characterization of sorption and quantitative analysis of hydroxyl complexes
DESCRIPTION
MEDGEO 2013 Conference. CHARACTERIZATION OF SORPTION AND QUANTITATIVE ANALYSIS OF HYDROXYL COMPLEXES CHARACTERIZATION OF SORPTION AND QUANTITATIVE ANALYSIS OF HYDROXYL COMPLEXES OF Cu and Zn IN AQUEOUS SOLUTION: THE INTERACTIVE EFFECTS OF MINE WASTEWATER-MIXED MINERAL SYSTEMS - PowerPoint PPT PresentationTRANSCRIPT
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CHARACTERIZATION OF SORPTION AND QUANTITATIVE ANALYSIS OF HYDROXYL COMPLEXES
CHARACTERIZATION OF SORPTION AND QUANTITATIVE ANALYSIS OF HYDROXYL COMPLEXES OF Cu and Zn IN AQUEOUS SOLUTION: THE
INTERACTIVE EFFECTS OF MINE WASTEWATER-MIXED MINERAL SYSTEMS
EGIRANI, D.E 1, ANDREWS, J 2 AND JICKELLS,, T 2
1.FACULTY OF SCIENCE, NIGER DELTA UNIVERSITY WILBERFORCE ISLAND, NIGERIA
2.SCHOOL OF ENVIRONMENTAL SCIENCES, UNIVERSITY OF EAST ANGLIA, UKE-mail: [email protected]
IN PRESS IJRSR 209 OF 2013
MEDGEO 2013 Conference
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HEALTH IMPLICATIONS
Cu and Zn are important in human body metabolism,
lead to poisoning at concentrations above safe limits.
a deficiency can cause growth depression, in a community where Cu-Zn metal-mineral
interaction exist, there is need to investigate the behavior of
these metals and their complexes as best revealed by sorption
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LOCATION OF STUDY SITE
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CHARACTERISTICS OF MINE WATER
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FLOW DIAGRAM OF STUDIES
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ISOTHERM and % SORPTION
where Kdtotal is the theoretical distribution coefficient for a 1:1 mixed suspension,
(a)kaolinite/montmorillonite,(b) kaolinite/goethite and (c)montmorillonite/goethite
Kdn is the distribution coefficient for n number of mineral suspensions,
n is the number of mineral suspensions,
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ISOTHERM and % SORPTION
% metal sorbed = where C1 and Ce are the initial and
equilibrium metal concentrations
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ASSUMPTIONS
differences between single and mixed mineral sorption are attributed to:
development of secondary mineral phase during sorbate-sorbent interaction
Activity of components minerals as individual networks or chemisorbed
species. differential mass of mixed and single
mineral phases
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QUANTITATIVE ANALYSIS
Aqueous speciation calculations using phreeqc use a chemical composition for a solution as input and calculate the distribution of aqueous species and
saturation indices for potential complexes.
Cu(OH)2⇒ CuOH+ +OH-
Zn(OH)2 ⇒ZnOH+ +OH-
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:ISOTHERM - PARYS MOUNTAIN MINE WATER
actual and theoretical % sorption difference vs. pH of mixed mineral systems (a.kaolinite-mont, b. kaol-goethite and c. mont-goethite
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ISOTHERM- CWMRHEIDOL MINE WATER
actual and theoretical % sorption difference vs. pH of mixed mineral systems (a.kaolinite-mont, b. kaol-goethite and c. mont-goethite
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Copper and Zinc hydroxylation
Plot of saturation indices vs. pH of mine wastewater
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Conclusions
None of the mineral systems reduced contaminants to U.S EPA levels,
for humans and aquatic life, Parys, mineral mixing favors Cu sorption
than Zn, Cwmrheidol, mixing favors Zn sorption
than Cu, Cu and Zn sorption was a function of the
mineral systems, mine water composition and pH
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THE END
Abstract-Presentation ID# 216877
Presented by Dr. Davidson E. Egirani, at the 2013 Conference of the International Medical Geology Association (25–29 August 2013), Arlington, Virginia, U.S.A