ar3ui+92sprom: hari prasad vff mahboobeh mecanic inorganic data reviewer senior oversight chemist...

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UNITED STATES ENVIRONMENTAL PROTECTION AGENCY

REGION mCENTRAL REGIONAL LABORATORY AOQTTOAW™

201 DEFENSE HIGHWAY **>?«™^ ^ SUITE 200 BRANCH

ANNAPOLIS, MARYLAND 214O1

DATE : November 10, 1994

SUBJECT: Region III Data QA Review

FROM : ' Susanne M. Stevens, ActingRegion III ESAT RPO (3ES30)

TO : Lisa MarinoRegional Project Manager (3HW42)

Attached is the organic data validation report for the Koppers Co.Fac. Plant Site (Case 22655) completed by the Region IIIEnvironmental Services Assistance Team (ESAT) contractor under thedirection of Region III BSD.

If you have any questions regarding this review, please call me at(410) 573-6832.

Attachment

cc: Chris Burns, TetraTech

TID File: 03941100

AR3UI+92SPrinted on Recycled Paper

?̂LockheedEnvironmental Sen/ices Assistance Teams Phone; (410) 268-7705Region 3 Fax: (410) 268-84721419 Forest Drive, Suite 104Annapolis, Maryland 21403

DATE: OCTOBER 31, 1994

SUBJECT: INORGANIC DATA VALIDATION (IM1 LEVEL)Case 22655 SITE: KOPPERS CO. FAC. PLANT

PROM: HARI PRASAD Vff MAHBOOBEH MECANICINORGANIC DATA REVIEWER SENIOR OVERSIGHT CHEMIST

TO: SUSANNE STEVENSESAT ACTING REGIONAL PROJECT OFFICER

1̂THROUGH://DALE S. BOSHART 'T ESAT TEAM MANAGER

OVERVIEW

Case 22655 consisted of seventeen (17) soil samplesanalyzed for metals by Associated Laboratories Inc. (ALI)according to the Contract Laboratory Program (CLP)Routine Analytical Services (RAS) Statement of Work (SOW)ILM02.1.

SUMMARY

All analytes were successfully analyzed in all samples.The data were validated according to the IM1 Levelprocedure, which includes the review of all QC formsexcept the ones for the Contract Required Detection Limit(CRDL) standard recovery, and excludes the review of theraw data.

Areas of concern with respect to data usability aregiven below according to the seriousness of theproblem.

MINOR ISSUES

The continuing calibration blanks had reported resultsgreater than the Instrument Detection Limit (IDL) for thepotassium (K), selenium (So) and thallium (Tl) analytes.The reported results for these analytes in the affectedsamples which are less than five times the blankconcentration may be biased high and have been qualified"B".

of 2

The ICP serial dilution results were outside the controllimit (10% D) for the calcium (Ca) and manganese (Mn)analytes. The reported results for these analytes areestimated and have been qualified "J".

The matrix spike recovery was low (30%-75%) for theantimony (Sb) analyte. The reported result andquantitation limits for this analyte may be biased lowand have been qualified ML" and "UL", respectively.

Sample MCND22 was collected on 9/19/1994 4nd wasanalyzed for the mercury (Hg) analyte on 10/18/1994,exceeding the twenty-eight (28) day holding period by one(1) day. The reported result for this analyte may bebiased low and has been qualified "L".

The preparation and continuing calibration blanks hadnegative results with absolute value greater than the IDLfor the Se and silver (Ag) analytes, respectively. Thequantitation limits for these analytes may be biased lowand have been qualified "UL".

NOTES

The laboratory flagged the aluminum (Al) analyte on theForm Is with an "*" denoting the laboratory duplicateresults outside the contractual control limit (20% RPD) .Since these results were within the technical controllimit for the soil samples (35% RPD), no action wastaken.

The laboratory analyzed the arsenic (As), lead (Pb),Se and Tl analytes using the ICP method, and had IDLvalues less than CRDL.

The data were reviewed in accordance with the InnovativeApproaches (IMl Level) For Validation of Inorganic Data,September, 1992 and the National Functional Guidelinesfor Evaluating Inorganic Analyses, with modifications foruse within Region III.

ATTACHMENTS

APPENDIX A ANNOTATED FORM Is

APPENDIX B GLOSSARY OF DATA QUALIFIER CODES

APPENDIX C SUPPORT DOCUMENTATION

HP410A06.KOP

APPENDIX A

ANNOTATED FORM Is

AR3U14928

U.S. EPA - CLP \_

U.S. EPA - CLP

1 EPA SAMPLE NO.INORGANIC ANALYSES DATA SHEET

MCND17Lab Name: ASSOCIATED LABORATORIES Contract: 68D20043

Lab Code: ALI__ Case No.: 22655_ SAS No.: _____ SDG No.: MCND16

Matrix (soil/water): SOIL_ Lab Sample ID: MCND17

Level (low/med): LOW_ Date Received: 09/16/94

% Solids: _83.2 0 Q'O 3

Concentration Units (ug/L or mg/kg dry weight): MG/KG

CAS No.

7429-90-57440-36-07440-38-27440-39-37440-41-77440-43-97440-70-27440-47-37440-48-47440-50-87439-89-67439-92-17439-95-47439-96-57439-97-67440-02-07440-09-77782-49-27440-22-47440-23-57440-28-07440-62-27440-66-6

Analyte

AluminumAntimonyArsenicBariumBerylliumCadmiumCalciumChromiumCobaltCopperIronLeadMagnesiumManganeseMercuryNickelPotassiumSeleniumSilverSodiumThalliumVanadiumZincCyanide

Concentration

U.S. EPA -


MCND18Lab Name: ASSOCIATED_LABORATORIES_ Contract: 68D20043

Lab Code: ALI__ Case No.: 22655_ SAS No.: *" '"̂ DG No. : llCNDie'



% Solids: _96.5 (J (If) A


CAS No.

7429-90-57440-36-07440-38-27440-39-37440-41-77440-43-97440-70-27440-47-37440-48-47440-50-87439-89-67439-92-17439-95-47439-96-57439-97-67440-02-07440-09-77782-49-27440-22-47440-23-57440-28-07440-62-27440-66-6

Analyte


Concentration

C682J)!5.70.56[38.8to. 6£0.60rT70(18.8

7.49.6

14500I 4.9\ 1540V434,0.07p.07̂1640\p.4i.0.36(34.10.7Tp9.2\18.3~ —

C

uuBBU

JU

BUBU

Q*N

E

E

U.S. EPA - CLP^L

U.S. EPA - CLP X


Lab Name: ASSOCIATEDLABORATORIES Contract: 68D20043MCND20

_Lab Code: ALI __ Case No.: 22655_ SAS No.: _____ SDG No.: MCND16

Matrix (soil/water) : SOIL_ Lab Sample ID: MCND20

Level (low/med): LOW _ Date Received: 09/16/94

% Solids: _82.0 - li ' Ano

Concentration Units (ug/L or mg/kg dry weight) : MG/KG

CAS No.

7429-90-57440-36-07440-38-27440-39-37440-41-77440-43-97440-70-27440-47-37440-48-47440-50-87439-89-67439-92-17439-95-47439-96-57439-97-67440-02-07440-09-77782-49-27440-22-47440-23-57440-28-07440-62-27440-66-6

Analyte


Concentration C

A7100J1 578 UrrrrlI 1071)U.eJ0.61JU/̂ B8\B/35.1I/ 10.4|1 13'7/ 1810013.3

1 4300N 89. Or~DT09 Upi. 71\145olvi.pl)OT37JU^Tl6AB/ 1-6IB/49.6J( 52.2]X~" —— 1

Q*N

E

E

Ŝ V

vu

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yuft

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PPPPPPPPPPPPPPcvPPPPPPPPNR

Color Before: GREY____ Clarity £efore: _____ Texture: MED

Color After: BEIGE___ Clarity After: _____ Artifacts: __

Comments:L

FORM I - IN ILM02.1

AR301+933,

U.S. EPA - CLP*X


MCND21Lab Name: ASSOCIATED_LABORATORIES Contract: 68D20043


Matrix (soil/water): SOIL_ ' Lab Sample ID: MCND21


% Solids: _81.1 0 007


CAS No.

7429-90-57440-36-07440-38-27440-39-37440-41-77440-43-97440-70-27440-47-37440-48-47440-50-87439-89-67439-92-17439-95-47439-96-57439-97-67440-02-07440-09-77782-49-27440-22-47440-23-57440-28-07440-62-27440-66-6

Analyte

AluminumAntimonyArsenicBariumBerylliumCadmium .CalciumChromiumCobaltCopperIronLeadMagnesiumManganeseMercuryNickelPotassiumSeleniumSilverSodiumThalliumVanadiumZincCyanide

Concentration

Cl97q£»—— 5^80.67tllS"U-3.0772

pioeo141.28.613.01970011.5

\ 3530V158,o;roU8.71U-410J0.410.43f333OT51\36^V51.X

c

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Color Before: GREY____ Clarity £efore: _____ Texture: MED.

Color After: BEIGE___ Clarity After: _____ Artifacts: ___

Comments:§ V ̂ n

FORM I - IN ILM02

U.S. EPA



Lab Code: ALI__ Case No.: 22655_ SAS No.: _____ S'DG No.: MCND16



% Solids: _86.5 0


CAS No.

7429-90-57440-36-07440-38-27440-39-37440-41-77440-43-97440-70-27440-47-37440-48-47440-50-87439-89-67439-92-17439-95-47439-96-57439-97-67440-02-07440-09-77782-49-27440-22-47440-23-57440-28-07440-62-27440-66-6

Analyte


Concentration

T2360Q,' "sTe0.55̂T1861 1-3^07297̂710"29.96.29.9

1100021.3

1 2610I 296\ 0.0912.6814

0.86_0.36C497T]L̂if33.r

>48.1v — "

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Color Before: BROWN___ Clarity £efore:

Color After: BROWN Clarity After: Artifacts: YES

Comments :STONES

U.S. EPA - CLP






% Solids: _83.8 0 009


CAS No.

7429-90-57440-36-07440-38-27440-39-37440-41-77440-43-97440-70-27440-47-37440-48-47440-50-87439-89-67439-92-17439-95-47439-96-57439-97-67440-02-07440-09-77782-49-27440-22-47440-23-57440-28-07440-62-27440-66-6

Analyte

AluminumAntimonyArsenicBariumBerylliumCadmiumCalciumChromiumCobaltCopperIronLeadMagnes iuraManganeseMercuryNickelPotassiumSeleniumSilverSodiumThallium'VanadiumZincCyanide

Concentration

[11900:— 6T3r"2~:6(82.3\1.10 .__££_9̂ia

f'z'S . 96.110

142009.32470113

\ 0.4113.0

\ 933\1.§.0.40-55". 3'1.0

\32.4\35.7

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Color Before: BROWN___ Clarity Before: _____ Texture: MED.

Color After: BROWN___ Clarity After: _____ Artifacts: YES

Comments:GRAVELS

U.S. EPA - CLP



I—oc-̂ ln 'tf-v̂ ', K-CjfSt

U.S. EPA - CLP



. U—1>Lab Code: ALI Case No.: 22655 SAS No.: SDG No.: MCNDlfe


Level (low/med): LOW_ Date Received: 09/21/94,

% Solids: _83.4 (j Q|j


CAS NO.

7429-90-57440-36-07440-38-27440-39-37440-41-77440-43-97440-70-27440-47-37440-48-47440-50-87439-89-67439-92-17439-95-47439-96-57439-97-67440-02-07440-09-77782-49-27440-22-47440-23-57440-28-07440-62-27440-66-6

Analyte


Concentration

C2450Q,—— ET77T1.5(72.3\1.5,OT50Toeo^39.310.910.82810014.1

\ 3360\ 135.OTTO[15.0Vl920_0.340.36

rso.T^2.7

\ 54.6V48.6^ —— ̂

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Color Before: BROWN___ Clarity Before: _____ Texture: MED.

Color After: BROWN___ Clarity After: _____ Artifacts: YES

Comments:GRAVELS-x̂ s**i 1 X- f~̂ t SJ - fl - ft 1-*--v~ \J

U.S. EPA - CLP X B

r

Q*N

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Q(\J

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"3"

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Color Before: BROWN___ Clarity 3efore: _____ Texture: MED.


Comments:

FORM I - IN ILM02.1

U.S. EPA - CLP



,Lab Code: ALI__ Case No.: 22655_ SAS No.: _____ SDG No.: MCND16

Matrix (soil/water): SOIL__ Lab Sample ID: MCND27


% Solids: _83.5 0 013


CAS No.

7429-90-57440-36-07440-38-27440-39-37440-41-77440-43-97440-70-27440-47-37440-48-47440-50-87439-89-67439-92-17439-95-47439-96-57439-97-67440-02-07440-09-77782-49-27440-22-47440-23-57440-28-07440-62-27440-66-6

Analyte


Concentration

\1360Q)" — 6T4^2.3(96.6V 1.0£-&&ri9io:"17.08.65.3

1120010.51920

V 139(T.091

( 11. 5*1596

V0.42,OT41£V;UT&lT27.T^34.3^— — '

C

U

BU

BB

U

BBUBU

Q

*N

E

E

U.S. EPA - CLP



Lab Code: ALI__ Case No.: 22655_ SAS No.: _____ SDG No. : MCND15

Matrix (soil/water) : SOIL__ Lab Sample ID: MCND28


% Solids: _84.7 0


CAS No.

7429-90-57440-36-07440-38-27440-39-37440-41-77440-43-97440-70-27440-47-37440-48-47440-50-87439-89-67439-92-17439-95-47439-96-57439-97-67440-02-07440-09-77782-49-27440-22-47440-23-57440-28-07440-62-27440-66-6

Analyte


Concentration

ri34ogj6.3

rzTT41.1Nil,1'O.T7A456'/ 25.112.49.4

18000\ 10.4\2720\ 149OT&8rro.i\ 99?,OT380.40~̂ 8 . 7"1.1

\ 44.0V31.3~"-~"

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Color Before: BROWN___ Clarity .Before: _____ Texture: MED.


Comments:£> V -^ Blu^

FORM I - IN ILM02.1

U.S. EPA - CLP


MCND30Lab Name: ASSOCIATED_LABORATORIES Contract: 68D20043

~ LoLab Code: ALI__ Case No.: 22655_ SAS No.: _____ SDG No.: MCND16



% Solids: _83.3 0 015


CAS No.

7429-90-57440-36-07440-38-27440-39-37440-41-77440-43-97440-70-27440-47-37440-48-47440-50-87439-89-67439-92-17439-95-47439-96-57439-97-67440-02-07440-09-77782-49-27440-22-47440-23-57440-28-07440-62-27440-66-6

Analyte


Concentration

nssoji)6.4

F̂ '5196.3U-7.0.67tT̂ 6$\I 34.41 13.417.62410012.6

\ 514V 2240̂

p.7.6\J3530OTT80.40

fTs/9̂2.360.7

\ 54.8

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B

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Color After: .BEIGE___ Clarity After: _____ Artifacts: ___

Comments:Q V •= XT)

FORM I - IN ILM02.1

U.S. EPA - CLP



L-oLab Code: ALI__ Case No.: 22655_ SAS No.: _____ SDG No.: MCND16



% Solids: _81.0 ' 0


CAS No.

7429-90-57440-36-07440-38-27440-39-37440-41-77440-43-97440-70-27440-47-37440-48-47440-50-87439-89-67439-92-17439-95-47439-96-57439-97-67440-02-07440-09-77782-49-27440-22-47440-23-57440-28-07440-62-27440-66-6

Analyte


Concentration

(21300\ 10.3

2.1I 144Vl. 7,O-JO^

/f-4541/ 48.0115.324.924200\12.217090\136.0.09rT4.r

( 4380,îr:4o0.4_3

re? . 3>1 2.3\ 75.9,\66.21—— —

C

BB

\-UB

FU

UUB

Q*N

E

E

U.S. EPA -



_ - •Lab Code: ALI__ Case No.: 22655_ SAS No.: _____ StiG No.: MCND16



% Solids: _81.2 0 017


CAS No.

7429-90-57440-36-07440-38-27440-39-37440-41-77440-43-97440-70-27440-47-37440-48-47440-50-87439-89-67439-92-17439-95-47439-96-57439-97-67440-02-07440-09-77782-49-27440-22-47440-23-57440-28-07440-62-27440-66-6

Analyte


Concentration

r 15700;6.0

/T..3,80.7/0.94r̂rS3Ti2o~o>

/ 19.95.26.6

1080011.91360

I 138\ 0.10

6.7467

0.81-̂tf-rS'S'nra.o;"crrre24.227.5\ —— --

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B

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Color After: f BEIGE___ Clarity After: _____ Artifacts: __

Comments:(S Vr - &,^ JLrU*~ ̂ Ĵ t̂ ^ ̂ /cOL̂ dÛ Vv, .0

FORM I - IN ILM02.1

U.S. EPA - CLP





Level (low/med): LOW_ Date Received: 09/24/94•

% Solids: _83.4 O'Otfi


CAS No.

7429-90-57440-36-07440-38-27440-39-37440-41-77440-43-97440-70-27440-47-37440-48-47440-50-87439-89-67439-92-17439-95-47439-96-57439-97-67440-02-07440-09-77782-49-27440-22-47440-23-57440-28-07440-62-27440-66-6

Analyte


Concentration

. 14300)6.3

rs.v57.6Vl.4.OT57r~533>27.61̂9.29.7

25100

C

u

YUB

H-4|r2850V 836.TTT09T14.F\127Q,ÔT3~80.40

rso.710.9345.4

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Y37.7 J

Q

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E

E

APPENDIX B

GLOSSARY OF QUALIFIER CODES

GLOSSARY OF DATA QUALIFIER CODES (INORGANIC)

CODES RELATED TO IDENTIFICATION(confidence concerning presence or absence of analytes):

U « Not detected. The associated number indicatesapproximate sample concentration necessary to bedetected.

(NO CODE) - Confirmed identification.

B = Not detected substantially above the level reportedin laboratory or field blanks.

R • Unusable result. Analyte may or may not be presentin the sample. Supporting data necessary toconfirm result.

CODES RELATED TO OUANTITATION(can be used for both positive results and sample quantitationlimits):

J = Analyte Present. Reported value may not beaccurate or precise.

K = Analyte present. Reported value may be biasedhigh. Actual value is expected to be lower.

L ~ Analyte present. Reported value may be biased low.Actual value is expected to be higher.

[ ] • Analyte present. As values approach the IDL thequantitation may not be accurate.

UJ = Not detected, quantitation limit may be inaccurateor imprecise.

UL - Not detected, quantitation limit is probablyhigher.

OTHER CODES

Q * No analytical result.

AR3GU9l*7

APPENDIX C

SUPPORT DOCUMENTATION

U.S. EPA - CLP

COVER PAGE - INORGANIC ANALYSES DATA PACKAGE

Lab Name: ASSOCIATED_LABORATORIES_ Contract: 68D20043_

Lab Code: ALI__ Case No.: 22655 SAS No.: _____ SDG No.:MCND16

SOW No.: ILM02.1

EPA Sample No. Lab Sample ID (J 001_MCND16______ _MCND16________MCND17 MCND17MCND18______ _MCND18"MCND19______ _MCND19IMCND20______ _MCND20MCND21______ _MCND21"MCND21D_____ _MCND21D"MCND21S_____ _MCND21S"MCND22______ _MCND22"MCND23______ _MCND23"MCND24______ _MCND24"MCND25______ _MCND25"MCND26______ _MCND26"MCND27______ _MCND27"MCND28______ _MCND28"MCND30______ _MCND30"MCND31______ _MCND31"MCND32______ _MCND32"MCND33 MCND33

Were ICP interelement corrections applied ? Yes/No YES

Were ICP background corrections applied ? Yes/No YESIf yes - were raw data generated beforeapplication of background corrections ? Yes/No NO_

Comments:

j/Z»*9̂ C jo*, 2.? V N , Frf/tfT~ rti&U I•* —————— * — 3-1 ———— «*— i ———— ' *'-r-ir ———— bL/X(V )̂xv >&;->/

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U.S. EPA - CLP

3BLANKS

U'024Lab Name: ASSOCIATED_LABORATORIES_ Contract: 68D20043_


Preparation Blank Matrix (soil/water): .SOIL_

Preparation Blank Concentration Units (ug/L or mg/kg): MG/KG

Analyte

AluminumAntimonyArsenicBarium __BerylliumCadmiumCalciumChromiumCobaltCopperIronLeadMagnesiumManganeseMercuryNickel __PotassiumSeleniumSilverSodiumThalliumVanadiumZincCyanide

InitialCalib.Blank(ug/L) c

32.928.42.810;61.83.0

79.14.012.31.97.91.1

51.91.30.217.3449.81.71.8

84.84.35.55.1

UUUUBUUUUUUUUUUUBUUUBUU

Continuing CalibrationBlank (ug/L)

1 C 2 C 3 C

32.928.42.810.61.63.0

79.14.012.31.913.11.1

51.91.30.217.3

462.2C3.0J)1.8

S4.83.65.55.1

UUUUUUUUUUBUUUUUBBUUUUU

32.928.42.810.61.63.0

79.14.012.32.615.71.151.91.30.217.3

831.9

C-1.8O^*O

3.6, 8.4

5.1

UUUUUUUUUBBUUUUUB&

%UBU

32.928.42.810.61.63.0

84.04.012.31.912.21.151.91.30.217.3

_̂ L52.0l

> 1.884.8C4.07.05.1

UUUUUUBUUUBUUUUUBUUUBBU

Prepa-rationBlank c

6.5805.6800.5602.1200.3200.60015.8200.8002.4600.3802.2200.22010.3800.2600.1003.460

-154.020

0.36016,9600.720-1.4001.020

UUUUUUUUUUBUUUUUBBUUUBU

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P

P

P

P

P

P

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FORM III - IN

AR3UU957

U.S. EPA - CLP

3BLANKS



Preparation Blank Matrix (soil/water): SOIL_

Preparation Blank Concentration Units (ug/L or mg/kg): MG/KG

Analyte

Aluminum\ntimonyrsenicârium __BerylliumCadmiumCalciumChromiumCobaltCopperIronLeadMagnesiumManganeseMercuryNickelPotassiumSeleniumSilverSodiumThalliumVanadiumZincCyanide

InitialCalib.Blank(ug/L) C

-

Continuing CalibrationBlank (ug/L)

1 C 2 C 3 C

32.928.42.8

10.61.63.0

79.14.012.31.99.8

-1.751.91.30.2

17.3622.41.7

C-3 . Q>84.83.65.55.1

UUuuuuuuuuBBUUUUBUBUUuu

Prepa-rationBlank C

0.100 u

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PPPPPPPPPPPPPPcvppppppppNR

FORM III - IN ILM02.1

AR3Ql*958

U.S. EPA - CLP

5A EPA SAMPLE NO.SPIKE SAMPLE RECOVERY

MCND21SLab Name: ASSOCIATED LABORATORIES Contract: 68D20043


Matrix (soil/water): SOIL_ Level (low/med): LOW_

% Solids for Sample: _81.1 0 031


Analyte


ControlLimit%R

75-12575-12575-12575-12575-125

75-12575-12575-125

75-125

75-12575-12575-125

75-12575-125

75-12575-12575-125

Spiked SampleResult (SSR)

34.8469406.3711555.835511.487712.7165

84.6620115.177265.0190

121.5641

284.35100.5897

123.1973

460.61019.1781

426.2381142.3685153.2837

CSample

Result (SR)

6.79970.6704

117.98931.31450.7183

41.15748.571513.0487

11.4882

157.75800.098618.7471

0.40700.4310

0.861936.704151.0936

C

UU

U

B

U

UU

U

SpikeAdded (SA)

107.22428.89428.8910.7210.72

42.89107.2253.61

107.22

107.220.54

107.22

428.8910.72

428.89107.22107.22

%R

32.594.7102.194.9118.6

101.499.496.9

102.7

118.1109.297.4

107.485.6

99.498.595.3

Q

N

M

NRPPPPPNRP

fn?PNRPcvPNRPPNRPPPNR

Comments:

FORM V (Part 1) - IN ILM02.1

AR30i»959

U.S. EPA - CLP

5B EPA SAMPLE NO.POST DIGEST SPIKE SAMPLE RECOVERY

MCND21ALab Name: ASSOCIATED LABORATORIES Contract: 68D20043


Matrix (soil/water) : SOIL_ Level (low/med): LOW

Concentration Units: ug/L "' 032

Analyte

AluminumAntimonyArsenicBariumBerylliumCadmiumCalcium"''•vromiumbait

i— opperIronLeadMagnesiumManganeseMercuryNickelPotassiumSeleniumSilverSodiumThalliumVanadiumZincCyanide

ControlLimit%R

Spiked SampleResult (SSR)

134.20

CSample

Result (SR)

28.40

C

U

Added (SA)

120.0

%R

111.8

Q M

NRPNRNRNRNRNRNRNRNRNRNRNRNRNRNRNRNRNRNRNRNRNRNR

Comments:

FORM V (Part 2} - IN ILM02.1

AR30U960

U.S. EPA - CLP

6 EPA SAMPLE NO.DUPLICATES

MCND21DLab Name: ASSOCIATED LABORATORIES Contract: 68D20043


Matrix (soil/water): SOIL_ Level (low/med): _LOW_

% Solids for Sample: _81.1 % Solids for Duplicate: _82.3

0 033Concentration Units (ug/L or mg/kg dry weight): MG/KG

Analyte


ControlLimit

47.91.2

6.0

1197.1

9.61197.1

12.0

Sample (S)

19747.88416.79970.6704

117.98931.31450.7183

1057.785541.15748.571513.0487

19716.758611.4882

3529.1442157.75800.098618.7471

1411.41820.40700.4310

332.80260.861936.704151.0936

C

UU

UB

B

U

UUBU

Duplicate (D)

15081.61866.42540.9849

110.02391.18330.6787

922.408635.74709.366612.0816

• 16473.037010.5191

3212.7060169.93400.102815.9278999.10630.38460.4072

307.92200.814529.050147.5797

C

UB

UB

B

U

BUUBU

RPD

26.8

200.07.0

10.5

13.714.18.97.7

17.98.89.47.4

16.334.2

7.8

23.37.1

Q

*

M


FORM VI - IN ILM0271

AR3G496

U.S. EPA - CLP

9 EPA SAMPLE NO.ICP SERIAL DILUTION

MCND21LLab Name: ASSOCIATED LABORATORIES Contract: 68D20043


Matrix (soil/water): SOIL_ Level (low/med): LOW_

0 037Concentration Units: ug/L

Analyte

AluminumAntimonyArsenicBariumBerylliumCadmiumCalciumChromiumCobaltCopperIronLeadMagnesiumManganeseMercuryNickelPotassiumSeleniumSilverSodiumThalliumVanadiumZinc

Initial SampleResult (I)

82480.0028.402.80

492.805.493.00

4418.00171.9035.8054.50

82350.0047.98

14740.00658.90

78.305895.00

1.701.80

1390.003.60

153.30213.40

C

Uu

UB

B

UUBU

SerialDilutionResult (S)

88450.00142.0014.00506.50

8.0015.00

5945.00191.0061.5054.50

90250.0047.94

15845.00738.50

108.0011915.00

8.509.00

3548.5038.92199.50311.00

C

UuBUuB

UB

B

BBUUBBB

%Differ-ence

7.2

2.8100.0

-Qî GTTTl100.00.09.60.17.5

_£3H237.9

102.1

155.3

30.145.7

Q

E

E

M

PPPPPPPPPPPPPPNRPPPPPPPP

FORM i x - I N AR3UH962 ILM°2'1

U.S. EPA - CLP

10Instrument Detection -Limits (Quarterly)



ICP ID Number: ICAP61_____ Date: 07/15/94

Flame AA ID Number : __________ (j 038

Furnace AA ID Number :

Comments:

Analyte


Wave-length(nm)

237.30206.80

493.40234.80228.80315.80267.70228.60324.70238.20

279.00257.60

231.60766.40

328.07589.50

292.40213.80

Back-ground

CRDL(ug/L)

200601020055

50001050251003

5000150.240

5000510

5000105020

IDL(ug/L)

32.928.4

10.61.63.0

79.14.012.31.97.9

51.91.3

17.3289.0

1.884.8

5.55.1

M

PPNRPPPPPPPPNRPPNRPPNRPPNRPP

FORM X - IN ILM02.1

U.S. EPA - CLP

10Instrument Detection-Limits (Quarterly)



ICP ID Number: ___________ Date: 07/15/94

Flame AA ID Number : HG-4_______ (J " fiOQ


Comments:

Analyte


Wave-length(nm)

253.70

Back-ground

CRDL(ug/L)

200601020055

5000105025100

35000

150.240

5000510

5000105020

IDL(ug/L)

0.2

M

NRNRNR.NRNRNRNRNRNRNRNRNRNRNRCVNRNRNRNRNRNRNRNR

FORM X - IN ILM02.1

U.S. EPA - CLP

10Instrument Detection' Limits (Quarterly)

Lab Name: ASSOCIATED__LABORATORIES_ Contract: 68D20043_


ICP ID Number: 61E-TA_____ Date: 07/15/94

Flame AA ID Number : __________ O


Comments:

Analyte


Wave-length(nm)

189.04

220.35

196.02

190.86

Back-ground

CRDL(ug/L)

200601020055

5000105025100

35000

150.240

5000510

5000105020

IDL(ug/L)

2.8

1.1

1.7

3.6

M

NRNRPNRNRNRNRNRNRNRNRPNRNRNRNRNRPNRNRPNRNR

FORM X - IN ILM02.1

U.S. EPA - CLP

13PREPARATION LOG


Lab Code: ALI__ Case No.;_22655_ SAS No.: _____ SDG No. :MCND16

Method: P_

U'046EPASampleNo.

LCSSMCND16MCND17MCND18MCND19MCND20MCND21MCND21DMCND21SMCND22MCND23MCND24MCND25MCND26MCND27MCND28MCND30MCND31MCND32MCND33PBS

PreparationDate

09/28/9409/28/9409/28/9409/28/9409/28/9409/28/9409/28/9409/28/9409/28/9409/28/9409/28/9409/28/9409/28/9409/28/9409/28/9409/28/9409/28/9409/28/9409/28/9409/28/9409/28/94

*

Weight(gram)

1.001.051.161.031.031.201.031.091.151.171.081.141.201.101.061.061.071.041.171.081.00

Volume(mL)

200200200200200200200200200200200200200200200200200200200200200

FORM XIII - IN ILM02.1

U.S. EPA - CLP

13PREPARATION LOG


Lab Code: ALI__ Case No.:_22655_ SAS No.: _____ SDG No.:MCND16

Method: CV

EPASampleNo.

LCSSMCND16MCND17MCND18MCND19MCND20MCND21MCND21DMCND21SMCND22MCND23MCND24MCND25MCND26MCND27MCND28MCND30MCND3 1MCND32MCND33PBS

PreparationDate

10/07/9410/07/9410/07/9410/07/9410/07/9410/07/9410/07/9410/07/9410/07/9410/07/9410/07/9410/07/9410/07/9410/07/9410/07/9410/07/9410/07/9410/07/9410/07/9410/07/9410/07/94

*

Weight(gram)

0.050.250.260.290.280.260.250.240.230.270.260.260.240.250.270.280.280.280.240.270.20

•

Volume(»L)

100100100100100100100100100100100100100100100100100100100100100

0'0'47

FORM XIII - IN ILM02.1

U.S. EPA - CLP

13PREPARATION LOG


Lab Code: ALI__ Case No.:_22655_ SAS No.: _____ SDG No. :MCND16

Method: CV

0 0'48EPASampleNo.

LCSSMCND22PBS

PreparationDate

10/18/9410/18/9410/18/94

*

Weight(gram)

0.050.270.20

Volume(mL)

100100100

FORM XIII -flWo, i nro ILM02.1J U 4 j 0 0

U.S. EPA - CLP

14ANALYSIS RUN LOG


Lab Code: ALI__ Case No.: 22655_ SAS No.: _____ SDG No. :MCND16

Instrument ID Number: ICAP61_____ Method: P_

Start Date: 10/05/94 End Date: 10/05/94 "48

EPASampleNo.

SOSsSICVICBCRIICSAICSABICSAICSABCCVCCB— 1PBSLCSSMCND21MCND21DMCND21SMCND16MCND17MCND18MCND19MCND21LCCVCCB -9MCND20MCND22MCND23MCND21AMCND21AMCND24MCND25

D/F

1.001.001.001.001.001.001.001.001.00

lO.O'O10.001.001.001.001.001.001.001.001.001.001.001.005.001.001.001.001.001.001.001.001.001.00

Time

09170920092409270928093009330943094709510954095609591002101210161019102210261030103310361040104210441047105110541057110011041107

% R

Analytes

AL

X

X

XX

XXXXXXXX

XXXXXXXXXX

XX

sB

X

X

XXXXX

XXXXXXXXXXXXXXXXXX

XX

As

—

—

BA

X

X

XX

XX

XXXXXXXXXXXXXXXX0(

XX

BE

—

cD

X

X

XXXXX

XXXXXXXXXXXXXXXXX

XX

cA

X

XXX

XX

XXXXXX

XXXXXXXXXX

XX

cR

X

X

XXXXX

XXXXXXXXXXXXXXXXX

XX

c0

X

X

XXXXX

XXXXXXXXXXXXXXXXX

XX

cuX

X

XXXXX

XXXXXXXXXXXXXXXXX

XX

FE

X

X

XX

XX

XXXXXX

XXXXXXXXXX

XX

pB

—

—

—

MG

X

XXX

XX

XXXXXX

XXXXXXXXXX

XX

MN

X

X

XXXXX

XXXXXXXXXXXXXXXXX

XXX

H/"•{j

NI

X

X

XXXXX

XXXXXXXXXXXXXXXXX

XX

K

X

XXX

XX

XXXXXX

XXXXXXXXXX

XX

sEAJ

XX

XXXXX

XXXXXXXXXXXXXXXXX

XX

NA

X

XXX

XX

XXXXXX

XXXXXXXXXX

XX

TL

—

V

X

X

XXXXX

XXXXXXXXXXXXXXXXX

XX

zN

X

X

XXXXX

TrXXXXXXXXXXXXXXXX

XX

cN

-

—

FORM XIV - IN ILM02.1

AR3049.69

U.S. EPA - CLP

14ANALYSIS RUN LOG


Lab Code: ALI__ Case No.: 22655_ SAS No.: _____ SDG No.:MCND16

Instrument ID Number: ICAP61_____ Method: P_

Start Date: 10/05/94 End Date: 10/05/94 "

EPASampleNo.

MCND26MCND27MCND32CCVCCBMCND28MCND30MCND31-;ND33.{I

riCSAICSABICSAICSABCCVCCB

D/F

1.001.001.001.001.001.001.001.001.001.001.001.00

10.0010.001.001.00

Time

1110111311171119112111241127113011331137113911441148115111531155

% R AL

XXXXXXXXX

XXXX

sB

XXXXXXXXXXXX

XX

AsBA

XXXXXXXXX

XX

XX

BECD

XXXXXXXXXXXX

XX

•

cA

XXXXXXXXX

XX

XX

cR

XXXXXXXXXXXX

XX

•

coXXXXXXXXXXXX

XX

Ar

CuXXXXXXXXXXXX

XX

laJ

FE

XXXXXXXXX

XX

XX

ytpB

.es

MG

XXXXXXXXX

XX

XX

MN

XXXXXXXXXXXX

XX

HG

NI

XXXXXXXXXXXX

XX

K

XXXXXXXXX

XX

XX

sEAG

XXXXXXXXXXXX

XX

NA

XXXXXXXXX

XX

XX

TLV

XXXXXXXXXXXX

XX

zN

XXXXXXXXXXXX

XX

cN


U.S. EPA - CLP

14ANALYSIS RUN LOG



Instrument ID Number: 61E-TA __ Method: P ,. . _—— - u 056Start Date: 10/05/94 End Date: 10/05/94

EPASampleNo.

SOSSSSSSSICVICBCRIICSAICSABCCVCCBiPBSLCSSLCSSMCND21MCND21DMCND21SMCND21SMCND16MCND17MCND21LCCVCCS IMCND18MCND19MCND20MCND22MCND23

D/F

1.001.001.001.001.001.001.001.001.001.001.00

10.0010.001.001.001.001.00

10.001.001.001.005.001.001.005.001.001.001.001.001.001.001.00

Time

09010903090509070908090909110912091709190923092609290931093309390942094409460949095109550957100010021004100710101012101410171019

% R ALSB

AS

XX

XXXXXXXX

XXX

XXXXXXXXXXX

BA

BECDCACRCO

An

CU

al

FE

ytpB

XX

XXXXXXXX

XXXX

XXXXXXXXXX

es

MG

MNHG

NIK SEAG

NATL

XX

XXXXXXXXX

XX

XXXXXXXXXXX

V

s

zN

*^ II *

cN

'


AR30WI

U.S. EPA - CLP

14ANALYSIS RUN LOG


Lab Code: ALI__ Case No.: 22655_ SAS No.: _____ SDG No.:MCND16

Instrument ID Number: 61E-TA______ Method: P_

Start Date: 10/05/94 End Date: 10/05/94 0 057

EPASampleNo.

MCND24MCND25MCND26MCND27MCND28CCVCCB}MCND30-7ND31JND32

rMCND33CRIICSAICSABCCVCCB

D/F

1.001.001.001.001.001.001.001.001.001.001.001.00

10.0010.001.001.00

Time

1022102410271029103110341036103810411043104510481055105811001102

% R ALSB

AS

XXXXXXXXXXXXXXXX

BA

BECDCACRC0

Ar

CU

lai

FE

ytpB

XXXXXXXXXXXXXXXX

.es

MG

MNHG

NIK SEAG

NATL

XXXXXXXXXXXXXXXX

V zNCN


U.S. EPA - CLP

14ANALYSIS RUN LOG

0*058Lab Name: ASSOCIATED_LABORATORIES_ Contract: 68D20043_


Instrument ID Number: 61E-TA______ Method: P_

Start Date: 10/05/94 End Date: 10/05/94

EPASampleNo.

SOsssssssICVICBCRIICSAICSABCCVCCB,PBSLCSSMCND21MCND21DMCND21SMCND21SMCND16MCND17MCND21LCCVCCBMCND18MCND19MCND20MCND22MCND23MCND24

D/F

1.001.001.001.001.001.001.001.001.001.001.0010.0010.001.001.001.001.001.001.001.005.001.001.005.001.001.001.001.001.001.001.001.00

Time

13261328133013311332133313351336133713391343134613501352135513571359140114041406140814111413141514181420142214251427142914321434

% R ALSB

ASBA

BECDCA

CRCO

Ar

CU

lal

FE

ytPB

es

MGMNHG

NIK SE

XX

XXXXXXXXXXX

XXXXXXXXXXXX

AG

,

NATL

V

\

zNCN

>

FORM XIV - IN IL.

U.S. EPA - CLP

14ANALYSIS RUN LOG ..

Lab Name: ASSOCIATED_LABORATORIES _ Contract: 68D20043 _

Lab Code: ALI __ Case No.: 22655_ SAS No.: _____ SDG No. :MCND16

Instrument ID Number: 61E-TA _____ Method: P_

Start Date: 10/05/94 End Date: 10/05/94

EPASampleNo.

MCND25MCND26MCND27MCND28CCVCCBMCND30MCND31"ND32.1033

[•crtlICSAICSABCCVCCB

D/F

1.001.001.001.001.001.001.001.001.001.001.0010.0010.001.001.00

Time

143614381441144314451447145014521454145615021506150815101512

% R ALSBAS

•

BA

BECD

•

CACRCo

Ar

CU

laJ

FE

Lyt

PB

:es

MGMNHG

NIK SE

XXXXXXXXXXXXXXX

AG

NATLV z

NCN


AR3l)l*97l*

U.S. EPA - CLP

14ANALYSIS RUN LOG



Instrument ID Number: HG-4_______ Method: CV———— 0'055Start Date: 10/18/94 End Date: 10/18/94

EPASampleNo.

SOS.5SIS5S10ICVICBCRACCVCCBPBSLCSSZZZZZZMCND22CCVCCB

D/F

1.001.001.001.001.001.001.001.001.001.001.001.001.001.001.001.00

Time

1340134413481352135614001404140814121416142014241428143214361440

% R ALSBASBA

BECDCA

CR

i.

co

Ar

CU

laJ

FE

Lyt

PB

:es

MGMNHG

XXXXXXXXXXXX

XXX

NIK S

EAGNATLV z

NCN

s


In Reference to Case No(s):22655 KOPPERS————————————03940404

Contract Laboratory ProgramREGIONAL/LABORATORY COMMUNICATION SYSTEM

Telephone Record Log

Date of Call: NOVEMBER 1.1994___________________

Sampler Name: ______TETRA TECH________________

Sampler Contact: BETSY RODGERS_______

Region: _____________III____________________________

Regional Contact: J. Janz. ESAT/A. Laae. EPA____________

Call Initiated by: ____ Laboratory X Region ___ SMO

In reference to data for the following sample number(s):

CNF24,CKS98,CKS99,CNF11 TO 14

Summary of Questions/Issues Discussed:

THE FOLLOWING SAMPLE PHASE IS LISTED INCORRECTLY ON THE SHIPPINGLOG. FOR SAMPLE CNF24 THE PHASE IS LISTED AS SOL AND THE SAMPLEIS A TRIP BLANK. THE PHASE NEEDS TO BE LISTED AS AQ. FOR SAMPLECKS98,CKS99,AND CNF11 TO 14 THE PHASE IS LISTED AS AQ AND IT SHOULDBE SOL.

Summary of Resolution:

BETSY RODGERS WILL SEND A REVISED SHIPPING LOG.

tion) Date

Signature (Affixation) Date

Distribution: (1) ORIGINAL TO SAMPLER TETRA TECH BETSY RODGERS 2)EPA RPM- LISA MARINO 3HW42 3) SHIPPING LOG

ar3ui+92sprom: hari prasad vff mahboobeh mecanic inorganic data reviewer senior oversight chemist...

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