analytical data report - epa.gov · the ,·esults in 1his report only apply to the samples analyzed...
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f1-135GZA GeoEnvironmental Inc
Engineers and
Scientists
380 Harvey Road Manchester New Hampshire 03103-3347 603-623-3600 FAX 603-624-9463 wwwgzacom
IVIAEMAIL
April272012 File No 04002930700
Ms Nancy Lesieur Industrial Pretreatment Coordinator Winnipesaukee River Basin Program Wastewater Treatment Plant Water Division New Hampshire Department ofEnvironmental Services 528 River Street Franklin New Hampshire 03235
Re Analytical Data Report Treated Wastewater Merrimack Station Public Service ofNew Hampshire Bow New Hampshire
Dear Ms Lesieur
On behalfofPublic Service ofNew Hampshire (PSNH) GZA GeoEnvironmental Inc is pleased to submit the attached Analytical Data Report for sampling conducted on January 5 2012 previously submitted on January 16 2012 In anticipation of extremely low metals concentrations the previous analysis was performed by Environmental Protection Agency (EPA) Method 1638 which was specifically developed by EPA to enable metals detection by Inductively Coupled PlasmaMass Spectrometry (ICP-MS) at extremely low concentrations in ambient water when used in conjunction with sampling Method 1669 Sampling Ambient Water for Determination ofTrace Metals at EPA Water Quality Criteria Levels
Total metals were reanalyzed using Method 2008MOD within the sample hold time in accordance 40 CFR 136 This method is specified in the United States EPA draft Standard Operating Procedure (SOP) for trace metals analysis of flue gas desulfurization (FGD) wastewater The SOP is discussed below
ANALYTICAL DISCUSSION
FGD wastewater requires specialized analytical techniques to overcome matrix interference for certain analysis of trace metals To assist you in evaluating this issue further we offer an excerpt below from the EPA web site and a link to their draft SOP for trace metals analysis of FGD wastewater that contains further guidance
LABORATORY ANALYSIS OF FGD WASTEWATER
Wastewater from FGD systems can contain constituents known to cause matrix interferences EPA has observed that during ICP-MS analysis of fGD wastewater certain clements commonly present in the wastewater may cause polyatomic interferences that bias the detection andor quantization ofcertain elements of interest These potential interferences may become significant when measuring trace elements at concentrations in the low parts-per-billion range
Copyrightcopy 2012 GZA GeoEnvironmental Inc
An Eqwd Opportunity Employer MFNH
bullbull
Wirmipesaukee River Basin Program Wastewater Treatment Plant File No 04002930700
April272012 Page2
As part of a recent sampling effort for the steam electric power generating effluent guidelines rulemaking EPA developed an SOP that was used in conjunction with EPA Method 2008 to conduct ICP-MS analyses of FGD wastewater The SOP describes critical technical and quality assurance procedures that were implemented to mitigate anticipated interferences and generate reliable data for FGD wastewater EPA regulations at 40 CFR 1366 already allow the analytical community flexibility to modify approved methods to lower the costs of measurements overcome matrix interferences or otherwise improve the analysis The draft SOP developed for FGD wastewater takes a proactive approach toward looking for and taking steps to mitigate matrix interferences including using specialized interference check solutions (ie a synthetic FGD wastewater matrix) EPAs draft SOP is being made available to laboratories contemplating ICP-MS analysis of FGD wastewater either for adoption as currently written or to serve as a framework for developing their own laboratory-specific SOP For further information see
Standard Operating Procedure Inductively Coupled PlasmaMass Spectrometry for Trace Element Analysis in Flue Gas Desulfurization Wastewaters (30 pp 174K) http water epagovscitechwastetechlguideuploadsteam _draft _soppdf EPA May 2011
Considering that specialized analytical teclmiques are necessary to overcome matrix interference for certain analysis of trace metals in FDG wastewater we recommend any analysis on FGD wastewater be conducted in accordance with the EPA draft SOP for trace metals analysis ofFGD wastewater
Should you have any questions concerning this report please do not hesitate to contact me at (603) 232-8744
Very truly yours
GZA GEO ENVIRONMENT AL INC
Ronald A Breton PE Michael P North P E Principal ConsultantReviewer
RABMPNtmd IGZAMANJobs04Jobsl002930004002930700WorklSAMPUNG AND REPORTINGRfPORTSFraollinlfuull 04002930700 franklin OlG112lIWll 042712docx
Attachment Analytical Data Report
ANALYTICAL DATA REPORT
----1~J___________e_a_~_t_~-~-~--~-~-~-bullv_t_i_~-~-bull-__
Paul Pepler
GZA GeoEnvironmental Inc (NH)
380 Harvey Road
Manchester NH 03103
Subject Laboratory Report
Eastern Analytical Inc ID 107555 Client Identification Merrimack Station
Date Received 152012
Dear Mr Pepler
Enclosed please find the report of analysis for the above identified project As discussed analyses were subcontracted and are listed as follows
Analysis Subcontract - Metals Method 2008 (AlSbBaBeCdCaCrCuFePbMnMoNaNiAgTlZnAsSe amp Hg)
Subcontractor Lab Frontier Global Sciences Inc
A complete copy of the report is attached This report may not be reproduced except in full without the written approval of the laboratory
We appreciate this opportunity to be of service and look forward to your continued patronage
Sincerely
Lorraine Olashaw Lab Direc r Date of pages (excluding cover letter)
Wmiddottaihb ~Clt l111 I
SAMPLE CONDITIONS PAGE EAi ID 107555
Client GZA GeoEnvironmental Inc (NH)
Client Designation Merrimack Station
Temperature upon receipt (degC) Acceptable temperature range (0 C) 0-6
Lab ID Sample ID
47
Date Received Sampled
Date
Received on ice or cold packs (YesNo)
Sample Ory Matrix Weight ExceptionsComments (other than
y
thermal preservation)
10755501 Treat Tank Eff Composite 115112 1512 aqueous Adheres to Sample Acceptance Policy
10755502 Treat Tank Eff Grab 11512 15112 aqueous Adheres to Sample Acceptance Policy
Samples were properly preserved and the pH measured when applicable unless otherwise noted Analysis of solids for pH Flashpoint lgnitibility Paint Filter Corrosivity Conductivity and Specific Gravity are reported on an as received basis All results contained in this report relate only to the above listed samples
References include 1) EPA 6004-79-020 1983 2) Standard Methods for Examination of Water and Wastewater lnorganics 19th Edition 1995 Microbiology 20th Edition 1998 3) Test Methods for Evaluating Solid Waste SW 846 3rd Edition including updates VA and VB 4) Hach Water Analysis Handbook 2nd edition 1992
eastern analytical inc wwweailabscom Phone (603) 228-0525 1
l l 720 North Creek Parkway North Suite 400 Bothell WA 98011
Ph 425-686-1996 Fx 425-686-3096 G L OBAL SCIENCES
25 April 2012
JeffGagne
Eastern Analytical Inc
25 Chenell Drive
Concord NH 0330 I
RE Merrimack Station
Enclosed are the analytical results for samples received by Frontier Global Sciences All quality control
measurements are within established control limits and there were no analytical difficulties encountered with the exception of those listed in the case narrative section of this report
If you have any questions concerning this report please feel free to contact me
Sincerely
Liz Siska
Project Manager
2
GLOBAL SCIENCES
11720 North Creek Parkway North Suite 400 Bothell WA 98011
Ph 425-686-1996 Fx 425-686-3096
ANALYTICAL REPORT FOR SAMPLES
Laboratory Frontier Global Sciences Inc SDG
Client Eastern Analytical Inc Project Merrimack Station
Sample ID Lab ID Matrix Date Sampled Date Received
Treat Tank EffComposite 1201073-01 Water 05-Jan-12 1000 06-Jan-12 0950
Treat Tank EffGrab 1201073-02 Water 05-Jan-12 0800 06-Jan-12 0950
Frontier Global Sciences Inc
Liz Siska Project Manager
The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Page 1 o261201073 Final Report 04252012 3
11720 North Creek Parkway North Suite 400 Bothell WA 98011
Ph 425-686-1996FRONTIER Fx 425-686-3096 GLOBAL SCIENCES
CASE NARRATIVE
Revised Report 42512
Per client request Boron was removed from report
Revised Report 32812
Per client request samples were prepared and analyzed for total metals in accordance with EPA 2008 (modified)
SAMPLE RECEIPT
Samples were received at Frontier Global Sciences (FGS) on January 6th 2012 The samples were received intact on-ice with temperatures measured at 34 degrees Celsius
SAMPLE PREPARATION AND ANAL YSJS
Samples were prepared and analyzed for total metals in accordance with FGS-054EPA 1638
Samples were prepared and analyzed for total mercury in accordance with EPA Method 163JE
ANALYTICAL AND QUALITY CONTROL IS SUES
There were no analytical difficulties experienced with analysis of these samples with the exceptions flagged in the report
Frontier Gtobal Sciences Inc The results in this reporr only apply 10 the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Liz Siska Project Manager Page 2of26 J20I073 Final Report 042512012 4
11720 North Creek Parkway North Suite 400 Bothell WA 98011~ Ph 425-686-1996 FRONTIER Fx 425-686-3096
GLOBAL SCIENCES
CHAIN OF CUSTODY FORMS
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Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report mus be reproduced in ilS entirety
Page3of26Liz Siska Project Manager 1201073 Final Report
041252012 5
Liz Siska Project Manager
11720 North Creek Parkway North Suite 400 Bothell WA 98011
Ph 425-686- 1996 ~ Fx 425-686-3096 G LOB A L SC I EN CE S
ANALYTICAL RESULTS
Treat Tank Eff Composite
Matrix Water Laboratory ID 1201073-01
Analyte Result MDL MRL Units Dilution Batch Sequence Analyzed Method Notes
Aluminum ND 89 800 microgL 20 F203271 2C22005 032212 EPA 2008 Mod u Antimony 0408 0092 0400 microgL 20 F20327l 2C22005 032212 EPA 2008 Mod Barium 240 054 400 microgL 20 F203271 2C22005 032212 EPA 2008 Mod Beryllium ND 0454 t20 microgL 20 F203271 2C22005 032212 EPA 2008 Mod u Cadmium ND 0083 0400 microgL 20 F203271 2C22005 032212 EPA 2008 Mod u Calcium 5010000 16200 200000 microgL 5000 F203271 2C22005 032212 EPA 2008 Mod Chromium ND 018 200 microgL 20 F20327I 2C22005 032212 EPA 2008 Mod u Copper ND 020 200 microgL 20 F203271 2C22005 032212 EPA 2008 Mod u Iron ND 260 200 microgL 20 F20327l 2C22005 032212 EPA 2008 Mod u Lead ND 0078 0800 microgL 20 F20327l 2C22005 032212 EPA 2008 Mod u Manganese 280 015 200 microgL 20 F203271 2C22005 032212 EPA 2008 Mod Molybdenum 134 012 120 microgL 20 F20327I 2C22005 032212 EPA 2008 Mod Nickel 979 016 2 00 microgL 20 F203271 2C22005 032212 EPA 2008 Mod Silver ND 0120 0400 microgL 20 F203271 2C22005 032212 EPA 2008 Mod u Sodium 259000 23 400 microgL 20 F203271 2C22005 032212 EPA 2008 Mod Thallium 556 0250 100 microgL 100 F203314 2C25005 032512 EPA 2008 Mod Zinc ND 033 400 microgL 20 F203271 2C22005 032212 EPA 2008 Mod u
Frontier Global Sciences Inc The middotesults in 1his report only apply to the samples analyzed in accordance wilh 11e chain ofcus1ody documem This analytical report must be reproduced in ifs entirety
Page 4of26 1201073 Final Report 04252012 6
Liz Siska Project Manager
11720 North Creek Parkway North Suite 400 Bothell WA 98011
Ph 425-686-1996 Fx 425-686-3096
GLOBAt SCIENCES
ANALYTICAL RESULTS
Treat Tank Eff Grab
Matrix Water Laboratory ID 1201073-02
Analyte Result MDL MRL Units Dilution Batch Sequence Analyzed Method Notes
Arsenic 851 102 300 microgL 20 F203271 2C22005 032212 EPA 2008 Mod Mercury 105 034 202 ngL 4 F20I063 2A09010 010912 EPA 1631E FB-1631 Selenium 689 388 120 microgL 20 F203271 2C22005 032212 EPA 2008 Mod
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcustody documenJ This analycical report must be reproduced in its entirety
Page 5 o261201073 Final Report 04252012 7
Liz Siska Project Manager
FRONTIERshycLoaAt SCI ENCES
11720 North Creek Parkway North Suite 400 Bothell WA 98011
Ph 425-686-1996 Fx 425-686-3096
MATRIX DUPLICATESfRIPLICATES
SOURCE 1201073-02
Batch F201063
Preparation BrCI Oxidation
Sequence 2A09010
Lab Number F201063-DUPI
Sample Duplicate Concentration Concentration RPD
Analyte ngL ngL MRL RPD Limit Method Notes Mercury 1048 1054 202 0617 24 EPA I631E
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Page 6of26 1201073 Final Report 04252012 8
11720 North Creek Parkway North Suite 400 BotheE WA 980 l l
Ph 425-686-1996 Fx 425-686-3096
GLOBAL SCIENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1201073-02
Batch F201063 Sequence 2A09010
Preparation BrCI Oxidation Lab Number F20 l 063-MSMSDl
Sample Spike MS MS Concentration Added Concentration RecoveryAnalyte (ngL) (ngL) (ngL) Recovery Method Limits Notes
Mercury 1048 20400 3136 102 71 125 EPA 163IE
Spike MSD MSD Added Concentration oo Recovery RPD
RPD Limits Limit Method Notes Analyte (ngL) (ngL) Recovery
Mercury 20400 2708 814 147 71 - 125 24 EPA 1631E
shy
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Page 7 o26Liz Siska Project Manager 120JO7 3 Final Repo1
04252012 9
Liz Siska Project Manager
11720 North Creek Parkway North Suite 400 Bothell WA 98011
Ph 425-686-1996~ Fx 425-686-3096 CL06AL SCIENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1112278-02
Batch F201063 Sequence 2A09010
Preparation BrCI Oxidation Lab Number F20 l 063-MSMSD2
Sample Spike MS MS
Analyte Concentration
(ogL) Added (ngL)
Concentration (ngL)
Recovery
RecoveryLimits Method Notes
Mercury 761 20400 2786 992 71 125 EPA 1631E
Spike MSD MSD Added Concentration Oo Recovery RPO
Analyte (ngL) (ngL) Recovery RPO Limits Limit Method Notes
Mercury 20400 2837 102 182 71 - 125 24 EPA l631E
shy
Frontier Global Sciences Inc The results in this report only apply to the somples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Page 8 o26 1201073 Final Report 042512012 10
11720 North Creek Parkway North Suite 400 Bothell WA 980 l l
Ph 425-686-1996 ~ Fx 425-686-3096 GLOBAL SCIENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1201029-01
Batch
Preparation
F201063
BrCI Oxidation
Sequence
Lab Number
2A09010
F20 I 063-MSMSD3
Analyte
Mercury
Analyte
Mercury
Sample Spike Concentration Added
(ngL) (ngL)
534 10200
Spike MSD Added Concentration (ngL) (ngL)
10200 1407
MS MS Concentration Recovery
(ngL) Recovery Limits
1558 JOO 7l shy 125
MSD oo Recovery RPD
Recovery RPD Limits Limit
856 102 71 - 125 24
Method
EPA l63lE
Method
EPA 631E
Notes
Notes
Frontier Global Sciences Inc The results in this repon only apply to rhe samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Page 9of26 1201073 Final Report 041252012
Liz Siska Project Manager
1 1
11720 North Creek Parkway North Suite 400 Bothell WA 98011
Ph 425-686-1996 FRONTIER- Fx 425-686-3096 cLosAL SCIENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1201030-02
Batch F20I063 Sequence 2A09010
Preparation BrCI Oxidation Lab Number F201063-MSMSD4
Sample Spike MS MS Concentration Added Concentration RecoveryAnalyte (ngL) (ngL) (ngL) Recovery MethodLimits Notes
Mercury 554 10200 1482 910 71 - 125 EPA I631E
Spike MSD MSD Oo Added Concentratio11 Recovery RPD
RPD Limits Limit Method Analyte (ngL) (ngL) Recovery Notes
Mercury 10200 1461 890 140 71 - 125 24 EPA 163IE
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed m accordance with the chain ofcus1ody document This anayt(ca repon must be reproduced in itr entirety
Page lOo26Liz Siska Project Manager 1201073 Final Report
041252012 12
I 1720 North Creek Parkway North Suite 400 Bothe I I WA 98011
Ph 425-686-1996 ~ Fx 425-686-3096 GLOBAL SCIENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1201073-01RE3
Batch F20327l Sequence 2C22005
Prcpa ration ((01ed Vessel ~ itric Oven Digestion Lab Number F203271-MSMSD 1
Analyte
Sample Concentration
(microgL)
Spike Added (microgL)
MS Concentration
(microgL)
MS Oo
Recovery Recovery
Method Limits Notes
Calcium 5013000 15150 4802000 -13900 70- 130 EPA 2008 Mod QM-02
Analyte
Spike Added (microgL)
MSD Concentration
(microgL)
MSD ~o
Recovery
Oo
RPD Recovery
Limits RPDLimit Method Notes
Calcium 15150 4943000 -4600 289 70 - 130 20 EPA 2008 Mod QM-02
Frontier Global Sciences Inc The results in this report only apply to the samples analyud inaccordance with the chain ofcustody document 17is analyticol report must be reproduced in its entirety
Page lI o16 1101073 Final Report 04152012
Liz Siska Project Manager
13
l l 720 North Creek Parkway North Suite 400 Bothell WA 98011
Ph 425-686-1996FRONTIER Fx 425-686-3096 GLOBAL SCIENCES
MATRIX SPIKE I MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1201073-01RE4
Batch F203271 Sequence 2C22005
Preparation Closed Vessel Nitric Oven Digestion Lab Number F203271-MSMSD2
Sample Spike MS MS Concentration Added Concentration Oo RecoveryAnalyte (microgL) (microgL) (microgL) Recovery Method Limits Notes
Beryllium 0507 20200 2442 958 70 - 130 EPA 2008 Mod Sodium 258800 50500 257700 -213 70 -130 EPA 2008 Mod QM-02 Aluminum 529 15150 2023 986 70 - 130 EPA 2008 Mod Chromium 057 70700 804 106 70 - 130 EPA 2008 Mod Manganese 2805 60600 2834 476 70 - 130 EPA 2008 Mod QM-02 Iron ND 50500 5200 103 70 130 EPA 2008 Mod Nickel 979 40400 141 l 107 70- 130 EPA 2008 Mod Copper 055 40400 434 939 70 - 130 EPA 2008 Mod Zinc 040 10100 842 794 70 - 130 EPA 2008 Mod Arsenic 1030 15150 2418 916 70 - 130 EPA 2008 Mod Selenium 6340 30300 8973 869 70 130 EPA 2008 Mod Molybdenum 1338 20200 1367 142 70 130 EPA 2008 Mod QM-02 Silver ND 15150 1388 916 70 - 130 EPA 2008 Mod Cadmium 0332 080800 1105 middot956 70 - 130 EPA 2008 Mod Antimony 0408 080800 1259 105 70- 130 EPA 2008 Mod Barium 2397 10100 2495 968 70 - 130 EPA 2008 Mod Lead ND 15150 1542 102 70 130 EPA 2008 Mod
shy
shy
shy
shy
Analyte
Spike Added (microgL)
MSD Concentration
(microgL)
MSD Oo
Recovery
Oo
RPD Recovery
Limits RPD Limit Method Notes
Beryllium
Sodium
Aluminum
Chromium
Manganese
Iron
Nickel
Copper
Zinc
Arsenic
Selenium
Molybdenum
20200
50500
15150
7Q700
60600
50500
40400
40400
10100
15150
30300
20200
2561
257100
2034
773
2852
5187
1381
419
916
2225
9400
1366
102
-336
993
101 769
103
995
902
868
789
101
137
474
0243
0564
385
0625
0242
213
347
849
831
464
00771
70 - 130
70 bull 130 70 - 130
70 - 130
70 - 130
70 - 130
70 - 130
70 - 130
70 - 130
70 bull 130 70 - 130
70 - 130
20
20
20
20
20
20
20
20
20
20
20
20
EPA 2008 Mod
EPA 2008 Mod
EPA 2008 Mod
EPA 2008 Mod
EPA 2008 Mod
EPA 2008 Mod
EPA 2008 Mod
EPA 2008 Mod
EPA 2008 Mod
EPA 2008 Mod
EPA 2008 Mod
EPA 2008 Mod
QM-02
QM-02
Frontier G lobal Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
--f_~ --~~~-~ -middot middot Page 12 o261201073 Final Report 041252012
Liz Siska Project Manager
14
11720 North Creek Parkway North Suite 400
~ Bothell WA 98011
~TIEmiddot Ph 425-686-1996 Fx 425-686-3096
GLOB11L SCIENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPO
SOURCE 1201073-01RE4
Batch F203271 Sequence 2C22005
Preparation ~lo~ed Vessel Nitric Oven Digestion Lab Number F20327 I-MSMSD2
Spike MSD MSD Added Concentration Oo Recovery RPO
Analyte (microgL) (microgL) Recovery RPD Limits Limit Method Notes
Silver 15150 1387 915 00874 70 - 130 20 EPA 2008 Mod Cadmium 080800 1061 902 403 70 - 130 20 EPA 200amp Mod Antimony 080800 1274 107 l2l 70 - 130 20 EPA 2008 Mod Barium 10100 2514 )16 0781 70 - 130 20 EPA 200amp Mod Lead 15150 1534 101 0525 70 shy 130 20 EPA 2008 Mod
Frontier Global Sciences Inc The results in this report only apply to 1he samples analyzed in accordance wiih the chain ofcustody document This analytical repo1 must be reproduced in ils entirety
Page 13 o26Liz Siska Project Manager 1201073 Final Reporl
04252012 15
11720 North Creek Parkway North Suite 400
~ Bothell WA 98011 Ph 425-686-I996
~RONTIER~ Fx 425-686-3096 GLOBAL SCIEN C ES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1201073-01RE3
Batch F203271 Sequence 2~22005
Preparation Closed Vessel Nitric Oven Digestion Lab Number F20327 I-MSMSD3
Sample Spike MS MS
Analyte Concentration
(microgL) Added (microgL)
Concentration (microgL) Recovery
Recovery Limits Method Notes
Calcium 5013000 10100000 15120000 100 70- 130 EPA 2008 Mod AS
Spike MSD MSD Added Concentration o Oo Recovery RPD
Analyte (microgL) (microgL) Recovery RPD Limits Limit Method Notes
Calcium 10100000 16140000 llO 653 70 - 130 20 EPA 2008 Mod AS
Frontier Global Sciences Inc The results in his report only apply 10 the samples analyzed in accordance ivth he chain ofcustody document This analytical report must be reproduced in its entirety
Page 14 o261201073 Final Report 0425201]
Liz Siska Project Manager
16
Frontier Global Sciences Inc The ruults in this rechain ofcustody do
~ -lt1-c--~ Liz Siska Project Manager
11720 North Creek Parkway North Suite 400 Bothell WA 98011
Ph 425-686-1996 Fx 425-686-3096
GLOBAL SCIENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1201073-01RE4
Batch J203271 Sequence 2C22005
Preparation ~ IQsed Ve~~el Nitric Oven Qigestion Lab Number F203271-MSMSQ4
Analyte
Beryllium
Sample Concentration
(11gL)
0507
Spike Added (11gL)
20200
MS Concentration
(microgL)
2041
MS Oo
Recovery
985
RecoveryMethod Limits
70 - 130 EPA 2008 Mod
Notes
AS
Sodium 258800 40400 292900 845 70- 130 EPA 2008 Mod AS
Aluminum 529 40400 3956 966 70 - 130 EPA 2008 Mod AS
Chromium 057 40400 430l 106 70- 130 EPA 2008 Mod AS
Manganese 2805 40400 7042 105 70 - 130 EPA 2008 Mod AS
Iron ND 20200 2121 105 70 - 130 EPA 2008 Mod AS
Nickel 979 50500 5112 993 70 l30 EPA 2008 Mod AS
Copper 055 50500 4754 940 70 - 130 EPA 2008 Mod AS
Zinc 040 10100 9074 898 70 - 130 EPA 2008 Mod AS
Arsenic 1030 40400 4317 104 70 130 EPA 2008 Mod AS
Selenium 6340 40400 4688 100 70 - 130 EPA 2008 Mod AS
Molybdenum 1338 20200 338l 101 70 - 130 EPA 2008 Mod AS
Silver ND 20200 1850 916 70 130 EPA 2008 Mod AS
Cadmium 0332 40400 3937 966 70 130 EPA 2008 Mod AS
Antimony 0408 20200 2091 102 70 - 130 EPA 2008 Mod AS
Barium 2397 80800 1056 101 70- 130 EPA 2008 Mod AS
Lead ND IO100 9932 983 70 130 EPA 2008 Mod AS
shy
shy
shy
shy
shy
Analyte
Spike Added (microgL)
MSD Concentration
(microgL)
MSD
Recovery
RPD
Recovery Limits
RPDLimit Method Notes
Beryllium 20200 2007 968 l71 70 - 130 20 EPA 2008 Mod AS Sodium 40400 292600 837 0114 70 130 20 EPA 2008 Mod AS Aluminum 40400 3954 966 00362 70 - 130 20 EPA 2008 Mod AS Chromium 40400 4287 106 0337 70 - 130 20 EPA 2008 Mod AS Manganese 40400 6944 102 140 70 - 130 20 EPA 2008 Mod AS Iron 20200 2077 103 211 70 - 130 20 EPA 2008 Mod AS Nickel 50500 5126 996 0276 70 - 130 20 EPA 2008 Mod AS Copper 50500 4707 931 0997 70 - 130 20 EPA 200 8 Mod AS Zinc 10100 9059 896 0166 70 - 130 20 EPA 2008 Mod AS Arsenic 40400 4299 104 0419 70 - 130 20 EPA 2008 Mod AS Selenium 40400 4682 100 0141 70 - 130 20 EPA 2008 Mod AS Molybdenum 20200 3365 100 0473 70 - 130 20 EPA 2008 Mod AS
shy
port only apply to the sampltts analyzed in accordance with the cument This analytical report must be reproduced in its entirety
Page 5 o26 201073 Final Report 042512012 17
Liz Sia Project Manager
11720 North Creek Parkway North Suite 400 Botheln VA 98011
Ph 425-686-1996 Fx 425-686-3096
CLOBAL SCIENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1201073-01RE4
Batch F203271 Sequence 2c2io2~
Preparation Clo~ed Vessel litric Oven Digestion Lab Number F20327 l -MSMSQ4
Analyte
Spike Added (microgL)
MSD Concentration
(microgL)
MSD
Recovery
Oo
RPD Recovery
Limits RPOLimit Method Notes
Silver 20200 1895 938 242 70 - 130 20 EPA 2008 Mod AS Cadmium 40400 3933 965 0104 70 -130 20 EPA 2008 Mod AS Antimony 20200 2107 102 0736 70- 130 20 EPA 2008 Mod AS
Barium 80800 1058 101 0205 70 - 130 20 EPA 2008 Mod AS
Lead 10100 9877 978 0549 70 - 130 20 EPA 2008 Mod AS
Frontier Global Sciences Inc The results in this report only apply to the samples analyudin accordance with lht chain ofcustody document This analytical report must be reproductd rn ilS enlirtty
Page l6of26 1201073 Final Report Ofn5202 18
l I 720 North Creek Parkway North Suite 400 Bothell WA 980I I
Ph 425-686-1996 Fx 425-686-3096
GLO B AL SCIENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1201073-01RE6
Batch F203314 Sequence 2C25005
Preparation Closed Vessel Nitric Oven Digestion Lab Number F203314-MSMSD2
Sample Spike MS MS Concentration Added Concentration RecoveryAnalyte (microgL) (microgL) (microgL) Recovery Method NotesLimits
Thallium 5563 040400 5875 773 70 - 130 EPA 2008 Mod
Spike MSD MSD Added o Concentration Recovery RPD
RPO Limits Limit Method Notes Analyte (microgL) (microgL) Recovery
Thallium 040400 5880 785 00859 70 - 130 20 EPA 2008 Mod
Frontier Global Sciences Inc 11e results in chis reporc only apply 10 1he samples analyzed in accordance wilh lhe chain ofcustody documenz This analycical report musl be reproduced in ils entirety
Page 17 of26 1201073 Fi11aReport 0412512012
Liz Siska Project Manager
19
11720 North Creek Parkway North Suite 400 Bothell WA 98011
Ph 425-686-1996 Fx 425-686-3096
GLOBAl SCIENC ES
MATRIX SPIKE I MATRIX SPIKE DUPLICATE RECOVERY AND RPO
SOURCE I201073-01RE6
Batch F203314
Preparation Closed Vessel Nitric Oven Digestion
Sequence 2C25005
Lab Number F203314-MSMSD4
Analyte
Sample Concentration
(microgL)
Spike Added (microgL)
MS MS Concentration Oo
(microgL) Recovery Recovery
Limits Method Notes
Thallium 5563 10100 1033 968 70- 130 EPA 2008 Mod AS
Analyte
Spike Added (microgL)
MSD Concentration
(microgL)
MS)) Oo
Recovery
RPD
Recovery Limits
RPD Limit Method Notes
Thallium IO100 1037 97l 0341 70 - 130 20 EPA 2008 Mod AS
Frontier Global Sciences Inc The resulrs in this report only apply to the samples analyzed in accordance with the chain ofcusrody document This analytical report must be reproduced in its entirely
Page 18of26 120073 Final Report 04252012
Liz Siska Project Manager
20
11720 North Creek Parkway North Suite 400 l ~ Bothell WA 980 l l Ph 425-686-1996
FRONTIER Fx 425-686-3096 GLOBAL SCIENCES
LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLICATE
RECOVERY AND RPD
Batch F20 l063 Sequence 2A09010
Preparation BrCI Oxidation Lab Number F201063-BSIBSJ21
LCS Source N ist 1641d
Analyte
Spike Added (ngL)
LCS Concentration
(ngL)
LCS
Recovery Recovery
Limits Method Notes
Mercury 15679 1550 988 80 - 120 EPA I631E
Analyte
Spike Added (ngL)
LCSD Concentration
(ngL)
LCSD Oo
Recovery
RPD Recovery
Limits RPD Limit Method Notes
Mercury 15679 1595 [02 289 80 - 120 24 EPA I631E
Frontier Global Sciences Inc The results in this report only apply to the samples analyzedin accordance with the chain ofcustody document This analytical report must be reproduced in ils entirety
Page 19of26 1201073 Final Report 0425 2012
Liz Siska Project Manager
21
11720 North Creek Parkway North Suite 400 Bothell WA 98011
Ph 425-686-1996 FRONTIER Fx 425-686-3096 GLOBAL SCIENCES
LABORA TORY CONTROL SAMPLE LABO RATORY CONTROL SAMPLE DUPLICATE
RECOVERY AND RPD
Batch F203271 Sequence 2C22005
Preparation Closed Vessel Nitric Oven Digestion Lab Number F203271-BSBSD1
LCS Source Blank Spike
Spike LCS LCS Added Concentration Oo Recovery
Analyte (microgL) (microgL) Recovery Limits Method Notes
Beryllium 20000 l930 965 85 - 115 EPA 2008 Mod
Sodium 50000 499 998 85 - 115 EPA 2008 Mod
Aluminum 15000 1460 973 85 - 115 EPA 2008 Mod
Calcium 15000 1528 102 85 - 115 EPA 2008 Mod
Chromium 70000 657 939 85 - 115 EPA 2008 Mod
Manganese 60000 586 976 85 - 115 EPA 2008 Mod
Iron 50000 4753 951 85 shy 115 EPA 2008 Mod
Nickel 40000 401 100 85 - 115 EPA 2008 Mod
Copper 40000 418 105 85 - 115 EPA 2008 Mod
Zinc 10000 1033 103 85 - 115 EPA 2008 Mod
Arsenic 15000 1437 958 85 - 115 EPA 2008 Mod
Selenium 30000 2966 989 85 - 115 EPA 2008 Mod
Molybdenum 20000 181 905 85 shy 115 EPA 2008 Mod
Silver 15000 1517 101 85 shy 115 EPA 2008 Mod
Cadmium 080000 0781 976 85 - 1lS EPA 2008 Mod
Antimony 080000 0815 102 85 - 115 EPA 2008 Mod
Barium 10000 969 969 85 - 115 EPA 2008 Mod
Lead 15000 1597 106 85 - 115 EPA 2008 Mod
Spike LCSD LCSD Added Concentration Recovery RPO
Analyte (microgL) (microgL) Recovery RPO Limits Limit Method Notes
Beryllium 20000 1949 974 0955 85 - 115 20 EPA 2008 Mod
Sodium 50000 500 100 0216 85 - 115 20 EPA 2008 Mod
Aluminum 15000 1485 990 171 85 - 115 20 EPA 2008 Mod
Calcium 15000 1544 103 103 85 - 115 20 EPA 2008 Mod
Chromium 70000 667 953 148 85 - 115 20 EPA 2008 Mod
Manganese 60000 596 994 175 85 - 115 20 EPA 2008 Mod
Iron 50000 4852 970 206 85 - 115 20 EPA 2008 Mod
Nickel 40000 402 IOI 0246 85 - 115 20 EPA 2008 Mod
Frontier Global Sciences Inc The results in his report only apply to the samples analyzed in accordance wirh the chain ofcustody document This analytical report must be reproduced in iLS entirety
Page 20of26 1201073 Final Report 04252012
Liz Siska Project Manager
22
11720 North Creek Parkway North Suite 400 ~~shy Bothell WA 98011 Ph 425-686-1996~ONTif Fx 425-686-3096
GLOBAL SCIENCES
LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLICATE
RECOVERY AND RPO
Batch F20327 l Sequence 2C22005
Preparation Closed Vessel Nitric Oven Digestion Lab Number F203271-BSBSD 1
LCS Source Blank Spike
Analyte
Spike Added (microgL)
LCSD Concentration
(microgL)
LCSD oo
Recovery
RPO Recovery
Limits RPO Limit Method Notes
Copper
Zinc
Arsenic
Selenium
40000
10000
15000
30000
428
1039
1452
3015
107
104
968
101
224
0570
0977
166
85 - 115
85 - 115
85 - 115
85 - 115
20
20
20
20
EPA 2008 Mod
EPA 2008 Mod
EPA 2008 Mod
EPA 2008 Mod Molybdenum
Silver
20000
15000
182
J502
910
100
0564
103
85 - 115
85 - 115
20
20
EPA 2008 Mod
EPA 2008 Mod Cadmium
Antimony
Barium
Lead
080000
080000
10000
15000
0828
0808
986
1620
103
101
986
108
585
0848
177
142
85 - 115
85 - 115
85 shy 11 S
85 - 115
20
20
20
20
EPA 2008 Mod
EPA 2008 Mod
EPA 2008 Mod
EPA 2008 Mod
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report mus be reproducedin its entirety
Page 2 o26J20J073 Final Report 041252012
Liz Siska Project Manager
23
11720 North Creek Parkway North Suite 400 Bothell WA 980 l l
Ph 425-686-1996FRONT[ER- Fx 425-686-3096 cLosAL SCIEN _CES
LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLICATE
RECOVERY AND RPD
Batch F203314 Sequence 2C25005
Preparation Closed Vessel Nitric Oven Digestion Lab Number F2033 l 4-BSBSD 1
LCS Source Blank Spike
Analyte
Thallium
Spike Added (microgL)
LCS Concentration
(microgL)
LCS 0o
Recovery Recovery
Limits Method
040000 0396 989 85 - 115 EPA 2008 Mod
Notes
Analyte
Spike Added (microgL)
LCSD Concentration
(microgL)
LCSD 0o
Recovery
RPD Recovery
Limits RPO Limit Method Notes
Thallium 040000 0391 978 112 85 - ll5 20 EPA 2008 Mod
Frontier Global Sciences Inc The results in this report only apply to the samples anayed in accordance with the chain ofcustody docwnenJ This analytical report must be reproduced in its entirety
Page 22of26 1201073 Final Report 04252012
Liz Siska Project Manager
24
Liz Siska P roject Manager
11720 North Creek Parkway North Suite 400
~ Bothell WA 98011 Ph 425-686-1996
~JTIEif middot Fx 425-686-3096 GLOBAL SCIENCES
PREPARATION BLANKS
Instrument Hg-17 Sequence 2A09010
Preparation BrCI Oxidation
Lab Sample ID Analyte Found MRL Units Batch Method Notes
F201063-BLK I Mercury -0009 050 ngL F201063 EPA 1631E u F20 I063-BLK2 Mercury -0006 050 ngL F201063 EPA 1631E u F201063-BLK3 Mercury -002 050 ngL F201063 EPA 163IE u F201063-BLK4 Mercury 003 050 ngL F201063 EPA 1631E U QB-04 F201063-BLKS Mercury 011 052 ngL F201063 EPA I631E U QB-06
Frontier Global Sciences Inc The results in this report only apply 10 1he samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Page 23 o26 1201073 Final Repon 04252012 25
Liz Siska Project Manager
11720 North Creek Parkway North Suite 400 Bothell WA 98011
Ph 425-686-1996 FROr~TIER- Fx 425-686-3096 GLOBAL SCIENCES
PREPARATION BLANKS
Instrument ICPMS-6 Sequence 2C22005
Preparation Closed Vessel Nitric Oven Digestion
Lab Sample ID Analyte Found MRL Units Batch Method Notes
F203271-BLK1 Beryllium 000008 0060 microgL F203271 PA 2008 Molt u F20327 1-BLK1 Sodium 2 20 microgL F20327l PA 2008 Moc u F20327I-BLK1 Aluminum -004 40 microgL F203271 PA 2008 Molt u F20327I -BLK1 Calcium 40 microgL F203271 PA 2008 Molt u F203271 -BLK1 Chromium -002 010 microgL F203271 ~A 2008 Molt u F203271-BLKI Manganese 001 010 microgL F203271 PA 2008 Molt u F20327 l -BLK 1 Iron -002 100 microgL F203271 PA 2008 Molt u F203271-BLKI Nickel 0004 010 microgL F203271 PA 2008 Moc u F203271-BLK1 Copper 0003 010 microgL F203271 PA 2008 Moc u F203271-BLK1 Zinc 0007 020 microgL F203271 PA 2008 Moc u F203271-BLK1 Arsenic -006 015 microgL F203271 PA 2008 Moc u F203271-BLK1 Selenium -002 060 microgL F203271 PA 2008 Moc u F203271-BLK1 Molybdenum 001 006 microgL F203271 PA 2008 Molt u F203271-BLK1 Silver -00005 0020 microgL F203271 PA 2008 Molt u F203271-BLKl Cadmium 0004 0020 microgL F203271 PA 2008 Molt u F20327 l-BLKl Antimony 0002 0020 microgL F203271 PA 2008 Molt u F203271-BLKI Barium 001 020 microgL F203271 PA 2008 Molt u F203271-BLKI Lead 0010 0040 microgL F203271 PA 2008 Moc u
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Page 24of26 1201073 Final Report 04252012 26
~
~TIER~ GLOBAL SCIENCES
11720 North Creek Parkway North Suite 400 Bothell WA 980ll
Ph 425-686-1996 Fx 425-686-3096
PREPARATION BLANKS
Instrument JCPMS-3 Sequence 2C25005
Preparation Closed Vessel Nitric Oven Digestion
Lab Sample ID Analyte Found MRL Units Batch Method Notes
F2033I4-BLK1 Thalium 00007 0010 microgL F2033I4 ~PA 2008 Molt u
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Page 25 o26Liz Siska Project Manager 1201073 Final Report
04252012 27
l l 720 North Creek Parkway North Suite 400~Vi-~ Bothell WA 98011 Ph 425-686-1 996~Tlmiddot~ Fx 425-686-3096
G L OBAL SCIENCE S
Notes and Definitions
U Analyte included in the analysis but not detected
QM-02 The MS andor MSD recoveries outside acceptance limits due to spike concentration less than I times the sample concentration The batch was accepted based on LCS and LCSD recoveries within control limits and when analysis permits acceptable AS ASD
QB-06 The blank was preserved to 5 BrCI rather than I The control limit for blanks preserved to greater than 1 BrCl is the preservation percentage multiplied by the MRL
QB-04 The blank was preserved to 2 BrCI rather than l The control limit for blanks preserved to greater than l BrCI is the preservation percentage multiplied by the MRL
FB-1631 Required equipmentfieldfilter blank not submitted by the client The sample has been analyzed according to 163 lE but does not meet 163 lE criteria
AS This MS andor MSD is an analytical spike andor an analytical spike duplicate
DET Analyte Detected
MDL Minimum Detection Limit
MRL Minimum Reporting Limit
ND Analyte Not Detected at or above the reporting limit
wet Sample results reported on a wet weight basis
dry Sample results reported on a dry weight basis
RPO Relative Percent Difference
RSD Relative Standard Deviation
Frontier Global Sciences Inc The lesults i111his reporl only apply to he samples analyzed In accordance with the chain ofcuslody document This analytical report must be reproduced in its entirely
Page 26of26 1201073 Final Report 04252012
Liz Siska Project Manager
28
CHAIN-OF-(USTODY ttECORD Page i of f 106677 _J
BoLD F1ELDS REQUIRED PLEASE C 1RCLE REQUESTED ANALYSIS
SAMPLE ID
middoti-rg -- bull ~rshy~ _- tzir +- lt-ltJ~ lt
SAMPLING
DATeTtME
IF COMPOSITE INDICATE BOTH
START amp FINISH
DATETIME li1J oc -r 111_- _vlt-c_
w Ishyt 0 n
w l w 0 ~ u X -Xmiddot ~ m Ishy lt( lt( 0
I C)
IIXJ JC
~ ~ irlte-t- T_ t- f r-n t I s-11 middott~ c~ J J1~w )(~ )
Trttbull rin K C-~-~ pound1t I 1Jtl~ t20~L lwlJI ishy
middot~ON Mm1x A-Al~ S-SOil GW-GampOUHO WATER SW-SUampfA(f WATER DWmiddotDRIIIKIKlti WATER
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107555
i
~ I NOTES MEOH VIAL
1 WW-WASTE WATER PmmATIVE H-HCL H-HN01 S-H1SO Na-NaOH H-HEOH -~ --~
PROJECT MANAGER llr middot1 ~Q Aw4---P1V- Het_ r COMPANY t-lo--tm ~ bd i ( I ~j 6 A ADP~SS 91 g~ez tJshy(ITJ ~ STATE fH_ ZIP c3o--
PHONE 22j-((omiddotf EXT ____
fAX--------------------- shyE-MAIL (JbHd-esa e n ta wamp Sm NAME Meccft1lt-1ltk f--g
PROJECT _
OTHEi________STATpound NH MA ME VT
REGULATORY PROGRAM NPDES RGP POTW STORHWATEl OR
GWP OIL FUHD BROWNIIELO OR OTHER----------
Quon PO o2J~-lt1Jpound)
DATE NEEDED _1--1 middot Z=-----shy4 (1-1_ METALS 8 RCRA 13 pp ff MN PB Cu
QAQC REPORTJNGYVEL
A CG) O R
PRESUMPTIVE CERTAINTY
7i2lt_
RECpound1VEO BYRELINQUISHED BY DATE TIME SUSPECTED (OHTAHIHATIOH________
TEHP~ C REPORTING OPTIONS 01HEA METAL------------PRELIHl Yu OR No
DISSOLVED METALS FIELD FllTEREDI YES 110
rmreg No
IF YH FAX OR POf 7~shy Hom (IE SPECIAL DETECTION LINITl BllLIKGINfO If DlffERrnT)ELECTRONIC OPTIONS zo 1 2 2) le~C1 1 Jc Id sJ 60 6c
1 cf Co
lo FAX pound-MAIL PDF EQUll C jCi (e I rt--111 Ao NiAJrJe middotn th
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ImiddotRELINQUISHED BY DATE TIHE RECflVEO BY I FIELD READINGS
eastern analytical inc 2s CHENELL D R1ve IC 0 Nco1to N H 0330 1 I TEL 60J22aos2s 1aoo2a1os2s IFAx 6032284591 j E-MA1t cus-roM111_mV1c~EAILAsscoMJ www1A1LAascoM
----i pmiddotofissionrrl11bomtorymim (WHITE ORIGINAL GREEN PROJECT MANAGER)
shy
bullbull
Wirmipesaukee River Basin Program Wastewater Treatment Plant File No 04002930700
April272012 Page2
As part of a recent sampling effort for the steam electric power generating effluent guidelines rulemaking EPA developed an SOP that was used in conjunction with EPA Method 2008 to conduct ICP-MS analyses of FGD wastewater The SOP describes critical technical and quality assurance procedures that were implemented to mitigate anticipated interferences and generate reliable data for FGD wastewater EPA regulations at 40 CFR 1366 already allow the analytical community flexibility to modify approved methods to lower the costs of measurements overcome matrix interferences or otherwise improve the analysis The draft SOP developed for FGD wastewater takes a proactive approach toward looking for and taking steps to mitigate matrix interferences including using specialized interference check solutions (ie a synthetic FGD wastewater matrix) EPAs draft SOP is being made available to laboratories contemplating ICP-MS analysis of FGD wastewater either for adoption as currently written or to serve as a framework for developing their own laboratory-specific SOP For further information see
Standard Operating Procedure Inductively Coupled PlasmaMass Spectrometry for Trace Element Analysis in Flue Gas Desulfurization Wastewaters (30 pp 174K) http water epagovscitechwastetechlguideuploadsteam _draft _soppdf EPA May 2011
Considering that specialized analytical teclmiques are necessary to overcome matrix interference for certain analysis of trace metals in FDG wastewater we recommend any analysis on FGD wastewater be conducted in accordance with the EPA draft SOP for trace metals analysis ofFGD wastewater
Should you have any questions concerning this report please do not hesitate to contact me at (603) 232-8744
Very truly yours
GZA GEO ENVIRONMENT AL INC
Ronald A Breton PE Michael P North P E Principal ConsultantReviewer
RABMPNtmd IGZAMANJobs04Jobsl002930004002930700WorklSAMPUNG AND REPORTINGRfPORTSFraollinlfuull 04002930700 franklin OlG112lIWll 042712docx
Attachment Analytical Data Report
ANALYTICAL DATA REPORT
----1~J___________e_a_~_t_~-~-~--~-~-~-bullv_t_i_~-~-bull-__
Paul Pepler
GZA GeoEnvironmental Inc (NH)
380 Harvey Road
Manchester NH 03103
Subject Laboratory Report
Eastern Analytical Inc ID 107555 Client Identification Merrimack Station
Date Received 152012
Dear Mr Pepler
Enclosed please find the report of analysis for the above identified project As discussed analyses were subcontracted and are listed as follows
Analysis Subcontract - Metals Method 2008 (AlSbBaBeCdCaCrCuFePbMnMoNaNiAgTlZnAsSe amp Hg)
Subcontractor Lab Frontier Global Sciences Inc
A complete copy of the report is attached This report may not be reproduced except in full without the written approval of the laboratory
We appreciate this opportunity to be of service and look forward to your continued patronage
Sincerely
Lorraine Olashaw Lab Direc r Date of pages (excluding cover letter)
Wmiddottaihb ~Clt l111 I
SAMPLE CONDITIONS PAGE EAi ID 107555
Client GZA GeoEnvironmental Inc (NH)
Client Designation Merrimack Station
Temperature upon receipt (degC) Acceptable temperature range (0 C) 0-6
Lab ID Sample ID
47
Date Received Sampled
Date
Received on ice or cold packs (YesNo)
Sample Ory Matrix Weight ExceptionsComments (other than
y
thermal preservation)
10755501 Treat Tank Eff Composite 115112 1512 aqueous Adheres to Sample Acceptance Policy
10755502 Treat Tank Eff Grab 11512 15112 aqueous Adheres to Sample Acceptance Policy
Samples were properly preserved and the pH measured when applicable unless otherwise noted Analysis of solids for pH Flashpoint lgnitibility Paint Filter Corrosivity Conductivity and Specific Gravity are reported on an as received basis All results contained in this report relate only to the above listed samples
References include 1) EPA 6004-79-020 1983 2) Standard Methods for Examination of Water and Wastewater lnorganics 19th Edition 1995 Microbiology 20th Edition 1998 3) Test Methods for Evaluating Solid Waste SW 846 3rd Edition including updates VA and VB 4) Hach Water Analysis Handbook 2nd edition 1992
eastern analytical inc wwweailabscom Phone (603) 228-0525 1
l l 720 North Creek Parkway North Suite 400 Bothell WA 98011
Ph 425-686-1996 Fx 425-686-3096 G L OBAL SCIENCES
25 April 2012
JeffGagne
Eastern Analytical Inc
25 Chenell Drive
Concord NH 0330 I
RE Merrimack Station
Enclosed are the analytical results for samples received by Frontier Global Sciences All quality control
measurements are within established control limits and there were no analytical difficulties encountered with the exception of those listed in the case narrative section of this report
If you have any questions concerning this report please feel free to contact me
Sincerely
Liz Siska
Project Manager
2
GLOBAL SCIENCES
11720 North Creek Parkway North Suite 400 Bothell WA 98011
Ph 425-686-1996 Fx 425-686-3096
ANALYTICAL REPORT FOR SAMPLES
Laboratory Frontier Global Sciences Inc SDG
Client Eastern Analytical Inc Project Merrimack Station
Sample ID Lab ID Matrix Date Sampled Date Received
Treat Tank EffComposite 1201073-01 Water 05-Jan-12 1000 06-Jan-12 0950
Treat Tank EffGrab 1201073-02 Water 05-Jan-12 0800 06-Jan-12 0950
Frontier Global Sciences Inc
Liz Siska Project Manager
The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Page 1 o261201073 Final Report 04252012 3
11720 North Creek Parkway North Suite 400 Bothell WA 98011
Ph 425-686-1996FRONTIER Fx 425-686-3096 GLOBAL SCIENCES
CASE NARRATIVE
Revised Report 42512
Per client request Boron was removed from report
Revised Report 32812
Per client request samples were prepared and analyzed for total metals in accordance with EPA 2008 (modified)
SAMPLE RECEIPT
Samples were received at Frontier Global Sciences (FGS) on January 6th 2012 The samples were received intact on-ice with temperatures measured at 34 degrees Celsius
SAMPLE PREPARATION AND ANAL YSJS
Samples were prepared and analyzed for total metals in accordance with FGS-054EPA 1638
Samples were prepared and analyzed for total mercury in accordance with EPA Method 163JE
ANALYTICAL AND QUALITY CONTROL IS SUES
There were no analytical difficulties experienced with analysis of these samples with the exceptions flagged in the report
Frontier Gtobal Sciences Inc The results in this reporr only apply 10 the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Liz Siska Project Manager Page 2of26 J20I073 Final Report 042512012 4
11720 North Creek Parkway North Suite 400 Bothell WA 98011~ Ph 425-686-1996 FRONTIER Fx 425-686-3096
GLOBAL SCIENCES
CHAIN OF CUSTODY FORMS
CML-1d Cc-t~lt7 shy~P~fci amp l sbtr3~~ry Aillylc P~ctirst J- ~V~-=lt S=-Jit=~1t Imiddot~ and 4J~~ Tssul
~ r~middotmiddotmiddot to ~-~ middot ~ ~middot ~rcshyr-11 ---4i--5~1-shy
y1tcirc1middot 6middot 01gter S1bulli1e
1 1 -middot shy
~middot-middotn middot~i---it =-middotmiddotrmiddot~-~r9ft~ri r s L lrj~JT ~- bull 1r bullermiddot~~(~lr- rlt-bull~~~~~ _ -tbull ~t-tmiddotbull I~ bull 1
middot middot l~~e ~middot rv~ 8Arvmiddott _ -middot
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report mus be reproduced in ilS entirety
Page3of26Liz Siska Project Manager 1201073 Final Report
041252012 5
Liz Siska Project Manager
11720 North Creek Parkway North Suite 400 Bothell WA 98011
Ph 425-686- 1996 ~ Fx 425-686-3096 G LOB A L SC I EN CE S
ANALYTICAL RESULTS
Treat Tank Eff Composite
Matrix Water Laboratory ID 1201073-01
Analyte Result MDL MRL Units Dilution Batch Sequence Analyzed Method Notes
Aluminum ND 89 800 microgL 20 F203271 2C22005 032212 EPA 2008 Mod u Antimony 0408 0092 0400 microgL 20 F20327l 2C22005 032212 EPA 2008 Mod Barium 240 054 400 microgL 20 F203271 2C22005 032212 EPA 2008 Mod Beryllium ND 0454 t20 microgL 20 F203271 2C22005 032212 EPA 2008 Mod u Cadmium ND 0083 0400 microgL 20 F203271 2C22005 032212 EPA 2008 Mod u Calcium 5010000 16200 200000 microgL 5000 F203271 2C22005 032212 EPA 2008 Mod Chromium ND 018 200 microgL 20 F20327I 2C22005 032212 EPA 2008 Mod u Copper ND 020 200 microgL 20 F203271 2C22005 032212 EPA 2008 Mod u Iron ND 260 200 microgL 20 F20327l 2C22005 032212 EPA 2008 Mod u Lead ND 0078 0800 microgL 20 F20327l 2C22005 032212 EPA 2008 Mod u Manganese 280 015 200 microgL 20 F203271 2C22005 032212 EPA 2008 Mod Molybdenum 134 012 120 microgL 20 F20327I 2C22005 032212 EPA 2008 Mod Nickel 979 016 2 00 microgL 20 F203271 2C22005 032212 EPA 2008 Mod Silver ND 0120 0400 microgL 20 F203271 2C22005 032212 EPA 2008 Mod u Sodium 259000 23 400 microgL 20 F203271 2C22005 032212 EPA 2008 Mod Thallium 556 0250 100 microgL 100 F203314 2C25005 032512 EPA 2008 Mod Zinc ND 033 400 microgL 20 F203271 2C22005 032212 EPA 2008 Mod u
Frontier Global Sciences Inc The middotesults in 1his report only apply to the samples analyzed in accordance wilh 11e chain ofcus1ody documem This analytical report must be reproduced in ifs entirety
Page 4of26 1201073 Final Report 04252012 6
Liz Siska Project Manager
11720 North Creek Parkway North Suite 400 Bothell WA 98011
Ph 425-686-1996 Fx 425-686-3096
GLOBAt SCIENCES
ANALYTICAL RESULTS
Treat Tank Eff Grab
Matrix Water Laboratory ID 1201073-02
Analyte Result MDL MRL Units Dilution Batch Sequence Analyzed Method Notes
Arsenic 851 102 300 microgL 20 F203271 2C22005 032212 EPA 2008 Mod Mercury 105 034 202 ngL 4 F20I063 2A09010 010912 EPA 1631E FB-1631 Selenium 689 388 120 microgL 20 F203271 2C22005 032212 EPA 2008 Mod
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcustody documenJ This analycical report must be reproduced in its entirety
Page 5 o261201073 Final Report 04252012 7
Liz Siska Project Manager
FRONTIERshycLoaAt SCI ENCES
11720 North Creek Parkway North Suite 400 Bothell WA 98011
Ph 425-686-1996 Fx 425-686-3096
MATRIX DUPLICATESfRIPLICATES
SOURCE 1201073-02
Batch F201063
Preparation BrCI Oxidation
Sequence 2A09010
Lab Number F201063-DUPI
Sample Duplicate Concentration Concentration RPD
Analyte ngL ngL MRL RPD Limit Method Notes Mercury 1048 1054 202 0617 24 EPA I631E
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Page 6of26 1201073 Final Report 04252012 8
11720 North Creek Parkway North Suite 400 BotheE WA 980 l l
Ph 425-686-1996 Fx 425-686-3096
GLOBAL SCIENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1201073-02
Batch F201063 Sequence 2A09010
Preparation BrCI Oxidation Lab Number F20 l 063-MSMSDl
Sample Spike MS MS Concentration Added Concentration RecoveryAnalyte (ngL) (ngL) (ngL) Recovery Method Limits Notes
Mercury 1048 20400 3136 102 71 125 EPA 163IE
Spike MSD MSD Added Concentration oo Recovery RPD
RPD Limits Limit Method Notes Analyte (ngL) (ngL) Recovery
Mercury 20400 2708 814 147 71 - 125 24 EPA 1631E
shy
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Page 7 o26Liz Siska Project Manager 120JO7 3 Final Repo1
04252012 9
Liz Siska Project Manager
11720 North Creek Parkway North Suite 400 Bothell WA 98011
Ph 425-686-1996~ Fx 425-686-3096 CL06AL SCIENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1112278-02
Batch F201063 Sequence 2A09010
Preparation BrCI Oxidation Lab Number F20 l 063-MSMSD2
Sample Spike MS MS
Analyte Concentration
(ogL) Added (ngL)
Concentration (ngL)
Recovery
RecoveryLimits Method Notes
Mercury 761 20400 2786 992 71 125 EPA 1631E
Spike MSD MSD Added Concentration Oo Recovery RPO
Analyte (ngL) (ngL) Recovery RPO Limits Limit Method Notes
Mercury 20400 2837 102 182 71 - 125 24 EPA l631E
shy
Frontier Global Sciences Inc The results in this report only apply to the somples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Page 8 o26 1201073 Final Report 042512012 10
11720 North Creek Parkway North Suite 400 Bothell WA 980 l l
Ph 425-686-1996 ~ Fx 425-686-3096 GLOBAL SCIENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1201029-01
Batch
Preparation
F201063
BrCI Oxidation
Sequence
Lab Number
2A09010
F20 I 063-MSMSD3
Analyte
Mercury
Analyte
Mercury
Sample Spike Concentration Added
(ngL) (ngL)
534 10200
Spike MSD Added Concentration (ngL) (ngL)
10200 1407
MS MS Concentration Recovery
(ngL) Recovery Limits
1558 JOO 7l shy 125
MSD oo Recovery RPD
Recovery RPD Limits Limit
856 102 71 - 125 24
Method
EPA l63lE
Method
EPA 631E
Notes
Notes
Frontier Global Sciences Inc The results in this repon only apply to rhe samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Page 9of26 1201073 Final Report 041252012
Liz Siska Project Manager
1 1
11720 North Creek Parkway North Suite 400 Bothell WA 98011
Ph 425-686-1996 FRONTIER- Fx 425-686-3096 cLosAL SCIENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1201030-02
Batch F20I063 Sequence 2A09010
Preparation BrCI Oxidation Lab Number F201063-MSMSD4
Sample Spike MS MS Concentration Added Concentration RecoveryAnalyte (ngL) (ngL) (ngL) Recovery MethodLimits Notes
Mercury 554 10200 1482 910 71 - 125 EPA I631E
Spike MSD MSD Oo Added Concentratio11 Recovery RPD
RPD Limits Limit Method Analyte (ngL) (ngL) Recovery Notes
Mercury 10200 1461 890 140 71 - 125 24 EPA 163IE
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed m accordance with the chain ofcus1ody document This anayt(ca repon must be reproduced in itr entirety
Page lOo26Liz Siska Project Manager 1201073 Final Report
041252012 12
I 1720 North Creek Parkway North Suite 400 Bothe I I WA 98011
Ph 425-686-1996 ~ Fx 425-686-3096 GLOBAL SCIENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1201073-01RE3
Batch F20327l Sequence 2C22005
Prcpa ration ((01ed Vessel ~ itric Oven Digestion Lab Number F203271-MSMSD 1
Analyte
Sample Concentration
(microgL)
Spike Added (microgL)
MS Concentration
(microgL)
MS Oo
Recovery Recovery
Method Limits Notes
Calcium 5013000 15150 4802000 -13900 70- 130 EPA 2008 Mod QM-02
Analyte
Spike Added (microgL)
MSD Concentration
(microgL)
MSD ~o
Recovery
Oo
RPD Recovery
Limits RPDLimit Method Notes
Calcium 15150 4943000 -4600 289 70 - 130 20 EPA 2008 Mod QM-02
Frontier Global Sciences Inc The results in this report only apply to the samples analyud inaccordance with the chain ofcustody document 17is analyticol report must be reproduced in its entirety
Page lI o16 1101073 Final Report 04152012
Liz Siska Project Manager
13
l l 720 North Creek Parkway North Suite 400 Bothell WA 98011
Ph 425-686-1996FRONTIER Fx 425-686-3096 GLOBAL SCIENCES
MATRIX SPIKE I MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1201073-01RE4
Batch F203271 Sequence 2C22005
Preparation Closed Vessel Nitric Oven Digestion Lab Number F203271-MSMSD2
Sample Spike MS MS Concentration Added Concentration Oo RecoveryAnalyte (microgL) (microgL) (microgL) Recovery Method Limits Notes
Beryllium 0507 20200 2442 958 70 - 130 EPA 2008 Mod Sodium 258800 50500 257700 -213 70 -130 EPA 2008 Mod QM-02 Aluminum 529 15150 2023 986 70 - 130 EPA 2008 Mod Chromium 057 70700 804 106 70 - 130 EPA 2008 Mod Manganese 2805 60600 2834 476 70 - 130 EPA 2008 Mod QM-02 Iron ND 50500 5200 103 70 130 EPA 2008 Mod Nickel 979 40400 141 l 107 70- 130 EPA 2008 Mod Copper 055 40400 434 939 70 - 130 EPA 2008 Mod Zinc 040 10100 842 794 70 - 130 EPA 2008 Mod Arsenic 1030 15150 2418 916 70 - 130 EPA 2008 Mod Selenium 6340 30300 8973 869 70 130 EPA 2008 Mod Molybdenum 1338 20200 1367 142 70 130 EPA 2008 Mod QM-02 Silver ND 15150 1388 916 70 - 130 EPA 2008 Mod Cadmium 0332 080800 1105 middot956 70 - 130 EPA 2008 Mod Antimony 0408 080800 1259 105 70- 130 EPA 2008 Mod Barium 2397 10100 2495 968 70 - 130 EPA 2008 Mod Lead ND 15150 1542 102 70 130 EPA 2008 Mod
shy
shy
shy
shy
Analyte
Spike Added (microgL)
MSD Concentration
(microgL)
MSD Oo
Recovery
Oo
RPD Recovery
Limits RPD Limit Method Notes
Beryllium
Sodium
Aluminum
Chromium
Manganese
Iron
Nickel
Copper
Zinc
Arsenic
Selenium
Molybdenum
20200
50500
15150
7Q700
60600
50500
40400
40400
10100
15150
30300
20200
2561
257100
2034
773
2852
5187
1381
419
916
2225
9400
1366
102
-336
993
101 769
103
995
902
868
789
101
137
474
0243
0564
385
0625
0242
213
347
849
831
464
00771
70 - 130
70 bull 130 70 - 130
70 - 130
70 - 130
70 - 130
70 - 130
70 - 130
70 - 130
70 bull 130 70 - 130
70 - 130
20
20
20
20
20
20
20
20
20
20
20
20
EPA 2008 Mod
EPA 2008 Mod
EPA 2008 Mod
EPA 2008 Mod
EPA 2008 Mod
EPA 2008 Mod
EPA 2008 Mod
EPA 2008 Mod
EPA 2008 Mod
EPA 2008 Mod
EPA 2008 Mod
EPA 2008 Mod
QM-02
QM-02
Frontier G lobal Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
--f_~ --~~~-~ -middot middot Page 12 o261201073 Final Report 041252012
Liz Siska Project Manager
14
11720 North Creek Parkway North Suite 400
~ Bothell WA 98011
~TIEmiddot Ph 425-686-1996 Fx 425-686-3096
GLOB11L SCIENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPO
SOURCE 1201073-01RE4
Batch F203271 Sequence 2C22005
Preparation ~lo~ed Vessel Nitric Oven Digestion Lab Number F20327 I-MSMSD2
Spike MSD MSD Added Concentration Oo Recovery RPO
Analyte (microgL) (microgL) Recovery RPD Limits Limit Method Notes
Silver 15150 1387 915 00874 70 - 130 20 EPA 2008 Mod Cadmium 080800 1061 902 403 70 - 130 20 EPA 200amp Mod Antimony 080800 1274 107 l2l 70 - 130 20 EPA 2008 Mod Barium 10100 2514 )16 0781 70 - 130 20 EPA 200amp Mod Lead 15150 1534 101 0525 70 shy 130 20 EPA 2008 Mod
Frontier Global Sciences Inc The results in this report only apply to 1he samples analyzed in accordance wiih the chain ofcustody document This analytical repo1 must be reproduced in ils entirety
Page 13 o26Liz Siska Project Manager 1201073 Final Reporl
04252012 15
11720 North Creek Parkway North Suite 400
~ Bothell WA 98011 Ph 425-686-I996
~RONTIER~ Fx 425-686-3096 GLOBAL SCIEN C ES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1201073-01RE3
Batch F203271 Sequence 2~22005
Preparation Closed Vessel Nitric Oven Digestion Lab Number F20327 I-MSMSD3
Sample Spike MS MS
Analyte Concentration
(microgL) Added (microgL)
Concentration (microgL) Recovery
Recovery Limits Method Notes
Calcium 5013000 10100000 15120000 100 70- 130 EPA 2008 Mod AS
Spike MSD MSD Added Concentration o Oo Recovery RPD
Analyte (microgL) (microgL) Recovery RPD Limits Limit Method Notes
Calcium 10100000 16140000 llO 653 70 - 130 20 EPA 2008 Mod AS
Frontier Global Sciences Inc The results in his report only apply 10 the samples analyzed in accordance ivth he chain ofcustody document This analytical report must be reproduced in its entirety
Page 14 o261201073 Final Report 0425201]
Liz Siska Project Manager
16
Frontier Global Sciences Inc The ruults in this rechain ofcustody do
~ -lt1-c--~ Liz Siska Project Manager
11720 North Creek Parkway North Suite 400 Bothell WA 98011
Ph 425-686-1996 Fx 425-686-3096
GLOBAL SCIENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1201073-01RE4
Batch J203271 Sequence 2C22005
Preparation ~ IQsed Ve~~el Nitric Oven Qigestion Lab Number F203271-MSMSQ4
Analyte
Beryllium
Sample Concentration
(11gL)
0507
Spike Added (11gL)
20200
MS Concentration
(microgL)
2041
MS Oo
Recovery
985
RecoveryMethod Limits
70 - 130 EPA 2008 Mod
Notes
AS
Sodium 258800 40400 292900 845 70- 130 EPA 2008 Mod AS
Aluminum 529 40400 3956 966 70 - 130 EPA 2008 Mod AS
Chromium 057 40400 430l 106 70- 130 EPA 2008 Mod AS
Manganese 2805 40400 7042 105 70 - 130 EPA 2008 Mod AS
Iron ND 20200 2121 105 70 - 130 EPA 2008 Mod AS
Nickel 979 50500 5112 993 70 l30 EPA 2008 Mod AS
Copper 055 50500 4754 940 70 - 130 EPA 2008 Mod AS
Zinc 040 10100 9074 898 70 - 130 EPA 2008 Mod AS
Arsenic 1030 40400 4317 104 70 130 EPA 2008 Mod AS
Selenium 6340 40400 4688 100 70 - 130 EPA 2008 Mod AS
Molybdenum 1338 20200 338l 101 70 - 130 EPA 2008 Mod AS
Silver ND 20200 1850 916 70 130 EPA 2008 Mod AS
Cadmium 0332 40400 3937 966 70 130 EPA 2008 Mod AS
Antimony 0408 20200 2091 102 70 - 130 EPA 2008 Mod AS
Barium 2397 80800 1056 101 70- 130 EPA 2008 Mod AS
Lead ND IO100 9932 983 70 130 EPA 2008 Mod AS
shy
shy
shy
shy
shy
Analyte
Spike Added (microgL)
MSD Concentration
(microgL)
MSD
Recovery
RPD
Recovery Limits
RPDLimit Method Notes
Beryllium 20200 2007 968 l71 70 - 130 20 EPA 2008 Mod AS Sodium 40400 292600 837 0114 70 130 20 EPA 2008 Mod AS Aluminum 40400 3954 966 00362 70 - 130 20 EPA 2008 Mod AS Chromium 40400 4287 106 0337 70 - 130 20 EPA 2008 Mod AS Manganese 40400 6944 102 140 70 - 130 20 EPA 2008 Mod AS Iron 20200 2077 103 211 70 - 130 20 EPA 2008 Mod AS Nickel 50500 5126 996 0276 70 - 130 20 EPA 2008 Mod AS Copper 50500 4707 931 0997 70 - 130 20 EPA 200 8 Mod AS Zinc 10100 9059 896 0166 70 - 130 20 EPA 2008 Mod AS Arsenic 40400 4299 104 0419 70 - 130 20 EPA 2008 Mod AS Selenium 40400 4682 100 0141 70 - 130 20 EPA 2008 Mod AS Molybdenum 20200 3365 100 0473 70 - 130 20 EPA 2008 Mod AS
shy
port only apply to the sampltts analyzed in accordance with the cument This analytical report must be reproduced in its entirety
Page 5 o26 201073 Final Report 042512012 17
Liz Sia Project Manager
11720 North Creek Parkway North Suite 400 Botheln VA 98011
Ph 425-686-1996 Fx 425-686-3096
CLOBAL SCIENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1201073-01RE4
Batch F203271 Sequence 2c2io2~
Preparation Clo~ed Vessel litric Oven Digestion Lab Number F20327 l -MSMSQ4
Analyte
Spike Added (microgL)
MSD Concentration
(microgL)
MSD
Recovery
Oo
RPD Recovery
Limits RPOLimit Method Notes
Silver 20200 1895 938 242 70 - 130 20 EPA 2008 Mod AS Cadmium 40400 3933 965 0104 70 -130 20 EPA 2008 Mod AS Antimony 20200 2107 102 0736 70- 130 20 EPA 2008 Mod AS
Barium 80800 1058 101 0205 70 - 130 20 EPA 2008 Mod AS
Lead 10100 9877 978 0549 70 - 130 20 EPA 2008 Mod AS
Frontier Global Sciences Inc The results in this report only apply to the samples analyudin accordance with lht chain ofcustody document This analytical report must be reproductd rn ilS enlirtty
Page l6of26 1201073 Final Report Ofn5202 18
l I 720 North Creek Parkway North Suite 400 Bothell WA 980I I
Ph 425-686-1996 Fx 425-686-3096
GLO B AL SCIENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1201073-01RE6
Batch F203314 Sequence 2C25005
Preparation Closed Vessel Nitric Oven Digestion Lab Number F203314-MSMSD2
Sample Spike MS MS Concentration Added Concentration RecoveryAnalyte (microgL) (microgL) (microgL) Recovery Method NotesLimits
Thallium 5563 040400 5875 773 70 - 130 EPA 2008 Mod
Spike MSD MSD Added o Concentration Recovery RPD
RPO Limits Limit Method Notes Analyte (microgL) (microgL) Recovery
Thallium 040400 5880 785 00859 70 - 130 20 EPA 2008 Mod
Frontier Global Sciences Inc 11e results in chis reporc only apply 10 1he samples analyzed in accordance wilh lhe chain ofcustody documenz This analycical report musl be reproduced in ils entirety
Page 17 of26 1201073 Fi11aReport 0412512012
Liz Siska Project Manager
19
11720 North Creek Parkway North Suite 400 Bothell WA 98011
Ph 425-686-1996 Fx 425-686-3096
GLOBAl SCIENC ES
MATRIX SPIKE I MATRIX SPIKE DUPLICATE RECOVERY AND RPO
SOURCE I201073-01RE6
Batch F203314
Preparation Closed Vessel Nitric Oven Digestion
Sequence 2C25005
Lab Number F203314-MSMSD4
Analyte
Sample Concentration
(microgL)
Spike Added (microgL)
MS MS Concentration Oo
(microgL) Recovery Recovery
Limits Method Notes
Thallium 5563 10100 1033 968 70- 130 EPA 2008 Mod AS
Analyte
Spike Added (microgL)
MSD Concentration
(microgL)
MS)) Oo
Recovery
RPD
Recovery Limits
RPD Limit Method Notes
Thallium IO100 1037 97l 0341 70 - 130 20 EPA 2008 Mod AS
Frontier Global Sciences Inc The resulrs in this report only apply to the samples analyzed in accordance with the chain ofcusrody document This analytical report must be reproduced in its entirely
Page 18of26 120073 Final Report 04252012
Liz Siska Project Manager
20
11720 North Creek Parkway North Suite 400 l ~ Bothell WA 980 l l Ph 425-686-1996
FRONTIER Fx 425-686-3096 GLOBAL SCIENCES
LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLICATE
RECOVERY AND RPD
Batch F20 l063 Sequence 2A09010
Preparation BrCI Oxidation Lab Number F201063-BSIBSJ21
LCS Source N ist 1641d
Analyte
Spike Added (ngL)
LCS Concentration
(ngL)
LCS
Recovery Recovery
Limits Method Notes
Mercury 15679 1550 988 80 - 120 EPA I631E
Analyte
Spike Added (ngL)
LCSD Concentration
(ngL)
LCSD Oo
Recovery
RPD Recovery
Limits RPD Limit Method Notes
Mercury 15679 1595 [02 289 80 - 120 24 EPA I631E
Frontier Global Sciences Inc The results in this report only apply to the samples analyzedin accordance with the chain ofcustody document This analytical report must be reproduced in ils entirety
Page 19of26 1201073 Final Report 0425 2012
Liz Siska Project Manager
21
11720 North Creek Parkway North Suite 400 Bothell WA 98011
Ph 425-686-1996 FRONTIER Fx 425-686-3096 GLOBAL SCIENCES
LABORA TORY CONTROL SAMPLE LABO RATORY CONTROL SAMPLE DUPLICATE
RECOVERY AND RPD
Batch F203271 Sequence 2C22005
Preparation Closed Vessel Nitric Oven Digestion Lab Number F203271-BSBSD1
LCS Source Blank Spike
Spike LCS LCS Added Concentration Oo Recovery
Analyte (microgL) (microgL) Recovery Limits Method Notes
Beryllium 20000 l930 965 85 - 115 EPA 2008 Mod
Sodium 50000 499 998 85 - 115 EPA 2008 Mod
Aluminum 15000 1460 973 85 - 115 EPA 2008 Mod
Calcium 15000 1528 102 85 - 115 EPA 2008 Mod
Chromium 70000 657 939 85 - 115 EPA 2008 Mod
Manganese 60000 586 976 85 - 115 EPA 2008 Mod
Iron 50000 4753 951 85 shy 115 EPA 2008 Mod
Nickel 40000 401 100 85 - 115 EPA 2008 Mod
Copper 40000 418 105 85 - 115 EPA 2008 Mod
Zinc 10000 1033 103 85 - 115 EPA 2008 Mod
Arsenic 15000 1437 958 85 - 115 EPA 2008 Mod
Selenium 30000 2966 989 85 - 115 EPA 2008 Mod
Molybdenum 20000 181 905 85 shy 115 EPA 2008 Mod
Silver 15000 1517 101 85 shy 115 EPA 2008 Mod
Cadmium 080000 0781 976 85 - 1lS EPA 2008 Mod
Antimony 080000 0815 102 85 - 115 EPA 2008 Mod
Barium 10000 969 969 85 - 115 EPA 2008 Mod
Lead 15000 1597 106 85 - 115 EPA 2008 Mod
Spike LCSD LCSD Added Concentration Recovery RPO
Analyte (microgL) (microgL) Recovery RPO Limits Limit Method Notes
Beryllium 20000 1949 974 0955 85 - 115 20 EPA 2008 Mod
Sodium 50000 500 100 0216 85 - 115 20 EPA 2008 Mod
Aluminum 15000 1485 990 171 85 - 115 20 EPA 2008 Mod
Calcium 15000 1544 103 103 85 - 115 20 EPA 2008 Mod
Chromium 70000 667 953 148 85 - 115 20 EPA 2008 Mod
Manganese 60000 596 994 175 85 - 115 20 EPA 2008 Mod
Iron 50000 4852 970 206 85 - 115 20 EPA 2008 Mod
Nickel 40000 402 IOI 0246 85 - 115 20 EPA 2008 Mod
Frontier Global Sciences Inc The results in his report only apply to the samples analyzed in accordance wirh the chain ofcustody document This analytical report must be reproduced in iLS entirety
Page 20of26 1201073 Final Report 04252012
Liz Siska Project Manager
22
11720 North Creek Parkway North Suite 400 ~~shy Bothell WA 98011 Ph 425-686-1996~ONTif Fx 425-686-3096
GLOBAL SCIENCES
LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLICATE
RECOVERY AND RPO
Batch F20327 l Sequence 2C22005
Preparation Closed Vessel Nitric Oven Digestion Lab Number F203271-BSBSD 1
LCS Source Blank Spike
Analyte
Spike Added (microgL)
LCSD Concentration
(microgL)
LCSD oo
Recovery
RPO Recovery
Limits RPO Limit Method Notes
Copper
Zinc
Arsenic
Selenium
40000
10000
15000
30000
428
1039
1452
3015
107
104
968
101
224
0570
0977
166
85 - 115
85 - 115
85 - 115
85 - 115
20
20
20
20
EPA 2008 Mod
EPA 2008 Mod
EPA 2008 Mod
EPA 2008 Mod Molybdenum
Silver
20000
15000
182
J502
910
100
0564
103
85 - 115
85 - 115
20
20
EPA 2008 Mod
EPA 2008 Mod Cadmium
Antimony
Barium
Lead
080000
080000
10000
15000
0828
0808
986
1620
103
101
986
108
585
0848
177
142
85 - 115
85 - 115
85 shy 11 S
85 - 115
20
20
20
20
EPA 2008 Mod
EPA 2008 Mod
EPA 2008 Mod
EPA 2008 Mod
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report mus be reproducedin its entirety
Page 2 o26J20J073 Final Report 041252012
Liz Siska Project Manager
23
11720 North Creek Parkway North Suite 400 Bothell WA 980 l l
Ph 425-686-1996FRONT[ER- Fx 425-686-3096 cLosAL SCIEN _CES
LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLICATE
RECOVERY AND RPD
Batch F203314 Sequence 2C25005
Preparation Closed Vessel Nitric Oven Digestion Lab Number F2033 l 4-BSBSD 1
LCS Source Blank Spike
Analyte
Thallium
Spike Added (microgL)
LCS Concentration
(microgL)
LCS 0o
Recovery Recovery
Limits Method
040000 0396 989 85 - 115 EPA 2008 Mod
Notes
Analyte
Spike Added (microgL)
LCSD Concentration
(microgL)
LCSD 0o
Recovery
RPD Recovery
Limits RPO Limit Method Notes
Thallium 040000 0391 978 112 85 - ll5 20 EPA 2008 Mod
Frontier Global Sciences Inc The results in this report only apply to the samples anayed in accordance with the chain ofcustody docwnenJ This analytical report must be reproduced in its entirety
Page 22of26 1201073 Final Report 04252012
Liz Siska Project Manager
24
Liz Siska P roject Manager
11720 North Creek Parkway North Suite 400
~ Bothell WA 98011 Ph 425-686-1996
~JTIEif middot Fx 425-686-3096 GLOBAL SCIENCES
PREPARATION BLANKS
Instrument Hg-17 Sequence 2A09010
Preparation BrCI Oxidation
Lab Sample ID Analyte Found MRL Units Batch Method Notes
F201063-BLK I Mercury -0009 050 ngL F201063 EPA 1631E u F20 I063-BLK2 Mercury -0006 050 ngL F201063 EPA 1631E u F201063-BLK3 Mercury -002 050 ngL F201063 EPA 163IE u F201063-BLK4 Mercury 003 050 ngL F201063 EPA 1631E U QB-04 F201063-BLKS Mercury 011 052 ngL F201063 EPA I631E U QB-06
Frontier Global Sciences Inc The results in this report only apply 10 1he samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Page 23 o26 1201073 Final Repon 04252012 25
Liz Siska Project Manager
11720 North Creek Parkway North Suite 400 Bothell WA 98011
Ph 425-686-1996 FROr~TIER- Fx 425-686-3096 GLOBAL SCIENCES
PREPARATION BLANKS
Instrument ICPMS-6 Sequence 2C22005
Preparation Closed Vessel Nitric Oven Digestion
Lab Sample ID Analyte Found MRL Units Batch Method Notes
F203271-BLK1 Beryllium 000008 0060 microgL F203271 PA 2008 Molt u F20327 1-BLK1 Sodium 2 20 microgL F20327l PA 2008 Moc u F20327I-BLK1 Aluminum -004 40 microgL F203271 PA 2008 Molt u F20327I -BLK1 Calcium 40 microgL F203271 PA 2008 Molt u F203271 -BLK1 Chromium -002 010 microgL F203271 ~A 2008 Molt u F203271-BLKI Manganese 001 010 microgL F203271 PA 2008 Molt u F20327 l -BLK 1 Iron -002 100 microgL F203271 PA 2008 Molt u F203271-BLKI Nickel 0004 010 microgL F203271 PA 2008 Moc u F203271-BLK1 Copper 0003 010 microgL F203271 PA 2008 Moc u F203271-BLK1 Zinc 0007 020 microgL F203271 PA 2008 Moc u F203271-BLK1 Arsenic -006 015 microgL F203271 PA 2008 Moc u F203271-BLK1 Selenium -002 060 microgL F203271 PA 2008 Moc u F203271-BLK1 Molybdenum 001 006 microgL F203271 PA 2008 Molt u F203271-BLK1 Silver -00005 0020 microgL F203271 PA 2008 Molt u F203271-BLKl Cadmium 0004 0020 microgL F203271 PA 2008 Molt u F20327 l-BLKl Antimony 0002 0020 microgL F203271 PA 2008 Molt u F203271-BLKI Barium 001 020 microgL F203271 PA 2008 Molt u F203271-BLKI Lead 0010 0040 microgL F203271 PA 2008 Moc u
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Page 24of26 1201073 Final Report 04252012 26
~
~TIER~ GLOBAL SCIENCES
11720 North Creek Parkway North Suite 400 Bothell WA 980ll
Ph 425-686-1996 Fx 425-686-3096
PREPARATION BLANKS
Instrument JCPMS-3 Sequence 2C25005
Preparation Closed Vessel Nitric Oven Digestion
Lab Sample ID Analyte Found MRL Units Batch Method Notes
F2033I4-BLK1 Thalium 00007 0010 microgL F2033I4 ~PA 2008 Molt u
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Page 25 o26Liz Siska Project Manager 1201073 Final Report
04252012 27
l l 720 North Creek Parkway North Suite 400~Vi-~ Bothell WA 98011 Ph 425-686-1 996~Tlmiddot~ Fx 425-686-3096
G L OBAL SCIENCE S
Notes and Definitions
U Analyte included in the analysis but not detected
QM-02 The MS andor MSD recoveries outside acceptance limits due to spike concentration less than I times the sample concentration The batch was accepted based on LCS and LCSD recoveries within control limits and when analysis permits acceptable AS ASD
QB-06 The blank was preserved to 5 BrCI rather than I The control limit for blanks preserved to greater than 1 BrCl is the preservation percentage multiplied by the MRL
QB-04 The blank was preserved to 2 BrCI rather than l The control limit for blanks preserved to greater than l BrCI is the preservation percentage multiplied by the MRL
FB-1631 Required equipmentfieldfilter blank not submitted by the client The sample has been analyzed according to 163 lE but does not meet 163 lE criteria
AS This MS andor MSD is an analytical spike andor an analytical spike duplicate
DET Analyte Detected
MDL Minimum Detection Limit
MRL Minimum Reporting Limit
ND Analyte Not Detected at or above the reporting limit
wet Sample results reported on a wet weight basis
dry Sample results reported on a dry weight basis
RPO Relative Percent Difference
RSD Relative Standard Deviation
Frontier Global Sciences Inc The lesults i111his reporl only apply to he samples analyzed In accordance with the chain ofcuslody document This analytical report must be reproduced in its entirely
Page 26of26 1201073 Final Report 04252012
Liz Siska Project Manager
28
CHAIN-OF-(USTODY ttECORD Page i of f 106677 _J
BoLD F1ELDS REQUIRED PLEASE C 1RCLE REQUESTED ANALYSIS
SAMPLE ID
middoti-rg -- bull ~rshy~ _- tzir +- lt-ltJ~ lt
SAMPLING
DATeTtME
IF COMPOSITE INDICATE BOTH
START amp FINISH
DATETIME li1J oc -r 111_- _vlt-c_
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middot~ON Mm1x A-Al~ S-SOil GW-GampOUHO WATER SW-SUampfA(f WATER DWmiddotDRIIIKIKlti WATER
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PRESUMPTIVE CERTAINTY
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RECpound1VEO BYRELINQUISHED BY DATE TIME SUSPECTED (OHTAHIHATIOH________
TEHP~ C REPORTING OPTIONS 01HEA METAL------------PRELIHl Yu OR No
DISSOLVED METALS FIELD FllTEREDI YES 110
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eastern analytical inc 2s CHENELL D R1ve IC 0 Nco1to N H 0330 1 I TEL 60J22aos2s 1aoo2a1os2s IFAx 6032284591 j E-MA1t cus-roM111_mV1c~EAILAsscoMJ www1A1LAascoM
----i pmiddotofissionrrl11bomtorymim (WHITE ORIGINAL GREEN PROJECT MANAGER)
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ANALYTICAL DATA REPORT
----1~J___________e_a_~_t_~-~-~--~-~-~-bullv_t_i_~-~-bull-__
Paul Pepler
GZA GeoEnvironmental Inc (NH)
380 Harvey Road
Manchester NH 03103
Subject Laboratory Report
Eastern Analytical Inc ID 107555 Client Identification Merrimack Station
Date Received 152012
Dear Mr Pepler
Enclosed please find the report of analysis for the above identified project As discussed analyses were subcontracted and are listed as follows
Analysis Subcontract - Metals Method 2008 (AlSbBaBeCdCaCrCuFePbMnMoNaNiAgTlZnAsSe amp Hg)
Subcontractor Lab Frontier Global Sciences Inc
A complete copy of the report is attached This report may not be reproduced except in full without the written approval of the laboratory
We appreciate this opportunity to be of service and look forward to your continued patronage
Sincerely
Lorraine Olashaw Lab Direc r Date of pages (excluding cover letter)
Wmiddottaihb ~Clt l111 I
SAMPLE CONDITIONS PAGE EAi ID 107555
Client GZA GeoEnvironmental Inc (NH)
Client Designation Merrimack Station
Temperature upon receipt (degC) Acceptable temperature range (0 C) 0-6
Lab ID Sample ID
47
Date Received Sampled
Date
Received on ice or cold packs (YesNo)
Sample Ory Matrix Weight ExceptionsComments (other than
y
thermal preservation)
10755501 Treat Tank Eff Composite 115112 1512 aqueous Adheres to Sample Acceptance Policy
10755502 Treat Tank Eff Grab 11512 15112 aqueous Adheres to Sample Acceptance Policy
Samples were properly preserved and the pH measured when applicable unless otherwise noted Analysis of solids for pH Flashpoint lgnitibility Paint Filter Corrosivity Conductivity and Specific Gravity are reported on an as received basis All results contained in this report relate only to the above listed samples
References include 1) EPA 6004-79-020 1983 2) Standard Methods for Examination of Water and Wastewater lnorganics 19th Edition 1995 Microbiology 20th Edition 1998 3) Test Methods for Evaluating Solid Waste SW 846 3rd Edition including updates VA and VB 4) Hach Water Analysis Handbook 2nd edition 1992
eastern analytical inc wwweailabscom Phone (603) 228-0525 1
l l 720 North Creek Parkway North Suite 400 Bothell WA 98011
Ph 425-686-1996 Fx 425-686-3096 G L OBAL SCIENCES
25 April 2012
JeffGagne
Eastern Analytical Inc
25 Chenell Drive
Concord NH 0330 I
RE Merrimack Station
Enclosed are the analytical results for samples received by Frontier Global Sciences All quality control
measurements are within established control limits and there were no analytical difficulties encountered with the exception of those listed in the case narrative section of this report
If you have any questions concerning this report please feel free to contact me
Sincerely
Liz Siska
Project Manager
2
GLOBAL SCIENCES
11720 North Creek Parkway North Suite 400 Bothell WA 98011
Ph 425-686-1996 Fx 425-686-3096
ANALYTICAL REPORT FOR SAMPLES
Laboratory Frontier Global Sciences Inc SDG
Client Eastern Analytical Inc Project Merrimack Station
Sample ID Lab ID Matrix Date Sampled Date Received
Treat Tank EffComposite 1201073-01 Water 05-Jan-12 1000 06-Jan-12 0950
Treat Tank EffGrab 1201073-02 Water 05-Jan-12 0800 06-Jan-12 0950
Frontier Global Sciences Inc
Liz Siska Project Manager
The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Page 1 o261201073 Final Report 04252012 3
11720 North Creek Parkway North Suite 400 Bothell WA 98011
Ph 425-686-1996FRONTIER Fx 425-686-3096 GLOBAL SCIENCES
CASE NARRATIVE
Revised Report 42512
Per client request Boron was removed from report
Revised Report 32812
Per client request samples were prepared and analyzed for total metals in accordance with EPA 2008 (modified)
SAMPLE RECEIPT
Samples were received at Frontier Global Sciences (FGS) on January 6th 2012 The samples were received intact on-ice with temperatures measured at 34 degrees Celsius
SAMPLE PREPARATION AND ANAL YSJS
Samples were prepared and analyzed for total metals in accordance with FGS-054EPA 1638
Samples were prepared and analyzed for total mercury in accordance with EPA Method 163JE
ANALYTICAL AND QUALITY CONTROL IS SUES
There were no analytical difficulties experienced with analysis of these samples with the exceptions flagged in the report
Frontier Gtobal Sciences Inc The results in this reporr only apply 10 the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Liz Siska Project Manager Page 2of26 J20I073 Final Report 042512012 4
11720 North Creek Parkway North Suite 400 Bothell WA 98011~ Ph 425-686-1996 FRONTIER Fx 425-686-3096
GLOBAL SCIENCES
CHAIN OF CUSTODY FORMS
CML-1d Cc-t~lt7 shy~P~fci amp l sbtr3~~ry Aillylc P~ctirst J- ~V~-=lt S=-Jit=~1t Imiddot~ and 4J~~ Tssul
~ r~middotmiddotmiddot to ~-~ middot ~ ~middot ~rcshyr-11 ---4i--5~1-shy
y1tcirc1middot 6middot 01gter S1bulli1e
1 1 -middot shy
~middot-middotn middot~i---it =-middotmiddotrmiddot~-~r9ft~ri r s L lrj~JT ~- bull 1r bullermiddot~~(~lr- rlt-bull~~~~~ _ -tbull ~t-tmiddotbull I~ bull 1
middot middot l~~e ~middot rv~ 8Arvmiddott _ -middot
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report mus be reproduced in ilS entirety
Page3of26Liz Siska Project Manager 1201073 Final Report
041252012 5
Liz Siska Project Manager
11720 North Creek Parkway North Suite 400 Bothell WA 98011
Ph 425-686- 1996 ~ Fx 425-686-3096 G LOB A L SC I EN CE S
ANALYTICAL RESULTS
Treat Tank Eff Composite
Matrix Water Laboratory ID 1201073-01
Analyte Result MDL MRL Units Dilution Batch Sequence Analyzed Method Notes
Aluminum ND 89 800 microgL 20 F203271 2C22005 032212 EPA 2008 Mod u Antimony 0408 0092 0400 microgL 20 F20327l 2C22005 032212 EPA 2008 Mod Barium 240 054 400 microgL 20 F203271 2C22005 032212 EPA 2008 Mod Beryllium ND 0454 t20 microgL 20 F203271 2C22005 032212 EPA 2008 Mod u Cadmium ND 0083 0400 microgL 20 F203271 2C22005 032212 EPA 2008 Mod u Calcium 5010000 16200 200000 microgL 5000 F203271 2C22005 032212 EPA 2008 Mod Chromium ND 018 200 microgL 20 F20327I 2C22005 032212 EPA 2008 Mod u Copper ND 020 200 microgL 20 F203271 2C22005 032212 EPA 2008 Mod u Iron ND 260 200 microgL 20 F20327l 2C22005 032212 EPA 2008 Mod u Lead ND 0078 0800 microgL 20 F20327l 2C22005 032212 EPA 2008 Mod u Manganese 280 015 200 microgL 20 F203271 2C22005 032212 EPA 2008 Mod Molybdenum 134 012 120 microgL 20 F20327I 2C22005 032212 EPA 2008 Mod Nickel 979 016 2 00 microgL 20 F203271 2C22005 032212 EPA 2008 Mod Silver ND 0120 0400 microgL 20 F203271 2C22005 032212 EPA 2008 Mod u Sodium 259000 23 400 microgL 20 F203271 2C22005 032212 EPA 2008 Mod Thallium 556 0250 100 microgL 100 F203314 2C25005 032512 EPA 2008 Mod Zinc ND 033 400 microgL 20 F203271 2C22005 032212 EPA 2008 Mod u
Frontier Global Sciences Inc The middotesults in 1his report only apply to the samples analyzed in accordance wilh 11e chain ofcus1ody documem This analytical report must be reproduced in ifs entirety
Page 4of26 1201073 Final Report 04252012 6
Liz Siska Project Manager
11720 North Creek Parkway North Suite 400 Bothell WA 98011
Ph 425-686-1996 Fx 425-686-3096
GLOBAt SCIENCES
ANALYTICAL RESULTS
Treat Tank Eff Grab
Matrix Water Laboratory ID 1201073-02
Analyte Result MDL MRL Units Dilution Batch Sequence Analyzed Method Notes
Arsenic 851 102 300 microgL 20 F203271 2C22005 032212 EPA 2008 Mod Mercury 105 034 202 ngL 4 F20I063 2A09010 010912 EPA 1631E FB-1631 Selenium 689 388 120 microgL 20 F203271 2C22005 032212 EPA 2008 Mod
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcustody documenJ This analycical report must be reproduced in its entirety
Page 5 o261201073 Final Report 04252012 7
Liz Siska Project Manager
FRONTIERshycLoaAt SCI ENCES
11720 North Creek Parkway North Suite 400 Bothell WA 98011
Ph 425-686-1996 Fx 425-686-3096
MATRIX DUPLICATESfRIPLICATES
SOURCE 1201073-02
Batch F201063
Preparation BrCI Oxidation
Sequence 2A09010
Lab Number F201063-DUPI
Sample Duplicate Concentration Concentration RPD
Analyte ngL ngL MRL RPD Limit Method Notes Mercury 1048 1054 202 0617 24 EPA I631E
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Page 6of26 1201073 Final Report 04252012 8
11720 North Creek Parkway North Suite 400 BotheE WA 980 l l
Ph 425-686-1996 Fx 425-686-3096
GLOBAL SCIENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1201073-02
Batch F201063 Sequence 2A09010
Preparation BrCI Oxidation Lab Number F20 l 063-MSMSDl
Sample Spike MS MS Concentration Added Concentration RecoveryAnalyte (ngL) (ngL) (ngL) Recovery Method Limits Notes
Mercury 1048 20400 3136 102 71 125 EPA 163IE
Spike MSD MSD Added Concentration oo Recovery RPD
RPD Limits Limit Method Notes Analyte (ngL) (ngL) Recovery
Mercury 20400 2708 814 147 71 - 125 24 EPA 1631E
shy
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Page 7 o26Liz Siska Project Manager 120JO7 3 Final Repo1
04252012 9
Liz Siska Project Manager
11720 North Creek Parkway North Suite 400 Bothell WA 98011
Ph 425-686-1996~ Fx 425-686-3096 CL06AL SCIENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1112278-02
Batch F201063 Sequence 2A09010
Preparation BrCI Oxidation Lab Number F20 l 063-MSMSD2
Sample Spike MS MS
Analyte Concentration
(ogL) Added (ngL)
Concentration (ngL)
Recovery
RecoveryLimits Method Notes
Mercury 761 20400 2786 992 71 125 EPA 1631E
Spike MSD MSD Added Concentration Oo Recovery RPO
Analyte (ngL) (ngL) Recovery RPO Limits Limit Method Notes
Mercury 20400 2837 102 182 71 - 125 24 EPA l631E
shy
Frontier Global Sciences Inc The results in this report only apply to the somples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Page 8 o26 1201073 Final Report 042512012 10
11720 North Creek Parkway North Suite 400 Bothell WA 980 l l
Ph 425-686-1996 ~ Fx 425-686-3096 GLOBAL SCIENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1201029-01
Batch
Preparation
F201063
BrCI Oxidation
Sequence
Lab Number
2A09010
F20 I 063-MSMSD3
Analyte
Mercury
Analyte
Mercury
Sample Spike Concentration Added
(ngL) (ngL)
534 10200
Spike MSD Added Concentration (ngL) (ngL)
10200 1407
MS MS Concentration Recovery
(ngL) Recovery Limits
1558 JOO 7l shy 125
MSD oo Recovery RPD
Recovery RPD Limits Limit
856 102 71 - 125 24
Method
EPA l63lE
Method
EPA 631E
Notes
Notes
Frontier Global Sciences Inc The results in this repon only apply to rhe samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Page 9of26 1201073 Final Report 041252012
Liz Siska Project Manager
1 1
11720 North Creek Parkway North Suite 400 Bothell WA 98011
Ph 425-686-1996 FRONTIER- Fx 425-686-3096 cLosAL SCIENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1201030-02
Batch F20I063 Sequence 2A09010
Preparation BrCI Oxidation Lab Number F201063-MSMSD4
Sample Spike MS MS Concentration Added Concentration RecoveryAnalyte (ngL) (ngL) (ngL) Recovery MethodLimits Notes
Mercury 554 10200 1482 910 71 - 125 EPA I631E
Spike MSD MSD Oo Added Concentratio11 Recovery RPD
RPD Limits Limit Method Analyte (ngL) (ngL) Recovery Notes
Mercury 10200 1461 890 140 71 - 125 24 EPA 163IE
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed m accordance with the chain ofcus1ody document This anayt(ca repon must be reproduced in itr entirety
Page lOo26Liz Siska Project Manager 1201073 Final Report
041252012 12
I 1720 North Creek Parkway North Suite 400 Bothe I I WA 98011
Ph 425-686-1996 ~ Fx 425-686-3096 GLOBAL SCIENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1201073-01RE3
Batch F20327l Sequence 2C22005
Prcpa ration ((01ed Vessel ~ itric Oven Digestion Lab Number F203271-MSMSD 1
Analyte
Sample Concentration
(microgL)
Spike Added (microgL)
MS Concentration
(microgL)
MS Oo
Recovery Recovery
Method Limits Notes
Calcium 5013000 15150 4802000 -13900 70- 130 EPA 2008 Mod QM-02
Analyte
Spike Added (microgL)
MSD Concentration
(microgL)
MSD ~o
Recovery
Oo
RPD Recovery
Limits RPDLimit Method Notes
Calcium 15150 4943000 -4600 289 70 - 130 20 EPA 2008 Mod QM-02
Frontier Global Sciences Inc The results in this report only apply to the samples analyud inaccordance with the chain ofcustody document 17is analyticol report must be reproduced in its entirety
Page lI o16 1101073 Final Report 04152012
Liz Siska Project Manager
13
l l 720 North Creek Parkway North Suite 400 Bothell WA 98011
Ph 425-686-1996FRONTIER Fx 425-686-3096 GLOBAL SCIENCES
MATRIX SPIKE I MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1201073-01RE4
Batch F203271 Sequence 2C22005
Preparation Closed Vessel Nitric Oven Digestion Lab Number F203271-MSMSD2
Sample Spike MS MS Concentration Added Concentration Oo RecoveryAnalyte (microgL) (microgL) (microgL) Recovery Method Limits Notes
Beryllium 0507 20200 2442 958 70 - 130 EPA 2008 Mod Sodium 258800 50500 257700 -213 70 -130 EPA 2008 Mod QM-02 Aluminum 529 15150 2023 986 70 - 130 EPA 2008 Mod Chromium 057 70700 804 106 70 - 130 EPA 2008 Mod Manganese 2805 60600 2834 476 70 - 130 EPA 2008 Mod QM-02 Iron ND 50500 5200 103 70 130 EPA 2008 Mod Nickel 979 40400 141 l 107 70- 130 EPA 2008 Mod Copper 055 40400 434 939 70 - 130 EPA 2008 Mod Zinc 040 10100 842 794 70 - 130 EPA 2008 Mod Arsenic 1030 15150 2418 916 70 - 130 EPA 2008 Mod Selenium 6340 30300 8973 869 70 130 EPA 2008 Mod Molybdenum 1338 20200 1367 142 70 130 EPA 2008 Mod QM-02 Silver ND 15150 1388 916 70 - 130 EPA 2008 Mod Cadmium 0332 080800 1105 middot956 70 - 130 EPA 2008 Mod Antimony 0408 080800 1259 105 70- 130 EPA 2008 Mod Barium 2397 10100 2495 968 70 - 130 EPA 2008 Mod Lead ND 15150 1542 102 70 130 EPA 2008 Mod
shy
shy
shy
shy
Analyte
Spike Added (microgL)
MSD Concentration
(microgL)
MSD Oo
Recovery
Oo
RPD Recovery
Limits RPD Limit Method Notes
Beryllium
Sodium
Aluminum
Chromium
Manganese
Iron
Nickel
Copper
Zinc
Arsenic
Selenium
Molybdenum
20200
50500
15150
7Q700
60600
50500
40400
40400
10100
15150
30300
20200
2561
257100
2034
773
2852
5187
1381
419
916
2225
9400
1366
102
-336
993
101 769
103
995
902
868
789
101
137
474
0243
0564
385
0625
0242
213
347
849
831
464
00771
70 - 130
70 bull 130 70 - 130
70 - 130
70 - 130
70 - 130
70 - 130
70 - 130
70 - 130
70 bull 130 70 - 130
70 - 130
20
20
20
20
20
20
20
20
20
20
20
20
EPA 2008 Mod
EPA 2008 Mod
EPA 2008 Mod
EPA 2008 Mod
EPA 2008 Mod
EPA 2008 Mod
EPA 2008 Mod
EPA 2008 Mod
EPA 2008 Mod
EPA 2008 Mod
EPA 2008 Mod
EPA 2008 Mod
QM-02
QM-02
Frontier G lobal Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
--f_~ --~~~-~ -middot middot Page 12 o261201073 Final Report 041252012
Liz Siska Project Manager
14
11720 North Creek Parkway North Suite 400
~ Bothell WA 98011
~TIEmiddot Ph 425-686-1996 Fx 425-686-3096
GLOB11L SCIENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPO
SOURCE 1201073-01RE4
Batch F203271 Sequence 2C22005
Preparation ~lo~ed Vessel Nitric Oven Digestion Lab Number F20327 I-MSMSD2
Spike MSD MSD Added Concentration Oo Recovery RPO
Analyte (microgL) (microgL) Recovery RPD Limits Limit Method Notes
Silver 15150 1387 915 00874 70 - 130 20 EPA 2008 Mod Cadmium 080800 1061 902 403 70 - 130 20 EPA 200amp Mod Antimony 080800 1274 107 l2l 70 - 130 20 EPA 2008 Mod Barium 10100 2514 )16 0781 70 - 130 20 EPA 200amp Mod Lead 15150 1534 101 0525 70 shy 130 20 EPA 2008 Mod
Frontier Global Sciences Inc The results in this report only apply to 1he samples analyzed in accordance wiih the chain ofcustody document This analytical repo1 must be reproduced in ils entirety
Page 13 o26Liz Siska Project Manager 1201073 Final Reporl
04252012 15
11720 North Creek Parkway North Suite 400
~ Bothell WA 98011 Ph 425-686-I996
~RONTIER~ Fx 425-686-3096 GLOBAL SCIEN C ES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1201073-01RE3
Batch F203271 Sequence 2~22005
Preparation Closed Vessel Nitric Oven Digestion Lab Number F20327 I-MSMSD3
Sample Spike MS MS
Analyte Concentration
(microgL) Added (microgL)
Concentration (microgL) Recovery
Recovery Limits Method Notes
Calcium 5013000 10100000 15120000 100 70- 130 EPA 2008 Mod AS
Spike MSD MSD Added Concentration o Oo Recovery RPD
Analyte (microgL) (microgL) Recovery RPD Limits Limit Method Notes
Calcium 10100000 16140000 llO 653 70 - 130 20 EPA 2008 Mod AS
Frontier Global Sciences Inc The results in his report only apply 10 the samples analyzed in accordance ivth he chain ofcustody document This analytical report must be reproduced in its entirety
Page 14 o261201073 Final Report 0425201]
Liz Siska Project Manager
16
Frontier Global Sciences Inc The ruults in this rechain ofcustody do
~ -lt1-c--~ Liz Siska Project Manager
11720 North Creek Parkway North Suite 400 Bothell WA 98011
Ph 425-686-1996 Fx 425-686-3096
GLOBAL SCIENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1201073-01RE4
Batch J203271 Sequence 2C22005
Preparation ~ IQsed Ve~~el Nitric Oven Qigestion Lab Number F203271-MSMSQ4
Analyte
Beryllium
Sample Concentration
(11gL)
0507
Spike Added (11gL)
20200
MS Concentration
(microgL)
2041
MS Oo
Recovery
985
RecoveryMethod Limits
70 - 130 EPA 2008 Mod
Notes
AS
Sodium 258800 40400 292900 845 70- 130 EPA 2008 Mod AS
Aluminum 529 40400 3956 966 70 - 130 EPA 2008 Mod AS
Chromium 057 40400 430l 106 70- 130 EPA 2008 Mod AS
Manganese 2805 40400 7042 105 70 - 130 EPA 2008 Mod AS
Iron ND 20200 2121 105 70 - 130 EPA 2008 Mod AS
Nickel 979 50500 5112 993 70 l30 EPA 2008 Mod AS
Copper 055 50500 4754 940 70 - 130 EPA 2008 Mod AS
Zinc 040 10100 9074 898 70 - 130 EPA 2008 Mod AS
Arsenic 1030 40400 4317 104 70 130 EPA 2008 Mod AS
Selenium 6340 40400 4688 100 70 - 130 EPA 2008 Mod AS
Molybdenum 1338 20200 338l 101 70 - 130 EPA 2008 Mod AS
Silver ND 20200 1850 916 70 130 EPA 2008 Mod AS
Cadmium 0332 40400 3937 966 70 130 EPA 2008 Mod AS
Antimony 0408 20200 2091 102 70 - 130 EPA 2008 Mod AS
Barium 2397 80800 1056 101 70- 130 EPA 2008 Mod AS
Lead ND IO100 9932 983 70 130 EPA 2008 Mod AS
shy
shy
shy
shy
shy
Analyte
Spike Added (microgL)
MSD Concentration
(microgL)
MSD
Recovery
RPD
Recovery Limits
RPDLimit Method Notes
Beryllium 20200 2007 968 l71 70 - 130 20 EPA 2008 Mod AS Sodium 40400 292600 837 0114 70 130 20 EPA 2008 Mod AS Aluminum 40400 3954 966 00362 70 - 130 20 EPA 2008 Mod AS Chromium 40400 4287 106 0337 70 - 130 20 EPA 2008 Mod AS Manganese 40400 6944 102 140 70 - 130 20 EPA 2008 Mod AS Iron 20200 2077 103 211 70 - 130 20 EPA 2008 Mod AS Nickel 50500 5126 996 0276 70 - 130 20 EPA 2008 Mod AS Copper 50500 4707 931 0997 70 - 130 20 EPA 200 8 Mod AS Zinc 10100 9059 896 0166 70 - 130 20 EPA 2008 Mod AS Arsenic 40400 4299 104 0419 70 - 130 20 EPA 2008 Mod AS Selenium 40400 4682 100 0141 70 - 130 20 EPA 2008 Mod AS Molybdenum 20200 3365 100 0473 70 - 130 20 EPA 2008 Mod AS
shy
port only apply to the sampltts analyzed in accordance with the cument This analytical report must be reproduced in its entirety
Page 5 o26 201073 Final Report 042512012 17
Liz Sia Project Manager
11720 North Creek Parkway North Suite 400 Botheln VA 98011
Ph 425-686-1996 Fx 425-686-3096
CLOBAL SCIENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1201073-01RE4
Batch F203271 Sequence 2c2io2~
Preparation Clo~ed Vessel litric Oven Digestion Lab Number F20327 l -MSMSQ4
Analyte
Spike Added (microgL)
MSD Concentration
(microgL)
MSD
Recovery
Oo
RPD Recovery
Limits RPOLimit Method Notes
Silver 20200 1895 938 242 70 - 130 20 EPA 2008 Mod AS Cadmium 40400 3933 965 0104 70 -130 20 EPA 2008 Mod AS Antimony 20200 2107 102 0736 70- 130 20 EPA 2008 Mod AS
Barium 80800 1058 101 0205 70 - 130 20 EPA 2008 Mod AS
Lead 10100 9877 978 0549 70 - 130 20 EPA 2008 Mod AS
Frontier Global Sciences Inc The results in this report only apply to the samples analyudin accordance with lht chain ofcustody document This analytical report must be reproductd rn ilS enlirtty
Page l6of26 1201073 Final Report Ofn5202 18
l I 720 North Creek Parkway North Suite 400 Bothell WA 980I I
Ph 425-686-1996 Fx 425-686-3096
GLO B AL SCIENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1201073-01RE6
Batch F203314 Sequence 2C25005
Preparation Closed Vessel Nitric Oven Digestion Lab Number F203314-MSMSD2
Sample Spike MS MS Concentration Added Concentration RecoveryAnalyte (microgL) (microgL) (microgL) Recovery Method NotesLimits
Thallium 5563 040400 5875 773 70 - 130 EPA 2008 Mod
Spike MSD MSD Added o Concentration Recovery RPD
RPO Limits Limit Method Notes Analyte (microgL) (microgL) Recovery
Thallium 040400 5880 785 00859 70 - 130 20 EPA 2008 Mod
Frontier Global Sciences Inc 11e results in chis reporc only apply 10 1he samples analyzed in accordance wilh lhe chain ofcustody documenz This analycical report musl be reproduced in ils entirety
Page 17 of26 1201073 Fi11aReport 0412512012
Liz Siska Project Manager
19
11720 North Creek Parkway North Suite 400 Bothell WA 98011
Ph 425-686-1996 Fx 425-686-3096
GLOBAl SCIENC ES
MATRIX SPIKE I MATRIX SPIKE DUPLICATE RECOVERY AND RPO
SOURCE I201073-01RE6
Batch F203314
Preparation Closed Vessel Nitric Oven Digestion
Sequence 2C25005
Lab Number F203314-MSMSD4
Analyte
Sample Concentration
(microgL)
Spike Added (microgL)
MS MS Concentration Oo
(microgL) Recovery Recovery
Limits Method Notes
Thallium 5563 10100 1033 968 70- 130 EPA 2008 Mod AS
Analyte
Spike Added (microgL)
MSD Concentration
(microgL)
MS)) Oo
Recovery
RPD
Recovery Limits
RPD Limit Method Notes
Thallium IO100 1037 97l 0341 70 - 130 20 EPA 2008 Mod AS
Frontier Global Sciences Inc The resulrs in this report only apply to the samples analyzed in accordance with the chain ofcusrody document This analytical report must be reproduced in its entirely
Page 18of26 120073 Final Report 04252012
Liz Siska Project Manager
20
11720 North Creek Parkway North Suite 400 l ~ Bothell WA 980 l l Ph 425-686-1996
FRONTIER Fx 425-686-3096 GLOBAL SCIENCES
LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLICATE
RECOVERY AND RPD
Batch F20 l063 Sequence 2A09010
Preparation BrCI Oxidation Lab Number F201063-BSIBSJ21
LCS Source N ist 1641d
Analyte
Spike Added (ngL)
LCS Concentration
(ngL)
LCS
Recovery Recovery
Limits Method Notes
Mercury 15679 1550 988 80 - 120 EPA I631E
Analyte
Spike Added (ngL)
LCSD Concentration
(ngL)
LCSD Oo
Recovery
RPD Recovery
Limits RPD Limit Method Notes
Mercury 15679 1595 [02 289 80 - 120 24 EPA I631E
Frontier Global Sciences Inc The results in this report only apply to the samples analyzedin accordance with the chain ofcustody document This analytical report must be reproduced in ils entirety
Page 19of26 1201073 Final Report 0425 2012
Liz Siska Project Manager
21
11720 North Creek Parkway North Suite 400 Bothell WA 98011
Ph 425-686-1996 FRONTIER Fx 425-686-3096 GLOBAL SCIENCES
LABORA TORY CONTROL SAMPLE LABO RATORY CONTROL SAMPLE DUPLICATE
RECOVERY AND RPD
Batch F203271 Sequence 2C22005
Preparation Closed Vessel Nitric Oven Digestion Lab Number F203271-BSBSD1
LCS Source Blank Spike
Spike LCS LCS Added Concentration Oo Recovery
Analyte (microgL) (microgL) Recovery Limits Method Notes
Beryllium 20000 l930 965 85 - 115 EPA 2008 Mod
Sodium 50000 499 998 85 - 115 EPA 2008 Mod
Aluminum 15000 1460 973 85 - 115 EPA 2008 Mod
Calcium 15000 1528 102 85 - 115 EPA 2008 Mod
Chromium 70000 657 939 85 - 115 EPA 2008 Mod
Manganese 60000 586 976 85 - 115 EPA 2008 Mod
Iron 50000 4753 951 85 shy 115 EPA 2008 Mod
Nickel 40000 401 100 85 - 115 EPA 2008 Mod
Copper 40000 418 105 85 - 115 EPA 2008 Mod
Zinc 10000 1033 103 85 - 115 EPA 2008 Mod
Arsenic 15000 1437 958 85 - 115 EPA 2008 Mod
Selenium 30000 2966 989 85 - 115 EPA 2008 Mod
Molybdenum 20000 181 905 85 shy 115 EPA 2008 Mod
Silver 15000 1517 101 85 shy 115 EPA 2008 Mod
Cadmium 080000 0781 976 85 - 1lS EPA 2008 Mod
Antimony 080000 0815 102 85 - 115 EPA 2008 Mod
Barium 10000 969 969 85 - 115 EPA 2008 Mod
Lead 15000 1597 106 85 - 115 EPA 2008 Mod
Spike LCSD LCSD Added Concentration Recovery RPO
Analyte (microgL) (microgL) Recovery RPO Limits Limit Method Notes
Beryllium 20000 1949 974 0955 85 - 115 20 EPA 2008 Mod
Sodium 50000 500 100 0216 85 - 115 20 EPA 2008 Mod
Aluminum 15000 1485 990 171 85 - 115 20 EPA 2008 Mod
Calcium 15000 1544 103 103 85 - 115 20 EPA 2008 Mod
Chromium 70000 667 953 148 85 - 115 20 EPA 2008 Mod
Manganese 60000 596 994 175 85 - 115 20 EPA 2008 Mod
Iron 50000 4852 970 206 85 - 115 20 EPA 2008 Mod
Nickel 40000 402 IOI 0246 85 - 115 20 EPA 2008 Mod
Frontier Global Sciences Inc The results in his report only apply to the samples analyzed in accordance wirh the chain ofcustody document This analytical report must be reproduced in iLS entirety
Page 20of26 1201073 Final Report 04252012
Liz Siska Project Manager
22
11720 North Creek Parkway North Suite 400 ~~shy Bothell WA 98011 Ph 425-686-1996~ONTif Fx 425-686-3096
GLOBAL SCIENCES
LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLICATE
RECOVERY AND RPO
Batch F20327 l Sequence 2C22005
Preparation Closed Vessel Nitric Oven Digestion Lab Number F203271-BSBSD 1
LCS Source Blank Spike
Analyte
Spike Added (microgL)
LCSD Concentration
(microgL)
LCSD oo
Recovery
RPO Recovery
Limits RPO Limit Method Notes
Copper
Zinc
Arsenic
Selenium
40000
10000
15000
30000
428
1039
1452
3015
107
104
968
101
224
0570
0977
166
85 - 115
85 - 115
85 - 115
85 - 115
20
20
20
20
EPA 2008 Mod
EPA 2008 Mod
EPA 2008 Mod
EPA 2008 Mod Molybdenum
Silver
20000
15000
182
J502
910
100
0564
103
85 - 115
85 - 115
20
20
EPA 2008 Mod
EPA 2008 Mod Cadmium
Antimony
Barium
Lead
080000
080000
10000
15000
0828
0808
986
1620
103
101
986
108
585
0848
177
142
85 - 115
85 - 115
85 shy 11 S
85 - 115
20
20
20
20
EPA 2008 Mod
EPA 2008 Mod
EPA 2008 Mod
EPA 2008 Mod
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report mus be reproducedin its entirety
Page 2 o26J20J073 Final Report 041252012
Liz Siska Project Manager
23
11720 North Creek Parkway North Suite 400 Bothell WA 980 l l
Ph 425-686-1996FRONT[ER- Fx 425-686-3096 cLosAL SCIEN _CES
LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLICATE
RECOVERY AND RPD
Batch F203314 Sequence 2C25005
Preparation Closed Vessel Nitric Oven Digestion Lab Number F2033 l 4-BSBSD 1
LCS Source Blank Spike
Analyte
Thallium
Spike Added (microgL)
LCS Concentration
(microgL)
LCS 0o
Recovery Recovery
Limits Method
040000 0396 989 85 - 115 EPA 2008 Mod
Notes
Analyte
Spike Added (microgL)
LCSD Concentration
(microgL)
LCSD 0o
Recovery
RPD Recovery
Limits RPO Limit Method Notes
Thallium 040000 0391 978 112 85 - ll5 20 EPA 2008 Mod
Frontier Global Sciences Inc The results in this report only apply to the samples anayed in accordance with the chain ofcustody docwnenJ This analytical report must be reproduced in its entirety
Page 22of26 1201073 Final Report 04252012
Liz Siska Project Manager
24
Liz Siska P roject Manager
11720 North Creek Parkway North Suite 400
~ Bothell WA 98011 Ph 425-686-1996
~JTIEif middot Fx 425-686-3096 GLOBAL SCIENCES
PREPARATION BLANKS
Instrument Hg-17 Sequence 2A09010
Preparation BrCI Oxidation
Lab Sample ID Analyte Found MRL Units Batch Method Notes
F201063-BLK I Mercury -0009 050 ngL F201063 EPA 1631E u F20 I063-BLK2 Mercury -0006 050 ngL F201063 EPA 1631E u F201063-BLK3 Mercury -002 050 ngL F201063 EPA 163IE u F201063-BLK4 Mercury 003 050 ngL F201063 EPA 1631E U QB-04 F201063-BLKS Mercury 011 052 ngL F201063 EPA I631E U QB-06
Frontier Global Sciences Inc The results in this report only apply 10 1he samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Page 23 o26 1201073 Final Repon 04252012 25
Liz Siska Project Manager
11720 North Creek Parkway North Suite 400 Bothell WA 98011
Ph 425-686-1996 FROr~TIER- Fx 425-686-3096 GLOBAL SCIENCES
PREPARATION BLANKS
Instrument ICPMS-6 Sequence 2C22005
Preparation Closed Vessel Nitric Oven Digestion
Lab Sample ID Analyte Found MRL Units Batch Method Notes
F203271-BLK1 Beryllium 000008 0060 microgL F203271 PA 2008 Molt u F20327 1-BLK1 Sodium 2 20 microgL F20327l PA 2008 Moc u F20327I-BLK1 Aluminum -004 40 microgL F203271 PA 2008 Molt u F20327I -BLK1 Calcium 40 microgL F203271 PA 2008 Molt u F203271 -BLK1 Chromium -002 010 microgL F203271 ~A 2008 Molt u F203271-BLKI Manganese 001 010 microgL F203271 PA 2008 Molt u F20327 l -BLK 1 Iron -002 100 microgL F203271 PA 2008 Molt u F203271-BLKI Nickel 0004 010 microgL F203271 PA 2008 Moc u F203271-BLK1 Copper 0003 010 microgL F203271 PA 2008 Moc u F203271-BLK1 Zinc 0007 020 microgL F203271 PA 2008 Moc u F203271-BLK1 Arsenic -006 015 microgL F203271 PA 2008 Moc u F203271-BLK1 Selenium -002 060 microgL F203271 PA 2008 Moc u F203271-BLK1 Molybdenum 001 006 microgL F203271 PA 2008 Molt u F203271-BLK1 Silver -00005 0020 microgL F203271 PA 2008 Molt u F203271-BLKl Cadmium 0004 0020 microgL F203271 PA 2008 Molt u F20327 l-BLKl Antimony 0002 0020 microgL F203271 PA 2008 Molt u F203271-BLKI Barium 001 020 microgL F203271 PA 2008 Molt u F203271-BLKI Lead 0010 0040 microgL F203271 PA 2008 Moc u
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Page 24of26 1201073 Final Report 04252012 26
~
~TIER~ GLOBAL SCIENCES
11720 North Creek Parkway North Suite 400 Bothell WA 980ll
Ph 425-686-1996 Fx 425-686-3096
PREPARATION BLANKS
Instrument JCPMS-3 Sequence 2C25005
Preparation Closed Vessel Nitric Oven Digestion
Lab Sample ID Analyte Found MRL Units Batch Method Notes
F2033I4-BLK1 Thalium 00007 0010 microgL F2033I4 ~PA 2008 Molt u
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Page 25 o26Liz Siska Project Manager 1201073 Final Report
04252012 27
l l 720 North Creek Parkway North Suite 400~Vi-~ Bothell WA 98011 Ph 425-686-1 996~Tlmiddot~ Fx 425-686-3096
G L OBAL SCIENCE S
Notes and Definitions
U Analyte included in the analysis but not detected
QM-02 The MS andor MSD recoveries outside acceptance limits due to spike concentration less than I times the sample concentration The batch was accepted based on LCS and LCSD recoveries within control limits and when analysis permits acceptable AS ASD
QB-06 The blank was preserved to 5 BrCI rather than I The control limit for blanks preserved to greater than 1 BrCl is the preservation percentage multiplied by the MRL
QB-04 The blank was preserved to 2 BrCI rather than l The control limit for blanks preserved to greater than l BrCI is the preservation percentage multiplied by the MRL
FB-1631 Required equipmentfieldfilter blank not submitted by the client The sample has been analyzed according to 163 lE but does not meet 163 lE criteria
AS This MS andor MSD is an analytical spike andor an analytical spike duplicate
DET Analyte Detected
MDL Minimum Detection Limit
MRL Minimum Reporting Limit
ND Analyte Not Detected at or above the reporting limit
wet Sample results reported on a wet weight basis
dry Sample results reported on a dry weight basis
RPO Relative Percent Difference
RSD Relative Standard Deviation
Frontier Global Sciences Inc The lesults i111his reporl only apply to he samples analyzed In accordance with the chain ofcuslody document This analytical report must be reproduced in its entirely
Page 26of26 1201073 Final Report 04252012
Liz Siska Project Manager
28
CHAIN-OF-(USTODY ttECORD Page i of f 106677 _J
BoLD F1ELDS REQUIRED PLEASE C 1RCLE REQUESTED ANALYSIS
SAMPLE ID
middoti-rg -- bull ~rshy~ _- tzir +- lt-ltJ~ lt
SAMPLING
DATeTtME
IF COMPOSITE INDICATE BOTH
START amp FINISH
DATETIME li1J oc -r 111_- _vlt-c_
w Ishyt 0 n
w l w 0 ~ u X -Xmiddot ~ m Ishy lt( lt( 0
I C)
IIXJ JC
~ ~ irlte-t- T_ t- f r-n t I s-11 middott~ c~ J J1~w )(~ )
Trttbull rin K C-~-~ pound1t I 1Jtl~ t20~L lwlJI ishy
middot~ON Mm1x A-Al~ S-SOil GW-GampOUHO WATER SW-SUampfA(f WATER DWmiddotDRIIIKIKlti WATER
Itlt
-glo c ~
c t I O
~ t = ~ ~
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107555
i
~ I NOTES MEOH VIAL
1 WW-WASTE WATER PmmATIVE H-HCL H-HN01 S-H1SO Na-NaOH H-HEOH -~ --~
PROJECT MANAGER llr middot1 ~Q Aw4---P1V- Het_ r COMPANY t-lo--tm ~ bd i ( I ~j 6 A ADP~SS 91 g~ez tJshy(ITJ ~ STATE fH_ ZIP c3o--
PHONE 22j-((omiddotf EXT ____
fAX--------------------- shyE-MAIL (JbHd-esa e n ta wamp Sm NAME Meccft1lt-1ltk f--g
PROJECT _
OTHEi________STATpound NH MA ME VT
REGULATORY PROGRAM NPDES RGP POTW STORHWATEl OR
GWP OIL FUHD BROWNIIELO OR OTHER----------
Quon PO o2J~-lt1Jpound)
DATE NEEDED _1--1 middot Z=-----shy4 (1-1_ METALS 8 RCRA 13 pp ff MN PB Cu
QAQC REPORTJNGYVEL
A CG) O R
PRESUMPTIVE CERTAINTY
7i2lt_
RECpound1VEO BYRELINQUISHED BY DATE TIME SUSPECTED (OHTAHIHATIOH________
TEHP~ C REPORTING OPTIONS 01HEA METAL------------PRELIHl Yu OR No
DISSOLVED METALS FIELD FllTEREDI YES 110
rmreg No
IF YH FAX OR POf 7~shy Hom (IE SPECIAL DETECTION LINITl BllLIKGINfO If DlffERrnT)ELECTRONIC OPTIONS zo 1 2 2) le~C1 1 Jc Id sJ 60 6c
1 cf Co
lo FAX pound-MAIL PDF EQUll C jCi (e I rt--111 Ao NiAJrJe middotn th
Ka)Jcr(c C(cdd -ltJ c -l -gtck- z Alt 5e1 Hj
Al l 4_) it fG) 1uJ c(iJoclt-U Sin HISTORY 0Se-d Cim- ~pound rc~L IH t--6
1 r
ImiddotRELINQUISHED BY DATE TIHE RECflVEO BY I FIELD READINGS
eastern analytical inc 2s CHENELL D R1ve IC 0 Nco1to N H 0330 1 I TEL 60J22aos2s 1aoo2a1os2s IFAx 6032284591 j E-MA1t cus-roM111_mV1c~EAILAsscoMJ www1A1LAascoM
----i pmiddotofissionrrl11bomtorymim (WHITE ORIGINAL GREEN PROJECT MANAGER)
shy
----1~J___________e_a_~_t_~-~-~--~-~-~-bullv_t_i_~-~-bull-__
Paul Pepler
GZA GeoEnvironmental Inc (NH)
380 Harvey Road
Manchester NH 03103
Subject Laboratory Report
Eastern Analytical Inc ID 107555 Client Identification Merrimack Station
Date Received 152012
Dear Mr Pepler
Enclosed please find the report of analysis for the above identified project As discussed analyses were subcontracted and are listed as follows
Analysis Subcontract - Metals Method 2008 (AlSbBaBeCdCaCrCuFePbMnMoNaNiAgTlZnAsSe amp Hg)
Subcontractor Lab Frontier Global Sciences Inc
A complete copy of the report is attached This report may not be reproduced except in full without the written approval of the laboratory
We appreciate this opportunity to be of service and look forward to your continued patronage
Sincerely
Lorraine Olashaw Lab Direc r Date of pages (excluding cover letter)
Wmiddottaihb ~Clt l111 I
SAMPLE CONDITIONS PAGE EAi ID 107555
Client GZA GeoEnvironmental Inc (NH)
Client Designation Merrimack Station
Temperature upon receipt (degC) Acceptable temperature range (0 C) 0-6
Lab ID Sample ID
47
Date Received Sampled
Date
Received on ice or cold packs (YesNo)
Sample Ory Matrix Weight ExceptionsComments (other than
y
thermal preservation)
10755501 Treat Tank Eff Composite 115112 1512 aqueous Adheres to Sample Acceptance Policy
10755502 Treat Tank Eff Grab 11512 15112 aqueous Adheres to Sample Acceptance Policy
Samples were properly preserved and the pH measured when applicable unless otherwise noted Analysis of solids for pH Flashpoint lgnitibility Paint Filter Corrosivity Conductivity and Specific Gravity are reported on an as received basis All results contained in this report relate only to the above listed samples
References include 1) EPA 6004-79-020 1983 2) Standard Methods for Examination of Water and Wastewater lnorganics 19th Edition 1995 Microbiology 20th Edition 1998 3) Test Methods for Evaluating Solid Waste SW 846 3rd Edition including updates VA and VB 4) Hach Water Analysis Handbook 2nd edition 1992
eastern analytical inc wwweailabscom Phone (603) 228-0525 1
l l 720 North Creek Parkway North Suite 400 Bothell WA 98011
Ph 425-686-1996 Fx 425-686-3096 G L OBAL SCIENCES
25 April 2012
JeffGagne
Eastern Analytical Inc
25 Chenell Drive
Concord NH 0330 I
RE Merrimack Station
Enclosed are the analytical results for samples received by Frontier Global Sciences All quality control
measurements are within established control limits and there were no analytical difficulties encountered with the exception of those listed in the case narrative section of this report
If you have any questions concerning this report please feel free to contact me
Sincerely
Liz Siska
Project Manager
2
GLOBAL SCIENCES
11720 North Creek Parkway North Suite 400 Bothell WA 98011
Ph 425-686-1996 Fx 425-686-3096
ANALYTICAL REPORT FOR SAMPLES
Laboratory Frontier Global Sciences Inc SDG
Client Eastern Analytical Inc Project Merrimack Station
Sample ID Lab ID Matrix Date Sampled Date Received
Treat Tank EffComposite 1201073-01 Water 05-Jan-12 1000 06-Jan-12 0950
Treat Tank EffGrab 1201073-02 Water 05-Jan-12 0800 06-Jan-12 0950
Frontier Global Sciences Inc
Liz Siska Project Manager
The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Page 1 o261201073 Final Report 04252012 3
11720 North Creek Parkway North Suite 400 Bothell WA 98011
Ph 425-686-1996FRONTIER Fx 425-686-3096 GLOBAL SCIENCES
CASE NARRATIVE
Revised Report 42512
Per client request Boron was removed from report
Revised Report 32812
Per client request samples were prepared and analyzed for total metals in accordance with EPA 2008 (modified)
SAMPLE RECEIPT
Samples were received at Frontier Global Sciences (FGS) on January 6th 2012 The samples were received intact on-ice with temperatures measured at 34 degrees Celsius
SAMPLE PREPARATION AND ANAL YSJS
Samples were prepared and analyzed for total metals in accordance with FGS-054EPA 1638
Samples were prepared and analyzed for total mercury in accordance with EPA Method 163JE
ANALYTICAL AND QUALITY CONTROL IS SUES
There were no analytical difficulties experienced with analysis of these samples with the exceptions flagged in the report
Frontier Gtobal Sciences Inc The results in this reporr only apply 10 the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Liz Siska Project Manager Page 2of26 J20I073 Final Report 042512012 4
11720 North Creek Parkway North Suite 400 Bothell WA 98011~ Ph 425-686-1996 FRONTIER Fx 425-686-3096
GLOBAL SCIENCES
CHAIN OF CUSTODY FORMS
CML-1d Cc-t~lt7 shy~P~fci amp l sbtr3~~ry Aillylc P~ctirst J- ~V~-=lt S=-Jit=~1t Imiddot~ and 4J~~ Tssul
~ r~middotmiddotmiddot to ~-~ middot ~ ~middot ~rcshyr-11 ---4i--5~1-shy
y1tcirc1middot 6middot 01gter S1bulli1e
1 1 -middot shy
~middot-middotn middot~i---it =-middotmiddotrmiddot~-~r9ft~ri r s L lrj~JT ~- bull 1r bullermiddot~~(~lr- rlt-bull~~~~~ _ -tbull ~t-tmiddotbull I~ bull 1
middot middot l~~e ~middot rv~ 8Arvmiddott _ -middot
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report mus be reproduced in ilS entirety
Page3of26Liz Siska Project Manager 1201073 Final Report
041252012 5
Liz Siska Project Manager
11720 North Creek Parkway North Suite 400 Bothell WA 98011
Ph 425-686- 1996 ~ Fx 425-686-3096 G LOB A L SC I EN CE S
ANALYTICAL RESULTS
Treat Tank Eff Composite
Matrix Water Laboratory ID 1201073-01
Analyte Result MDL MRL Units Dilution Batch Sequence Analyzed Method Notes
Aluminum ND 89 800 microgL 20 F203271 2C22005 032212 EPA 2008 Mod u Antimony 0408 0092 0400 microgL 20 F20327l 2C22005 032212 EPA 2008 Mod Barium 240 054 400 microgL 20 F203271 2C22005 032212 EPA 2008 Mod Beryllium ND 0454 t20 microgL 20 F203271 2C22005 032212 EPA 2008 Mod u Cadmium ND 0083 0400 microgL 20 F203271 2C22005 032212 EPA 2008 Mod u Calcium 5010000 16200 200000 microgL 5000 F203271 2C22005 032212 EPA 2008 Mod Chromium ND 018 200 microgL 20 F20327I 2C22005 032212 EPA 2008 Mod u Copper ND 020 200 microgL 20 F203271 2C22005 032212 EPA 2008 Mod u Iron ND 260 200 microgL 20 F20327l 2C22005 032212 EPA 2008 Mod u Lead ND 0078 0800 microgL 20 F20327l 2C22005 032212 EPA 2008 Mod u Manganese 280 015 200 microgL 20 F203271 2C22005 032212 EPA 2008 Mod Molybdenum 134 012 120 microgL 20 F20327I 2C22005 032212 EPA 2008 Mod Nickel 979 016 2 00 microgL 20 F203271 2C22005 032212 EPA 2008 Mod Silver ND 0120 0400 microgL 20 F203271 2C22005 032212 EPA 2008 Mod u Sodium 259000 23 400 microgL 20 F203271 2C22005 032212 EPA 2008 Mod Thallium 556 0250 100 microgL 100 F203314 2C25005 032512 EPA 2008 Mod Zinc ND 033 400 microgL 20 F203271 2C22005 032212 EPA 2008 Mod u
Frontier Global Sciences Inc The middotesults in 1his report only apply to the samples analyzed in accordance wilh 11e chain ofcus1ody documem This analytical report must be reproduced in ifs entirety
Page 4of26 1201073 Final Report 04252012 6
Liz Siska Project Manager
11720 North Creek Parkway North Suite 400 Bothell WA 98011
Ph 425-686-1996 Fx 425-686-3096
GLOBAt SCIENCES
ANALYTICAL RESULTS
Treat Tank Eff Grab
Matrix Water Laboratory ID 1201073-02
Analyte Result MDL MRL Units Dilution Batch Sequence Analyzed Method Notes
Arsenic 851 102 300 microgL 20 F203271 2C22005 032212 EPA 2008 Mod Mercury 105 034 202 ngL 4 F20I063 2A09010 010912 EPA 1631E FB-1631 Selenium 689 388 120 microgL 20 F203271 2C22005 032212 EPA 2008 Mod
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcustody documenJ This analycical report must be reproduced in its entirety
Page 5 o261201073 Final Report 04252012 7
Liz Siska Project Manager
FRONTIERshycLoaAt SCI ENCES
11720 North Creek Parkway North Suite 400 Bothell WA 98011
Ph 425-686-1996 Fx 425-686-3096
MATRIX DUPLICATESfRIPLICATES
SOURCE 1201073-02
Batch F201063
Preparation BrCI Oxidation
Sequence 2A09010
Lab Number F201063-DUPI
Sample Duplicate Concentration Concentration RPD
Analyte ngL ngL MRL RPD Limit Method Notes Mercury 1048 1054 202 0617 24 EPA I631E
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Page 6of26 1201073 Final Report 04252012 8
11720 North Creek Parkway North Suite 400 BotheE WA 980 l l
Ph 425-686-1996 Fx 425-686-3096
GLOBAL SCIENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1201073-02
Batch F201063 Sequence 2A09010
Preparation BrCI Oxidation Lab Number F20 l 063-MSMSDl
Sample Spike MS MS Concentration Added Concentration RecoveryAnalyte (ngL) (ngL) (ngL) Recovery Method Limits Notes
Mercury 1048 20400 3136 102 71 125 EPA 163IE
Spike MSD MSD Added Concentration oo Recovery RPD
RPD Limits Limit Method Notes Analyte (ngL) (ngL) Recovery
Mercury 20400 2708 814 147 71 - 125 24 EPA 1631E
shy
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Page 7 o26Liz Siska Project Manager 120JO7 3 Final Repo1
04252012 9
Liz Siska Project Manager
11720 North Creek Parkway North Suite 400 Bothell WA 98011
Ph 425-686-1996~ Fx 425-686-3096 CL06AL SCIENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1112278-02
Batch F201063 Sequence 2A09010
Preparation BrCI Oxidation Lab Number F20 l 063-MSMSD2
Sample Spike MS MS
Analyte Concentration
(ogL) Added (ngL)
Concentration (ngL)
Recovery
RecoveryLimits Method Notes
Mercury 761 20400 2786 992 71 125 EPA 1631E
Spike MSD MSD Added Concentration Oo Recovery RPO
Analyte (ngL) (ngL) Recovery RPO Limits Limit Method Notes
Mercury 20400 2837 102 182 71 - 125 24 EPA l631E
shy
Frontier Global Sciences Inc The results in this report only apply to the somples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Page 8 o26 1201073 Final Report 042512012 10
11720 North Creek Parkway North Suite 400 Bothell WA 980 l l
Ph 425-686-1996 ~ Fx 425-686-3096 GLOBAL SCIENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1201029-01
Batch
Preparation
F201063
BrCI Oxidation
Sequence
Lab Number
2A09010
F20 I 063-MSMSD3
Analyte
Mercury
Analyte
Mercury
Sample Spike Concentration Added
(ngL) (ngL)
534 10200
Spike MSD Added Concentration (ngL) (ngL)
10200 1407
MS MS Concentration Recovery
(ngL) Recovery Limits
1558 JOO 7l shy 125
MSD oo Recovery RPD
Recovery RPD Limits Limit
856 102 71 - 125 24
Method
EPA l63lE
Method
EPA 631E
Notes
Notes
Frontier Global Sciences Inc The results in this repon only apply to rhe samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Page 9of26 1201073 Final Report 041252012
Liz Siska Project Manager
1 1
11720 North Creek Parkway North Suite 400 Bothell WA 98011
Ph 425-686-1996 FRONTIER- Fx 425-686-3096 cLosAL SCIENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1201030-02
Batch F20I063 Sequence 2A09010
Preparation BrCI Oxidation Lab Number F201063-MSMSD4
Sample Spike MS MS Concentration Added Concentration RecoveryAnalyte (ngL) (ngL) (ngL) Recovery MethodLimits Notes
Mercury 554 10200 1482 910 71 - 125 EPA I631E
Spike MSD MSD Oo Added Concentratio11 Recovery RPD
RPD Limits Limit Method Analyte (ngL) (ngL) Recovery Notes
Mercury 10200 1461 890 140 71 - 125 24 EPA 163IE
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed m accordance with the chain ofcus1ody document This anayt(ca repon must be reproduced in itr entirety
Page lOo26Liz Siska Project Manager 1201073 Final Report
041252012 12
I 1720 North Creek Parkway North Suite 400 Bothe I I WA 98011
Ph 425-686-1996 ~ Fx 425-686-3096 GLOBAL SCIENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1201073-01RE3
Batch F20327l Sequence 2C22005
Prcpa ration ((01ed Vessel ~ itric Oven Digestion Lab Number F203271-MSMSD 1
Analyte
Sample Concentration
(microgL)
Spike Added (microgL)
MS Concentration
(microgL)
MS Oo
Recovery Recovery
Method Limits Notes
Calcium 5013000 15150 4802000 -13900 70- 130 EPA 2008 Mod QM-02
Analyte
Spike Added (microgL)
MSD Concentration
(microgL)
MSD ~o
Recovery
Oo
RPD Recovery
Limits RPDLimit Method Notes
Calcium 15150 4943000 -4600 289 70 - 130 20 EPA 2008 Mod QM-02
Frontier Global Sciences Inc The results in this report only apply to the samples analyud inaccordance with the chain ofcustody document 17is analyticol report must be reproduced in its entirety
Page lI o16 1101073 Final Report 04152012
Liz Siska Project Manager
13
l l 720 North Creek Parkway North Suite 400 Bothell WA 98011
Ph 425-686-1996FRONTIER Fx 425-686-3096 GLOBAL SCIENCES
MATRIX SPIKE I MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1201073-01RE4
Batch F203271 Sequence 2C22005
Preparation Closed Vessel Nitric Oven Digestion Lab Number F203271-MSMSD2
Sample Spike MS MS Concentration Added Concentration Oo RecoveryAnalyte (microgL) (microgL) (microgL) Recovery Method Limits Notes
Beryllium 0507 20200 2442 958 70 - 130 EPA 2008 Mod Sodium 258800 50500 257700 -213 70 -130 EPA 2008 Mod QM-02 Aluminum 529 15150 2023 986 70 - 130 EPA 2008 Mod Chromium 057 70700 804 106 70 - 130 EPA 2008 Mod Manganese 2805 60600 2834 476 70 - 130 EPA 2008 Mod QM-02 Iron ND 50500 5200 103 70 130 EPA 2008 Mod Nickel 979 40400 141 l 107 70- 130 EPA 2008 Mod Copper 055 40400 434 939 70 - 130 EPA 2008 Mod Zinc 040 10100 842 794 70 - 130 EPA 2008 Mod Arsenic 1030 15150 2418 916 70 - 130 EPA 2008 Mod Selenium 6340 30300 8973 869 70 130 EPA 2008 Mod Molybdenum 1338 20200 1367 142 70 130 EPA 2008 Mod QM-02 Silver ND 15150 1388 916 70 - 130 EPA 2008 Mod Cadmium 0332 080800 1105 middot956 70 - 130 EPA 2008 Mod Antimony 0408 080800 1259 105 70- 130 EPA 2008 Mod Barium 2397 10100 2495 968 70 - 130 EPA 2008 Mod Lead ND 15150 1542 102 70 130 EPA 2008 Mod
shy
shy
shy
shy
Analyte
Spike Added (microgL)
MSD Concentration
(microgL)
MSD Oo
Recovery
Oo
RPD Recovery
Limits RPD Limit Method Notes
Beryllium
Sodium
Aluminum
Chromium
Manganese
Iron
Nickel
Copper
Zinc
Arsenic
Selenium
Molybdenum
20200
50500
15150
7Q700
60600
50500
40400
40400
10100
15150
30300
20200
2561
257100
2034
773
2852
5187
1381
419
916
2225
9400
1366
102
-336
993
101 769
103
995
902
868
789
101
137
474
0243
0564
385
0625
0242
213
347
849
831
464
00771
70 - 130
70 bull 130 70 - 130
70 - 130
70 - 130
70 - 130
70 - 130
70 - 130
70 - 130
70 bull 130 70 - 130
70 - 130
20
20
20
20
20
20
20
20
20
20
20
20
EPA 2008 Mod
EPA 2008 Mod
EPA 2008 Mod
EPA 2008 Mod
EPA 2008 Mod
EPA 2008 Mod
EPA 2008 Mod
EPA 2008 Mod
EPA 2008 Mod
EPA 2008 Mod
EPA 2008 Mod
EPA 2008 Mod
QM-02
QM-02
Frontier G lobal Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
--f_~ --~~~-~ -middot middot Page 12 o261201073 Final Report 041252012
Liz Siska Project Manager
14
11720 North Creek Parkway North Suite 400
~ Bothell WA 98011
~TIEmiddot Ph 425-686-1996 Fx 425-686-3096
GLOB11L SCIENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPO
SOURCE 1201073-01RE4
Batch F203271 Sequence 2C22005
Preparation ~lo~ed Vessel Nitric Oven Digestion Lab Number F20327 I-MSMSD2
Spike MSD MSD Added Concentration Oo Recovery RPO
Analyte (microgL) (microgL) Recovery RPD Limits Limit Method Notes
Silver 15150 1387 915 00874 70 - 130 20 EPA 2008 Mod Cadmium 080800 1061 902 403 70 - 130 20 EPA 200amp Mod Antimony 080800 1274 107 l2l 70 - 130 20 EPA 2008 Mod Barium 10100 2514 )16 0781 70 - 130 20 EPA 200amp Mod Lead 15150 1534 101 0525 70 shy 130 20 EPA 2008 Mod
Frontier Global Sciences Inc The results in this report only apply to 1he samples analyzed in accordance wiih the chain ofcustody document This analytical repo1 must be reproduced in ils entirety
Page 13 o26Liz Siska Project Manager 1201073 Final Reporl
04252012 15
11720 North Creek Parkway North Suite 400
~ Bothell WA 98011 Ph 425-686-I996
~RONTIER~ Fx 425-686-3096 GLOBAL SCIEN C ES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1201073-01RE3
Batch F203271 Sequence 2~22005
Preparation Closed Vessel Nitric Oven Digestion Lab Number F20327 I-MSMSD3
Sample Spike MS MS
Analyte Concentration
(microgL) Added (microgL)
Concentration (microgL) Recovery
Recovery Limits Method Notes
Calcium 5013000 10100000 15120000 100 70- 130 EPA 2008 Mod AS
Spike MSD MSD Added Concentration o Oo Recovery RPD
Analyte (microgL) (microgL) Recovery RPD Limits Limit Method Notes
Calcium 10100000 16140000 llO 653 70 - 130 20 EPA 2008 Mod AS
Frontier Global Sciences Inc The results in his report only apply 10 the samples analyzed in accordance ivth he chain ofcustody document This analytical report must be reproduced in its entirety
Page 14 o261201073 Final Report 0425201]
Liz Siska Project Manager
16
Frontier Global Sciences Inc The ruults in this rechain ofcustody do
~ -lt1-c--~ Liz Siska Project Manager
11720 North Creek Parkway North Suite 400 Bothell WA 98011
Ph 425-686-1996 Fx 425-686-3096
GLOBAL SCIENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1201073-01RE4
Batch J203271 Sequence 2C22005
Preparation ~ IQsed Ve~~el Nitric Oven Qigestion Lab Number F203271-MSMSQ4
Analyte
Beryllium
Sample Concentration
(11gL)
0507
Spike Added (11gL)
20200
MS Concentration
(microgL)
2041
MS Oo
Recovery
985
RecoveryMethod Limits
70 - 130 EPA 2008 Mod
Notes
AS
Sodium 258800 40400 292900 845 70- 130 EPA 2008 Mod AS
Aluminum 529 40400 3956 966 70 - 130 EPA 2008 Mod AS
Chromium 057 40400 430l 106 70- 130 EPA 2008 Mod AS
Manganese 2805 40400 7042 105 70 - 130 EPA 2008 Mod AS
Iron ND 20200 2121 105 70 - 130 EPA 2008 Mod AS
Nickel 979 50500 5112 993 70 l30 EPA 2008 Mod AS
Copper 055 50500 4754 940 70 - 130 EPA 2008 Mod AS
Zinc 040 10100 9074 898 70 - 130 EPA 2008 Mod AS
Arsenic 1030 40400 4317 104 70 130 EPA 2008 Mod AS
Selenium 6340 40400 4688 100 70 - 130 EPA 2008 Mod AS
Molybdenum 1338 20200 338l 101 70 - 130 EPA 2008 Mod AS
Silver ND 20200 1850 916 70 130 EPA 2008 Mod AS
Cadmium 0332 40400 3937 966 70 130 EPA 2008 Mod AS
Antimony 0408 20200 2091 102 70 - 130 EPA 2008 Mod AS
Barium 2397 80800 1056 101 70- 130 EPA 2008 Mod AS
Lead ND IO100 9932 983 70 130 EPA 2008 Mod AS
shy
shy
shy
shy
shy
Analyte
Spike Added (microgL)
MSD Concentration
(microgL)
MSD
Recovery
RPD
Recovery Limits
RPDLimit Method Notes
Beryllium 20200 2007 968 l71 70 - 130 20 EPA 2008 Mod AS Sodium 40400 292600 837 0114 70 130 20 EPA 2008 Mod AS Aluminum 40400 3954 966 00362 70 - 130 20 EPA 2008 Mod AS Chromium 40400 4287 106 0337 70 - 130 20 EPA 2008 Mod AS Manganese 40400 6944 102 140 70 - 130 20 EPA 2008 Mod AS Iron 20200 2077 103 211 70 - 130 20 EPA 2008 Mod AS Nickel 50500 5126 996 0276 70 - 130 20 EPA 2008 Mod AS Copper 50500 4707 931 0997 70 - 130 20 EPA 200 8 Mod AS Zinc 10100 9059 896 0166 70 - 130 20 EPA 2008 Mod AS Arsenic 40400 4299 104 0419 70 - 130 20 EPA 2008 Mod AS Selenium 40400 4682 100 0141 70 - 130 20 EPA 2008 Mod AS Molybdenum 20200 3365 100 0473 70 - 130 20 EPA 2008 Mod AS
shy
port only apply to the sampltts analyzed in accordance with the cument This analytical report must be reproduced in its entirety
Page 5 o26 201073 Final Report 042512012 17
Liz Sia Project Manager
11720 North Creek Parkway North Suite 400 Botheln VA 98011
Ph 425-686-1996 Fx 425-686-3096
CLOBAL SCIENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1201073-01RE4
Batch F203271 Sequence 2c2io2~
Preparation Clo~ed Vessel litric Oven Digestion Lab Number F20327 l -MSMSQ4
Analyte
Spike Added (microgL)
MSD Concentration
(microgL)
MSD
Recovery
Oo
RPD Recovery
Limits RPOLimit Method Notes
Silver 20200 1895 938 242 70 - 130 20 EPA 2008 Mod AS Cadmium 40400 3933 965 0104 70 -130 20 EPA 2008 Mod AS Antimony 20200 2107 102 0736 70- 130 20 EPA 2008 Mod AS
Barium 80800 1058 101 0205 70 - 130 20 EPA 2008 Mod AS
Lead 10100 9877 978 0549 70 - 130 20 EPA 2008 Mod AS
Frontier Global Sciences Inc The results in this report only apply to the samples analyudin accordance with lht chain ofcustody document This analytical report must be reproductd rn ilS enlirtty
Page l6of26 1201073 Final Report Ofn5202 18
l I 720 North Creek Parkway North Suite 400 Bothell WA 980I I
Ph 425-686-1996 Fx 425-686-3096
GLO B AL SCIENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1201073-01RE6
Batch F203314 Sequence 2C25005
Preparation Closed Vessel Nitric Oven Digestion Lab Number F203314-MSMSD2
Sample Spike MS MS Concentration Added Concentration RecoveryAnalyte (microgL) (microgL) (microgL) Recovery Method NotesLimits
Thallium 5563 040400 5875 773 70 - 130 EPA 2008 Mod
Spike MSD MSD Added o Concentration Recovery RPD
RPO Limits Limit Method Notes Analyte (microgL) (microgL) Recovery
Thallium 040400 5880 785 00859 70 - 130 20 EPA 2008 Mod
Frontier Global Sciences Inc 11e results in chis reporc only apply 10 1he samples analyzed in accordance wilh lhe chain ofcustody documenz This analycical report musl be reproduced in ils entirety
Page 17 of26 1201073 Fi11aReport 0412512012
Liz Siska Project Manager
19
11720 North Creek Parkway North Suite 400 Bothell WA 98011
Ph 425-686-1996 Fx 425-686-3096
GLOBAl SCIENC ES
MATRIX SPIKE I MATRIX SPIKE DUPLICATE RECOVERY AND RPO
SOURCE I201073-01RE6
Batch F203314
Preparation Closed Vessel Nitric Oven Digestion
Sequence 2C25005
Lab Number F203314-MSMSD4
Analyte
Sample Concentration
(microgL)
Spike Added (microgL)
MS MS Concentration Oo
(microgL) Recovery Recovery
Limits Method Notes
Thallium 5563 10100 1033 968 70- 130 EPA 2008 Mod AS
Analyte
Spike Added (microgL)
MSD Concentration
(microgL)
MS)) Oo
Recovery
RPD
Recovery Limits
RPD Limit Method Notes
Thallium IO100 1037 97l 0341 70 - 130 20 EPA 2008 Mod AS
Frontier Global Sciences Inc The resulrs in this report only apply to the samples analyzed in accordance with the chain ofcusrody document This analytical report must be reproduced in its entirely
Page 18of26 120073 Final Report 04252012
Liz Siska Project Manager
20
11720 North Creek Parkway North Suite 400 l ~ Bothell WA 980 l l Ph 425-686-1996
FRONTIER Fx 425-686-3096 GLOBAL SCIENCES
LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLICATE
RECOVERY AND RPD
Batch F20 l063 Sequence 2A09010
Preparation BrCI Oxidation Lab Number F201063-BSIBSJ21
LCS Source N ist 1641d
Analyte
Spike Added (ngL)
LCS Concentration
(ngL)
LCS
Recovery Recovery
Limits Method Notes
Mercury 15679 1550 988 80 - 120 EPA I631E
Analyte
Spike Added (ngL)
LCSD Concentration
(ngL)
LCSD Oo
Recovery
RPD Recovery
Limits RPD Limit Method Notes
Mercury 15679 1595 [02 289 80 - 120 24 EPA I631E
Frontier Global Sciences Inc The results in this report only apply to the samples analyzedin accordance with the chain ofcustody document This analytical report must be reproduced in ils entirety
Page 19of26 1201073 Final Report 0425 2012
Liz Siska Project Manager
21
11720 North Creek Parkway North Suite 400 Bothell WA 98011
Ph 425-686-1996 FRONTIER Fx 425-686-3096 GLOBAL SCIENCES
LABORA TORY CONTROL SAMPLE LABO RATORY CONTROL SAMPLE DUPLICATE
RECOVERY AND RPD
Batch F203271 Sequence 2C22005
Preparation Closed Vessel Nitric Oven Digestion Lab Number F203271-BSBSD1
LCS Source Blank Spike
Spike LCS LCS Added Concentration Oo Recovery
Analyte (microgL) (microgL) Recovery Limits Method Notes
Beryllium 20000 l930 965 85 - 115 EPA 2008 Mod
Sodium 50000 499 998 85 - 115 EPA 2008 Mod
Aluminum 15000 1460 973 85 - 115 EPA 2008 Mod
Calcium 15000 1528 102 85 - 115 EPA 2008 Mod
Chromium 70000 657 939 85 - 115 EPA 2008 Mod
Manganese 60000 586 976 85 - 115 EPA 2008 Mod
Iron 50000 4753 951 85 shy 115 EPA 2008 Mod
Nickel 40000 401 100 85 - 115 EPA 2008 Mod
Copper 40000 418 105 85 - 115 EPA 2008 Mod
Zinc 10000 1033 103 85 - 115 EPA 2008 Mod
Arsenic 15000 1437 958 85 - 115 EPA 2008 Mod
Selenium 30000 2966 989 85 - 115 EPA 2008 Mod
Molybdenum 20000 181 905 85 shy 115 EPA 2008 Mod
Silver 15000 1517 101 85 shy 115 EPA 2008 Mod
Cadmium 080000 0781 976 85 - 1lS EPA 2008 Mod
Antimony 080000 0815 102 85 - 115 EPA 2008 Mod
Barium 10000 969 969 85 - 115 EPA 2008 Mod
Lead 15000 1597 106 85 - 115 EPA 2008 Mod
Spike LCSD LCSD Added Concentration Recovery RPO
Analyte (microgL) (microgL) Recovery RPO Limits Limit Method Notes
Beryllium 20000 1949 974 0955 85 - 115 20 EPA 2008 Mod
Sodium 50000 500 100 0216 85 - 115 20 EPA 2008 Mod
Aluminum 15000 1485 990 171 85 - 115 20 EPA 2008 Mod
Calcium 15000 1544 103 103 85 - 115 20 EPA 2008 Mod
Chromium 70000 667 953 148 85 - 115 20 EPA 2008 Mod
Manganese 60000 596 994 175 85 - 115 20 EPA 2008 Mod
Iron 50000 4852 970 206 85 - 115 20 EPA 2008 Mod
Nickel 40000 402 IOI 0246 85 - 115 20 EPA 2008 Mod
Frontier Global Sciences Inc The results in his report only apply to the samples analyzed in accordance wirh the chain ofcustody document This analytical report must be reproduced in iLS entirety
Page 20of26 1201073 Final Report 04252012
Liz Siska Project Manager
22
11720 North Creek Parkway North Suite 400 ~~shy Bothell WA 98011 Ph 425-686-1996~ONTif Fx 425-686-3096
GLOBAL SCIENCES
LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLICATE
RECOVERY AND RPO
Batch F20327 l Sequence 2C22005
Preparation Closed Vessel Nitric Oven Digestion Lab Number F203271-BSBSD 1
LCS Source Blank Spike
Analyte
Spike Added (microgL)
LCSD Concentration
(microgL)
LCSD oo
Recovery
RPO Recovery
Limits RPO Limit Method Notes
Copper
Zinc
Arsenic
Selenium
40000
10000
15000
30000
428
1039
1452
3015
107
104
968
101
224
0570
0977
166
85 - 115
85 - 115
85 - 115
85 - 115
20
20
20
20
EPA 2008 Mod
EPA 2008 Mod
EPA 2008 Mod
EPA 2008 Mod Molybdenum
Silver
20000
15000
182
J502
910
100
0564
103
85 - 115
85 - 115
20
20
EPA 2008 Mod
EPA 2008 Mod Cadmium
Antimony
Barium
Lead
080000
080000
10000
15000
0828
0808
986
1620
103
101
986
108
585
0848
177
142
85 - 115
85 - 115
85 shy 11 S
85 - 115
20
20
20
20
EPA 2008 Mod
EPA 2008 Mod
EPA 2008 Mod
EPA 2008 Mod
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report mus be reproducedin its entirety
Page 2 o26J20J073 Final Report 041252012
Liz Siska Project Manager
23
11720 North Creek Parkway North Suite 400 Bothell WA 980 l l
Ph 425-686-1996FRONT[ER- Fx 425-686-3096 cLosAL SCIEN _CES
LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLICATE
RECOVERY AND RPD
Batch F203314 Sequence 2C25005
Preparation Closed Vessel Nitric Oven Digestion Lab Number F2033 l 4-BSBSD 1
LCS Source Blank Spike
Analyte
Thallium
Spike Added (microgL)
LCS Concentration
(microgL)
LCS 0o
Recovery Recovery
Limits Method
040000 0396 989 85 - 115 EPA 2008 Mod
Notes
Analyte
Spike Added (microgL)
LCSD Concentration
(microgL)
LCSD 0o
Recovery
RPD Recovery
Limits RPO Limit Method Notes
Thallium 040000 0391 978 112 85 - ll5 20 EPA 2008 Mod
Frontier Global Sciences Inc The results in this report only apply to the samples anayed in accordance with the chain ofcustody docwnenJ This analytical report must be reproduced in its entirety
Page 22of26 1201073 Final Report 04252012
Liz Siska Project Manager
24
Liz Siska P roject Manager
11720 North Creek Parkway North Suite 400
~ Bothell WA 98011 Ph 425-686-1996
~JTIEif middot Fx 425-686-3096 GLOBAL SCIENCES
PREPARATION BLANKS
Instrument Hg-17 Sequence 2A09010
Preparation BrCI Oxidation
Lab Sample ID Analyte Found MRL Units Batch Method Notes
F201063-BLK I Mercury -0009 050 ngL F201063 EPA 1631E u F20 I063-BLK2 Mercury -0006 050 ngL F201063 EPA 1631E u F201063-BLK3 Mercury -002 050 ngL F201063 EPA 163IE u F201063-BLK4 Mercury 003 050 ngL F201063 EPA 1631E U QB-04 F201063-BLKS Mercury 011 052 ngL F201063 EPA I631E U QB-06
Frontier Global Sciences Inc The results in this report only apply 10 1he samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Page 23 o26 1201073 Final Repon 04252012 25
Liz Siska Project Manager
11720 North Creek Parkway North Suite 400 Bothell WA 98011
Ph 425-686-1996 FROr~TIER- Fx 425-686-3096 GLOBAL SCIENCES
PREPARATION BLANKS
Instrument ICPMS-6 Sequence 2C22005
Preparation Closed Vessel Nitric Oven Digestion
Lab Sample ID Analyte Found MRL Units Batch Method Notes
F203271-BLK1 Beryllium 000008 0060 microgL F203271 PA 2008 Molt u F20327 1-BLK1 Sodium 2 20 microgL F20327l PA 2008 Moc u F20327I-BLK1 Aluminum -004 40 microgL F203271 PA 2008 Molt u F20327I -BLK1 Calcium 40 microgL F203271 PA 2008 Molt u F203271 -BLK1 Chromium -002 010 microgL F203271 ~A 2008 Molt u F203271-BLKI Manganese 001 010 microgL F203271 PA 2008 Molt u F20327 l -BLK 1 Iron -002 100 microgL F203271 PA 2008 Molt u F203271-BLKI Nickel 0004 010 microgL F203271 PA 2008 Moc u F203271-BLK1 Copper 0003 010 microgL F203271 PA 2008 Moc u F203271-BLK1 Zinc 0007 020 microgL F203271 PA 2008 Moc u F203271-BLK1 Arsenic -006 015 microgL F203271 PA 2008 Moc u F203271-BLK1 Selenium -002 060 microgL F203271 PA 2008 Moc u F203271-BLK1 Molybdenum 001 006 microgL F203271 PA 2008 Molt u F203271-BLK1 Silver -00005 0020 microgL F203271 PA 2008 Molt u F203271-BLKl Cadmium 0004 0020 microgL F203271 PA 2008 Molt u F20327 l-BLKl Antimony 0002 0020 microgL F203271 PA 2008 Molt u F203271-BLKI Barium 001 020 microgL F203271 PA 2008 Molt u F203271-BLKI Lead 0010 0040 microgL F203271 PA 2008 Moc u
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Page 24of26 1201073 Final Report 04252012 26
~
~TIER~ GLOBAL SCIENCES
11720 North Creek Parkway North Suite 400 Bothell WA 980ll
Ph 425-686-1996 Fx 425-686-3096
PREPARATION BLANKS
Instrument JCPMS-3 Sequence 2C25005
Preparation Closed Vessel Nitric Oven Digestion
Lab Sample ID Analyte Found MRL Units Batch Method Notes
F2033I4-BLK1 Thalium 00007 0010 microgL F2033I4 ~PA 2008 Molt u
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Page 25 o26Liz Siska Project Manager 1201073 Final Report
04252012 27
l l 720 North Creek Parkway North Suite 400~Vi-~ Bothell WA 98011 Ph 425-686-1 996~Tlmiddot~ Fx 425-686-3096
G L OBAL SCIENCE S
Notes and Definitions
U Analyte included in the analysis but not detected
QM-02 The MS andor MSD recoveries outside acceptance limits due to spike concentration less than I times the sample concentration The batch was accepted based on LCS and LCSD recoveries within control limits and when analysis permits acceptable AS ASD
QB-06 The blank was preserved to 5 BrCI rather than I The control limit for blanks preserved to greater than 1 BrCl is the preservation percentage multiplied by the MRL
QB-04 The blank was preserved to 2 BrCI rather than l The control limit for blanks preserved to greater than l BrCI is the preservation percentage multiplied by the MRL
FB-1631 Required equipmentfieldfilter blank not submitted by the client The sample has been analyzed according to 163 lE but does not meet 163 lE criteria
AS This MS andor MSD is an analytical spike andor an analytical spike duplicate
DET Analyte Detected
MDL Minimum Detection Limit
MRL Minimum Reporting Limit
ND Analyte Not Detected at or above the reporting limit
wet Sample results reported on a wet weight basis
dry Sample results reported on a dry weight basis
RPO Relative Percent Difference
RSD Relative Standard Deviation
Frontier Global Sciences Inc The lesults i111his reporl only apply to he samples analyzed In accordance with the chain ofcuslody document This analytical report must be reproduced in its entirely
Page 26of26 1201073 Final Report 04252012
Liz Siska Project Manager
28
CHAIN-OF-(USTODY ttECORD Page i of f 106677 _J
BoLD F1ELDS REQUIRED PLEASE C 1RCLE REQUESTED ANALYSIS
SAMPLE ID
middoti-rg -- bull ~rshy~ _- tzir +- lt-ltJ~ lt
SAMPLING
DATeTtME
IF COMPOSITE INDICATE BOTH
START amp FINISH
DATETIME li1J oc -r 111_- _vlt-c_
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w l w 0 ~ u X -Xmiddot ~ m Ishy lt( lt( 0
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~ ~ irlte-t- T_ t- f r-n t I s-11 middott~ c~ J J1~w )(~ )
Trttbull rin K C-~-~ pound1t I 1Jtl~ t20~L lwlJI ishy
middot~ON Mm1x A-Al~ S-SOil GW-GampOUHO WATER SW-SUampfA(f WATER DWmiddotDRIIIKIKlti WATER
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1 WW-WASTE WATER PmmATIVE H-HCL H-HN01 S-H1SO Na-NaOH H-HEOH -~ --~
PROJECT MANAGER llr middot1 ~Q Aw4---P1V- Het_ r COMPANY t-lo--tm ~ bd i ( I ~j 6 A ADP~SS 91 g~ez tJshy(ITJ ~ STATE fH_ ZIP c3o--
PHONE 22j-((omiddotf EXT ____
fAX--------------------- shyE-MAIL (JbHd-esa e n ta wamp Sm NAME Meccft1lt-1ltk f--g
PROJECT _
OTHEi________STATpound NH MA ME VT
REGULATORY PROGRAM NPDES RGP POTW STORHWATEl OR
GWP OIL FUHD BROWNIIELO OR OTHER----------
Quon PO o2J~-lt1Jpound)
DATE NEEDED _1--1 middot Z=-----shy4 (1-1_ METALS 8 RCRA 13 pp ff MN PB Cu
QAQC REPORTJNGYVEL
A CG) O R
PRESUMPTIVE CERTAINTY
7i2lt_
RECpound1VEO BYRELINQUISHED BY DATE TIME SUSPECTED (OHTAHIHATIOH________
TEHP~ C REPORTING OPTIONS 01HEA METAL------------PRELIHl Yu OR No
DISSOLVED METALS FIELD FllTEREDI YES 110
rmreg No
IF YH FAX OR POf 7~shy Hom (IE SPECIAL DETECTION LINITl BllLIKGINfO If DlffERrnT)ELECTRONIC OPTIONS zo 1 2 2) le~C1 1 Jc Id sJ 60 6c
1 cf Co
lo FAX pound-MAIL PDF EQUll C jCi (e I rt--111 Ao NiAJrJe middotn th
Ka)Jcr(c C(cdd -ltJ c -l -gtck- z Alt 5e1 Hj
Al l 4_) it fG) 1uJ c(iJoclt-U Sin HISTORY 0Se-d Cim- ~pound rc~L IH t--6
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ImiddotRELINQUISHED BY DATE TIHE RECflVEO BY I FIELD READINGS
eastern analytical inc 2s CHENELL D R1ve IC 0 Nco1to N H 0330 1 I TEL 60J22aos2s 1aoo2a1os2s IFAx 6032284591 j E-MA1t cus-roM111_mV1c~EAILAsscoMJ www1A1LAascoM
----i pmiddotofissionrrl11bomtorymim (WHITE ORIGINAL GREEN PROJECT MANAGER)
shy
SAMPLE CONDITIONS PAGE EAi ID 107555
Client GZA GeoEnvironmental Inc (NH)
Client Designation Merrimack Station
Temperature upon receipt (degC) Acceptable temperature range (0 C) 0-6
Lab ID Sample ID
47
Date Received Sampled
Date
Received on ice or cold packs (YesNo)
Sample Ory Matrix Weight ExceptionsComments (other than
y
thermal preservation)
10755501 Treat Tank Eff Composite 115112 1512 aqueous Adheres to Sample Acceptance Policy
10755502 Treat Tank Eff Grab 11512 15112 aqueous Adheres to Sample Acceptance Policy
Samples were properly preserved and the pH measured when applicable unless otherwise noted Analysis of solids for pH Flashpoint lgnitibility Paint Filter Corrosivity Conductivity and Specific Gravity are reported on an as received basis All results contained in this report relate only to the above listed samples
References include 1) EPA 6004-79-020 1983 2) Standard Methods for Examination of Water and Wastewater lnorganics 19th Edition 1995 Microbiology 20th Edition 1998 3) Test Methods for Evaluating Solid Waste SW 846 3rd Edition including updates VA and VB 4) Hach Water Analysis Handbook 2nd edition 1992
eastern analytical inc wwweailabscom Phone (603) 228-0525 1
l l 720 North Creek Parkway North Suite 400 Bothell WA 98011
Ph 425-686-1996 Fx 425-686-3096 G L OBAL SCIENCES
25 April 2012
JeffGagne
Eastern Analytical Inc
25 Chenell Drive
Concord NH 0330 I
RE Merrimack Station
Enclosed are the analytical results for samples received by Frontier Global Sciences All quality control
measurements are within established control limits and there were no analytical difficulties encountered with the exception of those listed in the case narrative section of this report
If you have any questions concerning this report please feel free to contact me
Sincerely
Liz Siska
Project Manager
2
GLOBAL SCIENCES
11720 North Creek Parkway North Suite 400 Bothell WA 98011
Ph 425-686-1996 Fx 425-686-3096
ANALYTICAL REPORT FOR SAMPLES
Laboratory Frontier Global Sciences Inc SDG
Client Eastern Analytical Inc Project Merrimack Station
Sample ID Lab ID Matrix Date Sampled Date Received
Treat Tank EffComposite 1201073-01 Water 05-Jan-12 1000 06-Jan-12 0950
Treat Tank EffGrab 1201073-02 Water 05-Jan-12 0800 06-Jan-12 0950
Frontier Global Sciences Inc
Liz Siska Project Manager
The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Page 1 o261201073 Final Report 04252012 3
11720 North Creek Parkway North Suite 400 Bothell WA 98011
Ph 425-686-1996FRONTIER Fx 425-686-3096 GLOBAL SCIENCES
CASE NARRATIVE
Revised Report 42512
Per client request Boron was removed from report
Revised Report 32812
Per client request samples were prepared and analyzed for total metals in accordance with EPA 2008 (modified)
SAMPLE RECEIPT
Samples were received at Frontier Global Sciences (FGS) on January 6th 2012 The samples were received intact on-ice with temperatures measured at 34 degrees Celsius
SAMPLE PREPARATION AND ANAL YSJS
Samples were prepared and analyzed for total metals in accordance with FGS-054EPA 1638
Samples were prepared and analyzed for total mercury in accordance with EPA Method 163JE
ANALYTICAL AND QUALITY CONTROL IS SUES
There were no analytical difficulties experienced with analysis of these samples with the exceptions flagged in the report
Frontier Gtobal Sciences Inc The results in this reporr only apply 10 the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Liz Siska Project Manager Page 2of26 J20I073 Final Report 042512012 4
11720 North Creek Parkway North Suite 400 Bothell WA 98011~ Ph 425-686-1996 FRONTIER Fx 425-686-3096
GLOBAL SCIENCES
CHAIN OF CUSTODY FORMS
CML-1d Cc-t~lt7 shy~P~fci amp l sbtr3~~ry Aillylc P~ctirst J- ~V~-=lt S=-Jit=~1t Imiddot~ and 4J~~ Tssul
~ r~middotmiddotmiddot to ~-~ middot ~ ~middot ~rcshyr-11 ---4i--5~1-shy
y1tcirc1middot 6middot 01gter S1bulli1e
1 1 -middot shy
~middot-middotn middot~i---it =-middotmiddotrmiddot~-~r9ft~ri r s L lrj~JT ~- bull 1r bullermiddot~~(~lr- rlt-bull~~~~~ _ -tbull ~t-tmiddotbull I~ bull 1
middot middot l~~e ~middot rv~ 8Arvmiddott _ -middot
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report mus be reproduced in ilS entirety
Page3of26Liz Siska Project Manager 1201073 Final Report
041252012 5
Liz Siska Project Manager
11720 North Creek Parkway North Suite 400 Bothell WA 98011
Ph 425-686- 1996 ~ Fx 425-686-3096 G LOB A L SC I EN CE S
ANALYTICAL RESULTS
Treat Tank Eff Composite
Matrix Water Laboratory ID 1201073-01
Analyte Result MDL MRL Units Dilution Batch Sequence Analyzed Method Notes
Aluminum ND 89 800 microgL 20 F203271 2C22005 032212 EPA 2008 Mod u Antimony 0408 0092 0400 microgL 20 F20327l 2C22005 032212 EPA 2008 Mod Barium 240 054 400 microgL 20 F203271 2C22005 032212 EPA 2008 Mod Beryllium ND 0454 t20 microgL 20 F203271 2C22005 032212 EPA 2008 Mod u Cadmium ND 0083 0400 microgL 20 F203271 2C22005 032212 EPA 2008 Mod u Calcium 5010000 16200 200000 microgL 5000 F203271 2C22005 032212 EPA 2008 Mod Chromium ND 018 200 microgL 20 F20327I 2C22005 032212 EPA 2008 Mod u Copper ND 020 200 microgL 20 F203271 2C22005 032212 EPA 2008 Mod u Iron ND 260 200 microgL 20 F20327l 2C22005 032212 EPA 2008 Mod u Lead ND 0078 0800 microgL 20 F20327l 2C22005 032212 EPA 2008 Mod u Manganese 280 015 200 microgL 20 F203271 2C22005 032212 EPA 2008 Mod Molybdenum 134 012 120 microgL 20 F20327I 2C22005 032212 EPA 2008 Mod Nickel 979 016 2 00 microgL 20 F203271 2C22005 032212 EPA 2008 Mod Silver ND 0120 0400 microgL 20 F203271 2C22005 032212 EPA 2008 Mod u Sodium 259000 23 400 microgL 20 F203271 2C22005 032212 EPA 2008 Mod Thallium 556 0250 100 microgL 100 F203314 2C25005 032512 EPA 2008 Mod Zinc ND 033 400 microgL 20 F203271 2C22005 032212 EPA 2008 Mod u
Frontier Global Sciences Inc The middotesults in 1his report only apply to the samples analyzed in accordance wilh 11e chain ofcus1ody documem This analytical report must be reproduced in ifs entirety
Page 4of26 1201073 Final Report 04252012 6
Liz Siska Project Manager
11720 North Creek Parkway North Suite 400 Bothell WA 98011
Ph 425-686-1996 Fx 425-686-3096
GLOBAt SCIENCES
ANALYTICAL RESULTS
Treat Tank Eff Grab
Matrix Water Laboratory ID 1201073-02
Analyte Result MDL MRL Units Dilution Batch Sequence Analyzed Method Notes
Arsenic 851 102 300 microgL 20 F203271 2C22005 032212 EPA 2008 Mod Mercury 105 034 202 ngL 4 F20I063 2A09010 010912 EPA 1631E FB-1631 Selenium 689 388 120 microgL 20 F203271 2C22005 032212 EPA 2008 Mod
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcustody documenJ This analycical report must be reproduced in its entirety
Page 5 o261201073 Final Report 04252012 7
Liz Siska Project Manager
FRONTIERshycLoaAt SCI ENCES
11720 North Creek Parkway North Suite 400 Bothell WA 98011
Ph 425-686-1996 Fx 425-686-3096
MATRIX DUPLICATESfRIPLICATES
SOURCE 1201073-02
Batch F201063
Preparation BrCI Oxidation
Sequence 2A09010
Lab Number F201063-DUPI
Sample Duplicate Concentration Concentration RPD
Analyte ngL ngL MRL RPD Limit Method Notes Mercury 1048 1054 202 0617 24 EPA I631E
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Page 6of26 1201073 Final Report 04252012 8
11720 North Creek Parkway North Suite 400 BotheE WA 980 l l
Ph 425-686-1996 Fx 425-686-3096
GLOBAL SCIENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1201073-02
Batch F201063 Sequence 2A09010
Preparation BrCI Oxidation Lab Number F20 l 063-MSMSDl
Sample Spike MS MS Concentration Added Concentration RecoveryAnalyte (ngL) (ngL) (ngL) Recovery Method Limits Notes
Mercury 1048 20400 3136 102 71 125 EPA 163IE
Spike MSD MSD Added Concentration oo Recovery RPD
RPD Limits Limit Method Notes Analyte (ngL) (ngL) Recovery
Mercury 20400 2708 814 147 71 - 125 24 EPA 1631E
shy
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Page 7 o26Liz Siska Project Manager 120JO7 3 Final Repo1
04252012 9
Liz Siska Project Manager
11720 North Creek Parkway North Suite 400 Bothell WA 98011
Ph 425-686-1996~ Fx 425-686-3096 CL06AL SCIENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1112278-02
Batch F201063 Sequence 2A09010
Preparation BrCI Oxidation Lab Number F20 l 063-MSMSD2
Sample Spike MS MS
Analyte Concentration
(ogL) Added (ngL)
Concentration (ngL)
Recovery
RecoveryLimits Method Notes
Mercury 761 20400 2786 992 71 125 EPA 1631E
Spike MSD MSD Added Concentration Oo Recovery RPO
Analyte (ngL) (ngL) Recovery RPO Limits Limit Method Notes
Mercury 20400 2837 102 182 71 - 125 24 EPA l631E
shy
Frontier Global Sciences Inc The results in this report only apply to the somples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Page 8 o26 1201073 Final Report 042512012 10
11720 North Creek Parkway North Suite 400 Bothell WA 980 l l
Ph 425-686-1996 ~ Fx 425-686-3096 GLOBAL SCIENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1201029-01
Batch
Preparation
F201063
BrCI Oxidation
Sequence
Lab Number
2A09010
F20 I 063-MSMSD3
Analyte
Mercury
Analyte
Mercury
Sample Spike Concentration Added
(ngL) (ngL)
534 10200
Spike MSD Added Concentration (ngL) (ngL)
10200 1407
MS MS Concentration Recovery
(ngL) Recovery Limits
1558 JOO 7l shy 125
MSD oo Recovery RPD
Recovery RPD Limits Limit
856 102 71 - 125 24
Method
EPA l63lE
Method
EPA 631E
Notes
Notes
Frontier Global Sciences Inc The results in this repon only apply to rhe samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Page 9of26 1201073 Final Report 041252012
Liz Siska Project Manager
1 1
11720 North Creek Parkway North Suite 400 Bothell WA 98011
Ph 425-686-1996 FRONTIER- Fx 425-686-3096 cLosAL SCIENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1201030-02
Batch F20I063 Sequence 2A09010
Preparation BrCI Oxidation Lab Number F201063-MSMSD4
Sample Spike MS MS Concentration Added Concentration RecoveryAnalyte (ngL) (ngL) (ngL) Recovery MethodLimits Notes
Mercury 554 10200 1482 910 71 - 125 EPA I631E
Spike MSD MSD Oo Added Concentratio11 Recovery RPD
RPD Limits Limit Method Analyte (ngL) (ngL) Recovery Notes
Mercury 10200 1461 890 140 71 - 125 24 EPA 163IE
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed m accordance with the chain ofcus1ody document This anayt(ca repon must be reproduced in itr entirety
Page lOo26Liz Siska Project Manager 1201073 Final Report
041252012 12
I 1720 North Creek Parkway North Suite 400 Bothe I I WA 98011
Ph 425-686-1996 ~ Fx 425-686-3096 GLOBAL SCIENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1201073-01RE3
Batch F20327l Sequence 2C22005
Prcpa ration ((01ed Vessel ~ itric Oven Digestion Lab Number F203271-MSMSD 1
Analyte
Sample Concentration
(microgL)
Spike Added (microgL)
MS Concentration
(microgL)
MS Oo
Recovery Recovery
Method Limits Notes
Calcium 5013000 15150 4802000 -13900 70- 130 EPA 2008 Mod QM-02
Analyte
Spike Added (microgL)
MSD Concentration
(microgL)
MSD ~o
Recovery
Oo
RPD Recovery
Limits RPDLimit Method Notes
Calcium 15150 4943000 -4600 289 70 - 130 20 EPA 2008 Mod QM-02
Frontier Global Sciences Inc The results in this report only apply to the samples analyud inaccordance with the chain ofcustody document 17is analyticol report must be reproduced in its entirety
Page lI o16 1101073 Final Report 04152012
Liz Siska Project Manager
13
l l 720 North Creek Parkway North Suite 400 Bothell WA 98011
Ph 425-686-1996FRONTIER Fx 425-686-3096 GLOBAL SCIENCES
MATRIX SPIKE I MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1201073-01RE4
Batch F203271 Sequence 2C22005
Preparation Closed Vessel Nitric Oven Digestion Lab Number F203271-MSMSD2
Sample Spike MS MS Concentration Added Concentration Oo RecoveryAnalyte (microgL) (microgL) (microgL) Recovery Method Limits Notes
Beryllium 0507 20200 2442 958 70 - 130 EPA 2008 Mod Sodium 258800 50500 257700 -213 70 -130 EPA 2008 Mod QM-02 Aluminum 529 15150 2023 986 70 - 130 EPA 2008 Mod Chromium 057 70700 804 106 70 - 130 EPA 2008 Mod Manganese 2805 60600 2834 476 70 - 130 EPA 2008 Mod QM-02 Iron ND 50500 5200 103 70 130 EPA 2008 Mod Nickel 979 40400 141 l 107 70- 130 EPA 2008 Mod Copper 055 40400 434 939 70 - 130 EPA 2008 Mod Zinc 040 10100 842 794 70 - 130 EPA 2008 Mod Arsenic 1030 15150 2418 916 70 - 130 EPA 2008 Mod Selenium 6340 30300 8973 869 70 130 EPA 2008 Mod Molybdenum 1338 20200 1367 142 70 130 EPA 2008 Mod QM-02 Silver ND 15150 1388 916 70 - 130 EPA 2008 Mod Cadmium 0332 080800 1105 middot956 70 - 130 EPA 2008 Mod Antimony 0408 080800 1259 105 70- 130 EPA 2008 Mod Barium 2397 10100 2495 968 70 - 130 EPA 2008 Mod Lead ND 15150 1542 102 70 130 EPA 2008 Mod
shy
shy
shy
shy
Analyte
Spike Added (microgL)
MSD Concentration
(microgL)
MSD Oo
Recovery
Oo
RPD Recovery
Limits RPD Limit Method Notes
Beryllium
Sodium
Aluminum
Chromium
Manganese
Iron
Nickel
Copper
Zinc
Arsenic
Selenium
Molybdenum
20200
50500
15150
7Q700
60600
50500
40400
40400
10100
15150
30300
20200
2561
257100
2034
773
2852
5187
1381
419
916
2225
9400
1366
102
-336
993
101 769
103
995
902
868
789
101
137
474
0243
0564
385
0625
0242
213
347
849
831
464
00771
70 - 130
70 bull 130 70 - 130
70 - 130
70 - 130
70 - 130
70 - 130
70 - 130
70 - 130
70 bull 130 70 - 130
70 - 130
20
20
20
20
20
20
20
20
20
20
20
20
EPA 2008 Mod
EPA 2008 Mod
EPA 2008 Mod
EPA 2008 Mod
EPA 2008 Mod
EPA 2008 Mod
EPA 2008 Mod
EPA 2008 Mod
EPA 2008 Mod
EPA 2008 Mod
EPA 2008 Mod
EPA 2008 Mod
QM-02
QM-02
Frontier G lobal Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
--f_~ --~~~-~ -middot middot Page 12 o261201073 Final Report 041252012
Liz Siska Project Manager
14
11720 North Creek Parkway North Suite 400
~ Bothell WA 98011
~TIEmiddot Ph 425-686-1996 Fx 425-686-3096
GLOB11L SCIENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPO
SOURCE 1201073-01RE4
Batch F203271 Sequence 2C22005
Preparation ~lo~ed Vessel Nitric Oven Digestion Lab Number F20327 I-MSMSD2
Spike MSD MSD Added Concentration Oo Recovery RPO
Analyte (microgL) (microgL) Recovery RPD Limits Limit Method Notes
Silver 15150 1387 915 00874 70 - 130 20 EPA 2008 Mod Cadmium 080800 1061 902 403 70 - 130 20 EPA 200amp Mod Antimony 080800 1274 107 l2l 70 - 130 20 EPA 2008 Mod Barium 10100 2514 )16 0781 70 - 130 20 EPA 200amp Mod Lead 15150 1534 101 0525 70 shy 130 20 EPA 2008 Mod
Frontier Global Sciences Inc The results in this report only apply to 1he samples analyzed in accordance wiih the chain ofcustody document This analytical repo1 must be reproduced in ils entirety
Page 13 o26Liz Siska Project Manager 1201073 Final Reporl
04252012 15
11720 North Creek Parkway North Suite 400
~ Bothell WA 98011 Ph 425-686-I996
~RONTIER~ Fx 425-686-3096 GLOBAL SCIEN C ES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1201073-01RE3
Batch F203271 Sequence 2~22005
Preparation Closed Vessel Nitric Oven Digestion Lab Number F20327 I-MSMSD3
Sample Spike MS MS
Analyte Concentration
(microgL) Added (microgL)
Concentration (microgL) Recovery
Recovery Limits Method Notes
Calcium 5013000 10100000 15120000 100 70- 130 EPA 2008 Mod AS
Spike MSD MSD Added Concentration o Oo Recovery RPD
Analyte (microgL) (microgL) Recovery RPD Limits Limit Method Notes
Calcium 10100000 16140000 llO 653 70 - 130 20 EPA 2008 Mod AS
Frontier Global Sciences Inc The results in his report only apply 10 the samples analyzed in accordance ivth he chain ofcustody document This analytical report must be reproduced in its entirety
Page 14 o261201073 Final Report 0425201]
Liz Siska Project Manager
16
Frontier Global Sciences Inc The ruults in this rechain ofcustody do
~ -lt1-c--~ Liz Siska Project Manager
11720 North Creek Parkway North Suite 400 Bothell WA 98011
Ph 425-686-1996 Fx 425-686-3096
GLOBAL SCIENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1201073-01RE4
Batch J203271 Sequence 2C22005
Preparation ~ IQsed Ve~~el Nitric Oven Qigestion Lab Number F203271-MSMSQ4
Analyte
Beryllium
Sample Concentration
(11gL)
0507
Spike Added (11gL)
20200
MS Concentration
(microgL)
2041
MS Oo
Recovery
985
RecoveryMethod Limits
70 - 130 EPA 2008 Mod
Notes
AS
Sodium 258800 40400 292900 845 70- 130 EPA 2008 Mod AS
Aluminum 529 40400 3956 966 70 - 130 EPA 2008 Mod AS
Chromium 057 40400 430l 106 70- 130 EPA 2008 Mod AS
Manganese 2805 40400 7042 105 70 - 130 EPA 2008 Mod AS
Iron ND 20200 2121 105 70 - 130 EPA 2008 Mod AS
Nickel 979 50500 5112 993 70 l30 EPA 2008 Mod AS
Copper 055 50500 4754 940 70 - 130 EPA 2008 Mod AS
Zinc 040 10100 9074 898 70 - 130 EPA 2008 Mod AS
Arsenic 1030 40400 4317 104 70 130 EPA 2008 Mod AS
Selenium 6340 40400 4688 100 70 - 130 EPA 2008 Mod AS
Molybdenum 1338 20200 338l 101 70 - 130 EPA 2008 Mod AS
Silver ND 20200 1850 916 70 130 EPA 2008 Mod AS
Cadmium 0332 40400 3937 966 70 130 EPA 2008 Mod AS
Antimony 0408 20200 2091 102 70 - 130 EPA 2008 Mod AS
Barium 2397 80800 1056 101 70- 130 EPA 2008 Mod AS
Lead ND IO100 9932 983 70 130 EPA 2008 Mod AS
shy
shy
shy
shy
shy
Analyte
Spike Added (microgL)
MSD Concentration
(microgL)
MSD
Recovery
RPD
Recovery Limits
RPDLimit Method Notes
Beryllium 20200 2007 968 l71 70 - 130 20 EPA 2008 Mod AS Sodium 40400 292600 837 0114 70 130 20 EPA 2008 Mod AS Aluminum 40400 3954 966 00362 70 - 130 20 EPA 2008 Mod AS Chromium 40400 4287 106 0337 70 - 130 20 EPA 2008 Mod AS Manganese 40400 6944 102 140 70 - 130 20 EPA 2008 Mod AS Iron 20200 2077 103 211 70 - 130 20 EPA 2008 Mod AS Nickel 50500 5126 996 0276 70 - 130 20 EPA 2008 Mod AS Copper 50500 4707 931 0997 70 - 130 20 EPA 200 8 Mod AS Zinc 10100 9059 896 0166 70 - 130 20 EPA 2008 Mod AS Arsenic 40400 4299 104 0419 70 - 130 20 EPA 2008 Mod AS Selenium 40400 4682 100 0141 70 - 130 20 EPA 2008 Mod AS Molybdenum 20200 3365 100 0473 70 - 130 20 EPA 2008 Mod AS
shy
port only apply to the sampltts analyzed in accordance with the cument This analytical report must be reproduced in its entirety
Page 5 o26 201073 Final Report 042512012 17
Liz Sia Project Manager
11720 North Creek Parkway North Suite 400 Botheln VA 98011
Ph 425-686-1996 Fx 425-686-3096
CLOBAL SCIENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1201073-01RE4
Batch F203271 Sequence 2c2io2~
Preparation Clo~ed Vessel litric Oven Digestion Lab Number F20327 l -MSMSQ4
Analyte
Spike Added (microgL)
MSD Concentration
(microgL)
MSD
Recovery
Oo
RPD Recovery
Limits RPOLimit Method Notes
Silver 20200 1895 938 242 70 - 130 20 EPA 2008 Mod AS Cadmium 40400 3933 965 0104 70 -130 20 EPA 2008 Mod AS Antimony 20200 2107 102 0736 70- 130 20 EPA 2008 Mod AS
Barium 80800 1058 101 0205 70 - 130 20 EPA 2008 Mod AS
Lead 10100 9877 978 0549 70 - 130 20 EPA 2008 Mod AS
Frontier Global Sciences Inc The results in this report only apply to the samples analyudin accordance with lht chain ofcustody document This analytical report must be reproductd rn ilS enlirtty
Page l6of26 1201073 Final Report Ofn5202 18
l I 720 North Creek Parkway North Suite 400 Bothell WA 980I I
Ph 425-686-1996 Fx 425-686-3096
GLO B AL SCIENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1201073-01RE6
Batch F203314 Sequence 2C25005
Preparation Closed Vessel Nitric Oven Digestion Lab Number F203314-MSMSD2
Sample Spike MS MS Concentration Added Concentration RecoveryAnalyte (microgL) (microgL) (microgL) Recovery Method NotesLimits
Thallium 5563 040400 5875 773 70 - 130 EPA 2008 Mod
Spike MSD MSD Added o Concentration Recovery RPD
RPO Limits Limit Method Notes Analyte (microgL) (microgL) Recovery
Thallium 040400 5880 785 00859 70 - 130 20 EPA 2008 Mod
Frontier Global Sciences Inc 11e results in chis reporc only apply 10 1he samples analyzed in accordance wilh lhe chain ofcustody documenz This analycical report musl be reproduced in ils entirety
Page 17 of26 1201073 Fi11aReport 0412512012
Liz Siska Project Manager
19
11720 North Creek Parkway North Suite 400 Bothell WA 98011
Ph 425-686-1996 Fx 425-686-3096
GLOBAl SCIENC ES
MATRIX SPIKE I MATRIX SPIKE DUPLICATE RECOVERY AND RPO
SOURCE I201073-01RE6
Batch F203314
Preparation Closed Vessel Nitric Oven Digestion
Sequence 2C25005
Lab Number F203314-MSMSD4
Analyte
Sample Concentration
(microgL)
Spike Added (microgL)
MS MS Concentration Oo
(microgL) Recovery Recovery
Limits Method Notes
Thallium 5563 10100 1033 968 70- 130 EPA 2008 Mod AS
Analyte
Spike Added (microgL)
MSD Concentration
(microgL)
MS)) Oo
Recovery
RPD
Recovery Limits
RPD Limit Method Notes
Thallium IO100 1037 97l 0341 70 - 130 20 EPA 2008 Mod AS
Frontier Global Sciences Inc The resulrs in this report only apply to the samples analyzed in accordance with the chain ofcusrody document This analytical report must be reproduced in its entirely
Page 18of26 120073 Final Report 04252012
Liz Siska Project Manager
20
11720 North Creek Parkway North Suite 400 l ~ Bothell WA 980 l l Ph 425-686-1996
FRONTIER Fx 425-686-3096 GLOBAL SCIENCES
LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLICATE
RECOVERY AND RPD
Batch F20 l063 Sequence 2A09010
Preparation BrCI Oxidation Lab Number F201063-BSIBSJ21
LCS Source N ist 1641d
Analyte
Spike Added (ngL)
LCS Concentration
(ngL)
LCS
Recovery Recovery
Limits Method Notes
Mercury 15679 1550 988 80 - 120 EPA I631E
Analyte
Spike Added (ngL)
LCSD Concentration
(ngL)
LCSD Oo
Recovery
RPD Recovery
Limits RPD Limit Method Notes
Mercury 15679 1595 [02 289 80 - 120 24 EPA I631E
Frontier Global Sciences Inc The results in this report only apply to the samples analyzedin accordance with the chain ofcustody document This analytical report must be reproduced in ils entirety
Page 19of26 1201073 Final Report 0425 2012
Liz Siska Project Manager
21
11720 North Creek Parkway North Suite 400 Bothell WA 98011
Ph 425-686-1996 FRONTIER Fx 425-686-3096 GLOBAL SCIENCES
LABORA TORY CONTROL SAMPLE LABO RATORY CONTROL SAMPLE DUPLICATE
RECOVERY AND RPD
Batch F203271 Sequence 2C22005
Preparation Closed Vessel Nitric Oven Digestion Lab Number F203271-BSBSD1
LCS Source Blank Spike
Spike LCS LCS Added Concentration Oo Recovery
Analyte (microgL) (microgL) Recovery Limits Method Notes
Beryllium 20000 l930 965 85 - 115 EPA 2008 Mod
Sodium 50000 499 998 85 - 115 EPA 2008 Mod
Aluminum 15000 1460 973 85 - 115 EPA 2008 Mod
Calcium 15000 1528 102 85 - 115 EPA 2008 Mod
Chromium 70000 657 939 85 - 115 EPA 2008 Mod
Manganese 60000 586 976 85 - 115 EPA 2008 Mod
Iron 50000 4753 951 85 shy 115 EPA 2008 Mod
Nickel 40000 401 100 85 - 115 EPA 2008 Mod
Copper 40000 418 105 85 - 115 EPA 2008 Mod
Zinc 10000 1033 103 85 - 115 EPA 2008 Mod
Arsenic 15000 1437 958 85 - 115 EPA 2008 Mod
Selenium 30000 2966 989 85 - 115 EPA 2008 Mod
Molybdenum 20000 181 905 85 shy 115 EPA 2008 Mod
Silver 15000 1517 101 85 shy 115 EPA 2008 Mod
Cadmium 080000 0781 976 85 - 1lS EPA 2008 Mod
Antimony 080000 0815 102 85 - 115 EPA 2008 Mod
Barium 10000 969 969 85 - 115 EPA 2008 Mod
Lead 15000 1597 106 85 - 115 EPA 2008 Mod
Spike LCSD LCSD Added Concentration Recovery RPO
Analyte (microgL) (microgL) Recovery RPO Limits Limit Method Notes
Beryllium 20000 1949 974 0955 85 - 115 20 EPA 2008 Mod
Sodium 50000 500 100 0216 85 - 115 20 EPA 2008 Mod
Aluminum 15000 1485 990 171 85 - 115 20 EPA 2008 Mod
Calcium 15000 1544 103 103 85 - 115 20 EPA 2008 Mod
Chromium 70000 667 953 148 85 - 115 20 EPA 2008 Mod
Manganese 60000 596 994 175 85 - 115 20 EPA 2008 Mod
Iron 50000 4852 970 206 85 - 115 20 EPA 2008 Mod
Nickel 40000 402 IOI 0246 85 - 115 20 EPA 2008 Mod
Frontier Global Sciences Inc The results in his report only apply to the samples analyzed in accordance wirh the chain ofcustody document This analytical report must be reproduced in iLS entirety
Page 20of26 1201073 Final Report 04252012
Liz Siska Project Manager
22
11720 North Creek Parkway North Suite 400 ~~shy Bothell WA 98011 Ph 425-686-1996~ONTif Fx 425-686-3096
GLOBAL SCIENCES
LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLICATE
RECOVERY AND RPO
Batch F20327 l Sequence 2C22005
Preparation Closed Vessel Nitric Oven Digestion Lab Number F203271-BSBSD 1
LCS Source Blank Spike
Analyte
Spike Added (microgL)
LCSD Concentration
(microgL)
LCSD oo
Recovery
RPO Recovery
Limits RPO Limit Method Notes
Copper
Zinc
Arsenic
Selenium
40000
10000
15000
30000
428
1039
1452
3015
107
104
968
101
224
0570
0977
166
85 - 115
85 - 115
85 - 115
85 - 115
20
20
20
20
EPA 2008 Mod
EPA 2008 Mod
EPA 2008 Mod
EPA 2008 Mod Molybdenum
Silver
20000
15000
182
J502
910
100
0564
103
85 - 115
85 - 115
20
20
EPA 2008 Mod
EPA 2008 Mod Cadmium
Antimony
Barium
Lead
080000
080000
10000
15000
0828
0808
986
1620
103
101
986
108
585
0848
177
142
85 - 115
85 - 115
85 shy 11 S
85 - 115
20
20
20
20
EPA 2008 Mod
EPA 2008 Mod
EPA 2008 Mod
EPA 2008 Mod
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report mus be reproducedin its entirety
Page 2 o26J20J073 Final Report 041252012
Liz Siska Project Manager
23
11720 North Creek Parkway North Suite 400 Bothell WA 980 l l
Ph 425-686-1996FRONT[ER- Fx 425-686-3096 cLosAL SCIEN _CES
LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLICATE
RECOVERY AND RPD
Batch F203314 Sequence 2C25005
Preparation Closed Vessel Nitric Oven Digestion Lab Number F2033 l 4-BSBSD 1
LCS Source Blank Spike
Analyte
Thallium
Spike Added (microgL)
LCS Concentration
(microgL)
LCS 0o
Recovery Recovery
Limits Method
040000 0396 989 85 - 115 EPA 2008 Mod
Notes
Analyte
Spike Added (microgL)
LCSD Concentration
(microgL)
LCSD 0o
Recovery
RPD Recovery
Limits RPO Limit Method Notes
Thallium 040000 0391 978 112 85 - ll5 20 EPA 2008 Mod
Frontier Global Sciences Inc The results in this report only apply to the samples anayed in accordance with the chain ofcustody docwnenJ This analytical report must be reproduced in its entirety
Page 22of26 1201073 Final Report 04252012
Liz Siska Project Manager
24
Liz Siska P roject Manager
11720 North Creek Parkway North Suite 400
~ Bothell WA 98011 Ph 425-686-1996
~JTIEif middot Fx 425-686-3096 GLOBAL SCIENCES
PREPARATION BLANKS
Instrument Hg-17 Sequence 2A09010
Preparation BrCI Oxidation
Lab Sample ID Analyte Found MRL Units Batch Method Notes
F201063-BLK I Mercury -0009 050 ngL F201063 EPA 1631E u F20 I063-BLK2 Mercury -0006 050 ngL F201063 EPA 1631E u F201063-BLK3 Mercury -002 050 ngL F201063 EPA 163IE u F201063-BLK4 Mercury 003 050 ngL F201063 EPA 1631E U QB-04 F201063-BLKS Mercury 011 052 ngL F201063 EPA I631E U QB-06
Frontier Global Sciences Inc The results in this report only apply 10 1he samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Page 23 o26 1201073 Final Repon 04252012 25
Liz Siska Project Manager
11720 North Creek Parkway North Suite 400 Bothell WA 98011
Ph 425-686-1996 FROr~TIER- Fx 425-686-3096 GLOBAL SCIENCES
PREPARATION BLANKS
Instrument ICPMS-6 Sequence 2C22005
Preparation Closed Vessel Nitric Oven Digestion
Lab Sample ID Analyte Found MRL Units Batch Method Notes
F203271-BLK1 Beryllium 000008 0060 microgL F203271 PA 2008 Molt u F20327 1-BLK1 Sodium 2 20 microgL F20327l PA 2008 Moc u F20327I-BLK1 Aluminum -004 40 microgL F203271 PA 2008 Molt u F20327I -BLK1 Calcium 40 microgL F203271 PA 2008 Molt u F203271 -BLK1 Chromium -002 010 microgL F203271 ~A 2008 Molt u F203271-BLKI Manganese 001 010 microgL F203271 PA 2008 Molt u F20327 l -BLK 1 Iron -002 100 microgL F203271 PA 2008 Molt u F203271-BLKI Nickel 0004 010 microgL F203271 PA 2008 Moc u F203271-BLK1 Copper 0003 010 microgL F203271 PA 2008 Moc u F203271-BLK1 Zinc 0007 020 microgL F203271 PA 2008 Moc u F203271-BLK1 Arsenic -006 015 microgL F203271 PA 2008 Moc u F203271-BLK1 Selenium -002 060 microgL F203271 PA 2008 Moc u F203271-BLK1 Molybdenum 001 006 microgL F203271 PA 2008 Molt u F203271-BLK1 Silver -00005 0020 microgL F203271 PA 2008 Molt u F203271-BLKl Cadmium 0004 0020 microgL F203271 PA 2008 Molt u F20327 l-BLKl Antimony 0002 0020 microgL F203271 PA 2008 Molt u F203271-BLKI Barium 001 020 microgL F203271 PA 2008 Molt u F203271-BLKI Lead 0010 0040 microgL F203271 PA 2008 Moc u
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Page 24of26 1201073 Final Report 04252012 26
~
~TIER~ GLOBAL SCIENCES
11720 North Creek Parkway North Suite 400 Bothell WA 980ll
Ph 425-686-1996 Fx 425-686-3096
PREPARATION BLANKS
Instrument JCPMS-3 Sequence 2C25005
Preparation Closed Vessel Nitric Oven Digestion
Lab Sample ID Analyte Found MRL Units Batch Method Notes
F2033I4-BLK1 Thalium 00007 0010 microgL F2033I4 ~PA 2008 Molt u
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Page 25 o26Liz Siska Project Manager 1201073 Final Report
04252012 27
l l 720 North Creek Parkway North Suite 400~Vi-~ Bothell WA 98011 Ph 425-686-1 996~Tlmiddot~ Fx 425-686-3096
G L OBAL SCIENCE S
Notes and Definitions
U Analyte included in the analysis but not detected
QM-02 The MS andor MSD recoveries outside acceptance limits due to spike concentration less than I times the sample concentration The batch was accepted based on LCS and LCSD recoveries within control limits and when analysis permits acceptable AS ASD
QB-06 The blank was preserved to 5 BrCI rather than I The control limit for blanks preserved to greater than 1 BrCl is the preservation percentage multiplied by the MRL
QB-04 The blank was preserved to 2 BrCI rather than l The control limit for blanks preserved to greater than l BrCI is the preservation percentage multiplied by the MRL
FB-1631 Required equipmentfieldfilter blank not submitted by the client The sample has been analyzed according to 163 lE but does not meet 163 lE criteria
AS This MS andor MSD is an analytical spike andor an analytical spike duplicate
DET Analyte Detected
MDL Minimum Detection Limit
MRL Minimum Reporting Limit
ND Analyte Not Detected at or above the reporting limit
wet Sample results reported on a wet weight basis
dry Sample results reported on a dry weight basis
RPO Relative Percent Difference
RSD Relative Standard Deviation
Frontier Global Sciences Inc The lesults i111his reporl only apply to he samples analyzed In accordance with the chain ofcuslody document This analytical report must be reproduced in its entirely
Page 26of26 1201073 Final Report 04252012
Liz Siska Project Manager
28
CHAIN-OF-(USTODY ttECORD Page i of f 106677 _J
BoLD F1ELDS REQUIRED PLEASE C 1RCLE REQUESTED ANALYSIS
SAMPLE ID
middoti-rg -- bull ~rshy~ _- tzir +- lt-ltJ~ lt
SAMPLING
DATeTtME
IF COMPOSITE INDICATE BOTH
START amp FINISH
DATETIME li1J oc -r 111_- _vlt-c_
w Ishyt 0 n
w l w 0 ~ u X -Xmiddot ~ m Ishy lt( lt( 0
I C)
IIXJ JC
~ ~ irlte-t- T_ t- f r-n t I s-11 middott~ c~ J J1~w )(~ )
Trttbull rin K C-~-~ pound1t I 1Jtl~ t20~L lwlJI ishy
middot~ON Mm1x A-Al~ S-SOil GW-GampOUHO WATER SW-SUampfA(f WATER DWmiddotDRIIIKIKlti WATER
Itlt
-glo c ~
c t I O
~ t = ~ ~
~ o ~1
~ ~ ~
0
5 g sect ~ shy2 s z
rJ gII
)(
107555
i
~ I NOTES MEOH VIAL
1 WW-WASTE WATER PmmATIVE H-HCL H-HN01 S-H1SO Na-NaOH H-HEOH -~ --~
PROJECT MANAGER llr middot1 ~Q Aw4---P1V- Het_ r COMPANY t-lo--tm ~ bd i ( I ~j 6 A ADP~SS 91 g~ez tJshy(ITJ ~ STATE fH_ ZIP c3o--
PHONE 22j-((omiddotf EXT ____
fAX--------------------- shyE-MAIL (JbHd-esa e n ta wamp Sm NAME Meccft1lt-1ltk f--g
PROJECT _
OTHEi________STATpound NH MA ME VT
REGULATORY PROGRAM NPDES RGP POTW STORHWATEl OR
GWP OIL FUHD BROWNIIELO OR OTHER----------
Quon PO o2J~-lt1Jpound)
DATE NEEDED _1--1 middot Z=-----shy4 (1-1_ METALS 8 RCRA 13 pp ff MN PB Cu
QAQC REPORTJNGYVEL
A CG) O R
PRESUMPTIVE CERTAINTY
7i2lt_
RECpound1VEO BYRELINQUISHED BY DATE TIME SUSPECTED (OHTAHIHATIOH________
TEHP~ C REPORTING OPTIONS 01HEA METAL------------PRELIHl Yu OR No
DISSOLVED METALS FIELD FllTEREDI YES 110
rmreg No
IF YH FAX OR POf 7~shy Hom (IE SPECIAL DETECTION LINITl BllLIKGINfO If DlffERrnT)ELECTRONIC OPTIONS zo 1 2 2) le~C1 1 Jc Id sJ 60 6c
1 cf Co
lo FAX pound-MAIL PDF EQUll C jCi (e I rt--111 Ao NiAJrJe middotn th
Ka)Jcr(c C(cdd -ltJ c -l -gtck- z Alt 5e1 Hj
Al l 4_) it fG) 1uJ c(iJoclt-U Sin HISTORY 0Se-d Cim- ~pound rc~L IH t--6
1 r
ImiddotRELINQUISHED BY DATE TIHE RECflVEO BY I FIELD READINGS
eastern analytical inc 2s CHENELL D R1ve IC 0 Nco1to N H 0330 1 I TEL 60J22aos2s 1aoo2a1os2s IFAx 6032284591 j E-MA1t cus-roM111_mV1c~EAILAsscoMJ www1A1LAascoM
----i pmiddotofissionrrl11bomtorymim (WHITE ORIGINAL GREEN PROJECT MANAGER)
shy
l l 720 North Creek Parkway North Suite 400 Bothell WA 98011
Ph 425-686-1996 Fx 425-686-3096 G L OBAL SCIENCES
25 April 2012
JeffGagne
Eastern Analytical Inc
25 Chenell Drive
Concord NH 0330 I
RE Merrimack Station
Enclosed are the analytical results for samples received by Frontier Global Sciences All quality control
measurements are within established control limits and there were no analytical difficulties encountered with the exception of those listed in the case narrative section of this report
If you have any questions concerning this report please feel free to contact me
Sincerely
Liz Siska
Project Manager
2
GLOBAL SCIENCES
11720 North Creek Parkway North Suite 400 Bothell WA 98011
Ph 425-686-1996 Fx 425-686-3096
ANALYTICAL REPORT FOR SAMPLES
Laboratory Frontier Global Sciences Inc SDG
Client Eastern Analytical Inc Project Merrimack Station
Sample ID Lab ID Matrix Date Sampled Date Received
Treat Tank EffComposite 1201073-01 Water 05-Jan-12 1000 06-Jan-12 0950
Treat Tank EffGrab 1201073-02 Water 05-Jan-12 0800 06-Jan-12 0950
Frontier Global Sciences Inc
Liz Siska Project Manager
The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Page 1 o261201073 Final Report 04252012 3
11720 North Creek Parkway North Suite 400 Bothell WA 98011
Ph 425-686-1996FRONTIER Fx 425-686-3096 GLOBAL SCIENCES
CASE NARRATIVE
Revised Report 42512
Per client request Boron was removed from report
Revised Report 32812
Per client request samples were prepared and analyzed for total metals in accordance with EPA 2008 (modified)
SAMPLE RECEIPT
Samples were received at Frontier Global Sciences (FGS) on January 6th 2012 The samples were received intact on-ice with temperatures measured at 34 degrees Celsius
SAMPLE PREPARATION AND ANAL YSJS
Samples were prepared and analyzed for total metals in accordance with FGS-054EPA 1638
Samples were prepared and analyzed for total mercury in accordance with EPA Method 163JE
ANALYTICAL AND QUALITY CONTROL IS SUES
There were no analytical difficulties experienced with analysis of these samples with the exceptions flagged in the report
Frontier Gtobal Sciences Inc The results in this reporr only apply 10 the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Liz Siska Project Manager Page 2of26 J20I073 Final Report 042512012 4
11720 North Creek Parkway North Suite 400 Bothell WA 98011~ Ph 425-686-1996 FRONTIER Fx 425-686-3096
GLOBAL SCIENCES
CHAIN OF CUSTODY FORMS
CML-1d Cc-t~lt7 shy~P~fci amp l sbtr3~~ry Aillylc P~ctirst J- ~V~-=lt S=-Jit=~1t Imiddot~ and 4J~~ Tssul
~ r~middotmiddotmiddot to ~-~ middot ~ ~middot ~rcshyr-11 ---4i--5~1-shy
y1tcirc1middot 6middot 01gter S1bulli1e
1 1 -middot shy
~middot-middotn middot~i---it =-middotmiddotrmiddot~-~r9ft~ri r s L lrj~JT ~- bull 1r bullermiddot~~(~lr- rlt-bull~~~~~ _ -tbull ~t-tmiddotbull I~ bull 1
middot middot l~~e ~middot rv~ 8Arvmiddott _ -middot
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report mus be reproduced in ilS entirety
Page3of26Liz Siska Project Manager 1201073 Final Report
041252012 5
Liz Siska Project Manager
11720 North Creek Parkway North Suite 400 Bothell WA 98011
Ph 425-686- 1996 ~ Fx 425-686-3096 G LOB A L SC I EN CE S
ANALYTICAL RESULTS
Treat Tank Eff Composite
Matrix Water Laboratory ID 1201073-01
Analyte Result MDL MRL Units Dilution Batch Sequence Analyzed Method Notes
Aluminum ND 89 800 microgL 20 F203271 2C22005 032212 EPA 2008 Mod u Antimony 0408 0092 0400 microgL 20 F20327l 2C22005 032212 EPA 2008 Mod Barium 240 054 400 microgL 20 F203271 2C22005 032212 EPA 2008 Mod Beryllium ND 0454 t20 microgL 20 F203271 2C22005 032212 EPA 2008 Mod u Cadmium ND 0083 0400 microgL 20 F203271 2C22005 032212 EPA 2008 Mod u Calcium 5010000 16200 200000 microgL 5000 F203271 2C22005 032212 EPA 2008 Mod Chromium ND 018 200 microgL 20 F20327I 2C22005 032212 EPA 2008 Mod u Copper ND 020 200 microgL 20 F203271 2C22005 032212 EPA 2008 Mod u Iron ND 260 200 microgL 20 F20327l 2C22005 032212 EPA 2008 Mod u Lead ND 0078 0800 microgL 20 F20327l 2C22005 032212 EPA 2008 Mod u Manganese 280 015 200 microgL 20 F203271 2C22005 032212 EPA 2008 Mod Molybdenum 134 012 120 microgL 20 F20327I 2C22005 032212 EPA 2008 Mod Nickel 979 016 2 00 microgL 20 F203271 2C22005 032212 EPA 2008 Mod Silver ND 0120 0400 microgL 20 F203271 2C22005 032212 EPA 2008 Mod u Sodium 259000 23 400 microgL 20 F203271 2C22005 032212 EPA 2008 Mod Thallium 556 0250 100 microgL 100 F203314 2C25005 032512 EPA 2008 Mod Zinc ND 033 400 microgL 20 F203271 2C22005 032212 EPA 2008 Mod u
Frontier Global Sciences Inc The middotesults in 1his report only apply to the samples analyzed in accordance wilh 11e chain ofcus1ody documem This analytical report must be reproduced in ifs entirety
Page 4of26 1201073 Final Report 04252012 6
Liz Siska Project Manager
11720 North Creek Parkway North Suite 400 Bothell WA 98011
Ph 425-686-1996 Fx 425-686-3096
GLOBAt SCIENCES
ANALYTICAL RESULTS
Treat Tank Eff Grab
Matrix Water Laboratory ID 1201073-02
Analyte Result MDL MRL Units Dilution Batch Sequence Analyzed Method Notes
Arsenic 851 102 300 microgL 20 F203271 2C22005 032212 EPA 2008 Mod Mercury 105 034 202 ngL 4 F20I063 2A09010 010912 EPA 1631E FB-1631 Selenium 689 388 120 microgL 20 F203271 2C22005 032212 EPA 2008 Mod
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcustody documenJ This analycical report must be reproduced in its entirety
Page 5 o261201073 Final Report 04252012 7
Liz Siska Project Manager
FRONTIERshycLoaAt SCI ENCES
11720 North Creek Parkway North Suite 400 Bothell WA 98011
Ph 425-686-1996 Fx 425-686-3096
MATRIX DUPLICATESfRIPLICATES
SOURCE 1201073-02
Batch F201063
Preparation BrCI Oxidation
Sequence 2A09010
Lab Number F201063-DUPI
Sample Duplicate Concentration Concentration RPD
Analyte ngL ngL MRL RPD Limit Method Notes Mercury 1048 1054 202 0617 24 EPA I631E
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Page 6of26 1201073 Final Report 04252012 8
11720 North Creek Parkway North Suite 400 BotheE WA 980 l l
Ph 425-686-1996 Fx 425-686-3096
GLOBAL SCIENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1201073-02
Batch F201063 Sequence 2A09010
Preparation BrCI Oxidation Lab Number F20 l 063-MSMSDl
Sample Spike MS MS Concentration Added Concentration RecoveryAnalyte (ngL) (ngL) (ngL) Recovery Method Limits Notes
Mercury 1048 20400 3136 102 71 125 EPA 163IE
Spike MSD MSD Added Concentration oo Recovery RPD
RPD Limits Limit Method Notes Analyte (ngL) (ngL) Recovery
Mercury 20400 2708 814 147 71 - 125 24 EPA 1631E
shy
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Page 7 o26Liz Siska Project Manager 120JO7 3 Final Repo1
04252012 9
Liz Siska Project Manager
11720 North Creek Parkway North Suite 400 Bothell WA 98011
Ph 425-686-1996~ Fx 425-686-3096 CL06AL SCIENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1112278-02
Batch F201063 Sequence 2A09010
Preparation BrCI Oxidation Lab Number F20 l 063-MSMSD2
Sample Spike MS MS
Analyte Concentration
(ogL) Added (ngL)
Concentration (ngL)
Recovery
RecoveryLimits Method Notes
Mercury 761 20400 2786 992 71 125 EPA 1631E
Spike MSD MSD Added Concentration Oo Recovery RPO
Analyte (ngL) (ngL) Recovery RPO Limits Limit Method Notes
Mercury 20400 2837 102 182 71 - 125 24 EPA l631E
shy
Frontier Global Sciences Inc The results in this report only apply to the somples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Page 8 o26 1201073 Final Report 042512012 10
11720 North Creek Parkway North Suite 400 Bothell WA 980 l l
Ph 425-686-1996 ~ Fx 425-686-3096 GLOBAL SCIENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1201029-01
Batch
Preparation
F201063
BrCI Oxidation
Sequence
Lab Number
2A09010
F20 I 063-MSMSD3
Analyte
Mercury
Analyte
Mercury
Sample Spike Concentration Added
(ngL) (ngL)
534 10200
Spike MSD Added Concentration (ngL) (ngL)
10200 1407
MS MS Concentration Recovery
(ngL) Recovery Limits
1558 JOO 7l shy 125
MSD oo Recovery RPD
Recovery RPD Limits Limit
856 102 71 - 125 24
Method
EPA l63lE
Method
EPA 631E
Notes
Notes
Frontier Global Sciences Inc The results in this repon only apply to rhe samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Page 9of26 1201073 Final Report 041252012
Liz Siska Project Manager
1 1
11720 North Creek Parkway North Suite 400 Bothell WA 98011
Ph 425-686-1996 FRONTIER- Fx 425-686-3096 cLosAL SCIENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1201030-02
Batch F20I063 Sequence 2A09010
Preparation BrCI Oxidation Lab Number F201063-MSMSD4
Sample Spike MS MS Concentration Added Concentration RecoveryAnalyte (ngL) (ngL) (ngL) Recovery MethodLimits Notes
Mercury 554 10200 1482 910 71 - 125 EPA I631E
Spike MSD MSD Oo Added Concentratio11 Recovery RPD
RPD Limits Limit Method Analyte (ngL) (ngL) Recovery Notes
Mercury 10200 1461 890 140 71 - 125 24 EPA 163IE
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed m accordance with the chain ofcus1ody document This anayt(ca repon must be reproduced in itr entirety
Page lOo26Liz Siska Project Manager 1201073 Final Report
041252012 12
I 1720 North Creek Parkway North Suite 400 Bothe I I WA 98011
Ph 425-686-1996 ~ Fx 425-686-3096 GLOBAL SCIENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1201073-01RE3
Batch F20327l Sequence 2C22005
Prcpa ration ((01ed Vessel ~ itric Oven Digestion Lab Number F203271-MSMSD 1
Analyte
Sample Concentration
(microgL)
Spike Added (microgL)
MS Concentration
(microgL)
MS Oo
Recovery Recovery
Method Limits Notes
Calcium 5013000 15150 4802000 -13900 70- 130 EPA 2008 Mod QM-02
Analyte
Spike Added (microgL)
MSD Concentration
(microgL)
MSD ~o
Recovery
Oo
RPD Recovery
Limits RPDLimit Method Notes
Calcium 15150 4943000 -4600 289 70 - 130 20 EPA 2008 Mod QM-02
Frontier Global Sciences Inc The results in this report only apply to the samples analyud inaccordance with the chain ofcustody document 17is analyticol report must be reproduced in its entirety
Page lI o16 1101073 Final Report 04152012
Liz Siska Project Manager
13
l l 720 North Creek Parkway North Suite 400 Bothell WA 98011
Ph 425-686-1996FRONTIER Fx 425-686-3096 GLOBAL SCIENCES
MATRIX SPIKE I MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1201073-01RE4
Batch F203271 Sequence 2C22005
Preparation Closed Vessel Nitric Oven Digestion Lab Number F203271-MSMSD2
Sample Spike MS MS Concentration Added Concentration Oo RecoveryAnalyte (microgL) (microgL) (microgL) Recovery Method Limits Notes
Beryllium 0507 20200 2442 958 70 - 130 EPA 2008 Mod Sodium 258800 50500 257700 -213 70 -130 EPA 2008 Mod QM-02 Aluminum 529 15150 2023 986 70 - 130 EPA 2008 Mod Chromium 057 70700 804 106 70 - 130 EPA 2008 Mod Manganese 2805 60600 2834 476 70 - 130 EPA 2008 Mod QM-02 Iron ND 50500 5200 103 70 130 EPA 2008 Mod Nickel 979 40400 141 l 107 70- 130 EPA 2008 Mod Copper 055 40400 434 939 70 - 130 EPA 2008 Mod Zinc 040 10100 842 794 70 - 130 EPA 2008 Mod Arsenic 1030 15150 2418 916 70 - 130 EPA 2008 Mod Selenium 6340 30300 8973 869 70 130 EPA 2008 Mod Molybdenum 1338 20200 1367 142 70 130 EPA 2008 Mod QM-02 Silver ND 15150 1388 916 70 - 130 EPA 2008 Mod Cadmium 0332 080800 1105 middot956 70 - 130 EPA 2008 Mod Antimony 0408 080800 1259 105 70- 130 EPA 2008 Mod Barium 2397 10100 2495 968 70 - 130 EPA 2008 Mod Lead ND 15150 1542 102 70 130 EPA 2008 Mod
shy
shy
shy
shy
Analyte
Spike Added (microgL)
MSD Concentration
(microgL)
MSD Oo
Recovery
Oo
RPD Recovery
Limits RPD Limit Method Notes
Beryllium
Sodium
Aluminum
Chromium
Manganese
Iron
Nickel
Copper
Zinc
Arsenic
Selenium
Molybdenum
20200
50500
15150
7Q700
60600
50500
40400
40400
10100
15150
30300
20200
2561
257100
2034
773
2852
5187
1381
419
916
2225
9400
1366
102
-336
993
101 769
103
995
902
868
789
101
137
474
0243
0564
385
0625
0242
213
347
849
831
464
00771
70 - 130
70 bull 130 70 - 130
70 - 130
70 - 130
70 - 130
70 - 130
70 - 130
70 - 130
70 bull 130 70 - 130
70 - 130
20
20
20
20
20
20
20
20
20
20
20
20
EPA 2008 Mod
EPA 2008 Mod
EPA 2008 Mod
EPA 2008 Mod
EPA 2008 Mod
EPA 2008 Mod
EPA 2008 Mod
EPA 2008 Mod
EPA 2008 Mod
EPA 2008 Mod
EPA 2008 Mod
EPA 2008 Mod
QM-02
QM-02
Frontier G lobal Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
--f_~ --~~~-~ -middot middot Page 12 o261201073 Final Report 041252012
Liz Siska Project Manager
14
11720 North Creek Parkway North Suite 400
~ Bothell WA 98011
~TIEmiddot Ph 425-686-1996 Fx 425-686-3096
GLOB11L SCIENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPO
SOURCE 1201073-01RE4
Batch F203271 Sequence 2C22005
Preparation ~lo~ed Vessel Nitric Oven Digestion Lab Number F20327 I-MSMSD2
Spike MSD MSD Added Concentration Oo Recovery RPO
Analyte (microgL) (microgL) Recovery RPD Limits Limit Method Notes
Silver 15150 1387 915 00874 70 - 130 20 EPA 2008 Mod Cadmium 080800 1061 902 403 70 - 130 20 EPA 200amp Mod Antimony 080800 1274 107 l2l 70 - 130 20 EPA 2008 Mod Barium 10100 2514 )16 0781 70 - 130 20 EPA 200amp Mod Lead 15150 1534 101 0525 70 shy 130 20 EPA 2008 Mod
Frontier Global Sciences Inc The results in this report only apply to 1he samples analyzed in accordance wiih the chain ofcustody document This analytical repo1 must be reproduced in ils entirety
Page 13 o26Liz Siska Project Manager 1201073 Final Reporl
04252012 15
11720 North Creek Parkway North Suite 400
~ Bothell WA 98011 Ph 425-686-I996
~RONTIER~ Fx 425-686-3096 GLOBAL SCIEN C ES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1201073-01RE3
Batch F203271 Sequence 2~22005
Preparation Closed Vessel Nitric Oven Digestion Lab Number F20327 I-MSMSD3
Sample Spike MS MS
Analyte Concentration
(microgL) Added (microgL)
Concentration (microgL) Recovery
Recovery Limits Method Notes
Calcium 5013000 10100000 15120000 100 70- 130 EPA 2008 Mod AS
Spike MSD MSD Added Concentration o Oo Recovery RPD
Analyte (microgL) (microgL) Recovery RPD Limits Limit Method Notes
Calcium 10100000 16140000 llO 653 70 - 130 20 EPA 2008 Mod AS
Frontier Global Sciences Inc The results in his report only apply 10 the samples analyzed in accordance ivth he chain ofcustody document This analytical report must be reproduced in its entirety
Page 14 o261201073 Final Report 0425201]
Liz Siska Project Manager
16
Frontier Global Sciences Inc The ruults in this rechain ofcustody do
~ -lt1-c--~ Liz Siska Project Manager
11720 North Creek Parkway North Suite 400 Bothell WA 98011
Ph 425-686-1996 Fx 425-686-3096
GLOBAL SCIENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1201073-01RE4
Batch J203271 Sequence 2C22005
Preparation ~ IQsed Ve~~el Nitric Oven Qigestion Lab Number F203271-MSMSQ4
Analyte
Beryllium
Sample Concentration
(11gL)
0507
Spike Added (11gL)
20200
MS Concentration
(microgL)
2041
MS Oo
Recovery
985
RecoveryMethod Limits
70 - 130 EPA 2008 Mod
Notes
AS
Sodium 258800 40400 292900 845 70- 130 EPA 2008 Mod AS
Aluminum 529 40400 3956 966 70 - 130 EPA 2008 Mod AS
Chromium 057 40400 430l 106 70- 130 EPA 2008 Mod AS
Manganese 2805 40400 7042 105 70 - 130 EPA 2008 Mod AS
Iron ND 20200 2121 105 70 - 130 EPA 2008 Mod AS
Nickel 979 50500 5112 993 70 l30 EPA 2008 Mod AS
Copper 055 50500 4754 940 70 - 130 EPA 2008 Mod AS
Zinc 040 10100 9074 898 70 - 130 EPA 2008 Mod AS
Arsenic 1030 40400 4317 104 70 130 EPA 2008 Mod AS
Selenium 6340 40400 4688 100 70 - 130 EPA 2008 Mod AS
Molybdenum 1338 20200 338l 101 70 - 130 EPA 2008 Mod AS
Silver ND 20200 1850 916 70 130 EPA 2008 Mod AS
Cadmium 0332 40400 3937 966 70 130 EPA 2008 Mod AS
Antimony 0408 20200 2091 102 70 - 130 EPA 2008 Mod AS
Barium 2397 80800 1056 101 70- 130 EPA 2008 Mod AS
Lead ND IO100 9932 983 70 130 EPA 2008 Mod AS
shy
shy
shy
shy
shy
Analyte
Spike Added (microgL)
MSD Concentration
(microgL)
MSD
Recovery
RPD
Recovery Limits
RPDLimit Method Notes
Beryllium 20200 2007 968 l71 70 - 130 20 EPA 2008 Mod AS Sodium 40400 292600 837 0114 70 130 20 EPA 2008 Mod AS Aluminum 40400 3954 966 00362 70 - 130 20 EPA 2008 Mod AS Chromium 40400 4287 106 0337 70 - 130 20 EPA 2008 Mod AS Manganese 40400 6944 102 140 70 - 130 20 EPA 2008 Mod AS Iron 20200 2077 103 211 70 - 130 20 EPA 2008 Mod AS Nickel 50500 5126 996 0276 70 - 130 20 EPA 2008 Mod AS Copper 50500 4707 931 0997 70 - 130 20 EPA 200 8 Mod AS Zinc 10100 9059 896 0166 70 - 130 20 EPA 2008 Mod AS Arsenic 40400 4299 104 0419 70 - 130 20 EPA 2008 Mod AS Selenium 40400 4682 100 0141 70 - 130 20 EPA 2008 Mod AS Molybdenum 20200 3365 100 0473 70 - 130 20 EPA 2008 Mod AS
shy
port only apply to the sampltts analyzed in accordance with the cument This analytical report must be reproduced in its entirety
Page 5 o26 201073 Final Report 042512012 17
Liz Sia Project Manager
11720 North Creek Parkway North Suite 400 Botheln VA 98011
Ph 425-686-1996 Fx 425-686-3096
CLOBAL SCIENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1201073-01RE4
Batch F203271 Sequence 2c2io2~
Preparation Clo~ed Vessel litric Oven Digestion Lab Number F20327 l -MSMSQ4
Analyte
Spike Added (microgL)
MSD Concentration
(microgL)
MSD
Recovery
Oo
RPD Recovery
Limits RPOLimit Method Notes
Silver 20200 1895 938 242 70 - 130 20 EPA 2008 Mod AS Cadmium 40400 3933 965 0104 70 -130 20 EPA 2008 Mod AS Antimony 20200 2107 102 0736 70- 130 20 EPA 2008 Mod AS
Barium 80800 1058 101 0205 70 - 130 20 EPA 2008 Mod AS
Lead 10100 9877 978 0549 70 - 130 20 EPA 2008 Mod AS
Frontier Global Sciences Inc The results in this report only apply to the samples analyudin accordance with lht chain ofcustody document This analytical report must be reproductd rn ilS enlirtty
Page l6of26 1201073 Final Report Ofn5202 18
l I 720 North Creek Parkway North Suite 400 Bothell WA 980I I
Ph 425-686-1996 Fx 425-686-3096
GLO B AL SCIENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1201073-01RE6
Batch F203314 Sequence 2C25005
Preparation Closed Vessel Nitric Oven Digestion Lab Number F203314-MSMSD2
Sample Spike MS MS Concentration Added Concentration RecoveryAnalyte (microgL) (microgL) (microgL) Recovery Method NotesLimits
Thallium 5563 040400 5875 773 70 - 130 EPA 2008 Mod
Spike MSD MSD Added o Concentration Recovery RPD
RPO Limits Limit Method Notes Analyte (microgL) (microgL) Recovery
Thallium 040400 5880 785 00859 70 - 130 20 EPA 2008 Mod
Frontier Global Sciences Inc 11e results in chis reporc only apply 10 1he samples analyzed in accordance wilh lhe chain ofcustody documenz This analycical report musl be reproduced in ils entirety
Page 17 of26 1201073 Fi11aReport 0412512012
Liz Siska Project Manager
19
11720 North Creek Parkway North Suite 400 Bothell WA 98011
Ph 425-686-1996 Fx 425-686-3096
GLOBAl SCIENC ES
MATRIX SPIKE I MATRIX SPIKE DUPLICATE RECOVERY AND RPO
SOURCE I201073-01RE6
Batch F203314
Preparation Closed Vessel Nitric Oven Digestion
Sequence 2C25005
Lab Number F203314-MSMSD4
Analyte
Sample Concentration
(microgL)
Spike Added (microgL)
MS MS Concentration Oo
(microgL) Recovery Recovery
Limits Method Notes
Thallium 5563 10100 1033 968 70- 130 EPA 2008 Mod AS
Analyte
Spike Added (microgL)
MSD Concentration
(microgL)
MS)) Oo
Recovery
RPD
Recovery Limits
RPD Limit Method Notes
Thallium IO100 1037 97l 0341 70 - 130 20 EPA 2008 Mod AS
Frontier Global Sciences Inc The resulrs in this report only apply to the samples analyzed in accordance with the chain ofcusrody document This analytical report must be reproduced in its entirely
Page 18of26 120073 Final Report 04252012
Liz Siska Project Manager
20
11720 North Creek Parkway North Suite 400 l ~ Bothell WA 980 l l Ph 425-686-1996
FRONTIER Fx 425-686-3096 GLOBAL SCIENCES
LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLICATE
RECOVERY AND RPD
Batch F20 l063 Sequence 2A09010
Preparation BrCI Oxidation Lab Number F201063-BSIBSJ21
LCS Source N ist 1641d
Analyte
Spike Added (ngL)
LCS Concentration
(ngL)
LCS
Recovery Recovery
Limits Method Notes
Mercury 15679 1550 988 80 - 120 EPA I631E
Analyte
Spike Added (ngL)
LCSD Concentration
(ngL)
LCSD Oo
Recovery
RPD Recovery
Limits RPD Limit Method Notes
Mercury 15679 1595 [02 289 80 - 120 24 EPA I631E
Frontier Global Sciences Inc The results in this report only apply to the samples analyzedin accordance with the chain ofcustody document This analytical report must be reproduced in ils entirety
Page 19of26 1201073 Final Report 0425 2012
Liz Siska Project Manager
21
11720 North Creek Parkway North Suite 400 Bothell WA 98011
Ph 425-686-1996 FRONTIER Fx 425-686-3096 GLOBAL SCIENCES
LABORA TORY CONTROL SAMPLE LABO RATORY CONTROL SAMPLE DUPLICATE
RECOVERY AND RPD
Batch F203271 Sequence 2C22005
Preparation Closed Vessel Nitric Oven Digestion Lab Number F203271-BSBSD1
LCS Source Blank Spike
Spike LCS LCS Added Concentration Oo Recovery
Analyte (microgL) (microgL) Recovery Limits Method Notes
Beryllium 20000 l930 965 85 - 115 EPA 2008 Mod
Sodium 50000 499 998 85 - 115 EPA 2008 Mod
Aluminum 15000 1460 973 85 - 115 EPA 2008 Mod
Calcium 15000 1528 102 85 - 115 EPA 2008 Mod
Chromium 70000 657 939 85 - 115 EPA 2008 Mod
Manganese 60000 586 976 85 - 115 EPA 2008 Mod
Iron 50000 4753 951 85 shy 115 EPA 2008 Mod
Nickel 40000 401 100 85 - 115 EPA 2008 Mod
Copper 40000 418 105 85 - 115 EPA 2008 Mod
Zinc 10000 1033 103 85 - 115 EPA 2008 Mod
Arsenic 15000 1437 958 85 - 115 EPA 2008 Mod
Selenium 30000 2966 989 85 - 115 EPA 2008 Mod
Molybdenum 20000 181 905 85 shy 115 EPA 2008 Mod
Silver 15000 1517 101 85 shy 115 EPA 2008 Mod
Cadmium 080000 0781 976 85 - 1lS EPA 2008 Mod
Antimony 080000 0815 102 85 - 115 EPA 2008 Mod
Barium 10000 969 969 85 - 115 EPA 2008 Mod
Lead 15000 1597 106 85 - 115 EPA 2008 Mod
Spike LCSD LCSD Added Concentration Recovery RPO
Analyte (microgL) (microgL) Recovery RPO Limits Limit Method Notes
Beryllium 20000 1949 974 0955 85 - 115 20 EPA 2008 Mod
Sodium 50000 500 100 0216 85 - 115 20 EPA 2008 Mod
Aluminum 15000 1485 990 171 85 - 115 20 EPA 2008 Mod
Calcium 15000 1544 103 103 85 - 115 20 EPA 2008 Mod
Chromium 70000 667 953 148 85 - 115 20 EPA 2008 Mod
Manganese 60000 596 994 175 85 - 115 20 EPA 2008 Mod
Iron 50000 4852 970 206 85 - 115 20 EPA 2008 Mod
Nickel 40000 402 IOI 0246 85 - 115 20 EPA 2008 Mod
Frontier Global Sciences Inc The results in his report only apply to the samples analyzed in accordance wirh the chain ofcustody document This analytical report must be reproduced in iLS entirety
Page 20of26 1201073 Final Report 04252012
Liz Siska Project Manager
22
11720 North Creek Parkway North Suite 400 ~~shy Bothell WA 98011 Ph 425-686-1996~ONTif Fx 425-686-3096
GLOBAL SCIENCES
LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLICATE
RECOVERY AND RPO
Batch F20327 l Sequence 2C22005
Preparation Closed Vessel Nitric Oven Digestion Lab Number F203271-BSBSD 1
LCS Source Blank Spike
Analyte
Spike Added (microgL)
LCSD Concentration
(microgL)
LCSD oo
Recovery
RPO Recovery
Limits RPO Limit Method Notes
Copper
Zinc
Arsenic
Selenium
40000
10000
15000
30000
428
1039
1452
3015
107
104
968
101
224
0570
0977
166
85 - 115
85 - 115
85 - 115
85 - 115
20
20
20
20
EPA 2008 Mod
EPA 2008 Mod
EPA 2008 Mod
EPA 2008 Mod Molybdenum
Silver
20000
15000
182
J502
910
100
0564
103
85 - 115
85 - 115
20
20
EPA 2008 Mod
EPA 2008 Mod Cadmium
Antimony
Barium
Lead
080000
080000
10000
15000
0828
0808
986
1620
103
101
986
108
585
0848
177
142
85 - 115
85 - 115
85 shy 11 S
85 - 115
20
20
20
20
EPA 2008 Mod
EPA 2008 Mod
EPA 2008 Mod
EPA 2008 Mod
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report mus be reproducedin its entirety
Page 2 o26J20J073 Final Report 041252012
Liz Siska Project Manager
23
11720 North Creek Parkway North Suite 400 Bothell WA 980 l l
Ph 425-686-1996FRONT[ER- Fx 425-686-3096 cLosAL SCIEN _CES
LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLICATE
RECOVERY AND RPD
Batch F203314 Sequence 2C25005
Preparation Closed Vessel Nitric Oven Digestion Lab Number F2033 l 4-BSBSD 1
LCS Source Blank Spike
Analyte
Thallium
Spike Added (microgL)
LCS Concentration
(microgL)
LCS 0o
Recovery Recovery
Limits Method
040000 0396 989 85 - 115 EPA 2008 Mod
Notes
Analyte
Spike Added (microgL)
LCSD Concentration
(microgL)
LCSD 0o
Recovery
RPD Recovery
Limits RPO Limit Method Notes
Thallium 040000 0391 978 112 85 - ll5 20 EPA 2008 Mod
Frontier Global Sciences Inc The results in this report only apply to the samples anayed in accordance with the chain ofcustody docwnenJ This analytical report must be reproduced in its entirety
Page 22of26 1201073 Final Report 04252012
Liz Siska Project Manager
24
Liz Siska P roject Manager
11720 North Creek Parkway North Suite 400
~ Bothell WA 98011 Ph 425-686-1996
~JTIEif middot Fx 425-686-3096 GLOBAL SCIENCES
PREPARATION BLANKS
Instrument Hg-17 Sequence 2A09010
Preparation BrCI Oxidation
Lab Sample ID Analyte Found MRL Units Batch Method Notes
F201063-BLK I Mercury -0009 050 ngL F201063 EPA 1631E u F20 I063-BLK2 Mercury -0006 050 ngL F201063 EPA 1631E u F201063-BLK3 Mercury -002 050 ngL F201063 EPA 163IE u F201063-BLK4 Mercury 003 050 ngL F201063 EPA 1631E U QB-04 F201063-BLKS Mercury 011 052 ngL F201063 EPA I631E U QB-06
Frontier Global Sciences Inc The results in this report only apply 10 1he samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Page 23 o26 1201073 Final Repon 04252012 25
Liz Siska Project Manager
11720 North Creek Parkway North Suite 400 Bothell WA 98011
Ph 425-686-1996 FROr~TIER- Fx 425-686-3096 GLOBAL SCIENCES
PREPARATION BLANKS
Instrument ICPMS-6 Sequence 2C22005
Preparation Closed Vessel Nitric Oven Digestion
Lab Sample ID Analyte Found MRL Units Batch Method Notes
F203271-BLK1 Beryllium 000008 0060 microgL F203271 PA 2008 Molt u F20327 1-BLK1 Sodium 2 20 microgL F20327l PA 2008 Moc u F20327I-BLK1 Aluminum -004 40 microgL F203271 PA 2008 Molt u F20327I -BLK1 Calcium 40 microgL F203271 PA 2008 Molt u F203271 -BLK1 Chromium -002 010 microgL F203271 ~A 2008 Molt u F203271-BLKI Manganese 001 010 microgL F203271 PA 2008 Molt u F20327 l -BLK 1 Iron -002 100 microgL F203271 PA 2008 Molt u F203271-BLKI Nickel 0004 010 microgL F203271 PA 2008 Moc u F203271-BLK1 Copper 0003 010 microgL F203271 PA 2008 Moc u F203271-BLK1 Zinc 0007 020 microgL F203271 PA 2008 Moc u F203271-BLK1 Arsenic -006 015 microgL F203271 PA 2008 Moc u F203271-BLK1 Selenium -002 060 microgL F203271 PA 2008 Moc u F203271-BLK1 Molybdenum 001 006 microgL F203271 PA 2008 Molt u F203271-BLK1 Silver -00005 0020 microgL F203271 PA 2008 Molt u F203271-BLKl Cadmium 0004 0020 microgL F203271 PA 2008 Molt u F20327 l-BLKl Antimony 0002 0020 microgL F203271 PA 2008 Molt u F203271-BLKI Barium 001 020 microgL F203271 PA 2008 Molt u F203271-BLKI Lead 0010 0040 microgL F203271 PA 2008 Moc u
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Page 24of26 1201073 Final Report 04252012 26
~
~TIER~ GLOBAL SCIENCES
11720 North Creek Parkway North Suite 400 Bothell WA 980ll
Ph 425-686-1996 Fx 425-686-3096
PREPARATION BLANKS
Instrument JCPMS-3 Sequence 2C25005
Preparation Closed Vessel Nitric Oven Digestion
Lab Sample ID Analyte Found MRL Units Batch Method Notes
F2033I4-BLK1 Thalium 00007 0010 microgL F2033I4 ~PA 2008 Molt u
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Page 25 o26Liz Siska Project Manager 1201073 Final Report
04252012 27
l l 720 North Creek Parkway North Suite 400~Vi-~ Bothell WA 98011 Ph 425-686-1 996~Tlmiddot~ Fx 425-686-3096
G L OBAL SCIENCE S
Notes and Definitions
U Analyte included in the analysis but not detected
QM-02 The MS andor MSD recoveries outside acceptance limits due to spike concentration less than I times the sample concentration The batch was accepted based on LCS and LCSD recoveries within control limits and when analysis permits acceptable AS ASD
QB-06 The blank was preserved to 5 BrCI rather than I The control limit for blanks preserved to greater than 1 BrCl is the preservation percentage multiplied by the MRL
QB-04 The blank was preserved to 2 BrCI rather than l The control limit for blanks preserved to greater than l BrCI is the preservation percentage multiplied by the MRL
FB-1631 Required equipmentfieldfilter blank not submitted by the client The sample has been analyzed according to 163 lE but does not meet 163 lE criteria
AS This MS andor MSD is an analytical spike andor an analytical spike duplicate
DET Analyte Detected
MDL Minimum Detection Limit
MRL Minimum Reporting Limit
ND Analyte Not Detected at or above the reporting limit
wet Sample results reported on a wet weight basis
dry Sample results reported on a dry weight basis
RPO Relative Percent Difference
RSD Relative Standard Deviation
Frontier Global Sciences Inc The lesults i111his reporl only apply to he samples analyzed In accordance with the chain ofcuslody document This analytical report must be reproduced in its entirely
Page 26of26 1201073 Final Report 04252012
Liz Siska Project Manager
28
CHAIN-OF-(USTODY ttECORD Page i of f 106677 _J
BoLD F1ELDS REQUIRED PLEASE C 1RCLE REQUESTED ANALYSIS
SAMPLE ID
middoti-rg -- bull ~rshy~ _- tzir +- lt-ltJ~ lt
SAMPLING
DATeTtME
IF COMPOSITE INDICATE BOTH
START amp FINISH
DATETIME li1J oc -r 111_- _vlt-c_
w Ishyt 0 n
w l w 0 ~ u X -Xmiddot ~ m Ishy lt( lt( 0
I C)
IIXJ JC
~ ~ irlte-t- T_ t- f r-n t I s-11 middott~ c~ J J1~w )(~ )
Trttbull rin K C-~-~ pound1t I 1Jtl~ t20~L lwlJI ishy
middot~ON Mm1x A-Al~ S-SOil GW-GampOUHO WATER SW-SUampfA(f WATER DWmiddotDRIIIKIKlti WATER
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PROJECT MANAGER llr middot1 ~Q Aw4---P1V- Het_ r COMPANY t-lo--tm ~ bd i ( I ~j 6 A ADP~SS 91 g~ez tJshy(ITJ ~ STATE fH_ ZIP c3o--
PHONE 22j-((omiddotf EXT ____
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PROJECT _
OTHEi________STATpound NH MA ME VT
REGULATORY PROGRAM NPDES RGP POTW STORHWATEl OR
GWP OIL FUHD BROWNIIELO OR OTHER----------
Quon PO o2J~-lt1Jpound)
DATE NEEDED _1--1 middot Z=-----shy4 (1-1_ METALS 8 RCRA 13 pp ff MN PB Cu
QAQC REPORTJNGYVEL
A CG) O R
PRESUMPTIVE CERTAINTY
7i2lt_
RECpound1VEO BYRELINQUISHED BY DATE TIME SUSPECTED (OHTAHIHATIOH________
TEHP~ C REPORTING OPTIONS 01HEA METAL------------PRELIHl Yu OR No
DISSOLVED METALS FIELD FllTEREDI YES 110
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IF YH FAX OR POf 7~shy Hom (IE SPECIAL DETECTION LINITl BllLIKGINfO If DlffERrnT)ELECTRONIC OPTIONS zo 1 2 2) le~C1 1 Jc Id sJ 60 6c
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ImiddotRELINQUISHED BY DATE TIHE RECflVEO BY I FIELD READINGS
eastern analytical inc 2s CHENELL D R1ve IC 0 Nco1to N H 0330 1 I TEL 60J22aos2s 1aoo2a1os2s IFAx 6032284591 j E-MA1t cus-roM111_mV1c~EAILAsscoMJ www1A1LAascoM
----i pmiddotofissionrrl11bomtorymim (WHITE ORIGINAL GREEN PROJECT MANAGER)
shy
GLOBAL SCIENCES
11720 North Creek Parkway North Suite 400 Bothell WA 98011
Ph 425-686-1996 Fx 425-686-3096
ANALYTICAL REPORT FOR SAMPLES
Laboratory Frontier Global Sciences Inc SDG
Client Eastern Analytical Inc Project Merrimack Station
Sample ID Lab ID Matrix Date Sampled Date Received
Treat Tank EffComposite 1201073-01 Water 05-Jan-12 1000 06-Jan-12 0950
Treat Tank EffGrab 1201073-02 Water 05-Jan-12 0800 06-Jan-12 0950
Frontier Global Sciences Inc
Liz Siska Project Manager
The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Page 1 o261201073 Final Report 04252012 3
11720 North Creek Parkway North Suite 400 Bothell WA 98011
Ph 425-686-1996FRONTIER Fx 425-686-3096 GLOBAL SCIENCES
CASE NARRATIVE
Revised Report 42512
Per client request Boron was removed from report
Revised Report 32812
Per client request samples were prepared and analyzed for total metals in accordance with EPA 2008 (modified)
SAMPLE RECEIPT
Samples were received at Frontier Global Sciences (FGS) on January 6th 2012 The samples were received intact on-ice with temperatures measured at 34 degrees Celsius
SAMPLE PREPARATION AND ANAL YSJS
Samples were prepared and analyzed for total metals in accordance with FGS-054EPA 1638
Samples were prepared and analyzed for total mercury in accordance with EPA Method 163JE
ANALYTICAL AND QUALITY CONTROL IS SUES
There were no analytical difficulties experienced with analysis of these samples with the exceptions flagged in the report
Frontier Gtobal Sciences Inc The results in this reporr only apply 10 the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Liz Siska Project Manager Page 2of26 J20I073 Final Report 042512012 4
11720 North Creek Parkway North Suite 400 Bothell WA 98011~ Ph 425-686-1996 FRONTIER Fx 425-686-3096
GLOBAL SCIENCES
CHAIN OF CUSTODY FORMS
CML-1d Cc-t~lt7 shy~P~fci amp l sbtr3~~ry Aillylc P~ctirst J- ~V~-=lt S=-Jit=~1t Imiddot~ and 4J~~ Tssul
~ r~middotmiddotmiddot to ~-~ middot ~ ~middot ~rcshyr-11 ---4i--5~1-shy
y1tcirc1middot 6middot 01gter S1bulli1e
1 1 -middot shy
~middot-middotn middot~i---it =-middotmiddotrmiddot~-~r9ft~ri r s L lrj~JT ~- bull 1r bullermiddot~~(~lr- rlt-bull~~~~~ _ -tbull ~t-tmiddotbull I~ bull 1
middot middot l~~e ~middot rv~ 8Arvmiddott _ -middot
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report mus be reproduced in ilS entirety
Page3of26Liz Siska Project Manager 1201073 Final Report
041252012 5
Liz Siska Project Manager
11720 North Creek Parkway North Suite 400 Bothell WA 98011
Ph 425-686- 1996 ~ Fx 425-686-3096 G LOB A L SC I EN CE S
ANALYTICAL RESULTS
Treat Tank Eff Composite
Matrix Water Laboratory ID 1201073-01
Analyte Result MDL MRL Units Dilution Batch Sequence Analyzed Method Notes
Aluminum ND 89 800 microgL 20 F203271 2C22005 032212 EPA 2008 Mod u Antimony 0408 0092 0400 microgL 20 F20327l 2C22005 032212 EPA 2008 Mod Barium 240 054 400 microgL 20 F203271 2C22005 032212 EPA 2008 Mod Beryllium ND 0454 t20 microgL 20 F203271 2C22005 032212 EPA 2008 Mod u Cadmium ND 0083 0400 microgL 20 F203271 2C22005 032212 EPA 2008 Mod u Calcium 5010000 16200 200000 microgL 5000 F203271 2C22005 032212 EPA 2008 Mod Chromium ND 018 200 microgL 20 F20327I 2C22005 032212 EPA 2008 Mod u Copper ND 020 200 microgL 20 F203271 2C22005 032212 EPA 2008 Mod u Iron ND 260 200 microgL 20 F20327l 2C22005 032212 EPA 2008 Mod u Lead ND 0078 0800 microgL 20 F20327l 2C22005 032212 EPA 2008 Mod u Manganese 280 015 200 microgL 20 F203271 2C22005 032212 EPA 2008 Mod Molybdenum 134 012 120 microgL 20 F20327I 2C22005 032212 EPA 2008 Mod Nickel 979 016 2 00 microgL 20 F203271 2C22005 032212 EPA 2008 Mod Silver ND 0120 0400 microgL 20 F203271 2C22005 032212 EPA 2008 Mod u Sodium 259000 23 400 microgL 20 F203271 2C22005 032212 EPA 2008 Mod Thallium 556 0250 100 microgL 100 F203314 2C25005 032512 EPA 2008 Mod Zinc ND 033 400 microgL 20 F203271 2C22005 032212 EPA 2008 Mod u
Frontier Global Sciences Inc The middotesults in 1his report only apply to the samples analyzed in accordance wilh 11e chain ofcus1ody documem This analytical report must be reproduced in ifs entirety
Page 4of26 1201073 Final Report 04252012 6
Liz Siska Project Manager
11720 North Creek Parkway North Suite 400 Bothell WA 98011
Ph 425-686-1996 Fx 425-686-3096
GLOBAt SCIENCES
ANALYTICAL RESULTS
Treat Tank Eff Grab
Matrix Water Laboratory ID 1201073-02
Analyte Result MDL MRL Units Dilution Batch Sequence Analyzed Method Notes
Arsenic 851 102 300 microgL 20 F203271 2C22005 032212 EPA 2008 Mod Mercury 105 034 202 ngL 4 F20I063 2A09010 010912 EPA 1631E FB-1631 Selenium 689 388 120 microgL 20 F203271 2C22005 032212 EPA 2008 Mod
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcustody documenJ This analycical report must be reproduced in its entirety
Page 5 o261201073 Final Report 04252012 7
Liz Siska Project Manager
FRONTIERshycLoaAt SCI ENCES
11720 North Creek Parkway North Suite 400 Bothell WA 98011
Ph 425-686-1996 Fx 425-686-3096
MATRIX DUPLICATESfRIPLICATES
SOURCE 1201073-02
Batch F201063
Preparation BrCI Oxidation
Sequence 2A09010
Lab Number F201063-DUPI
Sample Duplicate Concentration Concentration RPD
Analyte ngL ngL MRL RPD Limit Method Notes Mercury 1048 1054 202 0617 24 EPA I631E
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Page 6of26 1201073 Final Report 04252012 8
11720 North Creek Parkway North Suite 400 BotheE WA 980 l l
Ph 425-686-1996 Fx 425-686-3096
GLOBAL SCIENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1201073-02
Batch F201063 Sequence 2A09010
Preparation BrCI Oxidation Lab Number F20 l 063-MSMSDl
Sample Spike MS MS Concentration Added Concentration RecoveryAnalyte (ngL) (ngL) (ngL) Recovery Method Limits Notes
Mercury 1048 20400 3136 102 71 125 EPA 163IE
Spike MSD MSD Added Concentration oo Recovery RPD
RPD Limits Limit Method Notes Analyte (ngL) (ngL) Recovery
Mercury 20400 2708 814 147 71 - 125 24 EPA 1631E
shy
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Page 7 o26Liz Siska Project Manager 120JO7 3 Final Repo1
04252012 9
Liz Siska Project Manager
11720 North Creek Parkway North Suite 400 Bothell WA 98011
Ph 425-686-1996~ Fx 425-686-3096 CL06AL SCIENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1112278-02
Batch F201063 Sequence 2A09010
Preparation BrCI Oxidation Lab Number F20 l 063-MSMSD2
Sample Spike MS MS
Analyte Concentration
(ogL) Added (ngL)
Concentration (ngL)
Recovery
RecoveryLimits Method Notes
Mercury 761 20400 2786 992 71 125 EPA 1631E
Spike MSD MSD Added Concentration Oo Recovery RPO
Analyte (ngL) (ngL) Recovery RPO Limits Limit Method Notes
Mercury 20400 2837 102 182 71 - 125 24 EPA l631E
shy
Frontier Global Sciences Inc The results in this report only apply to the somples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Page 8 o26 1201073 Final Report 042512012 10
11720 North Creek Parkway North Suite 400 Bothell WA 980 l l
Ph 425-686-1996 ~ Fx 425-686-3096 GLOBAL SCIENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1201029-01
Batch
Preparation
F201063
BrCI Oxidation
Sequence
Lab Number
2A09010
F20 I 063-MSMSD3
Analyte
Mercury
Analyte
Mercury
Sample Spike Concentration Added
(ngL) (ngL)
534 10200
Spike MSD Added Concentration (ngL) (ngL)
10200 1407
MS MS Concentration Recovery
(ngL) Recovery Limits
1558 JOO 7l shy 125
MSD oo Recovery RPD
Recovery RPD Limits Limit
856 102 71 - 125 24
Method
EPA l63lE
Method
EPA 631E
Notes
Notes
Frontier Global Sciences Inc The results in this repon only apply to rhe samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Page 9of26 1201073 Final Report 041252012
Liz Siska Project Manager
1 1
11720 North Creek Parkway North Suite 400 Bothell WA 98011
Ph 425-686-1996 FRONTIER- Fx 425-686-3096 cLosAL SCIENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1201030-02
Batch F20I063 Sequence 2A09010
Preparation BrCI Oxidation Lab Number F201063-MSMSD4
Sample Spike MS MS Concentration Added Concentration RecoveryAnalyte (ngL) (ngL) (ngL) Recovery MethodLimits Notes
Mercury 554 10200 1482 910 71 - 125 EPA I631E
Spike MSD MSD Oo Added Concentratio11 Recovery RPD
RPD Limits Limit Method Analyte (ngL) (ngL) Recovery Notes
Mercury 10200 1461 890 140 71 - 125 24 EPA 163IE
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed m accordance with the chain ofcus1ody document This anayt(ca repon must be reproduced in itr entirety
Page lOo26Liz Siska Project Manager 1201073 Final Report
041252012 12
I 1720 North Creek Parkway North Suite 400 Bothe I I WA 98011
Ph 425-686-1996 ~ Fx 425-686-3096 GLOBAL SCIENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1201073-01RE3
Batch F20327l Sequence 2C22005
Prcpa ration ((01ed Vessel ~ itric Oven Digestion Lab Number F203271-MSMSD 1
Analyte
Sample Concentration
(microgL)
Spike Added (microgL)
MS Concentration
(microgL)
MS Oo
Recovery Recovery
Method Limits Notes
Calcium 5013000 15150 4802000 -13900 70- 130 EPA 2008 Mod QM-02
Analyte
Spike Added (microgL)
MSD Concentration
(microgL)
MSD ~o
Recovery
Oo
RPD Recovery
Limits RPDLimit Method Notes
Calcium 15150 4943000 -4600 289 70 - 130 20 EPA 2008 Mod QM-02
Frontier Global Sciences Inc The results in this report only apply to the samples analyud inaccordance with the chain ofcustody document 17is analyticol report must be reproduced in its entirety
Page lI o16 1101073 Final Report 04152012
Liz Siska Project Manager
13
l l 720 North Creek Parkway North Suite 400 Bothell WA 98011
Ph 425-686-1996FRONTIER Fx 425-686-3096 GLOBAL SCIENCES
MATRIX SPIKE I MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1201073-01RE4
Batch F203271 Sequence 2C22005
Preparation Closed Vessel Nitric Oven Digestion Lab Number F203271-MSMSD2
Sample Spike MS MS Concentration Added Concentration Oo RecoveryAnalyte (microgL) (microgL) (microgL) Recovery Method Limits Notes
Beryllium 0507 20200 2442 958 70 - 130 EPA 2008 Mod Sodium 258800 50500 257700 -213 70 -130 EPA 2008 Mod QM-02 Aluminum 529 15150 2023 986 70 - 130 EPA 2008 Mod Chromium 057 70700 804 106 70 - 130 EPA 2008 Mod Manganese 2805 60600 2834 476 70 - 130 EPA 2008 Mod QM-02 Iron ND 50500 5200 103 70 130 EPA 2008 Mod Nickel 979 40400 141 l 107 70- 130 EPA 2008 Mod Copper 055 40400 434 939 70 - 130 EPA 2008 Mod Zinc 040 10100 842 794 70 - 130 EPA 2008 Mod Arsenic 1030 15150 2418 916 70 - 130 EPA 2008 Mod Selenium 6340 30300 8973 869 70 130 EPA 2008 Mod Molybdenum 1338 20200 1367 142 70 130 EPA 2008 Mod QM-02 Silver ND 15150 1388 916 70 - 130 EPA 2008 Mod Cadmium 0332 080800 1105 middot956 70 - 130 EPA 2008 Mod Antimony 0408 080800 1259 105 70- 130 EPA 2008 Mod Barium 2397 10100 2495 968 70 - 130 EPA 2008 Mod Lead ND 15150 1542 102 70 130 EPA 2008 Mod
shy
shy
shy
shy
Analyte
Spike Added (microgL)
MSD Concentration
(microgL)
MSD Oo
Recovery
Oo
RPD Recovery
Limits RPD Limit Method Notes
Beryllium
Sodium
Aluminum
Chromium
Manganese
Iron
Nickel
Copper
Zinc
Arsenic
Selenium
Molybdenum
20200
50500
15150
7Q700
60600
50500
40400
40400
10100
15150
30300
20200
2561
257100
2034
773
2852
5187
1381
419
916
2225
9400
1366
102
-336
993
101 769
103
995
902
868
789
101
137
474
0243
0564
385
0625
0242
213
347
849
831
464
00771
70 - 130
70 bull 130 70 - 130
70 - 130
70 - 130
70 - 130
70 - 130
70 - 130
70 - 130
70 bull 130 70 - 130
70 - 130
20
20
20
20
20
20
20
20
20
20
20
20
EPA 2008 Mod
EPA 2008 Mod
EPA 2008 Mod
EPA 2008 Mod
EPA 2008 Mod
EPA 2008 Mod
EPA 2008 Mod
EPA 2008 Mod
EPA 2008 Mod
EPA 2008 Mod
EPA 2008 Mod
EPA 2008 Mod
QM-02
QM-02
Frontier G lobal Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
--f_~ --~~~-~ -middot middot Page 12 o261201073 Final Report 041252012
Liz Siska Project Manager
14
11720 North Creek Parkway North Suite 400
~ Bothell WA 98011
~TIEmiddot Ph 425-686-1996 Fx 425-686-3096
GLOB11L SCIENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPO
SOURCE 1201073-01RE4
Batch F203271 Sequence 2C22005
Preparation ~lo~ed Vessel Nitric Oven Digestion Lab Number F20327 I-MSMSD2
Spike MSD MSD Added Concentration Oo Recovery RPO
Analyte (microgL) (microgL) Recovery RPD Limits Limit Method Notes
Silver 15150 1387 915 00874 70 - 130 20 EPA 2008 Mod Cadmium 080800 1061 902 403 70 - 130 20 EPA 200amp Mod Antimony 080800 1274 107 l2l 70 - 130 20 EPA 2008 Mod Barium 10100 2514 )16 0781 70 - 130 20 EPA 200amp Mod Lead 15150 1534 101 0525 70 shy 130 20 EPA 2008 Mod
Frontier Global Sciences Inc The results in this report only apply to 1he samples analyzed in accordance wiih the chain ofcustody document This analytical repo1 must be reproduced in ils entirety
Page 13 o26Liz Siska Project Manager 1201073 Final Reporl
04252012 15
11720 North Creek Parkway North Suite 400
~ Bothell WA 98011 Ph 425-686-I996
~RONTIER~ Fx 425-686-3096 GLOBAL SCIEN C ES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1201073-01RE3
Batch F203271 Sequence 2~22005
Preparation Closed Vessel Nitric Oven Digestion Lab Number F20327 I-MSMSD3
Sample Spike MS MS
Analyte Concentration
(microgL) Added (microgL)
Concentration (microgL) Recovery
Recovery Limits Method Notes
Calcium 5013000 10100000 15120000 100 70- 130 EPA 2008 Mod AS
Spike MSD MSD Added Concentration o Oo Recovery RPD
Analyte (microgL) (microgL) Recovery RPD Limits Limit Method Notes
Calcium 10100000 16140000 llO 653 70 - 130 20 EPA 2008 Mod AS
Frontier Global Sciences Inc The results in his report only apply 10 the samples analyzed in accordance ivth he chain ofcustody document This analytical report must be reproduced in its entirety
Page 14 o261201073 Final Report 0425201]
Liz Siska Project Manager
16
Frontier Global Sciences Inc The ruults in this rechain ofcustody do
~ -lt1-c--~ Liz Siska Project Manager
11720 North Creek Parkway North Suite 400 Bothell WA 98011
Ph 425-686-1996 Fx 425-686-3096
GLOBAL SCIENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1201073-01RE4
Batch J203271 Sequence 2C22005
Preparation ~ IQsed Ve~~el Nitric Oven Qigestion Lab Number F203271-MSMSQ4
Analyte
Beryllium
Sample Concentration
(11gL)
0507
Spike Added (11gL)
20200
MS Concentration
(microgL)
2041
MS Oo
Recovery
985
RecoveryMethod Limits
70 - 130 EPA 2008 Mod
Notes
AS
Sodium 258800 40400 292900 845 70- 130 EPA 2008 Mod AS
Aluminum 529 40400 3956 966 70 - 130 EPA 2008 Mod AS
Chromium 057 40400 430l 106 70- 130 EPA 2008 Mod AS
Manganese 2805 40400 7042 105 70 - 130 EPA 2008 Mod AS
Iron ND 20200 2121 105 70 - 130 EPA 2008 Mod AS
Nickel 979 50500 5112 993 70 l30 EPA 2008 Mod AS
Copper 055 50500 4754 940 70 - 130 EPA 2008 Mod AS
Zinc 040 10100 9074 898 70 - 130 EPA 2008 Mod AS
Arsenic 1030 40400 4317 104 70 130 EPA 2008 Mod AS
Selenium 6340 40400 4688 100 70 - 130 EPA 2008 Mod AS
Molybdenum 1338 20200 338l 101 70 - 130 EPA 2008 Mod AS
Silver ND 20200 1850 916 70 130 EPA 2008 Mod AS
Cadmium 0332 40400 3937 966 70 130 EPA 2008 Mod AS
Antimony 0408 20200 2091 102 70 - 130 EPA 2008 Mod AS
Barium 2397 80800 1056 101 70- 130 EPA 2008 Mod AS
Lead ND IO100 9932 983 70 130 EPA 2008 Mod AS
shy
shy
shy
shy
shy
Analyte
Spike Added (microgL)
MSD Concentration
(microgL)
MSD
Recovery
RPD
Recovery Limits
RPDLimit Method Notes
Beryllium 20200 2007 968 l71 70 - 130 20 EPA 2008 Mod AS Sodium 40400 292600 837 0114 70 130 20 EPA 2008 Mod AS Aluminum 40400 3954 966 00362 70 - 130 20 EPA 2008 Mod AS Chromium 40400 4287 106 0337 70 - 130 20 EPA 2008 Mod AS Manganese 40400 6944 102 140 70 - 130 20 EPA 2008 Mod AS Iron 20200 2077 103 211 70 - 130 20 EPA 2008 Mod AS Nickel 50500 5126 996 0276 70 - 130 20 EPA 2008 Mod AS Copper 50500 4707 931 0997 70 - 130 20 EPA 200 8 Mod AS Zinc 10100 9059 896 0166 70 - 130 20 EPA 2008 Mod AS Arsenic 40400 4299 104 0419 70 - 130 20 EPA 2008 Mod AS Selenium 40400 4682 100 0141 70 - 130 20 EPA 2008 Mod AS Molybdenum 20200 3365 100 0473 70 - 130 20 EPA 2008 Mod AS
shy
port only apply to the sampltts analyzed in accordance with the cument This analytical report must be reproduced in its entirety
Page 5 o26 201073 Final Report 042512012 17
Liz Sia Project Manager
11720 North Creek Parkway North Suite 400 Botheln VA 98011
Ph 425-686-1996 Fx 425-686-3096
CLOBAL SCIENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1201073-01RE4
Batch F203271 Sequence 2c2io2~
Preparation Clo~ed Vessel litric Oven Digestion Lab Number F20327 l -MSMSQ4
Analyte
Spike Added (microgL)
MSD Concentration
(microgL)
MSD
Recovery
Oo
RPD Recovery
Limits RPOLimit Method Notes
Silver 20200 1895 938 242 70 - 130 20 EPA 2008 Mod AS Cadmium 40400 3933 965 0104 70 -130 20 EPA 2008 Mod AS Antimony 20200 2107 102 0736 70- 130 20 EPA 2008 Mod AS
Barium 80800 1058 101 0205 70 - 130 20 EPA 2008 Mod AS
Lead 10100 9877 978 0549 70 - 130 20 EPA 2008 Mod AS
Frontier Global Sciences Inc The results in this report only apply to the samples analyudin accordance with lht chain ofcustody document This analytical report must be reproductd rn ilS enlirtty
Page l6of26 1201073 Final Report Ofn5202 18
l I 720 North Creek Parkway North Suite 400 Bothell WA 980I I
Ph 425-686-1996 Fx 425-686-3096
GLO B AL SCIENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1201073-01RE6
Batch F203314 Sequence 2C25005
Preparation Closed Vessel Nitric Oven Digestion Lab Number F203314-MSMSD2
Sample Spike MS MS Concentration Added Concentration RecoveryAnalyte (microgL) (microgL) (microgL) Recovery Method NotesLimits
Thallium 5563 040400 5875 773 70 - 130 EPA 2008 Mod
Spike MSD MSD Added o Concentration Recovery RPD
RPO Limits Limit Method Notes Analyte (microgL) (microgL) Recovery
Thallium 040400 5880 785 00859 70 - 130 20 EPA 2008 Mod
Frontier Global Sciences Inc 11e results in chis reporc only apply 10 1he samples analyzed in accordance wilh lhe chain ofcustody documenz This analycical report musl be reproduced in ils entirety
Page 17 of26 1201073 Fi11aReport 0412512012
Liz Siska Project Manager
19
11720 North Creek Parkway North Suite 400 Bothell WA 98011
Ph 425-686-1996 Fx 425-686-3096
GLOBAl SCIENC ES
MATRIX SPIKE I MATRIX SPIKE DUPLICATE RECOVERY AND RPO
SOURCE I201073-01RE6
Batch F203314
Preparation Closed Vessel Nitric Oven Digestion
Sequence 2C25005
Lab Number F203314-MSMSD4
Analyte
Sample Concentration
(microgL)
Spike Added (microgL)
MS MS Concentration Oo
(microgL) Recovery Recovery
Limits Method Notes
Thallium 5563 10100 1033 968 70- 130 EPA 2008 Mod AS
Analyte
Spike Added (microgL)
MSD Concentration
(microgL)
MS)) Oo
Recovery
RPD
Recovery Limits
RPD Limit Method Notes
Thallium IO100 1037 97l 0341 70 - 130 20 EPA 2008 Mod AS
Frontier Global Sciences Inc The resulrs in this report only apply to the samples analyzed in accordance with the chain ofcusrody document This analytical report must be reproduced in its entirely
Page 18of26 120073 Final Report 04252012
Liz Siska Project Manager
20
11720 North Creek Parkway North Suite 400 l ~ Bothell WA 980 l l Ph 425-686-1996
FRONTIER Fx 425-686-3096 GLOBAL SCIENCES
LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLICATE
RECOVERY AND RPD
Batch F20 l063 Sequence 2A09010
Preparation BrCI Oxidation Lab Number F201063-BSIBSJ21
LCS Source N ist 1641d
Analyte
Spike Added (ngL)
LCS Concentration
(ngL)
LCS
Recovery Recovery
Limits Method Notes
Mercury 15679 1550 988 80 - 120 EPA I631E
Analyte
Spike Added (ngL)
LCSD Concentration
(ngL)
LCSD Oo
Recovery
RPD Recovery
Limits RPD Limit Method Notes
Mercury 15679 1595 [02 289 80 - 120 24 EPA I631E
Frontier Global Sciences Inc The results in this report only apply to the samples analyzedin accordance with the chain ofcustody document This analytical report must be reproduced in ils entirety
Page 19of26 1201073 Final Report 0425 2012
Liz Siska Project Manager
21
11720 North Creek Parkway North Suite 400 Bothell WA 98011
Ph 425-686-1996 FRONTIER Fx 425-686-3096 GLOBAL SCIENCES
LABORA TORY CONTROL SAMPLE LABO RATORY CONTROL SAMPLE DUPLICATE
RECOVERY AND RPD
Batch F203271 Sequence 2C22005
Preparation Closed Vessel Nitric Oven Digestion Lab Number F203271-BSBSD1
LCS Source Blank Spike
Spike LCS LCS Added Concentration Oo Recovery
Analyte (microgL) (microgL) Recovery Limits Method Notes
Beryllium 20000 l930 965 85 - 115 EPA 2008 Mod
Sodium 50000 499 998 85 - 115 EPA 2008 Mod
Aluminum 15000 1460 973 85 - 115 EPA 2008 Mod
Calcium 15000 1528 102 85 - 115 EPA 2008 Mod
Chromium 70000 657 939 85 - 115 EPA 2008 Mod
Manganese 60000 586 976 85 - 115 EPA 2008 Mod
Iron 50000 4753 951 85 shy 115 EPA 2008 Mod
Nickel 40000 401 100 85 - 115 EPA 2008 Mod
Copper 40000 418 105 85 - 115 EPA 2008 Mod
Zinc 10000 1033 103 85 - 115 EPA 2008 Mod
Arsenic 15000 1437 958 85 - 115 EPA 2008 Mod
Selenium 30000 2966 989 85 - 115 EPA 2008 Mod
Molybdenum 20000 181 905 85 shy 115 EPA 2008 Mod
Silver 15000 1517 101 85 shy 115 EPA 2008 Mod
Cadmium 080000 0781 976 85 - 1lS EPA 2008 Mod
Antimony 080000 0815 102 85 - 115 EPA 2008 Mod
Barium 10000 969 969 85 - 115 EPA 2008 Mod
Lead 15000 1597 106 85 - 115 EPA 2008 Mod
Spike LCSD LCSD Added Concentration Recovery RPO
Analyte (microgL) (microgL) Recovery RPO Limits Limit Method Notes
Beryllium 20000 1949 974 0955 85 - 115 20 EPA 2008 Mod
Sodium 50000 500 100 0216 85 - 115 20 EPA 2008 Mod
Aluminum 15000 1485 990 171 85 - 115 20 EPA 2008 Mod
Calcium 15000 1544 103 103 85 - 115 20 EPA 2008 Mod
Chromium 70000 667 953 148 85 - 115 20 EPA 2008 Mod
Manganese 60000 596 994 175 85 - 115 20 EPA 2008 Mod
Iron 50000 4852 970 206 85 - 115 20 EPA 2008 Mod
Nickel 40000 402 IOI 0246 85 - 115 20 EPA 2008 Mod
Frontier Global Sciences Inc The results in his report only apply to the samples analyzed in accordance wirh the chain ofcustody document This analytical report must be reproduced in iLS entirety
Page 20of26 1201073 Final Report 04252012
Liz Siska Project Manager
22
11720 North Creek Parkway North Suite 400 ~~shy Bothell WA 98011 Ph 425-686-1996~ONTif Fx 425-686-3096
GLOBAL SCIENCES
LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLICATE
RECOVERY AND RPO
Batch F20327 l Sequence 2C22005
Preparation Closed Vessel Nitric Oven Digestion Lab Number F203271-BSBSD 1
LCS Source Blank Spike
Analyte
Spike Added (microgL)
LCSD Concentration
(microgL)
LCSD oo
Recovery
RPO Recovery
Limits RPO Limit Method Notes
Copper
Zinc
Arsenic
Selenium
40000
10000
15000
30000
428
1039
1452
3015
107
104
968
101
224
0570
0977
166
85 - 115
85 - 115
85 - 115
85 - 115
20
20
20
20
EPA 2008 Mod
EPA 2008 Mod
EPA 2008 Mod
EPA 2008 Mod Molybdenum
Silver
20000
15000
182
J502
910
100
0564
103
85 - 115
85 - 115
20
20
EPA 2008 Mod
EPA 2008 Mod Cadmium
Antimony
Barium
Lead
080000
080000
10000
15000
0828
0808
986
1620
103
101
986
108
585
0848
177
142
85 - 115
85 - 115
85 shy 11 S
85 - 115
20
20
20
20
EPA 2008 Mod
EPA 2008 Mod
EPA 2008 Mod
EPA 2008 Mod
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report mus be reproducedin its entirety
Page 2 o26J20J073 Final Report 041252012
Liz Siska Project Manager
23
11720 North Creek Parkway North Suite 400 Bothell WA 980 l l
Ph 425-686-1996FRONT[ER- Fx 425-686-3096 cLosAL SCIEN _CES
LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLICATE
RECOVERY AND RPD
Batch F203314 Sequence 2C25005
Preparation Closed Vessel Nitric Oven Digestion Lab Number F2033 l 4-BSBSD 1
LCS Source Blank Spike
Analyte
Thallium
Spike Added (microgL)
LCS Concentration
(microgL)
LCS 0o
Recovery Recovery
Limits Method
040000 0396 989 85 - 115 EPA 2008 Mod
Notes
Analyte
Spike Added (microgL)
LCSD Concentration
(microgL)
LCSD 0o
Recovery
RPD Recovery
Limits RPO Limit Method Notes
Thallium 040000 0391 978 112 85 - ll5 20 EPA 2008 Mod
Frontier Global Sciences Inc The results in this report only apply to the samples anayed in accordance with the chain ofcustody docwnenJ This analytical report must be reproduced in its entirety
Page 22of26 1201073 Final Report 04252012
Liz Siska Project Manager
24
Liz Siska P roject Manager
11720 North Creek Parkway North Suite 400
~ Bothell WA 98011 Ph 425-686-1996
~JTIEif middot Fx 425-686-3096 GLOBAL SCIENCES
PREPARATION BLANKS
Instrument Hg-17 Sequence 2A09010
Preparation BrCI Oxidation
Lab Sample ID Analyte Found MRL Units Batch Method Notes
F201063-BLK I Mercury -0009 050 ngL F201063 EPA 1631E u F20 I063-BLK2 Mercury -0006 050 ngL F201063 EPA 1631E u F201063-BLK3 Mercury -002 050 ngL F201063 EPA 163IE u F201063-BLK4 Mercury 003 050 ngL F201063 EPA 1631E U QB-04 F201063-BLKS Mercury 011 052 ngL F201063 EPA I631E U QB-06
Frontier Global Sciences Inc The results in this report only apply 10 1he samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Page 23 o26 1201073 Final Repon 04252012 25
Liz Siska Project Manager
11720 North Creek Parkway North Suite 400 Bothell WA 98011
Ph 425-686-1996 FROr~TIER- Fx 425-686-3096 GLOBAL SCIENCES
PREPARATION BLANKS
Instrument ICPMS-6 Sequence 2C22005
Preparation Closed Vessel Nitric Oven Digestion
Lab Sample ID Analyte Found MRL Units Batch Method Notes
F203271-BLK1 Beryllium 000008 0060 microgL F203271 PA 2008 Molt u F20327 1-BLK1 Sodium 2 20 microgL F20327l PA 2008 Moc u F20327I-BLK1 Aluminum -004 40 microgL F203271 PA 2008 Molt u F20327I -BLK1 Calcium 40 microgL F203271 PA 2008 Molt u F203271 -BLK1 Chromium -002 010 microgL F203271 ~A 2008 Molt u F203271-BLKI Manganese 001 010 microgL F203271 PA 2008 Molt u F20327 l -BLK 1 Iron -002 100 microgL F203271 PA 2008 Molt u F203271-BLKI Nickel 0004 010 microgL F203271 PA 2008 Moc u F203271-BLK1 Copper 0003 010 microgL F203271 PA 2008 Moc u F203271-BLK1 Zinc 0007 020 microgL F203271 PA 2008 Moc u F203271-BLK1 Arsenic -006 015 microgL F203271 PA 2008 Moc u F203271-BLK1 Selenium -002 060 microgL F203271 PA 2008 Moc u F203271-BLK1 Molybdenum 001 006 microgL F203271 PA 2008 Molt u F203271-BLK1 Silver -00005 0020 microgL F203271 PA 2008 Molt u F203271-BLKl Cadmium 0004 0020 microgL F203271 PA 2008 Molt u F20327 l-BLKl Antimony 0002 0020 microgL F203271 PA 2008 Molt u F203271-BLKI Barium 001 020 microgL F203271 PA 2008 Molt u F203271-BLKI Lead 0010 0040 microgL F203271 PA 2008 Moc u
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Page 24of26 1201073 Final Report 04252012 26
~
~TIER~ GLOBAL SCIENCES
11720 North Creek Parkway North Suite 400 Bothell WA 980ll
Ph 425-686-1996 Fx 425-686-3096
PREPARATION BLANKS
Instrument JCPMS-3 Sequence 2C25005
Preparation Closed Vessel Nitric Oven Digestion
Lab Sample ID Analyte Found MRL Units Batch Method Notes
F2033I4-BLK1 Thalium 00007 0010 microgL F2033I4 ~PA 2008 Molt u
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Page 25 o26Liz Siska Project Manager 1201073 Final Report
04252012 27
l l 720 North Creek Parkway North Suite 400~Vi-~ Bothell WA 98011 Ph 425-686-1 996~Tlmiddot~ Fx 425-686-3096
G L OBAL SCIENCE S
Notes and Definitions
U Analyte included in the analysis but not detected
QM-02 The MS andor MSD recoveries outside acceptance limits due to spike concentration less than I times the sample concentration The batch was accepted based on LCS and LCSD recoveries within control limits and when analysis permits acceptable AS ASD
QB-06 The blank was preserved to 5 BrCI rather than I The control limit for blanks preserved to greater than 1 BrCl is the preservation percentage multiplied by the MRL
QB-04 The blank was preserved to 2 BrCI rather than l The control limit for blanks preserved to greater than l BrCI is the preservation percentage multiplied by the MRL
FB-1631 Required equipmentfieldfilter blank not submitted by the client The sample has been analyzed according to 163 lE but does not meet 163 lE criteria
AS This MS andor MSD is an analytical spike andor an analytical spike duplicate
DET Analyte Detected
MDL Minimum Detection Limit
MRL Minimum Reporting Limit
ND Analyte Not Detected at or above the reporting limit
wet Sample results reported on a wet weight basis
dry Sample results reported on a dry weight basis
RPO Relative Percent Difference
RSD Relative Standard Deviation
Frontier Global Sciences Inc The lesults i111his reporl only apply to he samples analyzed In accordance with the chain ofcuslody document This analytical report must be reproduced in its entirely
Page 26of26 1201073 Final Report 04252012
Liz Siska Project Manager
28
CHAIN-OF-(USTODY ttECORD Page i of f 106677 _J
BoLD F1ELDS REQUIRED PLEASE C 1RCLE REQUESTED ANALYSIS
SAMPLE ID
middoti-rg -- bull ~rshy~ _- tzir +- lt-ltJ~ lt
SAMPLING
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IF COMPOSITE INDICATE BOTH
START amp FINISH
DATETIME li1J oc -r 111_- _vlt-c_
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middot~ON Mm1x A-Al~ S-SOil GW-GampOUHO WATER SW-SUampfA(f WATER DWmiddotDRIIIKIKlti WATER
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PROJECT MANAGER llr middot1 ~Q Aw4---P1V- Het_ r COMPANY t-lo--tm ~ bd i ( I ~j 6 A ADP~SS 91 g~ez tJshy(ITJ ~ STATE fH_ ZIP c3o--
PHONE 22j-((omiddotf EXT ____
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DATE NEEDED _1--1 middot Z=-----shy4 (1-1_ METALS 8 RCRA 13 pp ff MN PB Cu
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IF YH FAX OR POf 7~shy Hom (IE SPECIAL DETECTION LINITl BllLIKGINfO If DlffERrnT)ELECTRONIC OPTIONS zo 1 2 2) le~C1 1 Jc Id sJ 60 6c
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Ka)Jcr(c C(cdd -ltJ c -l -gtck- z Alt 5e1 Hj
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ImiddotRELINQUISHED BY DATE TIHE RECflVEO BY I FIELD READINGS
eastern analytical inc 2s CHENELL D R1ve IC 0 Nco1to N H 0330 1 I TEL 60J22aos2s 1aoo2a1os2s IFAx 6032284591 j E-MA1t cus-roM111_mV1c~EAILAsscoMJ www1A1LAascoM
----i pmiddotofissionrrl11bomtorymim (WHITE ORIGINAL GREEN PROJECT MANAGER)
shy
11720 North Creek Parkway North Suite 400 Bothell WA 98011
Ph 425-686-1996FRONTIER Fx 425-686-3096 GLOBAL SCIENCES
CASE NARRATIVE
Revised Report 42512
Per client request Boron was removed from report
Revised Report 32812
Per client request samples were prepared and analyzed for total metals in accordance with EPA 2008 (modified)
SAMPLE RECEIPT
Samples were received at Frontier Global Sciences (FGS) on January 6th 2012 The samples were received intact on-ice with temperatures measured at 34 degrees Celsius
SAMPLE PREPARATION AND ANAL YSJS
Samples were prepared and analyzed for total metals in accordance with FGS-054EPA 1638
Samples were prepared and analyzed for total mercury in accordance with EPA Method 163JE
ANALYTICAL AND QUALITY CONTROL IS SUES
There were no analytical difficulties experienced with analysis of these samples with the exceptions flagged in the report
Frontier Gtobal Sciences Inc The results in this reporr only apply 10 the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Liz Siska Project Manager Page 2of26 J20I073 Final Report 042512012 4
11720 North Creek Parkway North Suite 400 Bothell WA 98011~ Ph 425-686-1996 FRONTIER Fx 425-686-3096
GLOBAL SCIENCES
CHAIN OF CUSTODY FORMS
CML-1d Cc-t~lt7 shy~P~fci amp l sbtr3~~ry Aillylc P~ctirst J- ~V~-=lt S=-Jit=~1t Imiddot~ and 4J~~ Tssul
~ r~middotmiddotmiddot to ~-~ middot ~ ~middot ~rcshyr-11 ---4i--5~1-shy
y1tcirc1middot 6middot 01gter S1bulli1e
1 1 -middot shy
~middot-middotn middot~i---it =-middotmiddotrmiddot~-~r9ft~ri r s L lrj~JT ~- bull 1r bullermiddot~~(~lr- rlt-bull~~~~~ _ -tbull ~t-tmiddotbull I~ bull 1
middot middot l~~e ~middot rv~ 8Arvmiddott _ -middot
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report mus be reproduced in ilS entirety
Page3of26Liz Siska Project Manager 1201073 Final Report
041252012 5
Liz Siska Project Manager
11720 North Creek Parkway North Suite 400 Bothell WA 98011
Ph 425-686- 1996 ~ Fx 425-686-3096 G LOB A L SC I EN CE S
ANALYTICAL RESULTS
Treat Tank Eff Composite
Matrix Water Laboratory ID 1201073-01
Analyte Result MDL MRL Units Dilution Batch Sequence Analyzed Method Notes
Aluminum ND 89 800 microgL 20 F203271 2C22005 032212 EPA 2008 Mod u Antimony 0408 0092 0400 microgL 20 F20327l 2C22005 032212 EPA 2008 Mod Barium 240 054 400 microgL 20 F203271 2C22005 032212 EPA 2008 Mod Beryllium ND 0454 t20 microgL 20 F203271 2C22005 032212 EPA 2008 Mod u Cadmium ND 0083 0400 microgL 20 F203271 2C22005 032212 EPA 2008 Mod u Calcium 5010000 16200 200000 microgL 5000 F203271 2C22005 032212 EPA 2008 Mod Chromium ND 018 200 microgL 20 F20327I 2C22005 032212 EPA 2008 Mod u Copper ND 020 200 microgL 20 F203271 2C22005 032212 EPA 2008 Mod u Iron ND 260 200 microgL 20 F20327l 2C22005 032212 EPA 2008 Mod u Lead ND 0078 0800 microgL 20 F20327l 2C22005 032212 EPA 2008 Mod u Manganese 280 015 200 microgL 20 F203271 2C22005 032212 EPA 2008 Mod Molybdenum 134 012 120 microgL 20 F20327I 2C22005 032212 EPA 2008 Mod Nickel 979 016 2 00 microgL 20 F203271 2C22005 032212 EPA 2008 Mod Silver ND 0120 0400 microgL 20 F203271 2C22005 032212 EPA 2008 Mod u Sodium 259000 23 400 microgL 20 F203271 2C22005 032212 EPA 2008 Mod Thallium 556 0250 100 microgL 100 F203314 2C25005 032512 EPA 2008 Mod Zinc ND 033 400 microgL 20 F203271 2C22005 032212 EPA 2008 Mod u
Frontier Global Sciences Inc The middotesults in 1his report only apply to the samples analyzed in accordance wilh 11e chain ofcus1ody documem This analytical report must be reproduced in ifs entirety
Page 4of26 1201073 Final Report 04252012 6
Liz Siska Project Manager
11720 North Creek Parkway North Suite 400 Bothell WA 98011
Ph 425-686-1996 Fx 425-686-3096
GLOBAt SCIENCES
ANALYTICAL RESULTS
Treat Tank Eff Grab
Matrix Water Laboratory ID 1201073-02
Analyte Result MDL MRL Units Dilution Batch Sequence Analyzed Method Notes
Arsenic 851 102 300 microgL 20 F203271 2C22005 032212 EPA 2008 Mod Mercury 105 034 202 ngL 4 F20I063 2A09010 010912 EPA 1631E FB-1631 Selenium 689 388 120 microgL 20 F203271 2C22005 032212 EPA 2008 Mod
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcustody documenJ This analycical report must be reproduced in its entirety
Page 5 o261201073 Final Report 04252012 7
Liz Siska Project Manager
FRONTIERshycLoaAt SCI ENCES
11720 North Creek Parkway North Suite 400 Bothell WA 98011
Ph 425-686-1996 Fx 425-686-3096
MATRIX DUPLICATESfRIPLICATES
SOURCE 1201073-02
Batch F201063
Preparation BrCI Oxidation
Sequence 2A09010
Lab Number F201063-DUPI
Sample Duplicate Concentration Concentration RPD
Analyte ngL ngL MRL RPD Limit Method Notes Mercury 1048 1054 202 0617 24 EPA I631E
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Page 6of26 1201073 Final Report 04252012 8
11720 North Creek Parkway North Suite 400 BotheE WA 980 l l
Ph 425-686-1996 Fx 425-686-3096
GLOBAL SCIENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1201073-02
Batch F201063 Sequence 2A09010
Preparation BrCI Oxidation Lab Number F20 l 063-MSMSDl
Sample Spike MS MS Concentration Added Concentration RecoveryAnalyte (ngL) (ngL) (ngL) Recovery Method Limits Notes
Mercury 1048 20400 3136 102 71 125 EPA 163IE
Spike MSD MSD Added Concentration oo Recovery RPD
RPD Limits Limit Method Notes Analyte (ngL) (ngL) Recovery
Mercury 20400 2708 814 147 71 - 125 24 EPA 1631E
shy
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Page 7 o26Liz Siska Project Manager 120JO7 3 Final Repo1
04252012 9
Liz Siska Project Manager
11720 North Creek Parkway North Suite 400 Bothell WA 98011
Ph 425-686-1996~ Fx 425-686-3096 CL06AL SCIENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1112278-02
Batch F201063 Sequence 2A09010
Preparation BrCI Oxidation Lab Number F20 l 063-MSMSD2
Sample Spike MS MS
Analyte Concentration
(ogL) Added (ngL)
Concentration (ngL)
Recovery
RecoveryLimits Method Notes
Mercury 761 20400 2786 992 71 125 EPA 1631E
Spike MSD MSD Added Concentration Oo Recovery RPO
Analyte (ngL) (ngL) Recovery RPO Limits Limit Method Notes
Mercury 20400 2837 102 182 71 - 125 24 EPA l631E
shy
Frontier Global Sciences Inc The results in this report only apply to the somples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Page 8 o26 1201073 Final Report 042512012 10
11720 North Creek Parkway North Suite 400 Bothell WA 980 l l
Ph 425-686-1996 ~ Fx 425-686-3096 GLOBAL SCIENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1201029-01
Batch
Preparation
F201063
BrCI Oxidation
Sequence
Lab Number
2A09010
F20 I 063-MSMSD3
Analyte
Mercury
Analyte
Mercury
Sample Spike Concentration Added
(ngL) (ngL)
534 10200
Spike MSD Added Concentration (ngL) (ngL)
10200 1407
MS MS Concentration Recovery
(ngL) Recovery Limits
1558 JOO 7l shy 125
MSD oo Recovery RPD
Recovery RPD Limits Limit
856 102 71 - 125 24
Method
EPA l63lE
Method
EPA 631E
Notes
Notes
Frontier Global Sciences Inc The results in this repon only apply to rhe samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Page 9of26 1201073 Final Report 041252012
Liz Siska Project Manager
1 1
11720 North Creek Parkway North Suite 400 Bothell WA 98011
Ph 425-686-1996 FRONTIER- Fx 425-686-3096 cLosAL SCIENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1201030-02
Batch F20I063 Sequence 2A09010
Preparation BrCI Oxidation Lab Number F201063-MSMSD4
Sample Spike MS MS Concentration Added Concentration RecoveryAnalyte (ngL) (ngL) (ngL) Recovery MethodLimits Notes
Mercury 554 10200 1482 910 71 - 125 EPA I631E
Spike MSD MSD Oo Added Concentratio11 Recovery RPD
RPD Limits Limit Method Analyte (ngL) (ngL) Recovery Notes
Mercury 10200 1461 890 140 71 - 125 24 EPA 163IE
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed m accordance with the chain ofcus1ody document This anayt(ca repon must be reproduced in itr entirety
Page lOo26Liz Siska Project Manager 1201073 Final Report
041252012 12
I 1720 North Creek Parkway North Suite 400 Bothe I I WA 98011
Ph 425-686-1996 ~ Fx 425-686-3096 GLOBAL SCIENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1201073-01RE3
Batch F20327l Sequence 2C22005
Prcpa ration ((01ed Vessel ~ itric Oven Digestion Lab Number F203271-MSMSD 1
Analyte
Sample Concentration
(microgL)
Spike Added (microgL)
MS Concentration
(microgL)
MS Oo
Recovery Recovery
Method Limits Notes
Calcium 5013000 15150 4802000 -13900 70- 130 EPA 2008 Mod QM-02
Analyte
Spike Added (microgL)
MSD Concentration
(microgL)
MSD ~o
Recovery
Oo
RPD Recovery
Limits RPDLimit Method Notes
Calcium 15150 4943000 -4600 289 70 - 130 20 EPA 2008 Mod QM-02
Frontier Global Sciences Inc The results in this report only apply to the samples analyud inaccordance with the chain ofcustody document 17is analyticol report must be reproduced in its entirety
Page lI o16 1101073 Final Report 04152012
Liz Siska Project Manager
13
l l 720 North Creek Parkway North Suite 400 Bothell WA 98011
Ph 425-686-1996FRONTIER Fx 425-686-3096 GLOBAL SCIENCES
MATRIX SPIKE I MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1201073-01RE4
Batch F203271 Sequence 2C22005
Preparation Closed Vessel Nitric Oven Digestion Lab Number F203271-MSMSD2
Sample Spike MS MS Concentration Added Concentration Oo RecoveryAnalyte (microgL) (microgL) (microgL) Recovery Method Limits Notes
Beryllium 0507 20200 2442 958 70 - 130 EPA 2008 Mod Sodium 258800 50500 257700 -213 70 -130 EPA 2008 Mod QM-02 Aluminum 529 15150 2023 986 70 - 130 EPA 2008 Mod Chromium 057 70700 804 106 70 - 130 EPA 2008 Mod Manganese 2805 60600 2834 476 70 - 130 EPA 2008 Mod QM-02 Iron ND 50500 5200 103 70 130 EPA 2008 Mod Nickel 979 40400 141 l 107 70- 130 EPA 2008 Mod Copper 055 40400 434 939 70 - 130 EPA 2008 Mod Zinc 040 10100 842 794 70 - 130 EPA 2008 Mod Arsenic 1030 15150 2418 916 70 - 130 EPA 2008 Mod Selenium 6340 30300 8973 869 70 130 EPA 2008 Mod Molybdenum 1338 20200 1367 142 70 130 EPA 2008 Mod QM-02 Silver ND 15150 1388 916 70 - 130 EPA 2008 Mod Cadmium 0332 080800 1105 middot956 70 - 130 EPA 2008 Mod Antimony 0408 080800 1259 105 70- 130 EPA 2008 Mod Barium 2397 10100 2495 968 70 - 130 EPA 2008 Mod Lead ND 15150 1542 102 70 130 EPA 2008 Mod
shy
shy
shy
shy
Analyte
Spike Added (microgL)
MSD Concentration
(microgL)
MSD Oo
Recovery
Oo
RPD Recovery
Limits RPD Limit Method Notes
Beryllium
Sodium
Aluminum
Chromium
Manganese
Iron
Nickel
Copper
Zinc
Arsenic
Selenium
Molybdenum
20200
50500
15150
7Q700
60600
50500
40400
40400
10100
15150
30300
20200
2561
257100
2034
773
2852
5187
1381
419
916
2225
9400
1366
102
-336
993
101 769
103
995
902
868
789
101
137
474
0243
0564
385
0625
0242
213
347
849
831
464
00771
70 - 130
70 bull 130 70 - 130
70 - 130
70 - 130
70 - 130
70 - 130
70 - 130
70 - 130
70 bull 130 70 - 130
70 - 130
20
20
20
20
20
20
20
20
20
20
20
20
EPA 2008 Mod
EPA 2008 Mod
EPA 2008 Mod
EPA 2008 Mod
EPA 2008 Mod
EPA 2008 Mod
EPA 2008 Mod
EPA 2008 Mod
EPA 2008 Mod
EPA 2008 Mod
EPA 2008 Mod
EPA 2008 Mod
QM-02
QM-02
Frontier G lobal Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
--f_~ --~~~-~ -middot middot Page 12 o261201073 Final Report 041252012
Liz Siska Project Manager
14
11720 North Creek Parkway North Suite 400
~ Bothell WA 98011
~TIEmiddot Ph 425-686-1996 Fx 425-686-3096
GLOB11L SCIENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPO
SOURCE 1201073-01RE4
Batch F203271 Sequence 2C22005
Preparation ~lo~ed Vessel Nitric Oven Digestion Lab Number F20327 I-MSMSD2
Spike MSD MSD Added Concentration Oo Recovery RPO
Analyte (microgL) (microgL) Recovery RPD Limits Limit Method Notes
Silver 15150 1387 915 00874 70 - 130 20 EPA 2008 Mod Cadmium 080800 1061 902 403 70 - 130 20 EPA 200amp Mod Antimony 080800 1274 107 l2l 70 - 130 20 EPA 2008 Mod Barium 10100 2514 )16 0781 70 - 130 20 EPA 200amp Mod Lead 15150 1534 101 0525 70 shy 130 20 EPA 2008 Mod
Frontier Global Sciences Inc The results in this report only apply to 1he samples analyzed in accordance wiih the chain ofcustody document This analytical repo1 must be reproduced in ils entirety
Page 13 o26Liz Siska Project Manager 1201073 Final Reporl
04252012 15
11720 North Creek Parkway North Suite 400
~ Bothell WA 98011 Ph 425-686-I996
~RONTIER~ Fx 425-686-3096 GLOBAL SCIEN C ES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1201073-01RE3
Batch F203271 Sequence 2~22005
Preparation Closed Vessel Nitric Oven Digestion Lab Number F20327 I-MSMSD3
Sample Spike MS MS
Analyte Concentration
(microgL) Added (microgL)
Concentration (microgL) Recovery
Recovery Limits Method Notes
Calcium 5013000 10100000 15120000 100 70- 130 EPA 2008 Mod AS
Spike MSD MSD Added Concentration o Oo Recovery RPD
Analyte (microgL) (microgL) Recovery RPD Limits Limit Method Notes
Calcium 10100000 16140000 llO 653 70 - 130 20 EPA 2008 Mod AS
Frontier Global Sciences Inc The results in his report only apply 10 the samples analyzed in accordance ivth he chain ofcustody document This analytical report must be reproduced in its entirety
Page 14 o261201073 Final Report 0425201]
Liz Siska Project Manager
16
Frontier Global Sciences Inc The ruults in this rechain ofcustody do
~ -lt1-c--~ Liz Siska Project Manager
11720 North Creek Parkway North Suite 400 Bothell WA 98011
Ph 425-686-1996 Fx 425-686-3096
GLOBAL SCIENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1201073-01RE4
Batch J203271 Sequence 2C22005
Preparation ~ IQsed Ve~~el Nitric Oven Qigestion Lab Number F203271-MSMSQ4
Analyte
Beryllium
Sample Concentration
(11gL)
0507
Spike Added (11gL)
20200
MS Concentration
(microgL)
2041
MS Oo
Recovery
985
RecoveryMethod Limits
70 - 130 EPA 2008 Mod
Notes
AS
Sodium 258800 40400 292900 845 70- 130 EPA 2008 Mod AS
Aluminum 529 40400 3956 966 70 - 130 EPA 2008 Mod AS
Chromium 057 40400 430l 106 70- 130 EPA 2008 Mod AS
Manganese 2805 40400 7042 105 70 - 130 EPA 2008 Mod AS
Iron ND 20200 2121 105 70 - 130 EPA 2008 Mod AS
Nickel 979 50500 5112 993 70 l30 EPA 2008 Mod AS
Copper 055 50500 4754 940 70 - 130 EPA 2008 Mod AS
Zinc 040 10100 9074 898 70 - 130 EPA 2008 Mod AS
Arsenic 1030 40400 4317 104 70 130 EPA 2008 Mod AS
Selenium 6340 40400 4688 100 70 - 130 EPA 2008 Mod AS
Molybdenum 1338 20200 338l 101 70 - 130 EPA 2008 Mod AS
Silver ND 20200 1850 916 70 130 EPA 2008 Mod AS
Cadmium 0332 40400 3937 966 70 130 EPA 2008 Mod AS
Antimony 0408 20200 2091 102 70 - 130 EPA 2008 Mod AS
Barium 2397 80800 1056 101 70- 130 EPA 2008 Mod AS
Lead ND IO100 9932 983 70 130 EPA 2008 Mod AS
shy
shy
shy
shy
shy
Analyte
Spike Added (microgL)
MSD Concentration
(microgL)
MSD
Recovery
RPD
Recovery Limits
RPDLimit Method Notes
Beryllium 20200 2007 968 l71 70 - 130 20 EPA 2008 Mod AS Sodium 40400 292600 837 0114 70 130 20 EPA 2008 Mod AS Aluminum 40400 3954 966 00362 70 - 130 20 EPA 2008 Mod AS Chromium 40400 4287 106 0337 70 - 130 20 EPA 2008 Mod AS Manganese 40400 6944 102 140 70 - 130 20 EPA 2008 Mod AS Iron 20200 2077 103 211 70 - 130 20 EPA 2008 Mod AS Nickel 50500 5126 996 0276 70 - 130 20 EPA 2008 Mod AS Copper 50500 4707 931 0997 70 - 130 20 EPA 200 8 Mod AS Zinc 10100 9059 896 0166 70 - 130 20 EPA 2008 Mod AS Arsenic 40400 4299 104 0419 70 - 130 20 EPA 2008 Mod AS Selenium 40400 4682 100 0141 70 - 130 20 EPA 2008 Mod AS Molybdenum 20200 3365 100 0473 70 - 130 20 EPA 2008 Mod AS
shy
port only apply to the sampltts analyzed in accordance with the cument This analytical report must be reproduced in its entirety
Page 5 o26 201073 Final Report 042512012 17
Liz Sia Project Manager
11720 North Creek Parkway North Suite 400 Botheln VA 98011
Ph 425-686-1996 Fx 425-686-3096
CLOBAL SCIENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1201073-01RE4
Batch F203271 Sequence 2c2io2~
Preparation Clo~ed Vessel litric Oven Digestion Lab Number F20327 l -MSMSQ4
Analyte
Spike Added (microgL)
MSD Concentration
(microgL)
MSD
Recovery
Oo
RPD Recovery
Limits RPOLimit Method Notes
Silver 20200 1895 938 242 70 - 130 20 EPA 2008 Mod AS Cadmium 40400 3933 965 0104 70 -130 20 EPA 2008 Mod AS Antimony 20200 2107 102 0736 70- 130 20 EPA 2008 Mod AS
Barium 80800 1058 101 0205 70 - 130 20 EPA 2008 Mod AS
Lead 10100 9877 978 0549 70 - 130 20 EPA 2008 Mod AS
Frontier Global Sciences Inc The results in this report only apply to the samples analyudin accordance with lht chain ofcustody document This analytical report must be reproductd rn ilS enlirtty
Page l6of26 1201073 Final Report Ofn5202 18
l I 720 North Creek Parkway North Suite 400 Bothell WA 980I I
Ph 425-686-1996 Fx 425-686-3096
GLO B AL SCIENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1201073-01RE6
Batch F203314 Sequence 2C25005
Preparation Closed Vessel Nitric Oven Digestion Lab Number F203314-MSMSD2
Sample Spike MS MS Concentration Added Concentration RecoveryAnalyte (microgL) (microgL) (microgL) Recovery Method NotesLimits
Thallium 5563 040400 5875 773 70 - 130 EPA 2008 Mod
Spike MSD MSD Added o Concentration Recovery RPD
RPO Limits Limit Method Notes Analyte (microgL) (microgL) Recovery
Thallium 040400 5880 785 00859 70 - 130 20 EPA 2008 Mod
Frontier Global Sciences Inc 11e results in chis reporc only apply 10 1he samples analyzed in accordance wilh lhe chain ofcustody documenz This analycical report musl be reproduced in ils entirety
Page 17 of26 1201073 Fi11aReport 0412512012
Liz Siska Project Manager
19
11720 North Creek Parkway North Suite 400 Bothell WA 98011
Ph 425-686-1996 Fx 425-686-3096
GLOBAl SCIENC ES
MATRIX SPIKE I MATRIX SPIKE DUPLICATE RECOVERY AND RPO
SOURCE I201073-01RE6
Batch F203314
Preparation Closed Vessel Nitric Oven Digestion
Sequence 2C25005
Lab Number F203314-MSMSD4
Analyte
Sample Concentration
(microgL)
Spike Added (microgL)
MS MS Concentration Oo
(microgL) Recovery Recovery
Limits Method Notes
Thallium 5563 10100 1033 968 70- 130 EPA 2008 Mod AS
Analyte
Spike Added (microgL)
MSD Concentration
(microgL)
MS)) Oo
Recovery
RPD
Recovery Limits
RPD Limit Method Notes
Thallium IO100 1037 97l 0341 70 - 130 20 EPA 2008 Mod AS
Frontier Global Sciences Inc The resulrs in this report only apply to the samples analyzed in accordance with the chain ofcusrody document This analytical report must be reproduced in its entirely
Page 18of26 120073 Final Report 04252012
Liz Siska Project Manager
20
11720 North Creek Parkway North Suite 400 l ~ Bothell WA 980 l l Ph 425-686-1996
FRONTIER Fx 425-686-3096 GLOBAL SCIENCES
LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLICATE
RECOVERY AND RPD
Batch F20 l063 Sequence 2A09010
Preparation BrCI Oxidation Lab Number F201063-BSIBSJ21
LCS Source N ist 1641d
Analyte
Spike Added (ngL)
LCS Concentration
(ngL)
LCS
Recovery Recovery
Limits Method Notes
Mercury 15679 1550 988 80 - 120 EPA I631E
Analyte
Spike Added (ngL)
LCSD Concentration
(ngL)
LCSD Oo
Recovery
RPD Recovery
Limits RPD Limit Method Notes
Mercury 15679 1595 [02 289 80 - 120 24 EPA I631E
Frontier Global Sciences Inc The results in this report only apply to the samples analyzedin accordance with the chain ofcustody document This analytical report must be reproduced in ils entirety
Page 19of26 1201073 Final Report 0425 2012
Liz Siska Project Manager
21
11720 North Creek Parkway North Suite 400 Bothell WA 98011
Ph 425-686-1996 FRONTIER Fx 425-686-3096 GLOBAL SCIENCES
LABORA TORY CONTROL SAMPLE LABO RATORY CONTROL SAMPLE DUPLICATE
RECOVERY AND RPD
Batch F203271 Sequence 2C22005
Preparation Closed Vessel Nitric Oven Digestion Lab Number F203271-BSBSD1
LCS Source Blank Spike
Spike LCS LCS Added Concentration Oo Recovery
Analyte (microgL) (microgL) Recovery Limits Method Notes
Beryllium 20000 l930 965 85 - 115 EPA 2008 Mod
Sodium 50000 499 998 85 - 115 EPA 2008 Mod
Aluminum 15000 1460 973 85 - 115 EPA 2008 Mod
Calcium 15000 1528 102 85 - 115 EPA 2008 Mod
Chromium 70000 657 939 85 - 115 EPA 2008 Mod
Manganese 60000 586 976 85 - 115 EPA 2008 Mod
Iron 50000 4753 951 85 shy 115 EPA 2008 Mod
Nickel 40000 401 100 85 - 115 EPA 2008 Mod
Copper 40000 418 105 85 - 115 EPA 2008 Mod
Zinc 10000 1033 103 85 - 115 EPA 2008 Mod
Arsenic 15000 1437 958 85 - 115 EPA 2008 Mod
Selenium 30000 2966 989 85 - 115 EPA 2008 Mod
Molybdenum 20000 181 905 85 shy 115 EPA 2008 Mod
Silver 15000 1517 101 85 shy 115 EPA 2008 Mod
Cadmium 080000 0781 976 85 - 1lS EPA 2008 Mod
Antimony 080000 0815 102 85 - 115 EPA 2008 Mod
Barium 10000 969 969 85 - 115 EPA 2008 Mod
Lead 15000 1597 106 85 - 115 EPA 2008 Mod
Spike LCSD LCSD Added Concentration Recovery RPO
Analyte (microgL) (microgL) Recovery RPO Limits Limit Method Notes
Beryllium 20000 1949 974 0955 85 - 115 20 EPA 2008 Mod
Sodium 50000 500 100 0216 85 - 115 20 EPA 2008 Mod
Aluminum 15000 1485 990 171 85 - 115 20 EPA 2008 Mod
Calcium 15000 1544 103 103 85 - 115 20 EPA 2008 Mod
Chromium 70000 667 953 148 85 - 115 20 EPA 2008 Mod
Manganese 60000 596 994 175 85 - 115 20 EPA 2008 Mod
Iron 50000 4852 970 206 85 - 115 20 EPA 2008 Mod
Nickel 40000 402 IOI 0246 85 - 115 20 EPA 2008 Mod
Frontier Global Sciences Inc The results in his report only apply to the samples analyzed in accordance wirh the chain ofcustody document This analytical report must be reproduced in iLS entirety
Page 20of26 1201073 Final Report 04252012
Liz Siska Project Manager
22
11720 North Creek Parkway North Suite 400 ~~shy Bothell WA 98011 Ph 425-686-1996~ONTif Fx 425-686-3096
GLOBAL SCIENCES
LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLICATE
RECOVERY AND RPO
Batch F20327 l Sequence 2C22005
Preparation Closed Vessel Nitric Oven Digestion Lab Number F203271-BSBSD 1
LCS Source Blank Spike
Analyte
Spike Added (microgL)
LCSD Concentration
(microgL)
LCSD oo
Recovery
RPO Recovery
Limits RPO Limit Method Notes
Copper
Zinc
Arsenic
Selenium
40000
10000
15000
30000
428
1039
1452
3015
107
104
968
101
224
0570
0977
166
85 - 115
85 - 115
85 - 115
85 - 115
20
20
20
20
EPA 2008 Mod
EPA 2008 Mod
EPA 2008 Mod
EPA 2008 Mod Molybdenum
Silver
20000
15000
182
J502
910
100
0564
103
85 - 115
85 - 115
20
20
EPA 2008 Mod
EPA 2008 Mod Cadmium
Antimony
Barium
Lead
080000
080000
10000
15000
0828
0808
986
1620
103
101
986
108
585
0848
177
142
85 - 115
85 - 115
85 shy 11 S
85 - 115
20
20
20
20
EPA 2008 Mod
EPA 2008 Mod
EPA 2008 Mod
EPA 2008 Mod
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report mus be reproducedin its entirety
Page 2 o26J20J073 Final Report 041252012
Liz Siska Project Manager
23
11720 North Creek Parkway North Suite 400 Bothell WA 980 l l
Ph 425-686-1996FRONT[ER- Fx 425-686-3096 cLosAL SCIEN _CES
LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLICATE
RECOVERY AND RPD
Batch F203314 Sequence 2C25005
Preparation Closed Vessel Nitric Oven Digestion Lab Number F2033 l 4-BSBSD 1
LCS Source Blank Spike
Analyte
Thallium
Spike Added (microgL)
LCS Concentration
(microgL)
LCS 0o
Recovery Recovery
Limits Method
040000 0396 989 85 - 115 EPA 2008 Mod
Notes
Analyte
Spike Added (microgL)
LCSD Concentration
(microgL)
LCSD 0o
Recovery
RPD Recovery
Limits RPO Limit Method Notes
Thallium 040000 0391 978 112 85 - ll5 20 EPA 2008 Mod
Frontier Global Sciences Inc The results in this report only apply to the samples anayed in accordance with the chain ofcustody docwnenJ This analytical report must be reproduced in its entirety
Page 22of26 1201073 Final Report 04252012
Liz Siska Project Manager
24
Liz Siska P roject Manager
11720 North Creek Parkway North Suite 400
~ Bothell WA 98011 Ph 425-686-1996
~JTIEif middot Fx 425-686-3096 GLOBAL SCIENCES
PREPARATION BLANKS
Instrument Hg-17 Sequence 2A09010
Preparation BrCI Oxidation
Lab Sample ID Analyte Found MRL Units Batch Method Notes
F201063-BLK I Mercury -0009 050 ngL F201063 EPA 1631E u F20 I063-BLK2 Mercury -0006 050 ngL F201063 EPA 1631E u F201063-BLK3 Mercury -002 050 ngL F201063 EPA 163IE u F201063-BLK4 Mercury 003 050 ngL F201063 EPA 1631E U QB-04 F201063-BLKS Mercury 011 052 ngL F201063 EPA I631E U QB-06
Frontier Global Sciences Inc The results in this report only apply 10 1he samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Page 23 o26 1201073 Final Repon 04252012 25
Liz Siska Project Manager
11720 North Creek Parkway North Suite 400 Bothell WA 98011
Ph 425-686-1996 FROr~TIER- Fx 425-686-3096 GLOBAL SCIENCES
PREPARATION BLANKS
Instrument ICPMS-6 Sequence 2C22005
Preparation Closed Vessel Nitric Oven Digestion
Lab Sample ID Analyte Found MRL Units Batch Method Notes
F203271-BLK1 Beryllium 000008 0060 microgL F203271 PA 2008 Molt u F20327 1-BLK1 Sodium 2 20 microgL F20327l PA 2008 Moc u F20327I-BLK1 Aluminum -004 40 microgL F203271 PA 2008 Molt u F20327I -BLK1 Calcium 40 microgL F203271 PA 2008 Molt u F203271 -BLK1 Chromium -002 010 microgL F203271 ~A 2008 Molt u F203271-BLKI Manganese 001 010 microgL F203271 PA 2008 Molt u F20327 l -BLK 1 Iron -002 100 microgL F203271 PA 2008 Molt u F203271-BLKI Nickel 0004 010 microgL F203271 PA 2008 Moc u F203271-BLK1 Copper 0003 010 microgL F203271 PA 2008 Moc u F203271-BLK1 Zinc 0007 020 microgL F203271 PA 2008 Moc u F203271-BLK1 Arsenic -006 015 microgL F203271 PA 2008 Moc u F203271-BLK1 Selenium -002 060 microgL F203271 PA 2008 Moc u F203271-BLK1 Molybdenum 001 006 microgL F203271 PA 2008 Molt u F203271-BLK1 Silver -00005 0020 microgL F203271 PA 2008 Molt u F203271-BLKl Cadmium 0004 0020 microgL F203271 PA 2008 Molt u F20327 l-BLKl Antimony 0002 0020 microgL F203271 PA 2008 Molt u F203271-BLKI Barium 001 020 microgL F203271 PA 2008 Molt u F203271-BLKI Lead 0010 0040 microgL F203271 PA 2008 Moc u
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Page 24of26 1201073 Final Report 04252012 26
~
~TIER~ GLOBAL SCIENCES
11720 North Creek Parkway North Suite 400 Bothell WA 980ll
Ph 425-686-1996 Fx 425-686-3096
PREPARATION BLANKS
Instrument JCPMS-3 Sequence 2C25005
Preparation Closed Vessel Nitric Oven Digestion
Lab Sample ID Analyte Found MRL Units Batch Method Notes
F2033I4-BLK1 Thalium 00007 0010 microgL F2033I4 ~PA 2008 Molt u
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Page 25 o26Liz Siska Project Manager 1201073 Final Report
04252012 27
l l 720 North Creek Parkway North Suite 400~Vi-~ Bothell WA 98011 Ph 425-686-1 996~Tlmiddot~ Fx 425-686-3096
G L OBAL SCIENCE S
Notes and Definitions
U Analyte included in the analysis but not detected
QM-02 The MS andor MSD recoveries outside acceptance limits due to spike concentration less than I times the sample concentration The batch was accepted based on LCS and LCSD recoveries within control limits and when analysis permits acceptable AS ASD
QB-06 The blank was preserved to 5 BrCI rather than I The control limit for blanks preserved to greater than 1 BrCl is the preservation percentage multiplied by the MRL
QB-04 The blank was preserved to 2 BrCI rather than l The control limit for blanks preserved to greater than l BrCI is the preservation percentage multiplied by the MRL
FB-1631 Required equipmentfieldfilter blank not submitted by the client The sample has been analyzed according to 163 lE but does not meet 163 lE criteria
AS This MS andor MSD is an analytical spike andor an analytical spike duplicate
DET Analyte Detected
MDL Minimum Detection Limit
MRL Minimum Reporting Limit
ND Analyte Not Detected at or above the reporting limit
wet Sample results reported on a wet weight basis
dry Sample results reported on a dry weight basis
RPO Relative Percent Difference
RSD Relative Standard Deviation
Frontier Global Sciences Inc The lesults i111his reporl only apply to he samples analyzed In accordance with the chain ofcuslody document This analytical report must be reproduced in its entirely
Page 26of26 1201073 Final Report 04252012
Liz Siska Project Manager
28
CHAIN-OF-(USTODY ttECORD Page i of f 106677 _J
BoLD F1ELDS REQUIRED PLEASE C 1RCLE REQUESTED ANALYSIS
SAMPLE ID
middoti-rg -- bull ~rshy~ _- tzir +- lt-ltJ~ lt
SAMPLING
DATeTtME
IF COMPOSITE INDICATE BOTH
START amp FINISH
DATETIME li1J oc -r 111_- _vlt-c_
w Ishyt 0 n
w l w 0 ~ u X -Xmiddot ~ m Ishy lt( lt( 0
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Trttbull rin K C-~-~ pound1t I 1Jtl~ t20~L lwlJI ishy
middot~ON Mm1x A-Al~ S-SOil GW-GampOUHO WATER SW-SUampfA(f WATER DWmiddotDRIIIKIKlti WATER
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PROJECT MANAGER llr middot1 ~Q Aw4---P1V- Het_ r COMPANY t-lo--tm ~ bd i ( I ~j 6 A ADP~SS 91 g~ez tJshy(ITJ ~ STATE fH_ ZIP c3o--
PHONE 22j-((omiddotf EXT ____
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PROJECT _
OTHEi________STATpound NH MA ME VT
REGULATORY PROGRAM NPDES RGP POTW STORHWATEl OR
GWP OIL FUHD BROWNIIELO OR OTHER----------
Quon PO o2J~-lt1Jpound)
DATE NEEDED _1--1 middot Z=-----shy4 (1-1_ METALS 8 RCRA 13 pp ff MN PB Cu
QAQC REPORTJNGYVEL
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PRESUMPTIVE CERTAINTY
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RECpound1VEO BYRELINQUISHED BY DATE TIME SUSPECTED (OHTAHIHATIOH________
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DISSOLVED METALS FIELD FllTEREDI YES 110
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IF YH FAX OR POf 7~shy Hom (IE SPECIAL DETECTION LINITl BllLIKGINfO If DlffERrnT)ELECTRONIC OPTIONS zo 1 2 2) le~C1 1 Jc Id sJ 60 6c
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ImiddotRELINQUISHED BY DATE TIHE RECflVEO BY I FIELD READINGS
eastern analytical inc 2s CHENELL D R1ve IC 0 Nco1to N H 0330 1 I TEL 60J22aos2s 1aoo2a1os2s IFAx 6032284591 j E-MA1t cus-roM111_mV1c~EAILAsscoMJ www1A1LAascoM
----i pmiddotofissionrrl11bomtorymim (WHITE ORIGINAL GREEN PROJECT MANAGER)
shy
11720 North Creek Parkway North Suite 400 Bothell WA 98011~ Ph 425-686-1996 FRONTIER Fx 425-686-3096
GLOBAL SCIENCES
CHAIN OF CUSTODY FORMS
CML-1d Cc-t~lt7 shy~P~fci amp l sbtr3~~ry Aillylc P~ctirst J- ~V~-=lt S=-Jit=~1t Imiddot~ and 4J~~ Tssul
~ r~middotmiddotmiddot to ~-~ middot ~ ~middot ~rcshyr-11 ---4i--5~1-shy
y1tcirc1middot 6middot 01gter S1bulli1e
1 1 -middot shy
~middot-middotn middot~i---it =-middotmiddotrmiddot~-~r9ft~ri r s L lrj~JT ~- bull 1r bullermiddot~~(~lr- rlt-bull~~~~~ _ -tbull ~t-tmiddotbull I~ bull 1
middot middot l~~e ~middot rv~ 8Arvmiddott _ -middot
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report mus be reproduced in ilS entirety
Page3of26Liz Siska Project Manager 1201073 Final Report
041252012 5
Liz Siska Project Manager
11720 North Creek Parkway North Suite 400 Bothell WA 98011
Ph 425-686- 1996 ~ Fx 425-686-3096 G LOB A L SC I EN CE S
ANALYTICAL RESULTS
Treat Tank Eff Composite
Matrix Water Laboratory ID 1201073-01
Analyte Result MDL MRL Units Dilution Batch Sequence Analyzed Method Notes
Aluminum ND 89 800 microgL 20 F203271 2C22005 032212 EPA 2008 Mod u Antimony 0408 0092 0400 microgL 20 F20327l 2C22005 032212 EPA 2008 Mod Barium 240 054 400 microgL 20 F203271 2C22005 032212 EPA 2008 Mod Beryllium ND 0454 t20 microgL 20 F203271 2C22005 032212 EPA 2008 Mod u Cadmium ND 0083 0400 microgL 20 F203271 2C22005 032212 EPA 2008 Mod u Calcium 5010000 16200 200000 microgL 5000 F203271 2C22005 032212 EPA 2008 Mod Chromium ND 018 200 microgL 20 F20327I 2C22005 032212 EPA 2008 Mod u Copper ND 020 200 microgL 20 F203271 2C22005 032212 EPA 2008 Mod u Iron ND 260 200 microgL 20 F20327l 2C22005 032212 EPA 2008 Mod u Lead ND 0078 0800 microgL 20 F20327l 2C22005 032212 EPA 2008 Mod u Manganese 280 015 200 microgL 20 F203271 2C22005 032212 EPA 2008 Mod Molybdenum 134 012 120 microgL 20 F20327I 2C22005 032212 EPA 2008 Mod Nickel 979 016 2 00 microgL 20 F203271 2C22005 032212 EPA 2008 Mod Silver ND 0120 0400 microgL 20 F203271 2C22005 032212 EPA 2008 Mod u Sodium 259000 23 400 microgL 20 F203271 2C22005 032212 EPA 2008 Mod Thallium 556 0250 100 microgL 100 F203314 2C25005 032512 EPA 2008 Mod Zinc ND 033 400 microgL 20 F203271 2C22005 032212 EPA 2008 Mod u
Frontier Global Sciences Inc The middotesults in 1his report only apply to the samples analyzed in accordance wilh 11e chain ofcus1ody documem This analytical report must be reproduced in ifs entirety
Page 4of26 1201073 Final Report 04252012 6
Liz Siska Project Manager
11720 North Creek Parkway North Suite 400 Bothell WA 98011
Ph 425-686-1996 Fx 425-686-3096
GLOBAt SCIENCES
ANALYTICAL RESULTS
Treat Tank Eff Grab
Matrix Water Laboratory ID 1201073-02
Analyte Result MDL MRL Units Dilution Batch Sequence Analyzed Method Notes
Arsenic 851 102 300 microgL 20 F203271 2C22005 032212 EPA 2008 Mod Mercury 105 034 202 ngL 4 F20I063 2A09010 010912 EPA 1631E FB-1631 Selenium 689 388 120 microgL 20 F203271 2C22005 032212 EPA 2008 Mod
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcustody documenJ This analycical report must be reproduced in its entirety
Page 5 o261201073 Final Report 04252012 7
Liz Siska Project Manager
FRONTIERshycLoaAt SCI ENCES
11720 North Creek Parkway North Suite 400 Bothell WA 98011
Ph 425-686-1996 Fx 425-686-3096
MATRIX DUPLICATESfRIPLICATES
SOURCE 1201073-02
Batch F201063
Preparation BrCI Oxidation
Sequence 2A09010
Lab Number F201063-DUPI
Sample Duplicate Concentration Concentration RPD
Analyte ngL ngL MRL RPD Limit Method Notes Mercury 1048 1054 202 0617 24 EPA I631E
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Page 6of26 1201073 Final Report 04252012 8
11720 North Creek Parkway North Suite 400 BotheE WA 980 l l
Ph 425-686-1996 Fx 425-686-3096
GLOBAL SCIENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1201073-02
Batch F201063 Sequence 2A09010
Preparation BrCI Oxidation Lab Number F20 l 063-MSMSDl
Sample Spike MS MS Concentration Added Concentration RecoveryAnalyte (ngL) (ngL) (ngL) Recovery Method Limits Notes
Mercury 1048 20400 3136 102 71 125 EPA 163IE
Spike MSD MSD Added Concentration oo Recovery RPD
RPD Limits Limit Method Notes Analyte (ngL) (ngL) Recovery
Mercury 20400 2708 814 147 71 - 125 24 EPA 1631E
shy
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Page 7 o26Liz Siska Project Manager 120JO7 3 Final Repo1
04252012 9
Liz Siska Project Manager
11720 North Creek Parkway North Suite 400 Bothell WA 98011
Ph 425-686-1996~ Fx 425-686-3096 CL06AL SCIENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1112278-02
Batch F201063 Sequence 2A09010
Preparation BrCI Oxidation Lab Number F20 l 063-MSMSD2
Sample Spike MS MS
Analyte Concentration
(ogL) Added (ngL)
Concentration (ngL)
Recovery
RecoveryLimits Method Notes
Mercury 761 20400 2786 992 71 125 EPA 1631E
Spike MSD MSD Added Concentration Oo Recovery RPO
Analyte (ngL) (ngL) Recovery RPO Limits Limit Method Notes
Mercury 20400 2837 102 182 71 - 125 24 EPA l631E
shy
Frontier Global Sciences Inc The results in this report only apply to the somples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Page 8 o26 1201073 Final Report 042512012 10
11720 North Creek Parkway North Suite 400 Bothell WA 980 l l
Ph 425-686-1996 ~ Fx 425-686-3096 GLOBAL SCIENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1201029-01
Batch
Preparation
F201063
BrCI Oxidation
Sequence
Lab Number
2A09010
F20 I 063-MSMSD3
Analyte
Mercury
Analyte
Mercury
Sample Spike Concentration Added
(ngL) (ngL)
534 10200
Spike MSD Added Concentration (ngL) (ngL)
10200 1407
MS MS Concentration Recovery
(ngL) Recovery Limits
1558 JOO 7l shy 125
MSD oo Recovery RPD
Recovery RPD Limits Limit
856 102 71 - 125 24
Method
EPA l63lE
Method
EPA 631E
Notes
Notes
Frontier Global Sciences Inc The results in this repon only apply to rhe samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Page 9of26 1201073 Final Report 041252012
Liz Siska Project Manager
1 1
11720 North Creek Parkway North Suite 400 Bothell WA 98011
Ph 425-686-1996 FRONTIER- Fx 425-686-3096 cLosAL SCIENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1201030-02
Batch F20I063 Sequence 2A09010
Preparation BrCI Oxidation Lab Number F201063-MSMSD4
Sample Spike MS MS Concentration Added Concentration RecoveryAnalyte (ngL) (ngL) (ngL) Recovery MethodLimits Notes
Mercury 554 10200 1482 910 71 - 125 EPA I631E
Spike MSD MSD Oo Added Concentratio11 Recovery RPD
RPD Limits Limit Method Analyte (ngL) (ngL) Recovery Notes
Mercury 10200 1461 890 140 71 - 125 24 EPA 163IE
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed m accordance with the chain ofcus1ody document This anayt(ca repon must be reproduced in itr entirety
Page lOo26Liz Siska Project Manager 1201073 Final Report
041252012 12
I 1720 North Creek Parkway North Suite 400 Bothe I I WA 98011
Ph 425-686-1996 ~ Fx 425-686-3096 GLOBAL SCIENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1201073-01RE3
Batch F20327l Sequence 2C22005
Prcpa ration ((01ed Vessel ~ itric Oven Digestion Lab Number F203271-MSMSD 1
Analyte
Sample Concentration
(microgL)
Spike Added (microgL)
MS Concentration
(microgL)
MS Oo
Recovery Recovery
Method Limits Notes
Calcium 5013000 15150 4802000 -13900 70- 130 EPA 2008 Mod QM-02
Analyte
Spike Added (microgL)
MSD Concentration
(microgL)
MSD ~o
Recovery
Oo
RPD Recovery
Limits RPDLimit Method Notes
Calcium 15150 4943000 -4600 289 70 - 130 20 EPA 2008 Mod QM-02
Frontier Global Sciences Inc The results in this report only apply to the samples analyud inaccordance with the chain ofcustody document 17is analyticol report must be reproduced in its entirety
Page lI o16 1101073 Final Report 04152012
Liz Siska Project Manager
13
l l 720 North Creek Parkway North Suite 400 Bothell WA 98011
Ph 425-686-1996FRONTIER Fx 425-686-3096 GLOBAL SCIENCES
MATRIX SPIKE I MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1201073-01RE4
Batch F203271 Sequence 2C22005
Preparation Closed Vessel Nitric Oven Digestion Lab Number F203271-MSMSD2
Sample Spike MS MS Concentration Added Concentration Oo RecoveryAnalyte (microgL) (microgL) (microgL) Recovery Method Limits Notes
Beryllium 0507 20200 2442 958 70 - 130 EPA 2008 Mod Sodium 258800 50500 257700 -213 70 -130 EPA 2008 Mod QM-02 Aluminum 529 15150 2023 986 70 - 130 EPA 2008 Mod Chromium 057 70700 804 106 70 - 130 EPA 2008 Mod Manganese 2805 60600 2834 476 70 - 130 EPA 2008 Mod QM-02 Iron ND 50500 5200 103 70 130 EPA 2008 Mod Nickel 979 40400 141 l 107 70- 130 EPA 2008 Mod Copper 055 40400 434 939 70 - 130 EPA 2008 Mod Zinc 040 10100 842 794 70 - 130 EPA 2008 Mod Arsenic 1030 15150 2418 916 70 - 130 EPA 2008 Mod Selenium 6340 30300 8973 869 70 130 EPA 2008 Mod Molybdenum 1338 20200 1367 142 70 130 EPA 2008 Mod QM-02 Silver ND 15150 1388 916 70 - 130 EPA 2008 Mod Cadmium 0332 080800 1105 middot956 70 - 130 EPA 2008 Mod Antimony 0408 080800 1259 105 70- 130 EPA 2008 Mod Barium 2397 10100 2495 968 70 - 130 EPA 2008 Mod Lead ND 15150 1542 102 70 130 EPA 2008 Mod
shy
shy
shy
shy
Analyte
Spike Added (microgL)
MSD Concentration
(microgL)
MSD Oo
Recovery
Oo
RPD Recovery
Limits RPD Limit Method Notes
Beryllium
Sodium
Aluminum
Chromium
Manganese
Iron
Nickel
Copper
Zinc
Arsenic
Selenium
Molybdenum
20200
50500
15150
7Q700
60600
50500
40400
40400
10100
15150
30300
20200
2561
257100
2034
773
2852
5187
1381
419
916
2225
9400
1366
102
-336
993
101 769
103
995
902
868
789
101
137
474
0243
0564
385
0625
0242
213
347
849
831
464
00771
70 - 130
70 bull 130 70 - 130
70 - 130
70 - 130
70 - 130
70 - 130
70 - 130
70 - 130
70 bull 130 70 - 130
70 - 130
20
20
20
20
20
20
20
20
20
20
20
20
EPA 2008 Mod
EPA 2008 Mod
EPA 2008 Mod
EPA 2008 Mod
EPA 2008 Mod
EPA 2008 Mod
EPA 2008 Mod
EPA 2008 Mod
EPA 2008 Mod
EPA 2008 Mod
EPA 2008 Mod
EPA 2008 Mod
QM-02
QM-02
Frontier G lobal Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
--f_~ --~~~-~ -middot middot Page 12 o261201073 Final Report 041252012
Liz Siska Project Manager
14
11720 North Creek Parkway North Suite 400
~ Bothell WA 98011
~TIEmiddot Ph 425-686-1996 Fx 425-686-3096
GLOB11L SCIENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPO
SOURCE 1201073-01RE4
Batch F203271 Sequence 2C22005
Preparation ~lo~ed Vessel Nitric Oven Digestion Lab Number F20327 I-MSMSD2
Spike MSD MSD Added Concentration Oo Recovery RPO
Analyte (microgL) (microgL) Recovery RPD Limits Limit Method Notes
Silver 15150 1387 915 00874 70 - 130 20 EPA 2008 Mod Cadmium 080800 1061 902 403 70 - 130 20 EPA 200amp Mod Antimony 080800 1274 107 l2l 70 - 130 20 EPA 2008 Mod Barium 10100 2514 )16 0781 70 - 130 20 EPA 200amp Mod Lead 15150 1534 101 0525 70 shy 130 20 EPA 2008 Mod
Frontier Global Sciences Inc The results in this report only apply to 1he samples analyzed in accordance wiih the chain ofcustody document This analytical repo1 must be reproduced in ils entirety
Page 13 o26Liz Siska Project Manager 1201073 Final Reporl
04252012 15
11720 North Creek Parkway North Suite 400
~ Bothell WA 98011 Ph 425-686-I996
~RONTIER~ Fx 425-686-3096 GLOBAL SCIEN C ES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1201073-01RE3
Batch F203271 Sequence 2~22005
Preparation Closed Vessel Nitric Oven Digestion Lab Number F20327 I-MSMSD3
Sample Spike MS MS
Analyte Concentration
(microgL) Added (microgL)
Concentration (microgL) Recovery
Recovery Limits Method Notes
Calcium 5013000 10100000 15120000 100 70- 130 EPA 2008 Mod AS
Spike MSD MSD Added Concentration o Oo Recovery RPD
Analyte (microgL) (microgL) Recovery RPD Limits Limit Method Notes
Calcium 10100000 16140000 llO 653 70 - 130 20 EPA 2008 Mod AS
Frontier Global Sciences Inc The results in his report only apply 10 the samples analyzed in accordance ivth he chain ofcustody document This analytical report must be reproduced in its entirety
Page 14 o261201073 Final Report 0425201]
Liz Siska Project Manager
16
Frontier Global Sciences Inc The ruults in this rechain ofcustody do
~ -lt1-c--~ Liz Siska Project Manager
11720 North Creek Parkway North Suite 400 Bothell WA 98011
Ph 425-686-1996 Fx 425-686-3096
GLOBAL SCIENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1201073-01RE4
Batch J203271 Sequence 2C22005
Preparation ~ IQsed Ve~~el Nitric Oven Qigestion Lab Number F203271-MSMSQ4
Analyte
Beryllium
Sample Concentration
(11gL)
0507
Spike Added (11gL)
20200
MS Concentration
(microgL)
2041
MS Oo
Recovery
985
RecoveryMethod Limits
70 - 130 EPA 2008 Mod
Notes
AS
Sodium 258800 40400 292900 845 70- 130 EPA 2008 Mod AS
Aluminum 529 40400 3956 966 70 - 130 EPA 2008 Mod AS
Chromium 057 40400 430l 106 70- 130 EPA 2008 Mod AS
Manganese 2805 40400 7042 105 70 - 130 EPA 2008 Mod AS
Iron ND 20200 2121 105 70 - 130 EPA 2008 Mod AS
Nickel 979 50500 5112 993 70 l30 EPA 2008 Mod AS
Copper 055 50500 4754 940 70 - 130 EPA 2008 Mod AS
Zinc 040 10100 9074 898 70 - 130 EPA 2008 Mod AS
Arsenic 1030 40400 4317 104 70 130 EPA 2008 Mod AS
Selenium 6340 40400 4688 100 70 - 130 EPA 2008 Mod AS
Molybdenum 1338 20200 338l 101 70 - 130 EPA 2008 Mod AS
Silver ND 20200 1850 916 70 130 EPA 2008 Mod AS
Cadmium 0332 40400 3937 966 70 130 EPA 2008 Mod AS
Antimony 0408 20200 2091 102 70 - 130 EPA 2008 Mod AS
Barium 2397 80800 1056 101 70- 130 EPA 2008 Mod AS
Lead ND IO100 9932 983 70 130 EPA 2008 Mod AS
shy
shy
shy
shy
shy
Analyte
Spike Added (microgL)
MSD Concentration
(microgL)
MSD
Recovery
RPD
Recovery Limits
RPDLimit Method Notes
Beryllium 20200 2007 968 l71 70 - 130 20 EPA 2008 Mod AS Sodium 40400 292600 837 0114 70 130 20 EPA 2008 Mod AS Aluminum 40400 3954 966 00362 70 - 130 20 EPA 2008 Mod AS Chromium 40400 4287 106 0337 70 - 130 20 EPA 2008 Mod AS Manganese 40400 6944 102 140 70 - 130 20 EPA 2008 Mod AS Iron 20200 2077 103 211 70 - 130 20 EPA 2008 Mod AS Nickel 50500 5126 996 0276 70 - 130 20 EPA 2008 Mod AS Copper 50500 4707 931 0997 70 - 130 20 EPA 200 8 Mod AS Zinc 10100 9059 896 0166 70 - 130 20 EPA 2008 Mod AS Arsenic 40400 4299 104 0419 70 - 130 20 EPA 2008 Mod AS Selenium 40400 4682 100 0141 70 - 130 20 EPA 2008 Mod AS Molybdenum 20200 3365 100 0473 70 - 130 20 EPA 2008 Mod AS
shy
port only apply to the sampltts analyzed in accordance with the cument This analytical report must be reproduced in its entirety
Page 5 o26 201073 Final Report 042512012 17
Liz Sia Project Manager
11720 North Creek Parkway North Suite 400 Botheln VA 98011
Ph 425-686-1996 Fx 425-686-3096
CLOBAL SCIENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1201073-01RE4
Batch F203271 Sequence 2c2io2~
Preparation Clo~ed Vessel litric Oven Digestion Lab Number F20327 l -MSMSQ4
Analyte
Spike Added (microgL)
MSD Concentration
(microgL)
MSD
Recovery
Oo
RPD Recovery
Limits RPOLimit Method Notes
Silver 20200 1895 938 242 70 - 130 20 EPA 2008 Mod AS Cadmium 40400 3933 965 0104 70 -130 20 EPA 2008 Mod AS Antimony 20200 2107 102 0736 70- 130 20 EPA 2008 Mod AS
Barium 80800 1058 101 0205 70 - 130 20 EPA 2008 Mod AS
Lead 10100 9877 978 0549 70 - 130 20 EPA 2008 Mod AS
Frontier Global Sciences Inc The results in this report only apply to the samples analyudin accordance with lht chain ofcustody document This analytical report must be reproductd rn ilS enlirtty
Page l6of26 1201073 Final Report Ofn5202 18
l I 720 North Creek Parkway North Suite 400 Bothell WA 980I I
Ph 425-686-1996 Fx 425-686-3096
GLO B AL SCIENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1201073-01RE6
Batch F203314 Sequence 2C25005
Preparation Closed Vessel Nitric Oven Digestion Lab Number F203314-MSMSD2
Sample Spike MS MS Concentration Added Concentration RecoveryAnalyte (microgL) (microgL) (microgL) Recovery Method NotesLimits
Thallium 5563 040400 5875 773 70 - 130 EPA 2008 Mod
Spike MSD MSD Added o Concentration Recovery RPD
RPO Limits Limit Method Notes Analyte (microgL) (microgL) Recovery
Thallium 040400 5880 785 00859 70 - 130 20 EPA 2008 Mod
Frontier Global Sciences Inc 11e results in chis reporc only apply 10 1he samples analyzed in accordance wilh lhe chain ofcustody documenz This analycical report musl be reproduced in ils entirety
Page 17 of26 1201073 Fi11aReport 0412512012
Liz Siska Project Manager
19
11720 North Creek Parkway North Suite 400 Bothell WA 98011
Ph 425-686-1996 Fx 425-686-3096
GLOBAl SCIENC ES
MATRIX SPIKE I MATRIX SPIKE DUPLICATE RECOVERY AND RPO
SOURCE I201073-01RE6
Batch F203314
Preparation Closed Vessel Nitric Oven Digestion
Sequence 2C25005
Lab Number F203314-MSMSD4
Analyte
Sample Concentration
(microgL)
Spike Added (microgL)
MS MS Concentration Oo
(microgL) Recovery Recovery
Limits Method Notes
Thallium 5563 10100 1033 968 70- 130 EPA 2008 Mod AS
Analyte
Spike Added (microgL)
MSD Concentration
(microgL)
MS)) Oo
Recovery
RPD
Recovery Limits
RPD Limit Method Notes
Thallium IO100 1037 97l 0341 70 - 130 20 EPA 2008 Mod AS
Frontier Global Sciences Inc The resulrs in this report only apply to the samples analyzed in accordance with the chain ofcusrody document This analytical report must be reproduced in its entirely
Page 18of26 120073 Final Report 04252012
Liz Siska Project Manager
20
11720 North Creek Parkway North Suite 400 l ~ Bothell WA 980 l l Ph 425-686-1996
FRONTIER Fx 425-686-3096 GLOBAL SCIENCES
LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLICATE
RECOVERY AND RPD
Batch F20 l063 Sequence 2A09010
Preparation BrCI Oxidation Lab Number F201063-BSIBSJ21
LCS Source N ist 1641d
Analyte
Spike Added (ngL)
LCS Concentration
(ngL)
LCS
Recovery Recovery
Limits Method Notes
Mercury 15679 1550 988 80 - 120 EPA I631E
Analyte
Spike Added (ngL)
LCSD Concentration
(ngL)
LCSD Oo
Recovery
RPD Recovery
Limits RPD Limit Method Notes
Mercury 15679 1595 [02 289 80 - 120 24 EPA I631E
Frontier Global Sciences Inc The results in this report only apply to the samples analyzedin accordance with the chain ofcustody document This analytical report must be reproduced in ils entirety
Page 19of26 1201073 Final Report 0425 2012
Liz Siska Project Manager
21
11720 North Creek Parkway North Suite 400 Bothell WA 98011
Ph 425-686-1996 FRONTIER Fx 425-686-3096 GLOBAL SCIENCES
LABORA TORY CONTROL SAMPLE LABO RATORY CONTROL SAMPLE DUPLICATE
RECOVERY AND RPD
Batch F203271 Sequence 2C22005
Preparation Closed Vessel Nitric Oven Digestion Lab Number F203271-BSBSD1
LCS Source Blank Spike
Spike LCS LCS Added Concentration Oo Recovery
Analyte (microgL) (microgL) Recovery Limits Method Notes
Beryllium 20000 l930 965 85 - 115 EPA 2008 Mod
Sodium 50000 499 998 85 - 115 EPA 2008 Mod
Aluminum 15000 1460 973 85 - 115 EPA 2008 Mod
Calcium 15000 1528 102 85 - 115 EPA 2008 Mod
Chromium 70000 657 939 85 - 115 EPA 2008 Mod
Manganese 60000 586 976 85 - 115 EPA 2008 Mod
Iron 50000 4753 951 85 shy 115 EPA 2008 Mod
Nickel 40000 401 100 85 - 115 EPA 2008 Mod
Copper 40000 418 105 85 - 115 EPA 2008 Mod
Zinc 10000 1033 103 85 - 115 EPA 2008 Mod
Arsenic 15000 1437 958 85 - 115 EPA 2008 Mod
Selenium 30000 2966 989 85 - 115 EPA 2008 Mod
Molybdenum 20000 181 905 85 shy 115 EPA 2008 Mod
Silver 15000 1517 101 85 shy 115 EPA 2008 Mod
Cadmium 080000 0781 976 85 - 1lS EPA 2008 Mod
Antimony 080000 0815 102 85 - 115 EPA 2008 Mod
Barium 10000 969 969 85 - 115 EPA 2008 Mod
Lead 15000 1597 106 85 - 115 EPA 2008 Mod
Spike LCSD LCSD Added Concentration Recovery RPO
Analyte (microgL) (microgL) Recovery RPO Limits Limit Method Notes
Beryllium 20000 1949 974 0955 85 - 115 20 EPA 2008 Mod
Sodium 50000 500 100 0216 85 - 115 20 EPA 2008 Mod
Aluminum 15000 1485 990 171 85 - 115 20 EPA 2008 Mod
Calcium 15000 1544 103 103 85 - 115 20 EPA 2008 Mod
Chromium 70000 667 953 148 85 - 115 20 EPA 2008 Mod
Manganese 60000 596 994 175 85 - 115 20 EPA 2008 Mod
Iron 50000 4852 970 206 85 - 115 20 EPA 2008 Mod
Nickel 40000 402 IOI 0246 85 - 115 20 EPA 2008 Mod
Frontier Global Sciences Inc The results in his report only apply to the samples analyzed in accordance wirh the chain ofcustody document This analytical report must be reproduced in iLS entirety
Page 20of26 1201073 Final Report 04252012
Liz Siska Project Manager
22
11720 North Creek Parkway North Suite 400 ~~shy Bothell WA 98011 Ph 425-686-1996~ONTif Fx 425-686-3096
GLOBAL SCIENCES
LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLICATE
RECOVERY AND RPO
Batch F20327 l Sequence 2C22005
Preparation Closed Vessel Nitric Oven Digestion Lab Number F203271-BSBSD 1
LCS Source Blank Spike
Analyte
Spike Added (microgL)
LCSD Concentration
(microgL)
LCSD oo
Recovery
RPO Recovery
Limits RPO Limit Method Notes
Copper
Zinc
Arsenic
Selenium
40000
10000
15000
30000
428
1039
1452
3015
107
104
968
101
224
0570
0977
166
85 - 115
85 - 115
85 - 115
85 - 115
20
20
20
20
EPA 2008 Mod
EPA 2008 Mod
EPA 2008 Mod
EPA 2008 Mod Molybdenum
Silver
20000
15000
182
J502
910
100
0564
103
85 - 115
85 - 115
20
20
EPA 2008 Mod
EPA 2008 Mod Cadmium
Antimony
Barium
Lead
080000
080000
10000
15000
0828
0808
986
1620
103
101
986
108
585
0848
177
142
85 - 115
85 - 115
85 shy 11 S
85 - 115
20
20
20
20
EPA 2008 Mod
EPA 2008 Mod
EPA 2008 Mod
EPA 2008 Mod
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report mus be reproducedin its entirety
Page 2 o26J20J073 Final Report 041252012
Liz Siska Project Manager
23
11720 North Creek Parkway North Suite 400 Bothell WA 980 l l
Ph 425-686-1996FRONT[ER- Fx 425-686-3096 cLosAL SCIEN _CES
LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLICATE
RECOVERY AND RPD
Batch F203314 Sequence 2C25005
Preparation Closed Vessel Nitric Oven Digestion Lab Number F2033 l 4-BSBSD 1
LCS Source Blank Spike
Analyte
Thallium
Spike Added (microgL)
LCS Concentration
(microgL)
LCS 0o
Recovery Recovery
Limits Method
040000 0396 989 85 - 115 EPA 2008 Mod
Notes
Analyte
Spike Added (microgL)
LCSD Concentration
(microgL)
LCSD 0o
Recovery
RPD Recovery
Limits RPO Limit Method Notes
Thallium 040000 0391 978 112 85 - ll5 20 EPA 2008 Mod
Frontier Global Sciences Inc The results in this report only apply to the samples anayed in accordance with the chain ofcustody docwnenJ This analytical report must be reproduced in its entirety
Page 22of26 1201073 Final Report 04252012
Liz Siska Project Manager
24
Liz Siska P roject Manager
11720 North Creek Parkway North Suite 400
~ Bothell WA 98011 Ph 425-686-1996
~JTIEif middot Fx 425-686-3096 GLOBAL SCIENCES
PREPARATION BLANKS
Instrument Hg-17 Sequence 2A09010
Preparation BrCI Oxidation
Lab Sample ID Analyte Found MRL Units Batch Method Notes
F201063-BLK I Mercury -0009 050 ngL F201063 EPA 1631E u F20 I063-BLK2 Mercury -0006 050 ngL F201063 EPA 1631E u F201063-BLK3 Mercury -002 050 ngL F201063 EPA 163IE u F201063-BLK4 Mercury 003 050 ngL F201063 EPA 1631E U QB-04 F201063-BLKS Mercury 011 052 ngL F201063 EPA I631E U QB-06
Frontier Global Sciences Inc The results in this report only apply 10 1he samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Page 23 o26 1201073 Final Repon 04252012 25
Liz Siska Project Manager
11720 North Creek Parkway North Suite 400 Bothell WA 98011
Ph 425-686-1996 FROr~TIER- Fx 425-686-3096 GLOBAL SCIENCES
PREPARATION BLANKS
Instrument ICPMS-6 Sequence 2C22005
Preparation Closed Vessel Nitric Oven Digestion
Lab Sample ID Analyte Found MRL Units Batch Method Notes
F203271-BLK1 Beryllium 000008 0060 microgL F203271 PA 2008 Molt u F20327 1-BLK1 Sodium 2 20 microgL F20327l PA 2008 Moc u F20327I-BLK1 Aluminum -004 40 microgL F203271 PA 2008 Molt u F20327I -BLK1 Calcium 40 microgL F203271 PA 2008 Molt u F203271 -BLK1 Chromium -002 010 microgL F203271 ~A 2008 Molt u F203271-BLKI Manganese 001 010 microgL F203271 PA 2008 Molt u F20327 l -BLK 1 Iron -002 100 microgL F203271 PA 2008 Molt u F203271-BLKI Nickel 0004 010 microgL F203271 PA 2008 Moc u F203271-BLK1 Copper 0003 010 microgL F203271 PA 2008 Moc u F203271-BLK1 Zinc 0007 020 microgL F203271 PA 2008 Moc u F203271-BLK1 Arsenic -006 015 microgL F203271 PA 2008 Moc u F203271-BLK1 Selenium -002 060 microgL F203271 PA 2008 Moc u F203271-BLK1 Molybdenum 001 006 microgL F203271 PA 2008 Molt u F203271-BLK1 Silver -00005 0020 microgL F203271 PA 2008 Molt u F203271-BLKl Cadmium 0004 0020 microgL F203271 PA 2008 Molt u F20327 l-BLKl Antimony 0002 0020 microgL F203271 PA 2008 Molt u F203271-BLKI Barium 001 020 microgL F203271 PA 2008 Molt u F203271-BLKI Lead 0010 0040 microgL F203271 PA 2008 Moc u
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Page 24of26 1201073 Final Report 04252012 26
~
~TIER~ GLOBAL SCIENCES
11720 North Creek Parkway North Suite 400 Bothell WA 980ll
Ph 425-686-1996 Fx 425-686-3096
PREPARATION BLANKS
Instrument JCPMS-3 Sequence 2C25005
Preparation Closed Vessel Nitric Oven Digestion
Lab Sample ID Analyte Found MRL Units Batch Method Notes
F2033I4-BLK1 Thalium 00007 0010 microgL F2033I4 ~PA 2008 Molt u
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Page 25 o26Liz Siska Project Manager 1201073 Final Report
04252012 27
l l 720 North Creek Parkway North Suite 400~Vi-~ Bothell WA 98011 Ph 425-686-1 996~Tlmiddot~ Fx 425-686-3096
G L OBAL SCIENCE S
Notes and Definitions
U Analyte included in the analysis but not detected
QM-02 The MS andor MSD recoveries outside acceptance limits due to spike concentration less than I times the sample concentration The batch was accepted based on LCS and LCSD recoveries within control limits and when analysis permits acceptable AS ASD
QB-06 The blank was preserved to 5 BrCI rather than I The control limit for blanks preserved to greater than 1 BrCl is the preservation percentage multiplied by the MRL
QB-04 The blank was preserved to 2 BrCI rather than l The control limit for blanks preserved to greater than l BrCI is the preservation percentage multiplied by the MRL
FB-1631 Required equipmentfieldfilter blank not submitted by the client The sample has been analyzed according to 163 lE but does not meet 163 lE criteria
AS This MS andor MSD is an analytical spike andor an analytical spike duplicate
DET Analyte Detected
MDL Minimum Detection Limit
MRL Minimum Reporting Limit
ND Analyte Not Detected at or above the reporting limit
wet Sample results reported on a wet weight basis
dry Sample results reported on a dry weight basis
RPO Relative Percent Difference
RSD Relative Standard Deviation
Frontier Global Sciences Inc The lesults i111his reporl only apply to he samples analyzed In accordance with the chain ofcuslody document This analytical report must be reproduced in its entirely
Page 26of26 1201073 Final Report 04252012
Liz Siska Project Manager
28
CHAIN-OF-(USTODY ttECORD Page i of f 106677 _J
BoLD F1ELDS REQUIRED PLEASE C 1RCLE REQUESTED ANALYSIS
SAMPLE ID
middoti-rg -- bull ~rshy~ _- tzir +- lt-ltJ~ lt
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IF COMPOSITE INDICATE BOTH
START amp FINISH
DATETIME li1J oc -r 111_- _vlt-c_
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PROJECT MANAGER llr middot1 ~Q Aw4---P1V- Het_ r COMPANY t-lo--tm ~ bd i ( I ~j 6 A ADP~SS 91 g~ez tJshy(ITJ ~ STATE fH_ ZIP c3o--
PHONE 22j-((omiddotf EXT ____
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DATE NEEDED _1--1 middot Z=-----shy4 (1-1_ METALS 8 RCRA 13 pp ff MN PB Cu
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DISSOLVED METALS FIELD FllTEREDI YES 110
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IF YH FAX OR POf 7~shy Hom (IE SPECIAL DETECTION LINITl BllLIKGINfO If DlffERrnT)ELECTRONIC OPTIONS zo 1 2 2) le~C1 1 Jc Id sJ 60 6c
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ImiddotRELINQUISHED BY DATE TIHE RECflVEO BY I FIELD READINGS
eastern analytical inc 2s CHENELL D R1ve IC 0 Nco1to N H 0330 1 I TEL 60J22aos2s 1aoo2a1os2s IFAx 6032284591 j E-MA1t cus-roM111_mV1c~EAILAsscoMJ www1A1LAascoM
----i pmiddotofissionrrl11bomtorymim (WHITE ORIGINAL GREEN PROJECT MANAGER)
shy
Liz Siska Project Manager
11720 North Creek Parkway North Suite 400 Bothell WA 98011
Ph 425-686- 1996 ~ Fx 425-686-3096 G LOB A L SC I EN CE S
ANALYTICAL RESULTS
Treat Tank Eff Composite
Matrix Water Laboratory ID 1201073-01
Analyte Result MDL MRL Units Dilution Batch Sequence Analyzed Method Notes
Aluminum ND 89 800 microgL 20 F203271 2C22005 032212 EPA 2008 Mod u Antimony 0408 0092 0400 microgL 20 F20327l 2C22005 032212 EPA 2008 Mod Barium 240 054 400 microgL 20 F203271 2C22005 032212 EPA 2008 Mod Beryllium ND 0454 t20 microgL 20 F203271 2C22005 032212 EPA 2008 Mod u Cadmium ND 0083 0400 microgL 20 F203271 2C22005 032212 EPA 2008 Mod u Calcium 5010000 16200 200000 microgL 5000 F203271 2C22005 032212 EPA 2008 Mod Chromium ND 018 200 microgL 20 F20327I 2C22005 032212 EPA 2008 Mod u Copper ND 020 200 microgL 20 F203271 2C22005 032212 EPA 2008 Mod u Iron ND 260 200 microgL 20 F20327l 2C22005 032212 EPA 2008 Mod u Lead ND 0078 0800 microgL 20 F20327l 2C22005 032212 EPA 2008 Mod u Manganese 280 015 200 microgL 20 F203271 2C22005 032212 EPA 2008 Mod Molybdenum 134 012 120 microgL 20 F20327I 2C22005 032212 EPA 2008 Mod Nickel 979 016 2 00 microgL 20 F203271 2C22005 032212 EPA 2008 Mod Silver ND 0120 0400 microgL 20 F203271 2C22005 032212 EPA 2008 Mod u Sodium 259000 23 400 microgL 20 F203271 2C22005 032212 EPA 2008 Mod Thallium 556 0250 100 microgL 100 F203314 2C25005 032512 EPA 2008 Mod Zinc ND 033 400 microgL 20 F203271 2C22005 032212 EPA 2008 Mod u
Frontier Global Sciences Inc The middotesults in 1his report only apply to the samples analyzed in accordance wilh 11e chain ofcus1ody documem This analytical report must be reproduced in ifs entirety
Page 4of26 1201073 Final Report 04252012 6
Liz Siska Project Manager
11720 North Creek Parkway North Suite 400 Bothell WA 98011
Ph 425-686-1996 Fx 425-686-3096
GLOBAt SCIENCES
ANALYTICAL RESULTS
Treat Tank Eff Grab
Matrix Water Laboratory ID 1201073-02
Analyte Result MDL MRL Units Dilution Batch Sequence Analyzed Method Notes
Arsenic 851 102 300 microgL 20 F203271 2C22005 032212 EPA 2008 Mod Mercury 105 034 202 ngL 4 F20I063 2A09010 010912 EPA 1631E FB-1631 Selenium 689 388 120 microgL 20 F203271 2C22005 032212 EPA 2008 Mod
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcustody documenJ This analycical report must be reproduced in its entirety
Page 5 o261201073 Final Report 04252012 7
Liz Siska Project Manager
FRONTIERshycLoaAt SCI ENCES
11720 North Creek Parkway North Suite 400 Bothell WA 98011
Ph 425-686-1996 Fx 425-686-3096
MATRIX DUPLICATESfRIPLICATES
SOURCE 1201073-02
Batch F201063
Preparation BrCI Oxidation
Sequence 2A09010
Lab Number F201063-DUPI
Sample Duplicate Concentration Concentration RPD
Analyte ngL ngL MRL RPD Limit Method Notes Mercury 1048 1054 202 0617 24 EPA I631E
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Page 6of26 1201073 Final Report 04252012 8
11720 North Creek Parkway North Suite 400 BotheE WA 980 l l
Ph 425-686-1996 Fx 425-686-3096
GLOBAL SCIENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1201073-02
Batch F201063 Sequence 2A09010
Preparation BrCI Oxidation Lab Number F20 l 063-MSMSDl
Sample Spike MS MS Concentration Added Concentration RecoveryAnalyte (ngL) (ngL) (ngL) Recovery Method Limits Notes
Mercury 1048 20400 3136 102 71 125 EPA 163IE
Spike MSD MSD Added Concentration oo Recovery RPD
RPD Limits Limit Method Notes Analyte (ngL) (ngL) Recovery
Mercury 20400 2708 814 147 71 - 125 24 EPA 1631E
shy
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Page 7 o26Liz Siska Project Manager 120JO7 3 Final Repo1
04252012 9
Liz Siska Project Manager
11720 North Creek Parkway North Suite 400 Bothell WA 98011
Ph 425-686-1996~ Fx 425-686-3096 CL06AL SCIENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1112278-02
Batch F201063 Sequence 2A09010
Preparation BrCI Oxidation Lab Number F20 l 063-MSMSD2
Sample Spike MS MS
Analyte Concentration
(ogL) Added (ngL)
Concentration (ngL)
Recovery
RecoveryLimits Method Notes
Mercury 761 20400 2786 992 71 125 EPA 1631E
Spike MSD MSD Added Concentration Oo Recovery RPO
Analyte (ngL) (ngL) Recovery RPO Limits Limit Method Notes
Mercury 20400 2837 102 182 71 - 125 24 EPA l631E
shy
Frontier Global Sciences Inc The results in this report only apply to the somples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Page 8 o26 1201073 Final Report 042512012 10
11720 North Creek Parkway North Suite 400 Bothell WA 980 l l
Ph 425-686-1996 ~ Fx 425-686-3096 GLOBAL SCIENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1201029-01
Batch
Preparation
F201063
BrCI Oxidation
Sequence
Lab Number
2A09010
F20 I 063-MSMSD3
Analyte
Mercury
Analyte
Mercury
Sample Spike Concentration Added
(ngL) (ngL)
534 10200
Spike MSD Added Concentration (ngL) (ngL)
10200 1407
MS MS Concentration Recovery
(ngL) Recovery Limits
1558 JOO 7l shy 125
MSD oo Recovery RPD
Recovery RPD Limits Limit
856 102 71 - 125 24
Method
EPA l63lE
Method
EPA 631E
Notes
Notes
Frontier Global Sciences Inc The results in this repon only apply to rhe samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Page 9of26 1201073 Final Report 041252012
Liz Siska Project Manager
1 1
11720 North Creek Parkway North Suite 400 Bothell WA 98011
Ph 425-686-1996 FRONTIER- Fx 425-686-3096 cLosAL SCIENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1201030-02
Batch F20I063 Sequence 2A09010
Preparation BrCI Oxidation Lab Number F201063-MSMSD4
Sample Spike MS MS Concentration Added Concentration RecoveryAnalyte (ngL) (ngL) (ngL) Recovery MethodLimits Notes
Mercury 554 10200 1482 910 71 - 125 EPA I631E
Spike MSD MSD Oo Added Concentratio11 Recovery RPD
RPD Limits Limit Method Analyte (ngL) (ngL) Recovery Notes
Mercury 10200 1461 890 140 71 - 125 24 EPA 163IE
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed m accordance with the chain ofcus1ody document This anayt(ca repon must be reproduced in itr entirety
Page lOo26Liz Siska Project Manager 1201073 Final Report
041252012 12
I 1720 North Creek Parkway North Suite 400 Bothe I I WA 98011
Ph 425-686-1996 ~ Fx 425-686-3096 GLOBAL SCIENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1201073-01RE3
Batch F20327l Sequence 2C22005
Prcpa ration ((01ed Vessel ~ itric Oven Digestion Lab Number F203271-MSMSD 1
Analyte
Sample Concentration
(microgL)
Spike Added (microgL)
MS Concentration
(microgL)
MS Oo
Recovery Recovery
Method Limits Notes
Calcium 5013000 15150 4802000 -13900 70- 130 EPA 2008 Mod QM-02
Analyte
Spike Added (microgL)
MSD Concentration
(microgL)
MSD ~o
Recovery
Oo
RPD Recovery
Limits RPDLimit Method Notes
Calcium 15150 4943000 -4600 289 70 - 130 20 EPA 2008 Mod QM-02
Frontier Global Sciences Inc The results in this report only apply to the samples analyud inaccordance with the chain ofcustody document 17is analyticol report must be reproduced in its entirety
Page lI o16 1101073 Final Report 04152012
Liz Siska Project Manager
13
l l 720 North Creek Parkway North Suite 400 Bothell WA 98011
Ph 425-686-1996FRONTIER Fx 425-686-3096 GLOBAL SCIENCES
MATRIX SPIKE I MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1201073-01RE4
Batch F203271 Sequence 2C22005
Preparation Closed Vessel Nitric Oven Digestion Lab Number F203271-MSMSD2
Sample Spike MS MS Concentration Added Concentration Oo RecoveryAnalyte (microgL) (microgL) (microgL) Recovery Method Limits Notes
Beryllium 0507 20200 2442 958 70 - 130 EPA 2008 Mod Sodium 258800 50500 257700 -213 70 -130 EPA 2008 Mod QM-02 Aluminum 529 15150 2023 986 70 - 130 EPA 2008 Mod Chromium 057 70700 804 106 70 - 130 EPA 2008 Mod Manganese 2805 60600 2834 476 70 - 130 EPA 2008 Mod QM-02 Iron ND 50500 5200 103 70 130 EPA 2008 Mod Nickel 979 40400 141 l 107 70- 130 EPA 2008 Mod Copper 055 40400 434 939 70 - 130 EPA 2008 Mod Zinc 040 10100 842 794 70 - 130 EPA 2008 Mod Arsenic 1030 15150 2418 916 70 - 130 EPA 2008 Mod Selenium 6340 30300 8973 869 70 130 EPA 2008 Mod Molybdenum 1338 20200 1367 142 70 130 EPA 2008 Mod QM-02 Silver ND 15150 1388 916 70 - 130 EPA 2008 Mod Cadmium 0332 080800 1105 middot956 70 - 130 EPA 2008 Mod Antimony 0408 080800 1259 105 70- 130 EPA 2008 Mod Barium 2397 10100 2495 968 70 - 130 EPA 2008 Mod Lead ND 15150 1542 102 70 130 EPA 2008 Mod
shy
shy
shy
shy
Analyte
Spike Added (microgL)
MSD Concentration
(microgL)
MSD Oo
Recovery
Oo
RPD Recovery
Limits RPD Limit Method Notes
Beryllium
Sodium
Aluminum
Chromium
Manganese
Iron
Nickel
Copper
Zinc
Arsenic
Selenium
Molybdenum
20200
50500
15150
7Q700
60600
50500
40400
40400
10100
15150
30300
20200
2561
257100
2034
773
2852
5187
1381
419
916
2225
9400
1366
102
-336
993
101 769
103
995
902
868
789
101
137
474
0243
0564
385
0625
0242
213
347
849
831
464
00771
70 - 130
70 bull 130 70 - 130
70 - 130
70 - 130
70 - 130
70 - 130
70 - 130
70 - 130
70 bull 130 70 - 130
70 - 130
20
20
20
20
20
20
20
20
20
20
20
20
EPA 2008 Mod
EPA 2008 Mod
EPA 2008 Mod
EPA 2008 Mod
EPA 2008 Mod
EPA 2008 Mod
EPA 2008 Mod
EPA 2008 Mod
EPA 2008 Mod
EPA 2008 Mod
EPA 2008 Mod
EPA 2008 Mod
QM-02
QM-02
Frontier G lobal Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
--f_~ --~~~-~ -middot middot Page 12 o261201073 Final Report 041252012
Liz Siska Project Manager
14
11720 North Creek Parkway North Suite 400
~ Bothell WA 98011
~TIEmiddot Ph 425-686-1996 Fx 425-686-3096
GLOB11L SCIENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPO
SOURCE 1201073-01RE4
Batch F203271 Sequence 2C22005
Preparation ~lo~ed Vessel Nitric Oven Digestion Lab Number F20327 I-MSMSD2
Spike MSD MSD Added Concentration Oo Recovery RPO
Analyte (microgL) (microgL) Recovery RPD Limits Limit Method Notes
Silver 15150 1387 915 00874 70 - 130 20 EPA 2008 Mod Cadmium 080800 1061 902 403 70 - 130 20 EPA 200amp Mod Antimony 080800 1274 107 l2l 70 - 130 20 EPA 2008 Mod Barium 10100 2514 )16 0781 70 - 130 20 EPA 200amp Mod Lead 15150 1534 101 0525 70 shy 130 20 EPA 2008 Mod
Frontier Global Sciences Inc The results in this report only apply to 1he samples analyzed in accordance wiih the chain ofcustody document This analytical repo1 must be reproduced in ils entirety
Page 13 o26Liz Siska Project Manager 1201073 Final Reporl
04252012 15
11720 North Creek Parkway North Suite 400
~ Bothell WA 98011 Ph 425-686-I996
~RONTIER~ Fx 425-686-3096 GLOBAL SCIEN C ES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1201073-01RE3
Batch F203271 Sequence 2~22005
Preparation Closed Vessel Nitric Oven Digestion Lab Number F20327 I-MSMSD3
Sample Spike MS MS
Analyte Concentration
(microgL) Added (microgL)
Concentration (microgL) Recovery
Recovery Limits Method Notes
Calcium 5013000 10100000 15120000 100 70- 130 EPA 2008 Mod AS
Spike MSD MSD Added Concentration o Oo Recovery RPD
Analyte (microgL) (microgL) Recovery RPD Limits Limit Method Notes
Calcium 10100000 16140000 llO 653 70 - 130 20 EPA 2008 Mod AS
Frontier Global Sciences Inc The results in his report only apply 10 the samples analyzed in accordance ivth he chain ofcustody document This analytical report must be reproduced in its entirety
Page 14 o261201073 Final Report 0425201]
Liz Siska Project Manager
16
Frontier Global Sciences Inc The ruults in this rechain ofcustody do
~ -lt1-c--~ Liz Siska Project Manager
11720 North Creek Parkway North Suite 400 Bothell WA 98011
Ph 425-686-1996 Fx 425-686-3096
GLOBAL SCIENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1201073-01RE4
Batch J203271 Sequence 2C22005
Preparation ~ IQsed Ve~~el Nitric Oven Qigestion Lab Number F203271-MSMSQ4
Analyte
Beryllium
Sample Concentration
(11gL)
0507
Spike Added (11gL)
20200
MS Concentration
(microgL)
2041
MS Oo
Recovery
985
RecoveryMethod Limits
70 - 130 EPA 2008 Mod
Notes
AS
Sodium 258800 40400 292900 845 70- 130 EPA 2008 Mod AS
Aluminum 529 40400 3956 966 70 - 130 EPA 2008 Mod AS
Chromium 057 40400 430l 106 70- 130 EPA 2008 Mod AS
Manganese 2805 40400 7042 105 70 - 130 EPA 2008 Mod AS
Iron ND 20200 2121 105 70 - 130 EPA 2008 Mod AS
Nickel 979 50500 5112 993 70 l30 EPA 2008 Mod AS
Copper 055 50500 4754 940 70 - 130 EPA 2008 Mod AS
Zinc 040 10100 9074 898 70 - 130 EPA 2008 Mod AS
Arsenic 1030 40400 4317 104 70 130 EPA 2008 Mod AS
Selenium 6340 40400 4688 100 70 - 130 EPA 2008 Mod AS
Molybdenum 1338 20200 338l 101 70 - 130 EPA 2008 Mod AS
Silver ND 20200 1850 916 70 130 EPA 2008 Mod AS
Cadmium 0332 40400 3937 966 70 130 EPA 2008 Mod AS
Antimony 0408 20200 2091 102 70 - 130 EPA 2008 Mod AS
Barium 2397 80800 1056 101 70- 130 EPA 2008 Mod AS
Lead ND IO100 9932 983 70 130 EPA 2008 Mod AS
shy
shy
shy
shy
shy
Analyte
Spike Added (microgL)
MSD Concentration
(microgL)
MSD
Recovery
RPD
Recovery Limits
RPDLimit Method Notes
Beryllium 20200 2007 968 l71 70 - 130 20 EPA 2008 Mod AS Sodium 40400 292600 837 0114 70 130 20 EPA 2008 Mod AS Aluminum 40400 3954 966 00362 70 - 130 20 EPA 2008 Mod AS Chromium 40400 4287 106 0337 70 - 130 20 EPA 2008 Mod AS Manganese 40400 6944 102 140 70 - 130 20 EPA 2008 Mod AS Iron 20200 2077 103 211 70 - 130 20 EPA 2008 Mod AS Nickel 50500 5126 996 0276 70 - 130 20 EPA 2008 Mod AS Copper 50500 4707 931 0997 70 - 130 20 EPA 200 8 Mod AS Zinc 10100 9059 896 0166 70 - 130 20 EPA 2008 Mod AS Arsenic 40400 4299 104 0419 70 - 130 20 EPA 2008 Mod AS Selenium 40400 4682 100 0141 70 - 130 20 EPA 2008 Mod AS Molybdenum 20200 3365 100 0473 70 - 130 20 EPA 2008 Mod AS
shy
port only apply to the sampltts analyzed in accordance with the cument This analytical report must be reproduced in its entirety
Page 5 o26 201073 Final Report 042512012 17
Liz Sia Project Manager
11720 North Creek Parkway North Suite 400 Botheln VA 98011
Ph 425-686-1996 Fx 425-686-3096
CLOBAL SCIENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1201073-01RE4
Batch F203271 Sequence 2c2io2~
Preparation Clo~ed Vessel litric Oven Digestion Lab Number F20327 l -MSMSQ4
Analyte
Spike Added (microgL)
MSD Concentration
(microgL)
MSD
Recovery
Oo
RPD Recovery
Limits RPOLimit Method Notes
Silver 20200 1895 938 242 70 - 130 20 EPA 2008 Mod AS Cadmium 40400 3933 965 0104 70 -130 20 EPA 2008 Mod AS Antimony 20200 2107 102 0736 70- 130 20 EPA 2008 Mod AS
Barium 80800 1058 101 0205 70 - 130 20 EPA 2008 Mod AS
Lead 10100 9877 978 0549 70 - 130 20 EPA 2008 Mod AS
Frontier Global Sciences Inc The results in this report only apply to the samples analyudin accordance with lht chain ofcustody document This analytical report must be reproductd rn ilS enlirtty
Page l6of26 1201073 Final Report Ofn5202 18
l I 720 North Creek Parkway North Suite 400 Bothell WA 980I I
Ph 425-686-1996 Fx 425-686-3096
GLO B AL SCIENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1201073-01RE6
Batch F203314 Sequence 2C25005
Preparation Closed Vessel Nitric Oven Digestion Lab Number F203314-MSMSD2
Sample Spike MS MS Concentration Added Concentration RecoveryAnalyte (microgL) (microgL) (microgL) Recovery Method NotesLimits
Thallium 5563 040400 5875 773 70 - 130 EPA 2008 Mod
Spike MSD MSD Added o Concentration Recovery RPD
RPO Limits Limit Method Notes Analyte (microgL) (microgL) Recovery
Thallium 040400 5880 785 00859 70 - 130 20 EPA 2008 Mod
Frontier Global Sciences Inc 11e results in chis reporc only apply 10 1he samples analyzed in accordance wilh lhe chain ofcustody documenz This analycical report musl be reproduced in ils entirety
Page 17 of26 1201073 Fi11aReport 0412512012
Liz Siska Project Manager
19
11720 North Creek Parkway North Suite 400 Bothell WA 98011
Ph 425-686-1996 Fx 425-686-3096
GLOBAl SCIENC ES
MATRIX SPIKE I MATRIX SPIKE DUPLICATE RECOVERY AND RPO
SOURCE I201073-01RE6
Batch F203314
Preparation Closed Vessel Nitric Oven Digestion
Sequence 2C25005
Lab Number F203314-MSMSD4
Analyte
Sample Concentration
(microgL)
Spike Added (microgL)
MS MS Concentration Oo
(microgL) Recovery Recovery
Limits Method Notes
Thallium 5563 10100 1033 968 70- 130 EPA 2008 Mod AS
Analyte
Spike Added (microgL)
MSD Concentration
(microgL)
MS)) Oo
Recovery
RPD
Recovery Limits
RPD Limit Method Notes
Thallium IO100 1037 97l 0341 70 - 130 20 EPA 2008 Mod AS
Frontier Global Sciences Inc The resulrs in this report only apply to the samples analyzed in accordance with the chain ofcusrody document This analytical report must be reproduced in its entirely
Page 18of26 120073 Final Report 04252012
Liz Siska Project Manager
20
11720 North Creek Parkway North Suite 400 l ~ Bothell WA 980 l l Ph 425-686-1996
FRONTIER Fx 425-686-3096 GLOBAL SCIENCES
LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLICATE
RECOVERY AND RPD
Batch F20 l063 Sequence 2A09010
Preparation BrCI Oxidation Lab Number F201063-BSIBSJ21
LCS Source N ist 1641d
Analyte
Spike Added (ngL)
LCS Concentration
(ngL)
LCS
Recovery Recovery
Limits Method Notes
Mercury 15679 1550 988 80 - 120 EPA I631E
Analyte
Spike Added (ngL)
LCSD Concentration
(ngL)
LCSD Oo
Recovery
RPD Recovery
Limits RPD Limit Method Notes
Mercury 15679 1595 [02 289 80 - 120 24 EPA I631E
Frontier Global Sciences Inc The results in this report only apply to the samples analyzedin accordance with the chain ofcustody document This analytical report must be reproduced in ils entirety
Page 19of26 1201073 Final Report 0425 2012
Liz Siska Project Manager
21
11720 North Creek Parkway North Suite 400 Bothell WA 98011
Ph 425-686-1996 FRONTIER Fx 425-686-3096 GLOBAL SCIENCES
LABORA TORY CONTROL SAMPLE LABO RATORY CONTROL SAMPLE DUPLICATE
RECOVERY AND RPD
Batch F203271 Sequence 2C22005
Preparation Closed Vessel Nitric Oven Digestion Lab Number F203271-BSBSD1
LCS Source Blank Spike
Spike LCS LCS Added Concentration Oo Recovery
Analyte (microgL) (microgL) Recovery Limits Method Notes
Beryllium 20000 l930 965 85 - 115 EPA 2008 Mod
Sodium 50000 499 998 85 - 115 EPA 2008 Mod
Aluminum 15000 1460 973 85 - 115 EPA 2008 Mod
Calcium 15000 1528 102 85 - 115 EPA 2008 Mod
Chromium 70000 657 939 85 - 115 EPA 2008 Mod
Manganese 60000 586 976 85 - 115 EPA 2008 Mod
Iron 50000 4753 951 85 shy 115 EPA 2008 Mod
Nickel 40000 401 100 85 - 115 EPA 2008 Mod
Copper 40000 418 105 85 - 115 EPA 2008 Mod
Zinc 10000 1033 103 85 - 115 EPA 2008 Mod
Arsenic 15000 1437 958 85 - 115 EPA 2008 Mod
Selenium 30000 2966 989 85 - 115 EPA 2008 Mod
Molybdenum 20000 181 905 85 shy 115 EPA 2008 Mod
Silver 15000 1517 101 85 shy 115 EPA 2008 Mod
Cadmium 080000 0781 976 85 - 1lS EPA 2008 Mod
Antimony 080000 0815 102 85 - 115 EPA 2008 Mod
Barium 10000 969 969 85 - 115 EPA 2008 Mod
Lead 15000 1597 106 85 - 115 EPA 2008 Mod
Spike LCSD LCSD Added Concentration Recovery RPO
Analyte (microgL) (microgL) Recovery RPO Limits Limit Method Notes
Beryllium 20000 1949 974 0955 85 - 115 20 EPA 2008 Mod
Sodium 50000 500 100 0216 85 - 115 20 EPA 2008 Mod
Aluminum 15000 1485 990 171 85 - 115 20 EPA 2008 Mod
Calcium 15000 1544 103 103 85 - 115 20 EPA 2008 Mod
Chromium 70000 667 953 148 85 - 115 20 EPA 2008 Mod
Manganese 60000 596 994 175 85 - 115 20 EPA 2008 Mod
Iron 50000 4852 970 206 85 - 115 20 EPA 2008 Mod
Nickel 40000 402 IOI 0246 85 - 115 20 EPA 2008 Mod
Frontier Global Sciences Inc The results in his report only apply to the samples analyzed in accordance wirh the chain ofcustody document This analytical report must be reproduced in iLS entirety
Page 20of26 1201073 Final Report 04252012
Liz Siska Project Manager
22
11720 North Creek Parkway North Suite 400 ~~shy Bothell WA 98011 Ph 425-686-1996~ONTif Fx 425-686-3096
GLOBAL SCIENCES
LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLICATE
RECOVERY AND RPO
Batch F20327 l Sequence 2C22005
Preparation Closed Vessel Nitric Oven Digestion Lab Number F203271-BSBSD 1
LCS Source Blank Spike
Analyte
Spike Added (microgL)
LCSD Concentration
(microgL)
LCSD oo
Recovery
RPO Recovery
Limits RPO Limit Method Notes
Copper
Zinc
Arsenic
Selenium
40000
10000
15000
30000
428
1039
1452
3015
107
104
968
101
224
0570
0977
166
85 - 115
85 - 115
85 - 115
85 - 115
20
20
20
20
EPA 2008 Mod
EPA 2008 Mod
EPA 2008 Mod
EPA 2008 Mod Molybdenum
Silver
20000
15000
182
J502
910
100
0564
103
85 - 115
85 - 115
20
20
EPA 2008 Mod
EPA 2008 Mod Cadmium
Antimony
Barium
Lead
080000
080000
10000
15000
0828
0808
986
1620
103
101
986
108
585
0848
177
142
85 - 115
85 - 115
85 shy 11 S
85 - 115
20
20
20
20
EPA 2008 Mod
EPA 2008 Mod
EPA 2008 Mod
EPA 2008 Mod
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report mus be reproducedin its entirety
Page 2 o26J20J073 Final Report 041252012
Liz Siska Project Manager
23
11720 North Creek Parkway North Suite 400 Bothell WA 980 l l
Ph 425-686-1996FRONT[ER- Fx 425-686-3096 cLosAL SCIEN _CES
LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLICATE
RECOVERY AND RPD
Batch F203314 Sequence 2C25005
Preparation Closed Vessel Nitric Oven Digestion Lab Number F2033 l 4-BSBSD 1
LCS Source Blank Spike
Analyte
Thallium
Spike Added (microgL)
LCS Concentration
(microgL)
LCS 0o
Recovery Recovery
Limits Method
040000 0396 989 85 - 115 EPA 2008 Mod
Notes
Analyte
Spike Added (microgL)
LCSD Concentration
(microgL)
LCSD 0o
Recovery
RPD Recovery
Limits RPO Limit Method Notes
Thallium 040000 0391 978 112 85 - ll5 20 EPA 2008 Mod
Frontier Global Sciences Inc The results in this report only apply to the samples anayed in accordance with the chain ofcustody docwnenJ This analytical report must be reproduced in its entirety
Page 22of26 1201073 Final Report 04252012
Liz Siska Project Manager
24
Liz Siska P roject Manager
11720 North Creek Parkway North Suite 400
~ Bothell WA 98011 Ph 425-686-1996
~JTIEif middot Fx 425-686-3096 GLOBAL SCIENCES
PREPARATION BLANKS
Instrument Hg-17 Sequence 2A09010
Preparation BrCI Oxidation
Lab Sample ID Analyte Found MRL Units Batch Method Notes
F201063-BLK I Mercury -0009 050 ngL F201063 EPA 1631E u F20 I063-BLK2 Mercury -0006 050 ngL F201063 EPA 1631E u F201063-BLK3 Mercury -002 050 ngL F201063 EPA 163IE u F201063-BLK4 Mercury 003 050 ngL F201063 EPA 1631E U QB-04 F201063-BLKS Mercury 011 052 ngL F201063 EPA I631E U QB-06
Frontier Global Sciences Inc The results in this report only apply 10 1he samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Page 23 o26 1201073 Final Repon 04252012 25
Liz Siska Project Manager
11720 North Creek Parkway North Suite 400 Bothell WA 98011
Ph 425-686-1996 FROr~TIER- Fx 425-686-3096 GLOBAL SCIENCES
PREPARATION BLANKS
Instrument ICPMS-6 Sequence 2C22005
Preparation Closed Vessel Nitric Oven Digestion
Lab Sample ID Analyte Found MRL Units Batch Method Notes
F203271-BLK1 Beryllium 000008 0060 microgL F203271 PA 2008 Molt u F20327 1-BLK1 Sodium 2 20 microgL F20327l PA 2008 Moc u F20327I-BLK1 Aluminum -004 40 microgL F203271 PA 2008 Molt u F20327I -BLK1 Calcium 40 microgL F203271 PA 2008 Molt u F203271 -BLK1 Chromium -002 010 microgL F203271 ~A 2008 Molt u F203271-BLKI Manganese 001 010 microgL F203271 PA 2008 Molt u F20327 l -BLK 1 Iron -002 100 microgL F203271 PA 2008 Molt u F203271-BLKI Nickel 0004 010 microgL F203271 PA 2008 Moc u F203271-BLK1 Copper 0003 010 microgL F203271 PA 2008 Moc u F203271-BLK1 Zinc 0007 020 microgL F203271 PA 2008 Moc u F203271-BLK1 Arsenic -006 015 microgL F203271 PA 2008 Moc u F203271-BLK1 Selenium -002 060 microgL F203271 PA 2008 Moc u F203271-BLK1 Molybdenum 001 006 microgL F203271 PA 2008 Molt u F203271-BLK1 Silver -00005 0020 microgL F203271 PA 2008 Molt u F203271-BLKl Cadmium 0004 0020 microgL F203271 PA 2008 Molt u F20327 l-BLKl Antimony 0002 0020 microgL F203271 PA 2008 Molt u F203271-BLKI Barium 001 020 microgL F203271 PA 2008 Molt u F203271-BLKI Lead 0010 0040 microgL F203271 PA 2008 Moc u
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Page 24of26 1201073 Final Report 04252012 26
~
~TIER~ GLOBAL SCIENCES
11720 North Creek Parkway North Suite 400 Bothell WA 980ll
Ph 425-686-1996 Fx 425-686-3096
PREPARATION BLANKS
Instrument JCPMS-3 Sequence 2C25005
Preparation Closed Vessel Nitric Oven Digestion
Lab Sample ID Analyte Found MRL Units Batch Method Notes
F2033I4-BLK1 Thalium 00007 0010 microgL F2033I4 ~PA 2008 Molt u
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Page 25 o26Liz Siska Project Manager 1201073 Final Report
04252012 27
l l 720 North Creek Parkway North Suite 400~Vi-~ Bothell WA 98011 Ph 425-686-1 996~Tlmiddot~ Fx 425-686-3096
G L OBAL SCIENCE S
Notes and Definitions
U Analyte included in the analysis but not detected
QM-02 The MS andor MSD recoveries outside acceptance limits due to spike concentration less than I times the sample concentration The batch was accepted based on LCS and LCSD recoveries within control limits and when analysis permits acceptable AS ASD
QB-06 The blank was preserved to 5 BrCI rather than I The control limit for blanks preserved to greater than 1 BrCl is the preservation percentage multiplied by the MRL
QB-04 The blank was preserved to 2 BrCI rather than l The control limit for blanks preserved to greater than l BrCI is the preservation percentage multiplied by the MRL
FB-1631 Required equipmentfieldfilter blank not submitted by the client The sample has been analyzed according to 163 lE but does not meet 163 lE criteria
AS This MS andor MSD is an analytical spike andor an analytical spike duplicate
DET Analyte Detected
MDL Minimum Detection Limit
MRL Minimum Reporting Limit
ND Analyte Not Detected at or above the reporting limit
wet Sample results reported on a wet weight basis
dry Sample results reported on a dry weight basis
RPO Relative Percent Difference
RSD Relative Standard Deviation
Frontier Global Sciences Inc The lesults i111his reporl only apply to he samples analyzed In accordance with the chain ofcuslody document This analytical report must be reproduced in its entirely
Page 26of26 1201073 Final Report 04252012
Liz Siska Project Manager
28
CHAIN-OF-(USTODY ttECORD Page i of f 106677 _J
BoLD F1ELDS REQUIRED PLEASE C 1RCLE REQUESTED ANALYSIS
SAMPLE ID
middoti-rg -- bull ~rshy~ _- tzir +- lt-ltJ~ lt
SAMPLING
DATeTtME
IF COMPOSITE INDICATE BOTH
START amp FINISH
DATETIME li1J oc -r 111_- _vlt-c_
w Ishyt 0 n
w l w 0 ~ u X -Xmiddot ~ m Ishy lt( lt( 0
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IIXJ JC
~ ~ irlte-t- T_ t- f r-n t I s-11 middott~ c~ J J1~w )(~ )
Trttbull rin K C-~-~ pound1t I 1Jtl~ t20~L lwlJI ishy
middot~ON Mm1x A-Al~ S-SOil GW-GampOUHO WATER SW-SUampfA(f WATER DWmiddotDRIIIKIKlti WATER
Itlt
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107555
i
~ I NOTES MEOH VIAL
1 WW-WASTE WATER PmmATIVE H-HCL H-HN01 S-H1SO Na-NaOH H-HEOH -~ --~
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DISSOLVED METALS FIELD FllTEREDI YES 110
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ImiddotRELINQUISHED BY DATE TIHE RECflVEO BY I FIELD READINGS
eastern analytical inc 2s CHENELL D R1ve IC 0 Nco1to N H 0330 1 I TEL 60J22aos2s 1aoo2a1os2s IFAx 6032284591 j E-MA1t cus-roM111_mV1c~EAILAsscoMJ www1A1LAascoM
----i pmiddotofissionrrl11bomtorymim (WHITE ORIGINAL GREEN PROJECT MANAGER)
shy
Liz Siska Project Manager
11720 North Creek Parkway North Suite 400 Bothell WA 98011
Ph 425-686-1996 Fx 425-686-3096
GLOBAt SCIENCES
ANALYTICAL RESULTS
Treat Tank Eff Grab
Matrix Water Laboratory ID 1201073-02
Analyte Result MDL MRL Units Dilution Batch Sequence Analyzed Method Notes
Arsenic 851 102 300 microgL 20 F203271 2C22005 032212 EPA 2008 Mod Mercury 105 034 202 ngL 4 F20I063 2A09010 010912 EPA 1631E FB-1631 Selenium 689 388 120 microgL 20 F203271 2C22005 032212 EPA 2008 Mod
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcustody documenJ This analycical report must be reproduced in its entirety
Page 5 o261201073 Final Report 04252012 7
Liz Siska Project Manager
FRONTIERshycLoaAt SCI ENCES
11720 North Creek Parkway North Suite 400 Bothell WA 98011
Ph 425-686-1996 Fx 425-686-3096
MATRIX DUPLICATESfRIPLICATES
SOURCE 1201073-02
Batch F201063
Preparation BrCI Oxidation
Sequence 2A09010
Lab Number F201063-DUPI
Sample Duplicate Concentration Concentration RPD
Analyte ngL ngL MRL RPD Limit Method Notes Mercury 1048 1054 202 0617 24 EPA I631E
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Page 6of26 1201073 Final Report 04252012 8
11720 North Creek Parkway North Suite 400 BotheE WA 980 l l
Ph 425-686-1996 Fx 425-686-3096
GLOBAL SCIENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1201073-02
Batch F201063 Sequence 2A09010
Preparation BrCI Oxidation Lab Number F20 l 063-MSMSDl
Sample Spike MS MS Concentration Added Concentration RecoveryAnalyte (ngL) (ngL) (ngL) Recovery Method Limits Notes
Mercury 1048 20400 3136 102 71 125 EPA 163IE
Spike MSD MSD Added Concentration oo Recovery RPD
RPD Limits Limit Method Notes Analyte (ngL) (ngL) Recovery
Mercury 20400 2708 814 147 71 - 125 24 EPA 1631E
shy
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Page 7 o26Liz Siska Project Manager 120JO7 3 Final Repo1
04252012 9
Liz Siska Project Manager
11720 North Creek Parkway North Suite 400 Bothell WA 98011
Ph 425-686-1996~ Fx 425-686-3096 CL06AL SCIENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1112278-02
Batch F201063 Sequence 2A09010
Preparation BrCI Oxidation Lab Number F20 l 063-MSMSD2
Sample Spike MS MS
Analyte Concentration
(ogL) Added (ngL)
Concentration (ngL)
Recovery
RecoveryLimits Method Notes
Mercury 761 20400 2786 992 71 125 EPA 1631E
Spike MSD MSD Added Concentration Oo Recovery RPO
Analyte (ngL) (ngL) Recovery RPO Limits Limit Method Notes
Mercury 20400 2837 102 182 71 - 125 24 EPA l631E
shy
Frontier Global Sciences Inc The results in this report only apply to the somples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Page 8 o26 1201073 Final Report 042512012 10
11720 North Creek Parkway North Suite 400 Bothell WA 980 l l
Ph 425-686-1996 ~ Fx 425-686-3096 GLOBAL SCIENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1201029-01
Batch
Preparation
F201063
BrCI Oxidation
Sequence
Lab Number
2A09010
F20 I 063-MSMSD3
Analyte
Mercury
Analyte
Mercury
Sample Spike Concentration Added
(ngL) (ngL)
534 10200
Spike MSD Added Concentration (ngL) (ngL)
10200 1407
MS MS Concentration Recovery
(ngL) Recovery Limits
1558 JOO 7l shy 125
MSD oo Recovery RPD
Recovery RPD Limits Limit
856 102 71 - 125 24
Method
EPA l63lE
Method
EPA 631E
Notes
Notes
Frontier Global Sciences Inc The results in this repon only apply to rhe samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Page 9of26 1201073 Final Report 041252012
Liz Siska Project Manager
1 1
11720 North Creek Parkway North Suite 400 Bothell WA 98011
Ph 425-686-1996 FRONTIER- Fx 425-686-3096 cLosAL SCIENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1201030-02
Batch F20I063 Sequence 2A09010
Preparation BrCI Oxidation Lab Number F201063-MSMSD4
Sample Spike MS MS Concentration Added Concentration RecoveryAnalyte (ngL) (ngL) (ngL) Recovery MethodLimits Notes
Mercury 554 10200 1482 910 71 - 125 EPA I631E
Spike MSD MSD Oo Added Concentratio11 Recovery RPD
RPD Limits Limit Method Analyte (ngL) (ngL) Recovery Notes
Mercury 10200 1461 890 140 71 - 125 24 EPA 163IE
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed m accordance with the chain ofcus1ody document This anayt(ca repon must be reproduced in itr entirety
Page lOo26Liz Siska Project Manager 1201073 Final Report
041252012 12
I 1720 North Creek Parkway North Suite 400 Bothe I I WA 98011
Ph 425-686-1996 ~ Fx 425-686-3096 GLOBAL SCIENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1201073-01RE3
Batch F20327l Sequence 2C22005
Prcpa ration ((01ed Vessel ~ itric Oven Digestion Lab Number F203271-MSMSD 1
Analyte
Sample Concentration
(microgL)
Spike Added (microgL)
MS Concentration
(microgL)
MS Oo
Recovery Recovery
Method Limits Notes
Calcium 5013000 15150 4802000 -13900 70- 130 EPA 2008 Mod QM-02
Analyte
Spike Added (microgL)
MSD Concentration
(microgL)
MSD ~o
Recovery
Oo
RPD Recovery
Limits RPDLimit Method Notes
Calcium 15150 4943000 -4600 289 70 - 130 20 EPA 2008 Mod QM-02
Frontier Global Sciences Inc The results in this report only apply to the samples analyud inaccordance with the chain ofcustody document 17is analyticol report must be reproduced in its entirety
Page lI o16 1101073 Final Report 04152012
Liz Siska Project Manager
13
l l 720 North Creek Parkway North Suite 400 Bothell WA 98011
Ph 425-686-1996FRONTIER Fx 425-686-3096 GLOBAL SCIENCES
MATRIX SPIKE I MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1201073-01RE4
Batch F203271 Sequence 2C22005
Preparation Closed Vessel Nitric Oven Digestion Lab Number F203271-MSMSD2
Sample Spike MS MS Concentration Added Concentration Oo RecoveryAnalyte (microgL) (microgL) (microgL) Recovery Method Limits Notes
Beryllium 0507 20200 2442 958 70 - 130 EPA 2008 Mod Sodium 258800 50500 257700 -213 70 -130 EPA 2008 Mod QM-02 Aluminum 529 15150 2023 986 70 - 130 EPA 2008 Mod Chromium 057 70700 804 106 70 - 130 EPA 2008 Mod Manganese 2805 60600 2834 476 70 - 130 EPA 2008 Mod QM-02 Iron ND 50500 5200 103 70 130 EPA 2008 Mod Nickel 979 40400 141 l 107 70- 130 EPA 2008 Mod Copper 055 40400 434 939 70 - 130 EPA 2008 Mod Zinc 040 10100 842 794 70 - 130 EPA 2008 Mod Arsenic 1030 15150 2418 916 70 - 130 EPA 2008 Mod Selenium 6340 30300 8973 869 70 130 EPA 2008 Mod Molybdenum 1338 20200 1367 142 70 130 EPA 2008 Mod QM-02 Silver ND 15150 1388 916 70 - 130 EPA 2008 Mod Cadmium 0332 080800 1105 middot956 70 - 130 EPA 2008 Mod Antimony 0408 080800 1259 105 70- 130 EPA 2008 Mod Barium 2397 10100 2495 968 70 - 130 EPA 2008 Mod Lead ND 15150 1542 102 70 130 EPA 2008 Mod
shy
shy
shy
shy
Analyte
Spike Added (microgL)
MSD Concentration
(microgL)
MSD Oo
Recovery
Oo
RPD Recovery
Limits RPD Limit Method Notes
Beryllium
Sodium
Aluminum
Chromium
Manganese
Iron
Nickel
Copper
Zinc
Arsenic
Selenium
Molybdenum
20200
50500
15150
7Q700
60600
50500
40400
40400
10100
15150
30300
20200
2561
257100
2034
773
2852
5187
1381
419
916
2225
9400
1366
102
-336
993
101 769
103
995
902
868
789
101
137
474
0243
0564
385
0625
0242
213
347
849
831
464
00771
70 - 130
70 bull 130 70 - 130
70 - 130
70 - 130
70 - 130
70 - 130
70 - 130
70 - 130
70 bull 130 70 - 130
70 - 130
20
20
20
20
20
20
20
20
20
20
20
20
EPA 2008 Mod
EPA 2008 Mod
EPA 2008 Mod
EPA 2008 Mod
EPA 2008 Mod
EPA 2008 Mod
EPA 2008 Mod
EPA 2008 Mod
EPA 2008 Mod
EPA 2008 Mod
EPA 2008 Mod
EPA 2008 Mod
QM-02
QM-02
Frontier G lobal Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
--f_~ --~~~-~ -middot middot Page 12 o261201073 Final Report 041252012
Liz Siska Project Manager
14
11720 North Creek Parkway North Suite 400
~ Bothell WA 98011
~TIEmiddot Ph 425-686-1996 Fx 425-686-3096
GLOB11L SCIENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPO
SOURCE 1201073-01RE4
Batch F203271 Sequence 2C22005
Preparation ~lo~ed Vessel Nitric Oven Digestion Lab Number F20327 I-MSMSD2
Spike MSD MSD Added Concentration Oo Recovery RPO
Analyte (microgL) (microgL) Recovery RPD Limits Limit Method Notes
Silver 15150 1387 915 00874 70 - 130 20 EPA 2008 Mod Cadmium 080800 1061 902 403 70 - 130 20 EPA 200amp Mod Antimony 080800 1274 107 l2l 70 - 130 20 EPA 2008 Mod Barium 10100 2514 )16 0781 70 - 130 20 EPA 200amp Mod Lead 15150 1534 101 0525 70 shy 130 20 EPA 2008 Mod
Frontier Global Sciences Inc The results in this report only apply to 1he samples analyzed in accordance wiih the chain ofcustody document This analytical repo1 must be reproduced in ils entirety
Page 13 o26Liz Siska Project Manager 1201073 Final Reporl
04252012 15
11720 North Creek Parkway North Suite 400
~ Bothell WA 98011 Ph 425-686-I996
~RONTIER~ Fx 425-686-3096 GLOBAL SCIEN C ES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1201073-01RE3
Batch F203271 Sequence 2~22005
Preparation Closed Vessel Nitric Oven Digestion Lab Number F20327 I-MSMSD3
Sample Spike MS MS
Analyte Concentration
(microgL) Added (microgL)
Concentration (microgL) Recovery
Recovery Limits Method Notes
Calcium 5013000 10100000 15120000 100 70- 130 EPA 2008 Mod AS
Spike MSD MSD Added Concentration o Oo Recovery RPD
Analyte (microgL) (microgL) Recovery RPD Limits Limit Method Notes
Calcium 10100000 16140000 llO 653 70 - 130 20 EPA 2008 Mod AS
Frontier Global Sciences Inc The results in his report only apply 10 the samples analyzed in accordance ivth he chain ofcustody document This analytical report must be reproduced in its entirety
Page 14 o261201073 Final Report 0425201]
Liz Siska Project Manager
16
Frontier Global Sciences Inc The ruults in this rechain ofcustody do
~ -lt1-c--~ Liz Siska Project Manager
11720 North Creek Parkway North Suite 400 Bothell WA 98011
Ph 425-686-1996 Fx 425-686-3096
GLOBAL SCIENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1201073-01RE4
Batch J203271 Sequence 2C22005
Preparation ~ IQsed Ve~~el Nitric Oven Qigestion Lab Number F203271-MSMSQ4
Analyte
Beryllium
Sample Concentration
(11gL)
0507
Spike Added (11gL)
20200
MS Concentration
(microgL)
2041
MS Oo
Recovery
985
RecoveryMethod Limits
70 - 130 EPA 2008 Mod
Notes
AS
Sodium 258800 40400 292900 845 70- 130 EPA 2008 Mod AS
Aluminum 529 40400 3956 966 70 - 130 EPA 2008 Mod AS
Chromium 057 40400 430l 106 70- 130 EPA 2008 Mod AS
Manganese 2805 40400 7042 105 70 - 130 EPA 2008 Mod AS
Iron ND 20200 2121 105 70 - 130 EPA 2008 Mod AS
Nickel 979 50500 5112 993 70 l30 EPA 2008 Mod AS
Copper 055 50500 4754 940 70 - 130 EPA 2008 Mod AS
Zinc 040 10100 9074 898 70 - 130 EPA 2008 Mod AS
Arsenic 1030 40400 4317 104 70 130 EPA 2008 Mod AS
Selenium 6340 40400 4688 100 70 - 130 EPA 2008 Mod AS
Molybdenum 1338 20200 338l 101 70 - 130 EPA 2008 Mod AS
Silver ND 20200 1850 916 70 130 EPA 2008 Mod AS
Cadmium 0332 40400 3937 966 70 130 EPA 2008 Mod AS
Antimony 0408 20200 2091 102 70 - 130 EPA 2008 Mod AS
Barium 2397 80800 1056 101 70- 130 EPA 2008 Mod AS
Lead ND IO100 9932 983 70 130 EPA 2008 Mod AS
shy
shy
shy
shy
shy
Analyte
Spike Added (microgL)
MSD Concentration
(microgL)
MSD
Recovery
RPD
Recovery Limits
RPDLimit Method Notes
Beryllium 20200 2007 968 l71 70 - 130 20 EPA 2008 Mod AS Sodium 40400 292600 837 0114 70 130 20 EPA 2008 Mod AS Aluminum 40400 3954 966 00362 70 - 130 20 EPA 2008 Mod AS Chromium 40400 4287 106 0337 70 - 130 20 EPA 2008 Mod AS Manganese 40400 6944 102 140 70 - 130 20 EPA 2008 Mod AS Iron 20200 2077 103 211 70 - 130 20 EPA 2008 Mod AS Nickel 50500 5126 996 0276 70 - 130 20 EPA 2008 Mod AS Copper 50500 4707 931 0997 70 - 130 20 EPA 200 8 Mod AS Zinc 10100 9059 896 0166 70 - 130 20 EPA 2008 Mod AS Arsenic 40400 4299 104 0419 70 - 130 20 EPA 2008 Mod AS Selenium 40400 4682 100 0141 70 - 130 20 EPA 2008 Mod AS Molybdenum 20200 3365 100 0473 70 - 130 20 EPA 2008 Mod AS
shy
port only apply to the sampltts analyzed in accordance with the cument This analytical report must be reproduced in its entirety
Page 5 o26 201073 Final Report 042512012 17
Liz Sia Project Manager
11720 North Creek Parkway North Suite 400 Botheln VA 98011
Ph 425-686-1996 Fx 425-686-3096
CLOBAL SCIENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1201073-01RE4
Batch F203271 Sequence 2c2io2~
Preparation Clo~ed Vessel litric Oven Digestion Lab Number F20327 l -MSMSQ4
Analyte
Spike Added (microgL)
MSD Concentration
(microgL)
MSD
Recovery
Oo
RPD Recovery
Limits RPOLimit Method Notes
Silver 20200 1895 938 242 70 - 130 20 EPA 2008 Mod AS Cadmium 40400 3933 965 0104 70 -130 20 EPA 2008 Mod AS Antimony 20200 2107 102 0736 70- 130 20 EPA 2008 Mod AS
Barium 80800 1058 101 0205 70 - 130 20 EPA 2008 Mod AS
Lead 10100 9877 978 0549 70 - 130 20 EPA 2008 Mod AS
Frontier Global Sciences Inc The results in this report only apply to the samples analyudin accordance with lht chain ofcustody document This analytical report must be reproductd rn ilS enlirtty
Page l6of26 1201073 Final Report Ofn5202 18
l I 720 North Creek Parkway North Suite 400 Bothell WA 980I I
Ph 425-686-1996 Fx 425-686-3096
GLO B AL SCIENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1201073-01RE6
Batch F203314 Sequence 2C25005
Preparation Closed Vessel Nitric Oven Digestion Lab Number F203314-MSMSD2
Sample Spike MS MS Concentration Added Concentration RecoveryAnalyte (microgL) (microgL) (microgL) Recovery Method NotesLimits
Thallium 5563 040400 5875 773 70 - 130 EPA 2008 Mod
Spike MSD MSD Added o Concentration Recovery RPD
RPO Limits Limit Method Notes Analyte (microgL) (microgL) Recovery
Thallium 040400 5880 785 00859 70 - 130 20 EPA 2008 Mod
Frontier Global Sciences Inc 11e results in chis reporc only apply 10 1he samples analyzed in accordance wilh lhe chain ofcustody documenz This analycical report musl be reproduced in ils entirety
Page 17 of26 1201073 Fi11aReport 0412512012
Liz Siska Project Manager
19
11720 North Creek Parkway North Suite 400 Bothell WA 98011
Ph 425-686-1996 Fx 425-686-3096
GLOBAl SCIENC ES
MATRIX SPIKE I MATRIX SPIKE DUPLICATE RECOVERY AND RPO
SOURCE I201073-01RE6
Batch F203314
Preparation Closed Vessel Nitric Oven Digestion
Sequence 2C25005
Lab Number F203314-MSMSD4
Analyte
Sample Concentration
(microgL)
Spike Added (microgL)
MS MS Concentration Oo
(microgL) Recovery Recovery
Limits Method Notes
Thallium 5563 10100 1033 968 70- 130 EPA 2008 Mod AS
Analyte
Spike Added (microgL)
MSD Concentration
(microgL)
MS)) Oo
Recovery
RPD
Recovery Limits
RPD Limit Method Notes
Thallium IO100 1037 97l 0341 70 - 130 20 EPA 2008 Mod AS
Frontier Global Sciences Inc The resulrs in this report only apply to the samples analyzed in accordance with the chain ofcusrody document This analytical report must be reproduced in its entirely
Page 18of26 120073 Final Report 04252012
Liz Siska Project Manager
20
11720 North Creek Parkway North Suite 400 l ~ Bothell WA 980 l l Ph 425-686-1996
FRONTIER Fx 425-686-3096 GLOBAL SCIENCES
LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLICATE
RECOVERY AND RPD
Batch F20 l063 Sequence 2A09010
Preparation BrCI Oxidation Lab Number F201063-BSIBSJ21
LCS Source N ist 1641d
Analyte
Spike Added (ngL)
LCS Concentration
(ngL)
LCS
Recovery Recovery
Limits Method Notes
Mercury 15679 1550 988 80 - 120 EPA I631E
Analyte
Spike Added (ngL)
LCSD Concentration
(ngL)
LCSD Oo
Recovery
RPD Recovery
Limits RPD Limit Method Notes
Mercury 15679 1595 [02 289 80 - 120 24 EPA I631E
Frontier Global Sciences Inc The results in this report only apply to the samples analyzedin accordance with the chain ofcustody document This analytical report must be reproduced in ils entirety
Page 19of26 1201073 Final Report 0425 2012
Liz Siska Project Manager
21
11720 North Creek Parkway North Suite 400 Bothell WA 98011
Ph 425-686-1996 FRONTIER Fx 425-686-3096 GLOBAL SCIENCES
LABORA TORY CONTROL SAMPLE LABO RATORY CONTROL SAMPLE DUPLICATE
RECOVERY AND RPD
Batch F203271 Sequence 2C22005
Preparation Closed Vessel Nitric Oven Digestion Lab Number F203271-BSBSD1
LCS Source Blank Spike
Spike LCS LCS Added Concentration Oo Recovery
Analyte (microgL) (microgL) Recovery Limits Method Notes
Beryllium 20000 l930 965 85 - 115 EPA 2008 Mod
Sodium 50000 499 998 85 - 115 EPA 2008 Mod
Aluminum 15000 1460 973 85 - 115 EPA 2008 Mod
Calcium 15000 1528 102 85 - 115 EPA 2008 Mod
Chromium 70000 657 939 85 - 115 EPA 2008 Mod
Manganese 60000 586 976 85 - 115 EPA 2008 Mod
Iron 50000 4753 951 85 shy 115 EPA 2008 Mod
Nickel 40000 401 100 85 - 115 EPA 2008 Mod
Copper 40000 418 105 85 - 115 EPA 2008 Mod
Zinc 10000 1033 103 85 - 115 EPA 2008 Mod
Arsenic 15000 1437 958 85 - 115 EPA 2008 Mod
Selenium 30000 2966 989 85 - 115 EPA 2008 Mod
Molybdenum 20000 181 905 85 shy 115 EPA 2008 Mod
Silver 15000 1517 101 85 shy 115 EPA 2008 Mod
Cadmium 080000 0781 976 85 - 1lS EPA 2008 Mod
Antimony 080000 0815 102 85 - 115 EPA 2008 Mod
Barium 10000 969 969 85 - 115 EPA 2008 Mod
Lead 15000 1597 106 85 - 115 EPA 2008 Mod
Spike LCSD LCSD Added Concentration Recovery RPO
Analyte (microgL) (microgL) Recovery RPO Limits Limit Method Notes
Beryllium 20000 1949 974 0955 85 - 115 20 EPA 2008 Mod
Sodium 50000 500 100 0216 85 - 115 20 EPA 2008 Mod
Aluminum 15000 1485 990 171 85 - 115 20 EPA 2008 Mod
Calcium 15000 1544 103 103 85 - 115 20 EPA 2008 Mod
Chromium 70000 667 953 148 85 - 115 20 EPA 2008 Mod
Manganese 60000 596 994 175 85 - 115 20 EPA 2008 Mod
Iron 50000 4852 970 206 85 - 115 20 EPA 2008 Mod
Nickel 40000 402 IOI 0246 85 - 115 20 EPA 2008 Mod
Frontier Global Sciences Inc The results in his report only apply to the samples analyzed in accordance wirh the chain ofcustody document This analytical report must be reproduced in iLS entirety
Page 20of26 1201073 Final Report 04252012
Liz Siska Project Manager
22
11720 North Creek Parkway North Suite 400 ~~shy Bothell WA 98011 Ph 425-686-1996~ONTif Fx 425-686-3096
GLOBAL SCIENCES
LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLICATE
RECOVERY AND RPO
Batch F20327 l Sequence 2C22005
Preparation Closed Vessel Nitric Oven Digestion Lab Number F203271-BSBSD 1
LCS Source Blank Spike
Analyte
Spike Added (microgL)
LCSD Concentration
(microgL)
LCSD oo
Recovery
RPO Recovery
Limits RPO Limit Method Notes
Copper
Zinc
Arsenic
Selenium
40000
10000
15000
30000
428
1039
1452
3015
107
104
968
101
224
0570
0977
166
85 - 115
85 - 115
85 - 115
85 - 115
20
20
20
20
EPA 2008 Mod
EPA 2008 Mod
EPA 2008 Mod
EPA 2008 Mod Molybdenum
Silver
20000
15000
182
J502
910
100
0564
103
85 - 115
85 - 115
20
20
EPA 2008 Mod
EPA 2008 Mod Cadmium
Antimony
Barium
Lead
080000
080000
10000
15000
0828
0808
986
1620
103
101
986
108
585
0848
177
142
85 - 115
85 - 115
85 shy 11 S
85 - 115
20
20
20
20
EPA 2008 Mod
EPA 2008 Mod
EPA 2008 Mod
EPA 2008 Mod
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report mus be reproducedin its entirety
Page 2 o26J20J073 Final Report 041252012
Liz Siska Project Manager
23
11720 North Creek Parkway North Suite 400 Bothell WA 980 l l
Ph 425-686-1996FRONT[ER- Fx 425-686-3096 cLosAL SCIEN _CES
LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLICATE
RECOVERY AND RPD
Batch F203314 Sequence 2C25005
Preparation Closed Vessel Nitric Oven Digestion Lab Number F2033 l 4-BSBSD 1
LCS Source Blank Spike
Analyte
Thallium
Spike Added (microgL)
LCS Concentration
(microgL)
LCS 0o
Recovery Recovery
Limits Method
040000 0396 989 85 - 115 EPA 2008 Mod
Notes
Analyte
Spike Added (microgL)
LCSD Concentration
(microgL)
LCSD 0o
Recovery
RPD Recovery
Limits RPO Limit Method Notes
Thallium 040000 0391 978 112 85 - ll5 20 EPA 2008 Mod
Frontier Global Sciences Inc The results in this report only apply to the samples anayed in accordance with the chain ofcustody docwnenJ This analytical report must be reproduced in its entirety
Page 22of26 1201073 Final Report 04252012
Liz Siska Project Manager
24
Liz Siska P roject Manager
11720 North Creek Parkway North Suite 400
~ Bothell WA 98011 Ph 425-686-1996
~JTIEif middot Fx 425-686-3096 GLOBAL SCIENCES
PREPARATION BLANKS
Instrument Hg-17 Sequence 2A09010
Preparation BrCI Oxidation
Lab Sample ID Analyte Found MRL Units Batch Method Notes
F201063-BLK I Mercury -0009 050 ngL F201063 EPA 1631E u F20 I063-BLK2 Mercury -0006 050 ngL F201063 EPA 1631E u F201063-BLK3 Mercury -002 050 ngL F201063 EPA 163IE u F201063-BLK4 Mercury 003 050 ngL F201063 EPA 1631E U QB-04 F201063-BLKS Mercury 011 052 ngL F201063 EPA I631E U QB-06
Frontier Global Sciences Inc The results in this report only apply 10 1he samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Page 23 o26 1201073 Final Repon 04252012 25
Liz Siska Project Manager
11720 North Creek Parkway North Suite 400 Bothell WA 98011
Ph 425-686-1996 FROr~TIER- Fx 425-686-3096 GLOBAL SCIENCES
PREPARATION BLANKS
Instrument ICPMS-6 Sequence 2C22005
Preparation Closed Vessel Nitric Oven Digestion
Lab Sample ID Analyte Found MRL Units Batch Method Notes
F203271-BLK1 Beryllium 000008 0060 microgL F203271 PA 2008 Molt u F20327 1-BLK1 Sodium 2 20 microgL F20327l PA 2008 Moc u F20327I-BLK1 Aluminum -004 40 microgL F203271 PA 2008 Molt u F20327I -BLK1 Calcium 40 microgL F203271 PA 2008 Molt u F203271 -BLK1 Chromium -002 010 microgL F203271 ~A 2008 Molt u F203271-BLKI Manganese 001 010 microgL F203271 PA 2008 Molt u F20327 l -BLK 1 Iron -002 100 microgL F203271 PA 2008 Molt u F203271-BLKI Nickel 0004 010 microgL F203271 PA 2008 Moc u F203271-BLK1 Copper 0003 010 microgL F203271 PA 2008 Moc u F203271-BLK1 Zinc 0007 020 microgL F203271 PA 2008 Moc u F203271-BLK1 Arsenic -006 015 microgL F203271 PA 2008 Moc u F203271-BLK1 Selenium -002 060 microgL F203271 PA 2008 Moc u F203271-BLK1 Molybdenum 001 006 microgL F203271 PA 2008 Molt u F203271-BLK1 Silver -00005 0020 microgL F203271 PA 2008 Molt u F203271-BLKl Cadmium 0004 0020 microgL F203271 PA 2008 Molt u F20327 l-BLKl Antimony 0002 0020 microgL F203271 PA 2008 Molt u F203271-BLKI Barium 001 020 microgL F203271 PA 2008 Molt u F203271-BLKI Lead 0010 0040 microgL F203271 PA 2008 Moc u
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Page 24of26 1201073 Final Report 04252012 26
~
~TIER~ GLOBAL SCIENCES
11720 North Creek Parkway North Suite 400 Bothell WA 980ll
Ph 425-686-1996 Fx 425-686-3096
PREPARATION BLANKS
Instrument JCPMS-3 Sequence 2C25005
Preparation Closed Vessel Nitric Oven Digestion
Lab Sample ID Analyte Found MRL Units Batch Method Notes
F2033I4-BLK1 Thalium 00007 0010 microgL F2033I4 ~PA 2008 Molt u
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Page 25 o26Liz Siska Project Manager 1201073 Final Report
04252012 27
l l 720 North Creek Parkway North Suite 400~Vi-~ Bothell WA 98011 Ph 425-686-1 996~Tlmiddot~ Fx 425-686-3096
G L OBAL SCIENCE S
Notes and Definitions
U Analyte included in the analysis but not detected
QM-02 The MS andor MSD recoveries outside acceptance limits due to spike concentration less than I times the sample concentration The batch was accepted based on LCS and LCSD recoveries within control limits and when analysis permits acceptable AS ASD
QB-06 The blank was preserved to 5 BrCI rather than I The control limit for blanks preserved to greater than 1 BrCl is the preservation percentage multiplied by the MRL
QB-04 The blank was preserved to 2 BrCI rather than l The control limit for blanks preserved to greater than l BrCI is the preservation percentage multiplied by the MRL
FB-1631 Required equipmentfieldfilter blank not submitted by the client The sample has been analyzed according to 163 lE but does not meet 163 lE criteria
AS This MS andor MSD is an analytical spike andor an analytical spike duplicate
DET Analyte Detected
MDL Minimum Detection Limit
MRL Minimum Reporting Limit
ND Analyte Not Detected at or above the reporting limit
wet Sample results reported on a wet weight basis
dry Sample results reported on a dry weight basis
RPO Relative Percent Difference
RSD Relative Standard Deviation
Frontier Global Sciences Inc The lesults i111his reporl only apply to he samples analyzed In accordance with the chain ofcuslody document This analytical report must be reproduced in its entirely
Page 26of26 1201073 Final Report 04252012
Liz Siska Project Manager
28
CHAIN-OF-(USTODY ttECORD Page i of f 106677 _J
BoLD F1ELDS REQUIRED PLEASE C 1RCLE REQUESTED ANALYSIS
SAMPLE ID
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----i pmiddotofissionrrl11bomtorymim (WHITE ORIGINAL GREEN PROJECT MANAGER)
shy
Liz Siska Project Manager
FRONTIERshycLoaAt SCI ENCES
11720 North Creek Parkway North Suite 400 Bothell WA 98011
Ph 425-686-1996 Fx 425-686-3096
MATRIX DUPLICATESfRIPLICATES
SOURCE 1201073-02
Batch F201063
Preparation BrCI Oxidation
Sequence 2A09010
Lab Number F201063-DUPI
Sample Duplicate Concentration Concentration RPD
Analyte ngL ngL MRL RPD Limit Method Notes Mercury 1048 1054 202 0617 24 EPA I631E
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Page 6of26 1201073 Final Report 04252012 8
11720 North Creek Parkway North Suite 400 BotheE WA 980 l l
Ph 425-686-1996 Fx 425-686-3096
GLOBAL SCIENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1201073-02
Batch F201063 Sequence 2A09010
Preparation BrCI Oxidation Lab Number F20 l 063-MSMSDl
Sample Spike MS MS Concentration Added Concentration RecoveryAnalyte (ngL) (ngL) (ngL) Recovery Method Limits Notes
Mercury 1048 20400 3136 102 71 125 EPA 163IE
Spike MSD MSD Added Concentration oo Recovery RPD
RPD Limits Limit Method Notes Analyte (ngL) (ngL) Recovery
Mercury 20400 2708 814 147 71 - 125 24 EPA 1631E
shy
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Page 7 o26Liz Siska Project Manager 120JO7 3 Final Repo1
04252012 9
Liz Siska Project Manager
11720 North Creek Parkway North Suite 400 Bothell WA 98011
Ph 425-686-1996~ Fx 425-686-3096 CL06AL SCIENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1112278-02
Batch F201063 Sequence 2A09010
Preparation BrCI Oxidation Lab Number F20 l 063-MSMSD2
Sample Spike MS MS
Analyte Concentration
(ogL) Added (ngL)
Concentration (ngL)
Recovery
RecoveryLimits Method Notes
Mercury 761 20400 2786 992 71 125 EPA 1631E
Spike MSD MSD Added Concentration Oo Recovery RPO
Analyte (ngL) (ngL) Recovery RPO Limits Limit Method Notes
Mercury 20400 2837 102 182 71 - 125 24 EPA l631E
shy
Frontier Global Sciences Inc The results in this report only apply to the somples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Page 8 o26 1201073 Final Report 042512012 10
11720 North Creek Parkway North Suite 400 Bothell WA 980 l l
Ph 425-686-1996 ~ Fx 425-686-3096 GLOBAL SCIENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1201029-01
Batch
Preparation
F201063
BrCI Oxidation
Sequence
Lab Number
2A09010
F20 I 063-MSMSD3
Analyte
Mercury
Analyte
Mercury
Sample Spike Concentration Added
(ngL) (ngL)
534 10200
Spike MSD Added Concentration (ngL) (ngL)
10200 1407
MS MS Concentration Recovery
(ngL) Recovery Limits
1558 JOO 7l shy 125
MSD oo Recovery RPD
Recovery RPD Limits Limit
856 102 71 - 125 24
Method
EPA l63lE
Method
EPA 631E
Notes
Notes
Frontier Global Sciences Inc The results in this repon only apply to rhe samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Page 9of26 1201073 Final Report 041252012
Liz Siska Project Manager
1 1
11720 North Creek Parkway North Suite 400 Bothell WA 98011
Ph 425-686-1996 FRONTIER- Fx 425-686-3096 cLosAL SCIENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1201030-02
Batch F20I063 Sequence 2A09010
Preparation BrCI Oxidation Lab Number F201063-MSMSD4
Sample Spike MS MS Concentration Added Concentration RecoveryAnalyte (ngL) (ngL) (ngL) Recovery MethodLimits Notes
Mercury 554 10200 1482 910 71 - 125 EPA I631E
Spike MSD MSD Oo Added Concentratio11 Recovery RPD
RPD Limits Limit Method Analyte (ngL) (ngL) Recovery Notes
Mercury 10200 1461 890 140 71 - 125 24 EPA 163IE
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed m accordance with the chain ofcus1ody document This anayt(ca repon must be reproduced in itr entirety
Page lOo26Liz Siska Project Manager 1201073 Final Report
041252012 12
I 1720 North Creek Parkway North Suite 400 Bothe I I WA 98011
Ph 425-686-1996 ~ Fx 425-686-3096 GLOBAL SCIENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1201073-01RE3
Batch F20327l Sequence 2C22005
Prcpa ration ((01ed Vessel ~ itric Oven Digestion Lab Number F203271-MSMSD 1
Analyte
Sample Concentration
(microgL)
Spike Added (microgL)
MS Concentration
(microgL)
MS Oo
Recovery Recovery
Method Limits Notes
Calcium 5013000 15150 4802000 -13900 70- 130 EPA 2008 Mod QM-02
Analyte
Spike Added (microgL)
MSD Concentration
(microgL)
MSD ~o
Recovery
Oo
RPD Recovery
Limits RPDLimit Method Notes
Calcium 15150 4943000 -4600 289 70 - 130 20 EPA 2008 Mod QM-02
Frontier Global Sciences Inc The results in this report only apply to the samples analyud inaccordance with the chain ofcustody document 17is analyticol report must be reproduced in its entirety
Page lI o16 1101073 Final Report 04152012
Liz Siska Project Manager
13
l l 720 North Creek Parkway North Suite 400 Bothell WA 98011
Ph 425-686-1996FRONTIER Fx 425-686-3096 GLOBAL SCIENCES
MATRIX SPIKE I MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1201073-01RE4
Batch F203271 Sequence 2C22005
Preparation Closed Vessel Nitric Oven Digestion Lab Number F203271-MSMSD2
Sample Spike MS MS Concentration Added Concentration Oo RecoveryAnalyte (microgL) (microgL) (microgL) Recovery Method Limits Notes
Beryllium 0507 20200 2442 958 70 - 130 EPA 2008 Mod Sodium 258800 50500 257700 -213 70 -130 EPA 2008 Mod QM-02 Aluminum 529 15150 2023 986 70 - 130 EPA 2008 Mod Chromium 057 70700 804 106 70 - 130 EPA 2008 Mod Manganese 2805 60600 2834 476 70 - 130 EPA 2008 Mod QM-02 Iron ND 50500 5200 103 70 130 EPA 2008 Mod Nickel 979 40400 141 l 107 70- 130 EPA 2008 Mod Copper 055 40400 434 939 70 - 130 EPA 2008 Mod Zinc 040 10100 842 794 70 - 130 EPA 2008 Mod Arsenic 1030 15150 2418 916 70 - 130 EPA 2008 Mod Selenium 6340 30300 8973 869 70 130 EPA 2008 Mod Molybdenum 1338 20200 1367 142 70 130 EPA 2008 Mod QM-02 Silver ND 15150 1388 916 70 - 130 EPA 2008 Mod Cadmium 0332 080800 1105 middot956 70 - 130 EPA 2008 Mod Antimony 0408 080800 1259 105 70- 130 EPA 2008 Mod Barium 2397 10100 2495 968 70 - 130 EPA 2008 Mod Lead ND 15150 1542 102 70 130 EPA 2008 Mod
shy
shy
shy
shy
Analyte
Spike Added (microgL)
MSD Concentration
(microgL)
MSD Oo
Recovery
Oo
RPD Recovery
Limits RPD Limit Method Notes
Beryllium
Sodium
Aluminum
Chromium
Manganese
Iron
Nickel
Copper
Zinc
Arsenic
Selenium
Molybdenum
20200
50500
15150
7Q700
60600
50500
40400
40400
10100
15150
30300
20200
2561
257100
2034
773
2852
5187
1381
419
916
2225
9400
1366
102
-336
993
101 769
103
995
902
868
789
101
137
474
0243
0564
385
0625
0242
213
347
849
831
464
00771
70 - 130
70 bull 130 70 - 130
70 - 130
70 - 130
70 - 130
70 - 130
70 - 130
70 - 130
70 bull 130 70 - 130
70 - 130
20
20
20
20
20
20
20
20
20
20
20
20
EPA 2008 Mod
EPA 2008 Mod
EPA 2008 Mod
EPA 2008 Mod
EPA 2008 Mod
EPA 2008 Mod
EPA 2008 Mod
EPA 2008 Mod
EPA 2008 Mod
EPA 2008 Mod
EPA 2008 Mod
EPA 2008 Mod
QM-02
QM-02
Frontier G lobal Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
--f_~ --~~~-~ -middot middot Page 12 o261201073 Final Report 041252012
Liz Siska Project Manager
14
11720 North Creek Parkway North Suite 400
~ Bothell WA 98011
~TIEmiddot Ph 425-686-1996 Fx 425-686-3096
GLOB11L SCIENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPO
SOURCE 1201073-01RE4
Batch F203271 Sequence 2C22005
Preparation ~lo~ed Vessel Nitric Oven Digestion Lab Number F20327 I-MSMSD2
Spike MSD MSD Added Concentration Oo Recovery RPO
Analyte (microgL) (microgL) Recovery RPD Limits Limit Method Notes
Silver 15150 1387 915 00874 70 - 130 20 EPA 2008 Mod Cadmium 080800 1061 902 403 70 - 130 20 EPA 200amp Mod Antimony 080800 1274 107 l2l 70 - 130 20 EPA 2008 Mod Barium 10100 2514 )16 0781 70 - 130 20 EPA 200amp Mod Lead 15150 1534 101 0525 70 shy 130 20 EPA 2008 Mod
Frontier Global Sciences Inc The results in this report only apply to 1he samples analyzed in accordance wiih the chain ofcustody document This analytical repo1 must be reproduced in ils entirety
Page 13 o26Liz Siska Project Manager 1201073 Final Reporl
04252012 15
11720 North Creek Parkway North Suite 400
~ Bothell WA 98011 Ph 425-686-I996
~RONTIER~ Fx 425-686-3096 GLOBAL SCIEN C ES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1201073-01RE3
Batch F203271 Sequence 2~22005
Preparation Closed Vessel Nitric Oven Digestion Lab Number F20327 I-MSMSD3
Sample Spike MS MS
Analyte Concentration
(microgL) Added (microgL)
Concentration (microgL) Recovery
Recovery Limits Method Notes
Calcium 5013000 10100000 15120000 100 70- 130 EPA 2008 Mod AS
Spike MSD MSD Added Concentration o Oo Recovery RPD
Analyte (microgL) (microgL) Recovery RPD Limits Limit Method Notes
Calcium 10100000 16140000 llO 653 70 - 130 20 EPA 2008 Mod AS
Frontier Global Sciences Inc The results in his report only apply 10 the samples analyzed in accordance ivth he chain ofcustody document This analytical report must be reproduced in its entirety
Page 14 o261201073 Final Report 0425201]
Liz Siska Project Manager
16
Frontier Global Sciences Inc The ruults in this rechain ofcustody do
~ -lt1-c--~ Liz Siska Project Manager
11720 North Creek Parkway North Suite 400 Bothell WA 98011
Ph 425-686-1996 Fx 425-686-3096
GLOBAL SCIENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1201073-01RE4
Batch J203271 Sequence 2C22005
Preparation ~ IQsed Ve~~el Nitric Oven Qigestion Lab Number F203271-MSMSQ4
Analyte
Beryllium
Sample Concentration
(11gL)
0507
Spike Added (11gL)
20200
MS Concentration
(microgL)
2041
MS Oo
Recovery
985
RecoveryMethod Limits
70 - 130 EPA 2008 Mod
Notes
AS
Sodium 258800 40400 292900 845 70- 130 EPA 2008 Mod AS
Aluminum 529 40400 3956 966 70 - 130 EPA 2008 Mod AS
Chromium 057 40400 430l 106 70- 130 EPA 2008 Mod AS
Manganese 2805 40400 7042 105 70 - 130 EPA 2008 Mod AS
Iron ND 20200 2121 105 70 - 130 EPA 2008 Mod AS
Nickel 979 50500 5112 993 70 l30 EPA 2008 Mod AS
Copper 055 50500 4754 940 70 - 130 EPA 2008 Mod AS
Zinc 040 10100 9074 898 70 - 130 EPA 2008 Mod AS
Arsenic 1030 40400 4317 104 70 130 EPA 2008 Mod AS
Selenium 6340 40400 4688 100 70 - 130 EPA 2008 Mod AS
Molybdenum 1338 20200 338l 101 70 - 130 EPA 2008 Mod AS
Silver ND 20200 1850 916 70 130 EPA 2008 Mod AS
Cadmium 0332 40400 3937 966 70 130 EPA 2008 Mod AS
Antimony 0408 20200 2091 102 70 - 130 EPA 2008 Mod AS
Barium 2397 80800 1056 101 70- 130 EPA 2008 Mod AS
Lead ND IO100 9932 983 70 130 EPA 2008 Mod AS
shy
shy
shy
shy
shy
Analyte
Spike Added (microgL)
MSD Concentration
(microgL)
MSD
Recovery
RPD
Recovery Limits
RPDLimit Method Notes
Beryllium 20200 2007 968 l71 70 - 130 20 EPA 2008 Mod AS Sodium 40400 292600 837 0114 70 130 20 EPA 2008 Mod AS Aluminum 40400 3954 966 00362 70 - 130 20 EPA 2008 Mod AS Chromium 40400 4287 106 0337 70 - 130 20 EPA 2008 Mod AS Manganese 40400 6944 102 140 70 - 130 20 EPA 2008 Mod AS Iron 20200 2077 103 211 70 - 130 20 EPA 2008 Mod AS Nickel 50500 5126 996 0276 70 - 130 20 EPA 2008 Mod AS Copper 50500 4707 931 0997 70 - 130 20 EPA 200 8 Mod AS Zinc 10100 9059 896 0166 70 - 130 20 EPA 2008 Mod AS Arsenic 40400 4299 104 0419 70 - 130 20 EPA 2008 Mod AS Selenium 40400 4682 100 0141 70 - 130 20 EPA 2008 Mod AS Molybdenum 20200 3365 100 0473 70 - 130 20 EPA 2008 Mod AS
shy
port only apply to the sampltts analyzed in accordance with the cument This analytical report must be reproduced in its entirety
Page 5 o26 201073 Final Report 042512012 17
Liz Sia Project Manager
11720 North Creek Parkway North Suite 400 Botheln VA 98011
Ph 425-686-1996 Fx 425-686-3096
CLOBAL SCIENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1201073-01RE4
Batch F203271 Sequence 2c2io2~
Preparation Clo~ed Vessel litric Oven Digestion Lab Number F20327 l -MSMSQ4
Analyte
Spike Added (microgL)
MSD Concentration
(microgL)
MSD
Recovery
Oo
RPD Recovery
Limits RPOLimit Method Notes
Silver 20200 1895 938 242 70 - 130 20 EPA 2008 Mod AS Cadmium 40400 3933 965 0104 70 -130 20 EPA 2008 Mod AS Antimony 20200 2107 102 0736 70- 130 20 EPA 2008 Mod AS
Barium 80800 1058 101 0205 70 - 130 20 EPA 2008 Mod AS
Lead 10100 9877 978 0549 70 - 130 20 EPA 2008 Mod AS
Frontier Global Sciences Inc The results in this report only apply to the samples analyudin accordance with lht chain ofcustody document This analytical report must be reproductd rn ilS enlirtty
Page l6of26 1201073 Final Report Ofn5202 18
l I 720 North Creek Parkway North Suite 400 Bothell WA 980I I
Ph 425-686-1996 Fx 425-686-3096
GLO B AL SCIENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1201073-01RE6
Batch F203314 Sequence 2C25005
Preparation Closed Vessel Nitric Oven Digestion Lab Number F203314-MSMSD2
Sample Spike MS MS Concentration Added Concentration RecoveryAnalyte (microgL) (microgL) (microgL) Recovery Method NotesLimits
Thallium 5563 040400 5875 773 70 - 130 EPA 2008 Mod
Spike MSD MSD Added o Concentration Recovery RPD
RPO Limits Limit Method Notes Analyte (microgL) (microgL) Recovery
Thallium 040400 5880 785 00859 70 - 130 20 EPA 2008 Mod
Frontier Global Sciences Inc 11e results in chis reporc only apply 10 1he samples analyzed in accordance wilh lhe chain ofcustody documenz This analycical report musl be reproduced in ils entirety
Page 17 of26 1201073 Fi11aReport 0412512012
Liz Siska Project Manager
19
11720 North Creek Parkway North Suite 400 Bothell WA 98011
Ph 425-686-1996 Fx 425-686-3096
GLOBAl SCIENC ES
MATRIX SPIKE I MATRIX SPIKE DUPLICATE RECOVERY AND RPO
SOURCE I201073-01RE6
Batch F203314
Preparation Closed Vessel Nitric Oven Digestion
Sequence 2C25005
Lab Number F203314-MSMSD4
Analyte
Sample Concentration
(microgL)
Spike Added (microgL)
MS MS Concentration Oo
(microgL) Recovery Recovery
Limits Method Notes
Thallium 5563 10100 1033 968 70- 130 EPA 2008 Mod AS
Analyte
Spike Added (microgL)
MSD Concentration
(microgL)
MS)) Oo
Recovery
RPD
Recovery Limits
RPD Limit Method Notes
Thallium IO100 1037 97l 0341 70 - 130 20 EPA 2008 Mod AS
Frontier Global Sciences Inc The resulrs in this report only apply to the samples analyzed in accordance with the chain ofcusrody document This analytical report must be reproduced in its entirely
Page 18of26 120073 Final Report 04252012
Liz Siska Project Manager
20
11720 North Creek Parkway North Suite 400 l ~ Bothell WA 980 l l Ph 425-686-1996
FRONTIER Fx 425-686-3096 GLOBAL SCIENCES
LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLICATE
RECOVERY AND RPD
Batch F20 l063 Sequence 2A09010
Preparation BrCI Oxidation Lab Number F201063-BSIBSJ21
LCS Source N ist 1641d
Analyte
Spike Added (ngL)
LCS Concentration
(ngL)
LCS
Recovery Recovery
Limits Method Notes
Mercury 15679 1550 988 80 - 120 EPA I631E
Analyte
Spike Added (ngL)
LCSD Concentration
(ngL)
LCSD Oo
Recovery
RPD Recovery
Limits RPD Limit Method Notes
Mercury 15679 1595 [02 289 80 - 120 24 EPA I631E
Frontier Global Sciences Inc The results in this report only apply to the samples analyzedin accordance with the chain ofcustody document This analytical report must be reproduced in ils entirety
Page 19of26 1201073 Final Report 0425 2012
Liz Siska Project Manager
21
11720 North Creek Parkway North Suite 400 Bothell WA 98011
Ph 425-686-1996 FRONTIER Fx 425-686-3096 GLOBAL SCIENCES
LABORA TORY CONTROL SAMPLE LABO RATORY CONTROL SAMPLE DUPLICATE
RECOVERY AND RPD
Batch F203271 Sequence 2C22005
Preparation Closed Vessel Nitric Oven Digestion Lab Number F203271-BSBSD1
LCS Source Blank Spike
Spike LCS LCS Added Concentration Oo Recovery
Analyte (microgL) (microgL) Recovery Limits Method Notes
Beryllium 20000 l930 965 85 - 115 EPA 2008 Mod
Sodium 50000 499 998 85 - 115 EPA 2008 Mod
Aluminum 15000 1460 973 85 - 115 EPA 2008 Mod
Calcium 15000 1528 102 85 - 115 EPA 2008 Mod
Chromium 70000 657 939 85 - 115 EPA 2008 Mod
Manganese 60000 586 976 85 - 115 EPA 2008 Mod
Iron 50000 4753 951 85 shy 115 EPA 2008 Mod
Nickel 40000 401 100 85 - 115 EPA 2008 Mod
Copper 40000 418 105 85 - 115 EPA 2008 Mod
Zinc 10000 1033 103 85 - 115 EPA 2008 Mod
Arsenic 15000 1437 958 85 - 115 EPA 2008 Mod
Selenium 30000 2966 989 85 - 115 EPA 2008 Mod
Molybdenum 20000 181 905 85 shy 115 EPA 2008 Mod
Silver 15000 1517 101 85 shy 115 EPA 2008 Mod
Cadmium 080000 0781 976 85 - 1lS EPA 2008 Mod
Antimony 080000 0815 102 85 - 115 EPA 2008 Mod
Barium 10000 969 969 85 - 115 EPA 2008 Mod
Lead 15000 1597 106 85 - 115 EPA 2008 Mod
Spike LCSD LCSD Added Concentration Recovery RPO
Analyte (microgL) (microgL) Recovery RPO Limits Limit Method Notes
Beryllium 20000 1949 974 0955 85 - 115 20 EPA 2008 Mod
Sodium 50000 500 100 0216 85 - 115 20 EPA 2008 Mod
Aluminum 15000 1485 990 171 85 - 115 20 EPA 2008 Mod
Calcium 15000 1544 103 103 85 - 115 20 EPA 2008 Mod
Chromium 70000 667 953 148 85 - 115 20 EPA 2008 Mod
Manganese 60000 596 994 175 85 - 115 20 EPA 2008 Mod
Iron 50000 4852 970 206 85 - 115 20 EPA 2008 Mod
Nickel 40000 402 IOI 0246 85 - 115 20 EPA 2008 Mod
Frontier Global Sciences Inc The results in his report only apply to the samples analyzed in accordance wirh the chain ofcustody document This analytical report must be reproduced in iLS entirety
Page 20of26 1201073 Final Report 04252012
Liz Siska Project Manager
22
11720 North Creek Parkway North Suite 400 ~~shy Bothell WA 98011 Ph 425-686-1996~ONTif Fx 425-686-3096
GLOBAL SCIENCES
LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLICATE
RECOVERY AND RPO
Batch F20327 l Sequence 2C22005
Preparation Closed Vessel Nitric Oven Digestion Lab Number F203271-BSBSD 1
LCS Source Blank Spike
Analyte
Spike Added (microgL)
LCSD Concentration
(microgL)
LCSD oo
Recovery
RPO Recovery
Limits RPO Limit Method Notes
Copper
Zinc
Arsenic
Selenium
40000
10000
15000
30000
428
1039
1452
3015
107
104
968
101
224
0570
0977
166
85 - 115
85 - 115
85 - 115
85 - 115
20
20
20
20
EPA 2008 Mod
EPA 2008 Mod
EPA 2008 Mod
EPA 2008 Mod Molybdenum
Silver
20000
15000
182
J502
910
100
0564
103
85 - 115
85 - 115
20
20
EPA 2008 Mod
EPA 2008 Mod Cadmium
Antimony
Barium
Lead
080000
080000
10000
15000
0828
0808
986
1620
103
101
986
108
585
0848
177
142
85 - 115
85 - 115
85 shy 11 S
85 - 115
20
20
20
20
EPA 2008 Mod
EPA 2008 Mod
EPA 2008 Mod
EPA 2008 Mod
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report mus be reproducedin its entirety
Page 2 o26J20J073 Final Report 041252012
Liz Siska Project Manager
23
11720 North Creek Parkway North Suite 400 Bothell WA 980 l l
Ph 425-686-1996FRONT[ER- Fx 425-686-3096 cLosAL SCIEN _CES
LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLICATE
RECOVERY AND RPD
Batch F203314 Sequence 2C25005
Preparation Closed Vessel Nitric Oven Digestion Lab Number F2033 l 4-BSBSD 1
LCS Source Blank Spike
Analyte
Thallium
Spike Added (microgL)
LCS Concentration
(microgL)
LCS 0o
Recovery Recovery
Limits Method
040000 0396 989 85 - 115 EPA 2008 Mod
Notes
Analyte
Spike Added (microgL)
LCSD Concentration
(microgL)
LCSD 0o
Recovery
RPD Recovery
Limits RPO Limit Method Notes
Thallium 040000 0391 978 112 85 - ll5 20 EPA 2008 Mod
Frontier Global Sciences Inc The results in this report only apply to the samples anayed in accordance with the chain ofcustody docwnenJ This analytical report must be reproduced in its entirety
Page 22of26 1201073 Final Report 04252012
Liz Siska Project Manager
24
Liz Siska P roject Manager
11720 North Creek Parkway North Suite 400
~ Bothell WA 98011 Ph 425-686-1996
~JTIEif middot Fx 425-686-3096 GLOBAL SCIENCES
PREPARATION BLANKS
Instrument Hg-17 Sequence 2A09010
Preparation BrCI Oxidation
Lab Sample ID Analyte Found MRL Units Batch Method Notes
F201063-BLK I Mercury -0009 050 ngL F201063 EPA 1631E u F20 I063-BLK2 Mercury -0006 050 ngL F201063 EPA 1631E u F201063-BLK3 Mercury -002 050 ngL F201063 EPA 163IE u F201063-BLK4 Mercury 003 050 ngL F201063 EPA 1631E U QB-04 F201063-BLKS Mercury 011 052 ngL F201063 EPA I631E U QB-06
Frontier Global Sciences Inc The results in this report only apply 10 1he samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Page 23 o26 1201073 Final Repon 04252012 25
Liz Siska Project Manager
11720 North Creek Parkway North Suite 400 Bothell WA 98011
Ph 425-686-1996 FROr~TIER- Fx 425-686-3096 GLOBAL SCIENCES
PREPARATION BLANKS
Instrument ICPMS-6 Sequence 2C22005
Preparation Closed Vessel Nitric Oven Digestion
Lab Sample ID Analyte Found MRL Units Batch Method Notes
F203271-BLK1 Beryllium 000008 0060 microgL F203271 PA 2008 Molt u F20327 1-BLK1 Sodium 2 20 microgL F20327l PA 2008 Moc u F20327I-BLK1 Aluminum -004 40 microgL F203271 PA 2008 Molt u F20327I -BLK1 Calcium 40 microgL F203271 PA 2008 Molt u F203271 -BLK1 Chromium -002 010 microgL F203271 ~A 2008 Molt u F203271-BLKI Manganese 001 010 microgL F203271 PA 2008 Molt u F20327 l -BLK 1 Iron -002 100 microgL F203271 PA 2008 Molt u F203271-BLKI Nickel 0004 010 microgL F203271 PA 2008 Moc u F203271-BLK1 Copper 0003 010 microgL F203271 PA 2008 Moc u F203271-BLK1 Zinc 0007 020 microgL F203271 PA 2008 Moc u F203271-BLK1 Arsenic -006 015 microgL F203271 PA 2008 Moc u F203271-BLK1 Selenium -002 060 microgL F203271 PA 2008 Moc u F203271-BLK1 Molybdenum 001 006 microgL F203271 PA 2008 Molt u F203271-BLK1 Silver -00005 0020 microgL F203271 PA 2008 Molt u F203271-BLKl Cadmium 0004 0020 microgL F203271 PA 2008 Molt u F20327 l-BLKl Antimony 0002 0020 microgL F203271 PA 2008 Molt u F203271-BLKI Barium 001 020 microgL F203271 PA 2008 Molt u F203271-BLKI Lead 0010 0040 microgL F203271 PA 2008 Moc u
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Page 24of26 1201073 Final Report 04252012 26
~
~TIER~ GLOBAL SCIENCES
11720 North Creek Parkway North Suite 400 Bothell WA 980ll
Ph 425-686-1996 Fx 425-686-3096
PREPARATION BLANKS
Instrument JCPMS-3 Sequence 2C25005
Preparation Closed Vessel Nitric Oven Digestion
Lab Sample ID Analyte Found MRL Units Batch Method Notes
F2033I4-BLK1 Thalium 00007 0010 microgL F2033I4 ~PA 2008 Molt u
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Page 25 o26Liz Siska Project Manager 1201073 Final Report
04252012 27
l l 720 North Creek Parkway North Suite 400~Vi-~ Bothell WA 98011 Ph 425-686-1 996~Tlmiddot~ Fx 425-686-3096
G L OBAL SCIENCE S
Notes and Definitions
U Analyte included in the analysis but not detected
QM-02 The MS andor MSD recoveries outside acceptance limits due to spike concentration less than I times the sample concentration The batch was accepted based on LCS and LCSD recoveries within control limits and when analysis permits acceptable AS ASD
QB-06 The blank was preserved to 5 BrCI rather than I The control limit for blanks preserved to greater than 1 BrCl is the preservation percentage multiplied by the MRL
QB-04 The blank was preserved to 2 BrCI rather than l The control limit for blanks preserved to greater than l BrCI is the preservation percentage multiplied by the MRL
FB-1631 Required equipmentfieldfilter blank not submitted by the client The sample has been analyzed according to 163 lE but does not meet 163 lE criteria
AS This MS andor MSD is an analytical spike andor an analytical spike duplicate
DET Analyte Detected
MDL Minimum Detection Limit
MRL Minimum Reporting Limit
ND Analyte Not Detected at or above the reporting limit
wet Sample results reported on a wet weight basis
dry Sample results reported on a dry weight basis
RPO Relative Percent Difference
RSD Relative Standard Deviation
Frontier Global Sciences Inc The lesults i111his reporl only apply to he samples analyzed In accordance with the chain ofcuslody document This analytical report must be reproduced in its entirely
Page 26of26 1201073 Final Report 04252012
Liz Siska Project Manager
28
CHAIN-OF-(USTODY ttECORD Page i of f 106677 _J
BoLD F1ELDS REQUIRED PLEASE C 1RCLE REQUESTED ANALYSIS
SAMPLE ID
middoti-rg -- bull ~rshy~ _- tzir +- lt-ltJ~ lt
SAMPLING
DATeTtME
IF COMPOSITE INDICATE BOTH
START amp FINISH
DATETIME li1J oc -r 111_- _vlt-c_
w Ishyt 0 n
w l w 0 ~ u X -Xmiddot ~ m Ishy lt( lt( 0
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IIXJ JC
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Trttbull rin K C-~-~ pound1t I 1Jtl~ t20~L lwlJI ishy
middot~ON Mm1x A-Al~ S-SOil GW-GampOUHO WATER SW-SUampfA(f WATER DWmiddotDRIIIKIKlti WATER
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1 WW-WASTE WATER PmmATIVE H-HCL H-HN01 S-H1SO Na-NaOH H-HEOH -~ --~
PROJECT MANAGER llr middot1 ~Q Aw4---P1V- Het_ r COMPANY t-lo--tm ~ bd i ( I ~j 6 A ADP~SS 91 g~ez tJshy(ITJ ~ STATE fH_ ZIP c3o--
PHONE 22j-((omiddotf EXT ____
fAX--------------------- shyE-MAIL (JbHd-esa e n ta wamp Sm NAME Meccft1lt-1ltk f--g
PROJECT _
OTHEi________STATpound NH MA ME VT
REGULATORY PROGRAM NPDES RGP POTW STORHWATEl OR
GWP OIL FUHD BROWNIIELO OR OTHER----------
Quon PO o2J~-lt1Jpound)
DATE NEEDED _1--1 middot Z=-----shy4 (1-1_ METALS 8 RCRA 13 pp ff MN PB Cu
QAQC REPORTJNGYVEL
A CG) O R
PRESUMPTIVE CERTAINTY
7i2lt_
RECpound1VEO BYRELINQUISHED BY DATE TIME SUSPECTED (OHTAHIHATIOH________
TEHP~ C REPORTING OPTIONS 01HEA METAL------------PRELIHl Yu OR No
DISSOLVED METALS FIELD FllTEREDI YES 110
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IF YH FAX OR POf 7~shy Hom (IE SPECIAL DETECTION LINITl BllLIKGINfO If DlffERrnT)ELECTRONIC OPTIONS zo 1 2 2) le~C1 1 Jc Id sJ 60 6c
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Ka)Jcr(c C(cdd -ltJ c -l -gtck- z Alt 5e1 Hj
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ImiddotRELINQUISHED BY DATE TIHE RECflVEO BY I FIELD READINGS
eastern analytical inc 2s CHENELL D R1ve IC 0 Nco1to N H 0330 1 I TEL 60J22aos2s 1aoo2a1os2s IFAx 6032284591 j E-MA1t cus-roM111_mV1c~EAILAsscoMJ www1A1LAascoM
----i pmiddotofissionrrl11bomtorymim (WHITE ORIGINAL GREEN PROJECT MANAGER)
shy
11720 North Creek Parkway North Suite 400 BotheE WA 980 l l
Ph 425-686-1996 Fx 425-686-3096
GLOBAL SCIENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1201073-02
Batch F201063 Sequence 2A09010
Preparation BrCI Oxidation Lab Number F20 l 063-MSMSDl
Sample Spike MS MS Concentration Added Concentration RecoveryAnalyte (ngL) (ngL) (ngL) Recovery Method Limits Notes
Mercury 1048 20400 3136 102 71 125 EPA 163IE
Spike MSD MSD Added Concentration oo Recovery RPD
RPD Limits Limit Method Notes Analyte (ngL) (ngL) Recovery
Mercury 20400 2708 814 147 71 - 125 24 EPA 1631E
shy
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Page 7 o26Liz Siska Project Manager 120JO7 3 Final Repo1
04252012 9
Liz Siska Project Manager
11720 North Creek Parkway North Suite 400 Bothell WA 98011
Ph 425-686-1996~ Fx 425-686-3096 CL06AL SCIENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1112278-02
Batch F201063 Sequence 2A09010
Preparation BrCI Oxidation Lab Number F20 l 063-MSMSD2
Sample Spike MS MS
Analyte Concentration
(ogL) Added (ngL)
Concentration (ngL)
Recovery
RecoveryLimits Method Notes
Mercury 761 20400 2786 992 71 125 EPA 1631E
Spike MSD MSD Added Concentration Oo Recovery RPO
Analyte (ngL) (ngL) Recovery RPO Limits Limit Method Notes
Mercury 20400 2837 102 182 71 - 125 24 EPA l631E
shy
Frontier Global Sciences Inc The results in this report only apply to the somples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Page 8 o26 1201073 Final Report 042512012 10
11720 North Creek Parkway North Suite 400 Bothell WA 980 l l
Ph 425-686-1996 ~ Fx 425-686-3096 GLOBAL SCIENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1201029-01
Batch
Preparation
F201063
BrCI Oxidation
Sequence
Lab Number
2A09010
F20 I 063-MSMSD3
Analyte
Mercury
Analyte
Mercury
Sample Spike Concentration Added
(ngL) (ngL)
534 10200
Spike MSD Added Concentration (ngL) (ngL)
10200 1407
MS MS Concentration Recovery
(ngL) Recovery Limits
1558 JOO 7l shy 125
MSD oo Recovery RPD
Recovery RPD Limits Limit
856 102 71 - 125 24
Method
EPA l63lE
Method
EPA 631E
Notes
Notes
Frontier Global Sciences Inc The results in this repon only apply to rhe samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Page 9of26 1201073 Final Report 041252012
Liz Siska Project Manager
1 1
11720 North Creek Parkway North Suite 400 Bothell WA 98011
Ph 425-686-1996 FRONTIER- Fx 425-686-3096 cLosAL SCIENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1201030-02
Batch F20I063 Sequence 2A09010
Preparation BrCI Oxidation Lab Number F201063-MSMSD4
Sample Spike MS MS Concentration Added Concentration RecoveryAnalyte (ngL) (ngL) (ngL) Recovery MethodLimits Notes
Mercury 554 10200 1482 910 71 - 125 EPA I631E
Spike MSD MSD Oo Added Concentratio11 Recovery RPD
RPD Limits Limit Method Analyte (ngL) (ngL) Recovery Notes
Mercury 10200 1461 890 140 71 - 125 24 EPA 163IE
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed m accordance with the chain ofcus1ody document This anayt(ca repon must be reproduced in itr entirety
Page lOo26Liz Siska Project Manager 1201073 Final Report
041252012 12
I 1720 North Creek Parkway North Suite 400 Bothe I I WA 98011
Ph 425-686-1996 ~ Fx 425-686-3096 GLOBAL SCIENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1201073-01RE3
Batch F20327l Sequence 2C22005
Prcpa ration ((01ed Vessel ~ itric Oven Digestion Lab Number F203271-MSMSD 1
Analyte
Sample Concentration
(microgL)
Spike Added (microgL)
MS Concentration
(microgL)
MS Oo
Recovery Recovery
Method Limits Notes
Calcium 5013000 15150 4802000 -13900 70- 130 EPA 2008 Mod QM-02
Analyte
Spike Added (microgL)
MSD Concentration
(microgL)
MSD ~o
Recovery
Oo
RPD Recovery
Limits RPDLimit Method Notes
Calcium 15150 4943000 -4600 289 70 - 130 20 EPA 2008 Mod QM-02
Frontier Global Sciences Inc The results in this report only apply to the samples analyud inaccordance with the chain ofcustody document 17is analyticol report must be reproduced in its entirety
Page lI o16 1101073 Final Report 04152012
Liz Siska Project Manager
13
l l 720 North Creek Parkway North Suite 400 Bothell WA 98011
Ph 425-686-1996FRONTIER Fx 425-686-3096 GLOBAL SCIENCES
MATRIX SPIKE I MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1201073-01RE4
Batch F203271 Sequence 2C22005
Preparation Closed Vessel Nitric Oven Digestion Lab Number F203271-MSMSD2
Sample Spike MS MS Concentration Added Concentration Oo RecoveryAnalyte (microgL) (microgL) (microgL) Recovery Method Limits Notes
Beryllium 0507 20200 2442 958 70 - 130 EPA 2008 Mod Sodium 258800 50500 257700 -213 70 -130 EPA 2008 Mod QM-02 Aluminum 529 15150 2023 986 70 - 130 EPA 2008 Mod Chromium 057 70700 804 106 70 - 130 EPA 2008 Mod Manganese 2805 60600 2834 476 70 - 130 EPA 2008 Mod QM-02 Iron ND 50500 5200 103 70 130 EPA 2008 Mod Nickel 979 40400 141 l 107 70- 130 EPA 2008 Mod Copper 055 40400 434 939 70 - 130 EPA 2008 Mod Zinc 040 10100 842 794 70 - 130 EPA 2008 Mod Arsenic 1030 15150 2418 916 70 - 130 EPA 2008 Mod Selenium 6340 30300 8973 869 70 130 EPA 2008 Mod Molybdenum 1338 20200 1367 142 70 130 EPA 2008 Mod QM-02 Silver ND 15150 1388 916 70 - 130 EPA 2008 Mod Cadmium 0332 080800 1105 middot956 70 - 130 EPA 2008 Mod Antimony 0408 080800 1259 105 70- 130 EPA 2008 Mod Barium 2397 10100 2495 968 70 - 130 EPA 2008 Mod Lead ND 15150 1542 102 70 130 EPA 2008 Mod
shy
shy
shy
shy
Analyte
Spike Added (microgL)
MSD Concentration
(microgL)
MSD Oo
Recovery
Oo
RPD Recovery
Limits RPD Limit Method Notes
Beryllium
Sodium
Aluminum
Chromium
Manganese
Iron
Nickel
Copper
Zinc
Arsenic
Selenium
Molybdenum
20200
50500
15150
7Q700
60600
50500
40400
40400
10100
15150
30300
20200
2561
257100
2034
773
2852
5187
1381
419
916
2225
9400
1366
102
-336
993
101 769
103
995
902
868
789
101
137
474
0243
0564
385
0625
0242
213
347
849
831
464
00771
70 - 130
70 bull 130 70 - 130
70 - 130
70 - 130
70 - 130
70 - 130
70 - 130
70 - 130
70 bull 130 70 - 130
70 - 130
20
20
20
20
20
20
20
20
20
20
20
20
EPA 2008 Mod
EPA 2008 Mod
EPA 2008 Mod
EPA 2008 Mod
EPA 2008 Mod
EPA 2008 Mod
EPA 2008 Mod
EPA 2008 Mod
EPA 2008 Mod
EPA 2008 Mod
EPA 2008 Mod
EPA 2008 Mod
QM-02
QM-02
Frontier G lobal Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
--f_~ --~~~-~ -middot middot Page 12 o261201073 Final Report 041252012
Liz Siska Project Manager
14
11720 North Creek Parkway North Suite 400
~ Bothell WA 98011
~TIEmiddot Ph 425-686-1996 Fx 425-686-3096
GLOB11L SCIENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPO
SOURCE 1201073-01RE4
Batch F203271 Sequence 2C22005
Preparation ~lo~ed Vessel Nitric Oven Digestion Lab Number F20327 I-MSMSD2
Spike MSD MSD Added Concentration Oo Recovery RPO
Analyte (microgL) (microgL) Recovery RPD Limits Limit Method Notes
Silver 15150 1387 915 00874 70 - 130 20 EPA 2008 Mod Cadmium 080800 1061 902 403 70 - 130 20 EPA 200amp Mod Antimony 080800 1274 107 l2l 70 - 130 20 EPA 2008 Mod Barium 10100 2514 )16 0781 70 - 130 20 EPA 200amp Mod Lead 15150 1534 101 0525 70 shy 130 20 EPA 2008 Mod
Frontier Global Sciences Inc The results in this report only apply to 1he samples analyzed in accordance wiih the chain ofcustody document This analytical repo1 must be reproduced in ils entirety
Page 13 o26Liz Siska Project Manager 1201073 Final Reporl
04252012 15
11720 North Creek Parkway North Suite 400
~ Bothell WA 98011 Ph 425-686-I996
~RONTIER~ Fx 425-686-3096 GLOBAL SCIEN C ES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1201073-01RE3
Batch F203271 Sequence 2~22005
Preparation Closed Vessel Nitric Oven Digestion Lab Number F20327 I-MSMSD3
Sample Spike MS MS
Analyte Concentration
(microgL) Added (microgL)
Concentration (microgL) Recovery
Recovery Limits Method Notes
Calcium 5013000 10100000 15120000 100 70- 130 EPA 2008 Mod AS
Spike MSD MSD Added Concentration o Oo Recovery RPD
Analyte (microgL) (microgL) Recovery RPD Limits Limit Method Notes
Calcium 10100000 16140000 llO 653 70 - 130 20 EPA 2008 Mod AS
Frontier Global Sciences Inc The results in his report only apply 10 the samples analyzed in accordance ivth he chain ofcustody document This analytical report must be reproduced in its entirety
Page 14 o261201073 Final Report 0425201]
Liz Siska Project Manager
16
Frontier Global Sciences Inc The ruults in this rechain ofcustody do
~ -lt1-c--~ Liz Siska Project Manager
11720 North Creek Parkway North Suite 400 Bothell WA 98011
Ph 425-686-1996 Fx 425-686-3096
GLOBAL SCIENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1201073-01RE4
Batch J203271 Sequence 2C22005
Preparation ~ IQsed Ve~~el Nitric Oven Qigestion Lab Number F203271-MSMSQ4
Analyte
Beryllium
Sample Concentration
(11gL)
0507
Spike Added (11gL)
20200
MS Concentration
(microgL)
2041
MS Oo
Recovery
985
RecoveryMethod Limits
70 - 130 EPA 2008 Mod
Notes
AS
Sodium 258800 40400 292900 845 70- 130 EPA 2008 Mod AS
Aluminum 529 40400 3956 966 70 - 130 EPA 2008 Mod AS
Chromium 057 40400 430l 106 70- 130 EPA 2008 Mod AS
Manganese 2805 40400 7042 105 70 - 130 EPA 2008 Mod AS
Iron ND 20200 2121 105 70 - 130 EPA 2008 Mod AS
Nickel 979 50500 5112 993 70 l30 EPA 2008 Mod AS
Copper 055 50500 4754 940 70 - 130 EPA 2008 Mod AS
Zinc 040 10100 9074 898 70 - 130 EPA 2008 Mod AS
Arsenic 1030 40400 4317 104 70 130 EPA 2008 Mod AS
Selenium 6340 40400 4688 100 70 - 130 EPA 2008 Mod AS
Molybdenum 1338 20200 338l 101 70 - 130 EPA 2008 Mod AS
Silver ND 20200 1850 916 70 130 EPA 2008 Mod AS
Cadmium 0332 40400 3937 966 70 130 EPA 2008 Mod AS
Antimony 0408 20200 2091 102 70 - 130 EPA 2008 Mod AS
Barium 2397 80800 1056 101 70- 130 EPA 2008 Mod AS
Lead ND IO100 9932 983 70 130 EPA 2008 Mod AS
shy
shy
shy
shy
shy
Analyte
Spike Added (microgL)
MSD Concentration
(microgL)
MSD
Recovery
RPD
Recovery Limits
RPDLimit Method Notes
Beryllium 20200 2007 968 l71 70 - 130 20 EPA 2008 Mod AS Sodium 40400 292600 837 0114 70 130 20 EPA 2008 Mod AS Aluminum 40400 3954 966 00362 70 - 130 20 EPA 2008 Mod AS Chromium 40400 4287 106 0337 70 - 130 20 EPA 2008 Mod AS Manganese 40400 6944 102 140 70 - 130 20 EPA 2008 Mod AS Iron 20200 2077 103 211 70 - 130 20 EPA 2008 Mod AS Nickel 50500 5126 996 0276 70 - 130 20 EPA 2008 Mod AS Copper 50500 4707 931 0997 70 - 130 20 EPA 200 8 Mod AS Zinc 10100 9059 896 0166 70 - 130 20 EPA 2008 Mod AS Arsenic 40400 4299 104 0419 70 - 130 20 EPA 2008 Mod AS Selenium 40400 4682 100 0141 70 - 130 20 EPA 2008 Mod AS Molybdenum 20200 3365 100 0473 70 - 130 20 EPA 2008 Mod AS
shy
port only apply to the sampltts analyzed in accordance with the cument This analytical report must be reproduced in its entirety
Page 5 o26 201073 Final Report 042512012 17
Liz Sia Project Manager
11720 North Creek Parkway North Suite 400 Botheln VA 98011
Ph 425-686-1996 Fx 425-686-3096
CLOBAL SCIENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1201073-01RE4
Batch F203271 Sequence 2c2io2~
Preparation Clo~ed Vessel litric Oven Digestion Lab Number F20327 l -MSMSQ4
Analyte
Spike Added (microgL)
MSD Concentration
(microgL)
MSD
Recovery
Oo
RPD Recovery
Limits RPOLimit Method Notes
Silver 20200 1895 938 242 70 - 130 20 EPA 2008 Mod AS Cadmium 40400 3933 965 0104 70 -130 20 EPA 2008 Mod AS Antimony 20200 2107 102 0736 70- 130 20 EPA 2008 Mod AS
Barium 80800 1058 101 0205 70 - 130 20 EPA 2008 Mod AS
Lead 10100 9877 978 0549 70 - 130 20 EPA 2008 Mod AS
Frontier Global Sciences Inc The results in this report only apply to the samples analyudin accordance with lht chain ofcustody document This analytical report must be reproductd rn ilS enlirtty
Page l6of26 1201073 Final Report Ofn5202 18
l I 720 North Creek Parkway North Suite 400 Bothell WA 980I I
Ph 425-686-1996 Fx 425-686-3096
GLO B AL SCIENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1201073-01RE6
Batch F203314 Sequence 2C25005
Preparation Closed Vessel Nitric Oven Digestion Lab Number F203314-MSMSD2
Sample Spike MS MS Concentration Added Concentration RecoveryAnalyte (microgL) (microgL) (microgL) Recovery Method NotesLimits
Thallium 5563 040400 5875 773 70 - 130 EPA 2008 Mod
Spike MSD MSD Added o Concentration Recovery RPD
RPO Limits Limit Method Notes Analyte (microgL) (microgL) Recovery
Thallium 040400 5880 785 00859 70 - 130 20 EPA 2008 Mod
Frontier Global Sciences Inc 11e results in chis reporc only apply 10 1he samples analyzed in accordance wilh lhe chain ofcustody documenz This analycical report musl be reproduced in ils entirety
Page 17 of26 1201073 Fi11aReport 0412512012
Liz Siska Project Manager
19
11720 North Creek Parkway North Suite 400 Bothell WA 98011
Ph 425-686-1996 Fx 425-686-3096
GLOBAl SCIENC ES
MATRIX SPIKE I MATRIX SPIKE DUPLICATE RECOVERY AND RPO
SOURCE I201073-01RE6
Batch F203314
Preparation Closed Vessel Nitric Oven Digestion
Sequence 2C25005
Lab Number F203314-MSMSD4
Analyte
Sample Concentration
(microgL)
Spike Added (microgL)
MS MS Concentration Oo
(microgL) Recovery Recovery
Limits Method Notes
Thallium 5563 10100 1033 968 70- 130 EPA 2008 Mod AS
Analyte
Spike Added (microgL)
MSD Concentration
(microgL)
MS)) Oo
Recovery
RPD
Recovery Limits
RPD Limit Method Notes
Thallium IO100 1037 97l 0341 70 - 130 20 EPA 2008 Mod AS
Frontier Global Sciences Inc The resulrs in this report only apply to the samples analyzed in accordance with the chain ofcusrody document This analytical report must be reproduced in its entirely
Page 18of26 120073 Final Report 04252012
Liz Siska Project Manager
20
11720 North Creek Parkway North Suite 400 l ~ Bothell WA 980 l l Ph 425-686-1996
FRONTIER Fx 425-686-3096 GLOBAL SCIENCES
LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLICATE
RECOVERY AND RPD
Batch F20 l063 Sequence 2A09010
Preparation BrCI Oxidation Lab Number F201063-BSIBSJ21
LCS Source N ist 1641d
Analyte
Spike Added (ngL)
LCS Concentration
(ngL)
LCS
Recovery Recovery
Limits Method Notes
Mercury 15679 1550 988 80 - 120 EPA I631E
Analyte
Spike Added (ngL)
LCSD Concentration
(ngL)
LCSD Oo
Recovery
RPD Recovery
Limits RPD Limit Method Notes
Mercury 15679 1595 [02 289 80 - 120 24 EPA I631E
Frontier Global Sciences Inc The results in this report only apply to the samples analyzedin accordance with the chain ofcustody document This analytical report must be reproduced in ils entirety
Page 19of26 1201073 Final Report 0425 2012
Liz Siska Project Manager
21
11720 North Creek Parkway North Suite 400 Bothell WA 98011
Ph 425-686-1996 FRONTIER Fx 425-686-3096 GLOBAL SCIENCES
LABORA TORY CONTROL SAMPLE LABO RATORY CONTROL SAMPLE DUPLICATE
RECOVERY AND RPD
Batch F203271 Sequence 2C22005
Preparation Closed Vessel Nitric Oven Digestion Lab Number F203271-BSBSD1
LCS Source Blank Spike
Spike LCS LCS Added Concentration Oo Recovery
Analyte (microgL) (microgL) Recovery Limits Method Notes
Beryllium 20000 l930 965 85 - 115 EPA 2008 Mod
Sodium 50000 499 998 85 - 115 EPA 2008 Mod
Aluminum 15000 1460 973 85 - 115 EPA 2008 Mod
Calcium 15000 1528 102 85 - 115 EPA 2008 Mod
Chromium 70000 657 939 85 - 115 EPA 2008 Mod
Manganese 60000 586 976 85 - 115 EPA 2008 Mod
Iron 50000 4753 951 85 shy 115 EPA 2008 Mod
Nickel 40000 401 100 85 - 115 EPA 2008 Mod
Copper 40000 418 105 85 - 115 EPA 2008 Mod
Zinc 10000 1033 103 85 - 115 EPA 2008 Mod
Arsenic 15000 1437 958 85 - 115 EPA 2008 Mod
Selenium 30000 2966 989 85 - 115 EPA 2008 Mod
Molybdenum 20000 181 905 85 shy 115 EPA 2008 Mod
Silver 15000 1517 101 85 shy 115 EPA 2008 Mod
Cadmium 080000 0781 976 85 - 1lS EPA 2008 Mod
Antimony 080000 0815 102 85 - 115 EPA 2008 Mod
Barium 10000 969 969 85 - 115 EPA 2008 Mod
Lead 15000 1597 106 85 - 115 EPA 2008 Mod
Spike LCSD LCSD Added Concentration Recovery RPO
Analyte (microgL) (microgL) Recovery RPO Limits Limit Method Notes
Beryllium 20000 1949 974 0955 85 - 115 20 EPA 2008 Mod
Sodium 50000 500 100 0216 85 - 115 20 EPA 2008 Mod
Aluminum 15000 1485 990 171 85 - 115 20 EPA 2008 Mod
Calcium 15000 1544 103 103 85 - 115 20 EPA 2008 Mod
Chromium 70000 667 953 148 85 - 115 20 EPA 2008 Mod
Manganese 60000 596 994 175 85 - 115 20 EPA 2008 Mod
Iron 50000 4852 970 206 85 - 115 20 EPA 2008 Mod
Nickel 40000 402 IOI 0246 85 - 115 20 EPA 2008 Mod
Frontier Global Sciences Inc The results in his report only apply to the samples analyzed in accordance wirh the chain ofcustody document This analytical report must be reproduced in iLS entirety
Page 20of26 1201073 Final Report 04252012
Liz Siska Project Manager
22
11720 North Creek Parkway North Suite 400 ~~shy Bothell WA 98011 Ph 425-686-1996~ONTif Fx 425-686-3096
GLOBAL SCIENCES
LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLICATE
RECOVERY AND RPO
Batch F20327 l Sequence 2C22005
Preparation Closed Vessel Nitric Oven Digestion Lab Number F203271-BSBSD 1
LCS Source Blank Spike
Analyte
Spike Added (microgL)
LCSD Concentration
(microgL)
LCSD oo
Recovery
RPO Recovery
Limits RPO Limit Method Notes
Copper
Zinc
Arsenic
Selenium
40000
10000
15000
30000
428
1039
1452
3015
107
104
968
101
224
0570
0977
166
85 - 115
85 - 115
85 - 115
85 - 115
20
20
20
20
EPA 2008 Mod
EPA 2008 Mod
EPA 2008 Mod
EPA 2008 Mod Molybdenum
Silver
20000
15000
182
J502
910
100
0564
103
85 - 115
85 - 115
20
20
EPA 2008 Mod
EPA 2008 Mod Cadmium
Antimony
Barium
Lead
080000
080000
10000
15000
0828
0808
986
1620
103
101
986
108
585
0848
177
142
85 - 115
85 - 115
85 shy 11 S
85 - 115
20
20
20
20
EPA 2008 Mod
EPA 2008 Mod
EPA 2008 Mod
EPA 2008 Mod
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report mus be reproducedin its entirety
Page 2 o26J20J073 Final Report 041252012
Liz Siska Project Manager
23
11720 North Creek Parkway North Suite 400 Bothell WA 980 l l
Ph 425-686-1996FRONT[ER- Fx 425-686-3096 cLosAL SCIEN _CES
LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLICATE
RECOVERY AND RPD
Batch F203314 Sequence 2C25005
Preparation Closed Vessel Nitric Oven Digestion Lab Number F2033 l 4-BSBSD 1
LCS Source Blank Spike
Analyte
Thallium
Spike Added (microgL)
LCS Concentration
(microgL)
LCS 0o
Recovery Recovery
Limits Method
040000 0396 989 85 - 115 EPA 2008 Mod
Notes
Analyte
Spike Added (microgL)
LCSD Concentration
(microgL)
LCSD 0o
Recovery
RPD Recovery
Limits RPO Limit Method Notes
Thallium 040000 0391 978 112 85 - ll5 20 EPA 2008 Mod
Frontier Global Sciences Inc The results in this report only apply to the samples anayed in accordance with the chain ofcustody docwnenJ This analytical report must be reproduced in its entirety
Page 22of26 1201073 Final Report 04252012
Liz Siska Project Manager
24
Liz Siska P roject Manager
11720 North Creek Parkway North Suite 400
~ Bothell WA 98011 Ph 425-686-1996
~JTIEif middot Fx 425-686-3096 GLOBAL SCIENCES
PREPARATION BLANKS
Instrument Hg-17 Sequence 2A09010
Preparation BrCI Oxidation
Lab Sample ID Analyte Found MRL Units Batch Method Notes
F201063-BLK I Mercury -0009 050 ngL F201063 EPA 1631E u F20 I063-BLK2 Mercury -0006 050 ngL F201063 EPA 1631E u F201063-BLK3 Mercury -002 050 ngL F201063 EPA 163IE u F201063-BLK4 Mercury 003 050 ngL F201063 EPA 1631E U QB-04 F201063-BLKS Mercury 011 052 ngL F201063 EPA I631E U QB-06
Frontier Global Sciences Inc The results in this report only apply 10 1he samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Page 23 o26 1201073 Final Repon 04252012 25
Liz Siska Project Manager
11720 North Creek Parkway North Suite 400 Bothell WA 98011
Ph 425-686-1996 FROr~TIER- Fx 425-686-3096 GLOBAL SCIENCES
PREPARATION BLANKS
Instrument ICPMS-6 Sequence 2C22005
Preparation Closed Vessel Nitric Oven Digestion
Lab Sample ID Analyte Found MRL Units Batch Method Notes
F203271-BLK1 Beryllium 000008 0060 microgL F203271 PA 2008 Molt u F20327 1-BLK1 Sodium 2 20 microgL F20327l PA 2008 Moc u F20327I-BLK1 Aluminum -004 40 microgL F203271 PA 2008 Molt u F20327I -BLK1 Calcium 40 microgL F203271 PA 2008 Molt u F203271 -BLK1 Chromium -002 010 microgL F203271 ~A 2008 Molt u F203271-BLKI Manganese 001 010 microgL F203271 PA 2008 Molt u F20327 l -BLK 1 Iron -002 100 microgL F203271 PA 2008 Molt u F203271-BLKI Nickel 0004 010 microgL F203271 PA 2008 Moc u F203271-BLK1 Copper 0003 010 microgL F203271 PA 2008 Moc u F203271-BLK1 Zinc 0007 020 microgL F203271 PA 2008 Moc u F203271-BLK1 Arsenic -006 015 microgL F203271 PA 2008 Moc u F203271-BLK1 Selenium -002 060 microgL F203271 PA 2008 Moc u F203271-BLK1 Molybdenum 001 006 microgL F203271 PA 2008 Molt u F203271-BLK1 Silver -00005 0020 microgL F203271 PA 2008 Molt u F203271-BLKl Cadmium 0004 0020 microgL F203271 PA 2008 Molt u F20327 l-BLKl Antimony 0002 0020 microgL F203271 PA 2008 Molt u F203271-BLKI Barium 001 020 microgL F203271 PA 2008 Molt u F203271-BLKI Lead 0010 0040 microgL F203271 PA 2008 Moc u
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Page 24of26 1201073 Final Report 04252012 26
~
~TIER~ GLOBAL SCIENCES
11720 North Creek Parkway North Suite 400 Bothell WA 980ll
Ph 425-686-1996 Fx 425-686-3096
PREPARATION BLANKS
Instrument JCPMS-3 Sequence 2C25005
Preparation Closed Vessel Nitric Oven Digestion
Lab Sample ID Analyte Found MRL Units Batch Method Notes
F2033I4-BLK1 Thalium 00007 0010 microgL F2033I4 ~PA 2008 Molt u
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Page 25 o26Liz Siska Project Manager 1201073 Final Report
04252012 27
l l 720 North Creek Parkway North Suite 400~Vi-~ Bothell WA 98011 Ph 425-686-1 996~Tlmiddot~ Fx 425-686-3096
G L OBAL SCIENCE S
Notes and Definitions
U Analyte included in the analysis but not detected
QM-02 The MS andor MSD recoveries outside acceptance limits due to spike concentration less than I times the sample concentration The batch was accepted based on LCS and LCSD recoveries within control limits and when analysis permits acceptable AS ASD
QB-06 The blank was preserved to 5 BrCI rather than I The control limit for blanks preserved to greater than 1 BrCl is the preservation percentage multiplied by the MRL
QB-04 The blank was preserved to 2 BrCI rather than l The control limit for blanks preserved to greater than l BrCI is the preservation percentage multiplied by the MRL
FB-1631 Required equipmentfieldfilter blank not submitted by the client The sample has been analyzed according to 163 lE but does not meet 163 lE criteria
AS This MS andor MSD is an analytical spike andor an analytical spike duplicate
DET Analyte Detected
MDL Minimum Detection Limit
MRL Minimum Reporting Limit
ND Analyte Not Detected at or above the reporting limit
wet Sample results reported on a wet weight basis
dry Sample results reported on a dry weight basis
RPO Relative Percent Difference
RSD Relative Standard Deviation
Frontier Global Sciences Inc The lesults i111his reporl only apply to he samples analyzed In accordance with the chain ofcuslody document This analytical report must be reproduced in its entirely
Page 26of26 1201073 Final Report 04252012
Liz Siska Project Manager
28
CHAIN-OF-(USTODY ttECORD Page i of f 106677 _J
BoLD F1ELDS REQUIRED PLEASE C 1RCLE REQUESTED ANALYSIS
SAMPLE ID
middoti-rg -- bull ~rshy~ _- tzir +- lt-ltJ~ lt
SAMPLING
DATeTtME
IF COMPOSITE INDICATE BOTH
START amp FINISH
DATETIME li1J oc -r 111_- _vlt-c_
w Ishyt 0 n
w l w 0 ~ u X -Xmiddot ~ m Ishy lt( lt( 0
I C)
IIXJ JC
~ ~ irlte-t- T_ t- f r-n t I s-11 middott~ c~ J J1~w )(~ )
Trttbull rin K C-~-~ pound1t I 1Jtl~ t20~L lwlJI ishy
middot~ON Mm1x A-Al~ S-SOil GW-GampOUHO WATER SW-SUampfA(f WATER DWmiddotDRIIIKIKlti WATER
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107555
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1 WW-WASTE WATER PmmATIVE H-HCL H-HN01 S-H1SO Na-NaOH H-HEOH -~ --~
PROJECT MANAGER llr middot1 ~Q Aw4---P1V- Het_ r COMPANY t-lo--tm ~ bd i ( I ~j 6 A ADP~SS 91 g~ez tJshy(ITJ ~ STATE fH_ ZIP c3o--
PHONE 22j-((omiddotf EXT ____
fAX--------------------- shyE-MAIL (JbHd-esa e n ta wamp Sm NAME Meccft1lt-1ltk f--g
PROJECT _
OTHEi________STATpound NH MA ME VT
REGULATORY PROGRAM NPDES RGP POTW STORHWATEl OR
GWP OIL FUHD BROWNIIELO OR OTHER----------
Quon PO o2J~-lt1Jpound)
DATE NEEDED _1--1 middot Z=-----shy4 (1-1_ METALS 8 RCRA 13 pp ff MN PB Cu
QAQC REPORTJNGYVEL
A CG) O R
PRESUMPTIVE CERTAINTY
7i2lt_
RECpound1VEO BYRELINQUISHED BY DATE TIME SUSPECTED (OHTAHIHATIOH________
TEHP~ C REPORTING OPTIONS 01HEA METAL------------PRELIHl Yu OR No
DISSOLVED METALS FIELD FllTEREDI YES 110
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IF YH FAX OR POf 7~shy Hom (IE SPECIAL DETECTION LINITl BllLIKGINfO If DlffERrnT)ELECTRONIC OPTIONS zo 1 2 2) le~C1 1 Jc Id sJ 60 6c
1 cf Co
lo FAX pound-MAIL PDF EQUll C jCi (e I rt--111 Ao NiAJrJe middotn th
Ka)Jcr(c C(cdd -ltJ c -l -gtck- z Alt 5e1 Hj
Al l 4_) it fG) 1uJ c(iJoclt-U Sin HISTORY 0Se-d Cim- ~pound rc~L IH t--6
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ImiddotRELINQUISHED BY DATE TIHE RECflVEO BY I FIELD READINGS
eastern analytical inc 2s CHENELL D R1ve IC 0 Nco1to N H 0330 1 I TEL 60J22aos2s 1aoo2a1os2s IFAx 6032284591 j E-MA1t cus-roM111_mV1c~EAILAsscoMJ www1A1LAascoM
----i pmiddotofissionrrl11bomtorymim (WHITE ORIGINAL GREEN PROJECT MANAGER)
shy
Liz Siska Project Manager
11720 North Creek Parkway North Suite 400 Bothell WA 98011
Ph 425-686-1996~ Fx 425-686-3096 CL06AL SCIENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1112278-02
Batch F201063 Sequence 2A09010
Preparation BrCI Oxidation Lab Number F20 l 063-MSMSD2
Sample Spike MS MS
Analyte Concentration
(ogL) Added (ngL)
Concentration (ngL)
Recovery
RecoveryLimits Method Notes
Mercury 761 20400 2786 992 71 125 EPA 1631E
Spike MSD MSD Added Concentration Oo Recovery RPO
Analyte (ngL) (ngL) Recovery RPO Limits Limit Method Notes
Mercury 20400 2837 102 182 71 - 125 24 EPA l631E
shy
Frontier Global Sciences Inc The results in this report only apply to the somples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Page 8 o26 1201073 Final Report 042512012 10
11720 North Creek Parkway North Suite 400 Bothell WA 980 l l
Ph 425-686-1996 ~ Fx 425-686-3096 GLOBAL SCIENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1201029-01
Batch
Preparation
F201063
BrCI Oxidation
Sequence
Lab Number
2A09010
F20 I 063-MSMSD3
Analyte
Mercury
Analyte
Mercury
Sample Spike Concentration Added
(ngL) (ngL)
534 10200
Spike MSD Added Concentration (ngL) (ngL)
10200 1407
MS MS Concentration Recovery
(ngL) Recovery Limits
1558 JOO 7l shy 125
MSD oo Recovery RPD
Recovery RPD Limits Limit
856 102 71 - 125 24
Method
EPA l63lE
Method
EPA 631E
Notes
Notes
Frontier Global Sciences Inc The results in this repon only apply to rhe samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Page 9of26 1201073 Final Report 041252012
Liz Siska Project Manager
1 1
11720 North Creek Parkway North Suite 400 Bothell WA 98011
Ph 425-686-1996 FRONTIER- Fx 425-686-3096 cLosAL SCIENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1201030-02
Batch F20I063 Sequence 2A09010
Preparation BrCI Oxidation Lab Number F201063-MSMSD4
Sample Spike MS MS Concentration Added Concentration RecoveryAnalyte (ngL) (ngL) (ngL) Recovery MethodLimits Notes
Mercury 554 10200 1482 910 71 - 125 EPA I631E
Spike MSD MSD Oo Added Concentratio11 Recovery RPD
RPD Limits Limit Method Analyte (ngL) (ngL) Recovery Notes
Mercury 10200 1461 890 140 71 - 125 24 EPA 163IE
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed m accordance with the chain ofcus1ody document This anayt(ca repon must be reproduced in itr entirety
Page lOo26Liz Siska Project Manager 1201073 Final Report
041252012 12
I 1720 North Creek Parkway North Suite 400 Bothe I I WA 98011
Ph 425-686-1996 ~ Fx 425-686-3096 GLOBAL SCIENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1201073-01RE3
Batch F20327l Sequence 2C22005
Prcpa ration ((01ed Vessel ~ itric Oven Digestion Lab Number F203271-MSMSD 1
Analyte
Sample Concentration
(microgL)
Spike Added (microgL)
MS Concentration
(microgL)
MS Oo
Recovery Recovery
Method Limits Notes
Calcium 5013000 15150 4802000 -13900 70- 130 EPA 2008 Mod QM-02
Analyte
Spike Added (microgL)
MSD Concentration
(microgL)
MSD ~o
Recovery
Oo
RPD Recovery
Limits RPDLimit Method Notes
Calcium 15150 4943000 -4600 289 70 - 130 20 EPA 2008 Mod QM-02
Frontier Global Sciences Inc The results in this report only apply to the samples analyud inaccordance with the chain ofcustody document 17is analyticol report must be reproduced in its entirety
Page lI o16 1101073 Final Report 04152012
Liz Siska Project Manager
13
l l 720 North Creek Parkway North Suite 400 Bothell WA 98011
Ph 425-686-1996FRONTIER Fx 425-686-3096 GLOBAL SCIENCES
MATRIX SPIKE I MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1201073-01RE4
Batch F203271 Sequence 2C22005
Preparation Closed Vessel Nitric Oven Digestion Lab Number F203271-MSMSD2
Sample Spike MS MS Concentration Added Concentration Oo RecoveryAnalyte (microgL) (microgL) (microgL) Recovery Method Limits Notes
Beryllium 0507 20200 2442 958 70 - 130 EPA 2008 Mod Sodium 258800 50500 257700 -213 70 -130 EPA 2008 Mod QM-02 Aluminum 529 15150 2023 986 70 - 130 EPA 2008 Mod Chromium 057 70700 804 106 70 - 130 EPA 2008 Mod Manganese 2805 60600 2834 476 70 - 130 EPA 2008 Mod QM-02 Iron ND 50500 5200 103 70 130 EPA 2008 Mod Nickel 979 40400 141 l 107 70- 130 EPA 2008 Mod Copper 055 40400 434 939 70 - 130 EPA 2008 Mod Zinc 040 10100 842 794 70 - 130 EPA 2008 Mod Arsenic 1030 15150 2418 916 70 - 130 EPA 2008 Mod Selenium 6340 30300 8973 869 70 130 EPA 2008 Mod Molybdenum 1338 20200 1367 142 70 130 EPA 2008 Mod QM-02 Silver ND 15150 1388 916 70 - 130 EPA 2008 Mod Cadmium 0332 080800 1105 middot956 70 - 130 EPA 2008 Mod Antimony 0408 080800 1259 105 70- 130 EPA 2008 Mod Barium 2397 10100 2495 968 70 - 130 EPA 2008 Mod Lead ND 15150 1542 102 70 130 EPA 2008 Mod
shy
shy
shy
shy
Analyte
Spike Added (microgL)
MSD Concentration
(microgL)
MSD Oo
Recovery
Oo
RPD Recovery
Limits RPD Limit Method Notes
Beryllium
Sodium
Aluminum
Chromium
Manganese
Iron
Nickel
Copper
Zinc
Arsenic
Selenium
Molybdenum
20200
50500
15150
7Q700
60600
50500
40400
40400
10100
15150
30300
20200
2561
257100
2034
773
2852
5187
1381
419
916
2225
9400
1366
102
-336
993
101 769
103
995
902
868
789
101
137
474
0243
0564
385
0625
0242
213
347
849
831
464
00771
70 - 130
70 bull 130 70 - 130
70 - 130
70 - 130
70 - 130
70 - 130
70 - 130
70 - 130
70 bull 130 70 - 130
70 - 130
20
20
20
20
20
20
20
20
20
20
20
20
EPA 2008 Mod
EPA 2008 Mod
EPA 2008 Mod
EPA 2008 Mod
EPA 2008 Mod
EPA 2008 Mod
EPA 2008 Mod
EPA 2008 Mod
EPA 2008 Mod
EPA 2008 Mod
EPA 2008 Mod
EPA 2008 Mod
QM-02
QM-02
Frontier G lobal Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
--f_~ --~~~-~ -middot middot Page 12 o261201073 Final Report 041252012
Liz Siska Project Manager
14
11720 North Creek Parkway North Suite 400
~ Bothell WA 98011
~TIEmiddot Ph 425-686-1996 Fx 425-686-3096
GLOB11L SCIENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPO
SOURCE 1201073-01RE4
Batch F203271 Sequence 2C22005
Preparation ~lo~ed Vessel Nitric Oven Digestion Lab Number F20327 I-MSMSD2
Spike MSD MSD Added Concentration Oo Recovery RPO
Analyte (microgL) (microgL) Recovery RPD Limits Limit Method Notes
Silver 15150 1387 915 00874 70 - 130 20 EPA 2008 Mod Cadmium 080800 1061 902 403 70 - 130 20 EPA 200amp Mod Antimony 080800 1274 107 l2l 70 - 130 20 EPA 2008 Mod Barium 10100 2514 )16 0781 70 - 130 20 EPA 200amp Mod Lead 15150 1534 101 0525 70 shy 130 20 EPA 2008 Mod
Frontier Global Sciences Inc The results in this report only apply to 1he samples analyzed in accordance wiih the chain ofcustody document This analytical repo1 must be reproduced in ils entirety
Page 13 o26Liz Siska Project Manager 1201073 Final Reporl
04252012 15
11720 North Creek Parkway North Suite 400
~ Bothell WA 98011 Ph 425-686-I996
~RONTIER~ Fx 425-686-3096 GLOBAL SCIEN C ES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1201073-01RE3
Batch F203271 Sequence 2~22005
Preparation Closed Vessel Nitric Oven Digestion Lab Number F20327 I-MSMSD3
Sample Spike MS MS
Analyte Concentration
(microgL) Added (microgL)
Concentration (microgL) Recovery
Recovery Limits Method Notes
Calcium 5013000 10100000 15120000 100 70- 130 EPA 2008 Mod AS
Spike MSD MSD Added Concentration o Oo Recovery RPD
Analyte (microgL) (microgL) Recovery RPD Limits Limit Method Notes
Calcium 10100000 16140000 llO 653 70 - 130 20 EPA 2008 Mod AS
Frontier Global Sciences Inc The results in his report only apply 10 the samples analyzed in accordance ivth he chain ofcustody document This analytical report must be reproduced in its entirety
Page 14 o261201073 Final Report 0425201]
Liz Siska Project Manager
16
Frontier Global Sciences Inc The ruults in this rechain ofcustody do
~ -lt1-c--~ Liz Siska Project Manager
11720 North Creek Parkway North Suite 400 Bothell WA 98011
Ph 425-686-1996 Fx 425-686-3096
GLOBAL SCIENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1201073-01RE4
Batch J203271 Sequence 2C22005
Preparation ~ IQsed Ve~~el Nitric Oven Qigestion Lab Number F203271-MSMSQ4
Analyte
Beryllium
Sample Concentration
(11gL)
0507
Spike Added (11gL)
20200
MS Concentration
(microgL)
2041
MS Oo
Recovery
985
RecoveryMethod Limits
70 - 130 EPA 2008 Mod
Notes
AS
Sodium 258800 40400 292900 845 70- 130 EPA 2008 Mod AS
Aluminum 529 40400 3956 966 70 - 130 EPA 2008 Mod AS
Chromium 057 40400 430l 106 70- 130 EPA 2008 Mod AS
Manganese 2805 40400 7042 105 70 - 130 EPA 2008 Mod AS
Iron ND 20200 2121 105 70 - 130 EPA 2008 Mod AS
Nickel 979 50500 5112 993 70 l30 EPA 2008 Mod AS
Copper 055 50500 4754 940 70 - 130 EPA 2008 Mod AS
Zinc 040 10100 9074 898 70 - 130 EPA 2008 Mod AS
Arsenic 1030 40400 4317 104 70 130 EPA 2008 Mod AS
Selenium 6340 40400 4688 100 70 - 130 EPA 2008 Mod AS
Molybdenum 1338 20200 338l 101 70 - 130 EPA 2008 Mod AS
Silver ND 20200 1850 916 70 130 EPA 2008 Mod AS
Cadmium 0332 40400 3937 966 70 130 EPA 2008 Mod AS
Antimony 0408 20200 2091 102 70 - 130 EPA 2008 Mod AS
Barium 2397 80800 1056 101 70- 130 EPA 2008 Mod AS
Lead ND IO100 9932 983 70 130 EPA 2008 Mod AS
shy
shy
shy
shy
shy
Analyte
Spike Added (microgL)
MSD Concentration
(microgL)
MSD
Recovery
RPD
Recovery Limits
RPDLimit Method Notes
Beryllium 20200 2007 968 l71 70 - 130 20 EPA 2008 Mod AS Sodium 40400 292600 837 0114 70 130 20 EPA 2008 Mod AS Aluminum 40400 3954 966 00362 70 - 130 20 EPA 2008 Mod AS Chromium 40400 4287 106 0337 70 - 130 20 EPA 2008 Mod AS Manganese 40400 6944 102 140 70 - 130 20 EPA 2008 Mod AS Iron 20200 2077 103 211 70 - 130 20 EPA 2008 Mod AS Nickel 50500 5126 996 0276 70 - 130 20 EPA 2008 Mod AS Copper 50500 4707 931 0997 70 - 130 20 EPA 200 8 Mod AS Zinc 10100 9059 896 0166 70 - 130 20 EPA 2008 Mod AS Arsenic 40400 4299 104 0419 70 - 130 20 EPA 2008 Mod AS Selenium 40400 4682 100 0141 70 - 130 20 EPA 2008 Mod AS Molybdenum 20200 3365 100 0473 70 - 130 20 EPA 2008 Mod AS
shy
port only apply to the sampltts analyzed in accordance with the cument This analytical report must be reproduced in its entirety
Page 5 o26 201073 Final Report 042512012 17
Liz Sia Project Manager
11720 North Creek Parkway North Suite 400 Botheln VA 98011
Ph 425-686-1996 Fx 425-686-3096
CLOBAL SCIENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1201073-01RE4
Batch F203271 Sequence 2c2io2~
Preparation Clo~ed Vessel litric Oven Digestion Lab Number F20327 l -MSMSQ4
Analyte
Spike Added (microgL)
MSD Concentration
(microgL)
MSD
Recovery
Oo
RPD Recovery
Limits RPOLimit Method Notes
Silver 20200 1895 938 242 70 - 130 20 EPA 2008 Mod AS Cadmium 40400 3933 965 0104 70 -130 20 EPA 2008 Mod AS Antimony 20200 2107 102 0736 70- 130 20 EPA 2008 Mod AS
Barium 80800 1058 101 0205 70 - 130 20 EPA 2008 Mod AS
Lead 10100 9877 978 0549 70 - 130 20 EPA 2008 Mod AS
Frontier Global Sciences Inc The results in this report only apply to the samples analyudin accordance with lht chain ofcustody document This analytical report must be reproductd rn ilS enlirtty
Page l6of26 1201073 Final Report Ofn5202 18
l I 720 North Creek Parkway North Suite 400 Bothell WA 980I I
Ph 425-686-1996 Fx 425-686-3096
GLO B AL SCIENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1201073-01RE6
Batch F203314 Sequence 2C25005
Preparation Closed Vessel Nitric Oven Digestion Lab Number F203314-MSMSD2
Sample Spike MS MS Concentration Added Concentration RecoveryAnalyte (microgL) (microgL) (microgL) Recovery Method NotesLimits
Thallium 5563 040400 5875 773 70 - 130 EPA 2008 Mod
Spike MSD MSD Added o Concentration Recovery RPD
RPO Limits Limit Method Notes Analyte (microgL) (microgL) Recovery
Thallium 040400 5880 785 00859 70 - 130 20 EPA 2008 Mod
Frontier Global Sciences Inc 11e results in chis reporc only apply 10 1he samples analyzed in accordance wilh lhe chain ofcustody documenz This analycical report musl be reproduced in ils entirety
Page 17 of26 1201073 Fi11aReport 0412512012
Liz Siska Project Manager
19
11720 North Creek Parkway North Suite 400 Bothell WA 98011
Ph 425-686-1996 Fx 425-686-3096
GLOBAl SCIENC ES
MATRIX SPIKE I MATRIX SPIKE DUPLICATE RECOVERY AND RPO
SOURCE I201073-01RE6
Batch F203314
Preparation Closed Vessel Nitric Oven Digestion
Sequence 2C25005
Lab Number F203314-MSMSD4
Analyte
Sample Concentration
(microgL)
Spike Added (microgL)
MS MS Concentration Oo
(microgL) Recovery Recovery
Limits Method Notes
Thallium 5563 10100 1033 968 70- 130 EPA 2008 Mod AS
Analyte
Spike Added (microgL)
MSD Concentration
(microgL)
MS)) Oo
Recovery
RPD
Recovery Limits
RPD Limit Method Notes
Thallium IO100 1037 97l 0341 70 - 130 20 EPA 2008 Mod AS
Frontier Global Sciences Inc The resulrs in this report only apply to the samples analyzed in accordance with the chain ofcusrody document This analytical report must be reproduced in its entirely
Page 18of26 120073 Final Report 04252012
Liz Siska Project Manager
20
11720 North Creek Parkway North Suite 400 l ~ Bothell WA 980 l l Ph 425-686-1996
FRONTIER Fx 425-686-3096 GLOBAL SCIENCES
LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLICATE
RECOVERY AND RPD
Batch F20 l063 Sequence 2A09010
Preparation BrCI Oxidation Lab Number F201063-BSIBSJ21
LCS Source N ist 1641d
Analyte
Spike Added (ngL)
LCS Concentration
(ngL)
LCS
Recovery Recovery
Limits Method Notes
Mercury 15679 1550 988 80 - 120 EPA I631E
Analyte
Spike Added (ngL)
LCSD Concentration
(ngL)
LCSD Oo
Recovery
RPD Recovery
Limits RPD Limit Method Notes
Mercury 15679 1595 [02 289 80 - 120 24 EPA I631E
Frontier Global Sciences Inc The results in this report only apply to the samples analyzedin accordance with the chain ofcustody document This analytical report must be reproduced in ils entirety
Page 19of26 1201073 Final Report 0425 2012
Liz Siska Project Manager
21
11720 North Creek Parkway North Suite 400 Bothell WA 98011
Ph 425-686-1996 FRONTIER Fx 425-686-3096 GLOBAL SCIENCES
LABORA TORY CONTROL SAMPLE LABO RATORY CONTROL SAMPLE DUPLICATE
RECOVERY AND RPD
Batch F203271 Sequence 2C22005
Preparation Closed Vessel Nitric Oven Digestion Lab Number F203271-BSBSD1
LCS Source Blank Spike
Spike LCS LCS Added Concentration Oo Recovery
Analyte (microgL) (microgL) Recovery Limits Method Notes
Beryllium 20000 l930 965 85 - 115 EPA 2008 Mod
Sodium 50000 499 998 85 - 115 EPA 2008 Mod
Aluminum 15000 1460 973 85 - 115 EPA 2008 Mod
Calcium 15000 1528 102 85 - 115 EPA 2008 Mod
Chromium 70000 657 939 85 - 115 EPA 2008 Mod
Manganese 60000 586 976 85 - 115 EPA 2008 Mod
Iron 50000 4753 951 85 shy 115 EPA 2008 Mod
Nickel 40000 401 100 85 - 115 EPA 2008 Mod
Copper 40000 418 105 85 - 115 EPA 2008 Mod
Zinc 10000 1033 103 85 - 115 EPA 2008 Mod
Arsenic 15000 1437 958 85 - 115 EPA 2008 Mod
Selenium 30000 2966 989 85 - 115 EPA 2008 Mod
Molybdenum 20000 181 905 85 shy 115 EPA 2008 Mod
Silver 15000 1517 101 85 shy 115 EPA 2008 Mod
Cadmium 080000 0781 976 85 - 1lS EPA 2008 Mod
Antimony 080000 0815 102 85 - 115 EPA 2008 Mod
Barium 10000 969 969 85 - 115 EPA 2008 Mod
Lead 15000 1597 106 85 - 115 EPA 2008 Mod
Spike LCSD LCSD Added Concentration Recovery RPO
Analyte (microgL) (microgL) Recovery RPO Limits Limit Method Notes
Beryllium 20000 1949 974 0955 85 - 115 20 EPA 2008 Mod
Sodium 50000 500 100 0216 85 - 115 20 EPA 2008 Mod
Aluminum 15000 1485 990 171 85 - 115 20 EPA 2008 Mod
Calcium 15000 1544 103 103 85 - 115 20 EPA 2008 Mod
Chromium 70000 667 953 148 85 - 115 20 EPA 2008 Mod
Manganese 60000 596 994 175 85 - 115 20 EPA 2008 Mod
Iron 50000 4852 970 206 85 - 115 20 EPA 2008 Mod
Nickel 40000 402 IOI 0246 85 - 115 20 EPA 2008 Mod
Frontier Global Sciences Inc The results in his report only apply to the samples analyzed in accordance wirh the chain ofcustody document This analytical report must be reproduced in iLS entirety
Page 20of26 1201073 Final Report 04252012
Liz Siska Project Manager
22
11720 North Creek Parkway North Suite 400 ~~shy Bothell WA 98011 Ph 425-686-1996~ONTif Fx 425-686-3096
GLOBAL SCIENCES
LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLICATE
RECOVERY AND RPO
Batch F20327 l Sequence 2C22005
Preparation Closed Vessel Nitric Oven Digestion Lab Number F203271-BSBSD 1
LCS Source Blank Spike
Analyte
Spike Added (microgL)
LCSD Concentration
(microgL)
LCSD oo
Recovery
RPO Recovery
Limits RPO Limit Method Notes
Copper
Zinc
Arsenic
Selenium
40000
10000
15000
30000
428
1039
1452
3015
107
104
968
101
224
0570
0977
166
85 - 115
85 - 115
85 - 115
85 - 115
20
20
20
20
EPA 2008 Mod
EPA 2008 Mod
EPA 2008 Mod
EPA 2008 Mod Molybdenum
Silver
20000
15000
182
J502
910
100
0564
103
85 - 115
85 - 115
20
20
EPA 2008 Mod
EPA 2008 Mod Cadmium
Antimony
Barium
Lead
080000
080000
10000
15000
0828
0808
986
1620
103
101
986
108
585
0848
177
142
85 - 115
85 - 115
85 shy 11 S
85 - 115
20
20
20
20
EPA 2008 Mod
EPA 2008 Mod
EPA 2008 Mod
EPA 2008 Mod
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report mus be reproducedin its entirety
Page 2 o26J20J073 Final Report 041252012
Liz Siska Project Manager
23
11720 North Creek Parkway North Suite 400 Bothell WA 980 l l
Ph 425-686-1996FRONT[ER- Fx 425-686-3096 cLosAL SCIEN _CES
LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLICATE
RECOVERY AND RPD
Batch F203314 Sequence 2C25005
Preparation Closed Vessel Nitric Oven Digestion Lab Number F2033 l 4-BSBSD 1
LCS Source Blank Spike
Analyte
Thallium
Spike Added (microgL)
LCS Concentration
(microgL)
LCS 0o
Recovery Recovery
Limits Method
040000 0396 989 85 - 115 EPA 2008 Mod
Notes
Analyte
Spike Added (microgL)
LCSD Concentration
(microgL)
LCSD 0o
Recovery
RPD Recovery
Limits RPO Limit Method Notes
Thallium 040000 0391 978 112 85 - ll5 20 EPA 2008 Mod
Frontier Global Sciences Inc The results in this report only apply to the samples anayed in accordance with the chain ofcustody docwnenJ This analytical report must be reproduced in its entirety
Page 22of26 1201073 Final Report 04252012
Liz Siska Project Manager
24
Liz Siska P roject Manager
11720 North Creek Parkway North Suite 400
~ Bothell WA 98011 Ph 425-686-1996
~JTIEif middot Fx 425-686-3096 GLOBAL SCIENCES
PREPARATION BLANKS
Instrument Hg-17 Sequence 2A09010
Preparation BrCI Oxidation
Lab Sample ID Analyte Found MRL Units Batch Method Notes
F201063-BLK I Mercury -0009 050 ngL F201063 EPA 1631E u F20 I063-BLK2 Mercury -0006 050 ngL F201063 EPA 1631E u F201063-BLK3 Mercury -002 050 ngL F201063 EPA 163IE u F201063-BLK4 Mercury 003 050 ngL F201063 EPA 1631E U QB-04 F201063-BLKS Mercury 011 052 ngL F201063 EPA I631E U QB-06
Frontier Global Sciences Inc The results in this report only apply 10 1he samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Page 23 o26 1201073 Final Repon 04252012 25
Liz Siska Project Manager
11720 North Creek Parkway North Suite 400 Bothell WA 98011
Ph 425-686-1996 FROr~TIER- Fx 425-686-3096 GLOBAL SCIENCES
PREPARATION BLANKS
Instrument ICPMS-6 Sequence 2C22005
Preparation Closed Vessel Nitric Oven Digestion
Lab Sample ID Analyte Found MRL Units Batch Method Notes
F203271-BLK1 Beryllium 000008 0060 microgL F203271 PA 2008 Molt u F20327 1-BLK1 Sodium 2 20 microgL F20327l PA 2008 Moc u F20327I-BLK1 Aluminum -004 40 microgL F203271 PA 2008 Molt u F20327I -BLK1 Calcium 40 microgL F203271 PA 2008 Molt u F203271 -BLK1 Chromium -002 010 microgL F203271 ~A 2008 Molt u F203271-BLKI Manganese 001 010 microgL F203271 PA 2008 Molt u F20327 l -BLK 1 Iron -002 100 microgL F203271 PA 2008 Molt u F203271-BLKI Nickel 0004 010 microgL F203271 PA 2008 Moc u F203271-BLK1 Copper 0003 010 microgL F203271 PA 2008 Moc u F203271-BLK1 Zinc 0007 020 microgL F203271 PA 2008 Moc u F203271-BLK1 Arsenic -006 015 microgL F203271 PA 2008 Moc u F203271-BLK1 Selenium -002 060 microgL F203271 PA 2008 Moc u F203271-BLK1 Molybdenum 001 006 microgL F203271 PA 2008 Molt u F203271-BLK1 Silver -00005 0020 microgL F203271 PA 2008 Molt u F203271-BLKl Cadmium 0004 0020 microgL F203271 PA 2008 Molt u F20327 l-BLKl Antimony 0002 0020 microgL F203271 PA 2008 Molt u F203271-BLKI Barium 001 020 microgL F203271 PA 2008 Molt u F203271-BLKI Lead 0010 0040 microgL F203271 PA 2008 Moc u
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Page 24of26 1201073 Final Report 04252012 26
~
~TIER~ GLOBAL SCIENCES
11720 North Creek Parkway North Suite 400 Bothell WA 980ll
Ph 425-686-1996 Fx 425-686-3096
PREPARATION BLANKS
Instrument JCPMS-3 Sequence 2C25005
Preparation Closed Vessel Nitric Oven Digestion
Lab Sample ID Analyte Found MRL Units Batch Method Notes
F2033I4-BLK1 Thalium 00007 0010 microgL F2033I4 ~PA 2008 Molt u
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Page 25 o26Liz Siska Project Manager 1201073 Final Report
04252012 27
l l 720 North Creek Parkway North Suite 400~Vi-~ Bothell WA 98011 Ph 425-686-1 996~Tlmiddot~ Fx 425-686-3096
G L OBAL SCIENCE S
Notes and Definitions
U Analyte included in the analysis but not detected
QM-02 The MS andor MSD recoveries outside acceptance limits due to spike concentration less than I times the sample concentration The batch was accepted based on LCS and LCSD recoveries within control limits and when analysis permits acceptable AS ASD
QB-06 The blank was preserved to 5 BrCI rather than I The control limit for blanks preserved to greater than 1 BrCl is the preservation percentage multiplied by the MRL
QB-04 The blank was preserved to 2 BrCI rather than l The control limit for blanks preserved to greater than l BrCI is the preservation percentage multiplied by the MRL
FB-1631 Required equipmentfieldfilter blank not submitted by the client The sample has been analyzed according to 163 lE but does not meet 163 lE criteria
AS This MS andor MSD is an analytical spike andor an analytical spike duplicate
DET Analyte Detected
MDL Minimum Detection Limit
MRL Minimum Reporting Limit
ND Analyte Not Detected at or above the reporting limit
wet Sample results reported on a wet weight basis
dry Sample results reported on a dry weight basis
RPO Relative Percent Difference
RSD Relative Standard Deviation
Frontier Global Sciences Inc The lesults i111his reporl only apply to he samples analyzed In accordance with the chain ofcuslody document This analytical report must be reproduced in its entirely
Page 26of26 1201073 Final Report 04252012
Liz Siska Project Manager
28
CHAIN-OF-(USTODY ttECORD Page i of f 106677 _J
BoLD F1ELDS REQUIRED PLEASE C 1RCLE REQUESTED ANALYSIS
SAMPLE ID
middoti-rg -- bull ~rshy~ _- tzir +- lt-ltJ~ lt
SAMPLING
DATeTtME
IF COMPOSITE INDICATE BOTH
START amp FINISH
DATETIME li1J oc -r 111_- _vlt-c_
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Trttbull rin K C-~-~ pound1t I 1Jtl~ t20~L lwlJI ishy
middot~ON Mm1x A-Al~ S-SOil GW-GampOUHO WATER SW-SUampfA(f WATER DWmiddotDRIIIKIKlti WATER
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1 WW-WASTE WATER PmmATIVE H-HCL H-HN01 S-H1SO Na-NaOH H-HEOH -~ --~
PROJECT MANAGER llr middot1 ~Q Aw4---P1V- Het_ r COMPANY t-lo--tm ~ bd i ( I ~j 6 A ADP~SS 91 g~ez tJshy(ITJ ~ STATE fH_ ZIP c3o--
PHONE 22j-((omiddotf EXT ____
fAX--------------------- shyE-MAIL (JbHd-esa e n ta wamp Sm NAME Meccft1lt-1ltk f--g
PROJECT _
OTHEi________STATpound NH MA ME VT
REGULATORY PROGRAM NPDES RGP POTW STORHWATEl OR
GWP OIL FUHD BROWNIIELO OR OTHER----------
Quon PO o2J~-lt1Jpound)
DATE NEEDED _1--1 middot Z=-----shy4 (1-1_ METALS 8 RCRA 13 pp ff MN PB Cu
QAQC REPORTJNGYVEL
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PRESUMPTIVE CERTAINTY
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RECpound1VEO BYRELINQUISHED BY DATE TIME SUSPECTED (OHTAHIHATIOH________
TEHP~ C REPORTING OPTIONS 01HEA METAL------------PRELIHl Yu OR No
DISSOLVED METALS FIELD FllTEREDI YES 110
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IF YH FAX OR POf 7~shy Hom (IE SPECIAL DETECTION LINITl BllLIKGINfO If DlffERrnT)ELECTRONIC OPTIONS zo 1 2 2) le~C1 1 Jc Id sJ 60 6c
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ImiddotRELINQUISHED BY DATE TIHE RECflVEO BY I FIELD READINGS
eastern analytical inc 2s CHENELL D R1ve IC 0 Nco1to N H 0330 1 I TEL 60J22aos2s 1aoo2a1os2s IFAx 6032284591 j E-MA1t cus-roM111_mV1c~EAILAsscoMJ www1A1LAascoM
----i pmiddotofissionrrl11bomtorymim (WHITE ORIGINAL GREEN PROJECT MANAGER)
shy
11720 North Creek Parkway North Suite 400 Bothell WA 980 l l
Ph 425-686-1996 ~ Fx 425-686-3096 GLOBAL SCIENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1201029-01
Batch
Preparation
F201063
BrCI Oxidation
Sequence
Lab Number
2A09010
F20 I 063-MSMSD3
Analyte
Mercury
Analyte
Mercury
Sample Spike Concentration Added
(ngL) (ngL)
534 10200
Spike MSD Added Concentration (ngL) (ngL)
10200 1407
MS MS Concentration Recovery
(ngL) Recovery Limits
1558 JOO 7l shy 125
MSD oo Recovery RPD
Recovery RPD Limits Limit
856 102 71 - 125 24
Method
EPA l63lE
Method
EPA 631E
Notes
Notes
Frontier Global Sciences Inc The results in this repon only apply to rhe samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Page 9of26 1201073 Final Report 041252012
Liz Siska Project Manager
1 1
11720 North Creek Parkway North Suite 400 Bothell WA 98011
Ph 425-686-1996 FRONTIER- Fx 425-686-3096 cLosAL SCIENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1201030-02
Batch F20I063 Sequence 2A09010
Preparation BrCI Oxidation Lab Number F201063-MSMSD4
Sample Spike MS MS Concentration Added Concentration RecoveryAnalyte (ngL) (ngL) (ngL) Recovery MethodLimits Notes
Mercury 554 10200 1482 910 71 - 125 EPA I631E
Spike MSD MSD Oo Added Concentratio11 Recovery RPD
RPD Limits Limit Method Analyte (ngL) (ngL) Recovery Notes
Mercury 10200 1461 890 140 71 - 125 24 EPA 163IE
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed m accordance with the chain ofcus1ody document This anayt(ca repon must be reproduced in itr entirety
Page lOo26Liz Siska Project Manager 1201073 Final Report
041252012 12
I 1720 North Creek Parkway North Suite 400 Bothe I I WA 98011
Ph 425-686-1996 ~ Fx 425-686-3096 GLOBAL SCIENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1201073-01RE3
Batch F20327l Sequence 2C22005
Prcpa ration ((01ed Vessel ~ itric Oven Digestion Lab Number F203271-MSMSD 1
Analyte
Sample Concentration
(microgL)
Spike Added (microgL)
MS Concentration
(microgL)
MS Oo
Recovery Recovery
Method Limits Notes
Calcium 5013000 15150 4802000 -13900 70- 130 EPA 2008 Mod QM-02
Analyte
Spike Added (microgL)
MSD Concentration
(microgL)
MSD ~o
Recovery
Oo
RPD Recovery
Limits RPDLimit Method Notes
Calcium 15150 4943000 -4600 289 70 - 130 20 EPA 2008 Mod QM-02
Frontier Global Sciences Inc The results in this report only apply to the samples analyud inaccordance with the chain ofcustody document 17is analyticol report must be reproduced in its entirety
Page lI o16 1101073 Final Report 04152012
Liz Siska Project Manager
13
l l 720 North Creek Parkway North Suite 400 Bothell WA 98011
Ph 425-686-1996FRONTIER Fx 425-686-3096 GLOBAL SCIENCES
MATRIX SPIKE I MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1201073-01RE4
Batch F203271 Sequence 2C22005
Preparation Closed Vessel Nitric Oven Digestion Lab Number F203271-MSMSD2
Sample Spike MS MS Concentration Added Concentration Oo RecoveryAnalyte (microgL) (microgL) (microgL) Recovery Method Limits Notes
Beryllium 0507 20200 2442 958 70 - 130 EPA 2008 Mod Sodium 258800 50500 257700 -213 70 -130 EPA 2008 Mod QM-02 Aluminum 529 15150 2023 986 70 - 130 EPA 2008 Mod Chromium 057 70700 804 106 70 - 130 EPA 2008 Mod Manganese 2805 60600 2834 476 70 - 130 EPA 2008 Mod QM-02 Iron ND 50500 5200 103 70 130 EPA 2008 Mod Nickel 979 40400 141 l 107 70- 130 EPA 2008 Mod Copper 055 40400 434 939 70 - 130 EPA 2008 Mod Zinc 040 10100 842 794 70 - 130 EPA 2008 Mod Arsenic 1030 15150 2418 916 70 - 130 EPA 2008 Mod Selenium 6340 30300 8973 869 70 130 EPA 2008 Mod Molybdenum 1338 20200 1367 142 70 130 EPA 2008 Mod QM-02 Silver ND 15150 1388 916 70 - 130 EPA 2008 Mod Cadmium 0332 080800 1105 middot956 70 - 130 EPA 2008 Mod Antimony 0408 080800 1259 105 70- 130 EPA 2008 Mod Barium 2397 10100 2495 968 70 - 130 EPA 2008 Mod Lead ND 15150 1542 102 70 130 EPA 2008 Mod
shy
shy
shy
shy
Analyte
Spike Added (microgL)
MSD Concentration
(microgL)
MSD Oo
Recovery
Oo
RPD Recovery
Limits RPD Limit Method Notes
Beryllium
Sodium
Aluminum
Chromium
Manganese
Iron
Nickel
Copper
Zinc
Arsenic
Selenium
Molybdenum
20200
50500
15150
7Q700
60600
50500
40400
40400
10100
15150
30300
20200
2561
257100
2034
773
2852
5187
1381
419
916
2225
9400
1366
102
-336
993
101 769
103
995
902
868
789
101
137
474
0243
0564
385
0625
0242
213
347
849
831
464
00771
70 - 130
70 bull 130 70 - 130
70 - 130
70 - 130
70 - 130
70 - 130
70 - 130
70 - 130
70 bull 130 70 - 130
70 - 130
20
20
20
20
20
20
20
20
20
20
20
20
EPA 2008 Mod
EPA 2008 Mod
EPA 2008 Mod
EPA 2008 Mod
EPA 2008 Mod
EPA 2008 Mod
EPA 2008 Mod
EPA 2008 Mod
EPA 2008 Mod
EPA 2008 Mod
EPA 2008 Mod
EPA 2008 Mod
QM-02
QM-02
Frontier G lobal Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
--f_~ --~~~-~ -middot middot Page 12 o261201073 Final Report 041252012
Liz Siska Project Manager
14
11720 North Creek Parkway North Suite 400
~ Bothell WA 98011
~TIEmiddot Ph 425-686-1996 Fx 425-686-3096
GLOB11L SCIENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPO
SOURCE 1201073-01RE4
Batch F203271 Sequence 2C22005
Preparation ~lo~ed Vessel Nitric Oven Digestion Lab Number F20327 I-MSMSD2
Spike MSD MSD Added Concentration Oo Recovery RPO
Analyte (microgL) (microgL) Recovery RPD Limits Limit Method Notes
Silver 15150 1387 915 00874 70 - 130 20 EPA 2008 Mod Cadmium 080800 1061 902 403 70 - 130 20 EPA 200amp Mod Antimony 080800 1274 107 l2l 70 - 130 20 EPA 2008 Mod Barium 10100 2514 )16 0781 70 - 130 20 EPA 200amp Mod Lead 15150 1534 101 0525 70 shy 130 20 EPA 2008 Mod
Frontier Global Sciences Inc The results in this report only apply to 1he samples analyzed in accordance wiih the chain ofcustody document This analytical repo1 must be reproduced in ils entirety
Page 13 o26Liz Siska Project Manager 1201073 Final Reporl
04252012 15
11720 North Creek Parkway North Suite 400
~ Bothell WA 98011 Ph 425-686-I996
~RONTIER~ Fx 425-686-3096 GLOBAL SCIEN C ES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1201073-01RE3
Batch F203271 Sequence 2~22005
Preparation Closed Vessel Nitric Oven Digestion Lab Number F20327 I-MSMSD3
Sample Spike MS MS
Analyte Concentration
(microgL) Added (microgL)
Concentration (microgL) Recovery
Recovery Limits Method Notes
Calcium 5013000 10100000 15120000 100 70- 130 EPA 2008 Mod AS
Spike MSD MSD Added Concentration o Oo Recovery RPD
Analyte (microgL) (microgL) Recovery RPD Limits Limit Method Notes
Calcium 10100000 16140000 llO 653 70 - 130 20 EPA 2008 Mod AS
Frontier Global Sciences Inc The results in his report only apply 10 the samples analyzed in accordance ivth he chain ofcustody document This analytical report must be reproduced in its entirety
Page 14 o261201073 Final Report 0425201]
Liz Siska Project Manager
16
Frontier Global Sciences Inc The ruults in this rechain ofcustody do
~ -lt1-c--~ Liz Siska Project Manager
11720 North Creek Parkway North Suite 400 Bothell WA 98011
Ph 425-686-1996 Fx 425-686-3096
GLOBAL SCIENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1201073-01RE4
Batch J203271 Sequence 2C22005
Preparation ~ IQsed Ve~~el Nitric Oven Qigestion Lab Number F203271-MSMSQ4
Analyte
Beryllium
Sample Concentration
(11gL)
0507
Spike Added (11gL)
20200
MS Concentration
(microgL)
2041
MS Oo
Recovery
985
RecoveryMethod Limits
70 - 130 EPA 2008 Mod
Notes
AS
Sodium 258800 40400 292900 845 70- 130 EPA 2008 Mod AS
Aluminum 529 40400 3956 966 70 - 130 EPA 2008 Mod AS
Chromium 057 40400 430l 106 70- 130 EPA 2008 Mod AS
Manganese 2805 40400 7042 105 70 - 130 EPA 2008 Mod AS
Iron ND 20200 2121 105 70 - 130 EPA 2008 Mod AS
Nickel 979 50500 5112 993 70 l30 EPA 2008 Mod AS
Copper 055 50500 4754 940 70 - 130 EPA 2008 Mod AS
Zinc 040 10100 9074 898 70 - 130 EPA 2008 Mod AS
Arsenic 1030 40400 4317 104 70 130 EPA 2008 Mod AS
Selenium 6340 40400 4688 100 70 - 130 EPA 2008 Mod AS
Molybdenum 1338 20200 338l 101 70 - 130 EPA 2008 Mod AS
Silver ND 20200 1850 916 70 130 EPA 2008 Mod AS
Cadmium 0332 40400 3937 966 70 130 EPA 2008 Mod AS
Antimony 0408 20200 2091 102 70 - 130 EPA 2008 Mod AS
Barium 2397 80800 1056 101 70- 130 EPA 2008 Mod AS
Lead ND IO100 9932 983 70 130 EPA 2008 Mod AS
shy
shy
shy
shy
shy
Analyte
Spike Added (microgL)
MSD Concentration
(microgL)
MSD
Recovery
RPD
Recovery Limits
RPDLimit Method Notes
Beryllium 20200 2007 968 l71 70 - 130 20 EPA 2008 Mod AS Sodium 40400 292600 837 0114 70 130 20 EPA 2008 Mod AS Aluminum 40400 3954 966 00362 70 - 130 20 EPA 2008 Mod AS Chromium 40400 4287 106 0337 70 - 130 20 EPA 2008 Mod AS Manganese 40400 6944 102 140 70 - 130 20 EPA 2008 Mod AS Iron 20200 2077 103 211 70 - 130 20 EPA 2008 Mod AS Nickel 50500 5126 996 0276 70 - 130 20 EPA 2008 Mod AS Copper 50500 4707 931 0997 70 - 130 20 EPA 200 8 Mod AS Zinc 10100 9059 896 0166 70 - 130 20 EPA 2008 Mod AS Arsenic 40400 4299 104 0419 70 - 130 20 EPA 2008 Mod AS Selenium 40400 4682 100 0141 70 - 130 20 EPA 2008 Mod AS Molybdenum 20200 3365 100 0473 70 - 130 20 EPA 2008 Mod AS
shy
port only apply to the sampltts analyzed in accordance with the cument This analytical report must be reproduced in its entirety
Page 5 o26 201073 Final Report 042512012 17
Liz Sia Project Manager
11720 North Creek Parkway North Suite 400 Botheln VA 98011
Ph 425-686-1996 Fx 425-686-3096
CLOBAL SCIENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1201073-01RE4
Batch F203271 Sequence 2c2io2~
Preparation Clo~ed Vessel litric Oven Digestion Lab Number F20327 l -MSMSQ4
Analyte
Spike Added (microgL)
MSD Concentration
(microgL)
MSD
Recovery
Oo
RPD Recovery
Limits RPOLimit Method Notes
Silver 20200 1895 938 242 70 - 130 20 EPA 2008 Mod AS Cadmium 40400 3933 965 0104 70 -130 20 EPA 2008 Mod AS Antimony 20200 2107 102 0736 70- 130 20 EPA 2008 Mod AS
Barium 80800 1058 101 0205 70 - 130 20 EPA 2008 Mod AS
Lead 10100 9877 978 0549 70 - 130 20 EPA 2008 Mod AS
Frontier Global Sciences Inc The results in this report only apply to the samples analyudin accordance with lht chain ofcustody document This analytical report must be reproductd rn ilS enlirtty
Page l6of26 1201073 Final Report Ofn5202 18
l I 720 North Creek Parkway North Suite 400 Bothell WA 980I I
Ph 425-686-1996 Fx 425-686-3096
GLO B AL SCIENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1201073-01RE6
Batch F203314 Sequence 2C25005
Preparation Closed Vessel Nitric Oven Digestion Lab Number F203314-MSMSD2
Sample Spike MS MS Concentration Added Concentration RecoveryAnalyte (microgL) (microgL) (microgL) Recovery Method NotesLimits
Thallium 5563 040400 5875 773 70 - 130 EPA 2008 Mod
Spike MSD MSD Added o Concentration Recovery RPD
RPO Limits Limit Method Notes Analyte (microgL) (microgL) Recovery
Thallium 040400 5880 785 00859 70 - 130 20 EPA 2008 Mod
Frontier Global Sciences Inc 11e results in chis reporc only apply 10 1he samples analyzed in accordance wilh lhe chain ofcustody documenz This analycical report musl be reproduced in ils entirety
Page 17 of26 1201073 Fi11aReport 0412512012
Liz Siska Project Manager
19
11720 North Creek Parkway North Suite 400 Bothell WA 98011
Ph 425-686-1996 Fx 425-686-3096
GLOBAl SCIENC ES
MATRIX SPIKE I MATRIX SPIKE DUPLICATE RECOVERY AND RPO
SOURCE I201073-01RE6
Batch F203314
Preparation Closed Vessel Nitric Oven Digestion
Sequence 2C25005
Lab Number F203314-MSMSD4
Analyte
Sample Concentration
(microgL)
Spike Added (microgL)
MS MS Concentration Oo
(microgL) Recovery Recovery
Limits Method Notes
Thallium 5563 10100 1033 968 70- 130 EPA 2008 Mod AS
Analyte
Spike Added (microgL)
MSD Concentration
(microgL)
MS)) Oo
Recovery
RPD
Recovery Limits
RPD Limit Method Notes
Thallium IO100 1037 97l 0341 70 - 130 20 EPA 2008 Mod AS
Frontier Global Sciences Inc The resulrs in this report only apply to the samples analyzed in accordance with the chain ofcusrody document This analytical report must be reproduced in its entirely
Page 18of26 120073 Final Report 04252012
Liz Siska Project Manager
20
11720 North Creek Parkway North Suite 400 l ~ Bothell WA 980 l l Ph 425-686-1996
FRONTIER Fx 425-686-3096 GLOBAL SCIENCES
LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLICATE
RECOVERY AND RPD
Batch F20 l063 Sequence 2A09010
Preparation BrCI Oxidation Lab Number F201063-BSIBSJ21
LCS Source N ist 1641d
Analyte
Spike Added (ngL)
LCS Concentration
(ngL)
LCS
Recovery Recovery
Limits Method Notes
Mercury 15679 1550 988 80 - 120 EPA I631E
Analyte
Spike Added (ngL)
LCSD Concentration
(ngL)
LCSD Oo
Recovery
RPD Recovery
Limits RPD Limit Method Notes
Mercury 15679 1595 [02 289 80 - 120 24 EPA I631E
Frontier Global Sciences Inc The results in this report only apply to the samples analyzedin accordance with the chain ofcustody document This analytical report must be reproduced in ils entirety
Page 19of26 1201073 Final Report 0425 2012
Liz Siska Project Manager
21
11720 North Creek Parkway North Suite 400 Bothell WA 98011
Ph 425-686-1996 FRONTIER Fx 425-686-3096 GLOBAL SCIENCES
LABORA TORY CONTROL SAMPLE LABO RATORY CONTROL SAMPLE DUPLICATE
RECOVERY AND RPD
Batch F203271 Sequence 2C22005
Preparation Closed Vessel Nitric Oven Digestion Lab Number F203271-BSBSD1
LCS Source Blank Spike
Spike LCS LCS Added Concentration Oo Recovery
Analyte (microgL) (microgL) Recovery Limits Method Notes
Beryllium 20000 l930 965 85 - 115 EPA 2008 Mod
Sodium 50000 499 998 85 - 115 EPA 2008 Mod
Aluminum 15000 1460 973 85 - 115 EPA 2008 Mod
Calcium 15000 1528 102 85 - 115 EPA 2008 Mod
Chromium 70000 657 939 85 - 115 EPA 2008 Mod
Manganese 60000 586 976 85 - 115 EPA 2008 Mod
Iron 50000 4753 951 85 shy 115 EPA 2008 Mod
Nickel 40000 401 100 85 - 115 EPA 2008 Mod
Copper 40000 418 105 85 - 115 EPA 2008 Mod
Zinc 10000 1033 103 85 - 115 EPA 2008 Mod
Arsenic 15000 1437 958 85 - 115 EPA 2008 Mod
Selenium 30000 2966 989 85 - 115 EPA 2008 Mod
Molybdenum 20000 181 905 85 shy 115 EPA 2008 Mod
Silver 15000 1517 101 85 shy 115 EPA 2008 Mod
Cadmium 080000 0781 976 85 - 1lS EPA 2008 Mod
Antimony 080000 0815 102 85 - 115 EPA 2008 Mod
Barium 10000 969 969 85 - 115 EPA 2008 Mod
Lead 15000 1597 106 85 - 115 EPA 2008 Mod
Spike LCSD LCSD Added Concentration Recovery RPO
Analyte (microgL) (microgL) Recovery RPO Limits Limit Method Notes
Beryllium 20000 1949 974 0955 85 - 115 20 EPA 2008 Mod
Sodium 50000 500 100 0216 85 - 115 20 EPA 2008 Mod
Aluminum 15000 1485 990 171 85 - 115 20 EPA 2008 Mod
Calcium 15000 1544 103 103 85 - 115 20 EPA 2008 Mod
Chromium 70000 667 953 148 85 - 115 20 EPA 2008 Mod
Manganese 60000 596 994 175 85 - 115 20 EPA 2008 Mod
Iron 50000 4852 970 206 85 - 115 20 EPA 2008 Mod
Nickel 40000 402 IOI 0246 85 - 115 20 EPA 2008 Mod
Frontier Global Sciences Inc The results in his report only apply to the samples analyzed in accordance wirh the chain ofcustody document This analytical report must be reproduced in iLS entirety
Page 20of26 1201073 Final Report 04252012
Liz Siska Project Manager
22
11720 North Creek Parkway North Suite 400 ~~shy Bothell WA 98011 Ph 425-686-1996~ONTif Fx 425-686-3096
GLOBAL SCIENCES
LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLICATE
RECOVERY AND RPO
Batch F20327 l Sequence 2C22005
Preparation Closed Vessel Nitric Oven Digestion Lab Number F203271-BSBSD 1
LCS Source Blank Spike
Analyte
Spike Added (microgL)
LCSD Concentration
(microgL)
LCSD oo
Recovery
RPO Recovery
Limits RPO Limit Method Notes
Copper
Zinc
Arsenic
Selenium
40000
10000
15000
30000
428
1039
1452
3015
107
104
968
101
224
0570
0977
166
85 - 115
85 - 115
85 - 115
85 - 115
20
20
20
20
EPA 2008 Mod
EPA 2008 Mod
EPA 2008 Mod
EPA 2008 Mod Molybdenum
Silver
20000
15000
182
J502
910
100
0564
103
85 - 115
85 - 115
20
20
EPA 2008 Mod
EPA 2008 Mod Cadmium
Antimony
Barium
Lead
080000
080000
10000
15000
0828
0808
986
1620
103
101
986
108
585
0848
177
142
85 - 115
85 - 115
85 shy 11 S
85 - 115
20
20
20
20
EPA 2008 Mod
EPA 2008 Mod
EPA 2008 Mod
EPA 2008 Mod
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report mus be reproducedin its entirety
Page 2 o26J20J073 Final Report 041252012
Liz Siska Project Manager
23
11720 North Creek Parkway North Suite 400 Bothell WA 980 l l
Ph 425-686-1996FRONT[ER- Fx 425-686-3096 cLosAL SCIEN _CES
LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLICATE
RECOVERY AND RPD
Batch F203314 Sequence 2C25005
Preparation Closed Vessel Nitric Oven Digestion Lab Number F2033 l 4-BSBSD 1
LCS Source Blank Spike
Analyte
Thallium
Spike Added (microgL)
LCS Concentration
(microgL)
LCS 0o
Recovery Recovery
Limits Method
040000 0396 989 85 - 115 EPA 2008 Mod
Notes
Analyte
Spike Added (microgL)
LCSD Concentration
(microgL)
LCSD 0o
Recovery
RPD Recovery
Limits RPO Limit Method Notes
Thallium 040000 0391 978 112 85 - ll5 20 EPA 2008 Mod
Frontier Global Sciences Inc The results in this report only apply to the samples anayed in accordance with the chain ofcustody docwnenJ This analytical report must be reproduced in its entirety
Page 22of26 1201073 Final Report 04252012
Liz Siska Project Manager
24
Liz Siska P roject Manager
11720 North Creek Parkway North Suite 400
~ Bothell WA 98011 Ph 425-686-1996
~JTIEif middot Fx 425-686-3096 GLOBAL SCIENCES
PREPARATION BLANKS
Instrument Hg-17 Sequence 2A09010
Preparation BrCI Oxidation
Lab Sample ID Analyte Found MRL Units Batch Method Notes
F201063-BLK I Mercury -0009 050 ngL F201063 EPA 1631E u F20 I063-BLK2 Mercury -0006 050 ngL F201063 EPA 1631E u F201063-BLK3 Mercury -002 050 ngL F201063 EPA 163IE u F201063-BLK4 Mercury 003 050 ngL F201063 EPA 1631E U QB-04 F201063-BLKS Mercury 011 052 ngL F201063 EPA I631E U QB-06
Frontier Global Sciences Inc The results in this report only apply 10 1he samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Page 23 o26 1201073 Final Repon 04252012 25
Liz Siska Project Manager
11720 North Creek Parkway North Suite 400 Bothell WA 98011
Ph 425-686-1996 FROr~TIER- Fx 425-686-3096 GLOBAL SCIENCES
PREPARATION BLANKS
Instrument ICPMS-6 Sequence 2C22005
Preparation Closed Vessel Nitric Oven Digestion
Lab Sample ID Analyte Found MRL Units Batch Method Notes
F203271-BLK1 Beryllium 000008 0060 microgL F203271 PA 2008 Molt u F20327 1-BLK1 Sodium 2 20 microgL F20327l PA 2008 Moc u F20327I-BLK1 Aluminum -004 40 microgL F203271 PA 2008 Molt u F20327I -BLK1 Calcium 40 microgL F203271 PA 2008 Molt u F203271 -BLK1 Chromium -002 010 microgL F203271 ~A 2008 Molt u F203271-BLKI Manganese 001 010 microgL F203271 PA 2008 Molt u F20327 l -BLK 1 Iron -002 100 microgL F203271 PA 2008 Molt u F203271-BLKI Nickel 0004 010 microgL F203271 PA 2008 Moc u F203271-BLK1 Copper 0003 010 microgL F203271 PA 2008 Moc u F203271-BLK1 Zinc 0007 020 microgL F203271 PA 2008 Moc u F203271-BLK1 Arsenic -006 015 microgL F203271 PA 2008 Moc u F203271-BLK1 Selenium -002 060 microgL F203271 PA 2008 Moc u F203271-BLK1 Molybdenum 001 006 microgL F203271 PA 2008 Molt u F203271-BLK1 Silver -00005 0020 microgL F203271 PA 2008 Molt u F203271-BLKl Cadmium 0004 0020 microgL F203271 PA 2008 Molt u F20327 l-BLKl Antimony 0002 0020 microgL F203271 PA 2008 Molt u F203271-BLKI Barium 001 020 microgL F203271 PA 2008 Molt u F203271-BLKI Lead 0010 0040 microgL F203271 PA 2008 Moc u
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Page 24of26 1201073 Final Report 04252012 26
~
~TIER~ GLOBAL SCIENCES
11720 North Creek Parkway North Suite 400 Bothell WA 980ll
Ph 425-686-1996 Fx 425-686-3096
PREPARATION BLANKS
Instrument JCPMS-3 Sequence 2C25005
Preparation Closed Vessel Nitric Oven Digestion
Lab Sample ID Analyte Found MRL Units Batch Method Notes
F2033I4-BLK1 Thalium 00007 0010 microgL F2033I4 ~PA 2008 Molt u
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Page 25 o26Liz Siska Project Manager 1201073 Final Report
04252012 27
l l 720 North Creek Parkway North Suite 400~Vi-~ Bothell WA 98011 Ph 425-686-1 996~Tlmiddot~ Fx 425-686-3096
G L OBAL SCIENCE S
Notes and Definitions
U Analyte included in the analysis but not detected
QM-02 The MS andor MSD recoveries outside acceptance limits due to spike concentration less than I times the sample concentration The batch was accepted based on LCS and LCSD recoveries within control limits and when analysis permits acceptable AS ASD
QB-06 The blank was preserved to 5 BrCI rather than I The control limit for blanks preserved to greater than 1 BrCl is the preservation percentage multiplied by the MRL
QB-04 The blank was preserved to 2 BrCI rather than l The control limit for blanks preserved to greater than l BrCI is the preservation percentage multiplied by the MRL
FB-1631 Required equipmentfieldfilter blank not submitted by the client The sample has been analyzed according to 163 lE but does not meet 163 lE criteria
AS This MS andor MSD is an analytical spike andor an analytical spike duplicate
DET Analyte Detected
MDL Minimum Detection Limit
MRL Minimum Reporting Limit
ND Analyte Not Detected at or above the reporting limit
wet Sample results reported on a wet weight basis
dry Sample results reported on a dry weight basis
RPO Relative Percent Difference
RSD Relative Standard Deviation
Frontier Global Sciences Inc The lesults i111his reporl only apply to he samples analyzed In accordance with the chain ofcuslody document This analytical report must be reproduced in its entirely
Page 26of26 1201073 Final Report 04252012
Liz Siska Project Manager
28
CHAIN-OF-(USTODY ttECORD Page i of f 106677 _J
BoLD F1ELDS REQUIRED PLEASE C 1RCLE REQUESTED ANALYSIS
SAMPLE ID
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SAMPLING
DATeTtME
IF COMPOSITE INDICATE BOTH
START amp FINISH
DATETIME li1J oc -r 111_- _vlt-c_
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middot~ON Mm1x A-Al~ S-SOil GW-GampOUHO WATER SW-SUampfA(f WATER DWmiddotDRIIIKIKlti WATER
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PHONE 22j-((omiddotf EXT ____
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DATE NEEDED _1--1 middot Z=-----shy4 (1-1_ METALS 8 RCRA 13 pp ff MN PB Cu
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DISSOLVED METALS FIELD FllTEREDI YES 110
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IF YH FAX OR POf 7~shy Hom (IE SPECIAL DETECTION LINITl BllLIKGINfO If DlffERrnT)ELECTRONIC OPTIONS zo 1 2 2) le~C1 1 Jc Id sJ 60 6c
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eastern analytical inc 2s CHENELL D R1ve IC 0 Nco1to N H 0330 1 I TEL 60J22aos2s 1aoo2a1os2s IFAx 6032284591 j E-MA1t cus-roM111_mV1c~EAILAsscoMJ www1A1LAascoM
----i pmiddotofissionrrl11bomtorymim (WHITE ORIGINAL GREEN PROJECT MANAGER)
shy
11720 North Creek Parkway North Suite 400 Bothell WA 98011
Ph 425-686-1996 FRONTIER- Fx 425-686-3096 cLosAL SCIENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1201030-02
Batch F20I063 Sequence 2A09010
Preparation BrCI Oxidation Lab Number F201063-MSMSD4
Sample Spike MS MS Concentration Added Concentration RecoveryAnalyte (ngL) (ngL) (ngL) Recovery MethodLimits Notes
Mercury 554 10200 1482 910 71 - 125 EPA I631E
Spike MSD MSD Oo Added Concentratio11 Recovery RPD
RPD Limits Limit Method Analyte (ngL) (ngL) Recovery Notes
Mercury 10200 1461 890 140 71 - 125 24 EPA 163IE
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed m accordance with the chain ofcus1ody document This anayt(ca repon must be reproduced in itr entirety
Page lOo26Liz Siska Project Manager 1201073 Final Report
041252012 12
I 1720 North Creek Parkway North Suite 400 Bothe I I WA 98011
Ph 425-686-1996 ~ Fx 425-686-3096 GLOBAL SCIENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1201073-01RE3
Batch F20327l Sequence 2C22005
Prcpa ration ((01ed Vessel ~ itric Oven Digestion Lab Number F203271-MSMSD 1
Analyte
Sample Concentration
(microgL)
Spike Added (microgL)
MS Concentration
(microgL)
MS Oo
Recovery Recovery
Method Limits Notes
Calcium 5013000 15150 4802000 -13900 70- 130 EPA 2008 Mod QM-02
Analyte
Spike Added (microgL)
MSD Concentration
(microgL)
MSD ~o
Recovery
Oo
RPD Recovery
Limits RPDLimit Method Notes
Calcium 15150 4943000 -4600 289 70 - 130 20 EPA 2008 Mod QM-02
Frontier Global Sciences Inc The results in this report only apply to the samples analyud inaccordance with the chain ofcustody document 17is analyticol report must be reproduced in its entirety
Page lI o16 1101073 Final Report 04152012
Liz Siska Project Manager
13
l l 720 North Creek Parkway North Suite 400 Bothell WA 98011
Ph 425-686-1996FRONTIER Fx 425-686-3096 GLOBAL SCIENCES
MATRIX SPIKE I MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1201073-01RE4
Batch F203271 Sequence 2C22005
Preparation Closed Vessel Nitric Oven Digestion Lab Number F203271-MSMSD2
Sample Spike MS MS Concentration Added Concentration Oo RecoveryAnalyte (microgL) (microgL) (microgL) Recovery Method Limits Notes
Beryllium 0507 20200 2442 958 70 - 130 EPA 2008 Mod Sodium 258800 50500 257700 -213 70 -130 EPA 2008 Mod QM-02 Aluminum 529 15150 2023 986 70 - 130 EPA 2008 Mod Chromium 057 70700 804 106 70 - 130 EPA 2008 Mod Manganese 2805 60600 2834 476 70 - 130 EPA 2008 Mod QM-02 Iron ND 50500 5200 103 70 130 EPA 2008 Mod Nickel 979 40400 141 l 107 70- 130 EPA 2008 Mod Copper 055 40400 434 939 70 - 130 EPA 2008 Mod Zinc 040 10100 842 794 70 - 130 EPA 2008 Mod Arsenic 1030 15150 2418 916 70 - 130 EPA 2008 Mod Selenium 6340 30300 8973 869 70 130 EPA 2008 Mod Molybdenum 1338 20200 1367 142 70 130 EPA 2008 Mod QM-02 Silver ND 15150 1388 916 70 - 130 EPA 2008 Mod Cadmium 0332 080800 1105 middot956 70 - 130 EPA 2008 Mod Antimony 0408 080800 1259 105 70- 130 EPA 2008 Mod Barium 2397 10100 2495 968 70 - 130 EPA 2008 Mod Lead ND 15150 1542 102 70 130 EPA 2008 Mod
shy
shy
shy
shy
Analyte
Spike Added (microgL)
MSD Concentration
(microgL)
MSD Oo
Recovery
Oo
RPD Recovery
Limits RPD Limit Method Notes
Beryllium
Sodium
Aluminum
Chromium
Manganese
Iron
Nickel
Copper
Zinc
Arsenic
Selenium
Molybdenum
20200
50500
15150
7Q700
60600
50500
40400
40400
10100
15150
30300
20200
2561
257100
2034
773
2852
5187
1381
419
916
2225
9400
1366
102
-336
993
101 769
103
995
902
868
789
101
137
474
0243
0564
385
0625
0242
213
347
849
831
464
00771
70 - 130
70 bull 130 70 - 130
70 - 130
70 - 130
70 - 130
70 - 130
70 - 130
70 - 130
70 bull 130 70 - 130
70 - 130
20
20
20
20
20
20
20
20
20
20
20
20
EPA 2008 Mod
EPA 2008 Mod
EPA 2008 Mod
EPA 2008 Mod
EPA 2008 Mod
EPA 2008 Mod
EPA 2008 Mod
EPA 2008 Mod
EPA 2008 Mod
EPA 2008 Mod
EPA 2008 Mod
EPA 2008 Mod
QM-02
QM-02
Frontier G lobal Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
--f_~ --~~~-~ -middot middot Page 12 o261201073 Final Report 041252012
Liz Siska Project Manager
14
11720 North Creek Parkway North Suite 400
~ Bothell WA 98011
~TIEmiddot Ph 425-686-1996 Fx 425-686-3096
GLOB11L SCIENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPO
SOURCE 1201073-01RE4
Batch F203271 Sequence 2C22005
Preparation ~lo~ed Vessel Nitric Oven Digestion Lab Number F20327 I-MSMSD2
Spike MSD MSD Added Concentration Oo Recovery RPO
Analyte (microgL) (microgL) Recovery RPD Limits Limit Method Notes
Silver 15150 1387 915 00874 70 - 130 20 EPA 2008 Mod Cadmium 080800 1061 902 403 70 - 130 20 EPA 200amp Mod Antimony 080800 1274 107 l2l 70 - 130 20 EPA 2008 Mod Barium 10100 2514 )16 0781 70 - 130 20 EPA 200amp Mod Lead 15150 1534 101 0525 70 shy 130 20 EPA 2008 Mod
Frontier Global Sciences Inc The results in this report only apply to 1he samples analyzed in accordance wiih the chain ofcustody document This analytical repo1 must be reproduced in ils entirety
Page 13 o26Liz Siska Project Manager 1201073 Final Reporl
04252012 15
11720 North Creek Parkway North Suite 400
~ Bothell WA 98011 Ph 425-686-I996
~RONTIER~ Fx 425-686-3096 GLOBAL SCIEN C ES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1201073-01RE3
Batch F203271 Sequence 2~22005
Preparation Closed Vessel Nitric Oven Digestion Lab Number F20327 I-MSMSD3
Sample Spike MS MS
Analyte Concentration
(microgL) Added (microgL)
Concentration (microgL) Recovery
Recovery Limits Method Notes
Calcium 5013000 10100000 15120000 100 70- 130 EPA 2008 Mod AS
Spike MSD MSD Added Concentration o Oo Recovery RPD
Analyte (microgL) (microgL) Recovery RPD Limits Limit Method Notes
Calcium 10100000 16140000 llO 653 70 - 130 20 EPA 2008 Mod AS
Frontier Global Sciences Inc The results in his report only apply 10 the samples analyzed in accordance ivth he chain ofcustody document This analytical report must be reproduced in its entirety
Page 14 o261201073 Final Report 0425201]
Liz Siska Project Manager
16
Frontier Global Sciences Inc The ruults in this rechain ofcustody do
~ -lt1-c--~ Liz Siska Project Manager
11720 North Creek Parkway North Suite 400 Bothell WA 98011
Ph 425-686-1996 Fx 425-686-3096
GLOBAL SCIENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1201073-01RE4
Batch J203271 Sequence 2C22005
Preparation ~ IQsed Ve~~el Nitric Oven Qigestion Lab Number F203271-MSMSQ4
Analyte
Beryllium
Sample Concentration
(11gL)
0507
Spike Added (11gL)
20200
MS Concentration
(microgL)
2041
MS Oo
Recovery
985
RecoveryMethod Limits
70 - 130 EPA 2008 Mod
Notes
AS
Sodium 258800 40400 292900 845 70- 130 EPA 2008 Mod AS
Aluminum 529 40400 3956 966 70 - 130 EPA 2008 Mod AS
Chromium 057 40400 430l 106 70- 130 EPA 2008 Mod AS
Manganese 2805 40400 7042 105 70 - 130 EPA 2008 Mod AS
Iron ND 20200 2121 105 70 - 130 EPA 2008 Mod AS
Nickel 979 50500 5112 993 70 l30 EPA 2008 Mod AS
Copper 055 50500 4754 940 70 - 130 EPA 2008 Mod AS
Zinc 040 10100 9074 898 70 - 130 EPA 2008 Mod AS
Arsenic 1030 40400 4317 104 70 130 EPA 2008 Mod AS
Selenium 6340 40400 4688 100 70 - 130 EPA 2008 Mod AS
Molybdenum 1338 20200 338l 101 70 - 130 EPA 2008 Mod AS
Silver ND 20200 1850 916 70 130 EPA 2008 Mod AS
Cadmium 0332 40400 3937 966 70 130 EPA 2008 Mod AS
Antimony 0408 20200 2091 102 70 - 130 EPA 2008 Mod AS
Barium 2397 80800 1056 101 70- 130 EPA 2008 Mod AS
Lead ND IO100 9932 983 70 130 EPA 2008 Mod AS
shy
shy
shy
shy
shy
Analyte
Spike Added (microgL)
MSD Concentration
(microgL)
MSD
Recovery
RPD
Recovery Limits
RPDLimit Method Notes
Beryllium 20200 2007 968 l71 70 - 130 20 EPA 2008 Mod AS Sodium 40400 292600 837 0114 70 130 20 EPA 2008 Mod AS Aluminum 40400 3954 966 00362 70 - 130 20 EPA 2008 Mod AS Chromium 40400 4287 106 0337 70 - 130 20 EPA 2008 Mod AS Manganese 40400 6944 102 140 70 - 130 20 EPA 2008 Mod AS Iron 20200 2077 103 211 70 - 130 20 EPA 2008 Mod AS Nickel 50500 5126 996 0276 70 - 130 20 EPA 2008 Mod AS Copper 50500 4707 931 0997 70 - 130 20 EPA 200 8 Mod AS Zinc 10100 9059 896 0166 70 - 130 20 EPA 2008 Mod AS Arsenic 40400 4299 104 0419 70 - 130 20 EPA 2008 Mod AS Selenium 40400 4682 100 0141 70 - 130 20 EPA 2008 Mod AS Molybdenum 20200 3365 100 0473 70 - 130 20 EPA 2008 Mod AS
shy
port only apply to the sampltts analyzed in accordance with the cument This analytical report must be reproduced in its entirety
Page 5 o26 201073 Final Report 042512012 17
Liz Sia Project Manager
11720 North Creek Parkway North Suite 400 Botheln VA 98011
Ph 425-686-1996 Fx 425-686-3096
CLOBAL SCIENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1201073-01RE4
Batch F203271 Sequence 2c2io2~
Preparation Clo~ed Vessel litric Oven Digestion Lab Number F20327 l -MSMSQ4
Analyte
Spike Added (microgL)
MSD Concentration
(microgL)
MSD
Recovery
Oo
RPD Recovery
Limits RPOLimit Method Notes
Silver 20200 1895 938 242 70 - 130 20 EPA 2008 Mod AS Cadmium 40400 3933 965 0104 70 -130 20 EPA 2008 Mod AS Antimony 20200 2107 102 0736 70- 130 20 EPA 2008 Mod AS
Barium 80800 1058 101 0205 70 - 130 20 EPA 2008 Mod AS
Lead 10100 9877 978 0549 70 - 130 20 EPA 2008 Mod AS
Frontier Global Sciences Inc The results in this report only apply to the samples analyudin accordance with lht chain ofcustody document This analytical report must be reproductd rn ilS enlirtty
Page l6of26 1201073 Final Report Ofn5202 18
l I 720 North Creek Parkway North Suite 400 Bothell WA 980I I
Ph 425-686-1996 Fx 425-686-3096
GLO B AL SCIENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1201073-01RE6
Batch F203314 Sequence 2C25005
Preparation Closed Vessel Nitric Oven Digestion Lab Number F203314-MSMSD2
Sample Spike MS MS Concentration Added Concentration RecoveryAnalyte (microgL) (microgL) (microgL) Recovery Method NotesLimits
Thallium 5563 040400 5875 773 70 - 130 EPA 2008 Mod
Spike MSD MSD Added o Concentration Recovery RPD
RPO Limits Limit Method Notes Analyte (microgL) (microgL) Recovery
Thallium 040400 5880 785 00859 70 - 130 20 EPA 2008 Mod
Frontier Global Sciences Inc 11e results in chis reporc only apply 10 1he samples analyzed in accordance wilh lhe chain ofcustody documenz This analycical report musl be reproduced in ils entirety
Page 17 of26 1201073 Fi11aReport 0412512012
Liz Siska Project Manager
19
11720 North Creek Parkway North Suite 400 Bothell WA 98011
Ph 425-686-1996 Fx 425-686-3096
GLOBAl SCIENC ES
MATRIX SPIKE I MATRIX SPIKE DUPLICATE RECOVERY AND RPO
SOURCE I201073-01RE6
Batch F203314
Preparation Closed Vessel Nitric Oven Digestion
Sequence 2C25005
Lab Number F203314-MSMSD4
Analyte
Sample Concentration
(microgL)
Spike Added (microgL)
MS MS Concentration Oo
(microgL) Recovery Recovery
Limits Method Notes
Thallium 5563 10100 1033 968 70- 130 EPA 2008 Mod AS
Analyte
Spike Added (microgL)
MSD Concentration
(microgL)
MS)) Oo
Recovery
RPD
Recovery Limits
RPD Limit Method Notes
Thallium IO100 1037 97l 0341 70 - 130 20 EPA 2008 Mod AS
Frontier Global Sciences Inc The resulrs in this report only apply to the samples analyzed in accordance with the chain ofcusrody document This analytical report must be reproduced in its entirely
Page 18of26 120073 Final Report 04252012
Liz Siska Project Manager
20
11720 North Creek Parkway North Suite 400 l ~ Bothell WA 980 l l Ph 425-686-1996
FRONTIER Fx 425-686-3096 GLOBAL SCIENCES
LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLICATE
RECOVERY AND RPD
Batch F20 l063 Sequence 2A09010
Preparation BrCI Oxidation Lab Number F201063-BSIBSJ21
LCS Source N ist 1641d
Analyte
Spike Added (ngL)
LCS Concentration
(ngL)
LCS
Recovery Recovery
Limits Method Notes
Mercury 15679 1550 988 80 - 120 EPA I631E
Analyte
Spike Added (ngL)
LCSD Concentration
(ngL)
LCSD Oo
Recovery
RPD Recovery
Limits RPD Limit Method Notes
Mercury 15679 1595 [02 289 80 - 120 24 EPA I631E
Frontier Global Sciences Inc The results in this report only apply to the samples analyzedin accordance with the chain ofcustody document This analytical report must be reproduced in ils entirety
Page 19of26 1201073 Final Report 0425 2012
Liz Siska Project Manager
21
11720 North Creek Parkway North Suite 400 Bothell WA 98011
Ph 425-686-1996 FRONTIER Fx 425-686-3096 GLOBAL SCIENCES
LABORA TORY CONTROL SAMPLE LABO RATORY CONTROL SAMPLE DUPLICATE
RECOVERY AND RPD
Batch F203271 Sequence 2C22005
Preparation Closed Vessel Nitric Oven Digestion Lab Number F203271-BSBSD1
LCS Source Blank Spike
Spike LCS LCS Added Concentration Oo Recovery
Analyte (microgL) (microgL) Recovery Limits Method Notes
Beryllium 20000 l930 965 85 - 115 EPA 2008 Mod
Sodium 50000 499 998 85 - 115 EPA 2008 Mod
Aluminum 15000 1460 973 85 - 115 EPA 2008 Mod
Calcium 15000 1528 102 85 - 115 EPA 2008 Mod
Chromium 70000 657 939 85 - 115 EPA 2008 Mod
Manganese 60000 586 976 85 - 115 EPA 2008 Mod
Iron 50000 4753 951 85 shy 115 EPA 2008 Mod
Nickel 40000 401 100 85 - 115 EPA 2008 Mod
Copper 40000 418 105 85 - 115 EPA 2008 Mod
Zinc 10000 1033 103 85 - 115 EPA 2008 Mod
Arsenic 15000 1437 958 85 - 115 EPA 2008 Mod
Selenium 30000 2966 989 85 - 115 EPA 2008 Mod
Molybdenum 20000 181 905 85 shy 115 EPA 2008 Mod
Silver 15000 1517 101 85 shy 115 EPA 2008 Mod
Cadmium 080000 0781 976 85 - 1lS EPA 2008 Mod
Antimony 080000 0815 102 85 - 115 EPA 2008 Mod
Barium 10000 969 969 85 - 115 EPA 2008 Mod
Lead 15000 1597 106 85 - 115 EPA 2008 Mod
Spike LCSD LCSD Added Concentration Recovery RPO
Analyte (microgL) (microgL) Recovery RPO Limits Limit Method Notes
Beryllium 20000 1949 974 0955 85 - 115 20 EPA 2008 Mod
Sodium 50000 500 100 0216 85 - 115 20 EPA 2008 Mod
Aluminum 15000 1485 990 171 85 - 115 20 EPA 2008 Mod
Calcium 15000 1544 103 103 85 - 115 20 EPA 2008 Mod
Chromium 70000 667 953 148 85 - 115 20 EPA 2008 Mod
Manganese 60000 596 994 175 85 - 115 20 EPA 2008 Mod
Iron 50000 4852 970 206 85 - 115 20 EPA 2008 Mod
Nickel 40000 402 IOI 0246 85 - 115 20 EPA 2008 Mod
Frontier Global Sciences Inc The results in his report only apply to the samples analyzed in accordance wirh the chain ofcustody document This analytical report must be reproduced in iLS entirety
Page 20of26 1201073 Final Report 04252012
Liz Siska Project Manager
22
11720 North Creek Parkway North Suite 400 ~~shy Bothell WA 98011 Ph 425-686-1996~ONTif Fx 425-686-3096
GLOBAL SCIENCES
LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLICATE
RECOVERY AND RPO
Batch F20327 l Sequence 2C22005
Preparation Closed Vessel Nitric Oven Digestion Lab Number F203271-BSBSD 1
LCS Source Blank Spike
Analyte
Spike Added (microgL)
LCSD Concentration
(microgL)
LCSD oo
Recovery
RPO Recovery
Limits RPO Limit Method Notes
Copper
Zinc
Arsenic
Selenium
40000
10000
15000
30000
428
1039
1452
3015
107
104
968
101
224
0570
0977
166
85 - 115
85 - 115
85 - 115
85 - 115
20
20
20
20
EPA 2008 Mod
EPA 2008 Mod
EPA 2008 Mod
EPA 2008 Mod Molybdenum
Silver
20000
15000
182
J502
910
100
0564
103
85 - 115
85 - 115
20
20
EPA 2008 Mod
EPA 2008 Mod Cadmium
Antimony
Barium
Lead
080000
080000
10000
15000
0828
0808
986
1620
103
101
986
108
585
0848
177
142
85 - 115
85 - 115
85 shy 11 S
85 - 115
20
20
20
20
EPA 2008 Mod
EPA 2008 Mod
EPA 2008 Mod
EPA 2008 Mod
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report mus be reproducedin its entirety
Page 2 o26J20J073 Final Report 041252012
Liz Siska Project Manager
23
11720 North Creek Parkway North Suite 400 Bothell WA 980 l l
Ph 425-686-1996FRONT[ER- Fx 425-686-3096 cLosAL SCIEN _CES
LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLICATE
RECOVERY AND RPD
Batch F203314 Sequence 2C25005
Preparation Closed Vessel Nitric Oven Digestion Lab Number F2033 l 4-BSBSD 1
LCS Source Blank Spike
Analyte
Thallium
Spike Added (microgL)
LCS Concentration
(microgL)
LCS 0o
Recovery Recovery
Limits Method
040000 0396 989 85 - 115 EPA 2008 Mod
Notes
Analyte
Spike Added (microgL)
LCSD Concentration
(microgL)
LCSD 0o
Recovery
RPD Recovery
Limits RPO Limit Method Notes
Thallium 040000 0391 978 112 85 - ll5 20 EPA 2008 Mod
Frontier Global Sciences Inc The results in this report only apply to the samples anayed in accordance with the chain ofcustody docwnenJ This analytical report must be reproduced in its entirety
Page 22of26 1201073 Final Report 04252012
Liz Siska Project Manager
24
Liz Siska P roject Manager
11720 North Creek Parkway North Suite 400
~ Bothell WA 98011 Ph 425-686-1996
~JTIEif middot Fx 425-686-3096 GLOBAL SCIENCES
PREPARATION BLANKS
Instrument Hg-17 Sequence 2A09010
Preparation BrCI Oxidation
Lab Sample ID Analyte Found MRL Units Batch Method Notes
F201063-BLK I Mercury -0009 050 ngL F201063 EPA 1631E u F20 I063-BLK2 Mercury -0006 050 ngL F201063 EPA 1631E u F201063-BLK3 Mercury -002 050 ngL F201063 EPA 163IE u F201063-BLK4 Mercury 003 050 ngL F201063 EPA 1631E U QB-04 F201063-BLKS Mercury 011 052 ngL F201063 EPA I631E U QB-06
Frontier Global Sciences Inc The results in this report only apply 10 1he samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Page 23 o26 1201073 Final Repon 04252012 25
Liz Siska Project Manager
11720 North Creek Parkway North Suite 400 Bothell WA 98011
Ph 425-686-1996 FROr~TIER- Fx 425-686-3096 GLOBAL SCIENCES
PREPARATION BLANKS
Instrument ICPMS-6 Sequence 2C22005
Preparation Closed Vessel Nitric Oven Digestion
Lab Sample ID Analyte Found MRL Units Batch Method Notes
F203271-BLK1 Beryllium 000008 0060 microgL F203271 PA 2008 Molt u F20327 1-BLK1 Sodium 2 20 microgL F20327l PA 2008 Moc u F20327I-BLK1 Aluminum -004 40 microgL F203271 PA 2008 Molt u F20327I -BLK1 Calcium 40 microgL F203271 PA 2008 Molt u F203271 -BLK1 Chromium -002 010 microgL F203271 ~A 2008 Molt u F203271-BLKI Manganese 001 010 microgL F203271 PA 2008 Molt u F20327 l -BLK 1 Iron -002 100 microgL F203271 PA 2008 Molt u F203271-BLKI Nickel 0004 010 microgL F203271 PA 2008 Moc u F203271-BLK1 Copper 0003 010 microgL F203271 PA 2008 Moc u F203271-BLK1 Zinc 0007 020 microgL F203271 PA 2008 Moc u F203271-BLK1 Arsenic -006 015 microgL F203271 PA 2008 Moc u F203271-BLK1 Selenium -002 060 microgL F203271 PA 2008 Moc u F203271-BLK1 Molybdenum 001 006 microgL F203271 PA 2008 Molt u F203271-BLK1 Silver -00005 0020 microgL F203271 PA 2008 Molt u F203271-BLKl Cadmium 0004 0020 microgL F203271 PA 2008 Molt u F20327 l-BLKl Antimony 0002 0020 microgL F203271 PA 2008 Molt u F203271-BLKI Barium 001 020 microgL F203271 PA 2008 Molt u F203271-BLKI Lead 0010 0040 microgL F203271 PA 2008 Moc u
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Page 24of26 1201073 Final Report 04252012 26
~
~TIER~ GLOBAL SCIENCES
11720 North Creek Parkway North Suite 400 Bothell WA 980ll
Ph 425-686-1996 Fx 425-686-3096
PREPARATION BLANKS
Instrument JCPMS-3 Sequence 2C25005
Preparation Closed Vessel Nitric Oven Digestion
Lab Sample ID Analyte Found MRL Units Batch Method Notes
F2033I4-BLK1 Thalium 00007 0010 microgL F2033I4 ~PA 2008 Molt u
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Page 25 o26Liz Siska Project Manager 1201073 Final Report
04252012 27
l l 720 North Creek Parkway North Suite 400~Vi-~ Bothell WA 98011 Ph 425-686-1 996~Tlmiddot~ Fx 425-686-3096
G L OBAL SCIENCE S
Notes and Definitions
U Analyte included in the analysis but not detected
QM-02 The MS andor MSD recoveries outside acceptance limits due to spike concentration less than I times the sample concentration The batch was accepted based on LCS and LCSD recoveries within control limits and when analysis permits acceptable AS ASD
QB-06 The blank was preserved to 5 BrCI rather than I The control limit for blanks preserved to greater than 1 BrCl is the preservation percentage multiplied by the MRL
QB-04 The blank was preserved to 2 BrCI rather than l The control limit for blanks preserved to greater than l BrCI is the preservation percentage multiplied by the MRL
FB-1631 Required equipmentfieldfilter blank not submitted by the client The sample has been analyzed according to 163 lE but does not meet 163 lE criteria
AS This MS andor MSD is an analytical spike andor an analytical spike duplicate
DET Analyte Detected
MDL Minimum Detection Limit
MRL Minimum Reporting Limit
ND Analyte Not Detected at or above the reporting limit
wet Sample results reported on a wet weight basis
dry Sample results reported on a dry weight basis
RPO Relative Percent Difference
RSD Relative Standard Deviation
Frontier Global Sciences Inc The lesults i111his reporl only apply to he samples analyzed In accordance with the chain ofcuslody document This analytical report must be reproduced in its entirely
Page 26of26 1201073 Final Report 04252012
Liz Siska Project Manager
28
CHAIN-OF-(USTODY ttECORD Page i of f 106677 _J
BoLD F1ELDS REQUIRED PLEASE C 1RCLE REQUESTED ANALYSIS
SAMPLE ID
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START amp FINISH
DATETIME li1J oc -r 111_- _vlt-c_
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PHONE 22j-((omiddotf EXT ____
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DATE NEEDED _1--1 middot Z=-----shy4 (1-1_ METALS 8 RCRA 13 pp ff MN PB Cu
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eastern analytical inc 2s CHENELL D R1ve IC 0 Nco1to N H 0330 1 I TEL 60J22aos2s 1aoo2a1os2s IFAx 6032284591 j E-MA1t cus-roM111_mV1c~EAILAsscoMJ www1A1LAascoM
----i pmiddotofissionrrl11bomtorymim (WHITE ORIGINAL GREEN PROJECT MANAGER)
shy
I 1720 North Creek Parkway North Suite 400 Bothe I I WA 98011
Ph 425-686-1996 ~ Fx 425-686-3096 GLOBAL SCIENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1201073-01RE3
Batch F20327l Sequence 2C22005
Prcpa ration ((01ed Vessel ~ itric Oven Digestion Lab Number F203271-MSMSD 1
Analyte
Sample Concentration
(microgL)
Spike Added (microgL)
MS Concentration
(microgL)
MS Oo
Recovery Recovery
Method Limits Notes
Calcium 5013000 15150 4802000 -13900 70- 130 EPA 2008 Mod QM-02
Analyte
Spike Added (microgL)
MSD Concentration
(microgL)
MSD ~o
Recovery
Oo
RPD Recovery
Limits RPDLimit Method Notes
Calcium 15150 4943000 -4600 289 70 - 130 20 EPA 2008 Mod QM-02
Frontier Global Sciences Inc The results in this report only apply to the samples analyud inaccordance with the chain ofcustody document 17is analyticol report must be reproduced in its entirety
Page lI o16 1101073 Final Report 04152012
Liz Siska Project Manager
13
l l 720 North Creek Parkway North Suite 400 Bothell WA 98011
Ph 425-686-1996FRONTIER Fx 425-686-3096 GLOBAL SCIENCES
MATRIX SPIKE I MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1201073-01RE4
Batch F203271 Sequence 2C22005
Preparation Closed Vessel Nitric Oven Digestion Lab Number F203271-MSMSD2
Sample Spike MS MS Concentration Added Concentration Oo RecoveryAnalyte (microgL) (microgL) (microgL) Recovery Method Limits Notes
Beryllium 0507 20200 2442 958 70 - 130 EPA 2008 Mod Sodium 258800 50500 257700 -213 70 -130 EPA 2008 Mod QM-02 Aluminum 529 15150 2023 986 70 - 130 EPA 2008 Mod Chromium 057 70700 804 106 70 - 130 EPA 2008 Mod Manganese 2805 60600 2834 476 70 - 130 EPA 2008 Mod QM-02 Iron ND 50500 5200 103 70 130 EPA 2008 Mod Nickel 979 40400 141 l 107 70- 130 EPA 2008 Mod Copper 055 40400 434 939 70 - 130 EPA 2008 Mod Zinc 040 10100 842 794 70 - 130 EPA 2008 Mod Arsenic 1030 15150 2418 916 70 - 130 EPA 2008 Mod Selenium 6340 30300 8973 869 70 130 EPA 2008 Mod Molybdenum 1338 20200 1367 142 70 130 EPA 2008 Mod QM-02 Silver ND 15150 1388 916 70 - 130 EPA 2008 Mod Cadmium 0332 080800 1105 middot956 70 - 130 EPA 2008 Mod Antimony 0408 080800 1259 105 70- 130 EPA 2008 Mod Barium 2397 10100 2495 968 70 - 130 EPA 2008 Mod Lead ND 15150 1542 102 70 130 EPA 2008 Mod
shy
shy
shy
shy
Analyte
Spike Added (microgL)
MSD Concentration
(microgL)
MSD Oo
Recovery
Oo
RPD Recovery
Limits RPD Limit Method Notes
Beryllium
Sodium
Aluminum
Chromium
Manganese
Iron
Nickel
Copper
Zinc
Arsenic
Selenium
Molybdenum
20200
50500
15150
7Q700
60600
50500
40400
40400
10100
15150
30300
20200
2561
257100
2034
773
2852
5187
1381
419
916
2225
9400
1366
102
-336
993
101 769
103
995
902
868
789
101
137
474
0243
0564
385
0625
0242
213
347
849
831
464
00771
70 - 130
70 bull 130 70 - 130
70 - 130
70 - 130
70 - 130
70 - 130
70 - 130
70 - 130
70 bull 130 70 - 130
70 - 130
20
20
20
20
20
20
20
20
20
20
20
20
EPA 2008 Mod
EPA 2008 Mod
EPA 2008 Mod
EPA 2008 Mod
EPA 2008 Mod
EPA 2008 Mod
EPA 2008 Mod
EPA 2008 Mod
EPA 2008 Mod
EPA 2008 Mod
EPA 2008 Mod
EPA 2008 Mod
QM-02
QM-02
Frontier G lobal Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
--f_~ --~~~-~ -middot middot Page 12 o261201073 Final Report 041252012
Liz Siska Project Manager
14
11720 North Creek Parkway North Suite 400
~ Bothell WA 98011
~TIEmiddot Ph 425-686-1996 Fx 425-686-3096
GLOB11L SCIENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPO
SOURCE 1201073-01RE4
Batch F203271 Sequence 2C22005
Preparation ~lo~ed Vessel Nitric Oven Digestion Lab Number F20327 I-MSMSD2
Spike MSD MSD Added Concentration Oo Recovery RPO
Analyte (microgL) (microgL) Recovery RPD Limits Limit Method Notes
Silver 15150 1387 915 00874 70 - 130 20 EPA 2008 Mod Cadmium 080800 1061 902 403 70 - 130 20 EPA 200amp Mod Antimony 080800 1274 107 l2l 70 - 130 20 EPA 2008 Mod Barium 10100 2514 )16 0781 70 - 130 20 EPA 200amp Mod Lead 15150 1534 101 0525 70 shy 130 20 EPA 2008 Mod
Frontier Global Sciences Inc The results in this report only apply to 1he samples analyzed in accordance wiih the chain ofcustody document This analytical repo1 must be reproduced in ils entirety
Page 13 o26Liz Siska Project Manager 1201073 Final Reporl
04252012 15
11720 North Creek Parkway North Suite 400
~ Bothell WA 98011 Ph 425-686-I996
~RONTIER~ Fx 425-686-3096 GLOBAL SCIEN C ES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1201073-01RE3
Batch F203271 Sequence 2~22005
Preparation Closed Vessel Nitric Oven Digestion Lab Number F20327 I-MSMSD3
Sample Spike MS MS
Analyte Concentration
(microgL) Added (microgL)
Concentration (microgL) Recovery
Recovery Limits Method Notes
Calcium 5013000 10100000 15120000 100 70- 130 EPA 2008 Mod AS
Spike MSD MSD Added Concentration o Oo Recovery RPD
Analyte (microgL) (microgL) Recovery RPD Limits Limit Method Notes
Calcium 10100000 16140000 llO 653 70 - 130 20 EPA 2008 Mod AS
Frontier Global Sciences Inc The results in his report only apply 10 the samples analyzed in accordance ivth he chain ofcustody document This analytical report must be reproduced in its entirety
Page 14 o261201073 Final Report 0425201]
Liz Siska Project Manager
16
Frontier Global Sciences Inc The ruults in this rechain ofcustody do
~ -lt1-c--~ Liz Siska Project Manager
11720 North Creek Parkway North Suite 400 Bothell WA 98011
Ph 425-686-1996 Fx 425-686-3096
GLOBAL SCIENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1201073-01RE4
Batch J203271 Sequence 2C22005
Preparation ~ IQsed Ve~~el Nitric Oven Qigestion Lab Number F203271-MSMSQ4
Analyte
Beryllium
Sample Concentration
(11gL)
0507
Spike Added (11gL)
20200
MS Concentration
(microgL)
2041
MS Oo
Recovery
985
RecoveryMethod Limits
70 - 130 EPA 2008 Mod
Notes
AS
Sodium 258800 40400 292900 845 70- 130 EPA 2008 Mod AS
Aluminum 529 40400 3956 966 70 - 130 EPA 2008 Mod AS
Chromium 057 40400 430l 106 70- 130 EPA 2008 Mod AS
Manganese 2805 40400 7042 105 70 - 130 EPA 2008 Mod AS
Iron ND 20200 2121 105 70 - 130 EPA 2008 Mod AS
Nickel 979 50500 5112 993 70 l30 EPA 2008 Mod AS
Copper 055 50500 4754 940 70 - 130 EPA 2008 Mod AS
Zinc 040 10100 9074 898 70 - 130 EPA 2008 Mod AS
Arsenic 1030 40400 4317 104 70 130 EPA 2008 Mod AS
Selenium 6340 40400 4688 100 70 - 130 EPA 2008 Mod AS
Molybdenum 1338 20200 338l 101 70 - 130 EPA 2008 Mod AS
Silver ND 20200 1850 916 70 130 EPA 2008 Mod AS
Cadmium 0332 40400 3937 966 70 130 EPA 2008 Mod AS
Antimony 0408 20200 2091 102 70 - 130 EPA 2008 Mod AS
Barium 2397 80800 1056 101 70- 130 EPA 2008 Mod AS
Lead ND IO100 9932 983 70 130 EPA 2008 Mod AS
shy
shy
shy
shy
shy
Analyte
Spike Added (microgL)
MSD Concentration
(microgL)
MSD
Recovery
RPD
Recovery Limits
RPDLimit Method Notes
Beryllium 20200 2007 968 l71 70 - 130 20 EPA 2008 Mod AS Sodium 40400 292600 837 0114 70 130 20 EPA 2008 Mod AS Aluminum 40400 3954 966 00362 70 - 130 20 EPA 2008 Mod AS Chromium 40400 4287 106 0337 70 - 130 20 EPA 2008 Mod AS Manganese 40400 6944 102 140 70 - 130 20 EPA 2008 Mod AS Iron 20200 2077 103 211 70 - 130 20 EPA 2008 Mod AS Nickel 50500 5126 996 0276 70 - 130 20 EPA 2008 Mod AS Copper 50500 4707 931 0997 70 - 130 20 EPA 200 8 Mod AS Zinc 10100 9059 896 0166 70 - 130 20 EPA 2008 Mod AS Arsenic 40400 4299 104 0419 70 - 130 20 EPA 2008 Mod AS Selenium 40400 4682 100 0141 70 - 130 20 EPA 2008 Mod AS Molybdenum 20200 3365 100 0473 70 - 130 20 EPA 2008 Mod AS
shy
port only apply to the sampltts analyzed in accordance with the cument This analytical report must be reproduced in its entirety
Page 5 o26 201073 Final Report 042512012 17
Liz Sia Project Manager
11720 North Creek Parkway North Suite 400 Botheln VA 98011
Ph 425-686-1996 Fx 425-686-3096
CLOBAL SCIENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1201073-01RE4
Batch F203271 Sequence 2c2io2~
Preparation Clo~ed Vessel litric Oven Digestion Lab Number F20327 l -MSMSQ4
Analyte
Spike Added (microgL)
MSD Concentration
(microgL)
MSD
Recovery
Oo
RPD Recovery
Limits RPOLimit Method Notes
Silver 20200 1895 938 242 70 - 130 20 EPA 2008 Mod AS Cadmium 40400 3933 965 0104 70 -130 20 EPA 2008 Mod AS Antimony 20200 2107 102 0736 70- 130 20 EPA 2008 Mod AS
Barium 80800 1058 101 0205 70 - 130 20 EPA 2008 Mod AS
Lead 10100 9877 978 0549 70 - 130 20 EPA 2008 Mod AS
Frontier Global Sciences Inc The results in this report only apply to the samples analyudin accordance with lht chain ofcustody document This analytical report must be reproductd rn ilS enlirtty
Page l6of26 1201073 Final Report Ofn5202 18
l I 720 North Creek Parkway North Suite 400 Bothell WA 980I I
Ph 425-686-1996 Fx 425-686-3096
GLO B AL SCIENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1201073-01RE6
Batch F203314 Sequence 2C25005
Preparation Closed Vessel Nitric Oven Digestion Lab Number F203314-MSMSD2
Sample Spike MS MS Concentration Added Concentration RecoveryAnalyte (microgL) (microgL) (microgL) Recovery Method NotesLimits
Thallium 5563 040400 5875 773 70 - 130 EPA 2008 Mod
Spike MSD MSD Added o Concentration Recovery RPD
RPO Limits Limit Method Notes Analyte (microgL) (microgL) Recovery
Thallium 040400 5880 785 00859 70 - 130 20 EPA 2008 Mod
Frontier Global Sciences Inc 11e results in chis reporc only apply 10 1he samples analyzed in accordance wilh lhe chain ofcustody documenz This analycical report musl be reproduced in ils entirety
Page 17 of26 1201073 Fi11aReport 0412512012
Liz Siska Project Manager
19
11720 North Creek Parkway North Suite 400 Bothell WA 98011
Ph 425-686-1996 Fx 425-686-3096
GLOBAl SCIENC ES
MATRIX SPIKE I MATRIX SPIKE DUPLICATE RECOVERY AND RPO
SOURCE I201073-01RE6
Batch F203314
Preparation Closed Vessel Nitric Oven Digestion
Sequence 2C25005
Lab Number F203314-MSMSD4
Analyte
Sample Concentration
(microgL)
Spike Added (microgL)
MS MS Concentration Oo
(microgL) Recovery Recovery
Limits Method Notes
Thallium 5563 10100 1033 968 70- 130 EPA 2008 Mod AS
Analyte
Spike Added (microgL)
MSD Concentration
(microgL)
MS)) Oo
Recovery
RPD
Recovery Limits
RPD Limit Method Notes
Thallium IO100 1037 97l 0341 70 - 130 20 EPA 2008 Mod AS
Frontier Global Sciences Inc The resulrs in this report only apply to the samples analyzed in accordance with the chain ofcusrody document This analytical report must be reproduced in its entirely
Page 18of26 120073 Final Report 04252012
Liz Siska Project Manager
20
11720 North Creek Parkway North Suite 400 l ~ Bothell WA 980 l l Ph 425-686-1996
FRONTIER Fx 425-686-3096 GLOBAL SCIENCES
LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLICATE
RECOVERY AND RPD
Batch F20 l063 Sequence 2A09010
Preparation BrCI Oxidation Lab Number F201063-BSIBSJ21
LCS Source N ist 1641d
Analyte
Spike Added (ngL)
LCS Concentration
(ngL)
LCS
Recovery Recovery
Limits Method Notes
Mercury 15679 1550 988 80 - 120 EPA I631E
Analyte
Spike Added (ngL)
LCSD Concentration
(ngL)
LCSD Oo
Recovery
RPD Recovery
Limits RPD Limit Method Notes
Mercury 15679 1595 [02 289 80 - 120 24 EPA I631E
Frontier Global Sciences Inc The results in this report only apply to the samples analyzedin accordance with the chain ofcustody document This analytical report must be reproduced in ils entirety
Page 19of26 1201073 Final Report 0425 2012
Liz Siska Project Manager
21
11720 North Creek Parkway North Suite 400 Bothell WA 98011
Ph 425-686-1996 FRONTIER Fx 425-686-3096 GLOBAL SCIENCES
LABORA TORY CONTROL SAMPLE LABO RATORY CONTROL SAMPLE DUPLICATE
RECOVERY AND RPD
Batch F203271 Sequence 2C22005
Preparation Closed Vessel Nitric Oven Digestion Lab Number F203271-BSBSD1
LCS Source Blank Spike
Spike LCS LCS Added Concentration Oo Recovery
Analyte (microgL) (microgL) Recovery Limits Method Notes
Beryllium 20000 l930 965 85 - 115 EPA 2008 Mod
Sodium 50000 499 998 85 - 115 EPA 2008 Mod
Aluminum 15000 1460 973 85 - 115 EPA 2008 Mod
Calcium 15000 1528 102 85 - 115 EPA 2008 Mod
Chromium 70000 657 939 85 - 115 EPA 2008 Mod
Manganese 60000 586 976 85 - 115 EPA 2008 Mod
Iron 50000 4753 951 85 shy 115 EPA 2008 Mod
Nickel 40000 401 100 85 - 115 EPA 2008 Mod
Copper 40000 418 105 85 - 115 EPA 2008 Mod
Zinc 10000 1033 103 85 - 115 EPA 2008 Mod
Arsenic 15000 1437 958 85 - 115 EPA 2008 Mod
Selenium 30000 2966 989 85 - 115 EPA 2008 Mod
Molybdenum 20000 181 905 85 shy 115 EPA 2008 Mod
Silver 15000 1517 101 85 shy 115 EPA 2008 Mod
Cadmium 080000 0781 976 85 - 1lS EPA 2008 Mod
Antimony 080000 0815 102 85 - 115 EPA 2008 Mod
Barium 10000 969 969 85 - 115 EPA 2008 Mod
Lead 15000 1597 106 85 - 115 EPA 2008 Mod
Spike LCSD LCSD Added Concentration Recovery RPO
Analyte (microgL) (microgL) Recovery RPO Limits Limit Method Notes
Beryllium 20000 1949 974 0955 85 - 115 20 EPA 2008 Mod
Sodium 50000 500 100 0216 85 - 115 20 EPA 2008 Mod
Aluminum 15000 1485 990 171 85 - 115 20 EPA 2008 Mod
Calcium 15000 1544 103 103 85 - 115 20 EPA 2008 Mod
Chromium 70000 667 953 148 85 - 115 20 EPA 2008 Mod
Manganese 60000 596 994 175 85 - 115 20 EPA 2008 Mod
Iron 50000 4852 970 206 85 - 115 20 EPA 2008 Mod
Nickel 40000 402 IOI 0246 85 - 115 20 EPA 2008 Mod
Frontier Global Sciences Inc The results in his report only apply to the samples analyzed in accordance wirh the chain ofcustody document This analytical report must be reproduced in iLS entirety
Page 20of26 1201073 Final Report 04252012
Liz Siska Project Manager
22
11720 North Creek Parkway North Suite 400 ~~shy Bothell WA 98011 Ph 425-686-1996~ONTif Fx 425-686-3096
GLOBAL SCIENCES
LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLICATE
RECOVERY AND RPO
Batch F20327 l Sequence 2C22005
Preparation Closed Vessel Nitric Oven Digestion Lab Number F203271-BSBSD 1
LCS Source Blank Spike
Analyte
Spike Added (microgL)
LCSD Concentration
(microgL)
LCSD oo
Recovery
RPO Recovery
Limits RPO Limit Method Notes
Copper
Zinc
Arsenic
Selenium
40000
10000
15000
30000
428
1039
1452
3015
107
104
968
101
224
0570
0977
166
85 - 115
85 - 115
85 - 115
85 - 115
20
20
20
20
EPA 2008 Mod
EPA 2008 Mod
EPA 2008 Mod
EPA 2008 Mod Molybdenum
Silver
20000
15000
182
J502
910
100
0564
103
85 - 115
85 - 115
20
20
EPA 2008 Mod
EPA 2008 Mod Cadmium
Antimony
Barium
Lead
080000
080000
10000
15000
0828
0808
986
1620
103
101
986
108
585
0848
177
142
85 - 115
85 - 115
85 shy 11 S
85 - 115
20
20
20
20
EPA 2008 Mod
EPA 2008 Mod
EPA 2008 Mod
EPA 2008 Mod
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report mus be reproducedin its entirety
Page 2 o26J20J073 Final Report 041252012
Liz Siska Project Manager
23
11720 North Creek Parkway North Suite 400 Bothell WA 980 l l
Ph 425-686-1996FRONT[ER- Fx 425-686-3096 cLosAL SCIEN _CES
LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLICATE
RECOVERY AND RPD
Batch F203314 Sequence 2C25005
Preparation Closed Vessel Nitric Oven Digestion Lab Number F2033 l 4-BSBSD 1
LCS Source Blank Spike
Analyte
Thallium
Spike Added (microgL)
LCS Concentration
(microgL)
LCS 0o
Recovery Recovery
Limits Method
040000 0396 989 85 - 115 EPA 2008 Mod
Notes
Analyte
Spike Added (microgL)
LCSD Concentration
(microgL)
LCSD 0o
Recovery
RPD Recovery
Limits RPO Limit Method Notes
Thallium 040000 0391 978 112 85 - ll5 20 EPA 2008 Mod
Frontier Global Sciences Inc The results in this report only apply to the samples anayed in accordance with the chain ofcustody docwnenJ This analytical report must be reproduced in its entirety
Page 22of26 1201073 Final Report 04252012
Liz Siska Project Manager
24
Liz Siska P roject Manager
11720 North Creek Parkway North Suite 400
~ Bothell WA 98011 Ph 425-686-1996
~JTIEif middot Fx 425-686-3096 GLOBAL SCIENCES
PREPARATION BLANKS
Instrument Hg-17 Sequence 2A09010
Preparation BrCI Oxidation
Lab Sample ID Analyte Found MRL Units Batch Method Notes
F201063-BLK I Mercury -0009 050 ngL F201063 EPA 1631E u F20 I063-BLK2 Mercury -0006 050 ngL F201063 EPA 1631E u F201063-BLK3 Mercury -002 050 ngL F201063 EPA 163IE u F201063-BLK4 Mercury 003 050 ngL F201063 EPA 1631E U QB-04 F201063-BLKS Mercury 011 052 ngL F201063 EPA I631E U QB-06
Frontier Global Sciences Inc The results in this report only apply 10 1he samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Page 23 o26 1201073 Final Repon 04252012 25
Liz Siska Project Manager
11720 North Creek Parkway North Suite 400 Bothell WA 98011
Ph 425-686-1996 FROr~TIER- Fx 425-686-3096 GLOBAL SCIENCES
PREPARATION BLANKS
Instrument ICPMS-6 Sequence 2C22005
Preparation Closed Vessel Nitric Oven Digestion
Lab Sample ID Analyte Found MRL Units Batch Method Notes
F203271-BLK1 Beryllium 000008 0060 microgL F203271 PA 2008 Molt u F20327 1-BLK1 Sodium 2 20 microgL F20327l PA 2008 Moc u F20327I-BLK1 Aluminum -004 40 microgL F203271 PA 2008 Molt u F20327I -BLK1 Calcium 40 microgL F203271 PA 2008 Molt u F203271 -BLK1 Chromium -002 010 microgL F203271 ~A 2008 Molt u F203271-BLKI Manganese 001 010 microgL F203271 PA 2008 Molt u F20327 l -BLK 1 Iron -002 100 microgL F203271 PA 2008 Molt u F203271-BLKI Nickel 0004 010 microgL F203271 PA 2008 Moc u F203271-BLK1 Copper 0003 010 microgL F203271 PA 2008 Moc u F203271-BLK1 Zinc 0007 020 microgL F203271 PA 2008 Moc u F203271-BLK1 Arsenic -006 015 microgL F203271 PA 2008 Moc u F203271-BLK1 Selenium -002 060 microgL F203271 PA 2008 Moc u F203271-BLK1 Molybdenum 001 006 microgL F203271 PA 2008 Molt u F203271-BLK1 Silver -00005 0020 microgL F203271 PA 2008 Molt u F203271-BLKl Cadmium 0004 0020 microgL F203271 PA 2008 Molt u F20327 l-BLKl Antimony 0002 0020 microgL F203271 PA 2008 Molt u F203271-BLKI Barium 001 020 microgL F203271 PA 2008 Molt u F203271-BLKI Lead 0010 0040 microgL F203271 PA 2008 Moc u
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Page 24of26 1201073 Final Report 04252012 26
~
~TIER~ GLOBAL SCIENCES
11720 North Creek Parkway North Suite 400 Bothell WA 980ll
Ph 425-686-1996 Fx 425-686-3096
PREPARATION BLANKS
Instrument JCPMS-3 Sequence 2C25005
Preparation Closed Vessel Nitric Oven Digestion
Lab Sample ID Analyte Found MRL Units Batch Method Notes
F2033I4-BLK1 Thalium 00007 0010 microgL F2033I4 ~PA 2008 Molt u
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Page 25 o26Liz Siska Project Manager 1201073 Final Report
04252012 27
l l 720 North Creek Parkway North Suite 400~Vi-~ Bothell WA 98011 Ph 425-686-1 996~Tlmiddot~ Fx 425-686-3096
G L OBAL SCIENCE S
Notes and Definitions
U Analyte included in the analysis but not detected
QM-02 The MS andor MSD recoveries outside acceptance limits due to spike concentration less than I times the sample concentration The batch was accepted based on LCS and LCSD recoveries within control limits and when analysis permits acceptable AS ASD
QB-06 The blank was preserved to 5 BrCI rather than I The control limit for blanks preserved to greater than 1 BrCl is the preservation percentage multiplied by the MRL
QB-04 The blank was preserved to 2 BrCI rather than l The control limit for blanks preserved to greater than l BrCI is the preservation percentage multiplied by the MRL
FB-1631 Required equipmentfieldfilter blank not submitted by the client The sample has been analyzed according to 163 lE but does not meet 163 lE criteria
AS This MS andor MSD is an analytical spike andor an analytical spike duplicate
DET Analyte Detected
MDL Minimum Detection Limit
MRL Minimum Reporting Limit
ND Analyte Not Detected at or above the reporting limit
wet Sample results reported on a wet weight basis
dry Sample results reported on a dry weight basis
RPO Relative Percent Difference
RSD Relative Standard Deviation
Frontier Global Sciences Inc The lesults i111his reporl only apply to he samples analyzed In accordance with the chain ofcuslody document This analytical report must be reproduced in its entirely
Page 26of26 1201073 Final Report 04252012
Liz Siska Project Manager
28
CHAIN-OF-(USTODY ttECORD Page i of f 106677 _J
BoLD F1ELDS REQUIRED PLEASE C 1RCLE REQUESTED ANALYSIS
SAMPLE ID
middoti-rg -- bull ~rshy~ _- tzir +- lt-ltJ~ lt
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IF COMPOSITE INDICATE BOTH
START amp FINISH
DATETIME li1J oc -r 111_- _vlt-c_
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middot~ON Mm1x A-Al~ S-SOil GW-GampOUHO WATER SW-SUampfA(f WATER DWmiddotDRIIIKIKlti WATER
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PROJECT MANAGER llr middot1 ~Q Aw4---P1V- Het_ r COMPANY t-lo--tm ~ bd i ( I ~j 6 A ADP~SS 91 g~ez tJshy(ITJ ~ STATE fH_ ZIP c3o--
PHONE 22j-((omiddotf EXT ____
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PROJECT _
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REGULATORY PROGRAM NPDES RGP POTW STORHWATEl OR
GWP OIL FUHD BROWNIIELO OR OTHER----------
Quon PO o2J~-lt1Jpound)
DATE NEEDED _1--1 middot Z=-----shy4 (1-1_ METALS 8 RCRA 13 pp ff MN PB Cu
QAQC REPORTJNGYVEL
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eastern analytical inc 2s CHENELL D R1ve IC 0 Nco1to N H 0330 1 I TEL 60J22aos2s 1aoo2a1os2s IFAx 6032284591 j E-MA1t cus-roM111_mV1c~EAILAsscoMJ www1A1LAascoM
----i pmiddotofissionrrl11bomtorymim (WHITE ORIGINAL GREEN PROJECT MANAGER)
shy
l l 720 North Creek Parkway North Suite 400 Bothell WA 98011
Ph 425-686-1996FRONTIER Fx 425-686-3096 GLOBAL SCIENCES
MATRIX SPIKE I MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1201073-01RE4
Batch F203271 Sequence 2C22005
Preparation Closed Vessel Nitric Oven Digestion Lab Number F203271-MSMSD2
Sample Spike MS MS Concentration Added Concentration Oo RecoveryAnalyte (microgL) (microgL) (microgL) Recovery Method Limits Notes
Beryllium 0507 20200 2442 958 70 - 130 EPA 2008 Mod Sodium 258800 50500 257700 -213 70 -130 EPA 2008 Mod QM-02 Aluminum 529 15150 2023 986 70 - 130 EPA 2008 Mod Chromium 057 70700 804 106 70 - 130 EPA 2008 Mod Manganese 2805 60600 2834 476 70 - 130 EPA 2008 Mod QM-02 Iron ND 50500 5200 103 70 130 EPA 2008 Mod Nickel 979 40400 141 l 107 70- 130 EPA 2008 Mod Copper 055 40400 434 939 70 - 130 EPA 2008 Mod Zinc 040 10100 842 794 70 - 130 EPA 2008 Mod Arsenic 1030 15150 2418 916 70 - 130 EPA 2008 Mod Selenium 6340 30300 8973 869 70 130 EPA 2008 Mod Molybdenum 1338 20200 1367 142 70 130 EPA 2008 Mod QM-02 Silver ND 15150 1388 916 70 - 130 EPA 2008 Mod Cadmium 0332 080800 1105 middot956 70 - 130 EPA 2008 Mod Antimony 0408 080800 1259 105 70- 130 EPA 2008 Mod Barium 2397 10100 2495 968 70 - 130 EPA 2008 Mod Lead ND 15150 1542 102 70 130 EPA 2008 Mod
shy
shy
shy
shy
Analyte
Spike Added (microgL)
MSD Concentration
(microgL)
MSD Oo
Recovery
Oo
RPD Recovery
Limits RPD Limit Method Notes
Beryllium
Sodium
Aluminum
Chromium
Manganese
Iron
Nickel
Copper
Zinc
Arsenic
Selenium
Molybdenum
20200
50500
15150
7Q700
60600
50500
40400
40400
10100
15150
30300
20200
2561
257100
2034
773
2852
5187
1381
419
916
2225
9400
1366
102
-336
993
101 769
103
995
902
868
789
101
137
474
0243
0564
385
0625
0242
213
347
849
831
464
00771
70 - 130
70 bull 130 70 - 130
70 - 130
70 - 130
70 - 130
70 - 130
70 - 130
70 - 130
70 bull 130 70 - 130
70 - 130
20
20
20
20
20
20
20
20
20
20
20
20
EPA 2008 Mod
EPA 2008 Mod
EPA 2008 Mod
EPA 2008 Mod
EPA 2008 Mod
EPA 2008 Mod
EPA 2008 Mod
EPA 2008 Mod
EPA 2008 Mod
EPA 2008 Mod
EPA 2008 Mod
EPA 2008 Mod
QM-02
QM-02
Frontier G lobal Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
--f_~ --~~~-~ -middot middot Page 12 o261201073 Final Report 041252012
Liz Siska Project Manager
14
11720 North Creek Parkway North Suite 400
~ Bothell WA 98011
~TIEmiddot Ph 425-686-1996 Fx 425-686-3096
GLOB11L SCIENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPO
SOURCE 1201073-01RE4
Batch F203271 Sequence 2C22005
Preparation ~lo~ed Vessel Nitric Oven Digestion Lab Number F20327 I-MSMSD2
Spike MSD MSD Added Concentration Oo Recovery RPO
Analyte (microgL) (microgL) Recovery RPD Limits Limit Method Notes
Silver 15150 1387 915 00874 70 - 130 20 EPA 2008 Mod Cadmium 080800 1061 902 403 70 - 130 20 EPA 200amp Mod Antimony 080800 1274 107 l2l 70 - 130 20 EPA 2008 Mod Barium 10100 2514 )16 0781 70 - 130 20 EPA 200amp Mod Lead 15150 1534 101 0525 70 shy 130 20 EPA 2008 Mod
Frontier Global Sciences Inc The results in this report only apply to 1he samples analyzed in accordance wiih the chain ofcustody document This analytical repo1 must be reproduced in ils entirety
Page 13 o26Liz Siska Project Manager 1201073 Final Reporl
04252012 15
11720 North Creek Parkway North Suite 400
~ Bothell WA 98011 Ph 425-686-I996
~RONTIER~ Fx 425-686-3096 GLOBAL SCIEN C ES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1201073-01RE3
Batch F203271 Sequence 2~22005
Preparation Closed Vessel Nitric Oven Digestion Lab Number F20327 I-MSMSD3
Sample Spike MS MS
Analyte Concentration
(microgL) Added (microgL)
Concentration (microgL) Recovery
Recovery Limits Method Notes
Calcium 5013000 10100000 15120000 100 70- 130 EPA 2008 Mod AS
Spike MSD MSD Added Concentration o Oo Recovery RPD
Analyte (microgL) (microgL) Recovery RPD Limits Limit Method Notes
Calcium 10100000 16140000 llO 653 70 - 130 20 EPA 2008 Mod AS
Frontier Global Sciences Inc The results in his report only apply 10 the samples analyzed in accordance ivth he chain ofcustody document This analytical report must be reproduced in its entirety
Page 14 o261201073 Final Report 0425201]
Liz Siska Project Manager
16
Frontier Global Sciences Inc The ruults in this rechain ofcustody do
~ -lt1-c--~ Liz Siska Project Manager
11720 North Creek Parkway North Suite 400 Bothell WA 98011
Ph 425-686-1996 Fx 425-686-3096
GLOBAL SCIENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1201073-01RE4
Batch J203271 Sequence 2C22005
Preparation ~ IQsed Ve~~el Nitric Oven Qigestion Lab Number F203271-MSMSQ4
Analyte
Beryllium
Sample Concentration
(11gL)
0507
Spike Added (11gL)
20200
MS Concentration
(microgL)
2041
MS Oo
Recovery
985
RecoveryMethod Limits
70 - 130 EPA 2008 Mod
Notes
AS
Sodium 258800 40400 292900 845 70- 130 EPA 2008 Mod AS
Aluminum 529 40400 3956 966 70 - 130 EPA 2008 Mod AS
Chromium 057 40400 430l 106 70- 130 EPA 2008 Mod AS
Manganese 2805 40400 7042 105 70 - 130 EPA 2008 Mod AS
Iron ND 20200 2121 105 70 - 130 EPA 2008 Mod AS
Nickel 979 50500 5112 993 70 l30 EPA 2008 Mod AS
Copper 055 50500 4754 940 70 - 130 EPA 2008 Mod AS
Zinc 040 10100 9074 898 70 - 130 EPA 2008 Mod AS
Arsenic 1030 40400 4317 104 70 130 EPA 2008 Mod AS
Selenium 6340 40400 4688 100 70 - 130 EPA 2008 Mod AS
Molybdenum 1338 20200 338l 101 70 - 130 EPA 2008 Mod AS
Silver ND 20200 1850 916 70 130 EPA 2008 Mod AS
Cadmium 0332 40400 3937 966 70 130 EPA 2008 Mod AS
Antimony 0408 20200 2091 102 70 - 130 EPA 2008 Mod AS
Barium 2397 80800 1056 101 70- 130 EPA 2008 Mod AS
Lead ND IO100 9932 983 70 130 EPA 2008 Mod AS
shy
shy
shy
shy
shy
Analyte
Spike Added (microgL)
MSD Concentration
(microgL)
MSD
Recovery
RPD
Recovery Limits
RPDLimit Method Notes
Beryllium 20200 2007 968 l71 70 - 130 20 EPA 2008 Mod AS Sodium 40400 292600 837 0114 70 130 20 EPA 2008 Mod AS Aluminum 40400 3954 966 00362 70 - 130 20 EPA 2008 Mod AS Chromium 40400 4287 106 0337 70 - 130 20 EPA 2008 Mod AS Manganese 40400 6944 102 140 70 - 130 20 EPA 2008 Mod AS Iron 20200 2077 103 211 70 - 130 20 EPA 2008 Mod AS Nickel 50500 5126 996 0276 70 - 130 20 EPA 2008 Mod AS Copper 50500 4707 931 0997 70 - 130 20 EPA 200 8 Mod AS Zinc 10100 9059 896 0166 70 - 130 20 EPA 2008 Mod AS Arsenic 40400 4299 104 0419 70 - 130 20 EPA 2008 Mod AS Selenium 40400 4682 100 0141 70 - 130 20 EPA 2008 Mod AS Molybdenum 20200 3365 100 0473 70 - 130 20 EPA 2008 Mod AS
shy
port only apply to the sampltts analyzed in accordance with the cument This analytical report must be reproduced in its entirety
Page 5 o26 201073 Final Report 042512012 17
Liz Sia Project Manager
11720 North Creek Parkway North Suite 400 Botheln VA 98011
Ph 425-686-1996 Fx 425-686-3096
CLOBAL SCIENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1201073-01RE4
Batch F203271 Sequence 2c2io2~
Preparation Clo~ed Vessel litric Oven Digestion Lab Number F20327 l -MSMSQ4
Analyte
Spike Added (microgL)
MSD Concentration
(microgL)
MSD
Recovery
Oo
RPD Recovery
Limits RPOLimit Method Notes
Silver 20200 1895 938 242 70 - 130 20 EPA 2008 Mod AS Cadmium 40400 3933 965 0104 70 -130 20 EPA 2008 Mod AS Antimony 20200 2107 102 0736 70- 130 20 EPA 2008 Mod AS
Barium 80800 1058 101 0205 70 - 130 20 EPA 2008 Mod AS
Lead 10100 9877 978 0549 70 - 130 20 EPA 2008 Mod AS
Frontier Global Sciences Inc The results in this report only apply to the samples analyudin accordance with lht chain ofcustody document This analytical report must be reproductd rn ilS enlirtty
Page l6of26 1201073 Final Report Ofn5202 18
l I 720 North Creek Parkway North Suite 400 Bothell WA 980I I
Ph 425-686-1996 Fx 425-686-3096
GLO B AL SCIENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1201073-01RE6
Batch F203314 Sequence 2C25005
Preparation Closed Vessel Nitric Oven Digestion Lab Number F203314-MSMSD2
Sample Spike MS MS Concentration Added Concentration RecoveryAnalyte (microgL) (microgL) (microgL) Recovery Method NotesLimits
Thallium 5563 040400 5875 773 70 - 130 EPA 2008 Mod
Spike MSD MSD Added o Concentration Recovery RPD
RPO Limits Limit Method Notes Analyte (microgL) (microgL) Recovery
Thallium 040400 5880 785 00859 70 - 130 20 EPA 2008 Mod
Frontier Global Sciences Inc 11e results in chis reporc only apply 10 1he samples analyzed in accordance wilh lhe chain ofcustody documenz This analycical report musl be reproduced in ils entirety
Page 17 of26 1201073 Fi11aReport 0412512012
Liz Siska Project Manager
19
11720 North Creek Parkway North Suite 400 Bothell WA 98011
Ph 425-686-1996 Fx 425-686-3096
GLOBAl SCIENC ES
MATRIX SPIKE I MATRIX SPIKE DUPLICATE RECOVERY AND RPO
SOURCE I201073-01RE6
Batch F203314
Preparation Closed Vessel Nitric Oven Digestion
Sequence 2C25005
Lab Number F203314-MSMSD4
Analyte
Sample Concentration
(microgL)
Spike Added (microgL)
MS MS Concentration Oo
(microgL) Recovery Recovery
Limits Method Notes
Thallium 5563 10100 1033 968 70- 130 EPA 2008 Mod AS
Analyte
Spike Added (microgL)
MSD Concentration
(microgL)
MS)) Oo
Recovery
RPD
Recovery Limits
RPD Limit Method Notes
Thallium IO100 1037 97l 0341 70 - 130 20 EPA 2008 Mod AS
Frontier Global Sciences Inc The resulrs in this report only apply to the samples analyzed in accordance with the chain ofcusrody document This analytical report must be reproduced in its entirely
Page 18of26 120073 Final Report 04252012
Liz Siska Project Manager
20
11720 North Creek Parkway North Suite 400 l ~ Bothell WA 980 l l Ph 425-686-1996
FRONTIER Fx 425-686-3096 GLOBAL SCIENCES
LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLICATE
RECOVERY AND RPD
Batch F20 l063 Sequence 2A09010
Preparation BrCI Oxidation Lab Number F201063-BSIBSJ21
LCS Source N ist 1641d
Analyte
Spike Added (ngL)
LCS Concentration
(ngL)
LCS
Recovery Recovery
Limits Method Notes
Mercury 15679 1550 988 80 - 120 EPA I631E
Analyte
Spike Added (ngL)
LCSD Concentration
(ngL)
LCSD Oo
Recovery
RPD Recovery
Limits RPD Limit Method Notes
Mercury 15679 1595 [02 289 80 - 120 24 EPA I631E
Frontier Global Sciences Inc The results in this report only apply to the samples analyzedin accordance with the chain ofcustody document This analytical report must be reproduced in ils entirety
Page 19of26 1201073 Final Report 0425 2012
Liz Siska Project Manager
21
11720 North Creek Parkway North Suite 400 Bothell WA 98011
Ph 425-686-1996 FRONTIER Fx 425-686-3096 GLOBAL SCIENCES
LABORA TORY CONTROL SAMPLE LABO RATORY CONTROL SAMPLE DUPLICATE
RECOVERY AND RPD
Batch F203271 Sequence 2C22005
Preparation Closed Vessel Nitric Oven Digestion Lab Number F203271-BSBSD1
LCS Source Blank Spike
Spike LCS LCS Added Concentration Oo Recovery
Analyte (microgL) (microgL) Recovery Limits Method Notes
Beryllium 20000 l930 965 85 - 115 EPA 2008 Mod
Sodium 50000 499 998 85 - 115 EPA 2008 Mod
Aluminum 15000 1460 973 85 - 115 EPA 2008 Mod
Calcium 15000 1528 102 85 - 115 EPA 2008 Mod
Chromium 70000 657 939 85 - 115 EPA 2008 Mod
Manganese 60000 586 976 85 - 115 EPA 2008 Mod
Iron 50000 4753 951 85 shy 115 EPA 2008 Mod
Nickel 40000 401 100 85 - 115 EPA 2008 Mod
Copper 40000 418 105 85 - 115 EPA 2008 Mod
Zinc 10000 1033 103 85 - 115 EPA 2008 Mod
Arsenic 15000 1437 958 85 - 115 EPA 2008 Mod
Selenium 30000 2966 989 85 - 115 EPA 2008 Mod
Molybdenum 20000 181 905 85 shy 115 EPA 2008 Mod
Silver 15000 1517 101 85 shy 115 EPA 2008 Mod
Cadmium 080000 0781 976 85 - 1lS EPA 2008 Mod
Antimony 080000 0815 102 85 - 115 EPA 2008 Mod
Barium 10000 969 969 85 - 115 EPA 2008 Mod
Lead 15000 1597 106 85 - 115 EPA 2008 Mod
Spike LCSD LCSD Added Concentration Recovery RPO
Analyte (microgL) (microgL) Recovery RPO Limits Limit Method Notes
Beryllium 20000 1949 974 0955 85 - 115 20 EPA 2008 Mod
Sodium 50000 500 100 0216 85 - 115 20 EPA 2008 Mod
Aluminum 15000 1485 990 171 85 - 115 20 EPA 2008 Mod
Calcium 15000 1544 103 103 85 - 115 20 EPA 2008 Mod
Chromium 70000 667 953 148 85 - 115 20 EPA 2008 Mod
Manganese 60000 596 994 175 85 - 115 20 EPA 2008 Mod
Iron 50000 4852 970 206 85 - 115 20 EPA 2008 Mod
Nickel 40000 402 IOI 0246 85 - 115 20 EPA 2008 Mod
Frontier Global Sciences Inc The results in his report only apply to the samples analyzed in accordance wirh the chain ofcustody document This analytical report must be reproduced in iLS entirety
Page 20of26 1201073 Final Report 04252012
Liz Siska Project Manager
22
11720 North Creek Parkway North Suite 400 ~~shy Bothell WA 98011 Ph 425-686-1996~ONTif Fx 425-686-3096
GLOBAL SCIENCES
LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLICATE
RECOVERY AND RPO
Batch F20327 l Sequence 2C22005
Preparation Closed Vessel Nitric Oven Digestion Lab Number F203271-BSBSD 1
LCS Source Blank Spike
Analyte
Spike Added (microgL)
LCSD Concentration
(microgL)
LCSD oo
Recovery
RPO Recovery
Limits RPO Limit Method Notes
Copper
Zinc
Arsenic
Selenium
40000
10000
15000
30000
428
1039
1452
3015
107
104
968
101
224
0570
0977
166
85 - 115
85 - 115
85 - 115
85 - 115
20
20
20
20
EPA 2008 Mod
EPA 2008 Mod
EPA 2008 Mod
EPA 2008 Mod Molybdenum
Silver
20000
15000
182
J502
910
100
0564
103
85 - 115
85 - 115
20
20
EPA 2008 Mod
EPA 2008 Mod Cadmium
Antimony
Barium
Lead
080000
080000
10000
15000
0828
0808
986
1620
103
101
986
108
585
0848
177
142
85 - 115
85 - 115
85 shy 11 S
85 - 115
20
20
20
20
EPA 2008 Mod
EPA 2008 Mod
EPA 2008 Mod
EPA 2008 Mod
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report mus be reproducedin its entirety
Page 2 o26J20J073 Final Report 041252012
Liz Siska Project Manager
23
11720 North Creek Parkway North Suite 400 Bothell WA 980 l l
Ph 425-686-1996FRONT[ER- Fx 425-686-3096 cLosAL SCIEN _CES
LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLICATE
RECOVERY AND RPD
Batch F203314 Sequence 2C25005
Preparation Closed Vessel Nitric Oven Digestion Lab Number F2033 l 4-BSBSD 1
LCS Source Blank Spike
Analyte
Thallium
Spike Added (microgL)
LCS Concentration
(microgL)
LCS 0o
Recovery Recovery
Limits Method
040000 0396 989 85 - 115 EPA 2008 Mod
Notes
Analyte
Spike Added (microgL)
LCSD Concentration
(microgL)
LCSD 0o
Recovery
RPD Recovery
Limits RPO Limit Method Notes
Thallium 040000 0391 978 112 85 - ll5 20 EPA 2008 Mod
Frontier Global Sciences Inc The results in this report only apply to the samples anayed in accordance with the chain ofcustody docwnenJ This analytical report must be reproduced in its entirety
Page 22of26 1201073 Final Report 04252012
Liz Siska Project Manager
24
Liz Siska P roject Manager
11720 North Creek Parkway North Suite 400
~ Bothell WA 98011 Ph 425-686-1996
~JTIEif middot Fx 425-686-3096 GLOBAL SCIENCES
PREPARATION BLANKS
Instrument Hg-17 Sequence 2A09010
Preparation BrCI Oxidation
Lab Sample ID Analyte Found MRL Units Batch Method Notes
F201063-BLK I Mercury -0009 050 ngL F201063 EPA 1631E u F20 I063-BLK2 Mercury -0006 050 ngL F201063 EPA 1631E u F201063-BLK3 Mercury -002 050 ngL F201063 EPA 163IE u F201063-BLK4 Mercury 003 050 ngL F201063 EPA 1631E U QB-04 F201063-BLKS Mercury 011 052 ngL F201063 EPA I631E U QB-06
Frontier Global Sciences Inc The results in this report only apply 10 1he samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Page 23 o26 1201073 Final Repon 04252012 25
Liz Siska Project Manager
11720 North Creek Parkway North Suite 400 Bothell WA 98011
Ph 425-686-1996 FROr~TIER- Fx 425-686-3096 GLOBAL SCIENCES
PREPARATION BLANKS
Instrument ICPMS-6 Sequence 2C22005
Preparation Closed Vessel Nitric Oven Digestion
Lab Sample ID Analyte Found MRL Units Batch Method Notes
F203271-BLK1 Beryllium 000008 0060 microgL F203271 PA 2008 Molt u F20327 1-BLK1 Sodium 2 20 microgL F20327l PA 2008 Moc u F20327I-BLK1 Aluminum -004 40 microgL F203271 PA 2008 Molt u F20327I -BLK1 Calcium 40 microgL F203271 PA 2008 Molt u F203271 -BLK1 Chromium -002 010 microgL F203271 ~A 2008 Molt u F203271-BLKI Manganese 001 010 microgL F203271 PA 2008 Molt u F20327 l -BLK 1 Iron -002 100 microgL F203271 PA 2008 Molt u F203271-BLKI Nickel 0004 010 microgL F203271 PA 2008 Moc u F203271-BLK1 Copper 0003 010 microgL F203271 PA 2008 Moc u F203271-BLK1 Zinc 0007 020 microgL F203271 PA 2008 Moc u F203271-BLK1 Arsenic -006 015 microgL F203271 PA 2008 Moc u F203271-BLK1 Selenium -002 060 microgL F203271 PA 2008 Moc u F203271-BLK1 Molybdenum 001 006 microgL F203271 PA 2008 Molt u F203271-BLK1 Silver -00005 0020 microgL F203271 PA 2008 Molt u F203271-BLKl Cadmium 0004 0020 microgL F203271 PA 2008 Molt u F20327 l-BLKl Antimony 0002 0020 microgL F203271 PA 2008 Molt u F203271-BLKI Barium 001 020 microgL F203271 PA 2008 Molt u F203271-BLKI Lead 0010 0040 microgL F203271 PA 2008 Moc u
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Page 24of26 1201073 Final Report 04252012 26
~
~TIER~ GLOBAL SCIENCES
11720 North Creek Parkway North Suite 400 Bothell WA 980ll
Ph 425-686-1996 Fx 425-686-3096
PREPARATION BLANKS
Instrument JCPMS-3 Sequence 2C25005
Preparation Closed Vessel Nitric Oven Digestion
Lab Sample ID Analyte Found MRL Units Batch Method Notes
F2033I4-BLK1 Thalium 00007 0010 microgL F2033I4 ~PA 2008 Molt u
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Page 25 o26Liz Siska Project Manager 1201073 Final Report
04252012 27
l l 720 North Creek Parkway North Suite 400~Vi-~ Bothell WA 98011 Ph 425-686-1 996~Tlmiddot~ Fx 425-686-3096
G L OBAL SCIENCE S
Notes and Definitions
U Analyte included in the analysis but not detected
QM-02 The MS andor MSD recoveries outside acceptance limits due to spike concentration less than I times the sample concentration The batch was accepted based on LCS and LCSD recoveries within control limits and when analysis permits acceptable AS ASD
QB-06 The blank was preserved to 5 BrCI rather than I The control limit for blanks preserved to greater than 1 BrCl is the preservation percentage multiplied by the MRL
QB-04 The blank was preserved to 2 BrCI rather than l The control limit for blanks preserved to greater than l BrCI is the preservation percentage multiplied by the MRL
FB-1631 Required equipmentfieldfilter blank not submitted by the client The sample has been analyzed according to 163 lE but does not meet 163 lE criteria
AS This MS andor MSD is an analytical spike andor an analytical spike duplicate
DET Analyte Detected
MDL Minimum Detection Limit
MRL Minimum Reporting Limit
ND Analyte Not Detected at or above the reporting limit
wet Sample results reported on a wet weight basis
dry Sample results reported on a dry weight basis
RPO Relative Percent Difference
RSD Relative Standard Deviation
Frontier Global Sciences Inc The lesults i111his reporl only apply to he samples analyzed In accordance with the chain ofcuslody document This analytical report must be reproduced in its entirely
Page 26of26 1201073 Final Report 04252012
Liz Siska Project Manager
28
CHAIN-OF-(USTODY ttECORD Page i of f 106677 _J
BoLD F1ELDS REQUIRED PLEASE C 1RCLE REQUESTED ANALYSIS
SAMPLE ID
middoti-rg -- bull ~rshy~ _- tzir +- lt-ltJ~ lt
SAMPLING
DATeTtME
IF COMPOSITE INDICATE BOTH
START amp FINISH
DATETIME li1J oc -r 111_- _vlt-c_
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middot~ON Mm1x A-Al~ S-SOil GW-GampOUHO WATER SW-SUampfA(f WATER DWmiddotDRIIIKIKlti WATER
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PROJECT MANAGER llr middot1 ~Q Aw4---P1V- Het_ r COMPANY t-lo--tm ~ bd i ( I ~j 6 A ADP~SS 91 g~ez tJshy(ITJ ~ STATE fH_ ZIP c3o--
PHONE 22j-((omiddotf EXT ____
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PROJECT _
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REGULATORY PROGRAM NPDES RGP POTW STORHWATEl OR
GWP OIL FUHD BROWNIIELO OR OTHER----------
Quon PO o2J~-lt1Jpound)
DATE NEEDED _1--1 middot Z=-----shy4 (1-1_ METALS 8 RCRA 13 pp ff MN PB Cu
QAQC REPORTJNGYVEL
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DISSOLVED METALS FIELD FllTEREDI YES 110
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IF YH FAX OR POf 7~shy Hom (IE SPECIAL DETECTION LINITl BllLIKGINfO If DlffERrnT)ELECTRONIC OPTIONS zo 1 2 2) le~C1 1 Jc Id sJ 60 6c
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ImiddotRELINQUISHED BY DATE TIHE RECflVEO BY I FIELD READINGS
eastern analytical inc 2s CHENELL D R1ve IC 0 Nco1to N H 0330 1 I TEL 60J22aos2s 1aoo2a1os2s IFAx 6032284591 j E-MA1t cus-roM111_mV1c~EAILAsscoMJ www1A1LAascoM
----i pmiddotofissionrrl11bomtorymim (WHITE ORIGINAL GREEN PROJECT MANAGER)
shy
11720 North Creek Parkway North Suite 400
~ Bothell WA 98011
~TIEmiddot Ph 425-686-1996 Fx 425-686-3096
GLOB11L SCIENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPO
SOURCE 1201073-01RE4
Batch F203271 Sequence 2C22005
Preparation ~lo~ed Vessel Nitric Oven Digestion Lab Number F20327 I-MSMSD2
Spike MSD MSD Added Concentration Oo Recovery RPO
Analyte (microgL) (microgL) Recovery RPD Limits Limit Method Notes
Silver 15150 1387 915 00874 70 - 130 20 EPA 2008 Mod Cadmium 080800 1061 902 403 70 - 130 20 EPA 200amp Mod Antimony 080800 1274 107 l2l 70 - 130 20 EPA 2008 Mod Barium 10100 2514 )16 0781 70 - 130 20 EPA 200amp Mod Lead 15150 1534 101 0525 70 shy 130 20 EPA 2008 Mod
Frontier Global Sciences Inc The results in this report only apply to 1he samples analyzed in accordance wiih the chain ofcustody document This analytical repo1 must be reproduced in ils entirety
Page 13 o26Liz Siska Project Manager 1201073 Final Reporl
04252012 15
11720 North Creek Parkway North Suite 400
~ Bothell WA 98011 Ph 425-686-I996
~RONTIER~ Fx 425-686-3096 GLOBAL SCIEN C ES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1201073-01RE3
Batch F203271 Sequence 2~22005
Preparation Closed Vessel Nitric Oven Digestion Lab Number F20327 I-MSMSD3
Sample Spike MS MS
Analyte Concentration
(microgL) Added (microgL)
Concentration (microgL) Recovery
Recovery Limits Method Notes
Calcium 5013000 10100000 15120000 100 70- 130 EPA 2008 Mod AS
Spike MSD MSD Added Concentration o Oo Recovery RPD
Analyte (microgL) (microgL) Recovery RPD Limits Limit Method Notes
Calcium 10100000 16140000 llO 653 70 - 130 20 EPA 2008 Mod AS
Frontier Global Sciences Inc The results in his report only apply 10 the samples analyzed in accordance ivth he chain ofcustody document This analytical report must be reproduced in its entirety
Page 14 o261201073 Final Report 0425201]
Liz Siska Project Manager
16
Frontier Global Sciences Inc The ruults in this rechain ofcustody do
~ -lt1-c--~ Liz Siska Project Manager
11720 North Creek Parkway North Suite 400 Bothell WA 98011
Ph 425-686-1996 Fx 425-686-3096
GLOBAL SCIENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1201073-01RE4
Batch J203271 Sequence 2C22005
Preparation ~ IQsed Ve~~el Nitric Oven Qigestion Lab Number F203271-MSMSQ4
Analyte
Beryllium
Sample Concentration
(11gL)
0507
Spike Added (11gL)
20200
MS Concentration
(microgL)
2041
MS Oo
Recovery
985
RecoveryMethod Limits
70 - 130 EPA 2008 Mod
Notes
AS
Sodium 258800 40400 292900 845 70- 130 EPA 2008 Mod AS
Aluminum 529 40400 3956 966 70 - 130 EPA 2008 Mod AS
Chromium 057 40400 430l 106 70- 130 EPA 2008 Mod AS
Manganese 2805 40400 7042 105 70 - 130 EPA 2008 Mod AS
Iron ND 20200 2121 105 70 - 130 EPA 2008 Mod AS
Nickel 979 50500 5112 993 70 l30 EPA 2008 Mod AS
Copper 055 50500 4754 940 70 - 130 EPA 2008 Mod AS
Zinc 040 10100 9074 898 70 - 130 EPA 2008 Mod AS
Arsenic 1030 40400 4317 104 70 130 EPA 2008 Mod AS
Selenium 6340 40400 4688 100 70 - 130 EPA 2008 Mod AS
Molybdenum 1338 20200 338l 101 70 - 130 EPA 2008 Mod AS
Silver ND 20200 1850 916 70 130 EPA 2008 Mod AS
Cadmium 0332 40400 3937 966 70 130 EPA 2008 Mod AS
Antimony 0408 20200 2091 102 70 - 130 EPA 2008 Mod AS
Barium 2397 80800 1056 101 70- 130 EPA 2008 Mod AS
Lead ND IO100 9932 983 70 130 EPA 2008 Mod AS
shy
shy
shy
shy
shy
Analyte
Spike Added (microgL)
MSD Concentration
(microgL)
MSD
Recovery
RPD
Recovery Limits
RPDLimit Method Notes
Beryllium 20200 2007 968 l71 70 - 130 20 EPA 2008 Mod AS Sodium 40400 292600 837 0114 70 130 20 EPA 2008 Mod AS Aluminum 40400 3954 966 00362 70 - 130 20 EPA 2008 Mod AS Chromium 40400 4287 106 0337 70 - 130 20 EPA 2008 Mod AS Manganese 40400 6944 102 140 70 - 130 20 EPA 2008 Mod AS Iron 20200 2077 103 211 70 - 130 20 EPA 2008 Mod AS Nickel 50500 5126 996 0276 70 - 130 20 EPA 2008 Mod AS Copper 50500 4707 931 0997 70 - 130 20 EPA 200 8 Mod AS Zinc 10100 9059 896 0166 70 - 130 20 EPA 2008 Mod AS Arsenic 40400 4299 104 0419 70 - 130 20 EPA 2008 Mod AS Selenium 40400 4682 100 0141 70 - 130 20 EPA 2008 Mod AS Molybdenum 20200 3365 100 0473 70 - 130 20 EPA 2008 Mod AS
shy
port only apply to the sampltts analyzed in accordance with the cument This analytical report must be reproduced in its entirety
Page 5 o26 201073 Final Report 042512012 17
Liz Sia Project Manager
11720 North Creek Parkway North Suite 400 Botheln VA 98011
Ph 425-686-1996 Fx 425-686-3096
CLOBAL SCIENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1201073-01RE4
Batch F203271 Sequence 2c2io2~
Preparation Clo~ed Vessel litric Oven Digestion Lab Number F20327 l -MSMSQ4
Analyte
Spike Added (microgL)
MSD Concentration
(microgL)
MSD
Recovery
Oo
RPD Recovery
Limits RPOLimit Method Notes
Silver 20200 1895 938 242 70 - 130 20 EPA 2008 Mod AS Cadmium 40400 3933 965 0104 70 -130 20 EPA 2008 Mod AS Antimony 20200 2107 102 0736 70- 130 20 EPA 2008 Mod AS
Barium 80800 1058 101 0205 70 - 130 20 EPA 2008 Mod AS
Lead 10100 9877 978 0549 70 - 130 20 EPA 2008 Mod AS
Frontier Global Sciences Inc The results in this report only apply to the samples analyudin accordance with lht chain ofcustody document This analytical report must be reproductd rn ilS enlirtty
Page l6of26 1201073 Final Report Ofn5202 18
l I 720 North Creek Parkway North Suite 400 Bothell WA 980I I
Ph 425-686-1996 Fx 425-686-3096
GLO B AL SCIENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1201073-01RE6
Batch F203314 Sequence 2C25005
Preparation Closed Vessel Nitric Oven Digestion Lab Number F203314-MSMSD2
Sample Spike MS MS Concentration Added Concentration RecoveryAnalyte (microgL) (microgL) (microgL) Recovery Method NotesLimits
Thallium 5563 040400 5875 773 70 - 130 EPA 2008 Mod
Spike MSD MSD Added o Concentration Recovery RPD
RPO Limits Limit Method Notes Analyte (microgL) (microgL) Recovery
Thallium 040400 5880 785 00859 70 - 130 20 EPA 2008 Mod
Frontier Global Sciences Inc 11e results in chis reporc only apply 10 1he samples analyzed in accordance wilh lhe chain ofcustody documenz This analycical report musl be reproduced in ils entirety
Page 17 of26 1201073 Fi11aReport 0412512012
Liz Siska Project Manager
19
11720 North Creek Parkway North Suite 400 Bothell WA 98011
Ph 425-686-1996 Fx 425-686-3096
GLOBAl SCIENC ES
MATRIX SPIKE I MATRIX SPIKE DUPLICATE RECOVERY AND RPO
SOURCE I201073-01RE6
Batch F203314
Preparation Closed Vessel Nitric Oven Digestion
Sequence 2C25005
Lab Number F203314-MSMSD4
Analyte
Sample Concentration
(microgL)
Spike Added (microgL)
MS MS Concentration Oo
(microgL) Recovery Recovery
Limits Method Notes
Thallium 5563 10100 1033 968 70- 130 EPA 2008 Mod AS
Analyte
Spike Added (microgL)
MSD Concentration
(microgL)
MS)) Oo
Recovery
RPD
Recovery Limits
RPD Limit Method Notes
Thallium IO100 1037 97l 0341 70 - 130 20 EPA 2008 Mod AS
Frontier Global Sciences Inc The resulrs in this report only apply to the samples analyzed in accordance with the chain ofcusrody document This analytical report must be reproduced in its entirely
Page 18of26 120073 Final Report 04252012
Liz Siska Project Manager
20
11720 North Creek Parkway North Suite 400 l ~ Bothell WA 980 l l Ph 425-686-1996
FRONTIER Fx 425-686-3096 GLOBAL SCIENCES
LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLICATE
RECOVERY AND RPD
Batch F20 l063 Sequence 2A09010
Preparation BrCI Oxidation Lab Number F201063-BSIBSJ21
LCS Source N ist 1641d
Analyte
Spike Added (ngL)
LCS Concentration
(ngL)
LCS
Recovery Recovery
Limits Method Notes
Mercury 15679 1550 988 80 - 120 EPA I631E
Analyte
Spike Added (ngL)
LCSD Concentration
(ngL)
LCSD Oo
Recovery
RPD Recovery
Limits RPD Limit Method Notes
Mercury 15679 1595 [02 289 80 - 120 24 EPA I631E
Frontier Global Sciences Inc The results in this report only apply to the samples analyzedin accordance with the chain ofcustody document This analytical report must be reproduced in ils entirety
Page 19of26 1201073 Final Report 0425 2012
Liz Siska Project Manager
21
11720 North Creek Parkway North Suite 400 Bothell WA 98011
Ph 425-686-1996 FRONTIER Fx 425-686-3096 GLOBAL SCIENCES
LABORA TORY CONTROL SAMPLE LABO RATORY CONTROL SAMPLE DUPLICATE
RECOVERY AND RPD
Batch F203271 Sequence 2C22005
Preparation Closed Vessel Nitric Oven Digestion Lab Number F203271-BSBSD1
LCS Source Blank Spike
Spike LCS LCS Added Concentration Oo Recovery
Analyte (microgL) (microgL) Recovery Limits Method Notes
Beryllium 20000 l930 965 85 - 115 EPA 2008 Mod
Sodium 50000 499 998 85 - 115 EPA 2008 Mod
Aluminum 15000 1460 973 85 - 115 EPA 2008 Mod
Calcium 15000 1528 102 85 - 115 EPA 2008 Mod
Chromium 70000 657 939 85 - 115 EPA 2008 Mod
Manganese 60000 586 976 85 - 115 EPA 2008 Mod
Iron 50000 4753 951 85 shy 115 EPA 2008 Mod
Nickel 40000 401 100 85 - 115 EPA 2008 Mod
Copper 40000 418 105 85 - 115 EPA 2008 Mod
Zinc 10000 1033 103 85 - 115 EPA 2008 Mod
Arsenic 15000 1437 958 85 - 115 EPA 2008 Mod
Selenium 30000 2966 989 85 - 115 EPA 2008 Mod
Molybdenum 20000 181 905 85 shy 115 EPA 2008 Mod
Silver 15000 1517 101 85 shy 115 EPA 2008 Mod
Cadmium 080000 0781 976 85 - 1lS EPA 2008 Mod
Antimony 080000 0815 102 85 - 115 EPA 2008 Mod
Barium 10000 969 969 85 - 115 EPA 2008 Mod
Lead 15000 1597 106 85 - 115 EPA 2008 Mod
Spike LCSD LCSD Added Concentration Recovery RPO
Analyte (microgL) (microgL) Recovery RPO Limits Limit Method Notes
Beryllium 20000 1949 974 0955 85 - 115 20 EPA 2008 Mod
Sodium 50000 500 100 0216 85 - 115 20 EPA 2008 Mod
Aluminum 15000 1485 990 171 85 - 115 20 EPA 2008 Mod
Calcium 15000 1544 103 103 85 - 115 20 EPA 2008 Mod
Chromium 70000 667 953 148 85 - 115 20 EPA 2008 Mod
Manganese 60000 596 994 175 85 - 115 20 EPA 2008 Mod
Iron 50000 4852 970 206 85 - 115 20 EPA 2008 Mod
Nickel 40000 402 IOI 0246 85 - 115 20 EPA 2008 Mod
Frontier Global Sciences Inc The results in his report only apply to the samples analyzed in accordance wirh the chain ofcustody document This analytical report must be reproduced in iLS entirety
Page 20of26 1201073 Final Report 04252012
Liz Siska Project Manager
22
11720 North Creek Parkway North Suite 400 ~~shy Bothell WA 98011 Ph 425-686-1996~ONTif Fx 425-686-3096
GLOBAL SCIENCES
LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLICATE
RECOVERY AND RPO
Batch F20327 l Sequence 2C22005
Preparation Closed Vessel Nitric Oven Digestion Lab Number F203271-BSBSD 1
LCS Source Blank Spike
Analyte
Spike Added (microgL)
LCSD Concentration
(microgL)
LCSD oo
Recovery
RPO Recovery
Limits RPO Limit Method Notes
Copper
Zinc
Arsenic
Selenium
40000
10000
15000
30000
428
1039
1452
3015
107
104
968
101
224
0570
0977
166
85 - 115
85 - 115
85 - 115
85 - 115
20
20
20
20
EPA 2008 Mod
EPA 2008 Mod
EPA 2008 Mod
EPA 2008 Mod Molybdenum
Silver
20000
15000
182
J502
910
100
0564
103
85 - 115
85 - 115
20
20
EPA 2008 Mod
EPA 2008 Mod Cadmium
Antimony
Barium
Lead
080000
080000
10000
15000
0828
0808
986
1620
103
101
986
108
585
0848
177
142
85 - 115
85 - 115
85 shy 11 S
85 - 115
20
20
20
20
EPA 2008 Mod
EPA 2008 Mod
EPA 2008 Mod
EPA 2008 Mod
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report mus be reproducedin its entirety
Page 2 o26J20J073 Final Report 041252012
Liz Siska Project Manager
23
11720 North Creek Parkway North Suite 400 Bothell WA 980 l l
Ph 425-686-1996FRONT[ER- Fx 425-686-3096 cLosAL SCIEN _CES
LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLICATE
RECOVERY AND RPD
Batch F203314 Sequence 2C25005
Preparation Closed Vessel Nitric Oven Digestion Lab Number F2033 l 4-BSBSD 1
LCS Source Blank Spike
Analyte
Thallium
Spike Added (microgL)
LCS Concentration
(microgL)
LCS 0o
Recovery Recovery
Limits Method
040000 0396 989 85 - 115 EPA 2008 Mod
Notes
Analyte
Spike Added (microgL)
LCSD Concentration
(microgL)
LCSD 0o
Recovery
RPD Recovery
Limits RPO Limit Method Notes
Thallium 040000 0391 978 112 85 - ll5 20 EPA 2008 Mod
Frontier Global Sciences Inc The results in this report only apply to the samples anayed in accordance with the chain ofcustody docwnenJ This analytical report must be reproduced in its entirety
Page 22of26 1201073 Final Report 04252012
Liz Siska Project Manager
24
Liz Siska P roject Manager
11720 North Creek Parkway North Suite 400
~ Bothell WA 98011 Ph 425-686-1996
~JTIEif middot Fx 425-686-3096 GLOBAL SCIENCES
PREPARATION BLANKS
Instrument Hg-17 Sequence 2A09010
Preparation BrCI Oxidation
Lab Sample ID Analyte Found MRL Units Batch Method Notes
F201063-BLK I Mercury -0009 050 ngL F201063 EPA 1631E u F20 I063-BLK2 Mercury -0006 050 ngL F201063 EPA 1631E u F201063-BLK3 Mercury -002 050 ngL F201063 EPA 163IE u F201063-BLK4 Mercury 003 050 ngL F201063 EPA 1631E U QB-04 F201063-BLKS Mercury 011 052 ngL F201063 EPA I631E U QB-06
Frontier Global Sciences Inc The results in this report only apply 10 1he samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Page 23 o26 1201073 Final Repon 04252012 25
Liz Siska Project Manager
11720 North Creek Parkway North Suite 400 Bothell WA 98011
Ph 425-686-1996 FROr~TIER- Fx 425-686-3096 GLOBAL SCIENCES
PREPARATION BLANKS
Instrument ICPMS-6 Sequence 2C22005
Preparation Closed Vessel Nitric Oven Digestion
Lab Sample ID Analyte Found MRL Units Batch Method Notes
F203271-BLK1 Beryllium 000008 0060 microgL F203271 PA 2008 Molt u F20327 1-BLK1 Sodium 2 20 microgL F20327l PA 2008 Moc u F20327I-BLK1 Aluminum -004 40 microgL F203271 PA 2008 Molt u F20327I -BLK1 Calcium 40 microgL F203271 PA 2008 Molt u F203271 -BLK1 Chromium -002 010 microgL F203271 ~A 2008 Molt u F203271-BLKI Manganese 001 010 microgL F203271 PA 2008 Molt u F20327 l -BLK 1 Iron -002 100 microgL F203271 PA 2008 Molt u F203271-BLKI Nickel 0004 010 microgL F203271 PA 2008 Moc u F203271-BLK1 Copper 0003 010 microgL F203271 PA 2008 Moc u F203271-BLK1 Zinc 0007 020 microgL F203271 PA 2008 Moc u F203271-BLK1 Arsenic -006 015 microgL F203271 PA 2008 Moc u F203271-BLK1 Selenium -002 060 microgL F203271 PA 2008 Moc u F203271-BLK1 Molybdenum 001 006 microgL F203271 PA 2008 Molt u F203271-BLK1 Silver -00005 0020 microgL F203271 PA 2008 Molt u F203271-BLKl Cadmium 0004 0020 microgL F203271 PA 2008 Molt u F20327 l-BLKl Antimony 0002 0020 microgL F203271 PA 2008 Molt u F203271-BLKI Barium 001 020 microgL F203271 PA 2008 Molt u F203271-BLKI Lead 0010 0040 microgL F203271 PA 2008 Moc u
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Page 24of26 1201073 Final Report 04252012 26
~
~TIER~ GLOBAL SCIENCES
11720 North Creek Parkway North Suite 400 Bothell WA 980ll
Ph 425-686-1996 Fx 425-686-3096
PREPARATION BLANKS
Instrument JCPMS-3 Sequence 2C25005
Preparation Closed Vessel Nitric Oven Digestion
Lab Sample ID Analyte Found MRL Units Batch Method Notes
F2033I4-BLK1 Thalium 00007 0010 microgL F2033I4 ~PA 2008 Molt u
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Page 25 o26Liz Siska Project Manager 1201073 Final Report
04252012 27
l l 720 North Creek Parkway North Suite 400~Vi-~ Bothell WA 98011 Ph 425-686-1 996~Tlmiddot~ Fx 425-686-3096
G L OBAL SCIENCE S
Notes and Definitions
U Analyte included in the analysis but not detected
QM-02 The MS andor MSD recoveries outside acceptance limits due to spike concentration less than I times the sample concentration The batch was accepted based on LCS and LCSD recoveries within control limits and when analysis permits acceptable AS ASD
QB-06 The blank was preserved to 5 BrCI rather than I The control limit for blanks preserved to greater than 1 BrCl is the preservation percentage multiplied by the MRL
QB-04 The blank was preserved to 2 BrCI rather than l The control limit for blanks preserved to greater than l BrCI is the preservation percentage multiplied by the MRL
FB-1631 Required equipmentfieldfilter blank not submitted by the client The sample has been analyzed according to 163 lE but does not meet 163 lE criteria
AS This MS andor MSD is an analytical spike andor an analytical spike duplicate
DET Analyte Detected
MDL Minimum Detection Limit
MRL Minimum Reporting Limit
ND Analyte Not Detected at or above the reporting limit
wet Sample results reported on a wet weight basis
dry Sample results reported on a dry weight basis
RPO Relative Percent Difference
RSD Relative Standard Deviation
Frontier Global Sciences Inc The lesults i111his reporl only apply to he samples analyzed In accordance with the chain ofcuslody document This analytical report must be reproduced in its entirely
Page 26of26 1201073 Final Report 04252012
Liz Siska Project Manager
28
CHAIN-OF-(USTODY ttECORD Page i of f 106677 _J
BoLD F1ELDS REQUIRED PLEASE C 1RCLE REQUESTED ANALYSIS
SAMPLE ID
middoti-rg -- bull ~rshy~ _- tzir +- lt-ltJ~ lt
SAMPLING
DATeTtME
IF COMPOSITE INDICATE BOTH
START amp FINISH
DATETIME li1J oc -r 111_- _vlt-c_
w Ishyt 0 n
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IIXJ JC
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Trttbull rin K C-~-~ pound1t I 1Jtl~ t20~L lwlJI ishy
middot~ON Mm1x A-Al~ S-SOil GW-GampOUHO WATER SW-SUampfA(f WATER DWmiddotDRIIIKIKlti WATER
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1 WW-WASTE WATER PmmATIVE H-HCL H-HN01 S-H1SO Na-NaOH H-HEOH -~ --~
PROJECT MANAGER llr middot1 ~Q Aw4---P1V- Het_ r COMPANY t-lo--tm ~ bd i ( I ~j 6 A ADP~SS 91 g~ez tJshy(ITJ ~ STATE fH_ ZIP c3o--
PHONE 22j-((omiddotf EXT ____
fAX--------------------- shyE-MAIL (JbHd-esa e n ta wamp Sm NAME Meccft1lt-1ltk f--g
PROJECT _
OTHEi________STATpound NH MA ME VT
REGULATORY PROGRAM NPDES RGP POTW STORHWATEl OR
GWP OIL FUHD BROWNIIELO OR OTHER----------
Quon PO o2J~-lt1Jpound)
DATE NEEDED _1--1 middot Z=-----shy4 (1-1_ METALS 8 RCRA 13 pp ff MN PB Cu
QAQC REPORTJNGYVEL
A CG) O R
PRESUMPTIVE CERTAINTY
7i2lt_
RECpound1VEO BYRELINQUISHED BY DATE TIME SUSPECTED (OHTAHIHATIOH________
TEHP~ C REPORTING OPTIONS 01HEA METAL------------PRELIHl Yu OR No
DISSOLVED METALS FIELD FllTEREDI YES 110
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IF YH FAX OR POf 7~shy Hom (IE SPECIAL DETECTION LINITl BllLIKGINfO If DlffERrnT)ELECTRONIC OPTIONS zo 1 2 2) le~C1 1 Jc Id sJ 60 6c
1 cf Co
lo FAX pound-MAIL PDF EQUll C jCi (e I rt--111 Ao NiAJrJe middotn th
Ka)Jcr(c C(cdd -ltJ c -l -gtck- z Alt 5e1 Hj
Al l 4_) it fG) 1uJ c(iJoclt-U Sin HISTORY 0Se-d Cim- ~pound rc~L IH t--6
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ImiddotRELINQUISHED BY DATE TIHE RECflVEO BY I FIELD READINGS
eastern analytical inc 2s CHENELL D R1ve IC 0 Nco1to N H 0330 1 I TEL 60J22aos2s 1aoo2a1os2s IFAx 6032284591 j E-MA1t cus-roM111_mV1c~EAILAsscoMJ www1A1LAascoM
----i pmiddotofissionrrl11bomtorymim (WHITE ORIGINAL GREEN PROJECT MANAGER)
shy
11720 North Creek Parkway North Suite 400
~ Bothell WA 98011 Ph 425-686-I996
~RONTIER~ Fx 425-686-3096 GLOBAL SCIEN C ES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1201073-01RE3
Batch F203271 Sequence 2~22005
Preparation Closed Vessel Nitric Oven Digestion Lab Number F20327 I-MSMSD3
Sample Spike MS MS
Analyte Concentration
(microgL) Added (microgL)
Concentration (microgL) Recovery
Recovery Limits Method Notes
Calcium 5013000 10100000 15120000 100 70- 130 EPA 2008 Mod AS
Spike MSD MSD Added Concentration o Oo Recovery RPD
Analyte (microgL) (microgL) Recovery RPD Limits Limit Method Notes
Calcium 10100000 16140000 llO 653 70 - 130 20 EPA 2008 Mod AS
Frontier Global Sciences Inc The results in his report only apply 10 the samples analyzed in accordance ivth he chain ofcustody document This analytical report must be reproduced in its entirety
Page 14 o261201073 Final Report 0425201]
Liz Siska Project Manager
16
Frontier Global Sciences Inc The ruults in this rechain ofcustody do
~ -lt1-c--~ Liz Siska Project Manager
11720 North Creek Parkway North Suite 400 Bothell WA 98011
Ph 425-686-1996 Fx 425-686-3096
GLOBAL SCIENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1201073-01RE4
Batch J203271 Sequence 2C22005
Preparation ~ IQsed Ve~~el Nitric Oven Qigestion Lab Number F203271-MSMSQ4
Analyte
Beryllium
Sample Concentration
(11gL)
0507
Spike Added (11gL)
20200
MS Concentration
(microgL)
2041
MS Oo
Recovery
985
RecoveryMethod Limits
70 - 130 EPA 2008 Mod
Notes
AS
Sodium 258800 40400 292900 845 70- 130 EPA 2008 Mod AS
Aluminum 529 40400 3956 966 70 - 130 EPA 2008 Mod AS
Chromium 057 40400 430l 106 70- 130 EPA 2008 Mod AS
Manganese 2805 40400 7042 105 70 - 130 EPA 2008 Mod AS
Iron ND 20200 2121 105 70 - 130 EPA 2008 Mod AS
Nickel 979 50500 5112 993 70 l30 EPA 2008 Mod AS
Copper 055 50500 4754 940 70 - 130 EPA 2008 Mod AS
Zinc 040 10100 9074 898 70 - 130 EPA 2008 Mod AS
Arsenic 1030 40400 4317 104 70 130 EPA 2008 Mod AS
Selenium 6340 40400 4688 100 70 - 130 EPA 2008 Mod AS
Molybdenum 1338 20200 338l 101 70 - 130 EPA 2008 Mod AS
Silver ND 20200 1850 916 70 130 EPA 2008 Mod AS
Cadmium 0332 40400 3937 966 70 130 EPA 2008 Mod AS
Antimony 0408 20200 2091 102 70 - 130 EPA 2008 Mod AS
Barium 2397 80800 1056 101 70- 130 EPA 2008 Mod AS
Lead ND IO100 9932 983 70 130 EPA 2008 Mod AS
shy
shy
shy
shy
shy
Analyte
Spike Added (microgL)
MSD Concentration
(microgL)
MSD
Recovery
RPD
Recovery Limits
RPDLimit Method Notes
Beryllium 20200 2007 968 l71 70 - 130 20 EPA 2008 Mod AS Sodium 40400 292600 837 0114 70 130 20 EPA 2008 Mod AS Aluminum 40400 3954 966 00362 70 - 130 20 EPA 2008 Mod AS Chromium 40400 4287 106 0337 70 - 130 20 EPA 2008 Mod AS Manganese 40400 6944 102 140 70 - 130 20 EPA 2008 Mod AS Iron 20200 2077 103 211 70 - 130 20 EPA 2008 Mod AS Nickel 50500 5126 996 0276 70 - 130 20 EPA 2008 Mod AS Copper 50500 4707 931 0997 70 - 130 20 EPA 200 8 Mod AS Zinc 10100 9059 896 0166 70 - 130 20 EPA 2008 Mod AS Arsenic 40400 4299 104 0419 70 - 130 20 EPA 2008 Mod AS Selenium 40400 4682 100 0141 70 - 130 20 EPA 2008 Mod AS Molybdenum 20200 3365 100 0473 70 - 130 20 EPA 2008 Mod AS
shy
port only apply to the sampltts analyzed in accordance with the cument This analytical report must be reproduced in its entirety
Page 5 o26 201073 Final Report 042512012 17
Liz Sia Project Manager
11720 North Creek Parkway North Suite 400 Botheln VA 98011
Ph 425-686-1996 Fx 425-686-3096
CLOBAL SCIENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1201073-01RE4
Batch F203271 Sequence 2c2io2~
Preparation Clo~ed Vessel litric Oven Digestion Lab Number F20327 l -MSMSQ4
Analyte
Spike Added (microgL)
MSD Concentration
(microgL)
MSD
Recovery
Oo
RPD Recovery
Limits RPOLimit Method Notes
Silver 20200 1895 938 242 70 - 130 20 EPA 2008 Mod AS Cadmium 40400 3933 965 0104 70 -130 20 EPA 2008 Mod AS Antimony 20200 2107 102 0736 70- 130 20 EPA 2008 Mod AS
Barium 80800 1058 101 0205 70 - 130 20 EPA 2008 Mod AS
Lead 10100 9877 978 0549 70 - 130 20 EPA 2008 Mod AS
Frontier Global Sciences Inc The results in this report only apply to the samples analyudin accordance with lht chain ofcustody document This analytical report must be reproductd rn ilS enlirtty
Page l6of26 1201073 Final Report Ofn5202 18
l I 720 North Creek Parkway North Suite 400 Bothell WA 980I I
Ph 425-686-1996 Fx 425-686-3096
GLO B AL SCIENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1201073-01RE6
Batch F203314 Sequence 2C25005
Preparation Closed Vessel Nitric Oven Digestion Lab Number F203314-MSMSD2
Sample Spike MS MS Concentration Added Concentration RecoveryAnalyte (microgL) (microgL) (microgL) Recovery Method NotesLimits
Thallium 5563 040400 5875 773 70 - 130 EPA 2008 Mod
Spike MSD MSD Added o Concentration Recovery RPD
RPO Limits Limit Method Notes Analyte (microgL) (microgL) Recovery
Thallium 040400 5880 785 00859 70 - 130 20 EPA 2008 Mod
Frontier Global Sciences Inc 11e results in chis reporc only apply 10 1he samples analyzed in accordance wilh lhe chain ofcustody documenz This analycical report musl be reproduced in ils entirety
Page 17 of26 1201073 Fi11aReport 0412512012
Liz Siska Project Manager
19
11720 North Creek Parkway North Suite 400 Bothell WA 98011
Ph 425-686-1996 Fx 425-686-3096
GLOBAl SCIENC ES
MATRIX SPIKE I MATRIX SPIKE DUPLICATE RECOVERY AND RPO
SOURCE I201073-01RE6
Batch F203314
Preparation Closed Vessel Nitric Oven Digestion
Sequence 2C25005
Lab Number F203314-MSMSD4
Analyte
Sample Concentration
(microgL)
Spike Added (microgL)
MS MS Concentration Oo
(microgL) Recovery Recovery
Limits Method Notes
Thallium 5563 10100 1033 968 70- 130 EPA 2008 Mod AS
Analyte
Spike Added (microgL)
MSD Concentration
(microgL)
MS)) Oo
Recovery
RPD
Recovery Limits
RPD Limit Method Notes
Thallium IO100 1037 97l 0341 70 - 130 20 EPA 2008 Mod AS
Frontier Global Sciences Inc The resulrs in this report only apply to the samples analyzed in accordance with the chain ofcusrody document This analytical report must be reproduced in its entirely
Page 18of26 120073 Final Report 04252012
Liz Siska Project Manager
20
11720 North Creek Parkway North Suite 400 l ~ Bothell WA 980 l l Ph 425-686-1996
FRONTIER Fx 425-686-3096 GLOBAL SCIENCES
LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLICATE
RECOVERY AND RPD
Batch F20 l063 Sequence 2A09010
Preparation BrCI Oxidation Lab Number F201063-BSIBSJ21
LCS Source N ist 1641d
Analyte
Spike Added (ngL)
LCS Concentration
(ngL)
LCS
Recovery Recovery
Limits Method Notes
Mercury 15679 1550 988 80 - 120 EPA I631E
Analyte
Spike Added (ngL)
LCSD Concentration
(ngL)
LCSD Oo
Recovery
RPD Recovery
Limits RPD Limit Method Notes
Mercury 15679 1595 [02 289 80 - 120 24 EPA I631E
Frontier Global Sciences Inc The results in this report only apply to the samples analyzedin accordance with the chain ofcustody document This analytical report must be reproduced in ils entirety
Page 19of26 1201073 Final Report 0425 2012
Liz Siska Project Manager
21
11720 North Creek Parkway North Suite 400 Bothell WA 98011
Ph 425-686-1996 FRONTIER Fx 425-686-3096 GLOBAL SCIENCES
LABORA TORY CONTROL SAMPLE LABO RATORY CONTROL SAMPLE DUPLICATE
RECOVERY AND RPD
Batch F203271 Sequence 2C22005
Preparation Closed Vessel Nitric Oven Digestion Lab Number F203271-BSBSD1
LCS Source Blank Spike
Spike LCS LCS Added Concentration Oo Recovery
Analyte (microgL) (microgL) Recovery Limits Method Notes
Beryllium 20000 l930 965 85 - 115 EPA 2008 Mod
Sodium 50000 499 998 85 - 115 EPA 2008 Mod
Aluminum 15000 1460 973 85 - 115 EPA 2008 Mod
Calcium 15000 1528 102 85 - 115 EPA 2008 Mod
Chromium 70000 657 939 85 - 115 EPA 2008 Mod
Manganese 60000 586 976 85 - 115 EPA 2008 Mod
Iron 50000 4753 951 85 shy 115 EPA 2008 Mod
Nickel 40000 401 100 85 - 115 EPA 2008 Mod
Copper 40000 418 105 85 - 115 EPA 2008 Mod
Zinc 10000 1033 103 85 - 115 EPA 2008 Mod
Arsenic 15000 1437 958 85 - 115 EPA 2008 Mod
Selenium 30000 2966 989 85 - 115 EPA 2008 Mod
Molybdenum 20000 181 905 85 shy 115 EPA 2008 Mod
Silver 15000 1517 101 85 shy 115 EPA 2008 Mod
Cadmium 080000 0781 976 85 - 1lS EPA 2008 Mod
Antimony 080000 0815 102 85 - 115 EPA 2008 Mod
Barium 10000 969 969 85 - 115 EPA 2008 Mod
Lead 15000 1597 106 85 - 115 EPA 2008 Mod
Spike LCSD LCSD Added Concentration Recovery RPO
Analyte (microgL) (microgL) Recovery RPO Limits Limit Method Notes
Beryllium 20000 1949 974 0955 85 - 115 20 EPA 2008 Mod
Sodium 50000 500 100 0216 85 - 115 20 EPA 2008 Mod
Aluminum 15000 1485 990 171 85 - 115 20 EPA 2008 Mod
Calcium 15000 1544 103 103 85 - 115 20 EPA 2008 Mod
Chromium 70000 667 953 148 85 - 115 20 EPA 2008 Mod
Manganese 60000 596 994 175 85 - 115 20 EPA 2008 Mod
Iron 50000 4852 970 206 85 - 115 20 EPA 2008 Mod
Nickel 40000 402 IOI 0246 85 - 115 20 EPA 2008 Mod
Frontier Global Sciences Inc The results in his report only apply to the samples analyzed in accordance wirh the chain ofcustody document This analytical report must be reproduced in iLS entirety
Page 20of26 1201073 Final Report 04252012
Liz Siska Project Manager
22
11720 North Creek Parkway North Suite 400 ~~shy Bothell WA 98011 Ph 425-686-1996~ONTif Fx 425-686-3096
GLOBAL SCIENCES
LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLICATE
RECOVERY AND RPO
Batch F20327 l Sequence 2C22005
Preparation Closed Vessel Nitric Oven Digestion Lab Number F203271-BSBSD 1
LCS Source Blank Spike
Analyte
Spike Added (microgL)
LCSD Concentration
(microgL)
LCSD oo
Recovery
RPO Recovery
Limits RPO Limit Method Notes
Copper
Zinc
Arsenic
Selenium
40000
10000
15000
30000
428
1039
1452
3015
107
104
968
101
224
0570
0977
166
85 - 115
85 - 115
85 - 115
85 - 115
20
20
20
20
EPA 2008 Mod
EPA 2008 Mod
EPA 2008 Mod
EPA 2008 Mod Molybdenum
Silver
20000
15000
182
J502
910
100
0564
103
85 - 115
85 - 115
20
20
EPA 2008 Mod
EPA 2008 Mod Cadmium
Antimony
Barium
Lead
080000
080000
10000
15000
0828
0808
986
1620
103
101
986
108
585
0848
177
142
85 - 115
85 - 115
85 shy 11 S
85 - 115
20
20
20
20
EPA 2008 Mod
EPA 2008 Mod
EPA 2008 Mod
EPA 2008 Mod
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report mus be reproducedin its entirety
Page 2 o26J20J073 Final Report 041252012
Liz Siska Project Manager
23
11720 North Creek Parkway North Suite 400 Bothell WA 980 l l
Ph 425-686-1996FRONT[ER- Fx 425-686-3096 cLosAL SCIEN _CES
LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLICATE
RECOVERY AND RPD
Batch F203314 Sequence 2C25005
Preparation Closed Vessel Nitric Oven Digestion Lab Number F2033 l 4-BSBSD 1
LCS Source Blank Spike
Analyte
Thallium
Spike Added (microgL)
LCS Concentration
(microgL)
LCS 0o
Recovery Recovery
Limits Method
040000 0396 989 85 - 115 EPA 2008 Mod
Notes
Analyte
Spike Added (microgL)
LCSD Concentration
(microgL)
LCSD 0o
Recovery
RPD Recovery
Limits RPO Limit Method Notes
Thallium 040000 0391 978 112 85 - ll5 20 EPA 2008 Mod
Frontier Global Sciences Inc The results in this report only apply to the samples anayed in accordance with the chain ofcustody docwnenJ This analytical report must be reproduced in its entirety
Page 22of26 1201073 Final Report 04252012
Liz Siska Project Manager
24
Liz Siska P roject Manager
11720 North Creek Parkway North Suite 400
~ Bothell WA 98011 Ph 425-686-1996
~JTIEif middot Fx 425-686-3096 GLOBAL SCIENCES
PREPARATION BLANKS
Instrument Hg-17 Sequence 2A09010
Preparation BrCI Oxidation
Lab Sample ID Analyte Found MRL Units Batch Method Notes
F201063-BLK I Mercury -0009 050 ngL F201063 EPA 1631E u F20 I063-BLK2 Mercury -0006 050 ngL F201063 EPA 1631E u F201063-BLK3 Mercury -002 050 ngL F201063 EPA 163IE u F201063-BLK4 Mercury 003 050 ngL F201063 EPA 1631E U QB-04 F201063-BLKS Mercury 011 052 ngL F201063 EPA I631E U QB-06
Frontier Global Sciences Inc The results in this report only apply 10 1he samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Page 23 o26 1201073 Final Repon 04252012 25
Liz Siska Project Manager
11720 North Creek Parkway North Suite 400 Bothell WA 98011
Ph 425-686-1996 FROr~TIER- Fx 425-686-3096 GLOBAL SCIENCES
PREPARATION BLANKS
Instrument ICPMS-6 Sequence 2C22005
Preparation Closed Vessel Nitric Oven Digestion
Lab Sample ID Analyte Found MRL Units Batch Method Notes
F203271-BLK1 Beryllium 000008 0060 microgL F203271 PA 2008 Molt u F20327 1-BLK1 Sodium 2 20 microgL F20327l PA 2008 Moc u F20327I-BLK1 Aluminum -004 40 microgL F203271 PA 2008 Molt u F20327I -BLK1 Calcium 40 microgL F203271 PA 2008 Molt u F203271 -BLK1 Chromium -002 010 microgL F203271 ~A 2008 Molt u F203271-BLKI Manganese 001 010 microgL F203271 PA 2008 Molt u F20327 l -BLK 1 Iron -002 100 microgL F203271 PA 2008 Molt u F203271-BLKI Nickel 0004 010 microgL F203271 PA 2008 Moc u F203271-BLK1 Copper 0003 010 microgL F203271 PA 2008 Moc u F203271-BLK1 Zinc 0007 020 microgL F203271 PA 2008 Moc u F203271-BLK1 Arsenic -006 015 microgL F203271 PA 2008 Moc u F203271-BLK1 Selenium -002 060 microgL F203271 PA 2008 Moc u F203271-BLK1 Molybdenum 001 006 microgL F203271 PA 2008 Molt u F203271-BLK1 Silver -00005 0020 microgL F203271 PA 2008 Molt u F203271-BLKl Cadmium 0004 0020 microgL F203271 PA 2008 Molt u F20327 l-BLKl Antimony 0002 0020 microgL F203271 PA 2008 Molt u F203271-BLKI Barium 001 020 microgL F203271 PA 2008 Molt u F203271-BLKI Lead 0010 0040 microgL F203271 PA 2008 Moc u
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Page 24of26 1201073 Final Report 04252012 26
~
~TIER~ GLOBAL SCIENCES
11720 North Creek Parkway North Suite 400 Bothell WA 980ll
Ph 425-686-1996 Fx 425-686-3096
PREPARATION BLANKS
Instrument JCPMS-3 Sequence 2C25005
Preparation Closed Vessel Nitric Oven Digestion
Lab Sample ID Analyte Found MRL Units Batch Method Notes
F2033I4-BLK1 Thalium 00007 0010 microgL F2033I4 ~PA 2008 Molt u
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Page 25 o26Liz Siska Project Manager 1201073 Final Report
04252012 27
l l 720 North Creek Parkway North Suite 400~Vi-~ Bothell WA 98011 Ph 425-686-1 996~Tlmiddot~ Fx 425-686-3096
G L OBAL SCIENCE S
Notes and Definitions
U Analyte included in the analysis but not detected
QM-02 The MS andor MSD recoveries outside acceptance limits due to spike concentration less than I times the sample concentration The batch was accepted based on LCS and LCSD recoveries within control limits and when analysis permits acceptable AS ASD
QB-06 The blank was preserved to 5 BrCI rather than I The control limit for blanks preserved to greater than 1 BrCl is the preservation percentage multiplied by the MRL
QB-04 The blank was preserved to 2 BrCI rather than l The control limit for blanks preserved to greater than l BrCI is the preservation percentage multiplied by the MRL
FB-1631 Required equipmentfieldfilter blank not submitted by the client The sample has been analyzed according to 163 lE but does not meet 163 lE criteria
AS This MS andor MSD is an analytical spike andor an analytical spike duplicate
DET Analyte Detected
MDL Minimum Detection Limit
MRL Minimum Reporting Limit
ND Analyte Not Detected at or above the reporting limit
wet Sample results reported on a wet weight basis
dry Sample results reported on a dry weight basis
RPO Relative Percent Difference
RSD Relative Standard Deviation
Frontier Global Sciences Inc The lesults i111his reporl only apply to he samples analyzed In accordance with the chain ofcuslody document This analytical report must be reproduced in its entirely
Page 26of26 1201073 Final Report 04252012
Liz Siska Project Manager
28
CHAIN-OF-(USTODY ttECORD Page i of f 106677 _J
BoLD F1ELDS REQUIRED PLEASE C 1RCLE REQUESTED ANALYSIS
SAMPLE ID
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IF COMPOSITE INDICATE BOTH
START amp FINISH
DATETIME li1J oc -r 111_- _vlt-c_
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PHONE 22j-((omiddotf EXT ____
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DATE NEEDED _1--1 middot Z=-----shy4 (1-1_ METALS 8 RCRA 13 pp ff MN PB Cu
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----i pmiddotofissionrrl11bomtorymim (WHITE ORIGINAL GREEN PROJECT MANAGER)
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Frontier Global Sciences Inc The ruults in this rechain ofcustody do
~ -lt1-c--~ Liz Siska Project Manager
11720 North Creek Parkway North Suite 400 Bothell WA 98011
Ph 425-686-1996 Fx 425-686-3096
GLOBAL SCIENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1201073-01RE4
Batch J203271 Sequence 2C22005
Preparation ~ IQsed Ve~~el Nitric Oven Qigestion Lab Number F203271-MSMSQ4
Analyte
Beryllium
Sample Concentration
(11gL)
0507
Spike Added (11gL)
20200
MS Concentration
(microgL)
2041
MS Oo
Recovery
985
RecoveryMethod Limits
70 - 130 EPA 2008 Mod
Notes
AS
Sodium 258800 40400 292900 845 70- 130 EPA 2008 Mod AS
Aluminum 529 40400 3956 966 70 - 130 EPA 2008 Mod AS
Chromium 057 40400 430l 106 70- 130 EPA 2008 Mod AS
Manganese 2805 40400 7042 105 70 - 130 EPA 2008 Mod AS
Iron ND 20200 2121 105 70 - 130 EPA 2008 Mod AS
Nickel 979 50500 5112 993 70 l30 EPA 2008 Mod AS
Copper 055 50500 4754 940 70 - 130 EPA 2008 Mod AS
Zinc 040 10100 9074 898 70 - 130 EPA 2008 Mod AS
Arsenic 1030 40400 4317 104 70 130 EPA 2008 Mod AS
Selenium 6340 40400 4688 100 70 - 130 EPA 2008 Mod AS
Molybdenum 1338 20200 338l 101 70 - 130 EPA 2008 Mod AS
Silver ND 20200 1850 916 70 130 EPA 2008 Mod AS
Cadmium 0332 40400 3937 966 70 130 EPA 2008 Mod AS
Antimony 0408 20200 2091 102 70 - 130 EPA 2008 Mod AS
Barium 2397 80800 1056 101 70- 130 EPA 2008 Mod AS
Lead ND IO100 9932 983 70 130 EPA 2008 Mod AS
shy
shy
shy
shy
shy
Analyte
Spike Added (microgL)
MSD Concentration
(microgL)
MSD
Recovery
RPD
Recovery Limits
RPDLimit Method Notes
Beryllium 20200 2007 968 l71 70 - 130 20 EPA 2008 Mod AS Sodium 40400 292600 837 0114 70 130 20 EPA 2008 Mod AS Aluminum 40400 3954 966 00362 70 - 130 20 EPA 2008 Mod AS Chromium 40400 4287 106 0337 70 - 130 20 EPA 2008 Mod AS Manganese 40400 6944 102 140 70 - 130 20 EPA 2008 Mod AS Iron 20200 2077 103 211 70 - 130 20 EPA 2008 Mod AS Nickel 50500 5126 996 0276 70 - 130 20 EPA 2008 Mod AS Copper 50500 4707 931 0997 70 - 130 20 EPA 200 8 Mod AS Zinc 10100 9059 896 0166 70 - 130 20 EPA 2008 Mod AS Arsenic 40400 4299 104 0419 70 - 130 20 EPA 2008 Mod AS Selenium 40400 4682 100 0141 70 - 130 20 EPA 2008 Mod AS Molybdenum 20200 3365 100 0473 70 - 130 20 EPA 2008 Mod AS
shy
port only apply to the sampltts analyzed in accordance with the cument This analytical report must be reproduced in its entirety
Page 5 o26 201073 Final Report 042512012 17
Liz Sia Project Manager
11720 North Creek Parkway North Suite 400 Botheln VA 98011
Ph 425-686-1996 Fx 425-686-3096
CLOBAL SCIENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1201073-01RE4
Batch F203271 Sequence 2c2io2~
Preparation Clo~ed Vessel litric Oven Digestion Lab Number F20327 l -MSMSQ4
Analyte
Spike Added (microgL)
MSD Concentration
(microgL)
MSD
Recovery
Oo
RPD Recovery
Limits RPOLimit Method Notes
Silver 20200 1895 938 242 70 - 130 20 EPA 2008 Mod AS Cadmium 40400 3933 965 0104 70 -130 20 EPA 2008 Mod AS Antimony 20200 2107 102 0736 70- 130 20 EPA 2008 Mod AS
Barium 80800 1058 101 0205 70 - 130 20 EPA 2008 Mod AS
Lead 10100 9877 978 0549 70 - 130 20 EPA 2008 Mod AS
Frontier Global Sciences Inc The results in this report only apply to the samples analyudin accordance with lht chain ofcustody document This analytical report must be reproductd rn ilS enlirtty
Page l6of26 1201073 Final Report Ofn5202 18
l I 720 North Creek Parkway North Suite 400 Bothell WA 980I I
Ph 425-686-1996 Fx 425-686-3096
GLO B AL SCIENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1201073-01RE6
Batch F203314 Sequence 2C25005
Preparation Closed Vessel Nitric Oven Digestion Lab Number F203314-MSMSD2
Sample Spike MS MS Concentration Added Concentration RecoveryAnalyte (microgL) (microgL) (microgL) Recovery Method NotesLimits
Thallium 5563 040400 5875 773 70 - 130 EPA 2008 Mod
Spike MSD MSD Added o Concentration Recovery RPD
RPO Limits Limit Method Notes Analyte (microgL) (microgL) Recovery
Thallium 040400 5880 785 00859 70 - 130 20 EPA 2008 Mod
Frontier Global Sciences Inc 11e results in chis reporc only apply 10 1he samples analyzed in accordance wilh lhe chain ofcustody documenz This analycical report musl be reproduced in ils entirety
Page 17 of26 1201073 Fi11aReport 0412512012
Liz Siska Project Manager
19
11720 North Creek Parkway North Suite 400 Bothell WA 98011
Ph 425-686-1996 Fx 425-686-3096
GLOBAl SCIENC ES
MATRIX SPIKE I MATRIX SPIKE DUPLICATE RECOVERY AND RPO
SOURCE I201073-01RE6
Batch F203314
Preparation Closed Vessel Nitric Oven Digestion
Sequence 2C25005
Lab Number F203314-MSMSD4
Analyte
Sample Concentration
(microgL)
Spike Added (microgL)
MS MS Concentration Oo
(microgL) Recovery Recovery
Limits Method Notes
Thallium 5563 10100 1033 968 70- 130 EPA 2008 Mod AS
Analyte
Spike Added (microgL)
MSD Concentration
(microgL)
MS)) Oo
Recovery
RPD
Recovery Limits
RPD Limit Method Notes
Thallium IO100 1037 97l 0341 70 - 130 20 EPA 2008 Mod AS
Frontier Global Sciences Inc The resulrs in this report only apply to the samples analyzed in accordance with the chain ofcusrody document This analytical report must be reproduced in its entirely
Page 18of26 120073 Final Report 04252012
Liz Siska Project Manager
20
11720 North Creek Parkway North Suite 400 l ~ Bothell WA 980 l l Ph 425-686-1996
FRONTIER Fx 425-686-3096 GLOBAL SCIENCES
LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLICATE
RECOVERY AND RPD
Batch F20 l063 Sequence 2A09010
Preparation BrCI Oxidation Lab Number F201063-BSIBSJ21
LCS Source N ist 1641d
Analyte
Spike Added (ngL)
LCS Concentration
(ngL)
LCS
Recovery Recovery
Limits Method Notes
Mercury 15679 1550 988 80 - 120 EPA I631E
Analyte
Spike Added (ngL)
LCSD Concentration
(ngL)
LCSD Oo
Recovery
RPD Recovery
Limits RPD Limit Method Notes
Mercury 15679 1595 [02 289 80 - 120 24 EPA I631E
Frontier Global Sciences Inc The results in this report only apply to the samples analyzedin accordance with the chain ofcustody document This analytical report must be reproduced in ils entirety
Page 19of26 1201073 Final Report 0425 2012
Liz Siska Project Manager
21
11720 North Creek Parkway North Suite 400 Bothell WA 98011
Ph 425-686-1996 FRONTIER Fx 425-686-3096 GLOBAL SCIENCES
LABORA TORY CONTROL SAMPLE LABO RATORY CONTROL SAMPLE DUPLICATE
RECOVERY AND RPD
Batch F203271 Sequence 2C22005
Preparation Closed Vessel Nitric Oven Digestion Lab Number F203271-BSBSD1
LCS Source Blank Spike
Spike LCS LCS Added Concentration Oo Recovery
Analyte (microgL) (microgL) Recovery Limits Method Notes
Beryllium 20000 l930 965 85 - 115 EPA 2008 Mod
Sodium 50000 499 998 85 - 115 EPA 2008 Mod
Aluminum 15000 1460 973 85 - 115 EPA 2008 Mod
Calcium 15000 1528 102 85 - 115 EPA 2008 Mod
Chromium 70000 657 939 85 - 115 EPA 2008 Mod
Manganese 60000 586 976 85 - 115 EPA 2008 Mod
Iron 50000 4753 951 85 shy 115 EPA 2008 Mod
Nickel 40000 401 100 85 - 115 EPA 2008 Mod
Copper 40000 418 105 85 - 115 EPA 2008 Mod
Zinc 10000 1033 103 85 - 115 EPA 2008 Mod
Arsenic 15000 1437 958 85 - 115 EPA 2008 Mod
Selenium 30000 2966 989 85 - 115 EPA 2008 Mod
Molybdenum 20000 181 905 85 shy 115 EPA 2008 Mod
Silver 15000 1517 101 85 shy 115 EPA 2008 Mod
Cadmium 080000 0781 976 85 - 1lS EPA 2008 Mod
Antimony 080000 0815 102 85 - 115 EPA 2008 Mod
Barium 10000 969 969 85 - 115 EPA 2008 Mod
Lead 15000 1597 106 85 - 115 EPA 2008 Mod
Spike LCSD LCSD Added Concentration Recovery RPO
Analyte (microgL) (microgL) Recovery RPO Limits Limit Method Notes
Beryllium 20000 1949 974 0955 85 - 115 20 EPA 2008 Mod
Sodium 50000 500 100 0216 85 - 115 20 EPA 2008 Mod
Aluminum 15000 1485 990 171 85 - 115 20 EPA 2008 Mod
Calcium 15000 1544 103 103 85 - 115 20 EPA 2008 Mod
Chromium 70000 667 953 148 85 - 115 20 EPA 2008 Mod
Manganese 60000 596 994 175 85 - 115 20 EPA 2008 Mod
Iron 50000 4852 970 206 85 - 115 20 EPA 2008 Mod
Nickel 40000 402 IOI 0246 85 - 115 20 EPA 2008 Mod
Frontier Global Sciences Inc The results in his report only apply to the samples analyzed in accordance wirh the chain ofcustody document This analytical report must be reproduced in iLS entirety
Page 20of26 1201073 Final Report 04252012
Liz Siska Project Manager
22
11720 North Creek Parkway North Suite 400 ~~shy Bothell WA 98011 Ph 425-686-1996~ONTif Fx 425-686-3096
GLOBAL SCIENCES
LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLICATE
RECOVERY AND RPO
Batch F20327 l Sequence 2C22005
Preparation Closed Vessel Nitric Oven Digestion Lab Number F203271-BSBSD 1
LCS Source Blank Spike
Analyte
Spike Added (microgL)
LCSD Concentration
(microgL)
LCSD oo
Recovery
RPO Recovery
Limits RPO Limit Method Notes
Copper
Zinc
Arsenic
Selenium
40000
10000
15000
30000
428
1039
1452
3015
107
104
968
101
224
0570
0977
166
85 - 115
85 - 115
85 - 115
85 - 115
20
20
20
20
EPA 2008 Mod
EPA 2008 Mod
EPA 2008 Mod
EPA 2008 Mod Molybdenum
Silver
20000
15000
182
J502
910
100
0564
103
85 - 115
85 - 115
20
20
EPA 2008 Mod
EPA 2008 Mod Cadmium
Antimony
Barium
Lead
080000
080000
10000
15000
0828
0808
986
1620
103
101
986
108
585
0848
177
142
85 - 115
85 - 115
85 shy 11 S
85 - 115
20
20
20
20
EPA 2008 Mod
EPA 2008 Mod
EPA 2008 Mod
EPA 2008 Mod
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report mus be reproducedin its entirety
Page 2 o26J20J073 Final Report 041252012
Liz Siska Project Manager
23
11720 North Creek Parkway North Suite 400 Bothell WA 980 l l
Ph 425-686-1996FRONT[ER- Fx 425-686-3096 cLosAL SCIEN _CES
LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLICATE
RECOVERY AND RPD
Batch F203314 Sequence 2C25005
Preparation Closed Vessel Nitric Oven Digestion Lab Number F2033 l 4-BSBSD 1
LCS Source Blank Spike
Analyte
Thallium
Spike Added (microgL)
LCS Concentration
(microgL)
LCS 0o
Recovery Recovery
Limits Method
040000 0396 989 85 - 115 EPA 2008 Mod
Notes
Analyte
Spike Added (microgL)
LCSD Concentration
(microgL)
LCSD 0o
Recovery
RPD Recovery
Limits RPO Limit Method Notes
Thallium 040000 0391 978 112 85 - ll5 20 EPA 2008 Mod
Frontier Global Sciences Inc The results in this report only apply to the samples anayed in accordance with the chain ofcustody docwnenJ This analytical report must be reproduced in its entirety
Page 22of26 1201073 Final Report 04252012
Liz Siska Project Manager
24
Liz Siska P roject Manager
11720 North Creek Parkway North Suite 400
~ Bothell WA 98011 Ph 425-686-1996
~JTIEif middot Fx 425-686-3096 GLOBAL SCIENCES
PREPARATION BLANKS
Instrument Hg-17 Sequence 2A09010
Preparation BrCI Oxidation
Lab Sample ID Analyte Found MRL Units Batch Method Notes
F201063-BLK I Mercury -0009 050 ngL F201063 EPA 1631E u F20 I063-BLK2 Mercury -0006 050 ngL F201063 EPA 1631E u F201063-BLK3 Mercury -002 050 ngL F201063 EPA 163IE u F201063-BLK4 Mercury 003 050 ngL F201063 EPA 1631E U QB-04 F201063-BLKS Mercury 011 052 ngL F201063 EPA I631E U QB-06
Frontier Global Sciences Inc The results in this report only apply 10 1he samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Page 23 o26 1201073 Final Repon 04252012 25
Liz Siska Project Manager
11720 North Creek Parkway North Suite 400 Bothell WA 98011
Ph 425-686-1996 FROr~TIER- Fx 425-686-3096 GLOBAL SCIENCES
PREPARATION BLANKS
Instrument ICPMS-6 Sequence 2C22005
Preparation Closed Vessel Nitric Oven Digestion
Lab Sample ID Analyte Found MRL Units Batch Method Notes
F203271-BLK1 Beryllium 000008 0060 microgL F203271 PA 2008 Molt u F20327 1-BLK1 Sodium 2 20 microgL F20327l PA 2008 Moc u F20327I-BLK1 Aluminum -004 40 microgL F203271 PA 2008 Molt u F20327I -BLK1 Calcium 40 microgL F203271 PA 2008 Molt u F203271 -BLK1 Chromium -002 010 microgL F203271 ~A 2008 Molt u F203271-BLKI Manganese 001 010 microgL F203271 PA 2008 Molt u F20327 l -BLK 1 Iron -002 100 microgL F203271 PA 2008 Molt u F203271-BLKI Nickel 0004 010 microgL F203271 PA 2008 Moc u F203271-BLK1 Copper 0003 010 microgL F203271 PA 2008 Moc u F203271-BLK1 Zinc 0007 020 microgL F203271 PA 2008 Moc u F203271-BLK1 Arsenic -006 015 microgL F203271 PA 2008 Moc u F203271-BLK1 Selenium -002 060 microgL F203271 PA 2008 Moc u F203271-BLK1 Molybdenum 001 006 microgL F203271 PA 2008 Molt u F203271-BLK1 Silver -00005 0020 microgL F203271 PA 2008 Molt u F203271-BLKl Cadmium 0004 0020 microgL F203271 PA 2008 Molt u F20327 l-BLKl Antimony 0002 0020 microgL F203271 PA 2008 Molt u F203271-BLKI Barium 001 020 microgL F203271 PA 2008 Molt u F203271-BLKI Lead 0010 0040 microgL F203271 PA 2008 Moc u
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Page 24of26 1201073 Final Report 04252012 26
~
~TIER~ GLOBAL SCIENCES
11720 North Creek Parkway North Suite 400 Bothell WA 980ll
Ph 425-686-1996 Fx 425-686-3096
PREPARATION BLANKS
Instrument JCPMS-3 Sequence 2C25005
Preparation Closed Vessel Nitric Oven Digestion
Lab Sample ID Analyte Found MRL Units Batch Method Notes
F2033I4-BLK1 Thalium 00007 0010 microgL F2033I4 ~PA 2008 Molt u
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Page 25 o26Liz Siska Project Manager 1201073 Final Report
04252012 27
l l 720 North Creek Parkway North Suite 400~Vi-~ Bothell WA 98011 Ph 425-686-1 996~Tlmiddot~ Fx 425-686-3096
G L OBAL SCIENCE S
Notes and Definitions
U Analyte included in the analysis but not detected
QM-02 The MS andor MSD recoveries outside acceptance limits due to spike concentration less than I times the sample concentration The batch was accepted based on LCS and LCSD recoveries within control limits and when analysis permits acceptable AS ASD
QB-06 The blank was preserved to 5 BrCI rather than I The control limit for blanks preserved to greater than 1 BrCl is the preservation percentage multiplied by the MRL
QB-04 The blank was preserved to 2 BrCI rather than l The control limit for blanks preserved to greater than l BrCI is the preservation percentage multiplied by the MRL
FB-1631 Required equipmentfieldfilter blank not submitted by the client The sample has been analyzed according to 163 lE but does not meet 163 lE criteria
AS This MS andor MSD is an analytical spike andor an analytical spike duplicate
DET Analyte Detected
MDL Minimum Detection Limit
MRL Minimum Reporting Limit
ND Analyte Not Detected at or above the reporting limit
wet Sample results reported on a wet weight basis
dry Sample results reported on a dry weight basis
RPO Relative Percent Difference
RSD Relative Standard Deviation
Frontier Global Sciences Inc The lesults i111his reporl only apply to he samples analyzed In accordance with the chain ofcuslody document This analytical report must be reproduced in its entirely
Page 26of26 1201073 Final Report 04252012
Liz Siska Project Manager
28
CHAIN-OF-(USTODY ttECORD Page i of f 106677 _J
BoLD F1ELDS REQUIRED PLEASE C 1RCLE REQUESTED ANALYSIS
SAMPLE ID
middoti-rg -- bull ~rshy~ _- tzir +- lt-ltJ~ lt
SAMPLING
DATeTtME
IF COMPOSITE INDICATE BOTH
START amp FINISH
DATETIME li1J oc -r 111_- _vlt-c_
w Ishyt 0 n
w l w 0 ~ u X -Xmiddot ~ m Ishy lt( lt( 0
I C)
IIXJ JC
~ ~ irlte-t- T_ t- f r-n t I s-11 middott~ c~ J J1~w )(~ )
Trttbull rin K C-~-~ pound1t I 1Jtl~ t20~L lwlJI ishy
middot~ON Mm1x A-Al~ S-SOil GW-GampOUHO WATER SW-SUampfA(f WATER DWmiddotDRIIIKIKlti WATER
Itlt
-glo c ~
c t I O
~ t = ~ ~
~ o ~1
~ ~ ~
0
5 g sect ~ shy2 s z
rJ gII
)(
107555
i
~ I NOTES MEOH VIAL
1 WW-WASTE WATER PmmATIVE H-HCL H-HN01 S-H1SO Na-NaOH H-HEOH -~ --~
PROJECT MANAGER llr middot1 ~Q Aw4---P1V- Het_ r COMPANY t-lo--tm ~ bd i ( I ~j 6 A ADP~SS 91 g~ez tJshy(ITJ ~ STATE fH_ ZIP c3o--
PHONE 22j-((omiddotf EXT ____
fAX--------------------- shyE-MAIL (JbHd-esa e n ta wamp Sm NAME Meccft1lt-1ltk f--g
PROJECT _
OTHEi________STATpound NH MA ME VT
REGULATORY PROGRAM NPDES RGP POTW STORHWATEl OR
GWP OIL FUHD BROWNIIELO OR OTHER----------
Quon PO o2J~-lt1Jpound)
DATE NEEDED _1--1 middot Z=-----shy4 (1-1_ METALS 8 RCRA 13 pp ff MN PB Cu
QAQC REPORTJNGYVEL
A CG) O R
PRESUMPTIVE CERTAINTY
7i2lt_
RECpound1VEO BYRELINQUISHED BY DATE TIME SUSPECTED (OHTAHIHATIOH________
TEHP~ C REPORTING OPTIONS 01HEA METAL------------PRELIHl Yu OR No
DISSOLVED METALS FIELD FllTEREDI YES 110
rmreg No
IF YH FAX OR POf 7~shy Hom (IE SPECIAL DETECTION LINITl BllLIKGINfO If DlffERrnT)ELECTRONIC OPTIONS zo 1 2 2) le~C1 1 Jc Id sJ 60 6c
1 cf Co
lo FAX pound-MAIL PDF EQUll C jCi (e I rt--111 Ao NiAJrJe middotn th
Ka)Jcr(c C(cdd -ltJ c -l -gtck- z Alt 5e1 Hj
Al l 4_) it fG) 1uJ c(iJoclt-U Sin HISTORY 0Se-d Cim- ~pound rc~L IH t--6
1 r
ImiddotRELINQUISHED BY DATE TIHE RECflVEO BY I FIELD READINGS
eastern analytical inc 2s CHENELL D R1ve IC 0 Nco1to N H 0330 1 I TEL 60J22aos2s 1aoo2a1os2s IFAx 6032284591 j E-MA1t cus-roM111_mV1c~EAILAsscoMJ www1A1LAascoM
----i pmiddotofissionrrl11bomtorymim (WHITE ORIGINAL GREEN PROJECT MANAGER)
shy
Liz Sia Project Manager
11720 North Creek Parkway North Suite 400 Botheln VA 98011
Ph 425-686-1996 Fx 425-686-3096
CLOBAL SCIENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1201073-01RE4
Batch F203271 Sequence 2c2io2~
Preparation Clo~ed Vessel litric Oven Digestion Lab Number F20327 l -MSMSQ4
Analyte
Spike Added (microgL)
MSD Concentration
(microgL)
MSD
Recovery
Oo
RPD Recovery
Limits RPOLimit Method Notes
Silver 20200 1895 938 242 70 - 130 20 EPA 2008 Mod AS Cadmium 40400 3933 965 0104 70 -130 20 EPA 2008 Mod AS Antimony 20200 2107 102 0736 70- 130 20 EPA 2008 Mod AS
Barium 80800 1058 101 0205 70 - 130 20 EPA 2008 Mod AS
Lead 10100 9877 978 0549 70 - 130 20 EPA 2008 Mod AS
Frontier Global Sciences Inc The results in this report only apply to the samples analyudin accordance with lht chain ofcustody document This analytical report must be reproductd rn ilS enlirtty
Page l6of26 1201073 Final Report Ofn5202 18
l I 720 North Creek Parkway North Suite 400 Bothell WA 980I I
Ph 425-686-1996 Fx 425-686-3096
GLO B AL SCIENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1201073-01RE6
Batch F203314 Sequence 2C25005
Preparation Closed Vessel Nitric Oven Digestion Lab Number F203314-MSMSD2
Sample Spike MS MS Concentration Added Concentration RecoveryAnalyte (microgL) (microgL) (microgL) Recovery Method NotesLimits
Thallium 5563 040400 5875 773 70 - 130 EPA 2008 Mod
Spike MSD MSD Added o Concentration Recovery RPD
RPO Limits Limit Method Notes Analyte (microgL) (microgL) Recovery
Thallium 040400 5880 785 00859 70 - 130 20 EPA 2008 Mod
Frontier Global Sciences Inc 11e results in chis reporc only apply 10 1he samples analyzed in accordance wilh lhe chain ofcustody documenz This analycical report musl be reproduced in ils entirety
Page 17 of26 1201073 Fi11aReport 0412512012
Liz Siska Project Manager
19
11720 North Creek Parkway North Suite 400 Bothell WA 98011
Ph 425-686-1996 Fx 425-686-3096
GLOBAl SCIENC ES
MATRIX SPIKE I MATRIX SPIKE DUPLICATE RECOVERY AND RPO
SOURCE I201073-01RE6
Batch F203314
Preparation Closed Vessel Nitric Oven Digestion
Sequence 2C25005
Lab Number F203314-MSMSD4
Analyte
Sample Concentration
(microgL)
Spike Added (microgL)
MS MS Concentration Oo
(microgL) Recovery Recovery
Limits Method Notes
Thallium 5563 10100 1033 968 70- 130 EPA 2008 Mod AS
Analyte
Spike Added (microgL)
MSD Concentration
(microgL)
MS)) Oo
Recovery
RPD
Recovery Limits
RPD Limit Method Notes
Thallium IO100 1037 97l 0341 70 - 130 20 EPA 2008 Mod AS
Frontier Global Sciences Inc The resulrs in this report only apply to the samples analyzed in accordance with the chain ofcusrody document This analytical report must be reproduced in its entirely
Page 18of26 120073 Final Report 04252012
Liz Siska Project Manager
20
11720 North Creek Parkway North Suite 400 l ~ Bothell WA 980 l l Ph 425-686-1996
FRONTIER Fx 425-686-3096 GLOBAL SCIENCES
LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLICATE
RECOVERY AND RPD
Batch F20 l063 Sequence 2A09010
Preparation BrCI Oxidation Lab Number F201063-BSIBSJ21
LCS Source N ist 1641d
Analyte
Spike Added (ngL)
LCS Concentration
(ngL)
LCS
Recovery Recovery
Limits Method Notes
Mercury 15679 1550 988 80 - 120 EPA I631E
Analyte
Spike Added (ngL)
LCSD Concentration
(ngL)
LCSD Oo
Recovery
RPD Recovery
Limits RPD Limit Method Notes
Mercury 15679 1595 [02 289 80 - 120 24 EPA I631E
Frontier Global Sciences Inc The results in this report only apply to the samples analyzedin accordance with the chain ofcustody document This analytical report must be reproduced in ils entirety
Page 19of26 1201073 Final Report 0425 2012
Liz Siska Project Manager
21
11720 North Creek Parkway North Suite 400 Bothell WA 98011
Ph 425-686-1996 FRONTIER Fx 425-686-3096 GLOBAL SCIENCES
LABORA TORY CONTROL SAMPLE LABO RATORY CONTROL SAMPLE DUPLICATE
RECOVERY AND RPD
Batch F203271 Sequence 2C22005
Preparation Closed Vessel Nitric Oven Digestion Lab Number F203271-BSBSD1
LCS Source Blank Spike
Spike LCS LCS Added Concentration Oo Recovery
Analyte (microgL) (microgL) Recovery Limits Method Notes
Beryllium 20000 l930 965 85 - 115 EPA 2008 Mod
Sodium 50000 499 998 85 - 115 EPA 2008 Mod
Aluminum 15000 1460 973 85 - 115 EPA 2008 Mod
Calcium 15000 1528 102 85 - 115 EPA 2008 Mod
Chromium 70000 657 939 85 - 115 EPA 2008 Mod
Manganese 60000 586 976 85 - 115 EPA 2008 Mod
Iron 50000 4753 951 85 shy 115 EPA 2008 Mod
Nickel 40000 401 100 85 - 115 EPA 2008 Mod
Copper 40000 418 105 85 - 115 EPA 2008 Mod
Zinc 10000 1033 103 85 - 115 EPA 2008 Mod
Arsenic 15000 1437 958 85 - 115 EPA 2008 Mod
Selenium 30000 2966 989 85 - 115 EPA 2008 Mod
Molybdenum 20000 181 905 85 shy 115 EPA 2008 Mod
Silver 15000 1517 101 85 shy 115 EPA 2008 Mod
Cadmium 080000 0781 976 85 - 1lS EPA 2008 Mod
Antimony 080000 0815 102 85 - 115 EPA 2008 Mod
Barium 10000 969 969 85 - 115 EPA 2008 Mod
Lead 15000 1597 106 85 - 115 EPA 2008 Mod
Spike LCSD LCSD Added Concentration Recovery RPO
Analyte (microgL) (microgL) Recovery RPO Limits Limit Method Notes
Beryllium 20000 1949 974 0955 85 - 115 20 EPA 2008 Mod
Sodium 50000 500 100 0216 85 - 115 20 EPA 2008 Mod
Aluminum 15000 1485 990 171 85 - 115 20 EPA 2008 Mod
Calcium 15000 1544 103 103 85 - 115 20 EPA 2008 Mod
Chromium 70000 667 953 148 85 - 115 20 EPA 2008 Mod
Manganese 60000 596 994 175 85 - 115 20 EPA 2008 Mod
Iron 50000 4852 970 206 85 - 115 20 EPA 2008 Mod
Nickel 40000 402 IOI 0246 85 - 115 20 EPA 2008 Mod
Frontier Global Sciences Inc The results in his report only apply to the samples analyzed in accordance wirh the chain ofcustody document This analytical report must be reproduced in iLS entirety
Page 20of26 1201073 Final Report 04252012
Liz Siska Project Manager
22
11720 North Creek Parkway North Suite 400 ~~shy Bothell WA 98011 Ph 425-686-1996~ONTif Fx 425-686-3096
GLOBAL SCIENCES
LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLICATE
RECOVERY AND RPO
Batch F20327 l Sequence 2C22005
Preparation Closed Vessel Nitric Oven Digestion Lab Number F203271-BSBSD 1
LCS Source Blank Spike
Analyte
Spike Added (microgL)
LCSD Concentration
(microgL)
LCSD oo
Recovery
RPO Recovery
Limits RPO Limit Method Notes
Copper
Zinc
Arsenic
Selenium
40000
10000
15000
30000
428
1039
1452
3015
107
104
968
101
224
0570
0977
166
85 - 115
85 - 115
85 - 115
85 - 115
20
20
20
20
EPA 2008 Mod
EPA 2008 Mod
EPA 2008 Mod
EPA 2008 Mod Molybdenum
Silver
20000
15000
182
J502
910
100
0564
103
85 - 115
85 - 115
20
20
EPA 2008 Mod
EPA 2008 Mod Cadmium
Antimony
Barium
Lead
080000
080000
10000
15000
0828
0808
986
1620
103
101
986
108
585
0848
177
142
85 - 115
85 - 115
85 shy 11 S
85 - 115
20
20
20
20
EPA 2008 Mod
EPA 2008 Mod
EPA 2008 Mod
EPA 2008 Mod
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report mus be reproducedin its entirety
Page 2 o26J20J073 Final Report 041252012
Liz Siska Project Manager
23
11720 North Creek Parkway North Suite 400 Bothell WA 980 l l
Ph 425-686-1996FRONT[ER- Fx 425-686-3096 cLosAL SCIEN _CES
LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLICATE
RECOVERY AND RPD
Batch F203314 Sequence 2C25005
Preparation Closed Vessel Nitric Oven Digestion Lab Number F2033 l 4-BSBSD 1
LCS Source Blank Spike
Analyte
Thallium
Spike Added (microgL)
LCS Concentration
(microgL)
LCS 0o
Recovery Recovery
Limits Method
040000 0396 989 85 - 115 EPA 2008 Mod
Notes
Analyte
Spike Added (microgL)
LCSD Concentration
(microgL)
LCSD 0o
Recovery
RPD Recovery
Limits RPO Limit Method Notes
Thallium 040000 0391 978 112 85 - ll5 20 EPA 2008 Mod
Frontier Global Sciences Inc The results in this report only apply to the samples anayed in accordance with the chain ofcustody docwnenJ This analytical report must be reproduced in its entirety
Page 22of26 1201073 Final Report 04252012
Liz Siska Project Manager
24
Liz Siska P roject Manager
11720 North Creek Parkway North Suite 400
~ Bothell WA 98011 Ph 425-686-1996
~JTIEif middot Fx 425-686-3096 GLOBAL SCIENCES
PREPARATION BLANKS
Instrument Hg-17 Sequence 2A09010
Preparation BrCI Oxidation
Lab Sample ID Analyte Found MRL Units Batch Method Notes
F201063-BLK I Mercury -0009 050 ngL F201063 EPA 1631E u F20 I063-BLK2 Mercury -0006 050 ngL F201063 EPA 1631E u F201063-BLK3 Mercury -002 050 ngL F201063 EPA 163IE u F201063-BLK4 Mercury 003 050 ngL F201063 EPA 1631E U QB-04 F201063-BLKS Mercury 011 052 ngL F201063 EPA I631E U QB-06
Frontier Global Sciences Inc The results in this report only apply 10 1he samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Page 23 o26 1201073 Final Repon 04252012 25
Liz Siska Project Manager
11720 North Creek Parkway North Suite 400 Bothell WA 98011
Ph 425-686-1996 FROr~TIER- Fx 425-686-3096 GLOBAL SCIENCES
PREPARATION BLANKS
Instrument ICPMS-6 Sequence 2C22005
Preparation Closed Vessel Nitric Oven Digestion
Lab Sample ID Analyte Found MRL Units Batch Method Notes
F203271-BLK1 Beryllium 000008 0060 microgL F203271 PA 2008 Molt u F20327 1-BLK1 Sodium 2 20 microgL F20327l PA 2008 Moc u F20327I-BLK1 Aluminum -004 40 microgL F203271 PA 2008 Molt u F20327I -BLK1 Calcium 40 microgL F203271 PA 2008 Molt u F203271 -BLK1 Chromium -002 010 microgL F203271 ~A 2008 Molt u F203271-BLKI Manganese 001 010 microgL F203271 PA 2008 Molt u F20327 l -BLK 1 Iron -002 100 microgL F203271 PA 2008 Molt u F203271-BLKI Nickel 0004 010 microgL F203271 PA 2008 Moc u F203271-BLK1 Copper 0003 010 microgL F203271 PA 2008 Moc u F203271-BLK1 Zinc 0007 020 microgL F203271 PA 2008 Moc u F203271-BLK1 Arsenic -006 015 microgL F203271 PA 2008 Moc u F203271-BLK1 Selenium -002 060 microgL F203271 PA 2008 Moc u F203271-BLK1 Molybdenum 001 006 microgL F203271 PA 2008 Molt u F203271-BLK1 Silver -00005 0020 microgL F203271 PA 2008 Molt u F203271-BLKl Cadmium 0004 0020 microgL F203271 PA 2008 Molt u F20327 l-BLKl Antimony 0002 0020 microgL F203271 PA 2008 Molt u F203271-BLKI Barium 001 020 microgL F203271 PA 2008 Molt u F203271-BLKI Lead 0010 0040 microgL F203271 PA 2008 Moc u
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Page 24of26 1201073 Final Report 04252012 26
~
~TIER~ GLOBAL SCIENCES
11720 North Creek Parkway North Suite 400 Bothell WA 980ll
Ph 425-686-1996 Fx 425-686-3096
PREPARATION BLANKS
Instrument JCPMS-3 Sequence 2C25005
Preparation Closed Vessel Nitric Oven Digestion
Lab Sample ID Analyte Found MRL Units Batch Method Notes
F2033I4-BLK1 Thalium 00007 0010 microgL F2033I4 ~PA 2008 Molt u
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Page 25 o26Liz Siska Project Manager 1201073 Final Report
04252012 27
l l 720 North Creek Parkway North Suite 400~Vi-~ Bothell WA 98011 Ph 425-686-1 996~Tlmiddot~ Fx 425-686-3096
G L OBAL SCIENCE S
Notes and Definitions
U Analyte included in the analysis but not detected
QM-02 The MS andor MSD recoveries outside acceptance limits due to spike concentration less than I times the sample concentration The batch was accepted based on LCS and LCSD recoveries within control limits and when analysis permits acceptable AS ASD
QB-06 The blank was preserved to 5 BrCI rather than I The control limit for blanks preserved to greater than 1 BrCl is the preservation percentage multiplied by the MRL
QB-04 The blank was preserved to 2 BrCI rather than l The control limit for blanks preserved to greater than l BrCI is the preservation percentage multiplied by the MRL
FB-1631 Required equipmentfieldfilter blank not submitted by the client The sample has been analyzed according to 163 lE but does not meet 163 lE criteria
AS This MS andor MSD is an analytical spike andor an analytical spike duplicate
DET Analyte Detected
MDL Minimum Detection Limit
MRL Minimum Reporting Limit
ND Analyte Not Detected at or above the reporting limit
wet Sample results reported on a wet weight basis
dry Sample results reported on a dry weight basis
RPO Relative Percent Difference
RSD Relative Standard Deviation
Frontier Global Sciences Inc The lesults i111his reporl only apply to he samples analyzed In accordance with the chain ofcuslody document This analytical report must be reproduced in its entirely
Page 26of26 1201073 Final Report 04252012
Liz Siska Project Manager
28
CHAIN-OF-(USTODY ttECORD Page i of f 106677 _J
BoLD F1ELDS REQUIRED PLEASE C 1RCLE REQUESTED ANALYSIS
SAMPLE ID
middoti-rg -- bull ~rshy~ _- tzir +- lt-ltJ~ lt
SAMPLING
DATeTtME
IF COMPOSITE INDICATE BOTH
START amp FINISH
DATETIME li1J oc -r 111_- _vlt-c_
w Ishyt 0 n
w l w 0 ~ u X -Xmiddot ~ m Ishy lt( lt( 0
I C)
IIXJ JC
~ ~ irlte-t- T_ t- f r-n t I s-11 middott~ c~ J J1~w )(~ )
Trttbull rin K C-~-~ pound1t I 1Jtl~ t20~L lwlJI ishy
middot~ON Mm1x A-Al~ S-SOil GW-GampOUHO WATER SW-SUampfA(f WATER DWmiddotDRIIIKIKlti WATER
Itlt
-glo c ~
c t I O
~ t = ~ ~
~ o ~1
~ ~ ~
0
5 g sect ~ shy2 s z
rJ gII
)(
107555
i
~ I NOTES MEOH VIAL
1 WW-WASTE WATER PmmATIVE H-HCL H-HN01 S-H1SO Na-NaOH H-HEOH -~ --~
PROJECT MANAGER llr middot1 ~Q Aw4---P1V- Het_ r COMPANY t-lo--tm ~ bd i ( I ~j 6 A ADP~SS 91 g~ez tJshy(ITJ ~ STATE fH_ ZIP c3o--
PHONE 22j-((omiddotf EXT ____
fAX--------------------- shyE-MAIL (JbHd-esa e n ta wamp Sm NAME Meccft1lt-1ltk f--g
PROJECT _
OTHEi________STATpound NH MA ME VT
REGULATORY PROGRAM NPDES RGP POTW STORHWATEl OR
GWP OIL FUHD BROWNIIELO OR OTHER----------
Quon PO o2J~-lt1Jpound)
DATE NEEDED _1--1 middot Z=-----shy4 (1-1_ METALS 8 RCRA 13 pp ff MN PB Cu
QAQC REPORTJNGYVEL
A CG) O R
PRESUMPTIVE CERTAINTY
7i2lt_
RECpound1VEO BYRELINQUISHED BY DATE TIME SUSPECTED (OHTAHIHATIOH________
TEHP~ C REPORTING OPTIONS 01HEA METAL------------PRELIHl Yu OR No
DISSOLVED METALS FIELD FllTEREDI YES 110
rmreg No
IF YH FAX OR POf 7~shy Hom (IE SPECIAL DETECTION LINITl BllLIKGINfO If DlffERrnT)ELECTRONIC OPTIONS zo 1 2 2) le~C1 1 Jc Id sJ 60 6c
1 cf Co
lo FAX pound-MAIL PDF EQUll C jCi (e I rt--111 Ao NiAJrJe middotn th
Ka)Jcr(c C(cdd -ltJ c -l -gtck- z Alt 5e1 Hj
Al l 4_) it fG) 1uJ c(iJoclt-U Sin HISTORY 0Se-d Cim- ~pound rc~L IH t--6
1 r
ImiddotRELINQUISHED BY DATE TIHE RECflVEO BY I FIELD READINGS
eastern analytical inc 2s CHENELL D R1ve IC 0 Nco1to N H 0330 1 I TEL 60J22aos2s 1aoo2a1os2s IFAx 6032284591 j E-MA1t cus-roM111_mV1c~EAILAsscoMJ www1A1LAascoM
----i pmiddotofissionrrl11bomtorymim (WHITE ORIGINAL GREEN PROJECT MANAGER)
shy
l I 720 North Creek Parkway North Suite 400 Bothell WA 980I I
Ph 425-686-1996 Fx 425-686-3096
GLO B AL SCIENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1201073-01RE6
Batch F203314 Sequence 2C25005
Preparation Closed Vessel Nitric Oven Digestion Lab Number F203314-MSMSD2
Sample Spike MS MS Concentration Added Concentration RecoveryAnalyte (microgL) (microgL) (microgL) Recovery Method NotesLimits
Thallium 5563 040400 5875 773 70 - 130 EPA 2008 Mod
Spike MSD MSD Added o Concentration Recovery RPD
RPO Limits Limit Method Notes Analyte (microgL) (microgL) Recovery
Thallium 040400 5880 785 00859 70 - 130 20 EPA 2008 Mod
Frontier Global Sciences Inc 11e results in chis reporc only apply 10 1he samples analyzed in accordance wilh lhe chain ofcustody documenz This analycical report musl be reproduced in ils entirety
Page 17 of26 1201073 Fi11aReport 0412512012
Liz Siska Project Manager
19
11720 North Creek Parkway North Suite 400 Bothell WA 98011
Ph 425-686-1996 Fx 425-686-3096
GLOBAl SCIENC ES
MATRIX SPIKE I MATRIX SPIKE DUPLICATE RECOVERY AND RPO
SOURCE I201073-01RE6
Batch F203314
Preparation Closed Vessel Nitric Oven Digestion
Sequence 2C25005
Lab Number F203314-MSMSD4
Analyte
Sample Concentration
(microgL)
Spike Added (microgL)
MS MS Concentration Oo
(microgL) Recovery Recovery
Limits Method Notes
Thallium 5563 10100 1033 968 70- 130 EPA 2008 Mod AS
Analyte
Spike Added (microgL)
MSD Concentration
(microgL)
MS)) Oo
Recovery
RPD
Recovery Limits
RPD Limit Method Notes
Thallium IO100 1037 97l 0341 70 - 130 20 EPA 2008 Mod AS
Frontier Global Sciences Inc The resulrs in this report only apply to the samples analyzed in accordance with the chain ofcusrody document This analytical report must be reproduced in its entirely
Page 18of26 120073 Final Report 04252012
Liz Siska Project Manager
20
11720 North Creek Parkway North Suite 400 l ~ Bothell WA 980 l l Ph 425-686-1996
FRONTIER Fx 425-686-3096 GLOBAL SCIENCES
LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLICATE
RECOVERY AND RPD
Batch F20 l063 Sequence 2A09010
Preparation BrCI Oxidation Lab Number F201063-BSIBSJ21
LCS Source N ist 1641d
Analyte
Spike Added (ngL)
LCS Concentration
(ngL)
LCS
Recovery Recovery
Limits Method Notes
Mercury 15679 1550 988 80 - 120 EPA I631E
Analyte
Spike Added (ngL)
LCSD Concentration
(ngL)
LCSD Oo
Recovery
RPD Recovery
Limits RPD Limit Method Notes
Mercury 15679 1595 [02 289 80 - 120 24 EPA I631E
Frontier Global Sciences Inc The results in this report only apply to the samples analyzedin accordance with the chain ofcustody document This analytical report must be reproduced in ils entirety
Page 19of26 1201073 Final Report 0425 2012
Liz Siska Project Manager
21
11720 North Creek Parkway North Suite 400 Bothell WA 98011
Ph 425-686-1996 FRONTIER Fx 425-686-3096 GLOBAL SCIENCES
LABORA TORY CONTROL SAMPLE LABO RATORY CONTROL SAMPLE DUPLICATE
RECOVERY AND RPD
Batch F203271 Sequence 2C22005
Preparation Closed Vessel Nitric Oven Digestion Lab Number F203271-BSBSD1
LCS Source Blank Spike
Spike LCS LCS Added Concentration Oo Recovery
Analyte (microgL) (microgL) Recovery Limits Method Notes
Beryllium 20000 l930 965 85 - 115 EPA 2008 Mod
Sodium 50000 499 998 85 - 115 EPA 2008 Mod
Aluminum 15000 1460 973 85 - 115 EPA 2008 Mod
Calcium 15000 1528 102 85 - 115 EPA 2008 Mod
Chromium 70000 657 939 85 - 115 EPA 2008 Mod
Manganese 60000 586 976 85 - 115 EPA 2008 Mod
Iron 50000 4753 951 85 shy 115 EPA 2008 Mod
Nickel 40000 401 100 85 - 115 EPA 2008 Mod
Copper 40000 418 105 85 - 115 EPA 2008 Mod
Zinc 10000 1033 103 85 - 115 EPA 2008 Mod
Arsenic 15000 1437 958 85 - 115 EPA 2008 Mod
Selenium 30000 2966 989 85 - 115 EPA 2008 Mod
Molybdenum 20000 181 905 85 shy 115 EPA 2008 Mod
Silver 15000 1517 101 85 shy 115 EPA 2008 Mod
Cadmium 080000 0781 976 85 - 1lS EPA 2008 Mod
Antimony 080000 0815 102 85 - 115 EPA 2008 Mod
Barium 10000 969 969 85 - 115 EPA 2008 Mod
Lead 15000 1597 106 85 - 115 EPA 2008 Mod
Spike LCSD LCSD Added Concentration Recovery RPO
Analyte (microgL) (microgL) Recovery RPO Limits Limit Method Notes
Beryllium 20000 1949 974 0955 85 - 115 20 EPA 2008 Mod
Sodium 50000 500 100 0216 85 - 115 20 EPA 2008 Mod
Aluminum 15000 1485 990 171 85 - 115 20 EPA 2008 Mod
Calcium 15000 1544 103 103 85 - 115 20 EPA 2008 Mod
Chromium 70000 667 953 148 85 - 115 20 EPA 2008 Mod
Manganese 60000 596 994 175 85 - 115 20 EPA 2008 Mod
Iron 50000 4852 970 206 85 - 115 20 EPA 2008 Mod
Nickel 40000 402 IOI 0246 85 - 115 20 EPA 2008 Mod
Frontier Global Sciences Inc The results in his report only apply to the samples analyzed in accordance wirh the chain ofcustody document This analytical report must be reproduced in iLS entirety
Page 20of26 1201073 Final Report 04252012
Liz Siska Project Manager
22
11720 North Creek Parkway North Suite 400 ~~shy Bothell WA 98011 Ph 425-686-1996~ONTif Fx 425-686-3096
GLOBAL SCIENCES
LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLICATE
RECOVERY AND RPO
Batch F20327 l Sequence 2C22005
Preparation Closed Vessel Nitric Oven Digestion Lab Number F203271-BSBSD 1
LCS Source Blank Spike
Analyte
Spike Added (microgL)
LCSD Concentration
(microgL)
LCSD oo
Recovery
RPO Recovery
Limits RPO Limit Method Notes
Copper
Zinc
Arsenic
Selenium
40000
10000
15000
30000
428
1039
1452
3015
107
104
968
101
224
0570
0977
166
85 - 115
85 - 115
85 - 115
85 - 115
20
20
20
20
EPA 2008 Mod
EPA 2008 Mod
EPA 2008 Mod
EPA 2008 Mod Molybdenum
Silver
20000
15000
182
J502
910
100
0564
103
85 - 115
85 - 115
20
20
EPA 2008 Mod
EPA 2008 Mod Cadmium
Antimony
Barium
Lead
080000
080000
10000
15000
0828
0808
986
1620
103
101
986
108
585
0848
177
142
85 - 115
85 - 115
85 shy 11 S
85 - 115
20
20
20
20
EPA 2008 Mod
EPA 2008 Mod
EPA 2008 Mod
EPA 2008 Mod
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report mus be reproducedin its entirety
Page 2 o26J20J073 Final Report 041252012
Liz Siska Project Manager
23
11720 North Creek Parkway North Suite 400 Bothell WA 980 l l
Ph 425-686-1996FRONT[ER- Fx 425-686-3096 cLosAL SCIEN _CES
LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLICATE
RECOVERY AND RPD
Batch F203314 Sequence 2C25005
Preparation Closed Vessel Nitric Oven Digestion Lab Number F2033 l 4-BSBSD 1
LCS Source Blank Spike
Analyte
Thallium
Spike Added (microgL)
LCS Concentration
(microgL)
LCS 0o
Recovery Recovery
Limits Method
040000 0396 989 85 - 115 EPA 2008 Mod
Notes
Analyte
Spike Added (microgL)
LCSD Concentration
(microgL)
LCSD 0o
Recovery
RPD Recovery
Limits RPO Limit Method Notes
Thallium 040000 0391 978 112 85 - ll5 20 EPA 2008 Mod
Frontier Global Sciences Inc The results in this report only apply to the samples anayed in accordance with the chain ofcustody docwnenJ This analytical report must be reproduced in its entirety
Page 22of26 1201073 Final Report 04252012
Liz Siska Project Manager
24
Liz Siska P roject Manager
11720 North Creek Parkway North Suite 400
~ Bothell WA 98011 Ph 425-686-1996
~JTIEif middot Fx 425-686-3096 GLOBAL SCIENCES
PREPARATION BLANKS
Instrument Hg-17 Sequence 2A09010
Preparation BrCI Oxidation
Lab Sample ID Analyte Found MRL Units Batch Method Notes
F201063-BLK I Mercury -0009 050 ngL F201063 EPA 1631E u F20 I063-BLK2 Mercury -0006 050 ngL F201063 EPA 1631E u F201063-BLK3 Mercury -002 050 ngL F201063 EPA 163IE u F201063-BLK4 Mercury 003 050 ngL F201063 EPA 1631E U QB-04 F201063-BLKS Mercury 011 052 ngL F201063 EPA I631E U QB-06
Frontier Global Sciences Inc The results in this report only apply 10 1he samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Page 23 o26 1201073 Final Repon 04252012 25
Liz Siska Project Manager
11720 North Creek Parkway North Suite 400 Bothell WA 98011
Ph 425-686-1996 FROr~TIER- Fx 425-686-3096 GLOBAL SCIENCES
PREPARATION BLANKS
Instrument ICPMS-6 Sequence 2C22005
Preparation Closed Vessel Nitric Oven Digestion
Lab Sample ID Analyte Found MRL Units Batch Method Notes
F203271-BLK1 Beryllium 000008 0060 microgL F203271 PA 2008 Molt u F20327 1-BLK1 Sodium 2 20 microgL F20327l PA 2008 Moc u F20327I-BLK1 Aluminum -004 40 microgL F203271 PA 2008 Molt u F20327I -BLK1 Calcium 40 microgL F203271 PA 2008 Molt u F203271 -BLK1 Chromium -002 010 microgL F203271 ~A 2008 Molt u F203271-BLKI Manganese 001 010 microgL F203271 PA 2008 Molt u F20327 l -BLK 1 Iron -002 100 microgL F203271 PA 2008 Molt u F203271-BLKI Nickel 0004 010 microgL F203271 PA 2008 Moc u F203271-BLK1 Copper 0003 010 microgL F203271 PA 2008 Moc u F203271-BLK1 Zinc 0007 020 microgL F203271 PA 2008 Moc u F203271-BLK1 Arsenic -006 015 microgL F203271 PA 2008 Moc u F203271-BLK1 Selenium -002 060 microgL F203271 PA 2008 Moc u F203271-BLK1 Molybdenum 001 006 microgL F203271 PA 2008 Molt u F203271-BLK1 Silver -00005 0020 microgL F203271 PA 2008 Molt u F203271-BLKl Cadmium 0004 0020 microgL F203271 PA 2008 Molt u F20327 l-BLKl Antimony 0002 0020 microgL F203271 PA 2008 Molt u F203271-BLKI Barium 001 020 microgL F203271 PA 2008 Molt u F203271-BLKI Lead 0010 0040 microgL F203271 PA 2008 Moc u
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Page 24of26 1201073 Final Report 04252012 26
~
~TIER~ GLOBAL SCIENCES
11720 North Creek Parkway North Suite 400 Bothell WA 980ll
Ph 425-686-1996 Fx 425-686-3096
PREPARATION BLANKS
Instrument JCPMS-3 Sequence 2C25005
Preparation Closed Vessel Nitric Oven Digestion
Lab Sample ID Analyte Found MRL Units Batch Method Notes
F2033I4-BLK1 Thalium 00007 0010 microgL F2033I4 ~PA 2008 Molt u
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Page 25 o26Liz Siska Project Manager 1201073 Final Report
04252012 27
l l 720 North Creek Parkway North Suite 400~Vi-~ Bothell WA 98011 Ph 425-686-1 996~Tlmiddot~ Fx 425-686-3096
G L OBAL SCIENCE S
Notes and Definitions
U Analyte included in the analysis but not detected
QM-02 The MS andor MSD recoveries outside acceptance limits due to spike concentration less than I times the sample concentration The batch was accepted based on LCS and LCSD recoveries within control limits and when analysis permits acceptable AS ASD
QB-06 The blank was preserved to 5 BrCI rather than I The control limit for blanks preserved to greater than 1 BrCl is the preservation percentage multiplied by the MRL
QB-04 The blank was preserved to 2 BrCI rather than l The control limit for blanks preserved to greater than l BrCI is the preservation percentage multiplied by the MRL
FB-1631 Required equipmentfieldfilter blank not submitted by the client The sample has been analyzed according to 163 lE but does not meet 163 lE criteria
AS This MS andor MSD is an analytical spike andor an analytical spike duplicate
DET Analyte Detected
MDL Minimum Detection Limit
MRL Minimum Reporting Limit
ND Analyte Not Detected at or above the reporting limit
wet Sample results reported on a wet weight basis
dry Sample results reported on a dry weight basis
RPO Relative Percent Difference
RSD Relative Standard Deviation
Frontier Global Sciences Inc The lesults i111his reporl only apply to he samples analyzed In accordance with the chain ofcuslody document This analytical report must be reproduced in its entirely
Page 26of26 1201073 Final Report 04252012
Liz Siska Project Manager
28
CHAIN-OF-(USTODY ttECORD Page i of f 106677 _J
BoLD F1ELDS REQUIRED PLEASE C 1RCLE REQUESTED ANALYSIS
SAMPLE ID
middoti-rg -- bull ~rshy~ _- tzir +- lt-ltJ~ lt
SAMPLING
DATeTtME
IF COMPOSITE INDICATE BOTH
START amp FINISH
DATETIME li1J oc -r 111_- _vlt-c_
w Ishyt 0 n
w l w 0 ~ u X -Xmiddot ~ m Ishy lt( lt( 0
I C)
IIXJ JC
~ ~ irlte-t- T_ t- f r-n t I s-11 middott~ c~ J J1~w )(~ )
Trttbull rin K C-~-~ pound1t I 1Jtl~ t20~L lwlJI ishy
middot~ON Mm1x A-Al~ S-SOil GW-GampOUHO WATER SW-SUampfA(f WATER DWmiddotDRIIIKIKlti WATER
Itlt
-glo c ~
c t I O
~ t = ~ ~
~ o ~1
~ ~ ~
0
5 g sect ~ shy2 s z
rJ gII
)(
107555
i
~ I NOTES MEOH VIAL
1 WW-WASTE WATER PmmATIVE H-HCL H-HN01 S-H1SO Na-NaOH H-HEOH -~ --~
PROJECT MANAGER llr middot1 ~Q Aw4---P1V- Het_ r COMPANY t-lo--tm ~ bd i ( I ~j 6 A ADP~SS 91 g~ez tJshy(ITJ ~ STATE fH_ ZIP c3o--
PHONE 22j-((omiddotf EXT ____
fAX--------------------- shyE-MAIL (JbHd-esa e n ta wamp Sm NAME Meccft1lt-1ltk f--g
PROJECT _
OTHEi________STATpound NH MA ME VT
REGULATORY PROGRAM NPDES RGP POTW STORHWATEl OR
GWP OIL FUHD BROWNIIELO OR OTHER----------
Quon PO o2J~-lt1Jpound)
DATE NEEDED _1--1 middot Z=-----shy4 (1-1_ METALS 8 RCRA 13 pp ff MN PB Cu
QAQC REPORTJNGYVEL
A CG) O R
PRESUMPTIVE CERTAINTY
7i2lt_
RECpound1VEO BYRELINQUISHED BY DATE TIME SUSPECTED (OHTAHIHATIOH________
TEHP~ C REPORTING OPTIONS 01HEA METAL------------PRELIHl Yu OR No
DISSOLVED METALS FIELD FllTEREDI YES 110
rmreg No
IF YH FAX OR POf 7~shy Hom (IE SPECIAL DETECTION LINITl BllLIKGINfO If DlffERrnT)ELECTRONIC OPTIONS zo 1 2 2) le~C1 1 Jc Id sJ 60 6c
1 cf Co
lo FAX pound-MAIL PDF EQUll C jCi (e I rt--111 Ao NiAJrJe middotn th
Ka)Jcr(c C(cdd -ltJ c -l -gtck- z Alt 5e1 Hj
Al l 4_) it fG) 1uJ c(iJoclt-U Sin HISTORY 0Se-d Cim- ~pound rc~L IH t--6
1 r
ImiddotRELINQUISHED BY DATE TIHE RECflVEO BY I FIELD READINGS
eastern analytical inc 2s CHENELL D R1ve IC 0 Nco1to N H 0330 1 I TEL 60J22aos2s 1aoo2a1os2s IFAx 6032284591 j E-MA1t cus-roM111_mV1c~EAILAsscoMJ www1A1LAascoM
----i pmiddotofissionrrl11bomtorymim (WHITE ORIGINAL GREEN PROJECT MANAGER)
shy
11720 North Creek Parkway North Suite 400 Bothell WA 98011
Ph 425-686-1996 Fx 425-686-3096
GLOBAl SCIENC ES
MATRIX SPIKE I MATRIX SPIKE DUPLICATE RECOVERY AND RPO
SOURCE I201073-01RE6
Batch F203314
Preparation Closed Vessel Nitric Oven Digestion
Sequence 2C25005
Lab Number F203314-MSMSD4
Analyte
Sample Concentration
(microgL)
Spike Added (microgL)
MS MS Concentration Oo
(microgL) Recovery Recovery
Limits Method Notes
Thallium 5563 10100 1033 968 70- 130 EPA 2008 Mod AS
Analyte
Spike Added (microgL)
MSD Concentration
(microgL)
MS)) Oo
Recovery
RPD
Recovery Limits
RPD Limit Method Notes
Thallium IO100 1037 97l 0341 70 - 130 20 EPA 2008 Mod AS
Frontier Global Sciences Inc The resulrs in this report only apply to the samples analyzed in accordance with the chain ofcusrody document This analytical report must be reproduced in its entirely
Page 18of26 120073 Final Report 04252012
Liz Siska Project Manager
20
11720 North Creek Parkway North Suite 400 l ~ Bothell WA 980 l l Ph 425-686-1996
FRONTIER Fx 425-686-3096 GLOBAL SCIENCES
LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLICATE
RECOVERY AND RPD
Batch F20 l063 Sequence 2A09010
Preparation BrCI Oxidation Lab Number F201063-BSIBSJ21
LCS Source N ist 1641d
Analyte
Spike Added (ngL)
LCS Concentration
(ngL)
LCS
Recovery Recovery
Limits Method Notes
Mercury 15679 1550 988 80 - 120 EPA I631E
Analyte
Spike Added (ngL)
LCSD Concentration
(ngL)
LCSD Oo
Recovery
RPD Recovery
Limits RPD Limit Method Notes
Mercury 15679 1595 [02 289 80 - 120 24 EPA I631E
Frontier Global Sciences Inc The results in this report only apply to the samples analyzedin accordance with the chain ofcustody document This analytical report must be reproduced in ils entirety
Page 19of26 1201073 Final Report 0425 2012
Liz Siska Project Manager
21
11720 North Creek Parkway North Suite 400 Bothell WA 98011
Ph 425-686-1996 FRONTIER Fx 425-686-3096 GLOBAL SCIENCES
LABORA TORY CONTROL SAMPLE LABO RATORY CONTROL SAMPLE DUPLICATE
RECOVERY AND RPD
Batch F203271 Sequence 2C22005
Preparation Closed Vessel Nitric Oven Digestion Lab Number F203271-BSBSD1
LCS Source Blank Spike
Spike LCS LCS Added Concentration Oo Recovery
Analyte (microgL) (microgL) Recovery Limits Method Notes
Beryllium 20000 l930 965 85 - 115 EPA 2008 Mod
Sodium 50000 499 998 85 - 115 EPA 2008 Mod
Aluminum 15000 1460 973 85 - 115 EPA 2008 Mod
Calcium 15000 1528 102 85 - 115 EPA 2008 Mod
Chromium 70000 657 939 85 - 115 EPA 2008 Mod
Manganese 60000 586 976 85 - 115 EPA 2008 Mod
Iron 50000 4753 951 85 shy 115 EPA 2008 Mod
Nickel 40000 401 100 85 - 115 EPA 2008 Mod
Copper 40000 418 105 85 - 115 EPA 2008 Mod
Zinc 10000 1033 103 85 - 115 EPA 2008 Mod
Arsenic 15000 1437 958 85 - 115 EPA 2008 Mod
Selenium 30000 2966 989 85 - 115 EPA 2008 Mod
Molybdenum 20000 181 905 85 shy 115 EPA 2008 Mod
Silver 15000 1517 101 85 shy 115 EPA 2008 Mod
Cadmium 080000 0781 976 85 - 1lS EPA 2008 Mod
Antimony 080000 0815 102 85 - 115 EPA 2008 Mod
Barium 10000 969 969 85 - 115 EPA 2008 Mod
Lead 15000 1597 106 85 - 115 EPA 2008 Mod
Spike LCSD LCSD Added Concentration Recovery RPO
Analyte (microgL) (microgL) Recovery RPO Limits Limit Method Notes
Beryllium 20000 1949 974 0955 85 - 115 20 EPA 2008 Mod
Sodium 50000 500 100 0216 85 - 115 20 EPA 2008 Mod
Aluminum 15000 1485 990 171 85 - 115 20 EPA 2008 Mod
Calcium 15000 1544 103 103 85 - 115 20 EPA 2008 Mod
Chromium 70000 667 953 148 85 - 115 20 EPA 2008 Mod
Manganese 60000 596 994 175 85 - 115 20 EPA 2008 Mod
Iron 50000 4852 970 206 85 - 115 20 EPA 2008 Mod
Nickel 40000 402 IOI 0246 85 - 115 20 EPA 2008 Mod
Frontier Global Sciences Inc The results in his report only apply to the samples analyzed in accordance wirh the chain ofcustody document This analytical report must be reproduced in iLS entirety
Page 20of26 1201073 Final Report 04252012
Liz Siska Project Manager
22
11720 North Creek Parkway North Suite 400 ~~shy Bothell WA 98011 Ph 425-686-1996~ONTif Fx 425-686-3096
GLOBAL SCIENCES
LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLICATE
RECOVERY AND RPO
Batch F20327 l Sequence 2C22005
Preparation Closed Vessel Nitric Oven Digestion Lab Number F203271-BSBSD 1
LCS Source Blank Spike
Analyte
Spike Added (microgL)
LCSD Concentration
(microgL)
LCSD oo
Recovery
RPO Recovery
Limits RPO Limit Method Notes
Copper
Zinc
Arsenic
Selenium
40000
10000
15000
30000
428
1039
1452
3015
107
104
968
101
224
0570
0977
166
85 - 115
85 - 115
85 - 115
85 - 115
20
20
20
20
EPA 2008 Mod
EPA 2008 Mod
EPA 2008 Mod
EPA 2008 Mod Molybdenum
Silver
20000
15000
182
J502
910
100
0564
103
85 - 115
85 - 115
20
20
EPA 2008 Mod
EPA 2008 Mod Cadmium
Antimony
Barium
Lead
080000
080000
10000
15000
0828
0808
986
1620
103
101
986
108
585
0848
177
142
85 - 115
85 - 115
85 shy 11 S
85 - 115
20
20
20
20
EPA 2008 Mod
EPA 2008 Mod
EPA 2008 Mod
EPA 2008 Mod
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report mus be reproducedin its entirety
Page 2 o26J20J073 Final Report 041252012
Liz Siska Project Manager
23
11720 North Creek Parkway North Suite 400 Bothell WA 980 l l
Ph 425-686-1996FRONT[ER- Fx 425-686-3096 cLosAL SCIEN _CES
LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLICATE
RECOVERY AND RPD
Batch F203314 Sequence 2C25005
Preparation Closed Vessel Nitric Oven Digestion Lab Number F2033 l 4-BSBSD 1
LCS Source Blank Spike
Analyte
Thallium
Spike Added (microgL)
LCS Concentration
(microgL)
LCS 0o
Recovery Recovery
Limits Method
040000 0396 989 85 - 115 EPA 2008 Mod
Notes
Analyte
Spike Added (microgL)
LCSD Concentration
(microgL)
LCSD 0o
Recovery
RPD Recovery
Limits RPO Limit Method Notes
Thallium 040000 0391 978 112 85 - ll5 20 EPA 2008 Mod
Frontier Global Sciences Inc The results in this report only apply to the samples anayed in accordance with the chain ofcustody docwnenJ This analytical report must be reproduced in its entirety
Page 22of26 1201073 Final Report 04252012
Liz Siska Project Manager
24
Liz Siska P roject Manager
11720 North Creek Parkway North Suite 400
~ Bothell WA 98011 Ph 425-686-1996
~JTIEif middot Fx 425-686-3096 GLOBAL SCIENCES
PREPARATION BLANKS
Instrument Hg-17 Sequence 2A09010
Preparation BrCI Oxidation
Lab Sample ID Analyte Found MRL Units Batch Method Notes
F201063-BLK I Mercury -0009 050 ngL F201063 EPA 1631E u F20 I063-BLK2 Mercury -0006 050 ngL F201063 EPA 1631E u F201063-BLK3 Mercury -002 050 ngL F201063 EPA 163IE u F201063-BLK4 Mercury 003 050 ngL F201063 EPA 1631E U QB-04 F201063-BLKS Mercury 011 052 ngL F201063 EPA I631E U QB-06
Frontier Global Sciences Inc The results in this report only apply 10 1he samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Page 23 o26 1201073 Final Repon 04252012 25
Liz Siska Project Manager
11720 North Creek Parkway North Suite 400 Bothell WA 98011
Ph 425-686-1996 FROr~TIER- Fx 425-686-3096 GLOBAL SCIENCES
PREPARATION BLANKS
Instrument ICPMS-6 Sequence 2C22005
Preparation Closed Vessel Nitric Oven Digestion
Lab Sample ID Analyte Found MRL Units Batch Method Notes
F203271-BLK1 Beryllium 000008 0060 microgL F203271 PA 2008 Molt u F20327 1-BLK1 Sodium 2 20 microgL F20327l PA 2008 Moc u F20327I-BLK1 Aluminum -004 40 microgL F203271 PA 2008 Molt u F20327I -BLK1 Calcium 40 microgL F203271 PA 2008 Molt u F203271 -BLK1 Chromium -002 010 microgL F203271 ~A 2008 Molt u F203271-BLKI Manganese 001 010 microgL F203271 PA 2008 Molt u F20327 l -BLK 1 Iron -002 100 microgL F203271 PA 2008 Molt u F203271-BLKI Nickel 0004 010 microgL F203271 PA 2008 Moc u F203271-BLK1 Copper 0003 010 microgL F203271 PA 2008 Moc u F203271-BLK1 Zinc 0007 020 microgL F203271 PA 2008 Moc u F203271-BLK1 Arsenic -006 015 microgL F203271 PA 2008 Moc u F203271-BLK1 Selenium -002 060 microgL F203271 PA 2008 Moc u F203271-BLK1 Molybdenum 001 006 microgL F203271 PA 2008 Molt u F203271-BLK1 Silver -00005 0020 microgL F203271 PA 2008 Molt u F203271-BLKl Cadmium 0004 0020 microgL F203271 PA 2008 Molt u F20327 l-BLKl Antimony 0002 0020 microgL F203271 PA 2008 Molt u F203271-BLKI Barium 001 020 microgL F203271 PA 2008 Molt u F203271-BLKI Lead 0010 0040 microgL F203271 PA 2008 Moc u
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Page 24of26 1201073 Final Report 04252012 26
~
~TIER~ GLOBAL SCIENCES
11720 North Creek Parkway North Suite 400 Bothell WA 980ll
Ph 425-686-1996 Fx 425-686-3096
PREPARATION BLANKS
Instrument JCPMS-3 Sequence 2C25005
Preparation Closed Vessel Nitric Oven Digestion
Lab Sample ID Analyte Found MRL Units Batch Method Notes
F2033I4-BLK1 Thalium 00007 0010 microgL F2033I4 ~PA 2008 Molt u
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Page 25 o26Liz Siska Project Manager 1201073 Final Report
04252012 27
l l 720 North Creek Parkway North Suite 400~Vi-~ Bothell WA 98011 Ph 425-686-1 996~Tlmiddot~ Fx 425-686-3096
G L OBAL SCIENCE S
Notes and Definitions
U Analyte included in the analysis but not detected
QM-02 The MS andor MSD recoveries outside acceptance limits due to spike concentration less than I times the sample concentration The batch was accepted based on LCS and LCSD recoveries within control limits and when analysis permits acceptable AS ASD
QB-06 The blank was preserved to 5 BrCI rather than I The control limit for blanks preserved to greater than 1 BrCl is the preservation percentage multiplied by the MRL
QB-04 The blank was preserved to 2 BrCI rather than l The control limit for blanks preserved to greater than l BrCI is the preservation percentage multiplied by the MRL
FB-1631 Required equipmentfieldfilter blank not submitted by the client The sample has been analyzed according to 163 lE but does not meet 163 lE criteria
AS This MS andor MSD is an analytical spike andor an analytical spike duplicate
DET Analyte Detected
MDL Minimum Detection Limit
MRL Minimum Reporting Limit
ND Analyte Not Detected at or above the reporting limit
wet Sample results reported on a wet weight basis
dry Sample results reported on a dry weight basis
RPO Relative Percent Difference
RSD Relative Standard Deviation
Frontier Global Sciences Inc The lesults i111his reporl only apply to he samples analyzed In accordance with the chain ofcuslody document This analytical report must be reproduced in its entirely
Page 26of26 1201073 Final Report 04252012
Liz Siska Project Manager
28
CHAIN-OF-(USTODY ttECORD Page i of f 106677 _J
BoLD F1ELDS REQUIRED PLEASE C 1RCLE REQUESTED ANALYSIS
SAMPLE ID
middoti-rg -- bull ~rshy~ _- tzir +- lt-ltJ~ lt
SAMPLING
DATeTtME
IF COMPOSITE INDICATE BOTH
START amp FINISH
DATETIME li1J oc -r 111_- _vlt-c_
w Ishyt 0 n
w l w 0 ~ u X -Xmiddot ~ m Ishy lt( lt( 0
I C)
IIXJ JC
~ ~ irlte-t- T_ t- f r-n t I s-11 middott~ c~ J J1~w )(~ )
Trttbull rin K C-~-~ pound1t I 1Jtl~ t20~L lwlJI ishy
middot~ON Mm1x A-Al~ S-SOil GW-GampOUHO WATER SW-SUampfA(f WATER DWmiddotDRIIIKIKlti WATER
Itlt
-glo c ~
c t I O
~ t = ~ ~
~ o ~1
~ ~ ~
0
5 g sect ~ shy2 s z
rJ gII
)(
107555
i
~ I NOTES MEOH VIAL
1 WW-WASTE WATER PmmATIVE H-HCL H-HN01 S-H1SO Na-NaOH H-HEOH -~ --~
PROJECT MANAGER llr middot1 ~Q Aw4---P1V- Het_ r COMPANY t-lo--tm ~ bd i ( I ~j 6 A ADP~SS 91 g~ez tJshy(ITJ ~ STATE fH_ ZIP c3o--
PHONE 22j-((omiddotf EXT ____
fAX--------------------- shyE-MAIL (JbHd-esa e n ta wamp Sm NAME Meccft1lt-1ltk f--g
PROJECT _
OTHEi________STATpound NH MA ME VT
REGULATORY PROGRAM NPDES RGP POTW STORHWATEl OR
GWP OIL FUHD BROWNIIELO OR OTHER----------
Quon PO o2J~-lt1Jpound)
DATE NEEDED _1--1 middot Z=-----shy4 (1-1_ METALS 8 RCRA 13 pp ff MN PB Cu
QAQC REPORTJNGYVEL
A CG) O R
PRESUMPTIVE CERTAINTY
7i2lt_
RECpound1VEO BYRELINQUISHED BY DATE TIME SUSPECTED (OHTAHIHATIOH________
TEHP~ C REPORTING OPTIONS 01HEA METAL------------PRELIHl Yu OR No
DISSOLVED METALS FIELD FllTEREDI YES 110
rmreg No
IF YH FAX OR POf 7~shy Hom (IE SPECIAL DETECTION LINITl BllLIKGINfO If DlffERrnT)ELECTRONIC OPTIONS zo 1 2 2) le~C1 1 Jc Id sJ 60 6c
1 cf Co
lo FAX pound-MAIL PDF EQUll C jCi (e I rt--111 Ao NiAJrJe middotn th
Ka)Jcr(c C(cdd -ltJ c -l -gtck- z Alt 5e1 Hj
Al l 4_) it fG) 1uJ c(iJoclt-U Sin HISTORY 0Se-d Cim- ~pound rc~L IH t--6
1 r
ImiddotRELINQUISHED BY DATE TIHE RECflVEO BY I FIELD READINGS
eastern analytical inc 2s CHENELL D R1ve IC 0 Nco1to N H 0330 1 I TEL 60J22aos2s 1aoo2a1os2s IFAx 6032284591 j E-MA1t cus-roM111_mV1c~EAILAsscoMJ www1A1LAascoM
----i pmiddotofissionrrl11bomtorymim (WHITE ORIGINAL GREEN PROJECT MANAGER)
shy
11720 North Creek Parkway North Suite 400 l ~ Bothell WA 980 l l Ph 425-686-1996
FRONTIER Fx 425-686-3096 GLOBAL SCIENCES
LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLICATE
RECOVERY AND RPD
Batch F20 l063 Sequence 2A09010
Preparation BrCI Oxidation Lab Number F201063-BSIBSJ21
LCS Source N ist 1641d
Analyte
Spike Added (ngL)
LCS Concentration
(ngL)
LCS
Recovery Recovery
Limits Method Notes
Mercury 15679 1550 988 80 - 120 EPA I631E
Analyte
Spike Added (ngL)
LCSD Concentration
(ngL)
LCSD Oo
Recovery
RPD Recovery
Limits RPD Limit Method Notes
Mercury 15679 1595 [02 289 80 - 120 24 EPA I631E
Frontier Global Sciences Inc The results in this report only apply to the samples analyzedin accordance with the chain ofcustody document This analytical report must be reproduced in ils entirety
Page 19of26 1201073 Final Report 0425 2012
Liz Siska Project Manager
21
11720 North Creek Parkway North Suite 400 Bothell WA 98011
Ph 425-686-1996 FRONTIER Fx 425-686-3096 GLOBAL SCIENCES
LABORA TORY CONTROL SAMPLE LABO RATORY CONTROL SAMPLE DUPLICATE
RECOVERY AND RPD
Batch F203271 Sequence 2C22005
Preparation Closed Vessel Nitric Oven Digestion Lab Number F203271-BSBSD1
LCS Source Blank Spike
Spike LCS LCS Added Concentration Oo Recovery
Analyte (microgL) (microgL) Recovery Limits Method Notes
Beryllium 20000 l930 965 85 - 115 EPA 2008 Mod
Sodium 50000 499 998 85 - 115 EPA 2008 Mod
Aluminum 15000 1460 973 85 - 115 EPA 2008 Mod
Calcium 15000 1528 102 85 - 115 EPA 2008 Mod
Chromium 70000 657 939 85 - 115 EPA 2008 Mod
Manganese 60000 586 976 85 - 115 EPA 2008 Mod
Iron 50000 4753 951 85 shy 115 EPA 2008 Mod
Nickel 40000 401 100 85 - 115 EPA 2008 Mod
Copper 40000 418 105 85 - 115 EPA 2008 Mod
Zinc 10000 1033 103 85 - 115 EPA 2008 Mod
Arsenic 15000 1437 958 85 - 115 EPA 2008 Mod
Selenium 30000 2966 989 85 - 115 EPA 2008 Mod
Molybdenum 20000 181 905 85 shy 115 EPA 2008 Mod
Silver 15000 1517 101 85 shy 115 EPA 2008 Mod
Cadmium 080000 0781 976 85 - 1lS EPA 2008 Mod
Antimony 080000 0815 102 85 - 115 EPA 2008 Mod
Barium 10000 969 969 85 - 115 EPA 2008 Mod
Lead 15000 1597 106 85 - 115 EPA 2008 Mod
Spike LCSD LCSD Added Concentration Recovery RPO
Analyte (microgL) (microgL) Recovery RPO Limits Limit Method Notes
Beryllium 20000 1949 974 0955 85 - 115 20 EPA 2008 Mod
Sodium 50000 500 100 0216 85 - 115 20 EPA 2008 Mod
Aluminum 15000 1485 990 171 85 - 115 20 EPA 2008 Mod
Calcium 15000 1544 103 103 85 - 115 20 EPA 2008 Mod
Chromium 70000 667 953 148 85 - 115 20 EPA 2008 Mod
Manganese 60000 596 994 175 85 - 115 20 EPA 2008 Mod
Iron 50000 4852 970 206 85 - 115 20 EPA 2008 Mod
Nickel 40000 402 IOI 0246 85 - 115 20 EPA 2008 Mod
Frontier Global Sciences Inc The results in his report only apply to the samples analyzed in accordance wirh the chain ofcustody document This analytical report must be reproduced in iLS entirety
Page 20of26 1201073 Final Report 04252012
Liz Siska Project Manager
22
11720 North Creek Parkway North Suite 400 ~~shy Bothell WA 98011 Ph 425-686-1996~ONTif Fx 425-686-3096
GLOBAL SCIENCES
LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLICATE
RECOVERY AND RPO
Batch F20327 l Sequence 2C22005
Preparation Closed Vessel Nitric Oven Digestion Lab Number F203271-BSBSD 1
LCS Source Blank Spike
Analyte
Spike Added (microgL)
LCSD Concentration
(microgL)
LCSD oo
Recovery
RPO Recovery
Limits RPO Limit Method Notes
Copper
Zinc
Arsenic
Selenium
40000
10000
15000
30000
428
1039
1452
3015
107
104
968
101
224
0570
0977
166
85 - 115
85 - 115
85 - 115
85 - 115
20
20
20
20
EPA 2008 Mod
EPA 2008 Mod
EPA 2008 Mod
EPA 2008 Mod Molybdenum
Silver
20000
15000
182
J502
910
100
0564
103
85 - 115
85 - 115
20
20
EPA 2008 Mod
EPA 2008 Mod Cadmium
Antimony
Barium
Lead
080000
080000
10000
15000
0828
0808
986
1620
103
101
986
108
585
0848
177
142
85 - 115
85 - 115
85 shy 11 S
85 - 115
20
20
20
20
EPA 2008 Mod
EPA 2008 Mod
EPA 2008 Mod
EPA 2008 Mod
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report mus be reproducedin its entirety
Page 2 o26J20J073 Final Report 041252012
Liz Siska Project Manager
23
11720 North Creek Parkway North Suite 400 Bothell WA 980 l l
Ph 425-686-1996FRONT[ER- Fx 425-686-3096 cLosAL SCIEN _CES
LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLICATE
RECOVERY AND RPD
Batch F203314 Sequence 2C25005
Preparation Closed Vessel Nitric Oven Digestion Lab Number F2033 l 4-BSBSD 1
LCS Source Blank Spike
Analyte
Thallium
Spike Added (microgL)
LCS Concentration
(microgL)
LCS 0o
Recovery Recovery
Limits Method
040000 0396 989 85 - 115 EPA 2008 Mod
Notes
Analyte
Spike Added (microgL)
LCSD Concentration
(microgL)
LCSD 0o
Recovery
RPD Recovery
Limits RPO Limit Method Notes
Thallium 040000 0391 978 112 85 - ll5 20 EPA 2008 Mod
Frontier Global Sciences Inc The results in this report only apply to the samples anayed in accordance with the chain ofcustody docwnenJ This analytical report must be reproduced in its entirety
Page 22of26 1201073 Final Report 04252012
Liz Siska Project Manager
24
Liz Siska P roject Manager
11720 North Creek Parkway North Suite 400
~ Bothell WA 98011 Ph 425-686-1996
~JTIEif middot Fx 425-686-3096 GLOBAL SCIENCES
PREPARATION BLANKS
Instrument Hg-17 Sequence 2A09010
Preparation BrCI Oxidation
Lab Sample ID Analyte Found MRL Units Batch Method Notes
F201063-BLK I Mercury -0009 050 ngL F201063 EPA 1631E u F20 I063-BLK2 Mercury -0006 050 ngL F201063 EPA 1631E u F201063-BLK3 Mercury -002 050 ngL F201063 EPA 163IE u F201063-BLK4 Mercury 003 050 ngL F201063 EPA 1631E U QB-04 F201063-BLKS Mercury 011 052 ngL F201063 EPA I631E U QB-06
Frontier Global Sciences Inc The results in this report only apply 10 1he samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Page 23 o26 1201073 Final Repon 04252012 25
Liz Siska Project Manager
11720 North Creek Parkway North Suite 400 Bothell WA 98011
Ph 425-686-1996 FROr~TIER- Fx 425-686-3096 GLOBAL SCIENCES
PREPARATION BLANKS
Instrument ICPMS-6 Sequence 2C22005
Preparation Closed Vessel Nitric Oven Digestion
Lab Sample ID Analyte Found MRL Units Batch Method Notes
F203271-BLK1 Beryllium 000008 0060 microgL F203271 PA 2008 Molt u F20327 1-BLK1 Sodium 2 20 microgL F20327l PA 2008 Moc u F20327I-BLK1 Aluminum -004 40 microgL F203271 PA 2008 Molt u F20327I -BLK1 Calcium 40 microgL F203271 PA 2008 Molt u F203271 -BLK1 Chromium -002 010 microgL F203271 ~A 2008 Molt u F203271-BLKI Manganese 001 010 microgL F203271 PA 2008 Molt u F20327 l -BLK 1 Iron -002 100 microgL F203271 PA 2008 Molt u F203271-BLKI Nickel 0004 010 microgL F203271 PA 2008 Moc u F203271-BLK1 Copper 0003 010 microgL F203271 PA 2008 Moc u F203271-BLK1 Zinc 0007 020 microgL F203271 PA 2008 Moc u F203271-BLK1 Arsenic -006 015 microgL F203271 PA 2008 Moc u F203271-BLK1 Selenium -002 060 microgL F203271 PA 2008 Moc u F203271-BLK1 Molybdenum 001 006 microgL F203271 PA 2008 Molt u F203271-BLK1 Silver -00005 0020 microgL F203271 PA 2008 Molt u F203271-BLKl Cadmium 0004 0020 microgL F203271 PA 2008 Molt u F20327 l-BLKl Antimony 0002 0020 microgL F203271 PA 2008 Molt u F203271-BLKI Barium 001 020 microgL F203271 PA 2008 Molt u F203271-BLKI Lead 0010 0040 microgL F203271 PA 2008 Moc u
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Page 24of26 1201073 Final Report 04252012 26
~
~TIER~ GLOBAL SCIENCES
11720 North Creek Parkway North Suite 400 Bothell WA 980ll
Ph 425-686-1996 Fx 425-686-3096
PREPARATION BLANKS
Instrument JCPMS-3 Sequence 2C25005
Preparation Closed Vessel Nitric Oven Digestion
Lab Sample ID Analyte Found MRL Units Batch Method Notes
F2033I4-BLK1 Thalium 00007 0010 microgL F2033I4 ~PA 2008 Molt u
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Page 25 o26Liz Siska Project Manager 1201073 Final Report
04252012 27
l l 720 North Creek Parkway North Suite 400~Vi-~ Bothell WA 98011 Ph 425-686-1 996~Tlmiddot~ Fx 425-686-3096
G L OBAL SCIENCE S
Notes and Definitions
U Analyte included in the analysis but not detected
QM-02 The MS andor MSD recoveries outside acceptance limits due to spike concentration less than I times the sample concentration The batch was accepted based on LCS and LCSD recoveries within control limits and when analysis permits acceptable AS ASD
QB-06 The blank was preserved to 5 BrCI rather than I The control limit for blanks preserved to greater than 1 BrCl is the preservation percentage multiplied by the MRL
QB-04 The blank was preserved to 2 BrCI rather than l The control limit for blanks preserved to greater than l BrCI is the preservation percentage multiplied by the MRL
FB-1631 Required equipmentfieldfilter blank not submitted by the client The sample has been analyzed according to 163 lE but does not meet 163 lE criteria
AS This MS andor MSD is an analytical spike andor an analytical spike duplicate
DET Analyte Detected
MDL Minimum Detection Limit
MRL Minimum Reporting Limit
ND Analyte Not Detected at or above the reporting limit
wet Sample results reported on a wet weight basis
dry Sample results reported on a dry weight basis
RPO Relative Percent Difference
RSD Relative Standard Deviation
Frontier Global Sciences Inc The lesults i111his reporl only apply to he samples analyzed In accordance with the chain ofcuslody document This analytical report must be reproduced in its entirely
Page 26of26 1201073 Final Report 04252012
Liz Siska Project Manager
28
CHAIN-OF-(USTODY ttECORD Page i of f 106677 _J
BoLD F1ELDS REQUIRED PLEASE C 1RCLE REQUESTED ANALYSIS
SAMPLE ID
middoti-rg -- bull ~rshy~ _- tzir +- lt-ltJ~ lt
SAMPLING
DATeTtME
IF COMPOSITE INDICATE BOTH
START amp FINISH
DATETIME li1J oc -r 111_- _vlt-c_
w Ishyt 0 n
w l w 0 ~ u X -Xmiddot ~ m Ishy lt( lt( 0
I C)
IIXJ JC
~ ~ irlte-t- T_ t- f r-n t I s-11 middott~ c~ J J1~w )(~ )
Trttbull rin K C-~-~ pound1t I 1Jtl~ t20~L lwlJI ishy
middot~ON Mm1x A-Al~ S-SOil GW-GampOUHO WATER SW-SUampfA(f WATER DWmiddotDRIIIKIKlti WATER
Itlt
-glo c ~
c t I O
~ t = ~ ~
~ o ~1
~ ~ ~
0
5 g sect ~ shy2 s z
rJ gII
)(
107555
i
~ I NOTES MEOH VIAL
1 WW-WASTE WATER PmmATIVE H-HCL H-HN01 S-H1SO Na-NaOH H-HEOH -~ --~
PROJECT MANAGER llr middot1 ~Q Aw4---P1V- Het_ r COMPANY t-lo--tm ~ bd i ( I ~j 6 A ADP~SS 91 g~ez tJshy(ITJ ~ STATE fH_ ZIP c3o--
PHONE 22j-((omiddotf EXT ____
fAX--------------------- shyE-MAIL (JbHd-esa e n ta wamp Sm NAME Meccft1lt-1ltk f--g
PROJECT _
OTHEi________STATpound NH MA ME VT
REGULATORY PROGRAM NPDES RGP POTW STORHWATEl OR
GWP OIL FUHD BROWNIIELO OR OTHER----------
Quon PO o2J~-lt1Jpound)
DATE NEEDED _1--1 middot Z=-----shy4 (1-1_ METALS 8 RCRA 13 pp ff MN PB Cu
QAQC REPORTJNGYVEL
A CG) O R
PRESUMPTIVE CERTAINTY
7i2lt_
RECpound1VEO BYRELINQUISHED BY DATE TIME SUSPECTED (OHTAHIHATIOH________
TEHP~ C REPORTING OPTIONS 01HEA METAL------------PRELIHl Yu OR No
DISSOLVED METALS FIELD FllTEREDI YES 110
rmreg No
IF YH FAX OR POf 7~shy Hom (IE SPECIAL DETECTION LINITl BllLIKGINfO If DlffERrnT)ELECTRONIC OPTIONS zo 1 2 2) le~C1 1 Jc Id sJ 60 6c
1 cf Co
lo FAX pound-MAIL PDF EQUll C jCi (e I rt--111 Ao NiAJrJe middotn th
Ka)Jcr(c C(cdd -ltJ c -l -gtck- z Alt 5e1 Hj
Al l 4_) it fG) 1uJ c(iJoclt-U Sin HISTORY 0Se-d Cim- ~pound rc~L IH t--6
1 r
ImiddotRELINQUISHED BY DATE TIHE RECflVEO BY I FIELD READINGS
eastern analytical inc 2s CHENELL D R1ve IC 0 Nco1to N H 0330 1 I TEL 60J22aos2s 1aoo2a1os2s IFAx 6032284591 j E-MA1t cus-roM111_mV1c~EAILAsscoMJ www1A1LAascoM
----i pmiddotofissionrrl11bomtorymim (WHITE ORIGINAL GREEN PROJECT MANAGER)
shy
11720 North Creek Parkway North Suite 400 Bothell WA 98011
Ph 425-686-1996 FRONTIER Fx 425-686-3096 GLOBAL SCIENCES
LABORA TORY CONTROL SAMPLE LABO RATORY CONTROL SAMPLE DUPLICATE
RECOVERY AND RPD
Batch F203271 Sequence 2C22005
Preparation Closed Vessel Nitric Oven Digestion Lab Number F203271-BSBSD1
LCS Source Blank Spike
Spike LCS LCS Added Concentration Oo Recovery
Analyte (microgL) (microgL) Recovery Limits Method Notes
Beryllium 20000 l930 965 85 - 115 EPA 2008 Mod
Sodium 50000 499 998 85 - 115 EPA 2008 Mod
Aluminum 15000 1460 973 85 - 115 EPA 2008 Mod
Calcium 15000 1528 102 85 - 115 EPA 2008 Mod
Chromium 70000 657 939 85 - 115 EPA 2008 Mod
Manganese 60000 586 976 85 - 115 EPA 2008 Mod
Iron 50000 4753 951 85 shy 115 EPA 2008 Mod
Nickel 40000 401 100 85 - 115 EPA 2008 Mod
Copper 40000 418 105 85 - 115 EPA 2008 Mod
Zinc 10000 1033 103 85 - 115 EPA 2008 Mod
Arsenic 15000 1437 958 85 - 115 EPA 2008 Mod
Selenium 30000 2966 989 85 - 115 EPA 2008 Mod
Molybdenum 20000 181 905 85 shy 115 EPA 2008 Mod
Silver 15000 1517 101 85 shy 115 EPA 2008 Mod
Cadmium 080000 0781 976 85 - 1lS EPA 2008 Mod
Antimony 080000 0815 102 85 - 115 EPA 2008 Mod
Barium 10000 969 969 85 - 115 EPA 2008 Mod
Lead 15000 1597 106 85 - 115 EPA 2008 Mod
Spike LCSD LCSD Added Concentration Recovery RPO
Analyte (microgL) (microgL) Recovery RPO Limits Limit Method Notes
Beryllium 20000 1949 974 0955 85 - 115 20 EPA 2008 Mod
Sodium 50000 500 100 0216 85 - 115 20 EPA 2008 Mod
Aluminum 15000 1485 990 171 85 - 115 20 EPA 2008 Mod
Calcium 15000 1544 103 103 85 - 115 20 EPA 2008 Mod
Chromium 70000 667 953 148 85 - 115 20 EPA 2008 Mod
Manganese 60000 596 994 175 85 - 115 20 EPA 2008 Mod
Iron 50000 4852 970 206 85 - 115 20 EPA 2008 Mod
Nickel 40000 402 IOI 0246 85 - 115 20 EPA 2008 Mod
Frontier Global Sciences Inc The results in his report only apply to the samples analyzed in accordance wirh the chain ofcustody document This analytical report must be reproduced in iLS entirety
Page 20of26 1201073 Final Report 04252012
Liz Siska Project Manager
22
11720 North Creek Parkway North Suite 400 ~~shy Bothell WA 98011 Ph 425-686-1996~ONTif Fx 425-686-3096
GLOBAL SCIENCES
LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLICATE
RECOVERY AND RPO
Batch F20327 l Sequence 2C22005
Preparation Closed Vessel Nitric Oven Digestion Lab Number F203271-BSBSD 1
LCS Source Blank Spike
Analyte
Spike Added (microgL)
LCSD Concentration
(microgL)
LCSD oo
Recovery
RPO Recovery
Limits RPO Limit Method Notes
Copper
Zinc
Arsenic
Selenium
40000
10000
15000
30000
428
1039
1452
3015
107
104
968
101
224
0570
0977
166
85 - 115
85 - 115
85 - 115
85 - 115
20
20
20
20
EPA 2008 Mod
EPA 2008 Mod
EPA 2008 Mod
EPA 2008 Mod Molybdenum
Silver
20000
15000
182
J502
910
100
0564
103
85 - 115
85 - 115
20
20
EPA 2008 Mod
EPA 2008 Mod Cadmium
Antimony
Barium
Lead
080000
080000
10000
15000
0828
0808
986
1620
103
101
986
108
585
0848
177
142
85 - 115
85 - 115
85 shy 11 S
85 - 115
20
20
20
20
EPA 2008 Mod
EPA 2008 Mod
EPA 2008 Mod
EPA 2008 Mod
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report mus be reproducedin its entirety
Page 2 o26J20J073 Final Report 041252012
Liz Siska Project Manager
23
11720 North Creek Parkway North Suite 400 Bothell WA 980 l l
Ph 425-686-1996FRONT[ER- Fx 425-686-3096 cLosAL SCIEN _CES
LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLICATE
RECOVERY AND RPD
Batch F203314 Sequence 2C25005
Preparation Closed Vessel Nitric Oven Digestion Lab Number F2033 l 4-BSBSD 1
LCS Source Blank Spike
Analyte
Thallium
Spike Added (microgL)
LCS Concentration
(microgL)
LCS 0o
Recovery Recovery
Limits Method
040000 0396 989 85 - 115 EPA 2008 Mod
Notes
Analyte
Spike Added (microgL)
LCSD Concentration
(microgL)
LCSD 0o
Recovery
RPD Recovery
Limits RPO Limit Method Notes
Thallium 040000 0391 978 112 85 - ll5 20 EPA 2008 Mod
Frontier Global Sciences Inc The results in this report only apply to the samples anayed in accordance with the chain ofcustody docwnenJ This analytical report must be reproduced in its entirety
Page 22of26 1201073 Final Report 04252012
Liz Siska Project Manager
24
Liz Siska P roject Manager
11720 North Creek Parkway North Suite 400
~ Bothell WA 98011 Ph 425-686-1996
~JTIEif middot Fx 425-686-3096 GLOBAL SCIENCES
PREPARATION BLANKS
Instrument Hg-17 Sequence 2A09010
Preparation BrCI Oxidation
Lab Sample ID Analyte Found MRL Units Batch Method Notes
F201063-BLK I Mercury -0009 050 ngL F201063 EPA 1631E u F20 I063-BLK2 Mercury -0006 050 ngL F201063 EPA 1631E u F201063-BLK3 Mercury -002 050 ngL F201063 EPA 163IE u F201063-BLK4 Mercury 003 050 ngL F201063 EPA 1631E U QB-04 F201063-BLKS Mercury 011 052 ngL F201063 EPA I631E U QB-06
Frontier Global Sciences Inc The results in this report only apply 10 1he samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Page 23 o26 1201073 Final Repon 04252012 25
Liz Siska Project Manager
11720 North Creek Parkway North Suite 400 Bothell WA 98011
Ph 425-686-1996 FROr~TIER- Fx 425-686-3096 GLOBAL SCIENCES
PREPARATION BLANKS
Instrument ICPMS-6 Sequence 2C22005
Preparation Closed Vessel Nitric Oven Digestion
Lab Sample ID Analyte Found MRL Units Batch Method Notes
F203271-BLK1 Beryllium 000008 0060 microgL F203271 PA 2008 Molt u F20327 1-BLK1 Sodium 2 20 microgL F20327l PA 2008 Moc u F20327I-BLK1 Aluminum -004 40 microgL F203271 PA 2008 Molt u F20327I -BLK1 Calcium 40 microgL F203271 PA 2008 Molt u F203271 -BLK1 Chromium -002 010 microgL F203271 ~A 2008 Molt u F203271-BLKI Manganese 001 010 microgL F203271 PA 2008 Molt u F20327 l -BLK 1 Iron -002 100 microgL F203271 PA 2008 Molt u F203271-BLKI Nickel 0004 010 microgL F203271 PA 2008 Moc u F203271-BLK1 Copper 0003 010 microgL F203271 PA 2008 Moc u F203271-BLK1 Zinc 0007 020 microgL F203271 PA 2008 Moc u F203271-BLK1 Arsenic -006 015 microgL F203271 PA 2008 Moc u F203271-BLK1 Selenium -002 060 microgL F203271 PA 2008 Moc u F203271-BLK1 Molybdenum 001 006 microgL F203271 PA 2008 Molt u F203271-BLK1 Silver -00005 0020 microgL F203271 PA 2008 Molt u F203271-BLKl Cadmium 0004 0020 microgL F203271 PA 2008 Molt u F20327 l-BLKl Antimony 0002 0020 microgL F203271 PA 2008 Molt u F203271-BLKI Barium 001 020 microgL F203271 PA 2008 Molt u F203271-BLKI Lead 0010 0040 microgL F203271 PA 2008 Moc u
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Page 24of26 1201073 Final Report 04252012 26
~
~TIER~ GLOBAL SCIENCES
11720 North Creek Parkway North Suite 400 Bothell WA 980ll
Ph 425-686-1996 Fx 425-686-3096
PREPARATION BLANKS
Instrument JCPMS-3 Sequence 2C25005
Preparation Closed Vessel Nitric Oven Digestion
Lab Sample ID Analyte Found MRL Units Batch Method Notes
F2033I4-BLK1 Thalium 00007 0010 microgL F2033I4 ~PA 2008 Molt u
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Page 25 o26Liz Siska Project Manager 1201073 Final Report
04252012 27
l l 720 North Creek Parkway North Suite 400~Vi-~ Bothell WA 98011 Ph 425-686-1 996~Tlmiddot~ Fx 425-686-3096
G L OBAL SCIENCE S
Notes and Definitions
U Analyte included in the analysis but not detected
QM-02 The MS andor MSD recoveries outside acceptance limits due to spike concentration less than I times the sample concentration The batch was accepted based on LCS and LCSD recoveries within control limits and when analysis permits acceptable AS ASD
QB-06 The blank was preserved to 5 BrCI rather than I The control limit for blanks preserved to greater than 1 BrCl is the preservation percentage multiplied by the MRL
QB-04 The blank was preserved to 2 BrCI rather than l The control limit for blanks preserved to greater than l BrCI is the preservation percentage multiplied by the MRL
FB-1631 Required equipmentfieldfilter blank not submitted by the client The sample has been analyzed according to 163 lE but does not meet 163 lE criteria
AS This MS andor MSD is an analytical spike andor an analytical spike duplicate
DET Analyte Detected
MDL Minimum Detection Limit
MRL Minimum Reporting Limit
ND Analyte Not Detected at or above the reporting limit
wet Sample results reported on a wet weight basis
dry Sample results reported on a dry weight basis
RPO Relative Percent Difference
RSD Relative Standard Deviation
Frontier Global Sciences Inc The lesults i111his reporl only apply to he samples analyzed In accordance with the chain ofcuslody document This analytical report must be reproduced in its entirely
Page 26of26 1201073 Final Report 04252012
Liz Siska Project Manager
28
CHAIN-OF-(USTODY ttECORD Page i of f 106677 _J
BoLD F1ELDS REQUIRED PLEASE C 1RCLE REQUESTED ANALYSIS
SAMPLE ID
middoti-rg -- bull ~rshy~ _- tzir +- lt-ltJ~ lt
SAMPLING
DATeTtME
IF COMPOSITE INDICATE BOTH
START amp FINISH
DATETIME li1J oc -r 111_- _vlt-c_
w Ishyt 0 n
w l w 0 ~ u X -Xmiddot ~ m Ishy lt( lt( 0
I C)
IIXJ JC
~ ~ irlte-t- T_ t- f r-n t I s-11 middott~ c~ J J1~w )(~ )
Trttbull rin K C-~-~ pound1t I 1Jtl~ t20~L lwlJI ishy
middot~ON Mm1x A-Al~ S-SOil GW-GampOUHO WATER SW-SUampfA(f WATER DWmiddotDRIIIKIKlti WATER
Itlt
-glo c ~
c t I O
~ t = ~ ~
~ o ~1
~ ~ ~
0
5 g sect ~ shy2 s z
rJ gII
)(
107555
i
~ I NOTES MEOH VIAL
1 WW-WASTE WATER PmmATIVE H-HCL H-HN01 S-H1SO Na-NaOH H-HEOH -~ --~
PROJECT MANAGER llr middot1 ~Q Aw4---P1V- Het_ r COMPANY t-lo--tm ~ bd i ( I ~j 6 A ADP~SS 91 g~ez tJshy(ITJ ~ STATE fH_ ZIP c3o--
PHONE 22j-((omiddotf EXT ____
fAX--------------------- shyE-MAIL (JbHd-esa e n ta wamp Sm NAME Meccft1lt-1ltk f--g
PROJECT _
OTHEi________STATpound NH MA ME VT
REGULATORY PROGRAM NPDES RGP POTW STORHWATEl OR
GWP OIL FUHD BROWNIIELO OR OTHER----------
Quon PO o2J~-lt1Jpound)
DATE NEEDED _1--1 middot Z=-----shy4 (1-1_ METALS 8 RCRA 13 pp ff MN PB Cu
QAQC REPORTJNGYVEL
A CG) O R
PRESUMPTIVE CERTAINTY
7i2lt_
RECpound1VEO BYRELINQUISHED BY DATE TIME SUSPECTED (OHTAHIHATIOH________
TEHP~ C REPORTING OPTIONS 01HEA METAL------------PRELIHl Yu OR No
DISSOLVED METALS FIELD FllTEREDI YES 110
rmreg No
IF YH FAX OR POf 7~shy Hom (IE SPECIAL DETECTION LINITl BllLIKGINfO If DlffERrnT)ELECTRONIC OPTIONS zo 1 2 2) le~C1 1 Jc Id sJ 60 6c
1 cf Co
lo FAX pound-MAIL PDF EQUll C jCi (e I rt--111 Ao NiAJrJe middotn th
Ka)Jcr(c C(cdd -ltJ c -l -gtck- z Alt 5e1 Hj
Al l 4_) it fG) 1uJ c(iJoclt-U Sin HISTORY 0Se-d Cim- ~pound rc~L IH t--6
1 r
ImiddotRELINQUISHED BY DATE TIHE RECflVEO BY I FIELD READINGS
eastern analytical inc 2s CHENELL D R1ve IC 0 Nco1to N H 0330 1 I TEL 60J22aos2s 1aoo2a1os2s IFAx 6032284591 j E-MA1t cus-roM111_mV1c~EAILAsscoMJ www1A1LAascoM
----i pmiddotofissionrrl11bomtorymim (WHITE ORIGINAL GREEN PROJECT MANAGER)
shy
11720 North Creek Parkway North Suite 400 ~~shy Bothell WA 98011 Ph 425-686-1996~ONTif Fx 425-686-3096
GLOBAL SCIENCES
LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLICATE
RECOVERY AND RPO
Batch F20327 l Sequence 2C22005
Preparation Closed Vessel Nitric Oven Digestion Lab Number F203271-BSBSD 1
LCS Source Blank Spike
Analyte
Spike Added (microgL)
LCSD Concentration
(microgL)
LCSD oo
Recovery
RPO Recovery
Limits RPO Limit Method Notes
Copper
Zinc
Arsenic
Selenium
40000
10000
15000
30000
428
1039
1452
3015
107
104
968
101
224
0570
0977
166
85 - 115
85 - 115
85 - 115
85 - 115
20
20
20
20
EPA 2008 Mod
EPA 2008 Mod
EPA 2008 Mod
EPA 2008 Mod Molybdenum
Silver
20000
15000
182
J502
910
100
0564
103
85 - 115
85 - 115
20
20
EPA 2008 Mod
EPA 2008 Mod Cadmium
Antimony
Barium
Lead
080000
080000
10000
15000
0828
0808
986
1620
103
101
986
108
585
0848
177
142
85 - 115
85 - 115
85 shy 11 S
85 - 115
20
20
20
20
EPA 2008 Mod
EPA 2008 Mod
EPA 2008 Mod
EPA 2008 Mod
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report mus be reproducedin its entirety
Page 2 o26J20J073 Final Report 041252012
Liz Siska Project Manager
23
11720 North Creek Parkway North Suite 400 Bothell WA 980 l l
Ph 425-686-1996FRONT[ER- Fx 425-686-3096 cLosAL SCIEN _CES
LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLICATE
RECOVERY AND RPD
Batch F203314 Sequence 2C25005
Preparation Closed Vessel Nitric Oven Digestion Lab Number F2033 l 4-BSBSD 1
LCS Source Blank Spike
Analyte
Thallium
Spike Added (microgL)
LCS Concentration
(microgL)
LCS 0o
Recovery Recovery
Limits Method
040000 0396 989 85 - 115 EPA 2008 Mod
Notes
Analyte
Spike Added (microgL)
LCSD Concentration
(microgL)
LCSD 0o
Recovery
RPD Recovery
Limits RPO Limit Method Notes
Thallium 040000 0391 978 112 85 - ll5 20 EPA 2008 Mod
Frontier Global Sciences Inc The results in this report only apply to the samples anayed in accordance with the chain ofcustody docwnenJ This analytical report must be reproduced in its entirety
Page 22of26 1201073 Final Report 04252012
Liz Siska Project Manager
24
Liz Siska P roject Manager
11720 North Creek Parkway North Suite 400
~ Bothell WA 98011 Ph 425-686-1996
~JTIEif middot Fx 425-686-3096 GLOBAL SCIENCES
PREPARATION BLANKS
Instrument Hg-17 Sequence 2A09010
Preparation BrCI Oxidation
Lab Sample ID Analyte Found MRL Units Batch Method Notes
F201063-BLK I Mercury -0009 050 ngL F201063 EPA 1631E u F20 I063-BLK2 Mercury -0006 050 ngL F201063 EPA 1631E u F201063-BLK3 Mercury -002 050 ngL F201063 EPA 163IE u F201063-BLK4 Mercury 003 050 ngL F201063 EPA 1631E U QB-04 F201063-BLKS Mercury 011 052 ngL F201063 EPA I631E U QB-06
Frontier Global Sciences Inc The results in this report only apply 10 1he samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Page 23 o26 1201073 Final Repon 04252012 25
Liz Siska Project Manager
11720 North Creek Parkway North Suite 400 Bothell WA 98011
Ph 425-686-1996 FROr~TIER- Fx 425-686-3096 GLOBAL SCIENCES
PREPARATION BLANKS
Instrument ICPMS-6 Sequence 2C22005
Preparation Closed Vessel Nitric Oven Digestion
Lab Sample ID Analyte Found MRL Units Batch Method Notes
F203271-BLK1 Beryllium 000008 0060 microgL F203271 PA 2008 Molt u F20327 1-BLK1 Sodium 2 20 microgL F20327l PA 2008 Moc u F20327I-BLK1 Aluminum -004 40 microgL F203271 PA 2008 Molt u F20327I -BLK1 Calcium 40 microgL F203271 PA 2008 Molt u F203271 -BLK1 Chromium -002 010 microgL F203271 ~A 2008 Molt u F203271-BLKI Manganese 001 010 microgL F203271 PA 2008 Molt u F20327 l -BLK 1 Iron -002 100 microgL F203271 PA 2008 Molt u F203271-BLKI Nickel 0004 010 microgL F203271 PA 2008 Moc u F203271-BLK1 Copper 0003 010 microgL F203271 PA 2008 Moc u F203271-BLK1 Zinc 0007 020 microgL F203271 PA 2008 Moc u F203271-BLK1 Arsenic -006 015 microgL F203271 PA 2008 Moc u F203271-BLK1 Selenium -002 060 microgL F203271 PA 2008 Moc u F203271-BLK1 Molybdenum 001 006 microgL F203271 PA 2008 Molt u F203271-BLK1 Silver -00005 0020 microgL F203271 PA 2008 Molt u F203271-BLKl Cadmium 0004 0020 microgL F203271 PA 2008 Molt u F20327 l-BLKl Antimony 0002 0020 microgL F203271 PA 2008 Molt u F203271-BLKI Barium 001 020 microgL F203271 PA 2008 Molt u F203271-BLKI Lead 0010 0040 microgL F203271 PA 2008 Moc u
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Page 24of26 1201073 Final Report 04252012 26
~
~TIER~ GLOBAL SCIENCES
11720 North Creek Parkway North Suite 400 Bothell WA 980ll
Ph 425-686-1996 Fx 425-686-3096
PREPARATION BLANKS
Instrument JCPMS-3 Sequence 2C25005
Preparation Closed Vessel Nitric Oven Digestion
Lab Sample ID Analyte Found MRL Units Batch Method Notes
F2033I4-BLK1 Thalium 00007 0010 microgL F2033I4 ~PA 2008 Molt u
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Page 25 o26Liz Siska Project Manager 1201073 Final Report
04252012 27
l l 720 North Creek Parkway North Suite 400~Vi-~ Bothell WA 98011 Ph 425-686-1 996~Tlmiddot~ Fx 425-686-3096
G L OBAL SCIENCE S
Notes and Definitions
U Analyte included in the analysis but not detected
QM-02 The MS andor MSD recoveries outside acceptance limits due to spike concentration less than I times the sample concentration The batch was accepted based on LCS and LCSD recoveries within control limits and when analysis permits acceptable AS ASD
QB-06 The blank was preserved to 5 BrCI rather than I The control limit for blanks preserved to greater than 1 BrCl is the preservation percentage multiplied by the MRL
QB-04 The blank was preserved to 2 BrCI rather than l The control limit for blanks preserved to greater than l BrCI is the preservation percentage multiplied by the MRL
FB-1631 Required equipmentfieldfilter blank not submitted by the client The sample has been analyzed according to 163 lE but does not meet 163 lE criteria
AS This MS andor MSD is an analytical spike andor an analytical spike duplicate
DET Analyte Detected
MDL Minimum Detection Limit
MRL Minimum Reporting Limit
ND Analyte Not Detected at or above the reporting limit
wet Sample results reported on a wet weight basis
dry Sample results reported on a dry weight basis
RPO Relative Percent Difference
RSD Relative Standard Deviation
Frontier Global Sciences Inc The lesults i111his reporl only apply to he samples analyzed In accordance with the chain ofcuslody document This analytical report must be reproduced in its entirely
Page 26of26 1201073 Final Report 04252012
Liz Siska Project Manager
28
CHAIN-OF-(USTODY ttECORD Page i of f 106677 _J
BoLD F1ELDS REQUIRED PLEASE C 1RCLE REQUESTED ANALYSIS
SAMPLE ID
middoti-rg -- bull ~rshy~ _- tzir +- lt-ltJ~ lt
SAMPLING
DATeTtME
IF COMPOSITE INDICATE BOTH
START amp FINISH
DATETIME li1J oc -r 111_- _vlt-c_
w Ishyt 0 n
w l w 0 ~ u X -Xmiddot ~ m Ishy lt( lt( 0
I C)
IIXJ JC
~ ~ irlte-t- T_ t- f r-n t I s-11 middott~ c~ J J1~w )(~ )
Trttbull rin K C-~-~ pound1t I 1Jtl~ t20~L lwlJI ishy
middot~ON Mm1x A-Al~ S-SOil GW-GampOUHO WATER SW-SUampfA(f WATER DWmiddotDRIIIKIKlti WATER
Itlt
-glo c ~
c t I O
~ t = ~ ~
~ o ~1
~ ~ ~
0
5 g sect ~ shy2 s z
rJ gII
)(
107555
i
~ I NOTES MEOH VIAL
1 WW-WASTE WATER PmmATIVE H-HCL H-HN01 S-H1SO Na-NaOH H-HEOH -~ --~
PROJECT MANAGER llr middot1 ~Q Aw4---P1V- Het_ r COMPANY t-lo--tm ~ bd i ( I ~j 6 A ADP~SS 91 g~ez tJshy(ITJ ~ STATE fH_ ZIP c3o--
PHONE 22j-((omiddotf EXT ____
fAX--------------------- shyE-MAIL (JbHd-esa e n ta wamp Sm NAME Meccft1lt-1ltk f--g
PROJECT _
OTHEi________STATpound NH MA ME VT
REGULATORY PROGRAM NPDES RGP POTW STORHWATEl OR
GWP OIL FUHD BROWNIIELO OR OTHER----------
Quon PO o2J~-lt1Jpound)
DATE NEEDED _1--1 middot Z=-----shy4 (1-1_ METALS 8 RCRA 13 pp ff MN PB Cu
QAQC REPORTJNGYVEL
A CG) O R
PRESUMPTIVE CERTAINTY
7i2lt_
RECpound1VEO BYRELINQUISHED BY DATE TIME SUSPECTED (OHTAHIHATIOH________
TEHP~ C REPORTING OPTIONS 01HEA METAL------------PRELIHl Yu OR No
DISSOLVED METALS FIELD FllTEREDI YES 110
rmreg No
IF YH FAX OR POf 7~shy Hom (IE SPECIAL DETECTION LINITl BllLIKGINfO If DlffERrnT)ELECTRONIC OPTIONS zo 1 2 2) le~C1 1 Jc Id sJ 60 6c
1 cf Co
lo FAX pound-MAIL PDF EQUll C jCi (e I rt--111 Ao NiAJrJe middotn th
Ka)Jcr(c C(cdd -ltJ c -l -gtck- z Alt 5e1 Hj
Al l 4_) it fG) 1uJ c(iJoclt-U Sin HISTORY 0Se-d Cim- ~pound rc~L IH t--6
1 r
ImiddotRELINQUISHED BY DATE TIHE RECflVEO BY I FIELD READINGS
eastern analytical inc 2s CHENELL D R1ve IC 0 Nco1to N H 0330 1 I TEL 60J22aos2s 1aoo2a1os2s IFAx 6032284591 j E-MA1t cus-roM111_mV1c~EAILAsscoMJ www1A1LAascoM
----i pmiddotofissionrrl11bomtorymim (WHITE ORIGINAL GREEN PROJECT MANAGER)
shy
11720 North Creek Parkway North Suite 400 Bothell WA 980 l l
Ph 425-686-1996FRONT[ER- Fx 425-686-3096 cLosAL SCIEN _CES
LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLICATE
RECOVERY AND RPD
Batch F203314 Sequence 2C25005
Preparation Closed Vessel Nitric Oven Digestion Lab Number F2033 l 4-BSBSD 1
LCS Source Blank Spike
Analyte
Thallium
Spike Added (microgL)
LCS Concentration
(microgL)
LCS 0o
Recovery Recovery
Limits Method
040000 0396 989 85 - 115 EPA 2008 Mod
Notes
Analyte
Spike Added (microgL)
LCSD Concentration
(microgL)
LCSD 0o
Recovery
RPD Recovery
Limits RPO Limit Method Notes
Thallium 040000 0391 978 112 85 - ll5 20 EPA 2008 Mod
Frontier Global Sciences Inc The results in this report only apply to the samples anayed in accordance with the chain ofcustody docwnenJ This analytical report must be reproduced in its entirety
Page 22of26 1201073 Final Report 04252012
Liz Siska Project Manager
24
Liz Siska P roject Manager
11720 North Creek Parkway North Suite 400
~ Bothell WA 98011 Ph 425-686-1996
~JTIEif middot Fx 425-686-3096 GLOBAL SCIENCES
PREPARATION BLANKS
Instrument Hg-17 Sequence 2A09010
Preparation BrCI Oxidation
Lab Sample ID Analyte Found MRL Units Batch Method Notes
F201063-BLK I Mercury -0009 050 ngL F201063 EPA 1631E u F20 I063-BLK2 Mercury -0006 050 ngL F201063 EPA 1631E u F201063-BLK3 Mercury -002 050 ngL F201063 EPA 163IE u F201063-BLK4 Mercury 003 050 ngL F201063 EPA 1631E U QB-04 F201063-BLKS Mercury 011 052 ngL F201063 EPA I631E U QB-06
Frontier Global Sciences Inc The results in this report only apply 10 1he samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Page 23 o26 1201073 Final Repon 04252012 25
Liz Siska Project Manager
11720 North Creek Parkway North Suite 400 Bothell WA 98011
Ph 425-686-1996 FROr~TIER- Fx 425-686-3096 GLOBAL SCIENCES
PREPARATION BLANKS
Instrument ICPMS-6 Sequence 2C22005
Preparation Closed Vessel Nitric Oven Digestion
Lab Sample ID Analyte Found MRL Units Batch Method Notes
F203271-BLK1 Beryllium 000008 0060 microgL F203271 PA 2008 Molt u F20327 1-BLK1 Sodium 2 20 microgL F20327l PA 2008 Moc u F20327I-BLK1 Aluminum -004 40 microgL F203271 PA 2008 Molt u F20327I -BLK1 Calcium 40 microgL F203271 PA 2008 Molt u F203271 -BLK1 Chromium -002 010 microgL F203271 ~A 2008 Molt u F203271-BLKI Manganese 001 010 microgL F203271 PA 2008 Molt u F20327 l -BLK 1 Iron -002 100 microgL F203271 PA 2008 Molt u F203271-BLKI Nickel 0004 010 microgL F203271 PA 2008 Moc u F203271-BLK1 Copper 0003 010 microgL F203271 PA 2008 Moc u F203271-BLK1 Zinc 0007 020 microgL F203271 PA 2008 Moc u F203271-BLK1 Arsenic -006 015 microgL F203271 PA 2008 Moc u F203271-BLK1 Selenium -002 060 microgL F203271 PA 2008 Moc u F203271-BLK1 Molybdenum 001 006 microgL F203271 PA 2008 Molt u F203271-BLK1 Silver -00005 0020 microgL F203271 PA 2008 Molt u F203271-BLKl Cadmium 0004 0020 microgL F203271 PA 2008 Molt u F20327 l-BLKl Antimony 0002 0020 microgL F203271 PA 2008 Molt u F203271-BLKI Barium 001 020 microgL F203271 PA 2008 Molt u F203271-BLKI Lead 0010 0040 microgL F203271 PA 2008 Moc u
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Page 24of26 1201073 Final Report 04252012 26
~
~TIER~ GLOBAL SCIENCES
11720 North Creek Parkway North Suite 400 Bothell WA 980ll
Ph 425-686-1996 Fx 425-686-3096
PREPARATION BLANKS
Instrument JCPMS-3 Sequence 2C25005
Preparation Closed Vessel Nitric Oven Digestion
Lab Sample ID Analyte Found MRL Units Batch Method Notes
F2033I4-BLK1 Thalium 00007 0010 microgL F2033I4 ~PA 2008 Molt u
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Page 25 o26Liz Siska Project Manager 1201073 Final Report
04252012 27
l l 720 North Creek Parkway North Suite 400~Vi-~ Bothell WA 98011 Ph 425-686-1 996~Tlmiddot~ Fx 425-686-3096
G L OBAL SCIENCE S
Notes and Definitions
U Analyte included in the analysis but not detected
QM-02 The MS andor MSD recoveries outside acceptance limits due to spike concentration less than I times the sample concentration The batch was accepted based on LCS and LCSD recoveries within control limits and when analysis permits acceptable AS ASD
QB-06 The blank was preserved to 5 BrCI rather than I The control limit for blanks preserved to greater than 1 BrCl is the preservation percentage multiplied by the MRL
QB-04 The blank was preserved to 2 BrCI rather than l The control limit for blanks preserved to greater than l BrCI is the preservation percentage multiplied by the MRL
FB-1631 Required equipmentfieldfilter blank not submitted by the client The sample has been analyzed according to 163 lE but does not meet 163 lE criteria
AS This MS andor MSD is an analytical spike andor an analytical spike duplicate
DET Analyte Detected
MDL Minimum Detection Limit
MRL Minimum Reporting Limit
ND Analyte Not Detected at or above the reporting limit
wet Sample results reported on a wet weight basis
dry Sample results reported on a dry weight basis
RPO Relative Percent Difference
RSD Relative Standard Deviation
Frontier Global Sciences Inc The lesults i111his reporl only apply to he samples analyzed In accordance with the chain ofcuslody document This analytical report must be reproduced in its entirely
Page 26of26 1201073 Final Report 04252012
Liz Siska Project Manager
28
CHAIN-OF-(USTODY ttECORD Page i of f 106677 _J
BoLD F1ELDS REQUIRED PLEASE C 1RCLE REQUESTED ANALYSIS
SAMPLE ID
middoti-rg -- bull ~rshy~ _- tzir +- lt-ltJ~ lt
SAMPLING
DATeTtME
IF COMPOSITE INDICATE BOTH
START amp FINISH
DATETIME li1J oc -r 111_- _vlt-c_
w Ishyt 0 n
w l w 0 ~ u X -Xmiddot ~ m Ishy lt( lt( 0
I C)
IIXJ JC
~ ~ irlte-t- T_ t- f r-n t I s-11 middott~ c~ J J1~w )(~ )
Trttbull rin K C-~-~ pound1t I 1Jtl~ t20~L lwlJI ishy
middot~ON Mm1x A-Al~ S-SOil GW-GampOUHO WATER SW-SUampfA(f WATER DWmiddotDRIIIKIKlti WATER
Itlt
-glo c ~
c t I O
~ t = ~ ~
~ o ~1
~ ~ ~
0
5 g sect ~ shy2 s z
rJ gII
)(
107555
i
~ I NOTES MEOH VIAL
1 WW-WASTE WATER PmmATIVE H-HCL H-HN01 S-H1SO Na-NaOH H-HEOH -~ --~
PROJECT MANAGER llr middot1 ~Q Aw4---P1V- Het_ r COMPANY t-lo--tm ~ bd i ( I ~j 6 A ADP~SS 91 g~ez tJshy(ITJ ~ STATE fH_ ZIP c3o--
PHONE 22j-((omiddotf EXT ____
fAX--------------------- shyE-MAIL (JbHd-esa e n ta wamp Sm NAME Meccft1lt-1ltk f--g
PROJECT _
OTHEi________STATpound NH MA ME VT
REGULATORY PROGRAM NPDES RGP POTW STORHWATEl OR
GWP OIL FUHD BROWNIIELO OR OTHER----------
Quon PO o2J~-lt1Jpound)
DATE NEEDED _1--1 middot Z=-----shy4 (1-1_ METALS 8 RCRA 13 pp ff MN PB Cu
QAQC REPORTJNGYVEL
A CG) O R
PRESUMPTIVE CERTAINTY
7i2lt_
RECpound1VEO BYRELINQUISHED BY DATE TIME SUSPECTED (OHTAHIHATIOH________
TEHP~ C REPORTING OPTIONS 01HEA METAL------------PRELIHl Yu OR No
DISSOLVED METALS FIELD FllTEREDI YES 110
rmreg No
IF YH FAX OR POf 7~shy Hom (IE SPECIAL DETECTION LINITl BllLIKGINfO If DlffERrnT)ELECTRONIC OPTIONS zo 1 2 2) le~C1 1 Jc Id sJ 60 6c
1 cf Co
lo FAX pound-MAIL PDF EQUll C jCi (e I rt--111 Ao NiAJrJe middotn th
Ka)Jcr(c C(cdd -ltJ c -l -gtck- z Alt 5e1 Hj
Al l 4_) it fG) 1uJ c(iJoclt-U Sin HISTORY 0Se-d Cim- ~pound rc~L IH t--6
1 r
ImiddotRELINQUISHED BY DATE TIHE RECflVEO BY I FIELD READINGS
eastern analytical inc 2s CHENELL D R1ve IC 0 Nco1to N H 0330 1 I TEL 60J22aos2s 1aoo2a1os2s IFAx 6032284591 j E-MA1t cus-roM111_mV1c~EAILAsscoMJ www1A1LAascoM
----i pmiddotofissionrrl11bomtorymim (WHITE ORIGINAL GREEN PROJECT MANAGER)
shy
Liz Siska P roject Manager
11720 North Creek Parkway North Suite 400
~ Bothell WA 98011 Ph 425-686-1996
~JTIEif middot Fx 425-686-3096 GLOBAL SCIENCES
PREPARATION BLANKS
Instrument Hg-17 Sequence 2A09010
Preparation BrCI Oxidation
Lab Sample ID Analyte Found MRL Units Batch Method Notes
F201063-BLK I Mercury -0009 050 ngL F201063 EPA 1631E u F20 I063-BLK2 Mercury -0006 050 ngL F201063 EPA 1631E u F201063-BLK3 Mercury -002 050 ngL F201063 EPA 163IE u F201063-BLK4 Mercury 003 050 ngL F201063 EPA 1631E U QB-04 F201063-BLKS Mercury 011 052 ngL F201063 EPA I631E U QB-06
Frontier Global Sciences Inc The results in this report only apply 10 1he samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Page 23 o26 1201073 Final Repon 04252012 25
Liz Siska Project Manager
11720 North Creek Parkway North Suite 400 Bothell WA 98011
Ph 425-686-1996 FROr~TIER- Fx 425-686-3096 GLOBAL SCIENCES
PREPARATION BLANKS
Instrument ICPMS-6 Sequence 2C22005
Preparation Closed Vessel Nitric Oven Digestion
Lab Sample ID Analyte Found MRL Units Batch Method Notes
F203271-BLK1 Beryllium 000008 0060 microgL F203271 PA 2008 Molt u F20327 1-BLK1 Sodium 2 20 microgL F20327l PA 2008 Moc u F20327I-BLK1 Aluminum -004 40 microgL F203271 PA 2008 Molt u F20327I -BLK1 Calcium 40 microgL F203271 PA 2008 Molt u F203271 -BLK1 Chromium -002 010 microgL F203271 ~A 2008 Molt u F203271-BLKI Manganese 001 010 microgL F203271 PA 2008 Molt u F20327 l -BLK 1 Iron -002 100 microgL F203271 PA 2008 Molt u F203271-BLKI Nickel 0004 010 microgL F203271 PA 2008 Moc u F203271-BLK1 Copper 0003 010 microgL F203271 PA 2008 Moc u F203271-BLK1 Zinc 0007 020 microgL F203271 PA 2008 Moc u F203271-BLK1 Arsenic -006 015 microgL F203271 PA 2008 Moc u F203271-BLK1 Selenium -002 060 microgL F203271 PA 2008 Moc u F203271-BLK1 Molybdenum 001 006 microgL F203271 PA 2008 Molt u F203271-BLK1 Silver -00005 0020 microgL F203271 PA 2008 Molt u F203271-BLKl Cadmium 0004 0020 microgL F203271 PA 2008 Molt u F20327 l-BLKl Antimony 0002 0020 microgL F203271 PA 2008 Molt u F203271-BLKI Barium 001 020 microgL F203271 PA 2008 Molt u F203271-BLKI Lead 0010 0040 microgL F203271 PA 2008 Moc u
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Page 24of26 1201073 Final Report 04252012 26
~
~TIER~ GLOBAL SCIENCES
11720 North Creek Parkway North Suite 400 Bothell WA 980ll
Ph 425-686-1996 Fx 425-686-3096
PREPARATION BLANKS
Instrument JCPMS-3 Sequence 2C25005
Preparation Closed Vessel Nitric Oven Digestion
Lab Sample ID Analyte Found MRL Units Batch Method Notes
F2033I4-BLK1 Thalium 00007 0010 microgL F2033I4 ~PA 2008 Molt u
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Page 25 o26Liz Siska Project Manager 1201073 Final Report
04252012 27
l l 720 North Creek Parkway North Suite 400~Vi-~ Bothell WA 98011 Ph 425-686-1 996~Tlmiddot~ Fx 425-686-3096
G L OBAL SCIENCE S
Notes and Definitions
U Analyte included in the analysis but not detected
QM-02 The MS andor MSD recoveries outside acceptance limits due to spike concentration less than I times the sample concentration The batch was accepted based on LCS and LCSD recoveries within control limits and when analysis permits acceptable AS ASD
QB-06 The blank was preserved to 5 BrCI rather than I The control limit for blanks preserved to greater than 1 BrCl is the preservation percentage multiplied by the MRL
QB-04 The blank was preserved to 2 BrCI rather than l The control limit for blanks preserved to greater than l BrCI is the preservation percentage multiplied by the MRL
FB-1631 Required equipmentfieldfilter blank not submitted by the client The sample has been analyzed according to 163 lE but does not meet 163 lE criteria
AS This MS andor MSD is an analytical spike andor an analytical spike duplicate
DET Analyte Detected
MDL Minimum Detection Limit
MRL Minimum Reporting Limit
ND Analyte Not Detected at or above the reporting limit
wet Sample results reported on a wet weight basis
dry Sample results reported on a dry weight basis
RPO Relative Percent Difference
RSD Relative Standard Deviation
Frontier Global Sciences Inc The lesults i111his reporl only apply to he samples analyzed In accordance with the chain ofcuslody document This analytical report must be reproduced in its entirely
Page 26of26 1201073 Final Report 04252012
Liz Siska Project Manager
28
CHAIN-OF-(USTODY ttECORD Page i of f 106677 _J
BoLD F1ELDS REQUIRED PLEASE C 1RCLE REQUESTED ANALYSIS
SAMPLE ID
middoti-rg -- bull ~rshy~ _- tzir +- lt-ltJ~ lt
SAMPLING
DATeTtME
IF COMPOSITE INDICATE BOTH
START amp FINISH
DATETIME li1J oc -r 111_- _vlt-c_
w Ishyt 0 n
w l w 0 ~ u X -Xmiddot ~ m Ishy lt( lt( 0
I C)
IIXJ JC
~ ~ irlte-t- T_ t- f r-n t I s-11 middott~ c~ J J1~w )(~ )
Trttbull rin K C-~-~ pound1t I 1Jtl~ t20~L lwlJI ishy
middot~ON Mm1x A-Al~ S-SOil GW-GampOUHO WATER SW-SUampfA(f WATER DWmiddotDRIIIKIKlti WATER
Itlt
-glo c ~
c t I O
~ t = ~ ~
~ o ~1
~ ~ ~
0
5 g sect ~ shy2 s z
rJ gII
)(
107555
i
~ I NOTES MEOH VIAL
1 WW-WASTE WATER PmmATIVE H-HCL H-HN01 S-H1SO Na-NaOH H-HEOH -~ --~
PROJECT MANAGER llr middot1 ~Q Aw4---P1V- Het_ r COMPANY t-lo--tm ~ bd i ( I ~j 6 A ADP~SS 91 g~ez tJshy(ITJ ~ STATE fH_ ZIP c3o--
PHONE 22j-((omiddotf EXT ____
fAX--------------------- shyE-MAIL (JbHd-esa e n ta wamp Sm NAME Meccft1lt-1ltk f--g
PROJECT _
OTHEi________STATpound NH MA ME VT
REGULATORY PROGRAM NPDES RGP POTW STORHWATEl OR
GWP OIL FUHD BROWNIIELO OR OTHER----------
Quon PO o2J~-lt1Jpound)
DATE NEEDED _1--1 middot Z=-----shy4 (1-1_ METALS 8 RCRA 13 pp ff MN PB Cu
QAQC REPORTJNGYVEL
A CG) O R
PRESUMPTIVE CERTAINTY
7i2lt_
RECpound1VEO BYRELINQUISHED BY DATE TIME SUSPECTED (OHTAHIHATIOH________
TEHP~ C REPORTING OPTIONS 01HEA METAL------------PRELIHl Yu OR No
DISSOLVED METALS FIELD FllTEREDI YES 110
rmreg No
IF YH FAX OR POf 7~shy Hom (IE SPECIAL DETECTION LINITl BllLIKGINfO If DlffERrnT)ELECTRONIC OPTIONS zo 1 2 2) le~C1 1 Jc Id sJ 60 6c
1 cf Co
lo FAX pound-MAIL PDF EQUll C jCi (e I rt--111 Ao NiAJrJe middotn th
Ka)Jcr(c C(cdd -ltJ c -l -gtck- z Alt 5e1 Hj
Al l 4_) it fG) 1uJ c(iJoclt-U Sin HISTORY 0Se-d Cim- ~pound rc~L IH t--6
1 r
ImiddotRELINQUISHED BY DATE TIHE RECflVEO BY I FIELD READINGS
eastern analytical inc 2s CHENELL D R1ve IC 0 Nco1to N H 0330 1 I TEL 60J22aos2s 1aoo2a1os2s IFAx 6032284591 j E-MA1t cus-roM111_mV1c~EAILAsscoMJ www1A1LAascoM
----i pmiddotofissionrrl11bomtorymim (WHITE ORIGINAL GREEN PROJECT MANAGER)
shy
Liz Siska Project Manager
11720 North Creek Parkway North Suite 400 Bothell WA 98011
Ph 425-686-1996 FROr~TIER- Fx 425-686-3096 GLOBAL SCIENCES
PREPARATION BLANKS
Instrument ICPMS-6 Sequence 2C22005
Preparation Closed Vessel Nitric Oven Digestion
Lab Sample ID Analyte Found MRL Units Batch Method Notes
F203271-BLK1 Beryllium 000008 0060 microgL F203271 PA 2008 Molt u F20327 1-BLK1 Sodium 2 20 microgL F20327l PA 2008 Moc u F20327I-BLK1 Aluminum -004 40 microgL F203271 PA 2008 Molt u F20327I -BLK1 Calcium 40 microgL F203271 PA 2008 Molt u F203271 -BLK1 Chromium -002 010 microgL F203271 ~A 2008 Molt u F203271-BLKI Manganese 001 010 microgL F203271 PA 2008 Molt u F20327 l -BLK 1 Iron -002 100 microgL F203271 PA 2008 Molt u F203271-BLKI Nickel 0004 010 microgL F203271 PA 2008 Moc u F203271-BLK1 Copper 0003 010 microgL F203271 PA 2008 Moc u F203271-BLK1 Zinc 0007 020 microgL F203271 PA 2008 Moc u F203271-BLK1 Arsenic -006 015 microgL F203271 PA 2008 Moc u F203271-BLK1 Selenium -002 060 microgL F203271 PA 2008 Moc u F203271-BLK1 Molybdenum 001 006 microgL F203271 PA 2008 Molt u F203271-BLK1 Silver -00005 0020 microgL F203271 PA 2008 Molt u F203271-BLKl Cadmium 0004 0020 microgL F203271 PA 2008 Molt u F20327 l-BLKl Antimony 0002 0020 microgL F203271 PA 2008 Molt u F203271-BLKI Barium 001 020 microgL F203271 PA 2008 Molt u F203271-BLKI Lead 0010 0040 microgL F203271 PA 2008 Moc u
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Page 24of26 1201073 Final Report 04252012 26
~
~TIER~ GLOBAL SCIENCES
11720 North Creek Parkway North Suite 400 Bothell WA 980ll
Ph 425-686-1996 Fx 425-686-3096
PREPARATION BLANKS
Instrument JCPMS-3 Sequence 2C25005
Preparation Closed Vessel Nitric Oven Digestion
Lab Sample ID Analyte Found MRL Units Batch Method Notes
F2033I4-BLK1 Thalium 00007 0010 microgL F2033I4 ~PA 2008 Molt u
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Page 25 o26Liz Siska Project Manager 1201073 Final Report
04252012 27
l l 720 North Creek Parkway North Suite 400~Vi-~ Bothell WA 98011 Ph 425-686-1 996~Tlmiddot~ Fx 425-686-3096
G L OBAL SCIENCE S
Notes and Definitions
U Analyte included in the analysis but not detected
QM-02 The MS andor MSD recoveries outside acceptance limits due to spike concentration less than I times the sample concentration The batch was accepted based on LCS and LCSD recoveries within control limits and when analysis permits acceptable AS ASD
QB-06 The blank was preserved to 5 BrCI rather than I The control limit for blanks preserved to greater than 1 BrCl is the preservation percentage multiplied by the MRL
QB-04 The blank was preserved to 2 BrCI rather than l The control limit for blanks preserved to greater than l BrCI is the preservation percentage multiplied by the MRL
FB-1631 Required equipmentfieldfilter blank not submitted by the client The sample has been analyzed according to 163 lE but does not meet 163 lE criteria
AS This MS andor MSD is an analytical spike andor an analytical spike duplicate
DET Analyte Detected
MDL Minimum Detection Limit
MRL Minimum Reporting Limit
ND Analyte Not Detected at or above the reporting limit
wet Sample results reported on a wet weight basis
dry Sample results reported on a dry weight basis
RPO Relative Percent Difference
RSD Relative Standard Deviation
Frontier Global Sciences Inc The lesults i111his reporl only apply to he samples analyzed In accordance with the chain ofcuslody document This analytical report must be reproduced in its entirely
Page 26of26 1201073 Final Report 04252012
Liz Siska Project Manager
28
CHAIN-OF-(USTODY ttECORD Page i of f 106677 _J
BoLD F1ELDS REQUIRED PLEASE C 1RCLE REQUESTED ANALYSIS
SAMPLE ID
middoti-rg -- bull ~rshy~ _- tzir +- lt-ltJ~ lt
SAMPLING
DATeTtME
IF COMPOSITE INDICATE BOTH
START amp FINISH
DATETIME li1J oc -r 111_- _vlt-c_
w Ishyt 0 n
w l w 0 ~ u X -Xmiddot ~ m Ishy lt( lt( 0
I C)
IIXJ JC
~ ~ irlte-t- T_ t- f r-n t I s-11 middott~ c~ J J1~w )(~ )
Trttbull rin K C-~-~ pound1t I 1Jtl~ t20~L lwlJI ishy
middot~ON Mm1x A-Al~ S-SOil GW-GampOUHO WATER SW-SUampfA(f WATER DWmiddotDRIIIKIKlti WATER
Itlt
-glo c ~
c t I O
~ t = ~ ~
~ o ~1
~ ~ ~
0
5 g sect ~ shy2 s z
rJ gII
)(
107555
i
~ I NOTES MEOH VIAL
1 WW-WASTE WATER PmmATIVE H-HCL H-HN01 S-H1SO Na-NaOH H-HEOH -~ --~
PROJECT MANAGER llr middot1 ~Q Aw4---P1V- Het_ r COMPANY t-lo--tm ~ bd i ( I ~j 6 A ADP~SS 91 g~ez tJshy(ITJ ~ STATE fH_ ZIP c3o--
PHONE 22j-((omiddotf EXT ____
fAX--------------------- shyE-MAIL (JbHd-esa e n ta wamp Sm NAME Meccft1lt-1ltk f--g
PROJECT _
OTHEi________STATpound NH MA ME VT
REGULATORY PROGRAM NPDES RGP POTW STORHWATEl OR
GWP OIL FUHD BROWNIIELO OR OTHER----------
Quon PO o2J~-lt1Jpound)
DATE NEEDED _1--1 middot Z=-----shy4 (1-1_ METALS 8 RCRA 13 pp ff MN PB Cu
QAQC REPORTJNGYVEL
A CG) O R
PRESUMPTIVE CERTAINTY
7i2lt_
RECpound1VEO BYRELINQUISHED BY DATE TIME SUSPECTED (OHTAHIHATIOH________
TEHP~ C REPORTING OPTIONS 01HEA METAL------------PRELIHl Yu OR No
DISSOLVED METALS FIELD FllTEREDI YES 110
rmreg No
IF YH FAX OR POf 7~shy Hom (IE SPECIAL DETECTION LINITl BllLIKGINfO If DlffERrnT)ELECTRONIC OPTIONS zo 1 2 2) le~C1 1 Jc Id sJ 60 6c
1 cf Co
lo FAX pound-MAIL PDF EQUll C jCi (e I rt--111 Ao NiAJrJe middotn th
Ka)Jcr(c C(cdd -ltJ c -l -gtck- z Alt 5e1 Hj
Al l 4_) it fG) 1uJ c(iJoclt-U Sin HISTORY 0Se-d Cim- ~pound rc~L IH t--6
1 r
ImiddotRELINQUISHED BY DATE TIHE RECflVEO BY I FIELD READINGS
eastern analytical inc 2s CHENELL D R1ve IC 0 Nco1to N H 0330 1 I TEL 60J22aos2s 1aoo2a1os2s IFAx 6032284591 j E-MA1t cus-roM111_mV1c~EAILAsscoMJ www1A1LAascoM
----i pmiddotofissionrrl11bomtorymim (WHITE ORIGINAL GREEN PROJECT MANAGER)
shy
~
~TIER~ GLOBAL SCIENCES
11720 North Creek Parkway North Suite 400 Bothell WA 980ll
Ph 425-686-1996 Fx 425-686-3096
PREPARATION BLANKS
Instrument JCPMS-3 Sequence 2C25005
Preparation Closed Vessel Nitric Oven Digestion
Lab Sample ID Analyte Found MRL Units Batch Method Notes
F2033I4-BLK1 Thalium 00007 0010 microgL F2033I4 ~PA 2008 Molt u
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Page 25 o26Liz Siska Project Manager 1201073 Final Report
04252012 27
l l 720 North Creek Parkway North Suite 400~Vi-~ Bothell WA 98011 Ph 425-686-1 996~Tlmiddot~ Fx 425-686-3096
G L OBAL SCIENCE S
Notes and Definitions
U Analyte included in the analysis but not detected
QM-02 The MS andor MSD recoveries outside acceptance limits due to spike concentration less than I times the sample concentration The batch was accepted based on LCS and LCSD recoveries within control limits and when analysis permits acceptable AS ASD
QB-06 The blank was preserved to 5 BrCI rather than I The control limit for blanks preserved to greater than 1 BrCl is the preservation percentage multiplied by the MRL
QB-04 The blank was preserved to 2 BrCI rather than l The control limit for blanks preserved to greater than l BrCI is the preservation percentage multiplied by the MRL
FB-1631 Required equipmentfieldfilter blank not submitted by the client The sample has been analyzed according to 163 lE but does not meet 163 lE criteria
AS This MS andor MSD is an analytical spike andor an analytical spike duplicate
DET Analyte Detected
MDL Minimum Detection Limit
MRL Minimum Reporting Limit
ND Analyte Not Detected at or above the reporting limit
wet Sample results reported on a wet weight basis
dry Sample results reported on a dry weight basis
RPO Relative Percent Difference
RSD Relative Standard Deviation
Frontier Global Sciences Inc The lesults i111his reporl only apply to he samples analyzed In accordance with the chain ofcuslody document This analytical report must be reproduced in its entirely
Page 26of26 1201073 Final Report 04252012
Liz Siska Project Manager
28
CHAIN-OF-(USTODY ttECORD Page i of f 106677 _J
BoLD F1ELDS REQUIRED PLEASE C 1RCLE REQUESTED ANALYSIS
SAMPLE ID
middoti-rg -- bull ~rshy~ _- tzir +- lt-ltJ~ lt
SAMPLING
DATeTtME
IF COMPOSITE INDICATE BOTH
START amp FINISH
DATETIME li1J oc -r 111_- _vlt-c_
w Ishyt 0 n
w l w 0 ~ u X -Xmiddot ~ m Ishy lt( lt( 0
I C)
IIXJ JC
~ ~ irlte-t- T_ t- f r-n t I s-11 middott~ c~ J J1~w )(~ )
Trttbull rin K C-~-~ pound1t I 1Jtl~ t20~L lwlJI ishy
middot~ON Mm1x A-Al~ S-SOil GW-GampOUHO WATER SW-SUampfA(f WATER DWmiddotDRIIIKIKlti WATER
Itlt
-glo c ~
c t I O
~ t = ~ ~
~ o ~1
~ ~ ~
0
5 g sect ~ shy2 s z
rJ gII
)(
107555
i
~ I NOTES MEOH VIAL
1 WW-WASTE WATER PmmATIVE H-HCL H-HN01 S-H1SO Na-NaOH H-HEOH -~ --~
PROJECT MANAGER llr middot1 ~Q Aw4---P1V- Het_ r COMPANY t-lo--tm ~ bd i ( I ~j 6 A ADP~SS 91 g~ez tJshy(ITJ ~ STATE fH_ ZIP c3o--
PHONE 22j-((omiddotf EXT ____
fAX--------------------- shyE-MAIL (JbHd-esa e n ta wamp Sm NAME Meccft1lt-1ltk f--g
PROJECT _
OTHEi________STATpound NH MA ME VT
REGULATORY PROGRAM NPDES RGP POTW STORHWATEl OR
GWP OIL FUHD BROWNIIELO OR OTHER----------
Quon PO o2J~-lt1Jpound)
DATE NEEDED _1--1 middot Z=-----shy4 (1-1_ METALS 8 RCRA 13 pp ff MN PB Cu
QAQC REPORTJNGYVEL
A CG) O R
PRESUMPTIVE CERTAINTY
7i2lt_
RECpound1VEO BYRELINQUISHED BY DATE TIME SUSPECTED (OHTAHIHATIOH________
TEHP~ C REPORTING OPTIONS 01HEA METAL------------PRELIHl Yu OR No
DISSOLVED METALS FIELD FllTEREDI YES 110
rmreg No
IF YH FAX OR POf 7~shy Hom (IE SPECIAL DETECTION LINITl BllLIKGINfO If DlffERrnT)ELECTRONIC OPTIONS zo 1 2 2) le~C1 1 Jc Id sJ 60 6c
1 cf Co
lo FAX pound-MAIL PDF EQUll C jCi (e I rt--111 Ao NiAJrJe middotn th
Ka)Jcr(c C(cdd -ltJ c -l -gtck- z Alt 5e1 Hj
Al l 4_) it fG) 1uJ c(iJoclt-U Sin HISTORY 0Se-d Cim- ~pound rc~L IH t--6
1 r
ImiddotRELINQUISHED BY DATE TIHE RECflVEO BY I FIELD READINGS
eastern analytical inc 2s CHENELL D R1ve IC 0 Nco1to N H 0330 1 I TEL 60J22aos2s 1aoo2a1os2s IFAx 6032284591 j E-MA1t cus-roM111_mV1c~EAILAsscoMJ www1A1LAascoM
----i pmiddotofissionrrl11bomtorymim (WHITE ORIGINAL GREEN PROJECT MANAGER)
shy
l l 720 North Creek Parkway North Suite 400~Vi-~ Bothell WA 98011 Ph 425-686-1 996~Tlmiddot~ Fx 425-686-3096
G L OBAL SCIENCE S
Notes and Definitions
U Analyte included in the analysis but not detected
QM-02 The MS andor MSD recoveries outside acceptance limits due to spike concentration less than I times the sample concentration The batch was accepted based on LCS and LCSD recoveries within control limits and when analysis permits acceptable AS ASD
QB-06 The blank was preserved to 5 BrCI rather than I The control limit for blanks preserved to greater than 1 BrCl is the preservation percentage multiplied by the MRL
QB-04 The blank was preserved to 2 BrCI rather than l The control limit for blanks preserved to greater than l BrCI is the preservation percentage multiplied by the MRL
FB-1631 Required equipmentfieldfilter blank not submitted by the client The sample has been analyzed according to 163 lE but does not meet 163 lE criteria
AS This MS andor MSD is an analytical spike andor an analytical spike duplicate
DET Analyte Detected
MDL Minimum Detection Limit
MRL Minimum Reporting Limit
ND Analyte Not Detected at or above the reporting limit
wet Sample results reported on a wet weight basis
dry Sample results reported on a dry weight basis
RPO Relative Percent Difference
RSD Relative Standard Deviation
Frontier Global Sciences Inc The lesults i111his reporl only apply to he samples analyzed In accordance with the chain ofcuslody document This analytical report must be reproduced in its entirely
Page 26of26 1201073 Final Report 04252012
Liz Siska Project Manager
28
CHAIN-OF-(USTODY ttECORD Page i of f 106677 _J
BoLD F1ELDS REQUIRED PLEASE C 1RCLE REQUESTED ANALYSIS
SAMPLE ID
middoti-rg -- bull ~rshy~ _- tzir +- lt-ltJ~ lt
SAMPLING
DATeTtME
IF COMPOSITE INDICATE BOTH
START amp FINISH
DATETIME li1J oc -r 111_- _vlt-c_
w Ishyt 0 n
w l w 0 ~ u X -Xmiddot ~ m Ishy lt( lt( 0
I C)
IIXJ JC
~ ~ irlte-t- T_ t- f r-n t I s-11 middott~ c~ J J1~w )(~ )
Trttbull rin K C-~-~ pound1t I 1Jtl~ t20~L lwlJI ishy
middot~ON Mm1x A-Al~ S-SOil GW-GampOUHO WATER SW-SUampfA(f WATER DWmiddotDRIIIKIKlti WATER
Itlt
-glo c ~
c t I O
~ t = ~ ~
~ o ~1
~ ~ ~
0
5 g sect ~ shy2 s z
rJ gII
)(
107555
i
~ I NOTES MEOH VIAL
1 WW-WASTE WATER PmmATIVE H-HCL H-HN01 S-H1SO Na-NaOH H-HEOH -~ --~
PROJECT MANAGER llr middot1 ~Q Aw4---P1V- Het_ r COMPANY t-lo--tm ~ bd i ( I ~j 6 A ADP~SS 91 g~ez tJshy(ITJ ~ STATE fH_ ZIP c3o--
PHONE 22j-((omiddotf EXT ____
fAX--------------------- shyE-MAIL (JbHd-esa e n ta wamp Sm NAME Meccft1lt-1ltk f--g
PROJECT _
OTHEi________STATpound NH MA ME VT
REGULATORY PROGRAM NPDES RGP POTW STORHWATEl OR
GWP OIL FUHD BROWNIIELO OR OTHER----------
Quon PO o2J~-lt1Jpound)
DATE NEEDED _1--1 middot Z=-----shy4 (1-1_ METALS 8 RCRA 13 pp ff MN PB Cu
QAQC REPORTJNGYVEL
A CG) O R
PRESUMPTIVE CERTAINTY
7i2lt_
RECpound1VEO BYRELINQUISHED BY DATE TIME SUSPECTED (OHTAHIHATIOH________
TEHP~ C REPORTING OPTIONS 01HEA METAL------------PRELIHl Yu OR No
DISSOLVED METALS FIELD FllTEREDI YES 110
rmreg No
IF YH FAX OR POf 7~shy Hom (IE SPECIAL DETECTION LINITl BllLIKGINfO If DlffERrnT)ELECTRONIC OPTIONS zo 1 2 2) le~C1 1 Jc Id sJ 60 6c
1 cf Co
lo FAX pound-MAIL PDF EQUll C jCi (e I rt--111 Ao NiAJrJe middotn th
Ka)Jcr(c C(cdd -ltJ c -l -gtck- z Alt 5e1 Hj
Al l 4_) it fG) 1uJ c(iJoclt-U Sin HISTORY 0Se-d Cim- ~pound rc~L IH t--6
1 r
ImiddotRELINQUISHED BY DATE TIHE RECflVEO BY I FIELD READINGS
eastern analytical inc 2s CHENELL D R1ve IC 0 Nco1to N H 0330 1 I TEL 60J22aos2s 1aoo2a1os2s IFAx 6032284591 j E-MA1t cus-roM111_mV1c~EAILAsscoMJ www1A1LAascoM
----i pmiddotofissionrrl11bomtorymim (WHITE ORIGINAL GREEN PROJECT MANAGER)
shy
CHAIN-OF-(USTODY ttECORD Page i of f 106677 _J
BoLD F1ELDS REQUIRED PLEASE C 1RCLE REQUESTED ANALYSIS
SAMPLE ID
middoti-rg -- bull ~rshy~ _- tzir +- lt-ltJ~ lt
SAMPLING
DATeTtME
IF COMPOSITE INDICATE BOTH
START amp FINISH
DATETIME li1J oc -r 111_- _vlt-c_
w Ishyt 0 n
w l w 0 ~ u X -Xmiddot ~ m Ishy lt( lt( 0
I C)
IIXJ JC
~ ~ irlte-t- T_ t- f r-n t I s-11 middott~ c~ J J1~w )(~ )
Trttbull rin K C-~-~ pound1t I 1Jtl~ t20~L lwlJI ishy
middot~ON Mm1x A-Al~ S-SOil GW-GampOUHO WATER SW-SUampfA(f WATER DWmiddotDRIIIKIKlti WATER
Itlt
-glo c ~
c t I O
~ t = ~ ~
~ o ~1
~ ~ ~
0
5 g sect ~ shy2 s z
rJ gII
)(
107555
i
~ I NOTES MEOH VIAL
1 WW-WASTE WATER PmmATIVE H-HCL H-HN01 S-H1SO Na-NaOH H-HEOH -~ --~
PROJECT MANAGER llr middot1 ~Q Aw4---P1V- Het_ r COMPANY t-lo--tm ~ bd i ( I ~j 6 A ADP~SS 91 g~ez tJshy(ITJ ~ STATE fH_ ZIP c3o--
PHONE 22j-((omiddotf EXT ____
fAX--------------------- shyE-MAIL (JbHd-esa e n ta wamp Sm NAME Meccft1lt-1ltk f--g
PROJECT _
OTHEi________STATpound NH MA ME VT
REGULATORY PROGRAM NPDES RGP POTW STORHWATEl OR
GWP OIL FUHD BROWNIIELO OR OTHER----------
Quon PO o2J~-lt1Jpound)
DATE NEEDED _1--1 middot Z=-----shy4 (1-1_ METALS 8 RCRA 13 pp ff MN PB Cu
QAQC REPORTJNGYVEL
A CG) O R
PRESUMPTIVE CERTAINTY
7i2lt_
RECpound1VEO BYRELINQUISHED BY DATE TIME SUSPECTED (OHTAHIHATIOH________
TEHP~ C REPORTING OPTIONS 01HEA METAL------------PRELIHl Yu OR No
DISSOLVED METALS FIELD FllTEREDI YES 110
rmreg No
IF YH FAX OR POf 7~shy Hom (IE SPECIAL DETECTION LINITl BllLIKGINfO If DlffERrnT)ELECTRONIC OPTIONS zo 1 2 2) le~C1 1 Jc Id sJ 60 6c
1 cf Co
lo FAX pound-MAIL PDF EQUll C jCi (e I rt--111 Ao NiAJrJe middotn th
Ka)Jcr(c C(cdd -ltJ c -l -gtck- z Alt 5e1 Hj
Al l 4_) it fG) 1uJ c(iJoclt-U Sin HISTORY 0Se-d Cim- ~pound rc~L IH t--6
1 r
ImiddotRELINQUISHED BY DATE TIHE RECflVEO BY I FIELD READINGS
eastern analytical inc 2s CHENELL D R1ve IC 0 Nco1to N H 0330 1 I TEL 60J22aos2s 1aoo2a1os2s IFAx 6032284591 j E-MA1t cus-roM111_mV1c~EAILAsscoMJ www1A1LAascoM
----i pmiddotofissionrrl11bomtorymim (WHITE ORIGINAL GREEN PROJECT MANAGER)
shy