cheminform abstract: chromium oxides and lithiated chromium oxides. promising cathode materials for...

1
1999 potentials, cells, elements potentials, cells, elements (inorganic) F 3000 07 - 012 Chromium Oxides and Lithiated Chromium Oxides. Promising Cathode Materials for Secondary Lithium Batteries. Chemically modified m-CrOx compounds are prepared by thermal decomposition of CrO 3 at high temp. and O 2 pressures. These materials are stable intercalation hosts for Li and exhibit a higher capacity than any of the prominent positive electrodes used in secondary Li batteries. The discharge capacity of m-CrOx exceeded 250 mAh/g when cycled between 2.0 and 4.2 V, and the energy density of this electrode is ca. 600–650 Wh/kg. — (ARORA, PANKAJ; ZHANG, DONG; POPOV, BRANKO N.; WHITE, RALPH E.; Electrochem. Solid-State Lett. 1 (1998) 6, 249-251; Dep. Chem. Eng., Univ. S. C., Columbia, SC 29208, USA; EN) 1

Upload: pankaj-arora

Post on 06-Jun-2016

219 views

Category:

Documents


0 download

TRANSCRIPT

Page 1: ChemInform Abstract: Chromium Oxides and Lithiated Chromium Oxides. Promising Cathode Materials for Secondary Lithium Batteries

1999 potentials, cells, elements

potentials, cells, elements (inorganic)F 3000

07 - 012Chromium Oxides and Lithiated Chromium Oxides. PromisingCathode Materials for Secondary Lithium Batteries. — Chemicallymodified m-CrOx compounds are prepared by thermal decomposition of CrO3

at high temp. and O2 pressures. These materials are stable intercalationhosts for Li and exhibit a higher capacity than any of the prominent positiveelectrodes used in secondary Li batteries. The discharge capacity of m-CrOx

exceeded 250 mAh/g when cycled between 2.0 and 4.2 V, and the energy densityof this electrode is ca. 600–650 Wh/kg. — (ARORA, PANKAJ; ZHANG,DONG; POPOV, BRANKO N.; WHITE, RALPH E.; Electrochem. Solid-StateLett. 1 (1998) 6, 249-251; Dep. Chem. Eng., Univ. S. C., Columbia, SC 29208,USA; EN)

1