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Page 1: ADVANCED CLEANING PRODUCT FORMULATIONS · 2019. 2. 28. · This book (Volume 3) presents more than 630 up-to-date advanced cleaning product formulations for household, industrial
Page 2: ADVANCED CLEANING PRODUCT FORMULATIONS · 2019. 2. 28. · This book (Volume 3) presents more than 630 up-to-date advanced cleaning product formulations for household, industrial

ADVANCED CLEANING PRODUCT FORMULATIONS

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ADVANCED

CLEANING

PRODUCT

FORM U LATIONS Volume 3

by

Ernest W. Flick

NOYES PUBLICATIONS Park Ridge, New Jersuy, U S A .

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Copyright 8 1995 by Ernest W. Rick No part of this book may be reproduced or utilized in any form or by any means, electronic or mechanical, including photocopying. recording or by any informa- tion storage and retrieval system, without permission in writing from the Publisher.

Library of Congress Catalog Card Number: 89-30274

Printed in the United States ISBN: 0-8155-1382-8

Published in the United States of America by Noyes Publications Mill Road, Park Ridge, New Jersey 07656

10 9 8 7 6 5 4 3 2 1

Library of Congress Cataloging-in-Publication Data (Revised for vol. 3)

Flick, Ernest W. Advanced cleaning produd formulations.

Includes bibliographical references and index. 1. Cleaning compounds. I. Title.

TP990.F56 1989 668'1 89-30274 ISBN 0-8155-1186-8 (v. 1) ISBN 0-8155-1346-1 (v. 2) ISBN 0-8155-1382-8 (v. 3)

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To

Charlotte Morgan

V

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Preface

This book (Volume 3) presents more than 630 up-to-date advanced cleaning product formulations for household, industrial and automotive applications. It is the result of information received from numerous industrial companies and other organizations. The data represent selections made at no cost to, nor influence from, the makers or distributors of these materials. Only the most recent formulas have been included. All formulations are completely different than those contained in Volumes 1 and 2 published earlier.

Formulation in the cleaning product industry has gradually been undergoing significant change during the past years. Raw materials costs have risen and manufacturers have been reluctant to pass along these increases. Environmental considerations have also played a part. By changing formulations to improve cost/performance characteristics, manufacturers have been able to control costs but still enhance performance. This book presents manufacturers' suggested formulations which might meet new performance criteria.

The formulations in this book are divided into the following sections and chapters, with the number of formulations indicated in ( ):

I. Household and Industrial Cleaners and Polishes 1. 2. 3. 4. 5. 6. 7. 8. 9.

10. 11. 12. 13. 14.

Bathroom Cleaners (14) Dairy, Food and General Industrial Cleaners (52) Degreasers (25) Dishwashing Detergents (70) General Purpose Cleaners (29) Glass CLeanersPolishes (18) Hard Surface Cleaners (59) Laundry Products (100) Metal Cleaners and Polishes (52) Oven, Grill and Hot Plate Cleaners (11) Polishes, Coatings and Finishes (19) Rinse Aids (5) Rug, Floor, Carpet, Upholstery Shampoos and Cleaners (41) Miscellaneous (49)

vii

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viii Preface

11. Transportation Cleaners and Polishes 15. Auto Cleaners and Polishes (32) 16. Car and Truck Wash Compounds (34) 17. Whitewall Tire Cleaners (11) 18. Miscellaneous (12)

Each formula is located in the chapter which is most applicable. The reader, seeking a formula for a specific end use, should check each chapter which could possibly apply. In addition to the above, there are two other sections which will be helpful to the reader.

111. Achemical trademark section where each tradenamed raw material included in the book is listed with a chemical description and the supplier's name. The specifications which each raw material meets are included, if applicable.

IV. Main office addresses of the suppliers of trademarked raw materials.

Each formulation in the book lists the following information, as available, in the manufacturer's own words:

0 Description of end use and most outstanding properties.

0 The percent by weight or volume of each raw material included in the formula, rounded to a decimal figure.

0 Key properties of the formula, which are the features that the source considers to be more outstanding than other formulations of the same type.

0 The formula source, which is the company or organization that supplied the formula. The secondary source may be the originating company and/or the primary source's publication title, or both. A formula number is included, if applicable.

The table of contents is organized in such a way as to serve as a subject index.

My fullest appreciation is expressed to the companies and organizations who supplied the original starting formulations included in this book. I also thank the suppliers of the raw materials included in these formulations, who furnished information describing their trademarked raw materials.

Newburyport, Massachusetts September 1994

Ernest W. Flick

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NOTICE

To the best of our knowledge the information in this publication is accurate; however, the Publisher does not assume any responsibility or liability for the accuracy or completeness of, or consequences arising from, such information. This book is intended for informational purposes only. Mention of trade names or commercial products does not constitute endorsement or recommendation for use by the Publisher. Final determ- ination of the suitability of any information or product for use contemplated by any user, and the manner of that use, is the sole responsibility of the user. We recommend that anyone intending to rely on any recommendation of materials or pro- cedures mentioned in this publication should satisfy himself as to such suitability, and that he can meet all applicable safety and health standards.

X

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Contents and Subject Index

SECTION I HOUSEHOLD AND INDUSTRIAL

CLEANERS AND POLISHES

1 . BATHROOM CLEANERS . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 2 Clear Liquid Bowl Cleaner . . . . . . . . . . . . . . . . . . . . . . . . . . . . 3 Thick Toilet Bowl Cleaner . . . . . . . . . . . . . . . . . . . . . . . . . . . . 3 Disinfectant Bowl Cleaner Formulation Name: TB-A23 . . . . . . . 4 Viscous PhosphoridHCI Acid Cleaner . . . . . . . . . . . . . . . . . . . . 4 Gentle Abrasive Lotion Cleanser for Bathroom and Kitchen . . . . 5 Cream Cleanser . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 5 Mixed Acid Bath Cleaner . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 6 Liquid Scouring Cleanser I . . . . . . . . . . . . . . . . . . . . . . . . . . . . 6 HCI Acid Bowl Cleaner . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 6 Solid Automatic Toilet Bowl Cleaner Formulation . . . . . . . . . . . 7 Acid Bowl Cleaner . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 7 Viscous Organic Acid Cleaner4 . . . . . . . . . . . . . . . . . . . . . . . . 8 Viscous Organic Acid Cleaner41 . . . . . . . . . . . . . . . . . . . . . . . . 8 Viscous Organic Acid Cleaner411 . . . . . . . . . . . . . . . . . . . . . . . 8

2 . DAIRY. FOOD AND GENERAL INDUSTRIAL CLEANERS . . . . 9 Acid Cleaner . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 10 Alkaline All-Purpose Industrial Cleaner Phosphated.

Powder Type . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 10 Acid Cleaners. Foamy Acid Dairy Cleaner Aluminum Brightener A103 . . . . . . . . . . . . . . . . . . . . . . . . . . 11 Aluminum Brightener A102 . . . . . . . . . . . . . . . . . . . . . . . . . . 11 Built Steam Cleaner . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 12 Aluminum Soak Tank CleanerDrightener . . . . . . . . . . . . . . . . . 12 Heavy Duty Steam Cleaner . . . . . . . . . . . . . . . . . . . . . . . . . . . 12 d-Limonene . Microemulsion Cleaner/Degreaser . . . . . . . . . . . . . 13 Heavy Duty Industrial Cleaner . . . . . . . . . . . . . . . . . . . . . . . . . 13 Electrocleaner . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 14 Low Foam Tanktruck Cleaner . . . . . . . . . . . . . . . . . . . . . . . . . 14 Food Plant Cleaners

. . . . . . . . . . . . . . . . 11

Foamy Acid Dairy Cleaner . . . . . . . . . . . . . . . . . . . . . . . . 15

xi

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xii Contents and Subject Index

Low Foam-Self Demulsifying Cleaner . . . . . . . . . . . . . . . . 15 Low Foam Moderate pH. Self Demulsifying . . . . . . . . . . . . 15

Graffiti Remover 1 . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 16 Graffiti Remover 2 . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 16 Heavy Duty Cleaners (Industrial)

Steam Cleaners-Liquids . . . . . . . . . . . . . . . . . . . . . . . . . 17 Steam Cleaners-Powders . . . . . . . . . . . . . . . . . . . . . . . . . 17

Heavy Duty Industrial Spray Cleaner Concentrate F-543 . . . . . . 18

Concentrate F-544 . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 18 High Solids Alkaline Cleaner F-555 . . . . . . . . . . . . . . . . . . . . 18 High Foaming Smokehouse Cleaner-I . . . . . . . . . . . . . . . . . . . 19 High Foaming Smokehouse Cleaner-II . . . . . . . . . . . . . . . . . . . 19

Acid Based AluminurdSS Cleaner . . . . . . . . . . . . . . . . . . . 20 Acid Based Metal Cleaner ........................ 20 Light Duty Neutral Cleaner ........................ 20 Anionic/Nonionic Glycol Ether HSC . . . . . . . . . . . . . . . . . 21 Anionic/Nonionic HD HSC ........................ 21

Non-Caustic Industrial Cleaner ..................... 22 Low VOC Heavy Duty Presoak ..................... 22 Non-Solvent Medium Duty Degreaser . . . . . . . . . . . . . . . . 23 Non-Solvent Heavy Duty Steam Cleaner . . . . . . . . . . . . . . 23 Low VOC Solvent Cleaner-Isopar G . . . . . . . . . . . . . . . . 24 Low VOC Solvent Cleaner-Isopar M . . . . . . . . . . . . . . . . 24

Detergent for Blood Removal ...................... 25 Food Plant and Dairy Detergent Sanitizer . . . . . . . . . . . . . . 25 General Purpose Sanitizers

Alkaline . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 25 Acidic . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 25

General Purpose Equipment Detergent4 . . . . . . . . . . . . . . 26 General Purpose Equipment Detergent41 . . . . . . . . . . . . . . 26 Milk Can Cleaners4 ............................ 26 Milk Can Cleaner-II . . . . . . . . . . . . . . . . . . . . . . . . . . . . 26 Soak Bottle Cleaner-I . . . . . . . . . . . . . . . . . . . . . . . . . . . 26 Soak Bottle Cleaner-I1 . . . . . . . . . . . . . . . . . . . . . . . . . . . 26 Heavy Duty Chlorinated Cleaner .................... 27 Heavy Duty Liquid Chlorinated Cleaner-I . . . . . . . . . . . . . 27 Heavy Duty Liquid Chlorinated Cleaner-II . . . . . . . . . . . . 27 Heavy Duty Liquid Chlorinated Cleaner411 . . . . . . . . . . . . 27

Heavy Duty Industrial Spray Metal Cleaner

Industrial Cleaners

Low VOC Cleaners

Sanitizers and Food Plant Cleaners

Mildly Acidic .............................. 25

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Contents and Subject Index xiii

2 . DEGREASERS . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 28 All Purpose Alkaline Degreaser-A . . . . . . . . . . . . . . . . . . . . . . 29 All Purpose Alkaline Degreaser-B . . . . . . . . . . . . . . . . . . . . . . 29 All Purpose Alkaline Degreaser-C . . . . . . . . . . . . . . . . . . . . . . 30 All Purpose Alkaline Degreaser-D . . . . . . . . . . . . . . . . . . . . . . 30 Industrial Degreaser . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 31 Spray Degreaser . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 31 Engine Cleaner and Degreaser . . . . . . . . . . . . . . . . . . . . . . . . . 31

Degreaser Formulation . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 32 Metal Cleaner Spray . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 32 D-Limonene Degreaser-I . . . . . . . . . . . . . . . . . . . . . . . . . . . . 33 D-Limonene Degreaser-I1 . . . . . . . . . . . . . . . . . . . . . . . . . . . 33 Heavy Duty Degreaser . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 34 Metal Degreaser Cleaner . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 34

Glycol Ether Degreaser-I . . . . . . . . . . . . . . . . . . . . . . . . . 36 Glycol Ether Degreaser-I1 . . . . . . . . . . . . . . . . . . . . . . . . 36

Glycol Ether Cleaner 3 . . . . . . . . . . . . . . . . . . . . . . . . . . . 37 Water Rinseable Degreaser I . . . . . . . . . . . . . . . . . . . . . . . 37 Isopar M Emulsion . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 38 Kerosene Emulsion Cleaner . . . . . . . . . . . . . . . . . . . . . . . . 38 Acid/Solvent Cleaner . . . . . . . . . . . . . . . . . . . . . . . . . . . . 38

Cosmoline Remover (Heavy oil or greasy-wax remover) . . . . . . 31

Micro-Emulsions with Aloe Vera and d-Limonene . . . . . . . . . . 35 Phosphate Free Cleaners

Solvent Cleaners

4 . DISHWASHING DETERGENTS . . . . . . . . . . . . . . . . . . . . . . . . . 39 Automatic Dishwash I . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 40 Automatic Dishwash I1 . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 40 Rinse Aid-Commercial Machine . . . . . . . . . . . . . . . . . . . . . . . 40 Automatic Dishwash Liquid . . . . . . . . . . . . . . . . . . . . . . . . . . 41 Automatic Dishwashing Gel-I . . . . . . . . . . . . . . . . . . . . . . . . . 42 Automatic Dishwashing Gel-I1 . . . . . . . . . . . . . . . . . . . . . . . . 42 Automatic Dishwashing Liquid . . . . . . . . . . . . . . . . . . . . . . . . 43 Crystal Clear Hand Dishwash . . . . . . . . . . . . . . . . . . . . . . . . . 43 Clear Hand Dishwashing Liquid (25% actives)-A . . . . . . . . . . 44 Clear Hand Dishwashing Liquid (25% actives)-B . . . . . . . . . . . 44 Clear Hand Dishwashing Liquid (25% actives)-(= . . . . . . . . . . . 45 Clear Hand Dishwashing Liquid (25% actives)-D . . . . . . . . . . 45 Clear Hand Dishwashing Liquid (25% actives)-D . . . . . . . . . . 46 Clear Hand Dishwashing Liquid (30% actives)-A . . . . . . . . . . 46 Clear Hand Dishwashing Liquid (30% actives)-B . . . . . . . . . . . 47 Clear Hand Dishwashing Liquid (30% actives)-C . . . . . . . . . . . 47 Clear Hand Dishwashing Liquid (30% actives)-D . . . . . . . . . . 48

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xiv Contents and Subject Index

Clear Hand Dishwashing Liquid (30% actives)-E . . . . . . . . . . . 48

. . . . . . . . . . . 49 . . . . . . . . . . . . . . . . 49

Commercial Machine Dishwashing Compound4 . . . . . . . . . . . . 49 Commercial Machine Dishwashing Compound41

Liquid Machine Dishwashing Detergent4 . . . . . . . . . . . . . . . . 49 Non-DDBSA Dishwashing Liquid ...................... 49

Pearlescent Premium I1 . . . . . . . . . . . . . . . . . . . . . . . . . . . 50 Low Cost Formula . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 50 Low Cost Formula I1 ............................ 50

Hand Dishwash-Premium . . . . . . . . . . . . . . . . . . . . . . . . . . . 51 Hand Dishwash-Intermediate ......................... 51 Hand Dishwash-Economy ........................... 51 Hand Dishwashing-Solid-I1 .......................... 52 Hand Dishwashing-Solid-I1 . . . . . . . . . . . . . . . . . . . . . . . . . . 52 Hand Dishwashing--Li quid . . . . . . . . . . . . . . . . . . . . . . . . . . . 52

Soft Water . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 52 Hard Water . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 52

High Performance Dishwash . . . . . . . . . . . . . . . . . . . . . . . . . . 53 Dish Washing Agents (Manual Use) ..................... 53 High-Performance Hand Dish Detergent . . . . . . . . . . . . . . . . . 54 Mild Liquid Hand Dish Detergent ...................... 54 Liquid Dishwasher Detergent .......................... 55 Liquid Hand Dish Detergent .......................... 56 Liquid Hand Dish Detergent .......................... 56 Liquid Hand Dish Detergent .......................... 56

Liquid Machine Dishwashing Detergent4

Dishwash Products

Automatic Dishwashing Detergent

Liquid Manual Dishwashing Detergents Premium Performance

Glucopon & AES . . . . . . . . . . . . . . . . . . . . . . . . . . . . 57 Glucopon & LAS . . . . . . . . . . . . . . . . . . . . . . . . . . . . 57

Glucopon & AES . . . . . . . . . . . . . . . . . . . . . . . . . . . . 57 Glucopon & LAS ............................ 57

Economy Performance

Liquid Manual Dishwashing Detergents (Based on Added Value Surfactant Concentrates)

Premium Perfarmance ............................ 58 Economy Performance ........................... 58 Premium Performance with h i d e . . . . . . . . . . . . . . . . . . 58 Premium Performance with Betaine . . . . . . . . . . . . . . . . . . 58

Intermediate Performance

Premium Performance

Liquid Manual Dishwashing Detergents

Lauryl Sulfate & AES . . . . . . . . . . . . . . . . . . . . . . . . 59

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Contents and Subject Index xv

LAS & A E S . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 59 Glucopon & AOS . . . . . . . . . . . . . . . . . . . . . . . . . . . . 59

Glucopon & AOS . . . . . . . . . . . . . . . . . . . . . . . . . . . . 59 Low Cost Liquid Dishwasher Detergent . . . . . . . . . . . . . . . . . . 60 Machine Dishwash Detergents (Institutional)

Economy Performance

Liquids . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 61

Machine Dishwashing Formulation . . . . . . . . . . . . . . . . . . . . . . 62 Powders . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 61

Mechanical Dishwashing Detergent Liquid . . . . . . . . . . . . . . . . 63 Mechanical Dishwashing Detergent Chlorinated . . . . . . . . . . . . 63 Premium Dishwash 1 . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 64 Premium Dishwash 2 . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 64 Premium Dishwash 3 . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 65 Premium Dishwash 4 . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 65 Premium Hand Dishwash Formula-1 . . . . . . . . . . . . . . . . . . . . 66 Premium Hand Dishwash Formula-2 . . . . . . . . . . . . . . . . . . . . 66 Premium Hand Dishwash FOrmda-3 . . . . . . . . . . . . . . . . . . . . 66 Premium Hand Dishwash Formula-4 . . . . . . . . . . . . . . . . . . . . 66

5 . GENERAL PURPOSE CLEANERS . . . . . . . . . . . . . . . . . . . . . . . 67 All Purpose Cleaner . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 68 Heavy Duty Alkaline Cleaner . . . . . . . . . . . . . . . . . . . . . . . . . 68 Alkaline Powder Cleaner . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 68 Ammoniated General Purpose Household Detergent . . . . . . . . . 69 Butyl Cleaner . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 69 Ammoniated Liquid General Purpose Detergent-I . . . . . . . . . . . 70 Ammoniated Liquid General Purpose Detergent-I1 . . . . . . . . . . 70 Ammoniated Liquid General Purpose Detergent-I11 . . . . . . . . . . 70

Scouring Powder-I1 . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 70 All Purpose Bleach Cleaner . . . . . . . . . . . . . . . . . . . . . . . . . . . 71 All Purpose Cleaner . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 71 All Purpose Vegetable Oil Soap . . . . . . . . . . . . . . . . . . . . . . . . 71 Heavy Duty All Purpose Cleaner-A . . . . . . . . . . . . . . . . . . . . . 72 Heavy Duty All Purpose Cleaner-B . . . . . . . . . . . . . . . . . . . . . 72 Heavy Duty All Purpose Cleaner-C . . . . . . . . . . . . . . . . . . . . . 73 Heavy Duty All Purpose Cleaner-D . . . . . . . . . . . . . . . . . . . . . 73 Heavy Duty All Purpose Cleaner-E . . . . . . . . . . . . . . . . . . . . . 74 Heavy Duty All Purpose Cleaner-F . . . . . . . . . . . . . . . . . . . . . 74 Heavy Duty Cleaner . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 75 General Purpose Cleaner . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 75 Neutral Cleaner . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 75 Non-Caustic All Purpose Cleaner . . . . . . . . . . . . . . . . . . . . . . 76

Scouring Powder-I . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 70

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mi Contents and Subject Index

Non-Caustic Powder . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 76 Non-Caustic Steam Cleaner . . . . . . . . . . . . . . . . . . . . . . . . . . 76 Non-Phosphate All Purpose Cleaner .................... 77 Oil Splitting General Purpose Cleaner . . . . . . . . . . . . . . . . . . . 77

6 . GLASS CLEANERSPOLISHES ......................... 78 Ammoniated Glass Cleaner . . . . . . . . . . . . . . . . . . . . . . . . . . . 79 Glass Cleaner I . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 79 Low VOC/Non-Acid Glass Cleaner ..................... 79 CleanerPolish for Glass . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 80

Glass Cleaner Ammonia Dry Powder Cleaning Compound. Low Aggressive Type . . . . . . 80

Heavy Duty . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 81

Heavy Duty . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 82

Economical . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 81

Glass Cleaner Vinegar Economical . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 82

Glass Cleaner & Polish .............................. 83 Glass Cleaner-Polish ............................... 83 Glass Cleaners

All-Purpose Glass Cleaner ........................ 84

Industrial Glass Cleaner . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 85 Multi-Feature Glass Cleaner . . . . . . . . . . . . . . . . . . . . . . . . . . 85 Glass Cleaner . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 85

All-Purpose Glass Cleaner. Liquid Spray . . . . . . . . . . . . . . 84

7 . HARD SURFACE CLEANERS . . . . . . . . . . . . . . . . . . . . . . . . . . 86 Abrasive Hard Surface Cleaner-A ...................... 87 Abrasive Hard Surface Cleaner-B ...................... 87 Abrasive Hard Surface Cleaner-C ...................... 87 D-Limonene Based Cleaner-I ......................... 88 D-Limonene Based Cleaner-I1 ........................ 88 D-Limonene Based Cleaner-I11 ........................ 89 Low Foaming Liquid Cleaner with Abrasive . . . . . . . . . . . . . . . 89 D-Limonene Hard Surface Cleaner

D-Limonene Concentrate . . . . . . . . . . . . . . . . . . . . . . . . . 90 . . . . . . . . . 90

. . . . . . . . . . . . 91 D-Limonene All-Purpose Cleaner . . . . . . . . . . . . . . . . . . . 91

Economical Pine Oil Hard-surface Cleaner . . . . . . . . . . . . . . . 92 Heavy-Duty Cleaner Powder .......................... 92 D-Limonene Emulsifiable Concentrate . . . . . . . . . . . . . . . . . . . 92 General Purpose Hard-surface Cleaners

Solvent-Free Non-Phosphate Type . . . . . . . . . . . . . . . . . . 93

All-Purpose Spray Cleaner Type (1:9 Dilution) Heavy-Duty Degreaser Type (1:3 Dilution)

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Solvent-Free Phosphate Type . . . . . . . . . . . . . . . . . . . . . . 93 Heavy-Duty Solvent Type . . . . . . . . . . . . . . . . . . . . . . . . 93

General Purpose Spray-and-Wipe Cleaner . . . . . . . . . . . . . . . . 94

Glycol Ether Cleaner 1 . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 95 Glycol Ether Cleaner 2 . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 95

All Purpose Cleaner . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 96 All Purpose Cleaner with Solvent . . . . . . . . . . . . . . . . . . . 96 Pine Oil Cleaner . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 96 Heavy Duty Degreaser . . . . . . . . . . . . . . . . . . . . . . . . . . . 96 All Surface Bathroom Acid Type . . . . . . . . . . . . . . . . . . . . 97 All Surface Bathroom Type . . . . . . . . . . . . . . . . . . . . . . . . 97

Hard Surface Cleaner-A . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 98 Hard Surface Cleaner-B . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 98 Hard Surface Cleaner-C . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 99 Hard Surface Cleaner-D . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 99 Heavy Duty HSC . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 100 Powder-Heavy Duty HSC . . . . . . . . . . . . . . . . . . . . . . . . . . . 100

High.Foaming. Light-Duty Cleaner . . . . . . . . . . . . . . . . . . . . 101 Spray Cleaner . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 101 Pine Oil Detergent-Cleaner-Sanitizer . . . . . . . . . . . . . . . . . . 101 Heavy-Duty Steam Cleaner . . . . . . . . . . . . . . . . . . . . . . . . . . 101

Solvent-Free Non-Phosphate Type . . . . . . . . . . . . . . . . . 102 Solvent-Free Phosphate Type . . . . . . . . . . . . . . . . . . . . . 102 Heavy-Duty Solvent Type . . . . . . . . . . . . . . . . . . . . . . . 102

High Pressure Spray Concentrate (Liquid. Low Foam) . . . . . . . 103 Spray and Wipe Household Hardsurface (Liquid) . . . . . . . . . . 103 Destainer . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 103 HSC/Food Service Degreaser I . . . . . . . . . . . . . . . . . . . . . . . 104 HSC/Food Service Degreaser I1 . . . . . . . . . . . . . . . . . . . . . . . 104 Liquid Abrasive Cleaner-A . . . . . . . . . . . . . . . . . . . . . . . . . . 105 Liquid Abrasive Cleaner-B . . . . . . . . . . . . . . . . . . . . . . . . . . 105

Mold and Mildew Remover . . . . . . . . . . . . . . . . . . . . . . . . . . . 94

Hard Surface Cleaners

High.Foaming. Clear. Light-Duty Liquid Cleaner . . . . . . . . . 101

High.Performance. Hard Surface Cleaners

Low Foam Cleaners Self Demulsifying Hard Surface Cleaner . . . . . . . . . . . . . 106 HSC. Moderate pH. Self Demulsifying . . . . . . . . . . . . . . . 106

Phosphate Free Cleaners Heavy Duty Non-Solvent Degreaser . . . . . . . . . . . . . . . . 107 AnionicDIonionic HSC . . . . . . . . . . . . . . . . . . . . . . . . . . 107

Thickened D-Limonene Cleaner . . . . . . . . . . . . . . . . . . . . . . 108 D-Limonene HSCDegreaser . . . . . . . . . . . . . . . . . . . . . . . . . 108 Unbuilt. High-Sudsing. Hard-surface Cleaner . . . . . . . . . . . . 109

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High-Performance General Purpose Cleaner Concentrate . . . . . 109 Viscous Phosphoric Acid Cleaner ...................... 110 Viscous HCI Acid Cleaner .......................... 110 Viscous Mixed Acid Cleaner ......................... 110

. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 8 . LAUNDRY PRODUCTS 111 Alkaline Laundry Formulation-Emulsion Type . . . . . . . . . . . 112 Alkaline Laundry Fomulation-Slurry Type . . . . . . . . . . . . . 112

Chlorine Dry Bleach-I . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 114 Chlorine Dry Bleach-I1 . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 114 SOW-I . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 114 SOW-I1 . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 114 Oxygen Safety Dry Bleach4 ......................... 114 Oxygen Safety Dry Bleach-I1 ........................ 114 Cold Water Detergent (for Wool and Delicate Fabrics) . . . . . . 115 Fine Fabric Detergent .............................. 115 Commercial Laundry Formulations

Phosphated Alkali or Builder ......................

AnionidNonionic Heavy-Duty Laundry Detergent . . . . . . . . . 113 AnionidNonionic Heavy-Duty Laundry Detergent . . . . . . . . . 113

116

Light Duty . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 116

116 116

Tallow Soap Detergent

Heavy Duty . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 116 Built Detergent (Light Duty) ...................... Built Detergent (Heavy Duty) .....................

One-Shot Liquid .............................. 117 Commercial Low-Built Laundry Detergent

Multi-Component System Detergent Break . . . . . . . . . . . 117 Enzymatic Heavy Duty Laundry Detergent . . . . . . . . . . . . . . . 118 Nonionidhphoteric Heavy Duty Laundry Liquid . . . . . . . . . 118 Fine Fabric Handwash .............................. 119 Low Temperature Powder Detergent . . . . . . . . . . . . . . . . . . . 119 Heavy Duty Laundry Detergent

High Sudsing . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 120 Low Sudsing . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 120

Cold Water Wool Detergent . . . . . . . . . . . . . . . . . . . . . . . . . 120

Heavy Duty Laundry. Liquid ......................... Light Duty Liquid Detergent ......................... 121

Heavy Duty Liquid Laundry Detergent . . . . . . . . . . . . . . . . . . 120 121

Heavy Duty Liquid Laundry Detergent . . . . . . . . . . . . . . . . . . 122 Heavy Duty Powdered Laundry Detergent . . . . . . . . . . . . . . . 122 Heavy Duty Liquid Laundry Formulad . . . . . . . . . . . . . . . . . 123

123 Heavy Duty Liquid Laundry Formula-7 . . . . . . . . . . . . . . . . . 123 Heavy Duty Liquid Laundry Formula-6 . . . . . . . . . . . . . . . . .

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Heavy Duty Liquid Laundry Formula-8 . . . . . . . . . . . . . . . . . 123 Heavy Duty Phosphate Free Laundry Powder-A . . . . . . . . . . . 124 Heavy Duty Phosphate Free Laundry Powder-B . . . . . . . . . . . 124 Concentrated Liquid Laundry Detergent . . . . . . . . . . . . . . . . . 124 Industrial and Institutional Detergent Concentrate

Formulation A . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 125 Formulation B . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 125 Formulation C . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 125

Uniforms . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 126 Industrial Laundry Powder

Hotel Linen Supply . . . . . . . . . . . . . . . . . . . . . . . . . . . . 126

Greases and Oils) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 127 Industrial Laundry Two-Part Systems-Uniforms (Petroleum

Hoteminen Supply (Animal and Vegetable Grease) . . . . . . . . 127 Industrial Laundry One-Shot Liquid . . . . . . . . . . . . . . . . . . . 127 Laundry Alkali Builders

Powders-Industrial Supply. Moderate Alkalinity . . . . . . . 128 Liquids

Linen Supply . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 128 Industrial Supply . . . . . . . . . . . . . . . . . . . . . . . . . . . 128

Laundry Detergent. I and I-Unbuilt (Liquid) . . . . . . . . . . . . . 129 Laundry Detergent-Linen Supply (Powder. Low Alkalinity) . . 129 Laundry Detergents (Consumer)

Dry Blended . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 130 Phosphorous-Free . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 130 Agglomerated . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 130

Phosphorous-Free (Economy) ..................... 131

Low Phosphorous (Economy) . . . . . . . . . . . . . . . . . . 130 Premium . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 131

Premium . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 131

RestauranVHotel Laundry I ....................... 132 RestauranVHotel Laundry I1 . . . . . . . . . . . . . . . . . . . . . . 132 Concentrated Prespotter . . . . . . . . . . . . . . . . . . . . . . . . . 132

Laundry Powder Detergent . . . . . . . . . . . . . . . . . . . . . . . . . . 133 Non-Phosphate Laundry Powder ...................... 133 Liquid Commercial Laundry .Detergents . . . . . . . . . . . . . . . . . 134 Industrial and Institutional Detergent Concentrates

Formulation A . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 134 Formulation B . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 134 Formulation C . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 134

Liquid Laundry/Anionic Phosphate-Free . . . . . . . . . . . . . . . . 135 Liquid LaundryJNonionic Phosphate-Free . . . . . . . . . . . . . . . 135

Laundry Formulas

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Liquid Laundry Detergents Anionic & Nonionic ............................ 136 All Nonionic ................................. 136 Anionic & Nonionic with Builder . . . . . . . . . . . . . . . . . . 136 Nonionic with Builder .......................... 136

Liquid Laundry Detergents (Based on Added Value Surfactant Concentrates)

Premium HDL ................................ 137 Economy HDL ................................ 137 Concentrate with Nonionics ....................... 137 Ultra High Active .............................. 137

Liquid LaundryDJonionic Phosphate .................... 138 Liquid Laundry/Anionic Phosphate .................... 138 Oxygen Safety Dry Bleach-I ......................... 139 Oxygen Safety Dry Bleach-I1 ........................ 139 Detergent Sanitizer-I .............................. 139 Detergent Sanitizer-I1 .............................. 139 Super Concentrate Laundry Liquid ..................... 140 Laundry Detergents Industrial and Institutional

Liquid (Dispersion) ............................. 140 Liquid (Solution) .............................. 140

Unbuilt Laundry Detergent-A ........................ 141 Unbuilt Laundry Detergent-B ........................ 141 Unbuilt Laundry Detergent-C ........................ 142 Unbuilt Laundry Detergent-D ........................ 142 Unbuilt Laundry Liquid-A .......................... 143 Unbuilt Laundry Liquid-B .......................... 143 Unbuilt Laundry Liquid-C .......................... 144 Unbuilt Laundry Liquid-D .......................... 144

9 . METAL CLEANERS AND POLISHES . . . . . . . . . . . . . . . . . . . 145 Acid Cleaner . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 146 High-Foaming Acid Scrubber ........................ 146 Acid Metal Cleaner No . 392 ......................... 147 Acid Cleaner No . 288 . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 147 Aluminum Brightener-I ............................ 148 Aluminum Brightener41 . . . . . . . . . . . . . . . . . . . . . . . . . . . . 148 Aluminum Brightener-111 ........................... 148 Aluminum Cleaner . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 149 Aluminum Cleaner . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 150 Aluminum Cleaner Concentrate F-498 . . . . . . . . . . . . . . . . . . 151 Aluminum Wash F-499 ............................ 151 Aluminum CleanerPolish. Soft Paste . . . . . . . . . . . . . . . . . . . 152 Silver Polish. Soft Paste ............................ 152

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Aluminum Cleaner/Polish. Soft Paste . . . . . . . . . . . . . . . . . . . 153 Tarnish-Retardant Silver Polish. Soft Paste . . . . . . . . . . . . . . 153 Fine Brass Polish . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 154 Emulsion Metal Polish . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 154

Liquid Products . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 155

Powder . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 155 Liquid . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 155

Liquid-I . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 156 Liquid-I1 . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 156 Industrial Soak Tank Aluminum Cleaner . . . . . . . 156 Rust Remover for Steel . . . . . . . . . . . . . . . . . . . 156 Degreaser (for Engine Blocks and Automotive

Machine Parts) . . . . . . . . . . . . . . . . . . . . . . . . 156 Solid Products . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 157

158 158 158

Iron Phosphating and Cleaning Formulations

Steam Cleaners

Acid Cleaners Powder . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 156

Low Foam Heavy Duty Alkaline Cleaner-A . . . . . . . . . . . . . . Low Foam Heavy Duty Alkaline Cleaner-B . . . . . . . . . . . . . . Moderate Alkalinity. Soil Splitting Soak Cleaner . . . . . . . . . . . Metal Cleaner Formulas

Liquid A-14 . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 159 Liquid A-15 . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 159 Powder A-16 . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 159

Ferrous Metals-Immersion Liquid-Light Duty . . . . . . . . . . . . . . . . . . . . . . . . . 160 Powder-Heavy Duty . . . . . . . . . . . . . . . . . . . . . . . . 160 Powder-Medium Duty . . . . . . . . . . . . . . . . . . . . . . 160 Powder-Light Duty . . . . . . . . . . . . . . . . . . . . . . . . 160

Liquid-Light Duty . . . . . . . . . . . . . . . . . . . . . . . . . 160 Powder-Light Duty . . . . . . . . . . . . . . . . . . . . . . . . 160

Non-Acid Aluminum Brightener-I . . . . . . . . . . . . . . . . . . . . 161 Non-Acid Aluminum Brightener-I1 . . . . . . . . . . . . . . . . . . . . 161 Soak-Tank Metal Cleaner (Powder. for Magnesium) . . . . . . . . High Temperature Spray Cleaner . . . . . . . . . . . . . . . . . . . . . . Viscous Phosphoric/Oxalic Acid Cleaner-I . . . . . . . . . . . . . . .

Viscous Phosphoric/Oxalic Acid Cleaner-I11 . . . . . . . . . . . . . .

Metal Cleaning (Industrial)

Ferrous Metals-Spray

162 162 163

163 Viscous Phosphoric/Oxalic Acid Cleaner-I1

10 . OVEN. GRILL AND HOT PLATE CLEANERS . . . . . . . . . . . . 164 Aluminum Cleaner . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 165

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Grill Cleaner . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 165 Oven Cleaner . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 165 Caustic Oven. Grill and Drain Cleaners . . . . . . . . . . . . . . . . . 166

Formulation A . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 166 Formulation B . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 166 Formulation C . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 166

Hot Plate/Grill Cleaner . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 167 Oven Cleaner . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 167 Industrial Cleaners . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 168

Oven Cleaner . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 168 Thickened Alkaline Cleaner ......................... 168

11 . POLISHES. COATINGS AND FINISHES . . . . . . . . . . . . . . . . . 169 Aerosol Appliance Polish ........................... 170 Aerosol Furniture Polish ............................ 170 Aerosol Furniture Polish ............................ 171 Furniture Polish .................................. 171 Furniture Polish (Cationic Emulsion) . . . . . . . . . . . . . . . . . . . 171 Detergent/Corrosion-Resistant Polish . . . . . . . . . . . . . . . . . . . 172 Detergent-Resistant Paste Polish ...................... 172 Furniture Polish .................................. 173 Spray and Wipe Furniture Polish ...................... 173 Furniture Polish No . 337 ............................ 174 Scratched Wood Polish No . 210 ....................... 174 Industrial Floor Finish-Formula B (24% Solids) . . . . . . . . . . . 175 Industrial Floor Finish-Formula A (22% Solids) . . . . . . . . . . . 175 Industrial Floor Finish-Formula B (25% Solids) . . . . . . . . . . . 176 Industrial Floor Finish-Formula C (18% Solids) . . . . . . . . . . . 176 Industrial Floor Finish-Formula A (20% Solids) . . . . . . . . . . . 177 Industrial Floor Finish-Formula B (16% Solids) . . . . . . . . . . . 177 Industrial Floor Finish-Fomula C (20% Solids) . . . . . . . . . . . 178 Industrial Floor Finish-Formula D (25% Solids) . . . . . . . . . . . 178

12 . RINSE AIDS . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 179 Automatic Dishwasher Rinse Aid-I .................... 180 Automatic Dishwasher Rinse Aid-I1 . . . . . . . . . . . . . . . . . . . 180 Automatic Dishwasher Rinse Aid-111 . . . . . . . . . . . . . . . . . . . 180 Rinse Aid . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 181

12 . RUG. FLOOR, CARPET UPHOLSTERY SHAMPOOS AND CLEANERS ......................... 182

Carpet Shampoo for Automatic Carpet Shampooer (may also be used for cleaning vinyl and upholstery) . . . . . . . . . . 183

Aerosol Rug Shampoo ............................. 183

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Carpet Shampoo with Grease-Cutting Solvent . . . . . . . . . . . . 184

water systems) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 184 Floor and Carpet Care Products . . . . . . . . . . . . . . . . . . . . . . . 185

Floor and Tile Cleaner . . . . . . . . . . . . . . . . . . . . . . . . . . 185 Wax Stripper . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 185 Wax Stripper (Solvent) . . . . . . . . . . . . . . . . . . . . . . . . . . 185 Machine Floor Scrubber . . . . . . . . . . . . . . . . . . . . . . . . . 185

Floor Care Products . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 186 Floor Cleaner . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 186 Floor Wax Stripper . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 186

Floor Cleaner . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 187 Waxed Floor Cleaner . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 187 Floor Cleanerwax Stripper (Liquid) . . . . . . . . . . . . . . . . . . . 188 Floor Cleanerwax Stripper B . . . . . . . . . . . . . . . . . . . . . . . . Floor Stripper . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 189 No Rinse Wax Stripper . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Wax Stripper . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 189

Liquid . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 190

Liquid . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 190 Concrete Garage Floor Cleaner4 . . . . . . . . . . . . . . . . . . . . . . Concrete Garage Floor Cleaner4 . . . . . . . . . . . . . . . . . . . . . 190 Ceramic Tile Cleaner . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 190 Heavy Duty Concrete Cleaner . . . . . . . . . . . . . . . . . . . . . . . . Evaporative (No Rinse) Wax Stripper . . . . . . . . . . . . . . . . . . . 191 Liquid Carpet Cleaner . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 192 Carpet Stain Remover-Liquid . . . . . . . . . . . . . . . . . . . . . . . . 192 Carpet Cleaner/Booster-Dry Destainer . . . . . . . . . . . . . . . . . . 192

Machine Floor Cleaner I . . . . . . . . . . . . . . . . . . . . . . . . . 193 Machine Floor Cleaner I1 . . . . . . . . . . . . . . . . . . . . . . . . 193 Carpet Stain Remover/Prespotter . . . . . . . . . . . . . . . . . . . 193

Pumpsprays for Removal of Odors . . . . . . . . . . . . . . . . . . . . . 194 Deodorant Rug Shampoo . . . . . . . . . . . . . . . . . . . . . . . . . . . . 194 Rug Shampoo . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 195 Rug and Upholstery Shampoo . . . . . . . . . . . . . . . . . . . . . . . . 195

Liquid Steam Cleaner for Carpets (for use in hard

188

189

General Purpose Floor and Wall Cleaner Powder . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 190

Floor Wax Remover Powder . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 190

190

191

Low Foam Cleaners

. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 14 . MISCELLANEOUS 196 Aerosol Bathroom Cleaner . . . . . . . . . . . . . . . . . . . . . . . . . . 197 Aerosol Oven Release . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 197

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xxiv Contents and Subject Index

Aerosol Water-Repellent Fabric Treatment . . . . . . . . . . . . . . 198 Liquid. Vinyl Surface Protectant ...................... 198 Asphalt Emulsion . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 199 Road Tar Emulsion . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 199 Cationic Oil-in-Water Emulsifier ..................... 200 Cationic Water-in-Oil Emulsion ...................... 200 Concrete Cleaner ................................. 200 Rust Remover . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 200 Chain Belt Lube 1 ................................ 201

Concrete Cleaner (Dry Type) ......................... 202 Polishing Cloth . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 202 Detergent Sanitizer ................................ 203 Steam-Cleaning Compound .......................... 203 d-Limonene Microemulsion Cleaner F-478 . . . . . . . . . . . . . . 204 d-Limonene Alkaline Cleaner F-524 . . . . . . . . . . . . . . . . . . . 204 d-Limonene Microemulsions that Give Clear Dilutions . . . . . . 205 Water Spot and Soap Film Remover . . . . . . . . . . . . . . . . . . . 205 Dry Cleaning Formula ............................. 206 Dry Cleaning Formula ............................. 206 Egg Cleaner (Powder) .............................. 207 Grill Cleaner (Liquid) .............................. 207 Printing Plant Cleaner (Powder) ....................... 207 Graffiti Cleaner . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 208 Penetrating Lubricant . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 208 Bottle Wash Cleaner F-542 . . . . . . . . . . . . . . . . . . . . . . . . . . 208 Heavy Duty Presoak ............................... 209 Underbody Rust Inhibitor ........................... 209 Railcar Cleaner . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 209 Leather Preservative . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 210 "Liquid Sandpaper" (Water Base) ..................... 211 "Marble Polish" (Water Base) ........................ 211 Paint Stripper .................................... 212

Liquid . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 213 Powders . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 213

Chain Belt Lube 2 ................................ 201

Paint Strippers

Wax Strippers Liquids ..................................... 213 Powder . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 213

Paraffin Wax Emulsion . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 214 Liquid Drain Opener . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 214 Low VOC Heavy Duty Presoak ....................... 214 Penetrating Gel Base . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 215 Water-in-Oil Emulsion Base ........................ 215

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Contents and Subject Index ~ n ,

Solvent Cleaners Blood Stain Remover . . . . . . . . . . . . . . . . . . . . . . . . . . . 216 Paint Stripper . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 216

SECIlON II TRANSPORTATION CLEANERS AND POLISHES

15 . AUTO CLEANERS AND POLISHES . . . . . . . . . . . . . . . . . . . . 218 Auto CleanerPolish. Aerosol Packed . . . . . . . . . . . . . . . . . . . 219 Detergent-Resistant Auto CleanerPolish (Thick. Liquid.

Oil-External) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 219 Auto CleanerPolish. Hard Paste . . . . . . . . . . . . . . . . . . . . . . 220 Cream Cleanser-Non-Wax Type . . . . . . . . . . . . . . . . . . . . . . 220 Auto CleanerPolish. Hard Paste . . . . . . . . . . . . . . . . . . . . . . 221 Detergent-Resistant Auto CleanerPolish (Thick. Liquid.

Oil-External) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 221 Auto CleanerPolish. High Gloss . . . . . . . . . . . . . . . . . . . . . . 222 Pre-Wax Cleaner. Automotive. Liquid . . . . . . . . . . . . . . . . . . 222 Auto CleanerPolish. Low-Temperature Compounded

(Thick Liquid. Water-External) . . . . . . . . . . . . . . . . . . . . . 223 Auto CleanerPolish. for Machine Buffing . . . . . . . . . . . . . . . 223 Auto CleanerPolish. Soft Paste. Emulsion . . . . . . . . . . . . . . . 224 "Luster-Powder" Auto Polish . . . . . . . . . . . . . . . . . . . . . . . . 224 Auto CleanerPolish. Thick Liquid. Oil External . . . . . . . . . . . 225 Detergent-Resistant AutoKleaner Polish. Thin Liquid . . . . . . . 225 Cream Car Wax . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 236 Rubbing Compound . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 226 Detergent-Resistant Auto Cleaner Polish . . . . . . . . . . . . . . . . 227 Detergent-Resistant Auto Cleaner Polish . . . . . . . . . . . . . . . . 228

PolishA . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 228 Polish B . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 228

Auto Cleaner-Polish . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 228 Liquid Silicone Car Polish . . . . . . . . . . . . . . . . . . . . . . . . . . . 229 Auto Rinse-Wax Concentrate . . . . . . . . . . . . . . . . . . . . . . . . 229 Auto Vinyl-Top Protector . . . . . . . . . . . . . . . . . . . . . . . . . . . 229 Spraywax I1 . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 230 Non-Hydrocarbon Spraywax-N-3 . . . . . . . . . . . . . . . . . . . . . 230 Non-Hydrocarbon Spraywax-N-4 . . . . . . . . . . . . . . . . . . . . . 230 Transportation Cleaners

Wash and Wax 1 . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 231 Wash and Wax 2 . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 231 Polish or "Hot Wax" . . . . . . . . . . . . . . . . . . . . . . . . . . . . 231

Paste Polish . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 232 Waxless. Presoftened. Detergent-Resistant. Cleaner.

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mi Contents and Subject Index

Auto-Rinse Polish . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 232

16 . CAR AND TRUCK WASH COMPOUNDS . . . . . . . . . . . . . . . . 233

Concentrated Car Wash ......................... 234 Car Wash (Automatic) .......................... 234 Power Car Wash (Self Service) .................... 234 Hand Wash and Upholstery ....................... 234

Car Wash Powder . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 235 Carwash Shampoo-I . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 236

Auto and Truck Care Products

Car Wash Liquid . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 235

Carwash Shampoo-I1 .............................. 236 Spraywax-Drying Agent ............................ 236 High Oil Splitting Vehicle Wash-A .................... 237 High Oil Splitting Vehicle Wash-B .................... 237 Non-Phosphate Truck Wash ......................... 237

Liquid Car Wash-Formula B ......................... 238 Spray-On Car Wash Concentrate "Grease and Grime"

Remover . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 238 Liquid Truck Wash . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 239 Non-Phosphate Truckwash . . . . . . . . . . . . . . . . . . . . . . . . . . 240

Transportation Cleaners. Car Wash Solids

Liquid Car Wash-Formula A ........................ 238

Self Demulsifying Truckwash ........................ 240

Manual . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 241 Spray . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 241 Commercial High Performance .................... 241 Car Wash-Liquid I . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 241 'Car Wash-Liquid I1 ............................ 241 Traffic Film Remover . . . . . . . . . . . . . . . . . . . . . . . . . . . 242 Viscous Wire Wheel Cleaner ...................... 242 Glass Cleaner . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 242

Truck Wash Detergent Formulation-I . . . . . . . . . . . . . . . . . . 243 Truck Wash Detergent Formulation-I1 . . . . . . . . . . . . . . . . . . 243 Aluminum Truck Body CleanerBrightener-I . . . . . . . . . . . . . 243 Aluminum Truck Body CleanerBrightener-I1 . . . . . . . . . . . . . 243 Aluminum Truck Body CleanerBrightener-111 . . . . . . . . . . . . 243 Truck Wash Liquid . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 244 Economy Truck Wash High-Pressure Spray . . . . . . . . . . . . . . 244

17 . WHITEWALL TIRE CLEANERS ....................... 245 Whitewall Tire Cleaner-I . . . . . . . . . . . . . . . . . . . . . . . . . . . 246 Whitewall Tire Cleaner-I1 . . . . . . . . . . . . . . . . . . . . . . . . . . . 246 Whitewall Tire Cleaner-I . . . . . . . . . . . . . . . . . . . . . . . . . . . 247

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Contents and Subject Index xxvii

Whitewall Tire Cleaner-I1 ........................... 247 Liquid Whitewall Tire Cleaner-Type I . . . . . . . . . . . . . . . . . . 247 Liquid Whitewall Tire Cleaner-Type I1 . . . . . . . . . . . . . . . . . 247 Whitewall Tire Cleaner Liquid ....................... 248 Whitewall Tire Cleaner Concentrate .................... 248 Whitewall Tire Cleaner 1 ........................... 249 Whitewall Tire Cleaner 2 won-Caustic) . . . . . . . . . . . . . . . . 249 Whitewall Tire Cleaner 3 ........................... 249

18 . MISCELLANEOUS . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 250 Brake Cleaner . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 251 Mag Wheel Cleaner . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 251 Concrete Floor Cleaner ............................. 251 Liquid Aluminum Engine Block Cleaner . . . . . . . . . . . . . . . . 252 Foaming Engine Cleaner ............................ 252 Liquid Boat Polish . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 253 Paste Boat Polish . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 253 Locomotive Cleaner I .............................. 254 Locomotive Cleaner I1 ............................. 254 Locomotive Cleaner 111 ............................. 254 Polishing Cleaner for Plastic Windows . . . . . . . . . . . . . . . . . . 255 Hard-surface CleanerNax (May be Aerosol Loaded) . . . . . . . 255

SECTION Ilk TRADEMARKED RAW MATERIALS . . . . . . . . . . 256

SECTION IV: SUPPLIERS' ADDRESSES . . . . . . . . . . . . . . . . . . . 276

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Section I

Household and Industrial Cleaners and Polishes

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1 Bathroom Cleaners

2

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Bathroom Cleaners 3

Clear L i q u i d Bowl Cleaner

M i rano l FBS Hydroch lo r i c Ac id (20Be) Water

W L % 3.0

2 0 . 0 77.0

Procedure:

Add t h e M i rano l FBS. Mix u n t i l un i fo rm.

Phys ica l P r o p e r t i e s :

Add t h e water . S lowly add t h e h y d r o c h l o r i c ac id , w i t h m ix ing .

Appearance: C lea r , l i g h t y e l l o w V i s c o s i t y : <10 cps S p e c i f i c G r a v i t y : 1 .03 pH (as i s ) : t l . 0

Formula t ion BC-0001

T h i c k T o i l e t Bowl Cleaner

M i r a t a i ne TM Hydroch lo r i c Ac id (20Be) Water

u L L % 5 . 0

32.0 Q . S .

Procedure:

add t h e M i r a t a i n e TM and mix u n t i l un i fo rm.

Phys ica l P r o p e r t i e s :

Add t h e h y d r o c h l o r i c a c i d t o t h e water , w i t h s t i r r i n g . S lowly

Appearance: C1 ea r , ye1 low 1 i qu i d V i s c o s i t y : 1.035 cps S p e c i f i c G r a v i t y : 1.037 pH (as i s ) : t l . 0

Formula BC-0002

SOURCE: Rhone-Poulenc: Suggested Formula t ions

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4 Advanced Cleaning Product Formulations

D i s i n f e c t a n t Bowl C1 eaner Formula t ion Name: TB-A23

I n a r e d i en t : Dei on i zed Water Tomah Ac id Thickener*

Add, mix w e l l Nonionic Surfactant-HLB 13

Add, mix w e l l Tomah Amphoteric L

Add, mix w e l l Ethylene G lyco l

Add, mix w e l l FMB-210-15 Quat (50%)*

Add, mix w e l l HCL Ac id (31.5%)

Add s low ly , mix w e l l , coo l

Wt% 58.19

5.00

3.00

2.00

3.00

2.88

25.93

Recommended D i l u t i o n s : 1-4 oz/bowl (3 /4 g a l l o n water ) A p p l i c a t i o n s : Reg is te red d i s i n f e c t a n t fo rmula Notes: Mix Ac id Thickener p r i o r t o use i n o rde r t o assure

*EPA R e g i s t r a t i o n No. 47371-86 and FMB-210-15 homogeneity

quat f rom Hunt ing ton Chemicals Formul a A-1 00

Viscous Phosphori c/HCl A c i d C1 eaner

I n Q r e d i e n t : Water Phosphori c Aci d (75%)

Ac id Thickener*

HC1 (37%)

Add, mix. coo l

Add, mix w e l l

Add, mix w e l l

W B 70.00

2.00

3.00

24.40

pH: 1.30 Recommended D i 1 u t i ons : 0-30 : 1 A p p l i c a t i o n s : T o i l e t bowl c lean ing , v e r t i c a l su r face c l e a n i n g Notes: Easy mix fo rmula

M ix Ac id Thickener p r i o r t o use i n o rde r t o assure homogenei t y

Formula A-1 06

SOURCE: Tomah Products, I nc . : Suggested Formula t ions

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Bathroom Cleaners 5

Gent le Abras ive L o t i o n Cleanser f o r Bathroom and K i t chen

I ngred i en t s : % by Weiqht (1) Deion ized Water 60.8 ( 2 ) K o r t h i x H 0 .2 ( 3 ) Sodium Carbonate, anhydrous 1 . o ( 4 ) Tetrasodium Pyrophosphate, anhydrous 1 . o (5) .Sodium M e t a s i l i c a t e , pentahydra te 1 . o (6) K a o p o l i t e SF o r 1168 24.0 (7 ) CMS-7M8S (5% S o l u t i o n i n Water) 10.0 (8) Synthrapo l N 2.0 Procedure:

D isperse i n g r e d i e n t s ( 2 ) th rough ( 7 ) , i n t h a t sequence, i n t o (l), w i t h v igo rous a g i t a t i o n , a l l o w i n g t i m e f o r each t o d i s s o l v e o r d i spe rse t h o r o u g h l y . Reduce a g i t a t i o n t o avo id excess ive foaming, s l o w l y add (8).

each produc t used. Comments :

keeping same r a t i o . These can be ad jus ted t o g i v e t h e d e s i r e d v i s c o s i t y c h a r a a c t e r i s t i c s .

Use o f K a o p o l i t e 1168 g i v e s more aggress ive c l e a n i n g and p o l i s h i n g a c t i o n t o t h e f o r m u l a t i o n .

Fo l l ow recommended hand l i ng p r a c t i c e s o f t h e s u p p l i e r s of

I f a more v i scous produc t i s des i red , i nc rease ( 2 ) and (71,

Cream Cleanser

I n g r e d i e n t s : % by Weiqht (1 ) Odor1 ess Kerosene 5 . 0 ( 2 ) VM&P Naphtha 2 0 . 0 ( 3 ) O l e i c Ac id 9 . 0 ( 4 ) T r ie thano lamine 3 . 0 ( 5 ) Propyl ene G1 yco l 3 . 0 (6) T e r g i t o l NP-10 4.0 ( 7 ) De ion ized Water 40.0 ( 8 ) Sodium Hexametaphosphate 1 . o ( 9 ) K a o p o l i t e SF o r 1168 10.0

Procedure:

u n t i l w e l l d ispersed. I n another vesse l , d i spe rse ( 5 ) , (61, ( 7 ) ’ and (8). Then d i spe rse (9) and (10) i n t h e m i x t u r e w i t h maximum a g i t a t i o n . Reduce a g i t a t i o n i n t h e o i l m i x t u r e t o moderate, add t h e water m i x t u r e s l o w l y , and s t i r u n t i l w e l l b l ended.

each p roduc t used.

f lammable i n g r e d i e n t s . Comments :

( 1 0 ) K o r t h i x H 5.0

Combine ( 1 ) th rough ( 4 ) , w i t h v igo rous a g i t a t i o n , c o n t i n u i n g

Fo l l ow recommended hand l i ng p r a c t i c e s o f t h e s u p p l i e r s of

Good i n d u s t r i a l p r a c t i c e s shou ld be used when hand l i ng

Ad jus t (1) t o g i v e cons is tency d e r i r e d . Use o f K a o p o l i t e 1168 g i v e s more aggress ive c l e a n i n g and

p o l i s h i n g a c t i o n t o t h e f o r m u l a t i o n .

SOURCE: Kaopo l i t e , I n c . : Suggested Formula t ions

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6 Advanced Cleaning Product Formulations

Mixed A c i d Bath Cleaner Ino red ien t : Water Hydroxyacetic a c i d

Add, mix Sulfamic a c i d

Add, mix Tomah AO-728 Special

Add, mix pH: 1.00 Recommended D i l u t i o n s : As necessary Appl icat ions: T u b / t i l e c leaner, good descal ing

Formula 8-102

L i a u i d Scourina Cleanser I I nq red i ent : So f t Water Tomah OAT 1000

Add t o vo r tex and mix we l l u n t i l s o l u b i l i z e d Tomah A0-728 Special

Add, mix w e l l DDBSA. Na S a l t (60%)

Add, mix w e l l Sodi um o r Potassi um C i t r a t e

Add, mix w e l l Calcium carbonate (100 mesh)

Add, mix we l l pH: 9.90 Recommended D i 1 u t i ons : as- i s Appl icat ions: Rub and r i n s e from surface. Notes: Creamy, v iscous l i q u i d good f o r c leaning

t u b / t i l e / s i n k s . W i l l s e t t l e , shake before use. Pack i n opaque b o t t l e .

Formula 8-1 04

W B 80.00 5.00

5 . 0 0

10.00

W B 35.60

0.40

7.00

5.00

2.00

50.00

HCl Ac id Bowl Cleaner Inq red i ent : E% Water 71.40 Tomah Acid Thickener 3.00

H C l Acid (37%) 25.60 Add, mix we l l

Add s lowly , mix w e l l , cool pH: 1.30 Recommended D i l u t i o n s : as - i s App l i ca t i ons : T o i l e t bowl c leaning, v e r t i c a l surface c leaning. Notes: Mix Acid Thickener p r i o r t o use i n order t o assure

homogenei t y Formula B-105

SOURCE: Tomah Products, Irte.: Suggested Formulations

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Bathroom Cleaners 7

S o l i d Automat ic T o i l e t Bowl Cleaner Formula t ion

I n q r e d i e n t : Macol DNP 150 Incromi de L90 Carbowax PEG 8000 Macol 27 Versa f l ex 207 ( d r y ) Water

%y&yy 25.0 25.0 20.0 20.0

5.0 5 .0

Procedure: 1 . M e l t t h e Macol 27, Macol DNP 150, and Carbowax PEG 8000,

2. M a i n t a i n a temperature o f about 70C, and add t h e Incromide

3 . Add water and Versa f l ex 207 ( d r y ) and mix. 4. Pour f o r m u l a t i o n i n t o a mold, and a l l o w t o c o o l .

SOURCE: Na t iona l S ta rch and Chemical C o . : Reference #8069:49

and mix toge the r .

L90 w h i l e m ix ing .

A c i d Bowl Cleaner

Mackam 2CSF (Cocoamphodipropionate) Hydroch lo r i c Ac id (30%) Rodine 213 Water

Procedure: 1 . Add components t o water . 2 . Blend u n t i l c l e a r .

SOURCE: Mc In ty re Group L t d . : I n d u s t r i a l Formulary

Weiqht,% 3 .5

18.5 0 . 4

77.6

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8 Advanced Cleaning Product Formulations

Viscous Orqanic A c i d Cleaner- I

I nq red ien t : Water C i t r i c Acid

Add, d i sso l ve w i t h mixing Tomah Acid Thickener

Add. mix we l l Alcohol Ethoxy late (8 mole)

Add, mix we l l S a l t (NaC1)

Dissolve w i t h mix ing Perf ume*

Add, mix w e l l V i scos i t y (cps): 816

Viscous Oraanic Ac id Cleaner- I1

Inaredi ent : Water C i t r i c Ac id

Tomah Acid Thickener

Formic Acid

Alcohol Ethoxy late (8 mole)

S a l t (NaC1)

Perf ume*

Add, d i sso l ve w i t h mixing

Add, mix we l l

Add, mix w e l l

Add, mix we l l

D i ssolve w i t h m i x i ng

Add, mix w e l l V i scosi t y (cps) : 784

Viscous Organic A c i d Cleaner-I11

Ing red ien t : Water Tomah Acid Thickener

Formic Acid

Alcohol Ethoxy late (8 mole)

S a l t (NaC1)

Perfume*

Add, mix w e l l

Add, m3x w e l l

Add, mix w e l l

D i ssolve w i t h m i x i ng

Add, mix w e l l V i scos i t y (cps): 556

Wt% 88. DO

2.50

3.00

0.30

6.00

0.20

W B 88.00

1.25

3.00

1.25

0.30

6.00

0.20

W t % 88.00

3.00

2.50

0.30

6.00

0 .20

Recommnded D i 1 u t i ons : As-i s Appl i c a t i ons : Toi 1 e t bowl c leaners w i t h good c l i ng ti me Notes: *Quest I n t ' l C i t r u s X004.950

SOURCE: Tomah Products, l n c . : Suggested Formulations

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2. Dairy, Food and General Industrial Cleaners

9

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I0 Advanced Cleaning Product Fotmulatiom

A c i d Cleaner

M i r a t a i ne CBS H y d r o f l o u r i c Ac id (70%) Phosphoric Ac id (85%) Butoxyethanol Water

Wt.% 3.0 3.0

30.0 3 .0

61 .O

Procedure:

and phosphor ic ac ids . Add t h e butoxyethanol and mix u n t i l un i fo rm.

Phys ica l P r o p e r t i e s :

Add t h e water and M i r a t a i n e CBS. S lowly add t h e h y d r o f l u o r i c

Appearance: C lear s o l u t i o n pH: 3 .1 V i s c o s i t y : t 10 cps S p e c i f i c G r a v i t y : 1 .17

Formula MS-0073

A1 k a l i ne A1 1 -Purpose I n d u s t r i a1 C1 eaner PhosDhated. Powder TVDe

Sodi um T r i p o l yphosphate ( L t . Dens i ty ) Sodium Carbonate ( L t . Dens i ty ) Sodium M e t a s i l i c a t e Pentahydrate Rhodafac RA-600

Wt.% 52.5 20.0 22.5 5.0

Procedure: 1 . Mix Rhodafac RA-600 w i t h Sodium Tr ipo lyphosphate t o o b t a i n a

2. Add Sodium M e t a s i l i c a t e and Sodium Carbonate.

Phys ica l P roper t i es : pH (1%): 11.4 S p e c i f i c G r a v i t y : 0.82

Formula MS-0074

un i fo rm, powdered m ix tu re .

SOURCE: Rhone-Poulenc: Suggested Formula t ions

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Daity, Food and General Industrial Cleaners 11

A c i d Cleaners Foamy A c i d Dai r y Cleaner

I n a r e d i en t : Water Phosphoric Ac id (75%)

Monosodium phosphate, monohydrate

Amphoteric SC, A1 k a l i Sur fac tan t

Add, mix, coo l

Add, d i s s o l v e , mix w e l l

Add, mix w e l l

SpG 20/20C: 1.47 pH: 1.67 Recommended D i l u t i o n s : 10-3O:l A p p l i c a t i o n s : D a i r y p l a n t c lean ing

Formula A-101

A l u m i n u m B r igh tener A103

I n a r e d i en t : Water Ac id Foamer

Add, mix w e l l * S u l f u r i c Ac id (95%)

Add, mix w e l l H y d r o f l u o r i c Ac id (70%)

Add, mix w e l l

A1 u m i num B r i sh tener A1 02

I n g r e d i e n t : Water Ac id Foamer

Add, mix w e l l * S u l f u r i c Ac id (95%)

Add, mix, then coo l Ammoni um B i f 1 u o r i de

Add, mix w e l l

W S 32.40 17.60

45.00

5 . 0 0

W B 70.00

3.00

10.00

17.00

W B 64.00

3.00

20.00

13.00

pH: 3 .50 Recommended D i 1 u t i ons : 10-30 : 1 A p p l i c a t i o n s : Truckwash, v e r t i c a l aluminum sur face c lean ing Notes: *A p r e p a r a t i o n and use o f a s tock s o l u t i o n o f 3%

g l y c o l ether/97% Ac id Foamer w i l l a i d i n s o l u b i l - i z a t i o n and homogeniety

SOURCE: Tomah Products, I n c . : Suggested Formula t ions

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12 Advanced Cleaning Product Formulations

Bui 1 t Steam Cleaner

Inq red i ent : Water STPP

Dissolve, mix w e l l Na M e t a s i l i c a t e Pentahydrate

Dissolve, m i x w e l l Nonionic Surfactant-HLB 13

Add, mix we l l Tomah A l k a l i Sur factant

Add, mix u n t i l c l e a r SpG 20/20F: 1.10 pH: 10.40 Recommended D i l u t i o n s : 1 oz/gal Appl icat ions: I n d u s t r i a l degreasing and c leaning

Formula 1-105

A1 umi num Soak Tank C l eaner/Bri ahtener

Ins red i ent : Water EDTA (39%)

KOH (45%)

42 Sodium S i l i c a t e 3.22/1

Nonionic Surfactant-HLB 13

Tomah A l k a l i Sur factant

Add, mix w e l l

Add, mix w e l l

Add, mix w e l l

Add, mix we l l

Add. mix w e l l pH: 13.50 Recommended D i l u t i o n s : 10-3O:l Appl icat ions: p a r t s soak

Formula 1-102

Heavy Duty Steam Cleaner

W B 79.00 10.00

2.00

5.00

5.00

Wt% 51 .OO 2.00

20.00

20.00

3.00

2.00

I nq red i ent : Water Na M e t a s i l i c a t e Pentahydrate

KOH (45%)

Tomah A1 ka l i Surfactant

Dissolve u n t i l c l e a r

Add, mix w e l l

Add, mix w e l l pH: 14.00 Recommended D i l u t i o n s : 20-5O:l Appl icat ions: I n d u s t r i a l c leaning and degreasing Notes: Long term storage should be i n p l a s t i c containers,

as w i l l e tch g lass Formula 1-109

Wt% 45.00 30.00

10.00

15.00

SOURCE: Tomah Products, I n c . : Suggested Formulations

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Dairy, Food and General Industrial Cleaners 13

Burco TME Burco FA€ D-Limonene Water

d-Li monene M i croernul s i on C1 eaner/Deareaser

1 1 p a r t s 1 1 p a r t s 16 p a r t s 62 p a r t s

Mix i n o rder l i s t e d , add water s l o w l y . Product w i l l t h i cken , then break as water i s added.

No co -so l ven t i s r e q u i r e d when mixed i n p r o p o r t i o n s g iven above. Produces a c l e a r p roduc t . Burco FAE impar t s c o r r o s i o n r e s i s t a n c e i n a d d i t i o n t o emulsion c h a r a c t e r i s t i c s .

b u t r a t i o s o f t h e o t h e r a c t i v e s must remain s i m i l a r t o t h e above Exampl e:

To make a more concent ra ted p roduc t , l e s s water can be used,

TME FAE d-L i monene Water

22 p a r t s 22 p a r t s 32 p a r t s 24 p a r t s

High a c t i v e p roduc ts can reach a g e l - l i k e v i s c o s i t y , bu t can be th inned w i t h Isopropano l o r B u t y l P r o p y l s o l v .

Heavy Duty I n d u s t r i a l Cleaner

Components: % by Weiqht Water 6 . 5 Burco NPS-225 Burco LAA-38 Burco TME 45% KOH K a s i l #1 TKPP

1 0 . 0 0.75 0 . 7 5

24.0 48.0 10 .0

Procedure: 1 ) D i s s o l v e Burco NPS-225, Burco LAA-38 and Burco TME i n water. 2 ) Add 45% KOH and b lend u n t i l un i fo rm then add K a s i l #1 and

3 ) Add TKPP and s t i r u n t i l f u l l y d i s s o l v e d . b lend u n t i l un i fo rm.

T h i s concent ra ted f o r m u l a t i o n can be used f o r a v a r i e t y o f a p p l i c a t i o n s . The b u i l d e r systam i s designed t o be sa fe f o r use on a v a r i e t y o f su r faces a t use d i l u t i o n s . Poss ib le a p p l i c a t i o n s i n c l ude :

* I n d u s t r i a1 1 aundry * Equipment c l e a n i n g * Veh ic le c l e a n i n g * Other i n d u s t r i a l a p p l i c a t i o n s r e q u i r i n g a ve ry heavy d u t y

de te rgen t .

SOURCE: B u r l i n g t o n Chemical Co., I n c . : Suggested Formula t ions

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14 Advanced Cleaning Product Formulations

E l ec t roc leaner

Components: Water Burco BSGH-400 Burco NPS-225 Burco TME 50% NaOH

% by Weight 2-8 1-4

0.75-3 0.25-1

To 100% T o t a l

Basic Formula t ing Gu ide l ines : 1) R a t i o o f Burco NPS-225/Burco TME should be 3/1. 2 ) The l e v e l o f Burco BSGH-400 i s p r e f e r a b l y equal t o t h e sum

3) The water charge should be equal t o t h e sum o f Burco BSGH-400,

4) Premix a l l components b u t NaOH, then add NaOH w i t h s t i r r i n g .

Th is f o r m u l a t i o n w i l l p r o v i d e moderate foam l e v e l s and i s s u i t a b l e f o r use as an e lec t roc leaner , food p l a n t c leaner o r o the r a p p l i c a t i o n s where h i g h c a u s t i c concent ra tes a r e used. For reduced foam l e v e l s as i n an a l k a l i n e spray c leaner , rep lace Burco NPS-225 w i t h Burco HCS-SONF.

o f Burco NPS-225 and Burco TME.

Burco NPS-225 and Burco TME.

Low Foam Tankt ruck Cleaner

Safe on aluminum sur faces f o r e x t e r i o r and i n t e r i o r c lean ing . S tab le i n hard water .

Water KOH-45% K a s i l #1 STPP Burco HCS-5ONF

% by Weiaht 26.5 19.5 39.0 8.0 7 . 0

% S o l i d s : 31.0

Add components i n o rde r l i s t e d . Blend between a d d i t i o n s . To fo rmula te a lower a c t i v i t y p roduc t , keep t h e r a t i o s o f

t h e components t h e same. so t h a t t h e ba lance o f t h e f o r m u l a t i o n i s no t destroyed. End use concen t ra t i ons w i l l depend on degree o f s o i l t o be removed.

A s l i g h t s i l i c a t e p r e c i p i t a t e may occur upon l o n g s tand ing .

SOURCE: B u r l i ngton Chemical Co. , I n c . : SUQQeSted Formula t ions

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Dairy, Food and General Industrial Cleaners 15

Food P l a n t C?eaners Foamy A c i d Dai r y C1 eaner

I n a r e d i e n t : Water Phosphoric Ac id (85%)

Add, mix, coo l Monosodium phosphate, monohydrate

Add, d i s s o l v e , mix w e l l Tomah Amphoteric SC

Add, mix w e l l SpG 20/20C: 1.47 pH: 1.67 Recommended D i l u t i o n s : 10-2O:l Appl i c a t i ons : Dai r y p l a n t c l eani ng

Formula A-101

Low Foam-Sel f Demul s i f v i na C1 eaner I n a r e d i en t : Water T r i sodi um Phosphate

D i sso l ve

Mix w e l l Tomah Amphoteric 400

Mix w e l l T r i t o n CF-10

Mix w e l l pH: 11.50 Recommended D i l u t i o n s : 10-2O:l A p p l i c a t i o n s : Low foam f l o o r , CIP Notes: Demu ls i f i es food o i l s r a p i d l y w i t h no t rea tment

EDTA (39-40%)

Formula LF-101

Wt% 32.40 17.60

45.00

5.00

W B 92.20

1.30

2.00

3.50

1 .oo

Low Foam Moderate DH. S e l f Demu ls i f y inq I n a r e d i e n t : Wt% Water 86.90 C i t r i c a c i d 1 .oo

T r i sodium phosphate 1.30 D i sso l ve

D isso lve

Mix w e l l

M ix w e l l

M ix w e l l pH: 8.50 Recommended D i l u t i o n s : 10-2O:l A p p l i c a t i o n s : Low foam f l o o r , C I P Notes: Demu ls i f i es food o i l s r a p i d l y w i t h no t rea tment

EDTA (39-40%) 2.00

Tomah Amphoteric 400 7.80

T r i t o n CF-10 1 .oo

Good detergency even a t lower pH Formula LF-102

SOURCE: Tomah Products, I n c . : Suggested Formula t ions

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I6 Advanced Cleaning Product Formulations

G r a f f i t i Remover 1

Inaredi ent : Dei oni zed Water KOH (45%)

Add, mix w e l l Sodi um g l uconate

Add, mix we l l Methanol

Add, mix we l l Ethylene g l yco l b u t y l e ther

Add, mix w e l l Tomah A l k a l i Sur factant

Add, mix w e l l

SpG 20/20C: 1.225 pH: 13.9 Recommended D i l u t i o n s : 1-1O:l Appl icat ions: Removes most p a i n t , markers, e t c

Formula S-103

G r a f f i t i Remover 2

Inaredi ent : So f t Water KOH (45%)

Sodi um G1 uconate

Tomah A1 ka l i Surfactant

Methanol

Dipropylene g l yco l methyl e ther

Mix we l l

Mix we l l

Mix we l l

Mix we l l

Mix w e l l

SpG 20/20C: 1.22 pH: 13.70 Recommended D i l u t i o n s : 10-2O:l Notes: E f f e c t i v e on most p a i n t s and inks

Formula S-104

SOURCE: Tomah Products, I n c . : Suggested Formulations

Wt% 2 0 . 0 0 5 0 . 0 0

5.00

5.00

5.00

15.00

Wt% 28.00 50.00

2.00

10.00

5.00

5.00

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Dairy, Food and General Industrial Cleaners I7

Heavy Duty C leaners ( I n d u s t r i a l 1 Steam_Cle_ners-Liquids

Water TKPP Potassium Hydroxide (45%) Starso sodi um s i 1 i c a t e Phosphate e s t e r Octy lpheno l , 7-8 moles EO

Water TKPP Potassium hyd rox ide (45%) Starso sodi urn s i 1 i c a t e Phosphate e s t e r C9-Cll l i n e a r a l c o h o l , 6 moles EO

- Steam Cleaners-Powders -__-

STPP Sodi um carbonate C9-C10 l i n e a r a l c o h o l , 12 moles EO Metso Beads 2048 sodi um metasi 1 i c a t e

STPP C9-C10 1 i near a l c o h o l , 12 moles EO Sodi um g l uconate Metso Pentabead 20 sodium m e t a s i l i c a t e

18.8% 17.2% 31 .3% 30.0% 2.3% 0.4%

34.1% 17.2% 31.1% 15.2% 2.0% 0.4%

35% 2 0% 10% 3 5%

50% 3% 2% 4 5%

SOURCE: PQ Corp.: Detergent Formulary: Suggested Formula t ions

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18 Advanced Cleaning Product Formulations

Heavy D u t y I n d u s t r i a l S w a y Cleaner Concentrate F-543

Water Sodium Hydroxide (50%) Mona NF-25

‘k BY. Wei s h t 40 50 10

Procedure:

Typ ica l P r o p e r t i e s :

Add i n g r e d i e n t s i n t h e order l i s t e d w i t h a g i t a t i o n

Cloud P o i n t : t75C K r a f f t P o i n t : (5C

Recommended Use D i l u t i o n : 1 t o 4 o z . / g a l .

Heavy D u t y I n d u s t r i a l Spray Meta l Cleaner Concentrate F-544

Water Potassi um Hydroxide Sodi um Metasi 1 i c a t e (Anhydrous) Sodium Carbonate Mona NF-25

% By Weight 65 10 10

5 10

Procedure: Add i n g r e d i e n t s i n t h e order l i s t e d w i t h a g i t a t i o n .

Typi c a l Proper t i 8s : Cloud P o i n t : 43C K r a f f t P o i n t : t O C

Recommended Use D i l u t i o n : 6 t o 8 o z . / g a l .

H i ah Sol i d s A1 k a l i ne Cl-eaner F-555

Water Potassi um Hydroxide Sodium M e t a s i l i c a t e (Anhydrous) Tetrapotassium Pyrophosphate Mona NF-25

% By Weiaht 45.0 1 0 . 0 1 0 . 0 25.0 1 0 . 0

Procedure:

SOURCE: Mona I n d u s t r i e s , I n c . : Suggested Formula t ions

Mix i n g r e d i e n t s i n t h e order l i s t e d w i t h a g i t a t i o n .

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Dairy, Food and General Industrial Cleaners 19

High Foamina Smokehouse C leaner - I

I n q r e d i e n t : S o f t Water NaOH (50%)

Add, mix, coo l Tomah A0-728 Speci a1

Add, mix w e l l Tomah Amphoteric SC

Add, mix w e l l Non ion ic Surfactant-HLB 13

Add, mix w e l l

W B 60.70 30.00

3.00

5.30

1 .oo

pH: 14.50 Recommended D i 1 u t i ons : 5-1 0 : 1 A p p l i c a t i o n s : Food p l a n t c lean ing , good e m u l s i f i c a t i o n and

foam Formula 1-116-1

H igh Foaminq Smokehouse C leaner - I1

I n q r e d i en t : S o f t Water NaOH (50%)

Add, mix, coo l Tomah A0-728 Spec ia l

Add, mix w e l l Tomah Ampohoteric N

Add, mix w e l l Non ion ic Surfactant-HLB 13

Add, mix w e l l

W t % 60.40 30.00

3.00

5.60

1 .oo

pH: 14.50 Recommended D i 1 u t i ons : 5-1 0 : 1 A p p l i c a t i o n s : Food p l a n t c lean ing , good e m u l s i f i c a t i o n and

foam Formula 1-116-11

SOURCE: Tomah Products, I n c . : Suggested Formula t ions

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20 Advanced Cleaning Product Formulations

I n d u s t r i a l Cleaners A c i d Based A1 u m i nurn/SS C1 eaner

I n q r e d i en t : Water Phosphoric Ac id (85%)

Add, mix w e l l C i t r i c Ac id

Add, mix w e l l Amphoteric SC o r A l k a l i Su r fac tan t

Add, mix w e l l Methyl E t h y l Ketone

Add, mix w e l l SpG 20/20C: 1.03 pH: 1.2-1.4 Recommended D i 1 u t i ons: 1-2 oz/gal 1 on A p p l i c a t i o n s : metal c lean ing

Formula 1-100

A c i d Based Meta l Cleaner

I n a r e d i e n t : Water Phosphoric Ac id (85%)

G l y c o l i c Ac id

Tomah A l k a l i Su r fac tan t

SDG 20/20C: 1.19

Add, coo l

Add, coo l

Add, mix w e l l

Wt% 88.00 3.00

4.00

2.00

3.00

W S 61 .OO 35.00

1 .oo

3.00

pH: 0.90 Recommended D i l u t i o n s : 1-2 o z / g a l l o n A p p l i c a t i o n s : Metal c leaner Notes: Rinse w e l l a f t e r wash. N e u t r a l i z e i f necessary

Formula 1-101

L i g h t Duty Neu t ra l Cleaner

I n g r e d i e n t : W B

Tomah AO-14-2 1 .oo

Tomah P-17-2 1 .oo

Water 95.00

Add, mix w e l l

Add, mix w e l l

Add, mix w e l l SpG 20/20F: 1.00 pH: 7.6 Recommended D i l u t i o n s : as i s o r 1O:l A p p l i c a t i o n s : Wal l , f l o o r , t i l e wash Notes: Good on l i g h t hydrocarbon and food s o i l s

Formula 1-110

SOURCE: Tomah Products, I n c . : Suggested Formula t ions

Non ion ic Surfactant-HLB 13 3.00

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Dairy, Food and General Industrial Cleaners 21

I n d u s t r i a l Cleaners A n i o n i c/Noni o n i c G1 v c o l E ther HSC

I n a r e d i e n t : S o f t Water TKPP

D isso lve KOH (45%)

Add, mix w e l l D i p ropy l ene g l y c o l methyl e the r

Add, mix w e l l DDBSA, Na s a l t (60%)

Add, mix w e l l Non ion ic Surfactant-HLB 13

Add, mix w e l l Tomah Amphoteric 400

Add, mix w e l l

pH: 14.06 Recommended D i l u t i o n s : 10-3O:l A p p l i c a t i o n s : HSC Notes: Good foam and degreasing

Formula 1-103

An ion ic /Non ion ic HD HSC

I n n r e d i en t : S o f t Water EDTA

D i sso l ve KDH (45%)

Add, mix w e l l TKPP

D i sso l ve Potass i um S i 1 i c a t e

Add, mix w e l l DDBSA, Na s a l t (60%)

Add, mix w e l l Non ion ic Surfactant-HLB 13

Add, mix w e l l Tomah A l k a l i Su r fac tan t

Add, mix w e l l

pH: 13.86 Recommended D i l u t i o n s : 10-3O:l Appl i c a t i ons : HSC Notes: E x c e l l e n t b u i l t c leaner

Formula 1-104

SOURCE: Tomah Products, I n c . : Suggested Formula t ions

W B 76.50

5.00

5.00

5.00

3 .50

2 . 0 0

3.00

W B 80.00

0.50

5.00

3.00

3.00

3.50

2.00

3.00

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22 Advanced Cleaning Product Formulations

Low VOC Cleaners Non-Caustic I n d u s t r i a l Cleaner

Ina red ien t : Water Na M e t a s i l i c a t e Pentahydrate

EDTA 100%

TKPP

Tomah AO-14-2

Tomah P-14-2

Nonionic Surfactant-HLB 13

D i ssolve completely w i t h m i x i ng

Dissolve completely w i t h mix ing

Dissolve completely w i t h mix ing

Add w i t h mixing

Add w i t h mix ing

Add w i t h mix ing

SpG 20/20F: 1.03 pH: 12.95 Recommended D i l u t i o n s : 10-2O:l Appl icat ions: I n d u s t r i a1

Formula LV-I 02

Low VOC Heavy Duty Presoak

Ina red i ent : Water Na M e t a s i l i c a t e Pentahydrate

Dissolve completely w i t h mix ing

Dissolve completely w i t h mix ing

Dissolve completley w i t h mix ing

Add w i t h mixing

Add w i t h mix ing

Add w i t h mix ing

SpG 20/20F: 1.00 pH: 12.50 Recommended D i l u t i o n s : 10-5O:l depending on cond i t i ons Appl icat ions: Carwash presoak, soak tank c leaner

Formula LV-105

SOURCE: Tornah Products, I nc . : Suggested Formulations

NTA (40%)

TKPP

Tomah AO-14-2

Tomah Q-14-2

Nonionic Surfactant-HLB13

Wt% 90.40

2.00

I .60

2.00

1 .oo

1 .oo

2.00

Wt% 77.00

2.00

4.00

6.00

1 .oo

3.00

3.00

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Dairy, Food and General Industrial Cleaners 23

Low VOC Cleaners Non Solvent Medium Dutv Deareaser

Inq red i ent : Water Na M e t a s i l i c a t e Pentahydrate

TKPP

NaOH (50%)

EDTA (40%)

Tomah AO-14-2

Tomah 9-14-2

Nonionic Surfactant-HLB 13

Dissolve completely w i t h mixing

Dissolve completely w i t h mix ing

Add s lowly w i t h mix ing

Add s lowly w i t h mixing

Add w i t h mixing

Add w i t h mix ing

Add w i t h mix ing

3 86.50

2.50

1 .oo

4.50

1.50

1 .oo

1 .oo

2.00

SpG 20/20F: 1 .08 pH: 12.50 Recommended D i 1 u t i on : 10-20 : 1 Appl icat ions: I n d u s t r i a l c leaning, metal, concrete, e t c

Formula LV-100

Non-Solvent Heavv Duty Steam Cleaner

Inn red i ent : Water Na Metasi 1 i c a t e Pentahydrate

NaOH (50%) D i ssolve completely w i t h m i x i ng

Add s lowly w i t h mixing

Add s lowly w i t h mix ing

Add w i t h mix ing

Add w i t h mix ing

Add w i t h mixing

NTA (40%)

Tomah AO-14-2

Tomah 9-14-2

Nonionic Surfactant-HLB 13

W t % 81.50

2.00

9 .50

1 .oo

1 .50

1 .50

3.00

SpG 20/20F: 1 .03 pH: 12.60 Recommended D i 1 u t i ons : 10-20 : 1 Appl icat ions: I n d u s t r i a l steam c leaning, concrete, metal. e t c

Formula LV-101

SOURCE: Tomah Products, I n c . : Suggested Formulations

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24 Advanced Cleaning Product Formulations

Low VOC Solvent Cleaner-Isopar G

Inq red i ent : Exxon Isopar G Tomah (2-17-2

Mix we l l Nonionic Surfactant-HLB 13

Mix w e l l Tomah E-14-2

Mix we l l Water

Add very s low ly w i t h mixing Tomah AO-14-2

Add w i t h mix ing Water

Add very s lowly w i t h mix ing Tomah A l k a l i Sur factant

Add w i t h mix ing

W B 7.00 3.00

2.00

3.00

65.00

2.00

18.00

q . s .

pH: neu t ra l Recommended D i l u t i o n s : 10-3O:l Appl icat ions: G r a f f i t i Remover, Degreaser, Cosmoline Remover Notes: Faster d ry ing than Isopar M formula, bu t lower f l a s h

p o i n t Formula LV-104

Low VOC Solvent Cleaner-Isopar M

Ina red i ent : Exxon Isopar M Tomah 0-17-2

Mix w e l l Nonionic Surfactant-HLB 13

Mix w e l l Tomah E-14-2

Mix w e l l Water

Add very Tomah AO-14

Add w i t h Water

Add very Tomah A lka l

Add w i t h

s lowly w i t h mixing 2 m i x i ng

s lowly w i t h mix ing

m i x i ng Sur factant

Wt% 7.00 1 .oo

2.00

4.00

66.00

2.00

17.50

0.50

pH: Neutral Recommended D i l u t i o n s : 10-3O:l App l i ca t i ons : G r a f f i t i Remover, Degreaser. Cosmoline Remover Notes: High f l a s h formula

Formula LV-103

SOURCE: Tomah Products, I nc . : Suggested Formulations

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Dairy, Food and General Industrial Cleaners 25

S a n i t i z e r s and Food P l a n t C leaners Detergent f o r B lood Removal

STPP o r TSPP Sesqui carbonate An ion ic Foam s t a b i 1 i zer

To be used i n coo l wa te r .

45-60% 35-40

3- 5 0- 3

Food P1 a n t and Dai r y Deteraent Sani t i zer*

CDB Clearon STPP Sodium m e t a s i l i c a t e anhydrous LAS (85% a c t i v e ) Sodi urn s u l f a t e

* EPA r e g i s t e r e d s a n i t i z e r

5.6% 35

5 5

4 9 . 4

General Purpose S a n i t i z e r s * * A1 k a l i ne

CDB Clearon STPP Sodium s u l f a t e

2 5% 10 65

A c i d i c

28% 42 30

CDB Clearon Sodium s u l f a t e Monosodium phosphate

M i l d l y A c i d i c

CDB Clearon Sodi um s u l f a t e

**EPA r e g i s t e r e d sani t i ze rs

3 4% 66

SOURCE: FMC Corp. : Detergent A p p l i c a t i o n s B u l l e t i n No. 4 : Suggested Formula t ions

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26 Advanced Cleaning Product Formulations

Sani t i zerg and Food P1 a n t Cleaners General Purpose Eauipment Detergent-1

STPP Sodium m e t a s i l i c a t e anhydrous NaOH Anionic or Nonionic* Soda ash

General Purpose E q u i p m e n t - w r a e n t - I 1

STPP Sodi um metasi 1 i ca te anhydrous Ani oni c or Noni on i c* Soda ash

* O m i t a l l su r fac tan ts f o r C I P app l i ca t i ons .

STPP Sodi um metasi 1 i cate Anionic or Nonionic CDB Clearon Soda ash

STPP TSP Crys ta l s Sesquicarbonate Anionic or Nonionic

STPP or TSPP Anionic or Nonionic** Sodium gluconate Soda ash NaOH

M i l k Can Cleaners-I

M i 1 k Can Cleaner- I1

- Soak B o t t l e Cleaner- I

Soak B o t t l e Cleaner- I1

TSP Anionic or Nonionic** NaOH

30-50% 10-20 10-20 0- 2

balance

30-50% 10-15 5- 6

balance

30-50% 20-40

2 2- 3

balance

50% 20 25

5

20% 0-2 1-3 10

balance

5% 0-2

balance

**For spray cleaners, low foam su r fac tan t requi red. Must be compati b l e w i t h NaOH .

SOURCE: FMC Corp.: Detergent App l i ca t i ons B u l l e t i n No. 4: Suggested Formulations

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Dairy, Food and General Industrial Cleaners 27

S a n i t i z e r s and Food P lan t Cleaners Heavy Duty Ch lo r ina ted Cleaner

CDB Clearon STPP Sodium m e t a s i l i c a t e anhydrous NaOH Soda ash o r sodium s u l f a t e

Heavy Duty L i q u i d Chlor inated Cleaner- I

Water STPP Kasi 1 #1 (Potassi um s i 1 i c a t e ) KOH (100% bas is ) Sodium hypoch lo r i t e (15% s o l u t i o n )

Heavy Duty L i q u i d Chlor inated Cleaner- I1

Water TKPP STPP Kasi 1 #1 (Potassi um s i 1 i c a t e ) KOH ( 1 00% basi s ) Sodium hypoch lo r i t e (15% s o l u t i o n )

Heavy Duty L i q u i d Chlor inated Cleaner-I11

Water TKPP STPP Kas i l #1 (Potassium s i l i c a t e ) KOH (100% basis) Sodium hypoch lo r i t e (15% s o l u t i o n )

SOURCE: FMC Corp.: Detergent App l i ca t i ons B u l l e t i n No.4: Suggested Formulations

2- 5% 30-45 10-20 5-20

balance

50.1% 10 .0 1 4 . 4 1 5 . 5 10 .0

3 5% 5 . 0

1 0 . 5 24 .0 15 .5 1 0 . 0

25.0 20.0

5 . 5 2 4 . 0 15 .5 10

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3. Degreasers

28

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Degreasers 29

A l l Purpose A l k a l i n e Degreaser-A

Components: Water Tetrasodium EOTA ( l oo%)* L i q u i d potassium s i l i c a t e (2.1Si02/K20)** Potassium hydrox ide (50%) Sodium xy lene s u l f o n a t e (40%)*** Non ion ic s u r f a c t a n t : Genapol UO 079

Phys ica l P roper t i es : Appearance (25C): c l e a r pH ( l % , 25C): 10.8 Ross M i l e s (49C, 1%, cm):

1 m in . : 3 . 0 5 min . : 1.0

Cloud Po in t ( l% /as i s , C ) : 40/65 Surface tens ion (0.25%, dynes/cm): 27.42 Freeze thaw s t a b l e : f r e e z i n g p o i n t (C): ( 0

A1 1 Purpose A1 k a l i ne Degreaser-B

Components: Water Tet rasod i um EOTA ( 100%) * L i q u i d potassium s i l i c a t e (2.1Si02/K20)** Potass i um hydrox ide (50%) Sodium xy lene s u l f o n a t e (40%)*** Nonionic s u r f a c t a n t :

Genapol UD 030 Genapol UO 079

Phys ica l P r o p e r t i es : Appearance (25C): c l e a r pH ( l % , 25C): 10.8 Ross M i l e s (49C, 1%, cm):

1 min . : 4.0 5 min . : 0.5

Cloud Po in t ( l % / a s i s , C): 35/52 Sur face t e n s i o n (0.25%, dynes/cm): 26.85 Freeze thaw s t a b l e : f r e e z i n g p o i n t (C): <O

W t . % 72

4 7 2 5

10

W t . % 73 5 7 2 5

2 6

Procedure:

con t inuous s t i r r i n g . Be sure t h e te t rasod ium EDTA i s t o t a l l y d i sso l ved be fo re adding t h e l i q u i d s i l i c a t e .

Blend t h e components one a t a t ime i n t h e g iven order w i t h

* Versene 220 c r y s t a l ** K a s i l #6

*** Witconate 1260

SOURCE: Hoechst Celanese Corp.: Suggested Formulat ions

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30 Advanced Cleaning Product Formulatiom

A1 1 Purpose A1 k a l i ne Desreaser-C

ComDonents: Water Tet rasod i um EDTA ( 100%) * L i q u i d potassium s i l i c a t e (2.1Si02/K20)** Potassi um hydrox ide (50%) Sodium xy lene s u l f o n a t e (40%)*** Nonionic s u r f a c t a n t :

Genapol 26-L-2 Genapol 26-L-60

W t . % 74

4 7

2 5

2 6

Phys ica l P roper t i es : Appearance (25C): c l e a r pH (1%’ 25C): 10.8 Ross M i l e s (49C, 1%. cm):

1 min . : 4.0 5 min . : 1.0

Cloud P o i n t ( l% /as i s , C) : 37/75 Surface t e n s i o n (0.25%. dynes/cm): 26.85 Freeze thaw s t a b l e: f reez i ng po i n t (C) : f rozen, b u t s t a b l e

A1 1 Purpose A1 k a l i ne Depreaser-D

ComDonents: Water Te t rasod i um EDTA (1 O O % ) * L i q u i d potassium s i l i c a t e (2.1Si02/K20)** Potassi um hydrox ide (50%) Sodium xy lene s u l f o n a t e (40%)*** Non ion ic s u r f a c t a n t :

Hostapal N 040 Hostapal N 090

Phys ica l P roper t i es : Appearance (25C): c l e a r pH (l%, 25C): 10.8 Ross M i l e s (49C, 1%. cm):

1 min.: 4.0 5 min. : 2.0

Cloud Po in t ( l%/as i s , C): 32/25 Sur face t e n s i o n (0.25%, dynes/cm): 29.98 Freeze thaw s t a b l e : f r e e z i n g p o i n t ( C ) : tO

W t . % 75

4 7 2 5

2 5

Procedure:

cont inuous s t i r r i n g . Be sure t h e te t rasod ium EDTA i s t o t a l l y d i sso l ved be fo re adding t h e l i q u i d s i l i c a t e .

Blend t h e components one a t a t i m e i n t h e g i ven o rde r w i t h

* Versene 220 C r y s t a l ** K a s i l #6

*** Wi tconate 1260

SOURCE: Hoechst Celanese Corp.: SuOOested Formula t ions

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Degreasers 3 I

Deareasers I n d u s t r i a1 Degreaser

Formula t ion : Kerosene Oowanol DPM ( o r 1:l PnB:DPM) g l y c o l e ther S i poni c SK condensate

Soray Degreaser

Formula t ion : M i r ano l C2M amphoteric Sodium t r i po l yphospha te Sodi um metasi 1 i c a t e T r i sodi um phosphate T a l l o i l f a t t y a c i d Potassium hydrox ide (45%) Dowanol PM ( o r 1 : 1 PM:PnB) g l y c o l e the r Water

Engine Cleaner and Deoreaser

Formula t ion : Monoi sopropanol ami ne Water At1 as (53300 s u r f a c t a n t Dowanol OPM ( o r PnB) g l y c o l e ther Versene 100 c h e l a t i n g agont

Cosmoline Remover (Heavy o i l o r greasy-wax remover)

Formu 1 a t i on : Xyl ene Perch lo roe thy lene Igepa l CO-530 s u r f a c t a n t Dowanol DPM ( o r PnB) g l y c o l e the r

SOURCE: Dow Chemical Co. : Suggested Formula t ions

Wt.% 60.0 15.0 25.0

Wt.% 3.3 1 . 4 2.7 1.4 1.7 1 . o 8.5

80.0

Wt.% 20.0 58.0 5.0 15.0 2.0

Wt.% 30.0 30.0 20.0 20.0

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32 Advanced Cleaning Product Formulations

Deareaser Formula t ion

Kerosene Alcodet MC-2000 Rhodacal 330 Bu ty l C e l l o s o l v e

Wt.% 70 10 10 10

Procedure:

Physi c a l Proper t i es : Appearance: Clear, ye l l ow l i q u i d pH, 1% S o l u t i o n : 6.5 S p e c i f i c G r a v i t y : 0.83 V i s c o s i t y : t10 cps

Formula MC-0066

Add a l l i n g r e d i e n t s and mix w i t h a g i t a t i o n u n t i l homogeneous.

Metal Cleaner Spray

Butoxyethanol Igepa l CO-630 Kerosene

W t -3 20.0 20.0 60.0

Procedure:

Mix tho rough ly .

Phys ica l P roper t i es :

Mix Butoxyethanol and Kerosene toge the r . Add Igepa l CO-630.

pH (as i s ) : 7 . 5 pH ( 1 % ) : 6.4 S p e c i f i c G r a v i t y : 0.96 V i s c o s i t y : 10 cps

Formula MC-0067

SOURCE: Rhone-Poulenc: Suggested Formula t ions

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Degreasers 33

D-Limonene Deqreaser- I

I n q r e d i e n t : E thy lene g l y c o l b u t y l e the r

D-1 i monene

Tomah E-14-5

Tomah A1 k a l i Sur fac tan t

Non ion ic Surfactant-HLB 13

S o f t Water

EDTA (40%)

KOH (45%)

P a r t A

P a r t A-Mix we1 1

P a r t A-Mix w e l l

P a r t A-Mix w e l l

P a r t A-Mix w e l l

S lowly mix i n t o P a r t A

Add s l o w l y w i t h m ix ing

Add s l o w l y w i t h m ix ing

SpG 20/20C: 1 . O O pH: 12.60 Recommended D i 1 u t i ons : 5-20 : 1 A p p l i c a t i o n s : I n d u s t r i a l c lean ing , HSC

D-Limonene Deareaser- I1

I n q r e d i en t : E thy lene g l y c o l b u t y l e the r

D-1 i monene

Tomah E-14-5

Tomah A l k a l i Su r fac tan t

Non ion ic Surfactant-HLB 13

P a r t A

P a r t A-Mix w e l l

P a r t A-Mix w e l l

P a r t A-Mix w e l l

P a r t A-Mix w e l l

S lowly mix i n t o Par

Add s l o w l y w i t h mix

Add s l o w l y w i t h mix

Add s l o w l y w i t h mix

SpG 20/20C: 1.00 p H : 12.60

S o f t Water

EDTA (40%)

KOH (45%)

Monoethanol ami ne

Recommended D i 1 u t i ons : 5-20 : 1 A p p l i c a t i o n s : I n d u s t r i a l c lean ing , HSC

SOURCE: Tomah Products, I n c . : Formula S-109

Wt% 15.00

3.50

3.50

5 .00

2.00

69.00

1 .oo

1 .oo

15.00

3.50

3.50

5.00

2.00

68.00

1 .oo

1 .oo

1 .oo

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34 Advanced Cleaning Product Formulotiom

Heavy D u t y Deareaser

Butoxy Ethanol Mackam 2CSF Sodi um Metasi 1 i ca te Pentahydrate Sodium Tripolyphosphate Trisodium Phosphate T a l l O i l F a t t y Acid KOH (45%) EDTA (40%) Deionized Water

Procedure: 1. Add components t o water and heat t o 40C. 2 . Blend u n t i l c l e a r .

Heavy D u t y Deareaser

Mackam 2CSF (Cocoamphodipropionate) Mackamide LLM (Laurami de DEA) TKPP Trisodium NTA (40%) Caust ic Potash (45%) T r i t o n X-100 Water qs t o

Procedures: Add components i n order . Heat t o 40 degrees u n t i l c l e a r . Cool and f i 11.

Metal Deareaser Cleaner

Mackamide CDM (Cocamide DEA (and) DEA Oleate High Flash Naphtha

Weiqht .% 0.0 3.5 3.0 1.5 2.5 2.0 2.1 0.3

79.0

WeiQht .% 4.0 4.5 2.4 3.5 1.6 4.0

100.0

Wei aht .% 5.0

95.0

Procedure: Add Mackamide CDM t o Naphtha and blend u n t i l c l e a r .

Remarks :

c leaning engine blocks, garage f l o o r , e t c . The res idua l Mackamide CDM ac ts as a co r ros ion i n h i b i t o r .

SOURCE: McIntyre Group L td . : I n d u s t r i a l Formulary

This product can be r e a d i l y mixed w i t h water when used f o r

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Degreasers 35

M i cro-Emu1 s i ons w i t h A1 oe Vera and d-Li monene

The f o l l o w i n g fo rmulas a r e c l e a r , microemulsions o f d-Limonene and Aloe Vera. They represent t h e range o f d-Limonene and Aloe Vera concen t ra t i ons commonly used as degreas ing so l ven t c leaners . These fo rmulas a r e g e n e r a l l y used by d i l u t i n g i n water (1->16 o z . / g a l l o n depending on t h e use requ i rements ) . The fo rmulas a r e c l e a r and e x h i b i t a bloom e f f e c t upon d i l u t i o n .

d -L i monene Monamul se DL-1273 Isopropano l Water Aloe Vera Gel ( T e r r y AG002)

d -L i monene Monamul se DL-1273 Isopropano l Water A loe Vera Gel ( T e r r y AG002)

d -L i monene Monamul se DL-1273 Aloe Vera Gel ( T e r r y AG002)

%& 10.0 18 .0 10 .0 42.0 20.0

%& 35.0 28.0

5 .0 12.0 20.0

65.0 23.0 12 .0

Procedure:

comple te ly d i s s o l v e d and o f u n i f o r m cons is tency . Add t h e Iso- propano l , m i x i n g u n t i l homogeneous. Pre-mix A loe Vera Gel w i t h water . S lowly add t o ba tch w i t h s t i r r i n g u n t i l un i fo rm.

SOURCE: T e r r y L a b o r a t o r i e s , I n c . : Suggested Formula t ions

I n a l l cases, mix Monamulse DL-1273 w i t h d-Limonene u n t i l

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36 Advanced Cleaning Product Formulations

Phosphate Free Cleaners Glycol Ether Deareaser-I

I nn red i ent : So f t Water NaOH (50%)

Na M e t a s i l i c a t e Pentahydrate

EDTA (39%)

D i propyl ene g l yco l methyl ether

Tomah Amphoteric 400

Nonionic Surfactant-HLB 13

Add, mix w e l l

D i ssol ve

Add, mix we l l

Add, mix w e l l

Add, mix we l l

Add, m i x we l l

SDG 20/20C: 1.06 pH: 12’.80 Recommended D i l u t i o n : 10-5O:l Appl icat ions: High performance degreaser

Glycol Ether Deqreaser-I1

Inqredi ent : So f t Water NaOH (50%)

Add, mix we l l Na M e t a s i l i c a t e Pentahydrate

D i ssol ve EDTA (39%)

Add, mix w e l l Ethylene g l y c o l b u t y l e ther

Add, mix we l l Tomah Amphoteric 400

Add, m i x w e l l Nonionic Surfactant-HLB 13

Add, mix w e l l

SpG 20/20C: 1.06 pH: 12.80 Recommended D i l u t i o n : 10-5O:l Appl icat ions: High performance degreaser

SOURCE: Tomah Products, I n c . : Formula NP-100

W t % 72.00 5.00

3.00

2.00

10.00

6.00

2.00

Wt% 72.00 5.00

3.00

2.00

10.00

6.00

2.00

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Degreasers 37

So lven t C leaners G lvco l E t h e r Cleaner 3

I n q r e d i e n t : S o f t Water Sodium m e t a s i l i c a t e pentahydra te

EDTA (40%)

Ethy lene g l y c o l b u t y l e t h e r

Non ion ic Surfactant-HLB 13

Tomah A l k a l i S u r f a c t a n t

D i s s o l v e

Add, mix w e l l

Add, mix w e l l

Add, mix w e l l

Add, mix w e l l

SpG 20/20C: 1.04 pH: 12.50 Recommended D i l u t i o n s : 10-3O:l Appl i c a t i ons: HSC Notes: B u i l t degreaser

Formula S-102

Water R i nseab le Deqreaser I

I n n r e d i e n t : M ine ra l S p i r i t s Tomah Q-14-2

Nonion ic Surfactant-HLB 13

Tomah E-17-2

Dei on i zed water

Mix w e l l

Mix w e l l

M ix w e l l

S lowly add and mix w e l l

W S 83.00

5.00

2.00

5.00

3.00

2.00

W S 75.00

2.00

6.00

7.00

10.00

SpG 20/20C: 0.03 pH: 8.60 Recommended D i l u t i o n s : as necessary f o r a p p l i c a t i o n A p p l i c a t i o n s : C lean ing o f heavy g reases /pa in t / va rn i sh s t r i p p e r Notes: Viscous c leaner f o r b e t t e r c l i n g

Formula S-105

SOURCE: Tomah Products, I n c . : Suggested A p p l i c a t i o n s

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38 Advanced Cleaning Product Formulations

Solvent Cleaners Isopar M Emulsion

Ina red i ent : Exxon Isopar M

Par t A Tomah Emu1 s i f i e r Four

Par t A-Mix we l l Alcohol Ethoxylate-7E0

Par t A-Mix w e l l Ethylene g l y c o l b u t y l e ther

Par t A-Mix w e l l Water

Add s lowly w i t h good mixing pH: 7.00 Recommended D i l u t i o n s : 10-3O:l Appl i c a t i ons : HSC Notes: Unbu i l t degreaser, exce l l en t f o r heavy o i l s

Formula S-115

Kerosene Emu1 s i on Cleaner Inaredi ent : Kerosene Tomah E-14-2

Tomah Q-14-2

Nonionic Surfactant-HLB 13

So f t Water

Mix w e l l

Mix w e l l

Mix w e l l

Add very s lowly, mix w e l l SpG 20/20C: 0.92 pH: 9.30 Recommended D i l u t i o n s : As necessary Appl i c a t i ons: Degreaser

Formul a S-112

Aci d/Sol vent C1 eaner

actant

Ether

85%)

Ina red i ent : Water Tomah A l k a l i Sur

Mix w e l l Propyl ene G1 ycol

Mix w e l l Phosphoric Acid

Mix w e l l G1 uconi c Aci d

M i x we1 1 SpG 20/20C: 1.18 pH: 1.05 Recommended D i 1 u t i ons : 1-1 0 : 1 App l i ca t i ons : Metal brightener/cleaner/degreaser

Formula S-114

SOURCE: Tomah Products, I nc . : Suggested Formulations

Wt% 20.00

14.90

1.10

3.00

61 .OO

Wt% 35.00 14.00

3.00

3.00

45.00

W X 37.00 10.00

15.00

30.00

8 . 0 0

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4. Dishwashing Detergents

39

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40 Advanced Cleaning Product Formulations

Automatic Dishwash I

I n a r e d i en t : Water TKPP

D i sso l ve Na Metasi 1 i c a t e

D i sso l ve Na Benzoate

D i sso l ve Tomah Amphoteric 400

Add, mix w e l l T r i t o n CF-10 ( o r equ iva len t )

Add, mix w e l l pH: 13.80 Recommended D i l u t i o n s : t y p i c a l l o a d i n g A p p l i c a t i o n s : machine dishwash. low foam fo rmula

Formula D-107

Automat ic Dishwash I1

I n a r e d i e n t : Water TKPP

D isso lve Na M e t a s i l i c a t e Pentahydrate

D i sso l ve Na Benzoate

D i sso l ve Tomah Amphoteric 400

Add, mix w e l l T r i t o n CF-54 ( o r equ iva len t )

Add, mix w e l l pH: 13.40 Recommended D i 1 u t i ons: Typ ica l 1 oadi ng A p p l i c a t i o n s : Automatic dishwash, low foam fo rmula

Formula D-108

R inse A i d-Commerci a1 Machine

I n a r e d i e n t : Water T r i t o n CF-10

Tomah Amphoteric 400 Add, mix w e l l

Add, mix w e l l pH: 7.00 Recommended D i l u t i o n s : 100 ppm i n f i n a l r i n s e Appl i c a t i ons: R i nse a i d i n commerci a1 warewash

A ids i n water spot p reven t ion , Low foam Formula D-109

SOURCE: Tomah Products, I n c . : Suggested Formula t ions

Wt% 56.60 20.70

9.40

1 .oo

10.40

1.90

W t % 57.10 21 .oo

9.50

1 .oo

9.50

1.90

W> 42.50 47.50

10.00

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Dishwashing Detergents 41

Automatic Dishwash L i q u i d

Wei qht/% Water-dei on i zed 48.8% Lapon i te RDS 1.6% High Mono S t e a r y l Ac id Phosphate 0.6% Caust ic Soda 50% Rayon Grade 2.0% L i g h t Dens i t y Soda Ash 5.0% Sodi um T r i polyphosphate ( L i g h t Dens i ty grade 067) 20.0% Metso 2048, Sodium M e t a s i l i c a t e Anhydrous 11 .O% Avanel S-74 1 .O% Sodi um Hypochori t e 12.5% 10.0%

Procedure: 1 . Charge t h e water and t h e Lapon i te RDS t o t h e m ix ing vessel

and a l l o w t o s i t f o r f i v e minutes t o s t a r t t h e h y d r a t i o n t o o f t h e c l a y .

2 . S t a r t a g i t a t i o n and s l o w l y add t h e Monostearyl Phosphate and t h e Caust ic Soda. Mix tho rough ly t o reduce lumps. M i x t u r e w i l l be v iscous .

3 . S lowly add t h e Soda Ash, Sodium Tr ipo lyphosphate and t h e Sodium M e t a s i l l c a t e b lend ing w e l l a f t e r each a d d i t i o n . Adding these i n g r e d i e n t s w i l l produce an exothermic reac t i on , h e a t i n g t h e m i x t u r e t o 125-14OF.

4. Apply e x t e r n a l c o o l i n g and coo l t h e m i x t u r e t o l e s s than 9OF. 5 . Reduce a g i t a t i o n and add t h e Avanel S-74 and t h e Sodium

H y p o c h l o r i t e s o l u t i o n . 6 . F in i shed f o r m u l a t i o n w i l l con t i nue t o t h i c k e n f o r severa l

days a f t e r t h e b lend ing opera t i on i s complete. Packaging i n f i n a l con ta ine rs should be completed as soon as poss ib le .

SOURCE: PPG I n d u s t r i e s , I n c . : Suggested Formula t ion

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42 Advanced Cleaning Product Formulations

Automatic Dishwashing Gel-I

I _nqredient. 1 D I water Carbopol 672 r e s i n NaOH (50%) KTPP K2C03 RU Sodium S i l i c a t e (52%) Oowfax 2A-1 (45%) NaOCL (12%)

W e i s ! & .%-L?cLiivd 74.3

1 .2 2 .0

15.0 1 .o 5.0 0 . 5 1 . o

pH: 12+-0.2 V i s c o s i t y : 2,500-3,500 CP ( B r o o k f i e l d RVT @ 20rpm)

Automat ic D i shwashi nQ Gel -11

I n g r e d i e n t : D I water Carbopol 672 r e s i n NaOH (50%) KTPP STPP (1 i gh t d e n s i t y , anhydrous) STPP (hexahydrate) K2C03 RU Sodium S i l i c a t e (52%) Oowfax 2A-1 (45%) NaOCl (12%)

Weight % (ac t i ve ) - 72.3

1 .2 2.0 7 .0 4.0 4.0 3.0 5 .0 0 .5 1 .o

pH: 12.0+-0.2 V i s c o s i t y : 2,500-35OOcP ( B r o o k f i e l d RVT @ 20 r p m )

Order o f A d d i t i o n : 1. Using a L i g h t n i n ' M ixe r o r s i m i l a r u n i t . and an i m p e l l e r

s u i t a b l e f o r general m ix ing , screen t h e Carbopol r e s i n i n t o t h e v o r t e x o f t h e r a p i d l y a g i t a t i n g water (approx imate ly 800 rpm). A l l ow t o mix u n t i l homogeneous.

2 . Add NaOH and mix u n t i l homogeneous. 3. Add KTPP and STPP and mix u n t i l system i s c l e a r . 4. Add t h e remain ing i n g r e d i e n t s i n o rde r l i s t e d above and mix

u n t i l homogeneous.

SOURCE: B.F. Goodrich Co.: CARBOPOL High Performance Polymers: Suggested Formula t ions

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Dishwashing Detergents 43

Automatic Dishwashins L i q u i d

Water Ge lwh i te GP Sodi um Hydroxide (50%) Sodium M e t a s i l i c a t e Anhydrous Sodium Carbonate Sodi um T r i polyphosphate Sodium H y p o c h l o r i t e (12%) Mona NF-15

% B y Weiqht 44.5

3.0 3.0

15.0 6.0

18.0 8 .5 2.0

Procedure: B lend Ge lwh i te GP i n 60C wa te r . Add sodium hydrox ide , sodium

metasi 1 i c a t e , sod i um carbonate and sod i urn t r i polyphosphate w i t h r a p i d a g i t a t i o n . Cool t o room temperature, add sodium hypo- c h l o r i t e and Mona NF-15. A g i t a t e u n t i l un i fo rm.

C r y s t a l C l e a r Hand D i shwash

Water Ammoni um Laury l S u l f a t e 28% Ammonium Laure th ( 4 ) S u l f a t e (60%) Monater ic CAB-LC Mona1 ux CAO-LC Nonoxynol 10

% By Weiqht 13.0 18.0 17.0 14.0 33.0

5 . 0

Procedure:

Nonoxynol 10 and heat t o 40-60C. S t i r coo l t o 35-40C and a d j u s t pH t o 6-6.5 w i t h 50% c i t r i c a c i d .

SOURCE: Mona I n d u s t r i e s , I n c . : Suggested Formula t ions

Blend water , ALS, ALES-4, Monater ic CAB-LC, Monalux CAO-LC,

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44 Advanced Cleaning Product Formulotions

Clear Hand Dishwashinn L i a u i d (25% act ives)-A

Components: Par t A : Hostapur SAS 60 Genapol ZRO L i q u i d Part B: Water Preservat i ve Dye Perfume

W t . %

33.3 17.9

40.6 0 . 1 q .s . 0.1

Physical P roper t i es : V i s c o s i t y (25C. mPas): 75 Cloud Point (l%, C): (-5

Procedure:

ents o f Par t B one a t a t ime t o Par t A w i t h continuous s t i r r i ng.

Blend t h e su r fac tan t components i n Par t A . Add t h e compon-

Clear Hand Dishwashinn L i a u i d (25% ac t i ves ) -8

ComDonents: Part A: Hostapur SAS 60 Genapol ZRO L i q u i d Par t B: Water Preservat ive

Perfume Genagen LAB

Physical Proper t ies:

Dye

V iscos i t y (25C, mPas): 100 Cloud Point (1%. C ) : <-5

W t . %

33.3 17.9

47.6 0.1 q.s . 0.1 1 .o

Procedure:

o f Par t B one a t a t ime t o Par t A w i t h continuous s t i r r i n g .

SOURCE: Hoechst Celanese Corp.: Suggested Formulations Provided

Blend the su r fac tan t components i n Par t A . Add t h e components

by Hoechst AG

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Dishwashing Detergents 45

Clear Hand Dishwashinq L i q u i d (25% ac t ives) -C

Components: Pa r t A: Hostapur SAS 60 Genapol ZRO L i q u i d Par t B: Water P r e s e r v a t i v e

Perfume Genagen LAB

Dye

W t . %

33.3 17.9

44.6 0 . 1 q . s . 0 .1 4 .0

Phys ica l P r o p e r t i e s : V i s c o s i t y (25C, mPas): 230 Cloud P o i n t ( I % , C): (-5

Procedure:

o f P a r t B one a t a t i m e t o P a r t A w i t h cont inuous s t i r r i n g . Blend t h e s u r f a c t a n t components i n Pa r t A . Add t h e components

C lea r Hand Dishwashinn L i q u i d (25% ac t i ves ) -D

Components: P a r t A : Hostapur SAS 60 Genapol ZRO L i q u i d P a r t 0: Water P r e s e r v a t i v e

Perfume Genapol 26-L-3

b e

W t . %

33.3 17.9

47.6 0 . 1 q . s . 0 .1 1 .o

Phys i ca l P r o p e r t i 8s: V i s c o s i t y (25C, mPas): 90 Cloud P o i n t ( l % , C): (-5

Procedure:

o f P a r t B one a t a t i m e t o P a r t A w i t h cont inuous s t i r r i n g .

SOURCE: Hoechst Celanese Corp.: SugQested Formula t ions Provided

Blend t h e s u r f a c t a n t components i n Pa r t A . Add t h e components

by Hoechst AG

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46 Advanced Cleaning Product Formulations

Clear Hand Dishwashins L i q u i d (25% Actives)-D

Components: Par t A: Hostapur SAS 60 Genapol ZRO L i q u i d Par t B: Water Preservat ive Dye Perfume Genapol 26-L-3

W t . %

33.3 17.9

44.6 0.1 q .s 0.1 4.0

Physical Proper t ies: V i scos i t y (25C, mPas): 410 Cloud Point ( l % , C ) : (-5

Procedure:

o f Par t B one a t a t ime t o Par t A w i t h continuous s t i r r i n g . Blend t h e su r fac tan t components i n Par t A. Add t h e components

Clear Hand Dishwashina L i q u i d (30% Actives)-A

Components : Par t A: Hostapur SAS 60 Genapol ZRO L i q u i d Par t B: Water Preservat ive

Perfume Dye

W t . %

40 21.4

30.4 0.1 q.s . 0.1

Physical P roper t i 8s: V i scos i t y (25C. mPas): 330 Cloud Point ( l % , C ) : (-5

Blend t h e su r fac tan t components i n Pa r t A. Add t h e components Procedure:

o f Par t B one a t a t ime t o Par t A w i t h continuous s t i r r i n g .

SOURCE: Hoechst Celanese Corp.: Suggested Formulations Provided by Hoechst AG

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Dishwashing Detergents 47

Clear Hand Dishwashinq L i q u i d (30% Act ives)-8

Components: Par t A: Hostapur SAS 60 Genapol ZRO L i q u i d Par t 0: Water Preservat ive

Perfume Genagen LAB

Dye

W t . %

40 21.4

37.4 0.1 q .s . 0.1 1 .o

Physical P roper t i 8s: Viscos i t y (25C, mPas): 380 Cloud Point (l%, C ) : <-5

Procedure:

o f Par t B one a t a t ime t o Par t A w i t h continuous s t i r r i n g . Blend t h e su r fac tan t components i n Par t A. Add t h e components

Clear Hand Dishwashinq L i q u i d (30% Actives)-C

Components: Par t A : Hostapur SAS 60 Genapol ZRO L i q u i d Par t B: Water Preservat i ve Dye Perfume Genagen LAB

W t . %

40 21.4

34.4 0.1 q.s. 0.1 4.0

Physical Propert i es : V i s c o s i t y (25C, mPas): 630 Cloud Point (l%, C ) : ( - 5

Blend t h e su r fac tan t components i n Par t A. Add t h e components Procedure:

o f Par t B one a t a t ime t o Par t A w i t h continuous s t i r r i n g .

SOURCE: Hoechst Celenese Corp.: Suggested Formulations Provided by Hoechst AG

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48 Advanced Cleaning Product Formulations

Clear Hand Dishwashing L i a u i d (30% Act ives) -D

Components: Pa r t A: Hostapur SAS 60 Genapol ZRO L i q u i d Par t B: Water P rese rva t i ve

Perfume Genapol 26-L-3

Dy e

W t . %

40 21.4

37.4 0.1 q .s . 0 .1 1 . o

Phys ica l P roper t i es : V i s c o s i t y (25C, mPas): 420 Cloud Po in t (l%, C ) : <-5

Procedure:

o f P a r t B one a t a t i m e t o P a r t A w i t h cont inuous s t i r r i n g . Blend t h e s u r f a c t a n t components i n P a r t A . Add t h e components

C lea r Hand Dishwashing L i q u i d (30% Act ives) -E

Components: Pa r t A: Hostapur SAS 60 Genapol ZRO L i q u i d Par t B: Water Preserva t i ve

Perfume Genapol 26-L-3

Dye

W t . %

40 21.4

34.4 0 .1 q . s . 0.1 4.0

Phys ica l P roper t i es : V i s c o s i t y (25C. mPas): 610 Cloud P o i n t ( l % , C ) : (-5

Procedure:

o f P a r t B one a t a t i m e t o P a r t A w i t h cont inuous s t i r r i n g .

SOURCE: Hoechst Celanese Corp.: Suggested Formula t ions Provided

Blend t h e s u r f a c t a n t components i n P a r t A. Add t h e components

by Hoechst AG

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Dishwashing Detergents 49

Commercial Machine D i shwashi ng Compound-I STPP Sodi um metasi 1 i c a t e anhydrous NaOH CDB Clearon Soda ash

Commercial Machine D i shwashi na Compound-I1 STPP Sodium o r t h o s i l i c a t e CDB Clearon Soda ash

TKPP (60% solu<?on) KOH (45% s o l u t i o n ) Potassium s i l i c a t e (Si02/K20=2:1) Sodium h y p o c h l o r i t e (15% s o l n . ) Water

L i u i d Machine D i shwashi ng De te rqen t - I

L i q u i d Machine Dishwashinq De te rgen t - I1 STPP KOH (45% s o l u t i o n ) Potassium s i l i c a t e (Si02/K20=2:1) Sodi um hypoch lo r i t e ( 1 5% s o l n . ) Water SOURCE: FMC Corp.: Suggested Formula t ions

Non-DDBSA D i shwashi na L i q u i d

Rhodacal A-246/L Rhodapex MA-360 A1 kami de DC-212/S Sodium Xylene Su l fona te (40%) Opaci f i e r Water C i t r i c A c i d t o pH 6.5-7.5 Prefume and Co lor

30-50% 10-20 10-20 3- 5

balance

30-50% 40

3- 5 balance

15-25% 35-45

0- 8 5-1 0

balance

10% 10-25 0- 8 5-1 0

balance

Wt.% 60.0 10 .0

5.0 4.0 1 . o

20.0 Q.S. Q.S.

Procedure: 1 . Charge water and sodium xy lene s u l f o n a t e t o vessel equipped

t o vessel and mix w i t h a g i t a t i o n .

u n t i 1 un i fo rm. 2. Add Rhodacal A-246/L and Rhodapex MA-360

3. Add Alkamide DC-212/S and mix as above. 4. Ad jus t pH 6.5-7.5 w i t h c i t r i c a c i d . 5. Add o p a c i f i e r ( o p t i o n a l ) , perfume and co Phys i ca l P roDer t i es :

o ran t . as des i red .

-Appearance: C lear g o l d l i q u i d , dye and o p a c i f y t o p re fe rence. pH, as i s : 6.5-7.5 S p e c i f i c G r a v i t y : 1.02-1.04 V i s c o s i t y : 200-300 cps

SOURCE: Rhone-Poulenc: Formula OW-0008

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50 Advanced Cleaning product Formulations

‘Dishwash Products Pear lescent Premi urn I1

Ins red ien t : Water

R% 44.70

DDBSA. Na s a l t (60%) 23.50

Lauryl e ther s u l f a t e , ammonium s a l t (60%) 16.50 Add, mix w e l l

Add, mix w e l l

Add, mix w e l l

Add, mix w e l l

Add, mix w e l l

Add, mix w e l l pH: 7.85 Recommended D i 1 u t i ons: 1 oz . /gal Appl icat ions: hand dishwash Notes: High foaming, degreasi ng, opaque premium d i shwash

Adjust v i s c o s i t y w i t h Ethanol

Lyt ron 295 (Morton) opaci f i e r 0.10

Euperlan PK-771 p e a r l i z e r 2.20

Tomah AO-728 Special 3.00

Tomah Amphoteric N 10.00

V i s c o s i t y 3220 cps ( B r o o k f i e l d 100 rpm sp ind le #5)

Formula D-103A

Low Cost Formula Ina red i ent : Water DDBSA. Na s a l t (40%)

Add, mix w e l l Tomah A0-728 Speci a1

Add, mix w e l l NaCl

as necessary t o th i cken pH: 7.80 Recommended D i 1 u t i ons : 1 oz. /ga l Appl icat ions: Hand d i shwash Notes: Simple, lower cos t formula

Formul a D-105

Low Cost Formula I1 Ina red ien t : Water DDBSA, Na S a l t (60%)

Add, mix w e l l Tomah A0-728 Special

Add, mix w e l l Tomah Amphoteric L

Add, mix w e l l pH: 8.00 Recommended D i l u t i o n s : 1 oz. /ga l Appl icat ions: hand dishwash Notes: Good, low cost product

Formula D-106

SOURCE: Tomah Products, I nc . : Suggested Formulations

Wt% 25.00 65.00

10.00

Wt% 71 .OO 19.00

5.00

5.00

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Dishwashing Detergents 51

Hand Dishwash-Premium

I n q r ed i e n t s : G1 ucopon LD-15 S u l f o t e x SXS Water

Typi c a l P r o p e r t i es : S o l i d s , %: 26 pH, as i s : 6.5-7.0 V i s c o s i t y , cps (25C): 300-400 C lear P o i n t , C : 8

Hand Dishwash-Intermediate

I n q r e d i e n t s : G1 ucopon LD-15 S u l f o t e x SXS Water

T y p i c a l P r o p e r t i es : S o l i d s , %: 17 pH, as i s : 6 .5 -7 .0 V i s c o s i t y , cps (25C): 300-400 C lear P o i n t , C : 8

Hand Dishwash-Economy

I n Q r e d i e n t s : G1 ucopon LD-15 Sodium C h l o r i d e Water

T y p i c a l P r o p e r t i e s : S o l i d s , %: 9 pH, as i s : 6.5-7.0 V i s c o s i t y , cps (25C) : 300-400 C lear P o i n t , C : 8

wt% 42.0

5 . 0 53.0

W t % 28.0

3 . 0 69.0

Wt% 1 5 . 0

0 . 2 04.8

SOURCE: Henkel Corp. : Glucopon S u r f a c t a n t s : Suggested Formulas

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52 Advanced Cleaning Product Formulations

Hand D i shwashi na-Sol i d - I

STPP Ani on i c* Sesqui carb . Foam s t a b i 1 i zer S a l t cake

STPP Soap Sesqui carb .

An ion ic* Foam s t a b i 1 i zer Water

Hand D i shwashi ng-Sol i d - I 1

0-10% 20-40

10 J

balance

5-10% 50-75

balance

30-40% 3

balance

*Choice o f s u r f a c t a n t should take i n t o account s k i n s e n s i t i v i t y

Automat ic Dishwashina Deteraent S o f t Water

STPP STPP hexahydrate Sodi um metasi 1 i c a t e anhydrous Nonionic (low foam) CDB Clearon Soda ash, sodium s u l f a t e , sesquicarb

1 5 2 0 % 5-1 0

25 2.0 2.5

balance

Automat ic Di shwashi na Detergent Hard Water

STPP 30-35% STPP hexahydrate 10-1 5 Sodium m e t a s i l i c a t e anhydrous 25

CDB Clearon 2.5 Soda ash, sodium s u l f a t e , sesquicarb balance

SOURCE: FMC Corp.: Detergent A p p l i c a t i o n s B u l l e t i n No. 4:

Nonionic ( l ow foam) 2.0

Suggested Formula t ions

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Dishwashing Detergents 53

Hi qh Performance D i shwash

Dodecyl benzene Sul f o n i c Ac id Caus t i c Soda (50%) Sodium Laure th S u l f a t e (60%) Mackam 35 (Cocamidopropyl Be ta ine ) Sodium Xylene S u l f o n a t e (40%) Water, Dye, Fragrance qs t o

S o l i d s , %: 30+-1.0

V i s c o s i t y (cps, 25 degrees C . ) : 250-350 Cloud P o i n t : 5 degrees C .

pH: 6.5-7.0

Weiqht,% 21.5

5 . 4 4 .0 5 . 5 8 .0

100.0

Procedure: 1 . Add c a u s t i c soda t o water and a d j u s t pH t o 7.0-8.0 w i t h DDBSA. 2. Add remain ing components and a d j u s t pH t o 6.5-7.0 w i t h c i t r i c

a c i d . 3. I f necessary, lower v i s c o s i t y w i t h SXS, o r r a i s e v i s c o s i t y

w i t h sodi urn- c h l o r i d e .

SOURCE: M c I n t y r e Group L t d . : I n d u s t r i a l Formulary

D 41/31: Ze teso l 2056 Amphotensid 0 4 Zuso la t 1008/85 Pur ton CFD Perfume Sodium c h l o r i d e Water, p r e s e r v a t i v e

Washi nn Anents (Manual Use)

D 41/33: Lumorol RK Sodium c h l o r i d e Water, perfume, p r e s e r v a t i v e

20.0% 2 .0% 1 .O% 0 . 5 % 0.1% 1.5%

q . s . t o make 100.0%

50.0% approx. 1.0%

q . s . t o make 100.0%

SOURCE: Zschimmer & Schwarz GmbH & C o . : Suggested Formula t ions

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54

Wa

Advanced Cleaning Product Formulations

High-Performance Hand D ish Detersent

e r SXS, 40 Caust ic Soda, 50% Dodecylbenzene S u l f o n i c Ac id Rhodapex NA-61 A1 kamide DC-212/S Rhodacal A-246/L Rhodasurf 25-9 C i t r i c Ac id (50%), t o pH 8 Ethanol SD3A Prese rva t i ve Fragrance Dve

Yt&%

3.0 6 .6

25.0 8 . 0 3.0

10.0 6 .0 Q.S 2.0 0 . 1

1 100

--- ---

Procedure :

u n t i l un i fo rm a f t e r each a d d i t i o n . C i t r i c Ac id and Caust ic Soda are used f o r pH adjustment. Phys ica l P r o p e r t i e s :

Add t h e i n g r e d i e n t s i n t h e order l i s t e d w i t h m ix ing . Mix

Appearance: C lear g o l d l i q u i d , dyed t o p re fe rence pH, as i s : 8 V i s c o s i t y : 400 cps S p e c i f i c G r a v i t y : 1 .05 Formula DW-0013

M i l d L i s u i d Hand D ish Detergent

Wt.%

Caust ic Soda (50%) 3 Dodecylbenzene S u l f o n i c Ac id 12 Mi rano l CS Conc. 15 A1 kami de DC-212/S 3 Rhodasurf 25-9 3 Cheelox BF-13 0.2 C i t r i c Ac id (SO%), t o pH 8 Q.S. Fragrance --- Dye Procedure:

Add t h e i n g r e d i e n t s i n t h e order l i s t e d w i t h mix ing . Mix u n t i l un i fo rm a f t e r each a d d i t i o n . C i t r i c Ac id and Caust ic Soda are used f o r pH adjustment. D isso lve t h e dye i n water be fo re a d d i t i o n . Phys ica l P roper t i es :

Water To 100

---

Appearance: C lear g o l d l i q u i d , dyed t o p re fe rence pH, as i s : 8 S p e c i f i c G r a v i t y : 1.04 V i s c o s i t y : 150 cps Formula DW-0014

SOURCE: Rhone-Poulenc: Suggested Formula t ions

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Dishwashing Detergents 55

- L i q u i d D i shwasher Deterqent

~- Inared ien ts : . ( 1 ) De ion ized Water ( 2 ) K o r t h i x H ( 3 ) High Mono S t e a r y l Ac id Phosphate ( 4 ) Caus t i c Soda 50% (Rayon Grade) ( 5 ) L i g h t Dens i t y , F ine P a r t i c l e S i ze Soda Ash ( 6 ) Sodi um T r i p o l y Phosphate ( L i gh t Dens i t y Grade ( 7 ) Metso 2040 Sodium Meta S i l i c a t e Anhydrous ( 8 ) Avanel S-74 ( 9 ) Sodium H y p o c h l o r i t e (12 .5% a c t i v e )

3 . 0 0 . 6 2 . 0

1 0 . 0 067) 2 0 . 0

11 . o 1 . o

10.0

Procedure: S lowly mix ( 1 ) and ( 2 ) under h i g h shear f o r 15-20 minutes.

Reduce speed o f a g i t a t i o n and s l o w l y add ( 3 ) and ( 4 ) . M i x t u r e w i l l become ve ry v i scous . S lowly add ( 5 ) , (61, and (7). b lend ing w e l l a f t e r each a d d i t i o n . Temperature w i l l i nc rease t o 125-14OF. Apply e x t e r n a l c o o l i n g t o reduce tempera ture t o 9OF o r l e s s . Add (8 ) and ( 9 ) , b l e n d i n g w e l l a f t e r each a d d i t i o n . Co loran t and f rag rance can a l s o be added as d e s i r e d .

Fo l l ow recommended hand l i ng p r a c t i c e s o f t h e s u p p l i e r s o f each p roduc t used.

Comments : * I t i s a b s o l u t e l y necessary t o add i n g r e d i e n t s i n o rder l i s t e d , and p a r t i c u l a r l y impor tan t t o use h i g h shear a g i t a t i o n t o d i spe rse K o r t h i x H p r o p e r l y b e f o r e o the r i n g r e d i e n t s a r e added, o the rw ise low v i s c o s i t y , phase separa t i on and severe s e t t l i n g occurs .

* Use o f t h e proper grade o f soda ash, sodium m e t a s i l i c a t e and sodium t r i - p o l y phosphate i s impor tan t . Use o f t h e wrong grade can cause separa t ion , s e t t l i n g , and l o s s of v i scos i t y .

SOURCE: Kaopo l i t e , I n c . : Suggested Fo rmu la t i on

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56 Advanced Cleaning Product Formulations

L i a u i d Hand Dish Deteraent

Water Caust ic Soda (50%) Dodecyl benzene Sul f o n i c Acid Rhodapex NA-61 Alkamide DC 212/S Cheel ox BF-13 C i t r i c Acid (50%), t o pH 8 Sodium Chlor ide Fragrance

Dpaci f i e r Dye

L i a u i d Hand Dish Deteraent

Water Caustic Soda (50%) Dodecyl benzene Sul f o n i c Acid Rhodapex NA-61 Alkamide DC 212/S Cheel ox BF-13 C i t r i c Acid (50%), t o pH 8 Sodium Chlor ide Fragrance DY e Opaci f i e r

L i a u i d Hand Dish Deteraent

Water Caust ic Soda (50%) Dodecylbenzene Su l fon i c Acid Rhodapex NA-61 A1 kamide DC 2 1 2 / S Cheel ox BF-13 C i t r i c Acid (50%). t o pH 8 Sodium Chlor ide Fragrance

ODaci f i er Dye

Wt.% To 100

2.5 10 4.5 1 0 . 5 Q.S. 1 ---

Wt.% To 100

3.3

4.5 13

2 0 .5 Q.S. 1 ---

Wt.% To 100

4.1 16

5 3 0 .5 Q.S. 1 --- ---

Procedure: Add t h e i ng red ien ts i n the order l i s t e d , w i t h mixing. Mix

u n t i l uni form a f t e r each add i t i on . C i t r i c Acid and Caust ic Soda are used f o r pH adjustment. Sodium Chlor ide b u i l d s v i s c o s i t y . Dissolve i t i n water before add i t i on .

Dissolve t h e dye i n water before add i t i on . I f o p a c i f i e r i s used, i t should be d i l u t e d w i t h water before add i t i on . A l l pH adjustments must be completed before t h e o p a c i f i e r i s added. Physical P roper t i 8s:

Appearance: L iqu id, co lored and o p a c i f i e d t o preference pH, as i s : 8 pH. 1%: 7.2 V iscos i t y : 200-4OOcps S p e c i f i c Grav i ty : 1.02-1.05 Formula DW-0016

SOURCE: Rhone-Poulenc: Suggested Formulations

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Dishwashing Detergents 57

L i q u i d Manual D i shwashi ne Deteraents Premi um Performance

Glucopon h AES

Water Sul fotex SXS 40 Standamid LD Standamid SD Glucopon 600 CSUP Sul fotex 6040s

So l ids : 35% Act ives: 29%

Glucopon I LAS

Water Sul fo tex SXS 40 Sodium LAS (60%) Standamid SD Glucopon 600 CSUP Ethanol

So l i ds : 33.5% Act ives: 31 .O%

Economy Performance GlucoDon & AES

Water Sul fo tex SXS 40 Standamid LD Standamid SD Glucopon 600 CSUP Sul fotex 6040s

So l ids : 24% Act ives: 20%

Glucopon h LAS

Water Sul fo tex SXS 40 Sodium LAS (60%) Standamid SD Glucopon 600 CSUP Ethanol

So l i ds : 23% Act ives: 21%

W t % 37 15 2 3 18 25

W U 41 6

30 4 16 3

k% 57 10 1 2 10 20

W- 58 5

20 3

12 2

Procedure:

l y us ing moderate a g i t a t i o n . Adjust t o neu t ra l pH w i t h c i t r i c ac id . Incorporate c o l o r and fragrance as needed.

SOURCE: Henkel Corp.: Suggested Formulations

Add i n t h e order l i s t e d , d i s s o l v i n g each ing red ien t complete

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58 Advanced Cleaning Product Formulations

L i q u i d Manual Dishwashina Deteraents (Based on Added Value Sur factant Concentrates)

-_ Premium Performance

Water G1 ucopon LD-15 Sul fo tex SXS 40

Sol ids: 26% Act ives: 21%

Water G1 ucopon LD-15 Sodium Chlor ide

Sol ids: 8 . 0 % Act ives: 7.5%

Water G1 ucopon AV-110 Sul fo tex SXS 40 Standamid LD

Sol ids: 34% Act ives: 28%

Water Glucopon AV-110 Sul fo tex SXS 40 Vel vetex BK-35

So l ids : 36% Act ives: 28%

____ Economy Performance

Premium Performance w i t h Amide

Premi urn Performance w i t h Beta i ne

W U 53 42 5

WE-% 84.8 15.0 0.2

W U 37 46 12 5

31.9 51 .o 10.0 7.1

Procedure:

us ing moderate a g i t a t i o n . Adjust t o neu t ra l pH w i t h c i t r i c ac id . Incorporate c o l o r and fragrance as needed.

SOURCE: Henkel Corp. : Suggested Formulations

Add i n t h e order 1 i sted, d i s s o l v i n g each i ngredi ent completely

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Dishwashing Detergents 59

L i a u i d Manual D i shwashi ng Deteraents In te rmed ia te Performance

Laurv l S u l f a t e I AES

Water Su l fo tex SXS 40 Standapol T Standapol ES-3 Standamid SD Ve lve tex BA-35 Sodi um Chl o r i de

S o l i d s : 24% Ac t i ves : 22%

Premium Performance LAS & AES

Water Su l fo tex SXS 40 Sodium LAS (60%) S u l f o t e x 6040s Standamid SD

S o l i d s : 34% A c t i v e s : 32%

Premium Performance Glucopon I AOS

Water S u l f o t e x SXS 40 Standamid SD Glucopon 600 CSUP Sodium AOS (40%)

S o l i d s : 35% Ac t i ves : 33%

Economv Performance Glucopon & AOS

Water Su l fo tex SXS 40 Standamid SD Glucopon 600 CSUP Sodium AOS (40%)

S o l i d s : 24.5% A c t i v e s : 22.5%

W t % 40.7

2.0 20.0 25.0

4.0 7 . 0 1.3

44 5

32 15 4

W t % 22

5 3

20 50

W 3 47

5 3

15 30

Procedure:

u s i n g moderate a g i t a t i o n . Ad jus t t o n e u t r a l pH w i t h c i t r i c ac id . I nco rpo ra te c o l o r and f ragrance as needed.

SOURCE: Henkel Corp. : Suggested Formula t ions

Add i n t h e o rde r l i s t e d , d i s s o l v i n g each i n g r e d i e n t completely

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60 Advanced Cleaning Product Formulations

~~ Low Cost L i a u i d Dishwasher Detergent

__ I nq r ed i en t s :- ( 1 ) Deionized Water ( 2 ) K a o p o l i t e AB ( 3 ) High Mono S t e a r y l Ac id Phosphate ( 4 ) Caust ic Soda 50% (Rayon Grade) ( 5 ) L i g h t Dens i t y , F ine P a r t i c l e S i ze Soda Ash ( 6 ) Sodi um T r i p o l y Phosphate ( L i g h t Dens i t y Grade ( 7 ) Metso 2048 Sodium Meta S i l i c a t e Anhydrous ( 8 ) Avanel S-74 ( 9 ) Sodium H y p o c h l o r i t e (12.5% a c t i v e )

% by Wei&t 41 . 4

4 .0 0 . 6 2 . 0

1 0 . 0 067) 20 .0

11 . o 1 . o

1 0 . 0

Procedure: S lowly mix ( 1 ) and ( 2 ) under h i g h shear f o r 10-15 minutes.

Reduce speed o f a g i t a t i o n and s l o w l y add ( 3 ) and ( 4 ) . M i x t u r e w i l l become ve ry v i scous . S lowly add ( 5 ) , (61, and ( 7 ) , b lend ing w e l l a f t e r each a d d i t i o n . Temperature w i l l i nc rease t o 125-14OF. Apply e x t e r n a l c o o l i n g t o reduce temperature t o 9OF o r l e s s . Add (8 ) and (.9), b l e n d i n g w e l l a f t e r each a d d i t i o n . Co lo ran t and f rag rance can a l s o be added as des i red .

each produc t used.

Comments:

Fo l l ow recommended hand l i ng p r a c t i c e s o f t h e s u p p l i e r s o f

* It i s a b s o l u t e l y necessary t o add i n g r e d i e n t s i n o rder l i s t e d , and p a r t i c u l a r l y impor tan t t o use h i g h shear a g i t a - t i o n t o d i spe rse K a o p o l i t e AB p r o p e r l y b e f o r e o t h e r i n g r e d i - en ts a r e added, o the rw ise low v i s c o s i t y , phase separa t i on and severe s e t t l i n g occurs .

* Use o f t h e proper grade o f soda ash, sodium m e t a s i l i c a t e and sodium t r i - p o l y phosphate i s impor tan t . Use o f t h e wrong grade can cause separa t i on , s e t t l i n g , and l o s s o f v i s c o s i t y .

SOURCE: Kaopo l i t e , I n c . : Suggested Formula t ion

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Dishwashing Detergents 61

Machine D i shwash Deterqent_s_LInst i tut io_nl> L i .qujds

Water Acryso l ASE-108 T r i t o n DF-16 Potass i um hydrox ide (45%) TKPP (60%) N C lear sodium s i l i c a t e

Water Potassium hyd rox ide (45%) Kasi 1 #1 p o t a s s i um s i 1 i c a t e TKPP (60%) Sodium h y p o c h l o r i t e (15%)

Powders __

STPP Metso Beads 2048 sodium m e t a s i l i c a t e Sodium carbonate Sodi um hyd rox ide beads ("PELS") C h l o r i n a t e d TSP

STPP Sodium carbonate C12-Cl3 1 i near a l c o h o l , 5 moles EO Metso Pentabead 20 sodium m e t a s i l i c a t e

50.9% 6.9% 3.0% 1.2%

25.0% 13.0%

10% 35% 30% 20%

5%

40% 20% 15% 20% 5%

40% 2 4%

6% 30%

SOURCE: PQ Corp.: Detergent Formulary: Suggested Formula t ions

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62 Advanced Cleaning Product Formulations

Machine D i shwashi na Foraul a t i on

Mazer Macol 40 Tetrasodium Pyrophosphate Sodi um T r i po l yphosphate Sodi um Metasi 1 i c a t e , Pentahydrate Chlor inated Cyanurate Sodium Carbonate Water*

Wei sht /% 3.0%

35.0% 25.0% 10.0% 2.0%

18.0% 12.0%

Procedure: 1. Spray a mixture o f t h e Macol 40 and water* onto t h e Tetra-

sodium Pyrophosphate (alone o r mixed w i t h t h e other anhydrous inorganic s a l t s ) w h i l e c o n t i n u a l l y mixing, whereby hyd ra t i on and simultaneous absorpt ion o f t h e su r fac tan t occur.

phates, s t i l l mix ing.

mixing u n t i l homogenized and a dry, f ree- f lowing, granular product i s ob ta i ned. Ch lo r i ne-contai n i ng compounds which may a l so be used i n t h i s process i nc lude t r i sod ium phosphate ( ch lo r i na ted ) , t r i ch lorocyanur ic ac id , s a l t s o f d i ch l orocya- n u r i c acid, dichlorodimethylhydantoin (Halane) and other organic-act ive compounds.

Maximum c h l o r i n e s t a b i l i t y i s obtained when t h e Macol 40, d i l u t e d w i t h water, i s completely absorbed by t h e phosphate mixture. Step 1 avoids temperature c o n t r o l problems and e l im in - ates t h e need f o r an aging per iod.

a t i on . I t i s essen t ia l t h a t t h e M e t a s i l i c a t e be added a f t e r t h e phosphate mixture has hydrated and absorbed t h e sur factant . t o avoid d i s c o l o r a t i o n and degradation.

2. Add t h e hydrated Sodium M e t a s i l i c a t e t o t h e hydrated phos-

3. Add t h e Chlor inated Cyanurate t o t h e mixture and cont inue

I n step 2, hydrated M e t a s i l i c a t e does not promote agglomer-

* The amount o f water used should not exceed t h a t shown i n t h e formulat ion.

SOURCE: PPG Indus t r i es , I nc . : Suggested Formulation

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Dishwashing Detergents 63

Mechanical D i shwashi na Detergent L i q u i d

Igepa l CO-730 Gantrez AN-149 Potassi um Hydroxi de (45% ac t i ve) Sodium S i l i c a t e (46% a c t i v e ) Antarox BL-330 Tetrapotassium Pyrophosphate (60% a c t i v e ) Water

Wt.% 0 . 5 1 . o 3.0

17.0 3.0

63.3 12.2

Procedure: 1 . Add Gantrez AN-149 t o Igepa l CO-730/Water m ix tu re and s t i r

a t room temperature u n t i l d i sso l ved . Heat t o 45-50C i f no t t o t a l l y i n s o l u t i o n .

2 . M a i n t a i n heat a t 45C and add r e s t o f i n g r e d i e n t s i n d i v i d u a l l y .

Physi c a l Proper t i es : pH (as i s ) : 13.2 pH (1%) : 10 .4 V i s c o s i t y : 1060 cps S p e c i f i c G r a v i t y : 1 .14

Formula DW-0010

Mechanical D i shwashi ng Detergent Ch 1 or i n a t d

Sodium Carbonate ( L t . Dens i t y ) Antarox BL-330 Sodium Tr ipoolyphosphate, Powder Sodium M e t a s i l i c a t e Pentahydrate Clearon CDB

Wt.% 41 .O

2.0 34.0 20.0

3.0

Procedure: Add t h e sodium carbonate t o t h e mixer . Spray on t h e Antarox

BL 330. Add t h e remaining i n g r e d i e n t s i n t h e order l i s t e d . Mix u n t i l un i fo rm.

Physi c a l P r o p e r t i es : Appearance: White, f r e e - f l o w i n g powder pH (1%): 11.2 Speci f i c G r a v i t y : 0.70

Formula DW-0009

SOURCE: Rhone-Poluenc: Suggested Formula t ions

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64 Advanced Cleaning Product Formulations

Premium Dishwash 1

Ina red i e n t : Water SXS (40%)

Add, mix w e l l C12 Diethanolamide (100%)

Add, mix w e l l COCO d i ethanol ami de (80%)

Add, mix w e l l Tomah Amphoteric N

Add, mix w e l l NaCl*

D i sso l ve

W X 37.00 15.00

2.00

3.00

18.00

q .s .

SpG 20/20C: 1.04 pH: 9.18 Ad jus t t o 7.0 w i t h c i t r i c a c i d Recommended D i l u t i o n s : 1 0 2 . ga l Appl i c a t i ons: V i scous h i g h qua1 i t y d i shwash Notes: V i s c o s i t y 45 cps ( B r o o k f i e l d RVT 100 rpm s p i n d l e #3)

*Add more NaCl t o i nc rease v i s c o s i t y Formula D-100

Premium Dishwash 2

I n g r e d i e n t : Water Neodol 91-8

Add, mix w e l l Tomah AO-728 Spec ia l

Add, mix w e l l Ethanol

Add, mix w e l l Tomah Amphoteric L

Add, mix w e l l Na Laury l E ther S u l f a t e (60%)

Add, mix w e l l

W B 58.50 27.00

1.50

4.00

1 .oo

8.00

pH: 7.00 Recommended D i l u t i o n s : 1 o z . / g a l l o n A p p l i c a t i o n s : Non ion ic based "low i r r i t a t i o n " premium wash

Formula D-101

SOURCE: Tomah Products, I n c . : Suggested Formula t ions

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Dishwashing Detergents 65

Premium Dishwash 3

I n a r e d i e n t : Water DDBSA, Na s a l t (60%)

Add, mix w e l l Lau ry l E ther S u l f a t e , Na s a l t (60%)

Add, mix w e l l - w i l l g e l and then t h i n Tomah A0-728 Spec ia l

Add, mix w e l l Tomah Amphoteric SC

Add, mix w e l l Non ion ic Surfactant-HLB 13

Add, mix w e l l Dye, Perfume

W S 61 . O O

3 .00

29.00

2 .00

4.00

1 .oo

q . s .

SpG 20/20C: 1.02 pH: 8.40 Ad jus t t o 7 . 0 w i t h c i t r i c a c i d Recommended D i 1 u t i ons: 1 o z . / ga l A p p l i c a t i o n s : Hand dishwash Notes: C lear fo rmula , e x c e l l e n t degreas ing power

V i s c o s i t y 40 cps ( B r o o k f i e l d RVT 100 rpm Sp ind le # 3 ) Formula D-102

Premium Dishwash 4

I n p r e d i e n t : Water DDBSA, Na S a l t (90%)

D i sso l ve Laury l e t h e r s u l f a t e , Na s a l t (60%)

Add, mix w e l l C i t r i c a c i d

D i sso l ve SXS (40%)

Add, mix w e l l Ethanol

Add, mix w e l l Tomah A0-728 Speci a1

Add, mix w e l l

pH: 8.00 Recommended D i 1 u t i ons : 1 oz . / ga l A p p l i c a t i o n s : H igh foaming premium d i s h

Formula D-104

SOURCE: Tomah Products, I n c . : Suggested Formula t ions

&% q . s .

16.00

8.00

1 .oo

3.00

5.00

3.00

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66 Advanced Cleaning Product Formulatiom

Prerni urn Hand D i shwash Formula-1 Inq red ien ts : Glucopon AV-110 S u l f o t e x SXS Standamid LM Water Typ ica l P r o p e r t i e s :

S o l i d s , %: 36 Ac t i ves , %: 28 pH, as i s : 6.5-7.0 V i s c o s i t y , cps (25C): 100-200 C lear P o i n t , C: 12

I n a r e d i en ts : G1 ucopon AV- 1

Prerni urn Hand D i shwash Forrnul a-2

10 S u l f o t e x SXS Standamid LD Water Typi c a l P r o p e r t i 8s :

S o l i d s , %: 34 Ac t i ves , %: 28 pH, as i s : 6.5-7.0 V i s c o s i t y , cps (25C): 150-250 C lear Po in t , C: 5

Prerni urn Hand D i shwash Forrnul a-3 I n q r e d i en ts : G1 ucopon AV-110 S u l f o t e x SXS Velvetex BK35 Water Typ ica l P r o p e r t i e s :

S o l i d s , %: 38 Ac t i ves , %: 28 pH, as i s : 6.5-7.0 V i s c o s i t y , cps (25C): 100-200 C lear P o i n t , C: 8

Prerni urn Hand D i shwash Formul a-4 I n q r e d i en ts : Glucopon AV-110 S u l f o t e x SXS Standami d LAO Water Typ ica l P r o p e r t i 8s:

S o l i d s , %: 34 Ac t i ves , %: 28 pH, as i s : 6.5-7.0 V i s c o s i t y , cps (25C): 200-300 C lear P o i n t , C: 5

W B 51 .O 15.0 2.5

31.5

W t % 46.0 12.0

5.0 37.0

K% 51 .O 10.0

7.1 31.9

Q 51 .O 10.0 8 .3

30.7

SOURCE: Henkel Corp.: Glucopon Sur fac tan ts : Suggested Formulas

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5. General Purpose Cleaners

67

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68 Advanced Cleaning Product Formulations

A l l Purpose Cleaner

Mazer Maphos 91 Mazer Mazon 60T Mazer Mazamide 70 Sodi um T r i po l yphosphate Water

A l l Purpose Cleaner

Mazer Macon 41 Mazer Macol 48 Pine O i l (steam d i s t i l l e d ) Mazer Mazon 7 1 A Versene Water

Heavv Duty A1 k a l i ne Cleaner

Water Sodi urn Metasi 1 i c a t e Sodium Carbonate Sodium Benzoate Mazer Macol 25 Mazer Maphos 66H Mazer Macol 48

A1 k a l i ne Powder C1 eaner

Sodi um Tr ipo lyphosphate Sodium M e t a s i l i c a t e (Anhydrous) Sodium Carbonate Sodi um Hydroxide Mazer Macol LF-110

Wei aht/% 5% 5% 1%

10% 7 9%

Wei sh t /% 25.0%

5.0% 1 . O % 1 .O% 1 . O %

67.0%

Wei Qh t /% 59.0% 10.0% 20.0%

1 .O% 4.0% 4.0% 2.0%

Wei qh t /% 24.0% 24.0% 24.0% 24.0%

4.0%

Procedure:

SOURCE: PPG I n d u s t r i e s , Lnc.: Suggested Formula t ions

For h i g h pressure spray, use l e v e l i s 1-4 ounces per g a l l o n .

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General Purpose Cleaners 69

Ammoniated General Purpose Household Detercaent

Mackami de CO-8 (Cocami de OEA) Sodium Tr ipo lyphosphate 60 Dense Mackadet 40K (Potassium Coconut Soap) TSPP Ammonia (29%) Water qs t o

Procedure: 1 . Add components (except ammonia) t o wa te r . 2. Blend u n t i l c l e a r . 3 . Cool t o room tempera ture and add ammonia.

Remarks : Use approx imate ly 1 /4 cup t o 1 /2 p a i l water .

B u t y l C l e a n s

Mackam 2CSF (Cocoamphodipropionate) B u t y l C e l l o s o l v e Sodium Carbonate Water

Procedure: 1 . Add components i n o r d e r . 2 . Heat t o 40 degrees C. and b l e n d u n t i l c l e a r .

B u t y l C1 eaner

Mackam 2CSF (Cocoamphodipropionate) B u t y l C e l l oso l ve Nonoxvnol 9 .5 Sodium Metasi 1 i c a t e 5H20 TKPP Water

Procedure: 1 . Add components t o water . 2 . Heat t o 50 degrees C. and b l e n d u n t i l c l e a r . 3 . Cool and f i l l .

SOURCE: Mc In ty re Group L td . : I n d u s t r i a l Formulary

Weiqht,% 8 . 0 5.0 4.3 3.0 0.5

100.0

Wei gh t .% 5 .0

10.0 2 .0

83.0

Weiqht .% 5 .5 3.8 1 .5 3.8 3.8

81.6

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70 Advanced Cleaning Product Formulations

Ammoni a ted L i q u i d General Purpose Detergent- I

TKPP NH4C1 Anionic Hydrotrope Water

TKPP NH4C1 Noni oni c Water

5-10% 1 .o 8 . 0 3 . 0

balance

Ammoniated L i a u i d General PurDose Deterqent- I1

5-10% 1 . o 8.0

balance

Ammoniated L i q u i d General Purpose Deterclent-I11

TKPP Anionic Ammoni um hydroxide Foam s tab i 1 i zer Water

CDB 90 Soda ash STPP* Anionic (40% a c t i v e ) S i l i c a f l o u r

CDB Clearon Soda ash STPP* Anionic (40% a c t i v e ) S i l i c a f l o u r

Scourinn Powder-I

Scourina Powder-I1

10-15% 4.0 5 .0 1 . o

balance

0 . 6 10.0 4.0 3 . 5

balance

1 . o 1 0 . 0 4.0 3.5

balance

*STPP enhances c h l o r i n e s t a b i l i t y . May be e l im ina ted i n phosphate r e s t r i c t e d areas.

SOURCE: FMC Corp.: Detergent App l i ca t i ons B u l l e t i n No. 4: Suggested Formulations

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General Purpose Cleaners 71

A l l Puroose Bleach Cleaner

Sodium H y p o c h l o r i t e (35%) Mackamine CO (Cocamine Oxide) TKPP Water, qs t o

Procedure: Add components t o water and b lend u n t i l c l e a r .

A l l Puroose Cleaner

Mackam 2CSF (Cocoamphodipropionate) TKPP TSPP KOH (45%) Low Rosin T a l l O i l F a t t y Ac id Water

Procedure: 1 . D i s s o l v e TKPP and TSPP a t 70 degrees C. 2. Add KOH. 3. D isperse T a l l O i l F a t t y Ac id . 4. Cool t o 50 degrees C. and s l o w l y add Mackam PCSF

Wei a h t 6.0 5.0 3.0

100.0

W&i gh t ,% 10.0

5 . 0 5 . 0 4 .0

10.0 66.0

Remarks :

pH between 9.5 and 10.5. The f i n a l p roduc t w i l l be a c l e a r v iscous l i q u i d w i t h a

A l l Purpose Veqetable O i l SoaD

Mackadet 40K (Potassium Coconut Soap) Mackamide S (Soyamide OEA) Te t rasod i um EOTA (40%) Mackstat DM (OMDM Hydanto in ) Sodium C h l o r i d e qs t o 200 cps De ion ized Water, Dye, Fragrance qs t o

Procedure: 1 . Add Mackadet 40K and Mackamide S t o water . 2. Heat t o 50 degrees C . w i t h a g i t a t i o n . 3 . Blend u n t i l c l e a r . 4. Cool t o 40 degrees C . and add remain ing components 5 . Ad jus t v i s c o s i t y w i t h Sodium C h l o r i d e .

SOURCE: M c I n t y r e Group L t d . : I n d u s t r i a l Formulary

Wei g h t .% 35.0 8.0 5.0

qs

100.0

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72 Advanced Cleaning Product Formulations

Heavy Duty A l l Purpose Cleaner-A

Components: Water Sodium xy lene s u l f o n a t e (40%) Ethy lene g l y c o l monobutyl e the r Non ion ic Sur fac tan t :

Hostapal N 090 Soda ash (grade 100) Tetrasodium EDTA (40%)

W t . % 73

8 5

8 2 4

Phys ica l P r o p e r t i e s : Appearance (25C): c l e a r Dens i ty ( l b / g a l ) : 8.73 pH ( l % , 25C): 10.7 Ross M i l e s (49C, 1%, cm):

1 min . : 7 5 min . : 2

Cloud Po in t (l%, C ) : 55 Surface t e n s i o n (0.25%, dynes/cm): 32.14 V i s c o s i t y , B r o o k f i e l d (25C, LV#l, 100rpm, cps ) : 5.1 Freeze thaw s t a b l e : f r e e z i n g p o i n t (C) : D i d no t f reeze

Blend t h e components i n t h e g iven o rde r w i t h cont inuous Procedure:

s t i r r i n g .

Heavy Duty A l l Purpose Cleaner-B

Components: Water Sodium xy lene s u l f o n a t e (40%) Ethy lene g l y c o l monobutyl e the r Nonionic S u r f a c t a n t :

Genapol UD 079 Soda ash (grade 100) Tetrasodium EDTA (40%)

W t . % 72

Phys ica l P r o p e r t i e s : Appearance (25C): c l e a r Dens i t y ( 1 b /ga l ) : 8.70 pH ( l % , 25C): 10.2 Ross M i l e s (49C, 1%, cm):

1 min . : 11 5 min.: 2

Cloud P o i n t ( l % , C): 53 Sur face t e n s i o n (0.25% dynes/cm): 28.17 V i s c o s i t y , B r o o k f i e l d (25C. LV#1, lOOrprn, cps ) : 5 .8 Freeze thaw s t a b l e : f r e e z i n g p o i n t (C): D i d n o t f reeze

Blend t h e components i n t h e g iven o rde r w i t h cont inuous Procedure:

s t i r r i n g .

SOURCE: Hoechst Celanese Corp.: Suggested Formula t ions

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General Purpose Cleaners 73

Heavy Duty A l l Purpose Cleaner-C

Components: Water Sodi um xy lene s u l f o n a t e (40%) Ethy lene g l y c o l monobutyl e t h e r Non ion ic S u r f a c t a n t :

Genapol 26-L-75 Soda ash (g rade 100) Tetrasodium EDTA (40%)

Phys i ca l P r o p e r t i e s : Appearance (25C): c l e a r Dens i t y ( 1 b /ga l ) : 8.66 pH ( l % , 25C): 10.7 Ross M i l e s (49C, 1%, cm

1 min . : 11 5 min . : 8

Cloud P o i n t ( l % , C ) : 60 Sur face t e n s i o n (0.25%, V i s c o s i t y , B r o o k f i e l d (

dynes/cm): 27.80

W t . % 73

8 5

8 2 4

5C, LV#l , 100 r p m , cps ) : 5 .1 Freeze thaw s t a b l e : f r e e z i n g p o i n t (C) : D i d n o t f r e e z e

Blend t h e components i n t h e g i ven o rde r w i t h cont inuous Procedure:

Heavy D u t y A l l Purpose Cleaner-D

Components : Water Sodium xy lene s u l f o n a t e (40%) E thy lene a l v c o l monobutvl e the r Non; o n i c S u i f a c t a n t :

Genapol 26-L-60 Soda ash (g rade 100) Te t rasod i um EDTA (40%)

Phys i ca l P r o p e r t i e s : Appearance (25C): c l e a r Dens i t y (1 b /ga l ) : 8.71 pH ( l%, 25C): 10.7 Ross M i l e s (49C, 1%, cm

1 min . : 9 5 min . : 4

Cloud P o i n t ( l % , C ) : 60 Sur face t e n s i o n (0.2596, V i s c o s i t y , B r o o k f i e l d (

W t . % 73

8 5

8 2 4

dynes/cm): 29.42 5C, LV#l, 100rpm, cps ) : 6 . 4

Freeze thaw s t a b l e : f r e e z i n g p o i n t (C ) : D i d n o t f r e e z e

Blend t h e components i n t h e g i ven o rde r w i t h cont inuous Procedure:

s t i rr i ng.

SOURCE: Hoechst Cel anese Corp. : Suggested Formula t ions

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74 Advanced Cleaning Product Formulations

Heavy Duty A l l PurDose Cleaner-€

Components: Water Sodium xylene su l fona te (40%) Ethylene g l yco l monobutyl e ther Nonionic Sur factant :

Genapol 26-L-5 Genapol 26-L-75

Soda ash (grade 100) Tetrasodium EDTA (40%) Physical Proper t ies:

Appearance (25C): c l e a r Densi ty (1 b/gal ) : 8.71 pH (l%, 25C): 10.7 Ross M i les (49C, 1%, cm):

1 min.: 9 5 min. : 6

Cloud Point ( l % , C ) : 60 Surface tens ion (0.25%, dynes/cm): 29.49 V iscos i t y , B r o o k f i e l d (25C, LV#1, 100rpm, Freeze thaw s tab le : f reez ing p o i n t (C): D

Blend the components i n t h e given order w Procedure:

s t i r r i n g .

W t . % 73

cps): 5.1 d not f reeze

t h continuous

Heavy Duty A l l PurDose Cleaner-F

ComDonents: Water Sodium xylene su l fona te (40%) Ethylene g l yco l monobutyl ether Nonionic Sur factant :

Genapol UD 050 Genapol UD 079

Soda ash (grade 100) Tetrasodium EDTA (40%) Physi ca l P roper t i es :

Appearance (2%): c l e a r Densi ty ( l b / g a l ) : 8.67 pH (l%, 25C): 10.7 Ross M i les (49C, 1%, cm):

1 min.: 7 5 min. : 2

Cloud Point ( l % , C ) : 50 Surface tens ion (0.25%, dynes/cm): 27.62 V iscos i t y , B r o o k f i e l d (25C. LV#l, 10Drpm. cps): 5.8 Freeze thaw s tab le : f reez ing p o i n t (C): Did not f reeze

Blend the components i n t h e given order w i t h continuous Procedure:

s t i r r i n g .

W t . % 72

SOURCE: Hoechst Celanese Corp.: Suggested Formulations

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General Purpose Cleaners 75

Heavy Duty Cleaner

Mackamide CDM (Cocamide DEA (and) DEA O lea te ) TSP TKPP Sodium M e t a s i l i c a t e Sodium LAS (60% S l u r r y ) Sodi um Xyl ene Sul f o n a t e (40%) Water

Weiqht,% 8.0 5.0 3.0 2.0 2.0 2 .0

7 8 . 0

Procedure: 1 . Blend components and heat t o 50 degrees C . 2 . Blend u n t i l c l e a r .

Remarks:

wax s t r i p p i n g . I t can be m o d i f i e d f o r s t r i p p i n g c ross l i n k e d polymers by adding 5 percent b u t y l c e l l o s o l v e and 2 percent ammonia.

T h i s fo rmula was designed f o r heavy du ty c l e a n i n g on f l o o r

General Purpose Cleaner

TSP TKPP Mackamide CDM (Cocamide DEA (and) DEA O lea te ) Water

Procedure: 1 . Add components t o water and heat t o 50 degrees C . 2. Blend u n t i l c l e a r .

Neu t ra l Cleaner

T a l l O i l F a t t y Ac id Potassium Hydrox ide (45%) Mackam 2CSF D i e thy lene G1 yco l EDTA (40%) P ine O i l Water

Wei s h t ,% 3.0 2 . 0 8.0

8 7 . 0

Wei a h t .% 8 . 0 3.3 2.0 2 . 5 2.0 0.6

82.6

Procedure: 1 . Add components t o water and b lend. 2. A d j u s t pH t o 7.0-8.0 w i t h KOH o r T a l l O i l F a t t y Ac id .

SOURCE: M c I n t y r e Group L t d . : I n d u s t r i a l Formulary

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76 Advanced Cleaning Product Formulations

Non Caus t i c A l l PurDose Cleaner

I n a r e d i en t : Water TKPP

Na M e t a s i l i c a t e Anhydrous

Tomah A l k a l i S u r f a c t a n t

Non ion ic Surfactant-HLB 13

D i sso l ve

D i sso l ve

Add, mix w e l l

Add, mix w e l l SpG 20/20F: 1.12 pH: 12.50 Recommended D i l u t i o n s : 10-3O:l A p p l i c a t i o n s : hard su r face c lean ing

Formula 1-111

Non-Caustic Powder

I n a r e d i e n t : Soda Ash STPP

Nonionic Surfactant-HLB 13

Tomah A l k a l i S u r f a c t a n t

Blend w e l l i n powder b lender

Spray app ly o r b lend w e l l

Spray app ly o r b lend w e l l Recommended D i l u t i o n s : 1 oz/5 ga l A p p l i c a t i o n s : I n d u s t r i a l degreasing and c lean ing Notes: O p t i c a l b r i g h t e n e r s u s e f u l a t 0.01%

Dye a t 0.02%, i f d e s i r e d Formula 1-112

Non-Caustic Steam Cleaner

I n a r e d i en t : Water Na M e t a s i l i c a t e Pentahvdrate

D i sso l ve STPP

D i sso l ve Non ion ic Surfactant-HLB 13

Mix w e l l Tomah A l k a l i Su r fac tan t

Mix w e l l SpG 20/20F: 1.10 pH: 10.40 Recommended D i l u t i o n s : 10-5O:l A p p l i c a t i o n s : Hard su r face c lean ing and degeasing

Formula 1-114

SOURCE: Tomah Products, I n c . : Suggested Formula t ions

W B 81 . O O 10.00

5.00

2.00

2.00

W> 80.00 10.00

8.00

2.00

W B 79.00

1 .oo

10.00

5.00

5.00

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General Purpose Cleaners 77

Non-Phosphate A l l Purpose Cleaner

Components: Water 45% KOH Burcosperse AP L i q u i d Sodium Xylene Su l fona tes 40% Sodi um C i t r a t e Dodecylbenzene S u l f o n i c Ac id Burco TME B u t y l Propasol Varso l o r M ine ra l S p i r i t s

% by Weiqht 77.15

0.75 3.00 3.40 1 .oo 1.75 6.00 6 .00 0 . 9 5

Procedure:

between each a d d i t i o n . Add components i n t h e o rde r l i s t e d . Blend u n t i l un i fo rm

O i 1 Spl i tti nq General Purpose Cleaner

Components: Water Sodium M e t a s i l i c a t e Pentahydrate Burco ADS-40 Burco TME Burco LAA-38 Burco EHS

%-by Weight 82.5

5 2 . 5 5 2.5 2 . 5

Procedure: Add components i n t h e o rde r l i s t e d . Blend u n t i l f u l l y d i s -

so l ved between each a d d i t i o n . T h i s i s a use as i s f o r m u l a t i o n f o r heavy du ty c lean ing . For

l i g h t e r du ty a p p l i c a t i o n s , d i l u t i o n w i t h water may be p o s s i b l e . T h i s f o r m u l a t i o n w i l l suspend o i l t o a s s i s t w i t h removal. The suspended o i l w i l l t hen f l o a t f o r easy removal.

Source: B u r l i n g t o n Chemical Co., I n c . : Suggested Formula t ions

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6. Glass Cleaners/Polishes

78

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Glass CleanerslPolkhes 79

Ammoni a t e d Glass C1 eaner

I n a r e d i e n t : Water EDTA (40%)

Tomah AO-14-2

Non ion ic S u r f a c t a n t (NP-6 t y p e )

Aqua ammonia (26)

Add, mix w e l l

Add, mix w e l l

Add, mix w e l l

Add, b o t t l e , cap

SpG 20/20C: 1 .OO pH: 11.20 Recommended D i 1 u t i ons : as - i s A p p l i c a t i o n s : Spray g l a s s c leaner Notes: Good foam, good c l e a n i n g

Formula G-1 00

Glass Cleaner I

I n a r e d i en t : Water A c e t i c A c i d ( G l a c i a l )

Tomah AO-14-2 Add, mix w e l l

Add, mix w e l l

pH: 4.30 Recommended D i l u t i o n s : a s - i s A p p l i c a t i o n s : Spray g l a s s c leaner Notes: good foam, good c l e a n i n g

Formula G-101

Low VOC/Non A c i d G lass Cleaner

I n s r e d i e n t : Water Tomah 9-17-2 (PG)

Tomah AO-14-2

Non ion ic Surfactant-HLB 13

Add, mix w e l l

Add, mix w e l l

pH: Neu t ra l Recommended D i 1 u t i ons: as - i s A p p l i c a t i o n s : Spray g l a s s c leaner , c a r o r home Notes: Good foam, good c l e a n i n g

Formula G-102

SOURCE: Tomah Products, I n c . : Suggested Formula t ions

W B 93.00

1 .oo

3.00

1 . o o

2.00

Wt% 95.50

2.50

2.00

W t % 99.80

0.05

0.05

0.10

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80 Advanced Cleaning Product Formulations

Cleaner /Po l ish fo r Glass

I n g r e d i e n t s : ( 1 ) Deionized Water (2 ) Carbopol 934 ( 3 ) Deionized Water (4 ) Kaopo l i t e SF o r 1168 ( 5 ) Odorless Minera l S p i r i t s (6 ) Kessco PEG-600 Monolaurate ( 7 ) Dowicide A ( 8 ) Ammonium Hydroxide

% by Wei g h t 4.75 0.25

73.9 10.0 10.0

1 .o 0.1 q s.

Procedure:

i n t o (3). Add (4 ) w i t h good a g i t a t i o n , c o n t i n u a l l y u n t i l smoothly dispersed. Add (5) . (6 ) and (7 ) w i t h c o n t i n u i n g a g i t a t i o n . Add (8 ) t o a d j u s t pH t o 7.2-7.5.

Fo l low recommended hand l i ng p r a c t i c e s o f t h e s u p p l i e r s of each produc t used.

Good i n d u s t r i a l p r a c t i c e s should be used when hand l i ng f 1 ammable i ngred i en ts .

Comments:

p o l i s h i n g a c t i o n t o t h e fo rmu la t i on .

S l u r r y (2 ) i n (1 ) w i t h i n t e n s i v e a g i t a t i o n , s t i r t h e mix

Use o f Kaopo l i t e 1168 g i ves more aggress ive c l e a n i n g and

u r e

Drv Powder C lean ing Conmound. Low Aqqressive Type

I n s r e d i e n t s : % bv Weight

(2 ) A e r o s i l 200 5.0 ( 1 ) Kaopo l i t e 1168 91 . o

( 3 ) Avanel-S 74 2.0 ( 4 ) Sodium D ich lo ro -s -T r iaz ine T r ione Dyhydrote 2.0

Procedure: Dry b lend ( 1 ) and ( 2 ) . Add (3) and ( 4 ) . Fo l low recommended hand l i ng p r a c t i c e s o f t h e s u p p l i e r s of

each produc t used.

SOURCE: Kaopol i t e , I n c . : Suggested Formula t ions

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Glass CleanersIPolishes 81

Glass C1 eaner -~ Ammon i a

Economical.

Water Rhodacal DSB Butoxyethanol Ammonium Hydroxide (28%) Dye

Wt.% 94.60

0 . 1 5 5 . 0 0 0 . 2 5 ----

Procedure: Blend i n g r e d i e n t s i n o rde r l i s t e d and mix u n t i l un i fo rm.

Physi c a l P r o p e r t i es : Appearance: C lear l i q u i d , dye t o p re fe rence pH (as i s ) : 1 0 . 5 pH ( 1 % ) : 9 . 0 S p e c i f i c G r a v i t y : 0 .99 V i s c o s i t y : t10 cps

Formula GC-0017

-_ Glass Cleaner Ammon i a

Heavy-Duty

Water Rhodacal DSB Butoxyet hanol Ammonium Hydroxide (28%) Dye

Htv% 88.70

0.30 10.00

1 .oo ----

Procedure: Blend i n g r e d i e n t s i n o rde r l i s t e d and mix u n t i l un i fo rm

Phys ica l P r o p e r t i e s : Appearance: C lear l i q u i d , dye t o p re fe rence pH (as i s ) : 10 .8 pH ( 1 % ) : 9 . 7 S p e c i f i c G r a v i t y : 0 .99 V i s c o s i t y : >10 cps

Formula GC-0017

SOURCE: Rhone-Poulenc: Suggested Formula t ions

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82 Advanced Cleaning Product Formulations

G l ass Cleaner V i neaar

Economical

Water Rhodacal DSB Butoxyethanol A c e t i c Ac id Dye

Wt.% 94.85

0.15 5.00

To pH=4 ----

Procedure: Blend i n g r e d i e n t s i n o rder l i s t e d and mix u n t i l un i fo rm.

Phys ica l P r o p e r t i e s : Appearance: C lear l i q u i d , dye t o p re fe rence pH (as i s ) : 4.0 pH (1%): 3.5 S p e c i f i c G r a v i t y : 0.99 V i s c o s i t y : < I 0 cps

Formula GC-0018

G1 ass Cleaner V i nesar

Heavy-Duty

Water Rhodacal DSB Butoxyethanol A c e t i c A c i d Dye

Wt.% 89.70

0.30 10.00

To pH=4 ----

Procedure:

Phys ica l P roper t i es : Appearance: C lea r l i q u i d , dye t o p re fe rence pH (as is): 4.0 pH (1%): 3.5 Speci f i c G r a v i t y : 0.99 V i s c o s i t y : t10 cps

Formula GC-0018

Blend i n g r e d i e n t s i n o rde r l i s t e d and mix u n t i l un i fo rm.

SOURCE: Rhone-Poulenc: Suggested Formula t ions

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Glass CleanerslPolishes 83

Glass Cleaner (L P o l i s h

E x c e l l e n t f o r c lean ing automobi le w indsh ie lds , household windows, r e f r i g e r a t o r s , s tove tops , and k i t c h e n counter sur faces . I t removes grease and d i r t and i s easy t o wipe o f f because o f t h e l u b r i c i t y p rov ided by t h e s i l i c o n e f l u i d . Th i s f o r m u l a t i o n a l s o p rov ides a n t i - f o g p r o p e r t i e s .

Incjredi en ts : Dow Corning 193 Sur fac tan t Dowanol EB G lyco l E ther Isopropanol (91%) Water (de ion i zed )

Percent by Weiaht 0 .5 4.0

10.0 85.5

Prepara t ion : 1 . D isso lve Dow Corning 193 Sur fac tan t i n t h e isopropano l and

2 . Add t h i s s o l u t i o n t o t h e water .

Use I n s t r u c t i o n s : T h i s p roduc t should be a c l e a r l i q u i d . I t s grease-removing

and c lean ing power can be s l i g h t l y improved by adding a smal l amount o f o rgan ic s u r f a c t a n t such as T r i t o n W-30.

The produc t can be sprayed on to su r faces w i t h a mechanical spray a p p l i c a t o r dev ice o r f rom a p l a s t i c squeeze b o t t l e . I t should be wiped o f f immediately w i t h a d ry , l i n t - f r e e c l o t h .

g l y c o l e t h e r .

Formula t ion E2-7247

Glass C l eaner-Pol i sh

P a r t : I n g r e d i e n t : A 200 F lu id -20 cs

O l e i c Ac id I sopar H

B Morphol i ne Water

C Water D Snowf 1 oss

Water E Carbopol 934, 2%

Percent by Weisht 1 .5 2.5

10.0 1 . 5

10.0 22.0 10.0 35.0 5.0

Method :

Eppenbach, s l o w l y add p a r t "€3." Add p a r t s "C," and "D" and "E" i n t h a t o rde r w i t h cont inued a g i t a t i o n .

SOURCE: Dow Corning Corp.: Suggested Formula t ions

When b lend ing p a r t "A" on a high-shear mixer such as an

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84 Advanced Cleaning Product Formulations

Glass Cleaners A1 1 -PurDose Glass C1 eaner

Formulation: Water Ammonium hydroxide (28%) Pluronic L-10 polymer Dowanol PnB g l yco l ether

Notes : Mix components Cleaners should

n t h e order l i s t e d . be c lea r and co lo r l ess .

All-Purpose Glass Cleaner

Formulation: Water Duponol C surface a c t i v e agent Dowanol PnB g l yco l e ther Dowanol DPnB g l y c o l e ther P luronic L-10 polymer C o l l o i d a l S i l i c a

Wt.% 92.4 2.5 0.1 5.0

Wt.% 91.85 0.05 3.0 2.0 0.1 3.0

Notes : Combine f i r s t two components and s t i r t o d i sso l ve s o l i d s . Add remaining components i n order l i s t e d . Cleaner should be c l e a r and co lo r l ess .

All-Purpose Glass Cleaner. L i a u i d Spray

Formulation: Dowanol PM ( o r DPM o r PnB) g l y c o l e ther Propylene g l yco l Isopropanol Water

A1 1 -PurDose G1 ass C1 eaner . L i aui d SDrav

Formulati on: Dowanol PM ( o r 1:l PM:PnB) g l y c o l e ther Ammonium hydroxide Pluronic F 108 polymer Water

SOURCE: Dow Chemical Co.: Suggested Formulations

Wt.% 5.0 5.0 35.0 55.0

Wt.% 8.0 1.5 0.1 90.4

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Glass CleanersIPolishes 85

I n d u s t r i a l Glass Cleaner

Wei Qht /% 75% Water

Mazer Macol NP 9 .5 Sodi urn D i hydrogen Phosphate Mazer Macol 212 Mazer Mazon DDBSA Mazer Mazawet DF I sop ropy l Alcohol

Procedure: Mix i n o rde r o f l i s t i n g .

3% 5% 5% 3% 4% 3%

Mu l t i -Fea tu re Glass Cleaner

Wei sh t /% 10-15%

85% 1.75% 0.25%

Isop ropy l Alcohol Water Mazer Macol 19 Mazer Mas i l 1066C

G1 ass C1 eaner

Weight/% 89.1% Water

Mazer Mas i l 1066C Mazer Mazawet DF Mazer Macol 212 I sop ropy l A lcoho l

0.2% 0.2% 0.5%

10.0%

SOURCE: PPG I n d u s t r i e s , I n c . : Suggested Formula t ions

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7. Hard Surface Cleaners

86

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Hard Surface Cleaners 87

Abras ive Hard Sur face Cleaner-A

Components: Water (40-5OC) Hostapur SAS 60 Genapol UD 030 Prese rva t i ve Perfume Calcium carbonate

Phys ica l P roper t i es : V i s c o s i t y ( s p i n d l e RVT, mPas): 1700 pH: 10.0

Abras ive Hard Sur face Cleaner-B

Components: Water (40-5OC) Hostapur SAS 60 Genapol UD 030 Prese rva t i ve Perfume Cal c i um carbonate

Physi c a l Proper t i es : V i s c o s i t y ( s p i n d l e RVT, mPas): 2800 pH: 10.0

Abras ive Hard Sur face Cleaner-C

Components: Water (40-5OC) Hostapur SAS 60 Genapol UD 030 Prese rva t i ve Perfume Calcium carbonate

W t . % 59.9 4.5 5.4 0 .1 0 . 1

30

W t . % 49.9

4.5 5 .4 0 .1 0 . 1

40

W t . % 39.9

4.5 5.4 0.1 0 .1 50

Phys ica l P r o p e r t i 8s: V i scos i t y ( s p i n d l e RVT, mPas) : 6400 pH: 1 0 . 0

Procedure: Add a m ix tu re o f t h e two s u r f a c t a n t s t o water . A l l ow t h e

water t o coo l t o 30C and con t inue t o add t h e o t h e r components i n t h e g i ven o rde r .

SOURCE: Hoechst Celanese Corp.: Suggested Formulat ions

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88 Advanced Cleaning Product Formulations

D-Limonene Based C leaner - I

I n g r e d i e n t : 01 Water d-Li monene Carbopol ETD-2001 r e s i n Propyl ene G1 yco l G lyce r ine Neodol 25-7 Germaben I I E NaOH (18%)

W t . % ( a c t i v e 1 67.5 25 .0

0 .5 2.0 3 . 0 0.5 0 .8 0 . 7

V i s c o s i t y (cPs, RVT @ 20rpm, 25C): 56,000 Appearance: Opaque 1 o t i on S t a b i l i t y : Pass 4+ weeks @ 50C, 5 c y c l e s o f f reeze/thaw

D-Limonene Based C leaner - I1

Inq red i e n t : D I Water d-Limonene Pemulen T R - I r e s i n Propyl ene Glyco l G lyce r ine Neodol 25-7 Germaben I I E NaOH (18%)

W t . % ( a c t i v e ) 68.2 25.0

0.2 2.0 3 . 0 0 .1 0 .8 0 .7

V i s c o s i t y (CPs, RVT @ 20rpm, 25C): 8,600 Appearance: Opaque l o t i o n S t a b i l i t y : Pass 4+ weeks @ 50C. 5 c y c l e s o f f reeze/thaw

Procedure: 1. Place t h e d-l imonene i n a beaker and add t h e Carbopol o r

Pemulen r e s i n t o t h e s o l v e n t . ( S i f t i n g t h e r e s i n i n t o t h e so l ven t i s recommended b u t n o t requ i red . )

2. Using moderate a g i t a t i o n p rov ided by a L i g h t n i n ' M ixer ( o r s i m i l a r t ype ) and a marine-type i m p e l l e r , add t h e water t o t h e so l ven t phase and mix f o r approx imate ly 10 minutes.

3 . M ix t h e propy lene g l y c o l , g l y c e r i n e . non ion i c s u r f a c t a n t and p r e s e r v a t i v e . Add t o t h e so lvent /water m ix tu re .

4 . Add t h e 18% NaOH u n t i l t h e f o r m u l a t i o n reaches pH 6 .0 . The q u a n t i t y o f NaOH l i s t e d i n t h e f o r m u l a t i o n s i s approximate and may r e q u i r e s l i g h t adjustment t o achieve t h e d e s i r e d pH.

C h a r a c t e r i s t i c s : * Pemul en r e s i ns p rov ide e f f i c i en t and stab1 e emu1 s i f i c a t i on o f d-l imonene so l ven t i n wa te r less hand c leaners and hard su r face c leaners

* Abrasives, such as pumice, can be suspended i f des i red .

SOURCE: B.F. Goodr ich Co.: CARBOPOL High Performance Polymers: Suggested Formula t ions

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Hard Surface Cleaners 89

D-Li monene Based C1 eaner - I I 1 I n s r e d i en= W t .% ( a c t i v e ) D I Water 68.2 d -L i monene 25.0 Pemulen TR-2 r e s i n 0 . 2 Propy l ene G1 yco l 2 . 0 G l y c e r i n e 3.0 Neodol 25-7 0.1 Germaben I I E 0 . 8 NaOH (18%) 0.7

V i s c o s i t y (cPs, 2 5 C ) : 3,400 Appearance: Opaque l o t i o n S t a b i l i t y : Pass 4 t weeks @ 50C, 5 c y c l e s o f f reeze/thaw

Procedure: 1 . Place t h e d-l imonene i n a beaker and add t h e Carbopol o r

Pemulen r e s i n t o t h e s o l v e n t . ( S i f t i n g t h e r e s i n i n t o t h e so l ven t i s recommended b u t n o t r e q u i r e d . )

2. Using moderate a g i t a t i o n p rov ided by a L i g h t n i n ' M ixer ( o r s i m i l a r t y p e ) and a marine-type i m p e l l e r , add t h e water t o t h e s o l v e n t phase and mix f o r approx imate ly 10 minutes.

3. Mix t h e propy lene g l y c o l , g l y c e r i n e , non ion i c s u r f a c t a n t and p r e s e r v a t i v e . Add t o t h e so l ven t /wa te r m i x t u r e .

3. Add t h e 18% NaOH u n t i l t h e f o r m u l a t i o n reaches pH 6 . 0 . The q u a n t i t y o f NaOH l i s t e d i n t h e f o r m u l a t i o n i s approx- imate and may r e q u i r e s l i g h t adjustment t o achieve t h e d e s i r e d pH.

C h a r a c t e r i s t i c s : * Pemulen r e s i n s p r o v i d e e f f i c i e n t and s t a b l e e m u l s i f i c a t i o n o f d-l imonene s o l v e n t i n wa te r less hand c leaners and hard su r face c leaners .

* Abrasives, such as pumice, can be suspended i f des i red .

I n n r e d i e n t : W t . % l a s i s ) DM Water 62.1 Ethanol 2.0 Carbopol 674 r e s i n 0.6 NaOH (50%) 1 .o NaHC03 1.2 Georgia Marb le White #8 30 .0 Neodol 25-3 2 .5 N ino l GR (80%) 0 . 6 Fragrance q . s . Procedure: 1 . Add t h e e thano l t o t h e wa te r . (Ho ld o u t a p o r t i o n o f t h e

2 . Using moderate (800 rpm) a g i t a t i o n p rov ided by a L i g h t n i n '

Low Foaming L i q u i d Cleaner w i t h Ab ras i ve

water f o r Step 3.)

Mixer o r s i m i l a r v a r i a b l e speed u n i t and an i m p e l l e r s u i t a b l e f o r general m ix ing and b l e n d i n g opera t i ons , screen t h e Carbopol r e s i n i n t o t h e e thano l /water s o l u t i o n . Mix t h e s o l u t i o n f o r approx imate ly 15 minutes o r u n t i 1 t h e d i s p e r s i o n i s homogeneous.

3. Prepare a n e u t r a l i z i n g s o l u t i o n o f water/NaOH/NaHCOB. Add i t t o t h e Carbopol r e s i n d i s p e r s i o n and mix u n t i l homogeneous.

4. Add t h e ab ras i ve and s u r f a c t a n t t o t h e s o l u t i o n and mix u n t i l homogeneous. Add f rag rance as des i red .

SOURCE: B.F. Goodr ich Co.: CARBOPOL Polymers: Suggested Formulas

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90 Advanced Cleaning Product Formulations

D-Limonene Hard-surface Cleaner ___________. D-Limonene Concentrate

Component: D-Li monene Alcodet HSC-1000 Igepa l CO-720 Mi rano l FBS T r i ethanol ami ne Water

20 .0 30.0 30.0 19.0

1 . o --- Procedure:

Blend i n g r e d i e n t s i n o rder l i s t e d and mix u n t i l un i fo rm.

Phys ica l P r o p e r t i e s : Appearance: C lear , g o l d l i q u i d S p e c i f i c G r a v i t y : 1 .02 V i s c o s i t y : 110 cps pH, as i s : 1 0 . 0

Formula HS-0093

D-Lirnonene Hard-surface Cleaner A1 1 -Purpose Spray C1 eaner Type ( 1 : 9 D i 1 u t i on)

ComDonent: D-Limonene Alcodet HSC-1000 Igepa l CO-720 Mi rano l FBS Tr ie thano lami ne Water

W a 2.0 3.0 3.0 1 .9 0 .1

90.0

Procedure: D i l u t e concen t ra te 1:9 w i t h water o r charge "Vessel A" w i t h

D-Limonene, A lcodet HSC-1000, and then Igepa l CO-720. Mix u n t i l un i fo rm. Charge a separate "Vessel B" w i t h water, t r i e thano lamine and Mi rano l FBS. Mix u n t i l un i fo rm. F i n a l l y , add t h e con ten ts o f "Vessel A" t o "Vessel 8'' and mix u n t i l un i fo rm.

Physi cal Proper t i es : Appearance: C1 ear, 1 i gh t ye1 1 ow 1 i qu i d Speci f i c G r a v i t y : 1 .OO V i s c o s i t y : <10 cps pH, as i s : 9 .5

Formula HS-0093

SOURCE: Rhone-Poulenc: Suggested Formula t ions

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Hard Surface Cleaners 91

D-Limonene Hard-surface Cleaners Heavy-Duty Deqreaser Type [1:3 D i l u t i o n 1

Component: D-Li monene A lcodet HSC-1000 Igepa l CO-720 M i rano l FBS T r i e thano l ami ne Water

Wt.% 5.0 7.5 7 . 5 4.75 0.25

75.0

Procedure: D i l u t e concen t ra te 1 :3 w i t h water o r b lend i n g r e d i e n t s i n

t h e same manner as s p e c i f i e d i n t h e spray c leaner procedure.

Physi c a l P r o p e r t i es : Appearance: C lea r , y e l l o w l i q u i d S p e c i f i c G r a v i t y : 1 . O O V i s c o s i t y : 110 cps pH: 9 .5

Formula HS-0093

D-Limonene A1 1-Purpose Cleaner

Component: Water Sodium Metasilicate-Pentahydrate Mi rano l FBS Rhodasurf 91-6 Cheel ox BF-13 A1 kami de DC-212/M D-Limonene

Wt.% 73.5

2.0 10.0 3.5 5 . 0 3 . 0 2 . 0

Procedure: Blend i n g r e d i e n t s i n o rde r l i s t e d and mix u n t i l un i fo rm.

Phys ica l P r o p e r t i es : Appearance: S l i g h t l y hazy, y e l l o w 1 pH, as i s : 12.5 S p e c i f i c G r a v i t y : 1.02 V i s c o s i t y : <10 cps

Formula HS-0033

SOURCE: Rhone-Poulenc: Suggested Formu

q u i d

a t i ons

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92 Advanced Cleaning Product Formulations

Economi c a l P i ne O i 1 Hard-Surf ace C1 eaner

Component: Wt.% Pine O i l 5 . 0 Rhodasurf BC-840 10.0 Water 85.0 Procedure: 1 . Add Rhodasurf BC-840 t o Pine O i l . Mix w e l l . Heat t o approx-

2 . Add water and mix thoroughly. Physical P roper t i 8s:

Appearance: Clear, water-white l i q u i d pH, as i s : 3.08 Spec i f i c Grav i t y : 0.99 V iscos i t y : 110 cps Formula HS-0037

imate ly 35-40C t o ob ta in homogeneous s o l u t i o n .

Heavy-Duty Cleaner Powder

Wt.% Trisodium Phosphate or Sodium Carbonate 40 Sodi um S i 1 i cate 10 Rhodacal DS-10 20 Sodium S u l f a t e 30 Fragrance Q.S.

Add ing red ien ts i n order l i s t e d t o powder blender. Mix u n t i l Procedure:

uni form. Physical P roper t i es :

Appearance: White, f ree - f l ow ing powder pH, 1% s o l u t i o n : 10.8 Formula HS-0039

D-Limonene Emu ls i f i ab le Concentrate

Comoonent: Wt.% D-Li monene 80.0 Rhodacal IPAM 15.0 Igepal CO-720 4.0 Triethanolami ne 1 .o Procedure:

Blend ing red ien ts i n order l i s t e d and mix u n t i l uni form. Physical P roper t i 8s:

Appearance: Clear, ye l low l i q u i d S p e c i f i c Grav i t y : 0.9 V iscos i t y : t10 cps pH, as i s : 10.0

Formula HS-0094 Note: Product forms m i l ky wh i te emulsions when d i l u t e d w i t h water

SOURCE: Rhone-Poul enc: Suggested Formulation

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Hard Surface Cleaners 93

General PurDose Hard-sur face Cleaners Solvent-Free Non-Phosphate Type

Component: w t -% Water 83.5 Sodium M e t a s i l i c a t e Pentahydrate 2 . 0 Rhodasurf 91-6 7 .5 Cheel ox BF-13 3.0 M i rano l FBS 4.0 Procedure:

Blend i n g r e d i e n t s i n o rde r l i s t e d and mix u n t i l un i fo rm. Phys ica l P r o p e r t i e s :

Appearance: C lea r , I t . y e l l o w S p e c i f i c G r a v i t y : 1.035 V i s c o s i t y : t 10 cps pH, as i s : 12.3

Solvent-Free Phosphate Type

C o m p o n m Wt.% Water 85.5 Sodium M e t a s i l i c a t e Pentahydrate 2 . 0 Rhodasurf 91 -6 7.5 Cheelox BF-13 3.0 Rhodafac RA-600 2.0 Procedure:

Blend i n g r e d i e n t s i n o rde r l i s t e d and mix u n t i l un i fo rm. Phys ica l P r o p e r t i e s :

Appearance: C lea r , water -wh i te Speci f i c G r a v i t y : 1 .012 V i s c o s i t y : t10 cps pH, as i s : 11.85

Heavy-Duty So lven t Type

Component: Wt.% Water 83.0 _ _ . Sodium M e t a s i l i c a t e Pentahydrate 1 . o Rhodasurf 91-6 6.0 Cheel ox BF-13 2.0 M i rano l FBS 2 . 0 Butoxyethanol 6 .0 Procedure:

Blend i n g r e d i e n t s i n o rde r l i s t e d and mix u n t i l un i fo rm. Phys i ca l P r o p e r t i e s :

Appearance: C lea r , water -wh i te Speci f i c G r a v i t y : 0.994 V i s c o s i t y : t10 cps pH, as i s : 12.20

SOURCE: Rhone-Poulenc: Formula HS-0034

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94 Advanced Cleaning Product Formulations

General Purpose SDrav-and-WiDe Cleaner

I n a r e d i ent: 01 Water Carbopol ETO-2691 Tet rasod i um EOTA Sodium Metasi l i c a t e (anhydrous) Dowanol PM Neodol 25-7

Wt.%(as 90.7

0.2 2.0 2.3 3.0 1 . 5

V i s c o s i t y : 120 CP pH: 12.3 C1 ear- to-hazy v i scous 1 i qu i d

Procedure: 1 . Combine Carbopol ETO-2691 w i t h t h e de ion ized water . 2. Mix u n t i l a homogeneous d i s p e r s i o n i s ob ta ined. 3. Combine t h e remaining i n g r e d i e n t s i n t h e o rde r l i s t e d t a k i n g

ca re t o mix tho rough ly a f t e r each a d d i t i o n . C h a r a c t e r i s t i c s :

* Leaves sur faces c lean and b r i g h t * Provides v e r t i c a l c l i ng--doesn ' t run down * Reduces m i s t i n a i r

Mold and Mildew Remover

I n a r e d i e n c DI Water Carbopol 672 NaOH (50%) Sodium M e t a s i l i c a t e Pentahydrate B i o te rge PAS-8S Sodium Hypoch lo r i t e (15%)

Wt.%(as i s ) 84.5

1 .o 2.0 0.5 5.0 7.0

V i s c o s i t y : 120 CP pH (as i s ) : 12.5 Opaque, v iscous l i q u i d

Procedure: 1 . Combine Carbopol 672 w i t h t h e de ion i zed water . M ix u n t i l a

2. N e u t r a l i z e t h e d i s p e r s i o n w i t h NaOH. Mix w i t h moderate

3. Add sodium m e t a s i l i c a t e pentahydra te and mix u n t i l d i sso l ved . 4. Add B i o t e r g e PAS-8S t o t h e m ix tu re . 5. Add sodium h y p o c h l o r i t e t o t h e m ix tu re . Reduce t h e m ix ing

speed t o p revent sp lash ing as a sudden drop i n v i s c o s i t y w i l l occur .

C h a r a c t e r i s t i c s : * Prov ides v e r t i c a l c l i ng--doesn't run down * Removes mildew s t a i n s and soap scum e f f e c t i v e l y by p ro long-

* Prevents sp lash ing * Reduces m i s t i n a i r SOURCE: B.F. Goodrich Co.: CARBOPOL Polymers: Suggested Formulas

homogeneous d i spe rs i on i s o b t a i ned.

(800-1 200rpm) a g i t a t i o n .

i n g con tac t t i m e

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Hard Surface Cleaners 95

G l y c o l E the r C leaner 1

I n q r e d i e n t : Water EDTA (39.0%)

Add, mix w e l l Sodi um G1 uconate

Add, mix w e l l 42 Sodium S i l i c a t e 3.22/1

Add, mix w e l l KOH (45%)

Add, mix w e l l E thy lene g l y c o l b u t y l e t h e r

Add, mix w e l l Tomah A l k a l i S u r f a c t a n t

Add, mix w e l l Nonionic-HLB 13

Add, mix w e l l

SpG 20C/20C: 1 .17 pH: 12.90 Recommended D i l u t i o n s : 12-3O:l A p p l i c a t i o n s : HSC, g r i l l c l eaner , etC

Formula S-1 00

G l y c o l E the r Cleaner 2

I n q r e d i en t : S o f t Water Sodi um G1 uconate

Add, mix w e l l E thy lene g l y c o l b u t y l e t h e r

Add, mix w e l l Noni o n i c-HLB 13

Add, mix w e l l Tomah A l k a l i S u r f a c t a n t

Add, mix w e l l KOH (45%)

Add, mix w e l l

SpG 20/20C: 1.095 pH: 13.5 Recommended D i 1 u t i ons : 10-30 : 1 A p p l i c a t i o n s : HSC

Formula S-1 01

SOURCE: Tomah Products, I n c . : Suggested Formula t ions

W> 66.00

1 .oo

1 .oo

10.00

10.00

5.00

5.00

2.00

Wt% 60.00 3.00

8.00

1 . oo

8.00

20.00

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96 Advanced Cleaning Product Formulations

Hard Surface Cleaners A l l Purpose Cleaner

Water Sodi urn Metasi 1 i cate T r i sodi urn Phosphate Glucopon 425 CS

A l l Purpose Cleaner w i t h Solvent

Water Sodium Metasi 1 i c a t e T r i sodi urn Phosphate Propylene Glycol nButyl Ether Glucopon 425 CS

Pine O i l Cleaner

Pine O i l Trycol 5963 Sul f o tex 6040s Glucopon 425 CS Isopropyl Alcohol T r i ethanol ami ne Water

Heavy Dutv Deareaser

Water TKPP Sodi urn Metasi 1 i ca te Potassi urn Hydroxide (45%) Glucopon 425 CS Propylene Glycol nButyl Ether

W t % 93

3 2 2

WE_% 91.5

2.0 1 .o 3.5 2.0

&% 15

5 5 4 8 3

60

W U 72

4 3

10 8 3

Procedure:

using moderate a g i t a t i o n . Incorporate c o l o r and fragrance as needed.

SOURCE: Henkel Corp. : SugQested Formul a t1 ons

Add i n t h e order 1 i sted, d i s s o l v i n g each ing red ien t completely

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Hard Surface Cleaners 97

Hard-surface Cleaner A l l - S u r f a c e Bathroom A c i d Type

M-Pyrol, N-Methy l -2 -Pyr ro l idone Igepa l CO-630 H y d r o x y e t h y l c e l l u l o s e Phosphor ic Ac id Water

Perfume and c o l o r a n t s may be added.

W_L% 4.0 1 . o 0.2 9 .5

85.3

Procedure: 1 . D i sperse h y d r o x y e t h y l c e l l u lose i n water . 2 . I n a separa te vesse l , mix M-Pyrol, I gepa l CO-630 t o g e t h e r .

Add hydroxyethylcellulose/water m i x t u r e . 3. Add a c i d and mix tho rough ly .

Phys ica l P r o p e r t i es : pH (as i s ) : 2.0 pH (1%): 2.4 V i s c o s i t y : 30 cps Speci f i c G r a v i t y : 1 . 0 2

Formula BC-0005

Hard-sur face Cleaner A1 1 -Surface_&throom Type

Water Igepa l CO-630 Cheel ox NTA-Na3 Sodium Xylene Su l fona te Sodi um Hydroxide Perfume and c o l o r a n t s added, as des i red , r e p l a c i n g water

Wt.% 70 .5

2.5 20.0

5.5 1 .5

Procedure: 1 . D i s s o l v e Igepa l CO-630 i n wa te r . Add Cheelox NTA-Na3. 2. Add sodium xy lene s u l f o n a t e and sodium hydrox ide , m ix ing

w e l l a f t e r each a d d i t i o n .

Physi c a l P r o p e r t i es : pH, as i s : 12 .9 pH (1%) : 11.4 V i s c o s i t y : 10 cps S p e c i f i c G r a v i t y : 1.05

Formula BC-0006

SOURCE: Rhone-Poulenc: Suggested Formula t ions

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98 Advanced Cleaning Product Formulations

Hard Surface Cleaner-A

Components: Water Tetrasodi um EDTA (40% sol n) Tetrapotassium Pyrophosphate (TKPP 60%) Dowanol PNB Sodium xylene su l fona te (96%) Nonionic su r fac tan t :

Hostapal N 090

W t . % 70 1 6 6 8

9

Physical Proper t ies: Appearance (25C): c l e a r Densi ty ( l b / g a l ) : 9.0 pH (l%, 25C): 10.1 Ross Mi les (49C, 1%, cm):

1 min. : 10 5 min.: 4

Cloud Point ( l % , C ) : 54.5 Surface Tension (0.25%, Dynes/cm): 31.84 V iscos i t y , B r o o k f i e l d (25C, 50 rpm, LV#l) : 24.3 Freeze thaw s tab le : f reez ing p o i n t (C): D id not f reeze

Blend the components i n the given order w i t h continuous Procedure:

s t i r r i n g .

Hard Surface Cleaner-8

Components: Water Tetrasodium EDTA (40% soln) Tetrapotassium Pyrophosphate (TKPP 60%) Dowanol PNB Sodium xylene su l fona te (96%) Nonionic su r fac tan t :

Genapol UD 079

Physical p roper t i es : Appearance (25C): c l e a r Densi ty ( l b / g a l ) : 9.1 pH ( l % , 25C): 10.8 Ross Mi les (49C. 196, cm

1 min. : 14 5 min.: 3

Cloud Point ( l % , C): 63 Surface Tension (0.25%, Dynes/cm): 27.92

W t . % 69

1 6 6 8

10

V iscos i t y , B r o o k f i e l d (-5C, 50 rpm, LV#1): 25.4 Freeze thaw s tab le : f reez ing p o i n t (C): D id no t f reeze

Blend t h e components i n t h e given order w i t h continuous Procedure:

s t i rri ng . Source: Hoechst Celanese Corp.: Suggested Formulatlons

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Hard Surface Cleaners 99

Hard Sur face Cleaner-C

Components: Water Tetrasodium EDTA (40% s o l n ) Tetrapotassium Pyrophosphate (TKPP 60%) Dowanol PNB Sodium xy lene s u l f o n a t e (96%) Nonionic s u r f a c t a n t :

Genapol 26-L-75

W t . % 70

1 6 6 8

9

Phys ica l P roper t i es : Appearance (25C): c l e a r Dens i t y ( l b / g a l ) : 9.00 pH ( l % , 25C): 10.6 Ross M i l e s (49C, 1%, cm):

1 min . : 16 5 min . : 10

Cloud Po in t ( l% , C): 76 Sur face Tension (0.25%, Dynes/cm): 31.69 V i s c o s i t y , B r o o k f i e l d (25C. 50 rpm, LV#1): 20.4 Freeze thaw s t a b l e : f reez ing p o i n t ( C ) : D i d no t f reeze

Procedure:

s t i r r i n g . Blend t h e components i n t h e g iven o rde r w i t h cont inuous

Hard Sur face Cleaner-D

Components: Water Tetrasodium EDTA (40% s o l n ) Tetrapotassium Pyrophosphate (TKPP 60%) Dowanol PNB Sodium xy lene s u l f o n a t e (96%) Nonionic s u r f a c t a n t :

Genapol 26-L-60

W t . % 70

1 6 6 8

9

Phys ica l P r o p e r t i e s : Appearance (25C): c l e a r pH ( l % , 25C): 10.17 Ross M i l e s (49C, 196, cm):

1 min . : 13 5 m i n . : 5

Cloud Po in t ( l % , C ) : 59 Surface Tension (0.25%, Dynes/cm): 29.44 V i s c o s i t y , B r o o k f i e l d (25C, 50 rpm, LV# l ) : 19.2 Freeze thaw s t a b l e : f r e e z i n g p o i n t ( C ) : D i d n o t f reeze

Procedure:

s t i r r i ng . SOURCE: Hoechst Celanese Corp.: Suggested Formulat ions

Blend t h e components i n t h e g iven o rde r w i t h cont inuous

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100 Advanced Cleaning Product Formulations

Heavy D u t y HSC

Inq red i ent : Water NTA (39%)

D i sso l ve Sodi um G1 uconate

Add, mix w e l l KOH (45%)

Add, mix w e l l Tomah A l k a l i Sur factant

Add, mix w e l l Nonionic Surfactant-HLB 13

Add, mix w e l l

pH: 14.20 Recommended D i l u t i o n s : 5-2O:l Appl icat ions: Soak tank, heavy duty HSC

Formula NP-103

Powder-Heavy Duty HSC

Ing red ien t : Soda Ash Nonionic Surfactant-HLB 13

Tomah A l k a l i Sur factant

Sodium M e t a s i l i c a t e Pentahydrate

NTA o r EDTA (100%)

Sodium Gluconate

NaOH ( f l a k e )

Blend i n powder blender o r spray over

Blend i n powder blender or spray over

Blend i n powder blender

Blend i n powder blender

Blend i n powder blender

Blend i n powder blender

SpG 20/20C: 0.97 Recommended D i l u t i o n s : 1-4 oz/gal Appl icat ions: Soak tank, heavy duty HSC

Formula NP-104

SOURCE: Tomah Products, Inc.: Suggested Formulations

Wt% 65.00 1 .oo

4.00

25.00

3.00

2.00

Wt% 65.00 2.00

2.00

15.00

2.00

4.00

10.00

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Hard Surface Cleaners 101

Hi Qh-Foaming. Clear. L iah t -Duty L i q u i d Cleaner

Rhodaterge SMC Water Perfume, Dye, P rese rva t i ve

P a r t s by Weinht 20-40 80-60

Q . S .

H i gh-Foami n e L i qht-Duty C1 eaner

A . Rhodaterge SMC

8. O p a c i f i e r *

C . Perfume, Dye, P rese rva t i ve

Water

Water

P a r t s by Weight 20-30 70-60

1 9

Q.S.

Add Rhodaterge SMC t o Water i n "A" u n t i l c l e a r . D i l u t e o p a c i f i e r i n Water i n " B " . Add "B" t o "A" s l o w l y w i t h g e n t l e s t i r r i n g . A f t e r t h e o p a c i f i e r i s u n i f o r m l y d ispersed, con t inue s t i r r i n g d u r i n g dye and perfume a d d i t i o n .

*Opaci f i e r E295, Morton Chemi c a l Co.

Spray Cleaner

Water Caust ic Soda Glyco l E ther Rhodaterge SMC Perfume, Dye, P rese rva t i ve

Par t s by Weight 88.0

1 . o 8.0 3 . 0 Q.S.

P i ne O i 1 Deteraent-Cleaner-Sani ti ze r

Rhodaterge SMC Pine O i l Water

Heavy-Duty Steam Cleaner

Gafac RE-610 Rhodaterge SMC Sodium M e t a s i l i c a t e Pentahydrate Sodi um S i 1 i c a t e Water

SOURCE: Rhone-Poulenc: SugQested Formula t ions

P a r t s by Weinht 20.0

0 . 5 79.5

Par t s by Weiqht 4 .0 3.0

10.0 5 .0

78

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102 Advanced Cleaning Product Formulations

Hiah-Performance. Hard-surface Cleaners Solvent-Free Non-Phosphate Type

Component: Wt.% Water 88 .0 Sodium M e t a s i l i c a t e Pentahydrate 2.0 Mi rano l FBS 3.0 Alcodet HSC-1000 4 . 0 Cheelox BF-13 3 .0 Procedure:

Blend i n g r e d i e n t s i n o rder l i s t e d and mix u n t i l un i fo rm. Phys ica l P roper t i es :

Appearance: C lear , l i g h t ye l l ow l i q u i d pH, as i s : 12.6 V i s c o s i t y : t 10 cps Speci f i c G r a v i t y : 0.978

Solvent-Free Phosphate TYDe

Component: Wt.% Water 87 .0 Sodium Metas l i c a t e Pentahydrate 2 . 0 Mi rano l FBS 1 . o Alcodet HSC- 000 4.0 Cheelox BF-1 3 .0 Rhodafac RA-600 3.0

Blend i n g r e d i e n t s i n o rder l i s t e d and mix u n t i l un i fo rm.

Appearance: Clear, l i g h t y e l l o w l l q u i d pH: 11.5 V i s c o s i t y : <10 cps S p e c i f i c G r a v i t y : 1.013

Procedure:

Phys ica l P roper t i es :

Heavy-Duty So lvent Type

Component: Water Sodium M e t a s i l i c a t e Pentahydrate Mi rano l FBS Alcodet HSC-1000 Cheelox BF-13 Butoxyethanol Procedure:

B1 end i ngred i en ts Phys ica l P r o p e r t i es :

Appearance: C lear , pH, as i s : 12.55 V i s c o s i t y : t 10 cps S p e c i f i c G r a v i t y :

SOURCE: Rhone-Poulenc

n o rde r

l i g h t ye

.016

Formula

Wt.% 85.0

2.0 2.0 3.0 2 . 0 6.0

i s t e d and mix u n t i l un i fo rm.

low l i q u i d

HS-0035

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Hard Surface Cleaners 103

Hinh Pressure Spray Concent ra te (L iqu id , low foam)

S o i l - Grease, o i l Sur face - P a i n t , po lymer ic , metal A p p l i c a t i o n Method - Spray Manufacture - Mix tank w i t h p r o p e l l e r s t i r r e r

Composi t i on : Water Metso Beads 2048 EDTA, Tetrasodium (37%) Sodium Xylene S u l f o n a t e (40%) C9-Cll L inea r A l coho l , 6 Moles EO C9-Cl l L inea r A l coho l , 2 . 5 Moles EO

Use D i l u t i o n : 10% bw ( 1 3 o z / g a l l o n )

%!t 76.0

2 .0 8.0 8 . 0 3.0 3 .0

Spray and Wipe Household Hardsurface ( L i q u i d)

S o i l - Food grease, o i l and p r o t e i n , pe t ro leum grease and o i l Sur face - Meta l , ceramic, po l ymer i c , g l a s s A p p l i c a t i o n Method - Spray and wipe Manufacture - Mix tank w i t h p r o p e l l e r s t i r r e r

Composi t i on : Water Metso Beads 2048 STPP EDTA, Tetrasodium (37%) Ethy lene G lyco l n -Buty l E ther C9-C11 L inea r A l coho l , 6 Moles EO

Use D i l u t i o n : As i s

Des ta i ne r

S o i l - Organic s t a i n s : food, mold and grass Sur face - Cement, wood, p a i n t , po lymer ic A p p l i c a t i o n Method - Brush Manufacture - Ribbon o r padd le b lender

Composi t i on : STPP Metso Beads 2048 Sodium S u l f a t e PQ Epsom S a l t Octylphenoxy Po lye thoxyethano l , 9-10 Moles €0 Sodium Perborate, Monohydrate

Use D i l u t i o n : 2.3-4.5% bw (3-6 o z / g a l l o n )

Source: The PQ Corp.: Suggested Formula t ions

%A 88.2

2.4 2.0 1 . 4 3.0 3 .0

25.0 25.0

8 . 0 2.0 2.0

38.0

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104 Advanced Cleaning Product Formulations

HSC/Food Serv ice Deareaser I

I na red i ent : Water EDTA (55%)

Add, mix w e l l Na Orthosi l c a t e

D i ssol ve Dowanol PM

Add Dowanol DPM

Add L i n . alcoho

Add, mix L i n . alcoho

Add, mix Tomah A lka l

Add, mix

ethoxyl a t e (3-6 mole) s l i g h t l y ethoxyl a t e (6-9 mole)

s l i g h t l y Sur factant

u n t i l c l e a r

pH: 13.00 Recommended D i l u t i o n s : 2 oz/gal lon Appl icat ions: Food serv ice degreasing, HSC

HSC/Food Serv ice DeQreaSer I1

I ng red ien t : Water EDTA (55%)

Add, mix Na O r t h o s i l

D i sso l ve

we1 1 cate

Buty l Carbi t o 1 Add

L i n . a lcohol e thoxy late (3-6 mole) Add, mix s l i g h t l y

L i n. a lcohol ethoxyl a t e (6-9 mole) Add, mix s l i g h t l y

Tomah A l k a l i Sur factant Add, mix u n t i l c l e a r

pH: 13.00 Recommended D i l u t i o n s : 2 oz/gal lon Appl icat ions: Food serv ice degreasing, HSC

SOURCE: Tomah Products, I nc . : Formula S-116

Wt% 71 . 5 D 6.00

6.00

6.00

4.00

1 .oo

3.00

3.50

Wt% 66.50 6.00

6.00

10.00

1 .OD

3.00

8.50

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Hard Surfnce Cleaners 105

L i q u i d Abras i ve Cl eaner-A

E f f e c t i v e c leaner t h a t shows no i n d i c a t i o n o f separa t i ng a f t e r 30 days a t room tempera ture .

I n q r e d i e n t s Water C a l c i um Carbonate* Acusol 820 S t a b i l i z e r (30%) B e n t o n i t e C1 ay*** NPE10 NaOH (10%)

% as Supp l ied 4 5 . 4 50

1 . o 2 . 5 0 . 5 0 .6

B r o o k f i e l d V i s c o s i t y , cps @ 0 . 5 r p m : 18,000 @ 12 r p m : 5,500

M i x i ng Procedure:

a g i t a t i o n . Add t h e i n g r e d i e n t s i n t h e s t a t e d o rde r w i t h moderate

*Q-3: Calcium Carbonate C o . ***a% d i s p e r s i o n

L i q u i d Abras i ve C1 eaner-B

E f f e c t i v e c leaner t h a t shows no i n d i c a t i o n o f separa t i ng a f t e r 30 days a t room tempera ture .

I n g r e d i e n t s : Water S i 1 i ca** Acusol 820 S t a b i l i z e r (30%) TKPP (60%) NPElO NaOH (10%)

% as Supp l ied 44.4 50

1 .5 3 0 . 2 5 0.85

B r o o k f i e l d V i s c o s i t y , cps @ 0 . 5 rpm: 53,000 @ 12 rpm: 12,400

M i x i ng Procedure:

a g i t a t i o n . Add t h e i n g r e d i e n t s i n t h e s t a t e d o rde r w i t h moderate

* *S i l -Co. S i l 53: U.S. S i l i c o n Co.

SOURCE: Rohm and Haas Co.: Acusol 820 S t a b i l i z e r : Suggested Formula t ions

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106 Advanced Cleaning Product Formulations

Low Foam Cleaners S e l f Demulsi fy ina Hard Surface Cleaner

Inaredi en t : Water T r i sodi um phosphate

D i ssol ve

Mix w e l l

Mix w e l l

Mix w e l l

EDTA (39-40%)

Tomah Amphoteri c 400

T r i t o n CF-10

Wt% 92.20

1.30

2.00

3.50

1 .oo

pH: 11.50 Recommended D i l u t i o n s : 10-2O:l Appl icat ions: Low foam f l o o r , C I P Notes: Demulsi f ies food o i l s r a p i d l y w i t h no treatment

Formula LF-101

HSC. Moderate pH. S e l f Demulsi fv ing

Ing red ien t : Water C i t r i c a c i d

D i sso l ve T r i sodi um phosphate

D i ssol ve

Mix w e l l

Mix w e l l

Mix w e l l

EDTA (39-40%)

Tomah Amphoteric 400

T r i t o n CF-10

Wt% 86.90

1 .oo

1.30

2.00

7.80

1 .oo

pH: 8.50 Recommended D i l u t i o n s : 10-2O:l Appl icat ions: Low foam f l o o r , CIP Notes: Demulsi f ies food o i l s r a p i d l y w i t h no treatment

Good detergency even a t lower pH Formula LF-102

SOURCE: Tomah Pr6ducts, I nc . : Suggested Formulations

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Hard Surface Cleaners 107

Phosphate Free C leaners Heavy Duty Non So lven t Degreaser

I n q r e d i e n t : S o f t Water Na m e t a s i l i c a t e pentahydra te

NTA (40%)

NaOH (50%)

Tomah AO-14-2

Tomah (2-17-2

Non ion ic Surfactant-HLB 13

D i sso l ve

D i sso l ve

Add, mix w e l l

Add, mix w e l l

Add, mix w e l l

Add, mix w e l l

pH: 14.50 Recommended D i 1 u t i ons: 5-30 : A p p l i c a t i o n s : HSC Notes: For ex t remely hard wa

Formula NP-101 e r , add 1-2% EDTA (40%

Ani o n i c/Noni o n i c HSC

I n q r e d i e n t : S o f t Water Na M e t a s i l i c a t e Pentahydrate

D i s s o l v e EDTA (39%)

Add, mix w e l l DDBSA, Na S a l t (60%)

Add, mix w e l l Tomah Amphoteric 400

Add, mix w e l l Non ion ic Surfactant-HLB 13

Add, mix w e l l

SpG 20/20C: 1.05 pH: 12.90 Recommended D i 1 u t i ons: 5-20 : 1 A p p l i c a t i o n s : Medium Duty HSC

Formula NP-102

SOURCE: Tomah Products, I n c . : Suggested Formula t ions

W B 81.50

2.00

1 .oo

9.50

1.50

1.50

3.00

9 82.50

5.00

3 .00

3.50

4.00

2.00

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108 Advanced Cleaning Product Formulations

Thickened D-Limonene Cleaner

I n q r e d i e n t : D-1 i monene

Ethy lene g l y c o l b u t y l e the r

Tomah E-14-5

Stepan N ino l l l C M

Nonionic Surfactant-HLB 13

S o f t Water

DDDBSA, Na S a l t , (60%)

TEA

Water

P a r t A-Add, mix

P a r t A-Add, mix

P a r t A-Add, mix

P a r t A-Add, mix

P a r t A-Add, mix

Add s l o w l y w i t h good m ix ing

Add t o A, mix w e l l

Add t o A, mix w e l l

Add s l o w l y w i t h good m ix ing

W X 7.20

7.20

4.50

2.00

1 .oo

50.00

6.50

1 .oo

20.60

pH: 5.60 Recommended D i l u t i o n s : 0-1O:l A p p l i c a t i o n s : Cleaner/degreaser Notes: T h i s p roduc t i s a s o f t ge l , e x c e l l e n t where c l i n g

t i m e i s d e s i r a b l e Formula S-107

D-Limonene HSC/Degreaser

I n q r e d i e n t : D-1 i monene

P a r t A Tomah E-14-5

P a r t A-Mix we1 Tomah AO-14-2

P a r t A-Mix we1 Tomah 9-17-2

P a r t A-Mix w e l l Nonionic Surfactant-HLB 13

P a r t A-mix w e l l S o f t Water

M ix s l o w l y i n t o P a r t A EDTA (40%)

Add, mix Tomah A l k a l i S u r f a c t a n t

Add, mix

SpG 20/20C: 1.01 pH: 10.60 Recommended D i l u t i o n s : 10-5O:l A p p l i c a t i o n s : HSC

Formula S-1 1 1 SOURCE: Tomah Products, I n c . : Suggested Formula t ions

W X 7.00

3.00

2.00

2.00

3.00

77.00

5.00

1 .oo

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Hard Surface Cleaners 109

Unbui l t . Hiah-Sudsinq. Hard-sur face Cleaner

Component: Water C a l s o f t F-90 M i rano l FBS Sodi um S i 1 i c a t e Igepa l CO-710 A1 kami de DC-212/S M-Pyrol , N-Methyl- .P-Pyrrol i done

Wt.% 79.7

5 . 3 3 . 0 5 . 5 1 . o 2 .0 3 . 5

Procedure:

T y p i c a l P r o p e r t i es :

Blend i n g r e d i e n t s i n o rde r l i s t e d and mix u n t i l un i fo rm.

Appearance: C lea r , y e l l o w l i q u i d V i s c o s i t y : <10 cps pH, as i s : 9 .85 S p e c i f i c G r a v i t y : 1.07

Formula HS-0036

Hiqh-Performance General Purpose Cleaner Concentrate

Water STPP (Anhydrous Granu la r ) Rhodapon UB Rhodapon BOS A lcodet HSC-1000 Butoxyethanol M i rano l FBS

Wt.% 65.0

6 . 0 13.0

5 . 0 5 . 0 4 . 0 2.0

Procedure:

Phys ica l P r o p e r t i e s :

Blend i n g r e d i e n t s i n o rde r l i s t e d and mix u n t i l un i fo rm.

Appearance: C lea r , l i g h t y e l l o w l i q u i d pH, as i s : 9 . 4 S p e c i f i c G r a v i t y : 1 .06 V i s c o s i t y : <10 cps

Formula HS-0038

SOURCE: Rhone-Poulenc: Suggested Formula t ions

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I10 Advanced Cleaning Product Formulations

Viscous PhosDhoric Ac id Cleaner

Inaredi ent : W X

Phosphoric Acid (75%) 12.70 Water 77.70

Add. mix, cool

Add, d isso lve, mix w e l l

D i ssolve

Add, mix we l l

Add, mix w e l l Recommended D i l u t i o n s : 5-1O:l Appl icat ions: Good c leaning and descal ing, good c l i n g t ime

Acid Thickener 4.00

S a l t (NaC1) 5.00

Noni oni c Sur factant (HLB 13) 0.50

Perfume 0.10

Formul a A-1 05

Viscous H C l Acid Cleaner

Ing red ien t : Water Tomah Acid Thickener*

Add, mix w e l l HC1 Acid (37%)

Add, s lowly , mix w e l l , cool pH: 1.30 Recommended D i 1 u t i ons : 0-30 : 1 Appl icat ions: T o i l e t bowl c leaning, v e r t i c a l surface c leaning Notes: *Mix Acid Thickener p r i o r t o use i n order t o assure

homogenei t y Formul a A-1 09

Viscous Mixed A c i d Cleaner

W X 71.40

3.00

25.60

Inaredi ent : Water Phosphoric Acid (75%)

Add, mix, cool Oxal ic Ac id

D i ssol ve Tomah Acid Thickener*

Add, mix w e l l S a l t (NaC1)

Add, d i sso l ve w i t h mixing V iscos i t y (cps): 693

Recommended Di 1 u t i ons: 10-20: 1 Appl icat ions: Metal c leaning, v e r t i c a l surface cleaning,

Notes: *Mix Ac id Thickener p r i o r t o use i n order t o assure

Formula A-108

descal i ng

homogenei t y

Wt% 71 .oo 22.00

1 .oo

3.00

3.00

SOURCE: Tomah Products, I nc . : Suggested Formulations

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8. Laundry Products

111

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112 Advanced Cleaning Product Formulations

A1 k a l i n e Laundry Formulat ion-Emulsion TYDe

Inq red i en ts : Water* Acusol 820 Stab i 1 i zer (30%) Acusol 81 0 S tab i 1 i zer (18%) Acusol 445 D ispersant (48%) NPElO NaOH (50%)

T o t a l S o l i d s (%) : 32.28 Appearance: Opaque V i s c o s i t y (cp. 12 rpm, #3 sp

M i x i ng I n s t r u c t i ons : Add i n g r e d i e n t s i n t h e o rde r

A l low s u f f i c i e n t t i m e f o r hydra o f t h e NaOH.

* Make sure t o heat water t o

% as SupDl i e d 42

2 4 2

10 40

n d l e ) : 1700

l i s t e d w i t h subsurface a g i t a t i o n . i o n o f t h e STPP be fo re a d d i t i o n

approxi mate1 y 86F (30C) t o i nsure easy d i s p o s i t i o n o f t h e s u r f a c t a n t and r a p i d h y d r a t i o n o f t h e phosphate.

A 1 k a l i ne Laundry Formul a t i on-Sl u r r y Type

I n g r e d i e n t s : Water* Acusol 820 S tab i 1 i zer (30%) Acusol 81 0 S tab i 1 i zer (18%) Acusol 445 D ispersant (48%) NPElO STPP NaOH (50%)

% as SuDPl i e d 32

2 4 2

10 10 40

To ta l S o l i d s (%): 42.28 Appearance: Opaque V i s c o s i t y (cp, 12 rpm, #3 s p i n d l e ) : 5500

M i x i ng I n s t r u c t i o n s : Add i n g r e d i e n t s i n t h e order l i s t e d w i t h subsurface a g i t a t i o n . A l l ow s u f f i c i e n t t i m e f o r h y d r a t i o n o f t h e STPP be fo re a d d i t i o n o f t h e NaOH. * Make sure t o heat water t o approx imate ly 86F (30C) t o

i n s u r e easy d i s p o s i t i o n o f t h e s u r f a c t a n t and r a p i d h y d r a t i o n o f t h e phosphate.

Excel 1 en t s t a b i 1 i t y and suspendabi 1 i t y a re p rov ided t o t h e h i g h l y - a l k a l i n e fo rmu la t i ons by a combinat ion o f Acusol 810 and Acusol 820 s t a b i l i z e r s . Both f o r m u l a t i o n s can be pumped w i t h a p e r i s t a l i c pump. Acusol 445 low-mol ecu l ar-wei gh t po l y - a c y l i c a c i d improves o v e r a l l c lean ing , p revents s o i l redeposi- t i o n and, i n t h e s l u r r y fo rmu la t i ons , a i d i n t h e p r e c i p i t a t i o n and d i s p e r s i o n o f t h e hydra ted STPP.

SOURCE: Rohm and Haas Co.: ACUSOL 820 S t a b i l i z e r : Suggested Formula t i on8

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Laundry Products 113

Anion ic /Non ion ic Heavy-Duty Laundry Deterqent

Pa r t A: Water Na C i t r a t e C a l s o f t F-90 P a r t B: Rhodasurf 25-7 MEA sxs P a r t C : Co lo ran t Perfume Water

Ktft

30 .0 8 . 0

17.0

8.0 2.0 6.0

0.02-1 0.1 -0 .5

Q.S.

Procedure:

add C a l s o f t F-90. Mix P a r t "B" i n t h e o rde r l i s t e d . Add "A" t o " B " . Add c o l o r a n t , perfume and water . Ad jus t pH t o 11.0.

Phys i ca l P r o p e r t i e s :

D i s s o l v e Sodium C i t r a t e i n Water by s t i r r i n g a t 45-50C and

p H : 11.0 pH (1% S o l u t i o n ) : 9 .50 S p e c i f i c G r a v i t y : 1.120 V i s c o s i t y : 75 cps

Formula LY-0043

A n i o n i c/Noni o n i c Heavy-Duty Laundry Detergent

Pa r t A: Water Na C i t r a t e C a l s o f t F-90 P a r t B: Rhodasurf 25- MEA sxs Par t C : Co lo ran t Perfume Water

7

Wt.%

3 0 . 0 8 . 0

17 .0

8 . 0 2.0 6 . 0

0.02-1 0 .1 - 0 . 5

Q . S .

Procedure:

C a l s o f t F-90. Mix P a r t "B" i n t h e o rde r l i s t e d . Add "A" t o " B " . Add c o l o r a n t , perfume and water . Ad jus t pH t o 11.0.

D i s s o l v e Sodium C i t r a t e i n water by s t i r r i n g a t 45-50C, add

Formula LY-0044

SOURCE: Rhone-Poulenc: Suggested Formula t ions

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11 4 Advanced Cleaning Product Formulations

C h l o r i n e D r y B leach- I

CDB Clearon STPP Sodi urn s u l f a t e

C h l o r i n e D r y B leach- I1

CDB 90 STPP Sodi urn metasi 1 i c a t e , anhydrous Sodi urn s u l f a t e

Note: These a r e f o r 16% a v a i l a b l e c h l o r i n e bleaches.

Sour - I

Sodi urn o r ammoni urn b i f 1 u o r i de Sodi urn o r ammoni urn s i 1 i c o f 1 u o r i de

Sour - I1

Sodi urn o r ammoni urn b i f 1 u o r i de Sodium o r ammonium s i l i c o f l u o r i d e

Oxvnen S a f e t y D r y B leach- I

Sodi urn perborate-H20 STPP Soda ash

Oxyaen S a f e t y D r y B leach- I1

Sodi urn pe rbo ra te t e t r a h y d r a t e STPP Soda ash

2 8% 5-20

balance

18% 5-20

5 balance

2 5% 75

50% 50

3 5% 0-40

balance

50% 0-40

ba lance

Note: These a r e f o r 5.5% a c t i v e oxygen bleaches.

SOURCE: FMC Corp.: Detergent A p p l i c a t i o n s B u l l e t i n No. 4 : Suggested Formula t ions

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Laundry Products 115

Cold Water Detergent (For Wool and D e l i c a t e F a b r i c s )

Water M i rano l CS Conc. Rhodapex ES-2 A1 kami de DC-212 F luorescent Whi ten ing Agent

Wt.% 55.9 10 .0 30.0

4 . 0 0 . 1

Procedure:

c l e a r .

Phys ica l P r o p e r t i e s :

Add i n g r e d i e n t s i n o rde r l i s t e d . Heat t o 50C and mix u n t i l

Appearance: C lea r , y e l l o w l i q u i d pH, as i s : 8 . 1 6 S p e c i f i c G r a v i t y : 1.02 V i s c o s i t y : 700 cps

Formula LY-0040

F i n e F a b r i c Deterqent

Rhodacal OS- 10 Sodium Hexametaphosphate Sodi um B icarbonate O p t i c a l B r i ghtener

Wt.% 32.0 30.0 38 .0

Q . S .

Procedure:

t o t h e b lender . Mix f i v e minu tes . Add t h e Rhodacal DS-10 w i t h m ix ing . Add t h e o p t i c a l b r i g h t e n e r w i t h m ix ing . Mix u n t i l un i fo rm.

Phys ica l P r o p e r t i e s :

Add t h e sodium b i ca rbona te and t h e sodium hexametaphosphate

Appearance: White, f r e e - f l o w i n g powder pH, 1% S o l u t i o n : 8 .5

Formula LY-0041

SOURCE: Rhone-Poulenc: Suggested Formula t ions

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116 Advanced Cleaning Product Formulations

Commerci a1 Laundry Formulations Phosphated a1 ka l i o r bui 1 der

Caustic soda, f l a k e STPP Sodium m e t a s i l i c a t e anhydrous CMC A l i p h a t i c so lvent (dedust ing) Soda ash

Tal low Soap Detergent L i s h t Duty

Tallow soap (Hi t i t e r ) Soda ash Sodium metas i l i ca te , anhydrous Opt ica l b r i ghtener A l i p h a t i c so lvent (dedust ing)

Heavy Duty

Tal low soap ( H i t i t e r ) Sodi urn metasi 1 i cate, anhydrous Caust ic soda, f l a k e

B u i l t Deterqent ( L i g h t D u t a

Anionic CMC Foam Stabi 1 i zer STPP Opt ica l br ightener Noni oni c Soda ash

Bui 1 t Detersent (Heavy Duty)

20-30% 15 10

0- 2 4

balance

3 5% 59 5

0-1 1

2 0% 40 40

20% 1 1

15 0.1 3

balance

Soda ash Nonionic (h igh foam) Anionic Sodi urn metasi 1 i cate. Anhydrous Caustic soda, f l a k e Opt ica l b r i gh tener CMC STPP

SOURCE: FMC Corp.: Detergent App l i ca t i ons B u l l e t i n No. 4: Suggested Formulations

39.9% 6 3

20 15 0.1 1

15

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Dairy, Food and General Industrial Cleaners 17

Heavy D u t y Cleaners ( I n d u s t r i a l 1 Steam C l eaners-Li au i ds

Water TKPP Potassi um Hydroxide (45%) Starso sodi um s i 1 i c a t e Phosphate e s t e r Octy lpheno l , 7-8 moles EO

Water TKPP Potass i um hydrox ide (45%) Starso sodium s i l i c a t e Phosphate e s t e r C9-C11 1 i n e a r a l coho l , 6 moles €0

Steam Cleaners-Powders

STPP Sodium carbonate C9-C10 l i n e a r a l coho l , 12 moles EO Metso Beads 2040 sodi um metasi 1 i c a t e

STPP CQ-ClO l i n e a r a l coho l , 12 moles EO Sodi urn g l uconate Metso Pentabead 20 sodium m e t a s i l i c a t e

18.8% 17.2% 31.3% 30.0% 2.3% 0.4%

34.1% 17.2% 31 .l% 15.2% 2.0% 0.4%

35% 20% 10% 3 5%

50% 3% 2% 4 5%

SOURCE: PQ Corp.: Detergent Formulary: Suggested Formulat ions

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118 Advanced Cleaning Product Formulations

Enzymatic Heavy-Duty Laundry Detergent

P a r t A: Water C i t r a t e C a l s o f t F-90 Par t B: Rhodasurf 25-7 MEA TEA sxs Rhodapex NA-61 Par t C: Na Formate Calcium Ch lo r ide Enzymes Co loran t Perfume Water

Ett%

10.0 5 .0 8 .0

6.0 2 . 0 2.0 3 .0 8 . 0

1 .2 0.2 0 .4

0.02-1 0.1- 0 .8

Q . S .

Procedure: D isso lve Sodium C i t r a t e i n Water by s t i r r i n g a t 45-50C, add

C a l s o f t F-90. Mix P a r t "B" i n t h e o rde r l i s t e d . Add "A" t o "B". Add Sodium Formate and Calcium Ch lo r ide . Cool t o room tempera- a t u r e . Add t h e enzymes. Add c o l o r a n t , perfume and water . Ad jus t pH t o 10.0. Phys ica l P r o p e r t i e s :

pH: 10 .0 pH (1% S o l u t i o n ) : 8.8 Speci f i c G r a v i t y : 1 . I 0 0 V i s c o s i t y : 100 cps Formula LY-0046

Nonionic/Amphoter ic Heavy-Duty Laundry L i a u i d

Water Glycosides Mi rano l FBS MEA Co loran t Perfume

wt.% Q.S.

20.0 7 . 0 2 .0

0.02-1 0.1- 0 .5

Procedure:

a d d i t i o n . Ad jus t pH t o 11.0. Phys ica l P r o p e r t i 8s:

Add t h e i n g r e d i e n t s i n t h e o rde r l i s t e d . Mix w e l l a f t e r each

pH: 11.0 pH (1% S o l u t i o n ) : 9.50 S p e c i f i c G r a v i t y : 1.100 V i s c o s i t y : 300 cps Formula LY-0045

SOURCE: Rhone-Poulenc: Suggested Formula t ions

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Laundry Products 119

F i n e F a b r i c Handwash

I n q r e d i en t : Water SXS (40%)

Add, mix w e l l C-12 D i e thano l ami de ( 100%)

Add, mix w e l l COCO D i e thano l ami de (80%)

Add, mix w e l l Tomah Amphoteric N

Add, mix w e l l C i t r i c A c i d

D isso lve , a d j u s t t o p H 7.00 NaCl*

D i sso l ve

W B 37.00 15.00

2.00

3 .00

18.00

q .s .

Q . S .

SpG 20/20C: 1 .04 pH: Ad jus t t o 7.0 w i t h c i t r i c a c i d Recommended D i l u t i o n s : 1 oz. g a l A p p l i c a t i o n s : Viscous h i g h q u a l i t y handwash Notes: V i s c o s i t y 45 cps ( B r o o k f i e l d RVT 100 rpm s p i n d l e #3)

*Add more NaCl t o i nc rease v i s c o s i t y Formula L-108

Low Temperature Powder Detergent

I n q r e d i e n t : Na M e t a s i l i c a t e Anhydrous Soda Ash

Mix i n powder b lender TKPP

Mix i n powder NaOH

Mix i n powder T r i t o n DF-12

Add i n conven Tomah Amphoteric

Add i n conven

b lender

b lender

e n t manner 400 e n t manner

Recommended D i l u t i o n s : 2-4 o z / g a l l o n Appl i c a t i ons: HSC, Degreaser Notes: Good de te rgen t even a t temps <35C

Formula LF-100

SOURCE: Tomah Products, I n c . : Suggested Formula t ions

W t % 35.00 25.00

20.00

15.00

2.50

2.50

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120 Advanced Cleaning Product Formulations

Heavy Duty Laundry Detergent High Sudsing

STPP Hydrous Sodium S i l i c a t e * Ani on i c Foam s t a b i 1 i zer CMC O p t i c a l b r i g h t e n e r S a l t cake

Low Sudsing

STPP Hydrous Sodi um S i 1 i c a t e * Nonionic CMC O p t i c a l b r i g h t e n e r S a l t cake

* S i l i c a t e s l e s s a l k a l i n e than m e t a s i l i c a t e .

Cold Water Wool Detersient

Hexaphos STPP An ion ic (40% a c t i v e ) CMC S a l t cake

35-50% 10-15 15-20 2- 5

0.5- 1 .0 0 . 2 - 0 .8

balance

35-50% 10-15 8-10 0.5-1.0 0.2-0.8

balance

30% 10 35

balance 0.5

Heavy Duty L i sui d Laundry Deteraent

Water CMC 50% KOH 39.4% Potassium s i l i c a t e s o l u t i o n Water 1 S t a b i l i z e r AS€-108 ) p reb lend 60% TKPP s o l u t i o n Noni on i c O p t i c a l b r i g h t e n e r

Add i n o rder l i s t e d w i t h v igorous

19.8% 0 .5 2.2

12.7 6.5 6.5

41 .7 10.0 0.2

a g i t a t i o n

SOURCE: FMC Corp.: Detergent A p p l i c a t i o n s B u l l e t i n No. 4 : Suggested Formula t ions

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Laundry Products 121

Heavy Duty Laundry, L i q u i d

I n n r e d i en& Pct. Water 30.10 50% Sodi urn Hydroxide 4.60 D i e thano l ami ne 5 . 0 0 P i l o t SXS-40 25.00 Cal s o f t LAS-99 30.00 C a l o x y l a t e N-9 5 . 0 0 Procedure: 1. Combine t h e water , 50% NaOH, and DEA i n t h e r e a c t o r . 2 . Turn on t h e s t i r r e r , and mix t h e i n g r e d i e n t s . 3 . S t a r t t h e LAS-99 a d d i t i o n . Add o n l y 50% o f t h e S u l f o n i c Ac id . 4. Add t h e C a l o x y l a t e N-9 t o a i d i n f l u i d i z i n g t h e n e u t r a l i z a t i o n

5 . F i n a l pH shou ld be 8.0. Ad jus t w i t h 50% NaOH o r LAS-99. r e a c t a n t s .

Formula No. HDL-005-01

L i q h t Duty L i q u i d Detergent

I n g r e d i e n t : Water

Pet. 26.26 . ~-

P i l o t SXS-40 12.53 C a l s o f t L-40 44.93 Cal foam EA-603 10.00 Calamide C 5.99 C i t r i c A c i d 0.19 Dye & Perfume 0.10 Procedure: 1 . Charge t h e water and SXS-40 t o t h e r e a c t o r . Turn on t h e

2 . Add t h e C a l s o f t L-40 t o t h e water and SXS-40 w h i l e mix ing . 3. Add t h e Calfoam EA-603 t o t h e r e a c t o r and con t inue mix ing . 4 . Add t h e Calamide C t o t h e f i r s t f o u r (4 ) i n g r e d i e n t s . 5 . C i t r i c A c i d i s added t o make minor adjustments i n l ower ing

6 . F i n a l pH=6.6-7.2

s t i r r e r .

t h e pH.

Formula No.: LDL-005-1

Heavy Duty Laundry. L i q u i d

I n a r e d i e n t : Calsuds A C a l o x y l a t e N-9 P i l o t SXS-40 Procedure:

Wi th m ix ina . add t h e C a l o x v l a t e N-9 and SXS-40 t o t h e

Pet. 71.43 21.43

7.14

-. Calsuds A .

Warming t h e i n g r e d i e n t s t o 80-1OOF w i l l a i d i n b lend ing . Formula No. HDL-003-1

SOURCE: P i 1 o t Chemical Co. : Suggested Formula t ions

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122 Advanced Cleaning Product Formulations

Heavy-Duty L i a u i d Laundry Deteraent

Mazer Macol 25 Carboxymethyl C e l l u l o s e Potassium Hydroxide (50% s o l u t i o n ) Tetrapotassium Pyrophosphate (60% s o l u t i o n ) V i n y l E thy l -Ma le i c Anhydride Copolymer* Sodi um Metasi 1 i c a t e Water

Wei nh t /% 10.0% 0.6% 4.0%

36.0% 0.6% 5.8%

43.0%

* Gantrez AN-149 (GAF) o r e q u i v a l e n t

Procedure: Mix t h e water, 0.01% o f t h e Macol 25 s u r f a c t a n t and t h e

Gantrez AN-149 ( i n t h a t o rde r ) w i t h g e n t l e a g i t a t i o n . Heat t h i s m ix tu re t o 176F and ma in ta in f o r 20-30 minutes, u n t i l i t becomes ve ry f l u i d . Wi th g e n t l e a g i t a t i o n , s l o w l y add t h e potassium hydrox ide s o l u t i o n . When t h i s m i x t u r e i s homogeneous, con t inue s t i r r i n g and d i s s o l v e t h e Carboxymethyl Ce l l u lose . Next add t h e sodium m e t a s i l i c a t e . Cool t h e m i x t u r e t o 140F and w i t h v igorous a g i t a t i o n , add t h e ba lance o f t h e s u r f a c t a n t . Cont inu ing t h e v igo rous a g i t a t i o n , r a p i d l y add t h e t e t r a p o t - ass i um s o l u t i o n (pre-heated t o 140F). O p t i c a l b r i g h t e n e r s , perfumes and dyes may be added immediately and t h e v igorous a g i t a t i o n cont inued f o r f i v e (5) minutes . The f i n a l p roduc t may be coo led and withdrawn i n t o s u i t a b l e con ta ine rs .

Heavy-Duty Powdered Laundry Deteraent

Mazer Macol 25 Carboxymethyl C e l l u l o s e Sodi um Tr ipo lyphosphate Sodium M e t a s i l i c a t e , Anhydrous Powder* Sodium S u l f a t e , B r igh teners , E t c .

* Na20:Si02 r a t i o 1:2-1:2:4, 80-85% s o l i d s

Wei nh t /% 12% 2%

3 4% 8%

4 4%

SOURCE: PPG I n d u s t r i e s , I n c . : Suggested Formula t ions

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Laundry Products 123

Heavy D u t y L i q u i d Laundry Formula-5 I n g r e d i en ts : G1 ucopon AV-110 S u l f o t e x SXS Monoethanol ami ne Water Typi c a l P r o p e r t i es :

S o l i d s , %: 33 Ac t i ves , %: 25 pH, as i s : 11-12 V i s c o s i t y , cps (2.32): 150-250

Heavy D u t y L i q u i d Laundry Formula-6 I n g r e d i e n t s : G I ucoDon AV-110 S u l f o t e x sxs Non ion ic S u r f a c t a n t * Monoethanol ami ne Water Typi c a l P r o p e r t i es :

S o l i d s , %: 32 Ac t i ves , %: 25 pH, as i s : 11-12 V i s c o s i t y , cps (25C) : 150-250

Heavy Duty L i qu i d Laundry Formul a-7 I ngred i en t s : G1 ucopon A V - 1 1 0 S u l f o t e x SXS Nonionic Sur fac tan t * Monoethanol ami ne Water Typ ica l P r o p e r t i e s :

S o l i d s , %: 32 Ac t i ves , %: 25 pH, as i s : 11-12 V i s c o s i t y , cps (25C): 150-250

Heavy D u t y L i qui d Laundry Formul a-8 I n g r e d i e n t s : Glucooon AV-110 S u l f o t e x sxs Non ion ic Sur fac tan t * Monoethanol ami ne Water Typi c a l P r o p e r t i es :

S o l i d s , %: 32 Ac t i ves , %: 25 pH, as i s : 11-12 V i s c o s i t y , cps (25C): 150-250

*Tryco l 5963, T ryco l 6964

W S 5 0 . 0 8.0 3 .0

39.0

W S 40.0

6 . 0 5.0 3 .0

46.0

Wt% 30.0 7.0

10.0 3.0 50.0

Wt% 25.0 8.0

12.5 3.0

61.5

SOURCE: Henkel Corp. : Glucopon Sur fac tan ts : Suggested Formulas

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124 Advanced Cleaning product Formulations

Heavy-Duty Phosohate Free Laundry Powder-A

Mazer Macol 25 Soda Ash, L i g h t , Anhydrous Sodium M e t a s i l i c a t e , L i q u i d Carboxymethyl C e l l u lose Sodi um S u l f a t e , B r igh tener , E tc .

Heavy-Duty Phosphate Free Laundry Powder-B

Mazer Macol 25 Soda Ash, L i g h t , Anhydrous Sodium M e t a s i l i c a t e , Anhydrous Powder Carboxymethyl C e l l u lose Sodium S u l f a t e , B r igh tener , E tc .

Wei Q h t f % 12% 65% 2 0%

2% 1%

Wei sh t /% 12% 50% 16%

2% 2 0%

Note: A l l f o rmu la t i ons should be sub jec ted t o s to rage t e s t s under v a r i o u s temperature and humid i t y c o n d i t i o n s .

Concentrated L i q u i d Laundry Deteraent

Avanel S-70 Mazer Macol 25 Mazer Macol 45 Mazer Macol 48 Mazer Macol 41 Dye Fragrance

SOURCE: PPG I n d u s t r i e s , I n c . : Suggested Formula t ions

Wei ah t /% 50.0% 25.0% 10.0% 7.0% 8.0% q . s . q . s .

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Laundry Products 125

I n d u s t r i a l and I n s t i t u t i o n a l Deterqent Concentrate-Formulat ion A

I n g r e d i e n t s : water Acusol 820 S t a b i l i z e r (30%) NPElO Sodium Hydroxide, (50%)

B r o o k f i e l d V i s c o s i t y , cp fj 12 rpm: 300 Appearance: Cloudy

%- as supp 1 i ed 8 2 . 5

2 . 5 5

10

I n d u s t r i a l and I n s t i t u t i o n a l Deteraent Concentrate-Formulat ion B

I ngred i en t s : water Acusol 820 S t a b i l i z e r (30%) NPElO Sodi urn Hydroxide, (50%)

B r o o k f i e l d V i s c o s i t y , cp @ 12 rpm: 900 Appearance: Cloudy

% as Syppl i ed 7 6 . 7

3 . 3 10 10

I n d u s t r i a l and I n s t i t u t i o n a l Deteraent Concentrate-Formulat ion C

I n Q r e d i e n t s : Water Acusol 820 S t a b i l i z e r (30%) NPElO Sodi um Hydroxide, (50%)

% as Supp l ied 66.7

3 . 3 10 20

B r o o k f i e l d V i s c o s i t y , cp fj 12 rpm: 600 Appearance: Opaque

M i x i n g I n s t r u c t i o n s :

s u r f a c t a n t w i t h adequate m ix ing . Add Acusol 820 s t a b i l i z e r f i r s t t o t h e water , t hen add t h e

S lowly add c a u s t i c s o l u t i o n w i t h adequate m ix ing .

SOURCE: Rohm and Haas C o . : ACUSOL 820 S t a b i l i z e r : Suggested Formula t ions

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126 Advanced Cleaning Product Formulations

I n d u s t r i a l Laundry Powder Uni forms

Sodi um Carbonate Igepa l CO-660 Sodium Tr ipo lyphosphate Sodium M e t a s i l i c a t e O p t i c a l B r igh tener

Wt.% 52.5 15 20 12

0 . 5

Procedure:

CO-660. Add t h e remaining i n g r e d i e n t s i n t h e order l i s t e d . Mix u n t i 1 un i fo rm.

Phys ica l P r o p e r t i e s :

Add t h e Sodium Carbonate t o t h e mixer . Spray on t h e Igepa l

Appearance: White, f r e e - f l o w i n g powder pH, 1% S o l u t i o n : 11.4

Formula LY-0050

I n d u s t r i a l Laundry Powder Ho te l L inen S u m l y

Sodi um Carbonate Igepa l CO-630 Igepa l CO-710 Sodium Tr ipo lyphosphate C a l s o f t F-90 Sodi um Hydroxide O p t i c a l B r igh tener

Wt.% 46.5

3 3

30 2

15 0 .5

Procedure: Add t h e Sodium Carbonate t o t h e mixer . Spray on t h e Igepa l

CO-630 and CO-710. Add t h e remaining i n g r e d i e n t s i n t h e order l i s t e d . Mix u n t i l un i fo rm.

Physi c a l Proper t i 8s : Appearance: White, f r e e - f l o w i n g powder pH. 1% S o l u t i o n : 13.0

Formula LY-0051

SOURCE: Rhone-Poul enc: Suggested Formula t ions

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Laundry Products 127

I n d u s t r i a l Laundry Two-Part Svstens Un i fo rms (Petroleum Greases and O i l s )

Pa r t A : I gepa l CO-660 C a l s o f t F-90 Water P a r t 0: Sodium S i l i c a t e (Si02/Na20 1.6-2.5)

H o t e l / L i nen Supply (Animal and Veaetable Grease)

Par t A : I gepa l CO-660 C a l s o f t F-90 Water P a r t 0 : Potassium Hydroxide (45%) STPP, TKPP o r KTPP

Formula LY-0052

Wt.%

8 2

90

100

Wt.%

10 2

88

85 15

I n d u s t r i a l Laundry One-Shot L i q u i d

Wt.% Water 69 Igepa l CO-630 3 I g e p a l CO-710 3 Cheel ox BF-13 10 Potassium Hydroxide (45%) 10 M i rano l FBS 5

Procedure: Add t h e i n g r e d i e n t s i n t h e o rde r l i s t e d . Mix u n t i l un i fo rm.

Phys i ca l P r o p e r t i e s : Appearance: C lea r l i q u i d pH, as i s : 13.0 pH, 1% S o l u t i o n : 11.8 S p e c i f i c G r a v i t y : 1 .06 V i s c o s i t y : t 1 0 cps

Formula LY-0049

SOURCE: Rhone-Poulenc: Suggested Formula t ions

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128 Advanced Cleaning Product Formulations

___- Laundry A1 k a l i B u i l d e r s Powders- -1ndust r i i l S U P ~ ~ y

Moderate A1 k a l i n i t y

Sodium carbonate STPP Nonylphenol , 9-10 moles EO Sodi um s u l f a t e P o l y v i n y l p y r r o l i d o n e CMC Metso Beads 2048 sodium m e t a s i l i c a t e

L i q u i d s __- Linen SueeLy

N C lear sodium s i l i c a t e Potassium hyd rox ide (45%)

N C lear sodium s i l i c a t e Potass i um hyd rox ide ( f 1 ake) Water

N C lear sodium s i l i c a t e Sodi um hyd rox ide beads ("PELS") Potass i um hyd rox ide ( f 1 ake) Water

I n d u s t r i a l SuDPly

D sodium s i l i c a t e Water

N C lear sodium s i l i c a t e Sodium hyd rox ide (50%)

20% 15% 12% 16%

1% 1%

35%

62% 38%

52% 37% 11%

52% 14% 28%

6%

90% 10%

88% 12%

SOURCE: PQ Corp.: Detergent Formulary: Suggested Formula t ions

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Laundry Products 129

Laundry Deterqent, I and I - U n b u i l t ( L i Qu id )

S o i l - A c i d i c food f a t , o i l and grease Sur face - Cotton, c o t t o n / p o l y e s t e r , p o l y e s t e r A p p l i c a t i o n Method - I n d u s t r i a l washing machine Manufacture - Mix tank w i t h p r o p e l l e r s t i r r e r

ComDosi t i on A : %&

F1 uorescent B r igh tener 0 .2 Water Balance

Nonylphenoxy Po lye thoxyethano l , 9-10 Moles EO 20-30 A l k y l a r y l S u l f o n i c Ac id (98%) 5-10 Sodium Hydroxide (50%) (Add t o pH) 6-8

Composi t i o m Water F luorescent B r igh tener Nonylphenoxy Po lye thoxyethano l , 9-10 Moles EO Coconut D i e thano l ami de

%A Balance

0.2 20-30

5-1 0

Use D i l u t i o n : L i g h t Soi 1 : 0.06% by we igh t o r 4 oz per 100 l b s laundry Medium S o i l : 0.06% - 0.12% by we igh t o r 4-0 ozs per 100 l b s

Heavy S o i l : 0.12% -0.25% by we igh t o r 8-16 oz per 100 l b s

Note: Use laundry de te rgen t , u n b u i l t i n c o n j u n c t i o n w i t h laundry

1 aundry

1 aundry

b u i l d e r , s i l i c a t e d (bo th l i n e n and i n d u s t r i a l ) a t 1 p a r t bw de te rgen t t o 2-4 p a r t s b u i l d e r s o l u t i o n .

Laundry Detergent - L inen Supply (Powder, Low A1 ka l i n i ty)

S o i l - A c i d i c food f a t , o i l and grease; b lood, sebum and body

Sur face - Cot ton and c o t t o n / p o l y e s t e r A p p l i c a t i o n Method - I n d u s t r i a l washing machine Manufacture - Ribbon o r paddle b lender

waste

Composit ion: B r i t e s i l H20 20.0 STPP Sodium Carbonate Nonylphenoxy Po lye thoxyethano l , 9-10 Moles EO Sodi um S u l f a t e Carboxymethy lce l lu lose (CMC) Sodi um A1 k y l a r y l Sul f ona te Powder (90%)

26.0 28.0 10.0 10.0 2.0 4.0

Use D i l u t i o n : L i g h t S o i l : 0.25% by we igh t o r 1 l b per 100 l b s laundry Medium S o i l : 0.50% by we igh t o r 2 l b s per 100 l b s laundry Heavy S o i l : 0.75% by we igh t o r 3 l b s per 100 l b s laundry

SOURCE: The PQ Corp . : Suggested Formula t ions

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130 Advanced Cleaning Product Formulations

Laundry Deterqents (Consumer) Dry Blended

B r i t e s i l C24 hydrous p o l y s i l i c a t e STPP Sodium carbonate C12-Cl5 l i n e a r a l c o h o l , 7 moles €0 Sodi um s u l f a t e CMC LAS O p t i c a l b r i g h t e n e r , Perfume

PhosDhorous-Free

V a l f o r 100 Z e o l i t e A B r i t e s i l C24 hydrous p o l y s i l i c a t e Sodium carbonate P o l y a c r y l a t e (MW 4500-5500) C12-Cl5 1 i n e a r a l coho l , 7 moles €0 LAS CMC O p t i c a l b r i g h t e n e r Sodi um s u l f a t e

A g ~ l omerated

STPP Sodi um carbonate E r i t e s i 1 C24 hydrous p o l y s i 1 i c a t e Sodium s u l f a t e LAS A 2447 sodium s i l i c a t e

Low Phosphorous (Economy)

V a l f o r 100 Z e o l i t e A Sodi um carbonate STPP Sodium s u l f a t e LAS A 2447 sodium s i l i c a t e

2 0% 30% 10.5%

4% 2 4%

1% 10%

0.5%

30% 7%

15% 1% 4%

10% 1% 0.5%

31.5%

30% 15% 10% 31% 7% 7%

20% 2 5% 5% 36%

7% 7%

SOURCE: PQ Corp.: Detergent Formulary: Suggested Formula t ions

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Laundry Products 131

.- Laundr- ~ De terqeLts (Consumer) [Cont inued) Aqqlomerated (Cont inued)

.(Premium) V a l f o r 100 Z e o l i t e A STPP Sodium carbonate CMC Sodium s u l f a t e LAS C12-Cl5 l i n e a r a l c o h o l , 7 moles EO A 2447 sodium s i l i c a t e

Phosphorous-Free .fEconomy) V a l f o r 100 z e o l i t e A- Sodi um carbonate Sodium s u l f a t e LAS P o l y a c r y l a t e (MW 4500) C12-C15 1 i near a l c o h o l , 7 moles EO A 2447 sodium s i l i c a t e

(Premi um) V a l f o r 100 z e o l i t e A Sodi um carbonate CMC Sodi um s u l f a t e P o l y a c r y l a t e (MW 4500) LAS C12-Cl5 l i n e a r a l c o h o l , 7 moles EO A 2447 sodium s i l i c a t e

2 7% 5%

10% 1%

2 9% 12% 6%

10%

2 5% 2 5% 35.5% 5% 0.5% 2% 7%

30% 15%

1% 22.5%

0 .5% 10% 11% 10%

SOURCE: PQ Corp . : Detergent Formulary: Suggested Formula t ions

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132 Advanced Cleaning Product Formulations

Laundry Formulas Restaurant/Hotel Laundry I

I n q r e d i en t : Water STPP

KOH (45%)

Nonionic Surfactant-HLB 13

Tomah Amphoteric 400

D isso lve , mix w e l l

Add, mix w e l l

Add, mix w e l l

Add, mix u n t i l c l e a r pH: 13.50 Recommended D i l u t i o n s : 1/4-1/2 cup A p p l i c a t i o n s : Res taurant /ho te l l aundry

Formula L-1 00

Restaurant/Hotel Laundry I1 I n a r e d i en t : Water STPP

Potassi um s i 1 i c a t e

KOH (45%)

Non ion ic Surfactant-HLB 13

Tomah Amphoteric 400

D i sso l ve

Add, mix w e l l

Add, mix w e l l

Add, mix w e l l

Add, mix w e l l pH: 13.50 Recommended D i l u t i o n s : 1/4-1/2 cup A p p l i c a t i o n s : Res taurant /ho te l l aundry

Formula L-101

W B 45.00

5.00

30.00

10.00

10.00

W B 40.50

5.00

4.50

30.00

10.00

10.00

Concentrated PresDot te r I n n r e d i e n t : Wt% C12-15 a l coho l e thoxy l a t e (3EO) 10.00 C12-15 a l coho l e t h o x y l a t e (7EO) 10.00

Mix w e l l

M ix w e l l

M ix w e l l

Add s low ly , m ix ing w e l l pH: n e u t r a l Recommended D i l u t i o n s : as necessary A p p l i c a t i o n s : pump spray p r e s p o t t e r Notes: Use o f de tergent quaternary g r e a t l y improves per -

Tomah (2-17-2 3.00

Exxon I sopar G 20.00

Water 10.00

formance o i l y so i 1 s Formula L-102

SOURCE: Tomah Products, I n c . : SUQQeSted Formula t ions

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Laundry Products 133

Laundry Powder Detergent

Sodi um Carbonate C a l s o f t F-90 Rhodapex NA-61 Rhodasurf 25-7 Sodi um Metasi 1 i c a t e Pentahydrate Sodium S u l f a t e Zeol i t e Sodi um Perbora te Enzymes can be added Dye Perfume

Procedure: Add t h e Sodium Carbonate t o t h e m ixe r . Spray on t h e

Rhodapex NA-61 and t h e Rhodasurf 25-7. Add t h e remain ing i n g r e d i e n t s i n t h e o rde r l i s t e d and mix u n t i l un i fo rm.

Wt.% 44.0 1 4 . 0

6 . 0 2 . 0 4 . 0

1 0 . 0 18 .0

2 .0

Phys ica l P r o p e r t i e s : Appearance: White, f r e e - f l o w i n g powder, dyed t o p re fe rence pH, 1% S o l u t i o n : 11

Formula LY-0047

Non-Phosphate Laundry Powder

Sodium Carbonate Igepa l CO-630 Sodi um S i 1 i c a t e Sodium S u l f a t e Carboxymethylcel l u l o s e O p t i c a l B r i g h t e n e r

Wt.% 50 .0 1 2 . 0 12 .0 24.5

1 . o 0 . 5

Procedure: Add t h e Sodium Carbonate t o t h e m ixe r . Spray t h e Igepa l

CO-630 on to t h e Sodium Carbonate. Add t h e remain ing i n g r e d i e n t s i n t h e o rde r l i s t e d . Mix u n t i l a homogeneous, f r e e - f l o w i n g p roduc t r e s u l t s .

Phys i ca l P r o p e r t i e s : Appearance: White, f r e e - f l o w i n g powder pH, 1% S o l u t i o n : 1 1 . 0

Formula LY-0048

SOURCE: Rhone-Poulenc: Suggested Formula t ions

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134 Advanced Cleaning Product Formulations

L i q u i d Commercial Laundry Deteraents

Acusol 820 s t a b i l i z e r i s usefu l i n prepar ing l i q u i d deter- gent systems on su r fac tan t /bu i l de r mix tures. I n these form- u l a t i o n s i t can f u n c t i o n i n e i t h e r o f two ways:

* To prov ide s t a b i l i z a t i o n or suspension o f nonion ic sur- f ac tan ts i n b u i l t l i q u i d systems o f low v i s c o s i t y .

o r * To prov ide th i cken ing t o g i ve h i g h l y v iscous o r g e l l e d

formulat ions.

I n d u s t r i a l and I n s t i t u t i o n a l Deteraent Concentrates Formul a t i on A

I ngredi ent s : Water Acusol 820 S t a b i l i z e r (30%) NPElO Sodium Hydroxide, (50%)

Brook f ie ld V iscos i t y , cp @ 12 rpm: 300 Appearance: c loudy

Formulat ion B

Ingredients : Water Acusol 820 S t a b i l i z e r (30%) NPElO Sodium Hydroxide, (50%)

B r o o k f i e l d V iscos i t y , cp @ 12 rpm: 900 Appearance: cloudy

Formulation C

Inq red i ents : Water Acusol 820 S t a b i l i z e r (30%) N P E 10 Sodium Hydroxide, (50%)

B r o o k f i e l d V iscos i t y , cp I3 12 rpm: 600 Appearance: opaque

% as suppl ied 8 2 . 5

2 . 5 5

10

% as suppl ied 76.7 3.3

10 10

% as suppl ied 66.7 3.3

10 20

MiXing I n s t r u c t i o n s :

su r fac tan t w i t h adequate mixing.

SOURCE: Rohm and Haas Go.: Acusol 820 S t a b i l i z e r : Suggested

Add Acusol 820 s t a b i l i z e r f i r s t t o t h e water, then add t h e

Slowly add caus t i c s o l u t i o n w i t h adequate mixing.

Formulations

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Laundry Products 135

L i o u i d Laundry/Ani on i c Phosphate Free I n q r e d i e n t : Water EDTA (40%)

Add, mix w e l l Na c i t r a t e (87%)

D isso lve Ethanol

Add, mix w e l l Propy l ene g l y c o l

Add, mix w e l l ODBSA, Na s a l t (60%)

Add, mix w e l l A lcoho l e t h e r s u l f a t e 4E0 (60%)

Add, mix w e l l FWA (CBS-X, Ciba-Geigy) 5% s tock s o l ' n

P red isso lve i n water t o make s tock s o l ' n Non ion ic Surfactant-HLB 13

Add, mix w e l l Tomah Amphoteric N

Add, mix w e l l Protease-Novo Nord isk ( o p t i o n a l )

Add, mix w e l l pH: 8.00 Ad jus t t o pH 8 .0 Recommended D i l u t i o n s : 1/2 cup A p p l i c a t i o n s : Household laundry

Formula L-105

L i q u i d Laundry/Nonionic Phosphate Free

I n s r e d i e n t : Dei on i zed water EDTA (40%)

Mix w e l l Sodi um c i t r a t e

Add, mix w e l l Ethanol

Add, mix w e l l Non ion ic Surfactant-HLB13

Add, mix w e l l Tomah Amphoteric N

Add, mix w e l l FWA (CBS-X, Ciba-Geigy) 5% s tock s o l ' n

P red isso lve i n water t o make s tock s o l ' n Propylene g l y c o l

Add, mix w e l l Protease. Novo Nord isk ( o p t i o n a l )

Add, mix w e l l pH: 8.00 a d j u s t t o pH 8 . 0 Recommended D i l u t i o n s : 1/2 cup Appl i c a t i ons: Household

Formula L-106

SOURCE: Tomah Products, I n c . : Suggested Formula t ions

K% 26.60 7.50

8.00

5.00

5.00

13.30

9 .60

10.00

4.00

5.00

6.00

W t % 43.50

5 .00

3.50

7.00

15 .00

5.00

10.00

5.00

6.00

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136 Advanced Cleaning Product Formulations

L i a u i d Laundry Detergents Anionic & Nonionic

Water Glucopon 600 CSUP Ethanol Sul f o tex 6040s

Water Glucopon 600 CSUP Ethanol Trycol 5963

Water Sodi urn C i t r a t e Sul fo tex SXS 40 Glucopon 600 CSUP Ethanol Sul fo tex 6040s

Water Sodium C i t r a t e Sul fo tex SXS 40 Glucopon 600 CSUP Ethanol Trycol 5963

A l l Nonionic

Anionic (L Nonionic w i t h Bu i l de r

Nonionic w i t h B u i l d e r

W a 62 10 3

25

72 10

3 15

!tL% 32

5 5

15 5

38

42.5 5.0

10.0 15.0 5.0

22.5

Procedure:

using moderate a g i t a t i o n . Incorporate c o l o r and fragrance as needed.

SOURCE: Henkel Corp.: Sugqested Formulations

Add i n t h e order 1 i sted, d i s s o l v i ng each i ngredi ent completely

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Laundry Products 137

L i q u i d Laundry Deterqents (Based on Added Value Sur factant Concentrates)

Premium HDL

Water Sul fo tex SXS 40 G l ucopon AV-110 Monoethanolamine

Water Sul fo tex SXS 40 G1 ucopon AV-110 Monoethanol ami ne

Water Sul fo tex SXS 40 G1 ucopon AV-110 Trycol 5963 Monoethanol ami ne

G1 ucopon AV-110 Sul fo tex SXS 40 Trycol 5963 Monoethanol ami ne

Economv HDL

Concentrate w i t h Noni oni cs

U l t r a Hiqh A c t i v e

W U 1

16 80

3

W U 55

2 40

3

W U 50

7 30 10

3

80 2

15 3

Procedure:

us ing moderate a g i t a t i o n . Incorporate c o l o r and fragrance as needed.

SOURCE: Henkel Corp.: Suggested Formulations

Add i n t h e order 1 i sted, d i s s o l v i ng each i ngredi ent completely

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138 Advanced Cleaning Product Formulations

L i qu i d Laundrv/Noni on i c PhosDhate Ina red i ent : Ethanol FWA (Tinopal CBS-X)

Add, mix we l l Dei oni zed Water

Add, mix w e l l Nonionic Surfactant-HLB 13

Add, mix w e l l TKPP

D i ssol ve Tomah Amphoteric N

Add, mix we l l Propyl ene G1 ycol

Add, mix we l l Tomah Q-17-2

Add, mix w e l l Protease (Opt ional )

Add, i f desired, mix we l l Water

Add, m i x w e l l pH: 8 . 0 0 Adjust t o pH 8 Recommended D i l u t i o n s : 1/2 cup App l i ca t i ons : Household laundry Notes: Use o f detergent quaternary g r e a t l y improves

ance on o i l y s o i l s Formula L-103

Inaredi ent : Deionized Water TKPP

Dissolve Ethanol

Add, mix w e l l Propyl ene g l yco l

Add, mix w e l l DDBSA. Na S a l t (60%)

Add, mix w e l l Alcohol Ether S u l f a t e 4E0 (60%)

Add, mix we l l -ad jus t t o pH 8 . 0 FWA (CBS-X, Ciba-Geigy) 5% stock s o l ' n

Predissolve i n water t o make stock s o l ' n Nonionic Surfactant-HLB 13

Add, mix w e l l Tornah Amphoteric N

Add, mix w e l l Protease, Novo Nordisk ( o p t i o n a l )

Add, mix w e l l Water

Add, mix w e l l pH: 8 . 0 0 Recommended D i l u t i o n s : 1/2 cup Appl icat ions: Household

L i q u i d Laundrv/Anionic Phosohate

Formula L-107 SOURCE: Tomah Products, Inc. : Suggested Formulations

g 10.00 0.50

45.00

15.00

4.00

5.00

5.00

1 .oo

6.00

q.s.

perform-

-% 31.60 10.00

5.00

5.00

13.30

9.60

10.00

4.00

5.00

6.00

q.s.

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Laundry Products 139

Oxygen S a f e t y Dry B leach- I

Sodium pe rbo ra te t e t r a h y d r a t e 20-35% Sodium t r i p o l y p h o s p h a t e 0-35 An ion ic o r non ion i c 0- 3 O p t i c a l b r i g h t e n e r 0- 0.3 F i l l e r (soda ash, sodium s u l f a t e , sesqu icarb . , e t c . ) balance

Oxygen Sa fe ty Dry B leach - I1

Sodium pe rbo ra te monohydrate 1 5 2 5 % Sodium t r i p o l y p h o s p h a t e 0-35 An ion ic o r non ion i c 0- 3 O p t i c a l b r i g h t e n e r 0- 0 . 3 F i l l e r (soda ash, sodium s u l f a t e , sesqu icarb . , e t c . ) balance

Deterqent S a n i t i z e r - I *

CDB Clearon STPP Sodium m e t a s i l i c a t e (anhydrous) An ion i c (85% a c t i v e ) S a l t cake

Detergent San i t i ze r -11*

CDB Clearon STPP An ion ic (85% a c t i v e ) S a l t cake Soda ash

*EPA Reg is te red sani t i ze rs

SOURCE: FMC Corp.: Detergent A p p l i c a t i o n s B u l l e t i n No. 4 : Suggested Formula t ions

5.6% 35

5 5

49.4

18% 25

3 29 25

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140 Advanced Cleaning R&ct Formulations

Super Concentrate Laundry L i q u i d

I n g r e d i e n t : W t . % (as i s ) 01 Water 37.5 B io -Sof t S-100 5.00 Tr ie thano lamine (99%) 0.12 Carbopol 2201 (30% a c t i v e ) 3.50 Propyl ene G1 yco l 5.00 Makon 10 20.00 Tr ie thano lamine (99%) 7.88 Standapol ES-3 16.00 Sodi um C i t r a t e 1 .oo Opaci f i e r O i spe rs i on (25%) 4.00 Dye (FO&C B lue #1, Red #33) q . s .

Procedure: 1. Combine Bio-Soft S-100 (Na-LAS) w i t h 01 water. N e u t r a l i z e

2. Add Carbopol 2201 w h i l e mix ing . 3. A d d p ropy lene g l y c o l t o t h e m ix tu re . 4. Add Makon 10 (nony l phenol e thoxy la te , 10 €0) t o t h e m i x t u r e

5. F u l l y n e u t r a l i z e t h e s o l u t i o n w i t h t h e remaining TEA. 6 . Warm t h e m i x t u r e t o 50C. Slowly add t h e Standapol ES-3 w h i l e

7. Add sodium c i t r a t e and mix u n t i l d i sso l ved . 8. Combine one p a r t o p a c i f i e r w i t h t h r e e p a r t s water . Add t h i s

V i s c o s i t y : 600-800 cPs pH: 8.3-8.8

s l i g h t l y w i t h TEA. Mix u n t i l homogeneous.

under a g i t a t i o n .

mix ing . Cont inue m ix ing u n t i l un i fo rm.

d i s p e r s i o n t o t h e m ix tu re . S lowly coo l m i x t u r e t o room temperature.

* Carbopol r e s i n p rov ides s t a b i l i t y w i t h o u t a f f e c t i n g perform-

* Easy-f 1 owi ng rheol ogy * Carbopol r e s i n s a r e a l s o s u i t a b l e f o r h i g h l y - b u i l t systems

9. Add dye and f ragrance as des i red . C h a r a c t e r i s t i c s :

ance o f t h i s concent ra ted fo rmula

SOURCE: B.F. Goodrich Co.: CARBOPOL High Performance Polymers: Suggested Formula t ions

Laundry Deteraents I n d u s t r i a l and I n s t i t u t i o n a l

L i aui d- (Di s p e r s i on 1 Water STPP Potassi um hydrox ide (45%) Kasi 1 #6 po tass i um s i 1 i c a t e LAS

Water Potassium hydrox ide (45%) STPP

L i a u i d - (Sol u t i on)

69% 17%

1.6% 7.4% 5%

69.0% 1.6%

17.0% Kasi 1 #6 po tass i um s i 1 i c a t e 7.4% LAS 5.0% SOURCE: PQ Corp.: Detergent Formulary: Suggested Formulas

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Laundry Products 141

U n b u i l t Laundry Deternent-A

ComDonents: Water Sodium carbonate Sodium xy lene s u l f o n a t e (40%) Ethanol Non ion ic s u r f a c t a n t :

Hostapal N 090 An ion ic Su fac tan t :

L i near a1 k y l s u l f o n a t e (60%)

Physi c a l P roper t i es : Appearance (25C): c l e a r Dens i t y ( 1 b /ga l ) : 8 . 9 pH (l%, 25C): 10.6 Ross M i l e s (49C, 1%, cm):

1 m i n . : 19 5 min. : 19

Cloud p o i n t ( l % , C) : > l o 0 Sur face t e n s i o n (0.25%, dynes/cm): 32.8 V i s c o s i t y , B r o o k f i e l d (25C, LV#l, 100 rpm, cps ) : 118 Freeze thaw s t a b l e f r e e z i n g p o i n t (C) : D i d n o t f r e e z e

U n b u i l t Laundry Detergent-B

ComDonents: Water Sodium carbonate Sodium xy lene carbonate (40%) Ethanol Non ion ic s u r f a c t a n t :

Genapol UD 079 An ion ic s u r f a c t a n t :

L i near a1 k y l s u l f o n a t e (60%)

Phys ica l P r o p e r t i e s : Appearance (25C): c l e a r Dens i t y ( l b / g a l ) : 8 .8 pH ( l % , 25C): 10.3 Ross M i l e s (49C, 1%’ cm):

1 m in . : 12 5 min . : 5

Cloud p o i n t ( l % , C ) : > l o 0 Sur face t e n s i o n (0.25%, dynes/cm): 29.2 V i s c o s i t y , B r o o k f i e l d (25C, LV #1, 100 rpm. c p s ) : 68 Freeze thaw s t a b l e f r e e z i n g p o i n t (C) : D i d n o t f r e e z e

W t . % 45

2 15

2

28

8

W t . % 40

2 14

2

33

9

Procedure:

components i n t h e g i ven o rde r w i t h cont inuous s t i r r i n g .

SOURCE: Hoechst Celanese Corp.: Suggested Formula t ions

D i s s o l v e sodium carbonate i n water and add t h e remain ing

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142 Advanced Cleaning Product Formulations

U n b u i l t Laundry Detergent-C

Components: Water Sodium carbonate Sodium xylene su l fona te (40%) Ethanol Nonionic su r fac tan t :

Genapol UD 030 Genapol UD 079

Physical Proper t ies: Appearance (25C): c l e a r Densi ty (1 b/gal ) : 8.7 pH (l%, 2%): 10.6 Ross M i les (49C, 1%, cm):

1 min.: 14 5 min.: 3

Cloud p o i n t ( l % , C ) : 53 Surface tens ion (0.25%, dynes/cm): 27.3 Viscos i t y , B r o o k f i e l d (25C. L V # l , 100 rpm. cps): 44 Freeze thaw s t a b l e f reez ing p o i n t (C): Did not f reeze

U n b u i l t Laundry Deterpent-D

Components: Water Sodium carbonate Sodi um x y l ene su l fonate (40%) Ethanol Nonionic su r fac tan t :

Hostapal N 090 Hostapal N 040

Physical Proper t ies: Appearance (25C): c l e a r Densi ty ( l b / g a l ) : 8.9 pH (l%, 25C): 10.3 Ross M i les (49C, 1%. cm):

1 min.: 3 5 min.: 3

Cloud p o i n t ( l % , C ) : 21 Surface tens ion (0.25%, dynes/cm): 29.9 Viscos i t y , B r o o k f i e l d (25C, L V # l , 100 rpm. cps): 194 Freeze thaw s tab le : f reez ing p o i n t ( C ) : Did no t f reeze

W t . % 47 2 15 2

6 28

W t . % 48 2 14 2

27 7

Procedure:

components i n t h e given order w i t h continuous s t i r r i n g .

SOURCE: Hoechst Celanese Corp.: Suggested Formulations

Dissolve sodium carbonate i n water and add t h e remaining

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Laundry Products 143

Unbui 1 t Laundry L i q u i d -A

Components: Water Ethanol Potass i um ch 1 o r i de T r i e thano l ami ne Noni o n i c s u r f a c t a n t :

Hostapal N 090 An ion ic s u r f a c t a n t :

L inea r a1 k y l s u l f ona te (60%)

Phys i ca l P r o p e r t i e s : Appearance (25C): c l e a r Dens i t y ( 1 b /ga l ) : 8.8 pH (l%, 25C): 9 .5 Ross M i l e s (49C, 1%, c m ) :

1 min . : 19 5 min . : 11

Cloud p o i n t ( l % , C) : > l o 0 Sur face t e n s i o n (0.25%, dynes/cm): 33.51 V i s c o s i t y , B r o o k f i e l d (25C, LV#l, 100 rpm, cps ) : 343 Freeze thaw s t a b l e : f r e e z i n g p o i n t (C) : tO

Unbui 1 t Laundry L i qui d-B

ComDQnents: Water Ethanol Potassium c h l o r i d e T r ie thano lamine Non ion ic s u r f a c t a n t :

Genapol UD 079 An ion ic s u r f a c t a n t :

L inea r a1 k y l s u l f o n a t e (60%)

Phys i ca l P r o p e r t i e s : Appearance (25C): c l e a r Dens i t y ( 1 b /ga l ) : 8 .6 pH (l%, 25C): 9 .5 Ross M i l e s (49C, 1%. cm):

1 m i n . : 12 5 min . : 4

Cloud p o i n t (l%, C): > l o 0 Sur face t e n s i o n (0.25%. dynes/crn): 29.85 V i s c o s i t y , B r o o k f i e l d (25C, LV#1, 100rpm. cps: 94.7 Freeze thaw s t a b l e : f r e e z i n g p o i n t (C) : tO

Wt, 41

5 1 3

35

15

W t . % 37

5 1 3

39

15

Procedure:

con t inuous s t i r r i n g , a t 75-8OF.

SOURCE: Hoechst Celanese Corp.: Suggested Formula t ions

Blend t h e components one a t a t i m e i n t h e g i ven order w i t h

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144 Advanced Cleaning Product Formulations

Unbui 1 t Laundry L i a u i d-C

Components : Water Ethanol Potassi um c h l o r i d e T r i ethanol ami ne Non ion ic s u r f a c t a n t :

Genapol 26-L-60 An ion ic - s u r f a c t a n t :

L inear a l k y l su l

Phys ica l P r o p e r t i e s Appearance (2%) Densi t v (1 b / a a l )

onate (60%)

c l e a r ge l 14.8

PH (1%; 25cjT 9;2 Ross M i l e s (49C, 1%, cm):

1 min . : 20 5 min. : 15

Cloud p o i n t (l%, C): > l o 0 Sur face t e n s i o n (0.25%. dynes/cm): 32.90 V i s c o s i t y , B r o o k f i e l d (25C. LV#1, 100 rpm, cps ) : 272 Freeze thaw s t a b l e : f r e e z i n g p o i n t (C): 13

Unbui It Laundry L iau id -0

Components: Water Ethanol Potassium c h l o r i d e Tr ie thano lamine Nonionic s u r f a c t a n t :

Genapol 26-L-60 An ion ic s u r f a c t a n t :

L inear a l k y l s u l f o n a t e (60%)

Phys ica l P roper t i es : Appearance (25C): c l e a r Dens i t y ( 1 b /ga l ) : 14.8 pH (l%, 25C): 9 .2 Ross M i l e s (49C, 1%, cm):

1 min. : 19 5 min . : 17

Cloud p o i n t (l%, C ) : > l o 0 Surface t e n s i o n (0.25%, dynes/cm): 33.47 V i s c o s i t y , B r o o k f i e l d (25C, LV#1, 100 rpm, cps) : 403 Freeze thaw s t a b l e : f r e e z i n g p o i n t (C): 12

W t . % 44 5 1 3

28

19

W t . % 40 5 1 3

30

21

Procedure:

cont inuous s t i r r i n g , a t 75-8OF. Formula t ion D remains a f r e e f l o w i n g l i q u i d a t 51% t o t a l s u r f a c t a n t concen t ra t i on .

SOURCE: Hoechst Cel anese Corp. : Suggested Formula t ions

Blend t h e components one a t a t i m e i n t h e g i ven order w i t h

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9. Metal Cleaners and Polishes

145

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146 Advanced Cleaning Product Formulations

A c i d Cleaner

Rhodafac RE-610 Igepa l CO-630 Phosphoric Acid, 75% Water

3.0 4.0

10.0 83.0

Procedure: Add Phosphoric Ac id t o Water and heat w i t h a g i t a t i o n t o 50C.

w i t h r a p i d b u t smooth a g i t a t i o n , s l o w l y b lend i n Rhodafac RE-610 and Igepa l GO-630. Once system i s comple te ly un i fo rm, coo l w i t h s t i r r i n g t o 40-45C, and package.

Physical P roper t i es : Appearance: S l i g h t l y hazy l i q u i d pH, as i s : 1 .6 S p e c i f i c G r a v i t y : 1.03 V i s c o s i t y : 20 cps

Formula BC-0004

Hiqh-Foaminq A c i d Scrubber*

Mi rano l FBS Igepa l CO 630 Sul famic Ac id G l y c o l i c (Hydroxyacet ic ) Ac id (70%) Butoxyethanol Water

Wt.% 5 . 0 2 . 0 4.0 4.0 3 .0

82 .0

Procedure: Add t h e water, su l fam ic and g l y c o l i c ac ids . Mix u n t i l

d i sso l ved . Add t h e remaining i ng red ien ts , w i t h m ix ing . Mix u n t i 1 un i fo rm.

Phys ica l P r o p e r t i e s : Appearance: C1 ear 1 i qu i d pH, as i s : 1 .5 Speci f i c G r a v i t y : 1 .027 V i s c o s i t y : < l o cps

* S u i t a b l e f o r a p p l i c a t i o n s w i t h a t r i g g e r - t y p e sprayer .

Formula BC-0003

SOURCE: Rhone-Poulenc: Suggested Formula t ions

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Metal Cleaners and Polishes 147

Ac id Metal Cleaner No. 392*

Veegum 0 . 8 A Rhodopol 23 0 . 4

Water 72.1

Monazol i ne CY 0.8 Hamp-ene 100 0 . 9

B Phosphoric a c i d 15.0 Super F loss 10.0

Procedure: Blend Veegum and Rhodopol. S lowly add t o t h e water w h i l e

ag i t a t i ng a t maxi mum avai 1 ab le shear. Cont i nue m i x i ng u n t i 1 smooth. Add €3 i n g r e d i e n t s i n o rde r , m ix ing w e l l a f t e r each a d d i t i o n u n t i l smooth and un i fo rm ( a v o i d i n c o r p o r a t i o n o f a i r ) . Consistency: White pourab le 1 i q u i d . Suggested Packaging: P l a s t i c squeeze b o t t l e w i t h p recaut ionary

l a b e l l i n g f o r a c i d . D i r e c t i o n s For Use:

Pour smal l amount on damp c l o t h or sponge and c lean a r t i c l e w i t h moderate rubb ing . Rinse w i t h water and d r y . Th i s fo rmula may be used on most nonfer rous meta ls i n c l u d i n g copper, brass, s t a i n l e s s s t e e l and aluminum. Comments:

and p rov ides a s t a b l e , f r e e f l o w i n g c leaner w i t h good c l i n g t o v e r t i c a l su r face . Veegum i s p r o t e c t e d aga ins t f l o c c u l a t i o n i n t h i s pH 1 compos i t ion th rough base exchange w i t h t h e im idazo l i ne Hamp-Ene 100 f a c i l i t a t e s t h i s exchange. The t r e a t e d Veegum and Rhodopol p rov ide s y n e r g i s t i c t h i c k e n i n g w i t h b e t t e r v i s c o s i t y s t a b i l i t y and i n h i b i t i o n o f syne res i s than i s p o s s i b l e w i t h e i t h e r t h i c k e n e r alone. Super F loss d i a t o m i t e a l l ows good c l eansi ng and p o l i sh i ng.

The combinat ion o f Veegum and Rhodopol suspends t h e abras ive

* U.S. Pa ten t No. 4,302,253

A c i d Cleaner No. 288

Van Gel ES 1 . o A Rhodopol 23 0.5

Water 86.5 B Phosphor ic a c i d 10.0 C T r i t o n X-100 2.0 Procedure:

a g i t a t i n g a t maximum a v a i l a b l e shear. Cont inue m ix ing u n t i l smooth. Add B t o A w h i l e m ix ing . Add C t o A/B and mix u n t i l smooth and un i fo rm. Consi s tency : Pourabl e 1 i qu id . Suggested Packaging: P l a s t i c squeeze b o t t l e w i t h p recaut ionary

Comments: The Van Gel ES/Rhodopol combinat ion a d j u s t s t h e

Blend Van Gel ES and Rhodopol. S lowly add t o t h e water w h i l e

l a b e l l i n g f o r ac id .

v i scos i t y and p rov ides good v e r t i c a l su r face c l i ng. Thi s bas i c fo rmula can be used as a s t a r t i n g p o i n t f o r a bowl c leaner o r metal c leaner .

SOURCE: R.T . V a n d e r b i l t Co.: Suggested Formula t ions

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148 Advanced Cleaning Product Formulations

Aluminum Br iah tener - I I n Q r e d i ent : Water

Wt% 83.00

Phosphoric Acid (85%) 3.00

C i t r i c Acid, Anhydrous 4.00

Ethylene g l yco l b u t y l e ther 5 . 0 0

Nonionic Surfactant-HLB 13 3.00

Tomah Q-17-2 2.00

Add slowly, mix we l l

D i ssol ve

Mix w e l l , u n t i l c l e a r

Mix w e l l , u n t i l c l e a r

Mix w e l l , u n t i l c l e a r SpG 2 0 / 2 0 C : 1.03 pH: 1.27 Recommended D i l u t i o n s : 5-1O:l Appl icat ions: Spray app l i ca t i ons f o r t rucks and equipment

Soak tank a p p l i c a t i o n f o r equipment/parts

Aluminum Br iah tener - I1 Ina red i ent : W B Water 80.50 Hydroxyacetic Ac id (70%) 10.00

Add slowly, mix w e l l

Mix we1 1, u n t i 1 c l e a r

Mix w e l l , u n t i 1 c l e a r

Mix w e l l , u n t i l c l e a r SpG 20/20C: 1.02 pH: 1.60 Recommended D i l u t i o n s : 5-1O:l Appl icat ions: Spray app l i ca t i ons f o r t rucks and equipment

Ethylene g l y c o l b u t y l e ther 5 . 0 0

Nonionic Surfactant-HLB 13 2.50

Tomah Q-17-2 2.00

Soak tank a p p l i c a t i o n f o r equipment/parts

A1 umi num B r i ahtener-111 Inn red i ent : Wt% Water 82.50 Hydroxyacetic Ac id (70%) 5 . 0 0

C i t r i c A c i d , Anhydrous 3.50

Ethylene g l y c o l b u t y l e ther 5 . 0 0

Nonionic Surfactant-HLB 13 2.00

Tomah Q-17-2 2.00

Add slowly, mix w e l l

D i ssol ve

Mix w e l l , u n t i 1 c l e a r

Mix w e l l , u n t i l c l e a r

Mix w e l l , u n t i 1 c l e a r SpG 20/20C: 1.02 pH: 1.67 Recommended D i l u t i o n s : 5-1O:l Appl icat ions: Spray app l i ca t i ons f o r t r u c k s and equipment

Soak tank a p p l i c a t i o n f o r equipment/parts SOURCE: Tomah Products, I nc . : Formula S-113

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Metal Cleaners and Polishes 149

A1 umi n u m C1 e a n x

Water Butoxyethanol M i rano l CS Conc. Phosphor ic Acid, 75% Ammoni um B i f 1 u o r i de

Wt.% 27.0 10.0 10.0 50 .0

3 .0

Procedure: Blend i n g r e d i e n t s i n o rde r l i s t e d and m i x u n t i l un i fo rm.

Phys ica l P r o p e r t i e s : Appearance: C lea r , y e l l o w l i q u i d pH, as i s : 1 .0 S p e c i f i c G r a v i t y : 1.24 V i s c o s i t y : <10 cps

Formula MC-0102

A1 uni nun C1 eaner

M i rano l FBS Cheel ox BF-Aci d Butoxyethanol Phosphoric Ac id (85%) Hydro f 1 u o r i c Aci d (70%) Water

Wt.% 5 . 0 1 . o 6.0

38.0 8 . 0

42.0

Procedure:

w i t h a g i t a t i o n . Mix u n t i l un i fo rm.

Phys i ca l P r o p e r t i e s :

Add t h e water, s t a r t t h e m ixe r . Add t h e remain ing i n g r e d i e n t s

Appearance: Hazy 1 i qu i d pH, as i s : 3 . 6 0 S p e c i f i c G r a v i t y : 1 .22 V i s c o s i t y : t 20

Formula MC-0063

SOURCE: Rhone-Poulenc: Suggested Formula t ions

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150 Advanced Cleaning Product Formulations

A1 u m i num C1 eaner

Mi rano l FBS Sodium M e t a s i l i c a t e , Pentahydrate Water

Procedure: Add water, s t a r t t h e mixer . Add t h e sodium m e t a s i l i c a t e

and mix u n t i l d i sso l ved . Add t h e M i rano l FBS and mix u n t i l un i fo rm.

Phys ica l P r o p e r t i e s : Appearance: C lear , ye l l ow l i q u i d pH, as i s : 12.75 S p e c i f i c G r a v i t y : 1 . 0 2 V i s c o s i t y : t 1 0 cps

Formula MC-0064 ,

Wt.% 10.0 5.0

8 5 . 0

A1 umi num C1 eaner

Wt.% Mi rano l FBS 3 .5 Igepa l CA-630 Tetrapotassium Pyrophosphate Sodium M e t a s i l i c a t e Pentahydrate Carbi t o 1 Water

1 . 5 5 . 0 1 . o 3.0

86.0

Procedure:

and TKPP and mix u n t i l d i sso l ved . Add t h e remaining i n g r e d i e n t s and mix u n t i l un i fo rm.

Phys ica l P r o p e r t i 8s:

Add t h e water, s t a r t t h e m ixe r . Add t h e sodium m e t a s i l i c a t e

Appearance: C lear , l i g h t y e l l o w l i q u i d pH, as i s : 12.55 S p e c i f i c G r a v i t y : 1.05 V i s c o s i t y : < l o cps

Formula MC-0065

SOURCE: Rhone-Poulenc: Suggested Formula t ions

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Metal Cleaners and Polishes 151

Aluminum Cleaner Concent ra te F-498

Water Sodium M e t a s i l i c a t e (Anhydrous) T e t r a Potassium Pyrophosphate (Powder) Mona NF-10

% B y Wei s h t 7 5 10

5 10

Procedure:

i n water w i t h mix ing , then add Mona NF-10.

Typi c a l P r o p e r t i es : Appearance: C1 ear 1 i qu i d Cloud P o i n t : 88C

Recommended Use D i l u t i o n : 1 t o 4 o z / g a l .

D i s s o l v e sodium metasi 1 i c a t e and t e t r a potassium pyrophosphate

Aluminum Wash F-499

Water Sodium M e t a s i l i c a t e (Anhydrous) T e t r a Sodium Pyrophosphate (Powder) B u t y l Carbi t o 1 Mona NF-10

% By Weight 88

2 3 2 5

Procedure:

i n water , t hen add B u t y l C a r b i t o l and Mona NF-10.

Typ ica l P r o p e r t i e s :

D isso lve sodi um metasi 1 i c a t e and t e t r a sodi um pyrophosphate

Appearance: C lea r l i q u i d pH: 1 2 . 8

Recommended Use D i 1 u t i on: 1 : 10 w i t h water

SOURCE: Mona I n d u s t r i e s , I n c . : Suggested Formula t ions

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152 Advanced Cleaning Product Formulations

Aluminum Cleaner/Polish. S o f t Paste

Inqredients : (1 ) Odor1 ess Kerosene ( 2 ) Duomeen TDO (3) Kaopol i te SF o r 1168 (4) Bentone 34 ( 5 ) T e r g i t o l NP-10 (6) Methanol

% bv Weisht 57.5

1 .o 26.5 10.3 1.3 3.4

Procedure:

thoroughly dispersed. When (6) i s added, t h e f l u i d system w i l l change i n a few minutes t o a s o f t paste.

each product used.

ab le ingredients .

Comments:

wipe w i t h a damp c l o t h . Product may be used w i t h f i n e s tee l wool i f t h e aluminum i s heav i l y weathered.

e ra tu re range. For more f l u i d product, omit (4) and ( 6 ) , o r use l esse r q u a n t i t i e s , keeping 3 : l r a t i o , t o g i ve des i red consi stency . p o l i s h i n g a c t i o n t o t h e formulat ion.

Combine f i r s t f i v e i ng red ien ts w i t h i n t e n s i v e a g i t a t i o n u n t i l

Follow recommended handl ing p r a c t i c e s o f t h e supp l i e rs o f

Good i n d u s t r i a l p rac t i ces should be used when handl ing flamm-

A f t e r rubbing t o s u f f i c i e n t l u s t e r , f l u s h o f f w i t h water, o r

Consistency o f t h i s product i s r a t h e r s tab le over wide temp-

Use o f Kaopol i te 1168 g ives more aggressive c leaning and

S i l v e r Pol ish, S o f t Paste

Ina red i ents : (1) Miranol DM (2) Kaopol i te SF

% by Wei qht 50 50

Procedure: Charge 40 p a r t s o f (1) t o s u i t a b l e paste mixer. Run mixer

cont inuously w h i l e adding (2). w i t h f u r t h e r small increments o f (1) i f necessary, t o avoid over loading t h e mixer d r i ve ; t h e ob jec t i s t o blend a t heaviest p r a c t i c a b l e consistency t o prov ide thorough d ispers ion. Continue mixing u n t i l f u l l y d i spersed and smooth.

each product used.

SOURCE: Kaopol i te, I n c . : Suggested Formulations

Follow recommended handl ing p rac t i ces o f t h e supp l i e rs o f

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Metal Cleaners and Polishes 153

A1 umi num Cleaner/Pol i sh, S o f t Paste

I n g r e d i e n t s : ( 1 ) Odor1 ess Kerosene ( 2 ) K a o p o l i t e SFO-NP ( 3 ) Bentone 34 ( 4 ) T e r g i t o l NP-10 ( 5 ) Methanol

% by Weiqht 58 .5 26 .5 10.3 1.3 3 . 4

Procedure: Combine f i r s t f o u r i n g r e d i e n t s w i t h i n t e n s i v e a g i t a t i o n

u n t i l t ho rough ly d ispersed. When ( 5 ) i s added, t h e f l u i d system w i l l change i n a few minutes t o a s o f t pas te .

Fo l l ow recommended hand l i ng p r a c t i c e s o f t h e s u p p l i e r s o f each produc t used.

Good i n d u s t r i a l p r a c t i c e s shou ld be used when hand l i ng flammable i n g r e d i e n t s .

Comments :

o r wipe w i t h a damp c l o t h . Product may be used w i t h f i n e s t e e l wool i f t h e aluminum i s h e a v i l y weathered.

Consistency o f t h i s p roduc t i s r a t h e r s t a b l e over wide temperature range. For more f l u i d p roduc t , omi t (3 ) and ( 5 ) , o r use l e s s e r q u a n t i t i e s , keeping 3 : l r a t i o .

A f t e r rubb ing t o s u f f i c i e n t l u s t e r , f l u s h o f f w i t h water,

Tarn ish-Retardant S i l v e r Po l ish. S o f t Paste

I nsred i en t s : ( 1 ) De ion ized Water ( 2 ) Nat roso l 250-LR ( 3 ) Ta rn i sh Retardant ( 4 ) B r i j 30 (5) K a o p o l i t e SF ( 6 ) K o r t h i x ( 7 ) Methyl p-hydroxybenzoate

% by Weisht 69.4

1 . o 5 .0 5 . 0

14 .5 5 . 0 0.1

Procedure: Mix ( 2 ) i n t o ( 1 ) . Separa te ly , d i s s o l v e ( 3 ) i n ( 4 ) , w i t h

s l i g h t warming i f necessary, t hen add t o p rev ious m ix tu re . W i t h i n t e n s i v e a g i t a t i o n , add (5 ) , t hen (S), c o n t i n u i n g a g i t a - t i o n u n t i l w e l l d i spe rsed and smooth. Add ( 7 ) as p r e s e r v a t i v e .

each p roduc t used.

SOURCE: Kaopo l i t e , I n c . : Sugegsted Formula t ions

Fo l l ow recommended hand l i ng p r a c t i c e s o f t h e s u p p l i e r s o f

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154 Advanced Cleaning Product Formulations

F i n e Brass P o l i s h

Ina red ien ts : ( 1 ) Deionized Water ( 2 ) Sodium Hexametaphosphate, anhydrous (3 ) K o r t h i x ( 4 ) Kaopo l i t e SF ( 5 ) B io -Sof t S-100 (6 ) Aminoacetic Acid, t e c h n i c a l grade ( 7 ) Propyl ene G1 yco l (8 ) Ammonia Water, 26 Be' (9 ) C o l l o i d 60

% by Weiqht 39.9

0 . 1 2 . 0

25.0 3.0 5 . 0

2 5 . 0 q . s . q . s .

Procedure: D isso lve ( 2 ) i n ( l ) , add (3) and (4 ) s low ly , w i t h v igorous

a g i t a t i o n u n t i l we l l -d i spe rsed and smooth. Reduce a g i t a t i o n t o moderate, add (5), (6 ) , and ( 7 ) , b lend tho rough ly . Cont inu ing moderate a g i t a t i o n , add (8 ) t o pH 8 .5 . About 0.2% o f (9 ) i s e f f e c t i v e , i f needed, t o c o n t r o l foam d u r i n g m ix ing and packagi ng.

each produc t used. Fo l low recommended hand l i ng p r a c t i c e s o f t h e s u p p l i e r s o f

Emu1 s i on Meta l Pol i sh

I n q r e d i e n t s : (1 ) Odor1 ess Kerosene ( 2 ) VM&P Naphtha (3 ) O l e i c Ac id (4) Deionized Water (5) Sodium Hexametaphosphate ( 6 ) Kaopo l i t e SF o r 1168 ( 7 ) Ammonia Water, 26 Be' (8 ) Tr ie thano lamine

% by Weiaht 1 2 . 0 24.0 2.5 43.0

1 .o 1 5 . 0

1 . 9 0.6

Procedure: Disperse (4 ) , ( 5 ) , ( 6 ) , ( 7 ) , and ( 8 ) . Then add t h i s s o l u t i o n

t o t h e o i l phase ( 1 1 , ( 2 ) . and (3), a g i t a t i n g w e l l u n t i l smooth. Fo l low recommended hand l i na p r a c t i c e s o f t h e s u p p l i e r s o f _ . . .

each produc t used.

a b l e i n g r e d i e n t s . Comments :

p o l i s h i n g a c t i o n t o t h i s f o r m u l a t i o n .

SOURCE: Kaopol i t e , I n c . : Suggested Formul a t i on8

Good i n d u s t r i a l p r a c t i c e s should be used when hand

Use o f Kaopo l i t e 1168 g i v e s more aggress ive c lean

i n g flamm-

ng and

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Metal Cleaners and Polishes 155

I r o n PhosDhatins and C lean ing Fo rmu la t i ons -L iqu id Products

1 . H3P04, 75% Sodi um molybdate-2H20 Sur fac tan ts Water

18.3% 1% 2.7%

78.3%

Comment:

systems. pH o f 3% s o l u t i o n : 2.1. B lue a c i d c leaner-phosphat ing system f o r use i n immersion

2. Monosodium orthophosphate (MSP) H3P04, 75% Sodi um molybdate-2H20 Sur fac tan ts Water

Comment: L i q u i d a c i d p roduc t used i n steam phosphators and steam

i n j e c t i o n equipment t o remove heavy s o i l s and depos i t i r o n phosphate c o a t i n g . pH o f 1% s o l u t i o n : 3.55.

12.5% 3% 3% 2.5%

7 9%

3. TKPP, 60% s o l u t i o n Monosodium orthophosphate (MSP) H3P04, 75% Sodi um n i t r a t e Sur fac tan ts Water

10% 10.4% 9.7% 1.2% 3.8%

Balance

Comment :

pH as i s : 3.35. Soak o r spray process, depos i t s 40 Mg / f t 2 i n one minute.

L i q u i d a c i d p roduc t , s l i g h t l y v iscous , f o r i r o n phosphat ing

Steam C1 eaners Powder

STPP Sodium m e t a s i l i c a t e pentahydra te Non ion ic Sodi um g l uconate

L i a u i d

Noni on i c Potassium s a l t o f a non ion i c phosphate e s t e r KOH (45%) Potass i um s i 1 i c a t e TKPP Water

5 0% 45

2 3

2% 6

25 12 12

balance

SOURCE: FMC Corp.: Detergent A p p l i c a t i o n s B u l l e t i n No. 4: Suggested Formula t ions

1

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156 Advanced Cleaning Product Formulations

I r o n PhosDhati nu and Cleani na Formulat i ons-Li au i d Products

A c i d C1 eaners Powder

SAPP Sodium b i s u l f a t e Anionic

Phosphori c Acid (85%) S u l f u r i c Acid (96%) Noni oni c Water

Phosphoric Acid (85%) Buty l Ce l l osol ve Noni oni c Water

L i q u i d - I

L i a u i d - I 1

I n d u s t r i a l Soak Tank Aluminum Cleaner

STPP Sodi um metasi 1 i cate anhydrous Sodium sesquicarbonate Anionic Nonionic

Rust Remover f o r Steel

Phosphoric a c i d (85%) Oxal ic a c i d or c i t r i c a c i d Water

60% 38 2

20% 15 2

balance

3 5% 10-20 0- 2

balance

30% 40-45

20 2- 3 1 - 2

15-20% 3- 5

balance

Deareaser ( f o r enaine b locks a automotive machine Darts)

Anionic TKPP Sodium xylene su l fona te Sodium m e t a s i l i c a t e anhydrous Buty l Ce l l osolve Water

SOURCE: FMC Corp.: Detergent App l i ca t i ons B u l l e t i n No. 4: Suggested Formulations

7% 5 3 7 1

77

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Metal Cleaners and Polishes 157

I r o n Phosphatina and C lean inq Formulat ions-Sol i d Products

Monosorb MSP SAPP Sodium molybdate-2H20 Nonionic s u r f a c t a n t

7 7% 6% 2.5%

14.5%

Comments:

than t h e usual l i g h t b l u e phosphate f i l m ; pH o f 2 oz/gal s o l u t i o n : 3 .5 .

c o l d r o l l e d s t e e l .

Med. temperature (120-14OF); g i ves s l i g h t l y darker c o a t i n g

Use a t 1 1/2-2 oz /ga l i n 3 stage spray system f o r phosphating

Monosorb MSP 71% SAPP 7% Sodi um mol ybdate-2H20 1.5% Sodi um s i 1 i c a t e 1% H y d r o f l u o r i c ac id , 70% 7% Nonionic s u r f a c t a n t 13%

Use b lend o f h i g h and low temperature non ion ics .

Comments:

dus t i ng , removes s o i l , l i g h t o i l , drawing compounds and o the r common contaminants; pH o f 2 oz/gal s o l u t i o n : 3 . 0

Use temperature 130-15OF; f o r m u l a t i o n avoids s t reak ing ,

Use a t 1 1/4-2 oz /ga l . i n 3 stage spray system, ma in ta in ope ra t i ng pH w i t h i n 3.2-4.5; f o r s t e e l , aluminum and ga lvan ized metal phosphat ing.

Monosorb MSP H3P04, 75% SAPP Sodi um Mol ybdate-2H20 Sodi um N i t r a t e Nonionic Sur fac tan t

Comments: Use temperature 130-15OF; produces dense, hard coat

e x c e l l e n t f o r p a i n t adhesion; fo rmula i s pH s t a b l e and 1 onger s e r v i c e .

Use a t 1 1/4-2 oz /ga l i n 3 stage spray system, main pH i n 3.5-4.0 range. Phosphate f i l m i s formed i n 46-60

Some non ion ic s u r f a c t a n t s t h a t can be used i n these

T r i t o n X102 Igepa l CA620 P l u r o n i c F68 P l u r a f a c D25

u l a t i ons :

55% 10% 9% 1%

11% 14%

ng I

o f f e r s

a i n i ng seconds.

form-

SOURCE: FMC Corp.: Detergent A p p l i c a t i o n s B u l l e t i n No. 4: Suggested Formula t ions

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158 Advanced Cleaning Product Formulations

Low Foam Heavy D u t y A1 k a l i n e Cleaner-A

Component: Water Sodium M e t a s i l i c a t e , Pentahydrate Burcene 100 Burcoso lv TM Burco TME Burcowet TM-LF

% bv Weight 58

5 2

10 20

5

Low Foam Heavy D u t y A1 k a l i ne Cleaner-B

Component: Water Sodium M e t a s i l i c a t e , Pentahydrate Sodium Xylene Su l fona tes 40% Burcosolv TM Burco TME Burco LAF-125

% bv Weinh_t 55

5 8 . 5

10 20

5

Procedure:

eous between each a d d i t i o n . Add a l l components i n t h e o rde r l i s t e d . S t i r u n t i l homogen-

Formula t ion A i s low foaming a t temperatures above 160F. Formula t ion B i s low foaming above 1OOF.

Moderate A1 k a l i n i ty , Soi 1 Spl i tti no Soak Cleaner

Components: Water Sodium M e t a s i l i c a t e (Pentahydra te) Tr isod ium Phosphate ( C r y s t a l s ) Burco ADS-40 Burco EHS Burco TME

% by Weight 70

5 10

5 5 5

Procedure: Add components i n t h e order l i s t e d . S t i r u n t i l homogeneous

between each a d d i t i o n .

SOURCE: B u r l i n g t o n Chemical Co., I n c . : Suggested Formula t ions

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Metal Cleaners and Polishes 159

Meta l C1 eaner Formulas L i q u i d A-14

Ma te r i a1 s : Yarmor o r Herco p i n e o i l D res ina te X X Pamak 4 o r 4A Caust ic soda (NaOH) Water

L i q u i d A - 1 5

Mate r ia l s : - Yarmor o r Herco p i n e o i l D res ina te TX Water

Ma te r i a1 s : Yarmor o r Herco p i n e o i l D res ina te X X Soda ash (Na2C03) Sodium orthophosphate (Na3P04-12H20) Water

P a r t s by Weiaht 38 18 10 2

32

P a r t s by Weiqht 38 30 32

Powder A - 1 6

P a r t s by Weiqht 10 10 45 30

5

Method o f P repara t i on : Formula A-14:

r i n g , d i s s o l v e t h e powdered soap i n t h i s m ix tu re ; t hen add t h e c a u s t i c soda d i s s o l v e d i n a l l t h e water . Cont inue s t i r r i n g u n t i l p roduc t i s homogeneous.

Formula A - I S : Heat water t o 50-60C and s l o w l y add t h e Dres ina te TX w i t h

a g i t a t i o n . Then s l o w l y add a p o r t i o n o f t h e p i n e o i l . Mix t h o r - oughly f o r a few minutes and add t h e remain ing p i n e o i l . S t i r u n t i l p roduc t appears un i fo rm.

Formula A - 1 6 :

Slowly add f i r s t t h e p i n e o i l and then t h e water . Cont inue m i 11 i ng u n t i 1 a f r e e - f 1 owi ng powder i s o b t a i ned.

SOURCE: Hercules, I n c . : P ine Oil Formulary

Blend t h e p i n e o i l and Pamak and heat t o 50-60C. Whi le s t i r -

I n a powder m i l l , t ho rough ly mix t h e powdered i n g r e d i e n t s .

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140 Advanced Cleaning Product Formulations

Metal Cleanina ( I n d u s t r i a l 1 Ferrous Metals--Immersion

L i q u i d-Li ght Duty

Water Potassi um hydroxide (45%) Metso Beads 2048 sodium m e t a s i l i c a t e TKPP (60%) Sodi um x y l ene su l fonate (40%) Nonylphenol , 11 -1 3 moles EO

Powder--Heavy Duty

Sodium carbonate TSPP Nonylphenol , 11 -1 3 moles €0 Sodi um g l uconate Metso Beads 2048 sodium m e t a s i l i c a t e Sodi um hydroxide beads ("PELS")

Powder--Medi urn Duty

Sodium carbonate TSP Nonylphenol, 11-13 moles EO Metso Beads 2048 sodium m e t a s i l i c a t e Sodium l i gnosu l fona te Sodi um hydroxide beads ("PELS")

Powder--Light Duty

Sodium carbonate STPP Nonylphenol , 11 -1 3 moles EO Metso Beads 2048 sodi um metasi 1 i c a t e

Ferrous Metals--SPray L iau id- -L ight Duty

Water Phosphate es te r , potess i um s a l t Nonylphenol, 9-11 moles EO Potassi um hydroxide (45%) Star sodi urn s i 1 i ca te Gluconic a c i d (50%)

49% 12% 12% 12% 12% 3%

22% 10% 3% 5%

2 0% 40%

40% 16% 4%

14% 4%

22%

4 5% 2 5%

5% 25%

10.0% 4.5% 1 .O% 38.0% 45.0%

1 . 5 %

Powder--Li aht Duty

Sodi um carbonate 55.0% TSPP 11 .O% C12-Cl3 l i n e a r a lcohol , 1 mole EO 2.0% C12-Cl3 l i n e a r a lcohol , 3 moles EO 2.0%

Sodium gluconate 5.0% Metso Pentabead 20 sodium m e t a s i l i c a t e 2 5%

SOURCE: PQ Corp.: Detergent Formulary: Suggested Formulations

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Metal Cleaners and Polishes 161

Non-Aci d A1 u m i n u m B r i ah tener - I

I n q r e d i en t : Water NTA

KOH (45%)

NaOH (50%)

Non ion ic Surfactant-HLB 13

Tomah A l k a l i S u r f a c t a n t

D i s s o l v e

Add, mix, coo

Add, mix, coo

Add, mix w e l l

Add, mix w e l l

pH: 13.80 Recommended D i l u t i o n s : 5-2O:l A p p l i c a t i o n s : Truckwash, p a r t s wash Notes: Rinse w e l l immediately a f t e r wash

Formula 1-113-1

Non-Aci d A1 umi num B r i qh tener - I I

I n g r e d i e n t : Water EDTA

KOH (45%)

NaOH (50%)

Noni o n i c Surfactant-HLB 13

Tomah A l k a l i S u r f a c t a n t

D i sso l ve

Add, mix, coo l

Add, mix, coo l

Add, mix w e l l

Add, mix w e l l

pH: 13.80 Recommended D i l u t i o n s : 5-2O:l A p p l i c a t i o n s : Truckwash, p a r t s wash Notes: Rinse w e l l immedia te ly a f t e r wash

Formula 1-113-11

SOURCE: Tomah Products, I n c . : Suggested Forrnulat lons

W t % 58.00 10.00

4.00

20.00

2.00

6.00

W t % 58.00 10 .00

4.00

20.00

2.00

6 . 0 0

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162 Advanced Cleaning Product Formulations

Soak-Tank Meta l Cleaner (Powder, For Maanesi u m l

Rhodafac RA-600 Igepa l CO-710 T a l l O i 1 F a t t y Ac id Soap Sodi um T r i polyphosphate Sodium Carbonate ( L t . Dens i t y ) Sodium Hydroxide, Flaked Sodi um Metasi 1 i cate , Anhydrous

Wt.% 5.0 2.0 5 . 0

20.0 18.0 20.0 30.0

Procedure: 1 . Mix Sodium Carbonate, Rhodafac RA-600, Igepa l CO-710 and

T a l l O i l F a t t y A c i d Soap toge the r u n t i l a un i fo rm powdered m ix tu re i s o b t a i ned.

2. Add r e s t o f i n g r e d i e n t s . M ix tho rough ly .

Phys ica l P r o p e r t i 8s: pH ( 7 % ) : 12.8 Speci f i c Gravi t y : 0.98

Formula MC-0068

- HiQh-Temperature Spray Cleaner

Water Sodi um Metasi 1 i ca te , Anh. Tetrapotassium Pyrophosphate, 60% M i r a t a i ne JC-HA Antarox L61 A lcodet MC 2000

Procedure: Add t h e Sodium M e t a s i l i c a t e t o t h e water, w i

u n t i l d i sso l ved . Add t h e remaining i n g r e d i e n t s , t h e o rde r l i s t e d , and con t inue m ix ing u n t i l a c s o l u t i o n r e s u l t s .

Phys ica l P roper t i es : Appearance: C lear , p a l e y e l l o w s o l u t i o n pH, as i s : 12.6 V i s c o s i t y : <20 cps S p e c i f i c G r a v i t y : 1.08

Formula MC-0104

SOURCE: Rhone-Poulenc: Suggested Formula t ions

w l y 73

5 10 5 2 5

h mix ing . Mix w i t h m ix ing i n ear , homogeneous

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Metal Cleaners and Polishes 163

V i scous PhosDhori c/Oxal i c Acid C1 eaner-I

Inqredi en t : Water Phosphoric Acid (75%)

Add, m i x , cool Oxal i c Acid

D i ssol ve Acid Thickener

Add, mix we l l S a l t (NaC1)

D i ssol ve w i t h m i x i ng V iscos i t y (cps) : 693

Viscous Phosphoric/Oxalic A c i d Cleaner- I1

Ing red ien t : Water Phosphoric Acid (75%)

Add, mix, cool Oxal ic Acid

D i ssol ve Aci d Thickener

Add, mix w e l l S a l t (NaCl)

Dissolve w i t h m i x i ng V iscos i t y (cps) : ll?

Viscous Phosphoric/Oxalic Ac id Cleaner-XI1

Ina red ien t : Water Phosphoric Acid (75%)

Abd, mix, cool Oxal ic Acid

D i ssol ve Acid Thickener

Add, m i x w e l l S a l t (NaCl)

D i ssolve w i t h m i x i ng V i s c o s i t y (cps): 2275

w 71 .OO 22.00

1 .oo

3.00

3.00

72.00 22.00

1 .oo

2.00

3.00

w 71 .OO 21 .oo

1 .oo

2.00

5.00

Recommended D i l u t i o n s : 0-1O:l Appl icat ions: Metal c leaning, r u s t removal, descal ing Notes: Mix Acid Thickener p r i o r t o use i n order t o assure

homogenei t y

SOURCE: Tomah Products, I nc . : Formula A-107

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10. Oven, Grill and Hot Plate Cleaners

364

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Metal Cleaners and Polishes 165

A1 urni n u m Cleaner

Mackam 2CSF (Cocoamphodipropionate) Sodium M e t a s i l i c a t e 5H20 Water

Procedure: 1 . Add components t o wa te r . 2 . Heat t o 50 degrees C . and b l e n d u n t i l c l e a r . 3. Cool and f i l l .

G r i 11 Cleaner

Sodium M e t a s i l i c a t e Pentahydrate Mackami ne LO (Laurami ne Oxide) Caus t i c Soda (50%) Sodium Xylene Su l fona te (40%) Te t rasod i um EDTA (40%) De ion ized Water, qs t o

Wei qh t ,% 7 . 5 4 .5 88.0

WeiQht,% 22.0 9.0 2.0 4 . 0 1 .o

100.0

Procedure: 1 . Add Sodium M e t a s i l i c a t e and Tetrasodium EDTA t o water and

2 . Add Mackamine LO and Caus t i c Soda (50%). 3. Add Sodium Xylene Su l fona te u n t i l c l e a r .

heat t o 60 degrees C.

Oven Cleaner

Mackam TM (D ihyd roxye thy l Ta l l ow G l y c i n a t e ) Caus t i c Soda (50%) Water

Wei gh t ,% 5.0

15.0 00.0

Procedure: 1 . Add c a u s t i c soda t o water . 2. Add Mackam TM and b l e n d u n t i l comple te ly d ispersed.

Remark:

t h e Mackam TM.

SOURCE: M c I n t y r e Group L t d . : I n d u s t r i a l Formulary

The v i s c o s i t y can be c o n t r o l l e d by i n c r e a s i n g o r decreas ing

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166 Advanced Cleaning Product Formulatiom

Caus t i c Oven, G r i l l and D r a i n Cleaners

Thickened s o l u t i o n s o f c a u s t i c a re used as oven and g r i l l

Most o f these fo rmu la t i ons can be a p p l i e d e a s i l y by b rush ing c leaners .

o r pump-spraying and do no t run on a v e r t i c a l su r face .

Formul a t i on A

I n q r e d i e n t s : Water Acusol 820 Stab i NPE lO NaOH (50%)

V i s c o s i t y (cp

zer (30%)

#3 s p i n d l e @ 12 rpm): 4300

Formula t ion B

I n a r e d i e n t s : Water Acusol 820 S t a b i l i z e r (30%) NPElO NaOH (50%)

V i s c o s i t y (cp; #3 s p i n d l e @ 12 rpm): 4000

Formula t ion C

I n a r e d i en ts : Water Acusol 820 S t a b i l i z e r (30%) NPElO NaOH (50%)

V i s c o s i t y (cp; #3 s p i n d l e I3 12 rpm): 675

% as supp l i ed 85.75

3.75 0.5

10

% as supp l i ed 75.25

4.25 0.5

20

% as supp l i ed 87.4

2 .5 0.1

10

MiXing I n s t r u c t i o n s : Add i n g r e d i e n t s i n t h e o rde r l i s t e d . Add Acusol 820 t h i c k e n e r t o t h e water and then t h e s u r f a c t a n t

Add c a u s t i c s o l u t i o n s l o w l y w i t h adequate mix ing . I n c r e a s i n g t h e s u r f a c t a n t l e v e l may lead t o p roduc t separa-

w i t h adequate a g i t a t i o n .

t i o n .

Note: A f l o c c u l a n t p r e c i p i t a t e may form upon adding t h e c a u s t i c

s o l u t i o n . The p r e c i p i t a t e i s caused by h i g h l o c a l concentra- t i o n s o f c a u s t i c and disappears a f t e r a few minutes o f a g i t a t i o n .

SOURCE: Rohm and Haas Co.: Acusol 820 S t a b i l i z e r : Suggested Formula t ions

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Metal Cleaners and Polishes 167

Hot P1 a te /Gr i 11 C1 eaner

Sodium M e t a s i l i c a t e , Anhydrous Cheel ox NTA-Na3 Rhodafac RA-600 Alkamide DC-212/S Sodium Xylene S u l f o n a t e (40% a c t i v e ) Sodium Hydroxide Water

Wt.% 22.0

1 . o 7 . 0 2 . 0

10 .0 1 . o

57.0

Procedure: 1 . D i s s o l v e Sodium M e t a s i l i c a t e , Anhydrous i n water . 2 . Add Cheelox NTA-Na3 and Sodium Xylene Su l fona te . Mix t h o r -

3 . Add Rhodafac RA-600, A1 kami de DC-212/5 and Sodi um Hydroxide,

4 . F i l t e r p roduc t .

oughl y .

m i x i n g a f t e r each a d d i t i o n .

Phys ica l P r o p e r t i es : pH, as i s : 13.0 pH (1%) : 11.6 V i s c o s i t y : 40 cps S p e c i f i c G r a v i t y : 1 .08

Formula MS-0076

Oven Cleaner

Rhodapol Veegum Water Sodium Hydroxide (50% a c t i v e ) Rhodafac RA-600

Wt.% 1 . 2 0 . 4

80.4 8.0

1 0 . 0

Procedure: 1 . Heat water t o 85-9OC. Add Veegum and Rhodapol. S t i r f o r one

hour . 2. B r i n g temperatures t o 55C. Add Sodium Hydroxide and Rhodafac

RA-600. Mix tho rough ly .

Phys ica l P r o p e r t i e s : pH (as i s ) : 12 .8 pH (1%) : 10.9 V i s c o s i t y : 830 cps S p e c i f i c G r a v i t y : 1.02

Formula MS-0075

SOURCE: Rhone-Poulenc: Suggested Formula t ions

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168 Advanced Cleaning Product Formulatiom

I n d u s t r i a l Cleaners Oven Cleaner

I n n r e d i en t : Water Sodi um G1 uconate

Add, mix w e l l NaOH ( f l a k e )

D isso lve , coo l Tomah A 1 k a l i Sur fac tan t

Add, mix w e l l Propyl ene G1 yco l

Add, mix w e l l Ethylene Glyco l Monobutyl E ther

Add, mix w e l l Non ion ic Surfactant-HLB 13

Add, mix w e l l pH: 13.10 Recommended D i l u t i o n s : As necessary A p p l i c a t i o n s : Oven, g r i l l c l eaner Notes: E x c e l l e n t on greasy res idues .

Formula 1-115

Wt% 57.00

2.00

20.00

10.00

6.00

4.00

1 .oo

Rinse a f t e r a p p l i c a t i o n .

Thickened A1 k a l i ne Cleaner I n a r e d i en t : Water NaOH ( f l a k e )

Add s low ly , d i sso l ve , coo l Tomah A l k a l i Su r fac tan t

Add. mix w e l l Tomah Amphoteric L

Add, mix w e l l pH: 14.00 Recommended D i 1 u t i ons: as- i s A p p l i c a t i o n s : Brush on g r i l l / o v e n c leaner Notes: #1 V i s c o s i t y @ 20C: 400 cps

Rinse w e l l a f t e r use Formula 1-117

Thickened A1 k a l i ne C1 eaner I n a r e d i e n t : Water NaOH ( f l a k e )

Add s low ly , d i s s o l v e , coo l Tomah A1 k a l i Sur fac tan t

Add, mix w e l l Tomah Amphoteric L

Add, mix w e l l pH: 14.00 Recommended D i l u t i o n s : a s - i s A p p l i c a t i o n s : Brush on g r i l l / o v e n c leaner Notes: #2 V i s c o s i t y @ 20C: 1900 cps

Rinse w e l l a f t e r use Formula 1-118

SOURCE: Tomah Products, I n c . : Suggested Formula t ions

W B 71.50 24.00

3.00

1.50

Wt% 72.00 20.00

5.00

3.00

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11 Polishes, Coatings and Finishes

169

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170 Advanced Cleaning Product Formulations

Aerosol ADD^ i ance P o l i s h

A w a t e r - i n - o i l emulsion p o l i s h which produces a h i g h g loss , no smear, hard f i l m when a p p l i e d t o Formica, as w e l l as most k i t c h e n appl i ances .

The concent ra te f o r m u l a t i o n can be a p p l i e d as a l i q u i d po l i sh. Aerosol Concentrate:

Percent bv Wei qh t P a r t : I n a r e d i e n t s : -_ A 200 S i l i c o n e F l u i d , 350 cs. 4.0

W i tcami de 51 1 1 . o Carnauba Wax #3 1 . o I sopar K 34.0

0 Water 60.0 Suggested Aerosol Formula t ion : I n q r e d i en t : __ Percent by Wei g h t Concentrate CP7-0227 80 Propel 1 an t o f cho ice 20 P repara t i on : 1 . Heat m i x t u r e o f P a r t A i n g r e d i e n t s t o 8OC (176F)--melt wax. 2. Heat water t o 8OC (176F). 3 . Add water s l o w l y t o Par t A m i x t u r e w i t h h i g h speed a g i t a t i o n . 4. Cont inue s t i r r i n g w h i l e c o o l i n g t o room temperature. 5. Package ae roso l .

Formula t ion CP2-0227

Aerosol F u r n i t u r e P o l i s h

Uses a unique b lend o f s i l i c o n e f l u i d s which g i ves t h i s

The concent ra te may be used as a l i q u i d f u r n i t u r e p o l i s h po l i sh exce l 1 en t g loss w i t h m i n i ma1 smear.

o r t o fo rmu la te an aerosol p roduc t . Aerosol Concentrate: P a r t : I n a r e d i e n t s : Percent by Wei q h t

200 S i l i c o n e F l u i d by Dow Corning. 350 cs . 4.0 W i tcami de 51 1 1 .4 L-140 So lvent 14.0 Lemon Fragrance 0 .5

0 C-340 Carnauba Wax Emulsion 16.0 Water 63.1

A 200 S i locone F l u i d by Dow Corning, 10,000 cs . 1 .o

Suggested Aerosol Formula t ion : I n q r e d i en t : E2-7300 Concentrate Aerosol Propel 1 an t

Percent bv Wei s h t 8 0 . 0 20.0

Prepara t ion : 1. Add a l l i n g r e d i e n t s i n P a r t A i n t o vessel w i t h good a g i t a t i o n 2. When P a r t A i s mixed thorough ly , add P a r t B w i t h good a g i t a -

t i o n . Formula t ion E2-7300

SOURCE: Dow Corning Corp.: Suggested Formula t ions

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Polishes, Coatings and Finishes I71

Aerosol F u r n i t u r e P o l i s h

P a r t : A

B

C

Method Mix

ag i t a t wax t o

I n q r e d i en t : 200 F l u i d - 60,000 cs 200 F l u i d - 350 cs W i tcami de 51 1 Stoddard So lvent Lemon Fragrance Stoddard So lvent C-340 Carnauba Wax Emulsion Water Propel 1 an t o f Choi ce

Percent by WeiRht 1.5 4.5 0.8

11.2 0 . 4

18.0 12.8 50.8 20.0

p a r t "A" u n t i l un i fo rm. Add P a r t "B" and mix w i t h good on. Package. Note: For co-wax d i l u t i o n , heat 10 p a r t s 9OC (194F) and heat 90 p a r t s water t o 9OC (194F). Mix

w i t h good a g i t a t i o n .

F u r n i t u r e Pol i sh

P a r t : I n q r e d i en t : A 200 F l u i d - 500 cs

Linseed O i 1 Igepa l CO-520 Stoddard So lvent

8 Water

Percent by Weight 3 9 5

35 48

Method: Add p a r t "B" t o p a r t "A" u s i n g a high-shear mixer .

F u r n i t u r e P o l i s h ( C a t i o n i c Emulsion)

P a r t : I n s r e d i e n t : Percent by Wei s h t A 200 F l u i d - 350 cs 3.00

Carnauba Wax, #1 Ye l low 1.25 Be Square Wax, White 190/195 0.25 Armac-HT 1.25 M ine ra l Spi r i t s 26.00

B Water 65.50

Method: Heat p a r t "A" t o 8OC ( 1 76F) and "B" t o 85C (185F). Whi l e

b lend ing "A" on a high-speed, high-shear mixer , s l o w l y add "B". Force-cool t o 35C (95F) i n i c e . CAUTION: Check cans f o r p o s s i b l e c o r r o s i o n s ince t h i s i s a c a t i o n i c emulsion.

SOURCE: Dow Corning Corp. : Suggested Formula t ion

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172 Advanced Cleaning Product Formulations

Deteraent - /Cor ros i on-Resi s t a n t Po l i sh

T h i s p o l i s h has e x c e l l e n t de te rgen t r e s i s t a n c e and a l s o a h i g h degree o f c o r r o s i o n r e s i s t a n c e .

I n g r e d i e n t s : Pa r t A : I s o s t e a r i c Ac id Dow Corn ing 531 F l u i d Dow Corning 536 F l u i d Kerosene Stoddard So lvent W i tcami de 51 1 Par t €3: Water Kaopo l i t e SF Par t C : Bentone 38 Par t D: I sop ropy l A lcoho l (Anhydrous)

Percent bv Weight

0.60 6.00 2 .00

10.00 16.40

1 .oo

53.25 10 .00

0.50

0.25

Add i s o s t e a r i c a c i d t o t h e combina t ion o f Dow Corning 531 and 536 f l u i d s , and a l l o w f i v e minutes t o r e a c t . Add t h e remain ing i n g r e d i e n t s i n p a r t "A" and tho rough ly mix t o i n s u r e u n i f o r m i t y . Add p a r t "8" s l o w l y w i t h good a g i t a t i o n . Add p a r t "6" s l o w l y w i t h good a g i t a t i o n . S i f t p a r t "C" i f low shear m i x i n g equipment i s used. Load p a r t I'D.

Detergent -Res is tan t Paste P o l i s h

T h i s creamy pas te p o l i s h i s a w a t e r - i n - o i l emulsion w i t h exce l l e n t p o l i sh p r o p e r t i es. Dow Corni ng 536 f 1 u i d g i ves de te rgen t res i s tance , w h i l e Dow Corn ing 200 f l u i d p rov ides easy rub-out and e x c e l l e n t depth o f g loss . The r a t i o o f these f l u i d s can be v a r i e d depending on d e s i r e d p r o p e r t i e s .

I n g r e d i e n t s : Emcol 14 Dow Corn ing 200 Carnauba Wax #3 Morphol i ne I sopar L Oow Corn ing 536 K a o p o l i t e SF Water

F l u i d , 1000 c S t .

F1 u i d

Percent by Wei a h t 1 .5 4.0

10.0 0 . 4

25.0 2.0

1 0 . 0 47.1

Combine Emcol 14, Dow Corn ing 200 f l u i d , Carnauba Wax and h a l f o f t h e I sopar L i n a c o n t a i n e r and heat a t 195F (9OC) w i t h a g i t a t i o n t o m e l t t h e wax. Add t h e morpho l ine w i t h a g i t a t i o n t o n e u t r a l i z e t h e wax. Add Dow Corn ing 536 f l u i d t o t h e remain ing I sopar L, keeping t h e tempera ture a t 176F (8OC). When t h e m i x t u r e i s un i fo rm, s l o w l y add t h e water and t h e K a o p o l i t e SF. Hold a t 176F (8OC). Remove t h e heat and mix u n t i l t h e s o l u t i o n reaches 131F (55C). Pour i n t o c o n t a i n e r s . SOURCE: Dow Corn ing Corp.: Suggested Formula t ions

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Polishes, Coatings and Finishes I73

F u r n i t u r e Po l i sh

P a r t A : Mazer M a s i l EM lOOP Mazer M a s i l EM l O O O P Wax Emulsion P a r t B: Carbopol 934 T r i e thano l ami ne Water

Wei ah t /%

3.0% 1 .O% 2.0%

3% 3%

07%

Procedure: 1. Blend P a r t A and B s e p a r a t e l y . 2 . Add P a r t B s l o w l y t o P a r t A w i t h m i l d a g i t a t i o n . Cont inue

t o mix u n t i l a homogeneous m i x t u r e i s ob ta ined.

Product shou ld be mixed p r i o r t o use. Apply t o su r face even ly i n a t h i n f i l m w i t h a d r y , s o f t c l o t h . Do a l l o w t o d r y . Turn c l o t h as o f t e n as necessary t o o b t a i n a b r i g h t , d r y su r face .

Spray and Wipe F u r n i t u r e P o l i s h

Par t A : I sopar E Concord CO Wax Mazer S-Maz 03R Mazer Masi 1 SF 100 Mazer Masi 1 SF 10,000 P a r t 8: Water

Wei eht/%

27.5% 2.0% 1 .O% 2.3% 0.5%

66.7%

Procedure: 1. Heat P a r t A t o 9OC w i t h a q i t a t i o n t o tho rough ly mix a l l

2 . Add P a r t B preheated t o 60C w i t h h i g h speed. 3. Cont inue m i x i n g u n t i l c o o l .

SOURCE: PPG I n d u s t r i e s , I n c . : Suggested Formula t ions

i n g r e d i e n t s .

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174 Advanced Cleaning Product Formulations

F u r n i t u r e P o l i s h No. 337 Veegum

A Water M i nera l s p i r i t s

B Dow Corning 200 F l u i d W i tcami de 51 1

C Carnauba Emulsion C-340 Preservat ive

Procedure: Slowly add Veegum t o the water wh

avai lab1 e shear. Conti nue m i x i na unt l e a g i t a t i n g a t max 1 smooth. Add abras

1.5 45.5 35.0 4.0 4.0

10 .0 q.s

mum ve where

requi red and mix u n t i l smooth. Mix B w e l l and add C t o B mix ing u n t i l smooth. Add A and Mix u n t i l smooth and uni form. Add desired preservat ive. Consistency: Pourable l o t i o n Suggested Packaging : P1 a s t i c squeeze b o t t l e D i rec t i ons For Use:

haze. Wipe t o a h igh g loss w i t h a c lean s o f t c l o t h . Comments:

Veegum s tab i 1 i zes these water- i n-oi 1 emulsions against separat ion or solvent phase bleed. I n t h e auto po l i sh , Veegum a lso keeps t h e m i l d abrasive un i fo rm ly suspended w i t h i n the i n t e r n a l phase. Both compositions apply e a s i l y , d ry q u i c k l y t o a haze, and r e a d i l y b u f f t o a h igh g loss.

Apply a t h i n even coat w i t h a s o f t c l o t h . Al low t o dry t o a

Scratched Wood P o l i s h No. 210 Veegum T 1 .so

A Water 25.50 S tea r i c ac id 4.50

B Carnauba wax 16.50 Beeswax, ye1 1 ow 16.50

C T r i ethanol ami ne 2.75 D Mineral s p i r i t s 27.00

Dye 0.50 E Water 5.25

Preservat ive q.s. Procedure:

a v a i l a b l e shear. Continue mix ing u n t i l smooth. Heat B t o 9OC. Add C w h i l e mainta in ing temperature. Add D and mainta in temp- erature. Heat A t o 9OC and add t o B/C/D mix ing u n t i l uni form. Prepare E using hot water and add t o mix ture. Continue mix ing u n t i l . Add preservat ive. Consi stency: High v i scosi t y cream. Suggested Packaging: Tube D i rec t l ons For Use: Work i n t o damaged area w i t h s o f t c l o t h .

Al low t o dry . Bu f f t o des i red sheen. Comments :

Veegum T s t a b i l i z e s t h e t r ie thanolamine s tea ra te emulsion. This h igh v i s c o s i t y cream not on l y r e s t a i n s wood scratches bu t a l so f i l l s depressed areas r e s t o r i n g o r i g i n a l surface appearance. As t h e mineral s p i r i t s evaporate, t h e carnauba wax/beeswax combination provides a r i g i d , non-cracking f i l l e r . Dye c o l o r and l e v e l may be adjusted as requi red. SOURCE: R.T. Vanderb l l t Co.: Suggested Formulations

Slowly add Veegum T t o t h e water w h i l e a g i t a t i n g a t maximum

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Polishes, Coatings and Finishes 175

~- I n d u s t r i a l F l o o r F i n i s h - F o r m u l a B (24% S o l i d s 1

Water F1 uorad FC-120 f 1 uorochemi c a l s u r f a c t a n t SWS-211 s i 1 i c o n e a n t i foam agent E k t a s o l v e DE g l y c o l e t h e r E k t a s o l v e DM g l y c o l e t h e r Texanol e s t e r a l c o h o l T r i b u t o x y e t h y l phosphate p l a s t i c i z e r Kathon CG/ICP p r e s e r v a t i v e (1 .5%) D u r a p l u s 2 po lymer (38%) R e s i n a l l 802 l e v e l i n g r e s i n (25%) Epolene E-43 wax n o n i o n i c e m u l s i o n (40%)

Epolene E-43 wax I g e p a l CO-630 s u r f a c t a n t P o t a s s i um h y d r o x i d e (86%) Water

Epolene E-20 wax I g e p a l CO-710 s u r f a c t a n t P o t a s s i um h y d r o x i d e (86%) Sodi um metabi s u l f i t e Water

Epolene E-20 n o n i o n i c emuls ion (40%) :

P a r t s by Wejnh t 29 .00

(1%) 0.90 0 . 0 2 4 .75 2.25 1 . 1 2 1.43 0.03

50.00 4 .50 2 . 7 8

40 12

4 84

40 12

1 0 . 4

8 0 . 1

2 . 7 8

I n d u s t r i a l F l o o r F i n i s h - F o r m u l a A (22% S o l i d s )

P a r t s b v Water T r i b u t o x y e t h y l phosphate p l a s t i c i z e r E k t a s o l v e DE g l y c o l e t h e r D i b u t y l p h t h a l a t e F l u o r a d FC-129 f l u o r o c h e m i c a l s u r f a c t a n t (1%) Es i -Cry1 Respond I polymer (38%) A c r y s o l 644 l e v e l i n g r e s i n Epolene E-43 wax n o n i o n i c emuls ion (40%)

Epolene E-43 wax 40 I g e p a l CO-630 s u r f a c t a n t 12 P o t a s s i um h y d r o x i d e (86%) 4 Water 84

Epolene E-20 wax 40 Epol ene E-20 wax n o n i o n i c emu1 s i on (35%) :

I g e p a l CO-710 s u r f a c t a n t 12 Potass ium h y d r o x i d e (86%) 1 Sodium m e t a b i s u l f i t e 0 . 4 Water 99 .2

SWS-211 s i l i c o n e a n t i f o a m agent P r e s e r v a t i v e

M i x i ng Procedure : 1 . Add a l l i n g r e d i e n t s , 2 . C o n t i n u e adequate ag 3 . A l l o w t o e q u i l i b r a t e SOURCE: Eastman Chemica

Wei q h t 39.44

1 .62 7.32 1.21 0.02

43.45 2 . 2 8 1 . 8 6

2.73

0 . 0 2 0 . 0 5

i n o r d e r l i s t e d , w i t h a g i t a t i o n . t a t i o n f o r 30 m i n u t e s . f o r 16 h o u r s b e f o r e t e s t i n g o r u s i n g .

Co.: Suggested F o r m u l a t i o n s

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176 Advanced Cleaning Product Formulations

I n d u s t r i a l F l o o r Finish-Formula B (25% S o l i d s )

Water T r i b u t o x y e t h y l phosphate p l a s t i c i z e r Ek taso lve DE g l y c o l e the r F1 uorad FC-129 f 1 uorochemi c a l s u r f a c t a n t E s i c r y l 20/20 polymer ( z inc - f ree ) (40%) Esi -F1 ex 802 1 evel i ng r e s i n Epolene E-43 wax non ion ic emulsion (40%)

Epolene E-43 wax Igepa l CO-630 s u r f a c t a n t Potassium hydrox ide (86%) Water

Epolene E-20 wax Igepa l CO-710 s u r f a c t a n t Potassium hydrox ide (86%) Sodi um metabi s u l f i t e Water

Epolene E-20 wax non ion ic emulsion (35%)

SWS-211 s i 1 i cone a n t i foam agent P rese rva t i ve

P a r t s by Weiqht 32.00

2.19 6.25

(1%) 0.03 48.81

4.55 2.86

40 12

4 84

40 12

1 0 .4

99.2 0.02 0.05

3.24

I n d u s t r i a l F l o o r Finish-Formula C (18% S o l i d s )

Water T r i bu toxye thy l phosphate p l a s t i c i z e r Ek taso lve DE g l y c o l e the r Esi-Cry1 20/20 polymer ( z i n c - f r e e ) (40%) Esi -F1 ex 802 1 evel i ng r e s i n Epolene E-43 wax non ion ic emulsion (40%)

Epolene E-43 wax Igepa l CO-630 s u r f a c t a n t Potass i um hydrox ide (86%) Water

Epolene E-20 wax Epolene E-20 wax non ion ic emulsion (35%)

CO-710 s u r f a c t a n t um hydrox ide (86%) m e t a b i s u l f i t e

Igepa l Potass Sodi um Water

sws-211 s Preservat

1 i cone a n t i foam agent ve

40 12

4 84

P a r t s by Weiqht 49.87

1.62 4.63

35.89 3.38 2.12

2.40 40 12

1 0.4

99.2 0.02 0 .05

M i x i ng Procedure : 1 . Add a l l i n g r e d i e n t s , i n o rder l i s t e d , w i t h a g i t a t i o n . 2. Cont inue adequate a g i t a t i o n f o r 30 minutes. 3. A l l ow t o e q u i l i b r a t e f o r 16 hours be fo re t e s t i n g o r us ing .

SOURCE: Eastman Chemical Co.: Suggested Formula t ions

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Polishes, Coatings and Finishes 177

I n d u s t r i a l _ F l o o r F i n i s h - F o r m u l a A (20% S o l i d s )

P a r t s b r Water T r i b u t o x y e t h y l phosphate p l a s t i c i z e r E k t a s o l v e DE g l y c o l e t h e r D i b u t y l p h t h a l a t e SWS-211 s i l i c o n e a n t i f o a m agent F l u o r a d FC-129 f l u o r o c h e m i c a l s u r f a c t a n t P r o x e l GXL p r e s e r v a t i v e NM 90 po lymer ( z i n c - f r e e ) (38%) Mor ton Conrez 500 l e v e l i n g r e s i n (25%) Epolene E-43 wax n o n i o n i c e m u l s i o n (40%)

Epolene E-43 wax I g e p a l CO-630 s u r f a c t a n t P o t a s s i urn h y d r o x i d e (86%) Water

Epolene E-20 wax I g e p a l CO-710 s u r f a c t a n t P o t a s s i um h y d r o x i d e (86%) Sodi um metabi s u l f i t e Water

Epolene E-20 wax n o n i o n i c e m u l s i o n (35%)

40 12

4 84

40 12

1 0 . 4

99.2

~ _ _ Wei L h t 430.0

1 4 . 0 41 .O

4 . 8 0 .2 6 . 0 1 . o

353.0 75.0 35.0

40.0

~~ I n d u s t r i a l F l o o r F i n i s h - F o r m u l a B (16% so l ids )

Water T r i b u t o x y e t h y l phosphate p l a s t i c i z e r E k t a s o l v e DE g l y c o l e t h e r D i b u t y l p h t h a l a t e SWS-211 s i 1 i c o n e a n t i foam agent F l u o r a d FC-129 f l u o r o c h e m i c a l s u r f a c t a n t P r o x e l GXL p r e s e r v a t i v e Mor-Glo 2 l a t e x po lymer (38%) Mor ton Conrez 500 l e v e l i n g r e s i n (25%) Epolene E-43 wax n o n i o n i c e m u l s i o n (40%)

Epolene E-43 wax I g e p a l CO-630 s u r f a c t a n t P o t a s s i urn h y d r o x i d e (86%) Water

Epolene E-20 wax I g e p a l CO-710 s u r f a c t a n t Potass ium h y d r o x i d e (86%) Sodi urn metabi s u l f i t e Water

Epolene E-20 wax n o n i o n i c e m u l s i o n (35%)

P a r t s by Weiqht 546.5

10.7 42 .9

5 . 6 0 .2

(1%) 4 . 5 1 .0

321.2 28 .7 1 8 . 0

40 12

4 84

40 12

1 0 . 4

99.2

2 0 . 7

M i x i n g Procedure : 1 . Add a l l i n g r e d i e n t s , i n o r d e r l i s t e d , w i t h a g i t a t i o n . 2 . C o n t i n u e adequate a g i t a t i o n f o r 30 m i n u t e s . 3 . A l l o w t o e q u i l i b r a t e f o r 16 h o u r s b e f o r e t e s t i n g o r u s i n g .

SOURCE: Eastman Chemical Co. : Suggested Formul a t i ons

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178 Advanced Cleaning Product Formulations

I n d u s t r i a l F l o o r Finish-Formula C (20% S o l i d s 1

P a r t s by Wei a h t Water 437.5 T r i b u t o x y e t h y l phosphate p l a s t i c i z e r 13.1 Ek taso lve DE g l y c o l e the r 52.9 D i b u t y l ph tha l a t e 7.0 SWS-211 s i l i c o n e an t i f oam agent 0 .2 Igepa l CO-977 s u r f a c t a n t 4.5 F luorad FC-129 f luorochemica l s u r f a c t a n t (1%) 5.5 Proxel GXL p r e s e r v a t i v e Mor-Glo 2 l a t e x polymer (38%) Morton Conrez 500 l e v e l i n g r e s i n (25%) Epolene E-43 wax non ion ic emulsion (40%)

Epolene E-43 wax Igepa l CO-630 s u r f a c t a n t Potassium hydrox ide (86%) Water

Epolene E-20 wax Igepa l CO-710 s u r f a c t a n t Potass i um hydrox ide (86%) Sodi um metabi s u l f i t e Water

Epolene E-20 wax non ion ic emulsion (35%)

. . 1 . o

395.4 35.3 22.2

40 12 4

84

40 12

1 0 . 4

99.2

25.4

I n d u s t r i a l F l o o r Finish-Formula D (25% S o l i d s )

Water T r i b u t o x y e t h y l phosphate p l a s t i c i z e r Ek taso lve DE g l y c o l e the r D i b u t y l p h t h a l a t e SWS-211 s i l i c o n e an t i f oam agent Igepa l CO-977 p r e s e r v a t i v e F luorad FC-129 f luorochemica l s u r f a c t a n t (1%) Proxe l GXL p r e s e r v a t i v e Mor-Glo 2 l a t e x polymer (38%) Morton Conrez 500 l e v e l i n g r e s i n (25%) Epolene E-43 wax non ion ic emulsion (40%)

Epolene E-43 wax 40 Igepa l CO-630 s u r f a c t a n t 12 Potassium hydrox ide (86%) 4 Water 84

Epolene E-20 wax 40 Igepa l CO-710 s u r f a c t a n t 12 Potassi um hydrox ide (86%) 1 Sodi um metabi s u l f i t e 0.4 Water 99.2

Epolene E-20 wax non ion ic emulsion (35%)

M ix ing Procedure: 1. Add a l l i n g r e d i e n t s , i n o rde r l i s t e d , w i t h ag 2. Cont inue adequate a g i t a t i o n f o r 30 minutes. 3. A l l ow t o e q u i l i b r a t e f o r 16 hours b e f o r e t e s t SOURCE: Eastmen Chemical Co.: Suggested Formulet

P a r t s by Weiqht 297.3

16.4 66.1

8 .7 0.2 5 .5 7.0 1 .o

494.2 44.1 27.7

31 .8

t a t i on.

ng o r us ing . on

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12. Rinse Aids

179

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180 Advanced Cleaning Product Formulations

Automatic Dishwasher R inse A i d - I

I na red i e n t : W t . % (As Rec'd Bas is ) Vanseal NALS-30 (Sodi um Lauroy l Sarcosi na te ) 7.00 A1 k y l a r y l Pol ye ther* * 40.00 Deionized Water 45.00

Automat ic Dishwasher R inse A i d - I 1

I n s r e d i e n t : W t . % (As Rec'd Bas is ) Vanseal NALS-30 (Sodium Lauroy l Sarcos ina te) 7.00 A1 k y l a r y l Pol ye the r * 23.00 A1 k y l a r y l Pol ye ther* * 23.00 Deionized Water 47.00

Automat ic D i shwasher R i nse A i d - I I I

I n q r e d i en t : W t . % (As Rec'd B a s i s 1 Vanseal NALS-30 (Sodium Lauroy l Sarcos ina te) 5.00 M o d i f i e d Polyphenoxy Adduct*** 50.00 Dei on i zed Water 45.00

* T r i t o n CF-10 * * T r i t o n CF-21

* * * T r i t o n CF-54

Because t h e sa rcos ina tes have t h e a b i l i t y t o r a i s e t h e c loud p o i n t o f non ion i c s u r f a c t a n t s , t h i s f e a t u r e can be used t o advantage i n t h e f o r m u l a t i o n o f dishwasher r i n s e a i d s . A t t h e c loud p o i n t and up t o 15C above it, foam genera t ion i s reduced and detergency i s enhanced. By a d j u s t i n g t h e c loud p o i n t of t h e fo rmula t o t h e use temperature, one can t a k e f u l l advantage o f t h i s performance f e a t u r e .

SOURCE: R . T . V a n d e r b i l t Co., I n c . : Suggested Formula t ions

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Rinse Aids I81

Antarox EL-240 Urea Water Dye

Procedure: 1 . D i s s o l v e urea i n wa te r . 2 . Add Antarox EL-240 t o water /u rea s o l u t i o n . Mix tho rough ly .

Phys i ca l P r o p e r t i e s : pH (as i s ) : 7 . 5 pH ( 1 % ) : 8 . 1 V i s c o s i t y : 50 cps S p e c i f i c G r a v i t y : 1 . 0 1

Formula DW-0011

___- Rinse A i d

Antarox BL-225 Isopropano l Water Dye

Procedure: 1 . D i s s o l v e Antarox EL-225 i n wa te r . Mix tho rough ly 2 . Add Isopropano l . Phys ica l P r o p e r t i e s :

pH (as i s ) : 6 .1 pH (1%): 8 . 3 V i s c o s i t y : 30 cps S p e c i f i c G r a v i t y : 0.99

Formula OW-0012

SOURCE: Rhone-Poulenc: Suggested Formula t ions

Wt.% 70.0 20 .0 1 0 . 0 ----

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13. Rug, Floor, Carpet, Upholstery Shampoos and Cleaners

182

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Rug, Floor, Carpet, Upholstery Shampoos and Cleaners 183

Carpet Shampoo f o r Automat ic Carpet Shampooer IMay a l s o be used f o r c l e a n i n g v i n y l & upho ls te ry )

Rhodaterge RS-25 Tet rasod i um EDTA (38%) Fragrance, Dye, P r e s e r v a t i v e Water

2: Rhodaterge RS-25 Tet rasod i um EDTA (38%) B u t y l C e l l oso l ve Fragrance, Dye, P r e s e r v a t i v e Water

Procedure:

Wt.% 50.0

1 . o Q.S.

49.0

Wt.% 50.0

1 . 0 5.0 Q.S.

44.0

Charge water i n t o m i x i n g vesse l and add EDTA. Once system i s un i form, b lend i n Rhodaterge RS-25. B1 end i n remai n i ng i ngred i - e n t s i n o rde r l i s t e d . Use I n s t r u c t i o n s f o r Automat ic Carpet Shampooer and Vacuum:

Normal Use Leve l : Mix 1 p a r t shampoo w i t h 32 p a r t s water . S t a i n s and Heavy S o i l s : Mix 1 p a r t shampoo w i t h 15 p a r t s water

Appearance: C lea r , y e l l o w l i q u i d pH, as i s : 9.95 9.95 S p e c i f i c G r a v i t y : 1.016 1.020 V i s c o s i t y : < l o cps t 1 0 cps

Physi c a l P roper t i es :

Formula CU-0062

Aerosol Rug Shampoo

Rhodacal 301-10/F Water Formal i n

Wt.% 10.00 89.85

0.15

Procedure:

When s o l u t i o n i s c l e a r , add Formal in . F i l l :

Add Rhodacal 301-10/F i n t o h o t water w i t h moderate a g i t a t i o n .

Shampoo Concentrate: 90% P r o p e l l a n t 12/114-40/60: 10%

Phys ica l P r o p e r t i e s f o r Concentrate: l i g h t y e l l o w l i q u i d Appearance: C lea r ,

pH, as i s : 5.06 Speci f i c G r a v i t y : V i s c o s i t y : t10 cps Formula CU-0059

SOURCE: Rhone-Poulenc

.015

SUQQeSted Formula t ions

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184 Advanced Cleaning Product Formulations

Carpet Shampoo w i t h Grease-Cutt ina So lvent

Rhodapon SB-8208/S Tetrasodium EDTA (38% S o l u t i o n ) A1 kami de DC-212/S Fragrance, Dye, P rese rva t i ve Water B u t y l C e l l o s o l v e

Wt.% 10.0 5.0 0.2 Q.S.

79.8 5.0

Procedure:

SB-8208/S, te t rasod ium EDTA, and Alkamide DC-212/S. Once system i s un i fo rm, b lend i n B u t y l Ce l l oso l ve . Fragrance, Dye and Prese rva t i ve .

Phys ica l P roper t i es : Appearance: C1 ear , water-whi t e 1 i qu i d pH, as i s : 12.0 S p e c i f i c G r a v i t y : 1 . O O V i s c o s i t y : t 10 cps

Formula CU-0061

Charge water i n t o m ix ing vessel and b lend i n Rhodapon

L i a u i d Steam Cleaner f o r Carpets (For Use i n Hard Water Svstems)

Sodium M e t a s i l i c a t e , Anhydrous Tetrapotassium Pyrophosphate (60%) Rhodafac RA-600 Igepa l CO-710 Water

Perfume and Co loran ts added, as des i red , r e p l a c i n g water.

Wt.% 7.5

12 .5 4.0 1 . o

75.0

Procedure: 1. D isso lve Sodium M e t a s i l i c a t e , Anhydrous i n water . 2. Add Rhodafac RA-600 and Igepa l CO-710, m ix ing tho rough ly

3. Add Tetrapotassium Pyrophosphate.

Phys ica l P r o p e r t i es: pH (as i s ) : 13.2 pH (1%): 11.0 V i s c o s i t y : 10 cps Speci f i c G r a v i t y : 1 .04

Formula CU-0060

a f t e r each a d d i t i o n .

SOURCE: Rhone-Poulenc: Suggested Formula t ions

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Water TKPP Sodi urn Metasi 1 i ca te Glucopon 425 CS

Rug, Floor, Carpet, Upholstery Shampoos and Cleaners I85

F l o o r (I Carpet Care Produc ts F l o o r (I T i l e Cleaner

Wax S t r i p o e r

Water Te t rasod i um EDTA Sodi um Metasi 1 i c a t e Monoethanol ami ne Glucopon 425 CS

Wax S t r i p p e r (So lvent )

Water Tetrasodium EDTA Ammonium Hydroxide (30%) Propylene Glyco l nButy l Ether Glucopon 425 CS

Usage: 1 p a r t t o 20 p a r t s water

Machine F l o o r Scrubber

Water TKPP KOH (45%) T ryco l 5963 Glucopon 425 CS

Usage: 1 p a r t t o 100 p a r t s water

SOURCE: Henkel Corp.: Suggested Formula t ions

W ! % 81

8 3 8

W t % 88

1 5 3 3

90 1 2 4 3

84.5 8 . 0 2.5 2.0 3 . 0

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186 Advanced Cleaning product Formulations

F loo r Care Products F1 oor C1 eaner

Formulation: Dowanol PnB g l y c o l e ther T r i ethanol ami ne O le i c a c i d Water

Wt.% 14.0 12.0 16.0 58.0

Note: Mix i n order l i s t e d . So lu t i on w i l l gel w i t h i n i t i a l a d d i t i o n

o f water bu t w i l l t h i n w i t h s t i r r i n g and a d d i t i o n o f a l l water. Cleaner should be c l e a r and s l i g h t l y ye l low i n c o l o r .

F loo r Cleaner

Formulati on: Dowanol PM (or PnB) g l yco l e ther Water Ole ic a c i d T r i ethanol ami ne

F loo r Wax S t r i p p e r

Formulation: Dowanol PM (or PnB) g l yco l e ther T r i sodi urn phosphate T r i t o n X-100 su r fac tan t Water

F loo r Wax S t r i m e r

Formul a t i on : Dowanol PM (o r 1 : l PM:PnB) g l y c o l ether Ammoni um hydroxide (8%) Niaproof 08 su r fac tan t Water

F loo r Wax S t r i p p e r

Formulation : Water T r i sodium phosphate Dowanol PnB g l y c o l e ther T r i t o n X-102 su r fac tan t

Wt.% 14 .0 58.0 16.0 12 .0

Wt.% 8 . 0 2.5 8 .5

81 . o

Wt.% 14.0

6.5 4.5

75.0

Wt.% 81 . o

2 . 5 8 . 0 8.5

Notes ; Combine f i r s t two components and s t i r t o d i ssol ve sol i d s . Add remaining components i n order l i s t e d . Cleaner should be c l e a r and co lo r l ess .

SOURCE: Dow Chemical Co.: Suggested Formulations

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Rug, Floor, Carpet, Upholstery Shampoos and Cleaners I87

Rhodafac LO-529 A1 kami de DC-212/S

F l o o r C1 eaner

Wt.% 5.0 1 . o

Tetrasodium Pyrophosphate (65% A c t i v e ) 2.0 T r i sodi um Phosphate 1 . o D ie thy lene G lyco l Monoethyl E ther 1 . o Water 90.0 Perfume and Co lo ran ts added, as des i red , r e p l a c i n g water Procedure: 1 . D i s s o l v e te t rasod ium pyrophosphate i n water . Add t r i s o d i u m

2. Add Rhodafac LO-529 and Alkamide DC-212/S. 3. Add s o l v e n t . Phys ica l P r o p e r t i e s :

pH, as i s : 11 .0 pH (1%) : 9.0 V i s c o s i t y : 290 cps S p e c i f i c G r a v i t y : 1 .01 Formula FC-0054

phosphate. D i sso l ve thorough1 y .

F1 o o r Cleaner

Rhodafac LO-529 Sodium Tr ipo lyphosphate Tetrasodium Pyrophosphate Water Procedure: 1 . D i s s o l v e s o l i d s i n t h e t o t a l amount o f water . 2. Add Rhodafac LO-529. Mix tho rough ly . Phys ica l P r o p e r t i es :

pH, as i s : 13.9 pH (1%): 8 .9 V i s c o s i t y : 60 cps S p e c i f i c G r a v i t y : 1.09 Formula FC-0053

Waxed F l o o r Cleaner

Wt.% 6.0 3.0 3.0

88.0

Wt.% Rhodafac RA-600 5 .0 Alkamide DC 212/S 1 . o Te t rapotass ium Pyrophosphate (60% a c t i v e ) 25.0 Water 69.0 Procedure:

w e l l a f t e r each a d d i t i o n . Phys ica l P r o p e r t i e s :

pH, as i s : 8 .6 pH (1%): 8 . 6 V i s c o s i t y : 10 cps S p e c i f i c G r a v i t y : 1.04 Formula FC-0055

Add i n g r e d i e n t s one by one, i n o rde r l i s t e d above, m ix ing

SOURCE: Rhone-Poulenc: Suggested Formula t ions

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188 Advanced Cleaning Product Formulations

F l o o r C leanermax S t r i m e r (Liaui d)

S o i l - F l o o r wax, o i l , grease, p a r t i c u l a t e s Surface - Polymeric f l o o r i n g A p p l i c a t i o n Method - Wipe o r mop Manufacture - M i x i n g tank w i t h p r o p e l l e r s t i r r e r

ComDos i t i on : Water Metso Beads 2040 Sodium Hydroxide (50%) D i ethanol ami ne (98%) EDTA, Tetrasodium (37%) Oipropylene G lyco l Monomethyl E ther Phosphate Es te r Nonylphenoxy Polyethoxyethanol , 9-10 Mole EO

Use D i l u t i o n : C lean ing - 6% bw (8 o z / g a l l o n ) S t r i p p i n g - 12% bw (16 o z / g a l l o n )

F l o o r Cleaner/Wax S t r i v v e r B

S o i l - F l o o r wax, food o i l and grease, p a r t i c u l a t e s Surface - Polymeric f l o o r i n g A p p l i c a t i o n Method - Wipe o r mop Manufacture - M i x i n g tank w i t h p r o p e l l e r s t i r r e r

ComDosi t i on : Water T r i t o n DF-12 (Non ion ic S u r f a c t a n t ) Acryso l ASE 108 ( A c r y l i c Polymer) Potassi um Hydroxide (45%) TKPP (60%)

K a s i l #6 S t r i p Wax

Use D i l u t i o n : Cleaning - 6% bw ( 8 oz /ga l l on ) S t r i p p i n g - 12% bw (16 o z / g a l l o n )

Source: The PQ Corp.: Suggested Formula t ions

75.0 5 . 0 1 . o 1 . o 6.0 4.0 3.0 5 . 0

38.6 3 .0 8.3 3.4

41.7

5 .0

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Rug, Floor, Carpet, Upholstery Shampoos and Cleaners I89

F l o o r S t r i p p e r

I n q r e d i e n t : S o f t Water Na m e t a s i l i c a t e pentahydra te

D i sso l ve EDTA (39%)

Add, mix w e l l Tomah A1 k a l i S u r f a c t a n t

Add, mix w e l l Non ion ic Surfactant-HLB 13

Add, mix w e l l Monoethanol ami ne

Add, mix w e l l Tomah Q-17-2

Add, mix w e l l

pH: 13.40 Recommended D i 1 u t i ons : 5-1 0 : 1 A p p l i c a t i o n s : F l o o r wax s t r i p p e r

SOURCE: Tomah Products, I n c . : Formula 1-107

No Rinse Wax S t r i p p e r

Isopropano l Monoethanol A m i ne Butoxethoxypropanol Mackam MEJ Water

Procedure: Add components t o water and b lend u n t i l c l e a r .

SOURCE: M c I n t y r e Group L td . : I n d u s t r i a l Formulary

Wax S t r i p p e r

Mackam CSF (Cocoamphopropionate) TKPP TSP Sodium M e t a s i l i c a t e Pentahydrate B u t y l C e l l oso l ve Water qs t o

Procedure: Add components t o water and b lend u n t i l c l e a r .

SOURCE: M c I n t y r e Group L t d . : I n d u s t r i a l Formulary

W t % 84.25 5.00

2.00

1.25

2.00

5.00

0.50

Weiaht ,% 19.0 6.5 2.5 0.5 71.5

Wei qh t .% 4.0 4.5 2.5 5.0 2.0

100.0

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190 Advanced Cleaning Product Formulations

General PurDose F loo r and Wall Cleaner Powder

10-35% 5

0- 1 balance

STPP Anionic o r Nonionic Ammonium c h l o r i d e Sesquicarbonate o r soda ash

L i au i d

15% 5

TKPP Soap Water Hydrotrope

balance 5

F loo r Wax Remover Powder

20% 15 30 35

TSP Anionic o r Nonionic Sodium m e t a s i l i c a t e pentahydrate Soda ash

L i su i d

5-1 0% 14-20

5-1 0 4-10

balance

TSP O le i c Acid Anionic o r Nonionic Monoethanol ami ne Water

Concrete Garage F loo r Cleaner- I

60% 2-5

balance

TSP Crys ta l s Anionic o r Nonionic Soda ash

Concrete Garaae F loo r Cleaner- I1

TSP Crys ta l s Anionic o r Nonionic Sodium m e t a s i l i c a t e pentahydrate

2 0% 5-1 0

balance

Cerami c T i 1 e C1 eaner

STPP 80-9096 Anionic o r Nonionic 3- 5 TSP 10-15

SOURCE: FMC Corp.: Detergent App l i ca t i ons B u l l e t i n No. 4: Suggested Formulations

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Rug, Floor, Carpet, Upholstery Shampoos and Cleaners 191

.~ Heavy-Duty Concrete Cleaner

Water Sodi um Metasi 1 i ca te , Anh. Te t rapotass ium Pyrophosphate, 60% Sodium Hydroxide, 50% Rhodafac RA-600 Igepa l CO-630 Butoxyethanol

Wt.% 70

Procedure: 1 . Add t h e water t o a mixer and then add t h e sodium m e t a s i l i c a t e

2 . Add t h e te t rapo tass ium pyrophosphate s o l u t i o n and t h e sodium

3 . Add t h e Rhodafac RA-600 s l o w l y w i t h a g i t a t i o n and mix u n t i l

4. Add t h e Igepa l CO-630 and t h e bu toxyethano l and mix u n t i l

w i t h a g i t a t i o n . Mix u n t i l comp le te l y d i s s o l v e d .

hyd rox ide s o l u t i o n s s l o w l y w i t h a g i t a t i o n . Mix u n t i l un i fo rm.

un i fo rm.

un i fo rm.

Phys ica l P r o p e r t i e s : Appearance: C lea r , wa te r -wh i te t o p a l e y e l l o w l i q u i d pH, as i s : 12.7 Speci f i c G r a v i t y : 1 .072 V i s c o s i t y : t 20 cps

Formula FC-0105

Evapora t i ve (No Rinse) Wax S t r i p p e r

M i r ano l JEM Concent ra te Monoethanol ami ne Butoxyethoxypropanol Isopropano l Water

Procedure: Add t h e i n g r e d i e n t s and mix u n t i l un i fo rm.

Phys i ca l P r o p e r t i e s : Appearance: C lear s o l u t i o n pH, as i s : 11.4 V i s c o s i t y : t 1 0 cps S p e c i f i c G r a v i t y : 0.97

Formula FC-0056

SOURCE: Rhone-Poulenc: Suggested Formula t ions

Wt.% 0 . 5 6.5 2.5

19 .0 72.5

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192 Advanced Cleaning Product Formulations

L i au i d Carpet Cleaner

Water SXS-40% Sodi um B icarbonate STPP Burcosperse AP-Liq Burco LAF-6

Carpet S t a i n Remover-Li o u i d

Water Burcoterge DG-40 Burcosperse AP-Li qu i d Propylene Glyco l S o r b i t o l 70% Burcotase SL-80

Carpet Cleaner/Booster - D r y Des ta i ner

Burco LAF-6 Soda Ash FB-Sodium Percarbonate

% bv Weiaht 72.5 10.0 5.0 5 . 0 5 . 0 2 .5

% by Wei qh t To 100

40 10 20 15

0.5-1 . O

% by Weiaht 2.0-6.0

40-60 40-60

Above a l s o e l i m i n a t e s odors such as those caused by p e t

Genera l l y 5 ounces o f above added t o 5 g a l l o n s o f de tergent u r i n e . Ox id izes s t a i n s such as co f fee , wine, j u i c e . e t c .

s o l u t i o n i s s u f f i c i e n t f o r good performance.

SOURCE: B u r l i n g t o n Chemical Co., I n c . : Suggested Formula t ions

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Rug, Floor, Carpet, Upholstery Shampoos and Cleaners 193

Low Foam Cleaners Machine F l o o r Cleaner I

I n q r e d i e n t : Water KOH (45%)

Add s l o w l y w i t h m i x i n g TKPP

D i s s o l v e comple te ly w i t h m i x i n g T r i t o n X-114

Add w i t h m i x i n g Tomah Amphoteric 400

Add w i t h m i x i n g SpG 20/20F: 1.08 pH: 13.60 Recommended D i l u t i o n s : 1-2 oz/4 g a l l o n s water A p p l i c a t i o n s : Machine c l e a n i n g

Formula LF-103

W S 83.00

2.50

8.00

3.00

3.50

Machine F l o o r Cleaner I1 I n g r e d i e n t : Water TKPP

D isso lve comple te ly w i t h m i x i n g T r i t o n CF-10

Add w i t h m i x i n g Tomah Amphoteric 400

Add w i t h m ix ing SpG 20/20F: 1.08 pH: 9 .30 Recommended D i l u t i o n s : 1-2 oz/4 g a l l o n s water A p p l i c a t i o n s : Machine c lean ing , l e s s a l k a l i n i t y , s a f e r t o

workers Formula LF-104

&% 78.00

8.00

4.00

10.00

Carpet S t a i n Remover/PresDotter I n q r e d i e n t : Water Na O c t y l S u l f a t e (33%)

EDTA (100%)

Dowanol PnB

Tomah Amphoteric 400

Add, mix w e l l

D i sso l ve , mix w e l l

Add, mix w e l l

Add, mix w e l l SpG 20/20F: 1.00 pH: 9.49 Recommended D i 1 u t i ons : as - i s A p p l i c a t i o n s : Carpet and l i n o l e u m prespot te r / remover f o r

o i l y s t a i n s Formula LF-105

W B 92.80

1 .oo

0.20

3 .00

3.00

SOURCE: Tomah Produc ts I n c . : Suggested Formula t ions

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194 Advanced Cleaning Product Formulations

PumDsDravs f o r Removal O f Odors

A t t r i b u t e s :

malodor e x i s t s . The odor w i l l be permanent ly removed i n seconds. 1: I n w e d i e n t s : % w/w 1 . G r i l l o c i n HY-77 2.00 2. P a t i o n i c 138C 6.60 3. I sopropyl A1 coho1 46.20 4. D i s t i l l e d Water 42.40

Can be sprayed on rugs, c l o t h i n g , animals o r wherever a

5. Pa t lac LA (44%) 0.80 6. Tr ie thano lamine (50%) 2.00

2. I n s r e d i en ts : 1. G r i l l o c i n HY-77 2. P a t i o n i c 138C 3. I sop ropy l Alcohol 4. D i s t i l l e d Water 5. P a t l a c LA (44%) 6. T r i ethanol ami ne (50%)

2.00 6.60

36.20 54.00

0.40 0.80

Compounding Procedure:

o the r i n g r e d i e n t s i n t h e g i ven o rde r . Both fo rmu la t i ons , 1 and 2, a re s u i t a b l e as t e x t i l e o r room sprays.

S t i r G r i l l o c i n HY-77 and P a t i o n i c 138C tho rough ly . Add t h e

Formula H-89-G-12

Deodorant RUQ Shampoo

A t t r i b u t e s : A rug c l e a n i n g produc t w i t h G r i 1 l o c i n HY-77 t o e l i m i na te

odors. I n a r e d i e n t s : 1 . G r i 1 l o c i n HY-77 2. P a t i o n i c 138C 3. Sodium C14-16 O l e f i n S u l f a t e 4. Cocami dopropyl Be ta i ne 5. D i s t i l l e d Water 6. Hydroxypropyl M e t h y l c e l l u l o s e 7. Po lysorbate 85 8 . Sodium C h l o r i d e (25% S o l u t i o n ) 9. Germaben I 1 10. Fragrance

% w/w 1 .oo 4.00

20.00 10.00 58.50

1 .oo 2.50

+-2.00 1 .oo QS

Compounding Procedure:

i e n t 6 i n t o 5, add t o t h e f i r s t phase. Heat t o 60C and add Polysorbate. Mix u n t i l un i fo rm. Begin c o o l i n g t o 45C. Add per - fume and p r e s e r v a t i v e . Cool t o 35C. A d j u s t v i s c o s i t y w i t h S a l t So lu t i on . Package.

SOURCE: R.I .T.A. Corp. : Suggested Formula t ions

Combine i ngred i en ts 1-4 i n o rde r w i t h m i x i ng. D i sperse i ngred-

Formula H-89-G-11

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Rug, Floor, Carpet, Upholstery Shampoos and Cleaners 195

Rug Shampoo

Rhodapon LSB Geropon TC-42 Isopropano l Water

Perfume and c o l o r a n t s added, as des i red , r e p l a c i n g water .

Procedure: 1 . D i s s o l v e Rhodapon LSB i n wa te r . 2. Add Geropon TC-42 and i sop ropano l . 3 . F i l t e r p roduc t .

Phys ica l P r o p e r t i e s : p H (as i s ) : 7 .8 pH ( 1 % ) : 7 . 0 V i s c o s i t y : 10 cps S p e c i f i c G r a v i t y : 1 .01

Formula CU-0057

Rug and Upho ls te ry Shampoo

Rhodapex ES Sodi um T r i p o l yphosphate E t h y l Carbi t o 1 T inopa l 5BM Water

Wt.% 7.5

22.0 3 . 0

67.5

Wt.% 20.00

2.00 1 .so 0.05

76.45

Procedure:

and O p t i c a l B r i g h t e n e r i n water . Mix u n t i l homogeneous and c l e a r , and a g i t a t e f o r t h i r t y minu tes .

Phys i ca l P r o p e r t i e s :

D isso lve Rhodapex ES, Sodium Tr ipo lyphosphate , E t h y l C a r b i t o l

Appearance: C lea r , water -wh i te l i q u i d pH: 10.2 S o l i d s : 9.5 S p e c i f i c G r a v i t y : 1 .0 V i s c o s i t y : 100 cps max.

Formula CU-0058

SOURCE: Rhone-Poulenc: Suggested Formula t ions

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14. Miscellaneous

1%

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Miscellaneous 197

Aerosol Bathroom Cleaner

A p roduc t t h a t i s used on su r faces such as ceramics o r meta ls . When app l i ed , t h i s p roduc t p rov ides t h e coated sur face w i t h e x c e l l e n t water-shedding c h a r a c t e r i s t i c s .

Aerosol Concentrate: P a r t : I n s r e d i e n t s :

A Dow Corning HV-490 Emu1 s i on

B Renex 698 I sopropano l

Dowanol DMP Versene Powder Water

Suggested Aerosol Formula t ion : I n a r e d i e n t s : E2-7258 Concentrate Isobutane

Percent by Wei qh t 1.5 2.6 4.1 4.1 6.1 81 . 6

Percent by Wei qh t 95.0 5.0

Prepara t ion : 1. Mix P a r t A w i t h a g i t a t i o n . 2. Mix P a r t B separa te l y . 3. Add P a r t B t o P a r t A w h i l e s t i r r i n g . 4. Pressure f i l l i n l a c q u e r - l i n e d cans w i t h Epon-coated vapor

t a p ve l ves and mechanical break-up spray heads. Formula t ion E2-7258

Aerosol Oven Re1 ease

A water-based aerosol f o r oven re lease . Since t h i s product f o r m u l a t i o n i s water-based, i t o f f e r s advantages over conven- t i o n a l sprays i n c l u d i n g lower c o s t and l e s s odor. Oven sur faces t r e a t e d w i t h t h i s p roduc t w i l l show increased res i s tance t o s t a i n p e n e t r a t i o n .

Aerosol Concentrate: I n a r e d i en ts : Dow Corning 24 Emulsion Carbopol 934 Morphol i ne Water Suggested Aerosol Formula t ion : I n q r e d i en ts : Concentrate E2-7248 I sobutane

Percent by Weight 7.5 0.2 0.2

92.1

Percent by Wei Q h t 95.0

5 . 0

Prepara t ion : 1. Premix a 2% d i s p e r s i o n o f Carbopol 934 i n water . 2. Mix 10 p a r t s o f t h i s d i s p e r s i o n w i t h t h e s i l i c o n e emulsion

3. Add t h e Morpho l ine and mix w i t h a p r o p e l l e r - t y p e a g i t a t o r . and 82.3 p a r t s o f water .

Formula t ion €2-7248

SOURCE: Dow Corning Corp. : Suggested Formula t ions

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198 Advanced Cleaning Product Formulations

Aerosol Water-Repellent Fabr i c Treatment

An exce l l en t f a b r i c water r e p e l l e n t t reatment f o r i tems such as automotive uphols tery and carpet . I t may a l so be used t o t r e a t r a i n wear, snow s u i t s , mi t tens, footwear, and uphols tery ma te r ia l s . Th is concentrate can be used t o formulate an aerosol product us i ng an appropr ia te propel l a n t . Aerosol Concent r a t e :

Inaredients : Percent by Wei qht Dow Corning C-2-0563 Fabr ic Water Repel lent 5.0 Isopar G Solvent 95.0

Suggested Aerosol Formulation: Concentrate CP7-0156D Propel 1 ant o f choi ce

Percent by Wei ah t 80 20

Preparat ion:

but ton. Pressure o r c o l d f i l l w i t h appropr ia te commercial va lve and

Formulat ion CP7-0156D

Can rubber a v i n y

L i q u i d , V i n v l Su r f ace Protectant

be used on var ious s o f t surfaces such as v i n y l , and p l a s t i c s . Th is fo rmu la t i on imparts exce l l en t

surface and r e s i s t s m u l t i p l e detergent washings

eather, g loss t o

Ing red ien ts : Percent by Wei aht Dow Corning 929 Ca t ion i c Emulsion 5.4 Dow Corning 347 Emulsion 9.9 Water 82.7 Makon o r Makon 6 1 .o 50% So lu t i on o f Sodium C i t r a t e i n Water 1 . o Acet ic Acid 0.5

Preparat ion: 1. Load Dow Corning 929 Ca t ion i c Emulsion and Dow Corning 347

2. S t a r t low-shear mixer. 3. Add water. 4. When mixture i s uniform, premix Makon 4 ( o r Makon 6) and t h e

sodium c i t r a t e so lu t i on . Slowly add premix t o mix ing vessel . 5. Mix u n t i l uni form. Package.

Formulation E2-7234

Emu1 s i on i n t o m i x i ng vessel .

SOURCE: Dow Corning Corp.: Suggested Formulations

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Miscellaneous 199

Aspha l t Emu1 s i on

A t t r i b u t e s :

suspended and p reven t i t from s e t t l i n g o u t . Aspha l t emulsion us ing Acr i tamer 941 t o keep t h e aspha l t

I n n r e d i en ts : 1 . D i s t i l l e d Water 2 . Acr i tamer 941 3. 10% Sodium Hydroxide 4 . Ethomeen C-25 5 . S o f t Aspha l t (180-200) o r

Hard Aspha l t (50-60)

%Z 400.00

1 . 5 0 4.50 0 . 7 5

400.00

Compounding Procedures: D isperse t h e Acr i tamer 941 i n t h e wa te r . Add NaOH and Etho-

meen C-25 one a t a t i m e . Mix . Heat water s o l u t i o n t o 65-70C. Heat aspha l t t o 85C. When bo th a r e a t temperature, s l o w l y add t h e mol ten aspha l t i n t o t h e water us ing modera te ly h i g h sheer. The r a t e o f a d d i t i o n shou ld be no g r e a t e r t han t h e r a t e o f d i s p e r - s i o n . Mix u n t i l un i fo rm. Shock coo l t o 30-35C us ing a c o l d water j a c k e t .

F i n a l pH: Approximately 6 . 5 V i scos i t y : 5 ,500 cps

Formula 107-190

Road Tar Emulsion

A t t r i b u t e s :

suspended and p reven t i t from s e t t l i n g o u t . Road Tar Emulsion us ing Acr i tamer 941 t o h e l p keep t h e t a r

I n g r e d i e n t s : 1 . D i s t i l l e d Water 2 . RT 12 3 . Acr i tamer 941 4. 10% Sodium Hydroxide 5 . Ethomeen C-25

%w/w 5 0 . 0 0 0 50.000

0 .125 0.375 0.625

Compounding Procedures:

C-25 one a t a t i m e . Mix . Separa te ly heat t h e water s o l u t i o n and t a r t o 65C. When b o t h a r e a t temperature, s l o w l y add t h e mol ten RT 12 i n t o t h e water w i t h v igo rous m ix ing . The r a t e o f a d d i t i o n shou ld be no g r e a t e r t han t h e r a t e o f d i s p e r s i o n . Mix u n t i l un i fo rm. Shock coo l t o 30-351: u s i n g a c o l d water j a c k e t . Formula 107-1 91

SOURCE: R . I .T.A. Corp. : Suggested Formula t ions

D isperse t h e Acr i tamer 941 i n t h e water . Add NaOH and Ethomeen

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200 Advanced Cleaning Product Formulations

C a t i o n i c O i 1-i n-Water Emul s i f i e r

Wei ght .% Mackazoline 0 (O ley l Hydroxyethyl Im idazo l i ne ) 69.0 I sop ropy l Alcohol 10.0 G l a c i a l A c e t i c Ac id 21 .o

Blend components i n o rde r . For a p p l i c a t i o n , d i spe rse e m u l s i f i e r i n o i l phase and add water w i t h a g i t a t i o n .

C a t i o n i c Water-In-Oi 1 Emul s i o n

Weiaht .% L i g h t M ine ra l O i l 25.0 Mackazoline 0 (O ley l Hydroxyethyl Im idazo l i ne ) 1 .2 O l e i c Ac id 2 .0 Water 71.8

Blend components except water. S lowly add water w i t h good a g i t a t i o n .

Concrete Cleaner

Mackam 2CSF (Cocoamphodipropionate) TKPP TSP Sodium M e t a s i l i c a t e 5H20 T r i t o n X - 1 0 0 Carbi t o 1 Water

Procedure: 1 . Add components t o water. 2. Heat t o 50 degrees C. and b lend u n t i l c l e a r .

Rust Remover

Mackam 2CYSF (Capryloamphodipropionate) KOH (45%) Tr ie thano lami ne Water

Procedure: Add components t o water and b lend u n t i l c l e a r .

SOURCE: McIn ty re Group L td . : I n d u s t r i a l Formulary

Weight ,% 4.0 5 .5 1 . o 2.5 2 .0 2.0

83.0

Wei qh t .% 2.0

70.0 12.0 16.0

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Miscellaneom 201

Chain B e l t Lube 1

I n q r e d i e n t : Wt% C a p r y l i c Ac id ) 10.00 O l e i c Ac id ) 10.00

Tomah Amphoteric N 10.00 Premix ac ids and a d j u s t w i t h NaOH t o pH 11.6

Add t o ad jus ted ac ids , mix w e l l

M ix w e l l

pH: 11.60 Recommended D i l u t i o n s : 100-2OO:l A p p l i c a t i o n s : I n d u s t r i a l cha in l u b r i c a t i o n ; b o t t l e , can,

Notes: High foaming system, may r e q u i r e b i o c i d e

Water 70.00

con ta ine r

Formula M-1 00

Chain B e l t Lube 2

I n q r e d i e n t P a r t A : Water G l a c i a l a c e t i c a c i d

Mix w e l l Tomah A0-728 Speci a1

Mix w e l l Hexyl ene G1 yco l P a r t B: Tomah DA-17 Tomah TAE-RI

Mix w e l l G l a c i a l a c e t i c a c i d

Ad jus t pH t o 7.5

W S

60.00 3.50

10.00

5.00

5.00 15.00

pH: 7.50 Recommended D i l u t i o n s : 100-3OO:l A p p l i c a t i o n s : I n d u s t r i a l cha in l u b r i c a t i o n ; b o t t l e , can,

Notes: Add P a r t B s l o w l y t o P a r t A w i t h good mix ing . con ta ine r

Ad jus t pH t o 7.5 Formula M-101

SOURCE: Tomah Products, I n c . : Suggested Formula t ions

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202 Advanced Cleaning Product Formulations

Concrete Cleaner (Dry Tvoe l

I n s r e d i ents.; % by Weiqht (1 ) Sodium Carbonate (soda ash) l i g h t d e n s i t y 10.0 ( 2 ) Sodium M e t a s i l i c a t e , anhydrous 35.0 ( 3 ) Pe t ro BAF powder 7.0 ( 4 ) Tetrasodium Pyrophosphate 2 0 . 0 (5 ) K o r t h i x H 8 . 0 ( 6 ) FB Sodium Percarbonate 15.0

Procedure: Dry b lend i n g r e d i e n t s i n t h e o rde r l i s t e d . Fo l l ow recommended hand l i ng p r a c t i c e s o f t h e s u p p l i e r s o f

each produc t used.

Comments :

t h e i r Pe t ro BAF i f increased foam i s d e s i r e d .

A p p l i c a t i o n : T o use, wet conc re te w i t h water and s p r i n k l e c leaner on

grease and o i l spo ts t o be c leaned. Scrub area down w i t h b rush and hose o f f .

Wi tco C o r p o r a t i o n ' s Udet 950 i s recommended i n p l a c e o f

Po l i s h i nq C l o t h

I n p r e d i e n t s : ( 1 ) De ion ized Water ( 2 ) K a o p o l i t e SF ( 3 ) K a o p o l i t e AB (4) A1 rosperse (5 ) Isopropano l ( 6 ) C o l l o i d s 581-B Defoamer ( 7 ) P ine O i l

% by Weight 37.5 20 .7 1 0 . 4 27 .6

3.1 0 .7 q . s .

Procedure:

a long w i t h p a r t o f ( 4 ) . Add ( 6 ) a long w i t h t h e r e s t o f ( 4 ) . ( 7 ) can be added as needed f o r f ragrance.

c o t t o n f l a n n e l c l o t h . A f t e r t h e c l o t h i s squeezed, i t i s u s u a l l y d r i e d i n a d r y i n g oven. A f t e r d r y i n g , t h e c l o t h shou ld be coo led b e f o r e s to rage .

p roduc t used.

ab le i ngred i e n t s .

SOURCE: Kaopo l i t e , I n c . : Suggested Formula t ions

Charge ( 1 ) and ( 5 ) i n t o t h e mixer and add (2 ) and ( 3 ) s l o w l y ,

The above m i x t u r e can then be used f o r impregnat ing bleached

Fo l l ow recommended hand l i ng p r a c t i c e s o f t h e s u p p l i e r s o f each

Good i n d u s t r i a l p r a c t i c e s shou ld be used when h a n d l i n g flamm-

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Miscellaneous 203

Deteraent S a n i t i z e r

Miranol FBS Quaternary Ammonium Germicide Sodium Carbonate Cheel ox BF-I 3 Water

Wt.% 15.0 2.0 2.0 0.5 80.5

Procedure:

remaining ma te r ia l and mix u n t i l uni form.

Physical Proper t ies:

Add t h e water, then d i sso l ve t h e sodium carbonate. Add t h e

Appearance: Clear, ye l low s o l u t i o n pH: 10.6 V i s c o s i t y : <I0 cps Speci f i c Grav i t y : 1 .0240

Formula MS-0069

Steam-Cleanina ComDound

Miranol FBS Sodium M e t a s i l i c a t e Pentahydrate Potassi um Hydroxide (45%) Water

Procedure: Add t h e water. Dissolve t h e

potass i urn hydroxide and M i ran0

Physical P roper t i es : Appearance: Clear, ye l low 1 pH: 12.0 V i s c o s i t y : 10-20 cps S p e c i f i c Grav i t y : 1.21

Formula MS-0072

Wt.% 15.0 25.0 11.0 49.0

sodium metas i l i ca te . Add t h e FBS. Mix u n t i l uni form.

qu id

SOURCE: Rhone-Poulenc: SuQQeSted Formulations

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204 Advanced Cleaning Product Formulations

d-Linonene M i c roenu l s i on Cleaner F-478

d-L i monene Monami ne R32-7 B u t y l Carbi t o 1 Water T e t r a sodium EDTA (40% s o l u t i o n )

% B y Weiqht 30.0 20.0 10.0 35 .0 5.0

Procedure:

EDTA and s l o w l y add t o o t h e r i n g r e d i e n t s w i t h good a g i t a t i o n .

Formula t ion P r o p e r t i e s :

B1 end d-Limonene, B u t y l Carbi t o 1 and Monami ne R32-7. Pre-mi x

Phys ica l Appearance: C lear l i g h t amber l i q u i d

d -L i monene A1 k a l i ne Cleaner F-524

d-L i monene Nonyl Phenol 10.5 Moles EO Monafax 785 Water KOH 45%

Procedure: 81 end i ngred i e n t s i n o rde r 1 i s ted .

Formula t ion P r o p e r t i e s : Appearance: C1 ear 1 i q u i d Cloud P o i n t : 51C D i l u t i o n s w i t h water : C lear l i q u i d s

% By Weigh ; 3.0 1 6 . 0 1 6.00

73.09 11 .ll

SOURCE: Mona I n d u s t r i e s , I n c . : Suggested Formula t ions

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Miscellaneous 205

d-Limonene Microemulsions t h a t G ive C lear D i l u t i o n s

Component: d-Li monene Burco TME Burco FAE

B u t y l C e l l o s o l v e Water

NP-9

% bv Weisht 15.0 5.0-6.0 5.0-6.0

10.0-1 2 .0 0.0- 4 . 0

To 100% To ta l

Procedure:

Add water s low ly , w i t h a g i t a t i o n . The f o r m u l a t i o n w i l l t h i c k e n then t h e v i s c o s i t y w i l l break t o form a non-viscous produc t .

Formula t ion Adjustment:

i n grades o f d-Limonene.

fo rmu la t i ons w i t h 5% Burco TME, 5% Burco FAE and 12% NP-9.

Add e m u l s i f i e r and B u t y l C e l l o s o l v e ( i f needed) t o d-Limonene.

T h i s f o r m u l a t i o n can be ad jus ted t o compensate f o r d i f f e r e n c e s

More h i g h l y r e f i n e d grades ( f rag rance grades) w i l l g i v e c l e a r

The bas i c adjustments f o r o t h e r grades a re : 1 ) Keep l e v e l s o f Burco TME and Burco FAE equal . I f t h e 5%

l e v e l s do n o t g i v e a c l e a r concent ra te , use 6% o f each. 2 ) Keep t o t a l e m u l s i f i e r (TME, FAE, NP-9) l e v e l s a t 22%.

Higher 1 eve1 s o f emu1 s i f i e r a r e normal 1 y no t benef i c i a1 . 3 ) Add B u t y l C e l l o s o l v e as needed t o y i e l d c l e a r concentrate.

Water SDot and Soap F i l m Remover

Components: Water 50% C i t r i c Ac id Burcosperse LP Dequest 2000 Burco NPS 50% 45% KOH

% bv Weisht 77.5

5 .0 5 .0 5.0 2.5 5 . 0

Procedure:

between each a d d i t i o n . F in i shed produc t pH should be 4.5-5.0.

Appl i c a t i on :

and o t h e r sur faces . For bes t r e s u l t s , i t should be wiped w i t h an absorbent c l o t h o r paper towe l . I t may a l s o be used as a d i p f o r shower heads, e t c . t o remove water depos i t s .

Source: B u r l i n g t o n Chemical Co., I n c . : SUQQeSted Formulat ions

Add i n g r e d i e n t s i n t h e o rde r l i s t e d . Blend u n t i l un i fo rm

Th is f o r m u l a t i o n may be sprayed on to shower doors, ba th tubs

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206 Advanced Cleaning Product Formulations

D r y - C l eani ng Formula

Rhodafac PE-510 Rhodafac RS-610 Igepa l CO-630 Potassium Hydroxide (45% a c t i v e ) Perch1 o roe thy l ene

Procedure: 1 . Add s u r f a c t a n t s toge the r . Mix tho rough ly . 2. Add Perch lo roe thy lene and Potassium Hydroxide.

Phys ica l P r o p e r t i e s : pH, as i s : 4.3 pH (1%) : 3.7 V i s c o s i t y : 50 cps Speci f i c G r a v i t y : 1 .08

Formula MS-0077

Dry-Cleanina Formula

Igepa l RC-520 Rhodafac RS-610 Geropon WT-27 Hexylene Glyco l Stoddard Sol vent Potassium Hydroxide (45% a c t i v e )

Wt.% 10.0 21 . o 15.0 4.0

5 0 . 0

Wt.% 30.0 30.0

7.5 10.0 18 .5 4 .0

Procedure: 1 . Add Rhodafac RS-610 t o Igepa l RC-520. Mix tho rough ly . 2. Add Geropon WT-27, Hexylene Glyco l and Stoddard So lvent ,

3. Add Potassium Hydroxide s l o w l y t o main ba tch .

Phys ica l P roper t i es : pH, as i s : 4.3 pH (1%): 3.4 V i scosi t y : 150 cps S p e c i f i c G r a v i t y : 1 . O

Formula MS-0078

m ix ing w e l l a f t e r each a d d i t i o n .

SOURCE: Rhone-Poulenc: Suggested Formula t ions

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Miscellaneous 207

Eqq Cleaner IPowder)

S o i l - P r o t e i n Surface - Eggs and egg hand l i ng equipment A p p l i c a t i o n Method - Spray Manufacture - Ribbon o r padd le b lender

Composit ion: TSPP Sodium Carbonate Metso Beads 2048 Sodium S u l f a t e Sodium D i c h l o r o i socyanurate, 2H20 Sodium A l k y l a r y l Su l fona te Powder, (90%)

Use D i l u t i o n : 0.75-1.5% bw (1-2 oz /ga l l on )

G r i 11 Cleaner ( L i auid)

S o i l - Animal f a t and grease, carbon b lack Surface - Metal A p p l i c a t i o n Method - Wipe o r brush Manufacture - Mix tank w i t h p r o p e l l e r s t i r r e r

Composi t i on : Water Sodium Po lyac ry la te , MW 4500-5500 Metso Beads 2048 TKPP (60%) Phosphate Es Oc ty l phenoxy

Use D i l u t

e r Polyethoxyethanol , 9-10 Moles EO

on: 0.80-1.5% bw (1-2 oz /ga l l on )

P r i n t i nq P1 a n t C1 eaner

S o i l - I n k pigment and o i l Surface - Metal A p p l i c a t i o n Method - Wipe o r brush Manufacture - None

Composi t i on : Metso Pentabead 20

Use D i l u t i o n : 3-4.5% bw (4-6 oz /ga l l on )

Source: The PQ Corp.: Suggested Formula t ions

%A 32.0 30.0 20.0 10.0

3.0 5 . 0

%B 78.2

0.5 7.9 3.0 5 .4 5.0

%B 100.0

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208 Advanced Cleaning Product Formulations

G r a f f i t i Cleaner

DuPont DBE Isopropanol Monawet MM-80 Water

% By WeiQht 35.0 5.0 12.0 4 8 . 0

Procedure: Add i n g r e d i e n t s i n o rde r l i s t e d w i t h good a g i t a t i o n .

P e n e t r a t i n g L u b r i c a n t

Sa f f l ower O i l 2 -E thy l hexanol Monacor TEH Monawet MO-70R Monacor 39

Procedure: Add i n g r e d i e n t s n o rde r l i s t e d w i t h good ag

B o t t l e Wash Cleaner F-542

Water Potass i um Hydroxide Sodium M e t a s i l i c a t e (Anhydrous) Tetrapotassium Pyrophosphate Mona NF-25

Procedure:

% By Weiaht 50 .0 40 .0

2 . 5 2 .5 5 . 0

t a t i o n .

% By Weiqht 58 17

5 10 10

Add i n a r e d i e n t s i n t h e o rde r l i s t e d w i t h a g i t a t i o n making d i sso lved b e f o r e adding nex t i n g r e d i e n t . sure each-product i s

Typ ica l P r o p e r t i e s : Cloud P o i n t : 50C K r a f f t P o i n t : t O C

Recommended Use D

SOURCE: Mona I n d u s t r

l u t i o n : 6 t o 8 o z . / g a l .

es, I n c . : Suggested Formula t ions

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Miscellaneous 209

Heavv Dutv Presoak

Ina red ien t : Water Sodium M e t a s i l i c a t e Pentahydrate

D i ssol ve NTA o r EDTA (100%)

Add, mix we l l TKPP

D i ssol ve Tomah AQ-14-2

Add, mix w e l l Tomah Q-14-2

Add, mix w e l l Nonionic Surfactant-HLB 13

Add, mix w e l l SpG 20/20F: 1.08 pH: 12.50 Recommended D i 1 u t i ons : 10-30 : 1 Appl icat ions: Carwash/truckwash Notes: Presoak f o r car/truckwash

Formula T-102

Underbodv Rust I n h i b i t o r

I na red i ent : Water Acet ic Ac id

Mix w e l l , ad jus t pH t o 7.5 I PA

Mix w e l l Tomah DA-17

Mix u n t i l c l e a r pH: 7.50 Recommended D i l u t i o n s : 10-2O:l App l i ca t i ons : Carwash-spray underbody treatment

Formula T-108 SOURCE: Tomah Products, I n c . : Suggested Formulations

R a i l c a r Cleaner

Mackam 2CSF (Cocoamphodipropionate) Buty l C e l l osol ve TKPP Sodium Meta S i l i c a t e 5H20 Caust ic Soda (50%) Water Procedure: 1. Add component i n order t o water. 2. Heat t o 50 degrees C. and b lend u n t i l c l e a r . 3. Cool and f i l l . SOURCE: McIntyre Group Ltd. : I n d u s t r i a1 Formulary

Wt% 77.00 2.00

6.00

1 .oo

3.00

3.00

4.00

Wt% 8 0 . 0 0

1 .oo

4.00

15.00

Wei aht .%

11.5 4.2 4.0 5.5 6.2

68.6

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210 Advanced Cleaning Product Formulations

Leather P r e s e r v a t i v e

A t t r i b u t e s :

aerosol foam t y p e produc t o r packaged i n t o a squeeze tube con ta ine r . I n s r e d i en ts : % W/W P a r t A - O i l Phase: 1 . R i t a l a n 1 .oo 2. Ri tacho l 4.00 3. Lano l i n USP 1 .oo 4. Ce ty l A lcoho l 2.00 5. G l y c e r i n 5.00 6. Propylene G lyco l 2.00 7. Methylparaben 0.15 P a r t B - Water Phase: 8 . Sodium Laury l S u l f a t e (30% S o l u t i o n ) 1.50 9. D i s t i l l e d Water 83.15 10.Perfume 0.20 Compounding Procedures:

70C. Combine P a r t A and P a r t B w i t h s t i r r i n g . Package i n t o con ta ine rs t o be used as a pump spray.

e l 1 en t o r equi Val e n t . Formula 112-66

A p roduc t f o r p rese rv ing l e a t h e r t h a t can be used as an

Combine P a r t A and heat t o 65C. Combine P a r t B and heat t o

For an aeroso l foam t y p e produc t , p r e s s u r i z e w i t h A46 prop-

Leather P r e s e r v a t i v e

A p roduc t f o r p rese rv ing l e a t h e r t h a t can be used as an aerosol foam t y p e produc t o r packaged i n t o a con ta ine r f i t t e d w i t h a pump. I nared i en t s : % w/w P a r t A - O i l Phase: 1 . Lano l i n USP 1 .oo 2. R i t a c h o l 5.00 3. S t e a r i c Ac id 3.00 4. G l y c e r i n 5.00 5. Methylparaben 0.15 6. Tr ie thano lamine (50%) 1 .oo P a r t B: 7. Sodium Laury l S u l f a t e (30% S o l u t i o n ) 1.50 8. D i s t i l l e d Water 83.15 9. Perfume 0 .20 Compounding Procedures:

Combine P a r t A w i t h heat t o 6 5 C . Combine P a r t B and heat t o 70C. Combine P a r t A and P a r t B w i t h s t i r r i n g . Package i n t o con ta ine rs t o be used as a pump spray.

For an aeroso l foam t y p e produc t , p r e s s u r i z e w i t h A46 p r o p e l l e n t o r equ iva len t .

Formula 11 2-67

SOURCE: R.I.T.A. Corp.: Suggested Formula t ions

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Miscellaneous 211

" L

I n q r e d i ents;. ( 1 ) S i l t e x -50 + l o 0 ( 2 ) K a o p o l i t e AB ( 3 ) K o r t h i x ( 4 ) De ion ized Water

Procedure:

qgcd. L a m a p e r " (Water Base l

Mesh % by weinhf

42.0 4 . 0 4 . 0

50 .0

Add ( 2 ) and (3) t o ( 4 ) w i t h f a s t m ix ing . Slow mixer and add ( 1 ) . Some s e t t l i n g w i l l occur , b u t i s e a s i l y re -d ispersed by shaking c o n t a i ne r .

Fo l low recommended hand l i ng p r a c t i c e s o f t h e s u p p l i e r s o f each produc t used.

Comments:

( 3 ) t o 5%. For more v i s c o s i t y and even l e s s s e t t l i n g , i nc rease (2 ) and

"Marble Pol i sh" (Water Baser

~~. Ingredients:. ~

(1 ) F e r r o s i l 14 ( 2 ) K a o p o l i t e AB (3 ) K o r t h i x ( 4 ) De ion ized Water

%-by Wei q h t 40.0

3 . 0 3 .0

5 4 . 0

Procedure:

( 1 ) . Some s e t t l i n g w i l l occur, b u t i s e a s i l y re -d ispersed by shaking c o n t a i n e r .

Fo l l ow recommended hand l i ng p r a c t i c e s o f t h e s u p p l i e r s o f each produc t used.

Comments :

( 3 ) t o 5%.

SOURCE: K a o p o l i t e Corp . : Suggested Formula t ions

Add ( 2 ) and ( 3 ) t o ( 4 ) w i t h f a s t m ix ing . Slow mixer and add

For more v i s c o s i t y and even l e s s s e t t l i n g , i nc rease (2 ) and

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212 Advanced Cleaning Product Formulations

P a i n t S t r i m e r

F u r f u r y l Alcohol (FA) K luce l H Water T a l l O i l Oowfax 302 Methanol C i t rus -d-1 i monene ( i nd. )

68.5 p a r t s 1 .3 p a r t s 4.1 p a r t s 6.8 p a r t s 2.7 p a r t s

13.7 p a r t s 2.9 p a r t s

M ix ing D i r e c t i o n s (Wi th Heat) : 1 . Combine f u r f u r y l a l coho l , water, t a l l o i l , Dowfax 382. M ix

2. Disperse K luce l H i n above m ix tu re . Mix u n t i l d i sso l ved . Cool. 3. Add methanol and c i t rus-d- l imonene. Mix we1 1.

M i x i ng D i r e c t i ons (Without Heat) : 1. Disperse K luce l H i n t o f u r f u r y l a l c o h o l . Mix f o r 10-15 minutes

un t i 1 compl e t e l y d i sso l ved . 2. Add remaining i n g r e d i e n t s . M ix tho rough ly .

Developmental Formula t ion SC-9E

w e l l and heat t o 110-12OF.

Pai n t S t r i m e r

T e t r a h y d r o f u r f u r y l A lcoho l T a l l O i l Dei on i zed Water Dowfax 382 K luce l H Ethanol C i t rus -d-1 imonene

F1 ash Poi n t (Se ta f 1 ash) : 118F

65.3 p a r t s 7.2 p a r t s 4.3 p a r t s 3.85 p a r t s 1 . O p a r t s

14 .5 p a r t s 3.85 p a r t s

M i x i n g D i r e c t i o n s (Wi th Heat) : 1 . Combine t e t r a h y d r o f u r f u r y l a l coho l , water, t a l l o i l .

Dowfax 382. Mix w e l l and heat t o 110-12OF. 2. D isperse K luce l H. Mix u n t i 1 d i sso l ved . Cool . 3. Add e thano l and c i t rus-d- l imonene. Mix th roough ly .

M i x i n g D i r e c t i o n s (Wi thout Heat ) : 1 . Disperse K luce l H i n t o t e t r a h y d r o f u r f u r y l a l c o h o l . Mix u n t i 1

2. Add remaining i n g r e d i e n t s . M ix tho rough ly .

SOURCE: Great Lakes Chemical Corp. : Suggested Formula t ions

comple te ly d i sso l ved .

Developmental Formula t ion SC-20T

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Miscellaneous 213

P a i n t S t r i pDers __ L ipUid

Water Metso Beads 2048 sodi um metasi 1 i c a t e Biodegradable g l ucos i de a n i o n i c Sodi um hyd rox ide (50%)

____-

Powders Metso 200 sodi um o r t h o s i 1 i c a t e

Usage: 6 o z . / g a l . water

Metso Pentabead 20 sodium m e t a s i l i c a t e G sodium s i l i c a t e Sodi um r e s i na te

W a x S t r i ppers L i a u i d s

Water C12-Cl5 l i n e a r a l coho l , 3-4 moles €0 Acryso l AS€-1 08 Potassium hyd rox ide (45%) TKPP (60%) Kasi 1 #6 p o t a s s i um s i 1 i c a t e

Water Metso Beads 2048 sodium metasi 1 Sodium hyd rox ide (50%) D i e thano l ami ne EDTA, te t rasod ium (37%) O i p r o p y l ene g l y c o l monomethyl e Phosphate e s t e r Nonylphenol , 9-10 moles EO

c a t e

her

Powder ____ Metso Pentabead 20 sodi um metasi 1 i c a t e Sodium carbonate TSP Sodium a l k y l a r y l s u l f o n a t e

40% 10% 10% 40%

100%

40% 50% 2%

38.6% 3.0% 8.3% 3.4% 41 .7% 5.0%

75% 5% 1% 1% 6% 4% 3% 5%

3 5% 30% 20% 15%

SOURCE: PQ Corp.: Detergent Formulary: Suggested Formula t ions

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214 Advanced Cleaning Product Formulations

P a r a f f i n Wax Emu1 s i on I n a r e d i e n t : P a r a f f i n Wax 125/7

P a r t A PEG 660 monooleate

M e l t and mix Tomah E-18-2

M e l t and mix-heat P a r t A t o 170F Hot water-170F

Pump i n t o P a r t A w i t h mixing-then coo l t o 140F G l a c i a l a c e t i c a c i d

Add a c e t i c a c i d a t 130-140F S i l i c o n e an t i f oam 10%

Cool t o 11OF-add and mix Formaldehyde 37%

Cool t o 11OF-add and mix Recommended D i l u t i o n s : A p p l i c a t i o n dependent A p p l i c a t i o n s : P r o t e c t i v e coa t ings , l u b r i c a n t s

Formula M-103

Wt% 20.00

4.00

2.00

73.50

0.30

0.05

0.15

L i p u i d D r a i n Ooener I n a r e d i e n t : W> Water 49.00 NaOH (50%) 50.00

Tomah A l k a l i Su r fac tan t 1 .oo Add, coo l

Add, mix w e l l pH: 14.00 Recommended D i l u t i o n s : a s - i s A p p l i c a t i o n s : Removes o rgan ic d r a i n c l o g s Notes: A l k a l i Su r fac tan t added t o improve p e n e t r a t i o n and

w e t t i n g Formula 1-106

Low VOC Heavy D u t y Presoak I n n r e d i e n t : Water

Wt% 77.00

Na -Metasi 1 i c a t e Pentahydrate 2.00

NTA (40%) 4.00

TKPP 6.00

Tomah AO-14-2 1 .oo

Tomah Q-14-2 3.00

Non ion ic Surfactant-HL813 3.00

D isso lve comple te ly w i t h m i x i n g

D isso lve comple te ly w i t h m ix ing

D i sso l ve compl e t e l y w i t h m i x i ng

Add w i t h m ix ing

Add w i t h m ix ing

Add w i t h m ix ing SpG 20/20F: 1.08 pH: 12.50 Recommended D i l u t i o n s : 10-5O:l depending on c o n d i t i o n s A p p l i c a t i o n s : Carwash presoak, soak tank c leaner

Formula LV-105 SOURCE: Tomah Products, I n c . : Suggested Formula t ions

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Miscellaneous 215

Pene t ra t i ng Gel Base A t t r i b u t e s :

ge l v e h i c l e f o r a c t i v e i ngred i en ts . I t con ta i ns p ropy l ene g l y c o l and 2-phenoxyethanol as s o l u b i l i z e r s / p e n e t r a n t . I n a r e d i e n t s : % w/w P a r t A : 1. Propylene G lyco l 5.00 2. R i t o l e t h - 1 0 3.00

T h i s p roduc t i s an e x c e l l e n t , c l e a r , e m o l l i e n t mo is tu r i ng

3. 2-Phenoxyethanol 2.00 4. Methylparaben 0.10 5. Propyl paraben 0.05 P a r t 0: 6. D i s t i l l e d Water 86.55 7. DL Panthenol 0.50 P a r t C : 8. Acr i tamer 940 1 .oo P a r t D: 9. T r i ethanolami ne 99% 0.45 10.Di s t i 1 l e d Water 1.35 Compounding Procedure:

Add i t e m 3 t o i t e m 1 and mix. Add i tems 2, 4 and 5, m ix ing a f t e r each a d d i t i o n . Combine P a r t B i n main m ix ing tank and mix u n t i l un i fo rm. Add P a r t A t o P a r t B and mix u n t i l un i fo rm. Add P a r t C and mix u n t i l w e l l b lended and f r e e o f lumps. Add P a r t D f o r n e u t r a l i z a t i o n .

Formula H-89-A-12 Water i n O i l Emulsion Base

A t t r i b u t e s :

R i tahydrox produces a s t a b l e p roduc t , which a l l o w s f o r t h e a d d i t i o n o f o the r m a t e r i a l s , i f des i red . The emulsion w i l l t i g h t e n and t h e v i s c o s i t y w i l l i nc rease as t h e R i tahydrox l e v e l i s r a i s e d ( t o about t h e 1% l e v e l ) . I n a r e d i e n t s : % w/w P a r t A: 1. M ine ra l O i l 80/90 21 .oo 2. P a t i o n i c CSL 7.20 3. P a t i o n i c ISL 0.80 4. R i tahydrox 0.50 5. Methyl paraben 0.10 6. Propy l paraben 0.05 P a r t 0: 7. G l y c e r i n 5.00 8. D i s t i l l e d Water 65.15 P a r t C: 9. Glydant (40-700) 0.20 Compounding Procedure:

Combine i n g r e d i e n t s o f P a r t A and heat t o 72C. Combine i n g r e d i e n t s o f P a r t 0, h e a t i n g t o 72C. Add P a r t A t o P a r t B w h i l e s t i r r i n g and con t inue t o s t i r t o room temperature. Add P a r t C. M ix . Package. V i s c o s i t y : B r o o k f i e l d RVT s p i n d l e TA @ 4 rpm @ 27 C: 24,750 cps.

SOURCE: R . I . T . A . Corp.: Suggested Formula t ions

T h i s w a t e r - i n - o i l emulsion i s smooth and non-greasy. The

Formula H-89-P-23

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216 Advanced Cleaning Product Formulations

Solvent Cleaners Blood S t a i n Remover

Inq red ien t : So f t Water TKPP

Ammoni um Hydroxide (28%)

Tomah Amphoteric SC

I PA

Ethylene g l yco l b u t y l e ther

D i sso l ve

Mix w e l l

Mix w e l l

Mix w e l l

Mix w e l l

pH: 12.07 Recommended D i l u t i o n s : 0-5:l

Formula S-116

Pai n t S t r i Dver

I na red i ent : Water Ethylene g l yco l b u t y l e ther

Mix w e l l Na a l k y l e ther s u l f a t e , (60%)

Mix we l l NaOH (50%)

Add s lowly , mix w e l l Tomah A1 ka l i Surfactant

Mix we l l

y& 72.00

4 . 0 0

8 . 0 0

4 . 0 0

8 . 0 0

4 . 0 0

Wt% 66.50 10.00

3.00

15.00

5.50

SpG 20/20C: 1.08 pH: 13.50 Recommended D i 1 u t i ons : as i s Appl icat ions: Paint remover f o r wood and metal surfaces Notes: Paint on w i t h brush and remove w i t h p u t t y k n i f e ,

s tee l wool, e t c . Formula S-108

SOURCE: Tomah Products, I n c . : Suggested Formulations

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Section II Transportation Cleaners

and Polishes

217

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15. Auto Cleaners and Polishes

218

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Auto Cleaners and Polishes 219

Auto C leaner /Po l ish . Aerosol Packed

I n n r e d i en ts : % by Weight ( 1 ) Hoechst Wax LP 4 .0 ( 2 ) P e t r o l i t e Wax C-36 3.0 ( 3 ) Dimethyl S i l i c o n e , 350 c e n t i s t o k e s 3.0 ( 4 ) A r l a c e l C 1.5 ( 5 ) Odorless M ine ra l S p i r i t s 38.5 (6 ) Kaopo l i t e SFO-NP 10.0 ( 7 ) Deionized Water 40.0

Procedure: Me l t ( 1 ) and ( 2 ) a t 150F, and ma in ta in t h i s temperature as

o the r i n g r e d i e n t s a re added, r e a d j u s t i n g as necessary. Add ( 3 ) , ( 4 ) , and (5 ) w i t h moderate a g i t a t i o n , then add (6 ) s low ly and con t inue good a g i t a t i o n u n t i 1 we1 1 d ispersed and smooth. Preheat ( 7 ) t o 150F and add s l o w l y w i t h c o n t i n u i n g a g i t a t i o n . Shut off heat and con t inue a g i t a t i n g u n t i l m i x t u r e coo ls t o 9 O F

Fol low recommended hand l i ng p r a c t i c e s of t h e s u p p l i e r s of each produc t used.

Good i n d u s t r i a l p r a c t i c e s should be used when hand l i ng f 1 ammabl e i ngred i en t s .

Deterqent -Res is tan t Auto C leaner /Po l ish Th ick L i q u i d , O i l -Ex te rna l

I n q r e d i e n t s : (1 ) I sopar L ( 2 ) I sopar M (3 ) Dow Corning 536 F l u i d (4 ) Dow Corning 531 F l u i d ( 5 ) Emcol 14 ( 6 ) Kaopo l i t e SFO-NP ( 7 ) Deionized Water

% by Weisht 14.0 10.0

1 . o 6 .0 1 . o

10.0 58.0

Procedure:

( 6 ) s l o w l y w i t h v igorous a g i t a t i o n , c o n t i n u i n g u n t i l w e l l d ispersed. Add ( 7 ) s low ly , w h i l e a g i t a t i n g s t r o n g l y u n t i l smoot h . each produc t used.

flammable i n g r e d i e n t s .

SOURCE: Kaopo l i te , I n c . : Suggested Formula t ions

Combine (1 ) th rough (4 ) , then (51, and mix tho rough ly . Add

Fo l low recommended hand l i ng p r a c t i c e s o f t h e s u p p l i e r s of

Good i n d u s t r i a l p r a c t i c e s should be used when hand l i ng

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220 Advanced Cleaning Product Formulations

Auto C1 eaner/Pol i sh. Hard Paste

Inqredients : (1) V i s c a s i l 10,000 (2) Hoechst Wax E ( 3 ) Hoechst Wax F (4) Hoechst Wax S (5) Odorless Mineral S p i r i t s (6 ) Odor1 ess Kerosene ( 7 ) Kaopol i te SFO-NP

Procedure:

% bv Weiaht 5.0 7 .2 4.0 1.8

57.5 12.5 12.0

Combine ( l ) , (2), (3), and (4) together , heat t o 194F, ho ld u n t i l melted. I n separate vessel , heat (5) and (6 ) t o 140F, add s lowly t o t h e melt w i t h gen t le a g i t a t i o n , con t inu ing f i v e m i nutes a f t e r complete add i t i on . Shut o f f heat, bu t c o n t i nue a g i t a t i o n ; add (7) s lowly, cont inue a g i t a t i o n u n t i l mix ture cools nea r l y t o s o l i d i f i c a t i o n , and discharge i n t o c h i l l e d conta iners.

each product used.

f 1 ammable i ngredi ents .

Fol low recommended handl ing p rac t i ces o f t h e supp l i e rs o f

Good i n d u s t r i a l p rac t i ces should be used when handl ing

Cream Cleanser-Non Wax TvDe

I naredi ent s : (1) Odorless Kerosene (2) VM&P Naphtha (3) O le i c Acid (4) Triethanolamine (5) Kaopol i te SFO-NP (6) Deionized Water (7) Propyl ene G1 ycol ( 8 ) T e r g i t o l NPX (9) K o r t h i x H

% by Weiaht 5.0

20.0 9.0 3.0

10.0 40.0 4.0 4.0 5.0

Procedure:

a g i t a t i o n , con t inu ing u n t i l w e l l dispersed. I n another vessel , combine ( 6 ) . (7), and ( 8 ) . Then disperse (9) i n t h e mixture w i t h good a g i t a t i o n . Reduce a g i t a t i o n i n t h e o i l mix ture t o moderate, add t h e water mix ture s lowly , and s t i r u n t i l w e l l blended.

each product used.

f 1 ammabl e i ngredi ents.

SOURCE: Kaopol i te , I n c . : Suggested Formulations

Combine (1) through (4 ) , then add (5) s lowly w i t h v igorous

Fol low recommended handl ing p rac t i ces o f t h e supp l i e rs of

Good i n d u s t r i a l p rac t i ces should be used when handl ing

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Auto Cleaners and Polishes 221

Auto C leaner /Po l ish . Hard Paste

I n g r e d i e n t s : (1) V i s c a s i l 10,000 (2) Hoechst Wax E (3) Hoechst Wax F ( 4 ) Hoechst Wax S ( 5 ) Odor less Kerosene (6) Ionac PE 110 ( 7 ) Kaopo l i t e SF o r 1168 (8) Odorless Minera l S p i r i t s

% bv Wei qh t 5.0 7.2 4.0 1.8

12.5 0.25 12.0 57.25

Procedure:

melted. I n separate vesse l , b lend ( 5 ) and (6) w i t h g e n t l e a g i t a t i o n ; add (7 ) s low ly , and inc rease f o r 5 minutes t o v igorous a g i t a t i o n . Reduce t o moderate a g i t a t i o n and add (8) When w e l l d ispersed, combine ( 5 th rough 8) w i t h t h e melted (1 th rough 4). When cooled, d ischarge i n t o con ta ine rs .

each produc t used.

flammable i n g r e d i e n t s .

Comments:

p o l i s h i n g a c t i o n t o t h e fo rmu la t i on .

Heat ( l ) , ( 2 ) , (3), and ( 4 ) t oge the r t o 194F, h o l d u n t i l

Fo l low recommended hand l i ng p r a c t i c e s o f t h e s u p p l i e r s o f

Good i n d u s t r i a l p r a c t i c e s should be used when hand l i ng

Use o f Kaopo l i t e 1168 g ives more aggress ive c lean ing and

DeterQent -Res is tan t Auto C leaner /Po l ish Th ick L i q u i d , O i l -Ex te rna l

I n a r e d i e n t s : (1) I sopar L (2) I sopar M (3) Dow Corning 536 ( 4 ) Dow Corning 531 ( 5 ) Emcol 14 (6 ) Kaopo l i t e SF (7 ) Deionized Water

F l u i d F l u i d

% by Weiaht 14.0 10.0 1 . o 6.0 1 . o

10.0 58.0

Procedure: Combine (1) th rough ( 4 ) , then add (5), and mix thorough ly .

Add (6) s l o w l y w i t h v igorous a g i t a t i o n , c o n t i n u i n g u n t i l w e l l d ispersed. Add (7 ) s low ly , w h i l e a g i t a t i n g s t r o n g l y u n t i l smooth.

each produc t used.

flammable i n g r e d i e n t s .

SOURCE: Kaopo l i t e , I n c . : Suggested Formulat ions

Fo l low recommended hand l i ng p r a c t i c e s o f t h e s u p p l i e r s o f

Good i n d u s t r i a l p r a c t i c e s should be used when hand l i ng

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222 Advanced Cleaning Product Formulations

Auto-Cl eaner/Pol i sh. Hi ph Gloss

Inqredients : (1) Deionized Water (2) Ko r th i x ( 3 ) Kaopol i te SF (4) Hoechst Wax E (5) Hoechst Wax LP (6) Dimethyl S i l i cone , 350 cent is tokes ( 7 ) O le i c Acid (8) Odorless Mineral S p i r i t s (9 ) Morphol i ne

% by Weight 40.4

2.0 15.0 0.2 1.4 4.0 3 .0

32.0 2.0

Procedure: Add (2) t o (l), w i t h s t rong a g i t a t i o n u n t i l smooth, w h i l e

heat ing t o 150F. Cont inuing a g i t a t i o n and mainta in ing tempera- tu re , s lowly add (3 ) and s t i r a c t i v e l y u n t i l u n t i l f r e e from coarse agglomerates.

I n another vessel , heat (4 ) , (5 ) , and (6) t o 150F and blend thoroughly. Add ( 7 ) and ( 8 ) , mainta in 150F and mix we1 1.

S t i r (9) i n t o t h e ho t o i l mixture, and immediately pour ho t water s l u r r y i n t o hot o i l mixture, s t i r r i n g w e l l t o emuls i fy . Continue moderate a g i t a t i o n w h i l e coo l i ng t o f i l l i n g temperature.

Good i n d u s t r i a l p rac t i ces should be used when handl ing f 1 ammabl e i ngredi ents . each product used.

Fol low recommended handl ing p rac t i ces o f t h e supp l i e rs of

Pre-Wax Cleaner, Automotive. L i a u i d

Innredients : (1 ) Deioni zed Water (2) Kaopol i te SF ( 3 ) Odor1 ess Kerosene (4) VM&P Naphtha (5) T r i ethanol ami ne (6) Ole ic Acid ( 7 ) Pine O i l (8) Bentone 38

% bv Wei Qht 44.0 16.5 10.0 20.0 2.5 4.0 2.0 1 .o

Procedure:

warm (3) and (4) t o 100-llOF, add ( 5 ) ’ (6). ( 7 ) . and ( 8 ) , mix thoroughly. Pour water m ix tu re s lowly, w i t h good a g i t a t i o n , i n t o warm o i l mixture, and b lend u n t i l smooth.

Fol low recommended handl ing p r a c t i c e s o f t h e supp l i e rs o f each product used.

Good i n d u s t r i a l p rac t i ces should be used when handl ing flammable i ngredi ents. Comments :

w i t h water, or i f prefer red, may be al lowed t o d ry and then wiped o f f w i t h c lean, d ry c l o t h .

SOURCE: Kaopol i te, I n c . : Suggested Formulations

S l u r r y (2) i n (1) w i t h s t rong a g i t a t i o n . I n a separate vessel ,

I n use, a f t e r s u i t a b l e rubbing, product may be f lushed of f

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Auto Cleaners and Polishes 223

Auto C leaner /Po l ish . Low-Temperature Conwounded Th ick L i q u i d , Water-External

I n q r e d i en ts : % by Weiaht ( 1 ) Deionized Water 35.0 (2 ) Kaopo l i t e SF 17.0 ( 3 ) Deionized Water 7.5 ( 4 ) Odorless Minera l S p i r i t s 32.0 ( 5 ) Dimethyl S i l i c o n e , 350 c e n t i s t o k e s 4.0 (6) O l e i c Ac id 2.0 (7 ) Hoechst Wax E 0.2 ( 8 ) Hoechst Wax LP 1 .4 (9 ) Morphol i ne 0 . 9 Procedure:

Add (2 ) s l o w l y t o ( 1 ) w i t h v igorous a g i t a t i o n , w h i l e hea t ing t o 150F, u n t i l w e l l d i s i n t e g r a t e d and smooth, than add ( 3 ) , and reheat t o 150F.

I n another vesse l , combine (4 ) th rough (8 ) w i t h moderate a g i t a t i o n , heat t o 150F and h o l d u n t i l c l e a r s o l u t i o n r e s u l t s . Cont inu ing a g i t a t i o n , add 9, then s l o w l y add Kaopoli te-Water s l u r r y .

t o l lOF .

each produc t used.

l i n g flammable i n g r e d i e n t s .

Shut o f f heat, con t i nue g e n t l e a g i t a t i o n u n t i l emulsion coo ls

Fo l low recommended hand l i ng p r a c t i c e s o f t h e s u p p l i e r s o f

Good i n d u s t r i a l hand l i ng p r a c t i c e s should be used when hand-

Auto C1 eaner/Pol i sh , f o r Machi ne B u f f i n g

I n a r e d i e n t s : % by Weiqht ( 1 ) Hoechst Wax S 5 . 5 (2 ) P a r a f f i n O i l , Faxam No. 40 o r 45 5 . 0 ( 3 ) A c t i n o l FA-3 0 .9 ( 4 ) Deionized Water 1.5 (5) D i e thy lami noethanol 0 .5 (6) Deionized Water 66.6 ( 7 ) Odor less Minera l S p i r i t s 5 . 0 (8 ) Drakeol 2251 5 . 0 (9) Kaopo l i t e SF 10.0 Procedure:

M e l t (1 ) . (2 ) . and (3 ) t oge the r a t 210F. Mix ( 4 ) and (5), add t o t h e me l t w h i l e s t i r r i n g . Preheat (6) t o 150F and add, s l o w l y a t f i r s t , w h i l e c o n t i n u a l l y s t i r r i n g . Preheat ( 7 ) and (8) t o 150F. e i t h e r separa te l y o r t oge the r , and s t i r i n . Add (9) s lowly , con t i nue s t i r r i n g a t 150F. o r h ighe r , u n t i l t h o r - oughly d ispersed and blended. Shut o f f heat, bu t con t inue s t i r - r i n g u n t i l ba tch c o o l s t o room temperature.

Fo l l ow recommended hand l i ng p r a c t i c e s o f t h e s u p p l i e r s o f each produc t used.

Good i n d u s t r i a l p r a c t i c e s should be used when hand l i ng f 1 ammabl e i ngredi en ts .

SOURCE: Kaopo l i te , I n c . : Suggested Formula t ions

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224 Advanced Cleaning Product Formulations

Auto Cleaner/Pol i sh, S o f t Paste, Emul s i on

I n q r e d i e n t s : ( 1 ) Odor1 ess Kerosene (2) Hoechst Wax S ( 3 ) V i s c a s i l 10,000 (4) O l e i c A c i d (5) Morphol i ne ( 6 ) De ion ized Water ( 7 ) K a o p o l i t e SF (8) De ion ized Water (9) Odorless M ine ra l S p i r i t s ( 1 O ) S i 1 i cone Emul s i o n SM-2035

% by WeiphA 10.0 8 . 0 2 . 5 2 . 0 1.1

24.0 12.0 15.4 2 0 . 0

5 . 0

Procedure: Combine ( 1 ) th rough ( 5 ) and heat t o 210F w i t h a g i t a t i o n .

Prov ide i n t e n s i v e a g i t a t i o n w h i l e i n t r o d u c i n g t h e remain ing i n g r e d i e n t s as desc r ibed below.

S l u r r y t h e K a o p o l i t e SF by s low a d d i t i o n o f ( 7 ) i n t o (6 ) w i t h a g i t a t i o n . A f t e r thorough i n c o r p o r a t i on, add remain ing water (8 ) t o t h e s l u r r y w i t h a g i t a t i o n . Heat s l u r r y t o 150F. Slowly add t h e heated s l u r r y t o t h e ba tch w i t h i n t e n s i v e a g i t a t i o n . A l l ow t i m e f o r thorough i n c o r p o r a t i o n . S lowly add (9 ) t o t h e ba tch w i t h i n t e n s i v e a g i t a t i o n a l l o w i n g t i m e f o r thorough i n c o r p o r a t i o n .

s t i r r i n g u n t i 1 m i x t u r e c o o l s t o packaging temperature o f Change a g i t a t i o n t o a s low s t i r r i n g , add (10) and con t inue

105-1 2OF. Fo l low recommended hand l i ng p r a c t i c e s o f t h e s u p p l i e r s o f

Good i n d u s t r i a l p r a c t i c e s shou ld be used when hand l i ng each p roduc t used.

f 1 ammabl e i ngred i en ts .

"Luster-Powder" Auto Pol i sh

I n q r e d i e n t s : % by Weiqht (1) K a o p o l i t e SF 95.0 (2) M i c r o f i n e VI 3 . 0 ( 3 ) Dimethyl S i l i c o n e , 350 c e n t i s t o k e s 2.0

Procedures:

s l o w l y add ing ( 3 ) u n t i l w e l l mixed.

each produc t used.

SOURCE: Kaopo l i t e , I n c . : Suggested Formula t ions

Dry b l e n d ( 1 ) and (2) t ho rough ly . Cont inue b lend ing , w h i l e

Fo l l ow recommended hand l i ng p r a c t i c e s o f t h e s u p p l i e r s o f

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Auto Cleaners and Polishes 225

Auto C leaner /Po l ish , T h i c k L i a u i d . O i l - E x t e r n a l

I n a r e d i e n t s : % by Weiqht ( 1 ) De ion ized Water 40.2 ( 2 ) K o r t h i x H 2 .1 ( 3 ) Hoechst Wax E 0.2 ( 4 ) Hoechst Wax LP 1 . 4 (5 ) O l e i c Ac id 2.0 ( 6 ) Dimethyl S i l i c o n e , 350 c e n t i s t o k e s 4.0 ( 7 ) Odor less M ine ra l S p i r i t s 32.0 (8 ) K a o p o l i t e SFO-NP 17.2 ( 9 ) Morpho l ine 0.9

Procedure:

w e l l d ispersed. I n a separa te vesse l , m e l t ( 3 ) and ( 4 ) a t 180-190F, add (5 ) , ( 6 ) , and ( 7 ) , r e h e a t i n g as necessary t o m a i n t a i n a t 140-15OF. Add (8) s l o w l y t o t h e o i l m ix tu re , main- t a i n i n g temperature, a g i t a t i n g w e l l u n t i l t ho rough ly d ispersed and smooth, t hen s t i r i n ( 9 ) .

Add t h e water m i x t u r e s l o w l y t o t h e o i l m ix tu re , b lend ing u n t i l smooth. Shut o f f heat and con t inue a g i t a t i o n u n t i l t h e produc t c o o l s t o 9OF.

Fo l l ow recommended hand l i ng p r a c t i c e s o f t h e s u p p l i e r s o f each p roduc t used.

Good i n d u s t r i a l p r a c t i c e s shou ld be used when hand l i ng f 1 ammabl e i ngred i en ts .

Heat (1 ) t o 140-150F and add (21, w i t h good a g i t a t i o n u n t i l

Deterqent-Resi s t a n t Auto/Cl eaner Pol i sh, Th i n L i q u i d

I n q r e d i e n t s : ( 1 ) Stoddard Sol ven t ( 2 ) Odor less Kerosene ( 3 ) Epolene E-10 Wax (4 ) Dow Corn ing 531 F l u i d (5 ) Dow Corn ing 536 F l u i d (6 ) K a o p o l i t e SFO-NP ( 7 ) Span 80 (8) Deion ized Water

% by Weiaht 16.0 10.0 2.0 4.5 0 .8

10.0 1 . o

55.7

Procedure:

r e s u l t s . Add (6 ) s low ly , w i t h v igo rous a g i t a t i o n u n t i l w e l l d i spe rsed and smooth. Add ( 7 ) and r e a d j u s t temperature t o 19OF

I n another vesse l , heat (8 ) t o 19OF, then add t o above m i x t u r e w i t h good a g i t a t i o n . Cont inue a g i t a t i o n , m a i n t a i n i n g tempera ture above 180F u n t i l t ho rough ly mixed, then a g i t a t e s l o w l y w h i l e c o o l i n g t o room tempera ture .

Combine ( 1 ) th rough (5 ) , heat t o 19OF u n t i l c l e a r s o l u t i o n

Fo l l ow recommended hand l i na D r a c t i c e s o f t h e s u p p l i e r s o f _ . each p roduc t used.

f 1 ammabl e i ngred i en ts . Good i n d u s t r i a l p r a c t i c e s shou ld be used

SOURCE: Kaopo l i t e , I n c . : Suggested Formulat

when hand l i ng

ons

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226 Advanced Cleaning Product Formulations

Cream Car Wax

I ngred i en t s : ( 1 ) S i l i c o n e F l u i d L45 (2) S i l i c o n e AFL 40 (3) Carnauba Wax #3 (4 ) Odorless M ine ra l S p i r i t s (5 ) O l e i c Ac id ( 6 ) Deionized Water (7 ) Morphol i ne (8) Kaopo l i t e 1152

% by Weight 4.0 2.0 6.0

29.0 2.0

46.0 2.0 9.0

Procedure:

t i o n t o 19OF u n t i l wax me l t s and a c l e a r s o l u t i o n r e s u l t s . Add (7 ) t o n e u t r a l i z e wax. Then add (2) and t h e remainder o f (43. S l u r r y (8 ) i n t o t h e water w i t h h i g h a g i t a t i o n . Add ho t s o l v e n t s o l u t i o n t o t h e s l u r r y and remove heat w h i l e c o n t i n u i n g t o mix u n t i l pas te p o l i s h reaches 130F. Pour i n t o con ta ine rs .

Fo l low recommended hand l i ng p r a c t i c e s o f t h e s u p p l i e r s o f each produc t used.

Good i n d u s t r i a l p r a c t i c e s should be used when hand l i ng f 1 ammabl e i ngred i en ts .

Combine (l), (3), and (5 ) i n t o h a l f o f ( 4 ) . Heat w i t h a g i t a -

Rubbing ComDound

I n q r e d i e n t s : (1 ) Deionized Water (2) Kaopo l i t e SF (3) Odorless Kerosene ( 4 ) G lyce r ine (5 ) Tr ie thano lamine (6 ) O l e i c Ac id ( 7 ) P ine O i l ( 8 ) S i l t e x 44

% bv Weiqht 52.0

5.6 9.9 25.0

0.5 0.8 0.5 5.7

Procedure: Mix ( 5 ) and (6 ) t o form t e a o l e a t e . Add (1 ) and mix. S lowly

add (3) and emu ls i f y . Add (4 ) w i t h cont inued s t i r r i n g . I n c l u d e ( 2 ) and (8 ) w i t h a g i t a t i o n . Add ( 7 ) f o r perfume.

Fo l low recommended hand l i ng p r a c t i c e s o f t h e s u p p l i e r s of each produc t used.

Good i n d u s t r i a l p r a c t i c e s should be used when hand l i ng f 1 ammabl e i ngred i en ts . Comments :

A f t e r s u i t a b l e rubb ing , p roduc t may be f l ushed o f f w i t h water; o r i f p r e f e r r e d , may be a l lowed t o d r y and then wiped o f f w i t h c lean, d r y c l o t h .

SOURCE: Kaopo l i te , I n c . : Suggested Formula t ions

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Auto Cleaners and Polishes 227

DeterQent-Resi s t a n t Auto Cleaner Po l i sh

Both formulat ions are wa te r - i n -o i l emulsions w i t h exce l l en t g loss and de te rgen t - res i s tan t p roper t i es . I n each, t h e r a t i o o f Dow Corning 536 f l u i d t o Dow Corning 200 f l u i d o r Dow Corning 531 f l u i d i s c r i t i c a l . For example, i f Dow Corning 200 f l u i d i s i ncreased i n Formulation "B" , t h e detergent res is tance w i 11 decrease.

I ng red ien ts : Dow Corning 536 F l u i d Dow Corning 531 F l u i d W i tcami de 51 1 Stoddard Solvent Kaopol i te SF Water Bentone 38 Isopropyl Alcohol (Anhydrous)

Inqredients : Dow Corning 536 F l u i d Dow Corning 200 F l u i d , 12,500 cSt. W i tcami de 51 1 Stoddard Solvent Kaopol i te SF Water Bentone 38 Isopropyl Alcohol (Anhydrous)

Percent by Weight Po l i sh A

1 .oo 6.00 1 .oo

22.00 10.00 59.25 0.50 0.25

Po l i sh B 2.00 2.00 1 .oo

25.00 10.00 59.25 0.50 0.25

Slowly add water and Kaopol i te SF t o mix ture o f o ther ingred- i e n t s . S i f t i n Bentone 38 i f low shear mixing equipment i s used. Solvents other than Stoddard may be used depending on the desired d r y i n g r a t e . Kerosene may be added t o slow the evaporat ion r a t e . Isopar L and Isopar M (Exxon Company) combinations are a l so excel l e n t .

SOURCE: Dow Corning Corp.: Suggested Formulations

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228 Advanced Cleaning Product Formulations

___ Detergent -Res is tan t Auto Cleaner- P o l i s h - P o l i s h 4

-. I nqred i en ts : Percent by Wei n h t W i tcami de 51 1 1 . o Stoddard So lvent * 20.5 K a o p o l i t e SF 10.0 Water 57.0 Dow Corn ing 929 C a t i o n i c Emulsion 11 .5

__ Deterqent-Resi s t a n t Auto Cleaner Pol i sh-Pol i sh B

I n redi-ents: w i :cami de 51 1 Stoddard So lvent * K a o p o l i t e SF Dow Corning 531 f l u i d Water Dow Corning 929 C a t i o n i c Emulsion

Percent by Weight 1 . o

19.5 10.0 2 .0

59.0 8.5

Method:

Dow Corn ing 929 c a t i o n i c emulsion. Add water s l o w l y . Then add Dow Corn ing 929 c a t i o n i c emulsion.

* Other s o l v e n t s may be used depending upon t h e degree o f d r y i n g r a t e d e s i r e d . Kerosene slows t h e evapora t i on r a t e , w h i l e combinat ions o f I s o p a r L and I sopar M (Exxon O i l Co.) a r e a l s o exce l 1 en t s o l ven t s u b s t i t u t e s .

W i th cont inuous a g i t a t i o n , mix a l l i n g r e d i e n t s toge the r except

Auto C1 eaner-Pol i sh

Part: I n g r e d i m A 200 F l u i d - 100 c s

200 F l u i d - 1,000 cs Carnaube Wax, #1 Ye l low Beeswax O l e i c A c i d Kerosene Stoddard Sol ven t

Water

K a o p o l i t e SF Carbopol 934 Water

B Morpho l ine

C Snowf l o s s

Percent by Wei Qht 1 .5 4.5 1 .0 1 . o 2.5 2 .0

18.0 1 .5

16.0 7.0 7.0 0 .1

37.9

~~

Method : Heat p a r t "A" i n g r e d i e n t s t o 79C (175F) t o m e l t waxes

(WARNING: FLAMMABLE). Mix p a r t s "B" and "C" separa te l y . Whi le b lend ing "A" w i t h a high-shear mixer, add phase "B" s l o w l y . M a i n t a i n tempera ture between 71 and 7 9 C (160 and 175F). Remove heat, t hen add phase "C" w i t h s t i r r i n g .

SOURCE: Dow Corn ing Corp.: Suggested Formula t ions

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Auto Cleaners and Polishes 229

L i a u i d S i 1 i cone Car Pol ish

gned t o g i v e a l u s t r o u s , h igh-g loss , p r o t e c t i v e au to sur faces . T h i s suggested f o r m u l a t i o n i s t o produce and can be used as a s t a r t i n g p o i n t e v a r i a t i o n s .

A p o l i s h des f i l m on p a i n t e d s imp le and easy f o r many poss ib

P a r t : I n a r e d i en ts : Percent bv Wei q h t A 200 S i l i c o n e F l u i d by Dow Corning, 350 cs . 4.0

Stoddard So lvent 19.0 Kerosene 2.0 O l e i c Ac id 2 .5

B Morphol i ne 1 .5 Water 16.0

C Snow F loss 14.0 Water 41 .O

Prepara t i on : 1. Mix P a r t A w i t h a high-shear mixer ( C o l l o i d M i 1

mixer ) . 2. S lowly add P a r t B t o P a r t A w h i l e c o n t i n u i n g t o

or Eppenbach

mix. 3 . Cont inue t o mix w h i l e adding P a r t C t o t h e AB combinat ion 4. O l e i c a c i d may be added t o P a r t B, i f des i red , and then

mixed as above. Formula CP-92A

Auto Rinse-Wax Concentrate

I n a r e d i en ts : Percent bv Wei qh t Dow Corning 929 C a t i o n i c Emulsion 33.3 Carnauba Wax 6 .7 Armac-HT 2.0 Water 58.0

Method : M e l t wax w i t h Armac-HT and add t o 9OC (194F) water w i t h

cont inuous s t i r r i n g . Then coo l t o room temperature and add s o l u t i o n t o Dow Corning 929 c a t i o n i c emulsion.

Auto Vinyl-Top P r o t e c t o r

P a r t : I n q r e d i e n t s : Percent by Wei ah t A W i tcami de 51 1 1 .o

200 F l u i d , 1,000 cSt 0 .5 Stoddard So lvent 25.0

B Dow Corning 929 C a t i o n i c Emulsion 12.0 Water 61.5

Method:

cont inuous a g i t a t i o n , add "8" t o "A" .

SOURCE: Dow Corning Corp.: Suggested Formula t ions

Mix p a r t "A" and p a r t "B" i n g r e d i e n t s separa te l y . Then, w i t h

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230 Advanced Cleaning Product Formulations

Soravwax I1

Ina red i ent : KerrMac 600 MSO Tomah Emu1 s i f i e r 827

Ethylene g l yco l b u t y l e ther Add, mix we l l

Add, mix w e l l

Add s lowly t o above, m

pH: 7.90 Recommended D i 1 u t i ons : Appl i ca t i ons : Carwash Notes: Formulation may

mineral seal o i

Water (70-9OF)

Formula T-115

x w e l l

1O:l than i n j e c t 6 oz/car

need s l i g h t adjustment f o r other

Wt% 18.00 15.00

4.00

63.00

Non-Hydrocarbon Soraywax-N-3

Inaredi en t : Water (70-9OF) Tomah Ecowax N-3

Blend i n t o water very s lowly w i t h constant mix ing

Wt% 59.00 41 .OO

Recommended D i l u t i o n s : 1O:l then i n j e c t 6 oz/car Appl icat ions: d r y i n g a i d "Environmentally f r i e n d l y " - e x c e l l e n t f o r regions w i t h hydro-

carbon e f f l u e n t r e s t r i c t o n s Formula T-116

Non-Hydrocarbon Sprawax-N-4

Inq red i ent : Water (70-9OF) Tomah Ecowax N-7

Blend i n t o water very s lowly w i t h constant mix ing

Wt% 61 .OO 39.00

Recommended D i l u t i o n s : 1O:l then i n j e c t 6 oz/car Appl icat ions: Dry ing a i d "Envi ronmental 1 y f r i end1 y"-excel 1 ent f o r regions w i t h hydro-

carbon e f f l u e n t r e s t r i c t i o n s Formula T-116

SOURCE: Tomah Products, I nc . : Suggested Formulations

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Auto Cleaners and Polishes 231

T r a n s o o r t a t i on C1 eaners Wash and Wax 1

I n a r e d i e n t : Water Tomah Q-17-2

Add, mix w e l l Tomah Emu1 s i f i e r Four

Add, mix w e l l Tomah A0-728

Add, mix w e l l Tomah Amphoteric L

Add, mix w e l l Non ion ic Surfactant-HLB 13

Add, mix w e l l

pH: 7.50 Recommended D i 1 u t i o n s : 1 : 10 the use 10 z/car A p p l i c a t i o n s : Wash and Wax, Foam wax Notes: Good v i s c o s i t y , foaming, and beading

Formula T-109

Wash and Wax 2

I n n r e d i en t : Water Tomah Q-17-2 o r Q-14-2

Tomah Amphoteric L Blend w e l l

Blend w e l l

SpG 2 0 / 2 0 F : 1.01 pH: 7.9 Recommended D i l u t i o n s : 1 : lO then use 10 oz/car A p p l i c a t i o n s : Wash and Wax, Foam Wax Notes: More Foam, l e s s beading than Formula CW-109

Formula T-110

P o l i s h o r "Hot Wax"

I n a r e d i e n t : Tomah Emulsion C-340 Union Carbide S i l w e t L7600

Blend i n s l o w l y t o p revent foaming

W S 78.50

1 .so

5.00

8.50

5.00

1.50

Wt% 76.00

8.00

16.00

W S 98.00

2.00

Recommended D i l u t i o n s : 1 oz /car A p p l i c a t i o n s : Auto laundry h o t wax, sea le r wax, p o l i s h wax

Formula T-105

SOURCE: Tomah Products, I n c . : Suggested Formula t ions

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232 Advanced Cleaning Product Formulations

Waxless, P r e s 0 f t e n e d . n - R e s i s t a n t , Cleaner, Paste P o l i s h

I n p r e d i e n t s : P a r t A : Water K a o p o l i t e SF Par t B: L-140 So lvent Dow Corning 02-3225C Par t C : Dow Corning 536 F l u i d Dow Corning 531 F l u i d 50% S o l u t i o n o f Sodium Tween 20

C i t r a t e i n Water

_____ Percent b l W e i qh t

50.0 15.0

9 . 5 7 . 5

1 . o 6 .0 2 .0 1 . o

Load p a r t "A" i n t o a m i x i n g vesse l . S t a r t a g i t a t i o n and mix u n t i 1 un i fo rm. Load p a r t "B" i n t o a g i t a t e d m i x i n g vesse l . Mix f o r a minimum o f 10 t o 15 minu tes . Load Dow Corn ing 531 and 536 f l u i d s . Mix u n t i l a un i fo rm, w a t e r - i n - o i l emulsion i s formed. A f t e r t h e emulsion i s formed, l o a d t h e s o l u t i o n o f sodium c i t r a t e and water . Load t h e Tween 20. Mix u n t i l un i fo rm. F i n a l process th rough a h i g h shear m i x i n g o p e r a t i o n ( i . e . , c o l l o i d m i l l , homogenizer, hydroshear [Gau l i n Corp . ] , o r Cowles M ixe r , o r r e c i r c u l a t e th rough a h i g h shear auger o r c e n t r i f u g a l pump).

Auto-Ri nse Po l i sh

Dow Corn ing 536 f l u i d can be fo rmu la ted as an a u t o - r i n s e p o l i s h f o r e x c e l l e n t water beading and g l o s s . Emulsions o f t h i s f l u i d can a l s o be used as an e x c e l l e n t auto-wash p o l i s h fo rmula .

I n s r e d i e n t s : Dow Corn ing 536 F l u i d I sop ropy l A l coho l , 99 percent G l a c i a l A c e t i c A c i d

Percent by Wei Q h t 44 50

6

Mix t h e a c e t i c a c i d w i t h t h e i s o p r o p y l a l coho l and add t h i s t o Dow Corn ing 536 f l u i d . T h i s concen t ra te has good s h e l f s t a b i l i t y . To use, d i l u t e w i t h water and app ly . One p a r t o f t h e concen t ra te may be added t o 20 p a r t s water f o r e x c e l l e n t water beading and g l o s s p r o p e r t i e s . Apply w i t h a sponge o r c l o t h and r i n s e w i t h water w i t h o u t d ry ing , o r app ly and wipe d r y w i t h a c l o t h .

SOURCE: Dow Corn ing Corp. : Suggested Formula t ions

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16. Car and Truck Wash Compounds

233

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234 Advanced Cleaning Product Formulations

Auto L Truck Care Products Concentrated Car Wash

Water Tetrasodi um EDTA NaOH (50%) Sodium LAS (60%) Sul fo tex 6040s Standamid CD

Usage: 1 p a r t t o 60 p a r t s water

Car Wash (Automatic)

Water TKPP Sodium LAS (60%) Glucopon 425 CS Standamid CD Propylene Glycol nButyl Ether

Usage: 1 p a r t t o 30 p a r t s water

Power Car Wash ( S e l f Service)

Soda Ash Sodium LAS (60%) Glucopon 600 CSUP

Water Standapol A Glucopon 600 CSUP Standamid KD

L% 44 2 4

25 20

5

W t % 60 2

20 10 3 5

W 3 88

4 8

Hand Wash L UDholsterv

W 3 64.5 28.0

5.0 2.5

Procedure:

using moderate a g i t a t i o n . Incorporate c o l o r and fragrance as needed.

SOURCE: Henkel Corp.: Sugoested Formulations

Add i n t h e order l i s t e d , d i s s o l v i n g each ing red ien t completely

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Car and Truck Wash Compounds 235

Car Wash L i q u i d

Alkylbenzene S u l f o n i c Ac id Sodi um Xylene Sul f o n a t e Igepa l CO-710 Tet rapotass ium Pyrophosphate (60% A c t i v e ) Potass i um Hydroxide (45% A c t i v e ) Water

Wt.% 6 . 0

11.5 3 . 0

25.0 2.5

52.0

Procedure: 1 . D i s s o l v e a lky lbenzene s u l f o n i c a c i d i n water . 2. Add sodium xy lene s u l f o n a t e , I gepa l CO-710, Te t rapotass ium

pyrophosphate and potassium hydrox ide , m i x i n g w e l l a f t e r each addi t i on.

3. F i l t e r p roduc t .

Phys ica l P r o p e r t i e s : pH (as i s ) : 9 .5 pH (1%) : 9 .9 V i s c o s i t y : 10 cps S p e c i f i c G r a v i t y : 1.05

Formula TR-0023

Car Wash Powder

Igepa l 03-710 Sodi um T r i p o l yphosphate Sodi um Metasi 1 i c a t e Pentahydrate Sodium Carbonate ( L t . Dens i t y )

Wt.% 10.0 50.0

5 . 0 35.0

Procedure: 1 . Mix I g e p a l CO-710 w i t h Sodium Tr ipo lyphosphate . 2. Add Sodium M e t a s i l i c a t e Pentahydrate and Sodium Carbonate.

Phys i ca l P r o p e r t i e s : Appearance: White, f r e e - f l o w i n g powder pH (1%) : 11 .2 Speci f i c G r a v i t y : 0.73

Formula TR-0022

SOURCE: Rhone-Poulenc: Suggested Formula t ions

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236 Advanced Cleaning Product Formulations

Carwash Shampoo-I I n a r e d i e n t : Water NaOH (50%)

DDBSA ( f r e e a c i d ) Add c a r e f u l l y , mix w e l l

D i s s o l v e we1 1 Tomah Amphoteric

Add, mix w e l l S a l t t o t h i c k e n

Recommended D

A p p l i c a t i o n s : Notes: Very h

Formula T-117

I n a r e d i e n t : Water NaOH f50%)

%% 64.00

5.40

20.60

L 10 .00

q . s l u t i o n s : 1-3 oz . /ga l o r as necessary th rough

Foam brush, shampoo, bucket wash gh foaming, good detergency

au to system

Carwash Shampoo-I1 y&

42.00 6.20

DDBSA ( f r e e a c i d ) 23.80

Laury l e t h e r s u l f a t e , Na s a l t (60%) 15.00

Tomah A0-728 Speci a1 3.00

Tomah Amphoteric L 5.00

Non ion ic Surfactant-HLB 13 5.00

Add c a r e f u l l y , mix w e l l

D i sso l ve we1 1

Add, mix w e l l

Add, mix w e l l

Add, mix w e l l

Add, mix w e l l Recommended D i l u t i o n s : 1-3 oz . /ga l o r as necessary th rough

au to system A p p l i c a t i o n s : Foam brush, shampoo, bucket wash Notes: Very h i g h foaming, good detergency

Formula T-117

I n a r e d i e n t : M ine ra l Seal O i l Tomah Emu1 s i f i e r Four

Add, mix w e l l Non ion ic Surfactant-HLB 13

Add, mix w e l l E thy lene g l y c o l b u t y l e t h e r

Add, mix w e l l Water (70-9OF)

Add s l o w l y t o above, mix w e l l SpG 20/20F: 0.96 pH: 7.90 Recommended D i l u t i o n s : 1O:l then i n j e c t 6 oz /car Appl i c a t i ons: D r y i ng A i d-Carwash Notes: Fo rmu la t i on may need s l i g h t adjustment f o r s p e c i f i c

Spraywax-Drvinq Anent

MSO Formula T-106

W B 20.00 15.00

1 .oo

3.00

61 .OO

SOURCE: Tomah Products, Inc.: Suggested Formula t ions

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Car and Truck Wash CompoundF 237

High O i l S p l i t t i n g V e h i c l e Wash-A

co!vP~nen!s : Water Sodi um Metasi 1 i c a t e Pentahydrate TKPP Sodi um Xyl ene Sul f ona tes 40% Burco TME

~~ H igh O i l S p l i t t i n g -Vehic le Wash-B

Components: Water Sodium M e t a s i l i c a t e Pentahydrate Burco ADS-40 Sodi um Xylene Sul f ona tes 40% Burco TME

Add i n t h e o rde r l i s t e d . Blend u n t i l d i s s o l v e d a d d i t i o n .

~- Non-Phosphate Truck Wash

Component: Water 45% KOH Sodium M e t a s i l i c a t e (Pentahydra te) Sodi um Xyl ene Sul f ona tes 40% Burcosperse LP Burco TME Dodecyl benzene Sul f o n i c Ac id B u t y l Propasol D-Li monene

% by Weiqht 71 . 5 1 0 . 0

2 . 5 6 . 0

1 0 . 0

% by Weiqht 7 3 . 5 10 .0 5.0 1 . 5

1 0 . 0

between each

% by Weiqht 6 3 . 5

4 . 5 5 . 0

1 0 . 0 5.0 4 . 0 3.0 4 . 0 1 . o

Procedure:

between each a d d i t i o n .

SOURCE: B u r l i ngton Chemical Con , I n c . : Suggested Formula t ions

Add components i n t h e o rde r l i s t e d . Blend u n t i l un i fo rm

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238 Advanced Cleaning Product Formulations

Rhodapon SB A lcodet SK Tetrapotassium Pyrophosphate Sodi um Metasi 1 i c a t e Water Perfume W e

L i q u i d Car Wash-Formula A Wt.% 18.0

8 . 0 3.0 2.0

69.0 Q . S . Q . S .

L i q u i d Car Was -Formu

Rhodapon SB Rhodasurf 25-9 Tetrapotassium Pyrophosphate Sodi urn Metasi 1 i c a t e Water Perfume Dye

nB Wt.% 18.0

8 . 0 3.0 2 .0

69.0 Q . S . Q . S .

Procedure:

i n water . Add Rhodapon SB. A g i t a t e u n t i l c l e a r . Add A lcodet SK and Rhodasurf 25-9 and mix u n t i l u n i f o r m and c l e a r . Add perfume and dye, as des i red . Phys ica l P r o p e r t i 8s:

Disso lve Tet rapotass ium Pyrophosphate and sodium m e t a s i l i c a t e

Appearance: C lea r l i q u i d , dyed t o p re fe rence pH: 12.0 S p e c i f i c G r a v i t y : 1 .03 V i s c o s i t y : <50 cps Formula TR-0020

Spray-On Car Wash Concent ra te "Grease and Grime" Remover

Wt.% Rhodacal A-246/L 5.0 Rhodacal 330 20.0 Rhodapon BOS 3.3 A lcodet SK 5.0 Water 66.7 Procedure: 1. Charge water t o a vessel equipped w i t h a g i t a t i o n . 2. Add Rhodacal A-246/L and Rhodapon 00s t o ( 1 ) above. Mix u n t i l

u n i f o r m (5-10 m inu tes ) . 3 . Add Rhodacal 330 and A lcodet SK t o (2 ) above. Mix u n t i l

u n i f o r m (15-30 m inu tes ) . Phys ica l P r o p e r t i e s :

Appearance: V i scous, ge l -1 i ke 1 i q u i d pH, as i s : 9 .0 S p e c i f i c G r a v i t y : 1.02-1 .04 V i s c o s i t y : t50 cps Formula TR-0021

SOURCE: Rhone-Poulenc: Suggested Formula t ions

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Car and Truck Wash Compounds 239

L i qu i dTr .uc k Wash

Water M i rano l FBS Igepa l CA-630 Dowanol EB Potass i um Hydroxide (45%) T a l l O i l Te t rapotass ium Pyrophosphate Sodium M e t a s i l i c a t e , Pentahydrate

W t . 2 73.6

6 . 0 3.0 2.0 4 . 0 3 . 4 4 . 0 4 . 0

Procedure: Premix t h e T a l l O i l and B u t y l C e l l o s o l v e . Add t h e water t o

t h e m ixe r . Add t h e Sodium M e t a s i l i c a t e , t h e Potassium Hydroxide and t h e TKPP. Add t h e M i rano l FBS and Igepa l CA-630. Add t h e T a l l O i l / B u t y l C e l l o s o l v e premix . Mix u n t i l un i fo rm.

Phys ica l P r o p e r t i e s : Appearance: C1 ea r , amber 1 i qu i d pH, as i s : 12 .7 S p e c i f i c G r a v i t y : 1 .OB V i s c o s i t y : t 5 0 cps

Formula TR-0029

- L i q u i d Truck Wash

Water M i rano l FBS Rhodafac RA-600 Igepa l CA-720 Cheel ox BF-13 Tet rapotass ium Pyrophosphate Potass i um Hydroxide (45%) Sodium M e t a s i l i c a t e Pentahydrate Arcoso lv PTB

Wt.% 63.0

4 . 0 2.0 2 . 0

17.5 1 . o 6.0 2 .0 2.5

Procedure: Add t h e i n g r e d i e n t s i n t h e o rde r l i s t e d and mix u n t i l un i fo rm.

Phys ica l P r o p e r t i e s : Appearance: C lea r , y e l l o w l i q u i d pH, as i s : 12.9 S p e c i f i c G r a v i t y : 1.10 V i s c o s i t y : t 5 0 cps

Formula TR-0030

SOURCE: Rhone-Poulenc: Suggested Formula t ions

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240 Advanced Cleaning Product Formulations

Non-Phosohate Truckwash

Ina red ien t : Water KOH (45%)

Add Na M e t a s i l i c a t e Pentahydrate

D i ssolve Tomah A l k a l i Sur factant o r Amphoteric 400

Add, mix w e l l Burcosperse LP

Add, mix we l l Burco TME

Add, mix we l l DDBSA ( f 1 ake)

Add, mix w e l l Dowanol PNB

Add, mix we l l d-1 imonene

Add, mix w e l l

pH: 13.60-13.66 Recommended D i l u t i o n s : 10-2O:l App l i ca t i ons : Truckwash

Formula T-104

S e l f Demul s i f y i nq Truckwash

Inaredi ent : Water Na M e t a s i l i c a t e Pentahydrate

D i ssol ve KOH (45%)

Add, mix w e l l EDTA o r NTA

Dissolve Tomah AO-14-2

Add, mix we l l Tomah P-17-2

Add, mix we l l Tomah Tekstim 8741

Add, mix w e l l Tomah A1 k a l i Surfactant

Add, mix w e l l

W t % 64.50 4.50

5.00

9.00

5.00

4.00

3.00

4.00

1 .oo

W t % 85.70 4.20

2.60

1.80

1 .oo

1 .oo

2.00

1.70

Recommended D i l u t i o n s : 10-25:l Appl icat ions: Pressure Wash-Trucks Notes: Useful detergent which a1 so performs f i r s t "sp l i t "

o f o i l / g rease i n separators Formula 1-101

SOURCE: Tomah Products, I n c . : Suggested Formulations

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Car and Truck Wash Compounds 241

T r a n s p o r t a t i o n C1 eaners Car Wash-Sol i d s

Manual-

STPP Sodi um metasi 1 i c a t e anhydrous An ion ic (40% a c t i v e ) Non ion ic Sodi um S u l f a t e

STPP Sodium m e t a s i l i c a t e anhydrous Non ion ic Sodium S u l f a t e

__ Commercial H igh P_erformance

STPP Sodium m e t a s i l i c a t e anhydrous Noni on i c

Car Wash-Liquid-I

Water TKPP (60% s o l u t i o n ) L i q u i d sodium s i l i c a t e Sodium xy lene s u l f o n a t e Non ion ic*

35-50% 6

20 4

balance

35-50%

10-15 15

balance

75-80% 10

10-15

Q.S 15-20

4- 5 10-15

5

*C12-15 l i n e a r , p r imary a l coho l e t h o x y l a t e o r equ iva len t , such as Neodol 25-9 (She1 1 ) .

Car Wash-Liquid-I1

Water (de ion i zed ) TKPP (60% s o l u t i o n ) L i q u i d po tass i um s i 1 i c a t e Phosphate e s t e r Non ion ic**

Q . S . 10-12

2- 3 0- 1 3- 4

* *Mod i f i ed e t h o x y l a t e d s t r a i g h t c h a i n a l coho l o r equ iva len t , such as P l u f a f a c D-25 (BASF) .

Suggested Formula t ions SOURCE: FMC Corp.: Detergent A p p l i c a t i o n s B u l l e t i n No. 4 :

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242 Advanced Cleaning Product Formulations

Transpor tat ion Cleaners T r a f f i c F i l m Remover

Ina red i ent : Wt% Water 82.00 Sodium Metas i l i ca te . anhydrous 1 .oo

EDTA or NTA 10.00

Tomah AO-14-2 2.00

Tomah (2-17-2 2.00

Nonionic Surfactant-HLB 13 3.00

D i ssol ve

Add, mix w e l l

Add, mix w e l l

Add, mix w e l l

Add, mix w e l l Recommended D i l u t i o n s : 10-25:l Appl icat ions: Truckwash, t r a f f i c f i l m remover Notes: Has technology t h a t "releases" s o i l from sur face

Formula T-107

Viscous W i r e Wheel Cleaner Inq red i ent : Wt% Water 71 .OO Phosphoric Aci d (75%) 22.00

Oxal ic Acid 1 .oo

Tomah Acid Thickener* 3.00

S a l t (NaC1) 3.00

V iscos i t y (cps): 693

Add, mix, cool

D i sso l ve

Add, mix w e l l

Add, d i sso l ve w i t h mix ing

Recommended D i l u t i o n s : 10-2O:l Appl icat ions: Metal c leaning, v e r t i c a l surface cleaning,

Notes: *Mix Ac id Thickener p r i o r to use i n order t o assure descal i ng

homogeneity. Rinse w e l l a f t e r use. Formula T-112

G l ass Cleaner Ina red i ent : Deionized Water I P A (99%)

Add, mix w e l l Tomah Amphoteric

Add, mix w e l l Propylene g l y c o l

Add, mix w e l l

N

n-buty l e ther

Dye/perfume op t iona l Recommended D i 1 u t i ons : as- i s Appl icat ions: au to / t ruck windshie ld wiper f l u i d Notes: Dr ies q u i c k l y , wipes clean, non s t reak ing

Formula T-113

SOURCE: Tomah Products, I n c . : Suggested Formulations

Wt% 69.70 25.00

0.30

5.00

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Car and Truck Wash Compounds 243

Truck Wash Detersent Fo rmu la t i on - I

Sodium metas i l i ca te -5H20 TSP c r y s t a l s 40% a c t i v e a n i o n i c s u r f a c t a n t Nonionic s u r f a c t a n t

Truck Wash Deterqent Fo rmu la t i on - I1

Sodium metas i l i ca te -5H20 TSP c r y s t a l s Sodium s u l f a t e 90% a c t i v e a n i o n i c s u r f a c t a n t Noni on i c s u r f a c t a n t

A1 umi num Truck Body C leaner /Br i gh tener - I

Phosphoric Ac id (85%) Nonionic NaHF2 Water

Aluminum Truck Body C leaner /Br igh tener - I1

Phosphoric Ac id (85%) Noni on i c H y d r o f l u o r i c a c i d (48%) Water

A l u m i n u m Truck Body C leaner /Br iqh tener - I11

Phosphoric Ac id (85%) Noni o n i c Butoxyethanol Water

SOURCE: FMC Corp.: Detergent A p p l i c a t i o n s B u l l e t i n No Suggested Formula t ions

32% 10% 10% 8%

21% 6.6%

33.5% 6.6% 5.3%

35-40% 5-10 1- 2

balance

10% 4

15 balance

47.2%

16.0 34.0

2

4 :

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244 Advanced Cleaning Product Formulations

Truck Wash L i a u i d

Igepal CO-630 Rhodapex CO-436 A1 kami de OC-212/S Cheel ox BF-13 Ethylene G1 ycol Monobutyl Ether Water

Wt.% 3.0 3.5 2.0 3.5 3.0

85.0

Procedure: 1. Dissolve su r fac tan ts Igepal CO-630, Rhodapex CO-436 and

2. Add Cheelox BF-13. Mix w e l l . 3. Add Ethylene Glycol Monobutyl Ether.

Physical Proper t ies: pH (as i s ) : 9.9 pH (1%): 9.6 V iscos i t y : 10 cps S p e c i f i c Grav i t y : 1.01

Formula TR-0025

A1 kami de DC-212/S i n water.

Economy Truck Wash High-pressure S w a y

Igepal CO-660 Cheel ox BF-13 Sodium Xylene Sul fonate Water

Procedure: 1. Dissolve Sodium Xylene Sul fonate i n water. 2. Add Igepal CO-660. M i x thoroughly. Add Cheelox BF 13.

Physical P roper t i 8s: pH (as i s ) : 10.3 pH (1%): 10.1 V iscos i t y : 10 cps S p e c i f i c Grav i t y : 1 .02

Formula TR-0024

SOURCE: Rhone-Poulenc: Suggested Formulations

Wt.% 3.0 1 . o 1.5

84.5

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17. Whitewall Tire Cleaners

245

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246 Advanced Cleaning Product Formulations

Whi tewa l l T i r e Cleaner I

I n q r e d i en t : S o f t Water Na m e t a s i l i c a t e pentahydra te

KOH (45%)

D ie thy lene g l y c o l b u t y l e t h e r

Noni on i c HLB-13

Tomah Q-17-2

D isso lve , mix w e l l

Add, mix w e l l

Add, mix w e l l

Add, mix w e l l

Add, mix w e l l

Wt% 81 .oo

4 . 0 0

2.00

6.00

5.00

2.00

SpG 20/20C: 1.039 pH: 12.9 Recommended D i l u t i o n s : a s - i s A p p l i c a t i o n s : Rinse t i r e f i r s t , app y , then r i n s e aga n

W h i t e w a l l T i r e C leaner - I1

W B 79.00

I n a r e d i e n t : S o f t Water Na m e t a s i l i c a t e pentahydra te

STPP

D ie thy lene g l y c o l b u t y l e the r

Non ion ic HLB-13

Tomah Q-17-2

D isso lve , mix w e l l

D isso lve , mix w e l l

Add, mix w e l l

Add, mix w e l l

Add, mix w e l l

SpG 20/20C: 1.039 DH: 13.0

4 . 0 0

2.00

6.00

5.00

2.00

Recommended D i 1 u t i ons : as- i s A p p l i c a t i o n s : Rinse t i r e f i r s t , app ly , then r i n s e aga in

SOURCE: Tomah Products, I n c . : Formula S-110

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Wtitewall Tire Cleaners 247

Wh-ewall T i r e C leaner - I

STPP TSPP TSP c r y s t a l s L i q u i d sodium s i l i c a t e An ion ic Non ion ic

Whitewal-1 T i r e C leaner - I1

STPP TSPP TSP C r y s t a l s Sodium m e t a s i l i c a t e , anhydrous Ani on i c Non ion ic

L i sui d W h i tewa l 1 T i r e C l eaner-Tvpe I Concen t ra t i on i n Order o f A d d i t i o n : Ma te r i a1 : Dei on i zed water TKPP (60% s o l u t i o n ) TSP C r y s t a l s Potassium s i l i c a t e ( K a s i l #6) Sodium xy lene s u l f o n a t e (40% s o l u t i o n ) Neodol 25-9 B u t y l c e l l o s o l v e (E thy lene G lyco l Mono B u t y l E the r )

L i q u i d W h i tewa l 1 T i r e C l eaner-Type I I Concent ra t ion i n Order o f A d d i t i o n : Ma te r i a1 : De ion ized water TKPP (60% s o l u t i o n ) TSP C r y s t a l s Potass i um s i 1 i c a t e (Kasi 1 #6) Preblend and add as a u n i t : Sodium xy lene s u l f o n a t e (40% s o l u t i o n ) B u t y l C e l l o s o l v e (E thy lene G lyco l Mono B u t y l E the r ) Su l f ram in 60

SOURCE: FMC Corp. : Detergent A p p l i c a t i o n s B u l l e t i n No.4: Suggested Formula t ions

30 25 14 16 10 5

30 25 10 20 10

5

60.5% 8.0 7.0 4.0

11.4 4.5 4.6

58.3% 10.0 7.0 4.5

6.5 4.0 9.7

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248 Advanced Cleaning Product Formulations

W h i tewa l 1 T i r e C1 eaner L i md

I gepa l CA-630 Rhodaf ac RA-600 M-Pyrol N-Methyl-2-Pyrrol idone Sodium M e t a s i l i c a t e , Anhydrous Sodi urn T r i po l yphosphate Potassi um Hydroxide Water

Wt.% 2.0 6 .0 2.0 3.0 5 . 0 1 .5

8 0 . 5

Procedure: 1 . D i sso l ve Sodium M e t a s i l i c a t e , Anhydrous, Sodium Tr ipo lyphos-

2. Add Igepa l CA-630, Rhodafac RA-600, and M-Pyrol separa te l y , phate and Potassium Hydroxide i n t o water .

m ix ing w e l l a f t e r each a d d i t i o n .

Phys ica l P r o p e r t i es : pH (as i s ) : 13.3 pH (1%): 10.7 V i s c o s i t y : 10 cps S p e c i f i c G r a v i t y : 1 .03

Formula TR-0027

W h i t e w a l l T i r e Cleaner Concentrate

Water Mi rano l FBS Sodium M e t a s i l i c a t e , Pentahydrate Potassium Hydroxide (45%) Butoxyethanol

Procedure: Add i n g r e d i e n t s i n o rder l i s t e d . Mix u n t i l un i fo rm.

Phys ica l P r o p e r t i e s : Appearance: C1 ear, ye1 1 ow 1 i q u i d pH, as i s : 12.7 V i s c o s i t y : (50 cps Speci f i c G r a v i t y : 1 .16

Formula TR-0031

SOURCE: Rhone-Poulenc: Suggested Formula t ions

Wt.% 48.0 22.0 25 .0

3.0 2.0

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Whitewall Tire Cleaners 249

WW l i r e Cleaner 1 @

67.40 5 .00

I n e r e d i e n t : Water STPP

KOH (45%)

42 Sodium S i l i c a t e 3.22/1

Tomah A l k a l i S u r f a c t a n t

Non ion ic Surfactant-HLB 13

D i s s o l ve

Add, mix w e l l

Add, mix w e l l

Add, mix w e l l

Add, mix w e l l SpG 20/20F: 1 .15 pH: 13.00 Recommended D i l u t i o n s : 5-1O:l A p p l i c a t i o n s : Carwash Notes: White w a l l t i r e c leaner

Formula T-100

Whi tewa l l T i r e Cleaner 2 (Non-Caustic1 I n n r e d i e n t : Water Na M e t a s i l i c a t e Pentahydrate

D i sso l ve Non ion ic Surfactant-HLB 13

Add-Mix we1 1 Tomah A l k a l i S u r f a c t a n t

Add-Mix w e l l SpG 20/20F: 1.16 pH: 12.80 Recommended D i 1 u t i ons : 5-20 : 1 A p p l i c a t i o n s : Carwash WW t i r e p respray Notes: Non c a u s t i c , e f f e c t i v e WW c leaner

Formula T - I 0 3

Whi tewa l l l i r e Cleaner 3 I n n r e d i e n t : S o f t Water l r i sod i um Phosphate

Na M e t a s i l i c a t e Pentahydrate

Tomah A l k a l i S u r f a c t a n t

Non ion ic Surfactant-HLB 13

D i s s o l v e

D i sso l ve

Add, mix w e l l

Add, mix w e l l pH: 13.44 Recommended D i l u t i o n s : 5-1O:l A p p l i c a t i o n s : Carwash

Formula T-1 11

SOURCE: Tomah Products, I n c . : Suggested Formula t ions

15.60

8.00

2.00

2.00

W t % 70.00 25.00

2.00

3.00

W S 79.60 11.60

5.00

2.50

1.30

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18. Miscellaneous

250

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Miscellaneous 251

Brake C1 eaner

Water Burco NPS-816 Burco TME Burco SXS-40% B u t y l Propasol Burcosperse AP L i q u i d

65 5 5 5 5

15

I f des i red , can be made more a l k a l i n e - add smal l percentage o f sodium m e t a s i l i c a t e , a d j u s t l e v e l o f XS r e q u i r e d t o hydro- t r o p e

Maq Wheel Cleaner

Water KOH 45% Burcofac 9125 Burco TME Sodium M e t a s i l i c a t e , pentahydra te STPP Burco BSGH-270 *Dequest 2066

* From Monsanto o r use equ iva len t

Procedure:

each addi t i on.

Note:

Add components i n o rde r l i s t e d . S t i r u n t i l h

% by Wei- 74.55

2.45 4.0 5 . 0 2 .0 2 .0 5 . 0 5 .0

mogen ous betwe n

T o t h i c k e n , add smal l q u a n t i t i e s o f Sodium S tea ra te t o o b t a i n des i r e d v i scos i t y .

Concrete F loo r C1 eaner

Componen- Water TSP C r y s t a l sxs-40% Burco terge DG-40 B u t y l Propasol M ine ra l Spi r i t s

% by Weiqht 51 .O

7.5 6 .5

25.0 5 . 0 5.0

Procedure: Add components i n t h e o rde r l i s t e d . S t i r u n t i l homogeneous

between each a d d i t i o n . T h i s f o r m u l a t i o n p rov ides e x c e l l e n t removal o f o i l s t a i n s ,

d i r t and o t h e r s o i l s . For heavy du ty a p p l i c a t i o n s app ly as i s Some "scrubb ing" w i 11 a s s i s t o i 1 removal. Rinse w i t h water . L i g h t e r d u t y a p p l i c a t i o n s can use an aqueous d i l u t i o n o f t h e concen t ra te .

Source: B u r l i n g t o n Chemical Co., I n c . : Suggested Formula t ions

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252 Advanced Cleaning Product Formulations

L i q u i d Aluminum Enaine B lock Cleaner

Water Sodium M e t a s i l i c a t e , Anh. Mi rano l FBS M i r ano l JEM Conc. Alcodet HSC-1000 D-Li monene

Wt.% 82.5

4 . 5 5 . 0 2.0 4.0 2 .0

Procedure:

Add t h e remaining components, w i t h a g i t a t i o n , i n t h e order l i s t e d . Premix t h e D-Limonene w i t h t h e Alcodet HSC-1000 and add toge the r .

Typ ica l P r o p e r t i es : Appearance: C lear , ye l l ow t o amber l i q u i d pH, Conc.: 12.75 pH, 10%: 12.15 S p e c i f i c G r a v i t y : 1.04 V i s c o s i t y : <50 cps

Formula TR-0032

Completely d i s s o l v e t h e Sodium M e t a s i l i c a t e i n t h e water.

Foami ng Engine C1 eaner

Alcodet 260 Rhodacal 330 Water I sopar " K "

Wt.% 2.0 8.0 80.0 10.0

Procedure: 1 . Add A lcodet 260 and Rhodacal 330 t o water a t ambient tempera

2. Add I sopar K a t ambient temperature. S t i r u n t i l d i sso l ved t u r e , s t i r u n t i l d i sso l ved (10-15 m inu tes ) .

( 3 0 m i nu tes) . Phys ica l P roper t i es :

Appearance: C lear l i q u i d pH, as i s : 7.5 Speci f i c G r a v i t y : 0.99 V i s c o s i t y : 10 cps

Formul a t i on TR-0019

SOURCE: Rhone-Poulenc: Suggested Formula t ions

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Miscellaneous 253

I n g r e d i e n t . P a r t A :

( 2 ) V i s c a s i l 10,000 ( 3 ) O l e i c A c i d ( 4 ) I s o p a r M ( 5 ) Hoechst Wax E P a r t B: ( 6 ) D e i o n i z e d Water ( 7 ) K a o p o l i t e 1168 ( 8 ) K a o p o l i t e SF ( 9 ) M o r p h o l i ne ( 1 0 ) C a r b o p o l 934 ( 1 1 ) I s o p a r M

P rocedure : Add ( 7 ) and ( 8 ) t o

smooth, w h i l e h e a t i n g t a i n i ng t e m p e r a t u r e , s u n t i l f r e e f r o m c o a r s e

( 1 ) SF-96 (350 )

( 12 ) SF- 1 706

L i g u i d Boa t P o l i s h % by Weight

3 .50 1 . o o 1 . 5 0

10.00 1 . 5 0

65 .65 7 . 5 0 2 . 5 0 1 .60 0 . 2 5 3 . 0 0 2 . 0 0

6 ) ( P a r t B ) w i t h s t r o n g a g i t a t i o n u n t i l o 150F. C o n t i n u i n g a g i t a t i o n and main- o w l y add ( 9 ) and ( l o ) , and s t i r a c t i v e l y a g g l o m e r a t e s .

I n a n o t h e r v e s s e l , h e a t ( l ) , ( 2 ) , ( 3 ) , ( 4 ) , and ( 5 ) ( P a r t A) t o 150F and b l e n d t h o r o u g h l y . Add t o P a r t B m i x t u r e , m a i n t a i n 150F and m ix w e l l . S t i r ( 1 1 ) and ( 1 2 ) , h e a t t o 150F, and add t o t h e m i x t u r e . C o n t i n u e moderate a g i t a t i o n w h i l e c o o l i n g t o f i l l i n g t e m p e r a t u r e .

P a s t e Boa t P o l i s h I n g r e d i e_n=; K b r ~ w e i s h t P a r t A : ( 1 ) SF-96 (35 ) 4 .50 ( 2 ) V i s c a s i l 10,000 2 . 0 0 ( 3 ) Hoechst Wax S 5 . 0 0 ( 4 ) Hoechst Wax OP 1 . o o ( 5 ) S t e a r i c A c i d 1 . o o ( 6 ) I s o p a r M 24.00 P a r t 0 : ( 7 ) D e i o n i z e d Water 44.80 ( 8 ) Morphol i ne 0 . 7 0

P a r t C : ( 1 0 ) I s o p a r M 5.00

( 9 ) K a o p o l i t e 1168 10.00

( 1 1 )SF-1 706 2.00 P rocedure :

a t i o n . P r o v i d e i n t e n s i v e a g i t a t i o n w h i l e i n t r o d u c i n g t h e rema in - i ng i n g r e d i e n t s .

( P a r t 8) S l o w l y add (9 ) i n t o ( 7 ) w i t h a g i t a t i o n , t h e n add ( 8 ) and h e a t t o 150F. S l o w l y add P a r t B t o P a r t A w i t h i n t e n s i v e a g i t a t i o n . A l l o w t i m e f o r t h o r o u g h i n c o r p o r a t i o n .

t o 150F. S low a g i t a t i o n on m i x t u r e ( P a r t A + P a r t B ) , add P a r t C t o m i x t u r e , and c o n t i n u e s t i r r i n g u n t i l m i x t u r e c o o l s t o p a c k a g i n g t e m p e r a t u r e o f 105-12OF. SOURCE: K a o p o l i t e , I n c . : Suggested F o r m u l a t i o n s

( P a r t A ) Combine ( 1 ) t h r o u g h ( 6 ) and h e a t t o 210F w i t h a g i t -

( P a r t C ) I n a s e p a r a t e c o n t a i n e r , m i x ( 1 0 ) and ( 1 1 ) and h e a t

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254 Advanced Cleaning Product Formulations

Locomotive Cleaner I

I nq red i ent : Water Phosphoric Acid (75%)

Add, mix, cool Oxal ic Acid

Dissolve Tomah Acid Thickener

Add, mix w e l l S a l t (NaC1)

Dissolve w i t h mix ing V iscos i t y (cps): 693 Recommended D i l u t i o n s : 0-10: 1 Appl icat ions: Metal c leanine, r u s t removal, descal inp Notes: Mix Acid Thickener p r i o r t o use i n

homogenei t y

Locomoti ve Cleaner I I Insred i ent : Water Phosphoric Acid (75%)

Add, mix, cool Oxal ic Acid

D i ssol ve Tomah Acid Thickener

Add, mix w e l l S a l t (NaC1)

Dissolve w i t h mixing V i s c o s i t y (cps) : 112 Recommended D i l u t i o n s : 0-1O:l App l i ca t i ons : Metal c leaning, r u s t remova Notes: Mix Acid Thickener p r i o r t o use i n

homogenei t y

Locomotive Cleaner I11 Inp red i ent : Water Phosphoric Acid (75%)

Add, mix, cool Oxal i c Acid

D i ssol ve Tomah Acid Thickener

Add, mix we l l S a l t (NaC1)

Dissolve w i t h mixing V i s c o s i t y (cps) : 2275 Recommended D i l u t i o n s : 0-1O:l Appl icat ions: Metal c leaning, r u s t remova Notes: Mix Acid Thickener p r i o r t o use i n

hmogenei t y

SOURCE: Tomah Products, I nc . : Formula T-114

order t o

, descal order t o

, descal order t o

W B 71 . O O 22.00

1 .oo

3.00

3.00

- assure

W B 72.00 22.00

1 .oo

2.00

3.00

ng assure

Wt% 71 .OO 21 .oo

1 .oo

2.00

5.00

ng assure

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Miscellaneous 255

P o l i s h i n n Cleaner f o r P l a s t i c Windows

Ing red ien ts : ( 1 ) De ion ized Water ( 2 ) Tetrasodium Pyrophosphate ( 3 ) Potassium Tr ipo lyphosphate ( 4 ) K a o p o l i t e SF o r 1168 ( 5 ) Stepanate X (6 ) Synthrapo l N

4 . 0 2 .5

12.5 5 . 0

12 .5

Procedure:

a g i t a t i o n , c o n t i n u i n g u n t i l we l l -d i spe rsed and smooth. Reduce a g i t a t i o n t o avo id foaming, s t i r i n ( 5 ) and ( 6 ) .

each produc t used.

Comments:

p o l i s h i n g a c t i o n t o t h e f o r m u l a t i o n .

D isso lve ( 2 ) and ( 3 ) i n ( 1 ) . Add ( 4 ) s l o w l y w i t h v igorous

Fo l l ow recommended hand l i ng p r a c t i c e s o f t h e s u p p l i e r s o f

Use o f K a o p o l i t e 1168 g i ves more aggress ive c l e a n i n g and

Hard-surface Cleaner/Wax _(May Be Aerosol Loaded)

I n q r e d i e n t s : % by Weight ( 1 ) A r l a c e l 85 1 . o ( 2 ) Hoechst Wax E 1 . o ( 3 ) Dow Corning 200 F l u i d , 350 c e n t i s t o k e s 4 . 0 ( 4 ) Odor less M ine ra l S p i r i t s 34.0 ( 5 ) K a o p o l i t e SF 13.0 ( 6 ) De ion ized Water 47.0

Procedure:

h e a t i n g t o 175-18OF. Add ( 5 ) s l o w l y , s t i r r i n g v i g o r o u s l y u n t i l we1 1 - d i spersed and smooth.

Heat ( 6 ) i n separa te vessel t o 175-180F, and add s l o w l y t o above m i x t u r e w i t h moderate s t i r r i n g . Shut o f f heat, b u t con t inue moderate s t i r r i n g u n t i l p roduc t c o o l s t o 9OF o r below.

each produc t used.

f lammable i n g r e d i e n t s .

SOURCE: Kaopo l i t e , I n c . : Suggested Formula t ions

D i s s o l v e ( l ) , ( 2 ) , and ( 3 ) i n ( 4 ) w i t h moderate s t i r r i n g w h i l e

Fo l l ow recommended hand l i ng p r a c t i c e s o f t h e s u p p l i e r s o f

Good i n d u s t r i a l p r a c t i c e s shou ld be used when hand l i ng

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Section 111 Trademarked Raw Materials

256

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Trademarked Raw Materials 257

RAW MATERIAL A 2447

Ac id Foamer

A c r i tamer 940

Acr i tamer 941

Acryso ASE 108

Acryso 644

A c t i n o FA-3

Acusol 445

Acusol 505N

Acusol 810

Acusol 820

A e r o s i l 200

A1 codet HSC-1000

A1 codet MC-2000

A lcodet SK

A lcodet 260

A1 kami de DC-2 12/M

A1 kami de DC-212/S

A1 rosperse

Amphotensid 0 4

Antarox BL-225

Antarox BL-240

Antarox BL-330

Antarox L-61

CHEMICAL DESCRIPTION Sodium s i l i c a t e

C a t i o n i c s u r f a c t a n t

A c r y l i c polymer t h i c k e n e r

A c r y l i c polymer t h i c k e n e r

T a l l o i l f a t t y a c i d

Detergent polymer

Detergent polymer

Detergent polymer

Detergent polymer

S i l i c a

E thoxy la ted mercaptan

E thoxy la ted mercaptan

E thoxy la ted mercaptan

E thoxy la ted mercaptan

Noni on i c ami de s u r f a c t a n t . 2 : 1 a1 kanol ami de

Non ion ic amide s u r f a c t a n t . 1 :1 d ie thano lamide.

So lvent s o l u b l e s u r f a c t a n t

Amphoteric s u r f a c t a n t

Non ion ic . Capped e t h o x y l a t e .

Non ion ic . Capped e t h o x y l a t e .

Non ion ic . Capped e t h o x y l a t e .

Non ion ic . Poloxamer 181.

SOURCE PQ

Tomah

Rohm&

Rohm&

A r i zon

Rohm&

Rohm&

Rohm&

Rohm&

Deguss

Rhone

Rhone

Rhone

Rhone

Rhone

Rhone

Pai s-

Zshcim

Rhone

Rhone

Rhone

Rhone

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258 Advanced Cleaning Product Formulations

RAW MATERIAL Arcosolv PTB

A r lace l C

Ar lacel 85

A r lace l 186

Armac-HT

Avanel S-70

Avanel S-74

CHEMICAL DESCRIPTION Sol vent

Sur factant

Sur factant

Glycery l o lea te (and) propylene g l yco l su r fac tan t

A1 i pha t i c ami ne acetate

Sodium l i n e a r a1 k y l po lyether

Anionic su r fac tan t

Bentone 34

Bentone 38

i n g 8 suspend

i n g 8 suspend

Be Square, White 190/195 Wax

B i l t p l a t e s 156 Suspending agent

Ge 1

Ge 1

ng agent

ng agent

Bi o-Soft 5-100 Alkylbenrene s u l f o n i c ac id ,

Bio-Terge PAS-8S Sodi um 1 -octane su l fonate

B r i j 30 Sur factant

B r i t e s i l C24 Hydrous Sodium P o l y s i l i c a t e

B r i t e s i 1 H20 Hydrous Sodi um Polys i 1 i cate

Burcene 100

Burco ADS-40 Prop r ie ta ry Tex t i 1 e Auxi 1 i ary

Burco BSGH-270 Prop r ie ta ry T e x t i l e A u x i l i a r y

Burco BSGH-400 Prop r ie ta ry T e x t i l e A u x i l i a r y

Burco EHS Propr i e ta ry Tex t i 1 e Auxi 1 i ary

Burcofac 9125

SOURCE Arco

I C I

I C I

I C I

Akzo

PPG

PPG

Rheox

Rheox

P e t r o l

Vander

l i n e a r Stepan

Stepan

I C I

PO

PQ

Bur l i n

Bu r l i n

Bu r l i n

Bur l i n

Bu r l i n

Bu r l i n

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Trademarked Raw Materials 259

Burco NPS-225 P r o p r

B u r c o s o l v TM

Burcosperse AP L i q u

Burcosperse LP

RAW MATERIALS CHEMICAL DESCRIPTION Burco FAE P r o p r i e t a r y T e x t i l e A u x i l i a r y

Burco HCS-5ONF P r o p r i e t a r y T e x t i l e A u x i l i a r y

Burco LAA-38 P r o p r i e t a r y T e x t i l e Auxi 1 i a r y

Burco LAF-6 P r o p r i e t a r y T e x t i l e A u x i l i a r y

Burco LAF-125 P r o p r i e t a r y T e x t i l e Auxi 1 i a r y

Burco NCS 50% P r o p r i e t a r y T e x t i l e A u x i l i a r y

Burco NPS-216 P r o p r i e t a r y T e x t i l e Auxi l i a r y

e t a r y T e x t i l e A u x i l i a r y

Water s o l u b l e s o l v e n t m i x t u r e

d Sodi um p o l y a c r y l a t e s o l u t i on

Sodium p o l y a c r y l a t e s o l u t i o n

Burco SXS-40% P r o p r i e t a r y T e x t i l e A u x i l i a r y

B u r c o t a s e SL-80 P r o p r i e t a r y D e t e r g e n t Enzyme

B u r c o t e r g e DG-40 D e t e r g e n t c o n c e n t r a t e

Burco TME P r o p r i e t a r y T e x t i l e Aux i 1 i a r y

Auxi 1 i a r y

s o l v e n t

y c o l monobuty l e t h e r

s o l v e n t

Burcowet TM-LF P r o p r i e t a r y T e x t i l e

B u t y l C a r b i t o 1 I n d u s t r i a1

B u t y l C e l l o s o l v e E t h y l e n e g

B u t y l Propaso l I n d u s t r i a l

C-340

Calamide C

Cal foam EA-603

Cal o x y l a t e N-9

Carnuaba wax emu1 s i on

Coconut d e r i v e d ami de

L i q u i d d e t e r g e n t

SOURCE B u r l i n

B u r l i n

B u r l i n

B u r l i n

B u r l i n

B u r l i n

B u r l i n

B u r l i n

B u r l i n

B u r l i n

B u r l i n

B u r l i n

B u r l i n

B u r l i n

B u r l i n

B u r l i n

UnCarb

UnCarb

UnCarb

Tomah

P i l o t

P i l o t

P i l o t

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260 Advanced Cleaning product Formulations

RAW MATERIAL CHEMICAL DESCRIPTION C a l s o f t L-40 Sodi um dodecyl benzene s u l f o n a t e

Cal s o f t LAS-99 L inear a1 k y l a t e su l f ona te

C a l s o f t F-90 L inear a l k y l a t e s u l f o n a t e

Carbi t o 1 So lvent

Carbopol ETD-2001 Resin Th icken ing agent

Carbopol ETD-2691 Resin Th icken ing agent

Carbopol 672 Resin

Carbopol 674 Resin

Carbopol 934 Resin

Carbopol 2201 Resin

Carbowax PEG 8000

CDB Clearon

CDB 90

Cheelox BF-Aci d

Cheelox BF-13

Cheel ox NTA-Na3

C i t r u s X004.950

C1 e a r l an

CMC-7M8S

C o l l o i d 60

Col 1 o i d 581 -B

Concord CO Wax

Th icken ing agent

Th icken ing agent

Th icken i ng agent

Th icken ing agent

Po lye thy lene g l y c o l

Ch lo r ina ted i socyanurate

Ch lo r ina ted isocyanura te

Chel a t i ng agent

Chel a t i ng agent

Chel a t i ng agent

Perfume

Lanol i n

Sodium carboxymethylcel l u l o s e

Polymeric d i spersant

Polymeric d i spe rsan t

Wax. MP: 184F.

SOURCE P i l o t

P i l o t

P i l o t

UnCarb

BFGood

BFGood

BFGood

BFGood

BFGood

BFGood

UnCarb

O l i n

01 i n

Rhone

Rhone

Rhone

Quest

Henkel

Aqua1 o

Rhone

Rhone

Concor

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Trademarked Raw Materials 261

RAW M A T E R I A L Dowanol DPnB

Dowanol EB

Dowanol PM

Dowanol PnB

Dow Corn ing C-2-0563

Dow Corn ing HV-490

Dow Corn ing Q2-3225C

Dow Corn ing 24 Emulsion

Dow Corn ing 193

Dow Corn ing 200 F l u i d

Dow Corn ing 347

Dow Corn ing 531 F l u d

Dow Corn ing 536 F l u d

Dow Corn ing 929

Dowfax 2A-1 (45%)

Dowfax 382

Dowicide A

Drakeol 2251

Dres ina te TX

Dres ina te XX

D Sodium S i 1 i c a t e

Duomeen TDO

Duponol C

Duraplus 2 Polymer

CHEMICAL D E S C R I P T I O N Glyco l e the r

E thy lene g l y c o l n - b u t y l e the r

Propylene g l y c o l methyl e the r

G lyco l e the r

S i 1 i cone

S i 1 i cone emul s i on

S i 1 i cone

Po lyd ime thy l cyc los i loxane

S i l i c o n e s u r f a c t a n t

A m i n o f u n c t i onal

S i 1 i cone emul s i on

S i l i c o n e f l u i d

S i l i c o n e f l u i d

S i l i c o n e c a t i o n i c emulsion

A1 k y l a ted d i phenyl ox ide

s i 1 i cone

d i s u l f ona te

S u r f a c t a n t

Sodi um o-phenylphenate

S u r f a c t a n t

Rosin soap

Rosin soap

Sur face a c t i v e agent

SOURCE Dow

Dow

Dow

Dow

DowCor

DowCor

DowCor

DowCor

DowCor

DowCor

DowCor

DowCor

DowCor

DowCor

DowCor

Dow

Dow

Penrec

Hercul

Hercul

PQ

Akzo

DuPont

Rohm&

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262 Advanced Cleaning I3.oduct Formulations

RAW MATERIALS Ektaso lve DE So lvent

Ek taso lve DM So lvent

Emcol 14

Epolene E-10

Epolene E-20

Epolene E-43

Esi -Cry1 20/20

Es i -F lex 802

Ethomeen C-25

Euper lan PK-771

Exxon I sopar G

Faxam No. 40

Faxam No. 45

F e r r o s i l 14

F luorad FC-120

F1 uorad FC-129

FMB-210-15 Quat (50%)

G Sodi um S i 1 i c a t e

Gafac RE-610

Gantrez AN-149

Ge lwh i te GP

Genagen LAB

Genapol UD030

CHEMICAL DESCRIPTION

Sur face -ac t i ve agent

Synt he t i c wax

S y n t h e t i c wax

S y n t h e t i c wax

Emulsion polymer

Level i ng r e s i n

E thoxy la ted a l i p h a t i c amine

Pear l i zer

I s o p a r a f f i n so l ven t

P a r a f f i n o i l

P a r a f f i n o i l

Fe r ro aluminum s u l f a t e

F1 uorochemi c a l s u r f a c t a n t

Fluorochemical s u r f a c t a n t

An ion i c s u r f a c t a n t

V i n y l e thy l -ma le i c anhydr ide copolymer

White montmori 1 l o n i t e

C12C14 a l k y l d i m e t h y l b e t a i n e

C11 0x0 a l coho l e t h o x y l a t e w i t h 3 moles EO

SOURCE Eastma

Eastma

W i t c o

Eastma

Eastma

Eastma

Emul s i

Emul s i

Akzo

Exxon

Kaopol

3M

3M

Hunt in

PQ

Rhone

GAF

ECC

Hoechs

Hoechs

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Trademarked Raw Materials 263

RAW MATERIALS CHEMICAL DESCRIPTION SOURCE Genapol UD 050 C11 0x0 a l coho l e t h o x y l a t e w i t h Hoechs

5 moles EO. Non ion ic .

Genapol UD 079 C11 0x0 a l coho l e t h o x y l a t e w i t h Hoechs 7 moles EO. Non ion ic .

Genapol ZRO L i q u i d A l k y l t r i g l y c o l e the r s u l f a t e s o l n Hoechs

Genapol 26-L-2 C12C16 a l c o h o l e t h o x y l a t e w i t h 2 moles EO. Non ion ic

Genapol 26-L-5 C12C16 a l coho l e t h o x y l a t e w i t h 5 moles EO. Non ion ic .

Genapol 26-L-60 C12C16 a l c o h o l e t h o x y l a t e w i t h c l o u d p o i n t o f 60C

Genapol 26-L-75 C12C16 a l coho l e t h o x y l a t e w i t h c l o u d p o i n t o f 75C

Georgia Marb le White #8 Calcium carbonate, 40-80 mic ron

Germaben I 1 Cosmetic p r e s e r v a t i v e

Germaben I I E Cosmetic p r e s e r v a t i v e

Geropon WT-27

G1 ucopon AV-110 S u r f a c t a n t concen t ra te

G l ucopon LD-15 S u r f a c t a n t concen t ra te

Glucopon 60 CSUP

Glucopon 425 CS A l k y l p o l y g l y c o s i d e (C8-C16),50%

Glucopon 600 CSUP A l k y l p o l y g l y c o s i d e (C12-C16),50%

Glucopon 625 CSUP A1 k y l p o l y g l y c o s i de (C12-C16), 50%

Hoechs

Hoechs

Hoechs

Hoechs

GeoMa r

Sut ton

Sut ton

Henkel

Henkel

Henkel

Henkel

Henkel

Henkel

G r i 11 o c i n HY-77 Odor remover R I T A

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264 Advanced Cleaning Product Formulations

RAW MATERIAL Herco P ine O i l

Hoechst Wax E

Hoechst Wax F

Hoechst Wax LP

Hoechst Wax OP

Hoechst Wax S

Hostapal N 040

Hostapal N 090

Hostapur SAS 60

Igepa l CA-620

Igepa l CA-630

Igepa l CA-720

Igepa l CO-520

Igepa l CO-530

Igepa l CO-630

Igepa l CO-660

Igepa l CO-710

Igepa l CO-720

Igepa l RC-520

CHEMICAL DESCRIPTION

Wax

Wax

Wax

Wax

Wax

Nonylphenol e thoxy la te -4 moles EO

Nonylphenol e thoxy la te -9 moles EO

Secondary a lkane s u l f o n a t e

Non ion ic e t h o x y l a t e s u r f a c t a n t

Non ion ic e t h o x y l a t e s u r f a c t a n t . Moles EO: 9-10

Non ion ic e t h o x y l a t e s u r f a c t a n t . Moles EO: 12.5

Non ion ic e t h o x y l a t e s u r f a c t a n t

Non ion ic e t h o x y l a t e s u r f a c t a n t

Non ion ic e t h o x y l a t e s u r f a c t a n t Moles EO: 9

Nonionic e t h o x y l a t e s u r f a c t a n t . Moles EO: 10

Non ion ic e t h o x y l a t e s u r f a c t a n t . Moles EO: 10.5-11

Non ion ic e t h o x y l a t e s u r f a c t a n t . Moles EO: 12

Non ion ic e t h o x y l a t e s u r f a c t a n t .

SOURCE Hercul

Hoechs

Hoechs

Hoechs

Hoechs

Hoechs

Hoechs

Hoechs

Hoechs

Rhone

Rhone

Rhone

Rhone

Rhone

Rhone

Rhone

Rhone

Rhone

Rhone

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Trademarked Raw Materials 265

RAW MATERIALS Incromide 690

Ionac PE-110

Isopar E

Isopar G

Isopar K

Isopar L

Isopar M

Kaopolite A0

Kaopolite SF

Kaopolite SFO-NP

Kaopol i te 1 152

Kaopol i te 1 1 68

Kasil #1

Kasi 1 #6

Kathon CG/ICP

KerMac 600 MSO

Kessco PEG-600

Klucel H

Korthi x

Korthix H

CHEMICAL DESCRIPTION

Ion exchange resin

Isoparaffin solvent

Isoparaffin solvent

vent

vent

vent

Isoparaffin so

I soparaf f i n so

Isoparaffin so

Anhydrous a1 umi num si 1 i cate

Anhydrous a1 umi num si 1 i cate

Anhydrous aluminum silicate

Anhydrous aluminum silicate

Anhydrous a1 umi num si 1 icate

Potassi um si 1 i cate

Liquid potassium silicate

Fungicide (biocide)

MSO

Fatty ester. Mono

Hydroxypropyl cel

Thickening agent

Thickening agent

aurate

ulose

SOURCE

Sybron

Exxon

Exxon

Exxon

Exxon

Exxon

Kaopol

Kaopol

Kaopol

Kaopol

Kaopol

PQ

PQ

Rohm

Kerr-

Stepan

Aqua1 o

Kaopol

Kaopol

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266 Advanced Cleaning Product Formulations

RAW MATERIAL L-140 So lvent

Lapon i te RDS

L y t r o n 295 Opaci f i e r

Mackadet 40K

Mackam CSF

Mackam MEJ

Mackam 2CSF

Mackam 2CYSF

Mackam TM

Mackam 35

Mackami de CDM

Mackami de LLM

Mackamide S

Mackamine CO

Mackamine LO

Mackazol i ne 0

Mackstat DM

Macol LF-110

Macol DNP 150

Macol NP 9.5

Macol 25

Macol 27

CHEMICAL DESCRIPTION

Po lys ty rene emulsion

Potassium coconut soap

Cocoamphopropionate

Amphoteric s u r f a c t a n t

Cocoamphodipropionate

Capryl ampodi p r o p i onate

D i hydroxyethy l t a l low g l y c i na te

Cocoami dopropyl b e t a i ne

Cocamide DEA (and) DEA o l e a t e

Laurami de DEA

Soyamide DEA

Cocami ne ox ide

Laurami ne ox ide

01 e y l hydroxyethy l i m i dazol i ne

DMDM hydantoi n

Po lyoxyethy lene f a t t y e the r

Po lyoxyethy lene f a t t y e the r

Po lyoxyethy lene f a t t y e the r

Po lyoxyethy lene f a t t y e the r

Po lyoxyethy lene f a t t y e the r

SOURCE

Morton

Mc In t

McIn t

McIn t

McIn t

Mc In t

McIn t

McI n t

McIn t

McIn t

Mc In t

Mc In t

McIn t

Mc In t

McIn t

PPG

P PG

P PG

PPG

PPG

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Trademarked Raw Materials 267

RAW MATERIAL Macol 40

Macol 41

Macol 45

Macol 48

Macol 212

Makon

Makon 6

Makon 10

Maphos 66H

Maphos 91

Mas i l EM 1000 P

Mas i l SF 100

Mas i l SF 10,000

Mas i l 1066C

Mazamide 70

Mazawet DF

Mazon DDBSA

Mazon 41

Mazon 601

Mazon 71A

Metso Beads 2048

Metso Pentabead 20

Metso 200

M i c r o f i n e V I

CHEMICAL DESCRIPTION Po lyoxyethy lene f a t t y e the r

Po lyoxyethy lene f a t t y e the r

Po lyoxyethy lene f a t t y e the r

Po lyoxyethy lene f a t t y e the r

Po lyoxyethy lene f a t t y e the r

A l k y l phenol e t h e r

A l k y l phenol e t h e r

A l k y l phenol e t h e r

Phosphate e s t e r

Phosphate e s t e r

S i l i c o n e f l u i d

S i l i c o n e f l u i d

S i 1 i cone f 1 u i d

S i l i c o n e f l u i d

Speci a1 t y a1 kanol ami de

S u r f a c t a n t

Speci a1 t y p r o p r i e t a r y

Speci a1 t y p r o p r i e t a r y

S p e c i a l t y p r o p r i e t a r y

Speci a1 t y p r o p r i e t a r y

Anhydrous sod i um metasi 1 i c a t e

Sodium m e t a s i l i c a t e pentahydra te

Sodi um o r t h o s i 1 i c a t e

A i r f l o a t e d b e n t o n i t e

SOURCE PPG

P PG

P PG

PPG

P PG

Stepan

Stepan

Stepan

PPG

PPG

P PG

PPG

P PG

PPG

P PG

PPG

P PG

P PG

PPG

PPG

PQ

PQ

PQ

AmCol 1

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268 Advanced Cleaning Produc# Formulations

RAW MATERIALS Mi rano l CS Conc.

Mi rano l DN

Mi rano l FBS

M i r ano l JEM Conc.

M i r a t a i ne CBS

M i r a t a i ne JC-HA

M i r a t a i n e TM

Monacor TEH

Monacor 39

Monafax 785

Mona1 ux CAO-LC

Monami ne R32-7

Monamulse DL-1273

Mona NF-10

Mona NF-15

Mona NF-25

Monater ic CAB-LC

Monawet MM-80

Monawet MO-70R

Monazol i ne CY

Monosorb MSP

Mor-Glo 2 Latex

Morton Conrez 500

M- Py ro l

Nat roso l 250-LR

CHEMICAL DESCRIPTION Amphoteric s u l f ona te s u r f a c t a n t

Sodium stearoampho ace ta te

D i sodi um cocoampho d i p r o p i onate

Sodium mixed C8-amphocarboxylate

Cocoamidopropyl hydroxy s u l t a i n e

P r o p r i e t a r y ami nopropi onate

D i hydroxyethy l t a l low g l y c i na te

Cor ros ion i n h i b i t o r

Cor ros ion i n h i b i t o r

SOURCE Rhone

Rhone

Rhone

Rhone

Rhone

Rhone

Rhone

Mona

Mona

Organic phosphate e s t e r s u r f a c t a n t Mona

Sur fac tan t Mona

Mona

P r o p r i e t a r y e m u l s i f i e r / s o l u b i l i z e r Mona

Sur fac tan t

Su r fac tan t

Su r fac tan t

Su r fac tan t

Su r fac tan t

Su r fac tan t

1-Hydroxyethylene-2-Caprylimid- azol i ne

Sodium phosphate, monobasic

F l o o r p o l i s h l a t e x (38%)

Polymer emulsion

N-methyl-2-pyrrol i done

Hydroxye thy l ce l l u lose

Mona

Mona

Mona

Mona

Mona

Mona

Mona

FMC

Morton

Morton

ISP

Aqua1 o

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Trademarked Raw Materials 269

N-C RAW MATERIAL ear

Neodol 25-3 E thoxy la te

Neodol 25-7 E thoxy la te

Neodol 25-9 Ethoxy l a t e

Neodol 91-8 E thoxy la te

N i aproo f 08

N i n o l GR (80%)

N i n o l 11-CM

NM-90 La tex Polymer

Opaci f i e r E295

P a t i o n i c CSL

P a t i o n i c ISL

Pat i o n i c 138C

P a t l a c LA

Pemulen TR-1 Resin

Pemulen TR-2 Resin

P e t r o l i t e Wax C-36

P i l o t SXS-40

P l u r a f a c D-25

P l u r o n i c F68

P1 u r o n i c F108

CHEMICAL DESCRIPTION Sodium metasi i c a t e

L inea r p r imary a l c o h o l . MW: 336

L inea r p r imary a l c o h o l . MW: 519

L inea r p r imary a l c o h o l . MW: 610

L inea r p r imary a l c o h o l . MW: 529

An ion ic s u r f a c t a n t

COCO d i e thano l ami de

Coconut d ie thano lamide, mod i f i ed

Polymer emulsion

La tex opaci f i e r

E m u l s i f i e r

Emu1 s i f i e r

Wax

Sodi urn x y l ene s u l f o n a t e

L inea r a l coho l a l k o x y l a t e . MW:930

Pol yoxya l k y l ene g l y c o l b l o c k polymer

Po lyoxya lky lene g l y c o l b l o c k polymer

SOURCE PP

Shel 1

Shel 1

Shel 1

Shel 1

N i acet

Stepan

Stepan

Morton

Morton

BFGood

BFGood

P e t r o l

P i l o t

BASF

BASF

BASF

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270 Advanced Cleaning Product Formulations

CHEMICAL DESCRIPTION SOURCE RAW MATERIAL P l u r o n i c L-10 Polyoxyal ky lene g r a f t b l o c k polymer BASF

PQ Epsom S a l t PQ

Protease-Novo Nord isk

Proxel GXL I C I

Purton CFD Zschi m

Chemi c a l b i o c i de

F a t t y a c i d a1 kanol ami de

Q-3

Renex 698

R e s i n a l l 802

Rhodacal A-246/L

Rhodacal DS-10

Rhodacal DSB

Rhodacal IPAM

Rhodacal 301 -1O/F

Rhodacal 330

Rhodaf ac LO-529

Rhodafac PE-510

Rhodaf ac RA-600

Rhodafac RE-610

Rhodaf ac RS-610

Rhodapex CO-436

Rhodapex ES

Ben ton i te c l a y

Detergent

Leve l i ng r e s i n (25%)

Sodium alpha o l e f i n s u l f o n a t e

Sodium dodecylbenzene (branched)

D i sodi um dodecyl d i phenyl ox ide , d i s u l f ona te

L inea r I P A DDBSA

Sodium alpha o l e f i n s u l f o n a t e

Branched i sopropyl ami ne dodecyl benzene s u l f o n a t e

Nonylphenol e thoxy la te , p a r t i a l sodium s a l t

An ion i c s u r f a c t a n t

L i near a1 coho1 e thoxy l a t e

Nonylphenol e thoxy l a t e

Branched a l coho l e thoxy l a t e

Ammonium nonoxyno l -&su l fa te

An ion ic s u r f a c t a n t

CalCar

I C I

Resin

Rhone

Rhone

Rhone

Rhone

Rhone

Rhone

Rhone

Rhone

Rhone

Rhone

Rhone

Rhone

Rhone

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Trademarked Raw Materials 271

RAW MATERIAL Rhodapex ES-2

Rhodapex MA-360

Rhodapex NA-61

Rhodapol

Rhodapol 23

Rhodapon BOS

Rhodapon LSB

Rhodapon SB

Rhodapon SB B208/S

Rhodapon UB

Rhodasurf BC-840

Rhodasurf 25-7

Rhodasurf 25-9

Rhodasurf 91 -6

Rhodaterge RS-25

Rhodaterge SMC

R i t a c h o l

R i tahydrox

R i t a l an

R i t o l e t h - 1 0

Rodine 213

RU Sodi um S i 1 i c a t e

CHEMICAL DESCRIPTION Sodium l a u r e t h (2 ) s u l f a t e

An ion ic s u r f a c t a n t

Sodium l a u r e t h (3) s u l f a t e

Xanthan gum

Xanthan gum

Sodi urn 2 -e thy l hexy l s u l f a t e

Sodium l a u r y l s u l f a t e

Sodi um 1 a u r y l s u l f a t e

Sodium l a u r y l s u l f a t e

Sodium l a u r y l s u l f a t e

Branched c h a i n i s o t r i d e c y l - a l coho l e t h o x y l a t e

Mixed l i n e a r a l coho l ethoxy

Noni o n i c s u r f a c t a n t

M i xed 1 i near a1 cohol ethoxy

Cleaner concen t ra te

Cleaner concen t ra te

L i q u i d abso rp t i on base

L a n o l i n o i l

E thoxy l a ted o l e y l a1 cohol

Cor ros ion i n h i b i t o r

Cor ros ion i n h i b i t o r

a t e

a t e

SOURCE Rhone

Rhone

Rhone

Rhone

Rhone

Rhone

Rhone

Rhone

Rhone

Rhone

Rhone

Rhone

Rhone

Rhone

Rhone

Rhone

R I T A

R I T A

R I T A

R I T A

Parker

PP

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272 Advanced Cleaning Product Formulations

RAW MATERIAL CHEMICAL DESCRIPTION SF-96 S i l i c o n e (350) Po lyd imethy l s i l i c o n e f l u i d

SF-1 706

S i 1 -Co-Si 1 53 S i l i c a

S i l i c o n e AFL 40 S i 1 i cone

S i 1 i cone Emu1 s i on SM-2035

S i 1 i cone

S i l i c o n e F l u i d L45

S i 1 t e x

S i l t e x 44

S i l w e t L7600

S-Maz 83R

Snow F loss

Sodium N S

Span 80

S tab i 1 i zer

1 i c a t e

ASE-108

Standamid CD

Standamid KD

Standami d LAO

Standamid LD

Standamid LM

Standamid SD

Standapol ES-3

Standapol T

S t a r Sodi um S i 1 i c a t e

Starso Sodi um S i 1 i c a t e

Fused s i l i c a -50+100 mesh

Fused s i l i c a

Sur face a c t i v e copo lymer -s i l i cone

S o r b i t a n f a t t y e s t e r

M i n e r a l f i 1 l e r

SOURCE GE

GE

USSi 1

UnCarb

S u r f a c t a n t

A c r y l i c emulsion copolymer

Caprami de DEA

Cocamide DEA

Laurami de DEA

Cocamide DEA

Sodi um 1 aure th-3-su l f a t e

TEA l a u r y l s u l f a t e , 40%

Kaopol

Kaopol

UnCarb

PPG

JM

PQ

I C I

Rohm&

Henkel

Henkel

Hen k e l

Henkel

Henkel

Henkel

Henkel

Henkel

PQ

PQ

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Trademarked Raw Materials 273

RAW MATERIAL Stepanate X

S u l f o t e x SXS

S u l f o t e x SXS 40

S u l f o t e x 60405

S u l f r a m i n 60

Super F loss

sws-211

Synthrapo l N

T e r g i t o l NP-10

T e r g i t o l NPX

T e r r y AGO02

Texanol

Texs t im 8741

T i nopal CBS-X

T inopa l 5BM

Tomah Ac id Thickener

Tomah A1 k a l i S u r f a c t a n t

Tomah Amphoteric L

Tomah Amphoteric N

Tomah Amphoteric SC

Tomah Amphoteri c 400

Tomah AO-14-2

Tomah A0-728 Speci a1

Tomah DA-17

CHEMICAL DESCRIPTION Hydrot rope

Sodium xy lene s u l f o n a t e

Sodium xy lene s u l f o n a t e , 40%

Sodium l a u r y l e t h e r s u l f a t e , 59%

Detergent p roduc t

M ine ra l f i l l e r

S i l i c o n e an t i f oam agent

Detergent

Nonoxynol -1 0

S p e c i a l t y n o n i o n i c s u r f a c t a n t

Aloe Vera ge l

Es te r a l coho l

Noni o n i c s u r f a c t a n t

F1 uorescent whi t e n i ng agent

F1 uorescent whi t e n i ng agent

C a t i o n i c s u r f a c t a n t

Amphoteric (35% a c t i v e )

M i l d s u r f a c t a n t

S u r f a c t a n t

S u r f a c t a n t

S u r f a c t a n t

E ther amine o x i d e

P r o p r i e t a r y ami ne ox ide

SOURCE Stepan

Henkel

Henkel

Henkel

D i a1

JM

sws

I C I

UnCarb

UnCarb

Te r ry

Eastma

Tomah

C i ba-G

C i ba-G

Tomah

Tomah

Tomah

Tomah

Tomah

Tomah

Tomah

Tomah

Tomah

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274 Advanced Cleaning Product Formulations

RAW MATERIAL Tomah E-14-2

Tomah E-14-5

Tomah E-17-2

Tomah E-18-2

Tomah Ecowax N-3

Tomah Ecowax N-7

Tomah Emul s i f i e r Four

Tomah Emul s i f i e r 827

Tomah OAT 1000

Tomah (2-14-2

Tomah 9-17-2 (PG)

Tomah TAE-RI

T r i t o n CF-10

T r i t o n CF-21

T r i t o n CF-54

T r i t o n DF-12

T r i t o n X-100

T r i t o n X-102

T r i t o n X-114

Trycol 5963

Trycol 5964

Tween 20

CHEMICAL DESCRIPTION Ethoxyl ated ami ne

Ethoxylated ami ne

Ethoxyl ated ami ne

Ethoxylated amine

"Hydrocarbon Free" Spraywax

"Hydrocarbon Free" Spraywax

D i a1 k y l quaternary

M i xed d i a1 k y l quaternary

Organic a c i d th ickener

Quaternary

Quaternary

A l k y l a r y l po lyether nonion

A l k y l a r y l po lyether nonion

C

C

Modi f i ed po l yethoxy adduct

Modi f ied polyethoxy lated a lcohol nonionic

Octoxynol-9

Octoxynol-13

Octy l phenol

POE (8) l a u r y l e ther s u l f a t e

Polyoxyethylene a1 k y l es te r

Sur factant

nonion ic

SOURCE Tomah

Tomah

Tomah

Tomah

Tomah

Tomah

Tomah

Tomah

Tomah

Tomah

Tomah

Tomah

Rohm&

Rohm&

Rohm&

Rohm&

UnCarb

UnCarb

UnCarb

Hen ke l

Henkel

I C I

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Trademarked Raw Materials 275

RAW MATERIAL V a l f o r 100

Van Gel ES

Varso l

Veegum

Veegum T

Ve lve tex BA-35

Vel ve tex BK-35

Versaf 1 ex 207

Versene Powder

Versene 220 C r y s t a l

V i s c a s i l 10,000

W i tcami de 51 1

Wi tconate 1260

Yarmor

Zeteso l 2056

Zusol a t 1008/85

CHEMICAL DESCRIPTION Z e o l i t e A b u i l d e r

Na tu ra l smecti t e c l a y

M ine ra l sp i r i t s

S t a b i l i z e r , suspending agent

S tab i 1 i zer , suspending agent

Cocami dopropyl b e t a i ne, 35%

Cocami dopropyl b e t a i ne, 35%

Emulsion c o a t i n g

C h e l a t i n g agent

Chel a t i ng agent

S i l i c o n e f l u i d

Oleamide DEA

C-12 LAS (60%)

Pine o i l

F a t t y a l coho l e t h e r s u l f a t e

F a t t y a l coho l e t h e r s u l f a t e

SOURCE PQ

Vander

Exxon

Vander

Vander

Hen ke l

Henkel

Grace

Dow

Dow

GE

W i t c o

W i t c o

Hercul

Zschim

Zschim

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Section IV Suppliers' Addresses

276

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Suppliers' Addresses 277

Akzo Chemical s, I n c . 300 S. R i v e r s i d e P laza Chicago, I L 60175 (312)-906-7500/(800)-257-8292

American C o l l o i d Co. 1500 W . Shure D r . A r l i ngton Hei gh ts , I L 60004 (312)-392-4600

Aqua1 on P . O . Box 15417 271 1 Cent rev i 11 e Rd. Wi lming ton , DE 19850 (302)-996-2000/(800)-345-8104

Arc0 Chemical Co. 3801 West Chester P i k e Newtown Square, PA 19073 (215)-359-2000

A r i zona Chemi c a l Co. 1001 E . Business Hwy 98 Panama C i t y , FL 32401 (904)-785-6700/(800)-526-5294

BASF Corp. 100 Cherry H i l l Rd. Pa rs i ppany, NJ 07054 (201)-316-3000/(800)-526-1072

B u r l i n g t o n Chemical Co., I n c . P.O. Box 1 1 1 615 Huffman M i l l Rd. B u r l i n g t o n , NC 27215 (919)-584-0111/(800)-672-5888

C i ba-Gei gy Corp. 7 S k y l i n e D r i v e Hawthorne, NY 10532 (914)-347-4700/(800)-431-1900

Concord Chemical Co. 17th and Federal S t s . Camden, N J 08105 (609)-966-1526

Degussa Corp. 65 Chal lenger Rd. R i d g e f i e l d Park, NJ 07660 (201 )-641-6100

D i a l Corp. 1 1 1 W . Clarendon Ave. Phoenix, AZ 85013 (602)-248-5251/(800)-323-5385

Dow Chemical Co. Mid land, M I 48674 (800)-258-CHEM

Oow Corn ing Corp. Box 0994 Midland, M I 48686 (51 7)-496-4000

DuPont Market S t . W i 1 m i ng ton , DE 19898 (800)-441-7515

Eastman Chemical Co. P . 0 . Box 431 Kingspor t , TN 37662 (615)-229-2318/(800)-327-8626

ECC America 5775 Peachtree Dunwoody Rd. A t l a n t a , GA 30342 (404)-843-1551/(800)-843-3222

Emulsion Systems, I n c . P.O. Box 307 Lemont, I L 60439 (718)-388-2653/(800)-762-7676

Exxon Chemi c a l Aner i cas 13501 Katy Frwy Houston, TX 77079 (713)-870-6000/(800)-231-6633

FMC Corp. 2000 Market S t . P h i l a d e l p h i a , PA 19103 (215)-299-6000/(800)-526-3649

GAF Chemicals Corp. Rhone-Poul enc 1361 Alps Rd. Wayne, NJ 07470 (201)-628-3000/(800)-848-7659

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278 Advanced Cleaning Product Formulations

GE S i l i c o n e s 260 Hudson R ive r Rd. Waterford, NY 12188 (518)-237-3330/(800)-255-0886

Georgia Marble Co. 1201 Roberts E l vd . Kennesaw, GA 30144 (404)-421-6500

E.F. Goodrich Co. 9911 0 r e c k s v i l l e Rd. Brecksvi 11 e, OH 441 41 (216)-447-5000/(800)-331-1144

W.R. Grace & Co. 55 Hayden Ave. Lexington, MA 02173 (61 7)-861-6600

Henkel Corp. 5325 S. N i n t h Ave. LaGrange, I 1 60525 (708)-530-7300/(800)-543-7370

Hercules, I n c . Hercules P1 aza W i 1 m i ngton , DE 19894 (800)-247-4372

Hunt ing ton Labs I n c . 970 E. T i p t o n S t . Hunt ington, I N 46750 (219)-356-8100/(800)-537-5724

I C I S p e c i a l t i e s Concord P ike 8, New Murphy Rd. W i 1 m i ngton , DE 19897 (302)-886-3000/(000)-822-8215

Johns-Manvi 1 l e Ken-Caryl Ranch Denver, CO 80217

Kaopo l i t e , I n c . 2444 M o r r i s Ave. Union, N J 07083 (908)-789-0609

Kerr-McGee Chemical Corp. Kerr-McGee C t r . P.O. Box 25861 Oklahoma C i t y , OK 73125 (405)-270-1313/(000)-654-3911

McIn ty re Group L t d . 4851 S. S t . Lou is Ave. Chicago, I L 60513 (312)-927-2401

Mona I n d u s t r i e s I n c . 76 E. 24 S t . P . O . Box 425 Paterson, N J 07544 (201)-345-8220/(800)-553-6662

Morton I n t e r n a t i o n a l I n c . 100 N. R i v e r s i d e Plaza Chicago, I L 60606 (312)-807-2000/(800)-367-3319

Niace t Corp. 47 S t . & Niagara F a l l s E lvd . Niagara F a l l s , NY 14304 (716)-285-1474/(800)-E28-1207

01 i n Chemical s O l i n Corp. 120 Long Ridge Rd. P.O. Box 1355 Stamford, CT 06904

M.S. Paisner, I n c . 53 Beaumont St. P.O. Box 358 Canton, MA 02021

(203)-356-2000/(800)-243-9171

(617)-828-2040

Parker + Amchem Henkel Corp. 300 Welsh Rd. Horsham, PA 19044 (215)-E30-1200/(800)-521-6895

Penreco 106 S. Main S t . B u t l e r , PA 16001 (412)-283-5600/(000)-245-3952

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Suppliers' Addresses 279

P e t r o l i t e Corp. 6910 E. 14 S t . Tulsa, OK 74112 (918)-836-1601

P i l o t Chemical Co. 11756 Burke S t . Santa Fe Spr ings , CA 90670 (310)-723-0036

PPG I n d u s t r i e s Chemical s Group One PPG P lace P i t t s b u r g h , PA 15272 (412 ) -434-3131 / (800 ) -243-6774

PQ Corp. P.O. Box 840 Val l e y Forge, PA 19482 (215)-293-7200

Quest I n t e r n a t i o n a l Fragrances 400 I n t e r n a t i o n a l D r i v e Mount O l i v e , NJ 07828 (201 )-691-7100

Resi n a l l Corp. P .O. Box 8149 Stamford, CT 06905 (203)-329-7100

Rheox, I n c . P .O. Box 700 H igh ts town, NJ 08520 (609)-443-2500

Rhone-Poul enc CN 7500 Prospect P1 a i ns Road Cranbury, NJ 08512 (609)-860-4000/(800)-626-2613

R I T A Corp. P.O. Box 585 Woodstock, I L 60098 (815)-337-2500/(800)-426-7759

Rohm and Haas Co. Independence M a l l West P h i l a d e l p h i a , PA 19105 (21 5)-592-3000

Stepan Co. 22 W . Frontage Rd. N o r t h f i e l d , I L 60093 (708)-446-7500/(800)-745-7837

Sut ton Labora to r ies I n c . 116 Summit Ave. Chatham, NJ 07928 (201)-635-1551

SWS Wacker S i l i c o n e s Corp. 3301 Su t ton Rd. Adr ian , M I 49221 (517)-264-8500/(800)-248-0063

Sybron Chemical s I n c . P.O. Box 66 B i r m i ngham, NJ 0801 1 (609)-893-llOO/(800)-678-0020

Ter ry Labora to r ies , I n c . 3270 Pineda Ave. Melbourne, FL 32940 (407)-259-1630/(800)-FOR ALOE

3M 3M Center S t . Pau l , MN 55144 (612)-733-5454

Tomah Products, I n c . 1012 T e r r a D r i v e M i 1 ton , W I 53563 (608)-868-6811/(800)-441-0708

U.S. S i l i c a Co. P.O. Box 187 Berke ley Spr ings , WV 25411 (304)-258-2500/(800)-243-7500

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280 Advanced Cleaning Product Formulations

Union Carbide Corp. 39 Old Ridgebury Rd. Danbury, CT 06817 (203)-794-2000

R.T . V a n d e r b i l t Co. , I n c . P . O . Box 5150 30 W i n f i e l d S t . Norwalk, CT 06856 (203)-853-1400/(800)-243-6064

Witco Corp. 520 Madison Ave. New York. NY 10022 (212)-605-3941/(800)-634-4010

Zschimmer & Schwarz Max-Schwarz-Strabe 3-5 D-56112 Lahnstei n/RH 0 26 21/12 0

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Other Noyes Publications

COSMETIC AND TOILETRY

FORMULATIONS

Second Edition - Volume 3

by

Ernest W. Flick

This book contains 775 cosmetic and toiletry formulations based on information received from numerous industrial companies and other organizations. This is Volume 3 of the Second Edition of this work; Volume 1 was published in 1989.Volume 2waspublishedin1992.Thereare no duplications in any of these volumes.

The data represent selections from manu- facturers' desaiptions made at no cost to, nor influencefrom, themakersordistributoe of these materials. Only the most recent formulas have been included. It is believed that all of the trademarked raw materials listed are currently available, which will be of interest to readers concerned with raw material discontinuances.

The cosmetic and toiletry market is projected to increase to dose to $2 billion by 1995, thus making the information in the book particularly interesting to anyone considering new products

or process variations. Each formulation in the book is identified by a

description of end use. The formulations include the following as available, in the manufacturer's own words: a listing of each raw material con- tained; the percent by weight of each raw material; suggested formulation procedure; and the formula source, which is the company or or- ganization that supplied the formula.

The formulations in the book are divided into thirleencategories asshown below. Inaddition, a valuable section on Trade-Named Raw Mate- rials is included, which liststrade-names. atnief chemical description, and the supplier's name. Thefinalsection contains Suppllers' Addresses and will no doubt be a useful tool to the reader.

W o n titles are listed below. Parenthetic numbers indicate the number of formulations per topic.

1. Antiperspirants and Deodorants (28)

II. Baby Products (21)

111. Bath and Shower Productl(57)

N. Beauty Aids (1 19)

V. Creams(79)

Vl. Hair Care Products (1 18)

VII. i n r d Repellents (24)

VIII. Lotions (62)

IX. Shampoos (120)

X. Shaving Products (4)

XI. Soaps and Hand Cleaners (57)

XII. Sun Cam Products (68)

XIII. Miscellaneous (1 8)

XN. Trade-Named Raw Materids

XV. Suppliers' Addresses

ISBN 0-8155-1367-4 (1995) 6' x9' 464 pages

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Other Noyes Publications

ADVANCED CLEANING

PRODUCT FORMULATIONS

Volume 2

by Ernest W. Flick

This book (Volume 2) presents more than 800 up-to-date advanced cleaning product formulations for household, industrial and automotive applications. It is the result of information received from numerous industrial companies and other organizations. The data represent selections made at no cost to, nor influencefrom, the makers or distributors of these materials. Only the most recent formulas have been included. All formulations are completely different than those contained in Volume 1. which was published in 1989.

Formulation in the cleaning product in- dustry has gradually been undergoing sig- nificant change during the past years. Raw materials costs have risen and manufacturers have been reluctant to pass along these in- creases. Environmental considerations have also played a part. By changing formulations to improve cost-performance characteristics, manufacturers have been able to control costs but still enhance performance. This book pre- sents supplier's suggested formulations which might meet new performance criteria.

Theformulations in thisbook aredivided into the following sections and chapters, with the number of formulations indicated in ( ):

1.

1.

2.

3.

4.

5.

6.

7.

8.

9.

10.

11.

Household and industrial Cleaners and Polishes (733)

Bathroom Cleaners (29)

Dairy and Food Industry Cleaners (15)

Degreasers (20)

Dishwashing Detergents (67)

DetergentsDisinfectants (36)

General Purpose Cleaners (47)

Hard Surface Cleaners (60)

Laundry Products (217)

Metal Cleaners (87)

Polishes, Coatings and Sealers (32)

Rinse Aids (6)

12. Rug, Carpet and Upholstery Shampoos

13. Miscellaneous Cleaners (96)

and Cleaners (21)

11. Transportation Cleaners and Polishes (76)

14. Auto Cleaners and Polishes (9)

15. Car and Truck Wash Compounds (38)

16. Whitewall Tire Cleaners (10)

17. Miscellaneous (19)

In addition to the above, there are two other sections which will be helpful to the reader.

111. A chemical trademark section where each tradenamed raw material included in the book is listed with a chemical description and the sup- plier's name. The specifications which each raw material meets are included, if applicable.

IV. Main office addresses of the suppliers of trademarked raw materials.

Each formulation in the book lists the following information, as available:

1. Description of end use and most outstanding properties.

2. The percent by weight or volume of each raw material included in the formula.

3. Key properties of the formula, which are the features that the source considers to be more outstanding than other formulations of the same type.

4. The formula source, which is the company or organization that supplied the formula. The secondary source maybe the originating company and/or the primary source's publication title, or both. A formula number is included, if applicable.

ISBN 0-8155-1346-1 (1994) 6" x9' 394 pages

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Other Noyes Publications

INDUSTRIAL SURFACTANTS

An Industrial Guide

Second Edition

by Ernest W. Flick

The second Edition of this useful book describes almost 2900 surfactants which are currently available for industrial use. Thebookwill be of value to technical and managerial personnel involved in the specitition and use of these products. The information has been developed directly from information received from 46 surfactant suppliers.

Industrial surfactants find uses in almost every industry, from asphalt manufacturing to carpet fibers, from pulp and paper production to leather processing. Examples of the types of Chemicals used as surfactants are fatty alcohol sulfates, alkanolamides, alkoxylates, sulfosuccinates, amines, quaternaries, phosphate esters, acid esters, blockcopolymers, betaines, imidazolines, alkyl sulfonates, etc.

The market for these products has, and is expected to continue to have, a steady growth rate, of the order of 2% per year. Surfactants, besides their widely recognized use in soaps and detergents, find use as, or in, floor strippers, engine degreasers, corrosion inhibitors, hard

Air Products and Chemicals Akzo Chemicals, Inc. Albright &Wilson Americas Alcolac-Rhone Poulenc American Cyanamid Co. American Lecithin Co. Burlington Chemical Co., Inc. Central Soya Climax Performance Materials Costec Inc. Daniel Products Co. Dexter Chemical Corp. Dow Chemical Co. DuPont Co. Emulsion Systems Inc. Ethyl Corp. Exxon Chemical Co. GAF Chemicals Corp. Goldschmidt Chemical Corp. W.A. Grace & Co. Harcros Organics Henkel Corp. lnolex Chemical Co.

surface cleaners, fabric softeners, paint dispersants, cutting fluids, anti-stats,viscosily builders, rinse aids, mold release agents, foam generators, foam stabilizers, etc.

The data included represent selections from manufacturers' descriptions made at no cost to, nor influence from, the makers or distributors of thematerial. Onlythemost recent information has been included. It isbelieved that all of the products listed here are currently available, which will be of utmost interestto readers concerned with product discontinuances.

Products are presented by company. Also included is a Trade Name Index and Supplier's addresses.

Thebook lists the following product information:

1 .Company name and product category 2.Trade name and product numbers 3.Product Description: a brief description of the product and its use.

The following companies are represented in the book.

Lonza Inc. Mclntyre Group Ltd. Miranol Inc. Mona Industries. Inc. MTM Research Chemicals, Inc. Niacet Corp. Olin Corp. M.S. Paisner. Inc. Pilot Chemical Co. PPG/Mazer Chemicals Dr. Rhone-Poulenc Ruetgers-Nease Chemical Co., Inc. Sandoz Chemicals Scher Chemicals, Inc. Shell Chemical Co. Sherex Chemical Co., Inc. Stepan Co. 3M Industrial Chemical Products Division Texaco Chemical Co. Union Carbide Chemicals & Plastics Co., Inc. R.T. Vanderbilt Co.. Inc. Vista Chemical Co. Witco Corp.

ISBN 0-8155-1332-1 (1993) 6" x 9" 547 pages

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Other Noyes Publications

ADVANCED CLEANING PRODUCT

FORM U LATl ON S Household, Industrial, Automotive

Volume 1

by Ernest W. Flick

This book presents more than 800 up-to- date advanced cleaning product formulations lor household, industrial and automotive applica- tions I t is the result 01 information received lrom numerous industrial companies and other organizations The data represent selections made at no cost lo. nor inlluence lrom. the makers or distributors of these malerials Only the most recent (ormulas have been included i t is believed that all 01 the trademarked raw materials listed here are currently available

The lormulalions in the book are divided as follows Parenthetic numbers indicate the number 01 lormulalions in each chapter

1.

1.

2.

3.

4.

5.

6.

7.

8.

9.

10.

11.

12.

13.

I1

14.

HOUSEHOLD/INDUSTRIAL CLEANERS

Bathroom Cleaners (16)

Disinfectants (1 1)

Dishwashing Detergents (57)

Floor Cleaners and Wax Strlppers(41)

General Purpose Cleaners (73)

Laundry Products (143)

Metal Cleaners (74)

Oven Cleaners (10)

Rinse Additives and Alds (97)

Rug, Carpet and Upholstery Cleaners and Shampoos (41)

Wall and Hard Surface Cleaners (52)

Window and Glass Cleaners (25)

Miscellaneous Cleaners (130)

A U TOM0 TI VE CL E A NERS

Car and Truck Washes (48)

15. Whitewall Tlre Cleaners (8)

16. Miscellaneous Cleaners (22)

Each formulation in the book liststhe lollowlng inlormation. as available. in the manufacturer's own words:

Description of end use and most out- standing properties.

The percent by weight or volume of each raw material included in the formula, rounded to a decimal ligure.

Key propertiesof the formula, whichare the leatures that the source considers to be more outstanding than other lormulations of the same type.

The formula source, which is the com- pany or organization that supplied the lormula. The secondary source may be the originating company andlor the primary source's publication title. or both. A formula number is included, il applicable.

In addition to the sections listed above, there are two other sections which will be helpful to the reader

A chemical trade name section where trade-named raw materials included in the book are listed with a briel chemical description and the sup- plier s name Thespecifications which each raw material meelsare included, 1 1 applicable

Main ollice addresses 01 the suppliers 0 1 trade named raw materials

ISBN 0-8155-1186-8 (1989) 6"x9" 372 pages