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    CHEMISTRYWorld ofZumdahl Zumdahl DeCoste

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    Copyright by Houghton Mifflin Company. All rights reserved.

    Chapter 14

    Liquids andSolids

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    Figure 14.1: Representations of the gas, liquid, and solid states.

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    Figure 14.2: Intermolecular forces exist between molecules. Bonds exist within molecules.

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    Figure 14.3: (a)

    Interaction of

    two polar

    molecules. (b)

    Interaction of

    many dipoles in

    a liquid.

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    Figure 14.4: Polar water molecules.

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    Figure 14.4: Hydrogen bonding among water molecules.

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    Figure 14.5: The boiling points of covalent hydrides.

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    Figure 14.6: Atoms with spherical electron probability.

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    14.6: The atom on the left develops an instantaneous dipole.

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    Figure 14.6: Instantaneous dipole on A induces a dipole on B.

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    Figure 14.7: The heating/cooling curve for water heated or cooled at a constant rate.

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    Figure 14.8:

    Both liquid

    water and

    gaseous water

    contain H2O

    molecules.

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    Figure 14.9: Microscopic view of a liquid near its surface.

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    Figure 14.10: Behavior of a liquid in a closed container.

    i 14 11 ( ) i f li id b i i l b

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    Figure 14.11: (a) Measuring vapor of a liquid by using a simple barometer.

    (b) The water vapor pushed the mercury level down.

    (c) Diethyl ether shows a higher vapor pressure than water.

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    Figure 14.12: Water rapidly boiling on a stove.

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    Figure 14.13: Bubble expands as H2O molecules enter.

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    Figure 14.14: The formation of the bubble is opposed by atmospheric pressure.

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    Figure 14.15: Sodium and chloride ions.

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    Figure 14.17: The classes of crystalline solids.

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    Figure 14.18: Molecular representation of diamond.

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    Figure 14.18: Molecular representation of sodium chloride.

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    Figure 14.18: A molecular solid.

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    Figure 14.19: The packing of Cl and Na+ ions in solid sodium chloride.

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    Figure 14.21: A representation of part of the structure of solid phosphorus.

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    Figure 14.22: Molecular representation of brass.

    Fi 14 22 M l l i f l

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    Figure 14.22: Molecular representation of steel.