analytical report 6 - 3348 south street report testamerica ... method: 200.7 rev 4.4 - metals (icp)...
TRANSCRIPT
ANALYTICAL REPORTTestAmerica Laboratories, Inc.TestAmerica Savannah5102 LaRoche AvenueSavannah, GA 31404Tel: (912)354-7858
TestAmerica Job ID: 680-146495-1Client Project/Site: South Street Site
For:GFA International Inc5851 Country Lakes DriveFort Myers, Florida 33905-5504
Attn: Scott McManus
Authorized for release by:12/18/2017 3:02:45 PM
Noel Savoie, Project Manager I(850)[email protected]
The test results in this report meet all 2003 NELAC and 2009 TNI requirements for accreditedparameters, exceptions are noted in this report. This report may not be reproduced except in full,and with written approval from the laboratory. For questions please contact the Project Managerat the e-mail address or telephone number listed on this page.
This report has been electronically signed and authorized by the signatory. Electronic signature isintended to be the legally binding equivalent of a traditionally handwritten signature.
Results relate only to the items tested and the sample(s) as received by the laboratory.
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Definitions/GlossaryTestAmerica Job ID: 680-146495-1Client: GFA International Inc
Project/Site: South Street Site
Qualifiers
Metals
Qualifier Description
U Indicates that the compound was analyzed for but not detected.
Qualifier
I The reported value is between the laboratory method detection limit and the laboratory practical quantitation limit.
Glossary
These commonly used abbreviations may or may not be present in this report.
¤ Listed under the "D" column to designate that the result is reported on a dry weight basis
Abbreviation
%R Percent Recovery
CFL Contains Free Liquid
CNF Contains No Free Liquid
DER Duplicate Error Ratio (normalized absolute difference)
Dil Fac Dilution Factor
DL Detection Limit (DoD/DOE)
DL, RA, RE, IN Indicates a Dilution, Re-analysis, Re-extraction, or additional Initial metals/anion analysis of the sample
DLC Decision Level Concentration (Radiochemistry)
EDL Estimated Detection Limit (Dioxin)
LOD Limit of Detection (DoD/DOE)
LOQ Limit of Quantitation (DoD/DOE)
MDA Minimum Detectable Activity (Radiochemistry)
MDC Minimum Detectable Concentration (Radiochemistry)
MDL Method Detection Limit
ML Minimum Level (Dioxin)
NC Not Calculated
ND Not Detected at the reporting limit (or MDL or EDL if shown)
PQL Practical Quantitation Limit
QC Quality Control
RER Relative Error Ratio (Radiochemistry)
RL Reporting Limit or Requested Limit (Radiochemistry)
RPD Relative Percent Difference, a measure of the relative difference between two points
TEF Toxicity Equivalent Factor (Dioxin)
TEQ Toxicity Equivalent Quotient (Dioxin)
TestAmerica Savannah
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Sample SummaryTestAmerica Job ID: 680-146495-1Client: GFA International Inc
Project/Site: South Street Site
Lab Sample ID Client Sample ID ReceivedCollectedMatrix
680-146495-1 MW-7 Water 12/04/17 11:55 12/07/17 09:15
680-146495-2 MW-8 Water 12/04/17 14:10 12/07/17 09:15
680-146495-3 MW-10 Water 12/04/17 16:00 12/07/17 09:15
680-146495-4 MW-1R Water 12/04/17 17:09 12/07/17 09:15
TestAmerica Savannah
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Case NarrativeClient: GFA International Inc TestAmerica Job ID: 680-146495-1Project/Site: South Street Site
Job ID: 680-146495-1
Laboratory: TestAmerica Savannah
Narrative
Job Narrative680-146495-1
Comments
Samples collected on 12/5/17 will be reported on job 680-146495-2.
Receipt
The samples were received on 12/7/2017 9:15 AM; the samples arrived in good condition, properly preserved and, where required, on ice.
The temperature of the cooler at receipt was 2.6º C.
Metals No analytical or quality issues were noted, other than those described in the Definitions/Glossary page.
General Chemistry No analytical or quality issues were noted, other than those described in the Definitions/Glossary page.
TestAmerica SavannahPage 4 of 22 12/18/2017
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Client Sample ResultsTestAmerica Job ID: 680-146495-1Client: GFA International Inc
Project/Site: South Street Site
Lab Sample ID: 680-146495-1Client Sample ID: MW-7Matrix: WaterDate Collected: 12/04/17 11:55
Date Received: 12/07/17 09:15
Method: 200.7 Rev 4.4 - Metals (ICP)PQL MDL
Antimony 5.30 U 20.0 5.30 ug/L 12/11/17 10:41 12/12/17 07:23 1
Analyte Dil FacAnalyzedPreparedUnit DResult Qualifier
20.0 6.20 ug/L 12/11/17 10:41 12/15/17 15:16 1Arsenic 18.9 I
4.00 0.100 ug/L 12/11/17 10:41 12/12/17 07:23 1Beryllium 0.100 U
5.00 1.00 ug/L 12/11/17 10:41 12/12/17 07:23 1Cadmium 1.00 U
10.0 1.60 ug/L 12/11/17 10:41 12/12/17 07:23 1Chromium 2.18 I
20.0 1.80 ug/L 12/11/17 10:41 12/12/17 07:23 1Copper 1.80 U
10.0 3.90 ug/L 12/11/17 10:41 12/12/17 07:23 1Lead 3.90 U
10.0 1.00 ug/L 12/11/17 10:41 12/12/17 07:23 1Molybdenum 22.8
40.0 2.10 ug/L 12/11/17 10:41 12/12/17 07:23 1Nickel 2.49 I
20.0 9.90 ug/L 12/11/17 10:41 12/12/17 07:23 1Selenium 9.90 U
10.0 0.600 ug/L 12/11/17 10:41 12/12/17 07:23 1Silver 0.600 U
25.0 6.00 ug/L 12/11/17 10:41 12/12/17 07:23 1Thallium 6.00 U
20.0 7.00 ug/L 12/11/17 10:41 12/12/17 07:23 1Zinc 7.00 U
Method: 200.8 - ICPMS Dissolved Metals by 200.8 - DissolvedPQL MDL
Dissolved Arsenic 18.3 1.00 0.370 ug/L 12/12/17 11:42 12/12/17 20:06 1
Analyte Dil FacAnalyzedPreparedUnit DResult Qualifier
Method: 245.1 - Mercury (CVAA)PQL MDL
Mercury 0.0800 U 0.200 0.0800 ug/L 12/08/17 09:29 12/08/17 16:03 1
Analyte Dil FacAnalyzedPreparedUnit DResult Qualifier
General ChemistryPQL MDL
Total Dissolved Solids 574 10.0 10.0 mg/L 12/11/17 16:17 1
Analyte Dil FacAnalyzedPreparedUnit DResult Qualifier
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Client Sample ResultsTestAmerica Job ID: 680-146495-1Client: GFA International Inc
Project/Site: South Street Site
Lab Sample ID: 680-146495-2Client Sample ID: MW-8Matrix: WaterDate Collected: 12/04/17 14:10
Date Received: 12/07/17 09:15
Method: 200.7 Rev 4.4 - Metals (ICP)PQL MDL
Antimony 5.30 U 20.0 5.30 ug/L 12/11/17 10:41 12/12/17 07:46 1
Analyte Dil FacAnalyzedPreparedUnit DResult Qualifier
20.0 6.20 ug/L 12/11/17 10:41 12/15/17 15:42 1Arsenic 11.3 I
4.00 0.100 ug/L 12/11/17 10:41 12/12/17 07:46 1Beryllium 0.100 U
5.00 1.00 ug/L 12/11/17 10:41 12/12/17 07:46 1Cadmium 1.00 U
10.0 1.60 ug/L 12/11/17 10:41 12/12/17 07:46 1Chromium 2.33 I
20.0 1.80 ug/L 12/11/17 10:41 12/12/17 07:46 1Copper 1.80 U
10.0 3.90 ug/L 12/11/17 10:41 12/12/17 07:46 1Lead 3.90 U
10.0 1.00 ug/L 12/11/17 10:41 12/12/17 07:46 1Molybdenum 46.9
40.0 2.10 ug/L 12/11/17 10:41 12/12/17 07:46 1Nickel 2.79 I
20.0 9.90 ug/L 12/11/17 10:41 12/12/17 07:46 1Selenium 9.90 U
10.0 0.600 ug/L 12/11/17 10:41 12/12/17 07:46 1Silver 0.600 U
25.0 6.00 ug/L 12/11/17 10:41 12/12/17 07:46 1Thallium 6.00 U
20.0 7.00 ug/L 12/11/17 10:41 12/12/17 07:46 1Zinc 7.00 U
Method: 200.8 - ICPMS Dissolved Metals by 200.8 - DissolvedPQL MDL
Dissolved Arsenic 12.6 1.00 0.370 ug/L 12/12/17 11:42 12/12/17 20:10 1
Analyte Dil FacAnalyzedPreparedUnit DResult Qualifier
Method: 245.1 - Mercury (CVAA)PQL MDL
Mercury 0.0800 U 0.200 0.0800 ug/L 12/08/17 09:55 12/11/17 23:24 1
Analyte Dil FacAnalyzedPreparedUnit DResult Qualifier
General ChemistryPQL MDL
Total Dissolved Solids 514 10.0 10.0 mg/L 12/11/17 16:17 1
Analyte Dil FacAnalyzedPreparedUnit DResult Qualifier
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Client Sample ResultsTestAmerica Job ID: 680-146495-1Client: GFA International Inc
Project/Site: South Street Site
Lab Sample ID: 680-146495-3Client Sample ID: MW-10Matrix: WaterDate Collected: 12/04/17 16:00
Date Received: 12/07/17 09:15
Method: 200.7 Rev 4.4 - Metals (ICP)PQL MDL
Antimony 5.30 U 20.0 5.30 ug/L 12/11/17 10:41 12/12/17 07:51 1
Analyte Dil FacAnalyzedPreparedUnit DResult Qualifier
20.0 6.20 ug/L 12/11/17 10:41 12/15/17 15:57 1Arsenic 36.5
4.00 0.100 ug/L 12/11/17 10:41 12/12/17 07:51 1Beryllium 0.100 U
5.00 1.00 ug/L 12/11/17 10:41 12/12/17 07:51 1Cadmium 1.00 U
10.0 1.60 ug/L 12/11/17 10:41 12/12/17 07:51 1Chromium 2.39 I
20.0 1.80 ug/L 12/11/17 10:41 12/12/17 07:51 1Copper 1.80 U
10.0 3.90 ug/L 12/11/17 10:41 12/12/17 07:51 1Lead 3.90 U
10.0 1.00 ug/L 12/11/17 10:41 12/12/17 07:51 1Molybdenum 91.3
40.0 2.10 ug/L 12/11/17 10:41 12/12/17 07:51 1Nickel 3.34 I
20.0 9.90 ug/L 12/11/17 10:41 12/12/17 07:51 1Selenium 9.90 U
10.0 0.600 ug/L 12/11/17 10:41 12/12/17 07:51 1Silver 0.600 U
25.0 6.00 ug/L 12/11/17 10:41 12/12/17 07:51 1Thallium 6.00 U
20.0 7.00 ug/L 12/11/17 10:41 12/12/17 07:51 1Zinc 7.00 U
Method: 200.8 - ICPMS Dissolved Metals by 200.8 - DissolvedPQL MDL
Dissolved Arsenic 35.8 1.00 0.370 ug/L 12/12/17 11:42 12/12/17 20:03 1
Analyte Dil FacAnalyzedPreparedUnit DResult Qualifier
Method: 245.1 - Mercury (CVAA)PQL MDL
Mercury 0.0800 U 0.200 0.0800 ug/L 12/08/17 09:29 12/08/17 15:26 1
Analyte Dil FacAnalyzedPreparedUnit DResult Qualifier
General ChemistryPQL MDL
Total Dissolved Solids 668 10.0 10.0 mg/L 12/11/17 16:17 1
Analyte Dil FacAnalyzedPreparedUnit DResult Qualifier
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Client Sample ResultsTestAmerica Job ID: 680-146495-1Client: GFA International Inc
Project/Site: South Street Site
Lab Sample ID: 680-146495-4Client Sample ID: MW-1RMatrix: WaterDate Collected: 12/04/17 17:09
Date Received: 12/07/17 09:15
Method: 200.7 Rev 4.4 - Metals (ICP)PQL MDL
Aluminum 206 200 24.0 ug/L 12/11/17 15:07 12/12/17 21:51 1
Analyte Dil FacAnalyzedPreparedUnit DResult Qualifier
50.0 17.0 ug/L 12/11/17 15:07 12/12/17 21:51 1Iron 708
10.0 1.00 ug/L 12/11/17 15:07 12/12/17 21:51 1Manganese 20.5
Method: 200.8 - ICPMS Dissolved Metals by 200.8 - DissolvedPQL MDL
Dissolved Arsenic 1.23 1.00 0.370 ug/L 12/12/17 11:42 12/12/17 20:28 1
Analyte Dil FacAnalyzedPreparedUnit DResult Qualifier
Method: 200.8 - Metals (ICP/MS)PQL MDL
Arsenic 1.48 1.00 0.370 ug/L 12/11/17 15:07 12/12/17 16:29 1
Analyte Dil FacAnalyzedPreparedUnit DResult Qualifier
General ChemistryPQL MDL
Total Dissolved Solids 888 10.0 10.0 mg/L 12/11/17 16:17 1
Analyte Dil FacAnalyzedPreparedUnit DResult Qualifier
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QC Sample ResultsTestAmerica Job ID: 680-146495-1Client: GFA International Inc
Project/Site: South Street Site
Method: 200.7 Rev 4.4 - Metals (ICP)
Client Sample ID: Method BlankLab Sample ID: MB 680-505870/1-AMatrix: Water Prep Type: Total/NAAnalysis Batch: 506043 Prep Batch: 505870
PQL MDL
Antimony 5.30 U 20.0 5.30 ug/L 12/11/17 10:41 12/12/17 07:04 1
MB MB
Analyte Dil FacAnalyzedPreparedDUnitResult Qualifier
0.100 U 0.1004.00 ug/L 12/11/17 10:41 12/12/17 07:04 1Beryllium
1.00 U 1.005.00 ug/L 12/11/17 10:41 12/12/17 07:04 1Cadmium
1.60 U 1.6010.0 ug/L 12/11/17 10:41 12/12/17 07:04 1Chromium
1.80 U 1.8020.0 ug/L 12/11/17 10:41 12/12/17 07:04 1Copper
3.90 U 3.9010.0 ug/L 12/11/17 10:41 12/12/17 07:04 1Lead
1.00 U 1.0010.0 ug/L 12/11/17 10:41 12/12/17 07:04 1Molybdenum
2.10 U 2.1040.0 ug/L 12/11/17 10:41 12/12/17 07:04 1Nickel
9.90 U 9.9020.0 ug/L 12/11/17 10:41 12/12/17 07:04 1Selenium
0.600 U 0.60010.0 ug/L 12/11/17 10:41 12/12/17 07:04 1Silver
6.00 U 6.0025.0 ug/L 12/11/17 10:41 12/12/17 07:04 1Thallium
7.00 U 7.0020.0 ug/L 12/11/17 10:41 12/12/17 07:04 1Zinc
Client Sample ID: Method BlankLab Sample ID: MB 680-505870/1-AMatrix: Water Prep Type: Total/NAAnalysis Batch: 506685 Prep Batch: 505870
PQL MDL
Arsenic 6.20 U 20.0 6.20 ug/L 12/11/17 10:41 12/15/17 15:06 1
MB MB
Analyte Dil FacAnalyzedPreparedDUnitResult Qualifier
Client Sample ID: Lab Control SampleLab Sample ID: LCS 680-505870/2-AMatrix: Water Prep Type: Total/NAAnalysis Batch: 506043 Prep Batch: 505870
Antimony 50.0 53.87 ug/L 108 85 - 115
Analyte
LCS LCS
DUnitResult Qualifier %Rec
Spike
Added
%Rec.
Limits
Beryllium 50.0 52.48 ug/L 105 85 - 115
Cadmium 50.0 52.02 ug/L 104 85 - 115
Chromium 100 108.1 ug/L 108 85 - 115
Copper 100 98.78 ug/L 99 85 - 115
Lead 500 522.7 ug/L 105 85 - 115
Molybdenum 100 101.2 ug/L 101 85 - 115
Nickel 100 107.7 ug/L 108 85 - 115
Selenium 100 99.54 ug/L 100 85 - 115
Silver 50.0 49.96 ug/L 100 85 - 115
Thallium 40.0 40.96 ug/L 102 85 - 115
Zinc 100 107.8 ug/L 108 85 - 115
Client Sample ID: Lab Control SampleLab Sample ID: LCS 680-505870/2-AMatrix: Water Prep Type: Total/NAAnalysis Batch: 506685 Prep Batch: 505870
Arsenic 100 102.5 ug/L 102 85 - 115
Analyte
LCS LCS
DUnitResult Qualifier %Rec
Spike
Added
%Rec.
Limits
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QC Sample ResultsTestAmerica Job ID: 680-146495-1Client: GFA International Inc
Project/Site: South Street Site
Method: 200.7 Rev 4.4 - Metals (ICP) (Continued)
Client Sample ID: MW-7Lab Sample ID: 680-146495-1 MSMatrix: Water Prep Type: Total/NAAnalysis Batch: 506043 Prep Batch: 505870
Antimony 5.30 U 50.0 56.47 ug/L 113 75 - 125
Analyte
MS MS
DUnitResult Qualifier %Rec
Spike
Added
Sample
Result
Sample
Qualifier
%Rec.
Limits
Beryllium 0.100 U 50.0 52.97 ug/L 106 75 - 125
Cadmium 1.00 U 50.0 51.50 ug/L 103 75 - 125
Chromium 2.18 I 100 108.8 ug/L 107 75 - 125
Copper 1.80 U 100 101.4 ug/L 101 75 - 125
Lead 3.90 U 500 520.4 ug/L 104 75 - 125
Molybdenum 22.8 100 122.9 ug/L 100 75 - 125
Nickel 2.49 I 100 107.9 ug/L 105 75 - 125
Selenium 9.90 U 100 101.7 ug/L 102 75 - 125
Silver 0.600 U 50.0 51.59 ug/L 103 75 - 125
Thallium 6.00 U 40.0 41.01 ug/L 103 75 - 125
Zinc 7.00 U 100 108.3 ug/L 108 75 - 125
Client Sample ID: MW-7Lab Sample ID: 680-146495-1 MSMatrix: Water Prep Type: Total/NAAnalysis Batch: 506685 Prep Batch: 505870
Arsenic 18.9 I 100 124.3 ug/L 105 75 - 125
Analyte
MS MS
DUnitResult Qualifier %Rec
Spike
Added
Sample
Result
Sample
Qualifier
%Rec.
Limits
Client Sample ID: MW-7Lab Sample ID: 680-146495-1 MSDMatrix: Water Prep Type: Total/NAAnalysis Batch: 506043 Prep Batch: 505870
Antimony 5.30 U 50.0 53.61 ug/L 107 75 - 125 5 20
Analyte
MSD MSD
DUnitResult Qualifier %Rec
Spike
Added
Sample
Result
Sample
Qualifier
%Rec.
Limits LimitRPD
RPD
Beryllium 0.100 U 50.0 52.61 ug/L 105 75 - 125 1 20
Cadmium 1.00 U 50.0 51.23 ug/L 102 75 - 125 1 20
Chromium 2.18 I 100 108.0 ug/L 106 75 - 125 1 20
Copper 1.80 U 100 101.3 ug/L 101 75 - 125 0 20
Lead 3.90 U 500 514.9 ug/L 103 75 - 125 1 20
Molybdenum 22.8 100 122.0 ug/L 99 75 - 125 1 20
Nickel 2.49 I 100 107.1 ug/L 105 75 - 125 1 20
Selenium 9.90 U 100 101.2 ug/L 101 75 - 125 1 20
Silver 0.600 U 50.0 51.35 ug/L 103 75 - 125 0 20
Thallium 6.00 U 40.0 39.05 ug/L 98 75 - 125 5 20
Zinc 7.00 U 100 107.3 ug/L 107 75 - 125 1 20
Client Sample ID: MW-7Lab Sample ID: 680-146495-1 MSDMatrix: Water Prep Type: Total/NAAnalysis Batch: 506685 Prep Batch: 505870
Arsenic 18.9 I 100 125.7 ug/L 107 75 - 125 1 20
Analyte
MSD MSD
DUnitResult Qualifier %Rec
Spike
Added
Sample
Result
Sample
Qualifier
%Rec.
Limits LimitRPD
RPD
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QC Sample ResultsTestAmerica Job ID: 680-146495-1Client: GFA International Inc
Project/Site: South Street Site
Method: 200.7 Rev 4.4 - Metals (ICP) (Continued)
Client Sample ID: Method BlankLab Sample ID: MB 680-505946/1-AMatrix: Water Prep Type: Total/NAAnalysis Batch: 506233 Prep Batch: 505946
PQL MDL
Aluminum 24.0 U 200 24.0 ug/L 12/11/17 15:07 12/12/17 20:22 1
MB MB
Analyte Dil FacAnalyzedPreparedDUnitResult Qualifier
17.0 U 17.050.0 ug/L 12/11/17 15:07 12/12/17 20:22 1Iron
1.00 U 1.0010.0 ug/L 12/11/17 15:07 12/12/17 20:22 1Manganese
Client Sample ID: Lab Control SampleLab Sample ID: LCS 680-505946/2-AMatrix: Water Prep Type: Total/NAAnalysis Batch: 506233 Prep Batch: 505946
Aluminum 2000 2015 ug/L 101 85 - 115
Analyte
LCS LCS
DUnitResult Qualifier %Rec
Spike
Added
%Rec.
Limits
Iron 2000 2049 ug/L 102 85 - 115
Manganese 200 213.9 ug/L 107 85 - 115
Method: 200.8 - Metals (ICP/MS)
Client Sample ID: Method BlankLab Sample ID: MB 680-505943/1-AMatrix: Water Prep Type: Total/NAAnalysis Batch: 506216 Prep Batch: 505943
PQL MDL
Arsenic 0.370 U 1.00 0.370 ug/L 12/11/17 15:07 12/12/17 15:30 1
MB MB
Analyte Dil FacAnalyzedPreparedDUnitResult Qualifier
Client Sample ID: Lab Control SampleLab Sample ID: LCS 680-505943/2-AMatrix: Water Prep Type: Total/NAAnalysis Batch: 506216 Prep Batch: 505943
Arsenic 40.0 41.91 ug/L 105 85 - 115
Analyte
LCS LCS
DUnitResult Qualifier %Rec
Spike
Added
%Rec.
Limits
Method: 200.8 - ICPMS Dissolved Metals by 200.8
Client Sample ID: Method BlankLab Sample ID: MB 680-506063/1-AMatrix: Water Prep Type: Total/NAAnalysis Batch: 506216 Prep Batch: 506063
PQL MDL
Dissolved Arsenic 0.370 U 1.00 0.370 ug/L 12/12/17 11:42 12/12/17 19:02 1
MB MB
Analyte Dil FacAnalyzedPreparedDUnitResult Qualifier
Client Sample ID: Lab Control SampleLab Sample ID: LCS 680-506063/2-AMatrix: Water Prep Type: Total/NAAnalysis Batch: 506216 Prep Batch: 506063
Dissolved Arsenic 40.0 41.57 ug/L 104 85 - 115
Analyte
LCS LCS
DUnitResult Qualifier %Rec
Spike
Added
%Rec.
Limits
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QC Sample ResultsTestAmerica Job ID: 680-146495-1Client: GFA International Inc
Project/Site: South Street Site
Method: 245.1 - Mercury (CVAA)
Client Sample ID: Method BlankLab Sample ID: MB 680-505603/13-AMatrix: Water Prep Type: Total/NAAnalysis Batch: 505859 Prep Batch: 505603
PQL MDL
Mercury 0.0800 U 0.200 0.0800 ug/L 12/08/17 09:29 12/08/17 15:06 1
MB MB
Analyte Dil FacAnalyzedPreparedDUnitResult Qualifier
Client Sample ID: Lab Control SampleLab Sample ID: LCS 680-505603/14-AMatrix: Water Prep Type: Total/NAAnalysis Batch: 505859 Prep Batch: 505603
Mercury 2.50 2.443 ug/L 98 85 - 115
Analyte
LCS LCS
DUnitResult Qualifier %Rec
Spike
Added
%Rec.
Limits
Client Sample ID: MW-7Lab Sample ID: 680-146495-1 MSMatrix: Water Prep Type: Total/NAAnalysis Batch: 505859 Prep Batch: 505603
Mercury 0.0800 U 1.00 0.9866 ug/L 99 70 - 130
Analyte
MS MS
DUnitResult Qualifier %Rec
Spike
Added
Sample
Result
Sample
Qualifier
%Rec.
Limits
Client Sample ID: MW-7Lab Sample ID: 680-146495-1 MSDMatrix: Water Prep Type: Total/NAAnalysis Batch: 505859 Prep Batch: 505603
Mercury 0.0800 U 1.00 0.9850 ug/L 99 70 - 130 0 20
Analyte
MSD MSD
DUnitResult Qualifier %Rec
Spike
Added
Sample
Result
Sample
Qualifier
%Rec.
Limits LimitRPD
RPD
Client Sample ID: Method BlankLab Sample ID: MB 680-505613/1-AMatrix: Water Prep Type: Total/NAAnalysis Batch: 506039 Prep Batch: 505613
PQL MDL
Mercury 0.0800 U 0.200 0.0800 ug/L 12/08/17 09:55 12/11/17 23:14 1
MB MB
Analyte Dil FacAnalyzedPreparedDUnitResult Qualifier
Client Sample ID: Lab Control SampleLab Sample ID: LCS 680-505613/2-AMatrix: Water Prep Type: Total/NAAnalysis Batch: 506039 Prep Batch: 505613
Mercury 2.50 2.314 ug/L 93 85 - 115
Analyte
LCS LCS
DUnitResult Qualifier %Rec
Spike
Added
%Rec.
Limits
Client Sample ID: MW-8Lab Sample ID: 680-146495-2 MSMatrix: Water Prep Type: Total/NAAnalysis Batch: 506039 Prep Batch: 505613
Mercury 0.0800 U 1.00 0.9567 ug/L 96 70 - 130
Analyte
MS MS
DUnitResult Qualifier %Rec
Spike
Added
Sample
Result
Sample
Qualifier
%Rec.
Limits
Client Sample ID: MW-8Lab Sample ID: 680-146495-2 MSDMatrix: Water Prep Type: Total/NAAnalysis Batch: 506039 Prep Batch: 505613
Mercury 0.0800 U 1.00 0.9156 ug/L 92 70 - 130 4 20
Analyte
MSD MSD
DUnitResult Qualifier %Rec
Spike
Added
Sample
Result
Sample
Qualifier
%Rec.
Limits LimitRPD
RPD
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QC Sample ResultsTestAmerica Job ID: 680-146495-1Client: GFA International Inc
Project/Site: South Street Site
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QC Association SummaryTestAmerica Job ID: 680-146495-1Client: GFA International Inc
Project/Site: South Street Site
Metals
Prep Batch: 505603
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Water 245.1680-146495-1 MW-7 Total/NA
Water 245.1680-146495-3 MW-10 Total/NA
Water 245.1MB 680-505603/13-A Method Blank Total/NA
Water 245.1LCS 680-505603/14-A Lab Control Sample Total/NA
Water 245.1680-146495-1 MS MW-7 Total/NA
Water 245.1680-146495-1 MSD MW-7 Total/NA
Prep Batch: 505613
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Water 245.1680-146495-2 MW-8 Total/NA
Water 245.1MB 680-505613/1-A Method Blank Total/NA
Water 245.1LCS 680-505613/2-A Lab Control Sample Total/NA
Water 245.1680-146495-2 MS MW-8 Total/NA
Water 245.1680-146495-2 MSD MW-8 Total/NA
Analysis Batch: 505859
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Water 245.1 505603680-146495-1 MW-7 Total/NA
Water 245.1 505603680-146495-3 MW-10 Total/NA
Water 245.1 505603MB 680-505603/13-A Method Blank Total/NA
Water 245.1 505603LCS 680-505603/14-A Lab Control Sample Total/NA
Water 245.1 505603680-146495-1 MS MW-7 Total/NA
Water 245.1 505603680-146495-1 MSD MW-7 Total/NA
Prep Batch: 505870
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Water 200.7-1994 R4.4680-146495-1 MW-7 Total/NA
Water 200.7-1994 R4.4680-146495-2 MW-8 Total/NA
Water 200.7-1994 R4.4680-146495-3 MW-10 Total/NA
Water 200.7-1994 R4.4MB 680-505870/1-A Method Blank Total/NA
Water 200.7-1994 R4.4LCS 680-505870/2-A Lab Control Sample Total/NA
Water 200.7-1994 R4.4680-146495-1 MS MW-7 Total/NA
Water 200.7-1994 R4.4680-146495-1 MSD MW-7 Total/NA
Prep Batch: 505943
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Water 200680-146495-4 MW-1R Total/NA
Water 200MB 680-505943/1-A Method Blank Total/NA
Water 200LCS 680-505943/2-A Lab Control Sample Total/NA
Prep Batch: 505946
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Water 200680-146495-4 MW-1R Total/NA
Water 200MB 680-505946/1-A Method Blank Total/NA
Water 200LCS 680-505946/2-A Lab Control Sample Total/NA
Analysis Batch: 506039
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Water 245.1 505613680-146495-2 MW-8 Total/NA
Water 245.1 505613MB 680-505613/1-A Method Blank Total/NA
Water 245.1 505613LCS 680-505613/2-A Lab Control Sample Total/NA
TestAmerica Savannah
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QC Association SummaryTestAmerica Job ID: 680-146495-1Client: GFA International Inc
Project/Site: South Street Site
Metals (Continued)
Analysis Batch: 506039 (Continued)
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Water 245.1 505613680-146495-2 MS MW-8 Total/NA
Water 245.1 505613680-146495-2 MSD MW-8 Total/NA
Analysis Batch: 506043
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Water 200.7 Rev 4.4 505870680-146495-1 MW-7 Total/NA
Water 200.7 Rev 4.4 505870680-146495-2 MW-8 Total/NA
Water 200.7 Rev 4.4 505870680-146495-3 MW-10 Total/NA
Water 200.7 Rev 4.4 505870MB 680-505870/1-A Method Blank Total/NA
Water 200.7 Rev 4.4 505870LCS 680-505870/2-A Lab Control Sample Total/NA
Water 200.7 Rev 4.4 505870680-146495-1 MS MW-7 Total/NA
Water 200.7 Rev 4.4 505870680-146495-1 MSD MW-7 Total/NA
Prep Batch: 506063
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Water 200680-146495-1 MW-7 Dissolved
Water 200680-146495-2 MW-8 Dissolved
Water 200680-146495-3 MW-10 Dissolved
Water 200680-146495-4 MW-1R Dissolved
Water 200MB 680-506063/1-A Method Blank Total/NA
Water 200LCS 680-506063/2-A Lab Control Sample Total/NA
Analysis Batch: 506216
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Water 200.8 506063680-146495-1 MW-7 Dissolved
Water 200.8 506063680-146495-2 MW-8 Dissolved
Water 200.8 506063680-146495-3 MW-10 Dissolved
Water 200.8 506063680-146495-4 MW-1R Dissolved
Water 200.8 505943680-146495-4 MW-1R Total/NA
Water 200.8 505943MB 680-505943/1-A Method Blank Total/NA
Water 200.8 506063MB 680-506063/1-A Method Blank Total/NA
Water 200.8 505943LCS 680-505943/2-A Lab Control Sample Total/NA
Water 200.8 506063LCS 680-506063/2-A Lab Control Sample Total/NA
Analysis Batch: 506233
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Water 200.7 Rev 4.4 505946680-146495-4 MW-1R Total/NA
Water 200.7 Rev 4.4 505946MB 680-505946/1-A Method Blank Total/NA
Water 200.7 Rev 4.4 505946LCS 680-505946/2-A Lab Control Sample Total/NA
Analysis Batch: 506685
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Water 200.7 Rev 4.4 505870680-146495-1 MW-7 Total/NA
Water 200.7 Rev 4.4 505870680-146495-2 MW-8 Total/NA
Water 200.7 Rev 4.4 505870680-146495-3 MW-10 Total/NA
Water 200.7 Rev 4.4 505870MB 680-505870/1-A Method Blank Total/NA
Water 200.7 Rev 4.4 505870LCS 680-505870/2-A Lab Control Sample Total/NA
Water 200.7 Rev 4.4 505870680-146495-1 MS MW-7 Total/NA
Water 200.7 Rev 4.4 505870680-146495-1 MSD MW-7 Total/NA
TestAmerica Savannah
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QC Association SummaryTestAmerica Job ID: 680-146495-1Client: GFA International Inc
Project/Site: South Street Site
General Chemistry
Analysis Batch: 505965
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Water SM 2540C680-146495-1 MW-7 Total/NA
Water SM 2540C680-146495-2 MW-8 Total/NA
Water SM 2540C680-146495-3 MW-10 Total/NA
Water SM 2540C680-146495-4 MW-1R Total/NA
TestAmerica Savannah
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Lab ChronicleClient: GFA International Inc TestAmerica Job ID: 680-146495-1Project/Site: South Street Site
Client Sample ID: MW-7 Lab Sample ID: 680-146495-1Matrix: WaterDate Collected: 12/04/17 11:55
Date Received: 12/07/17 09:15
Prep 200.7-1994 R4.4 BCB12/11/17 10:41 TAL SAV505870
Type
Batch
Method
Batch
Prep Type LabAnalystRun
Prepared
or Analyzed
Initial
Amount Amount
Final Batch
NumberFactor
Dil
Total/NA 50 mL 50 mL
Analysis 200.7 Rev 4.4 1 506043 12/12/17 07:23 BWR TAL SAVTotal/NA
ICPEInstrument ID:
Prep 200.7-1994 R4.4 505870 12/11/17 10:41 BCB TAL SAVTotal/NA 50 mL 50 mL
Analysis 200.7 Rev 4.4 1 506685 12/15/17 15:16 BWR TAL SAVTotal/NA
ICPEInstrument ID:
Prep 200 506063 12/12/17 11:42 AJR TAL SAVDissolved 50 mL 50 mL
Analysis 200.8 1 506216 12/12/17 20:06 BJB TAL SAVDissolved
ICPMSDInstrument ID:
Prep 245.1 505603 12/08/17 09:29 NVF TAL SAVTotal/NA 50 mL 50 mL
Analysis 245.1 1 505859 12/08/17 16:03 NVF TAL SAVTotal/NA
LEEMAN2Instrument ID:
Analysis SM 2540C 1 505965 12/11/17 16:17 JEC TAL SAVTotal/NA 50 mL 100 mL
NOEQUIPInstrument ID:
Client Sample ID: MW-8 Lab Sample ID: 680-146495-2Matrix: WaterDate Collected: 12/04/17 14:10
Date Received: 12/07/17 09:15
Prep 200.7-1994 R4.4 BCB12/11/17 10:41 TAL SAV505870
Type
Batch
Method
Batch
Prep Type LabAnalystRun
Prepared
or Analyzed
Initial
Amount Amount
Final Batch
NumberFactor
Dil
Total/NA 50 mL 50 mL
Analysis 200.7 Rev 4.4 1 506043 12/12/17 07:46 BWR TAL SAVTotal/NA
ICPEInstrument ID:
Prep 200.7-1994 R4.4 505870 12/11/17 10:41 BCB TAL SAVTotal/NA 50 mL 50 mL
Analysis 200.7 Rev 4.4 1 506685 12/15/17 15:42 BWR TAL SAVTotal/NA
ICPEInstrument ID:
Prep 200 506063 12/12/17 11:42 AJR TAL SAVDissolved 50 mL 50 mL
Analysis 200.8 1 506216 12/12/17 20:10 BJB TAL SAVDissolved
ICPMSDInstrument ID:
Prep 245.1 505613 12/08/17 09:55 NVF TAL SAVTotal/NA 50 mL 50 mL
Analysis 245.1 1 506039 12/11/17 23:24 NVF TAL SAVTotal/NA
LEEMAN2Instrument ID:
Analysis SM 2540C 1 505965 12/11/17 16:17 JEC TAL SAVTotal/NA 50 mL 100 mL
NOEQUIPInstrument ID:
Client Sample ID: MW-10 Lab Sample ID: 680-146495-3Matrix: WaterDate Collected: 12/04/17 16:00
Date Received: 12/07/17 09:15
Prep 200.7-1994 R4.4 BCB12/11/17 10:41 TAL SAV505870
Type
Batch
Method
Batch
Prep Type LabAnalystRun
Prepared
or Analyzed
Initial
Amount Amount
Final Batch
NumberFactor
Dil
Total/NA 50 mL 50 mL
Analysis 200.7 Rev 4.4 1 506043 12/12/17 07:51 BWR TAL SAVTotal/NA
ICPEInstrument ID:
Prep 200.7-1994 R4.4 505870 12/11/17 10:41 BCB TAL SAVTotal/NA 50 mL 50 mL
TestAmerica Savannah
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Lab ChronicleClient: GFA International Inc TestAmerica Job ID: 680-146495-1Project/Site: South Street Site
Client Sample ID: MW-10 Lab Sample ID: 680-146495-3Matrix: WaterDate Collected: 12/04/17 16:00
Date Received: 12/07/17 09:15
Analysis 200.7 Rev 4.4 BWR12/15/17 15:571 TAL SAV506685
Type
Batch
Method
Batch
Prep Type LabAnalystRun
Prepared
or Analyzed
Initial
Amount Amount
Final Batch
NumberFactor
Dil
Total/NA
ICPEInstrument ID:
Prep 200 506063 12/12/17 11:42 AJR TAL SAVDissolved 50 mL 50 mL
Analysis 200.8 1 506216 12/12/17 20:03 BJB TAL SAVDissolved
ICPMSDInstrument ID:
Prep 245.1 505603 12/08/17 09:29 NVF TAL SAVTotal/NA 50 mL 50 mL
Analysis 245.1 1 505859 12/08/17 15:26 NVF TAL SAVTotal/NA
LEEMAN2Instrument ID:
Analysis SM 2540C 1 505965 12/11/17 16:17 JEC TAL SAVTotal/NA 50 mL 100 mL
NOEQUIPInstrument ID:
Client Sample ID: MW-1R Lab Sample ID: 680-146495-4Matrix: WaterDate Collected: 12/04/17 17:09
Date Received: 12/07/17 09:15
Prep 200 BJB12/11/17 15:07 TAL SAV505946
Type
Batch
Method
Batch
Prep Type LabAnalystRun
Prepared
or Analyzed
Initial
Amount Amount
Final Batch
NumberFactor
Dil
Total/NA 50 mL 50 mL
Analysis 200.7 Rev 4.4 1 506233 12/12/17 21:51 BWR TAL SAVTotal/NA
ICPEInstrument ID:
Prep 200 506063 12/12/17 11:42 AJR TAL SAVDissolved 50 mL 50 mL
Analysis 200.8 1 506216 12/12/17 20:28 BJB TAL SAVDissolved
ICPMSDInstrument ID:
Prep 200 505943 12/11/17 15:07 BJB TAL SAVTotal/NA 50 mL 50 mL
Analysis 200.8 1 506216 12/12/17 16:29 BJB TAL SAVTotal/NA
ICPMSDInstrument ID:
Analysis SM 2540C 1 505965 12/11/17 16:17 JEC TAL SAVTotal/NA 50 mL 100 mL
NOEQUIPInstrument ID:
Laboratory References:
TAL SAV = TestAmerica Savannah, 5102 LaRoche Avenue, Savannah, GA 31404, TEL (912)354-7858
TestAmerica Savannah
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Accreditation/Certification SummaryClient: GFA International Inc TestAmerica Job ID: 680-146495-1Project/Site: South Street Site
Laboratory: TestAmerica SavannahThe accreditations/certifications listed below are applicable to this report.
Authority Program EPA Region Identification Number Expiration Date
Florida E870524NELAP 06-30-18
Laboratory: TestAmerica TampaThe accreditations/certifications listed below are applicable to this report.
Authority Program EPA Region Identification Number Expiration Date
Florida E842824NELAP 06-30-18
TestAmerica Savannah
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Method SummaryTestAmerica Job ID: 680-146495-1Client: GFA International Inc
Project/Site: South Street Site
Method Method Description LaboratoryProtocol
40CFR136A200.7 Rev 4.4 Metals (ICP) TAL SAV
EPA200.8 Metals (ICP/MS) TAL SAV
EPA200.8 ICPMS Dissolved Metals by 200.8 TAL SAV
EPA245.1 Mercury (CVAA) TAL SAV
SMSM 2540C Solids, Total Dissolved (TDS) TAL SAV
Protocol References:
40CFR136A = "Methods for Organic Chemical Analysis of Municipal Industrial Wastewater", 40CFR, Part 136, Appendix A, October 26, 1984 and
subsequent revisions.EPA = US Environmental Protection Agency
SM = "Standard Methods For The Examination Of Water And Wastewater",
Laboratory References:
TAL SAV = TestAmerica Savannah, 5102 LaRoche Avenue, Savannah, GA 31404, TEL (912)354-7858
TestAmerica Savannah
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Login Sample Receipt Checklist
Client: GFA International Inc Job Number: 680-146495-1
Login Number: 146495
Question Answer Comment
Creator: Edwards, Jessica R
List Source: TestAmerica Savannah
List Number: 1
N/ARadioactivity wasn't checked or is </= background as measured by a survey meter.
TrueThe cooler's custody seal, if present, is intact.
TrueSample custody seals, if present, are intact.
TrueThe cooler or samples do not appear to have been compromised or tampered with.
TrueSamples were received on ice.
TrueCooler Temperature is acceptable.
TrueCooler Temperature is recorded.
TrueCOC is present.
TrueCOC is filled out in ink and legible.
TrueCOC is filled out with all pertinent information.
TrueIs the Field Sampler's name present on COC?
TrueThere are no discrepancies between the containers received and the COC.
TrueSamples are received within Holding Time (excluding tests with immediate HTs)
TrueSample containers have legible labels.
TrueContainers are not broken or leaking.
TrueSample collection date/times are provided.
TrueAppropriate sample containers are used.
TrueSample bottles are completely filled.
N/ASample Preservation Verified.
TrueThere is sufficient vol. for all requested analyses, incl. any requested MS/MSDs
N/AContainers requiring zero headspace have no headspace or bubble is <6mm (1/4").
TrueMultiphasic samples are not present.
TrueSamples do not require splitting or compositing.
N/AResidual Chlorine Checked.
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