)

Concord Co-Wax Emulsion, 12% S i 1 i cone (Union Carbide LE-461) S i l i c o n e (Union Carbide LE-462) T r i ethanol ami ne Laury l S u l f a t e D i s t i 1 l e d Water

% by Weiqht 7.5

12.5 2.5 1 .5

76.0

The formulas l i s t e d above a re suggested formulas. Every e f f o r t has been made t o op t im ize a l l p r o p e r t i e s t o ge t t h e bes t p o l i s h w i t h regard t o s p e c i f i c amounts o f i n g r e d i e n t s . Formula #1 i s t h e bes t a l l around p o l i s h . I t fea tu res e x c e l l e n t g loss , a p p l i c a t i o n ease and economy. Formula #3 i s an example o f l i g h t foam-type p o l i s h , and o f f e r s b e t t e r removal o f s o i l and emuls- i f i c a t i o n o f p r o p e l l e n t s . Formula #2 i l l u s t r a t e s a h igh g loss fo rmula w i t h e x c e l l e n t p r o t e c t i v e q u a l i t i e s .

L i q u i d Wax-Solvent F u r n i t u r e o r F l o o r P o l i s h

Concord Wax #1600 S i l i c o n e General E l e c t r i c SF 96-100 Safety So lvent (Stoddard So lvent )

% by Weight 6.0 1 .o

93.0

Procedure: Me l t wax and s i l i c o n e together a t a temperature o f 195-200F

i n one h a l f o f t h e so l ven t . The balance o f t h e c o l d so l ven t i s then added t o t h i s s o l u t i o n a f t e r t h e waxes a re melted.

SOURCE: Concord Chemical Co., I n c . : Suggested Formulat ions

12. Rinse Aids

126

RinseAids 127

Automatic Dishwash Rinse A i d (For Hard Water1 A c i d Hard Water Tolerant Formulation

Inaredient : Oeioni zed Water Mazawet 36 G lyco l i c Acid (57%) Isopropyl Alcohol

pH, 1%: 2.0-3.0 Appearance: Clear, s l i ght S p r c i f i c Grav i ty : 1.01

y viscous, l i gh t - ye l l ow

Wt.% 30.00 55.00 10.00 5 . 0 0

i qui d

Procedure: Charge the water and Mazawet 36 t o the mixing vessel and

s t a r t a g i t a t i o n . Charge the G lyco l i c Acid and Isopropyl Alcohol and mix u n t i l c l ea r and f r e e o f " f i s h eyes."

Notes : Formulated f o r areas w i t h hard water. Normal use d i l u t i o n i s 100 ppm i n f i n a l r i n s e cyc le . Conc-

en t ra t i ons o f use so lu t i ons may be adjusted t o meet l oca l needs o r va r ta t i ons i n equipment. Formula CR-101

Automatic Dishwash Rinse A i d <For Neutral o r S o f t Water)

Standard Formulation f o r Neutral o r Sof t Water

Ingredient : Mazawet 36 Oeioni zed Water Isopropyl A1 coho1 Sodi um Hydroxide

Wt.% 55 .00 40.00

5 . 0 0 P.S . t o pH 6.0-7.0

pH. 1%: 6.0-7.0 Appearance; Clear, s l i g h t l y viscous, l i gh t - ye l l ow l i q u i d Spec i f i c Grav i ty : 1.01

Procedure:

u n t i l c l ea r and f r e e o f " f i s h eyes."

Notes : Formulated f o r areas w i t h neutra l o r s o f t water. Normal use d i l u t i o n i s 100 ppm i n f i n a l r i n s e cyc le . Conc-

en t ra t i ons o f use so lu t i ons may be adjusted t o meet l o c a l needs o r v a r i a t i o n s i n equipment.

The formulator may adjust t h e c loud-point o f t h i s system by using add i t i ona l a lcohol t o increase i t o r Sodium Hydroxide t o decrease i t . Formula CR-102


Charge the ingredients i n t h e sequence given above and mix


Rinse A i d Formula DW-0011

Antarox BL-240 Urea Water Dye

Wt.% 50.0

9.0 41 . O

Procedure 1. Dissolve urea i n water. 2. Add Antarox BL-240 t o water/urea so lu t i on . Mix thoroughly.

Physical PrpDertiea pH (as i s ) : 7.5 pH (1%): 8.1 Viscos i ty : 50 cps Spec i f i c Grav i t y : 1.01

Rinse A i d Formula DW-0012

Antarox BL-225 Isopropanol Water Dye

Procedure 1. Dissolve Antarox BL-225 i n water. Mix thoroughly. 2. Add isopropanol.

Physical Proper t ies pH (as i s ) ; 6.1 pH (1%): 8 .3 Viscos i t y : 30 cps Spec i f i c Grav i ty : 0.99


Wt.% 70.0 20.0 10 .0 -

13. Rug, Floor, Carpet, Upholstery Shampoos and Cleaners

129

130 Advanced Cleaning product Formdations

Basic F loor Cleaner. Liauid-A

Marlon A 360 o r A 365 Marl i pal 01 3/99 Solvent BG* Tetrapotassium pyrophosphate Sodi um metasi 1 i c a t e pentahydrate KNA cumene sulphonate 40 Ammonia, 25% Balance water, fragrance, preservat ive


Basic F loor C1 eaner, L i aui d-B

Mar l i pa l 013/99 Marl owet 5622 Solvent BG* Tetrapotassium pyrophosphate Ammonia, 25% Balance water, fragrance, preservat ive


Floor Cleaner. f o r Everyday Use. Liauid-A

Marlon PS 65 L i poxol 12000* Marlamid DF 1218 Isopropanol* Fragrance Balance water, dyes tu f f


Floor Cleaner. f o r Everyday Use. Liauid-B

Mar l i pa l KF C i t r i c ac id Isopropanol* Fragrance Balance water, dyes tu f f

% 7.0 3.0 3.0 5.0 5.0 10.0 1 .o

t o 100

!% 3.0 4.0 20.0 3.0 1 .o

t o 100

% 5.0 6.0 1.5 20.0

0 . 5 t o 100

!% 3.0 0.2 25.0 0.5

t o 100


SOURCE: Huls America, I n c . : Basic Formulations o f Detergents and Cleaning Agents f o r Household Purposes

&g, Floor, Catpet, Upholstery ShampOchF and Cleaners 131

CarDet and UDhol s t e w C1 eaners Dry-Foam C 1 eaner. L i aui d-A

M a r l i n a t SRN 30 Methacry la te copolymer, e.g. Syntran 6520 N i t r i l o t r i a c e t a t e powder Balance water, f ragrance, p rese rva t i ve


Dry-Foam C1 eaner . L i aui d-B

M a r l i n a t SRN 30 N i t r i l o t r i a c e t a t e powder Balance water, f ragrance, p rese rva t i ve


Dry-Foam Cleaner. Powder-A

M a r l i n a t SRN 30 Methoxypropanol Technocell 90 DU Balance water, f ragrance, p rese rva t i ve


Dry-Foam Cleaner, Powder-B

M a r l i n a t DFK 30 Methoxypropanol Technocell 90 DU Balance water, f ragrance, p rese rva t i ve

% 3 0 . 0 20.0

1 .o t o 100

% 40.0

0.5 t o 100

% 5 . 0 5 . 0

50.0 t o 100

% 5.0 5.0

50.0 t o 100


SOURCE: Hu ls America, I n c . : Bas ic Formulat ions o f Detergents and Cleaning Agents f o r Houaehold Purposes


Carpet Shampoo, Hiah Foam

Water Pe t ro BAF L i q u i d W i t c o l a t e WAC-LA

B lend ing Procedure: Blend i n g r e d i e n t s i n t h e order l i s t e d .

%__by Weigh2 10.0 15 .0 75 .0

Pe t ro BAF, i n combinat ion w i t h sodium l a u r y l s u l f a t e , reduces t h e low temperature c loud p o i n t , g i v i n g e x c e l l e n t f reeze/thaw p r o p e r t i e s . The Pet ro BAF combinat ion d r i e s l e s s tacky than sodium l a u r y l s u l f a t e alone.

Formula 911

Carpet. Shampoo, H i &h -Foam

Water Pe t ro BAF L i q u i d W i t c o l a t e WAC-LA

?4 by Weight 78 .3

5 . 0 1 6 . 7

B1 endi ng Procedure: Blend i n g r e d i e n t s i n t h e order l i s t e d .

Pe t ro BAF, i n combinat ion w i t h sodium l a u r y l s u l f a t e , reduces t h e low temperature c l o u d p o i n t , g i v i n g e x c e l l e n t f reeze/thaw p r o p e r t i e s . The Pe t ro BAF combinat ion d r i e s l e s s tacky than sodium l a u r y l s u l f a t e alone.

Formula 908


Rug Floor, Carper, Uphktety Shampoos and Cleaners 133

Evaporative (No Rinse) Wax S t r i ppe r Formula FC-0056

Miranol JEM Concentrate Monoethanol ami ne Butoxyethoxypropanol Isopropanol Water

Procedure

Phvsi c a l ProDerti es

Add t h e ingredients and mix u n t i l uniform.

Appearance: Clear s o l u t i o n pH, as i s : 1 1 . 4 Viscos i ty : t 1 0 cps Spec i f i c Grav i ty : 0.97

Waxed F loo r Cleaner Formula FC-0055

Rhodaf ac RA-600 A1 kami de DC 212/S Tetrapotassium Pyrophosphate (60% Act ive) Water

Wt.% 0.5 6.5 2.5

1 9 . 0 ' 72 .5

Wt.% 5.0 1 . o

25.0 69.0

=Q

a f t e r each add i t i on . Add ingredients one by one, i n order l i s t e d above, mixing wel l

Phvsi c a l ProDerti es pH. as i s : 8.6 pH (1%): 8.6 V i scos i t y : 10 cps Spec i f i c Grav i ty : 1 . 0 4



F1 oor C l eaner Formula FC-0053

Rhodafac LO-529 Sodi um Tr ipolyphosphate Tetrasodium Pyrophosphate Water

Wt.% 6.0 3.0 3.0

8 8 . 0

Procedure 1. D isso lve s o l i d s i n t h e t o t a l amount o f water. 2. Add Rhodafac LO-529. Mix thorough ly .

Phvsi c a l ProDert i es pH, as i s : 13.9 pH (1%): 8.9 V i s c o s i t y : 60 cps S p e c i f i c G r a v i t y : 1.09

F l o o r Cleaner Formula FC-0054

Wt.% Rhodafac LO-529 5.0 A1 kami de DC-212/S 1 .o Tetrasodium Pyrophosphate (65% Ac t i ve ) 2.0 T r i sodi um Phosphate 1 .o D ie thy lene Glyco l Monoethyl Ether 1 .o Water 90.0 Perfume and Co loran ts added, as des i red , r e p l a c i n g water

Procedu r e 1. D isso lve Tetrasodium Pyrophosphate i n water. Add Tr isodium

2. Add Rhodafac LO-529 and Alkamide DC-212/S. 3. Add so lvent .

Phosphate. D i sso l ve thorough1 y .

1 pH. as i s : 11.0 pH (1%?: 9.0 V i s c o s i t y : 290 cps S p e c i f i c Grav i t y : 1.01


F l o o r P o l i s h Mor-Glo 2-457 20% S o l i d s

Use w i t h low speed spray b u f f i n g and h igh speed maintenance programs us ing p l u g - i n e l e c t r i c burn ishers and s y n t h e t i c pads. Produces h ighe r i n i t i a l g loss than t h e 442 fo rmu la t i on . Can be burn ished d a i l y o r on an i n t e r m i t t e n t schedule w i thou t p roduc ing excessive amounts o f dus t . M u l t i p l e recoats o f 4-5 coa ts per a p p l i c a t i o n a re recommended w i t h 30-45 min. d r y i n g t ime depending on s o l i d s . Wi th these maintainance procedures a cons is ten t h i g h l e v e l o f appearance can be sus ta ined over an extended p e r i o d o f t ime.

___ Item: 1 2 3 4 5 6 7 8 9

10

Components: Wei Qh t Water D ie thy lene Glyco l Monoethyl Ether T r i bu toxyethy l Phosphate F luorad FC-129 (1% a c t i v e s o l u t i o n ) A n t i foam Emu1 s i on* Proxel GXL Mor-Glo 2 Latex (38%) Morton Conrez 510 (25% s o l u t i o n ) AC-325 An ion ic (35%) E-43 Nonionic (40%)

Percent 47.07

3 .37 2 .95 0 .50 0.02 0 .10

39 9 49 1 .oo 2 .51 2 .19

Procedure: Wi th good a g i t a t i o n add t h e components i n t h e order l i s t e d .

A f t e r t h e a d d i t i o n o f i t e m #6, a l l o w t o mix f o r 30 min. b e f o r e con t inu ing . Add t h e remaining components s low ly .

Formula t ion Constants: Polymer/Resin/Wax Ra t io : 90/0/10 Typ ica l pH: 8 . 5 Formula t ion Dens i ty : 8 .54 l b s . / g a l . S p e c i f i c G r a v i t y : 1.026

TvDi c a l Densi t y Val ues: __- S o l i d s : Pounds/Qal.

2 5% 8.60 20% 8 .54

S p e c i f i c G r a v i t y 1.032 1 .026

15% 8 .49 1.019

*SAG 1010 f rom Union Carbide Corp., o r SWS 211 f rom Wacker S i 1 icones Corp.

SOURCE: Morton I n t e r n a t i o n a l , I n c . : Formula Mor-Glo 2-457 20% Sol i d s

Rug, Floor, Carpet, Upholsfery Shampom and Cleaners 135


Floor Po l i sh ML-870-389 20% So l i ds

Use w i t h low speed spray b u f f i n g and high speed maintenance programs. This product maintains a h igh i n i t i a l g loss and can be burnished on an i n t e r m i t t e n t schedule. With these maintenance procedures, a consistent h igh l e v e l o f appearance can be sustained over an extended pe r iod o f t ime. Up t o f i v e coats per app l i ca t i on may be appl ied w i th 30-45 min. d ry ing t i m e depending on s o l i d s and condi t ions.

Item: 1 2 3 4 5 6 7 8 9 10 1 1 12

Components: Water Diethylene Glycol Monoethyl Ether T r i butoxyethyl Phosphate D i b u t y l Phthalate Igepal CO 977 F l uorad FC-129 (1% so lu t i on ) Ant i foam* Proxel GXL ML-870 Latex (38%) Morton Conrez 510 (25% so lu t i on ) AC-325 Noni oni c (35%) E-43 Nonionic (40%)

W_ei qht Percent 42.36 4.97 1.24 0.65 0.20 0.60 0.02 0.10 34.89 7.45 4.01 3.51

Procedure:

A f t e r t he add i t i on o f i tem #8, al low t o mix f o r 30 minutes before cont inuing. Add the remaining components s lowly.

Formulation Constants: Polymer/Resin/Wax Rat io: 74/10/16 Typical pH: 8.0 Formulation Density: 8.52 l bs . /ga l . Speci f i c Grav i ty : 1 .023

With good ag i ta t i on , add t h e components i n the order l i s t e d .

Typical Densi ty Values: Sol i ds : Pounds/Gal . Speci f i c Grav i ty 2 5% 8.57 1.029 2 0% 8.52 1.023 15% 8.47 1.017

*SAG 1010 from Union Carbide Corp., o r SWS 211 from Wacker

SOURCE: Morton I n t e r n a t i o n a l : Formulation ML-870-389 20% Sol ids

S i 1 i cones Corp.

Water SXS-40% Sodi um Bicarbonate STPP Burcosperse AP-Liq Burco LAF-6

Water Burcoterge DG-40 Burcosperse AP-Liq Propylene Glycol So rb i to l 70% Burcotase SL-80

Rug, Floor, Carpet, Upholsfery Shampom and Cleaners 137

L i aui d Carpet Cleaner

Carpet S ta in Remover-Liauid

Carpet Cleaner/Booster-Dry Destai ner

Burco LAF-6 Soda Ash FB-Sodi um Percarbonate

% bv We- 72.5 10.0 5.0 5.0 5.0 2.5

% by Weight To 100

40 10 20 15

0.5-1 . o

96 bv Weipht 2.0-6.0 40-60 40-60

Above a l so e l iminates odors such as those caused by pet ur ine.

General ly 5 ounces o f above added t o 5 ga l lons o f detergent Oxidizes s ta ins such as cof fee, wine, j u i ce , e t c .

s o l u t i o n i s s u f f i c i e n t f o r good performance.

SOURCE: Bur l ington Chemical Co., Inc. : Suggested Formulations


Low Cost Ex t rac t i on CarDet Cleaner

Water, D . I . Petro 22 Powder EDTA Powder Perfume

Blending Procedure:

Use D i l u t i o n : 1-2 ot /ga l o f water

Formula 901

Blend ingredients i n the order l i s t e d .

% bv Weight 91 . o

5.0 4.0 Q . S .

Medium Cost Steam Ex t rac t i on Carpet Cleaner

Water, D . I . Petro 22 Powder Sodi um T r i po l yphosphate Sodium S i l i c a t e 42 Be' (Star)* T r i sodi um Phosphate, Crystal DeSonic 9N Perfume

*Pa Corp.

Blend ingredients i n the order l i s t e d 01 end1 ng Procedure:

Use D i l u t i o n : 1-2 oz/gal . o f water

Formula 902

% bv Weight 76.5

3.5 5.0 9.0 2.0 4.0 q . s .

Premium. Heavy Duty Steam Ex t rac t i on Carpet Cleaner

Sodium Tripolyphosphate, L igh t Density Sodium Metas i l i ca te , Pentahydrate Petro 22 Powder Opt ica l Br ightener

01 endi ng Procedure:

Use D i l u t i o n : 1-2 oz/gal

Formula 906


Blend ingredients i n the order l i s t e d .

% by Weight 40.0 54.5

5 . 0 0 . 5

Rug, Floor, Carper, Upholstery shonrpocrs and Cleaners 139

Non-Ammaniated F loor S t r i m e r

Water Sodium Metas i l icate, Pentahydrate Monoethanolamine Potassium Hydroxide, 45% Witcamide S-771 Buty l Cel losolve Witconate SXS L i q u i d

%-by Weight 65.44

1 .oo 16.25 3.25 8.00 4.06 2.00

Blending Procedure:


Typical Propert ies: Sol ids: 13.3% pH, as i s : 13.3


Formula 924

Non-Ammoniated F loor S t r i m e r

Monoethanolamine Witcamide S-771 Buty l Cel losolve

9b bv Weiaht 40.0 20.0 40.0



Typical Propert ies: Sol ids: 20.0% pH, as i s : 11.4


Formula 923


I40 Advanced Cleaning R h t FormJatiotu

Quarry T i l e Cleaner

I n q r e d i e n t s : Water Bi o -Sof t S-1 00 Makon 10 Hydroxy A c e t i c Ac id (70%) HC1 (37%)

M i x i ng Procedure :

Typ ica l P roper t i es :

Mix thorough ly i n o rder g iven .

Appearance: L i g h t ye l low, c l e a r l i q u i d p H , as i s : 1.87 S p e c i f i c G r a v i t y , g/ml: 1.01 V i s c o s i t y , @ 25C, cps: 15

S t a b i l i t y : 40F ( 7 days): Pass 75F ( 7 days): Pass 120F ( 7 days) : Pass Freeze/Thaw ( 3 c y c l e s ) : Pass

% bv WeiQht 88.0

4 .0 3.5 3.0 1 . 5

Use I n s t r u c t i o n s :

pour concent ra te d i r e c t l y on. Spread w i t h mop and leave f o r t e n minutes. Scrub and squeegee, r i n s e w i t h water . Dry w i t h c lean mop.

leave f o r f i v e minutes, then scrub, r i n s e , and d ry .

SOURCE: Stepan Co.: Formula t ion No. 582

One t i m e o n l y : Heav i l y s o i l e d f l o o r : wet f l o o r w i t h water and

D a i l y Cleaning: 4 oz/l ga l water d i l u t i o n . Apply w i t h mop and

L o w Foam Floor Cleaner

Water Sodium M e t a s i l i c a t e (Anhydrous) Tetrapotassium Pyrophosphate Mona NF-10

% by Weisht 70

5 14 11

Procedure: Add i n g r e d i e n t s i n t h e order l i s t e d w i t h a g i t a t i o n .

Typi c a l Proper t i es : Cloud P o i n t : 93C K r a f t P o i n t : C O C

Recommended Use D i l u t i o n : 1 t o 4 o z . / g a l .

SOURCE: Mona I n d u s t r i e s , I n c . : Formula t ion F-545

Rug, Floor, Carpet, Uphoktery Shampoos and Cleaners 141

SDeci a1 -PurDose F loo r C1 eaner . L i aui d-A

Marlon A 365 Marlophor ND-DEA-salt Marlowet T or 5622 Na cumene sulphonate 40 T r i ethanol ami ne* Tetrapotassium pyrophosphate Balance water, fragrance, preservat ive

Act ive matter: 16.5% Formulation A w i t h a n t i s t a t i c p roper t i es

Special-Purpose F loor Cleaner. L iauid-6

Marlon PS 65 Isopropanol* Lonzabac 12.30 N i t r i l o t r i a c e t a t e , 40% Balance water, fragrance, preservat ive

Act ive matter: 3.3% Formulation B w i t h microbic ida l p roper t i es

Wash-and-Wax Floor Cleaner. L i aui d-A

Mar l i pa l 013/79 Marlox FK 64 Marlowet 5622 N i t r i l o t r i a c e t a t e powder C i t r i c a c i d Wax emulsion. 15%. basis Vestowax AW 1060* Balance water, fragrance, preservat ive


%

5.0 10.0

5.0 10.0 4.0 6.0

t o 100

% 5.0

25.0 3.0 0.5

t o 100

% 5.0 3.0 2.0 0.2 0.3 10.0

t o 100

Wash-and-Wax F1 oor Cleaner, L i aui d-B

% Marl i pa l 01 3/60 8.0 Marlowet 5622 2.0 N i t r i l o t r i a c e t a t e powder 0.2 C i t r i c ac id 0.3 Wax emulsion, 15%, basis Vestowax AW 1060* 10.0 Balance water, fragrance, preservat ive t o 100



14. Miscellaneous

142

Miscellaneous 143

Condensate TL: Typ ica l Formulat ions

A l l Purpose Cleaner Condensate TL Harco 20% Soap STPP Water

Bubble Bath Diethanolamine Laurel S u l f a t e (35% A c t i v e )

Stepanol DEA Condensate TL Water

D i l u t a b l e Shampoo(l:8) Diethanolamine Laurel S u l f a t e (35% Ac t i ve )

Stepanol DEA Condensate TL

Isopropanol H2S04 (conc.) (TO pH 7.0-7.5)

V i scous F loo r Cleaner Condensate TL TSPP STPP Harco 20% Soap Water

5 . 0 % 50.0%

1-2% To 100%

30.0% 5.0% 65.0%

60.0% 35.0%

1.15% 4%

9.0% 4.0% 4.0%

20.0% 63.0%

Di shwashi ne L i au i d Sodium Xylene Su l fonate 4.0% Dodecylbenzene S u l f o n i c Ac id 12.5% Noni on i c Detergent 6.0% Condensate TL 3.0% 50% Caust ic Soda Ad jus t t o pH o f 7 . 0 + - 0 . 5 SDA 3A Alcohol 2.0 Dye 8 Perfume Water To 100%

ODacif ied Hand SoaD Opaci f i e r Water So lub le Lano l i n Condensate TL Conc. Coconut/Veg. O i l Potash Soap Perfume 8 Dye Water

0.70% 1.25%

12.5% 20.0%

To 100%

SOURCE: Concord Chemical Co., I n c . : Suggested Formulat ions

I44 Advanced Cleaning product Formulations

d' Limonene Waterless Hand Cleaner

Phase I: Water, D.I. T r i sodi um Phosphate Sodium C i t r a t e G1 yce r i ne

Phase 11: d ' L i monene DeSonic 9N Varonic T202

% by Weight

81 .o 1 . o 2.0 2.0

7.0 5.0 2.0

Blending Procedure:

Heat t o 140F. Combine Phase I1 ingredients i n separate vessel and mix thoroughly. Heat t o 140F. While mixing rap id l y , add Phase I1 t o Phase I. Cool qu i ck l y t o s t a b i l i z e emulsion.

Typical Propert ies: Appearance, Room Temp.: Heavy Cream Sol ids: 12.0% pH: 10.4

I n vessel #1 combine Phase I ingredients and mix thoroughly.

Formula 1120

Water1 ess Hand C1 eaner

Emphos PS-220 Kerosene, deodorized Stoddard Solvent, deodorized T r i ethanol ami ne, 99% Water

% by Weight 8.7

37.9 15.4 2.2

35.8

81 ending Procedure:


Formula 1119


01 end i ngredi ents i n the order shown, m i x i ng thorough1 y

Miscellaneous 145

D r y Cleanina

By using Aerosol OT-100% Surfactant i n d ry c leaning solvent a t a concentrat ion o f ca. 0.1 oz. /gal . t he soaps used as a ids i n water-soluble s t a i n removal can be replaced i n t h e d ry c leaning indust ry . I n contrast t o many soaps, Aerosol OT does not ox id i ze w i t h consequent development o f undesirable odor upon aging.

Aerosol OT-100% dissolved i n a s u i t a b l e solvent, such as t r i ch lo roe thy lene . naphtha, carbon te t rach lo r i de , or comb- i n a t i o n s o f these, can be used t o remove solvent-soluble s ta ins a f t e r f a b r i c s have become wet w i t h water. The mixture can then be f lushed out w i t h add i t i ona l water.

As a whitener f o r k i d gloves, i t i s recommended t h a t 4 oz. o f Aerosol OT-100% be dissolved i n a ga l l on o f Stoddard solvent, t o which may be added from 4 t o 8 oz. o f z inc s tearate.

A water brushing f o r r e t a i n i n g p lea ts i s made by d i sso l v ing 4 oz. o f Aerosol OT-100% Surfactant i n one-half ga l l on o f Stoddard solvent, t o which i s added one p i n t o f wet spot ter and one-half p i n t o f water. The p leated items should be brushed thoroughly w i t h the mixture, then simply hung i n t h e a i r t o dry, t o e l im ina te water. The i tem should be re-cleaned w i t h solvent t o dispose o f t he other agents present. It w i l l come out wi thout wr ink les o r d is turbed p lea ts .

Sa t i s fac to ry s p o t t i n g mixtures can be made as fo l lows:

To1 uol 3 q t . Perch1 oroethyl ene 1 q t . Water 1/2 p t .

1 . Aerosol MA-80 Surfactant* 1 l b .

* I f Aerosol OT i s used instead o f Aerosol MA, t he mixture becomes t u r b i d when water i s added.

2. Aerosol OT-100% Surfactant 1 l b . Stoddard Solvent 2 ga l . Water 3 p t .

I n order t o increase the wet t ing out (reduce the break t ime) o f except ional ly greasy a r t i c l e s , t he use o f 0.25% to 1.0% of a 10% aqueous s o l u t i o n o f Aerosol OT Surfactant (based upon t h e weight o f t he water) i s resorted t o occasional ly i n laundry pract ices. During except ional ly busy periods, t he use o f 10% aqueous Aerosol OT so lut ions w i l l reduce the treatment t me and thus increase e f f i c i ency , although i t i s t r u e t h a t a k a l i together w i t h hot water over a longer treatment per iod w 11 accomplish the same r e s u l t s . A l k a l i w i t h hot water f i x e s egg albumin whereas Aerosol OT Surfactant does no t .



Dust Cont ro l

Areas o f Use:

o f t a l c o r face powder, m i l l i n g g r a i n and sawing wood are a l l f i r e , exp los ion and/or h e a l t h hazards. Such dus ty cond i t i ons can be a l l e v i a t e d o r c o n t r o l l e d by water sprays con ta in ing small amounts o f Aerosol GPG Sur fac tan t . Reasons f o r Using Aerosol GPO Sur fac tan t :

r a t i o n s o f o n l y 0.01% t o 0.05% o f Aerosol GPG Sur fac tan t i n water p rov ide e f f i c i e n t and economical we t t i ng . Areas t o be Sprayed:

c r e a t i o n o f dus t . Dusty m a t e r i a l s be ing conveyed may a l s o be sprayed. Th is p r a c t i c e no t o n l y minimizes t h e problem o f a i rbo rne dust, b u t s imultaneously reduces product l oss . Spray heads may be l oca ted a t as many l o c a t i o n s as have dust problems because t h e equipment requ i red i s moderate i n cos t and t h e r e i s no hazard t o personnel f rom Aerosol GPG Sur fac tan t .

Dust r e s u l t i n g f rom opera t ions such as mining coa l , p roduc t i on

Most dus ts a re r e s i s t a n t t o w e t t i n g by water alone. Concent-

Work sur faces may be wetted w i t h a f i n e spray t o prevent

Concentrat ions o f Aerosol GPG Sur fac tan t c We1 h t Ino red i en ts : Aerosol GPG Sur fac tan t Ethanol Water Ina red i en ts : Aerosol GPG Sur fac tan t Ethanol Water Ina red ien ts : Aerosol GPG Sur fac tan t Ethanol Water Ing red ien ts : Aerosol GPG Sur fac tan t Ethanol Water Ing red ien ts : Aerosol GPG Sur fac tan t Ethanol Water Procedure:

The s tock s o l u t i o n may stream by a p r o p o r t i o n i n g t h e f i n a l s o l u t i o n may be

- 1% 1.43 none

t o make 100 p a r t s - 5%

7.15

t o make 100 p a r t s - 10%

14.3

t o make 100 Dar t s

10-20

15-20

25% 35.7

10-15 t o make 100 Dar t s

- 50% 7 1 . 5

15-20 t o make 100 p a r t s

be in t roduced i n t o t h e main water DumD o r an eductor. The s t rena th o f . . ad jus ted by changing t h e amount o r

s t r e n g t h o f t h e s tock s o l u t i o n be ing added. The range o f s t reng th concent ra t ions shown i n t h e t a b l e above w i l l a l l o w any o rd ina ry method o f meter ing.

Fu r the r c o n t r o l may be prov ided by use o f ad jus tab le spray heads.


Miscellaneous 147

Hand and Body Cleanser

Phase I: Water, D . I . Witconate AOS Varonic LI-48 Varonic LI-67 Ethylene Glycol Monostearate Varamide ML-1

Phase 11: Glycer ine Lanoquat 50 EDTA Rewoteric AM 8-15

Phase 111: C i t r i c Acid

Phase I V : Sodium Chlor ide

Phase V: Preservat i ve

96 by Weight

67.0 20.0 3.7 1.3 1.6 2 . 5

0.2 0.5 0.1 3.1

q.s.

q.s.

q.s.

Blending Procedure: Heat Phase I water t o 8OC. Blend i n Witconate AOS w i t h good

a g i t a t i o n . When t h i s i s blended completely, add the remaining Phase I ingredients , mel t ing them f i r s t before adding. Cool t o 45C and add Phase 11, i n the order l i s t e d . Cool t o 35C and adjust pH = 7.0-7.7 w i t h c i t r i c acid. Add sodium ch lo r i de t o desired v i scos i t y .

Typical Propert ies: Sol ids: 19.5% pH: 7.3



Heavv Dutv Deareaser

Butoxyethanol Mac kam JS Sodium Metas i l i ca te Pentahydrate Sodi um T r i po l yphosphate T r i sodi urn Phosphate T a l l O i l Fa t t y Acid KOH (45%) EDTA (40%) Deionized Water

Procedure: 1. Add components t o water and heat t o 40C. 2 . Blend u n t i l c l e a r .

Mackamide CD TKPP Glycer in Mackadet 40K

Procedure:

Burni sh i na Colnpound

(Cocami de DEA)

(Potassium Coconut Soap)

Weiqht,% 8 . 0 3.5 3.0 1.5 2.5 2.0 2.1 0.3 77.3

Wei qht .% 93.0 1.5 2.7 2.7

1. Disperse TKPP i n Glycer in and add Mackadet 40K. 2. Then blend i n Mackamide CD.

Remarks :

The product upon d i l u t i o n w i t h water w i l l form a cloudy emulsion which requi res shaking before use.

The f i n a l product w i l l form an almost water c l e a r product.

Corrosion I n h i b i t i n g Coating O i 1 -Emulsi f iable

Wei aht .% Mackazoline 0 (Oleyl Hydroxyethyl Imidazol ine) 16.5 L igh t Mineral O i l 75.0 Glac ia l Acet ic Acid 1.5 Ole ic Acid 7 .0

Procedure: 1. Blend Mackazol i n e 0 and Mineral O i 1. 2. Add Acet ic Acid and Ole ic Acid. 3. Blend u n t i l c l ea r .

SOURCE: McIntyre Group Ltd. : I n d u s t r l a l Formulary

Miscellaneous 149

Heavy D u t y I n d u s t r i a l Spray Metal Cleaner Concentrate

Water Potassi um Hydroxide Sodium M e t a s i l i c a t e (Anhydrous) Sodium Carbonate Mona NF-25

% by Weiaht 65 10 10

5 10

Procedure:

Typ ica l P roper t i es : Cloud P o i n t : 43C K r a f t Po in t : C O C

Add i n g r e d i e n t s i n t h e order l i s t e d w i t h a g i t a t i o n .


Formula t ion F-544

Low Foam Hypoch lo r i t e Cleaner

I n redients;. water Sodium Hypoch lo r i t e (5.25%) Mona NF-10

% bv Wei qh t 79.0 19.0

2 . 0

Procedure: Blend i n g r e d i e n t s i n o rder l i s t e d . Ad jus t pH t o 13-14 w i t h 45%

KOH . Formula t ion F-655


Metal CleanerJBri nhtener

Eastman EB so l ven t C i t r i c a c i d Phosphoric a c i d (85%) Nonionic s u r f a c t a n t * Water

% by WeixhL 4.5 4.0 2.5 3 .0

86.0

*Such as Neodol 91-8 a l coho l e thoxy la te (She l l Chemical Co.) o r Rhodasurf LA-9 a lcoho l e thoxy la te (Rhone-Poulenc).

SOURCE: Eastman Chemical Co.: Eastman EB and DB So lvents f o r Cleaners: Suggested Formula t ion


Hot l a n k - StripperjCleaner/Deruster

Component: Caust ic Potash Crys ta l Anhydrous Sodium M e t a s i l i c a t e Burco BSGH-270 o r BSGH-Crystals Burco ADS-100 Burco TME Dodecylbenzenesulfonate Powder

10.0 15.0

5.0 2.5 5.0

Procedure:

on to m ix tu re and b lend u n t i l f u l l y absorbed. Add 8urco ADS-100, Gluconate o r Glucoheptonate and Dodecylbenzenesulfonate. Blend u n t i 1 un i fo rm.

inc rease p a i n t s t r i p p i n g e f f i c i e n c y prov ided s u f f i c i e n t a l k a l - i n i t y i s present. The Gluconate o r Glucoheptonate p rov ide t h e de rus t i ng . Burco TME and 8urco ADS-100 prov ide removal and d i sp - e r s i o n o f p a r t i c u l a t e s o i l s w h i l e t h e Dodecylbenzenesulfonate adds w e t t i n g and o i l y s o i l detergency. Each component can be ad jus ted according t o t h e improvement needed.

Blend Caust ic Potash and Sodium M e t a s i l i c a t e . Spray Burco TME

Each component has a s p e c i f i c f u n c t i o n . The M e t a s i l i c a t e w i l l

~~ Low Foam _Heavy Duty A1 k a l i ne C l eaner-A

CommDonent: %. bx_Wei.&t Water 58 Sodium M e t a s i l i c a t e , Pentahydrate Burcene 100 Burcosolv TM Burco TME Burcowet TM-LF

5 2

10 20

5

Procedure:

eous between each a d d i t i o n . Add a l l components i n t h e order l i s t e d . S t i r u n t i l homogen-

Formulat ion A i s low foaming a t temperatures above 160F.

Low Foam Heavy-Duty A1 k a l i ne. Cleaner-6

Component: Water Sodium M e t a s i l i c a t e , Pentahydrate Sodi um Xylene Sul fonates 40% Burcosolv TM Burco TME Burco LAF-125

% by Weight 55 5 8.5

10 20

5

Procedure:


SOURCE: B u r l i n g t o n Chemical Co., I nc . : Suggested Formulat ions

Add a l l components i n t h e order l i s t e d . S t i r u n t i l homogeneous

Formulat ion B i s low foaming above 1OOF.

Miscelloneous 151

Pai n t Brush C1 eaners

Aerosol C-61 Surfactant i s a c a t i o n i c reagent t h a t w i l l a c t i v a t e s t rong ly the v o l a t i l e solvents commonly used f o r removing p a i n t . B r i s t l e brushes and r o l l e r s , glass, porce la in , metal, p l a s t i c , and c l o t h i n g have been t rea ted successful ly. A 5 1 0 % s o l u t i o n o f Aerosol C-61 i n a solvent, o r mixed solvents i s recommended.

Extremely rap id sedimentation o f p a i n t pigment has been obtained w i t h t h e fo l l ow ing composition:

Inaredi ents: Aerosol C-61 Surfactant Buty l Cel loso lve Solvent Xyl ene

% by Weight o r Volume

5 5

90

Brushes and r o l l e r s may be cleaned immediately a f t e r use by being suspended i n t h i s mixture. I n a few hours p r a c t i c a l l y a l l o f t he p a i n t pigment s e t t l e s i n a l aye r beneath the b r i s t l e s . The solvent mix ture may be reused repeatedly. When the pigment has s e t t l e d the brush may be removed and hung i n c i r c u l a t i n g a i r t o dry. For best resu l t s , t he brush then should be washed i n soapy water and r insed. I f the brush i s t o be used again immediately, i t may be r insed i n solvent instead o f d ry ing and waterwashi ng.

w i t h hard, dry pa in t , t h e fo l l ow ing formulat ion has proved suc- essf u l .

For renovat ing brushes t h a t have been allowed t o become caked

Ingredients : Aerosol C-61 Surfactant Xyl ene Butanol Mineral Spi r i t s

?4 by Weight o r Volume

10 45

5 40

The brush i s soaked i n the mixture f o r a time, then worked up and down t o a i d the penetrat ion i n t o the caked p a i n t . The soaking and working may be repeated several t imes i f the p a i n t i s very hard and d ry . When the o l d p a i n t has soaked out o f t he brush, t h e brush i s r insed i n clean, warm water and f i n a l l y washed i n soapy water and r i nsed again, then hung up t o d ry . A f t e r being d r i e d t h e b r i s t l e s have the appearance and f e e l of those o f a new brush.



Steam Cleaner

Water Potassi um Hydroxide Sodium M e t a s i l i c a t e (Anhydrous) Tetrapotassium Pyrophosphate Mona NF-15

% by WeiQht 65

3 10 10 12


Typ ica l P r o p e r t i es : Cloud P o i n t : 75C K r a f t P o i n t : >OC


Formula t ion F-541

Water Sodium Hydroxide (50%) Mona NF-25

Helvy Duty Indus-ray c l e a n e r Concentrate

% by Weigh% 40 50 10


Typ ica l P r o p e r t i e s : Cloud P o i n t : 75C K r a f t P o i n t : >5C


Formula t ion F-543

H igh Sol i ds A1 k a l i ne C1 eaner

Water Potassium Hydroxide Sodium M e t a s i l i c a t e (Anhydrous) Tetrapotassium Pyrophosphate Mona NF-25

% bv Weiclht 45.0 10 .0 10 .0 25.0 10.0

Procedure: Mix i n g r e d i e n t s i n t h e order l i s t e d w i t h a g i t a t i o n .

Formula t ion F-555


Miscellaneous 153

Wall DaDer Removal

A s tock s o l u t i o n o f Aerosol OT-75% Sur fac tan t , o r a powder con ta in ing Aerosol OT-B Sur fac tan t can be prepared f o r use as a wal lpaper remover. D i l u t e d w i t h water by t h e user t o a con- c e n t r a t i o n o f 0.025% Aerosol OT, t h e s o l u t i o n i s h i g h l y e f f e c t - i v e i n soaking o f f o l d wal lpaper, and o f t e n renders t h e use of an expensive and bu lky steamer unnecessary.

A t y p i c a l l i q u i d concent ra te wal lpaper remover can be prepared as fo l l ows .

I nq red i en ts : Aerosol OT-75% Sur fac tan t I sop ropy l Alcohol Water

% by Weisht 15.0 15.0 70.0

D i r e c t i o n s : Use one tablespoon o f t h e above fo rmu la t i on per g a l l o n o f

warm water. Apply t o a l a r g e sec t i on o f wal lpaper and w a i t a few minutes. I f necessary, apply again.

Aerosol OT-B Sur fac tan t : The f o l l o w i n g powdered concent ra te may be prepared us ing

Inq red ien ts : Sodium S u l f a t e (Powder) Aerosol OT-B Sur fac tan t

% by Weiqht 90.0 10.0

D i r e c t i o n s :

recommended above.

SOURCE: Cytec I n d u s t r i e s , I nc . : Suggested Formulat ions

Use one teaspoonful per g a l l o n o f warm water and apply as

Section II Transportation Cleaners

and Polishes

154

15. Auto Cleaners and Polishes

155


Auto Pol i sh/Cl eanser O i l i n Water Emulsion

Phase A: 1 Deionized Water 2 668 P o l i s h i n g Powder 3 Vo lc lay NF-BC Phase 0: 4 PEG-10 Carnauba

6 Montan Wax "S" 7 O l e i c Ac id 8 Morphol ine Phase C: 9 Odorless Minera l S p i r i t s

5 SF96-350

% by Weiqht 40.5 15.0

1 . o

7.0 4.0 2.5 1 .5 1 .o

27.5

Procedure:

hydra te f o r 15 minutes. B r ing temperature up t o 75C. I n a separate vessel , combine Phase B and w h i l e mixing, b r i n g temperature up t o 85C t o me l t t h e waxes. Gent ly heat t h e minera l s p i r i t s t o 65C and add t o Phase 0. Once un i fo rm and a 75C temp- e r a t u r e i s reached, s low ly add t h i s t o Phase A, ma in ta in ing good a g i t a t i o n . Continue mix ing u n t i l emulsion coo ls t o 40C. Pour i n t o app rop r ia te conta iners .

emulsion, w h i l e p rese rv ing t h e s t reng th and i n t e g r i t y o f a n a t u r a l carnauba f i n i sh.

Combine Phase A under a g i t a t i o n and a l l o w t h e Vo lc lay t o

The PEG-10 Carnauba i n t h i s formula he lps t o c rea te a s t a b l e

Detergent Res is tan t Auto Pol i sh/Cleanser Paste Wax

1 Odorless Minera l Spi r i t s 2 787 P o l i s h i n g Alumina P-10 Fe ins t 3 Ozoker i te 170 4 #3 Carnauba 5 Syn the t i c Carnauba 6 SF1706 7 Hexanedi o l Behenyl Beeswax 8 V i s c a s i l 12M

% by WeiQht 57.0 12.0 8.0 6 .0 6.0 5.0 4.0 2.0

Procedure:

8OC. Mix u n t i l homogeneous. Add t h e alumina w h i l e mixing, and coo l t o 35c.

equal p a r t s o f #3 Carnauba and Syn the t i c Carnauba. Th is s u b s t i - t u t i o n has no e f f e c t on t h e f i n i s h e d product and w i l l y i e l d t h e same r e s u l t s . The o n l y d i f f e r e n c e i s a reduc t i on i n cos t .

SOURCE: Koster Keunen I n c . : Suggested Formulat ions

Combine a l l i ng red ien ts , l eav ing ou t t h e alumina, and heat t o

The #1 Yel low Carnauba i n t h i s formula has been replaced by

Auto Cleaners and Polishes 157

Carnauba Hotwax

Carnauba spraywax w i th excel lent performance and s t a b i l i t y i s produced using:

Inaredi ent : Mineral seal o i l Tomah Emu1 s i f i e r Four 9-10 mole ethox. nonionic Ethylene g l yco l monobutyl ether Water (70-9OF) Emulsion C-340

Wei aht% 9.0 6.9 0.3 1.3

67.5 15.0

Add ingredients sequent ia l ly and mix completely p r i o r t o each add i t i on . The carwash w i l l use the "hotwax" by d i l u t i n g 1:lO w i t h water and then i n j e c t i n g 6-8 0 2 . o f the d i l u t e product onto each car. The product w i l l not separate or g e l l .

Pressure Spray Truckwash

Water Sodium Metas i l i ca te Pentahydrate EDTA ( l i q u i d 46%) Tomah Q-17-2 Tomah AO-14-2 Texstim 0741 45% Caustic Potash Tomah A l k a l i Surfactant

Wei aht% 05.7 4.2 1.8 1 . o 1 .o 2.0 2.6 1.7

Texstim 0741 i s a nonionic sur factant which performs as a "sel f -demulsi fy ing" detergent. This i s extremely useful i n truckwash appl icat ions. I n most o i l /wa te r separators, the formulat ion " s p l i t " t he o i l and water i n t o two phases without f u r t h e r treatment. The o i l phase can then be skimmed o f f f o r recovery o r disposal and not be sent t o the sewage treatment p lan t .

SOURCE: Tomah Products, Inc. : Suggested Formulations


D e t e r q e n t R e s i s t a n t A u t o P o l i s h O i l i n Water Emuls ion

% bv Weight Phase A: 1 D e i o n i z e d Water 44.3 2 678 P o l i s h i n g Powder 8.0 3 V o l c l a y NF-BC 1 .o 4 Morpho l ine 0 . 7 Phase B: 5 I s o p a r L 1 8 . 0 6 I s o p a r M 8 . 0 7 PEG-I0 Carnauba 6 .0 8 S i l i c o n y l Beeswax 6 .0 9 SF96-350 3 .0 10 S t e a r i c A c i d 1 . o Phase C : 11 I s o p a r M 5 . 0 12 SF1706 2 .0 Procedure:

Combine Phase A under a g i t a t i o n and b r i n g tempera ture up t o 85C. I n a s e p a r a t e v e s s e l , combine Phase B and w h i l e m i x i n g , b r i n g t h e tempera ture up t o 9OC. Once b o t h phases a r e up t o tempera ture , add Phase B t o Phase A and m a i n t a i n moderate a g i t - a t i o n . S l o w l y c o o l and a t 60C add Phase C .

The S i l i c o n y l Beeswax p e r f o r m s w h i l e a p p l y i n g t h e p o l i s h b y c r e a t i n g a smooth, even c o a t i n g on t h e s u r f a c e o f t h e au tomobi le . The PEG-10 Carnauba t o g e t h e r w i t h t h e amine f u n c t i o n a l s i l i c o n e , g i v e s t h e p o l i s h e d s u r f a c e a deep g l o s s and an e x t r e m e l y d u r a b l e f i n i s h .

H i g h L u s t e r Auto F i n i s h Pas te Wax

1 Odor less M i n e r a l S p i r i t s 2 I s o p a r L 3 I s o p a r M

5 #3 Carnauba 6 S y n t h e t i c Carnauba 7 O z o k e r i t e 170 8 Whi te Beeswax 9 V i s c a s i l 12M

4 SF96-350

% by Weight 49 .0 14.0 10.0 8 . 0 6 .0 6 .0 3 .0 2 .0 2 . 0

Procedure: Combine a l l waxes and s i l i c o n e s . Heat t o 85C. W h i l e m i x i n g ,

s l o w l y add t h e s o l v e n t s . Cont inue m i x i n g and c o o l t o 40C. Equal p a r t s o f #3 Carnauba and S y n t h e t i c Carnauba a r e used

w i t h t h e i n t e n t i o n s o f t h e s e b e i n g a d i r e c t s u b s t i t u t e f o r #1 Y e l l o w Carnauba. The #3 Carnauba and S y n t h e t i c Carnauba w i l l y i e l d t h e same r e s u l t s as #1 Y e l l o w Carnauba, b u t a t a s i g n i f - i c a n t c o s t s a v i n g s .

SOURCE: K o s t e r Keunen I n c . : Suggested F o r m u l a t i o n s

Auto Cleoners ond P o l i s h 159

High Gloss, Detergent Res is tan t P o l i s h

Formula t ion 20-6 i s a wax-free p o l i s h , which p rov ides a h igh- g loss , de tergent r e s i s t a n t f i n i s h on non-porous subs t ra tes . Simple a p p l i c a t i o n , w i thou t hard rubb ing o r b u f f i n g r e s u l t s i n bo th depth o f g loss and de tergent res i s tance f o r extended p r o p e r t i e s .

I ng red ien ts : ( 1 ) GP-121 S i l i c o n e P o l i s h A d d i t i v e ( 2 ) GP-10-1,000 S i l i c o n e F l u i d ( 3 ) Stoddard So lvent ( 4 ) Minera l S p i r i t s (Odor less) ( 5 ) Witcamide 511 (6 ) Kaopo l i t e SF (7) S o f t Water ( 8 ) Giv-Gard DXN

Combine i n o rder shown w i t h h igh shear m ix ing un t i n g occurs. Mix u n t i l homogeneous and package.

Formul a t i on P roper t i es : *Contains no wax *Non-smeari ng *High g loss *Cost e f f i c i e n t *Detergent r e s i s t a n t *Cold b lend (0n ly mix * E a s i l y a p p l i e d *Res is tan t t o wash-o

Formula 20-6

High Gloss Auto P o l i s h f F i n i s h

% by weight 13.0 2.0 5.5

1.4 5.0

67.5 0.1

5.5 ,

1 th i cken -

ng requ i red ) f

Ing red ien ts : ( 1 ) GP-121 ( S i l i c o n e P o l i s h A d d i t i v e ) (2 ) Witcamide 511 (3) Kaopo l i t e SF ( 4 ) S o f t Water ( 5 ) Giv-Gard DXN

% by. Weight 26.0

1.4 5.0

67.5 0.1

Combine i n o rder shown w i t h h igh shear m ix ing u n t i l t h i c k e n i n g occurs. Mix u n t i l homogeneous and package.

Formula t ion P roper t i es : *Contains no wax *High g loss *Detergent r e s i s t a n t *Easi 1 y appl i e d *Non-smeari ng *Cost e f f i c i en t *Cold b lend Only mix ing requ i red

Formula 20-5

SOURCE: Genesee Polymers Corp.: Suggested Formulat ions


Spravwax Concentrate

The fo l l ow ing formula should produce a c lea r , s tab le spraywax concentrate.

Comonent: Kerr-McGee Mineral seal o i 1 Emul s i f i er 827 Ethylene g l yco l monobutyl ether Water (70-9OF)

Grams 18.0 15.0

4 . 0 63.0

D i r e c t ions :

monobutyl ether and m i x u n t i l c l ea r . Add water s lowly wh i l e mixing. When water has been added, mix about 5 more minutes. Add dye i f desired. Addi t ion o f a fragrance may requ i re a s l i g h t formulat ion change. The f i n a l product w i l l be c lea r and i s normally packaged i n 5 ga l l on p a i l s . The carwash should d i l u t e 5 ga l lons o f concentrate w i th 50 ga l lons o f water and then i n j e c t about 6 02s. o f the d i l u t e spraywax through a DEMA system onto each ca r .

Charge the mineral seal o i l , Emu ls i f i e r 827, ethylene g l yco l

Spraywax

The fo l l ow ing t y p i c a l formulat ion i s h igh l y e f f e c t i v e , problem f ree, and s tab le i n both concentrate and d i l u t e form.

Inaredi ent : Kerr McGee Mineral Seal O i l Emul s i f i e r Four-HF 9-10 mole ethoxylated nonionic Ethylene g l yco l monobutyl ether Tap Water

Weiaht % 20.0 15.0 1 .o 3.0

61 . O

Di rec t i ons :

nonionic, ethylene g l yco l monobutyl ether and mix u n t i l c l ea r . Add water s lowly wh i l e mixing. When water has been added, mix about 5 more minutes. Add dye i f desired. Addi t ion o f a f ragrance may requ i re a s l i g h t formulat ion change. The f i n a l product w i l l be c lea r and i s normally packaged i n 5 ga l l on p a i l s . The carwash should d i l u t e 5 ga l lons o f concentrate w i t h 50 ga l lons o f water and then i n j e c t about 6 0 2 s . o f the d i l u t e spraywax through a DEMA system onto each car .

SOURCE: Tomah Products, I n c . : Suggested Formulations

Charge the mineral seal o i 1, Emuls i f ier Four-HF, ethoxylated

Auto Cleaners and Polishes 161

Spravwax Ladder of Formulas

Because mineral seal o i l s d i f f e r i n emu ls i f i ca t i on char- a c t e r i s t i c s , i t i s necessary t o modify the formulat ion t o achieve optimum performance. The best formula can be deter- mined by running a ladder o f formulas. Typical examples are:

Comonent: Mineral seal o i l Emul s i f i er Four-HF 9-10 mole ethoxylated nonionic Ethylene g l y c o l monobutyl ether Water

Component: Mineral seal o i l Emul s i f i er Four-HF 9-10 mole ethoxylated nonionic Ethylene g l yco l monobutyl ether Water

Comoonent: Mineral seal o i l Emu ls i f i e r Four-HF 9-1 0 mole ethoxyl ated noni oni c Ethylene g l yco l monobutyl ether Water

Components: Mineral seal o i l Emul s i f i e r Four-HF 9-10 mole ethoxylated nonionic Ethylene g l yco l monobutyl ether Water

Grams-B 40.0 31 . O

1 .o 6.0

122.0

Grams-C 40.0 30.5

1.5 6 . 0

122.0

Grams-D 40.0 30.0 2.0 6 .0

122.0

Grams-E 40.0 29.5 2.5 6 .0

122.0

Check a l l formulas f o r : 1. 1: lO d i l u t i o n i n water. 2 . 120F s t a b i l i t y (3 hours i n sealed container i n water bath a t

3 . Freeze/thaw-24 hour recovery (sealed conta iner) .

The optimum formula w i 11 : 1. D i l u t e c l e a r and e a s i l y a t 1:lO dT lu t i on . 2. Not c loud at . 120F. 3. Recover completely from freeze/thaw cyc le (wi thout shaking).

SOURCE: Tomah Products, I n c . : Emu ls i f i e r Four-HF: Formulas

120F).

16. Car and Truck Wash Compounds

162

Car and Truck Wash Compounds 163

Automatic Car Wash Concentrate A High A lka l i ne D i l u t a b l e Concentrate

Inaredi ent : Oeioni zed Water Maphos 60-A Potassi um Hydroxide Tetrapotassium Pyrophosphate Sodium Metas i l i ca te , Anhydrous Macol LF-120 Mazamide 80 Sodium Xylene Sul fonate (40%) Macol 48 Oei oni zed Water

pH (as i s ) : 12.5-13.5 Appearance: Clear, l i gh t - ye l l ow l i q u i d Spec i f i c Grav i ty : 1.06

Procedure: Charge the f i r s t water p o r t i o n t o t h e mixing vessel and

s t a r t a g i t a t i o n . Add t h e ingredients i n the given sequence and mix u n t i l c l e a r . Notes :

This i s a h i g h l y a l k a l i n e cleaner designed t o be used i n commercial automatic car washes a t a d i l u t i o n r a t e o f 1-2 ounces per ga l lon. Do not use d i r e c t l y on automotive f i n i shes . Formula CA-102

Wt.% 50 .00

6 . 0 0 3.00 2.00 2.00 2.00 2 .00 3.00 3.00

27.00

General Purtmse Car Wash High Foami ng A1 1 -Purpose D i 1 u tab l e Concentrate

Ineredi ent : Wt.% Deioni zed Water 50.00 Mazon 98 9.50 Macol TD-3 1.50 SLS (Sodi um Lauryl Sul fate) 2.50 Mazamide 80 3.00 Macol 48 1 .oo Triethanolamine (85%) 1.50 Deionized Water 31 .OO

pH (as i s ) : 8.5-9 .5 Appearance: Clear, l i g h t - y e l l o w l i q u i d Spec i f i c Grav i ty : 1.02

Procedure: Charge t h e f i r s t p o r t i o n o f water t o the mixing vessel and

s t a r t slow a g i t a t i o n . Excessive a g i t a t i o n w i 11 produce a foami ng problem. Add the remaining ingredients i n the given sequence and mix u n t i l c l ea r . Notes:

t o be safe on car f i n i shes , yet e f f e c t i v e i n t h e removal o f road grime and other s o i l s .

Formula CA-103

SWRCE: Mazer Chemicals: Supposted Formulations

This i s a copious-foaming, al l -purpose car wash formulated

Use concentrat ion i s 1-2 ounces per ga l l on o f warm water.

164 Advanced Cleaning R h c t Formulations

Auto Shampoo Concentrate

Water, D.I. Rewoteric AM KSF-40 Wi tco late SE-5

% by Weight 80.0 15.0

5.0

Blending Procedure:

between each add i t i on . Typical Propert ies:

V iscos i ty , cps: 4.0 Sol ids: Q.O% pH: 9.5


Formula 628

High Foaming Car Wash

Water, D.I. D i ethanol ami ne Witco 1298SA Varox 1770 Buty l Cel losolve Sodi urn Metasi 1 i c a t e Sodium Tripolyphosphate

% by Weight 65.0

5.0 15.0 10.0

1 . o 1 . o 3.0


1298 i n t o so lu t i on . Next, add remai n i ng ingredients a1 lowi ng t o d isso lve completely between addi t ions. Typical Propert i es :

Viscos i ty . cps: 77.0 Sol ids: 27.5% pH: 9.3

Add DEA t o water and mix thoroughly. Slowly d isso lve Witco

Formula 631

Car Wash

Water Wi tco late A W i t c o l a te S-l285C Emcol NA-30 Preservat ive Blending Procedure:

Blend ing red ien ts i n the order l i s t e d . Typi ca l Propert i es :

Sol ids: 28.4% pH: 6.9 V i scos i t y , cps: Gel

Formula 623 SOURCE: Witco Corp.: Suggested Formulations

% by Wei aht 34.9 25.0 25.0 15.0 0.1

Car and l h c k Wash Compowrds 165

Car Wash L i q u i d Formula TR-0023

A1 k y l benzene s u l f o n i c a c i d Sodium xy lene s u l f o n a t e Igepa l CO-710 Tetrapotassium pyrophosphate (60% a c t i v e ) Potassium hydrox ide (45% a c t i v e ) Water

W t .% 6 . 0

11 .5 3 . 0

2 5 . 0 2 . 5

5 2 . 0

-

Procedure 1 . D i sso l ve a1 k y l benzene s u l f o n i c a c i d i n water. 2 . A d d sodium xy lene su l fonate , Igepa l CO-710, t e t rapo tass ium

pyrophosphate and potassium hydroxide, m ix ing w e l l a f t e r each a d d i t i o n .

3. F i l t e r p roduc t .

Phys ica l P r o p e r t i e s pH (as i s ) : 9 . 5 pH (1%): 9.9 V i s c o s i t y : 10 cps S p e c i f i c G r a v i t y : 1 .05

Car Wash Powder Formula TR-0022

Igepa l CO-710 Sodi um t r i po l yphospha te Sodium m e t a s i l i c a t e pentahydrate Sodium carbonate ( L t . d e n s i t y )

W t .% 1 0 . 0 50.0

5 . 0 35 .0

Procedure: 1 . Mix Igepa l CO-710 w i t h sodium t r i po l yphospha te . 2 . Add sodium m e t a s i l i c a t e pentahydrate and sodium carbonate

Phys ica l P roper t i es : Appearance: White, f r e e - f l o w i n g powder pH (1%) : 11 .2 S p e c i f i c G r a v i t y : 0 . 7 3


166 Advanced Cleaning Product Formulotiom

Igepa l CO-660 Cheel ox BF-13 Sodi um Xylene Sul fonate Water

Procedure 1 . D isso lve sodium xy 2. Add Igepa l CO-660.

Phys ica l Propert i-eg pH (as i s ) : 10.3 DH (1%): 10.1

Economy Truck Wash High-pressure Spray

(Formula TR-0024)

ene s u l fonate Mix thorough ly .

n water . Add Cheelox BF 13.

V i s c o s i t y : 10 cps Speci f i c G r a v i t y : 1 .02

Truck Wash L iqu id Formula TR-0025

Igepa l CO-630 Rhodapex CO-436 A1 kami de DC-212/S Cheelox BF-13 Ethy lene G lyco l Monobutyl Ether Water

W t .% 3.0 1 . o 1 .5

84.5

Procedure 1 . D isso lve s u r f a c t a n t s Igepa l GO-630, Rhodapex CO-436 and

2. Add Cheelox BF-13. Mix w e l l . 3. Add e thy lene g l y c o l monobutyl e the r .

Phys ica l PrQpe-rti 89 pH (as i s ) : 9.9 pH (1%): 9.6 V i s c o s i t y : 10 cps S p e c i f i c G r a v i t y : 1.01

A1 kami de DC-212/5 i n water .


W t .% 3.0 3.5 2.0 3 .5 3.0

85.0

Gar and h k Wash Compounds 167

Water, D . I . * Caustic Soda, 50% Witco 1298SA Witco late SE-5 Petro BAF L iqu id W i tcami de 128T Formal i n Sodium Chlor ide

Foamy Brush Car Wash. L i q u i d

% by Weight 79.75

1.40 5.00 7.00 3.00 3.00 0.10 0.75

Blending Procedure:

used t o ad just v i s c o s i t y o f t he product.

Typical Propert i es:

Blend ingredients i n the order l i s t e d . Sodium Chlor ide i s

Spec i f i c Grav i ty : 1.015 Wt./Gal. l bs . : 8.46 pH, as i s : 9.8 Viscos i ty , cps: 410

D i l u t i o n Rat io a t Wand = 1:40 * I f unsoftened tap water i s used, add 0.25% l i q u i d EDTA,

40% t o counteract hardness.

Formula 621

1:2 D i l u t a b l e Car Wash

Water Sodium Hydroxide, 50% Witconate SXS (40%) Witco 12988 W i tcami de 128T W i tcami de CDA

Blend4 ng Procedure:

Typi c a l Propert i es :

Blend ingredients i n t h e order l i s t e d .

Sol ids: 54.0% pH. as i s : 8.5 Viscos i ty , as i s , cps: 580 Viscos i ty , 1:2. cps: 440

Formula 622

SOURCE: Witco Corp.: Sugueated Formulations

% by Weight 33.71 5.96

14.90 25.88 16.76 2.79


High O i l S p l i t t i n g Vehic le Wash-A

Components: Water Sodium Metas i l i ca te Pentahydrate TKPP Sodi um Xylene Sul fonates 40% Burco TME

% by Weiqht 71.5 10.0

2 . 5 6.0

10.0

Add i n t h e order l i s t e d . Blend u n t i l d issolved between each add i t i on .

High O i l S D l i t t i n g Vehic le Wash-B

Components: Water Sodium Metas i l i ca te Pentahydrate Burcosol ADS-40 Glycol Ether Burco TME Burcotrope 1250

% by Weiqht 73.5 10.0

5.0 5.0

10.0 As Required

Add i n t h e order l i s t e d . Blend u n t i l d issolved between each add i t i on .

SOURCE: Bu r l i ng ton Chemical Co., I n c . : Suggested Formulations

Car and Truck Wosh Cornpout& 169

L i aui d Car Wash Formula TR-0020

Rhodapon SB Alcodet SK Rhodasurf 25-9 Tetrapotassium pyrophosphate Sodi um metasi 1 i c a t e Water Perfume Dye

Formula Formula A B

W t T % wtT% 1 8 . 0 18.0 ---- 8 . 0 --- 8 . 0

3.0 3.0 2.0 2.0

69.0 69.0 Q . S . Q . S . Q . S . Q . S .

Procedure

i n water. Add Rhodapon SB. Ag i ta te u n t i l c l ea r . Add Alcodet SK and Rhodasurf 25-9 and mix u n t i l uni form and c lea r . Add perfume and dye, as desired.

Physical ProDertiea

Dissolve tetrapotassium pyrophosphate and sodium metas i l i ca te

Appearance: Clear l i q u i d , dyed t o preference pH: 12.0 Spec i f i c Grav i ty : 1.03 V iscos i t y : t50 cps

Spray-On Car Wash Concentrate "Grease and Grime" Remover

Formula TR-0021

Rhodacal A-246/L Rhodacal 330 Rhodapon BOS Alcodet SK Water

Wt.% 5.0

20.0 3.3 5.0

66.7

Procedure: 1. Charge water t o a vessel equipped w i t h a g i t a t i o n . 2 . Add Rhodacal A-246/L and Rhodapon 00s t o ( 1 ) above. Mix u n t i l

3. Add Rhodacal 330 and Alcodet SK t o (2) above. Mix u n t i l

Phvsi ca 1 Proper t igp Appearance: Viscous, gel -1 i ke 1 i q u i d pH. as i s : 9.0 Spec i f i c Grav i ty : 1.02-1.04 V iscos i t y : t50 cps

uni form (5-10 minutes).

uni form (15-30 minutes).

SOURCE: Rhone-Poulenc Special t iem a Surfactmtm: Formulas

I70 Advanced Cleaning Product Formulotions

L i q u i d Hiah Pressure Concentrate

Water, D.I. Oowanol EB Witconate SXS L iqu id Sodium Benzoate Sodium Metas i l i ca te Tetrapotassium Pyrophosphate Varion AM-KSF-40%

% by Weiaht 46.0

2 . 0 1 .o 1 .o 10.0 20.0 20.0

Blending Procedure:



Formula 605


Truck Wash w/Vararide A-83

Water, D . I . Sodium Tripolyphosphate T r i sodi um Phosphate Sodium Metas i l i ca te Varami de A-83 Buty l Ce l l osol ve

% by Weight 81 . o

3.0 3.0 1 .o 9.0 3.0

Blending Procedure:


Typical Propert ies: V iscos i ty , cps: 1 2 Sol ids: 16.0% pH: 11.0

Formula 608



Car and Truck Wash Compounds 171

L i q u i d Truck Wash Formula TR-0029

Water Mi rano l FBS Igepa l CA-630 Dowanol EB (Dow Chemical ) Potassi um Hydroxide (45%) T a l l O i l Tetrapotassium Pyrophosphate Sodium M e t a s i l i c a t e , Pentahydrate

Wt.% 73.6

6.0 3.0 2.0 4.0 3.4 4.0 4.0

Procedure Premix t h e t a l l o i l and Dowanol EB. Add t h e water t o

t h e mixer . Add t h e sodium m e t a s i l i c a t e , t h e potassium hydroxide and t h e TKPP. Add t h e Mi rano l FBS and Igepa l CA-630. Add t h e t a l l oi l /Dowanol EB premix. Mix u n t i l uni form.

Phys ica l ProDer t ies Appearance: Clear, amber l i q u i d pH, as i s : 12.7 S p e c i f i c G r a v i t y : 1.08 V i s c o s i t y : 6 0 cps

L i q u i d Truck Wash Formula TR-0030

Water Mi rano l FBS Rhodafac RA-600 Igepa l CA-720 Cheel ox BF-13 Tet rapotass i um Pyrophosphate Potassi um Hydroxide (45%) Sodium M e t a s i l i c a t e Pentahydrate Arcosolv PTB

Wt.% 63.0

4 . 0 2.0 2.0

17.5 1 .o 6.0 2.0 2.5

Phvsl c a l P rooer t i es Appearance: C1 ear, ye1 1 ow 1 i qu i d pH, as i s : 12.9 S p e c i f i c Grav i t y : 1.10 V i s c o s i t y : <SO cps

SOURCE: Rhone-Poulenc Sur fac tan ts & Spec

Procedure Add t h e i ng red ien ts i n t h e order l i s t e d and mix u n t i l uniform.

as a1 t i 8s : Formu


M i l d Car Shampoo

A m i l d r i c h foaming car shampoo w i t h e x c e l l e n t detergency and sheet ing a c t i o n , I n a r e d i en ts : % ComDosi t o n W / W Sandobet SC 4.5 DDBSA, 60% 10.8 Sandoxylate SX-424 3 .6 Tr ie thano lamine 0 . 8 Dye, Fragrance, P rese rva t i ve , Water Q.S. Procedure:

Charge water t o m ix ing vessel w i t h moderate a g i t a t i o n . Ho ld ou t smal l p o r t i o n o f t h e water t o d i s s o l v e dye. Charge t h e r e - maining components i n sequence, mix ing a f t e r each a d d i t i o n . D isso lve t h e dye w i t h a g i t a t i o n i n t h e water p r e v i o u s l y h e l d ou t and add t o t h e produc t . P roper t i es :

Appearance: C1 ear 1 i qu i d

A p p l i c a t i o n : Use 1 t o 2 oz per 5 g a l l o n bucket SOURCE: Sandoz Chemicals Corp. : Formula t ion HHA-01

pH: 7.0-8.0

Carspray CW Concentrate

% by Weight Water, D . I . 80.0


s o l u t i o n i s homogeneous. Typ ica l P roper t i es :

S o l i d s : 11.6% Formula 632

Carspray CW 20 .0

Add Carspray t o water w h i l e mix ing . Continue mix ing u n t i l

Automotive "Wash 8 Wax"

% by Weiqht Witcamine AL42-12 6.9 Isopropanol 1 . o G l a c i a l A c e t i c Ac id 2.1 Water 65.0 Witcamide 5195 25.0 B lend ing Procedure:

Heat t h e m i x t u r e t o 70C and then add Witcamide 5195. Cont inue m ix ing u n t i l s o l u t i o n i s c l e a r .

T h i s f o r m u l a t i o n leaves a water "beading" f i l m on t h e automobi le f i n i s h ,

Formula 636

Mix a l l i n g r e d i e n t s except Witcamide 5195 i n t h e order l i s t e d .

SOURCE: Wi tco Corp.: Suggested Formulat ions

Car and Truck WaFh Compounds I73

Premium CarsDrav 500 Concentrate

Carspray 500 B u t y l C e l l oso l ve Minera l Seal O i l * Water, D . I .

?6 by Weight 20.0

5 . 0 25.0 50.0

*Kermac 600 So lvent : Ker r McGee O i l Co. D i a l a A O i 1 : Shel 1 Chemical I sopar V : Exxon Chemical

B1 endi ng Procedure :

thorough ly . I n a separate vessel weigh i n t h e water. Whi le m ix ing t h e water, pour i n t h e blend. Mix u n t i l s o l u t i o n i s homogeneous.

Use D i l u t i o n :

Combine Carspray, B u t y l Ce l l oso l ve and O i l i n vessel and mix

5 g a l l o n s Concentrate t o 50 g a l l o n s water.

Carspray 500: Beading Agent w i t h s i l i c o n e . Comments:

Formula 687

Standard Carspray 500 Concentrate

Carspray 500 B u t y l Cel l o s o l v e M ine ra l Seal O i l * Water, D . I .

*Kermac 600 So lvent : Ker r McGee O i l Co D i a l a A O i 1 : Shel 1 Chemical I sopar V : Exxon Chemical

% by Weipht 16.0 3.0

20.0 61 .O

81 endi ng Procedure: Combine Carspray, B u t y l Ce l l oso l ve and O i l i n vessel and

mix thorough ly . I n a separate vessel weigh i n t h e water. Whi le m ix ing t h e water, pour i n t h e b lend. Mix u n t i l s o l u t i o n i s homogeneous.

Use D i 1 u t i on :

Comments :

5 g a l l o n s Concentrate t o 50 g a l l o n s water.

Carspray 500: Beading Agent i n s i l i c o n e

Formula 688

SOURCE: Wi tco Corp.: Suggested Formulat ions


Premium Carspray 700 Concentrate

Carspray 700 Minera l Seal O i l * Water, D . I .

*Kermac 600 Solvent: Kerr McGee O i l Co. D i a1 a A O i 1 : She1 1 Chemical Isopar V : Exxon Chemical

%_by Wei qh t 25.0 25.0 50 .0

Blending Procedure:

heat t o l l O F w i t h thorough mix ing . I n vessel #2, weigh i n t h e water and mix u n t i l a vo r tex i s formed. Whi le mix ing t h e water, pour t h e b lend i n t o t h e vo r tex . Mix u n t i l s o l u t i o n i s homogeneous.


I n vessel #1, combine Carspray 700 and Minera l Seal O i l and

5 ga l l ons Concentrate t o 50 ga l l ons water.

Comments : Carspray 700: Foaming beading agent

Formula 685

Standard Carspray 70-0 Concentrate

Carspray 700 Minera l Seal O i l * Water, D . I .

*Kermac 600 So lvent : Kerr McGee O i l Co. D i a l a A O i l : She l l Chemical Isopar V : Exxon Chemical

% u Y A ! h t 16.0 16.0 68.0

Blending Procedure:

heat t o l l O F w i t h thorough mixing. I n vessel #2, weigh i n t h e water and mix u n t i l a vo r tex i s formed. While mix ing the water, pour t h e b lend i n t o t h e vo r tex . Mix u n t i l s o l u t i o n i s homogeneous.


I n vessel #1, combine Carspray 700 and Minera l Seal O i l and

5 g a l l o n s Concentrate t o 50 ga l l ons water.

Comments :

Formula 686


Carspray 700: Foaming beading agent

17. Whitewall Tire Cleaners

175


W h i t e Wal 1 T i r e C leaner

I n g r e d i e n t s : Sodium Metas i 1 i c a t e Sodium T r i p o l y p h o s p h a t e T e t r a p o t a s s i u m Pyrophosphate Sodium L a u r y l E t h e r S u l f a t e S o l i n (35%) Sandopan B Water (warm)

% b y . W t . 2.00 2.00 2.00 4.00 2.30 5.00

83.00

Procedure: Charge t h e w a t e r t o a vesse l w i t h good a g i t a t i o n . Charge t h e

f i r s t t h r e e components and m i x t i l l d i s s o l v e d . Charge t h e remain- i n g p r o d u c t s and m ix t i l l comp e t e l y d i s s o l v e d and f r e e o f g e l p a r t i c l e s .

P h y s i c a l P r o p e r t i e s : Appearance: C l e a r w a t e r whi p H ( a s i s ) : >9.0 T o t a l S o l i d s : 11.0-12.0%

Use L e v e l s :

e t o l i g h t y e l l o w l i q u i d

Fo r f i n a l use, d i l u t e between 4:l and B : l w i t h w a t e r

SOURCE: Sandoz Chemicals C o r p . : F o r m u l a t i o n HHA-03

Bug Remover C o n c e n t r a t e

T r i e thano lami ne (TEA) B u t y l C e l l o s o l v e I s o p r o p a n o l R e w o t e r i c AM 8-15

% by W e i . a 17.14 42.86 17.14 22.86

81 end ing Procedure: B l e n d t h e components i n t h e o r d e r shown. M ix u n t i l homogeneous

D i l u t i o n Ra tes : 1 : 2 E x t r a Heavy Du ty 1 : 4 Heavy Du ty 1 : 16 Medi um Du ty 1 :32 L i g h t Duty

D i 1 u t i on I n s t r u c t i o n s :

m i x i n g u n t i l homogeneous.

Comments:

Add Bug Remover C o n c e n t r a t e t o wa te r w h i l e m

Appearance @ 77F: C r y s t a l c l e a r , y e l l o w l i q u

SOURCE: W i t c o Corp . : Formula 677

Xing; c o n t i n u e

d

Whitewall Ere Cleaners 177

Whitewal l T i r e Cleaner Concentrate Formula TR-0031

Water Mi rano l FBS Sodium M e t a s i l i c a t e , Pentahydrate Potassium Hydroxide (45%) Butoxyethanol

Procedure

Phys ica l ProDer t ies

Add i n g r e d i e n t s i n o rder l i s t e d . Mix u n t i l un i fo rm.

Appearance: Clear, ye l l ow l i q u i d pH, as i s : 12.7 V i s c o s i t y : <50 cps S p e c i f i c G r a v i t y : 1.16

W h i tewa l 1 T i r e C1 eaner L i aui d Formula TR-0027

Igepa l CA-630 Rhodafac RA-600 M-Pyrol N-Methyl-2-Pyrrol idone ( I S P ) Sodium M e t a s i l i c a t e , Anhydrous Sodi um Tr ipolyphosphate Potassi um Hydroxide Water

Wt.% 48.0 22.0 25.0

3.0 2.0

Wt.% 2.0 6.0 2.0 3.0 5.0 1 . 5

8 0 . 5

Procedu PQ 1. D isso lve sodium m e t a s i l i c a t e , anhydrous, sodium t r i p o l y -

phosphate and potassium hydroxide i n t o water. 2. Add Igepa l CA-630, Rhodafac RA-BOO, and M-Pyrol separa te ly ,

m ix ing w e l l a f t e r each a d d i t i o n .

Phys ica l ProDer t iea pH (as i s ) : 13.3 pH (1%): 10.7 V i s c o s i t y : 10 cps S p e c i f i c Grav i t y : 1.03

SOURCE; Rhone-Poulenc Sur fac tan ts a S p e c i a l t i e s : Formulas

18. Miscellaneous

178

Miscellaneous 179

Automobi 1 e W i ndshi e l d Cleaners

Ina red ien ts : Aerosol MA-80 Sur fac tan t Su r fon i c N-95 Isopropanol Water

% by Weiaht 3.5 0.5 51 .o 45.0

The above i s d i l u t e d 5 oz. t o 1 g a l l o n o f water f o r use. I n w in te r t ime , t h e recommended d i l u t i o n i s 10 oz. per ga l l on . Freezi ng i s prevented by t h e i sopropanol . Thi s f o rmu la t i on leaves a small amount o f res idue on t h e unwiped p o r t i o n o f t h e wind- s h i e l d upon d ry ing . There are severa l ways o f p revent ing these v i s i b l e residues.

1 . Use a m ix tu re o f v o l a t i l e so l ven ts w i t h o r w i thou t su r fac tan ts . A suggested fo rmu la t i on i s :

I na red ien ts : 2-Ethyl Hexanol Aerosol OT-75% Sur fac tan t Isopropanol Water

% by Weiaht 5.0 1 . o

47.0 47.0

The above i s d i l u t e d 5-10 0 2 . per g a l l o n o f water, and w i l l n o t f reeze a t t h e h ighe r l e v e l o f concent ra t ion .

2. Using su r fac tan ts , bu t i n c l u d i n g small amounts o f non- v o l a t i l e so l ven ts which g i v e a t ransparent f i l m on t h e g lass w i t h t h e s u r f a c t a n t . Non-vo la t i l e so l ven ts having approximately t h e same r e f r a c t i v e index o f g lass should be se lec ted . A suggested fo rmu la t i on i s :

I nn red ien ts : Aerosol MA-80 Sur fac tan t Aerosol OT-75% Sur fac tan t D ie thy lene Glyco l Isopropanol n-Butyl-p-Hydroxy Benzoate Methyl-p-Hydroxy Benzoate Water

% by Weight 2.5 3.3 4.4

40.0 0 .1 0.1

49.78

The above concent ra te i s used a t 5 02. per g a l l o n (10 02'. per g a l l o n i n w i n t e r ) . The b a c t e r i c i d e s a r e present t o keep t h e window c lean ing s o l u t i o n f r e e o f s l ime and t u r b i d i t y due t o b a c t e r i a . I na red ien ts : % by Weight Aerosol OT-75% Sur fac tan t 3 .5 D i b u t y l ph tha la te 0.5-2.0 Isopropanol 40.0 Water 46-48

The above s o l u t i o n i s d i l u t e d 5-10 02. per g a l l o n o f water and w i l l no t f reeze a t t h e h igher l e v e l o f concent ra t ion .



General PurDose L i q u i d Boat Po l i sh - (1 1

M a t e r i a l s : Pa r t A: SF 96 (350) V i scasi 1 (10,000) O l e i c a c i d Isopar M Hoechst Wax E

Pa r t B: Water Morphol i ne Carbopol 934

Par t C: I sopar M SF 1706

Par t D: Snow Floss Super F loss

General Purpose L i q u i d Boat Po l i sh - (2 )

Mater i a1 s : Pa r t A: SF 96 (350) V i scasi 1 ( 10,000) O l e i c a c i d Isopar M Hoechst Wax E

Pa r t B: Water Morphol i ne Carbopol 934

Par t C : I sopar M SF 1706

Par t D: Kaopol i t e 1 1 68

Part/Wt (%Z

3.50 1 .oo 1.50

10.00 1.50

65.65 1.60 0.25

3.00 2.00

7.50 2.50

Part/Wt(%)

3.50 1 . oo 1.50 10.00 1.50

63.65 1.60 0.25

3.00 2.00

12.00

Procedure: 1.) Heat Par t A t o 90-95C. (2.) Heat Par t B t o 60-85C. 3.) Add Par t A t o Pa r t B w i t h good mix ing . 4 . ) When homogeneous, coo l t o 60-65C and add Par t C w i t h

cont inued h igh shear m ix ing . 5.) Add Par t D w i t h good mix ing . 6.) When un i fo rm, coo l and package i n s u i t a b l e con ta ine rs

SOURCE: GE S i l i c o n e s : Formula BP 2000

Miscellaneous 181

L i a u i d Aluminum Engine B lock Cleaner Formula TR-0032

Water Sodium Metasi 1 i c a t e , Anh Mi rano l FBS M i rano l JEM Conc. A lcodet HSC-1000 D-Limonene

W t .% 82.5

4.5 5 .0 2.0 4.0 2.0

Procedure Completely d i s s o l v e t h e sodium m e t a s i l i c a t e i n t h e water

Add t h e remaining components, w i t h a g i t a t i o n , i n t h e order l i s t e d . Premix t h e 0-Limonene w i t h t h e Alcodet HSC-1000 and add toge the r .

T y p i c a l PropertJ es Appearance: C lea r , ye l l ow t o amber l i q u i d pH, Conc.: 12.75 pH, 10%: 12.15 S p e c i f i c G r a v i t y : 1.04 V i s c o s i t y : t50 cps

Foami ng Engi ne C1 eaner Formula TR-0019

A lcodet 260 Rhodacal 330 Water Isopar " K " (Exxon)

W t .% 2 . 0 8.0

80.0 10.0

Procedure 1. Add A lcodet 260 and Rhodacal 330 t o water a t ambient temp-

e r a t u r e , s t i r u n t i l d i sso l ved (10-15 minu tes) . 2. Add I sopar K a t ambient temperature. S t i r u n t i l d i sso l ved

(30 minutes) . Physi ca l P roeer t i es

Appearance: C lear l i q u i d pH, as i s : 7 . 5 Speci f i c G r a v i t y : 0 .99 V i s c o s i t y : 10 cps


Section 111 Trademarked Raw Materials

182

Trademarked Raw Materials 183

RAW MATERIALS AC-325 Nonionic

ACL-59

Acrysol ICS-1

Aerosol A-102

Aerosol A-1 03

Aerosol C-61

Aerosol GPG

Aerosol MA-80

Aerosol 0s

Aerosol OT

Aerosol OT-B

Aerosol OT-75%

Aerosol OT-100%

Aerosol 22

AF 9020

Alcodet HSC-1000

Alcodet SK

Alcodet 260

A1 kami de DC-212

A1 kami de DC-212/M

A1 kamide DC-212/S

Aluminum Oxide FPTO

Ammonyx LO

CHEMICAL DESCRIPTION SOURCE Polymer A l l i e d

Ch lo r ina ted isocyanura te Monsanto

Water-soluble a c r y l i c r e s i n Rohm&

Mono-ester su l fosucc i na te Cytec

Mono-ester su l fosucc i na te Cytec

s u r f a c t a n t

s u r f a c t a n t

A1 k y l ami ne-guani d

Sodium d i o c t y l su

Sodium d ihexy l su

A1 k y l naphthalane

Sodium d i o c t y l su

ne e thoxy la te Cytec

fosucc i na te Cytec

fosucc ina te Cyt ec

ox ide su l fona te Cytec

fosucc i na te Cytec

Sodium d i o c t y l su l fosucc ina te Cytec

Sodi um d i o c t y l s u l fosucc i na te( 75%) Cytec

Sodi um d i o c t y l s u l fosucc i na te Cytec

Sul fosucc i namate Cytec

T e r t i a r y t h i o e t h e r su r fac tan t Rhone-

Cleaning s u r f a c t a n t Rhone-

Cleaning s u r f a c t a n t Rhone-

F a t t y a1 kanolamide ISP

F a t t y a1 kanolamide I S P

F a t t y a1 kanolanide ISP

Laurami ne ox ide Stepan


RAW MATERIALS Amphol y t JB130

Antarox BL-225

Antarox BL-240

Antarox BL-330

Aquamoll i n BC Powder

Arcosolv PTB

Avanel N-1525-90

Avanel S-70/5-74/ S-l50/590

BASF Sur fac tan ts

B r i t e s i l H24

Burcene 100

Burco ADS-40

Burco ADS-100

Burco BSGH-270

Burco BSGH-Crystals

Burco BSGH-400

Burco EHS

Burco FAE

Burco LAA-38

Burco LAF-6

Burco LAF-125

Burco NPS-225

CHEMICAL DESCRIPTION Coconut f a t t y a c i d amidopropyl

b e t a i ne

A l i p h a t i c po l ye the r non ion i c

on i c

on i c

A l i p h a t i c po l ye the r non

A l i p h a t i c po l ye the r non

Sol vent

Su r fac tan t

Sodi urn 1 i near a1 k y l po l ye ther su l fona te s u r f a c t a n t

P lu ron ic , P lu ra fac , I n d u s t r o l

Hydrous sodi um s i 1 i ca te

Sur fac tan t

Su r fac tan t

Su r fac tan t

Su r fac tan t

Su r fac tan t

Su r fac tan t

P r o p r i e t a r y t e x t i l e aux

Sur fac tan t

Su r fac tan t

P r o p r i e t a r y t e x t i l e aux

Sur fac tan t

l i a r y

1 i ary

SOURCE Huls

Rhone-

Rhone-

Rhone-

Arco

PPG

P PG

BASF

PQ

B u r l

B u r l

B u r l

ng-

ng-

ng-

Bur1 i ng-

B u r l i ng-

B u r l i ng-

Bur l i ng-

B u r l i ng -

B u r l i ng-

B u r l i ng-

B u r l i ng-

B u r l i ng-


RAW MATERIALS Burco NPS 50%

Burcosolv TM

Burcosperse AP

Burcosperse LP

Burcotase SL-80

Burco TM€

Burcotrope 1250

Burcowet TM-LF

Bu ty l Carbit07

Buty l Cel losolve

Buty l Propasol

Calamide C

Calamide 0

Calfax DB-45

Cal foam €A-603

Cal foam ES-303

Cal foam SLS-30

C a l i b r i t e SL

Cal irnul se PRS

Caloxylate N-9

Calsof t F-90

Calsof t L-40

CHEMICAL DESCRIPTION Propr ie tary t e x t i l e a u x i l i a r y

Water so lub le solvent mixture

L iqu id detergent polymer

Propr ie tary detergent polymer

Propr ie tary detergent enzyme

Nonionic th ioe the r sur factant

I ndus t r

I ndus t r

I ndus t r

Surfactant

a7 solvent

a1 solvent

a1 solvent

Foam s tab i 1 i z e r 8 emu1 s i f i er

Super amide

D i sul fonate

L i q u i d detergent

L iqu id detergent

Sodium l a u r y l s u l f a t e 30%

Emu1 s i f i e r

Sodi um 1 i near a1 k y l benzene

Linear sodium dodecylbenzene

su l fonate 90%

sul fonate

SOURCE Bur l i ng-

Bur l i ng-

Bur l i ng-

Bur l i ng-

Bur l i ng-

Bur l i ng-

Bur l i ng-

Bur l ing-

UnCarb

UnCarb

UnCarb

P i 1 o t

P i l o t

P i l o t

P i l o t

P i l o t

P i l o t

P i l o t

P i l o t

P i 1 o t

P i l o t

186 Advanced Cleaning Product Formulationr

R A W MATERIALS CHEMICAL DESCRIPTION C a l s o f t L-60 Sodium alkylbenzene sul fonate(60%)

Cal s o f t LAS-99 Dodecylbenzene s u l f o n i c acid(60%)

Calsuds A L i q u i d de tergent b lend

Calsuds CD-6 Coconut o i 1 amide w/sul fonate

Calsuds 81 Concentrated de tergent b lend

Carbopol 934 A c r y l i c a c i d polymer.MW:3,000,000

Card is 36 Wax Ox id ized m i c r o c r y s t a l l i n e wax

Carspray 500 Beadi ng agent w i t h s i 1 i cone

Carspray 700 Foaming beading agent

Cel lobond HEC 1OOOOOA

Cheel ox BF-13

Cheelox NTA-Na3

Clearon CDB Sodi um d i c h l o r o i socyanurate

Concord Co-Wax Emulsion, 12%

Concord Wax #1600

Condensate TL

Cyanamer A-100L Polyacrylamide

Dequest 20605

Dequest 2066

Desonic 9N

D i a l a A O i l

D ion i c OC

Organophosphorous produc t

Organophosphorous product

Nonionic s u r f a c t a n t

Minera l seal o i l

F a t t y a c i d methanolamide p o l y g l y c o l e the r

SOURCE P i l o t

P i l o t

P i l o t

P i l o t

P i l o t

Goodri ch

P e t r o l - W i t c o

W i t c o

FMC

Concord

Concord

Concord

Cyt ec

Monsan t o

Monsanto

DeSoto

She1 1

n u i s


RAW MATERIALS Dowanol D

Dowanol DE

Dowanol DPM

Dowanol EB

Dowanol PnB

Dow Corning EP-1-14

Dowfax 2A-1

Dowicide 32

Durcal 40

Durer Resin 15546

CHEMICAL DESCRIPTION Glyco l e the r

G lyco l e ther

Dipropylene g l y c o l methyl e the r

Ethylene g l y c o l n -bu ty l e ther

G lyco l e the r

An ion ic s u r f a c t a n t

An t im ic rob ia l agent

Cal c i um carbonate

E Sodium s i l i c a t e 40 Be'

E-43 Noni on i c

Emcol NA-30 Surface a c t i v e agent

Emcol 4500 Surface a c t i v e agent

Emersol 213 F a t t y a c i d

Emphos PS-220

Emu1 s i f i e r Four-HF D i a1 k y l quaternary

E m u l s i f i e r 827

E m u l s i o n C-340

F7 uorad FC- 129 F7uorochemica7 surfactant

SOURCE Dow

Dow

Dow

Dow

Dow

DowCorn

Dow

Dow

PQ

W i t c o

W i t c o

Henkel

W i t c o

Tomah

Tomah

Toma h

3 M


RAW MATERIALS CHEMICAL DESCRIPTION Gantrez AN-149 V i n y l e the r polymer

Genagen LAB

Genami n 5-250

Genaminox MY

Genapol OA-80

Genapol UD-030

Genapol UD-050

Genapol UD-080

Genapol ZRO L i q u i d

Genapol 2908

General E l e c t r i c SF96-100 S i 1 i cone

Genopur ASA

Giv-Gard DXN

GP-10-1.000 c s t k Dimethyl s i l i c o n e f

GP-10-12,500 c s t k Dimethyl s i l i c o n e f

GP-121 S i l i c o n e p o l i s h add

GP-7104 S i l i c o n e f l u i d

u i d

u i d

t i v e

SOURCE ISP

Hoechst

Hoechst

Hoechst

Hoechst

Hoechst

Hoechst

Hoechst

Hoec hs t

Hoechst

GESi 1 i - Hoechst

Genesee

Gene see

Genesee

Genesee

Harco 20% Soap

Hoe S 3924

Hoechst Wax A3 CS

Hoechst Wax E

Hoechst Wax F

Hoechst Wax OM

Hoechst

Hoechst

Es ter t y p e wax. Drop po in t :175F Hoechst

Hoechst

Hoechst

nademarked Raw Materials 189

CHEMICAL DESCRIPTION RAW MATERIALS Hoechst Wax OP

Hoechst Wax S

Hostapur SAS 60

Hypof resh Perfume

Igepa l CA-630 A l k y l e thoxy la te non ion ic

Igepa l CA-720 A1 k y l phenol e thoxy l a t e noni oni c

Igepa l C0-630/C0-660/ A lky lpheno l e thoxy la te CO-710

Igepa l CO-977

Isopar E/K/L/M/V

Lanoquat 50

L i poxol

L ipoxo l 6000 & 12000

Lonzabac 12.30

L y t r o n 295 Latex

Kaopo l i t e SF/1152/

Kathon CG

Kel zan

Kermac 600

K o r t h i x Th ixo t rop i c

1168

Agent

Water so lub le s u r f a c t a n t (70%)

I sopara f f i n i c s o l vent

Quaternary product

Po lys ty rene

Anhydrous a

emu1 s i on

umi num s i 1 i ca te

Fungi c i de (B i o c i de)

Xanthan gum

Minera l seal o i l

Ref ined wh i te ben ton i te

SOURCE Hoechst

Hoechst

Hoechst

I S P

I SP

ISP

ISP

Exxon

Henkel

Hul s

Hul s

Lonza

Morton

Kaopol-

Rohm&

Kelco

Kerr-Mc

Kaopol-


RAW MATERIALS Mackadet 40K

Mackam JS

Mackam MEJ

Mackam 2CSF

Mackam 2CYSF

Mackam 35

Mackamide CD

Mackami ne C-10

Mackamine LO

Mackazol i ne 0

Mackstat DM

Macol 48

Macol LF-120

Macol TD-3

Macol TD-12

Maphos 60-A

Marl ami ds

Mar laz i ns

Marl i n a t s

Mar l i p a l s

Marlons

Marlophors

CHEMICAL DESCRIPTION Potassium coconut soap

Low foam s u r f a c t a n t

Amphoteric w e t t i n g agent

Su r fac tan t

Low foaming s u r f a c t a n t

Cocami dopropyl b e t a i ne

Cocamide DEA

Amine ox ide s u r f a c t a n t

Amine ox ide s u r f a c t a n t

01 e y l hydroxyethy l i m i dazol i ne

DMDM hydanto in

B lock p o l y o l

Rinse a i d . MW: 1,000

Nonionic s u r f a c t a n t . HLB: 8 .0

Nonionic s u r f a c t a n t . HLB: 14.1

Phosphate es te r

F a t t y a c i d a1 kanol ami des

F a t t y amine p o l y g l y c o l e the rs

F a t t y a l coho l e the r sulphates

F a t t y a l coho l p o l y g l y c o l e t h e r s

A1 kylbenzenesulphonates, sodium s a l t s

P a r t i a l phosphate e s t e r s

SOURCE M c I n t y r e

McI n t y r e

M c I n t y r e

McI n t y r e

Mc I n t y r e

McI n t y r e

Mc I n t y r e

McI n t y r e

McI n t y r e

McI n t y r e

Mc In ty re

PPG

PPG

PPG

PPG

PPG

Hul s

Hul s

Hul s

Hul s

Hul s

Huls

Trademarked Rmu Materials 191

RAW MATERIALS CHEMICAL DESCRIPTION Mar losof t IQ 90 Quaternary i m i dazol i nes

Mar 1 owets Emu1 s i f i ers

Mar 1 ox I s

Mazamide 80

Mazawet 36

Fa t t y a1 coho1 a1 k y l ene oxide add i t i on products

Speci a1 t y a1 kanol ami de

Surfactant

Mazclean EP

Mazon 98 Propr ie tary sur factant

Medialan LD

Methyl Carb i to l Solvent

Metso Pentabead 20 Sodium metas i l icate, pentahydrate

Miranol CS Conc. Cocoamphopropylsulfonate

Miranol FBS Surfactant

M i ranol JEM Conc. Mixed C8 amphocarboxylate

amphoteric sur factant

amphoteric

M i r a t a i n e TM D i hydroxyethyl t a l l ow g l yc i nate amphoteric sur factant

ML-870 Latex A c r y l i c polymer emulsion

Mon t an Wax "S 'I

Mor-Glo 2 Latex Floor p o l i s h l a t e x (38%)

Morton Conrez 510 Polymer emu1 s i on

M- Py 1-01 N-Methyl-2-Pyrrolidone

SOURCE Huls

Hul s

Hul s

PPG

PPG

PPG

P PG

UnCarb

PQ

M i ranol

M i ranol

M i ranol

M i ranol

Morton

Stroh-

Morton

Morton

I S P

192 Advanced Cleaning Product Formulotions

RAW MATERIALS Neodol 25-3 Ethoxy

Neodol 25-3s

Neodol 25-7 Ethoxy

Neodol 91-8 Ethoxy

Ozokeri t e 170

PEG-10 Carnauba

Permulsin SP

Pe t ro BAF L i q u i d

B e t r o BAF Powder

Pe t ro LBA/ULF/22

Pe t ro SXS-40

Prapagen WK

P r i f a c 7976

Proxel GXL

CHEMICAL DESCRIPTION a t e L inear p r imary a l coho l

E thoxysu l fa te . Sodium c a t i o n

a t e Alcohol e thoxy la te . MW: 519

a t e L inea l p r imary a l c o h o l . MW: 529

Pol ycarboxyl a t e

An ion ic s u r f a c t a n t & d ispersant

An ion ic s u r f a c t a n t & d ispersant

An ion ic s u r f a c t a n t & d i spe rsan t

Sodium xy lene s u l f o n a t e 40%

F a t t y a c i d

Chemical b i o c i de

Ref ined Concord Wax #407

Rewoter ic AM B-15

Rewoter ic AM KSF-40

Rewoter ic AM V

Rhodacal A-246/L

Rhodacal DS-10

Rhodacal DSB

Sur fac tan t

SOURCE Shel 1

Shel 1

Shel 1

Shel 1

Koster

Koster

DeSoto

DeSoto

DeSoto

DeSoto

Unichema

I C I

Concord

w i t C O

w i t c o

w i t c o

Rhone-

Rhone-

Rhone-

Trademarked Rcmt Materials 193

R A W MATERIALS Rhodacal I PAM

Rhodacal 330

Rhodafac LO-529

Rhodafac RA-600

Rhodaf ac RE-61 0

Rhodapex GO-436

Rhodapex ES-2

Rhodapax MA-460

Rhodapex NA-61

Rhodopol 23

Rhodapon BOS

Rhodapon S0

Rhodapon U 0

Rhodasurf 0C-840

Rhodasurf 25-7

Rhodasurf 25-9

Rhodasurf 91 -6

Ross Micro Wax 1133/15W

Ross Ozoker i te Wax 77Y

CHEMICAL DESCRIPTION

Phosphate ester nonioni c

PhosDhate ester an ion ic

SOURCE Rhone-

Rhone-

Rhone-

Rhone-

Rhone-

Rhone-

Rhone-

Rhone-

Rhone-

Rhone-

Rhone-

Rhone-

Rhone-

Ethoxylated t r i d e c y l a lcohol Rhone-

Rhone-

Rhone-

Rhone-

Ross

Ross

SAG 1010 S i l i cone a n t i foam UnGarb

Sequi on 1 ONa2 Phosphonate HEDP

SF96(100)/SF96(350)/ Polydimethyl s i l i c o n e f l u i d GESi 1

Shel lso l T I sopara f f i n i c solvent She1 1

SM 2109 GESi 1

SF96(1OOO)/SF 1705/SF 1706


RAW MATERIALS SM 2133/SM 2135

Snow F loss S i l i c a

Sokalan CP 5

Sokalan HP 22

Sokalan HP 50

Sokalan PA 40

Solvent BG

Solvent

Span 80

SR 107

S t a r

Stepano

GX 5

DEA (35%)

Super F loss

Sur fon i c N-95

SWS 211 S i l i c o n e

Syntran 6520

Technocell 90 DU

Texst im 8741

Thermphos NW

T i nopal CBS-X

CHEMICAL DESCRIPTION

Processed diatomaceous s i l i c a

Po lycarboxy la te

P o l y v i n y l p y r r o l i done

Po lycarboxy la te

Sur fac tan t

Sodium s i l i c a t e 42 Be’

D i ethanol ami ne 1 a u r y l s u l f a t e

Minera l f i l l e r

Nonionic s u r f a c t a n t . HLB: 12.9

A n t i foam

Acry l i c emu1 s i on

Nonionic s u r f a c t a n t

F1 uorescent

Tomah A l k a l i Su r fac tan t : Amphoter

Tomah AO-14-2 Ether amine

Tomah A0-728 Special Amine ox ide

wh i ten ing agent

c (35% A c t i v e )

ox ide s u r f a c t a n t

s u r f a c t a n t

SOURCE GESi 1

Manvi 11 e

I C I

PQ

Step n

Manvi 11 e

Texaco

Wac ker

I n t e r -

Tomah

C i ba-

Tomah

Tomah

Tomah

Trademarkmi Raw Materials 195

R A W MATERIALS CHEMICAL DESCRIPTION Tomah E m u l s i f i e r Four D i a l k y l quaternary s u r f a c t a n t

Tomah Q-17-2

Tr iethanolamine R

T r i t o n CF-10 A l k y l a r y l po lye ther non ion ic

Tween 81 Sur fac tan t

Tylose CBR 10000

Ucon

Ucon

Union

Union

1 Propel 1 an t

2 Propel l a n t

Carbide L-45, 100 cs tks . S i l i c o n e

Carbide L-45, 30,000 cs tks . S i l i c o n e

Union Carbide L-46

Union Carbide LE-461

Union Carbide LE-462

Varami de A-83

Varamide ML-1

Var ion AM-KSF-40%

Varonic K205/LI-48/ LI-67

Varox 365

Varox 1770

Varsol 81 Varsol No.2

Veegum Pro

S i 1 i cone

S i 1 i cone

S i 1 i cone

Detergent a1 kanolamide

Detergent a1 kanolamide

Sur fac tan t

Nonionic w e t t i n g agent

Wett ing agent,degreaser,detergent

Amine ox ide

Minera l sp i r i t s

Complex c o l 1 o i da l magnesi urn aluminum s i l i c a t e

SOURCE Tonah

Tomah

UnCarb

I C I

UnCarb

UnCarb

UnCarb

UnCarb

UnCarb

UnCarb

UnCarb

W i t c o

W i t c o

W i t c o

W i t c o

W i t c o

W i t c o

Exxon

Vander-

1% Advanced Cleaning Product Formulations

R A W MATERIALS CHEMICAL DESCRIPTION SOURCE Versene 100/220 S o l u t i o n o f te t rasod ium s a l t o f Dow

EDTA

Ves t i no l C Hu ls

Vestowax AW 1060 Wax emulsion, 15% bas is Hul s

V i s c a s i l l O , O O O / S i l i c o n e f l u i d 12,000/30,000

GESi 1

Vol c l ay NF-BC Western b e n t o n i t e AmColl

Wessa l i th P Z e o l i t h A

W i tcami de CDA/ A1 kanol ami de s u r f a c t a n t Wi tco 5-771 /128T/511/5195

Witco 1298 S o f t Ac id W i t c o

W i t c o l a t e A Sodium l a u r y l s u l f a t e . An ion ic W i t c o

W i t c o l a t e AE-3/ S u l f a t e d s u r f a c t a n t s ES-3/LES-60A/S-1285C/SE-5/WAC-LA/2310/7031

W i t conate AOS/ Sul fonate s u r f a c t a n t SXS/3ODS/45LX

Witconate 1260 S l u r r y C-12 LAS (60%)

Witconol 14 Noni on i c

Z e o l i t h A

#3 Carnauba

668 P o l i s h i n g Powder

678 Pol i s h i ng Powder

787 P o l i s h i n g Alumina P-10 F e i n s t

W i t c o

W i t c o

W i t c o

W i t c o

Koster

Whi t tCD

Whi t t C D

Whi t t C D

Section IV Suppliers' Addresses

197


A1 1 i ed-Si gnal I n c . P.O. Box 2332R Morr istown, NJ 07962 (201)-455-2000/(800)-526-0717

American C o l l o i d Co. 1500 W. Shure D r . A r l i n g t o n Heights, I L 60004 (312)-392-4600

Arc0 Chemical Co. 3801 West Chester P ike Newtown Square, PA 19073 (215)-359-2000

BASF Corp. 100 Cherry H i l l Rd. Pars i ppany, NJ 07054 (201)-316-3000/(800)-526-1072

BP O i l I n c . 200 P u b l i c Square Cleveland, OH 44114 (216)-586-6364/(800)-321-8598

B u r l i ngton Chemical Co. , I n c . P.O. Box 111 615 Huffman M i l l Rd. Bu r l i ng ton , NC 27215 (919)-584-0111/(800)-672-5888

Concord Chemical Co. 17 th and Federal S ts . Camden, NJ 08105 (609)-966-1526

Cytec I n d u s t r i e s , I n c . F i v e Gar re t Mountain Plaza West Paterson, N J 07424 (908)-B62-6000/(800)-253-4078

DeSoto, I n c . 1700 S. M t . Prospect Rd. Des P la ines , I L 60018 (312)-391-9000

Dow Chemical Co. Midland, M I 48674 (800)-258-CHEM

Dow Corning Corp. Box 0994 Midland, M I 48686 (51 7)-496-4000

Eastman Chemical Co. P.O. Box 431 K ingspor t , TN 37662 (615)-229-2318/(800)-327-8626

Exxon Chemica? Americas 13501 Katy Frwy Houston, TX 77079 (713)-870-6000/(800)-231-6633

FMC Corp. 2000 Market S t . Ph i l ade lph ia , PA 19103 (215)-299-6000/(800)-526-3649

ISP/GAF Corp. 1361 Alps Road Wayne, NJ 07470

Genesee Polymers Corp. Fenton Rd. P.O. Box 7047 F l i n t , M I 48507

(201)-628-3000/(800)-848-7659

(31 3 ) -238-4966

GE S i 1 icones 260 Hudson R iver Rd. Waterford, NY 12188 (518)-237-3330/(800)-255-8886

BF Goodrich Co. 991 1 Brecksvi 11 e Rd. B r e c k s v i l l e , OH 44141 (216)-447-5000/(800)-332-1144

Haarman & Reimer Corp. P.O. Box 175 70 Diamond Rd. S p r i n g f i e l d , NJ 07081 (201)-467-5600/(800)-422-1559

Suppliers' Addresses 199

Henkel Corp. 5325 S. N i n t h Ave. LaGrange, I L 60525 (708)-530-7300/(800)-543-7370

Hoechst-Celanese Corp. 26 Main S t . Chatham, NJ 07960

Huls America I n c . Turner P1. P i scataway, NJ 08855

In te rpo lymer Corp. 330 Pine S t . Canton, MA 02021

Kaopo l i te , I n c . 2444 M o r r i s Ave. Union, N J 07083

(201)-635-2600/(800)-526-4960

(201)-981-5000/(800)-526-0339

(617)-828-7120/(800)-444-1281

(908)-769-0609

Kelco D iv . Merck & Co., I nc . 8355 Aero D r i v e San Diego, CA 92123

Kerr-McGee Chemical Corp. Kerr-McGee C t r . P.O. Box 25861 Oklahoma C i t y , OK 73125

(619)292-4900/(800)-535-2656

(405)-270-1313/(800)-654-3911

Koster Keunen I n c . P.O. Box 447 90 Bourne B lvd . S a y v i l l e , NY 11782 (51 6)-589-0456

Johns-Manvil le Ken Caryl Ranch Denver, CO 80217

McIn ty re Group L td . 4851 S. S t . Lou is Ave. Chicago, I L 60513 (312)-927-2401

Mi rano l I n c . P.O. Box 436 Dayton, NJ 08810

Mona I n d u s t r i e s I n c . 76 E. 24 S t . P.O. Box 425 Paterson, NJ 07544

Monsanto Chemical Co. 800 N. Lindbergh Blvd. S t . Louis, MO 63167

Morton I n t e r n a t i o n a l I nc . 100 N. R ive rs ide Plaza Chicago, I L 60606

P e t r o l i t e Corp. 6910 E. 14 S t . Tulsa, OK 74112 (918)-838-1601

(201)-329-3900

(201)-345-8220/(800)-553-6662

(314)-694-1000/(800)-325-4330

(312)-807-2000/(800)-367-3318

P i l o t Chemical Co. 11756 Burke S t . Santa Fe Spr ings, CA 90670 (310)-723-0036

PPG Chemical s 3938 P o r e t t D r i v e Gurnee, I L 60031

PQ Corp. P.O. Box 840 Va l l ey Forge, PA 19482

Rhone-Poulenc CN 7500 Prospect P l a i n s Rd. Cranbury, NJ 08512

Rohm & Haas Co. Independence Ma l l West Ph i lade lph ia , PA 19105

(708)-244-3410/(800)-323-0856

(215)-293-7200

(609)-860-4000/(800)-620-2613

(215)-592-3000


Ross Chemical I n c . 303 Da le O r . F o u n t a i n I n n , SC 29644 (803)-862-4474

Sandoz Chemical s Corp. 4000 Monroe Rd. C h a r l o t t e , NC 28205 (704)-331-7078/(800)-631-6077

S h e l l Chemical Co. P . O . Box 2463 Houston, TX 77252 (713)-241-6161

Stepan Co. 22 W . F ron tage Rd. N o r t h f i e l d , I L 60093 (708)-446-7500/(800)-745-7837

Strohmeyer & Arpe Co., I n c . 89 M i 1 b u r n Ave. M i l b u r n , N J 07041 (201)-761-7600

Texaco Chemical Co. 3040 Post Oak B l v d . Houston, TX 77056 (71 3)-961-3711

Tomah Produc ts , I n c . 1012 T e r r a D r i v e M i l t o n , W 1 53563 (608)-868-6811/(800)-441-0708

3M 3M Center S t . Pau l , MN 55144 (612)-733-5454

Unichema Chemicals, I p c . 4650 S. Racine Ave. /'

Chicago, I L 60609 (312)-376-9000/(800)-833-2864

Union Carb ide Corp. 39 O l d Ridgebury R d . Danbury, CT 06817 (203)-794-2000

RT V a n d e r b i l t Co., I n c . P.O. Box 5150 30 W i n f i e l d S t . N o r f o l k , CT 06856

Wacker S i l i c o n e s Corp. 3301 S u t t o n Rd. Adr ian , M I 49221

(203)-853-1400/(800)-243-6064

(517)-264-8500/(800)-246-0063

W h i t t a k e r , C l a r k & D a n i e l s , I n c . 1000 Coo l idge S t . S. P l a i n f i e l d , NJ 07080 (201)-561-6100

W i t c o Chemical Co. 5777 F r a n t z Rd. P.O. Box 646 D u b l i n , OH 43017 (614)-765-6500/(800)-366-6500

Witco Corp. 520 Madison Ave. New York , NY 10022 (212)-605-3941/(800)-634-4010

Other Noyes Arblications

ADVANCED CLEANING

PRODUCT FORMULATIONS

Volume 3

by Ernest W. Flick

This book (Volume 3) presents more than 630 up-to-date advanced cleaning product formulations for household, industrial and automotive applications. It istheresultof information received from numerous industrial companies and other organizations. The data represent selections madeatnocostto, norinfluencefrom, themakers or distributors of these materials. Only the most recent formulas have been included. All formulations are completely different than those contained in Volume 1 published in 1989 and Volume 2 published in 1994.

Formulation in the cleaning product industry has gradually been undergoing significant change during the past years. Raw materials costs have risen and manufacturers have been reluctant to pass alongthese increases. Environmental considerations have also played a part. By changing formulations to improve cost/performance characteristics, manufacturers have been able to control costs but still enhance performance. This book presents manufacturers' suggested formulations which might meet new performance criteria.

The formulations in this book are divided into the following sections and chapters, with the number of formulations indicated in ():

1.

1.

2.

3.

4.

5.

6.

7.

8.

9.

10.

11.

12.

Household and Industrial Cleaners and Polishes

Bathroom Cleaners (14)

Dairy Food and General Industrial Cleaners (52)

Degreasers (25)

Dishwashing Detergents (70)

General Purpose Cleaners (29)

Glass CleanarsPolishes (18)

Hard Surface Cleaners (59)

Laundry Products (100)

Metal Cleaners and Polishes (52)

Oven, Grill and Hot Plate Cleaners (1 1)

Polishes, Coatings and Finishes (19)

Rinse Aids (5)

13.

14.

II.

15.

16.

17.

18.

Rug, Floor, Carpet, Upholstery Sham-

Miscellaneous (49)

Transportation Cleaners and Polishes

Auto Cleaners and Polishes (32)

Car and Truck Wash Compounds (34)

Whitewall Tire Cleaners (11)

Miscellaneous

poos and Cleaners (41)

Each formula is located in the chapter which is most applicable. The reader, seeking a formula for aspecific end use, should check each chapter which could possibly apply. In addition to the above, there are two other sections which will be helpful to the reader. 111. A chemical trademark section where

each tradenamed raw material included in the book is listed with a chemical description andthe supplier's name. The specifications which each raw material meets are included, if applicable.

IV. Main office addresses of the suppliers of trademarked raw materials.

Each formulation in the book lists the following information, as available, in the manufacturets own words:

0 Description of end use and most outstanding properties.

0 The percent by weight orvolume of each raw material included inthe formula, rounded toa decimal figure.

0 Key propertii of the formula, which are the featuresthatthesource considentobemore outstanding than other formulations of the same type.

0 The formula source, which is the company or organization that supplied the formula. The secondary source may be the originating company and/or the primary source's publication title, or both. Aformula number is included, if applicable.

ISBN 0-8155-1382-8 (1995) 6" x9' 280 pages

Other Noyes Publications

ADVANCED CLEANING

PRODUCT FORMULATIONS

Volume 2

by

Ernest W. Flick

This book (volume 2) presents more than 800 up-to-date advanced cleaning product formulations for household, industrial and automotive applications. It is the result of information received from numerous industrial companies and other organizations. The data represent selections made at no cost to, nor influence from, the makers ordistributors of these materials. Only the most recent formulas have been included. All formulations are completely different than those contained in Volume 1, which was published in 1989.

Formulation in the cleaning product industry has gradually been undergoing significant change during the past years. Raw materials costs have risen and manufacturers have been reluctant to pass along these increases. Environmental considerations have also played a part. By changing formulations to improve cost-performance characteristics. manufacturers have been able to control costs but still enhance performance. This book presents supplier's suggested formulations which might meet new performance criteria.

Theformulations inthis bookaredivided into the following sections and chapters, with the number of formulations indicated in ():

1.

1.

2.

3.

4.

5.

6.

7.

8.

9.

10.

11.

Household and industrial Cleaners and Polishes (733)

Bathroom Cleaners (29)

Dairy and Food Industry Cleaners (15)

Degreasers (20)

Dishwashing Detergents (67)

DetergentsDisinfectants (36)

General Purpose Cleaners (47)

Hard Surface Cleaners (60)

Laundry Products (217)

Metal Cleaners (87)

Polishes, Coatings and Sealers (32)

Rinse Aids (6)

ISBN 0-8155-1346-1 (1994)

12.

13.

/I.

14.

15.

16.

17.

Rug, Carpet and Upholstery Shampoos

Miscellaneous Cleaners (96)

Transportation Cleaners and Polishes (76)

Auto Cleaners and Polishes (9)

Car and Truck Wash Compounds (38)

Whitewall Tire Cleaners (10)

Miscellaneous (19)

In addition to the above, there are two other

and Cleaners (21)

sections which will be helpful to the reader.

111. A chemical trademark section where each tradenamed raw material included in the book is listed with a chemical description and the supplier's name. The specifications which each raw material meets are included, if applicable.

lV. Main office addresses of the suppliers of trademarked raw materials.

Each formulation in the book lists the following information, as available:

1. Description of end use and most outstanding properties.

2. The percent by weight or volume of each raw material included in the formula.

3. Key properties of the formula, which are the features that the source considers to be more outstanding than other formulations of the same type.

4. The formula source, which is the company or organization that supplied the formula. The secondary source maybe theoriginating company and/or the primary source's publication title. or both. A formula number is included, if applicable.

f64 6" x9" 394 pages

advanced cleaning product formulations vol. 4

Healthcare

transportation cleaners

auto cleaners

metal cleaners

bathroom cleaners

general industrial cleaners

number of formulations

general purpose cleaners

hot plate cleaners