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    Chemistry Unit 1

    AQA

    W Richards

    mailto:[email protected]:[email protected]
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    The structure of the atom

    ELECTRON

    negative, massnearly nothing

    PROTON positive, same

    mass asneutron (1)

    NEUTRON neutral, same

    mass asproton (1)

    The Ancient Greeks used to believe that

    everything was made up of very small particles. Idid some experiments in 1808 that proved thisand called these particles ATOMS:

    Dalton

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    Mass and atomic number

    Particle Relative Mass Relative Charge

    Proton 1 +1

    Neutron 1 0

    Electron Very small -1

    MASS NUMBER = number ofprotons + number of neutrons

    SYMBOL

    PROTON NUMBER = number of

    protons (obviously)

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    Mass and atomic numberHow many protons, neutrons and electrons?

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    04/08/2013Electron structure

    Consider an atom of Potassium:

    Potassium has 19 electrons.These electrons occupyspecific energy levelsshells

    Nucleus

    The inner shell has __ electrons

    The next shell has __ electrons

    The next shell has __ electrons

    The next shell has the remaining __ electron

    Electron structure

    = 2,8,8,1

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    04/08/2013Electron structure

    Draw the electronic structure of the following atoms:

    Electron structure

    = 2,8,8,2

    Nucleus

    Electron structure

    = 2,8,2

    Nucleus

    Electron structure

    = 2,5

    Nucleus

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    04/08/2013Periodic Table IntroductionHow would you arrange these elements into groups?

    http://localhost/var/www/apps/conversion/tmp/scratch_7/rates%20of%20reaction.exe
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    Mendeleev

    Periodic table

    The periodic table arranges all the elements

    in groups according to their properties.

    Horizontal rows are called PERIODS

    Vertical

    columns arecalled GROUPS

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    H He

    Li Be B C N O F Ne

    Na Mg Al Si P S Cl Ar

    K Ca Fe Ni Cu Zn Br Kr

    Ag I Xe

    Pt Au Hg

    The Periodic TableFact 1: Elements in the same group have the

    same number of electrons in the outer shell (thiscorresponds to their group number)

    E.g. all group 1 metals

    have __ electron intheir outer shell

    These elements

    have __ electronsin their outer shell

    These elements have

    __ electrons in theirouter shells

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    H He

    Li Be B C N O F Ne

    Na Mg Al Si P S Cl Ar

    K Ca Fe Ni Cu Zn Br Kr

    Ag I Xe

    Pt Au Hg

    The Periodic TableFact 2: As you move down through the periods an

    extra electron shell is added:

    E.g. Lithium has 3electron in theconfiguration 2,1

    Potassium has 19 electrons in

    the configuration __,__,__,__

    Sodium has 11electrons in the

    configuration 2,8,1

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    H He

    Li Be B C N O F Ne

    Na Mg Al Si P S Cl Ar

    K Ca Fe Ni Cu Zn Br Kr

    Ag I Xe

    Pt Au Hg

    The Periodic TableFact 3: Most of the elements are metals:

    These elementsare metals

    This line divides

    metals from non-metals

    These elements are

    non-metals

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    H He

    Li Be B C N O F Ne

    Na Mg Al Si P S Cl Ar

    K Ca Fe Ni Cu Zn Br Kr

    Ag I Xe

    Pt Au Hg

    The Periodic TableFact 4: (Most important) All of the elements in

    the same group have similar PROPERTIES. Thisis how I thought of the periodic table in the firstplace. This is called PERIODICITY.

    E.g. consider the group 1 metals. They all:

    1) Are soft

    2) Can be easily cut with a knife

    3) React with water

    4/ / 1

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    04/08/2013Group 1 The alkali metals

    Li

    Na

    K

    Rb

    Cs

    Fr

    Watch video of thesemetals reacting with water(from Sky Ones Brainiac)

    04/08/2013

    http://www.youtube.com/watch?v=m55kgyApYrYhttp://www.youtube.com/watch?v=m55kgyApYrYhttp://www.youtube.com/watch?v=m55kgyApYrYhttp://www.youtube.com/watch?v=m55kgyApYrYhttp://www.youtube.com/watch?v=m55kgyApYrYhttp://www.youtube.com/watch?v=m55kgyApYrY
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    04/08/2013Group 0 The Noble gases

    He

    Ne

    Ar

    Kr

    Xe

    Rn

    Questions:

    1) How many electrons do these elements havein their outer shell?

    2) How does this affect their reactivity?

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    CompoundsCompounds are formedwhen two or moreelements arechemically combinedby sharing or giving ofelectrons. Some

    examples:

    Glucose

    Methane

    Sodiumchloride (salt)

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    Some simple compounds

    Methane, CH4 Water, H2O

    Carbondioxide, CO2

    Ethyne, C2H2sulfuric acid,

    H2SO4

    Key

    Hydrogen

    Oxygen

    Carbon

    sulfur

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    04/08/2013Bonding introduced

    Hi. My names Johnny Chlorine.Im in Group 7, so I have 7

    electrons in my outer shell

    Id quite like to have a full outershell. To do this I need to GAINan electron. Who can help me?

    Cl

    Cl

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    04/08/2013Bonding

    Here comes one of my friends, HarryHydrogen

    Hey Johnny. Ive only got one

    electron but its really close to mynucleus so I dont want to lose it.

    Fancy sharing?

    Cl

    H

    Cl H

    Now were both really stable.Weve formed a covalent bond.

    04/08/2013d

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    04/08/2013Bonding

    Here comes another friend, Sophie

    Sodium

    Hey Johnny. Im in Group 1 so I haveone electron in my outer shell. UnlikeHarry, this electron is far away from

    the nucleus so Im quite happy to getrid of it. Do you want it?

    Cl

    Now weve both got full outer shellsand weve both gained a charge.

    Were both called IONS and weve

    formed an IONIC bond.

    Na

    Okay

    Cl Na

    +-

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    B l

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    04/08/2013Balancing equations

    Consider the following reaction:

    Na O

    H HH HNa

    OH

    Sodium + water sodium hydroxide + hydrogen

    + +

    This equation doesnt balance there are 2 hydrogenatoms on the left hand side (the reactants and 3 onthe right hand side (the products)

    04/08/2013

    B l

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    04/08/2013Balancing equations

    We need to balance the equation:

    NaO

    H H

    H H

    Na

    OH

    Sodium + water sodium hydroxide + hydrogen

    + +

    Na

    O

    H H

    Na

    OH

    Now the equation is balanced, and we can write it as:

    2Na(s) + 2H2O(l) 2NaOH(aq) + H2(g)

    04/08/2013l

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    04/08/2013Some examples

    Mg + O2

    Zn + HCl

    Fe + Cl2

    NaOH + HCl

    CH4 + O2

    Ca + H2O

    NaOH + H2SO4

    CH3OH + O2

    MgOZnCl2 + H2

    FeCl3

    NaCl + H2O

    CO2 + H2O

    Ca(OH)2 + H2

    Na2SO4 + H2O

    CO2 + H2O

    22

    2 3

    2

    2

    2

    2 3

    2

    2

    2

    2

    2 4

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    f

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    04/08/2013Conservation of mass in reactions

    In any reaction the total mass of products isthe same as the total mass of the reactants

    Example 1Magnesium oxide and hydrochloric acid

    MgO

    H Cl

    MgCl

    Cl

    H

    H

    OH Cl

    1 x magnesium, 1 x oxygen, 2 xhydrogen and 2 x chlorine atoms

    Also 1 x magnesium, 1 x oxygen, 2x hydrogen and 2 x chlorine atoms

    C

    H

    H

    H

    HO

    O

    OO

    OH H

    OH H

    CO

    O

    Example 2Burning methane

    04/08/2013Li

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    04/08/2013Limestone

    Limestone is a rock made up of mainly calciumcarbonate. Its cheap and easy to obtain. Some

    uses:

    1) Building materials limestone can be ______and cut into blocks to be used in _______.However, it is badly affected by ____ ____.

    2) Cement making limestone can be

    roasted

    in a rotary kilnto produce dry cement. Its then mixed with sand and _____to make _______.

    View video of limestone being quarried

    Words building, quarried, gravel, concrete, acid rain

    04/08/2013Li

    http://www.youtube.com/watch?v=VlLKQncIl6Ehttp://www.youtube.com/watch?v=VlLKQncIl6E
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    04/08/2013Limestone

    If soil is too _____ crops will fail. Limestone can also be usedas a neutralising agent. There are two reactions to know:

    1) Firstly, a THERMAL _________________ reaction is usedto break the calcium carbonate down into calcium oxide and

    _______ __________:

    2) This is then slaked with water to produce calciumhydroxide:

    Calcium hydroxide is alkaline and is used to ______ acidic soil.

    Calcium carbonate calcium oxide + carbon dioxideHEAT

    Calcium oxide calcium hydroxideWATER

    Words acidic, neutralise, decomposition,

    carbon dioxide

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    Th

    Li C l

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    The Limestone Cycle

    Calcium Carbonate

    (limestone)

    Calcium Oxide

    Calcium Hydroxide

    Step 1:heat

    Step 2:add a littlewater

    Step 3: addmore waterand filter

    Step 4:add CO2

    CO2

    Calcium Hydroxide solution

    04/08/2013

    Th l d i i f b

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    04/08/2013Thermal decomposition of carbonates

    Limestone undergoes thermal decomposition when heated. Thesame happens to other carbonates. For example, consider

    copper carbonate:

    Limewater

    Copper carbonate(green) turns intocopper oxide (black)

    Limewater goescloudy due to carbondioxide being made

    Copper carbonate copper oxide + carbon dioxide

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    Th P i di T bl

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    H He

    Li Be B C N O F Ne

    Na Mg Al Si P S Cl Ar

    K Ca Fe Ni Cu Zn Br Kr

    Ag I Xe

    Pt Au Hg

    The Periodic TableRecall something we said earlier some of the

    elements are metals:These elementsare metals

    This line dividesmetals from non-metals

    These elements are

    non-metals

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    Properties of metals

    Metals have very high melting points (which means that they are usually

    _____) whereas non-metals will melt at lower ___________All metals conduct heat and __________ very well, whereas non-metalsdont (usually)

    Metals are strong and ______ but bendable. Non-metals are usually

    _____ or they will snap.Metals will _____ when freshly cut or scratched, whereas non-metals areusually dull.

    Metals have higher _______ than non-metals (i.e. they weigh more)

    Metals can be used to make ______ (a mixture of different metals)Words - alloys, electricity, solids, weak, densities,

    temperatures, tough, shine

    04/08/2013E t ti M t l

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    04/08/2013Extracting Metals

    A METAL ORE is a mineral or mixture ofminerals from which it is economicallyviable to extract some metal.

    To extract a metal from a metal oxide we need to REDUCE

    the oxygen. This is called a REDUCTION reaction. To put itsimply:

    Most ores contain METAL OXIDES (e.g. rust = iron oxide).

    Some definitions:

    Iron OxideIronore

    Reduce the oxygento make iron

    04/08/2013How do we do it?

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    OxideIron

    How do we do it?Potassium

    Sodium

    Calcium

    Magnesium

    Aluminium

    Carbon

    Zinc

    Iron

    Tin

    LeadCopper

    Silver

    Gold

    Platinum

    Metals ABOVE CARBON, becauseof their high reactivity, are

    extracted by ELECTROLYSIS,which is very expensive!

    Metals BELOW CARBON areextracted by heating them withcarbon in a BLAST FURNACE.This is a displacement reaction

    These LOW REACTIVITY metalswont need to be extracted becausethey are SO unreactive youll find

    them on their own, not in a metal oxide

    Carbon

    04/08/2013E t ti t l

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    04/08/2013Extracting metals

    1) What is an ore?

    2) In what form are metals usually found in the Earth?

    3) How do you get a metal out of a metal oxide?

    4) What is this type of reaction called?

    Type of metal Extraction process Examples

    High reactivity (i.e anythingabove carbon)

    Middle reactivity (i.e.anything below carbon)

    Low reactivity

    04/08/2013

    Th T iti M t l

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    04/08/2013The Transition Metals

    1) This section includes metals like gold, mercury, iron, copper

    Somefacts

    2) They are all ______ and solid (except _________)

    3) They are ____ reactive than the alkali metals

    Words hard, coloured, mercury, less, catalyst, insoluble

    4) They can form __________ compounds, usually _______5) They can be used as a ______ (a chemical that speeds up areaction)

    04/08/2013

    C Al i i d Tit i

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    / /Copper, Aluminium and Titanium

    Metal Uses and why Extraction method Problems

    Copper Electrical wires good conductor

    Electrolysis Limited supply

    Aluminium andtitanium

    Planes light andcorrrosionresistant

    Complicated andexpensive

    Expensive anddifficult to extract

    Supplies of any raw material are limited so what are the

    options?

    04/08/2013U in I n

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    Using Iron

    Iron produced by the blast furnace (cast iron) contains

    about 96% iron and 4% impurities. These impurities make itvery brittle and easy to break.

    Ironbridge, Shropshire made out of cast ironand safe for horses and

    carts but not modernvehicles.

    04/08/2013Usin Ir n

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    Using Iron

    In pure iron all

    impurities areremoved. Thismakes the iron soft:

    Adding 1% impuritiesmakes the iron muchstronger:

    04/08/2013M kin st l

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    Making steel

    Amount ofcarbon

    added (%)0.5% 1%

    Strong

    Weak

    1.5%

    Strength

    Hardness

    Steel with a lowcarbon content iseasily shaped

    Steel with a highcarbon content isstrong but brittle

    Steel with chromiumand nickel is calledstainless steel

    04/08/2013Alloys

    http://www.bbc.co.uk/london/whereyoulive/west/hounslow/eating.shtml
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    AlloysSteel is an alloy i.e. a mixture of metals. Here are otheralloys:

    Gold mixed with

    copper

    Aluminium mixed

    with magnesiumand copper

    Aluminiun mixed

    with chromium

    04/08/2013Electrolysis

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    Electrolysis

    +++

    +

    ---

    -

    Positive

    electrode

    Cu2+

    Cu2+

    Cu2+

    Negative

    electrode

    Cl-

    Cl-

    Cl-

    Solution

    containingcopper andchloride ions

    04/08/2013Electrolysis

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    Electrolysis

    Electrolysis is used to separate a metal from its compound.

    = chloride ion

    = copper ion

    When we electrolysedcopper chloride the _____chloride ions moved to the

    ______ electrode and the______ copper ions movedto the ______ electrodeOPPOSITES ATTRACT!!!

    Extracting and purifying copper04/08/2013

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    Extracting and purifying copperCopper can be extracted from copper-rich ores by heating theores in a furnace and then purifying it by electrolysis.

    Extracting copperuses large amounts of

    heat and energy

    Bingham Canyon coppermine in Utah, one of the

    largest in the world

    04/08/2013

    Purifying Copper by electrolysis

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    Purifying Copper by electrolysis

    +++

    +

    ---

    -

    Solution

    containingcopper ions

    Impure

    copper

    Cu2+

    Cu2+

    Cu2+

    Pure copper

    New ways of extracting copper04/08/2013

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    New ways of extracting copper

    Mining lower-grade ____

    Phytomining growing_____ that absorb metals

    and then ______ them toextract the metal from __.

    Bioleaching using ______ toproduce leachate solutions thatcontain metal _________.

    Words compounds, plants, ores, bacteria, burning, ash

    04/08/2013

    Extracting Aluminium

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    Extracting Aluminium

    Aluminium has to be extracted from its ore by electrolysis. This isbecause aluminium is very ___________ and so it cannot be extracted

    using ______. The amount of energy and _____ required to extractaluminium and other metals is very high and so ________ is a muchbetter option.

    Words reactive, recycling, money, carbon

    Extracting metals from soil04/08/2013

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    Extracting metals from soil

    Where metals have

    contaminated land (e.g.brown field sites), plantssuch as brassica can be usedto extract the metals back

    out of the soil and the metalscan then be recovered fromthe plants.

    04/08/2013Crude Oil

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    Crude Oil

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    Hydrocarbons and crude oil

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    Hydrocarbons and crude oil

    Longer chains mean

    1. Less ability to flow

    2. Less flammable

    3. Less volatile

    4. Higher boiling point

    In

    creasing

    le

    ngth

    Crude oil is a mixture of HYDROCARBONS

    (compounds made up of carbon and hydrogen).Some examples:

    Ethane

    C C

    HH

    H

    HH

    H

    Butane

    C CHH H

    HH

    H C C HH

    HH

    04/08/2013Distillation rev

    ision

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    Distillation revision

    This apparatus can be used to

    separate water and inkbecause they have different

    _____ ______. The ______will evaporate first, turn backinto a _______ in the

    condenser and collect in the_______. The ink remains inthe round flask, as long as the

    _______ does not exceedinks boiling point. This

    method can be used toseparate crude oil.

    Words temperature, boiling points, water, beaker, liquid

    04/08/2013

    Fractional distillation

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    Fractional distillationCrude oil can be separated by fractional distillation. The oil is evaporatedand the hydrocarbon chains of different lengths condense at differenttemperatures:

    Fractions withlow boilingpoints condense

    at the top

    Fractions withhigh boilingpoints condenseat the bottom

    04/08/2013Alkanes

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    AlkanesAlkanes are SATURATED HYDROCARBONS. What does thismean?

    HYDROCARBONS are molecules that are made up ofhydrogen and carbon atoms

    SATURATED means that all of these atoms are held

    together by single COVALENT bonds, for example:

    Ethane

    Alkanes are fairly unreactive (but they do burn well). The

    general formula for an alkane is CnH2n+2

    C C

    HH

    H

    HH

    H

    Butane

    C C

    HH H

    HH

    H C C H

    H

    HH

    04/08/2013

    General Formulae for Alkanes

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    General Formulae for AlkanesInstead of circles, lets use letters

    General formula for alkanes = CnH2n+2

    Butane (n=4)

    H

    C C

    H

    HH

    H

    C C

    H

    HH

    H H

    Methane (n=1)

    H

    C H

    H

    H

    Ethane (n=2)

    H

    H

    C C

    H

    HH

    H

    Propane (n=3)

    H

    C H

    H

    H

    C C

    H

    HH

    H

    04/08/2013Burning Fossil

    Fuels

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    Burning Fossil FuelsBurning fossil fuels like oil and coal causes pollution.

    Oil contains carbon:

    C

    H

    H

    H

    HO

    O

    OO

    OH H

    OH H

    CO

    O

    Carbon dioxide is a greenhousegas it helps cause global warming

    Coal contains carbon, sulfur and other particles:sulfur + oxygen sulfur dioxide

    Sulfur dioxide causes acid rain. Other particles cancause global dimming sunlight is absorbed by the

    particles in the atmosphere.

    04/08/2013Removing Sulfur 04/08/2013

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    Removing SulfurSulfur dioxide is clearly bad for the environment so its a goodidea to remove as much sulfur as possible:

    Vehicles can remove sulfurfrom fuels before theyare burned.

    Power stations can removesulfur dioxide from wastegases after combustion.

    04/08/2013Other fuel sources

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    Other fuel sources

    Task: Identify two other fuel sources (biofuels) currently

    being developed and find out the following:

    1) What is the source called and what is it made of?

    2) Why is the fuel better than coal?

    3) What are the disadvantages of this fuel?

    04/08/2013Using Crude Oil

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    Using Crude Oil

    Crude Oil

    Benefits Drawbacks

    Cheap toextract

    Wide range ofuses as fuel

    Used to makeplastics

    Plastics dontbiodegrade

    Burning

    fossil fuelscauses

    pollution

    Disposal ofmaterials

    uses up landfill sites

    Itsgoing torun out

    04/08/2013Disposal

    of plastics

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    Disposal of plastics1) Landfill sites - most plastics do not

    _________ which means that landfill sitesare quickly filled up. Research is beingcarried out on __________ plastics.

    2) Burning this releases carbon

    dioxide which causes the________ effect, as well asother ________ gases.

    3) _______ the best option, butdifficult because of the differenttypes of plastic

    Words recycling, greenhouse,

    decompose, biodegradable, poisonous

    04/08/2013Ethanol

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    EthanolEthanol is an important chemical. Many

    countries are increasing the amount ofethanol put into their petrol supplies:

    Ethanol is a clean burning energy source and produces littleor no greenhouse gases. How is it made and what are the

    advantages and disadvanatges of each method?

    Ford Escape E85 runs on 85% ethanol

    The fossil fuel way

    The renewable way

    Ethene + steam ethanolEthene is produced bycracking oil

    Sugar ethanol + carbon dioxide

    Sugar is produced fromstandard crops like

    sugar cane and corn

    04/08/2013

    Making ethanol from ethene

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    Making ethanol from ethene

    Ethene

    Reaction vessel with hightemperature and pressure

    and a catalyst Ethanol

    Unused ethene recycled

    Ethene + water ethanol

    C2H + H20 C2H5OH

    04/08/2013Cracking

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    CrackingShorter chain hydrocarbons are in greater demand becausethey burn easier. They can be made from long chain

    hydrocarbons bycracking

    :

    Butane

    Ethane

    For example, this bondcan be cracked togive these:

    Ethene

    04/08/2013Cracking

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    Cracking

    This is a THERMAL DECOMPOSITION reaction,with clay used as a catalyst

    1) Carbon dioxide causes the _________ effect

    2) Sulfur dioxide causes _____ _____

    3) Plastics are not _____________

    Cracking is used to produce plastics such as polymers and polyethanes. The

    waste products from this reaction include carbon dioxide, sulfur dioxideand water vapour. There are three main environmental problems here:

    Long chainhydrocarbon

    Heatedcatalyst

    Gaseoushydrocarbon

    Liquid

    hydrocarbon

    04/08/2013Alkenes

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    AlkenesAlkenes are different to alkanes; they contain DOUBLECOVALENT bonds. For example:

    Ethane Ethene

    Butane Butene

    This double bond means that alkenes have the potential to joinwith other molecules this make them REACTIVE. Alkenes

    turn bromine water colourless.

    ALKANES

    ALKENES

    Testing for alkenes 04/08/2013

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    Testing for alkenes

    Oil Bromine goescolourless

    Brominewater

    04/08/2013

    General Formulae for Alkenes

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    General Formulae for Alkenes

    General formula for alkenes = CnH2n

    Propene (n=3)

    H

    C H

    H

    H

    C C

    H

    H

    Ethene (n=2)

    H

    H

    C C

    H

    H

    Butene (n=4)

    H

    C C

    H

    HH

    H

    C C

    H

    H H

    04/08/2013

    Monomers and Polymers

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    Monomers and Polymers

    C CHH

    HH

    Ethene

    Heres ethene again. Ethene is called aMONOMER because it is just one smallmolecule. We can use ethene to makeplastics

    Step 1: Break the double bond

    Step 2: Addthe molecules

    together:

    This molecule is called POLYETHENE,and the process that made it is called

    POLYMERISATION

    04/08/2013

    Another way of drawing it

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    Another way of drawing itInstead of circles, lets use letters

    Ethene

    C C

    HH

    HH

    C C

    HH

    HH

    Ethene

    H

    C C

    H

    HH

    H

    C C

    H

    HH

    Poly(e)thene

    General formula for addition polymerisation:

    C Cn C C

    n

    e.g. C Cn

    H CH3

    HH

    C C

    n

    H CH3

    HH

    04/08/2013Some examples

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    Some examples

    C C n

    H H

    HH

    C Cn

    H H

    HCl

    C Cn

    H H

    HH

    C CnH H

    HCl

    C CnH Cl

    HBr

    C Cn

    H Cl

    HBr

    04/08/2013

    Uses of addition polymers

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    Uses of addition polymersPoly(ethene) Poly(propene)

    Poly(chloroethene), PVCPoly(styrene)

    Biodegradable carrier bags04/08/2013

    http://www.picsearch.com/info.cgi?q=guttering&cid=15840292808http://www.picsearch.com/info.cgi?q=pvc%20window&cid=593466145508http://www.picsearch.com/info.cgi?q=polystyrene&cid=638188450599&start=65http://www.picsearch.com/info.cgi?q=polystyrene&cid=829276250103http://www.picsearch.com/info.cgi?q=plastic%20chair&cid=216224297352http://www.picsearch.com/info.cgi?q=rope&cid=179471179647http://www.picsearch.com/info.cgi?q=car%20bumper&cid=651416074300http://www.picsearch.com/info.cgi?q=bleach%20bottle&cid=96274832671http://www.picsearch.com/info.cgi?q=plastic%20tub&cid=930236873411http://www.picsearch.com/info.cgi?q=carrier%20bag&cid=571236659116&start=65
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    Biodegradable carrier bags

    This carrier bag has been made with flax fibre fromindustrial waste.

    04/08/2013

    Measuring Energy in Food

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    Measuring Energy in Food

    The energy contentin foods is measured

    in Joules and calories

    Foods with large carbohydrate and fatcontents have lots of energy, but toomuch energy and too little exercise

    could lead to obesity.

    04/08/2013Vegetable Oils

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    Vegetable O ls

    Use of oil Benefits Drawbacks

    Oily foods

    Fuel

    When plants photosynthesise they produce glucose. They canalso produce vegetable oils and we can use these for food and

    fuel:

    04/08/2013Extracting Oil

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    E tract ng O

    Step 1: Crush

    the plant

    Step 2: Remove oilby pressing

    OR step 3: Removeoil by distillation

    Why use oil for cooking?04/08/2013

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    W y f g1) Why do we use oil for cooking and not just water?

    2) What are the problems associated with using oil in cooking?

    04/08/2013

    Healthy and Unhealthy Oils

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    y y

    Unhealthy oils:

    Healthy oils:

    Saturated

    Unsaturated

    04/08/2013

    Saturated vs. Unsaturated Fats

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    Some oils are more healthy than others. Fish

    oils contain the nutrients Omega-3 and Omega-6. These oils are unsaturated like ethene:

    C C

    HH

    HH

    Ethene

    Testing for double bonds:

    Clearly, it is important forscientists to be able to test if

    a food contains healthyunsaturated fats orunhealthy saturated fats.Heres how its done:

    Oil (in ethanol)Bromine goescolourless

    Bromine

    water

    04/08/2013

    Turning unsaturates into saturates

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    g

    The unsaturated fat is hardened byhydrogenation

    .

    Hydrogenated oils have a higher melting point and soare solid at room temperature, making them useful forspreads and pastries.

    600C, Nickel catalyst

    04/08/2013Emulsions

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    Whats an emulsion?

    Its a mixture of oil and

    water, like in salad dressing

    Paint is an emulsion. Other examples:

    Milk Cream Butter

    Butterfat

    Watery liquid

    04/08/2013

    Why use emulsions?

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    yEmulsions can have varying textures and this makes themuseful. Some examples:

    Differentthicknesses

    of cream

    Paint andmayonnaise

    04/08/2013Emulsifiers

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    An emulsifier is an additive that will stop oiland water from seperating, like in mayonnaise.

    How they work:

    Water Oil

    Im an emulsifier Illsort this out with my

    hydrophobic end andmy hydrophilic end!I dont want tomix with you!

    The water and oil drops become coated and insulated from

    one another, which prevents them from seperating.

    04/08/2013

    Uses of emulsifiers in food

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    Emulsifiers are used:

    1) In bread, to stop large _____ developing when it bakes

    2) In low fat spreads, to allow the oil and water to be _____

    3) In ice cream and spray cream, to ______ the foam

    4) In sponge cakes, to make tiny pockets of ____

    5) In chocolate, to stop melted chocolate forming _______

    Words crystals, air, holes, mixed, stabilise

    04/08/2013

    The Structure of the Earth

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    A thin crust -10-100km thick

    A mantle has theproperties of a solidbut it can also flow

    A core made of

    molten nickel and iron.Outer part is liquidand inner part is solid

    The average density of the Earth is much higher than

    the crust, so the inner core must be very dense

    04/08/2013

    Movement of the Lithosphere

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    pThe Earths LITHOSPHERE (i.e. the _______) is splitup into different sections called ________ plates:

    These plates are moving apart from each other afew centimetres every _______ due to the________ currents in the mantle caused by the________ decay of rocks inside the core.

    Words radioactive, crust, convection, tectonic, year

    04/08/2013Plate Movements

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    Oceanic Crust

    Mantle

    Magma

    Convection

    Currents

    Earthquakes andvolcanic eruptions can

    be common here

    04/08/2013The

    Earths Atmosphere

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    p

    Carbon dioxide, water vapour Oxygen Nitrogen Noble gases

    For the last 200 million years the atmosphere has remained roughly thesame it contains 78% nitrogen, 21% oxygen, 1% noble gases and about

    0.03% CO2

    04/08/2013Evolution of the E

    arths Atmosphere

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    4 Billion years 3 Billion years 2 Billion years 1 Billion years Present day

    Carbon

    dioxide

    Methane Ammonia Oxygen Nitrogen Others

    Present dayatmosphere contains78% nitrogen, 21%oxygen, 1% noblegases and about0.03% CO

    2

    04/08/2013Evolution of the E

    arths Atmosphere

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    4 Billion years 3 Billion years 2 Billion years 1 Billion years Present day

    Volcanic activityreleases CO2, methane,ammonia and water

    vapour into theatmosphere. The watervapour condenses toform oceans.

    Some of the oxygen isconverted into ozone.

    The ozone layer blocksout harmful ultra-violetrays which allows for thedevelopment of new life.

    Green plants evolve which take in CO2 andgive out oxygen. Carbon from CO2

    becomes locked up in sedimentary rocks ascarbonates and fossil fuels. Methane andammonia react with the oxygen andnitrogen is released.

    One theory about how life was formed04/08/2013h d l h

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    The Primordial Soup theory:

    A collection ofsimple molecules

    like methane

    Amino acids

    Dr StanleyMiller 1930-

    2007

    In 1953 I conducted an experiment thatproved that an electrical discharge can turnmethane into amino acids! This is called the

    Miller-Urey experiment.

    04/08/2013

    Carbon dioxide in the atmosphereTh f CO h h ff d b 3 h

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    The amount of CO2 in the atmosphere is affected by 3 things:

    1) Geological activity moves carbonate rocks deep into

    the Earth and they release ______ _______ into theatmosphere during volcanic activity.

    2) When fossil fuels are burned the carboncontained in them reacts with _____ to form CO2.

    3) Increased CO2 in the atmosphere causes a reactionbetween it and _______. These reactions do not remove ALLof the new CO2 so the greenhouse effect is still getting

    _______!

    Words oxygen, seawater, carbon dioxide, worse

    04/08/2013Separating air

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    p gAir can be separated into the different gases that make it up.To do this you first have to cool air down to -2000C and turn it

    into a liquid:

    Liquid air

    (-200OC)Fractionaldistillation

    In this chamber the air is gradually heated up again and

    Nitrogen

    Argon

    Oxygen

    RemoveCO2 and

    H2O vapour