2 nd sc meeting, rome, 19-20 january, 2014
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2nd SC meeting, Rome, 19-20 January, 2014
EMODNET Lot No. 4 - Chemistry
Black Sea
Luminiţa BugaNIMRD, Romania
Azov Sea
Marmara Sea
IMS-METU
IMSM-IU
IO-BAS
NIMRD
UkrSCES
MHI
IBSS MB-UHI
YugNIRO
SOI SIO-RAS
RIHMI-WDC
TSU-DNA(+GAMMA)
NEA
HCMR
MARUM
Partners Black Sea
Group ExamplesPesticidides and biocides DDT, HCB
Antifoulants TBT, TPT
Pharmaceuticals oxytetracycline
Heavy metals mercury, cadmium, lead
Hydrocarbons anthracene, fluoroanthene
Radionuclides 137Cs, 239Pu
Fertilisers nitrogen (DIN, TN), phosphorus (DIP, TP)
Organic matter (e.g. from sewers or mariculture) total carbon (TOC)
Chlorophyll
Silicates
Partial pressures of dissolved gases oxygen, carbon dioxide
Plastics polyethelyne, polypropylene25
Acidity (from pH, pCO2, Total Inorganic Carbon, alkalinity) pH
The Chemistry portal should deliver data and metadata for the following chemical groups, providing data in the most appropriate
matrix (water column, in sediments, in biota).
Action: M1 - M6: gathering data sets following the inventory, converting these to ODV format (using NEMO software), compiling metadata in CDI format (using MIKADO software), populating the CDI service (in cooperation with MARIS), getting connected in case not yet done (configuring the Download Manager software in cooperation with MARIS) following the priority list:
start with observation data sets from 1999 to present with oxygen, fertilisers/nutrients, chlorophyll-a, silicates and acidity in the water column;
then follow up by observation data sets with heavy metals, hydrocarbon, pesticides, and antifulants, first in sediment and biota (Mytilus sp);
then later for the water column and other biota species.
The aim is to have at least the first priority done in the first 6 months to allow for the QA/QC and production of the first data products between M6 and M12. The data gathering and CDI population will continue during the project (all participants).
Bulgaria: IO-BAS
(From SDN/EMONET CDI interface; all SDN Licence)
Nitrate concentration parameters in the water column 117Phosphate concentration parameters in the water column 117Dissolved oxygen parameters in the water column 104Silicate concentration parameters in the water column 64Ammonium concentration parameters in the water column 63Alkalinity, acidity and pH of the water column 51Nitrite concentration parameters in the water column 46
Turkey: IMS METU
- Preparation of observation data with oxygen, fertilizers/nutrients, chlorophyll-a, silicates and acidity in the water column from 1999 to present: 588 oceanographic stations with required parameters were carried out by IMS METU in Black Sea in that period.
- The CDI files were prepared for all stations. At present, 73 CDIs are already included in SeaDataNet, while others are ready for submission.
- The data are now undergoing quality control, which is planned to be completed at the first half of Feb 2014. Upon completing QC the ODV files will be generated and submitted to regional coordinator presumably by Feb 16, 2014
Total statio
nsDOW H2S NO3-N+
NO2-N NO2-N NH4 PO4 Si Active Chl Phaeo Total Chl pH
588 434 205 582 329 368 582 577 344 96 370 175
Turkey: IU-IMSM
Preparation od CDIs/ODVs will start after 24 January and all data will be available for EMODNET
Heavy metals Pb, Cu, Fe, Mn, Cd 3 Stations Black Sea and Black Sea exit of Istanbul Strait
1998-2000,2005-2006 (Seasonal)
Heavy metals Pb, Cu, Fe, Mn, Cd 2 Stations Sea of Marmara exit of Istanbul Strait
1998-2000,2005-2006 (Seasonal)
Organic matter POC, TOC 3 Stations Black Sea and Black Sea exit of Istanbul Strait
1998-2000,2005-2006 (Seasonal)
Organic matter POC, TOC 2 Stations Sea of Marmara exit of Istanbul Strait
1998-2000,2005-2006 (Seasonal)
Hydrochemical and hydrology
temperature, salinity, O2, TSS
3 Stations Black Sea and Black Sea exit of Istanbul Strait
1998-2000,2005-2006 (Seasonal)
Hydrochemical and hydrology
temperature, salinity, O2, TSS
2 Stations Sea of Marmara exit of Istanbul Strait
1998-2000,2005-2006 (Seasonal)
Georgia:Number of CDI/ODV files provided by TSU/GAMMA from 1999:
Parameters Number of CDI/ODV files
1 Dissolved oxygen content in water column (+pH, Turbidity, TSS, salinity, EC) 330
2 Fertilizers/nutrients 793 Chlorophyll-a 54 Heavy metals content in water column 1595 Heavy metals content in sediments 4246 Hydrocarbons in water column 1217 Hydrocarbons content in sediments 174
8 Water column parameters (pH, Turbidity, TSS, salinity, EC) 309
TOTAL 1602
About 240 new CDI ODV files will be delivered during the year 2014.
Ukraine: UkrSCES (Ukrainian Scientific Centre of Ecology of the Sea )
1. Water column 1999-2003 DDT, DDE, DDD, PHB, Deldrine, Aldrine, Endrine, b-Hexachlorocyclohexane (b-HCH), Heptachlor
2. Water column 1991-2003 Phenanthrene,Anthracene,Chrysene,Fluorene,Fluoranthene,Pyrene,Perylene,Naphthalene, Acenaphthene,Pristane,Octadecene,Chrysene, Benzo(a)pyrene, Benzo(ghi)perylene .
3. Water column 2000-2003temperature, salinity, O2, CO, SO4.
Already in EMODNET (1999 +2000):
Dissolved oxygen parameters 316Phosphate concentration parameters 186Nitrite concentration parameters 176Nitrate concentration parameters 125Dissolved total and organic nitrogen concentrations 106Dissolved total or organic phosphorus concentration 106
Ukraine: UHI-MB 1. Processed data prepared before for the UBSS project (2003 – 2010): 2. The work is continued toward time limits expantion (to 1992 and 2012), pollutant groups addition and also bottom sediment data inclusion.
Continuous Ukrainian monitoring program(Dnieper-Bug estuary + Ilyichevsk + Odessa + Yalta +
Kerch Strait)NH4, NO2, NO3, NO2+NO3, PO4, TP, [µg/l] 2506Silicate [µg/l] 2501Oxygen, hydrogen sulphide [ml/l]
Oxygen = 3539, HSUL = 1133
Total alkalinity [mmol/l], pH ALKY = 2505, pH = 3509
Research project SC1 of GEF/BSERP, timeseries(Kiliya delta of Danube, Vilkovo + Dniester delta, Mayaki
Dniester liman outlet, Zatoka)NH4, NO2, NO3, NO2+NO3, PO4, TP, [µg/l] 158Silicate [µg/l] 158Oxygen 52pH 100
Research project SC1 of GEF/BSERP (Dnieper liman outlet, Ochakov + Kerch Strait)
2003-2004 PHOS =282, TPHS = 195, NTRI = 190, NTRA = 229, AMON = 154, NTOT = 300 2003-2004 2982003-2004 Oxygen = 3092003-2004 PHOS = 300, TPHS = 301, NTRI = 300, NTRA = 300, AMON = 301, NTOT = 299 2003-2004 3012003-2004 Oxygen = 301, HSUL = 322003-2004 ALKY = 301, pH = 300
Ukraine: IBSS
1. Mercury concentration in the Black Sea mussels over the period from 1987 to 2011, total amount of the data available are 138 (fig 1, 2)
3
19
64
10 5 3
23
5 4 10
10203040506070
1987 1988 1989 1990 1991 2002 2005 2006 2007 2011
Year
Num
ber o
f Dat
a
Round Bay
Sevastopol Bay
Sevastopol
South Bay
Fig. 2. Location of the sampling sites in different Sevastopol bays where the mercury concentration in mussels was determined by IBSS in 1987-2011
Fig. 1. Number of IBSS own data on concentration of mercury in the Black Sea mussels over the period 1987-2011
Ukraine: IBSS
Fig. 3. Overall map of the sampling sites in the Black Sea where the mercury concentration in mussels was determined by IBSS in 1987-2011
Fig. 4. Map of the Black Sea locations where PCBs and DDT concentrations were measured by IBSS in surficial sediments in 2007-2011
Ukraine: MHI
Sent the ODVs file till 2010 (most of them before 1999)- Chemistry water column: 1724 (fertilizers, Silicates, alkalinity, PH, etc)- Sediment: 75 Heavy metals- Radionuclides: 1200
Ukraine: YugNIRO (Southern Scientific Research Institute of Marine Fisheries and Oceanography )
NO any information received YET!!But data in SDN till 1996
Russia: SIO-RAS
1. CDI data were provided up to 2011, other will be provided start with observation data sets from 1999 to present with oxygen, fertilizers/nutrients, chlorophyll-a, silicates and acidity in the water column; 2. In addition also heavy metals will be provided
Water column Fertilisers PO4-P, TP, NO3-N, NO2-N,
NH4-N, TNSIO RAS, Southern branch SIO RAS
~7800 stations Eastern coast of Black Sea 1989-2008 Monitoring
program
Water column Organic matter BOD5, oxydizability (Mn),
organic P, organic NSIO RAS, Southern branch SIO RAS
~200 stations Eastern coast of Black Sea 2006-2008 Monitoring
program
Water column
Some of the classes
O2, H2S, pH, Total alkalinity, Si
SIO RAS, Southern branch SIO RAS
~7800 stations Eastern coast of Black Sea 1999-2008 Monitoring
program
Water column
Hydrocarbons including oil pollution
SIO RAS, Southern branch SIO RAS
183 stations Eastern coast of Black Sea 2006-2008
Water column Contaminants
Detergents, Fenols, Suspended solids, TPHs
SIO RAS, Southern branch SIO RAS
183 stations Eastern coast of Black Sea 2006-2008 Monitoring
program
SedimentTotal Petroleum Hydrocarbons (TPHs)
SIO RAS, Southern branch SIO RAS
58 stations Black Sea 2007, 2008
Sediment Heavy metals12 parameters, including Mn, Fe, Cu, Zn, Cd, Pb, Hg, Ni
SIO RAS, Southern branch SIO RAS
58 stations Black Sea 2007, 2008
Russia: RIHMI-WDC- oceanographic data ODV format: 401 cruises, 15366 oceanographic stations (Black and Azov Seas) - NO new data after 1996- CDIs files: working with MARIS for check these CDIs.
0
100
200
300
400
500
600
700
800
900
1000
1957 1959 1961 1963 1965 1967 1969 1971 1973 1975 1977 1979 1981 1983 1985 1987 1989 1991 1993 1995
Number oceanographic stations for Black Sea (RNODC)
Fig 1 – Number stations by year for period 1957-1996
(Black and Azov Seas)
Fig 2 – Data coverage
Russia: SOI
- Sent 921 ODV files (1996 (??? Maybe 1999) – 2011)
- Chemistry: Nutrients, Silicates Oxygen, Organic Carbon, Alkalinity- T, S
Romania: NIMRD
Ammonium concentration parameters in the water column 738
Dissolved oxygen parameters in the water column 738
Nitrate concentration parameters in the water column 738
Nitrite concentration parameters in the water column 738
Phosphate concentration parameters in the water column 738
Silicate concentration parameters in the water column 738
Total metal concentrations in water bodies 456
Inorganic chemical composition of sediment or rocks 337
Pesticide concentrations in water bodies 267
Chlorophyll pigment concentrations in the water column 239
Pesticide concentrations in sediment 233
Greece: HCMR
Group Data Period Area StationsWater column SPM Sep 2002, Sep 2004 Danube estuary 54
Sediment Metals Sep 2002 Danube estuary 9
Water column Nutrients Oct 2007 Danube estuary 28
Water column Chlorophyll Oct 2007 Danube estuary 28
SPMBottle data of Suspended Particulate Matter in the water from two cruises in Danube estuary30 stations in September 2002 and 24 stations in September 2004No CDI yetMetalsMetals in sediment9 stations in Danube estuary in September 2002, 1 to 3 cores in each stationConcentrations of metals in core slices of different thicknessNo CDI yetNutrients and ChlorophyllNutrients and Chlorophyll data in the water column from 28 stations during SESAME cruise in October 2007 in Black SeaNo CDI yet
Germany: UNI-Bremen
PANGAEA has about 350 datasets containing chemical oceanography from the Black Sea
- started to generate ODV
Present situation
Present situation (1999 -2013) Data sets per partnersPer CDI Partner Datasets Country AccessNational Institute of Meteorology and Hydrology, Bulgarian Academy of Sciences 442 Bulgaria +/-Institute of Fishery Resources (IFR) 247 Bulgaria +Bulgarian National Oceanographic Data Centre(BGODC), Institute of Oceanology 117 Bulgaria +IFREMER / IDM/SISMER 4 FranceScientific - Research Firm GAMMA 903 Georgia +Iv.Javakhishvili Tbilisi State University, Centre of Relations with UNESCO Oceanological Research Centre and GeoDNA (UNESCO) 81 Georgia +
National Institute for Marine Research and Development Grigore Antipa 2035 Romania +P.P.Shirshov Institute of Oceanology, RAS 6421 Russian Federation +
All-Russia Research Institute of Hydrometeorological Information - World Data Centre (RIHMI-WDC) National Oceanographic Data Centre (NODC) 16 Russian Federation +
Karadeniz Technical University, Faculty of Marine Sciences 242 Turkey Not tried
Institute of Marine Sciences, Middle East Technical University 201 Turkey +Sinop University, Fisheries Faculty 183 Turkey +Ankara University 24 Turkey +
Marine branch of Ukrainian Hydrometeorological Institute 1200 Ukraine +Odessa National I.I.Mechnikov University 800 Ukraine -
Ukrainian scientific center of Ecology of Sea (UkrSCES) 502 Ukraine +Danube Hydro-meteorological Observatory 44 Ukraine River
Scientific Research Institute of Ecological Problems (USRIEP) 4 Ukraine RiverMarine Hydrophysical Institute 2 Ukraine -
1996 1997 1998 1999 2000 2001 2002 2003 2004 2005 2006 2007 2008 2009 2010 2011 2012 20130
200
400
600
800
1000
1200
1400
1600
1800
2000
3 4 4
606
936 994 950
1171
17891877
1265
955
11651042
683
1269 3
Present situation1996 - 2013
Data sets per years
Seems to be data series started in the respective years
Present situation (1999 -2013) activities done:
Contact with BS partners Received short reports No answer from: NEA (Georgia), IO-BAS (Bulgaria), YugNIRO
(Ukraine) Received ODV/CDI files from some partners Downloaded Nutrients ODVs from SDN for 1999 – 2013 period ODV files analyses started Contacted MHI (Alexey Khaliulin)
- received some ODVs from Emodnet 1;
- next: the PARADOX files will be transferred to NIMRD
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