2 nd sc meeting, rome, 19-20 january, 2014

2nd SC meeting, Rome, 19-20 January, 2014

EMODNET Lot No. 4 - Chemistry

Black Sea

Luminiţa BugaNIMRD, Romania

Azov Sea

Marmara Sea

IMS-METU

IMSM-IU

IO-BAS

NIMRD

UkrSCES

MHI

IBSS MB-UHI

YugNIRO

SOI SIO-RAS

RIHMI-WDC

TSU-DNA(+GAMMA)

NEA

HCMR

MARUM

Partners Black Sea

Group ExamplesPesticidides and biocides DDT, HCB

Antifoulants TBT, TPT

Pharmaceuticals oxytetracycline

Heavy metals mercury, cadmium, lead

Hydrocarbons anthracene, fluoroanthene

Radionuclides 137Cs, 239Pu

Fertilisers nitrogen (DIN, TN), phosphorus (DIP, TP)

Organic matter (e.g. from sewers or mariculture) total carbon (TOC)

Chlorophyll

Silicates

Partial pressures of dissolved gases oxygen, carbon dioxide

Plastics polyethelyne, polypropylene25

Acidity (from pH, pCO2, Total Inorganic Carbon, alkalinity) pH

The Chemistry portal should deliver data and metadata for the following chemical groups, providing data in the most appropriate

matrix (water column, in sediments, in biota).

Action: M1 - M6: gathering data sets following the inventory, converting these to ODV format (using NEMO software), compiling metadata in CDI format (using MIKADO software), populating the CDI service (in cooperation with MARIS), getting connected in case not yet done (configuring the Download Manager software in cooperation with MARIS) following the priority list:

start with observation data sets from 1999 to present with oxygen, fertilisers/nutrients, chlorophyll-a, silicates and acidity in the water column;

then follow up by observation data sets with heavy metals, hydrocarbon, pesticides, and antifulants, first in sediment and biota (Mytilus sp);

then later for the water column and other biota species.

The aim is to have at least the first priority done in the first 6 months to allow for the QA/QC and production of the first data products between M6 and M12. The data gathering and CDI population will continue during the project (all participants).

Bulgaria: IO-BAS

(From SDN/EMONET CDI interface; all SDN Licence)

Nitrate concentration parameters in the water column 117Phosphate concentration parameters in the water column 117Dissolved oxygen parameters in the water column 104Silicate concentration parameters in the water column 64Ammonium concentration parameters in the water column 63Alkalinity, acidity and pH of the water column 51Nitrite concentration parameters in the water column 46

Turkey: IMS METU

- Preparation of observation data with oxygen, fertilizers/nutrients, chlorophyll-a, silicates and acidity in the water column from 1999 to present: 588 oceanographic stations with required parameters were carried out by IMS METU in Black Sea in that period.

- The CDI files were prepared for all stations. At present, 73 CDIs are already included in SeaDataNet, while others are ready for submission.

- The data are now undergoing quality control, which is planned to be completed at the first half of Feb 2014. Upon completing QC the ODV files will be generated and submitted to regional coordinator presumably by Feb 16, 2014

Total statio

nsDOW H2S NO3-N+

NO2-N NO2-N NH4 PO4 Si Active Chl Phaeo Total Chl pH

588 434 205 582 329 368 582 577 344 96 370 175

Turkey: IU-IMSM

Preparation od CDIs/ODVs will start after 24 January and all data will be available for EMODNET

Heavy metals Pb, Cu, Fe, Mn, Cd 3 Stations Black Sea and Black Sea exit of Istanbul Strait

1998-2000,2005-2006 (Seasonal)

Heavy metals Pb, Cu, Fe, Mn, Cd 2 Stations Sea of Marmara exit of Istanbul Strait

1998-2000,2005-2006 (Seasonal)

Organic matter POC, TOC 3 Stations Black Sea and Black Sea exit of Istanbul Strait

1998-2000,2005-2006 (Seasonal)

Organic matter POC, TOC 2 Stations Sea of Marmara exit of Istanbul Strait

1998-2000,2005-2006 (Seasonal)

Hydrochemical and hydrology

temperature, salinity, O2, TSS

3 Stations Black Sea and Black Sea exit of Istanbul Strait

1998-2000,2005-2006 (Seasonal)

Hydrochemical and hydrology

temperature, salinity, O2, TSS

2 Stations Sea of Marmara exit of Istanbul Strait

1998-2000,2005-2006 (Seasonal)

Georgia:Number of CDI/ODV files provided by TSU/GAMMA from 1999:

Parameters Number of CDI/ODV files

1 Dissolved oxygen content in water column (+pH, Turbidity, TSS, salinity, EC) 330

2 Fertilizers/nutrients 793 Chlorophyll-a 54 Heavy metals content in water column 1595 Heavy metals content in sediments 4246 Hydrocarbons in water column 1217 Hydrocarbons content in sediments 174

8 Water column parameters (pH, Turbidity, TSS, salinity, EC) 309

TOTAL 1602

About 240 new CDI ODV files will be delivered during the year 2014.

Ukraine: UkrSCES (Ukrainian Scientific Centre of Ecology of the Sea )

1. Water column 1999-2003 DDT, DDE, DDD, PHB, Deldrine, Aldrine, Endrine, b-Hexachlorocyclohexane (b-HCH), Heptachlor

2. Water column 1991-2003 Phenanthrene,Anthracene,Chrysene,Fluorene,Fluoranthene,Pyrene,Perylene,Naphthalene, Acenaphthene,Pristane,Octadecene,Chrysene, Benzo(a)pyrene, Benzo(ghi)perylene .

3. Water column 2000-2003temperature, salinity, O2, CO, SO4.

Already in EMODNET (1999 +2000):

Dissolved oxygen parameters 316Phosphate concentration parameters 186Nitrite concentration parameters 176Nitrate concentration parameters 125Dissolved total and organic nitrogen concentrations 106Dissolved total or organic phosphorus concentration 106

Ukraine: UHI-MB 1. Processed data prepared before for the UBSS project (2003 – 2010): 2. The work is continued toward time limits expantion (to 1992 and 2012), pollutant groups addition and also bottom sediment data inclusion.

Continuous Ukrainian monitoring program(Dnieper-Bug estuary + Ilyichevsk + Odessa + Yalta +

Kerch Strait)NH4, NO2, NO3, NO2+NO3, PO4, TP, [µg/l] 2506Silicate [µg/l] 2501Oxygen, hydrogen sulphide [ml/l]

Oxygen = 3539, HSUL = 1133

Total alkalinity [mmol/l], pH ALKY = 2505, pH = 3509

Research project SC1 of GEF/BSERP, timeseries(Kiliya delta of Danube, Vilkovo + Dniester delta, Mayaki

Dniester liman outlet, Zatoka)NH4, NO2, NO3, NO2+NO3, PO4, TP, [µg/l] 158Silicate [µg/l] 158Oxygen 52pH 100

Research project SC1 of GEF/BSERP (Dnieper liman outlet, Ochakov + Kerch Strait)

2003-2004 PHOS =282, TPHS = 195, NTRI = 190, NTRA = 229, AMON = 154, NTOT = 300 2003-2004 2982003-2004 Oxygen = 3092003-2004 PHOS = 300, TPHS = 301, NTRI = 300, NTRA = 300, AMON = 301, NTOT = 299 2003-2004 3012003-2004 Oxygen = 301, HSUL = 322003-2004 ALKY = 301, pH = 300

Ukraine: IBSS

1. Mercury concentration in the Black Sea mussels over the period from 1987 to 2011, total amount of the data available are 138 (fig 1, 2)

3

19

64

10 5 3

23

5 4 10

10203040506070

1987 1988 1989 1990 1991 2002 2005 2006 2007 2011

Year

Num

ber o

f Dat

a

Round Bay

Sevastopol Bay

Sevastopol

South Bay

Fig. 2. Location of the sampling sites in different Sevastopol bays where the mercury concentration in mussels was determined by IBSS in 1987-2011

Fig. 1. Number of IBSS own data on concentration of mercury in the Black Sea mussels over the period 1987-2011

Ukraine: IBSS

Fig. 3. Overall map of the sampling sites in the Black Sea where the mercury concentration in mussels was determined by IBSS in 1987-2011

Fig. 4. Map of the Black Sea locations where PCBs and DDT concentrations were measured by IBSS in surficial sediments in 2007-2011

Ukraine: MHI

Sent the ODVs file till 2010 (most of them before 1999)- Chemistry water column: 1724 (fertilizers, Silicates, alkalinity, PH, etc)- Sediment: 75 Heavy metals- Radionuclides: 1200

Ukraine: YugNIRO (Southern Scientific Research Institute of Marine Fisheries and Oceanography )

NO any information received YET!!But data in SDN till 1996

Russia: SIO-RAS

1. CDI data were provided up to 2011, other will be provided start with observation data sets from 1999 to present with oxygen, fertilizers/nutrients, chlorophyll-a, silicates and acidity in the water column; 2. In addition also heavy metals will be provided

Water column Fertilisers PO4-P, TP, NO3-N, NO2-N,

NH4-N, TNSIO RAS, Southern branch SIO RAS

~7800 stations Eastern coast of Black Sea 1989-2008 Monitoring

program

Water column Organic matter BOD5, oxydizability (Mn),

organic P, organic NSIO RAS, Southern branch SIO RAS


program

Water column

Some of the classes

O2, H2S, pH, Total alkalinity, Si

SIO RAS, Southern branch SIO RAS


program

Water column

Hydrocarbons including oil pollution


183 stations Eastern coast of Black Sea 2006-2008

Water column Contaminants

Detergents, Fenols, Suspended solids, TPHs


183 stations Eastern coast of Black Sea 2006-2008 Monitoring

program

SedimentTotal Petroleum Hydrocarbons (TPHs)


58 stations Black Sea 2007, 2008

Sediment Heavy metals12 parameters, including Mn, Fe, Cu, Zn, Cd, Pb, Hg, Ni


58 stations Black Sea 2007, 2008

Russia: RIHMI-WDC- oceanographic data ODV format: 401 cruises, 15366 oceanographic stations (Black and Azov Seas) - NO new data after 1996- CDIs files: working with MARIS for check these CDIs.

0

100

200

300

400

500

600

700

800

900

1000

1957 1959 1961 1963 1965 1967 1969 1971 1973 1975 1977 1979 1981 1983 1985 1987 1989 1991 1993 1995

Number oceanographic stations for Black Sea (RNODC)

Fig 1 – Number stations by year for period 1957-1996

(Black and Azov Seas)

Fig 2 – Data coverage

Russia: SOI

- Sent 921 ODV files (1996 (??? Maybe 1999) – 2011)

- Chemistry: Nutrients, Silicates Oxygen, Organic Carbon, Alkalinity- T, S

Romania: NIMRD

Ammonium concentration parameters in the water column 738

Dissolved oxygen parameters in the water column 738

Nitrate concentration parameters in the water column 738

Nitrite concentration parameters in the water column 738

Phosphate concentration parameters in the water column 738

Silicate concentration parameters in the water column 738

Total metal concentrations in water bodies 456

Inorganic chemical composition of sediment or rocks 337

Pesticide concentrations in water bodies 267

Chlorophyll pigment concentrations in the water column 239

Pesticide concentrations in sediment 233

Greece: HCMR

Group Data Period Area StationsWater column SPM Sep 2002, Sep 2004 Danube estuary 54

Sediment Metals Sep 2002 Danube estuary 9

Water column Nutrients Oct 2007 Danube estuary 28

Water column Chlorophyll Oct 2007 Danube estuary 28

SPMBottle data of Suspended Particulate Matter in the water from two cruises in Danube estuary30 stations in September 2002 and 24 stations in September 2004No CDI yetMetalsMetals in sediment9 stations in Danube estuary in September 2002, 1 to 3 cores in each stationConcentrations of metals in core slices of different thicknessNo CDI yetNutrients and ChlorophyllNutrients and Chlorophyll data in the water column from 28 stations during SESAME cruise in October 2007 in Black SeaNo CDI yet

Germany: UNI-Bremen

PANGAEA has about 350 datasets containing chemical oceanography from the Black Sea

- started to generate ODV

Present situation

Present situation (1999 -2013) Data sets per partnersPer CDI Partner Datasets Country AccessNational Institute of Meteorology and Hydrology, Bulgarian Academy of Sciences 442 Bulgaria +/-Institute of Fishery Resources (IFR) 247 Bulgaria +Bulgarian National Oceanographic Data Centre(BGODC), Institute of Oceanology 117 Bulgaria +IFREMER / IDM/SISMER 4 FranceScientific - Research Firm GAMMA 903 Georgia +Iv.Javakhishvili Tbilisi State University, Centre of Relations with UNESCO Oceanological Research Centre and GeoDNA (UNESCO) 81 Georgia +

National Institute for Marine Research and Development Grigore Antipa 2035 Romania +P.P.Shirshov Institute of Oceanology, RAS 6421 Russian Federation +

All-Russia Research Institute of Hydrometeorological Information - World Data Centre (RIHMI-WDC) National Oceanographic Data Centre (NODC) 16 Russian Federation +

Karadeniz Technical University, Faculty of Marine Sciences 242 Turkey Not tried

Institute of Marine Sciences, Middle East Technical University 201 Turkey +Sinop University, Fisheries Faculty 183 Turkey +Ankara University 24 Turkey +

Marine branch of Ukrainian Hydrometeorological Institute 1200 Ukraine +Odessa National I.I.Mechnikov University 800 Ukraine -

Ukrainian scientific center of Ecology of Sea (UkrSCES) 502 Ukraine +Danube Hydro-meteorological Observatory 44 Ukraine River

Scientific Research Institute of Ecological Problems (USRIEP) 4 Ukraine RiverMarine Hydrophysical Institute 2 Ukraine -

1996 1997 1998 1999 2000 2001 2002 2003 2004 2005 2006 2007 2008 2009 2010 2011 2012 20130

200

400

600

800

1000

1200

1400

1600

1800

2000

3 4 4

606

936 994 950

1171

17891877

1265

955

11651042

683

1269 3

Present situation1996 - 2013

Data sets per years

Seems to be data series started in the respective years

Present situation (1999 -2013) activities done:

Contact with BS partners Received short reports No answer from: NEA (Georgia), IO-BAS (Bulgaria), YugNIRO

(Ukraine) Received ODV/CDI files from some partners Downloaded Nutrients ODVs from SDN for 1999 – 2013 period ODV files analyses started Contacted MHI (Alexey Khaliulin)

- received some ODVs from Emodnet 1;

- next: the PARADOX files will be transferred to NIMRD

2 nd sc meeting, rome, 19-20 january, 2014

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