from: hari prasad */-f mahboobeh mecanic ...page 2 of 3 the reported results for this analyte are...

UNITED STATES ENVIRONMENTAL PROTECTION AGENCY

REGION HI QITAITTVCENTRAL REGIONAL LABORATORY

201 DEFENSE HIGHWAY WAHSUITE 200 BRANCH

1 - -ANNAPOLIS. MARYLAND 214O1 / - .-

DATE : December 12, 1994

SUBJECT: Region III Data QA Review

FROM : Susanne M. Stevens,Region III ESAT RPO (3ES30)

TO : Lisa MarinoRegional Project Manager (3HW42)

Attached is the inorganic data validation report for the KoppersCo* Fac. Plant Site (Case 22840) completed by the Region IIIEnvironmental Services Assistance Team (ESAT) contractor under thedirection of Region III ESD.

If you have any questions regarding this review, please call me at(410) 573-6832.

Attachment

cc: Chris Burns, TetraTech

TID File: 03941214

Printed on Recycled Paper

Environmental Services Assistance Teams Phone: (410) 268-7705Region 3 Fax: (410) 268-84721419 Forest Drive, Suite 104Annapolis. Maryland 21403

DATE: DECEMBER 8, 1994SUBJECT: INORGANIC DATA VALIDATION (IMI LEVEL)

CASE 22840 SITE: KOPPERS CO. FAC. PLANTFROM: HARI PRASAD */-f MAHBOOBEH MECANIC

INORGANIC DATA REVIEWER SENIOR OVERSIGHT CHEMISTTO: SUSANNE STEVENS

ESAT ACTING REGIONAL PROJECT OFFICERTHROUGH:, / DALE s. BOSHART^

ESAT TEAM MANAGER

OVERVIEW

Case 22840 consisted of seventeen (17) soil samplesanalyzed for metals by ITAS, Pittsburgh Laboratory(ITPA) according to the Contract Laboratory Program(CLP) Routine Analytical Services (RAS) Statement ofWork (SOW) ILM03.0.

SUMMARY

All analytes except antimony (Sb) were successfullyanalyzed in all samples.

The data were validated according to the IMI Levelprocedures, which includes the review of all QA/QCforms except the ones for the Contract RequiredDetection Limit (CRDL) standard recovery, and excludesthe review of the raw data.

Areas of concern with respect to data usability aregiven below according to the seriousness of theproblem.

MAJOR PROBLEM

The matrix spike recovery was extremely low (< 30%) forthe Sb analyte. The quantitation limits for thisanalyte are unusable and have been qualified "R".

MINOR ISSUES

The ICP serial dilution results were outside thecontrol limit (10% D) for the zinc (Zn) analyte.

of 3

The reported results for this analyte are estimated andhave been qualified "J".

The preparation blank had a negative result withabsolute value greater than the IDL for the Sb analyte.The quantitation limits for this analyte may be biasedlow. The "UL" qualifier for this analyte has beensuperseded by the HRn qualifier previously mentioned.

MOTES

The laboratory analyzed the arsenic (As), lead (Pb) ,'selenium (Se) and thallium (Tl) analytes using the ICPmethod (trace analyzer), and had IDL values less thanCRDL.

The laboratory flagged on the Form Is, the copper (Cu),Pb and mercury (Hg) analytes with an "*" denoting thelaboratory duplicate results outside the contractualcontrol limit (20% RPD). Since these results werewithin the technical control limit for soil samples(35% RPD), no action was taken.

The laboratory flagged on the Form Is, the vanadium(V) analyte with an "E" denoting the ICP serialdilution result outside the control limit. Since thisresult (10.1%) is within the limit when rounded off, noaction was taken.

Soil sample results are calculated on the basis of theraw data values (in ug/L), the gram weight of sampleused, the volume of the digestate, and the % solidsaccording to the following formula:

(raw value, ug/L) (digestate volume, L)mg/Kg = ———————————————————————————————

(weight, g) (% solids/100)

To obtain quantitation limits, insert the IDL (Form X)for the raw value; refer to Form XIII to obtain eachsample preparation weight and volume used. Thequantitation limits thus obtained are specific for eachsample and preparation method.

The data were reviewed in accordance with theInnovative Approaches (IM1 Level) For Validation ofInorganic Data, September, 1992 and the NationalFunctional Guidelines for Evaluating InorganicAnalyses, with modifications for use within Region III.

RR305387

of 3

ATTACHMENTS

APPENDIX A ANNOTATED FORM Is

APPENDIX B GLOSSARY OF DATA QUALIFIER CODES

APPENDIX C SUPPORT DOCUMENTATION

HP412A04.KOP

AR305388

APPENDIX A

ANNOTATED FORM IS

305389

U.S. EPfl - CLP'XoA^. 000005

L^ Name: ITAS

Lab Code: 1TPA

Matrix (soil/w*

. Level ( low/med

' % Solids :

COT

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Color Before :

Color After:

Comments :ARTIFACTS:

1INORGANIC ANALYSES DATA SHEET

PITTSBURGH Contract : &6-D3-CI04S

Case No. : ££840 SAS No. :

EPA SAMPLE NO.

1 11 MCND5£ 11 1

SDG No. : MCND50

ater): 50IL_ Lab Sample ID: MCND5£

: LOW _ Date Received: 10/£9/94

icentration Units (ug/L or mg/kg dry weight): MG/KG

1CAS No. 1 Analyte

1

7440-36-074*+0-36-£74*+0— 39— 37440-41-77440-43-9

7440— s-7-37440-48-47440-50-87439-89-67439-92-17439-95-47439-96-57439-97-6

7440-09-7778£-49-£7440-££-47440-£3-57440-£S-07440— 6£—£7440-66-6

BROWN

BROWN

STONES

AluminumAnt imonyfir s en i rBar i un.Beryl 1 iumCadmiumCalciumChroroi urnCobaltCocoerIronLeadMagnesiumManganeseMercuryNickeiPotassiumSeleniumSilverSodiumThai 1 iumVanadium_ZincCyanide

Concentration C

d~l90jZ!>£L9

fl£. 31£5

10. 4810. 833640

1 £1.49. 8

1 59. 5££10051. 81850347

1 £. £11.8890c.'. 3£. ££113.43£. 6104

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Texture: MEDIUM

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FORM I - IN ILM03.0

U.S. EPfl - CLP m. U00006j_ r v \1 EPA SAMPLE NO.

INORGftNIC RNflLYSES DftTfl SHEET _____________II MCND53

Lab Name: ITfiS PITTSBURGH_________ Contract: 6&-D3-0048 I

Lab Code: ITPfl__ Case No.: 2£&H0_ SflS No.: _____ SDG No.: MCND50

Matrix (soil/water): SOIL_ . Lab Sample ID: MCND53

Level Clow/med): LOW_ Date Received: 10/29/94

'* Solids: .74.1 U,oC Jn* > ; K

Concentration Units (ug/L or mg/kg dry weight): MB/KG

1CP5 No. 1 flnalyte

17429-90-5 miuminum7440-36-0 1 ftnt imony7440-38-2 1 Arsenic7440-39-3 IBarium7440-*+ 1-7 1 Beryl 1 ; um74*t0-4 -9 1 Cadmiun,7440-70-2 | Calcium7440-47-3 | Chrom i um7440-48-4 i Cobalt7440-50-B 1 Copper7439-89-6 1 Iron7439 -92- i i Lead7439-95-4 1 Magnesium7439-96-5 1 Manganese/ 4 9-97-6 i Mercury74i+£i-tfc:-0 I Nickel74*+0-09 — 7 i Potassium7782-49-2 1 Selenium7440-22-4 1 Silver7440-23-5 1 Sod i um7440-28-13 1 Thallium7440-62-2 1 Vanadium7440-66-6 1 Zinc

ICvanide1

Concent rat ion

(T650a)^«_d_r&.

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——— f-7'1/ 14. 9I 23600\ 37.0\3040Vl£0/0>T/TT5T?]\L350Iu.s)0TS256.5T

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STONES ftNDi » O ___

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Texture: MEDIUM

ftrtifacts: YES

FORM I - IN

^30539

U.S. EPfl - CLP ^ UOU007

1 EPfl SAMPLE NO.INQRGflNIC ANALYSES DATA SHEET _____________

II MCND54 I

Name: ITflS_PITTSBURGH _________ Contract: 66-D3-0048 I ______________ I

Lab Code: ITPfl _ Case No.: ££84tZi_ SAS No.: _____ SDG No.: MCND50

Matrix (soil/water) : SOIL_ Lab Sample ID: MCND54

Level (low/med) : LOW _ Date Received: 10/£9/94

% Solids: 79.8

Concentration Units (ug/L or mg/kg dry weight): MG/KG

1 tICflS No. 1 Analytei 1I 7429-90-5 1 Aluminum1 7440-36-0 1 Ant imony1 7440-j;S-£ 1 Arsenic1 7440-39-3 1 Barium17440-41-7 1 Beryllium1 7440-4 J.-9 1 Cadmium1 7440-70-c: 1 Calcium1 /44(Zt— 4^— j 1 Chromium17440-48-4 ! Cobalt1 7440-50-8 1 CoooerI 7439-S9— 6 1 Iron174^9-9^-1 ILead1 7439-95-4 1 Magnesium1 7439-9&-b (Manganese1 7439-9 /-& 1 MercuryI7440-0EI-0 1 Nickel1 7440-09-7 i Pot as si urn1 778 —49—!=; (Selenium!7440-2£-4 [Silver1 7440-S3-5 1 Sod i urni 7440-28-0 1 Thai 1 i urn1 7440-6£-£ 1 Vanad i urn17440-66-6 IZinci ICvanide1 1

Concentrat ion

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STONES AND ROOTSL \ ~~£<(> a L4-e \ f« 3C-V oLsut t<rv\

Texture: MEDIUM

Artifacts: YES

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FORM I - IN ILMI33.I3

1R305392

U.S. EPfl - CL.P ^ UOUOOS

1 EPft SAMPLE NO.INORGANIC ANALYSES DATA SHEET

I MCND55Lab Names ITAS PITTSBURGH_________ Contract: 68-03-0048 !

Lab Code: ITPfl_ Case No. : ££S4iZi_ SA5 No. : _____ SDG No. : MCND50

Matrix (soil/water): SOIL_ Lab Sample ID: MCND55

Level <low/med) : LOW_ Date Received: 10/29/94

* Solids: _85.7 LoC Jrvt '. ~ O f £

Concentration Units (ug/L or mg/kg dry weight): MS/KG

1CAS No. 1 Analyte

1/ 4^9-^0— 5 t Aluminum74H0-36-0 1 Pint imony7440-36-c: 1 Arsenic7440-39-j; 1 Ban urn7440-41-7 1 Beryl 1 i urnf 40-4 -9 1 Cadmium,- inZi-70-c: i Calci un74*tiZi-*+7-3 I Chromium7440-48-4 1 Cobalt7440-50-8 1 Copper7439-89-6 1 Iron74j,9-9d-l ILead7439-95-4 1 Magnesium7439-96-5 i Manganese74ji9-97-6 i Mercury7440-02-0 1 Nick el744£i-£i<^~7 | Potassiumf /6 -49-c; i Selenium744iit-££-4 ISilver7440-,±3-5 1 Sodium7440-2S-0 | Thai 1 i urn7440-6£-iE: 1 Vanadium744iZi-6t>-6 I Zinc

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Concentrat ion

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STONES

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FORM I - IN ILM03.

U. S. EPA - CLP UOUOQ9

1 EPA SAMPLE NO.INORGANIC ANALYSES DATA SHEET

I MCND56Name: ITA5 PITTSBURGH_________ Contract: &8-D3-0046 I

Lab Code: ITPA_ Case No.: ££840_ SAS No.: _____ SDS No.: MCND50


Level (low/med): LOW_ Date Received: 10/£9/94

% Solids: _8i2. 7 \_^ oeuxA? \rv-t '

Concentration Units (ug/L or mg/kg dry weight): MS/KB

1CAS No. 1 Anaiyte

174i±9-9tZi-5 i Aluminum/4 0--i6-£! i nnt imony7 4 0-3 8 -£ i Hrsen ic7440-39-3 1 Bar i um7440-41-7 1 Beryl 1 ium

1 /440-<+j-9 1 Cadmium1 7440-7£i-£ 1 Calcium7440-47-3 1 Chrom i um7440-48-4 1 Cobalt7440-50-8 I Copper7439-89-6 1 Iron7439-9£-l ILead7439-95-4 I Magnesium7439-96-5 1 (Manganese7439-97-6 I hercurv7440-0£-0 1 Nickel7440-09-7 1 Potassium778£-49-£ 1 Selenium7440-££-4 1 Si 1 ver/ 440- :3-5 1 bod ium7440-£8-0 1 Thai 1 i um7440-6£-£ 1 Vanadium7440-66-6 I Zinc

1 Cyanide1

Concentrat ion

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Comments:ARTIFACTS:_STONES_AND_ROOTS.

FORM I - IN ILM03.0

A D O n i- n * .'-• n u ', 0 j M[

UUUU101 EPA SAMPLE NO.

INORGANIC ANALYSES DATA SHEET

I MCND57Lab Name: ITfiS PITTSBURGH_________ Contract: 68-03-13048 I

Lab Code: ITPfl _ Case No.: 2£S40_ SAS No.: _____ SDG No.: MCND50

Matrix (soil/water): SQIL_ Lab Sample ID: MCND57

Level (low/med): LOW _ Date Received: 10/29/94

% Solids: S5.4 \ .— • —Concentration Units <ug/L or mg/kg dry weight): MG/KG

CflS No.

74£9-90-574A0-3&-07440-38-2/440-J.9-J74-4-0-41-77440-43-97-*40-7®-£7440-47-374n0— 48— 47440-30-87439-B9-&7439-92-17439-95-474 9-96-57439-97-67440-02-07440-09-77782-49-E7440-22-47440-23-57440-28-07440—62—27440-66-6

Anal yte.

AluminumAnt i monyArsenicBan urnBeryl 1 iumCad mi urnCalciumChromiumCobaltCopperIronLeadMagnesiumManganeseMercuryNickelPotassiumSeleniumSilverSodiumThai 1 iumVanadiumZincCvanide

Concentrat ion_<T&30i3i

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FORM I - IN ILM03,

U.S. EPA - CLP -y_ \

i '—————INORGANIC ANALYSES DATA SHEET ______________

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Lab Code: ITPA_ Case No. : c'£S40_ SAS No. : _____ SDG No. : MCND50

Matrix (soil/water): SDIL_ Lab Sample ID: 01CND5S

• Level (low/med) : LOW_ Date Received: 10/29/9-+

'•/-Solids: 81.5 \__ ,- U- o^ • t o<~ o / *- —oo^-t-^v> , kicrs S£>vConcentration Units (ug/L or mg/kg dry weight): MB/KG

1 t1 CAS No. 1 Analyte1 • 11 74£9-90-b 1 Aluminum1 7440-36 -0 1 Ant imony1 7440-33-c. 1 Arsenic1 7440-j -j, 1 Bar i urn1 7440—41-7 1 Bery 111 urn1 7440-43-9 1 Cadmi urn1 7440-70-c: 1 Calcium7440—47-3 1 Chromi urn7440-46-4 1 Cobalt7440-50-8 1 Copper7439-89-6 i Iron7439-9c;-i i Lead7439-95-4 IMagnesium7439-96-5 1 Manganese7439-97-6 1 Mercury7440-0iE:-0 1 NicKel7440-09-7 1 Pot as si urn778S-49-c: 1 Selenium7440-£c!-4 1 Si 1 ver7440-23-5 I Sod i urn7440-ES-tZi 1 Thai 1 i urn7440-6c.'-£ 1 Vanad i urn7440-66-6 IZinc

1 Cyanide1

Concent rat ion

(i 3c:00——————— £T5

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FORM I - IN ILM03.0

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I MCND59Lab Name: ITflS PITTSBURGH_________ Contract: 68-D3-0048 I

Lab Code: ITPA_ Case No.: ££840_ SAS No.: _____ SDG No.: MCND50


• Level (low/med) : LOW_ Date Received: 10/29/94

'/-Solids: _k & • 5 i i , ,\_OCL^Jo (rv -, R

Concentration Units (ug/L or rng/kg dry weight): MB/KG

CAS No.

74£9-90-57440- 6-07440-3B-,::7440-39-37440-41—77440-43-97440-7W-£7440-47-37440-48-47440-50-87439-89-67439-9£-l7439-95-47439-9fr-574j»9-97-6744i2i-iZi£-07440-09-777S£-49-£7440-££-47440-23-57440-£S-07440-b£-£7440-&Q-&

Analyt e

AluminumAnt i monyArsenicBari umBeryl 1 iumCadm i umCalciumChromiumCobaltCopperIronLeadMagnesiumManganeseMercuryNickelPotassiumSeleniumSilverSodiumThai 1 iumVanadiumZincCyanide

Concentrat ion

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1 EPfl SAMPLE NO.INQRGflNIC ANALYSES DflTft SHEET ______________

I I'- I MCND60 ILao Name: ITftS_PITTSBURGH_________ Contract: 6S-D3-0048 I______________I

Lab Code: ITPn_ Case No.: 22840_ SflS No.: -_____ SDG No.: NCND50

Matrix (soil/water): 30IL_ Lab Sample ID: MCND60

.Level (low/med): LOW_ Date Received: 10/29/94

"'• Solids: _84.7 Uoc^Js tfvx'. KcfS fctlsf *.

Concentrat ion Units (ug/L or ing/kg dry weight) : MB/KG

1 1ICflS No. 1 Analyte1 11 74e:9-9iZ)-5 1 Rlum mum1 7440-36-0 Ifintimony1 7440-38-2 1 firsenic1 7440-39-3 I Par i umI 744^1-41-7 1 Beryl 1 iumi 7440-43-9 1 Cadmium1 /440-/0-c: 1 Calcium1 7440-47-3 1 Chromium17440-48-4 1 Cobalt17440-50-8 ICoooer1 7439-69-6 1 Iron17439-92-1 ILeadi 7439-95-4 1 Magnesiumi 7439 -9 & -5 1 Manganesei 7439-97-6 t Mercuryi 74412-02-0 1 Nickeli 7440-09-7 I Potassiumi 778!=:— 49— £ 1 Sel eni um17440-22-4 ISilver1 7440-23-5 1 Sodium1 7440-28-0 1 Thai 1 i um1 7440-62-2 1 Vanad i um1 7440-66-6 1 Zinc1 ICvanide1 1

Concentrat ion

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FORM I - IN ILMI33. 0

U.S. EPA - CLP 000014

1 " EPA SAMPLE NO.INORGANIC ANALYSES DATA SHEET _____________

II MCND61

Lab Name: ITflS PITTSBURGH _________ Contract:

Lab Code: ITPR_ Case No. : ££B4Ci_ 3AS No. : _____ SDG No. : MCND50

Matrix (soil/water): SDIL_ Lab Sample ID: MCND61

Level Clow/med): LOW_ Date Received: 10/29/94

% Solids: _79.9 L

Concentration Units (ug/L or mg/kg cry weight): M5/K5

i 1ICAS No. 1 Analyte1 11 74cl9-90-5 1 Aluminum1 7440-36-0 1 ftnt imony1 7440-38-2 1 Arsenic17440-39-3 1 Barium1 7440-41-7 1 Beryl 1 i urn1 7440-43-9 1 Cad m i urn1 7440-70— S 1 Calcium1 7440-47-3 1 Chrom i urn17440-48-4 1 Cobalt1 7440-50-8 1 Cooper17439-89-6 1 Iron17439-92-1 ILead1 7439-95-4 1 Magnesium1 7439-96-5 1 Manganese1 74 9-97-6 1 Mercury17440-02-13 1 Nickel17440-09-7 (Potassium1 7762-49-2 1 Se i em urn17440-22-4 ! Silver17440-23-5 1 Sodium1 7440-28-0 1 Thai 1 iun1 7440~6£~£ i Vanadium1 7440-66-6 1 Zinc1 ICvanideI 1

Concentrat ion

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AND ROOTS _- <X A€/V.o

tyty

Before :

After:

Texture: MED

Artifacts: YES

Y „ u i

FORM I - IN ILM03.

AR3U5399

U. S. EPA - CLP r^ , _ _£^ OOU015

1 EPft SAMPLE NO.INORGANIC ANALYSES DATA SHEET ______________

I II MCND64 I

Name : 1TAS_PITTSBURGH_________ Contract : 68-03-0046 I ______________I

Lab Code: ITPfl_ Case No.: 22S40_ SflS No.: _____ SDG No.: MCND50


Level (low/med): LOW_ Date Received: 11/04/94

% Solids: _75. 1 \__oc rb\yv* '. Ko ?


CflS No.

7429-90-57440-36-07440-38-27440-39-37440-41-77440-4J--97440-70-2^440— 4 /-^7440-48-47440-50-87439-S9-&743^-92-17439-95-4743S-96-57439-S7-&7440-02-07440-09-77782-49-27440-22-47440-23-57440-28-S7440-&2-27440-&D-6

flnalyt e

AluminumAnt i monyArsenicBar i urnBeryl 1 iumCadmiumCalciumChromiumCobaltCopperIronLeadMagnesiumManganeseMercuryNickelPotassiumSeleniumSilverSodiumThall iumVanadiumZincCyanide

Concentrat ion

(12700-37Trs. 0£440. 560. 50

225021.0S-234. 6187001 203l£010\ 36810.27114. &111 701 1 - 70.51(bTT"TT0&3. \ 153^ —— "

C

U

BB

B

IIB1UBU

11

Q

N

*

*

*

EE

W

^

T

M

PPPPPPPPPPPPPPCv1PPPPPPPPNR


Color After: J3ROWN___ Clarity After: _____ Artifacts: YES__

Comments:ART I FACTS: __STONES_____ ______n—T—T______________________________CS? V f^ 1 CLs>>. o (/i-e ,~* l] tAaJ^r* .

FORM I - IN ILM03.0

U.S. EPA ~000016

1 EPA SAMPLE NO.INORGANIC ANALYSES DATA SHEET ______________

I iI MCND65 I

Lab Name: ITAS_PITTSBURGH _________ Contract: 68-03-0048 i ______________ I

Lab Code: ITPA _ Case No.: 2284iZi_ SAS No,: _____ SD6 No.: MCND50


Level Clow/med): LOW _ Date Received: i 1/04/94

% Solids: 86.3 U- o I -i,—

Concentration Units (ug/L or mg/kg dry weight): MS/KG

1CAS No. 1 Analyte

17429-90-5 1 Aluminum7440- 6-0 1 Ant imony7440-36-c: 1 Arsenic7440-39-3 i Barium7440-41-7 IBeryllium7440— j-9 1 Cadm i urn7440— 70— £ 1 Calcium7440-47-3 1 Chromium7440-48-4 1 Cobalt7440-50-S 1 Copper7439-89-6 1 Iron7439-92-1 ILead7439-95-4 1 Magnesium7439-96-5 1 Manganese7439-97-6 1 Mercury7440-02— 0 1 Nick e 17440-09-7 1 Potassium77S2-49-£ 1 Selenium7440-22-4 1 Silver7440-23-5 ISodium7440-28-0 1 Thai 1 i urn7440-62-£ 1 Vanadium7440-66-6 IZinc

i Cvanide1

Concentrat ion

fn f IT* IT; i

2. 7/ A • *l 1

/32. 7(0.270T ¥f 4711. 94. 44. 09040\ 5.6\ 160\£030.JJTf6 . 9\(6500.580.45<S9.1Si0.90/£2. fT(20. 7

C

UBIBIBUB

B3

UBBUUBU\}

Q

N

#

#

*

EE

1

1IP

(2^ 1 PIPIPIPIPIF1i PIPIPIPIPIPIPICVIPIPIPIPIPIPIP

-=snpINR1

I______ ______ ________ _ ____ _I

Color Before: BROWN___ Clarity Before: _____ Texture: FINE.

Color After: BROWN___ Clarity After: _____ Artifacts: YES_

Comments:ARTIFACTS:_STONES

A:

FORM I - IN ILM03.

U.S. EPft - CLP X^ \ uOUOl?1 EPA SAMPLE NO.


I MCND66^ Name: ITAS PITTSBURGH_________ Contract: 66-03-0048 I

Lab Code: 1TPA__ Case No.: 22840_ SAS No.: _____ SDG No.: MCND50


\ Level (low/med): LOW__ Date Received: 11/04/94

; % Solids: _S7.2 I—o C tv trv ". Ko(?S£>


1 1JCftS No. 1 Analyte1 11 7429-9121-5 Iflluminum1 7440-36-0 1 flnt imony1 7440-36-£ 1 Arsenic7440-39-3 1 Barium7440-41-7 1 Beryl 1 ium7440-43-S 1 Cad m i urn7440-70-;=: I Calcium7440-47-3 1 Chrom i urn7 440-48- + 1 Cobalt7440-50-8 1 Copper7439-S9-6 llron7439-92-1 ILead7439-95-4 1 Magnesium7439-96-5 1 Manganese74.i9-9 ,--6 1 Mercury7440-02-0 1 Nickel744.121-09-7 | Potassium7782-49-2 1 Selenium744S-22-4 1 Silver7440—23—5 1 Sod i urn7440-28-0 I Thai 1 ium7440-62-2 1 Vanadium7440-66-6 IZinc

1 Cyanide1

Concent rat ion

(10200

£-r-Y4.21/ 363(0.50

"w.ji i-rf320/ 15. 3/ 5.7/ 15. 9/12700

128\ 1270\3440. 10fT0. 6\\ 660U.I0. 45OT4.3iTi. qiTi

/ 'O fFC.O. <_)E OT Q\ O j. j^ —— __s

c

1u*IbIU11IB11111IU1

UIBU\}

Q

N

*

#

*•

EE

1*^M

1IP

ElPIPIPi PIPIPIPIPIPIPIPIPIPICvIPIPi P1IPIPIPIP

31 PiNRt

Color Before: BROWN___ Clarity Before: _____ Texture: FINE.

Color After: BROWN___ Clarity ftfter: _____ flrtifacts: YES__

Comments:ARTIFACTS:__STONES AND ROOTS

FORM I - IN ILM03. 0

AR3u5l*02

U.b. EPA - CLP

1 EPAINORGANIC ANALYSES DATA SHEET

I MCND67Lab Name: ITAS PITTSBURGH_________ Contract: 6S-D3-Q04& I

Lab Code: ITPA_ Case No.: c'£S40_ SAS No.: _____ SDG No.: MCND50

Matrix (soil/water): SOIL_ Lab Sample ID: MCND&7

Level (low/med): LOW_ Date Received: 11/04/94

% Solids: _95.4 Loc aJa'ttvn -. <<.o ?S B>

Concentration Units (ug/L or mg/kg dry weignt): MG/KG

1 i i1 CAS No. 1 Analyse 1 Co.ncentrat i on1 ! 1l74£S-9i3-5 miuminum i (135(8I7440-3&-0 Iflntimony 1 — cTTST7440-3&-C; 1 Arsenic i / .4I/440— j -j, i Barium i (34.4/44iZi-*+ 1-/ l & e r y i i i u m i [0.4 j,7440-43-9 1 Cadmium 1 0T31744fl-/iZi-c: ICalcium i /&77/440-4 (—& (Chromium i /.£4. 17440-4S-4 ICobaii: i / 6. 17440-50-8 1 Copper 1 I 1 1. B7439-89-6 1 Iron 1 U930iZi7439-9£-l ILead 1 \ 8. £7439-95-4 1 Maqnes i urn 1 "\£86GH7439-9&-S 1 tnanqanese i \1 1&7439-97-S 1 Mercury I 07~T07 40-08-0 t Nickel i fT£. 4\7440-09-7 1 Potassium 1 ill70778£-49-£ 1 Selenium I \1. 47440-££-4 1 Silver 1 0T4~£7440-£3-5 i Sodium i fSBTR7440-2S-0 1 Thallium 1 0TS37440-6£-£ I Vanad i urn 1 A\ . 4\7440-66-6 IZinc 1 32.7

ICvanide 1 "" —— ^1 1

C

1u(Bl&U

IB1IB

1

11U

1

UBU

-

Q

Nj

#

*

*

EE

1s^v i M

iIP

RJPIPIPi PIPiPIPIPiPIPIP!PIPicyIPIPIPIPIPIPIP

*=3T|pI N R 1I

Color Before:

Color After:

Comment s :ARTIFACTS:<R V - CDv*

'



STONES^XzC~p*^ A It"*-** - w^_S^ v<4La yirv,

k O

Texture: FINE

Artifacts: YES

FORM I - IN ILM03.

AR3(J5<403

U.S.

1 EPA SAMPLE NO.INORGANIC ANALYSES DATA SHEET _____________

I" I MCND50

_< Name : ITHS_PITT3BURGH _________ Contract : 68-03-0046 I

Lab Code: ITPfl _ Case No.: ££840_ SAS No.: _____ 5DG No.: MCND50

Matrix (soil/water) : SOIL_ Lab Sample ID: MCND50

• Level (low/med): LOW _ Date Received: iiZi/£9/94

' % Solids: _73.9 ^- oc*tjc\ <m '. K_oPSP> <o

Concentration Units (ug/L or mg/kg dry weight): MG/K5

1CAS No. 1 Analyte

174i=:9-90-5 lAlurainum744ift— j&— ta 1 Ant imony7440-j,8-£ 1 Arsenic7440-39-3 1 Barium7440-H- 1 -7 1 Bery 1 1 i urn744ti-*t3— 9 1 uadm i urn7440-76-E 1 Lalcium7440-47-3 1 Chromium7440-46-4 1 Cobalt7440-50-8 1 CoDoer743 -6 -6 1 Iron743^-<?£-l ILead7439 -95—4 1 Magnesium7439-96-5 1 Manganese74 9-9 /— 6 1 Mercury7440-ei£-ti 1 Nickel7440-lft(s— 7 1 Potass i urn776c:-49-E: ISelenium7440-££-4 1 Silver7440-£3-5 1 Sodium744i3-£8-0 1 Thai 1 i ura7440-fe£-£ I Vanad i urn7440-66-6 I Zinc

1 Cvanide1

Concentrat ion C

C14900)3. 1

£0.~4*1103

0.6£iZi. 601090tZ.i > c!7.046. 531&060. i£030,149\Z5.0TT4. 51_647\ £. 70.5£A0£)/5.9(44. £

U

BBB

B

B

UB

I-\119J.lV^

Q

N

#

#

*

EE

1CjVtM

1IP

A

3Z

pppp'pppppppPpcvppppppppNR



Comments:ARTIFACTS:_STONES________________________________________________

FORM I - IN ILM03. 0

H - OOUU04i EPfi SAMPLE NO.

INORGANIC ANALYSES DATA SHEET ______________II MCND51

Lab Name: ITAS PITTSBURGH_________ Contract: 68-D3-0048 1

Lab Code: ITPfl_ Case No.: 22840_ SAS No.: _____ SDG No.: MCND50

Matrix (soil/water): SDIL_ Lab Sample ID: MCND51

Level <low/med) : LOW_ Date Received: 18/29/94

% Solids: _73.9 V—oc_^buv^- Kof£ £>(D\fr/o-


1CAS No. 1 Analyte

174d9-9w-b [Aluminum7440- .6-0 i Hnt imony7440-38-£ 1 Arsenic/440-jCj-j, j Bar i um7440-41-7 iBeryllium7440-43-9 1 Cadm i um7440-70-2 i Calciumi 440-4 1-4 1 Chromium7440-48-4 1 Cobalt7440-50-8 ICooper7439-89-6 1 Iron7439-92-1 ILead7439 -9 5-H i Magnesium7439-96-5 1 Manganese7439-97-6 1 Mercury7440-02-0 1 Nickel7440-09-7 1 Potass i um7782-49-2 1 Se 1 en i um7440-22-4 ISilver7440-23-5 1 Sodium7440-28-0 1 Thai 1 i um7440-62-2 1 Vanadium7440-66-6 1 Zinc

i Cvanide1

Concentrat ion C

874013. 254.0110

0.382. 2398015.95.01669700

1770L_£661 7. 2he. 6\ 64913.80.52A 90

/17.0{£4.9\1£3\— --*

U

B

B

—

t?

UB

Q

N

#

*

+•

EjE

ICT

1

PP..P"PPpPPp.PPPPPCvPPPPPPPPNR


Color flfter: BROWN___ Clarity After: _____ Artifacts: YES__

Comments:ARTIFACTS:STQNES

FORM I - IN ILM03,

APPENDIX B

GLOSSARY OF QUALIFIER CODES

GLOSSARY OF DATA QUALIFIER COOES (INORGANIC)

CODES RELATED TO IDENTIFICATION(confidence concerning presence or absence of analytes):

U «- Not detected. The associated number indicatesapproximate sample concentration necessary to bedetected.

(NO CODE) - Confirmed identification.

B «• Not detected substantially above the level reportedin laboratory or field blanks.

R - Unusable result. Analyte may or may not be presentin the sample. Supporting data necessary toconfirm result.

CODES RELATED TO OUANTITATION(can be used for both positive results and sample quantitationlimits):

J « Analyte Present. Reported value may not beaccurate or precise.

K = Analyte present. Reported value may be biasedhigh. Actual value is expected to be lower.

L • Analyte present. Reported value may be biased low.Actual value is expected to be higher.

[ ] = Analyte present. As values approach the IDL thequantitation may not be accurate.

UJ = Not detected, quantitation limit may be inaccurateor imprecise.

UL = Not detected, quantitation limit is probablyhigher.

OTHER CODES

Q - No analytical result.

APPENDIX C

SUPPORT DOCUMENTATION

November 29, 1994 INTERNATIONAL TECHNOLOGY CORPORATION

CASE NARRATIVE

Laboratory Name: ITAS Pittsburgh, PennsylvaniaLaboratory Code: ITPA

Project Name: USEPA/CLPInorganic SOW: ILM03.0Project Number: 662004

Work Order Number: Q410361 and Q411091Contract Number: 68-D3-0048

Case Number: 22840SDG Number: MCND50

Sample Number:MCND50 MCND54 MCND58 MCND64MCND51 MCND55 MCND59 MCND65MCND52 MCND56 MCND60 MCND66MCND53 MCND57 MCND61 MCND67

Shipment

Sixteen soil samples were received at the ITAS Pittsburgh Laboratory on October 29 and November1994, for metals analysis.

Metals

A duplicate digestion and a matrix spike were performed on sample MCND50. A serial dilution wasperformed on sample MCND51.

The matrix spike recovery exceeded the 75 to 125 percent control limit for antimony. All associatedresults were flagged with an "N" qualifier.

The serial dilution percent difference exceeded the control limit for vanadium and zinc. All associatedresults were flagged with an "E" qualifier.

The duplicate digestion RPD exceeded the 20 percent control limit for copper, iron, and mercury. Allassociated results were flagged with a "*" qualifier.

Sample MCND51 was over the calibration range for mercury, and required dilution.

Page 1 of ,1

5103 Old William Penn Highway, Export, Pennsylvania 15632- (412) 731-8806

U. S. EPfi - CLP - ^^U00002

COVER h'ftGE - INORGANIC fiNALVSES DATA PACKAGE

•» Name: ITAS_PI TTSBURuH _________ Contract: 68-05

"tab Code: ITPA _ Case No. : ££840 SftS No. : _____ SDG No. : MCND5O

SOW No. : ILM03. 0

£PA Sample No. Lab Sample IDMCND50 _______ MCND5®

MCND5£iD

_MCND51 ______ MCND51

_MCND53 ______ _MCND53.MCND54 ______ _MCND54

MCND55.MCND56 ______ J*lCND5bJ1CND57 ______MCND58_MCND59 hiCND59

.MCND& 1 ______ _MCNDb iilCNDb4

J-1CND65 ______ _KiCNDb5J1CND66 _______ _MCND66MCND67 MCND67

Were ICP inter el ement correct i o n s a p p l i e c i ? Yes /No YES

Were ICP back ground correct ions applied ? Yes/No YESIf yes - were raw aat a generated beforeapplication of oackground corrections '•' Yes/No Nu_

Comment s :

I certify that this data package is in compliance with the terms andconditions of the contract, both technically and for completeness, forother than the conditions detailed above. Release of the data containedin this hardcop-v data package and in the comput ei—readable data submittedon floppy diskette.has been Authorised by the Laboratory Manager\or theManager's desigjieeY as \eryfiifd by/trte following sigta^ture.

Si

Date: ________/ // T/7T Title:

7COVER PAGE - IN ILM03. 0

AR305klQ REVIEWED RY- r«jDATE- ///*•>*

Signature

Signature

shed

Rel

ved by:

(Signature

eceived by:

(Signature

B

Relinquished

tory by:

s •t -IsR - a

inquished by

DDM1I

C H ~? O O

S

* frs? o

I tf o5 °i s& *! I

a5

t-rflii«a S •* £g2 |?w So

Signature

Signat

Relinquished

Signature

iI £ e- s-9>yi

Relinquished

DD

S

U.S. EPfl - CLP

3 000030BLflNKS

Lab Name: ITftS_PITTSBURGH_________ Contract: 68-D3-004S

j Lab Code: ITPft_ Case No.: 22840_ SftS No.: _____ SDG No.: MCND50!• Preparation Blank Matrix (soil/water): SOIL_

I Preparat ion Blank Concentration Units (ug/L or mg/kg): MS/KB

1111Iftnalyte1(Aluminum1 ftnt imony_Iflrsenic1 Barium1 Beryl 1 iumI Cadmium1 Calcium[Chromium1 Co baitICopper1 IronILead1 Magnesium1 Manganese1 MercuryINickel1 Potassium1 Selenium(Silver1 SodiumIThallium1 Vanadium1 Zinc(Cyanide1

Init ialCal ib.Blank(ug/L)

11.0 I

___ 12.2 !£.3 t0.5 10. 1 I1.5 16.3 11.8 11.9 11.4 !

-£.4 11.4 1

11. 1 10.4 10. £ t4.3 1

381.0 12.6 12.0 19.2 14.0 1-1.4 13.5 1

11

1111

Cl1

UlUiUlUlUlUlUlUlUlUlBlUlUlUlUlUlUlUlUlUlUlBlBl

11

1 I I I1 I I I

Continuing Calibration 1 Prepa- 1 1Blank ( jg/L) I ration I I

1 C 2 C 3 Cl Blank Cl 1 M1 1 1

11.UIU1 1 1 . 0 1 U 1 11.0IUI 2. 200 1 U 1 1 P___ 12. £ 1UI ___ 12.2 IUI ___ 12.2 IUI (g§. 056) BMP

~d. J IUI t.j; IUI i. IUI W. 4€TtflUllP0.5 IUI 0,5 IUI 0.5 IUI 0. 1001111 IP

-0. 1 1 B 1 0. 1 1 U 1 0. 1 1 U 1 0. 020 1 U 1 1 r1.5 IUI 1.5 IUI 1.5IUI 0. 300IUII6.3 IUI &.3 IUI &.3 IUI £.5&41BIIP~X1.3 IUI 1.3 IUI -3.2 IBI 0.3&01UIIP1.9 IUI 1.9 IUI -2.5 IBI 0.380IUIIP

-2. 5 IBI 1.4 IUI -2.7 IBI 0. 280 1 U 1 1 P-2.0 IBI 1.5 IUI -2. 8 IBI 1.366 IBI IP1.4 IUI 1.4 IUI 1.4 IUI 0.280IUMP

11.1 1 U 1 11.1 IUI -23. 1 1 B 1 £. 220 1 U 1 1 P0.4 IUI 0.4 IUI 0.4 IUI 0.0S0IUIIP0.2 IUI 0.£ IUI 0.2 IUI 0.103IUIICV4.3 IUI 4.3 IUI 4.3 IUI 0.86QMJIIP

381.0 IUI 381.0 IUI -733.6 IBI 7&.200IUI1P _2. 7 I B 1 2. & 1 U 1 2. & 1 U 1 0. 520 1 U 1 1 P2. 0 IUI £.0 IUI 2.0 IUI 0. 400IUIIP _9.2 IUI 9.2 IUI 9.E IUI 1.840IUIIP.4.0 IUI 4.0 IUI 4.0 IUI 0. 800IUIIP-2.8 IBI 1.4 IUI -2. 4 IBI -0.326 IBI IP3.8 IBI 5.2 IBI 3.8 IBI 1.23&IBIIP

I I I I I I 1 I I N RI I I I I I I I I .

K•'. FORM III - IN

RR305M7

U.S. EPfl - CLP

BLANKS

r-! Lab Name: ITfiS_PITTSBURGH _________ Contract: 68-03-0048

.'Lab Code: ITPfl __ Case No.: ££840_ SflS No.: _____ SDG No.: MCND50I -~n-" — - —

| Preparation Blank Matrix (soil/water): SOIL_iPreparat ion Blank Concent rat ion Units (ug/L or mg/kg) : MS/KG

4<ri.ii1 Analyte

; AluminumAnt imony

\ rium-_^ry 1 1 ium1 Cadmium

! 1 Calcium1 Chromium(Cobalt(Copper1 IronILead1 Magnes i urn(Manganese

. (Mercury(Nickel(Potassium: 1 Selenium(Silver1 Sodium1 Thall ium1 Vanadium

• (Zinc• 1 Cyanide

I

Init ialCalib.Blank(ug/L) C

11

Continuing Calibrat ion 1Blank (ug/L) 1

i C £ C 3 Cl1

11.0 IUI 11.0 (Ul 11. 0 IUI-15.3 IBI !£.£ IUI !£.£ IUI

£.3 IUI 2. 3 IUI £.3 IUI0.5 IUI 0.5 IUI 0.5 IUI

-0. 1 IBI -0. 1 IBI 0. 1 IUI1.5 IUI 1.5 IUI 1.5 IUI6.3 IUI 6.3 IUI 6.3 IUI-3.0 IBI -£.4 IBI -1.8 IBI-£.3 IBI -2. 1 IBI 1. 9 (Ul-£. £ IBI -£.0 IBI 1.4 IUI-1.3 I B I I I I I1.4 IUI 1.4 IUI 1.4 IUI

-15.6 IBI -18.4 IBI 11. 1 IUI0.4 IUI 0.4 IUI 0.4 IUI0.£ IUI 0.2 IUI 0.2 IUI4 . 3 I U I I I I I

-432.9 IBI -601.3 IBI -396.8 IBI£.6 IUI 2.6 IUI 2.6 IUI2.0 IUI £.0 IUI 2.0 IUI9.2 IUI 9.£ IUI 9.2 IUI4.0 IUI 4.0 IUI 4.0 IUI-1.8 IBI -£.6 IBI 1.4 IUI3. 4 IBI 3. 4 IBI 3. 8 IBI

I I I I I II I I I I I

Pre pa-rat ionBlank

0. 100

C

U

1I111 M1IPIP1 Pi pIP.IPIPIPIPIPIPIP1 PIPICVIPIPIPIPIPIPIPIPINR1

FORM III - IN ILM03.0

AR3G5M8

U.S. EPA - CLP

SPIKE SAMPLE RECOVERY

I MCND50SLab Name: ITflS_PITTSBURGH _________ Contract: 68-03-013481

Lab Code: ITPft __ Case No.: ££840_ SflS No.: _____ SD6 No.: MCND50

j Matrix (soil/water) : SOIL _ Level (low/med) : LOW

% Solids for Sample: _73. 9

Concentration Units (ug/L or mg/kg dry weight): MB/KG

1I

.1Al Analyte

1, 1 Aluminumj (Antimonyj lArsenic! (Bariumi (Beryl 1 ium4 (Cadmium(Calcium

. 1 Chromi urn' ICobalt(Copper1 Iron

j (Leadj (Magnesiumi (Manganese

1 Mercury(Nickel(Potassium1 SeleniumISilver. (Sodium

1 Thall ium1 Vanadium

,-IZinc(Cyanide

- 1

ControlLimit•/.R

75-12575-12575-12575-12575-125

75-12575-12575-125

75-125

75-125

75-125

75-12575-125

75-12575-12575-125

Spiked SampleResult (SSR)

37.6164501.4447573. 395211.877112.2044

66. 26£®124. 0209104.4139

184. 1949

254. 29473. 92£9

133. 1864

493. 116810.3821

480. 0670161.7011231.9562

CSample

Result (SR) C

13. 1445IU£0.38021103.024710. 6160IB0.5954 IB

122. 158617. 0365 IB46.52621

160.06831

1149.447815.0048114. 47001

1£. 6806 10.51551U

15.9179144.20651118.90201

11

SpikeAdded (SA)

126.87515. 50515.50

12.8912.89

51.55128.8764.44

126.87

128. 870.64

128.87

515.5012.89

515.50128.87128.87

C29.~ci93.391.287.490. i

85.690.839.8

96.3

81.4-169.092. 1

95. 160.5

92.091. £87.7

111

Q) M1INR

NIPIPIPIPIPINRIPIP1(N«-IPINRIPICVIPINRIPIPINRIPIPIPINR1

Comment s:

FORM V (Part 1) - IN ILM03.0"i

AR30514J9

U.S. EPfl - CLP

5B EPfl SflMPLE NO.POST DIGEST SPIKE SflMPLE RECOVERY

Name : ITflS PITTSBURGH

ab Code: ITPfl

Contract: 68-D:

Case No. : ££840 SflS No. :

1 11 MCNDStffl 1

3-0048 1 1

SDG No. : MCND50

atrix (soil/water) : SOIL _ Level (low/med) : LOW __

Concentration Units; ug/L

Analyt e

flluminumflnt imonyflrsenicBariumBeryl 1 ii.mCad mi urnCalciumChromiumCobaltrnoper

in. adMagnesi urnManganeseMercuryNickelPotassiumSeleniumSilverSodiumThai 1 iumVanadiumZincCyanide

ControlLimit•/.R

Spiked SampleResult (SSR) C

118.76

~

SampleResult (SR) C

12. £0 U

fldded (Sft)

180. 0

%R

94.0

1 11 I1 1

Gl Ml1 1INRtIP 1INRII N R tINRIINRIINR!I N R fINRIINRIINR IINRII N R iINRIINRIINRIINRII N R IINRIINRIINRIINRIINRIINRI1 1

omment s :

j

FORM V (Part £) - IN ILM03.0

U.S. EPft - CLP OUUU41

6 EPft SAMPLE NO.DUPLICATES

1 MCND50DLab Name: ITftS PITTSBURGH_________ Contract: 68-03-13048 1

(Lab Code: ITPft_ Case No.: £2840_ SAS No.: _____ SDG No.: MCND50^

]Matrix <soiI/water): SOIL_ Level (low/med): _LOW_

•{ % Solids for Sample: _73. 9 % Solids for Duplicate: _73. S


11 Analyte1(Aluminum(Ant imony1 Arsenic1 Barium1 Beryl 1 ium1 Cadmium1 Calcium1 Chromium(Cobalt1 Copper1 Iron(Lead1 Magnesium(Manganese1 MercuryINickel1 Potassium1 SeleniumISilver1 Sod ium(Thai 1 ium1 Vanadium1 Zinc(Cyanide1

ControlLimit

51.6

1288.7

10.3

1.3

2.612.9

Sample (S) C'

14909.834413. 1445 IU20. 38021103.024710.6160IB0.5954 IB

1094. 4726 IB22. 158617. 0365 IB46.52621

23114.8115160.06831

£082.51821149.447815.0048114.47001

847. £092 IB2.680610.5155IU

102. 2849 IB5.9179144.20651118.90201

11

Duplicate (D) C

15924.577613. 1445IU£0.75391112.679910,6341 IB0.8171 IB

928. 5573 IB23.364917, 2298 IB60.0631 1

24578.9961 173.66451

£140. 22041141.578713.7145114.02151

920. 0490 IB2.6651 10.51551U

102. 7231 IB. 8. 0366 146.50041136.58101

11

RPD

6.6

1.89.02.9

31.416.45 "**2.7£5. 46. 1£0. 32.75. 4

£9.63. 18.20. 6

0.430.45. i13.8

11

Ql M1IPIPIP1 pIPIPIPIPIP

*IPIP

#IPIPIP

*ICVIPIPIPIPIPIPIPIPINR1

FORM VI - IN ILM0;

U.S. EPfl - CLP «n,..% M *'U000449 EPft SflMPLE NO.

ICP SERIfiL DILUTION

I I MCND51Lj t_»o Name: ITftS_PITTSBURGH_________ Contract: 68-D3-0048 I______________i-jLab Code: ITPfl_ Case No.: ££840_ SflS No.: _____ SDG No.: MCND50i!Matrix (soil/wacer): SOIL_ Level Uow/med): LOW_it

: Concentration Units: ug/L

11Iflnalyt e11 filuminum__1 ftnt imony1 firs en ic1 Barium1 Beryl 1 ium1 Cadmium1 Ca 1 c i u m _1 ChromiumICobalt1 Coooer1 Iron(Lead1 Magnesium1 Manganese1 MercuryINickel1 Potassi urn1 SeleniumISi 1 ver1 Sod i urn1 Thai 1 ium1 Vanadium1 ZincI

Initial SampleResult <I)

33570. 0912.20

£07. 554£3. 35

1.478.59

___ .15284.31 _61.0419.21

639. 1175559.88473. 466798.461030. 43

40.752493. £8

14.79£. 00

731.7665. 1495.61

47£. 15

C

U

B

~B

B

UB

Serial 1Dilution 1

Result (S) Cl1

___ 34758. 40 _ 1 _l6 1 . 00 IUI£18.35 1 1431.35 IBI0.90 IBI7.50 IUI

16092. 10 IBI48.35 IBI9.50 IUI

646.40 1 178874.75 1 1487.50 1 16986.70 IBI1068.65 1 1

1 153.85 IBI

1905.00 IUI13.95 IBI10.00 IUI787.65 IBI76.50 1 185.95 IBI

525. 35 1 11 1

%Differ-ence

__ 3.5_

5. £1. 9

38. S100.0

__ 5. 3_20. a100.0

1. 14.43. 02.83. 7

32. 1100. 05. 7

7. 617.410. 1cTrrs s«- — •*

iiQl M

1_IP_IPIPIPIPIPIPIPIPIPIPIPIPIPINRIPIPIPIPIPIP

EIPEIP

1

FORM IX - IN ILM03.0

; u. s. EPfl - CLP

i 10 OOUU45I Instrument Detection Limits (Quarterly)

'Lab Name: ITflS_PITTSBURGH_________ Contract: 68-D3-0048

I Lab Code: ITPfl__ Case No.: ££840 SflS No.: _____ SDG No.: MCND50i — i

j ICP ID Number: TRflCE______ Date: 10/15/94

]Flame flfl ID Number : .__________•iFurnace flft ID Number :

t Comments

I111 ftnalyte1(AluminumIftnt imony1 Arsenic1 Barium1 Beryl 1 ium1 Cadmium1 Calcium1 ChromiumICobalti Copper1 IronI Leadt Magnesium1 Manganese1 MercuryINickel1 Potassium1 Selenium(Silver1 Sodium1 Thai 1 ium1 Vanadium1 Zinc1

Wave-length(nm)

189.04

££0. 35

196.1213

190.86

Back-ground

CRDL(ug/L)

3006010£0055

50001050£51003

500015

0. £40

5000510

5000105020

I1

IDL 1(ug/L) 1 M

1INRINR

S. SIPINRINRINRINRINRINRINRINR

1.41PINRINRINRINRINR

£. &IPINRINR

4.0IPINRINR1

FORM X - IN ILM03.

U. S. EPfl - CLP

10 OOU04B: Instrument Detect ion Limits (Quarterly)

I Name : ITflS_PITTSBURGH__________ Contract : 68-D3-004S

, Lab Code: ITPfl__ Case No.: ££840_ SflS No.: _____ SDG No.: MCND50

ICP ID Number: Jft&lE______ Date: 10/15/94

Flame flfl ID Number : __________

'Furnace flfi ID Number :

Comments:

111I ftnalyte1(Aluminum1 ftnt imony1 Arsenic1 Barium(Beryllium1 Cadmium1 Ca 1 c i u mI ChromiumICobalt1 Cooper1 IronILead1 Magnesi urn1 Manganese1 MercuryINickel1 Potassium1 Selen i urn[Silver1 Sodium1 Thai 1 ium1 Vanadium1 Zinc1

Wave-length(nm)

308. £££06.84

493. 41313. 04££8. 80317. 93£67. 7£££8. 6£3S4. 75£59. 94

£79. 08£57.61

£31 . 60766.49

3£8. 07588. 99

£9£. 40£13.86

Back-ground

CRDL(ug/L)

£006010

£0055

500010

50£51003

500015

0.£40

5000510

50001050£0

11

IDL 1(ug/L) 1 M

11 1 . 0 i P1£.£IP

1NR0.51P0. 1 1 P1 . 5 1 P6 . 3 1 P1 . 8 1 P1.9IP1 . 4 1 P1 . 5 1 P

INR11. IIP0.4 IP

INR4. 3 IP

381.0IPINR

£.0IP9.£IP

INR1 . 4 1 P1 . 0 1 P

1

FORM X - IN ILM03. 0

; U. S. EPft - CLP

, le W047j Instrument Detection Limits (Quarterly)

J Lab Name: ITftS_PITTSBURGh_________ Contract: 63-03-0048

jLab Code: ITPft_ Case No.: ££840_ SfiS No.: _____ SDS No.: MCND50

j ICP ID Number: ___________ Date: 10/15/94

iFlame flft ID Number : LEEMftN_PS£00

,; Furnace ftfl ID Number :

Comments:

1111 ftnalyte11 Aluminum1 ftnt imony1 Arsenic,1 Barium1 Beryl 1 ium1 Cadmium '1 Calcium1 ChromiumICobalt1 Coooer1 IronILead1 Magnesium1 Manganese1 MercuryINicUel1 Potassium1 SeleniumISilver1 Sodium1 Thai 1 ium1 Vanadium1 Zinc1

Wave-length(nm)

£53. 7tZi

Back-ground

CRDL<ug/L)

£006010£00

55

50001050as1003

5000150.240

5000510

50001050£0

11

IDL 1(ug/L) 1 M

1INRINRINRINRINRINRINRINRINRINRINRINRINRINR

0.2ICVINRINRINRINRINRINRINRINR1

FORM X - IN ILM03.

U.S. EPfl - CLP

UOU057i wPREPARATION LOG

j-w-rj Name: ITflS_PITTSBURGH_________ Contract: 68-D3-0048('Lab Code: ITPft_ Case No. : _££'S40__ SflS No.: _____ SDG No.:MCND50

I Method: P

1 EPft1 Sample1 No.1ILCSS1 MCND501 MCND50D1 MCND50S _IMCND511 MCND52 __IMCND531 MCND54IMCND55IMCND56IMCND571 MCND581 MCND59IMCND&0IMCND&lIMCND&4IMCND65 __IMCND&& __IMCND67iPBS1111111111111

Preparat ionDate

11/11/9411/11/9411/11/94

_ll/ll/94 _11/11/94

_ll/ll/94 _1L/11/9411/11/9411/11/9411/11/9411/11/94ll/ 11/9411/11/9411/11/9411/11/9411/11/94

_li/ll/94 _11/11/9411/11/9411/11/94

Weight(gram)

1,0131.051.05

_ 1.05 _1.041.051.041.051.021.011.051.031.011.011.041.041.031.0£1.011.00

Volume<mL)

£00800200

___ £00 __£00

____ £00 ___

£00£00£00£00£00£00£00£00£00£00

____ £00 ______ £00 __

£00£00

FORM XIII - IN ILM03.0

AR3U51*26

13i PREPflRflTION LOGit-

Lab Name: ITflS_PITTSBURGH_________ Contract: &S-D3-0048i| Lab Code: ITPfi_ Case No.:_£E:a40_ SftS No.: _____ SDS No.:MCND50

i Method: CV

1 EPfl1 Sample1 No.1ILCSS1 MCND50 __1 MCND50DIMCND50S _IMCND511 MCND52 __IMCND53IMCND54 __IMCND551 MCND56IMCND57 __IMCND581 MCND59IMCND&0IMCND61 __IMCND64 __IMCND65IMCNDfefeIMCND&7 __IPBS111111I111111

Preparat ionDate

11/07/94_ll/07/9411/137/9411/07/94

_1 1/07/94_1 1/07/94 ___1 1/07/94 __ii/07/9411/07/94

_1 1/07/94 ___1 1/07/94 _11/07/94

_ll/07/94_1 1/07/94 _11/07/94

_1 1/07/94 _11/07/9411/07/94

_ll/07/94 _11/07/94

Weight(gram)

0.05

_ 0.81 __ 0. ae __ 0. £1 ___ 0. £0 ___ 0. £3 _0. £0

_ 0.210.£5

___ 0. £0 ___

_ 0. £0 _0. £3

_ 0. £0 __ 0. ££ __ 0. £4 __ 0. £1

0.£10. £3

__ 0. £0 __0. £0

Volume(tnL)

100____ 100 ___

100____ 100____ 100 ______ 100 ______ 100____ 100 __

100____ 100 ______ 100 __

100

____ 100 ______ 100 ______ 100 ______ 100 __

100100

____ 100 __100

FORM XIII - IN ILM03.0

U.S. EPP - CLP

PNPLYSIS RUN LOG

: ITflS_PITTSBURGH_________ Contract: 68-03-00 ASi; Lab Code: ITPP_ Case No.: ££S40_ SPS No.: _____ SDG No.:MCND50

I Instrument ID Number: TRPCE_______ Method: P_

:Start Date: 11/13/94 End Date: 11/18/94

I

jJ^

1)

'

1

>

t11 -Ji*

]

jijIi!:-;

;;i

EPPSampleNo.

S0SSSICVICVICVICVICB

3fljflB

TRIccvccvCCBzzzzzzzzzzzzzzzzzzzzzzzzzzzzzzICSflICSABCRIccvccvCCBPBSLCSSMCND50MCND50DMCND50S

11

D/F ITime11

1. 001 1 £121.031 1 £161. 001 12 191. 001 1CI231. 001 1££61.001 ic:301. 001 12331.001 1£371.001 1E:401.001 1£441. 001 1£481.001 12311.001 12551.001 1£581. 001 130£1. 001 13061.001 13091.00! 13151. 001 13211.001 13£51.00113291.001 133£1.001 13361.001 13391.00113431.001 13471. 001 13541.001 13581.001 14011,001 14051.001 1408

MCND51 1 1.00114121 1

X- R

flnalyt es

PLSB

AS

X

X

X

XXXXX

X

XXXX

X

Bft

BECDCACRC0CUFEPB

X

X

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X

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TL

X

X

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X

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V zNCN

FORM XIV - IN ILM03.0

U.S. EPA - CLP14ANALYSIS RUN LOG

Lab Name: ITAS PITTSBURGH_________ Contract: 68-D3-0048f - —————————j Lab Code: ITPft_ Case No.: Sa840_ SAS No.: _____ SDG No.:MCND50iij Instrument ID Number: TRACE_______ Method: P_

iStart Date: 11/16/94 End Date: 11/18/94

| 1 EPflj 1 Sample'4 1 No.t 1•flMCND51Li IMCND5£.1 IMCND53.; izzzzzzH 1 ICSA•' 1 ICSABJ ICCVi ICCYj ICCB.1 1MCND541 IMCND551 IMCND56' IMCND57\ IMCND58i IMCND59i 1MCND60i IMCND61i IMCND64j iccv1 ICCBj IMCND65j IMCND66-i IMCND671 1 ICSA!••! ICSftBi ICRI" iccvICCB

:= IPBSI ILCSS.3' IMCND50' IMCND50D

11

D/F ITime11

5. 001 141&1.001 14191.001 14£31.001 14£91. 001 14331. 001 14361.001 14401.001 14441.001 14471.0.91 14511.0011 4541.001 14581.001 150E1.001 15051.001 15091.001 15131.001 15161. 03115201. 001 15231.001 15£71.001 15311.001 15341. 001 15381.001 15411.001 15451.001 15491.001 15521.001 15561.001 16051.001 16091.00116121.0011616

1

% R

Analyt es

ftLSB

AS

XXXXXXXXXXXXXXXX

XXXXXX

BA

BEcDCACR

I

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PIMBIG

11111111

X IX IXIX IX IX 1X IX IX IX IX IX IX IX IX IX I

111

X IXIX IX IX IX I

1

MNHG

NIK S1AI

EIG111I1111

X IX IXIXIXIX IX IX IX IX IX IX IX IX IX IX I

111

X IX IX IX IX IX I

1

N1TI VAIL!

1 11 11 11 11 11 11 11 1I X II X II X II X II X I

ZICN N

-ixi r-fI X II X I1 X 11 X 1I X II X II X II X II X I1 X 11 11 11 1I X II X II X II X II X II X I1 1

i

FORM XIV - IN ILMitf r. 0

RR305U29

U.S. EPfl - CLP

flNflLYSIS RUN LOG

j j Name: ITflS_PITTSBURBH_________ Contract: 6S-D3-004Si| Lab Code: ITPfl_ Case No.: ££840_ SflS No.: _____ SDG No. :MCND5i3ij Instrument ID Number: TRflCE_______ Method: P_

jStart Date: 11/18/94 End Date: 11/18/94ti•t ______J1

ji

ii'i!•!I\tiPj

;>;

1

\iI

ii..•

•

EPflSampleNo.

MCND50SMCND51MCND51LMCND52MCND53222222CCVCCBICSfl*rsflB

II-*»*J V

CCB

D/F

1. 00

1. 005. 00

1. 00

1. 00

1. 00

1. 00

1. 1201. 00

1. 001. 001. 001. 00

-

Time

1620168416£71631163516381642164516491653165617001704

% R

finalyt es

PiLSBPS

XXXXX

XXXXXXX

BA

BECDCACRC0CUFEPB

XXXXX

XXXXXXX

MG

MN

HS

NIK SE

XXXXX

XXXXXXX

flG

NftTL

XXXXX

XXXXXXX

V 2NCN


14ANALYSIS RUN LOG

Lab Name : ITflS_PITTSBURGH_________ Contract: 68-D3-0048

Lab Code: ITPft_ Case No.: 2£840_ SftS No.: _____ SDG No.:MCND50

j Instrument ID Number: Jft&lE_______ Method: P_

iStart Date: 11/16/94 End Date: 11/16/94\ii

jiii}4

j

i

il

.;•

<

\

EPftSampleNo.

S0

SSSSSSicyicyICBICSAICSflBCRIccyCCB222222222222222222222222222222222222222222222222222222222222ccyCCBICSftICSABCRICCVCCB

D/F

1.00

1.001.00

1.001. 001.001. 001.001. 001.001. 001.001.001.001. 001.001. 001.001.001.001.001.001.001.001.001.001.001.001.001.001.001.00

Time

11511201120312051207120912121214121712191222122412261229123112341236123812411243124612481251125312551258130013031305130813101312

% R

flnalyt es

AL

X

X

XXXX

XX

XXXX

XX

SB

X

X

X

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XXXXXXX

AS

~

BA

X

X

XXXX

XX

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BE

X

X

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cD

X

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cA

X

X

XXXX

XX

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XX

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1X I X

111

XII X11

X 1 XX I XX I XX I XX I XX I XX I X

1111111111

XIXX I XX I XX I XX I XX I XX I X

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—

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1X I X

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XIXX I XX I XX I XIX

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1

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X I X111iIX

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1

FORM XIV - IN ILfK*" 0

: U.S. EPR - CLP UOOU64

j flNPLYSIS RUN LOGj

' Name: ITAS^PITTSBURGH_________ Contract: 68-D3-0048

jLab Code: ITPft_ Case No.: £2840_ SftS No.: _____ SDG No.:MCND50

i Instrument ID Number: JA61E_______ Method: P_iiStart Date: 11/16/94 End Date: 11/16/94

EPflSampleNo.

PBSLCSSLCSSMCND50MCND50DMCND505MCNDSiSflMCND51MCND51Lrcv

1. ND52MCND53MCND54MCND55MCND56MCND57MCND5SMCND59MCND&0MCND61CCVCCBMCND&4MCND65MCND66MCND67ICSftICSftBCRICCVCCB

11

D/F ITime11

1. 001 14255. 001 14281. 001 143131. 1301 14331.001 1435i. 001 14371. 001 14401. 001 14425.001 14451.001 14471. 001 14501.001 14521. 0131 14541.001 14571. 001 14591. 001 15021.001 15041. 001 15071.001 15091, 1301 15111.001 15141.001 15161.001 15191.001 15211.001 15241.001 15261.001 15281.001 15311.001 15331.001 15361*801 15381.001 1541

1

/. R

>-

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ftL

X

XXX

XXXXXXXXXXXXXXXXXXXXXX

XX

sB

X

XXXXXXXXXXXXXXXXXXXXXXXXXXXXXX

ftsBfl

X

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XXXXXXXXXXXXXXXXXXXXXX

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1 1 i 1x i x m x i x

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1 1 1 1X I X I X I X I XX 1 X 1 X 1 XI XX I X I X I X I XX I X I X I X I XX I X I X I X I XX I X I X I X I XX I X I X I X I XX I X I X I X I XX I X I X I X I XX I X I X I X I XX I X I X I X I XX I X I X I X I XX I X I X I X I XX I X I X I X I XX I X I X I X I XX I X I X I X I XX I X I X I X I XX I X I X I X I XX I X I X I X I XX I X I X I X I XX I X I X I X I XX I X I X I X I XX I I X I X I XX I X I X I X I XX l X t X I X i X

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1 I X I 1 I X I X IX I I X I X I I X I X IX I I X I X I I X I X I1 1 1 1 1 1 1


from: hari prasad */-f mahboobeh mecanic ...page 2 of 3 the reported results for this analyte are...

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