classification & labelling summary (c&l … documents/p-i163...aquatic chronic cat 3 : h412...

Version September 2017

1

CLASSIFICATION & LABELLING SUMMARY (C&L Summary)

Environment Hazards .............................................. 2

Physical chemical Hazards ....................................... 7

Health Hazards ..................................................... 13

Disclaimer

The information contained in this paper is intended for guidance only and whilst the information is provided in utmost good faith and has been based on the best

information currently available, is to be relied upon at the user’s own risk. No representations or warranties are made with regards to its completeness or accuracy and

no liability will be accepted by the Hydrocarbon Solvents Producers Association (HSPA) - Cefic nor any company participating in HSPA for damages of any nature

whatsoever resulting from the use of or reliance on the information. This document does not necessarily represent the views of any company participating in HSPA -

Cefic. Users are reminded that the text of the REACH Regulation is the only authentic legal reference and that the information in this paper cannot serve as substitute

for legal advice and each company must decide the strategy to follow.


2

Environment Hazards

Substance Name CLP classification GHS classification DSD classification

Category 1 : C9 Aromatics

Hydrocarbons, C9, aromatics Aquatic Chronic Cat 2 : H411 Aquatic Acute cat 2, Chronic cat 2 : H401, H411

Toxic for environment : R51/53

Category 2 : C10-C12 Aromatics

Hydrocarbons, C10, aromatics, >1% naphthalene Aquatic Chronic Cat 2 : H411 Aquatic Acute cat 2, Chronic cat 2 : H401, H411


Hydrocarbons, C10, aromatics, <1% naphthalene Aquatic Chronic Cat 2 : H411 Aquatic Acute cat 2, Chronic cat 2 : H401, H411


Hydrocarbons, C10-C13, aromatics, <1% naphthalene Aquatic Chronic Cat 2 : H411 Aquatic Acute cat 2, Chronic cat 2 : H401, H411


Hydrocarbons, C10-C13, aromatics, >1% naphthalene Aquatic Chronic Cat 2 : H411 Aquatic Acute cat 2, Chronic cat 2 : H401, H411


Category 3 : C9-C14 Aliphatics (2-25% Aromatics)

Hydrocarbons, C10-C13, n-alkanes, isoalkanes, cyclics, aromatics (2-25%)

Aquatic Chronic cat 3 : H412 Aquatic acute cat 3, Chronic cat 3 : H402, H412

Harmful for environment : R52/53


Aquatic Chronic Cat 2 : H411 Aquatic Acute cat 2, Chronic cat 2 : H401, H411




Not classified


Hydrocarbons, C14-C18, n-alkanes, isoalkanes, cyclics, aromatics (2-30 %)

Not classified Not classified

Not classified


Aquatic chronic cat 4 : H413 Aquatic chronic cat 4 : H413

Long term effect in aquatic environment : R53

Category 5 : C5 Aliphatics

Normal-Pentane Aquatic Chronic Cat 2 : H411 Aquatic Acute cat 2 : H401


Iso-Pentane (2-methylbutane) Aquatic Chronic Cat 2 : H411 Aquatic Acute cat 2 : H401



3

Environment Hazards


Cyclopentane Aquatic Chronic Cat 3 : H412 Aquatic Acute cat 2 : H401


Hydrocarbons, C5, n-alkanes, isoalkanes Aquatic Chronic Cat 2 : H411 Aquatic Acute cat 2 : H401


Category 6 : 6 Aliphatics

n-Hexane Aquatic Chronic Cat 2 : H411 Aquatic Acute cat 2, Chronic cat 2 : H401, H411


Hydrocarbons, C6, isoalkanes, <5% n-hexane Aquatic Chronic Cat 2 : H411 Aquatic Acute cat 3, Chronic cat 2 : H402, H411


Hydrocarbons, C6, n-alkanes, isoalkanes, cyclics, n-hexane rich



Hydrocarbons, C5-C6, n-alkanes, isoalkanes, <5% n-hexane



Hydrocarbons, C6-C7, isoalkanes, cyclics, <5% n-hexane Aquatic Chronic Cat 2 : H411 Aquatic Acute cat 3, Chronic cat 2 : H402, H411


Hydrocarbons, C5-C7, n-alkanes, isoalkanes, n-hexane rich Aquatic Chronic Cat 2 : H411 Aquatic Acute cat 2, Chronic cat 2 : H401, H411


Category 7 : C7-C9 Aliphatics

Hydrocarbons, C7, n-alkanes, isoalkanes, cyclics Aquatic Chronic Cat 2 : H411 Aquatic Acute cat 2, Chronic cat 2 : H401, H411


Hydrocarbons, C6-C7, n-alkanes, isoalkanes, cyclics, >5% n-hexane



Hydrocarbons, C6-C7, n-alkanes, isoalkanes, cyclics, <5% n-hexane



Hydrocarbons, C7-C9, n-alkanes, isoalkanes, cyclics Aquatic Chronic Cat 2 : H411 Aquatic Acute cat 2, Chronic cat 2 : H401, H411


Hydrocarbons, C6-C10, n-alkanes, isoalkanes, >5% n-hexane



Hydrocarbons, C7-C9, isoalkanes Aquatic Chronic Cat 2 : H411 Aquatic Acute cat 2, Chronic cat 2 : H401, H411



4

Environment Hazards


Hydrocarbons, C7-C8, cyclics Aquatic Chronic Cat 2 : H411 Aquatic Acute cat 2, Chronic cat 2 : H401, H411


Normal-Heptane Aquatic Acute cat 1, Chronic cat 1 : H400, H410

Aquatic Acute cat 1, Chronic cat 1 : H400, H410

Very toxic for environment : R50/53

M factor : 10 M factor : 10

Iso-Heptane Aquatic Acute cat 1, Chronic cat 1 : H400, H410



Normal-Octane Aquatic Acute cat 1, Chronic cat 1 : H400, H410



Iso-Octane (2,2,4-triméthylpentane) Aquatic Acute cat 1, Chronic cat 1 : H400, H410



Nonane Aquatic Acute cat 1, Chronic cat 1 : H400, H410



Category 8 : C9-C14 Aliphatics (<2% Aromatics)

Hydrocarbons, C9-C11, n-alkanes, isoalkanes, cyclics, <2% aromatics


Not classified



Not classified

Hydrocarbons, C9-C11, isoalkanes, cyclics, <2% aromatics Aquatic Chronic Cat 2 : H411 Aquatic Acute cat 2, Chronic cat 2 : H401, H411




Not classified

Hydrocarbons, C10-C13, isoalkanes, cyclics, <2% aromatics Aquatic Chronic cat 3 : H412 Aquatic Chronic cat 3 : H412

Not classified



Not classified



Not classified



Not classified

Hydrocarbons, C11-C14, isoalkanes, cyclics, <2% aromatics Not classified Not classified

Not classified


5

Environment Hazards


Hydrocarbons, C10-C12, isoalkanes, <2% aromatics Aquatic chronic cat 2 : H411 Aquatic chronic cat 2 : H411


Hydrocarbons, C11-C12, isoalkanes, <2% aromatics Not classified Not classified


Hydrocarbons, C11-C13, isoalkanes, <2% aromatics Not classified Not classified

Not classified

Hydrocarbons, C10-C13, n-alkanes, <2% aromatics Not classified Not classified

Not classified


Not classified

Hydrocarbons, C9-C11, cyclics, <2% aromatics Aquatic Chronic Cat 2 : H411 Aquatic Acute cat 2, Chronic cat 2 : H401, H411


Decane Not classified Not classified

Not classified

Undecane Not classified Not classified

Not classified

Dodecane Not classified Not classified

Not classified

Tridecane Not classified Not classified

Not classified

Tetradecane Not classified Not classified

Not classified

Isododecane (2,2,4,6,6-pentamethylheptane) Aquatic chronic cat 1 : H410 Aquatic chronic cat 1 : H410


Hydrocarbons, C10-C14 (even numbered), n-alkanes, isoalkanes, <2% aromatics


Not classified

Hydrocarbons, C12-C16, isoalkanes, cyclics, < 2% aromatics


Not classified

Hydrocarbons, C12-C13, isoalkanes, cyclics, <2% aromatics Aquatic Chronic cat 3 : H412 Aquatic Chronic cat 3 : H412


Hydrocarbons, C8-C11, n-alkanes, isoalkanes, <2% aromatics


Not classified



Not classified



Not classified


6

Environment Hazards




Not classified




Not classified



Not classified



Not classified


Not classified


Not classified


Not classified


Not classified

Pentadecane Not classified Not classified

Not classified

Hexadecane Not classified Not classified

Not classified

Isohexadecane (2,2,4,4,6,8,8 heptamethylnonane) Not classified Not classified

Not classified

Heptadecane Not classified Not classified

Not classified

Octadecane Not classified Not classified

Not classified

Icosane (Hydrocarbons, C4, 1,3-butadiene-free, polymd., pentaisobutylene fraction, hydrogenated)


Not classified


Not classified

Hydrocarbons, C17-C19, n-alkanes, <2%aromatics Not classified Not classified

Not classified


Not classified



Not published



Not published


7

Physical chemical Hazards

Substance Name CLP classification GHS-UN classification

DSD classification


Hydrocarbons, C9, aromatics Flammable liquid cat 3 : H226 Flammable liquid cat 3 : H226

Flammable : R10

Category 2 : C10–C12 Aromatics

Hydrocarbons, C10, aromatics, >1% naphthalene

Not classified Flammable liquid cat 4 : H227

Not classified

Hydrocarbons, C10, aromatics, <1% naphthalene


Not classified

Hydrocarbons, C10-C13, aromatics, <1% naphthalene


Not classified

Hydrocarbons, C10-C13, aromatics, >1% naphthalene


Not classified



Not classified Flammable liquid cat 4

Not classified


Flammable liquid cat 3 : H226 Flammable liquid cat 3 : H226

Flammable : R10



Not classified




Not classified



Not classified


Normal-Pentane IBP <= 35°C Flammable liquid cat 1 : H224 Flammable liquid cat 1 : H224

Extremely flammable : R12

IBP > 35°C Flammable liquid cat 2 : H225 Flammable liquid cat 2 : H225

Highly flammable : R11

Iso-Pentane (2-methylbutane) Flammable liquid cat 1 : H224 Flammable liquid cat 1 : H224



8



DSD classification

Cyclopentane Flammable liquid cat 2 : H225 Flammable liquid cat 2 : H225


Hydrocarbons, C5, n-alkanes, isoalkanes Flammable liquid cat 1 : H224 Flammable liquid cat 1 : H224



n-Hexane Flammable liquid cat 2 : H225 Flammable liquid cat 2 : H225


Hydrocarbons, C6, isoalkanes, <5% n-hexane Flammable liquid cat 2 : H225 Flammable liquid cat 2 : H225





Hydrocarbons C5-C6, n-alkanes, isoalkanes, <5% n-hexane



Hydrocarbons, C6-C7, isoalkanes, cyclics, <5% n-hexane



Hydrocarbons, C5-C7, n-alkanes, isoalkanes, n-hexane rich




Hydrocarbons, C7, n-alkanes, isoalkanes, cyclics









Hydrocarbons, C7-C9, n-alkanes, isoalkanes, cyclics






Hydrocarbons, C7-C9, isoalkanes Flammable liquid cat 2 : H225 Flammable liquid cat 2 : H225


Hydrocarbons, C7-C8, cyclics Flammable liquid cat 2 : H225 Flammable liquid cat 2 : H225


Normal-Heptane Flammable liquid cat 2 : H225 Flammable liquid cat 2 : H225



9



DSD classification

Iso-Heptane Flammable liquid cat 2 : H225 Flammable liquid cat 2 : H225


Normal-Octane Flammable liquid cat 2 : H225 Flammable liquid cat 2 : H225


Iso-Octane (2,2,4-triméthylpentane) Flammable liquid cat 2 : H225 Flammable liquid cat 2 : H225


Nonane Flammable liquid cat 2 : H225 Flammable liquid cat 2 : H225


Category 8 : C9-C14 Aliphatics < 2% Aromatic



Flammable : R10



Flammable : R10

Hydrocarbons, C9-C11, isoalkanes, cyclics, <2% aromatics


Flammable : R10



Not classified



Not classified



Not classified



Not classified



Not classified



Not classified

Hydrocarbons, C10-C12, isoalkanes, <2% aromatics


Flammable : R10



Not classified



Not classified


10



DSD classification

Hydrocarbons, C10-C13, n-alkanes, <2% aromatics


Not classified



Not classified

Hydrocarbons, C9-C11, cyclics, <2% aromatics Flammable liquid cat 3 : H226 Flammable liquid cat 3 : H226

Flammable : R10

Decane Flammable liquid cat 3 : H226 Flammable liquid cat 3 : H226

Flammable : R10

Undecane Not classified Not classified

Not classified

Dodecane Not classified Not classified

Not classified

Tridecane Not classified Not classified

Not classified

Tetradecane Not classified Not classified

Not classified

Isododecane (2,2,4,6,6-pentamethylheptane)


Not classified



Not classified



Not classified



Not classified






Flammable : R10



Not classified



Not classified

Category 9 : C14-C20 Aliphatics < 2% Aromatics



Not classified


11



DSD classification



Not classified



Not classified



Not classified



Not classified



Not classified



Not classified

Pentadecane Not classified Not classified

Not classified

Hexadecane Not classified Not classified

Not classified

Isohexadecane (2,2,4,4,6,8,8 heptamethylnonane)


Not classified

Heptadecane Not classified Not classified

Not classified

Octadecane Not classified Not classified

Not classified



Not classified



Not classified

Hydrocarbons, C17-C19, n-alkanes, <2%aromatics


Not classified



Not classified



Not classified


12



DSD classification



Not classified


13

Health Hazards

Substance Name CLP classification GHS classification

DSD classification


Hydrocarbons, C9, aromatics Aspiration toxicity Cat 1 : H304 STOT SE 3 cat 3 : H335, H336 Skin defatting statement : EUH 066

Aspiration toxicity Cat 1 : H304 STOT SE 3 cat 3 : H335, H336

Irritant to respiratory system : R37 Harmful : R65 Skin dryness : R66 Narcotic effect : R67

Category 2 : C10-C12 Aromatics

Hydrocarbons, C10, aromatics, >1% naphthalene

Carcinogen cat 2 : H351 Aspiration toxicity Cat 1 : H304 STOT SE 3 cat 3 : H336 Skin defatting statement : EUH 066

Carcinogen cat 2 : H351 Aspiration toxicity Cat 1 : H304 STOT SE 3 cat 3 : H336

Carcinogenic category 3 : R40 Harmful : R65 Skin dryness : R66 Narcotic effect : R67

Hydrocarbons, C10, aromatics, <1% naphthalene

Aspiration toxicity Cat 1 : H304 STOT SE 3 cat 3 : H336 Skin defatting statement : EUH 066

Aspiration toxicity Cat 1 : H304 STOT SE 3 cat 3 : H336

Harmful : R65 Skin dryness : R66 Narcotic effect : R67

Hydrocarbons, C10-C13, aromatics, <1% naphthalene

Aspiration toxicity Cat 1 : H304 Skin defatting statement : EUH 066

Aspiration toxicity Cat 1 : H304

Harmful : R65 Skin dryness : R66

Hydrocarbons, C10-C13, aromatics, >1% naphthalene

Carcinogen cat 2 : H351 Aspiration toxicity Cat 1 : H304 Skin defatting statement : EUH 066

Carcinogen cat 2 : H351 Aspiration toxicity Cat 1 : H304

Carcinogenic category 3 : R40 Harmful : R65 Skin dryness : R66



STOT RE 1 (inhalation) : H372 Aspiration toxicity Cat 1 : H304 Skin defatting statement : EUH 066

STOT RE 1 (inhalation) : H372 Aspiration toxicity Cat 1 : H304

Harmful by repeated exposure (inhalation) : R48/20 Harmful : R65 Skin dryness : R66


14

Health Hazards


DSD classification


STOT RE 1 (inhalation) : H372 Aspiration toxicity Cat 1 : H304 STOT SE 3 cat 3 : H336 Skin defatting statement : EUH 066

STOT RE 1 (inhalation) : H372 Aspiration toxicity Cat 1 : H304 STOT SE 3 cat 3 : H336

Harmful by repeated exposure (inhalation) : R48/20 Harmful : R65 Skin dryness : R66 Narcotic effect : R67















Normal-Pentane Aspiration toxicity Cat 1 : H304 STOT SE 3 cat 3 : H336 Skin defatting statement : EUH 066



Iso-Pentane (2-methylbutane) Aspiration toxicity Cat 1 : H304 STOT SE 3 cat 3 : H336 Skin defatting statement : EUH 066



Cyclopentane Aspiration toxicity Cat 1 : H304 STOT SE 3 cat 3 : H336 Skin defatting statement : EUH 066



Hydrocarbons, C5, n-alkanes, isoalkanes





15

Health Hazards


DSD classification

Skin defatting statement : EUH 066

Narcotic effect : R67

Category 6 : 6 Aliphatics

n-Hexane STOT RE cat 2 (inhalation) H373 Skin irritant cat 2 : H315 Reproductive toxicity Cat 2 : H361 Aspiration toxicity Cat 1 : H304 STOT SE 3 cat 3 : H336

STOT RE cat 2 (inhalation) H373 Skin irritant cat 2 : H315 Reproductive toxicity Cat 2 : H361 Aspiration toxicity Cat 1 : H304 STOT SE 3 cat 3 : H336

Harmful by repeated exposure (inhalation) : R48/20 Irritant to skin : R38 Toxic to reproduction category 3 : R62 Harmful : R65 Narcotic effect : R67

Hydrocarbons, C6, isoalkanes, <5% n-hexane

Skin irritant cat 2 : H315 Aspiration toxicity Cat 1 : H304 STOT SE 3 cat 3 : H336


Skin irritant : R38 Harmful : R65 Narcotic effect : R67





Hydrocarbons, C5-C6, n-alkanes, isoalkanes, <5% n-hexane




Hydrocarbons, C6-C7, isoalkanes, cyclics, <5% n-hexane




Hydrocarbons, C5-C7, n-alkanes, isoalkanes, n-hexane rich

STOT RE cat 2 (inhalation) H373 Skin irritant cat 2 : H315 Reproductive toxicity Cat 2 : H361 Aspiration toxicity Cat 1 : H304

STOT RE cat 2 (inhalation) H373 Skin irritant cat 2 : H315 Reproductive toxicity Cat 2 : H361 Aspiration toxicity Cat 1 : H304

Harmful by repeated exposure (inhalation) : R48/20 Irritant to skin : R38 Toxic to reproduction category 3 : R62


16

Health Hazards


DSD classification

STOT SE 3 cat 3 : H336 STOT SE 3 cat 3 : H336

Harmful : R65 Narcotic effect : R67


Hydrocarbons, C7, n-alkanes, isoalkanes, cyclics












Hydrocarbons, C7-C9, n-alkanes, isoalkanes, cyclics








Hydrocarbons, C7-C9, isoalkanes Skin irritant cat 2 : H315 Aspiration toxicity Cat 1 : H304 STOT SE 3 cat 3 : H336



Hydrocarbons, C7-C8, cyclics Skin irritant cat 2 : H315 Aspiration toxicity Cat 1 : H304

Skin irritant cat 2 : H315 Aspiration toxicity Cat 1 : H304

Skin irritant : R38 Harmful : R65


17

Health Hazards


DSD classification

STOT SE 3 cat 3 : H336 STOT SE 3 cat 3 : H336 Narcotic effect : R67

Normal-Heptane Skin irritant cat 2 : H315 Aspiration toxicity Cat 1 : H304 STOT SE 3 cat 3 : H336



Iso-Heptane Skin irritant cat 2 : H315 Aspiration toxicity Cat 1 : H304 STOT SE 3 cat 3 : H336



Normal-Octane Skin irritant cat 2 : H315 Aspiration toxicity Cat 1 : H304 STOT SE 3 cat 3 : H336



Iso-Octane (2,2,4-triméthylpentane)




Nonane Skin irritant cat 2 : H315 Aspiration toxicity Cat 1 : H304 STOT SE 3 cat 3 : H336
















Aspiration toxicity Cat 1 : H304 Aspiration toxicity Cat 1 : H304

Harmful : R65


18

Health Hazards


DSD classification



Skin dryness : R66









































Hydrocarbons, C9-C11, cyclics, <2% aromatics



Skin irritant : R38 Harmful : R65

Decane Aspiration toxicity Cat 1 : H304 Skin defatting statement : EUH 066




19

Health Hazards


DSD classification

Undecane Aspiration toxicity Cat 1 : H304 Skin defatting statement : EUH 066



Dodecane Aspiration toxicity Cat 1 : H304 Skin defatting statement : EUH 066



Tridecane Aspiration toxicity Cat 1 : H304 Skin defatting statement : EUH 066



Tetradecane Aspiration toxicity Cat 1 : H304 Skin defatting statement : EUH 066



Isododecane (2,2,4,6,6-pentamethylheptane)




























Aspiration toxicity Cat 1 : H304 Aspiration toxicity Cat 1 : H304

Harmful : R65


20

Health Hazards


DSD classification



Skin dryness : R66






























Pentadecane Aspiration toxicity Cat 1 : H304 Skin defatting statement : EUH 066



Hexadecane Aspiration toxicity Cat 1 : H304 Skin defatting statement : EUH 066



Isohexadecane (2,2,4,4,6,8,8 heptamethylnonane)

Toxic (inhalation) cat 4 : H332 Aspiration toxicity Cat 1 : H304 Skin defatting statement : EUH 066

Toxic (inhalation) cat 4 : H332 Aspiration toxicity Cat 1 : H304

Harmful : R20 Harmful : R65 Skin dryness : R66

Heptadecane Aspiration toxicity Cat 1 : H304 Skin defatting statement : EUH 066




21

Health Hazards


DSD classification

Octadecane Aspiration toxicity Cat 1 : H304 Skin defatting statement : EUH 066











Hydrocarbons, C17-C19, n-alkanes, <2%aromatics
















classification & labelling summary (c&l … documents/p-i163...aquatic chronic cat 3 : h412...

Documents