antec 2003 - willkommen — verbundzentrale des gbv · f. tofan, lavergne group t23—polymer...

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Investigation of the Processing Characteristics and Mechanical Properties of Metallocene Catalysed Polyethylene Foams for Rotational Moulding 1199 E.V. Archer, E.M. Harkin-Jones, The Queen's University Belfast A-M. Fatnes, Borealis AS The Effect of Coupling Agents on Foaming with Polymer Microspheres in Rotational Molding 1205 D. D'Agostino, E. Takacs, J. Vlachopoulos, McMaster University Manufacturability of Fine-Celled Cellular Structures in Rotational Foam Molding 1210 R. Pop-Iliev, D. Xu, C.B. Park, University of Toronto M33—Process Technology in Rotational Molding Oil Heating and Cooling Machines for the Rotational Moulding of Plastics 1216 R.J. Crawford, Queen's University Belfast M.J. Wright, Dundalk Institute of Technology The Effect of Direct Electrical Heating on the Cycle Time and Mechanical Properties of Rotationally Molded Polyethylene Parts 1222 M.P. Kearns, C. Daly, R.J. Crawford, Queen's University Belfast The Effect of Cooling Rate on Rotationally Molded Parts 1226 G. McDowell, E.M. Harkin-Jones, R.J. Crawford, W. McMinn, Queen's University Belfast M.C. Cramez, University ofMinho The Effect of Thermal Relaxations on the Crack Initiation Resistance of Rotomolded Linear Low Density Polyethylenes 1231 L.T. Pick, E.M. Harkin-Jones, Queen's University Belfast Rotational Molding of Micropelletized Polypropylene-Based Copolymers 1236 S.K. Baczek, Pennsylvania College of Technology M.E. Starsinic, Rotational Molding Center of Excellence Rotational Molding Process Control 1241 A. Spence, R. Scott, Centro Inc. Optimization of a Rotationally Molded Pressure Vessel 1246 M. McElhaney, N. Carroll, Penn State Erie, the Behrend College T13—Material Formulation and Properties Performance of a Rotationally Molded Thermotropic Liquid Crystalline Polymer 1252 E. Scribben, D.G. Baird, Virginia Tech Rotomoldability of Cyclic Polybutyleneterephthalate 1257 R.S. Al-Zubi, P. Larson, Poly Processing Company Y-F. Wang, Cyclics Corporation Metallocene Based Polyolefins for Rotational Molding Applications 1262 E. Maziers, ATOFINA RESEARCH Effects of Particle Morphology on the Processability of Ethylene Copolymers for Rotational Molding Applications 1267 C.T. Bellehumeur, W. Lin, University of Calgary M. Weber, NOVA Chemicals Corporation Particle Size Distributions in Rotomolded Parts 1272 B.A. Graham, ExxonMobil Chemical Canada Plasma Modified Polyolefin Powders for Rotational Molding 1278 D.E. Boersch, Rota Consult GmbH D. Knoth, D. Pfitzmann, ARPLAS Gesellschaft fur Plasmatechnologie mbH ELECTRICAL & ELECTRONIC DIVISION M23—Electrical and Electronic Electrical Conductivity of Composite Nanoflbers of Polypropylene/Carbon Nanofiber and Nanotubes 1284 R. Pipes, A. Guha, University of Akron Fill Pattern of Underfill and Particle Distribution 1289 Y. Huang, D. Bigio, M. Pecht, University of Maryland Low Shear In-Mould Decoration-Processes for the Manufacture of Three-Dimensional Moulded Interconnect Devices (3D-MID) 1294 R. Dorfler, G.W. Ehrenstein, University of Erlangen-Nuremberg xx / ANTEC 2003

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Page 1: ANTEC 2003 - Willkommen — Verbundzentrale des GBV · F. Tofan, Lavergne Group T23—Polymer Blends: Characterization and Performance

Investigation of the Processing Characteristics and Mechanical Properties of Metallocene CatalysedPolyethylene Foams for Rotational Moulding 1199

E.V. Archer, E.M. Harkin-Jones, The Queen's University BelfastA-M. Fatnes, Borealis ASThe Effect of Coupling Agents on Foaming with Polymer Microspheres in Rotational Molding 1205D. D'Agostino, E. Takacs, J. Vlachopoulos, McMaster UniversityManufacturability of Fine-Celled Cellular Structures in Rotational Foam Molding 1210R. Pop-Iliev, D. Xu, C.B. Park, University of Toronto

M33—Process Technology in Rotational Molding

Oil Heating and Cooling Machines for the Rotational Moulding of Plastics 1216R.J. Crawford, Queen's University BelfastM.J. Wright, Dundalk Institute of TechnologyThe Effect of Direct Electrical Heating on the Cycle Time and Mechanical Properties of Rotationally

Molded Polyethylene Parts 1222M.P. Kearns, C. Daly, R.J. Crawford, Queen's University BelfastThe Effect of Cooling Rate on Rotationally Molded Parts 1226G. McDowell, E.M. Harkin-Jones, R.J. Crawford, W. McMinn, Queen's University BelfastM.C. Cramez, University ofMinhoThe Effect of Thermal Relaxations on the Crack Initiation Resistance of Rotomolded Linear Low

Density Polyethylenes 1231L.T. Pick, E.M. Harkin-Jones, Queen's University BelfastRotational Molding of Micropelletized Polypropylene-Based Copolymers 1236S.K. Baczek, Pennsylvania College of TechnologyM.E. Starsinic, Rotational Molding Center of ExcellenceRotational Molding Process Control 1241A. Spence, R. Scott, Centro Inc.Optimization of a Rotationally Molded Pressure Vessel 1246M. McElhaney, N. Carroll, Penn State Erie, the Behrend College

T13—Material Formulation and Properties

Performance of a Rotationally Molded Thermotropic Liquid Crystalline Polymer 1252E. Scribben, D.G. Baird, Virginia TechRotomoldability of Cyclic Polybutyleneterephthalate 1257R.S. Al-Zubi, P. Larson, Poly Processing CompanyY-F. Wang, Cyclics CorporationMetallocene Based Polyolefins for Rotational Molding Applications 1262E. Maziers, ATOFINA RESEARCHEffects of Particle Morphology on the Processability of Ethylene Copolymers for Rotational Molding

Applications 1267C.T. Bellehumeur, W. Lin, University of CalgaryM. Weber, NOVA Chemicals CorporationParticle Size Distributions in Rotomolded Parts 1272B.A. Graham, ExxonMobil Chemical CanadaPlasma Modified Polyolefin Powders for Rotational Molding 1278D.E. Boersch, Rota Consult GmbHD. Knoth, D. Pfitzmann, ARPLAS Gesellschaft fur Plasmatechnologie mbH

ELECTRICAL & ELECTRONIC DIVISION

M23—Electrical and Electronic

Electrical Conductivity of Composite Nanoflbers of Polypropylene/Carbon Nanofiber and Nanotubes 1284R. Pipes, A. Guha, University of AkronFill Pattern of Underfill and Particle Distribution 1289Y. Huang, D. Bigio, M. Pecht, University of MarylandLow Shear In-Mould Decoration-Processes for the Manufacture of Three-Dimensional Moulded

Interconnect Devices (3D-MID) 1294R. Dorfler, G.W. Ehrenstein, University of Erlangen-Nuremberg

xx / ANTEC 2003

Page 2: ANTEC 2003 - Willkommen — Verbundzentrale des GBV · F. Tofan, Lavergne Group T23—Polymer Blends: Characterization and Performance

Control of Directional Electrical Conductivities in Carbon Black-Thermoplastic Extrusions Producedby Chaotic Advection 1299

D.A. Zumbrunnen, V. Chougule, Clemson UniversityNondestructive Characterization of Orientation in Thick Cast and Drawn Poh aniline Films 1304R. Samuels, R. Ou, Georgia Institute of Technology

T4—Electrical and Electronic

Three-Dimensional Simulation of Wire Sweep During Semiconductor-Chip Encapsulation 1310S. Han, MoldflowCorporationF.S. Costa, S.R. Ray, Moldflow Pty LtdImproving Gel Compatibility of Polyolefinic Polymers for Loose Buffer Tubes in Fiber Optic Cables 1315K.P. Pang, G.D. Brown, S.H. Wasserman, The Dow Chemical CompanyInvestigation of Packaging Properties as a Function of Filler Microstructure 1320Y. Huang, D. Bigio, M. Pecht, University of MarylandInteractions Between Reactive Impact Modifiers and Carbon Black in Copolyesters 1325D.S. McWilliams, Eastman Chemical CompanyConductive Polymer Blends for Injection-Molded Bipolar Plates 1330M.A. Huneault, F. Mighri, M.F. Champagne, National Research Council CanadaExperimental Study for Underfill of Flip Chip Packages 1335W-R. Jong, S. Chen, C. Lai, H. Tsai, H. Liu, Chung Yuan Christian UniversityS. Ho, W-Y. Lo, Ta Hwa Institute of Technology

ENGINEERING PROPERTIES AND STRUCTURE DIVISION

M7—Polypropylene Nanocomposites

Characterization of Structural Changes in Polypropylene Nanocomposites by Infrared Thermal WaveImaging 1342

A. Hernandez-Luna, N.A. D'Souza, University of North TexasThe Effect of Nanoclay on the Deformation Behavior of Polypropylene and PPGMA Blends Using

Online Birefringence Measurement System 1347J.H. Fujiyama, University of AkronM. Cakmak, The University of AkronNano-Composites Via Solid-State Modification for Toughening in Semi-Crystalline Polymers 1352S.H. Jain, F. Picchioni, H. Goossens, Dutch Polymer Institute/Technical University EindhovenM.V. Duin, DSMResearchPolypropylene/Clay Nanocomposites: Characterization and Interpretation of Structure - Property

Relationships 1357A. Vaxman, G. Lidor, R. Shalom, Carmel OlefinsM. Narkis, A. Siegmann, A. Tzur, Technion - Israel Institute of TechnologyNovel Nanostructured Polymer Blends with Enhanced Benefits 1362J. Teng, Iowa State UniversityJ.U. Otaigbe, E.P. Taylor, University of Southern MississippiPBT and PET Ionomer Based Clay Nanocomposites 1369G. Barber, S. Bellman, R.B. Moore, The University of Southern Mississippi

M8—Polyolefins: Structure/Properties of Polyolefin Films

Effect of Crystalline Structure on Tear Resistance of LDPE and LLDPE Blown Films 1376X. Zhang, S. Elkoun, A.Ajji, M.A. Huneault, Industrial Materials Institute, National Research Council CanadaEffect of Processing Parameters on Properties of LLDPE-Based Mono- and Multilayered Blown Films 1381S. Elkoun, M.A. Huneault, National Research Council CanadaK. McCormick, F. Puterbaugh, L. Kale, NOVA Chemicals, CorporationA Predictive Model for Dart Impact Strengths of Solution Octene LLDPE Film Resins 1386X. Wang, S. Marshall, L. Kale, NOVA Chemicals CorporationControl of Blown Film Tear Strength Anisotropy Through Blending of LDPE and LLDPE 1391X. Zhang, A.Ajji, M.A. Huneault, Industrial Materials Institute, National Research Council CanadaLLDPE Blown Film Property Enhancement Through Coextrusion 1396S. Elkoun, M.A. Huneault, X.M. Zhang National Research Council CanadaK. McCormick, F. Puterbaugh, L. Kale, NOVA Chemicals Corporation

ANTEC 2003 /xxi

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Orientation and Property Correlation on LLDPE Blown Films 1401H. Chen, C. Chau, T. Butler, B. Landes, M. Bishop, D. Bellmore, S. Chum, C. Dryzga, The Dow Chemical Company

M25—Polymer Nanocomposites

Enhancement of Poly (L-Lactide) Properties Through Nanocomposite Formation 1408B.H. Calhoun, R.B. Moore, J. Swanson, G. Behringer, The University of Southern MississippiIsothermal Crystallization Kinetics of Polyamide-6, Polyamide-66 and Their Nanocomposites 1413M.R. Kamal, N.K. Borse, S. Hasni, McGill UniversityMechanisms of Clay Exfoliation in a Polymer Matrix During an Extrusion Process: A Structure-

Property Relationship 1418C.Y. Lew, R. Murphy, G. McNally, Queen's University BelfastK. Abe, CO-OP Chemical Co. Ltd.S. Yanai, G.P. Brennan, UNICOOP JapanA Study on Intercalation and Exfoliation of Layered Silicate Nanoparticles in Thermoplastic

Polyurethanes 1424S.C. Jana, A. Pattanayak, University of AkronIntroducing a New Miniature Mixer For Specialty Polymer Blends And Nanoscale Composites 1429O. Breuer, U. Sundararaj, R.W. Toogood, University of AlbertaPreparation and Mechanical Property of Synthetic Zirconium Phosphate-Epoxy Nanocomposites 1434K. Gam, N. Bestaoui, N. Spurr, A. Clearfield, H-J. Sue, Texas A&M UniversityMechanism of Exfoliation of Nanoclay Particles in Epoxy-Clay Nanocomposites 1438J.H. Park, S.C. Jana, University of AkronEpoxy-Aided Dispersion of Nanoclay in PMMA 1443J.H. Park, S.C. Jana, University of AkronEnhanced Failure Properties in Layered Silicate Nanocomposites Formed by Melt Processing

I. Polyoxymethylene as a Model Matrix Material 1448P.T. Nagaraj, The Univeristy of AkronL. Goettler, University of Akron

M26—Polyolefins II: Structure/Properties of Polyolefins

Properties and Structure of LLDPE/HDPE 3-Layer Coextruded Blown Films with Blended MiddleLayers 1454

S. Elkoun, M.A. Huneault, National Research Council CanadaBiaxial Orientation in Polyethylene Films: Comparison of Infrared Spectroscopy and X-Ray

Techniques 1459A. Ajji, X. Zhang, S. Elkoun, Industrial Materials InstituteEffect of Extrusion Die Geometry on Molecular Orientation of Unfilled Polyethylene 1464E. Brown, A. Kelly, P. Coates, University of BradfordPermeability and Mechanical Performance of 3-Layer EVOH/LLDPE Barrier Films with Blended

Middle-Layers 1469S. Elkoun, M.A. Huneault, National Research Council CanadaThe Mechanical Properties And Crystallization Behaviour of Pigmented Propylene-Ethylene Random

Copolymer 1474I.F. Major, Polymer Processing Research CentreG. McNally, Queen's University BelfastStructure and Properties of the p" Nucleated Injection Molded Polypropylenes: Time Stability of the

P Phase and Impact Strength 1479M. Obadal, R. Cermak, K. Stoklasa, M. Petruchova, Tomas Bata UniversityMorphology and Mechanical Property Relationship in Polypropylene Composites 1484J. Weon, J. Lu, H-J. Sue, Texas A&M UniversityR. Davis, R. Clark, Luzenac AmericaC-M. Chan, J. Wu, Hong Kong University of Science and TechnologyImpact Modification of Calcium Carbonate Filled Polypropylene 1489S. D'uva, J.Z. Charlton, Ingenia PolymersSurface Grafting of Polyacrylamide from Polyethylene-Based Copolymer Film 1494N. Luo, S.M. Husson, D.E. Hirt, Clemson UniversityD.W. Schwark, Cryovac Division of Sealed Air Corporation

xxii / ANTEC 2003

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T5—Polymer Blends: Characterization and Performance

Viscoelastic Properties of Homogeneous Block Copolymer/Homopolymer Blends Near Microphase andMacrophase Separation Transitions 1500

C-Y. Huang, New Jersey Institute of TechnologyEffect of Reactive Additives on the Properties of Polypropylene/Unsaturated Polyester Blends 1503C. Wan, M. Xanthos, Polymer Processing InstituteMorphology Development in PA6/PP System by Chaotic Mixing: Effect of Viscosity Ratio and

Composition 1508M. Sau, S.C. Jana, University of AkronIn-Situ Compatibilization of PP/EPDM Blends During Ultrasound Aided Extrusion 1513W. Feng, A.I. Isayev, The University of AkronEffect of High Intensity Ultrasonic Waves on Polypropylene, Polyamide 6 and Their Blends 1518A.I. Isayev, H. Lin, The University of AkronMechanical Properties and Morphology of Ternary PP/EPDM/PE Blends 1523K. Tchomakov, B.D. Favis, Ecole Polytechnique de MontrealM.A. Huneault, M.F. Champagne, National Research Council CanadaF. Tofan, Lavergne Group

T23—Polymer Blends: Characterization and Performance

Mechanical Properties and Internal Structure of Injection Molded Glass Fiber Reinforced PC/ABS 1530S. Takashima, M. MMizoguchi, U.S. Ishiaku, H. Hamada, Kyoto Institute of TechnologyH. Hiroyuki, Graduate School, Kyoto Institute of TechnologyS. Otsuki, Y. Bin, T. Kuriyama, Yamagata UniversityRelationship Between Mechanical Properties and Internal Structure of PC/ABS Blend Injection

Moldings through Thickness Direction 1535S. Takashima, M. Machiko, Kyoto Institute of TechnologyH. Hiroyuki, Graduate School, Kyoto Institute of TechnologyS. Otuki, Yamagata UniversityT. Kuriyama, Dept. of polymer science&engineering, Yamagata univ.Influence of Ionomeric Compatibilizers on the Morphology and Properties of Amorphous

Polyester/Polyamide Blends 1540G.C. Gemeinhardt, A.A. Moore, R.B. Moore, The University of Southern MississippiThe Effectiveness of SPETG as a Compatibilizer for PC/PETG Blends 1545P.L. Hopson, R.B. Moore, The University of Southern MississippiLow Temperature Impact Resistant Coextruded Polypropylene Composite 1550S.K. Dey, V. Tan, D. Conti, Polymer Processing InstituteA Study on the Effects of Chaotic Mixer Design and Operating Conditions on the Development of

Morphology in Immiscible Polymer Systems 1556M. Sau, S.C. Jana, University of AkronThermal and Rheological Properties of Novel Thermoplastic Polyimide Blends 1561V.E. Yudin, J.U. Otaigbe, University of Southern MississippiV.M. Svetlichnyi, Inst. of Macromolecular CompoundsJ. Teng, Iowa State UniversityStructure and Properties of New Polyimide Bonded Magnets with Enhanced Benefits 1567V.E. Yudin, J.U. Otaigbe, University of Southern MississippiV.M. Svetlichnyi, Inst. of Macromolecular CompoundsT.X. Bui, The Magnetics Technology CenterCompatibilization of Poly(Phenylene Ether) and Polyamide-6 Blends by Functionalized Polystyrenes 1572H. Chin, Ciba Specialty Chemicals Corporation

W4—Novel Characterization Techniques for Determining Structure Property

Study on Adhesion to Metal Film by Measurement of Energy Release Rate in Skin Region of InjectionMolded Substrate 1578

K. Higashi, N. Ikegawa, M. Sato, Matsushita Electric Works, Ltd.H. Hamada, Kyoto Institute of Technology

ANTEC 2003 /xxiii

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A New Instrument to Monitor the True Stress-True Strain-Birefringence Behavior During MultiaxialDeformation and Annealing of PET Films 1583

M. Hassan, M. Cakmak, The University of AkronUniaxial Stretching of PLA Using Fully Automated On-Line Birefringence Coupled with True Stress -

True Strain Measurement - Part I: Stretching Rate Effects 1588J. Mulligan, M. Cakmak, University of AkronUniaxial Extension of PLA Using Fully Automated On-Line Birefringence Coupled With True Stress -

True Strain Measurement - Part II: Temperature Effects 1593J. Mulligan, M. Cakmak, University of AkronDrop Retraction Methods to Measure Interfacial Tension between Compatibilized Polymers 1597S. Velankar, University of PittsburghH. Zhou, H-K. Jeon, C.W. Macosko, University of MinnesotaA Technique for Absolute Biaxial Birefringence Measurements and Its Applications 1603A. Ajji, Industrial Materials Institute

W5—Recent Advances in Polymer Structure, Properties and Morphology

Processing of Intractable Polymers Using High-Pressure Carbon Dioxide 1610M. Garcia-Leiner, A.J. Lesser, University of Massachusetts at AmherstPrediction of the Melting Temperature of Polymers 1615M.R. Kamal, L. Feng, T. Huang, McGill UniversityStructural Recovery in a Model Epoxy after Rapid Relative Humidity Changes 1620Y. Zheng, G.B. McKenna, Texas Tech UniversityThe Effect of Shear-Induced Migration of Conductive Fillers on Conductivity of Injection Molded

Articles 1625C. Hong, J. Kim, S.C. Jana, University of AkronUV Degradation of Recycled Photo-Degraded Polymers 1630I.H. Craig, E. Loyd, W. Stevenson, J.R. White, University of Newcastle upon TynePolymer/Clay Nanocomposite Foams Prepared by CO2 1635C. Zeng, Y. Yang, X. Han, L.J. Lee, D.L. Tomasko, The Ohio State University

W12—Nanocomposites I

•Effectiveness of PPMA Compatibilizers for Nanolayer Dispersion in PP: Bound vs Free Anhydride 2200D. Marchant, K. Jayaraman, Michigan State University*Role of Nanoparticles on Crystalline Orientation in Polypropylene/Clay Nanocomposite Films 2205C.G. Woods, J.D. Muzzy, Georgia Institute of Technology*Modeling Cell Nucleation During Microcellular Injection Molding 2210J.P. Hernandez, A. Chandra, A. Winardi, T.A. Osswald, University of Wisconsin - MadisonL-S.T. Turng, University of Wisconsin-MadisonP. Gramann, The Madison Group*Electrically Activated Polypropylene/Clay Nanocomposites 2215D. Kim, J. Park, K. Ahn, S. Lee, Seoul national university*Application of Image Processing Technique in Analyzing Microstructure of Nanocomposites 2219W. Chuan-Yang, X. Zhi-Min, H. Han-Xiong, South China University of Technology*Effect of Mixing Element in a Single Screw Extruder on the Microstructure of

Polypropylene/Montmorillonite Nanocomposites 2223H. Han-Xiong, W. Chuan-Yang, H. You-Fa, J. Guo, Z. Yong-Hua, South China University of Technology

W24—Recent Advances in Polymer Structure, Properties and Morphology

Copolycarbonate of Bisphenol A and 4,4'-Dihydroxydiphenyl 1642J.Y. Chung, J.P. Mason, Bayer CorporationM. Moethrath, M. Erkelenz, Bayer AGMechanochemical Devulcanisation of Unfilled SBR Vulcanizates 1648S. Sangari, N. Kao, S. Bhattacharya, RMTT UniversityK. Silva, Rapid PacificAnionic Copolymerization of Lauryl Lactam and Polycaprolactone to Produce Polyesteramide Tri-

Block Copolymer 1653I. Kim, J.L. White, University of Akron

XXIV / ANTEC 2003 * p r e s e n t in a joint session.

Page 6: ANTEC 2003 - Willkommen — Verbundzentrale des GBV · F. Tofan, Lavergne Group T23—Polymer Blends: Characterization and Performance

Relationship between Structure and Properties of PBT Injection Moldings in the ThicknessDirection 1658

M. Shibaya, N. Ohkubo, H. Ishihara, Kyoto Institute of TechnologyK. Yamashita, N. Yoshihara, C. Nonomura, TOYOBO Co., Ltd.Morphological and Mechanical Evaluation of Hybrid Organic/Inorganic Thermoset Copolymers of

Dicyclopentadiene and Polyhedral Oligomeric Silsesquioxanes 1663G. Constable, A.J. Lesser, E. Coughlin, University of MassachusettsCharacterization of Polymer Resins Produced by Melt Disentanglement 1668J. Ibar, EKNETResearch CorpS. Morneau, SPRLIntroduction of a Novel Exterior PET-Bottle Plasma Coating System 1675E. Schmachtenberg, S. Gobel, R. Dahlmann, Institutfiir Kunststoffverarbeitung (IKV)The Effect of Surface Tension and Contact Angle on the Filling Behavior of Flip-Chip Underfill

Dispensing Process 1680Y-Y. Wang, H-C. Tseng, R-Y. Chang, National TsingHua UniversityEffects of Spinning and Process Conditions on Appearance and Diameter of Electrospun Polyamide-6

Nanofibers 1685C. Mit-uppatham, P. Supaphol, M. Nithitanakul, Chulalongkorn University

W25—Polymer Structure and Properties Under Deformation

Structure Development During Uniaxial Deformation of PEN Using Real Time Spectral BirefringenceTechnique 1692

C. Martins, M. Cakmak, University of AkronEffect of Rolling Process on the Uniformity of Extended PTFE 1697R.L. Huang, S.C. Chen, J. Huang, Chung Yuan Christian UniversityC. Chuo, W. Kuo, Feng Chia UniversityX-Ray Studies of Structural Development During Sequential and Simultaneous Biaxial Stretching of

Polylactic Acid Film 1701X. Ou, M. Cakmak, University of AkronEffects of Morphology on the Tribological Behavior of Thermoplastics in Sliding Contact 1706R. Kunkel, G.W. Ehrenstein, University of Erlangen-NurembergDetermination of the Deformation of Thermoplastics Under Unidirectional Compressive Load 1711E. Schmachtenberg, T. Krumpholz, Institutfiir Kunststoffverarbeitung (IKV)Plastics Part Design: Low Cycle Fatigue Strength of Glass-Fiber Reinforced Polyethylene

Terephthalate (PET) 1716I. Palley, N. Jia, Honeywell InternationalV. A. Kagan, Honeywell Plastics

W31—Nanocomposites II

*A Carbon Nanotube Alternative: Graphite Nanoplatelets as Reinforcements for Polymers 2230L.T. Drzal, H. Fukushima, Michigan State University*Carbon Nanotube Nucleation of Polypropylene Crystals 2235B.P. Grady, D. Resasco, F. Pompeo, R. Shambaugh, University of Oklahoma*Effect of Organoclay Structure on the Rheology and Crystallization Behavior of In-Situ Polymerized,

PA-6 Nanocomposites 2240K. Akkapeddi, J. Facinelli, D. Worley, Honeywell International*Polyol Modified Epoxy-Montmorillonite Nanocomposites 2245I. Isik, U. Yilmazer, G. Bayram, Middle East Technical University*Synthesise and Characterization of Hierarchical Structure in Supercritical CO2-Fabricated

Composites 2250T.C. Caskey, University of MassachusettsA.J. Lesser, University of Massachusetts*Effect of Mixer Type on Exfoliation of Polypropylene Nanocomposites 2255M.K. Dolgovskij, F. Lortie, C.W. Macosko, University of MinnesotaP.D. Fasulo, R.A. Ottaviani, W.R. Rodgers, General Motors*Synthesis and Characterization of High Density Polyethlene Clay Nanocomposites 2260M.R. Kamal, M. Mehrabzadeh, McGill University

* Resent in a joint session. ANTEC 2003 / XXV

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THERMOPLASTIC MATERIALS AND FOAMS DIVISION

M27—Thermoplastic Foams Applications Part II

Production of Thick Microcellular Thermoplastic Sheets 1722V. Kumar, K. Nadella, W. Li, University of WashingtonFundamental Study of Thermoplastic Foam Structure and Properties 1727S. Lee, M. Kolli, Sealed Air Corp.Extrusion of Polystyrene Foams Reinforced with Nano-Clays 1732X. Han, C. Zeng, K.W. Koelling, D.L. Tomasko, L.J. Lee, The Ohio State UniversityA Comparison of the Effect of GMS in LDPE and PP Foams 1737J. Zhao, M.B. Standlee, M.H. Tusim, Dow Chemical CompanyFracture Toughness and Impact Resistance of Syntactic Foam 1742E. Wouterson, F. Boey, X. Hu, Nanyang Technological UniversityS-C. Wong, North Dakota State UniversityEffect of Physical Foaming Agents on the Viscosity of Various Polyolefin Resins 1747R. Gendron,M.F. Champagne, Industrial Materials Institute, National Research Council CanadaA Study of Strain-Induced Nucleation in Thermoplastic Foam Extrusion 1752J. Tatibouet, R. Gendron, Industrial Materials Institute, National Research Council CanadaFoam Expansion of Styrene-Acrylic Acid Copolymers Using Baking Soda 1757C.P. Park, C. ParkCell Morphology and Impact Strength of Microcellular Foamed HDPE/PP Blends 1762P. Rachtanapun, L.M. Matuana, S.E. Selke, Michigan State University

T7—Polymerization Catalysis and Application of New Polymers

Material Classification and Applications of New Propylene-Ethylene Copolymers 1768K.W. Swogger, P. Ansems, S. Chum, The Dow Chemical CompanyB. Poon, C.H. Stephens, A. Hiltner, E. Baer, Case Western Reserve UniversitySolid State Properties of New Propylene-Ethylene (P/E) Copolymers 1775C.H. Stephens, B. Poon, A. Hiltner, E. Baer, Case Western Reserve UniversityS. Chum, P. Ansems, The Dow Chemical CompanyElastomeric Properties of New Propylene-Ethylene Copolymers Under Cyclic Loading 1780A. Hiltner, P.S. Dias, B. Poon, V.M. Ronesi, E. Baer, Case Western Reserve UniversityA. Chang, P. Ansems, The Dow Chemical CompanyEffect of Unsaturated Compounds on Ethylene Polymerization with the Catalyst System

Et(FIu)2ZrCl2/MAO 1785M.D. Marques, G.V. Andrade, Universidade Federal do Rio de JaneiroMetallocene Polyethylenes With Supported Catalyst 1789A.B. Marinha, M.D. Marques, Universidade Federal do Rio de JaneiroA Kinetic Study of the Polymerization of Methyl Methacrylate Under Supercritical Fluid CO2 1794S. Lu, Z. Zhang, A. V. Nawaby, M. Day, National Research Council Canada

T25—Thermoplastic Foams Part III

Mechanical Properties of High Density Polyethylene Foams 1800D. Rodrigue, Y. Zhang, Laval UniversityEffect of TSE Screw Configuration on Dissolution and Melt Sealing of HFC 134a Blowing Agent in

Polystyrene 1806M.A. Huneault, J. Tatibouet, R. Gendron, National Research Council Canada

W7—Thermoplastic Foams Applications Part I

Effect of Montmorillonite on Formation of Polystyrene Foams Using Supecritical CO2 1812W. Strauss, M. Paceley, N.A. D'Souza, A.J. Ranade, R.F. Reidy, University of North TexasEffect of Talc Content on the Volume Expansion Behavior of Extruded PP Foams 1817H.E. Naguib, University of OttawaC.B. Park, P. Lee, D. Xu, University of TorontoN. Reichelt, Borealis GmbHEffects of the Die Geometry on the Expansion Ratio of Polystyrene Foams Blown with Carbon Dioxide 1823X. Xu, C.B. Park, University of Toronto

xxvi / ANTEC 2003

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Lightweight Performance of Load Bearing Plastic Components with an Integral Foam Structure 1830N. Mueller, G.W. Ehrenstein, University of Erlangen-NurembergHigh Temperature Polymeric Microspheres and Foams: Liquid Phase Models 1835C.I. Cano, R. Pipes, University of AkronE. Weiser, NASA Langley Research Center

W27—Engineering Plastics: Applications of Polyetherimide and Other Resins

Glass Filled Polycarbonate Ester-Polyetherimide Blends 1842N. Gunduz, R.R. Gallucci, General Electric PlasticsInjection Molding of Polyetherimide Using Water Cooled Molds 1847G.F. Bixby, M.A. Sanner, General Electric PlasticsNew High Heat Polyetherimide Resins 1853R.R. Gallucci, R.R. Odle, General Electric PlasticsMold Release Agents for Polyetherimides 1858R.R. Gallucci, M.A. Sanner, General Electric PlasticsHigh Flow Glass Filled Polyetherimide Blends 1863R.R. Gallucci, General Electric PlasticsPolyetherimide Films for High Temperature and Electronic Applications 1868J.J. Scobbo, J. Vervoort, J. Newhart, General Electric PlasticsBranched Polyethylene Terephthalate Foaming using HFC-134a: On-Line Process Monitoring 1870

M.F. Champagne, M.A. Huneault, R. Gendron, National Research Council Canada

POLYMER ANALYSIS DIVISION

M9—Characterization and Analysis of Thermosets

Characterization of Epoxy Curing Using High Heating Rate DSC 1876B. Bilyeu, W. Brostow, K.P. Menard, M. Keselman, University of North TexasModification Mechanisms, Curing Kinetics and Properties of Polymethylphenyl Siloxane-Modified

Epoxy Resins 1881M. Zhang, G.C. Martin, Syracuse UniversityDynamic Mechanical Analysis of UV-curable Coatings While Curing 1886R.W. Johnson, DSMDesotech Inc.Thermal And Mechanical Properties of Epoxy/Monofunctional And Epoxy/Multifunctional POSS

Nanocomposites 1893S. Lu, G.C. Martin, Syracuse UniversityEvaluation of Different Methods of Measurement for the Isotropic Stress Development in Curing

Thermosets 1898M. Merzlyakov, Y. Meng, S.L. Simon, G.B. McKenna, Texas Tech UniversityA Mathematical Model for the Increase of G' with Time During the Irradiation of UV-Curable

Coatings 1903R.W. Johnson, DSM Desotech Inc.

M28—Characterization and Analysis of Optical Electronic Materials

Recent Advances in Organic Semiconductors for Optoelectronic Applications 1910B. Kippelen, The University of ArizonaConjugated Polymers for Controlling Light 1912G.D. Scholes, K.P. Fritz, R.M. Greenwald, University of TorontoDevelopment of a New Class of Nonlinear Optical Polymers with High Electro-Optic Coefficients 1915Z. Wang, N. Song, L. Men, A. Beaudin, C. Weir, J. Gao, Carleton UniversityG. Cross, M. Szablewski, University of DurhamImproving the Luminescent and Electronic Properties of OLED Materials Through Structural

Modification 1919Y. Tao, M. D'lorio, National Research Council of CanadaM. Wong, Z. Li, Hong Kong Baptist University

ANTEC 2003 /xxvii

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M29—Electronic Microscopy on Polymers

Study of Shark Skin and Die Swell of Calcium Filled-Polyethylene by Laser Micrometer and ScanningElectron Microscopy 1926

J. Lou, V. Harinath, J. Sankar, Z. Xu, North Carolina A&TState UniversityA Novel Characterization Method for Investigating the Morphology of Polymer Blends Including

Polyolefin/Polyolefin Blends 1931M. Lee, J-M. Kim, S. Kim, S-Y. Kang, LG Chem Ltd.

T28—Characterization and Analysis of Nanocomposites

Nylon 6 and Montmorillonite Layered Silicate (MLS) Nanocomposites 1938A.J. Ranade, N.A. D'Souza, B. Gnade, University of North TexasA. Dharia, Transmit Technology Group, LLCImproving Impact Properties of Polymer Clay Nanocomposites 1943A. Bhaskar, N. Tortorella, C.L. Beatty, University of FloridaK.A. Narh, New Jersey Institute of TechnologyConducting Molecular Wires: Nanofibers and Nanotubes for Electronics Applications 1948W.E. Jones, H. Dong, F. Ochanda, V. Nyame, State University at BinghamtonStudies on the Nature of the Interactions in SB Rubber and Mesoporous Silica Mixtures 1951B.L. Lopez, M.L. Sierra, N. Castano, L. Perez, Universidad de AntioquiaDiffraction and Thermal Effects in Non-Intercalating & Non-Exfoliating Amorphous PET

Montmorillonite Packaging 1956A.J. Ranade, N.A. D'Souza, B. Gnade, University of North TexasA. Dharia, Transmit Technology Group, LLC

T29—Polymer Analysis a la carte

Thermomechanical Characterization of Blends of Poly(vinyl acetate) with Semicrystalline Polymers forShape Memory Applications 1962

C. Liu, P.T. Mather, University of ConnecticutInfluence of Different Molecular Characteristics of Syndiotactic Polypropylene on Equilibrium Melting

Temperature and Crystallization Behavior 1967P. Thanomkiat, P. Supaphol, Chulalongkorn UniversityR.A. Phillips, Basell USA, Inc.The Influence of the Finite Step Time on the Measurement of the Viscoelastic Response Functions 1971A. Flory, G.B. McKenna, Texas Tech UniversityRapid Method to Assess Effect of Pigments on Photodegradability of Polymers 1976J.R. White, T.A. Egerton, C-Q. Jin, P.A. Christensen, University of Newcastle upon TyneN. MacDonald, Tioxide Europe S.A.S.

W28—Polymer Analysis a la carte

Structural Characterization of Linear Low-Density Polyethylene (LLDPE) Using Thermal Analysis 1982P. Roberts, S. Lee, University of MissouriDepression of Tg in Polystyrene by Freeze-Drying 1987P. Bernazzani, S.L. Simon, Texas Tech UniversityA Study on Modification of PP with Aliphatic Diamines 1992S. Vazquez-Rodriguez, S. Sanchez-Valdes, Centro de lnvestigacion en Quimica AplicadaO. Manero-Brito, Universidad Nacional Autonoma de MexicoThe Characterisation and Physical Testing of Micro-Mouldings 1995P.S. Allan, G.R. Greenway, P.R. Hornsby, Brunei UniversityThe Effect of Melt Temperature and Extrusion Rate on the Die Swell of Metallocene and Conventional

Polyethylenes 2000B.G. Millar, P. Laughlin, G. McNally, R. Murphy, Queen's University BelfastDesign, Fabrication, and Assembly of a Polymer Electrolyte Membrane Fuel Cell (PEMFC) 2005D. Weber, C.C. Ibeh, Pittsburg State University

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Polymer Defect Detection and Classification Utilizing Camera Optics, Real Time Computation andSmall Scale Resin Sample Processing 2010

S. Dominey, Crompton Davis StandardW. Goeckel, Lasor/SystronicsAromatic Hydrocarbon Content of Plastic Packaging Materials 2015M. Ezrin, G. Lavigne, University of ConnecticutMelt Processing of Tailored Acrylic Copolymers 2018J.E. McGrath, D.G. Baird, M.J. Bortner, V. A. Bhanu, Virginia Polytechnic Institute and State University

ENGINEERING PROPERTIES AND STRUCTURE DIVISION

M7—Polypropylene Nanocomposites

"Characterization of Structural Changes in Polypropylene Nanocomposites by Infrared Thermal WaveImaging 1342

A. Hernandez-Luna, N.A. D'Souza, University of North Texas*The Effect of Nanoclay on the Deformation Behavior of Polypropylene and Polypropylene-Grafted-

Maleic Anhydride Blends Using Online Birefringence Measurement System 1347J.H. Fujiyama, M. Cakmak, University of Akron*Nano-composites Via Solid-State Modification for Toughening in Semi-Crystalline Polymers 1352S.H. Jain, F. Picchioni, H. Goossens, Dutch Polymer Institute/Technical University EindhovenM. van Duin, DSM Research*Polypropylene/Clay Nanocomposites: Characterization and Interpretation of Structure - Property

Relationships 1357A. Vaxman, G. Lidor, R. Shalom, Carmel OlefinsM. Narkis, A. Siegmann, A. Tzur, Technion - Israel Institute of Technology*Novel Nanostructured Polymer Blends With Enhanced Benefits 1362J. Teng, Iowa State UniversityJ.U. Otaigbe, E.P. Taylor, The University of Southern Mississippi*PBT and PET Ionomer Based Clay Nanocomposites 1369

G. Barber, S. Bellman, R.B. Moore, The University of Southern Mississippi

COMPOSITES DIVISION

M12—Natural Reinforcements in Composites

Structural BioComposites from Natural Fibers and BioPolymers 2024M. Misra, A.K. Mohanty, L.T. Drzal, Michigan State UniversityThe Effect of Weathering on Wood-Polymer Composites 2029P. Douglas, W.R. Murphy, G. McNally, M. Billham, Queen's University BelfastInjection Molding of a Starch Based Polymer Reinforced with Natural Fibers 2034A.M. Cunha, R. Campos, University ofMinhoR. Beu Cheikh, Ecole Nationale d'Ingenieurs de TunisEffects of CBA on Extrusion Processing of Foamed Plastic/Wood-Flour Composites 2039G.M. Rizvi, C.B. Park, G. Guo, K. Wang, University of TorontoAn On-line Analytical Method for Quality Control for Bio-Fiber Reinforced Composites 2044S. Godavarti, Aspen Research CorporationOptimization of Coupling Agent Characteristics for Maximizing Performance of Wood Fiber

Thermoplastic Composites 2047

S. Godavarti, Aspen Research Corporation

ENGINEERING PROPERTIES AND STRUCTURE DIVISION

M25—Polymer Nanocomposites

'Enhancement of Poly (1-lactide) Properties Through Nanocomposite Formation 1408B.H. Calhoun, R.B. Moore, J. Swanson, G. Behringer, The University of Southern MississippiIsothermal Crystallization Kinetics of Polyamide-6, Polyamide-66 and Their Nanocomposites 1413M.R. Kamal, N.K. Borse, S. Hasni, McGill University

*Present in a joint session- ANTEC 2003 / xxix

. .

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•Mechanisms of Clay Exfoliation in a Polymer Matrix During an Extrusion Process: A Structure-Property Relationship 1418

C.Y. Lew, R. Murphy, G. McNally, G.P. Brennan, Queen's University BelfastK. Abe, CO-OP Chemical Co. Ltd.S. Yanai, UNICOOPJAPAN* A Study on Intercalation and Exfoliation of Layered Silicate Nanoparticles in Thermoplastic

Polyurethanes 1424S.C. Jana, A. Pattanayak, University of Akron•Introducing A New Miniature Mixer For Specialty Polymer Blends And Nanoscale Composites 1429O. Breuer, U. Sundararaj, R.W. Toogood, University of Alberta* Mechanical Property of Synthetic Zirconium Phosphate-Epoxy Nanocomposites 1434K. Gam, A. Clearfield, N. Bestaoui, N. Spurr, H-J. Sue, Texas A&M University"Mechanism of Exfoliation of Nanoclay Particles in Epoxy-Clay Nanocomposites 1438S.C. Jana, J.H. Park, University of Akron*Epoxy-Aided Dispersion of Nanoclay in PMMA 1443S.C. Jana, J.H. Park, University of Akron•Enhanced Failure Properties in Layered Silicate Nanocomposites Formed by Melt Processing

I. Polyoxymethylene as a Model Matrix Material 1448P.T. Nagaraj, L. Goettler, University of Akron

THERMOSET DIVISION

M32—Thermoset Composites

A Low-Cost Composite Bicycle Frame Produced by RTM: From Concept to Reality 2054N.G. Pantelelis, National Technical University of AthensCharacterization of BMI-Carbon Fiber Composite Microcrack Development under Thermal Cycling 2059J. Ju, R.J. Morgan, Texas A&M UniversityThe Effect of Thermal Spiking on the Moisture Absorbtion and Dynamic Mechanical Properties of

Carbon Fibre Epoxy Resin Laminates 2064G. McNally, M. McCourt, Queen's University BelfastA New Toughening Method for Thermosets 2069N.H. Kim, H.S. Kim, University of NewcastleElectromagnetic Shielding of Epoxy Resin Composites Containing Carbon Fibers Coated With

Polyaniline Base 2074M. Paligova, J. Vilcakova, P. Saha, V. Kresalek, Tomas Bata University in ZlinJ. Stejskal, O. Quadrat, Academy of Sciences of the Czech RepublicAn Approach to Couple Mold Design and On-line Control to Manufacture Complex Composite Parts

by Resin Transfer Molding 2079J.M. Lawrence, S.G. Advani, M. Devillard, University of DelawareInvestigation into FRP Repaired RC Columns 2084G. Li, S. Kidane, S-S. Pang, J.E. Helms, Louisiana State UniversityQuantification of Energy Absorption in Glass Fibre Reinforced Polymers (GFRP) under Transverse

Loading 2089T. Kuboki, P-Y.B. Jar, J.R. Cheng, University of AlbertaNano-clay and Long Fiber Reinforced Composites Based on Epoxy and Phenolic Resins 2094

G. Zhou, L.J. Lee, J.M. Castro, The Ohio State University

COMPOSITES DIVISION

T11—Composite Process Simulation & Modeling

A 3D-Simulation Study of Barrier Properties of Nanocomposite Films 2100C. Swannack, C.L. Cox, D.E. Hirt, Clemson UniversityA. Liakos, U.S. Naval AcademyMinimizing Voids in Pultruded Polymer Composites 2105A.D. Freed, R.K. Gupta, H.V. GangaRao, West Virginia UniversityModeling of the Scatter in the Mechanical Properties of Flax Fiber Composites 2110J.L. Spoormaker, Spoormaker ConsultancyK.G. Kaveline, Delft University of Technology

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Process Simulation of Structural Long Fiber Thermoplastic (LFT) Composites with Features ofGeometrical Complexity 2115

U.K. Vaidya, C. Ulven, S. Pillay, S. Bartus, G.M. Janowski, The University of Alabama at BirminghamK. Gleich, Southern Research Institute

T31— Thermoplastic Composites

Flow Induced Warpage in Polypropylene/TLCP Fiber Reinforced Composite Parts 2122W.S. DePolo, Virginia TechD.G. Baird, Virginia Tech.Using LSM to Investigate Maleated Polypropylene in Polypropylene/Glass Bead Composites 2127J. Toke, J.D. Muzzy, Georgia Institute of TechnologyM.T. Cicerone, National Institute of Standards and TechnologyMechanical Properties of Feather Fiber / Glass Fiber / Polypropylene Composites 2132T.A. Bullions, S.D. Moechnig, A.C. Caba, A.C. Loos, Virginia TechEngineered Hybrid Organic-Inorganic Thermoplastic Materials: Crystallization Kinetics And Tensile

Properties 2137P.C. Guschl, Iowa State UniversityJ.U. Otaigbe, E.P. Taylor, University of Southern MississippiThe Effect of Ambient Moisture and Temperature Conditions on the Mechanical Properties of Glass

Fiber/Carbon Fiber /Nylon 6 Sandwich Hybrid Composites Consisting of Skin-CoreMorphologies 2142

U.S. Ishiaku, H. Hamada, M. Mizoguchi, S. Takashima, Kyoto Institute of TechnologyZ.A. Mohd Ishak, W.S. Chow, Universiti Sains MalaysiaComposites Derived from Post-Consumer Nylon 6 Carpet 2147J.D. Muzzy, Y. Wang, M. Satcher, B. Shaw, A. McNamara, J. Norton, Georgia Institute of TechnologyCompression Molding of Highly Conductive Fuel Cell Bipolar Plates from a Thermoplastic Composite 2151J. Huang, D.G. Baird, Virginia Tech.Making Matrix-Free SPECTRA® Fiber Reinforced Composites 2156T. Xu, R.J. Farris, University of Massachusetts AmherstBlunt Object Impact Damage Resistance of Long Fiber Thermoplastic (LFT) Composites 2161U.K. Vaidya, S. Pillay, S. Bartus, C. Ulven, G.M. Janowski, The University of Alabama at BirminghamK. Gleich, Southern Research Institute

W11—Composite Properties and Testing

Damage Development in Glass Fiber Reinforced Polymers (GFRP) Under Transverse Loading 2168T. Kuboki, P-Y.B. Jar, J.R. Cheng, University of AlbertaFiber-Reinforcement of Composites By Reaction-Induced Phase Separation 2173S.C. Jana, A. Chandra, University of AkronA NOVEL Fiber Orientation Evaluation Using a Directional Imagine Processing Technique 2178J.P. Hernandez, K. A. Tschohl, H. Wagner, T.A. Osswald, University of Wisconsin - MadisonAssessing the Use of Lower Ordered Tensors in Numerical Predictions of Flow-Induced Fiber

Orientation 2183D.A. Jack, D.E. Smith, University of Missouri - ColumbiaStudy of Progressive Damage in a Knitted Fabric Reinforced Composite 2188C.R. Rios Soberanis, Centro de Investigacion Cientifica de YucatanS. Ogin, C. Lekakuo, University of SurreyK.H. Leong, PETRONAS ResearchCharacterization of Polyetherimide and Polystyrene in Shear Flow 2193J. Lou, V. Harinath, A. Shahbazi, North Carolina A&TState University

ENGINEERING PROPERTIES AND STRUCTURE DIVISION

W12—Nanocomposites I

Effectiveness of PPMA Compatibilizers for Nanolayer Dispersion in PP: Bound vs Free Anhydride 2200D. Marchant, K. Jayaraman, Michigan State UniversityRole of Nanoparticles on Crystalline Orientation in Polypropylene/Clay Nanocomposite Films 2205C.G. Woods, J.D. Muzzy, Georgia Institute of Technology

ANTEC 2003 /xxxi

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Modeling Cell Nucleation During Microcellular Injection Molding 2210J.P. Hernandez, A. Chandra, A. Winardi, T.A. Osswald, L-S.T. Turng, University of Wisconsin - MadisonP. Gramann, The Madison GroupElectrically Activated Polypropylene/Clay Nanocomposites 2215D. Kim, J. Park, K. Ahn, S. Lee, Seoul National UniversityApplication of Image Processing Technique in Analyzing Microstructure of Nanocomposites 2219C-Y Wang, H-X Huang, Z-M Zie, South China University of TechnologyEffect of Mixing Element in a Single Screw Extruder on the Microstructure of

Polypropylene/Montmorillonite Nanocomposites 2223H-X Huang, C-Y Wang, Y-F Hwang, J. Guo, Y-H Zhang, South China University of Technology

W31—Nanocomposites II

A Carbon Nanotube Alternative: Graphite Nanoplatelets as Reinforcements for Polymers 2230L.T. Drzal, H. Fukushima, Michigan State UniversityCarbon Nanotube Nucleation of Polypropylene Crystals 2235B.P. Grady, D. Resasco, F. Pompeo, R. Shambaugh, University of OklahomaEffect of Organoclay Structure on the Rheology and Crystallization Behavior of in-Situ Polymerized,

PA-6 Nanocomposites 2240K. Akkapeddi, J. Facinelli, D. Worley, Honeywell InternationalPolyol Modified Epoxy-Montmorillonite Nanocomposites 2245I. Isik, U. Yilmazer, G. Bayram, Middle East Technical UniversitySynthesis And Characterization of Hierarchical Structure in Supercritical CO2-Fabricated Composites 2250T.C. Caskey, A.S. Zerda, A.J. Lesser, University of MassachusettsEffect of Mixer Type on Exfoliation of Polypropylene Nanocomposites 2255M.K. Dolgovskij, F. Lortie, C.W. Macosko, University of MinnesotaP.D. Fasulo, R.A. Ottaviani, W.R. Rodgers, General MotorsSynthesis and Characterization of High Density Polyethlene Clay Nanocomposites 2260M.R. Kamal, M. Mehrabzadeh, V. Mollet, McGill University

ALLOYS AND BLENDS SIG

M16—Interface and Compatibilization

Interfacial Tension Effects in Ternary Biphasic Blends 2266M. Barger, R. Sammler, Dow Chemical Co.C. Carriere, National Center for Agricultural Utilization ResearchEffects of Supercritical CO2 on the Interfacial Reaction of Maleic Anhydride Functionalized

Polyethene and Polyamide-6 2271C. Tzoganakis, A. Xue, University of WaterlooEffects of Supercritical CO2 on the Interfacial Tension between PS and LDPE Melts 2276C. Tzoganakis, A. Xue, University of WaterlooLLDPE-g-GMA to Promote Adhesion of LLDPE with Polyesters 2281I. Pesneau, M.F. Champagne, M.A. Huneault, National Research Council CanadaCompatibilization of Nylon 6 Nanocomposites/ABS Blends Using Functionalized Metallocene

Polyolefin Elastomer 2286S. Lai, National l.-Lan Institute of TechnologyW-C. Chen, Y. Liao, Chinese Culture UniversityT-W. Chen, Y-K. Shiao, H-F Shen, Plastics Industry Development Center,Compatibilisation Studies of Blends of Nylon 6 With Metallocene Linear Low-Density Polyethylenes 2292F. Gribben, G. McNally, R.W. Murphy, T. McNally, Queen's University Belfast

M35—Novel Material and Process

Nano-Composites Derived from Melt Mixing a Thermotropic Liquid Crystalline Polyester and ZincSulfonated Polystyrene Ionomers 2298

H. Lee, R.A. Weiss, University of ConnecticutOxidized Polypropylene and Ionomers Thereof as Compatibilizers for Polypropylene/Nylon-6 Blends 2303V. Dang, C. Shu, D. Dong, Basell USA Inc.T.T. Phan, Mannington Mills, Inc.

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Oxidized-Polypropylene as a Compatibilizer/Dispersion Agent for Flame Retardants 2308V. Dang, C. Shu, D. Dong, Basell USA Inc.New Miscible Blends of Nylon 6 and Polyhydroxyaminoether Resins 2313K. Akkapeddi, C. Brown, D. Worley, Honeywell InternationalNew Alloying Possibilities with SBM Block Copolymers 2318L. Gervat, A. Bonnet, F. Court, M. Glotin, C. Navarro, ATOFINAIn Situ Block Copolymer Formation During Solid-State Shear Pulverization: An Explanation for Blend

Compatibilization via Interpolymer Radical Reactions 2323A.H. Lebovitz, J.M. Torkelson, Northwestern UniversityStability of Dispersed Phase To Static Coarsening: Polymer Blend Compatibilization Via Solid-State

Shear Pulverization 2328A.H. Lebovitz, J.M. Torkelson, Northwestern UniversityCompatibilization of PC-SAN Blends by Ultrasound-assisted Melt Mixing 2333H. Kim, Dankook UniversityJ. Ryu, H. Yang, J. Lee, Sogang University

T33—Morphology Development

Simulation of Droplet Breakup using a Lattice Boltzmann Method 2340F.R. Phelan Jr., N.S. Martys, National Institute of Standards and TechnologyDrop Breakup Mechanisms in Polymer-Polymer Systems 2345U. Sundararaj, B. Lin, University of AlbertaF. Mighri, M.A. Huneault, National Research Council CanadaPolymer Dispersion Visualization in a Couette Flow Cell 2350F. Mighri, M.A. Huneault, National Research Council CanadaInfluence of Weight Fraction and Shear Rate on Particle Size in Polymer Blends 2355Y.G. Cho, M.R. Kamal, McGill UniversityTime-Scales of Coalescence in Polymer Processing: Study on Polypropylene/Polyamide-6 Blends 2360S.C. Jana, J.E. Perilla, University of AkronMorphology Transitions in Multilayer Polymer Melts Due to Growth and Interaction of Holes 2365D.A. Zumbrunnen, A. Joshi, N. Coutris, Clemson UniversityLaminar Morphology of Extruded HDPE/PA-6 Blends Controlled by Flow Fields 2370H-X. Huang, Y-F. Hwang, S.L. Yang, South China University of TechnologyInterfacial Chemistry and Morphology of Blends of Polybutyleneterephthalate and Epoxy-Containing

Rubber 2374M.V. Duin, DSM ResearchP. Martin, R. Legras, Universite Catholique de LouvainA. Machado, University ofMinhoM. van Gurp, DSM Engineering Plastics

W33—Structure and Property

Interfacial Area and Rheological Measurements of Cocontinuous Pol\(ethylene oxide)/PolystyreneBlends 2380

J.A. Galloway, C.W. Macosko, University of MinnesotaMorphological Phase Behavior of PMMA and PC in PMMA/PC Binary and PP/PMMA/PC Ternary

Blends 2385M. Lee, S. Kim, B-K. Lee, LG Chem Ltd.An In-Situ Process for the Production of Electrically Conductive Polyaniline Fibres from a Polymer

Blend 2390R.H. Cruz-Estrada, Centro De Investigacion Cientifica De YucatanBlends of Ethylene-Methyl Acrylate-Acrylic Acid Terpolymers with Ethylene-Acrylic Acid Copolymers 2395B.P. Grady, University of OklahomaN. Pongrakananon, W. Visitsart, M. Nithitanakul, P. Supaphol, Chulalongkorn UniversityStudy on Mechanical Properties of Dynamically Cured PP/Epoxy Resin Blends 2398Y. Zhang, X. Jiang, Y. TJaan.%, H. Huang, Shanghai Jiaotong UniversityThe Processing and Performance of Polyvinyl Chloride / Ethyl-Vinyl Acetate Copolymer Blends 2403D. McConnell, G. McNally, R. Murphy, Queen's University BelfastThe Effects of Coupling Agents on the Mechanical Properties of Wood-Polymer Composites 2408P. Douglas, M. Billham, R. Murphy, G. McNally, Queen's University Belfast

ANTEC 2003 /xxxiii

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COLOR AND APPEARANCE DIVISION

M1—Color and Appearance

Pigments for Food Packaging - A Regulatory Journey 2414D. Jackson, Eastman Chemical CompanyNanoColorants - More Than Colored Nanoparticles 2419A.J. Boehm, A. Glaser, O. Koch, BASFAktiengesellschaftUsing the Internet to Calibrate Color Spectrophotometers Back to a Traceable NIST: A Revolutionary

Patented Technology for Color Control 2423R. Knapp, GretagMacbethColor and Appearance Measurement and Tolerancing Basics 2427J. Cameron, RTP Company

M19—Color and Appearance

Crystal Properties of Organic Pigments 2434R. Reinicker, Ciba Specialty ChemicalsVerification of Color Difference Equations — Part II 2450B. Mulholland, TiconaColor Matching Software from the Colorant Producer's Perspective 2456B. Coleman, R.A. Reinicker, Ciba Specialty ChemicalsQualitative Analysis of Optical Film Properties 2464A. Yacykewych, C. W. BRABENDER Instruments, Inc.Understanding the Effects of a Compounding Process on the Production of Co-Extruded Vinyl Sheet

through the Utilization of Design of Experiments 2469K. Effertz, Aspen Research CorporationPerylimide Fluorescent Dyestuffs - Specialty Colorants with a Brilliant Future 2474

A.J. Boehm, P. Blaschka, BASF Aktiengesellschaft

AUTOMOTIVE DIVISION

T8—Characterization of Automotive Plastics

Diffusion of Methanol, Ethanol and Toluene in Nylon 12 and Poly(Butyleneterephthalate) 2480M. McCourt, A. Ruddy, R. Murphy, G. McNally, Queen's University BelfastDegradation of Rubber Networks During the Ultrasonic Treatment 2485V.V. Yashin, A.I. Isayev, S-H. Kim, C-K. Hong, S. Shim, J. Yun, The University of AkronAlternatives to Coatings for Automotive Plastics 2490T.J. Pickett, General MotorsN. Kakarala, Delphi Automotive Systems

T27—Automotive Plastics Applications

Mechanical Behavior of TPV in Automotive Sealing Systems 2496W. Zoetelief, M. Teeuwen, DSM ResearchY. Wang, DSM Thermoplastic Elastomers, Inc.Structural Analysis of Components Molded Using Microcellular Foam Molding Process 2501S. Desai, M. Ansari, Valeo Engine CoolingW.D. Saunders, DuPont Engineering PolymersAbrasion Resistance Requirements for Automotive Interior Soft Skin Materials 2506T.J. Pickett, General MotorsCharacterizing Scratch and Mar Performance of Molded-in-Color Engineered Polyolefins for the

Automotive Industry 2511S. Bafna, M. Shah, D. Edge, SOLVAYENGINEERED POLYMERSPeroxide Initiated Grafting of Alkoxy silanes from Poly(isobutylene-co-para-methylstyrene) Utilizing a

Co-rotating Twin Screw Extruder 2516R.L. Tabler, T.A. Peitz, A.K. Shim, Dow Corning Corporation

xxxiv / ANTEC 2003

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DECORATING AND ASSEMBLY DIVISION

W8—Decorating and Assembly

Achievable Weld Strengths for Various Thermoplastics Using the Clearweld® Process 2522N. Woosman, R. Sallavanti, GENTEX CorporationDecorative Laminates for Thermoforming and Injection Molding Processes 2527D. Northrop, Avery DennisonKurz-Hastings Inmold Decoration 2529R. Bomberger, Kurz-Hastings, Inc.Post Mold Plastic Decorating 2535K. Hillestad, ITW United SiliconeUV Curable Pad Printing Inks in the Future of the Plastics Decorating Industry 2546D. Miller, Deco Technology Group, Inc.B. Puder, UVEXS

MEDICAL PLASTICS DIVISION

M10—Advances in Medical Materials and Analysis

The Suitability of Polyvinyl Chloride / Ethyl-Vinyl Acetate-Carbon Monoxide Terpolymer Blends forMedical Devices 2552

D. McConnell, G. McNally, R. Murphy, Queen's University BelfastCoextrusion of TPU and BaSO4 Filled Medical-GradeTPU 2557G. Lu, D.M. Kalyon, Stevens Institute of TechnologyI. Yilgor, E. Yilgor, Koc UniversityModification of Biodegradable Polyesters with Inorganic Fillers 2561G. Chouzouri, M. Xanthos, New Jersey Institute of TechnologyUltrasonic Welding of Copolyester Resins 2566E.J. Moskala, D.A. Free, B.T. Eiselstein, M.C. Morrow, Eastman Chemical CompanyThe Mechanical and Rheological Characterisation of Implantable Medical Devices Formulated from

Binary Mixtures of Cellulose Derivatives 2571G.P. Andrews, D.S. Jones, A.D. Woolfson, Queen's University BelfastThe Effect of Blending Drop Temperature on Properties of Extruded PVC Tubing 2576M. Moran, FenwalA. Buan-Delos Santos, J.J. Penn, Baxter

M30—Hot Topics: Micromolding and Biomaterials

Micromoulding: Consideration of Processing Effects on Medical Materials 2582M.T. Martyn, B. Whiteside, P. Coates, University of BradfordG. Greenway, P.S. Allan, P.R. Hornsby, Brunei UniversityNanomolding of Silicone Rubber Parts and Inserts in Thermoplastic 2587P.M. Leopold, Medical Murray, Inc.Designing Nylon 12 Nanocomposites for Catheter Shafts, "More Clay Is Not Always Better" 2593C.J. O'Neil, L.A. Acquarulo, J. Faucher, N. Jain, Foster CorporationDevelopment and Design of Novel Co-Injection Molded Soy Protein Delivery Devices 2598A.M. Cunha, C. Vaz, R. Reis, D. Tchalamov, University ofMinhoMedical Plastics Showing Bacteriostatic Properties 2603M. Lambert, G. Mann, T. Kelly, K. Darnell, C.R. Bard

W29—Medical Packaging

A Novel Seal/Peel System for Medical Packaging Applications 2610K.S. Sprain, J.S. Ozcomert, Rexam Healthcare FlexiblesInvestigating the High-Temperature Peel Properties of Medical Packaging Materials 2615D. Dixon, A. Crangle, R. Mcllhagger, Univeristy of UlsterK. McCracken, Perfecseal LtdThe Use of Calcium Oxide as a Desiccant in Extrusion Coatings 2620A.J. Hayden, J.S. Ozcomert, Rexam Healthcare Flexibles

ANTEC 2003/xxxv