certificate - qal1the relevant version of this certificate and the validity is also seen at the...
TRANSCRIPT
Certificate: 0000025927 / 2010-03-10
qal1.de [email protected] page 2 of 15
Test report: 936/21211350/A of 2009-10-26 First certification: 2010-02-12 Run of validity until: 2015-02-11 Publication BAnz. 2010-02-12, no.: 24, page: 554 Approved application: The suitability of the AMS for this application was assessed on basis of a laboratory test and a field test in countrified ambiance with a measuring length of 320 m. The AMS is approved for the tempera-ture range from +5 °C to +40 °C. Any potential user should ensure, in consultation with the manufacturer that this AMS is suitable for the planned site of operation. Basis of the certification This certification is based on the test report 936/21211350/A of 26.10.2009 of TÜV Rheinland Immis-sionsschutz und Energiesysteme GmbH and on the relevant bodies (German Umweltbundesamt) as-sessment and ongoing surveillance of the product and the manufacturing process and the publication in the German Federal Gazette (BAnz.):
AMS name: AR500 with ER 120 for NO2, SO2 and O3 Manufacturer: Opsis AB, Furulund, Schweden Approval: For stationary measuring of the concentrations of nitrogen dioxide, sulphur dioxide and ozone in ambient air Measuring ranges during the suitability test:
Component Certification range
Supplementary range Unit
NO2 0 - 400 0 - 1800 µg/m³
SO2 0 - 700 0 - 1000 µg/m³
O3 0 - 360 0 - 500 µg/m³
Software version: 7.21 Remarks: 1. The measuring path length during the suitability test was 320 m. 2. The maintenance interval is four weeks. 3. The equivalence with the reference measurement methods according to the guideline
“Demonstration of Equivalence of Ambient Air Monitoring Methods” has been proven for the components NO2 and O3.
4. Function tests by external sample gas feeding are possible. Test report: TÜV Rheinland Immissionsschutz und Energiesysteme GmbH, Köln Report-No.: 936/21211350/A of 2009-10-26
Certificate: 0000025927 / 2010-03-10
qal1.de [email protected] page 3 of 15
Certified product This certificate applies to automated measurement systems confirming to the following description: The measurement system AR500 with ER120 is working with the DOAS principle (differential optical absorption spectroscopy). The system consists of a combined Emitter/Receiver Unit (ER120), a reflector and the analyzer unit (AR500). The captured light is led via an opto-fibre to the analyzer. General notes: This certificate is based upon the equipment tested. The manufacturer is responsible for ensuring that on-going production complies with the requirements of the EN 15267. The manufacturer is required to maintain an approved quality management system controlling the manufacture of the certified product. Both the product and the quality management systems shall be subject to regular surveillance. If a certified product is found no longer to comply with the applicable European Standard, TÜV Rheinland Immissionsschutz und Energiesysteme GmbH should be notified at the address shown on page 1. The certification mark with the ID- Number that can be applied to the product or used in publicity mate-rial for the certified product is presented on page 1 of this certificate. This document as well as the certification mark remains the property of TÜV Rheinland Immissions-schutz und Energiesysteme GmbH. With revocation of the publication the certificate looses its validity. After the expiration of the validity of the certificate and on requests of the TÜV Rheinland Immis-sionsschutz und Energiesysteme GmbH this document shall be returned and the certificate mark must not be employed anymore. The relevant version of this certificate and the validity is also seen at the Internet Address: qal1.de.
Certificate: 0000025927 / 2010-03-10
qal1.de [email protected] page 4 of 15
Table 1: Total expanded uncertainty with the results of the laboratory test according to
EN 14211 (Component NO2) for system 1329
Dev
ice:
AR
500
Ser
ial N
o:13
29
Com
pone
nt:
NO
21h
-lim
it va
lue:
104,
6nm
ol/m
ol
No.
Perf
orm
ance
cha
ract
eris
ticR
esul
tSq
uare
of u
ncer
tain
ty1
Rep
eata
bilit
y at
zer
o≤
1,0
nmol
/mol
0,00
0u r
,Z0,
000,
0000
2R
epea
tabi
lity
at c
once
ntra
tion
ct≤
3,0
nmol
/mol
2,00
0u r
,lh0,
040,
0015
3"la
ck o
f fit"
≤
4,0%
of m
easu
red
valu
e0,
800
u l,lh
0,48
0,23
344
Sen
sitiv
ity c
oeffi
cien
t of s
ampl
e ga
s pr
essu
re≤
8,0
nmol
/mol
/kPa
0,00
0u g
p0,
000,
0000
5Se
nsiti
vity
coe
ffici
ent o
f sam
ple
gas
tem
pera
ture
≤3,
0 nm
ol/m
ol/K
0,02
6u g
t0,
040,
0016
6Se
nsiti
vity
coe
ffici
ent o
f sur
roun
ding
tem
pera
ture
≤3,
0 nm
ol/m
ol/K
-0,0
50u s
t-0
,06
0,00
367
Sens
itivi
ty c
oeffi
cien
t of e
lect
rical
vol
tage
≤0,
30 n
mol
/mol
/V-0
,021
u V-0
,07
0,00
468a
H20
with
con
cent
ratio
n 21
mm
ol/m
ol≤
5,0
nmol
/mol
0,00
0u H
2O0,
000,
0000
8b C
O2
with
con
cent
ratio
n 50
0 µm
ol/m
ol≤
5,0
nmol
/mol
0,00
1u i
nt,p
os
8c O
3 w
ith c
once
ntra
tion
200
nmol
/mol
≤2,
0 nm
ol/m
ol0,
002
or8d
NH
3 w
ith c
once
ntra
tion
200
nmol
/mol
≤5,
0 nm
ol/m
ol0,
002
u int
,neg
9A
vera
ging
effe
ct≤
7,0%
of m
easu
red
valu
e-0
,600
u av
-0,3
60,
1313
18D
iffer
ence
sam
ple/
calib
ratio
n po
rt ≤
1,0%
0,00
0u Δ
sc0,
000,
0000
21C
onve
rter e
ffici
ency
≥98
%10
0,00
0u C
E0,
000,
0000
22In
crea
se o
f NO
2 co
ncen
tratio
n du
e to
resi
denc
e tim
e≤
4,0
nmol
/mol
0,00
0u c
tr0,
000,
0000
23U
ncer
tain
ty c
alib
ratio
n ga
s≤
3,0%
2,00
0u c
g1,
051,
0941
com
bine
d st
anda
rd u
ncer
tain
tyu c
1,30
46nm
ol/m
olex
pand
ed u
ncer
tain
tyU
c2,
6092
nmol
/mol
exp
ande
d un
certa
inty
act
ual
Uc,
rel
2,49
% e
xpan
ded
unce
rtain
ty re
quire
dU
req,
rel.
15%
Unc
erta
inty
Crit
erio
n
0,48
0,23
04
Certificate: 0000025927 / 2010-03-10
qal1.de [email protected] page 5 of 15
Table 2: Total expanded uncertainty with the results of the laboratory test and field test according to EN 14211 (Component NO2) for system 1329
Dev
ice:
AR50
0Se
rial N
o:13
29
Com
pone
nt:
NO
21h
-lim
it va
lue:
104,
6nm
ol/m
ol
No.
Perf
orm
ance
cha
ract
eris
ticR
esul
tSq
uare
of u
ncer
tain
ty1
Rep
eata
bilit
y at
zer
o≤
1,0
nmol
/mol
0,00
0u r
,Z0,
000,
0000
2R
epea
tabi
lity
at c
once
ntra
tion
ct≤
3,0
nmol
/mol
2,00
0u r
,lh
not r
espe
cted
be
caus
e, u
r,lh
= 0,
075
< ur
,f-
3"la
ck o
f fit"
≤
4,0%
of m
easu
red
valu
e0,
800
u l,lh
0,48
0,23
344
Sens
itivi
ty c
oeffi
cien
t of s
ampl
e ga
s pr
essu
re≤
8,0
nmol
/mol
/kPa
0,00
0u g
p0,
000,
0000
5Se
nsiti
vity
coe
ffici
ent o
f sam
ple
gas
tem
pera
ture
≤3,
0 nm
ol/m
ol/K
0,02
6u g
t0,
040,
0016
6Se
nsiti
vity
coe
ffici
ent o
f sur
roun
ding
tem
pera
ture
≤3,
0 nm
ol/m
ol/K
-0,0
50u s
t-0
,06
0,00
367
Sens
itivi
ty c
oeffi
cien
t of e
lect
rical
vol
tage
≤0,
30 n
mol
/mol
/V-0
,021
u V-0
,07
0,00
468a
H20
with
con
cent
ratio
n 21
mm
ol/m
ol≤
5,0
nmol
/mol
0,00
0u H
2O0,
000,
0000
8b C
O2
with
con
cent
ratio
n 50
0 µm
ol/m
ol≤
5,0
nmol
/mol
0,00
1u i
nt,p
os
8c O
3 w
ith c
once
ntra
tion
200
nmol
/mol
≤2,
0 nm
ol/m
ol0,
002
or8d
NH
3 w
ith c
once
ntra
tion
200
nmol
/mol
≤5,
0 nm
ol/m
ol0,
002
u int
,neg
9Av
erag
ing
effe
ct≤
7,0%
of m
easu
red
valu
e-0
,600
u av
-0,3
60,
1313
10R
epro
duci
bilit
y un
der f
ield
con
ditio
ns≤
5,0%
of t
he a
vera
ge o
f 3 M
on.
4,72
0u r
,f4,
9424
,375
211
Long
term
drif
t at z
ero
leve
l≤
5,0
nmol
/mol
-1,4
20u d
,l,z
-0,8
20,
6721
12Lo
ng te
rm d
rift a
t spa
n le
vel
≤5,
0% o
f max
. of c
ertif
icat
ion
rang
e0,
430
u d,l,
lh0,
260,
0674
18D
iffer
ence
sam
ple/
calib
ratio
n po
rt ≤
1,0%
0,00
0uD
sc0,
000,
0000
21C
onve
rter e
ffici
ency
≥98
%10
0,00
0uC
E0,
000,
0000
22In
crea
se o
f NO
2 co
ncen
tratio
n du
e to
resi
denc
e tim
e≤
4,0
nmol
/mol
0,00
0uc
tr0,
000,
0000
23U
ncer
tain
ty c
alib
ratio
n ga
s≤
3,0%
2,00
0uc
g1,
051,
0941
com
bine
d st
anda
rd u
ncer
tain
tyu c
7,15
46nm
ol/m
olex
pand
ed u
ncer
tain
tyU
c14
,309
3nm
ol/m
ol e
xpan
ded
unce
rtain
ty a
ctua
lU
c,re
l13
,68
% e
xpan
ded
unce
rtain
ty re
quire
dU
req,
rel.
15%
Unc
erta
inty
Crit
erio
n
0,48
0,23
04
Certificate: 0000025927 / 2010-03-10
qal1.de [email protected] page 6 of 15
Table 3: Total expanded uncertainty with the results of the laboratory test according to EN 14211 (Component NO2) for system 1330
Dev
ice:
AR50
0Se
rial N
o:13
30
Com
pone
nt:
NO
21h
-lim
it va
lue:
104,
6nm
ol/m
ol
No.
Perf
orm
ance
cha
ract
eris
ticR
esul
tSq
uare
of u
ncer
tain
ty1
Rep
eata
bilit
y at
zer
o≤
1,0
nmol
/mol
0,10
0u r
,Z0,
020,
0003
2R
epea
tabi
lity
at c
once
ntra
tion
ct≤
3,0
nmol
/mol
0,90
0u r
,lh0,
020,
0004
3"la
ck o
f fit"
≤
4,0%
of m
easu
red
valu
e0,
000
u l,lh
0,36
0,13
134
Sen
sitiv
ity c
oeffi
cien
t of s
ampl
e ga
s pr
essu
re≤
8,0
nmol
/mol
/kPa
0,00
0u g
p0,
000,
0000
5Se
nsiti
vity
coe
ffici
ent o
f sam
ple
gas
tem
pera
ture
≤3,
0 nm
ol/m
ol/K
0,00
0u g
t-0
,05
0,00
256
Sen
sitiv
ity c
oeffi
cien
t of s
urro
undi
ng te
mpe
ratu
re≤
3,0
nmol
/mol
/K0,
000
u st
0,00
0,00
007
Sens
itivi
ty c
oeffi
cien
t of e
lect
rical
vol
tage
≤0,
30 n
mol
/mol
/V0,
000
u V0,
240,
0553
8a H
20 w
ith c
once
ntra
tion
21 m
mol
/mol
≤5,
0 nm
ol/m
ol0,
000
u H2O
0,00
0,00
008b
CO
2 w
ith c
once
ntra
tion
500
µmol
/mol
≤5,
0 nm
ol/m
ol0,
000
u int
,pos
8c O
3 w
ith c
once
ntra
tion
200
nmol
/mol
≤2,
0 nm
ol/m
ol0,
000
or8d
NH
3 w
ith c
once
ntra
tion
200
nmol
/mol
≤5,
0 nm
ol/m
ol0,
000
u int
,neg
9Av
erag
ing
effe
ct≤
7,0%
of m
easu
red
valu
e0,
000
u av
-0,1
80,
0328
18D
iffer
ence
sam
ple/
calib
ratio
n po
rt ≤
1,0%
0,00
0u Δ
sc0,
000,
0000
21C
onve
rter e
ffici
ency
≥98
%10
0,00
0u C
E0,
000,
0000
22In
crea
se o
f NO
2 co
ncen
tratio
n du
e to
resi
denc
e tim
e≤
4,0
nmol
/mol
0,00
0u c
tr0,
000,
0000
23U
ncer
tain
ty c
alib
ratio
n ga
s≤
3,0%
2,00
0u c
g1,
051,
0941
com
bine
d st
anda
rd u
ncer
tain
tyu c
1,22
22nm
ol/m
olex
pand
ed u
ncer
tain
tyU
c2,
4445
nmol
/mol
exp
ande
d un
certa
inty
act
ual
Uc,
rel
2,34
% e
xpan
ded
unce
rtain
ty re
quire
dU
req,
rel.
15%
Crit
erio
nU
ncer
tain
ty 0,42
0,17
64
Certificate: 0000025927 / 2010-03-10
qal1.de [email protected] page 7 of 15
Table 4: Total expanded uncertainty with the results of the laboratory test and field test according to EN 14211 (Component NO2) for system 1330
Dev
ice:
AR
500
Seria
l No:
1330
Com
pone
nt:
NO
21h
-lim
it va
lue:
104,
6nm
ol/m
ol
No.
Perf
orm
ance
cha
ract
eris
ticR
esul
tSq
uare
of u
ncer
tain
ty1
Rep
eata
bilit
y at
zer
o≤
1,0
nmol
/mol
0,10
0u r
,Z0,
020,
0003
2R
epea
tabi
lity
at c
once
ntra
tion
ct≤
3,0
nmol
/mol
0,90
0u r
,lh
not r
espe
cted
be
caus
e, u
r,lh
= 0,
034
< ur
,f-
3"la
ck o
f fit"
≤
4,0%
of m
easu
red
valu
e0,
600
u l,lh
0,36
0,13
134
Sens
itivi
ty c
oeffi
cien
t of s
ampl
e ga
s pr
essu
re≤
8,0
nmol
/mol
/kPa
0,00
0u g
p0,
000,
0000
5S
ensi
tivity
coe
ffici
ent o
f sam
ple
gas
tem
pera
ture
≤3,
0 nm
ol/m
ol/K
-0,0
32u g
t-0
,05
0,00
256
Sens
itivi
ty c
oeffi
cien
t of s
urro
undi
ng te
mpe
ratu
re≤
3,0
nmol
/mol
/K0,
000
u st
0,00
0,00
007
Sen
sitiv
ity c
oeffi
cien
t of e
lect
rical
vol
tage
≤0,
30 n
mol
/mol
/V0,
073
u V0,
240,
0553
8a H
20 w
ith c
once
ntra
tion
21 m
mol
/mol
≤5,
0 nm
ol/m
ol0,
000
u H2O
0,00
0,00
008b
CO
2 w
ith c
once
ntra
tion
500
µmol
/mol
≤5,
0 nm
ol/m
ol0,
001
u int
,pos
8c O
3 w
ith c
once
ntra
tion
200
nmol
/mol
≤2,
0 nm
ol/m
ol0,
002
or8d
NH
3 w
ith c
once
ntra
tion
200
nmol
/mol
≤5,
0 nm
ol/m
ol0,
000
u int
,neg
9Av
erag
ing
effe
ct≤
7,0%
of m
easu
red
valu
e-0
,300
u av
-0,1
80,
0328
10R
epro
duci
bilit
y un
der f
ield
con
ditio
ns≤
5,0%
of t
he a
vera
ge o
f 3 M
on.
4,72
0u r
,f4,
9424
,375
211
Long
term
drif
t at z
ero
leve
l≤
5,0
nmol
/mol
1,62
0u d
,l,z
0,94
0,87
4812
Long
term
drif
t at s
pan
leve
l≤
5,0%
of m
ax. o
f cer
tific
atio
n ra
nge
0,50
0u d
,l,lh
0,30
0,09
1218
Diff
eren
ce s
ampl
e/ca
libra
tion
port
≤1,
0%0,
000
uDsc
0,00
0,00
0021
Con
verte
r effi
cien
cy≥
0,98
100,
000
uCE
0,00
0,00
0022
Incr
ease
of N
O2
conc
entra
tion
due
to re
side
nce
time
≤4,
0 nm
ol/m
ol0,
000
uctr
0,00
0,00
0023
Unc
erta
inty
cal
ibra
tion
gas
≤3,
0%2,
000
ucg
1,05
1,09
41co
mbi
ned
stan
dard
unc
erta
inty
u c7,
1561
nmol
/mol
expa
nded
unc
erta
inty
Uc
14,3
121
nmol
/mol
exp
ande
d un
certa
inty
act
ual
Uc,
rel
13,6
8%
exp
ande
d un
certa
inty
requ
ired
Ure
q,re
l.15
%
Crit
erio
nU
ncer
tain
ty 0,42
0,17
64
Certificate: 0000025927 / 2010-03-10
qal1.de [email protected] page 8 of 15
Table 5: Total expanded uncertainty with the results of the laboratory test according to EN 14212 (Component SO2) for system 1329
Dev
ice:
AR50
0Se
rial-N
o.:
Ger
ät 1
(132
9)
Com
pone
nt:
SO2
1h-li
mit
valu
e:13
2nm
ol/m
ol
No.
Perf
orm
ance
cha
ract
eris
ticR
esul
tSq
uare
of u
ncer
tain
ty1
Rep
eata
bilit
y at
zer
o≤
1,0
nmol
/mol
0,10
0u r
,Z0,
020,
0003
2R
epea
tabi
lity
at c
once
ntra
tion
ct≤
3,0
nmol
/mol
0,10
0u r
,lv0,
020,
0003
3"la
ck o
f fit"
≤
4,0%
of m
easu
red
valu
e1,
600
u l,lv
1,22
1,48
684
Sens
itivi
ty c
oeffi
cien
t of s
ampl
e ga
s pr
essu
re≤
3,0
nmol
/mol
/kPa
0,00
0u g
p0,
000,
0000
5Se
nsiti
vity
coe
ffici
ent o
f sam
ple
gas
tem
pera
ture
≤1,
0 nm
ol/m
ol/K
0,07
1u g
t0,
540,
2908
6Se
nsiti
vity
coe
ffici
ent o
f sur
roun
ding
tem
pera
ture
≤1,
0 nm
ol/m
ol/K
-0,0
30u s
t-0
,23
0,05
237
Sen
sitiv
ity c
oeffi
cien
t of e
lect
rical
vol
tage
≤0,
30 n
mol
/mol
/V-0
,010
u V-0
,10
0,01
038a
H20
with
con
cent
ratio
n 21
mm
ol/m
ol≤
10 n
mol
/mol
0,00
0u H
2O0,
000,
0000
8bH
2S w
ith c
once
ntra
tion
200
nmol
/mol
≤5,
0 nm
ol/m
ol-0
,409
u int
,pos
8cN
H3
with
con
cent
ratio
n 20
0 nm
ol/m
ol≤
5,0
nmol
/mol
0,40
68d
NO
with
con
cent
ratio
n 50
0 nm
ol/m
ol≤
5,0
nmol
/mol
-0,6
04or
8eN
O2
with
con
cent
ratio
n 20
0 nm
ol/m
ol≤
5,0
nmol
/mol
-0,4
048f
m-X
ylol
with
con
cent
ratio
n 1
µmol
/mol
≤10
nm
ol/m
ol1,
421
u int
,neg
9Av
erag
ing
effe
ct≤
7,0%
of m
easu
red
valu
e-0
,100
u av
-0,0
80,
0058
18D
iffer
ence
sam
ple/
calib
ratio
n po
rt ≤
1,0%
0,00
0u D
sc0,
000,
0000
23U
ncer
tain
ty c
alib
ratio
n ga
s≤
3,0%
2,00
0uc
g1,
321,
7424
com
bine
d st
anda
rd u
ncer
tain
tyu c
1,93
63nm
ol/m
olex
pand
ed u
ncer
tain
tyU
c3,
8726
nmol
/mol
exp
ande
d un
certa
inty
act
ual
Uc,
rel
2,93
% e
xpan
ded
unce
rtain
ty re
quire
dU
req,
rel.
15%
Unc
erta
inty
Crit
erio
n
0,40
0,16
00
Certificate: 0000025927 / 2010-03-10
qal1.de [email protected] page 9 of 15
Table 6: Total expanded uncertainty with the results of the laboratory test and field test according to EN 14212 (Component SO2) for system 1329
Dev
ice:
AR50
0Se
rial-N
o.:
Ger
ät 1
(132
9)
Com
pone
nt:
SO2
1h-li
mit
valu
e:13
2nm
ol/m
ol
No.
Perf
orm
ance
cha
ract
eris
ticR
esul
tSq
uare
of u
ncer
tain
ty1
Rep
eata
bilit
y at
zer
o≤
1,0
nmol
/mol
0,10
0u r
,Z0,
020,
0003
2R
epea
tabi
lity
at c
once
ntra
tion
ct≤
3,0
nmol
/mol
0,10
0u r
,lv
not r
espe
cted
be
caus
e, u
r,lv
= 0,
01 <
ur,f
-
3"la
ck o
f fit"
≤
4,0%
of m
easu
red
valu
e1,
600
u l,lv
1,22
1,48
684
Sen
sitiv
ity c
oeffi
cien
t of s
ampl
e ga
s pr
essu
re≤
3,0
nmol
/mol
/kPa
0,00
0u g
p0,
000,
0000
5Se
nsiti
vity
coe
ffici
ent o
f sam
ple
gas
tem
pera
ture
≤1,
0 nm
ol/m
ol/K
0,07
1u g
t0,
540,
2908
6S
ensi
tivity
coe
ffici
ent o
f sur
roun
ding
tem
pera
ture
≤1,
0 nm
ol/m
ol/K
-0,0
30u s
t-0
,23
0,05
237
Sens
itivi
ty c
oeffi
cien
t of e
lect
rical
vol
tage
≤0,
30 n
mol
/mol
/V-0
,010
u V-0
,10
0,01
038a
H20
with
con
cent
ratio
n 21
mm
ol/m
ol≤
10 n
mol
/mol
0,00
0u H
2O0,
000,
0000
8bH
2S w
ith c
once
ntra
tion
200
nmol
/mol
≤5,
0 nm
ol/m
ol-0
,409
u int
,pos
8cN
H3
with
con
cent
ratio
n 20
0 nm
ol/m
ol≤
5,0
nmol
/mol
0,40
68d
NO
with
con
cent
ratio
n 50
0 nm
ol/m
ol≤
5,0
nmol
/mol
-0,6
04or
8eN
O2
with
con
cent
ratio
n 20
0 nm
ol/m
ol≤
5,0
nmol
/mol
-0,4
048f
m-X
ylol
with
con
cent
ratio
n 1
µmol
/mol
≤10
nm
ol/m
ol1,
421
u int
,neg
9A
vera
ging
effe
ct≤
7,0%
of m
easu
red
valu
e-0
,100
u av
-0,0
80,
0058
10R
epro
duci
bilit
y un
der f
ield
con
ditio
ns≤
5,0%
of t
he a
vera
ge o
f 3 M
on.
4,83
0u r
,f6,
3840
,648
311
Long
term
drif
t at z
ero
leve
l≤
5,0
nmol
/mol
-0,9
20u d
,l,z
-0,5
30,
2821
12Lo
ng te
rm d
rift a
t spa
n le
vel
≤5,
0% o
f max
. of c
ertif
icat
ion
rang
e1,
490
u d,l,
lv1,
141,
2894
18D
iffer
enz
Prob
en-/K
alib
rierg
asei
ngan
g≤
1,0%
0,00
0u D
sc0,
000,
0000
23U
nsic
herh
eit P
rüfg
as≤
3,0%
2,00
0uc
g1,
321,
7424
com
bine
d st
anda
rd u
ncer
tain
tyu c
6,78
00nm
ol/m
olex
pand
ed u
ncer
tain
tyU
c13
,560
0nm
ol/m
ol e
xpan
ded
unce
rtain
ty a
ctua
lU
c,re
l10
,27
% e
xpan
ded
unce
rtain
ty re
quire
dU
req,
rel.
15%
Unc
erta
inty
Crit
erio
n
0,40
0,16
00
Certificate: 0000025927 / 2010-03-10
qal1.de [email protected] page 10 of 15
Table 7: Total expanded uncertainty with the results of the laboratory test according to EN 14212 (Component SO2) for system 1330
Dev
ice:
AR50
0Se
rial-N
o.:
Ger
ät 2
(133
0)
Com
pone
nt:
SO2
1h-li
mit
valu
e:13
2nm
ol/m
ol
No.
Perf
orm
ance
cha
ract
eris
ticR
esul
tSq
uare
of u
ncer
tain
t y1
Rep
eata
bilit
y at
zer
o≤
1,0
nmol
/mol
0,00
0u r
,Z0,
000,
0000
2R
epea
tabi
lity
at c
once
ntra
tion
ct≤
3,0
nmol
/mol
0,10
0u r
,lv0,
020,
0003
3"la
ck o
f fit"
≤
4,0%
of m
easu
red
valu
e1,
400
u l,lv
1,07
1,13
844
Sens
itivi
ty c
oeffi
cien
t of s
ampl
e ga
s pr
essu
re≤
3,0
nmol
/mol
/kPa
0,00
0u g
p0,
000,
0000
5Se
nsiti
vity
coe
ffici
ent o
f sam
ple
gas
tem
pera
ture
≤1,
0 nm
ol/m
ol/K
0,01
1u g
t0,
080,
0070
6Se
nsiti
vity
coe
ffici
ent o
f sur
roun
ding
tem
pera
ture
≤1,
0 nm
ol/m
ol/K
-0,0
60u s
t-0
,46
0,20
917
Sens
itivi
ty c
oeffi
cien
t of e
lect
rical
vol
tage
≤0,
30 n
mol
/mol
/V0,
010
u V0,
100,
0103
8a H
20 w
ith c
once
ntra
tion
21 m
mol
/mol
≤10
nm
ol/m
ol0,
000
u H2O
0,00
0,00
008b
H2S
with
con
cent
ratio
n 20
0 nm
ol/m
ol≤
5,0
nmol
/mol
0,50
3u i
nt,p
os
8cN
H3
with
con
cent
ratio
n 20
0 nm
ol/m
ol≤
5,0
nmol
/mol
0,20
38d
NO
with
con
cent
ratio
n 50
0 nm
ol/m
ol≤
5,0
nmol
/mol
0,20
2or
8eN
O2
with
con
cent
ratio
n 20
0 nm
ol/m
ol≤
5,0
nmol
/mol
0,40
18f
m-X
ylol
with
con
cent
ratio
n 1
µmol
/mol
≤10
nm
ol/m
ol0,
809
u int
,neg
9Av
erag
ing
effe
ct≤
7,0%
of m
easu
red
valu
e0,
100
u av
0,08
0,00
5818
Diff
eren
ce s
ampl
e/ca
libra
tion
port
≤1,
0%0,
000
u Dsc
0,00
0,00
0023
Unc
erta
inty
cal
ibra
tion
gas
≤3,
0%2,
000
01,
321,
7424
com
bine
d st
anda
rd u
ncer
tain
tyu c
2,15
09nm
ol/m
olex
pand
ed u
ncer
tain
tyU
c4,
3017
nmol
/mol
exp
ande
d un
certa
inty
act
ual
Uc,
rel
3,26
% e
xpan
ded
unce
rtain
ty re
quire
dU
req,
rel.
15%
Crit
erio
nU
ncer
tain
ty 1,23
1,51
29
Certificate: 0000025927 / 2010-03-10
qal1.de [email protected] page 11 of 15
Table 8: Total expanded uncertainty with the results of the laboratory test and field test
according to EN 14212 (Component SO2) for system 1330
Dev
ice:
AR
500
Seria
l-No.
:G
erät
2 (1
330)
Com
pone
nt:
SO2
1h-li
mit
valu
e:13
2nm
ol/m
ol
No.
Perf
orm
ance
cha
ract
eris
ticR
esul
tSq
uare
of u
ncer
tain
ty1
Rep
eata
bilit
y at
zer
o≤
1,0
nmol
/mol
0,00
0u r
,Z0,
000,
0000
2R
epea
tabi
lity
at c
once
ntra
tion
ct≤
3,0
nmol
/mol
0,10
0u r
,lv
not r
espe
cted
be
caus
e, u
r,lv
= 0,
01 <
ur,f
-
3"la
ck o
f fit"
≤
4,0%
of m
easu
red
valu
e1,
400
u l,lv
1,07
1,13
844
Sens
itivi
ty c
oeffi
cien
t of s
ampl
e ga
s pr
essu
re≤
3,0
nmol
/mol
/kPa
0,00
0u g
p0,
000,
0000
5Se
nsiti
vity
coe
ffici
ent o
f sam
ple
gas
tem
pera
ture
≤1,
0 nm
ol/m
ol/K
0,01
1u g
t0,
080,
0070
6Se
nsiti
vity
coe
ffici
ent o
f sur
roun
ding
tem
pera
ture
≤1,
0 nm
ol/m
ol/K
-0,0
60u s
t-0
,46
0,20
917
Sens
itivi
ty c
oeffi
cien
t of e
lect
rical
vol
tage
≤0,
30 n
mol
/mol
/V0,
010
u V0,
100,
0103
8a H
20 w
ith c
once
ntra
tion
21 m
mol
/mol
≤10
nm
ol/m
ol0,
000
u H2O
0,00
0,00
008b
H2S
with
con
cent
ratio
n 20
0 nm
ol/m
ol≤
5,0
nmol
/mol
0,50
3u i
nt,p
os
8cN
H3
with
con
cent
ratio
n 20
0 nm
ol/m
ol≤
5,0
nmol
/mol
0,20
38d
NO
with
con
cent
ratio
n 50
0 nm
ol/m
ol≤
5,0
nmol
/mol
0,20
2or
8eN
O2
with
con
cent
ratio
n 20
0 nm
ol/m
ol≤
5,0
nmol
/mol
0,40
18f
m-X
ylol
with
con
cent
ratio
n 1
µmol
/mol
≤10
nm
ol/m
ol0,
809
u int
,neg
9Av
erag
ing
effe
ct≤
7,0%
of m
easu
red
valu
e0,
100
u av
0,08
0,00
5810
Rep
rodu
cibi
lity
unde
r fie
ld c
ondi
tions
≤5,
0% o
f the
ave
rage
of 3
Mon
.4,
830
u r,f
6,38
40,6
483
11Lo
ng te
rm d
rift a
t zer
o le
vel
≤5,
0 nm
ol/m
ol1,
160
u d,l,
z0,
670,
4485
12Lo
ng te
rm d
rift a
t spa
n le
vel
≤5,
0% o
f max
. of c
ertif
icat
ion
rang
e-2
,070
u d,l,
lv-1
,58
2,48
8718
Diff
eren
z Pr
oben
-/Kal
ibrie
rgas
eing
ang
≤1,
0%0,
000
u Dsc
0,00
0,00
0023
Uns
iche
rhei
t Prü
fgas
≤3,
0%2,
000
01,
321,
7424
com
bine
d st
anda
rd u
ncer
tain
tyu c
6,94
34nm
ol/m
olex
pand
ed u
ncer
tain
tyU
c13
,886
9nm
ol/m
ol e
xpan
ded
unce
rtain
ty a
ctua
lU
c,re
l10
,52
% e
xpan
ded
unce
rtain
ty re
quire
dU
req,
rel.
15%
Crit
erio
nU
ncer
tain
ty 1,23
1,51
29
Certificate: 0000025927 / 2010-03-10
qal1.de [email protected] page 12 of 15
Table 9: Total expanded uncertainty with the results of the laboratory test according to EN 14625 (Component O3) for system 1329
Dev
ice:
AR50
0S
erie
l No.
Ger
ät 1
(132
9)
Mea
sure
d co
mpo
nent
: O
3ho
urly
ale
rt th
resh
old
120
nmol
/mol
No.
Perf
orm
ance
cha
ract
eris
ticC
riter
ion
Res
ult
Squa
re o
f unc
erta
inty
1R
epea
tabi
lity
stan
dard
dev
iatio
n at
zer
o1,
0 nm
ol/m
ol0,
200
u r,Z
0,04
0,00
132
Rep
eata
bilit
y st
anda
rd d
evia
tion
at c
t3,
0 nm
ol/m
ol0,
600
u r,lv
0,11
0,01
203
"lack
of f
it" a
t the
hou
rly a
lert
thre
shol
d va
lue
4,0%
of m
easu
red
valu
e0,
400
u l,lv
0,28
0,07
684
Varia
tions
in s
ampl
e ga
s pr
essu
re2,
0 nm
ol/m
ol/k
Pa
0,00
0u g
p0,
000,
0000
5Va
riatio
ns in
sam
ple
gas
tem
pera
ture
1,0
nmol
/mol
/K0,
014
u gt
0,15
0,02
126
Varia
tions
in s
urro
undi
ng te
mpe
ratu
re1,
0 nm
ol/m
ol/K
0,15
0u s
t0,
520,
2700
7Va
riatio
ns in
ele
ctric
al v
olta
ge0,
30 n
mol
/mol
/V-0
,010
u V-0
,12
0,01
478a
Inte
rfere
nce
H20
with
21
mm
ol/m
ol10
nm
ol/m
ol0,
000
u H2O
0,00
0,00
008b
Inte
rfere
nce
Tolu
ol w
ith 0
,5 µ
mol
/mol
5,0
nmol
/mol
2,14
7u i
nt,p
os
8cIn
terfe
renc
e X
ylol
with
0,5
µm
ol/m
ol5,
0 nm
ol/m
ol0,
397
or u
int,
neg
9Av
erag
ing
effe
ct7,
0% o
f mea
sure
d va
lue
0,20
0u a
v0,
140,
0192
18D
iffer
ence
sam
ple/
calib
ratio
n po
rt1,
0%0,
000
u Dsc
0,00
0,00
0023
Unc
erta
inty
test
gas
3,0%
2,00
0uc
g1,
201,
4400
Com
bine
d st
anda
rd u
ncer
tain
tyu c
2,00
31nm
ol/m
olU
c4,
0062
nmol
/mol
Exp
ande
d un
certa
inty
act
ual
Uc,
rel
3,34
%Ex
pand
ed u
ncer
tain
ty re
quire
dU
req,
rel.
15%
Exp
ande
d un
certa
inty
Unc
erta
inty 1,
472,
1573
Certificate: 0000025927 / 2010-03-10
qal1.de [email protected] page 13 of 15
Table 10 Total expanded uncertainty with the results of the laboratory test and field test according to EN 14625 (Component O3) for system 1329
Dev
ice:
AR50
0Se
riel N
o.G
erät
1 (1
329)
Mea
sure
d co
mpo
nent
: O
3ho
urly
ale
rt th
resh
old
120
nmol
/mol
No.
Perf
orm
ance
cha
ract
eris
ticC
riter
ion
Res
ult
Squa
re o
f unc
erta
inty
1R
epea
tabi
lity
stan
dard
dev
iatio
n at
zer
o1,
0 nm
ol/m
ol0,
200
u r,Z
0,04
0,00
13
2R
epea
tabi
lity
stan
dard
dev
iatio
n at
ct
3,0
nmol
/mol
0,60
0u r
,lv
not r
espe
cted
be
caus
e, u
r,lv
= 0,
1 <
ur,f
-
3"la
ck o
f fit"
at t
he h
ourly
ale
rt th
resh
old
valu
e4,
0% o
f mea
sure
d va
lue
0,40
0u l
,lv0,
280,
0768
4Va
riatio
ns in
sam
ple
gas
pres
sure
2,0
nmol
/mol
/kPa
0,00
0u g
p0,
000,
0000
5Va
riatio
ns in
sam
ple
gas
tem
pera
ture
1,0
nmol
/mol
/K0,
014
u gt
0,15
0,02
126
Varia
tions
in s
urro
undi
ng te
mpe
ratu
re1,
0 nm
ol/m
ol/K
0,15
0u s
t0,
520,
2700
7Va
riatio
ns in
ele
ctric
al v
olta
ge0,
30 n
mol
/mol
/V-0
,010
u V-0
,12
0,01
478a
Inte
rfere
nce
H20
with
21
mm
ol/m
ol10
nm
ol/m
ol0,
000
u H2O
0,00
0,00
008b
Inte
rfere
nce
Tolu
ol w
ith 0
,5 µ
mol
/mol
5,0
nmol
/mol
2,14
7u i
nt,p
os
8cIn
terfe
renc
e X
ylol
with
0,5
µm
ol/m
ol5,
0 nm
ol/m
ol0,
397
or u
int,
neg
9Av
erag
ing
effe
ct7,
0% o
f mea
sure
d va
lue
0,20
0u a
v0,
140,
0192
10R
epro
duci
bilit
y st
anda
rd d
evia
tion
in fi
eld
5,0%
of a
vera
ge o
f 3 m
onth
2,41
0u r
,f2,
898,
3637
11Lo
ng te
rm d
rift a
t zer
o5,
0 nm
ol/m
ol1,
460
u d,l,
z0,
840,
7105
12Lo
ng te
rm d
rift a
t spa
n le
vel
5,0%
of r
ange
-2,4
50u d
,l,lv
-1,7
02,
8812
18D
iffer
ence
sam
ple/
calib
ratio
n po
rt1,
0%0,
000
uDsc
0,00
0,00
0023
Unc
erta
inty
test
gas
3,0%
2,00
0uc
g1,
201,
4400
Com
bine
d st
anda
rd u
ncer
tain
tyu c
3,99
45nm
ol/m
olU
c7,
9890
nmol
/mol
Expa
nded
unc
erta
inty
act
ual
Uc,
rel
6,66
%Ex
pand
ed u
ncer
tain
ty re
quire
dU
req,
rel.
15%
Expa
nded
unc
erta
intyUnc
erta
inty 1,
472,
1573
Certificate: 0000025927 / 2010-03-10
qal1.de [email protected] page 14 of 15
Table 11: Total expanded uncertainty with the results of the laboratory test according to EN 14625 (Component O3) for system 1330
Dev
ice:
AR50
0Se
riel N
o.G
erät
2 (1
330)
Mea
sure
d co
mpo
nent
: O
3ho
urly
ale
rt th
resh
old
120
nmol
/mol
No.
Perf
orm
ance
cha
ract
eris
ticC
riter
ion
Res
ult
Squa
re o
f unc
erta
inty
1R
epea
tabi
lity
stan
dard
dev
iatio
n at
zer
o1,
0 nm
ol/m
ol0,
200
u r,Z
0,04
0,00
132
Rep
eata
bilit
y st
anda
rd d
evia
tion
at c
t3,
0 nm
ol/m
ol0,
400
u r,lv
0,07
0,00
533
"lack
of f
it" a
t the
hou
rly a
lert
thre
shol
d va
lue
4,0%
of m
easu
red
valu
e-0
,300
u l,lv
-0,2
10,
0432
4Va
riatio
ns in
sam
ple
gas
pres
sure
2,0
nmol
/mol
/kPa
0,00
0u g
p0,
000,
0000
5V
aria
tions
in s
ampl
e ga
s te
mpe
ratu
re1,
0 nm
ol/m
ol/K
0,00
7u g
t0,
070,
0053
6Va
riatio
ns in
sur
roun
ding
tem
pera
ture
1,0
nmol
/mol
/K-0
,120
u st
-0,4
20,
1728
7Va
riatio
ns in
ele
ctric
al v
olta
ge0,
30 n
mol
/mol
/V0,
010
u V0,
120,
0147
8aIn
terfe
renc
e H
20 w
ith 2
1 m
mol
/mol
10 n
mol
/mol
0,00
0u H
2O0,
000,
0000
8bIn
terfe
renc
e To
luol
with
0,5
µm
ol/m
ol5,
0 nm
ol/m
ol0,
396
u int
,pos
8cIn
terfe
renc
e X
ylol
with
0,5
µm
ol/m
ol5,
0 nm
ol/m
ol2,
574
or u
int,
neg
9Av
erag
ing
effe
ct7,
0% o
f mea
sure
d va
lue
-0,9
00u a
v-0
,62
0,38
8818
Diff
eren
ce s
ampl
e/ca
libra
tion
port
1,0%
0,00
0u D
sc0,
000,
0000
23U
ncer
tain
ty te
st g
as3,
0%2,
000
01,
201,
4400
Com
bine
d st
anda
rd u
ncer
tain
tyu c
2,23
90nm
ol/m
olU
c4,
4780
nmol
/mol
Expa
nded
unc
erta
inty
act
ual
Uc,
rel
3,73
%Ex
pand
ed u
ncer
tain
ty re
quire
dU
req,
rel.
15%
Expa
nded
unc
erta
inty
Unc
erta
inty 1,
722,
9416
Certificate: 0000025927 / 2010-03-10
qal1.de [email protected] page 15 of 15
Table 12 Total expanded uncertainty with the results of the laboratory test and field test according to EN 14625 (Component O3) for system 1330
Dev
ice:
AR50
0Se
riel N
o.G
erät
2 (1
330)
Mea
sure
d co
mpo
nent
: O
3ho
urly
ale
rt th
resh
old
120
nmol
/mol
No.
Perf
orm
ance
cha
ract
eris
ticC
riter
ion
Res
ult
Squa
re o
f unc
erta
inty
1R
epea
tabi
lity
stan
dard
dev
iatio
n at
zer
o1,
0 nm
ol/m
ol0,
200
u r,Z
0,04
0,00
13
2R
epea
tabi
lity
stan
dard
dev
iatio
n at
ct
3,0
nmol
/mol
0,40
0u r
,lv
not r
espe
cted
, be
caus
e ur
,lv =
0,
07 <
ur,f
-
3"la
ck o
f fit"
at t
he h
ourly
ale
rt th
resh
old
valu
e4,
0% o
f mea
sure
d va
lue
-0,3
00u l
,lv-0
,21
0,04
324
Varia
tions
in s
ampl
e ga
s pr
essu
re2,
0 nm
ol/m
ol/k
Pa0,
000
u gp
0,00
0,00
005
Varia
tions
in s
ampl
e ga
s te
mpe
ratu
re1,
0 nm
ol/m
ol/K
0,00
7u g
t0,
070,
0053
6Va
riatio
ns in
sur
roun
ding
tem
pera
ture
1,0
nmol
/mol
/K-0
,120
u st
-0,4
20,
1728
7Va
riatio
ns in
ele
ctric
al v
olta
ge0,
30 n
mol
/mol
/V0,
010
u V0,
120,
0147
8aIn
terfe
renc
e H
20 w
ith 2
1 m
mol
/mol
10 n
mol
/mol
0,00
0u H
2O0,
000,
0000
8bIn
terfe
renc
e To
luol
with
0,5
µm
ol/m
ol5,
0 nm
ol/m
ol0,
396
u int
,pos
8cIn
terfe
renc
e X
ylol
with
0,5
µm
ol/m
ol5,
0 nm
ol/m
ol2,
574
or u
int,
neg
9Av
erag
ing
effe
ct7,
0% o
f mea
sure
d va
lue
-0,9
00u a
v-0
,62
0,38
8810
Rep
rodu
cibi
lity
stan
dard
dev
iatio
n in
fiel
d5,
0% o
f ave
rage
of 3
mon
th2,
410
u r,f
2,89
8,36
3711
Long
term
drif
t at z
ero
5,0
nmol
/mol
-1,8
40u d
,l,z
-1,0
61,
1285
12Lo
ng te
rm d
rift a
t spa
n le
vel
5,0%
of r
ange
2,90
0u d
,l,lv
2,01
4,03
6818
Diff
eren
ce s
ampl
e/ca
libra
tion
port
1,0%
0,00
0uD
sc0,
000,
0000
23U
ncer
tain
ty te
st g
as3,
0%2,
000
01,
201,
4400
Com
bine
d st
anda
rd u
ncer
tain
tyu c
4,30
54nm
ol/m
olU
c8,
6109
nmol
/mol
Expa
nded
unc
erta
inty
act
ual
Uc,
rel
7,18
%Ex
pand
ed u
ncer
tain
ty re
quire
dU
req,
rel.
15%
2,94
16
Unc
erta
inty 1,
72
Expa
nded
unc
erta
inty