fpl-043 exhibit 3
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Reported:
PTN - FPL Turkey Point Nuclear Plant
9760 SW 344 Street
08/26/2013 10:36Homestead FL, 33035
FPL Central Laboratory
6001A Village Blvd.
West Palm Beach, FL 33407
Phone: 561-640-2055
State of Florida CompQAQ/QA Manual: 920041
NELAC Certification #: E56078
LABORATORY RESULTS FOR WORK ORDER 13H0286
Marister RuizAttn:
Case Narrative for MD-WASD South District WWTP
SAMPLE COLLECTION:On 08/07/2013 at 08:45 AM, a flow-based compositor was set up at the Miami-Dade County South District Waste Water Treatment Plant. The
compositor was set up at the east side collection point. The compositor is a HACH Sigma 900 MAX auto samplers. The auto sampler collected and
placed into four separate 10 liter jugs 85 mL individual grab samples. Each grab sample was taken after a set amount of flow had past through the
system. The composite jugs are kept within a refrigerated are of the auto sampler. The temperature through-out the entire composite period of 24 hours
was maintained at less than 6 degrees Celsius.
On 08/08/2013 at 08:50 AM, the four 10 liter jugs from the east side collection point were composited in to one approximately forty liter sample that
was labeled East Composite. A duplicate composite sample was also prepared at the same time.
At 09:07 AM, a grab sample was taken from the east side collection point for the Volatile Organic Compounds analysis by EPA Method 624. This
sample was collected from a sampling point that did not need tubing and was labeled as East Grab. A separate grab sample was collected and tested in
the field for pH, Temperature, Free Chlorine and Total Chlorine.
A duplicate grab sample was also collected at the same time.
At 09:15 AM, a grab sample was taken from the west side collection point for the Volatile Organic Compounds analysis by EPA Method 624. This
sample was collected from a sampling point that did not need tubing and labeled as West Grab. A separate grab sample was collected and tested in the
field for pH, Temperature, Free Chlorine and Total Chlorine.
Tom Helton, QA Officer
FPL Central Lab The results in this report apply to the samples analyzed in accordance with the
chain of custody document. This analytical report must be reporduced in its
entirety. All analyses were performed using EPA methods and certified to meet
NELAC requirements.
Serial #: 08262013103644
Page 1 of 355
Exhibit 3FPL-043
FPL-043-001
Reported:
PTN - FPL Turkey Point Nuclear Plant
9760 SW 344 Street
08/26/2013 10:36Homestead FL, 33035
FPL Central Laboratory
6001A Village Blvd.
West Palm Beach, FL 33407
Phone: 561-640-2055
State of Florida CompQAQ/QA Manual: 920041
NELAC Certification #: E56078
LABORATORY RESULTS FOR WORK ORDER 13H0286
Marister RuizAttn:
A trip blank was provided and analyzed for the Volatile Organic Compounds analysis by EPA 624.
SAMPLE LOGIN:On 08/08/2013 at 16:00, the samples were received by representatives of PACE Analytical Services, Inc. at its Pompano Beach, Florida facility.
The sample containers were received in the EPA mandated bottle type and at a temperature of 3.7 Degrees C. No issues were noted and the sample was
logged into the PACE Analytical Services, Inc. database under Work Order number 35103494.
After the completion of the analysis a report was issued to the Florida Power & Light Central Lab (FPL Central Lab). The report was then logged into
the FPL Central Lab�s database under Work Order Number 13H0286 for internal tracking purposes.
SUBCONTRACTED ANALYSIS:
The samples were subcontracted to PACE Analytical Services, Inc. The samples were analyzed by the following laboratories within the PACE
Analytical Services, Inc. network. All PACE laboratories are certified by the State of Florida under it TNI certification program. The report contained
within shows the TNI certification numbers for each laboratory. All data is reported and any data qualifier flags associated with the results are listed at
the back of this report in the Notes and Definitions Section.
Tom Helton, QA Officer
FPL Central Lab The results in this report apply to the samples analyzed in accordance with the
chain of custody document. This analytical report must be reporduced in its
entirety. All analyses were performed using EPA methods and certified to meet
NELAC requirements.
Serial #: 08262013103644
Page 2 of 355FPL-043-002
Reported:
PTN - FPL Turkey Point Nuclear Plant
9760 SW 344 Street
08/26/2013 10:36Homestead FL, 33035
FPL Central Laboratory
6001A Village Blvd.
West Palm Beach, FL 33407
Phone: 561-640-2055
State of Florida CompQAQ/QA Manual: 920041
NELAC Certification #: E56078
LABORATORY RESULTS FOR WORK ORDER 13H0286
Marister RuizAttn:
Ormond Beach, FL.
EPA 608
EPA 624
Field Data as Received
Free ChlorineTotal ChlorineConductivityTemperature (Deg. C)pHSample Name
6.90 - - 0.75 0.11East Composite
- - - - -Duplicate Composite
6.81 28.69 1.79 1.13East Grab
- - - - -Duplicate Grab
6.82 28.57 1.72 1.09West Grab
- - - - -Trip Blank
Tom Helton, QA Officer
FPL Central Lab The results in this report apply to the samples analyzed in accordance with the
chain of custody document. This analytical report must be reporduced in its
entirety. All analyses were performed using EPA methods and certified to meet
NELAC requirements.
Serial #: 08262013103644
Page 3 of 355FPL-043-003
Reported:
PTN - FPL Turkey Point Nuclear Plant
9760 SW 344 Street
08/26/2013 10:36Homestead FL, 33035
FPL Central Laboratory
6001A Village Blvd.
West Palm Beach, FL 33407
Phone: 561-640-2055
State of Florida CompQAQ/QA Manual: 920041
NELAC Certification #: E56078
LABORATORY RESULTS FOR WORK ORDER 13H0286
Marister RuizAttn:
ResultAnalyte PQL Batch Prepared Analyzed MethodQualifier DilutionUnits
Lab Sample #: 13H0286-01 Sample Matrix: Water Sample Type: Water
Sampled: 8/8/2013 8:50:00AM Received: 8/8/2013 2:40:00PM
East Composite
CertificationMDL Analyst
Pace Analytical - NELAC Certification #: E83079
GC Semivolatiles
UHeptachlor 0.010 ug/L 1 138746 EPA 6088/14/2013 23:188/13/2013 7:300.0062 JLG
61-12123 %Surrogate: Decachlorobiphenyl (S) 138746 EPA 6088/14/2013 23:188/13/2013 7:30
53-11060 %Surrogate: Tetrachloro-m-xylene (S) 138746 EPA 6088/14/2013 23:188/13/2013 7:30
Tom Helton, QA Officer
FPL Central Lab The results in this report apply to the samples analyzed in accordance with the
chain of custody document. This analytical report must be reporduced in its
entirety. All analyses were performed using EPA methods and certified to meet
NELAC requirements.
Serial #: 08262013103644
Page 4 of 355FPL-043-004
Reported:
PTN - FPL Turkey Point Nuclear Plant
9760 SW 344 Street
08/26/2013 10:36Homestead FL, 33035
FPL Central Laboratory
6001A Village Blvd.
West Palm Beach, FL 33407
Phone: 561-640-2055
State of Florida CompQAQ/QA Manual: 920041
NELAC Certification #: E56078
LABORATORY RESULTS FOR WORK ORDER 13H0286
Marister RuizAttn:
ResultAnalyte PQL Batch Prepared Analyzed MethodQualifier DilutionUnits
Lab Sample #: 13H0286-02 Sample Matrix: Water Sample Type: Water
Sampled: 8/8/2013 8:50:00AM Received: 8/8/2013 2:40:00PM
Duplicate Composite
CertificationMDL Analyst
Pace Analytical - NELAC Certification #: E83079
GC Semivolatiles
UHeptachlor 0.010 ug/L 1 138746 EPA 6088/14/2013 22:598/13/2013 7:300.0062 JLG
61-12133 %Surrogate: Decachlorobiphenyl (S) 138746 EPA 6088/14/2013 19:238/13/2013 7:30
53-11048 %Surrogate: Tetrachloro-m-xylene (S) 138746 EPA 6088/14/2013 19:238/13/2013 7:30
Tom Helton, QA Officer
FPL Central Lab The results in this report apply to the samples analyzed in accordance with the
chain of custody document. This analytical report must be reporduced in its
entirety. All analyses were performed using EPA methods and certified to meet
NELAC requirements.
Serial #: 08262013103644
Page 5 of 355FPL-043-005
Reported:
PTN - FPL Turkey Point Nuclear Plant
9760 SW 344 Street
08/26/2013 10:36Homestead FL, 33035
FPL Central Laboratory
6001A Village Blvd.
West Palm Beach, FL 33407
Phone: 561-640-2055
State of Florida CompQAQ/QA Manual: 920041
NELAC Certification #: E56078
LABORATORY RESULTS FOR WORK ORDER 13H0286
Marister RuizAttn:
ResultAnalyte PQL Batch Prepared Analyzed MethodQualifier DilutionUnits
Lab Sample #: 13H0286-03 Sample Matrix: Water Sample Type: Water
Sampled: 8/8/2013 9:07:00AM Received: 8/8/2013 2:40:00PM
East Grab
CertificationMDL Analyst
Pace Analytical - NELAC Certification #: E83079
GC/MS Volatiles
UEthylbenzene 1.0 ug/L 1 138299 EPA 6248/11/2013 18:068/11/2013 18:060.50 RGF
UTetrachloroethene 1.0 ug/L 1 138299 EPA 6248/11/2013 18:068/11/2013 18:060.50 RGF
UToluene 1.0 ug/L 1 138299 EPA 6248/11/2013 18:068/11/2013 18:060.50 RGF
79-12391 %Surrogate: 1,2-Dichloroethane-d4 (S) 138299 EPA 6248/11/2013 18:068/11/2013 18:06
71-11195 %Surrogate: 4-Bromofluorobenzene (S) 138299 EPA 6248/11/2013 18:068/11/2013 18:06
88-11395 %Surrogate: Dibromofluoromethane (S) 138299 EPA 6248/11/2013 18:068/11/2013 18:06
77-11693 %Surrogate: Toluene-d8 (S) 138299 EPA 6248/11/2013 18:068/11/2013 18:06
Tom Helton, QA Officer
FPL Central Lab The results in this report apply to the samples analyzed in accordance with the
chain of custody document. This analytical report must be reporduced in its
entirety. All analyses were performed using EPA methods and certified to meet
NELAC requirements.
Serial #: 08262013103644
Page 6 of 355FPL-043-006
Reported:
PTN - FPL Turkey Point Nuclear Plant
9760 SW 344 Street
08/26/2013 10:36Homestead FL, 33035
FPL Central Laboratory
6001A Village Blvd.
West Palm Beach, FL 33407
Phone: 561-640-2055
State of Florida CompQAQ/QA Manual: 920041
NELAC Certification #: E56078
LABORATORY RESULTS FOR WORK ORDER 13H0286
Marister RuizAttn:
ResultAnalyte PQL Batch Prepared Analyzed MethodQualifier DilutionUnits
Lab Sample #: 13H0286-04 Sample Matrix: Water Sample Type: Water
Sampled: 8/8/2013 9:07:00AM Received: 8/8/2013 2:40:00PM
Duplicate Grab
CertificationMDL Analyst
Pace Analytical - NELAC Certification #: E83079
GC/MS Volatiles
UEthylbenzene 1.0 ug/L 1 138299 EPA 6248/11/2013 18:308/11/2013 18:300.50 RGF
UTetrachloroethene 1.0 ug/L 1 138299 EPA 6248/11/2013 18:308/11/2013 18:300.50 RGF
UToluene 1.0 ug/L 1 138299 EPA 6248/11/2013 18:308/11/2013 18:300.50 RGF
79-12392 %Surrogate: 1,2-Dichloroethane-d4 (S) 138299 EPA 6248/11/2013 18:308/11/2013 18:30
71-11193 %Surrogate: 4-Bromofluorobenzene (S) 138299 EPA 6248/11/2013 18:308/11/2013 18:30
88-11397 %Surrogate: Dibromofluoromethane (S) 138299 EPA 6248/11/2013 18:308/11/2013 18:30
77-11695 %Surrogate: Toluene-d8 (S) 138299 EPA 6248/11/2013 18:308/11/2013 18:30
Tom Helton, QA Officer
FPL Central Lab The results in this report apply to the samples analyzed in accordance with the
chain of custody document. This analytical report must be reporduced in its
entirety. All analyses were performed using EPA methods and certified to meet
NELAC requirements.
Serial #: 08262013103644
Page 7 of 355FPL-043-007
Reported:
PTN - FPL Turkey Point Nuclear Plant
9760 SW 344 Street
08/26/2013 10:36Homestead FL, 33035
FPL Central Laboratory
6001A Village Blvd.
West Palm Beach, FL 33407
Phone: 561-640-2055
State of Florida CompQAQ/QA Manual: 920041
NELAC Certification #: E56078
LABORATORY RESULTS FOR WORK ORDER 13H0286
Marister RuizAttn:
ResultAnalyte PQL Batch Prepared Analyzed MethodQualifier DilutionUnits
Lab Sample #: 13H0286-05 Sample Matrix: Water Sample Type: Water
Sampled: 8/8/2013 9:07:00AM Received: 8/8/2013 2:40:00PM
West Grab
CertificationMDL Analyst
Pace Analytical - NELAC Certification #: E83079
GC/MS Volatiles
UEthylbenzene 1.0 ug/L 1 138299 EPA 6248/11/2013 19:198/11/2013 19:190.50 RGF
UTetrachloroethene 1.0 ug/L 1 138299 EPA 6248/11/2013 19:198/11/2013 19:190.50 RGF
UToluene 1.0 ug/L 1 138299 EPA 6248/11/2013 19:198/11/2013 19:190.50 RGF
79-12393 %Surrogate: 1,2-Dichloroethane-d4 (S) 138299 EPA 6248/11/2013 19:198/11/2013 19:19
71-11195 %Surrogate: 4-Bromofluorobenzene (S) 138299 EPA 6248/11/2013 19:198/11/2013 19:19
88-11397 %Surrogate: Dibromofluoromethane (S) 138299 EPA 6248/11/2013 19:198/11/2013 19:19
77-11694 %Surrogate: Toluene-d8 (S) 138299 EPA 6248/11/2013 19:198/11/2013 19:19
Tom Helton, QA Officer
FPL Central Lab The results in this report apply to the samples analyzed in accordance with the
chain of custody document. This analytical report must be reporduced in its
entirety. All analyses were performed using EPA methods and certified to meet
NELAC requirements.
Serial #: 08262013103644
Page 8 of 355FPL-043-008
Reported:
PTN - FPL Turkey Point Nuclear Plant
9760 SW 344 Street
08/26/2013 10:36Homestead FL, 33035
FPL Central Laboratory
6001A Village Blvd.
West Palm Beach, FL 33407
Phone: 561-640-2055
State of Florida CompQAQ/QA Manual: 920041
NELAC Certification #: E56078
LABORATORY RESULTS FOR WORK ORDER 13H0286
Marister RuizAttn:
ResultAnalyte PQL Batch Prepared Analyzed MethodQualifier DilutionUnits
Lab Sample #: 13H0286-06 Sample Matrix: Water Sample Type: Water
Sampled: 8/8/2013 9:07:00AM Received: 8/8/2013 2:40:00PM
Trip Blank
CertificationMDL Analyst
Pace Analytical - NELAC Certification #: E83079
GC/MS Volatiles
UEthylbenzene 1.0 ug/L 1 138299 EPA 6248/11/2013 20:328/11/2013 20:320.50 RGF
UTetrachloroethene 1.0 ug/L 1 138299 EPA 6248/11/2013 20:328/11/2013 20:320.50 RGF
UToluene 1.0 ug/L 1 138299 EPA 6248/11/2013 20:328/11/2013 20:320.50 RGF
79-12393 %Surrogate: 1,2-Dichloroethane-d4 (S) 138299 EPA 6248/11/2013 20:328/11/2013 20:32
71-11193 %Surrogate: 4-Bromofluorobenzene (S) 138299 EPA 6248/11/2013 20:328/11/2013 20:32
88-11396 %Surrogate: Dibromofluoromethane (S) 138299 EPA 6248/11/2013 20:328/11/2013 20:32
77-11694 %Surrogate: Toluene-d8 (S) 138299 EPA 6248/11/2013 20:328/11/2013 20:32
Tom Helton, QA Officer
FPL Central Lab The results in this report apply to the samples analyzed in accordance with the
chain of custody document. This analytical report must be reporduced in its
entirety. All analyses were performed using EPA methods and certified to meet
NELAC requirements.
Serial #: 08262013103644
Page 9 of 355FPL-043-009
Reported:
PTN - FPL Turkey Point Nuclear Plant
9760 SW 344 Street
08/26/2013 10:36Homestead FL, 33035
FPL Central Laboratory
6001A Village Blvd.
West Palm Beach, FL 33407
Phone: 561-640-2055
State of Florida CompQAQ/QA Manual: 920041
NELAC Certification #: E56078
LABORATORY RESULTS FOR WORK ORDER 13H0286
Marister RuizAttn:
Result PQL Units Level
Spike
Result
Source
%REC
%REC
Limits RPD
RPD
LimitQualifiers Analyte
GC Semivolatiles - Quality Control
Pace Analytical - NELAC Certification #: E83079
MDL
Batch 138746 - EPA 608 SF
BLANK (693699) Prepared: 08/13/2013 Analyzed: 08/14/2013Source: 693699
Heptachlor U 0.010 -ug/L0.0060
0.0005 61-121Surrogate: Decachlorobiphenyl (S) 750.00038 ug/L
0.0005 53-110Surrogate: Tetrachloro-m-xylene (S) 740.00037 ug/L
LCS (693700) Prepared: 08/13/2013 Analyzed: 08/14/2013Source: 693700
Heptachlor 0.38 0.010 0.5 34-11176ug/L0.0060
0.0005 61-121Surrogate: Decachlorobiphenyl (S) 710.00036 ug/L
0.0005 53-110Surrogate: Tetrachloro-m-xylene (S) 640.00032 ug/L
LCS (694208) Prepared: 08/13/2013 Analyzed: 08/14/2013Source: 694208
0.0005 61-121Surrogate: Decachlorobiphenyl (S) 730.00036 ug/L
0.0005 53-110Surrogate: Tetrachloro-m-xylene (S) 640.00032 ug/L
MS (694209) Prepared: 08/13/2013 Analyzed: 08/14/2013Source: 13H0286-01
Heptachlor 0.64 0.020 1 .0029 34-11164ug/L0.012
0.001 61-121Surrogate: Decachlorobiphenyl (S) 360.00036 ug/LS7, P2,
Tom Helton, QA Officer
FPL Central Lab The results in this report apply to the samples analyzed in accordance with the
chain of custody document. This analytical report must be reporduced in its
entirety. All analyses were performed using EPA methods and certified to meet
NELAC requirements.
Serial #: 08262013103644
Page 10 of 355FPL-043-010
Reported:
PTN - FPL Turkey Point Nuclear Plant
9760 SW 344 Street
08/26/2013 10:36Homestead FL, 33035
FPL Central Laboratory
6001A Village Blvd.
West Palm Beach, FL 33407
Phone: 561-640-2055
State of Florida CompQAQ/QA Manual: 920041
NELAC Certification #: E56078
LABORATORY RESULTS FOR WORK ORDER 13H0286
Marister RuizAttn:
Result PQL Units Level
Spike
Result
Source
%REC
%REC
Limits RPD
RPD
LimitQualifiers Analyte
GC Semivolatiles - Quality Control
Pace Analytical - NELAC Certification #: E83079
MDL
Batch 138746 - EPA 608 SF
MS (694209) Prepared: 08/13/2013 Analyzed: 08/14/2013Source: 13H0286-01
0.001 53-110Surrogate: Tetrachloro-m-xylene (S) 690.00069 ug/L
MSD (694210) Prepared: 08/13/2013 Analyzed: 08/14/2013Source: 13H0286-01
Heptachlor 0.65 0.020 1 .0029 4034-11165 1ug/L0.012
0.001 61-121Surrogate: Decachlorobiphenyl (S) 450.00045 ug/LS7, P2,
0.001 53-110Surrogate: Tetrachloro-m-xylene (S) 640.00064 ug/L
Tom Helton, QA Officer
FPL Central Lab The results in this report apply to the samples analyzed in accordance with the
chain of custody document. This analytical report must be reporduced in its
entirety. All analyses were performed using EPA methods and certified to meet
NELAC requirements.
Serial #: 08262013103644
Page 11 of 355FPL-043-011
Reported:
PTN - FPL Turkey Point Nuclear Plant
9760 SW 344 Street
08/26/2013 10:36Homestead FL, 33035
FPL Central Laboratory
6001A Village Blvd.
West Palm Beach, FL 33407
Phone: 561-640-2055
State of Florida CompQAQ/QA Manual: 920041
NELAC Certification #: E56078
LABORATORY RESULTS FOR WORK ORDER 13H0286
Marister RuizAttn:
Result PQL Units Level
Spike
Result
Source
%REC
%REC
Limits RPD
RPD
LimitQualifiers Analyte
GC/MS Volatiles - Quality Control
Pace Analytical - NELAC Certification #: E83079
MDL
Batch 138299 - ***DEFAULT PREP***
BLANK (693424) Prepared & Analyzed: 08/11/2013Source: 693424
Ethylbenzene U 1.0 -ug/L0.50
Tetrachloroethene U 1.0 -ug/L0.50
Toluene U 1.0 -ug/L0.50
40 79-123Surrogate: 1,2-Dichloroethane-d4 (S) 9538.1 ug/L
40 71-111Surrogate: 4-Bromofluorobenzene (S) 9337.1 ug/L
40 88-113Surrogate: Dibromofluoromethane (S) 9538.2 ug/L
40 77-116Surrogate: Toluene-d8 (S) 9538 ug/L
LCS (693425) Prepared & Analyzed: 08/11/2013Source: 693425
Ethylbenzene 19.5 1.0 20 37-16298ug/L0.50
Tetrachloroethene 19.4 1.0 20 64-14897ug/L0.50
Toluene 19.8 1.0 20 47-15099ug/L0.50
40 79-123Surrogate: 1,2-Dichloroethane-d4 (S) 8433.4 ug/L
40 71-111Surrogate: 4-Bromofluorobenzene (S) 9839.2 ug/L
40 88-113Surrogate: Dibromofluoromethane (S) 9136.6 ug/L
40 77-116Surrogate: Toluene-d8 (S) 9337 ug/L
Tom Helton, QA Officer
FPL Central Lab The results in this report apply to the samples analyzed in accordance with the
chain of custody document. This analytical report must be reporduced in its
entirety. All analyses were performed using EPA methods and certified to meet
NELAC requirements.
Serial #: 08262013103644
Page 12 of 355FPL-043-012
Reported:
PTN - FPL Turkey Point Nuclear Plant
9760 SW 344 Street
08/26/2013 10:36Homestead FL, 33035
FPL Central Laboratory
6001A Village Blvd.
West Palm Beach, FL 33407
Phone: 561-640-2055
State of Florida CompQAQ/QA Manual: 920041
NELAC Certification #: E56078
LABORATORY RESULTS FOR WORK ORDER 13H0286
Marister RuizAttn:
Result PQL Units Level
Spike
Result
Source
%REC
%REC
Limits RPD
RPD
LimitQualifiers Analyte
GC/MS Volatiles - Quality Control
Pace Analytical - NELAC Certification #: E83079
MDL
Batch 138299 - ***DEFAULT PREP***
LCS (693425) Prepared & Analyzed: 08/11/2013Source: 693425
MS (693426) Prepared & Analyzed: 08/12/2013Source: 13H0286-03
Ethylbenzene 20.6 1.0 20 0.50U 37-162103ug/L0.50
Tetrachloroethene 20.6 1.0 20 0.50U 64-148103ug/L0.50
Toluene 21.0 1.0 20 0.50U 47-150105ug/L0.50
40 79-123Surrogate: 1,2-Dichloroethane-d4 (S) 8734.6 ug/L
40 71-111Surrogate: 4-Bromofluorobenzene (S) 9638.2 ug/L
40 88-113Surrogate: Dibromofluoromethane (S) 9538 ug/L
40 77-116Surrogate: Toluene-d8 (S) 9337 ug/L
DUP (693427) Prepared & Analyzed: 08/11/2013Source: 13H0286-04
Ethylbenzene U 1.0 0.50U 40-ug/L0.50
Tetrachloroethene U 1.0 0.50U 40-ug/L0.50
Toluene U 1.0 .193 40-ug/L0.50
40 79-123Surrogate: 1,2-Dichloroethane-d4 (S) 9236.7 ug/L
40 71-111Surrogate: 4-Bromofluorobenzene (S) 9337.1 ug/L
Tom Helton, QA Officer
FPL Central Lab The results in this report apply to the samples analyzed in accordance with the
chain of custody document. This analytical report must be reporduced in its
entirety. All analyses were performed using EPA methods and certified to meet
NELAC requirements.
Serial #: 08262013103644
Page 13 of 355FPL-043-013
Reported:
PTN - FPL Turkey Point Nuclear Plant
9760 SW 344 Street
08/26/2013 10:36Homestead FL, 33035
FPL Central Laboratory
6001A Village Blvd.
West Palm Beach, FL 33407
Phone: 561-640-2055
State of Florida CompQAQ/QA Manual: 920041
NELAC Certification #: E56078
LABORATORY RESULTS FOR WORK ORDER 13H0286
Marister RuizAttn:
Result PQL Units Level
Spike
Result
Source
%REC
%REC
Limits RPD
RPD
LimitQualifiers Analyte
GC/MS Volatiles - Quality Control
Pace Analytical - NELAC Certification #: E83079
MDL
Batch 138299 - ***DEFAULT PREP***
DUP (693427) Prepared & Analyzed: 08/11/2013Source: 13H0286-04
40 88-113Surrogate: Dibromofluoromethane (S) 9538.1 ug/L
40 77-116Surrogate: Toluene-d8 (S) 9337.3 ug/L
MS (694452) Prepared & Analyzed: 08/13/2013Source: 13H0286-05
Ethylbenzene 19.6 1.0 20 0.50U 37-16298ug/L0.50
Tetrachloroethene 16.9 1.0 20 0.50U 64-14884ug/L0.50
Toluene 19.8 1.0 20 .44 47-15097ug/L0.50
40 79-123Surrogate: 1,2-Dichloroethane-d4 (S) 10241 ug/L
40 71-111Surrogate: 4-Bromofluorobenzene (S) 9337 ug/L
40 88-113Surrogate: Dibromofluoromethane (S) 10240.9 ug/L
40 77-116Surrogate: Toluene-d8 (S) 9738.6 ug/L
MSD (694453) Prepared & Analyzed: 08/13/2013Source: 13H0286-05
Ethylbenzene 18.2 1.0 20 0.50U 4037-16291 7ug/L0.50
Tetrachloroethene 15.7 1.0 20 0.50U 4064-14879 7ug/L0.50
Toluene 18.4 1.0 20 .44 4047-15090 8ug/L0.50
Tom Helton, QA Officer
FPL Central Lab The results in this report apply to the samples analyzed in accordance with the
chain of custody document. This analytical report must be reporduced in its
entirety. All analyses were performed using EPA methods and certified to meet
NELAC requirements.
Serial #: 08262013103644
Page 14 of 355FPL-043-014
Reported:
PTN - FPL Turkey Point Nuclear Plant
9760 SW 344 Street
08/26/2013 10:36Homestead FL, 33035
FPL Central Laboratory
6001A Village Blvd.
West Palm Beach, FL 33407
Phone: 561-640-2055
State of Florida CompQAQ/QA Manual: 920041
NELAC Certification #: E56078
LABORATORY RESULTS FOR WORK ORDER 13H0286
Marister RuizAttn:
Result PQL Units Level
Spike
Result
Source
%REC
%REC
Limits RPD
RPD
LimitQualifiers Analyte
GC/MS Volatiles - Quality Control
Pace Analytical - NELAC Certification #: E83079
MDL
Batch 138299 - ***DEFAULT PREP***
MSD (694453) Prepared & Analyzed: 08/13/2013Source: 13H0286-05
40 79-123Surrogate: 1,2-Dichloroethane-d4 (S) 10341.2 ug/L
40 71-111Surrogate: 4-Bromofluorobenzene (S) 9538.1 ug/L
40 88-113Surrogate: Dibromofluoromethane (S) 10140.4 ug/L
40 77-116Surrogate: Toluene-d8 (S) 9839.4 ug/L
Tom Helton, QA Officer
FPL Central Lab The results in this report apply to the samples analyzed in accordance with the
chain of custody document. This analytical report must be reporduced in its
entirety. All analyses were performed using EPA methods and certified to meet
NELAC requirements.
Serial #: 08262013103644
Page 15 of 355FPL-043-015
Reported:
PTN - FPL Turkey Point Nuclear Plant
9760 SW 344 Street
08/26/2013 10:36Homestead FL, 33035
FPL Central Laboratory
6001A Village Blvd.
West Palm Beach, FL 33407
Phone: 561-640-2055
State of Florida CompQAQ/QA Manual: 920041
NELAC Certification #: E56078
LABORATORY RESULTS FOR WORK ORDER 13H0286
Marister RuizAttn:
Notes and Definitions
S7 Surrogate recovery outside control limits (not confirmed by re-analysis due to insufficient sample amount).
P2 Re-extraction or re-analysis could not be performed due to insufficient sample amount.
J(S1) Estimated Value. Surrogate recovery outside laboratory control limits (confirmed by re-analysis).
Sample results reported on a dry weight basis
Relative Percent DifferenceRPD
dry
Not ReportedNR
Analyte analyzed for but Not Detected at or above the MDLU
Analyte detected between the Laboratory MDL and PQLI
+ Not NELAC Certified
V Analyte detected in the sample and the associated preparation blank
Tom Helton, QA Officer
FPL Central Lab The results in this report apply to the samples analyzed in accordance with the
chain of custody document. This analytical report must be reporduced in its
entirety. All analyses were performed using EPA methods and certified to meet
NELAC requirements.
Serial #: 08262013103644
Page 16 of 355FPL-043-016
Data Package
Pace Project# 35103494
Page 17 of 355FPL-043-017
Summary of Contents
Final Report 1
EPA 608 Analytical Data & QC 23
EPA 608 Calibration and Sample Data 30
EPA 608 Logbooks 123
EPA 624 Analytical Data & QC 131
EPA 624 Calibration and Sample Data 147
EPA 624 Logbooks 332
Chain of Custody 335
Page 18 of 355FPL-043-018
#=CL#
August 20, 2013
LIMS USE: FR - PHOEBE BROWN
LIMS OBJECT ID: 35103494
35103494Project:Pace Project No.:
RE:
Phoebe BrownFPL - Central Lab6001-A Village BlvdWest Palm Beach, FL 33407
Miami Dade
Dear Phoebe Brown:Enclosed are the analytical results for sample(s) received by the laboratory on August 08, 2013. Theresults relate only to the samples included in this report. Results reported herein conform to themost current TNI standards and the laboratory's Quality Assurance Manual, where applicable, unlessotherwise noted in the body of the report.
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
Terrence Anderson
terrence.anderson@pacelabs.comProject Manager
Enclosures
cc: Tom Helton, FPL - Central LabDaniel Pustelnik, FPL - Central Lab
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
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Page 1 of 21Page 1 of 337
Page 19 of 355FPL-043-019
#=CP#
CERTIFICATIONS
Pace Project No.:
Project:
35103494
Miami Dade
Ormond Beach Certification IDs8 East Tower Circle, Ormond Beach, FL 32174Alabama Certification #: 41320Arizona Certification #: AZ0735Colorado Certification: FL NELAC ReciprocityConnecticut Certification #: PH-0216Florida Certification #: E83079Georgia Certification #: 955Guam Certification: FL NELAC ReciprocityHawaii Certification: FL NELAC ReciprocityIllinois Certification #: 200068Indiana Certification: FL NELAC ReciprocityKansas Certification #: E-10383Kentucky Certification #: 90050Louisiana Certification #: FL NELAC ReciprocityLouisiana Environmental Certificate #: 05007Maine Certification #: FL01264Massachusetts Certification #: M-FL1264Michigan Certification #: 9911Mississippi Certification: FL NELAC Reciprocity
Missouri Certification #: 236Montana Certification #: Cert 0074Nevada Certification: FL NELAC ReciprocityNew Hampshire Certification #: 2958New Jersey Certification #: FL765New York Certification #: 11608North Carolina Environmental Certificate #: 667North Carolina Certification #: 12710Pennsylvania Certification #: 68-00547Puerto Rico Certification #: FL01264Tennessee Certification #: TN02974Texas Certification: FL NELAC ReciprocityUS Virgin Islands Certification: FL NELAC ReciprocityVirginia Environmental Certification #: 460165Washington Certification #: C955West Virginia Certification #: 9962CWisconsin Certification #: 399079670Wyoming (EPA Region 8): FL NELAC Reciprocity
REPORT OF LABORATORY ANALYSIS
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Page 20 of 355FPL-043-020
#=SS#
SAMPLE SUMMARY
Pace Project No.:
Project:
35103494
Miami Dade
Lab ID Sample ID Matrix Date Collected Date Received
35103494001 EAST COMPOSITE Water 08/08/13 08:50 08/08/13 14:40
35103494002 EAST COMP DUPLICATE Water 08/08/13 08:50 08/08/13 14:40
35103494003 EAST GRAB Water 08/08/13 09:57 08/08/13 14:40
35103494004 EAST GRAB DUPLICATE Water 08/08/13 09:07 08/08/13 14:40
35103494005 WEST GRAB Water 08/08/13 09:13 08/08/13 14:40
35103494006 TRIP BLANK Water 08/08/13 08:00 08/08/13 14:40
REPORT OF LABORATORY ANALYSIS
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Page 21 of 355FPL-043-021
#=SA#
SAMPLE ANALYTE COUNT
Pace Project No.:
Project:
35103494
Miami Dade
Lab ID Sample ID Method
Analytes
Reported LaboratoryAnalysts
35103494001 EAST COMPOSITE EPA 608 3 PASI-OJLG
35103494002 EAST COMP DUPLICATE EPA 608 3 PASI-OJLG
35103494003 EAST GRAB EPA 624 7 PASI-ORGF
35103494004 EAST GRAB DUPLICATE EPA 624 7 PASI-ORGF
35103494005 WEST GRAB EPA 624 7 PASI-ORGF
35103494006 TRIP BLANK EPA 624 42 PASI-ORGF
REPORT OF LABORATORY ANALYSIS
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Page 22 of 355FPL-043-022
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
35103494
Miami Dade
Sample: EAST COMPOSITE Lab ID: 35103494001 Collected: 08/08/13 08:50 Received: 08/08/13 14:40 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualMDLPQL
Field Data Analytical Method:
Field pH 6.90 Std. Units 08/08/13 08:501Field Temperature 4.90 deg C 08/08/13 08:501Chlorine, Total Residual 0.75 mg/L 08/08/13 08:50 7782-50-51Chlorine, Free 0.11 mg/L 08/08/13 08:50 7782-50-51
608SF GCS Pesticides and PCBs Analytical Method: EPA 608 Preparation Method: EPA 608 SF
Heptachlor 0.0062U ug/L 08/14/13 23:18 76-44-808/13/13 07:300.010 0.0062 1SurrogatesTetrachloro-m-xylene (S) 60 % 08/14/13 23:18 877-09-808/13/13 07:3053-110 1Decachlorobiphenyl (S) 23 % 08/14/13 23:18 2051-24-3 P2,S708/13/13 07:3061-121 1
REPORT OF LABORATORY ANALYSIS
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Page 23 of 355FPL-043-023
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
35103494
Miami Dade
Sample: EAST COMP DUPLICATE Lab ID: 35103494002 Collected: 08/08/13 08:50 Received: 08/08/13 14:40 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualMDLPQL
608SF GCS Pesticides and PCBs Analytical Method: EPA 608 Preparation Method: EPA 608 SF
Heptachlor 0.0062U ug/L 08/14/13 22:59 76-44-808/13/13 07:300.010 0.0062 1SurrogatesTetrachloro-m-xylene (S) 48 % 08/14/13 19:23 877-09-8 J(S1),
P208/13/13 07:3053-110 1
Decachlorobiphenyl (S) 33 % 08/14/13 19:23 2051-24-3 J(S1),P2
08/13/13 07:3061-121 1
REPORT OF LABORATORY ANALYSIS
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Page 24 of 355FPL-043-024
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
35103494
Miami Dade
Sample: EAST GRAB Lab ID: 35103494003 Collected: 08/08/13 09:57 Received: 08/08/13 14:40 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualMDLPQL
Field Data Analytical Method:
Field pH 6.81 Std. Units 08/08/13 09:571Field Temperature 28.69 deg C 08/08/13 09:571Chlorine, Total Residual 1.79 mg/L 08/08/13 09:57 7782-50-51Chlorine, Free 1.13 mg/L 08/08/13 09:57 7782-50-51
624 Volatile Organics Analytical Method: EPA 624
Ethylbenzene 0.50U ug/L 08/11/13 18:06 100-41-41.0 0.50 1Tetrachloroethene 0.50U ug/L 08/11/13 18:06 127-18-41.0 0.50 1Toluene 0.50U ug/L 08/11/13 18:06 108-88-31.0 0.50 1SurrogatesDibromofluoromethane (S) 95 % 08/11/13 18:06 1868-53-788-113 14-Bromofluorobenzene (S) 95 % 08/11/13 18:06 460-00-471-111 1Toluene-d8 (S) 93 % 08/11/13 18:06 2037-26-577-116 11,2-Dichloroethane-d4 (S) 91 % 08/11/13 18:06 17060-07-079-123 1
REPORT OF LABORATORY ANALYSIS
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Page 25 of 355FPL-043-025
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
35103494
Miami Dade
Sample: EAST GRAB DUPLICATE Lab ID: 35103494004 Collected: 08/08/13 09:07 Received: 08/08/13 14:40 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualMDLPQL
624 Volatile Organics Analytical Method: EPA 624
Ethylbenzene 0.50U ug/L 08/11/13 18:30 100-41-41.0 0.50 1Tetrachloroethene 0.50U ug/L 08/11/13 18:30 127-18-41.0 0.50 1Toluene 0.50U ug/L 08/11/13 18:30 108-88-31.0 0.50 1SurrogatesDibromofluoromethane (S) 97 % 08/11/13 18:30 1868-53-788-113 14-Bromofluorobenzene (S) 93 % 08/11/13 18:30 460-00-471-111 1Toluene-d8 (S) 95 % 08/11/13 18:30 2037-26-577-116 11,2-Dichloroethane-d4 (S) 92 % 08/11/13 18:30 17060-07-079-123 1
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..Date: 08/20/2013 12:19 PM
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Page 26 of 355FPL-043-026
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
35103494
Miami Dade
Sample: WEST GRAB Lab ID: 35103494005 Collected: 08/08/13 09:13 Received: 08/08/13 14:40 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualMDLPQL
Field Data Analytical Method:
Field pH 6.82 Std. Units 08/08/13 09:131Field Temperature 28.57 deg C 08/08/13 09:131Chlorine, Total Residual 1.72 mg/L 08/08/13 09:13 7782-50-51Chlorine, Free 1.09 mg/L 08/08/13 09:13 7782-50-51
624 Volatile Organics Analytical Method: EPA 624
Ethylbenzene 0.50U ug/L 08/11/13 19:19 100-41-41.0 0.50 1Tetrachloroethene 0.50U ug/L 08/11/13 19:19 127-18-41.0 0.50 1Toluene 0.50U ug/L 08/11/13 19:19 108-88-31.0 0.50 1SurrogatesDibromofluoromethane (S) 97 % 08/11/13 19:19 1868-53-788-113 14-Bromofluorobenzene (S) 95 % 08/11/13 19:19 460-00-471-111 1Toluene-d8 (S) 94 % 08/11/13 19:19 2037-26-577-116 11,2-Dichloroethane-d4 (S) 93 % 08/11/13 19:19 17060-07-079-123 1
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..Date: 08/20/2013 12:19 PM
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Page 27 of 355FPL-043-027
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
35103494
Miami Dade
Sample: TRIP BLANK Lab ID: 35103494006 Collected: 08/08/13 08:00 Received: 08/08/13 14:40 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualMDLPQL
624 Volatile Organics Analytical Method: EPA 624
Acrolein 10.0U ug/L 08/11/13 20:32 107-02-820.0 10.0 1Acrylonitrile 5.0U ug/L 08/11/13 20:32 107-13-110.0 5.0 1Benzene 0.50U ug/L 08/11/13 20:32 71-43-21.0 0.50 1Bromodichloromethane 0.30U ug/L 08/11/13 20:32 75-27-40.60 0.30 1Bromoform 0.50U ug/L 08/11/13 20:32 75-25-21.0 0.50 1Bromomethane 0.50U ug/L 08/11/13 20:32 74-83-91.0 0.50 1Carbon tetrachloride 0.50U ug/L 08/11/13 20:32 56-23-51.0 0.50 1Chlorobenzene 0.40U ug/L 08/11/13 20:32 108-90-71.0 0.40 1Chloroethane 0.61U ug/L 08/11/13 20:32 75-00-31.0 0.61 12-Chloroethylvinyl ether 5.0U ug/L 08/11/13 20:32 110-75-810.0 5.0 1Chloroform 0.50U ug/L 08/11/13 20:32 67-66-31.0 0.50 1Chloromethane 0.50U ug/L 08/11/13 20:32 74-87-31.0 0.50 1Dibromochloromethane 0.25U ug/L 08/11/13 20:32 124-48-10.50 0.25 11,2-Dichlorobenzene 0.50U ug/L 08/11/13 20:32 95-50-11.0 0.50 11,3-Dichlorobenzene 0.50U ug/L 08/11/13 20:32 541-73-11.0 0.50 11,4-Dichlorobenzene 0.50U ug/L 08/11/13 20:32 106-46-71.0 0.50 11,1-Dichloroethane 0.50U ug/L 08/11/13 20:32 75-34-31.0 0.50 11,2-Dichloroethane 0.50U ug/L 08/11/13 20:32 107-06-21.0 0.50 11,2-Dichloroethene (Total) 0.50U ug/L 08/11/13 20:32 540-59-01.0 0.50 11,1-Dichloroethene 0.71U ug/L 08/11/13 20:32 75-35-41.0 0.71 1cis-1,2-Dichloroethene 0.50U ug/L 08/11/13 20:32 156-59-21.0 0.50 1trans-1,2-Dichloroethene 0.50U ug/L 08/11/13 20:32 156-60-51.0 0.50 11,2-Dichloropropane 0.50U ug/L 08/11/13 20:32 78-87-51.0 0.50 1cis-1,3-Dichloropropene 0.25U ug/L 08/11/13 20:32 10061-01-50.50 0.25 1trans-1,3-Dichloropropene 0.25U ug/L 08/11/13 20:32 10061-02-60.50 0.25 1Ethylbenzene 0.50U ug/L 08/11/13 20:32 100-41-41.0 0.50 1Methylene Chloride 2.5U ug/L 08/11/13 20:32 75-09-25.0 2.5 11,1,2,2-Tetrachloroethane 0.17U ug/L 08/11/13 20:32 79-34-50.50 0.17 1Tetrachloroethene 0.50U ug/L 08/11/13 20:32 127-18-41.0 0.50 1Toluene 0.50U ug/L 08/11/13 20:32 108-88-31.0 0.50 11,1,1-Trichloroethane 0.50U ug/L 08/11/13 20:32 71-55-61.0 0.50 11,1,2-Trichloroethane 0.50U ug/L 08/11/13 20:32 79-00-51.0 0.50 1Trichloroethene 0.50U ug/L 08/11/13 20:32 79-01-61.0 0.50 1Trichlorofluoromethane 0.66U ug/L 08/11/13 20:32 75-69-41.0 0.66 1Vinyl chloride 0.53U ug/L 08/11/13 20:32 75-01-41.0 0.53 1Xylene (Total) 1.0U ug/L 08/11/13 20:32 1330-20-73.0 1.0 1m&p-Xylene 0.50U ug/L 08/11/13 20:32 179601-23-11.0 0.50 1o-Xylene 0.50U ug/L 08/11/13 20:32 95-47-61.0 0.50 1SurrogatesDibromofluoromethane (S) 96 % 08/11/13 20:32 1868-53-788-113 14-Bromofluorobenzene (S) 93 % 08/11/13 20:32 460-00-471-111 1Toluene-d8 (S) 94 % 08/11/13 20:32 2037-26-577-116 11,2-Dichloroethane-d4 (S) 93 % 08/11/13 20:32 17060-07-079-123 1
REPORT OF LABORATORY ANALYSIS
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Page 28 of 355FPL-043-028
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
35103494
Miami Dade
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
MSV/9341
EPA 624
EPA 624
624 MSV
Associated Lab Samples: 35103494003, 35103494004, 35103494005, 35103494006
Parameter UnitsBlankResult
ReportingLimit Qualifiers
METHOD BLANK: 693424
Associated Lab Samples: 35103494003, 35103494004, 35103494005, 35103494006
Matrix: Water
Analyzed
1,1,1-Trichloroethane ug/L 0.50U 1.0 08/11/13 17:121,1,2,2-Tetrachloroethane ug/L 0.17U 0.50 08/11/13 17:121,1,2-Trichloroethane ug/L 0.50U 1.0 08/11/13 17:121,1-Dichloroethane ug/L 0.50U 1.0 08/11/13 17:121,1-Dichloroethene ug/L 0.71U 1.0 08/11/13 17:121,2-Dichlorobenzene ug/L 0.50U 1.0 08/11/13 17:121,2-Dichloroethane ug/L 0.50U 1.0 08/11/13 17:121,2-Dichloroethene (Total) ug/L 0.50U 1.0 08/11/13 17:121,2-Dichloropropane ug/L 0.50U 1.0 08/11/13 17:121,3-Dichlorobenzene ug/L 0.50U 1.0 08/11/13 17:121,4-Dichlorobenzene ug/L 0.50U 1.0 08/11/13 17:122-Chloroethylvinyl ether ug/L 5.0U 10.0 08/11/13 17:12Acrolein ug/L 10.0U 20.0 08/11/13 17:12Acrylonitrile ug/L 5.0U 10.0 08/11/13 17:12Benzene ug/L 0.50U 1.0 08/11/13 17:12Bromodichloromethane ug/L 0.30U 0.60 08/11/13 17:12Bromoform ug/L 0.50U 1.0 08/11/13 17:12Bromomethane ug/L 0.50U 1.0 08/11/13 17:12Carbon tetrachloride ug/L 0.50U 1.0 08/11/13 17:12Chlorobenzene ug/L 0.40U 1.0 08/11/13 17:12Chloroethane ug/L 0.61U 1.0 08/11/13 17:12Chloroform ug/L 0.50U 1.0 08/11/13 17:12Chloromethane ug/L 0.50U 1.0 08/11/13 17:12cis-1,2-Dichloroethene ug/L 0.50U 1.0 08/11/13 17:12cis-1,3-Dichloropropene ug/L 0.25U 0.50 08/11/13 17:12Dibromochloromethane ug/L 0.25U 0.50 08/11/13 17:12Ethylbenzene ug/L 0.50U 1.0 08/11/13 17:12m&p-Xylene ug/L 0.50U 1.0 08/11/13 17:12Methylene Chloride ug/L 2.5U 5.0 08/11/13 17:12o-Xylene ug/L 0.50U 1.0 08/11/13 17:12Tetrachloroethene ug/L 0.50U 1.0 08/11/13 17:12Toluene ug/L 0.50U 1.0 08/11/13 17:12trans-1,2-Dichloroethene ug/L 0.50U 1.0 08/11/13 17:12trans-1,3-Dichloropropene ug/L 0.25U 0.50 08/11/13 17:12Trichloroethene ug/L 0.50U 1.0 08/11/13 17:12Trichlorofluoromethane ug/L 0.66U 1.0 08/11/13 17:12Vinyl chloride ug/L 0.53U 1.0 08/11/13 17:12Xylene (Total) ug/L 1.0U 3.0 08/11/13 17:121,2-Dichloroethane-d4 (S) % 95 79-123 08/11/13 17:124-Bromofluorobenzene (S) % 93 71-111 08/11/13 17:12Dibromofluoromethane (S) % 95 88-113 08/11/13 17:12Toluene-d8 (S) % 95 77-116 08/11/13 17:12
REPORT OF LABORATORY ANALYSIS
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Page 29 of 355FPL-043-029
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
35103494
Miami Dade
Parameter UnitsLCS
Result% RecLimits Qualifiers% RecConc.
693425LABORATORY CONTROL SAMPLE:
LCSSpike
1,1,1-Trichloroethane ug/L 18.720 94 52-1621,1,2,2-Tetrachloroethane ug/L 18.120 90 14-1571,1,2-Trichloroethane ug/L 20.220 101 52-1501,1-Dichloroethane ug/L 16.920 84 59-1551,1-Dichloroethene ug/L 19.520 97 10-2341,2-Dichlorobenzene ug/L 18.420 92 18-1901,2-Dichloroethane ug/L 17.820 89 49-1551,2-Dichloroethene (Total) ug/L 37.440 94 54-1561,2-Dichloropropane ug/L 18.620 93 10-2101,3-Dichlorobenzene ug/L 18.420 92 59-1561,4-Dichlorobenzene ug/L 18.420 92 18-1902-Chloroethylvinyl ether ug/L 21.620 108 10-305Acrolein ug/L 67.4200 34 14-183Acrylonitrile ug/L 135200 68 60-146Benzene ug/L 18.520 93 37-151Bromodichloromethane ug/L 18.320 91 35-155Bromoform ug/L 20.220 101 45-169Bromomethane ug/L 17.620 88 10-242Carbon tetrachloride ug/L 18.920 95 70-140Chlorobenzene ug/L 19.720 99 37-160Chloroethane ug/L 16.720 84 10-230Chloroform ug/L 18.120 91 51-138Chloromethane ug/L 8.420 42 10-273cis-1,2-Dichloroethene ug/L 18.520 93 76-128cis-1,3-Dichloropropene ug/L 16.020 80 10-227Dibromochloromethane ug/L 19.320 96 35-155Ethylbenzene ug/L 19.520 98 37-162m&p-Xylene ug/L 40.740 102 70-130Methylene Chloride ug/L 20.620 103 10-221o-Xylene ug/L 19.020 95 70-130Tetrachloroethene ug/L 19.420 97 64-148Toluene ug/L 19.820 99 47-150trans-1,2-Dichloroethene ug/L 18.920 94 54-156trans-1,3-Dichloropropene ug/L 18.320 92 17-183Trichloroethene ug/L 17.620 88 71-157Trichlorofluoromethane ug/L 18.620 93 17-181Vinyl chloride ug/L 17.720 88 10-251Xylene (Total) ug/L 59.660 99 70-1301,2-Dichloroethane-d4 (S) % 84 79-1234-Bromofluorobenzene (S) % 98 71-111Dibromofluoromethane (S) % 91 88-113Toluene-d8 (S) % 93 77-116
Parameter UnitsMS
Result% RecLimits Qualifiers% RecConc.
693426MATRIX SPIKE SAMPLE:
MSSpikeResult
35103494003
1,1,1-Trichloroethane ug/L 21.320 106 52-1620.50U
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 08/20/2013 12:19 PM
Pace Analytical Services, Inc.
3610 Park Central Blvd N
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954-582-4300
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#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
35103494
Miami Dade
Parameter UnitsMS
Result% RecLimits Qualifiers% RecConc.
693426MATRIX SPIKE SAMPLE:
MSSpikeResult
35103494003
1,1,2,2-Tetrachloroethane ug/L 17.920 90 14-1570.17U
1,1,2-Trichloroethane ug/L 20.120 100 52-1500.50U
1,1-Dichloroethane ug/L 18.720 94 59-1550.50U
1,1-Dichloroethene ug/L 22.020 110 10-2340.71U
1,2-Dichlorobenzene ug/L 18.520 92 18-1900.50U
1,2-Dichloroethane ug/L 17.820 89 49-1550.50U
1,2-Dichloroethene (Total) ug/L 39.840 100 54-1560.50U
1,2-Dichloropropane ug/L 19.520 98 10-2100.50U
1,3-Dichlorobenzene ug/L 18.620 93 59-1560.50U
1,4-Dichlorobenzene ug/L 19.020 90 18-1900.93 I
2-Chloroethylvinyl ether ug/L 5.0U J(M1)20 0 10-3055.0U
Acrolein ug/L 13.3 I J(M1)200 7 14-18310.0U
Acrylonitrile ug/L 139200 69 60-1465.0U
Benzene ug/L 19.920 99 37-1510.50U
Bromodichloromethane ug/L 19.920 100 35-1550.30U
Bromoform ug/L 19.720 98 45-1690.50U
Bromomethane ug/L 22.820 114 10-2420.50U
Carbon tetrachloride ug/L 21.720 108 70-1400.50U
Chlorobenzene ug/L 20.520 103 37-1600.40U
Chloroethane ug/L 14.320 71 10-2300.61U
Chloroform ug/L 23.320 100 51-1383.4
Chloromethane ug/L 157 J(M1)20 785 10-2730.50U
cis-1,2-Dichloroethene ug/L 19.820 99 76-1280.50U
cis-1,3-Dichloropropene ug/L 15.920 79 10-2270.25U
Dibromochloromethane ug/L 20.020 100 35-1550.25U
Ethylbenzene ug/L 20.620 103 37-1620.50U
m&p-Xylene ug/L 42.540 106 70-1300.50U
Methylene Chloride ug/L 20.120 100 10-2212.5U
o-Xylene ug/L 19.520 97 70-1300.50U
Tetrachloroethene ug/L 20.620 103 64-1480.50U
Toluene ug/L 21.020 105 47-1500.50U
trans-1,2-Dichloroethene ug/L 20.020 100 54-1560.50U
trans-1,3-Dichloropropene ug/L 18.820 94 17-1830.25U
Trichloroethene ug/L 19.420 97 71-1570.50U
Trichlorofluoromethane ug/L 20.120 101 17-1810.66U
Vinyl chloride ug/L 21.420 107 10-2510.53U
Xylene (Total) ug/L 61.960 103 70-1301.0U
1,2-Dichloroethane-d4 (S) % 87 79-1234-Bromofluorobenzene (S) % 96 71-111Dibromofluoromethane (S) % 95 88-113Toluene-d8 (S) % 93 77-116
Parameter UnitsMS
Result% RecLimits Qual% RecConc.
694452MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpikeResult
35103494005
694453
MSDResult
MSD% Rec RPD RPD
MaxMSDMSSpikeConc.
1,1,1-Trichloroethane ug/L 3 4020.3 19.6
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 08/20/2013 12:19 PM
Pace Analytical Services, Inc.
3610 Park Central Blvd N
Pompano Beach, FL 33064
954-582-4300
Page 13 of 21Page 13 of 337
Page 31 of 355FPL-043-031
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
35103494
Miami Dade
Parameter UnitsMS
Result% RecLimits Qual% RecConc.
694452MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpikeResult
35103494005
694453
MSDResult
MSD% Rec RPD RPD
MaxMSDMSSpikeConc.
1,1,2,2-Tetrachloroethane ug/L 1 4019.6 19.31,1,2-Trichloroethane ug/L 7 4019.4 18.11,1-Dichloroethane ug/L 8 4018.0 16.61,1-Dichloroethene ug/L 12 4017.8 15.81,2-Dichlorobenzene ug/L 5 4020.1 19.11,2-Dichloroethane ug/L 11 4019.6 17.61,2-Dichloroethene (Total) ug/L 11 4036.4 32.51,2-Dichloropropane ug/L 6 4019.2 18.01,3-Dichlorobenzene ug/L 7 4019.8 18.41,4-Dichlorobenzene ug/L 8 4020.9 19.32-Chloroethylvinyl ether ug/L 405.0U 5.0UAcrolein ug/L 4015.5 I 10.0UAcrylonitrile ug/L 3 40160 155Benzene ug/L 7 4018.9 17.6Bromodichloromethane ug/L 7 4021.2 19.7Bromoform ug/L 4 4019.1 18.3Bromomethane ug/L 4 4023.9 22.8Carbon tetrachloride ug/L 9 4022.2 20.2Chlorobenzene ug/L 8 4019.4 18.0Chloroethane ug/L 400.61U 0.61UChloroform ug/L 10 4022.1 20.1Chloromethane ug/L 5 40228 216cis-1,2-Dichloroethene ug/L 15 4017.7 15.2cis-1,3-Dichloropropene ug/L 20 4015.3 12.6Dibromochloromethane ug/L 7 4019.1 17.8Ethylbenzene ug/L 20 98 37-16291 7 40200.50U 19.6 18.2m&p-Xylene ug/L 6 4039.5 37.1Methylene Chloride ug/L 7 4018.6 17.3o-Xylene ug/L 5 4019.1 18.1Tetrachloroethene ug/L 20 84 64-14879 7 40200.50U 16.9 15.7Toluene ug/L 20 97 47-15090 8 40200.50U 19.8 18.4trans-1,2-Dichloroethene ug/L 8 4018.7 17.3trans-1,3-Dichloropropene ug/L 24 4015.3 12.1Trichloroethene ug/L 4 4019.7 18.9Trichlorofluoromethane ug/L 2 4024.8 24.2Vinyl chloride ug/L 4 4021.2 20.3Xylene (Total) ug/L 6 4058.6 55.21,2-Dichloroethane-d4 (S) % 102 79-1231034-Bromofluorobenzene (S) % 93 71-11195Dibromofluoromethane (S) % 102 88-113101Toluene-d8 (S) % 97 77-11698
Parameter UnitsDup
ResultMaxRPD QualifiersRPDResult
35103494004
693427SAMPLE DUPLICATE:
1,1,1-Trichloroethane ug/L 0.50U 400.50U
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 08/20/2013 12:19 PM
Pace Analytical Services, Inc.
3610 Park Central Blvd N
Pompano Beach, FL 33064
954-582-4300
Page 14 of 21Page 14 of 337
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#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
35103494
Miami Dade
Parameter UnitsDup
ResultMaxRPD QualifiersRPDResult
35103494004
693427SAMPLE DUPLICATE:
1,1,2,2-Tetrachloroethane ug/L 0.17U 400.17U
1,1,2-Trichloroethane ug/L 0.50U 400.50U
1,1-Dichloroethane ug/L 0.50U 400.50U
1,1-Dichloroethene ug/L 0.71U 400.71U
1,2-Dichlorobenzene ug/L 0.50U 400.50U
1,2-Dichloroethane ug/L 0.50U 400.50U
1,2-Dichloroethene (Total) ug/L 0.50U 400.50U
1,2-Dichloropropane ug/L 0.50U 400.50U
1,3-Dichlorobenzene ug/L 0.50U 400.50U
1,4-Dichlorobenzene ug/L 0.99 I 400.92 I
2-Chloroethylvinyl ether ug/L 5.0U 405.0U
Acrolein ug/L 10.0U 4010.0U
Acrylonitrile ug/L 5.0U 405.0U
Benzene ug/L 0.50U 400.50U
Bromodichloromethane ug/L 0.30U 400.30U
Bromoform ug/L 0.50U 400.50U
Bromomethane ug/L 0.50U 400.50U
Carbon tetrachloride ug/L 0.50U 400.50U
Chlorobenzene ug/L 0.40U 400.40U
Chloroethane ug/L 0.61U 400.61U
Chloroform ug/L 3.4 1 403.3
Chloromethane ug/L 0.50U 400.50U
cis-1,2-Dichloroethene ug/L 0.50U 400.50U
cis-1,3-Dichloropropene ug/L 0.25U 400.25U
Dibromochloromethane ug/L 0.25U 400.25U
Ethylbenzene ug/L 0.50U 400.50U
m&p-Xylene ug/L 0.50U 400.50U
Methylene Chloride ug/L 2.5U 402.5U
o-Xylene ug/L 0.50U 400.50U
Tetrachloroethene ug/L 0.50U 400.50U
Toluene ug/L 0.50U 400.50U
trans-1,2-Dichloroethene ug/L 0.50U 400.50U
trans-1,3-Dichloropropene ug/L 0.25U 400.25U
Trichloroethene ug/L 0.50U 400.50U
Trichlorofluoromethane ug/L 0.66U 400.66U
Vinyl chloride ug/L 0.53U 400.53U
Xylene (Total) ug/L 1.0U 401.0U
1,2-Dichloroethane-d4 (S) % 92 .692
4-Bromofluorobenzene (S) % 93 .493
Dibromofluoromethane (S) % 95 297
Toluene-d8 (S) % 93 295
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..Date: 08/20/2013 12:19 PM
Pace Analytical Services, Inc.
3610 Park Central Blvd N
Pompano Beach, FL 33064
954-582-4300
Page 15 of 21Page 15 of 337
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#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
35103494
Miami Dade
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
OEXT/13826
EPA 608 SF
EPA 608
608 GCS Pest PCB
Associated Lab Samples: 35103494001, 35103494002
Parameter UnitsBlankResult
ReportingLimit Qualifiers
METHOD BLANK: 693699
Associated Lab Samples: 35103494001, 35103494002
Matrix: Water
Analyzed
Heptachlor ug/L 0.0060U 0.010 08/14/13 18:54Decachlorobiphenyl (S) % 75 61-121 08/14/13 18:54Tetrachloro-m-xylene (S) % 74 53-110 08/14/13 18:54
Parameter UnitsLCS
Result% RecLimits Qualifiers% RecConc.
693700LABORATORY CONTROL SAMPLE:
LCSSpike
Heptachlor ug/L 0.38.5 76 34-111Decachlorobiphenyl (S) % 71 61-121Tetrachloro-m-xylene (S) % 64 53-110
Parameter UnitsLCS
Result% RecLimits Qualifiers% RecConc.
694208LABORATORY CONTROL SAMPLE:
LCSSpike
Decachlorobiphenyl (S) % 73 61-121Tetrachloro-m-xylene (S) % 64 53-110
Parameter UnitsMS
Result% RecLimits Qual% RecConc.
694209MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpikeResult
35103494001
694210
MSDResult
MSD% Rec RPD RPD
MaxMSDMSSpikeConc.
Heptachlor ug/L 1 64 34-11165 1 4010.0062U
0.64 0.65
Decachlorobiphenyl (S) % P2,S736 61-12145Tetrachloro-m-xylene (S) % 69 53-11064
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 08/20/2013 12:19 PM
Pace Analytical Services, Inc.
3610 Park Central Blvd N
Pompano Beach, FL 33064
954-582-4300
Page 16 of 21Page 16 of 337
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#=QL#
QUALIFIERS
Pace Project No.:
Project:
35103494
Miami Dade
DEFINITIONS
DF - Dilution Factor, if reported, represents the factor applied to the reported data due to changes in sample preparation, dilution ofthe sample aliquot, or moisture content.ND - Not Detected at or above adjusted reporting limit.
MDL - Adjusted Method Detection Limit.
PRL - Pace Reporting Limit.
RL - Reporting Limit.
S - Surrogate
1,2-Diphenylhydrazine (8270 listed analyte) decomposes to Azobenzene.
Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.
LCS(D) - Laboratory Control Sample (Duplicate)
MS(D) - Matrix Spike (Duplicate)
DUP - Sample Duplicate
RPD - Relative Percent Difference
NC - Not Calculable.
SG - Silica Gel - Clean-Up
U - Indicates the compound was analyzed for, but not detected.N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported foreach analyte is a combined concentration.Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes.
TNI - The NELAC Institute.
LABORATORIES
Pace Analytical Services - Ormond BeachPASI-O
ANALYTE QUALIFIERS
The reported value is between the laboratory method detection limit and the laboratory practical quantitation limit. IEstimated Value. Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS)recovery.
J(M1)
Estimated Value. Surrogate recovery outside laboratory control limits (confirmed by re-analysis).J(S1)
Re-extraction or re-analysis could not be performed due to insufficient sample amount.P2
Surrogate recovery outside control limits (not confirmed by re-analysis).S7
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..Date: 08/20/2013 12:19 PM
Pace Analytical Services, Inc.
3610 Park Central Blvd N
Pompano Beach, FL 33064
954-582-4300
Page 17 of 21Page 17 of 337
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#=CR#
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Pace Project No.:
Project:
35103494
Miami Dade
Lab ID Sample ID QC Batch Method QC Batch Analytical Method
Analytical
Batch
35103494001 FLD/EAST COMPOSITE
35103494003 FLD/EAST GRAB
35103494005 FLD/WEST GRAB
35103494001 OEXT/13826 GCSV/9243EAST COMPOSITE EPA 608 SF EPA 60835103494002 OEXT/13826 GCSV/9243EAST COMP DUPLICATE EPA 608 SF EPA 608
35103494003 MSV/9341EAST GRAB EPA 62435103494004 MSV/9341EAST GRAB DUPLICATE EPA 62435103494005 MSV/9341WEST GRAB EPA 62435103494006 MSV/9341TRIP BLANK EPA 624
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..Date: 08/20/2013 12:19 PM
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3610 Park Central Blvd N
Pompano Beach, FL 33064
954-582-4300
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