air liquide biogas market and technology designed/owned/installed/operated/financed by air liquide...
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GLOBAL MARKETS & TECHNOLOGIES ∙
September 2017 Lauren Turner, Sales Manager - Clean Energy Solutions
Air Liquide US Biogas Overview •
THIS DOCUMENT IS PUBLIC AIR LIQUIDE, THE WORLD LEADER IN GASES, TECHNOLOGIES AND SERVICES FOR INDUSTRY AND HEALTH I
GLOBAL MARKETS & TECHNOLOGIES
THIS DOCUMENT IS PUBLIC
Lauren Turner Sales Manager - Clean Energy Solutions
Air Liquide Biogas Market and Technology
GLOBAL MARKETS & TECHNOLOGIES ∙
September 2017 Lauren Turner, Sales Manager - Clean Energy Solutions
Air Liquide US Biogas Overview •
THIS DOCUMENT IS PUBLIC AIR LIQUIDE, THE WORLD LEADER IN GASES, TECHNOLOGIES AND SERVICES FOR INDUSTRY AND HEALTH I
Air Liquide at a glance
68,000 employees
Revenue
>$ 23 billion
Present in
80 countries
More than
3 million customers
and patients
The world leader in gases, technologies and services
Business built upon >100 years in gas separation:
operations, safety, reliability
GLOBAL MARKETS & TECHNOLOGIES ∙
September 2017 Lauren Turner, Sales Manager - Clean Energy Solutions
Air Liquide US Biogas Overview •
THIS DOCUMENT IS PUBLIC AIR LIQUIDE, THE WORLD LEADER IN GASES, TECHNOLOGIES AND SERVICES FOR INDUSTRY AND HEALTH I
Robust, high performance hollow fiber membranes for gas separation. Medal™, IMS and PEEKsep™ membrane fibers
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● Biogas: 50+ systems for removal of water, VOCs, siloxanes, H2S and CO2. – 50 to 10,000+ SCFM
● Natural Gas: Membranes for wellhead to pipeline. Removal of H2O, Heavy HC’s, H2S, CO2 ● Hydrogen: High purity/recovery membranes for refinery and petrochemical applications ● Nitrogen: Solutions for diverse inerting applications in aerospace, mining, marine, energy,
food processing, and on-site N2 generation
GLOBAL MARKETS & TECHNOLOGIES ∙
September 2017 Lauren Turner, Sales Manager - Clean Energy Solutions
Air Liquide US Biogas Overview •
THIS DOCUMENT IS PUBLIC AIR LIQUIDE, THE WORLD LEADER IN GASES, TECHNOLOGIES AND SERVICES FOR INDUSTRY AND HEALTH I
Air Liquide Biogas Market Offerings
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●“Over the Fence” ● Plant designed/owned/installed/operated/financed by Air Liquide ● Demonstrated reliability 99.5% equipment availability ● Lessons Learned applied to following projects ● Sites for continuing biogas developments
● Sale Of Equipment ● Compression ● H2S Removal, VOC, siloxanes removal ● Membrane system for CO2 removal and partial O2 removal
●MEDAL, IMS and/or PEEKsep membrane fiber ● Overall control philosophy, Hazop, benefit of operating experience
● Experience and Applications ● 50+ units provided to date ● Design flow rates < 50 SCFM to the largest units over 10,000 SCFM. ● Landfill or any digester biogas (WWTP, agricultural, food waste etc.) ● Operating digester for 5 years - meeting Rule 30
GLOBAL MARKETS & TECHNOLOGIES ∙
September 2017 Lauren Turner, Sales Manager - Clean Energy Solutions
Air Liquide US Biogas Overview •
THIS DOCUMENT IS PUBLIC AIR LIQUIDE, THE WORLD LEADER IN GASES, TECHNOLOGIES AND SERVICES FOR INDUSTRY AND HEALTH I
Air Liquide Membrane Technology for Biogas
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I AIR LIQUIDE, THE WORLD LEADER IN GASES, TECHNOLOGIES AND SERVICES FOR INDUSTRY AND HEALTH
∙ September 2017 Lauren Turner, Sales Manager - Clean Energy Solutions
Air Liquide US Biogas Overview
THIS DOCUMENT IS PUBLIC
Missouri Hog Digester Project
● Hog farm → covered lagoons
● 400 SCFM raw biogas production
● Air Liquide’s MicroBiogaz membrane system
● Lowest cost / simple operation
● RNG used in CNG transportation market
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I AIR LIQUIDE, THE WORLD LEADER IN GASES, TECHNOLOGIES AND SERVICES FOR INDUSTRY AND HEALTH
∙ September 2017 Lauren Turner, Sales Manager - Clean Energy Solutions
Air Liquide US Biogas Overview
THIS DOCUMENT IS PUBLIC
Biogas and Rule 30 – Required Guarantee Performance Landfill Feed Digester Feed Typical Product Rule 30
Flow SCFM 1000 to 10,000 50 to 10,000+ Recovery 95 – 99% Pressure, psig 0 > Compressed 0 > Compressed Per Pipeline Per Pipeline Temperature, F 100 100 < 120 < 105 Composition, Mol%
C1 50 – 55 % 50 – 75 % Per HHV 8.45 N2 1 – 15 % <1% 4% Inerts 4% O2 0.5 – 2 % <0.2 0.2% 0.2 % (0.1%) CO2 35 – 45 % 25 – 40 % 2 % 3% H2S 10 – 1000 ppm 100 – 5000+ ppm 4 ppm 4 ppm
VOCs/SVOCs/PAH <2000 ppm < 150 ppm Silent 0.1 ppm
Siloxanes Nil to 30 ppm Nil to 30 ppm Silent Commercially Free 0.1 mg/m3
Hydrogen Nil Nil Silent 0.1 % Aldehydes / Ketones Ppm levels Nil Silent 0.1 ppm
Halocarbons Ppm levels Nil Silent 0.1 ppm Ammonia ppm levels ppm levels Silent 10 ppm Mercury Trace Nil Silent 0.01 ug/m3 Volatile Metals Nil Nil Silent 0.01 ug/m3 PCBs Nil Nil Silent 0.1 ppB Pesticides Nil Nil Silent 1 ppB Pharmaceuticals Nil Nil Silent 1 ppB H2O Sat’d Sat’d 7lb./MMSCF 7lb/MMSCF HHV, BTU/ft3 967 (4% inerts) 990 (2% inerts)
Gas Constituent
Percent
Methane 99.4
Carbon Dioxide 0.5
Nitrogen 0.1
Oxygen Nil
I AIR LIQUIDE, THE WORLD LEADER IN GASES, TECHNOLOGIES AND SERVICES FOR INDUSTRY AND HEALTH
∙ September 2017 Lauren Turner, Sales Manager - Clean Energy Solutions
Air Liquide US Biogas Overview
THIS DOCUMENT IS PUBLIC
Point Loma WWTP to Pipeline / Fuel Cell
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■ BioFuels Energy owner ■ Biogas to SDG&E Pipeline (Rule 30) ■ 3 Fuel Cell Energy Fuel Cells
– 2 via directed Biomethane – 1 on-site consuming actual biomethane
■ Gas processing by Air Liquide ■ Total plant built and operated by SCS
Sales Gas
Source: SCS
I AIR LIQUIDE, THE WORLD LEADER IN GASES, TECHNOLOGIES AND SERVICES FOR INDUSTRY AND HEALTH
∙ September 2017 Lauren Turner, Sales Manager - Clean Energy Solutions
Air Liquide US Biogas Overview
THIS DOCUMENT IS PUBLIC
Proven Removal of Siloxanes and VOCs for Rule 30
050
100150200
Tota
l (pp
mv)
Raw Feed WasteStream
Sales
Pipeline (Ref)
VOCs
I AIR LIQUIDE, THE WORLD LEADER IN GASES, TECHNOLOGIES AND SERVICES FOR INDUSTRY AND HEALTH
∙ September 2017 Lauren Turner, Sales Manager - Clean Energy Solutions
Air Liquide US Biogas Overview
THIS DOCUMENT IS PUBLIC
Market Trends
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● California growing slowly ● High cost – specifications, measurement , interconnection ● Projects driven by State grants
● California digester focused ● Landfill limited due to N2 removal requirement
● Interest in small scale continues (<200 SCFM) ● Only recently has cost dropped to economical point
● Municipal WWTP digester activity increasing ● Commercial and technical requirements hamper growth ● Much higher cost and longer timeline than private development
● Growing number of technology suppliers ● RINS attractive but ongoing long term concern ● International activity continues high. Highly competitive. ● Biogas to hydrogen interest growing
I AIR LIQUIDE, THE WORLD LEADER IN GASES, TECHNOLOGIES AND SERVICES FOR INDUSTRY AND HEALTH
∙ September 2017 Lauren Turner, Sales Manager - Clean Energy Solutions
Air Liquide US Biogas Overview•
THIS DOCUMENT IS PUBLIC
Questions?
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