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3

OSHABRIEFHazardCommunicationStandard:SafetyDataSheets

TheHazardCommunicationStandard(HCS)(29CFR1910.1200(g)),revisedin2012,requiresthatthechemicalmanufacturer,distributor,orimporterprovideSafetyDataSheets(SDSs)(formerlyMSDSsorMaterialSafetyDataSheets)foreachhazardouschemicaltodownstreamuserstocommunicateinformationonthesehazards.TheinformationcontainedintheSDSislargelythesameastheMSDS,exceptnowtheSDSsarerequiredtobepresentedinaconsistentuserfriendly,16sectionformat.ThisbriefprovidesguidancetohelpworkerswhohandlehazardouschemicalstobecomefamiliarwiththeformatandunderstandthecontentsoftheSDSs.

TheSDSincludesinformationsuchasthepropertiesofeachchemical;thephysical,health,andenvironmentalhealthhazards;protectivemeasures;andsafetyprecautionsforhandling,storing,andtransportingthechemical.TheinformationcontainedintheSDSmustbeinEnglish(althoughitmaybeinotherlanguagesaswell).Inaddition,OSHArequiresthatSDSpreparersprovidespecificminimuminformationasdetailedinAppendixDof29CFR1910.1200.TheSDSpreparersmayhavealsoincludedadditionalinformationinvarioussection(s).

Sections1through8containgeneralinformationaboutthechemical,identification,hazards,composition,safehandlingpractices,andemergencycontrolmeasures(e.g.,firefighting).Thisinformationshouldbehelpfultothosethatneedtogettheinformationquickly.Sections9through11and16containothertechnicalandscientificinformation,suchasphysicalandchemicalproperties,stabilityandreactivityinformation,toxicologicalinformation,exposurecontrolinformation,andotherinformationincludingthedateofpreparationorlastrevision.TheSDSmustalsostatethatnoapplicableinformationwasfoundwhenthepreparerdoesnotfindrelevantinformationforanyrequiredelement.

TheSDSmustalsocontainSections12through15,tobeconsistentwiththeUNGloballyHarmonizedSystemofClassificationandLabelingofChemicals(GHS),butOSHAwillnotenforcethecontentofthesesectionsbecausetheyconcernmattershandledbyotheragencies.

AlabamaCorrectionalIndustriesencouragesandexpectsyoutoreadandunderstandthe(M)SDSassociatedwithourJanitorialproductsasthereisimportantinformationthroughoutthedocument.Pleasefollowanyprecautionsidentifiedandlistedunlessyouruseconditionswouldnecessitateotherappropriatemethodsoractionsbetaken.

ContactInformation:AlabamaCorrectionalIndustries

1400LloydStreetMontgomery,Al.36107OfficeHours7:30a.m.4:30p.m.MF

Sales:1800ACI7007Phone:3342613600Fax:3342403162

Online:www.aci.alabama.govEmail:[email protected]:

CenterforDiseaseControl(CDC)18002324636oranyemergencymedicalfacilityinyourlocale.

Fornonemergencyassistance,call:12054672257

4

TableofContentsOSHABRIEF................................................................................................................................................................3

AIR FRESHENER MINT...........................................................................................................................................6

ALL PURPOSE LIQUID CLEANER.........................................................................................................................10

ALL PURPOSE MANUAL DETERGENT.................................................................................................................15

ANTIBACTERIAL LIQUID HAND SOAP...............................................................................................................19

AUTOMATIC DISHWASHING COMPOUND CHLORINATED.............................................................................23

AUTOMOTIVE WASH CONCENTRATE................................................................................................................27

BATHROOM CLEANER WITH MILDEW REMOVER............................................................................................31

CITRUS DEGREASER, HOUSEHOLD & INSTITUTIONAL.................................................................................35

DETERGENT/DISINFECTANT LEMON SCENT...................................................................................................39

DETERGENT/DISINFECTANT PINE SCENT........................................................................................................45

DRAIN OPENER LIQUID.......................................................................................................................................51

DRY BLEACH..........................................................................................................................................................55

DRYING AGENT.....................................................................................................................................................59

FLOOR FINISH 20% SOLIDS...............................................................................................................................63

GREEN FRIENDLY LIQUID LAUNDRY DETERGENT..........................................................................................67

HAND DISHWASHING LIQUID............................................................................................................................71

LAUNDRY DETERGENT POWDER.......................................................................................................................75

LIME SOLVENT......................................................................................................................................................79

LIQUID BLEACH.....................................................................................................................................................83

LIQUID HAND SOAP.............................................................................................................................................87

LIQUID HEAVY DUTY MACHINE DISH DETERGENT........................................................................................91

LIQUID LAUNDRY DETERGENT..........................................................................................................................95

LIQUID LAUNDRY SOUR......................................................................................................................................99

OVEN & GRILL CLEANER...................................................................................................................................103

SCOURING CLEANSER........................................................................................................................................107

SPRAY & WIPE CLEANER...................................................................................................................................111

TOILET BOWL CLEANER LIQUID......................................................................................................................115

UNDERCOAT SEALER..........................................................................................................................................119

WAX STRIPPER, AMMONIATED........................................................................................................................123

W

W

W

W

WAX STRIPP

WINDOW &

WINDOW &

WINDSHIELD

PER, NO AMM

GLASS CLEA

GLASS CLEA

D WASHER F

MONIA.........

ANER, AMMO

ANER, NO A

FLUID..........

.....................

ONIATED.....

AMMONIA.....

.....................

5

......................

......................

......................

......................

.....................

.....................

.....................

.....................

.....................

.....................

.....................

.....................

......................

......................

......................

......................

.........127

.........131

.........135

.........139

6

AIR FRESHENER MINT

0 HEALTH SAFETY DATA SHEET 0 FIRE 0 REACTIVITY

AIR FRESHENER MINT B PERSONAL PROTECTION

Section 1: Identification Product Name: Air Freshener Mint Contact Information:

Alabama Correctional Industries 1400 Lloyd Street Montgomery, Al. 36107 Office Hours 7:30 a.m. 4:30 p.m. M - F Sales: 1-800-ACI-7007 Phone: 334-261-3600 Fax: 334-240-3162 Online: www.aci.alabama.gov Email: [email protected]

After Hour emergency contact: Center for Disease Control (CDC) or any emergency medical facility in your locale. For non-emergency assistance, call:1-205-467-2257

Catalog Codes: JAAFM-size (ACI Janitorial Product)

Product Usage:

A fragrance can brighten your surroundings in seconds, while all unpleasant odors are dispelled instantly. Chemically neutralizes main unpleasant odors and replaces them with a clean fresh natural fragrance.

Section 2: Hazard(s) Identification

WARNING: Breathing concentrated vapors may cause slight irritation of respiratory tract. Contact with eyes may cause irritation. Prolonged contact may cause slight irritation.

THRESHOLD LIMIT VALUE: N/A CARCINOGEN: none EFFECTS OF OVEREXPOSURE: NO EFFECTS INDICATED

Section 3: Composition/Information on Ingredients Ingredients CAS# %by Weight

Triethylene Glycol 112-27-6 11.12 Isopropyl Alcohol 67-63-0 15.78 Bio-Terge Pas-8s Proprietary 2.27 Mint Fragrance 5989-27-5 1.2

0 0

0

7

Section 4: First-Aid Measures

INHALATION: Remove victim to fresh air; If symptoms persist, seek medical attention. EYES: Flush eyes for 15 minutes in clear running water. If irritation persists, seek medical attention. SKIN: Remove contaminated clothing; Wash area with clear water. If irritation persists, seek medical attention. INGESTION: Give two glasses or water for dilution; induce vomiting; Seek medical attention.

Section 5: Fire-Fighting Measures

FLASH POINT: No Flash at Boil FLAMMABLE LIMITS: N/A EXTINGUISHING MEDIA: CO2, Water Fog, Dry Chemical, Chemical Foam FIRE FIGHTING PROCEDURES: Keep cool with water spray to prevent container rupture due to pressure build up.

Section 6: Accidental Release Measures

SMALL SPILLS: Wash to sanitary sewer with plenty of water. LARGE SPILLS: Confine spill; Soak up with approved absorbent.

Section 7: Handling and Storage

PRECAUTIONS TO BE TAKEN IN HANDLING AND STORAGE: Keep container closed when not in use. Protect containers from abuse. Store in clean, dry cool area. OTHER PRECAUTIONS: As with all chemicals use due care according to labeled instructions and precautions.

Section 8: Exposure Controls/Personal Protection

RESPIRATORY PROTECTION: N/A PROTECTIVE GLOVES: Neoprene or Rubber EYE PROTECTION: Goggles with shields PROTECTIVE CLOTHING OR EQUIPMENT: Safety Eyebath nearby.

Section 9: Physical and Chemical Properties

Physical State Liquid Upper/Lower Flammability Or Explosive Limits; N/A

Color Green Volatility 85.4% Odor Mint Vapor Pressure N/A Odor Threshold N/A Vapor Density N/A Ph 6.44 Relative Density N/A Melting Point/Freezing Point N/A Solubility(Ies) Complete In Water

Initial Boiling Point And Boiling Range 212F Partition Coefficient: N-Octanol/Water Complete

Flash Point No Flash At Boil Auto-Ignition Temperature N/A Evaporation Rate N/A Decomposition Temperature N/A Flammability (Solid, Gas) N/A Viscosity N/A Specific Gravity 1.00

8

Section 10: Stability and Reactivity

STABILITY DATA: Stable HAZARDOUS POLYMERIZATION: Will not occur INCOMPATIBILITY: Avoid strong acids and strong oxidizers. CONDITIONS TO AVOID: None HAZARDOUS DECOMPOSITION PRODUCT: None

Section 11: Toxicological Information

This product is based on a formulation with over 69% water dilatant. The largest ingredient used within the formulation is isopropyl alcohol. The following information is based on this ingredient. Acute Toxicity:

Moderately Toxic: probable oral lethal dose (human) 0.5-5 gm/kg. for 70-kg person. Inhalation:

Moderate may involve both irreversible and reversible changes not severe enough to cause death or permanent damage.

Eye contact: Moderate may involve both irreversible and reversible changes not severe enough to cause death or permanent

damage. Skin contact:

Moderate may involve both irreversible and reversible changes not severe enough to cause death or permanent damage.

Carcinogenicity Information: IARC assessment: is not classifiable as to its carcinogenicity to humans (Group 3).

Section 12: Ecological Information (non-mandatory)

Non Available

Section 13: Disposal Considerations (non-mandatory)

WASTE DISPOSAL METHOD: Dispose in accordance with local, state, and federal regulations.

Section 14: Transport Information (non-mandatory)

None Available

Section 15: Regulatory Information (non-mandatory)

PRECAUTIONS TO BE TAKEN IN HANDLING AND STORAGE: Keep container closed when not in use. Protect containers from abuse. Store in clean, dry cool area.

OTHER PRECAUTIONS: As with all chemicals use due care according to labeled instructions and precautions

9

Section 16: Other Information

Created Date: 11-17-92 MSDS Revised: 12-03-02 Conversion to SDS and updated: 03-25-14

HEALTH HAZARD 4-Deadly 3-Extreme Danger 2-Hazardous 1-Slightly 0 Normal Material

FIRE HAZARD 4-Below 73F 3-Below 100F 2-Below 200F 1-Above 200F 0-Will not burn

Specific Hazard Oxidizer OXY Acid ACID Alkali ALK Corrosive COR Use NO WATER W Radiation Hazard

Polymerizes P

INSTABILITY 4-May Detonate 3-Shock and heat may detonate 2-Violent Chemical change 1-Unstable if Heated 0-Stable

PERSONAL PROTECTION: [A] = SAFETY GLASSES, [B] = SAFETY GLASSES & RUBBER GLOVES, [C] = SAFETY GLASESS, RUBBER GLOVES, CHEMICAL APRON, [D] = SAFETY GLASESS, RUBBER GLOVES, CHEMICAL APRON, FOOT COVERING The information above is believed to be accurate and represents the best information currently available to us. However, we make no warranty of merchantability or any other warranty, expressed or implied, with respect to such information, and we assume no liability resulting from its use. Users should make their own investigations to determine the stability of the information for their particular purposes. In no event shall Alabama Correctional Industries be liable for any claims, losses, or damages of any third party or for lost profits or any special, indirect, incidental, consequential or exemplary damages, however arising, even if Alabama Correctional Industries has been advised of the possibility of such damages.

TYP

E H

AZA

RD

HEALTH

DEG

REE

4-Extereme

FLAMMABILITY 3-SeriousINSTABILITY 2-Moderate

PROTECTIVEEQUIPMENT

1-slight

0-Minimal

10

ALL PURPOSE LIQUID CLEANER


ALL PURPOSE LIQUID CLEANER B PERSONAL PROTECTION

Section 1: Identification Product Name: All Purpose Liquid Cleaner Contact Information:



Catalog Codes: JACLAP size (ACI Janitorial Product)

Product Usage:

Synthetic Liquid Detergent For Use On Every Surface Not Harmed By Water


WARNING: INHALATION: Breathing concentrated vapors may cause slight irritation of respiratory tract. EYES: Contact with eyes will cause irritation. SKIN: Prolong contact may cause slight irritation. INGESTION: May cause gastric distress, vomiting, and diarrhea.

THRESHOLD LIMIT VALUE: N/A CARCINOGEN: This product contains and ingredient reported to have carcinogens or suspected carcinogens.

EFFECTS OF OVEREXPOSURE: No effects indicated


ESI-Tergge 1281 (HA-20) Proprietary 6.53 Sodium Tripolyphosphate 7758-29-4 2.08 Benzene Sulfonic Acid 68081-81-2 2.72 Trisodium Phosphate 10101-89-0 2.08

Section 4: First-Aid Measures INHALATION: Remove victim to fresh air, if symptoms persist seek medical attention. EYES: Flush eyes for 15 minutes in clear running water; if irritation persists, seek medical attention. SKIN: Remove contaminated clothing, wash area with clear water; If irritation persists, seek medical attention. INGESTION: Give two glasses of water for dilution. Do not induce vomiting; Seek medical attention.

0 1

0

11


FLASH POINT: No flash at boil. FLAMMABLE LIMITS: N/A EXTINGUISHING MEDIA: CO2, Water Fog, Dry Chemical, Chemical Foam. FIRE FIGHTING PROCEDURES: Keep cool with water spray to prevent container rupture due to steam build up. Floor will become slippery if material is released.


Keep container closed when not in use. Protect containers from abuse. Store in clean, dry cool area. OTHER PRECAUTIONS: As with all chemicals use due care according to labeled instructions and precautions.


RESPIRATORY PROTECTION: NIOSH approved respirator capable of removing airborne particles must be used if concentration exceeds maximum allowable TWA. PROTECTIVE GLOVES: Neoprene or Rubber EYE PROTECTION: Goggles with shields PROTECTIVE CLOTHING OR EQUIPMENT: Chemical resistant apron, foot covering. Safety Eyebath nearby.



Color Red Volatility 87.7% Odor Floral Vapor Pressure N/A Odor Threshold N/A Vapor Density N/A Ph 9.09 Relative Density N/A Melting Point/Freezing Point N/A Solubility(Ies) Complete In Water

Initial Boiling Point And Boiling Range 212F Partition Coefficient: N-Octanol/Water (Water Solubility)



SMALL SPILLS: Wash to sewer with plenty of water. LARGE SPILLS: Confine spill; Soak up with approved absorbent.

12

Section 10: Stability and Reactivity STABILITY DATA: Stable HAZARDOUS POLYMERIZATION: Will not occur INCOMPATIBILITY: Avoid strong acids and strong oxidizers CONDITIONS TO AVOID: Extreme temperatures HAZARDOUS DECOMPOSITION PRODUCT: None


This product is formulated with ESI-Tergge 1281 (HA-20) at 6.53%, the largest ingredient used within the formulation. The following information is based on this ingredient.

Acute Toxicity: May cause mouth, throat, esophagus and stomach irritation, nausea, vomiting and diarrhea.

Inhalation: Prolonged overexposure to vapors or dust in poorly ventilated areas mas cause nose and throat irritation.

Eye contact: May cause irritation

Skin contact: May cause mild irritation

Carcinogenicity Information: This product contains reported carcinogens or suspected carcinogens.

Chemical Name Oral LD50 Dermal LD50 Inhalation LC50 Diethanolamine 111-42-2

= 620 L/kg ( Rat ) = 7640 L/kg ( Rabbit ) -

Cocamide DEA 68603-42-9

= 12400 L/kg ( Rat ) - -

Tall Oil Fatty Acid 61790-12-3

= 7600 mg/kg ( Rat ) - -

1,2 Propanediol 57-55-6

= 20000 mg/kg ( Rat ) = 20800 mg/kg ( Rabbit ) -

Chemical Name ACGIH IARC NTP OSHA


Group 2B X

Diethanolamine 111-42-2

A3 Group 2B X

13


Chemical Name Algae/aquatic plants Fish Toxicity to microorganisms

Crustacea

Diethanolamine 111-42-2

7.8: 72 h Desmodesmus subspicatus mg/L EC50 2.1 - 2.3: 96 h Pseudokirchneriella subcapitata mg/L EC50

4460 - 4980: 96 h Pimephales promelas mg/L LC50 flow-through 1200 - 1580: 96 h Pimephales promelas mg/L LC50 static 600 - 1000: 96 h Lepomis macrochirus mg/L LC50 static

EC50 = 73 mg/L 5 min EC50 > 16 mg/L 16 h

55: 48 h Daphnia magna mg/L EC50


3.6: 96 h Brachydanio rerio mg/L LC50 semi-static

4.2: 24 h Daphnia magna mg/L EC50


3.6: 96 h Brachydanio rerio mg/L LC50 semi-static

Tall Oil Fatty Acid 61790-12-3

1000: 72 h Pseudokirchneriella subcapitata mg/L EC50


19000: 96 h Pseudokirchneriella subcapitata mg/L EC50

51600: 96 h Oncorhynchus mykiss mg/L LC50 static 41 - 47: 96 h Oncorhynchus mykiss mL/L LC50 static 51400: 96 h Pimephales promelas mg/L LC50 static 710: 96 h Pimephales promelas mg/L LC50

10000: 24 h Daphnia magna mg/L EC50 1000: 48 h Daphnia magna mg/L EC50 Static


Persistence and Degradability Not determined Bioaccumulation Not determined




None Available




14






Polymerizes P



TYP

E H

AZA

RD

HEALTH

DEG

REE

4-Extereme


PROTECTIVEEQUIPMENT

1-slight

0-Minimal

15

ALL PURPOSE MANUAL DETERGENT

Section 1: Identification Product Name: All Purpose Manual Detergent Contact Information:



Catalog Codes: JADAPMP-size (ACI Janitorial Product)

Product Usage:

This biodegradable product is properly balanced for quick and thorough removal of grease and soil from dishes, glassware, pots, pans, and other hard surfaces.


WARNING: INHALATION: Nuisance dust. EYES: Contact with eyes may be painful and irritating. SKIN: May be irritating with prolong contact. INGESTION: Irritating to digestive tract.

THRESHOLD LIMIT VALUE: N/A CARCINOGEN: None EFFECTS OF OVEREXPOSURE: No effects indicated.


Sodium Tripolyphosphate 7758-29-4 23.33 Sodium Sulfate 7757-82-6 50 Sodium Bicarbonate 144-55-8 20 Nonyl Phenol Ethoxylate 9016-45-9 5.33


ALL PURPOSE MANUAL DETERGENT B PERSONAL PROTECTION

0 1

0

16

Section 4: First-Aid Measures

INHALATION: Remove to fresh air. EYES: Immediately flush eyes for 15 minutes in clear running water. SKIN: Wash contact area w/soap & water; remove contaminated clothing and launder before reuse; If irritation persists, seek medical attention. INGESTION: Induce vomiting; Get medical attention.


FLASH POINT: N/A FLAMMABLE LIMITS: N/A EXTINGUISHING MEDIA: CO2, Water Fog, Dry Chemical, Chemical Foam. FIRE FIGHTING PROCEDURES: Exposure to water will cause the floor to become slippery.




Physical State Granular Powder Upper/Lower Flammability Or Explosive Limits; N/A

Color Orange Volatility N/A Odor None Vapor Pressure N/A Odor Threshold N/A Vapor Density N/A Ph 8.2 Relative Density N/A Melting Point/Freezing Point N/A Solubility(Ies) Complete In Water

Initial Boiling Point And Boiling Range N/A Partition Coefficient: N-Octanol/Water (Water Solubility)

Flash Point N/A Auto-Ignition Temperature N/A Evaporation Rate N/A Decomposition Temperature N/A Flammability (Solid, Gas) N/A Viscosity N/A Specific Gravity N/A


SMALL SPILLS: Sweep up as much solids as possible flush remaining material to drain with water. LARGE SPILLS: Same as small spills.

Section 8: Exposure Controls/Personal Protection RESPIRATORY PROTECTION: Dust mask PROTECTIVE GLOVES: Neoprene or Rubber EYE PROTECTION: Goggles with shields PROTECTIVE CLOTHING OR EQUIPMENT: None required

17


STABILITY DATA: Stable HAZARDOUS POLYMERIZATION: Will not occur INCOMPATIBILITY: Avoid strong acids or oxidizers CONDITIONS TO AVOID: Storing in damp or wet conditions. HAZARDOUS DECOMPOSITION PRODUCT: None


The largest ingredient used within the formulation is Sodium Sulfate-50lbs. The following information is based on this ingredient.

General: LD50 5989 mg/kg oral mouse

Inhalation: Irritation of the upper respiratory tract.

Eye contact: Irritation

Skin contact: Irritation

Carcinogenicity Information: None identified


Base on the largest ingredient: Sodium Sulfate, Anhydrous When released into the soil, this material is expected to leach into groundwater. This material is not expected

to significantly bioaccumulate. This material is not expected to be toxic to aquatic life. The LCD/96-hour values for fish are over 100 mg/l. The

ECO50/48-hour values for daphnia are over 100 mg/l.




None Available




18






Polymerizes P



TYP

E H

AZA

RD

HEALTH

DEG

REE

4-Extereme


PROTECTIVEEQUIPMENT

1-slight

0-Minimal

19

ANTIBACTERIAL LIQUID HAND SOAP


ANTIBACTERIAL LIQUID HAND SOAP B PERSONAL PROTECTION

Section 1: Identification Product Name: Antibacterial Liquid Hand Soap Contact Information:



Catalog Codes: JASHAB-size (ACI Janitorial Product)

Product Usage:

Antibacterial Hand Soap contains a proven germ fighting ingredient to provide strong antibacterial protection, specifically formulated for broad spectrum degerming. Ideal for restrooms, staff crew sinks and washrooms.


WARNING: INHALATION: None expected; no information available. EYES: Mildly irritating. Can cause severe eye irritation and permanent eye damage. SKIN: Prolonged contact may result in dermatitis and defatting. INGESTION: No information available.

THRESHOLD LIMIT VALUE: Not established. CARCINOGEN: Not established. EFFECTS OF OVEREXPOSURE: See SKIN WARNING above.


CustoBlend BAC Proprietary 26.2% Water 7732-15-5 73.7%

Section 4: First-Aid Measures INHALATION: Not an expected route of exposure. If irritation occurs, move subject to fresh air. If irritation still persists, consult a physician. EYES: Flush eyes with water for at least 15 minutes. If irritation persists, seek medical attention. SKIN: Remove contaminated clothing. Wash exposed skin with water. Launder clothing before reuse. INGESTION: Consult a physician or poison control. Drink 1 to 2 glass of water. Do not induce vomiting or give anything by mouth.

0 0

0

20


FLASH POINT: No flash at boil. FLAMMABLE LIMITS: N/A EXTINGUISHING MEDIA: Co2, Foam, Dry Chemical, Water Spray. FIRE FIGHTING PROCEDURES: No special requirements; closed containers may rupture due to build up of pressure when exposed to extreme heat.


HANDLING: Avoid contact with skin and eyes. Avoid breathing vapor. Wear gloves and safety glasses. STORAGE: Avoid extreme temperatures.



Color Light Blue Volatility 74.5% Odor Characteristic Vapor Pressure N/A Odor Threshold N/A Vapor Density N/A Ph 7.6 9.0 Relative Density N/A Melting Point/Freezing Point N/A Solubility(Ies) Complete In Water


Flash Point No Flash At Boil Auto-Ignition Temperature N/A Evaporation Rate N/A Decomposition Temperature N/A Flammability (Solid, Gas) N/A Viscosity N/A Specific Gravity .95 1.2

Section 10: Stability and Reactivity STABILITY DATA: Stable HAZARDOUS POLYMERIZATION: Will not occur. INCOMPATIBILITY: None CONDITIONS TO AVOID: Avoid extreme temperatures. HAZARDOUS DECOMPOSITION PRODUCT: Thermal decomposition may produce CO, CO2, Hydrogen chloride and oxides of nitrogen.


SMALL SPILLS: Flush with plenty of water, rinse to sewer. LARGE SPILLS: Dike spill. Absorb with sawdust, sand or other suitable absorbent material and collect in a suitable container for disposal.

Section 8: Exposure Controls/Personal Protection RESPIRATORY PROTECTION: General exhaust. Respirators not normally required. PROTECTIVE GLOVES: Neoprene or rubber gloves. EYE PROTECTION: Safety glasses with shields or goggles. PROTECTIVE CLOTHING OR EQUIPMENT: Safety Eyebath nearby.

21


This product is based on a formulation with over 73% water dilatant. The largest ingredient used within the formulation is 4- Choro- 3,5 Xylenol (CAS#: 88-04-0). The following information is based on this ingredient.

Threshold Limit value (ACGIH TLV): Not Established OSHA Permissible Exposure Limit (PEL): Not established Inhalation: Not Available Skin Contact: Prolonged contact may result in dermatitis and defatting. Eye contact: Not Available Ingestion: Not Available


Non Available

Section 13: Disposal Considerations (non-mandatory) WASTE DISPOSAL METHOD: Dispose in accordance with local, state, and federal regulations.


Not Applicable




22






Polymerizes P



TYP

E H

AZA

RD

HEALTH

DEG

REE

4-Extereme


PROTECTIVEEQUIPMENT

1-slight

0-Minimal

23

AUTOMATIC DISHWASHING COMPOUND CHLORINATED

0 HEALTH SAFETY DATA SHEET 0 FIRE 0 REACTIVITY AUTOMATIC DISHWASHING COMPOUND

CHLORINATED B PERSONAL PROTECTION

Section 1: Identification Product Name: Automatic Dishwashing Compound

Chlorinated Contact Information:



Catalog Codes: JADWMP-size (ACI Janitorial Product)

Product Usage:

A specially formulated compound for effective cleaning action. Contains stain removers. Its designed to be free rinsing without water spotting. Safe for porcelain and fine china. Will not discolor aluminum.


DANGER: INHALATION: Corrosive and irritating to upper respiratory tract and mucous membrane. EYES: Corrosive; contact with eyes is painful and irritating and will cause chemical burns. SKIN: Corrosive and irritating; Chemical burns may result from contact. Severe irritant. Wash contact area

w/soap & water. INGESTION: Corrosive and irritating to digestive tract; may cause gastric distress, stomach pains and

vomiting. THRESHOLD LIMIT VALUE: N/A CARCINOGEN: None EFFECTS OF OVEREXPOSURE: No effects indicated


Sodium Dichloroisocyanurate Dihyrate 51580-86-0 4.55 Sodium Metasilicate 6834-92-0 27.27 Sodium Tripoliphosphate, 7758-29-4 45.45 Sodium Carbonate (Nuisance Dust) 497-19-4 18.18

0 1

0

24

Section 4: First-Aid Measures INHALATION: Remove to fresh air; wash mouth and nasal passages with water repeatedly; if breathing difficulties persist-seek medical attention. EYES: Immediately flush eyes for 15 minutes in clear running water; get medical attention immediately. SKIN: Severe irritant. Wash contact area w/soap & water; Do not attempt to neutralize w/chemical agents. If irritation persists, seek medical attention. INGESTION: Drink large quantities of water or milk. Do not induce vomiting; Get medical attention. Give diluted vinegar or lemon juice to conscious person.


FLASH POINT: N/A FLAMMABLE LIMITS: N/A EXTINGUISHING MEDIA: CO2, Water Fog, Dry Chemical, Chemical Foam. FIRE FIGHTING PROCEDURES: Floor will become slippery if material is exposed to water.



Section 9: Physical and Chemical Properties Physical State Granular Powder Upper/Lower Flammability Or Explosive Limits; N/A

Color White Volatility N/A Odor Chlorine Vapor Pressure N/A Odor Threshold N/A Vapor Density N/A Ph 11.72 Relative Density N/A Melting Point/Freezing Point N/A Solubility(Ies) Complete In Water

Initial Boiling Point And Boiling Range N/A Partition Coefficient: N-Octanol/Water (Water Solubility)

Flash Point N/A Auto-Ignition Temperature N/A Evaporation Rate N/A Decomposition Temperature N/A Flammability (Solid, Gas) N/A Viscosity N/A Specific Gravity N/A


SMALL SPILLS: Wash to sewer with plenty of water. LARGE SPILLS: Shovel material into approved container.


RESPIRATORY PROTECTION: NIOSH approved dust mask required if airborne particles present in sufficient quantity to cause respiratory irritation. PROTECTIVE GLOVES: Neoprene or Rubber EYE PROTECTION: Goggles with shields PROTECTIVE CLOTHING OR EQUIPMENT: Chemical resistant apron, foot covering. Safety Eyebath nearby

25


STABILITY DATA: Stable HAZARDOUS POLYMERIZATION: Will not occur INCOMPATIBILITY: Avoid strong acids and oxidizers CONDITIONS TO AVOID: Avoid high humidity, damp, wet area. HAZARDOUS DECOMPOSITION PRODUCT: Thermal decomposition may yield CO; CO2; Phosphorous fumes; Chlorine fumes.


This product is based on a formulation with Sodium Tripoliphosphate. The largest ingredient used within the formulation is Sodium Tripoliphosphate. The following information is based on this ingredient.

LD50 (oral,rat): 6500 mg/kg (8) LD50 (oral,rat): 3900 mg/kg (9, unconfirmed) LD50 (oral,mouse): 3210 mg/kg (9, 10 unconfirmed) Effect of Long-Term Ingestion:

Kidney damage was observed in rats fed a diet containing 2% or 10% Sodium Tripoliphosphate for one month, but not in animals fed 0.2% (10). Kidney damage was also observed in rats fed 3% Sodium Tripoliphosphate for six months and 5% for 2 years. No detectable toxic effects were observed following ingestion of 1.8% in diet for 6 months and 0.5% for 2- years (10).

Skin contact: (rabbit, guinea pig) Negligible irritation and no visible tissue damage was observed after 50% solution was applied to intact and

abraded skin (1) Additional toxicological Information: To the best of the companys knowledge the acute and chronic toxicity of this substance is not fully known. Carcinogenicity Information:

Not considered a carcinogen by: EPA, IARC, ACGIH, NTP OR OSHA


Non Available




None Available




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AUTOMOTIVE WASH CONCENTRATE


AUTOMOTIVE WASH CONCENTRATE B PERSONAL PROTECTION

Section 1: Identification Product Name: Automotive Wash Concentrate Contact Information:



Catalog Codes: JADCWC30G (ACI Janitorial Product)

Product Usage: A concentrated detergent to remove dirt, grease and road film from automotive surfaces.


WARNING: INHALATION: May cause irritation to the respiratory tract. EYES: Will cause eye irritation. SKIN: May cause irritation and reddening. INGESTION: Will cause gastric distress.

THRESHOLD LIMIT VALUE: Not None CARCINOGEN: No information available EFFECTS OF OVEREXPOSURE: No information available


Sodium Xylene Sulfonate 1300-72-7 2.7% Calsoft L-60 Proprietary 28.62% Sodium Laurel Ether Sulphate 64-17-5 2.7% Lexaine C Proprietary 3.74%

Section 4: First-Aid Measures INHALATION: Use in adequately ventilated area. Remove to fresh air if irritation persists. EYES: Flush with water for 15 minutes, holding eyelids open. If irritation persists, contact a physician. SKIN: Remove affected clothing, Wash skin area. Launder clothing before reuse. If irritation persists, seek medical assistance. INGESTION: Induce vomiting by giving 2 to 4 glasses of water or milk. Call a physician.

0 1

0

28


FLASH POINT: No flash at boil. FLAMMABLE LIMITS: N/A EXTINGUISHING MEDIA: CO2, Water Fog, Dry Chemical, Chemical Foam. FIRE FIGHTING PROCEDURES: Keep cool with water spray to prevent container rupture due to steam build up. Floor will become slippery if material is released.


Keep containers closed when not in use. Protect containers from abuse and extreme temperatures. Store in clean, cool dry area.

OTHER PRECAUTIONS: As with all chemicals, use due care according to labeled instructions and precautions.


RESPIRATORY PROTECTION: None required if used in properly ventilated area. PROTECTIVE GLOVES: Rubber or neoprene. EYE PROTECTION: Use safety glasses with shields or goggles. PROTECTIVE CLOTHING OR EQUIPMENT: Safety Eyebath nearby.



Color Light Blue Volatility 80.1% Odor Characteristic Vapor Pressure N/A Odor Threshold N/A Vapor Density N/A Ph .95 1.2 Relative Density N/A Melting Point/Freezing Point N/A Solubility(Ies) Complete in Water


Flash Point No Flash At Boil Auto-Ignition Temperature N/A Evaporation Rate N/A Decomposition Temperature N/A Flammability (Solid, Gas) N/A Viscosity N/A Specific Gravity 6.8 - 10.5

Section 10: Stability and Reactivity STABILITY DATA: Stable HAZARDOUS POLYMERIZATION: None INCOMPATIBILITY: N/A CONDITIONS TO AVOID: Extreme temperatures. HAZARDOUS DECOMPOSITION PRODUCT: None known.


SMALL SPILLS: Dilute with plenty of water, flush to sewer. LARGE SPILLS: Dike spill. Use absorbent material such as sand or sawdust to soak up majority. Use plenty of water to flush the remainder to sewer.

29


This product is based on a formulation with over 62% water dilatant. The largest ingredient used within the formulation is Calsoft L-60. The following information is based on this ingredient.

Eyes: Eye Irritation Skin: Skin Irritation Ingestion: Unknown Inhalation Unknown Chronic Toxicity: No information available Carcinogenicity: Product is not listed Hazard Type: Skin/Eye Irritant


Ecotoxicity effects: Harmful to aquatic organisms. Marine pollutant. Chemical Fate: The ingredient (Calsoft-60) used in this product is not readily biodegradable.



Not Applicable




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BATHROOM CLEANER WITH MILDEW REMOVER

Section 1: Identification Product Name: BATHROOM CLEANER WITH MILDEW

REMOVER Contact Information:



Catalog Codes: JAMR61G (ACI Janitorial Product)

Product Usage: Removes mildew stains on grout and tubs, tub walls, shower curtains, and shower doors. Also used for cleaning trash cans.


WARNING: Inhalation: No effects indicated. Eyes: Contact with eyes may cause irritation. Skin: Not an irritant to skin Ingestion: No effects indicated.

THRESHOLD LIMIT VALUE: N/A CARCINOGEN: None EFFECTS OF OVEREXPOSURE: NO EFFECTS INDICATED


SODIUM HYPOCHLORITE SOLUTION 007681-52-9 20.99 SODIUM HYDROXIDE 1310-73-2 1.53 SODIUM METASILICATE 6834-92-0 .12 SURFACTANT PROPRIETARY 1.77


BATHROOM CLEANER WITH MILDEW REMOVER B PERSONAL PROTECTION

0 2

0

32


FLASH POINT: No Flash at Boil FLAMMABLE LIMITS: N/A EXTINGUISHING MEDIA: Water spray FIRE FIGHTING PROCEDURES: Keep cool with water spray to prevent container rupture due to steam build up. Floor will become slippery if material is released.


SMALL SPILLS: Wash to sanitary sewer with plenty of water. LARGE SPILLS: Confine spill; Soak up with approved absorbent


Keep container closed when not in use. Protect containers from abuse. Store in clean, dry cool area.

OTHER PRECAUTIONS: As with all chemicals use due care according to labeled instructions and precautions.


physical state Liquid Upper/lower flammability or explosive limits; n/a

color Clear Hazy Volatility 97.3% Odor Bleach Odor Vapor pressure n/a Odor threshold n/a Vapor density n/a pH 12.68 Relative density n/a Melting point/freezing point n/a Solubility(ies) n/a Initial boiling point and boiling range 212F Partition coefficient: n-octanol/water Complete Flash point n/a Auto-ignition temperature n/a Evaporation rate n/a Decomposition temperature n/a Flammability (solid, gas) n/a Viscosity n/a Specific Gravity 0.88 n/a

Section 4: First-Aid Measures INHALATION: Remove victim to fresh air. EYES: Flush eyes for 15 minutes in clear running water; if irritation persists, seek medical attention. SKIN: Flush with water. INGESTION: If swallowed give several glasses of water or milk but do not induce vomiting. If vomiting occurs, give fluids again.


RESPIRATORY PROTECTION: None required PROTECTIVE GLOVES: Neoprene or rubber EYE PROTECTION: Goggles with Shields PROTECTIVE CLOTHING OR EQUIPMENT: Safety Eyebath nearby.

33


STABILITY DATA: Stable HAZARDOUS POLYMERIZATION: Will Not Occur INCOMPATIBILITY: Contains bleach, do not use in conjunction with other types of cleaners. CONDITIONS TO AVOID: None HAZARDOUS DECOMPOSITION PRODUCT: None


This product is based on a formulation with over75% water. The largest ingredient used within the formulation is SODIUM HYPOCHLORITE SOLUTION .The following information is based on this ingredient.

Acute Toxicity: .

Inhalation: Irritating to respiratory system

Eye contact: Can cause eye damage

Skin contact: Cause severe skin burns

Carcinogenicity Information: Not considered a carcinogen by: IARC, ACGIH, NTP OR OSHA


INFORMATION BASE ON THE SODIUM HYPOCHLORITE SOLUTION WITHIN THE PRODUCT. Very toxic to aquatic organisms. Harmful to aquatic organisms. An environmental hazard cannot be excluded in the event of unprofessional handling or disposal.




None Available




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CITRUS DEGREASER, HOUSEHOLD & INSTITUTIONAL


CITRUS DEGREASER, HOUSEHOLD & INSTITUTIONAL B PERSONAL PROTECTION

Section 1: Identification Product Name: Citrus Degreaser, Household & Institutional Contact Information:



Catalog Codes: JACLCD-size (ACI Janitorial Product)

Product Usage:

It can be used for all household and institutional applications where an effective cleaner and degreaser is necessary. It is safe to use on any surface that is not harmed by water.


DANGER: INHALATION: Can cause nasal damage. EYES: Can cause severe damage very rapidly. SKIN: Can cause burns and possible ulcerations. INGESTION: Can cause severe damage to mucous membranes and deep tissue.

THRESHOLD LIMIT VALUE: N/A CARCINOGEN: None EFFECTS OF OVEREXPOSURE: No effects indicated


EDTA 38% / Perma Clear Proprietary .97 Sodium Metasilicate 6834-92-0 1.97 Delimonene 5989-27-5 2.43 Steposol SB-W 68919-53-9 2.43 Surfonic 9.5 / Tergitol NP-10 9016-45-9 8.74 Glycol Ether E.B. 111-76-2 2.43 Amphoterge K-2 Proprietary 1.97

1 3

0

36

Section 4: First-Aid Measures INHALATION: Remove victim to fresh air. EYES: Flush eyes for 15 minutes in clear running water. Get immediate medical attention! SKIN: Remove contaminated clothing; Flush with water for 15 minutes. Get medical attention. INGESTION: Do not induce vomiting. Dilute by giving water. Get immediate medical attention!


FLASH POINT: No Flash at boil FLAMMABLE LIMITS: N/A EXTINGUISHING MEDIA: CO2, Water Fog, Dry Chemical, Chemical Foam. FIRE FIGHTING PROCEDURES: Keep cool with water spray to prevent container rupture due to pressure build up.


SMALL SPILLS: Dissolve in large amounts of water and neutralize with hydrochloric acid. LARGE SPILLS: Flush to sanitary sewer with large amounts of water after neutralized and the majority of material has been poured into a large container for neutralization.




RESPIRATORY PROTECTION: NIOSH approved respirator capable of removing airborne particles. PROTECTIVE GLOVES: Neoprene or Rubber EYE PROTECTION: Goggles with shields PROTECTIVE CLOTHING OR EQUIPMENT: Safety Eyebath nearby.



Color Orange Volatility 80.3% Odor Citrus Vapor Pressure N/A Odor Threshold N/A Vapor Density N/A Ph 9.98 Relative Density N/A Melting Point/Freezing Point N/A Solubility(Ies) Complete In Water



Section 10: Stability and Reactivity STABILITY DATA: Stable HAZARDOUS POLYMERIZATION: Will not occur INCOMPATIBILITY: Avoid contact with strong mineral acids, organic materials & reactive metals such as aluminum and magnesium. CONDITIONS TO AVOID: Extreme temperatures HAZARDOUS DECOMPOSITION PRODUCT: May release hydrogen gas upon contact with aluminum or magnesium.

37


This product is formulated with Surfonic 9.5 / Tergitol NP-10 at 8.74%. The largest ingredient used within the formulation other than water. The following information is based on this ingredient.

Target Organs: No known significant effects or critical hazards.

Mutagenicity: No known significant effects or critical hazards.

Teratogenicity: No known significant effects or critical hazards.

Developmental Effects: No known significant effects or critical hazards.

Carcinogenicity Information: No known significant effects or critical hazards. Medical conditions aggravated by overexposure: None known


Environmental Effects Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. Water polluting

material. May be harmful to environment if released in large quantities. No known significant effects or critical hazards.



None Available




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DETERGENT/DISINFECTANT LEMON SCENT


DETERGENT/DISINFECTANT LEMON SCENT B PERSONAL PROTECTION

Section 1: Identification Product Name: DETERGENT/DISINFECTANT LEMON SCENT Contact Information:



EPA Number: 10324-57-57263 Product Class: Quaternary Ammonium Compound Catalog Codes: JADISL61G (ACI Janitorial Product)

Product Usage:

Cleaner Disinfectant Detergent Fungicide (against Pathogenic fungi) Mildewstat (on hard inanimate surfaces) For Industrial Use. Non-Acid Bathroom Cleaner Athletic Surface Disinfectant.


WARNING: potential Health Effects:

Inhalation: Mists and vapors can irritate the throat and respiratory tract High vapor concentrations may cause central nervous system effects, May be fatal if inhaled, Symptoms may include headaches, dizziness, and drowsiness,

Skin: Causes corrosive burns, Brief exposures may cause irritation and defatting of the skin. Eyes: Causes burns and may result in permanent injury to eyes including blindness.

Ingestion: Ingestion can cause gastrointestinal irritation, nausea, vomiting and diarrhea. THRESHOLD LIMIT VALUE: N/A CARCINOGEN: No Carcinogenicity data available for his product EFFECTS OF OVEREXPOSURE: Chronic: Ingestion of ethanol by pregnant women can cause reproductive toxicity to the fetus. DANGER OR WARNING:


Alkyl dimethyl benzyl ammonium chloride (C12-18)

68391-01-5 25.0-28

Alkyl dimethyl ethyl benzyl ammonium chloride (C12-14)

85409-23-0 25.0-28

Water 7732-18-5 48.0-50.0

0 3

0

40

Section 4: First-Aid Measures INHALATION: If symptoms are experienced, move victim to fresh air. If person is not breathing, call 911 or an ambulance, then give artificial respiration, preferably mouth-to-mouth if possible, Call a poison control center or doctor for further treatment advice. EYES: Immediately flush eyes with water for at least 15 minutes, while holding eyelids open. Remove contact lenses, if present, after the first 5 minutes, then continue rinsing eye, Seek medical attention at once. SKIN: Take off contaminated clothing. Rinse skin immediately with plenty of water for 15-20 minutes, Call a poison control center or doctor for treatment advice. INGESTION: Call a poison control center or doctor immediately for treatment advice, Have person sip a glass of water if able to swallow, Do not induce vomiting unless told to do so by a poison control center or doctor, Do not give anything by mouth to an unconscious person.


FLASH POINT: >200F (>93.3C) -Pensky Martin Closed Cup FLAMMABLE LIMITS: Not Determined EXTINGUISHING MEDIA: Dry chemical, foam, carbon dioxide or water fog . Solid water streams may spread burning liquid. FIRE FIGHTING PROCEDURES: Firefighters should wear full protective clothing including self-contained breathing apparatus. Cool fire exposed containers with spray.

HAZARDOUS PRODUCTS: Combustion Irritating and toxic gases or fumes may be released during a fire.

UNUSUAL FIRE EXPLOSION HAZARDS: Explosive mixtures can form with air. Combustion products are toxic. Solvent vapors can travel to an ignition source and flash back.


EMERGENCY ACTION: Isolate spill or leak area immediately. Keep unauthorized personnel away. Stay upwind. Keep out of low areas where vapors may accumulate. Eliminate all ignition sources (no smoking, flares, sparks or flames in immediate area).

SMALL SPILLS: Ventilate closed spaces before entering. All equipment used when handling the product must be grounded. Floor will be slippery. Do not touch or walk through spilled material. Stop leak if you can do it without risk. A vapor suppressing foam may be used to reduce vapors. Prevent entry into waterways, sewers, basements or confined areas. Absorb or cover with dry earth, sand or other non-combustible material and transfer to containers. Use clean non-sparking tools to collect absorbed material.

LARGE SPILLS: Dike far ahead of liquid spill for later disposal. Water spray may reduce vapor but will increase foaming. Water may not prevent ignition in closed spaces.

41


Handling Procedures: Avoid contact with skin and eyes. Use good personal hygiene practices. Wash hands before eating, drinking, smoking, or using toilet facilities. Wash thoroughly after work using soap and water.

Storage Procedures: Keep the container tightly closed and in a cool, well-ventilated place. Keep from freezing. Do not handle or store near an open flame, heat or other sources of ignition. Prevent electrostatic charge buildup by using common bonding and grounding techniques.


ENGINEERING CONTROLS: Provide adequate local exhaust ventilation (explosion proof) to maintain worker exposure below exposure limits. RESPIRATORY PROTECTION: If exposure limits are exceeded or if irritation is experienced, NIOSH approved respiratory protection should be worn. Ventilation and other forms of engineering controls are often the preferred means for controlling chemical exposures. Respiratory protection may be needed for non-routine or emergency situations. PROTECTIVE GLOVES: Use impervious gloves (rubber or neoprene). EYE PROTECTION: Wear chemical goggles. Use a face shield if splashing is possible. PROTECTIVE CLOTHING OR EQUIPMENT: Wear suitable protective clothing. Eye wash fountain and emergency showers are recommended.


physical state Liquid Upper/lower flammability or explosive limits; n/a

color Yellow Volatility 50% (weight %)

Odor benzaldehyde (organic) odor Vapor pressure n/a

Odor threshold n/a Vapor density n/a

pH 6 -8 for 10% Aqueous Solution Relative density n/a

Melting point/freezing point n/a Solubility(ies) n/a Initial boiling point and boiling range 25F Partition coefficient: n-octanol/water (Water Solubility)

Flash point

>200F (>93.3C) -Pensky Martin Closed Cup

Auto-ignition temperature n/a

Evaporation rate n/a Decomposition temperature n/a Flammability (solid, gas) n/a Viscosity n/a

Specific Gravity 0.97 (8.09Ibs/gal) n/a


STABILITY DATA: Material is stable. HAZARDOUS POLYMERIZATION: Will not occur. INCOMPATIBILITY: None Known CONDITIONS TO AVOID: Keep away from heat and strong oxidizing agents. Incompatibilities: Strong oxidizing agents (may result in fire), reducing agents. HAZARDOUS DECOMPOSITION PRODUCT: Carbon monoxide, carbon dioxide and toxic hydrogen chloride vapors.

42


Carcinogenicity: No Carcinogenicity data available for this product. Acute Oral LD50: 507 mg/kg for males and females combined. Acute Dermal: Greater than 2000 mg/kg rats. Primary Skin: Corrosive Primary Eye: Corrosive

Chemicals Ingredients Listed as Potential or Known Carcinogens: No ingredients listed in this section. OSHA, NTO, IARC


Ecotoxicity: Very Toxic to aquatic organisms Information available upon request. Please contact Mason Chemical Company Technical Service Department.

Environmental Fate: This product is biodegradable


WASTE DISPOSAL METHOD: Disposal Instructions This substance, when discarded or disposed of, is a characteristic hazardous waste according to Federal regulation (40 CFR 261) and is assigned the EPA Hazardous Waste Number of 0001. The discarding or disposal of this material must be done at a properly permitted facility in accordance with the regulations of 40 CFR 262, 263,264, and 268. Additionally, the discarding or disposal of this material may be further regulated by state, regional, or local regulations. Chemical additions, processing or otherwise altering this material may make the waste management information presented in this MSDS incomplete, inaccurate or otherwise inappropriate. The transportation, storage, treatment and disposal of this waste material must be conducted in compliance with all applicable Federal, state, and local regulations.


DOT: Hazard Class: 8 Corrosive

DOT Proper Shipping Name: Disinfectant Liquid Corrosive, NOS (Quaternary Ammonium Compound), 8, UN1903, PGII

43


TSCA Status This product is regulated as a pesticide under the Federal Insecticide, Fungicide and Rodenticide Act (FIFRA) and not subject to the TSCA Inventory rules for FIFRA uses. Other Chemical Inventories All components of this product are listed on the following inventories: European Union, China, Australia, Canada (DSL), Japan, Korea, and Philippines. CERCL/SARA SARA Title III, Sections 311/312 -This act requires reporting under the Community Right-to-Know provisions due to the

inclusion of the following components of this material in one or more of the five hazard categories listed in the 40 CFR 370: Classification of this product: Immediate, Fire

SARA Title 313 -This act requires submission of annual reports of releases of the following components of this material if the threshold reporting quantities, as listed in 40 CFR 372, are met or exceeded: Chemical Name CAS No. Maximum Concentration Comment No ingredients listed in this section Reportable Quantities/Threshold Planning Quantities: CERCLA requires notification of the National Response

I Center

(Telephone 1-800-424-8802) in the event of a release of quantities of the following hazardous materials contained in this product, if the release is equal to or greater than the Reportable Quantities (RQs). SARA 302/304 requires emergency planning, including agency notification, for possible release of the following components of this material, based upon the Threshold Planning Quantities (TPQs) and/or release of Reportable Quantities. Chemical Name Reportable Quantity RQ) Threshold Planning Quantity (TPQ) No ingredients listed in this section State & Provincial Right to Know & Selected Regulatory Lists The following ingredients appear on various state right to know lists and/or California's Proposition 65 List Chemical Name State List Benzyl Chloride (trace < 10 ppm) AZ, CA, CT, FL, 10, MA, MN, NJ, PA, RI

AZ -Arizona Ambient Air Quality Guidelines CT -Connecticut Hazardous Air Pollutants CA -California Director's List of Hazardous Substances FL -Florida Substances List ID -Idaho Non-carcinogen Toxic Air Pollutants MA -Massachusetts Right to Know List

MN -Minnesota Hazardous Substances List NJ -New Jersey Right to Know List PA -Pennsylvania Right to Know List RI -Rhode Island Hazardous Substances List

WHMIS Classification: B3, D1B, E. This product has been classified in accordance with hazard criteria of the Controlled Products Regulations and the MSDS contains all the information required by the Controlled Products Regulations.

44


Created Date: June 2005 MSDS Revised: April 2008 Conversion to SDS and updated: 03-25-14




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DETERGENT/DISINFECTANT PINE SCENT


DETERGENT/DISINFECTANT PINE SCENT B PERSONAL PROTECTION

Section 1: Identification Product Name: DETERGENT/DISINFECTANT PINE SCENT Contact Information:



EPA Number: 10324-57-57263 Product Class: Quaternary Ammonium Compound Catalog Codes: JADISP-size (ACI Janitorial Product)

Product Usage:

Cleaner Disinfectant Detergent Fungicide (against Pathogenic fungi) Mildewstat (on hard inanimate surfaces) For Industrial Use. Non-Acid Bathroom Cleaner Athletic Surface Disinfectant.


potential Health Effects:

Inhalation: Mists and vapors can irritate the throat and respiratory tract High vapor concentrations may cause central nervous system effects, May be fatal if inhaled, Symptoms may include headaches, dizziness, and drowsiness,

Skin: Causes corrosive burns, Brief exposures may cause irritation and defatting of the skin. Eyes: Causes burns and may result in permanent injury to eyes including blindness.

Ingestion: Ingestion can cause gastrointestinal irritation, nausea, vomiting and diarrhea. THRESHOLD LIMIT VALUE: N/A CARCINOGEN: No Carcinogenicity data available for his product EFFECTS OF OVEREXPOSURE: Chronic: Ingestion of ethanol by pregnant women can cause reproductive toxicity to the fetus. DANGER OR WARNING:


Alkyl dimethyl benzyl ammonium chloride (C12-18)

68391-01-5 25.0-28

Alkyl dimethyl ethyl benzyl ammonium chloride (C12-14)

85409-23-0 25.0-28

Water 7732-18-5 48.0-50.0

0 3

0

46

Section 4: First-Aid Measures INHALATION: If symptoms are experienced, move victim to fresh air. If person is not breathing, call 911 or an ambulance, then give artificial respiration, preferably mouth-to-mouth if possible, Call a poison control center or doctor for further treatment advice. EYES: Immediately flush eyes with water for at least 15 minutes, while holding eyelids open. Remove contact lenses, if present, after the first 5 minutes, then continue rinsing eye, Seek medical attention at once. SKIN: Take off contaminated clothing. Rinse skin immediately with plenty of water for 15-20 minutes, Call a poison control center or doctor for treatment advice. INGESTION: Call a poison control center or doctor immediately for treatment advice, Have person sip a glass of water if able to swallow, Do not induce vomiting unless told to do so by a poison control center or doctor, Do not give anything by mouth to an unconscious person,


FLASH POINT: >200F (>93.3C) -Pensky Martin Closed Cup FLAMMABLE LIMITS: Not Determined EXTINGUISHING MEDIA: Dry chemical, foam, carbon dioxide or water fog . Solid water streams may spread burning liquid. FIRE FIGHTING PROCEDURES: Firefighters should wear full protective clothing including self-contained breathing apparatus. Cool fire exposed containers with spray.

HAZARDOUS PRODUCTS: Combustion Irritating and toxic gases or fumes may be released during a fire.

UNUSUAL FIRE EXPLOSION HAZARDS: Explosive mixtures can form with air. Combustion products are toxic. Solvent vapors can travel to an ignition source and flash back.


EMERGENCY ACTION: Isolate spill or leak area immediately. Keep unauthorized personnel away. Stay upwind. Keep out of low areas where vapors may accumulate. Eliminate all ignition sources (no smoking, flares, sparks or flames in immediate area).

SMALL SPILLS: Ventilate closed spaces before entering. All equipment used when handling the product must be grounded. Floor will be slippery. Do not touch or walk through spilled material. Stop leak if you can do it without risk. A vapor suppressing foam may be used to reduce vapors. Prevent entry into waterways, sewers, basements or confined areas. Absorb or cover with dry earth, sand or other non-combustible material and transfer to containers. Use clean non-sparking tools to collect absorbed material.

LARGE SPILLS: Dike far ahead of liquid spill for later disposal. Water spray may reduce vapor but will increase foaming. Water may not prevent ignition in closed spaces.

47


Handling Procedures: Avoid contact with skin and eyes. Use good personal hygiene practices. Wash hands before eating, drinking, smoking, or using toilet facilities. Wash thoroughly after work using soap and water.

Storage Procedures: Keep the container tightly closed and in a cool, well-ventilated place. Keep from freezing. Do not handle or store near an open flame, heat or other sources of ignition. Prevent electrostatic charge buildup by using common bonding and grounding techniques.

Section 9: Physical and Chemical Properties physical state Liquid Upper/lower flammability or explosive limits; n/a

color Light Green Volatility 50% (weight %)

Odor benzaldehyde (organic) odor Pine scent

Vapor pressure n/a

Odor threshold n/a Vapor density n/a

pH 6 -8 for 10% Aqueous Solution Relative density n/a

Melting point/freezing point n/a Solubility(ies) n/a Initial boiling point and boiling range 25F Partition coefficient: n-octanol/water (Water Solubility)

Flash point

>200F (>93.3C) -Pensky Martin Closed Cup

Auto-ignition temperature n/a

Evaporation rate n/a Decomposition temperature n/a Flammability (solid, gas) n/a Viscosity n/a

Specific Gravity 0.97 (8.09Ibs/gal) n/a


S

co nication standard - alabama... (formerly msdss or material safety data sheets) ... 67 hand...

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