cheminform abstract: gold(i)-catalyzed tandem c—h and c—c activation (cleavage)

ChemInform 2010, 41, issue 23 © 2010 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim www.cheminform.wiley-vch.de Polyphenyl derivatives Q 0700 DOI: 10.1002/chin.201023083 Gold(I)-Catalyzed Tandem C—H and C—C Activation (Cleavage). — The reac- tion is catalyzed by AuCl(PPh3)/AgOTf through dehydrogenative rearrangement of methylene cyclopropanes to afford the biaryl derivatives. The mechanistic studies are carried out using DFT calculations. — (JIANG, M.; LIU, L.-P.; SHI*, M.; LI, Y.; Org. Lett. 12 (2010) 1, 116-119; State Key Lab. Organomet. Chem., Shanghai Inst. Org. Chem., Chin. Acad. Sci., Shanghai 200032, Peop. Rep. China; Eng.) — R. Steudel 23- 083

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Page 1: ChemInform Abstract: Gold(I)-Catalyzed Tandem C—H and C—C Activation (Cleavage)

www.cheminform.wiley-vch.de

Polyphenyl derivativesQ 0700 DOI: 10.1002/chin.201023083

Gold(I)-Catalyzed Tandem C—H and C—C Activation (Cleavage). — The reac-tion is catalyzed by AuCl(PPh3)/AgOTf through dehydrogenative rearrangement of methylene cyclopropanes to afford the biaryl derivatives. The mechanistic studies are carried out using DFT calculations. — (JIANG, M.; LIU, L.-P.; SHI*, M.; LI, Y.; Org. Lett. 12 (2010) 1, 116-119; State Key Lab. Organomet. Chem., Shanghai Inst. Org. Chem., Chin. Acad. Sci., Shanghai 200032, Peop. Rep. China; Eng.) —R. Steudel

23- 083

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