data pelatihan 1

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Method: Pelat Ins 2015 Page 1 Date: 12/21/2015 3:52:13 PM Sequence No.: 1 Autosampler Location: Sample ID: Calib Blank 1 Date Collected: 12/21/2015 12:45:46 PM Analyst: Data Type: Reprocessed on 12/21/2015 3:52:06 PM Logged In Analyst (Original) : HP Initial Sample Wt: Initial Sample Vol: Dilution: Sample Prep Vol: Replicate Data: Calib Blank 1 Net Corrected Calib. Analysis Repl# Analyte Intensity Intensity Conc. Units Time Mean Data: Calib Blank 1 Mean Corrected Calib Analyte Intensity Std.Dev. RSD Conc. Units Sequence No.: 2 Autosampler Location: Sample ID: Std 1a Date Collected: 12/21/2015 12:51:09 PM Analyst: Data Type: Reprocessed on 12/21/2015 3:52:06 PM Logged In Analyst (Original) : HP Initial Sample Wt: Initial Sample Vol: Dilution: Sample Prep Vol: Replicate Data: Std 1a Net Corrected Calib. Analysis Repl# Analyte Intensity Intensity Conc. Units Time ==================================================================================================== ---------------------------------------------------------------------------------------------------- 1 Cu 324.752 2516.7 2516.7 [0.00] mg/L 12:46:55 PM 1 Cr 283.563 1604.0 1604.0 [0.00] mg/L 12:46:55 PM 1 Fe 259.939 412.9 412.9 [0.00] mg/L 12:46:55 PM 1 K 766.490 68690.7 68690.7 [0.00] mg/L 12:46:49 PM 1 Cd 228.802 131.5 131.5 [0.00] mg/L 12:46:55 PM 1 Pb 283.306 299.5 299.5 [0.00] mg/L 12:46:55 PM 1 Ca 393.366 409940.5 409940.5 [0.00] mg/L 12:46:49 PM 1 Na 588.995 -25164.6 -25164.6 [0.00] mg/L 12:46:49 PM 1 Mg 279.553 90896.4 90896.4 [0.00] mg/L 12:46:49 PM 1 Ni 341.476 -99.1 -99.1 [0.00] mg/L 12:46:55 PM 1 Mn 257.610 325.6 325.6 [0.00] mg/L 12:46:55 PM 1 Zn 213.857 3364.2 3364.2 [0.00] mg/L 12:46:55 PM 1 Co 228.616 3.7 3.7 [0.00] mg/L 12:46:55 PM ---------------------------------------------------------------------------------------------------- Cu 324.752 2516.7 [0.00] mg/L Cr 283.563 1604.0 [0.00] mg/L Fe 259.939 412.9 [0.00] mg/L K 766.490 68690.7 [0.00] mg/L Cd 228.802 131.5 [0.00] mg/L Pb 283.306 299.5 [0.00] mg/L Ca 393.366 409940.5 [0.00] mg/L Na 588.995 -25164.6 [0.00] mg/L Mg 279.553 90896.4 [0.00] mg/L Ni 341.476 -99.1 [0.00] mg/L Mn 257.610 325.6 [0.00] mg/L Zn 213.857 3364.2 [0.00] mg/L Co 228.616 3.7 [0.00] mg/L ==================================================================================================== ---------------------------------------------------------------------------------------------------- 1 Cu 324.752 2820636.4 2818119.7 [10] mg/L 12:51:24 PM 1 Cr 283.563 1495852.2 1494248.1 [10] mg/L 12:51:24 PM 1 Fe 259.939 976.3 563.4 [0] mg/L 12:51:30 PM 1 K 766.490 165323.3 96632.6 [0] mg/L 12:51:24 PM 1 Cd 228.802 161.9 30.4 [0] mg/L 12:51:30 PM 1 Pb 283.306 -136.4 -435.9 [0] mg/L 12:51:30 PM 1 Ca 393.366 6884743.7 6474803.1 [0] mg/L 12:51:23 PM 1 Na 588.995 376896.6 402061.2 [0] mg/L 12:51:24 PM 1 Mg 279.553 543163.4 452266.9 [0] mg/L 12:51:24 PM 1 Ni 341.476 19.9 118.9 [0] mg/L 12:51:30 PM

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Method: Pelat Ins 2015 Page 1 Date: 12/21/2015 3:52:13 PM

Sequence No.: 1 Autosampler Location: Sample ID: Calib Blank 1 Date Collected: 12/21/2015 12:45:46 PMAnalyst: Data Type: Reprocessed on 12/21/2015 3:52:06 PMLogged In Analyst (Original) : HP Initial Sample Wt: Initial Sample Vol: Dilution: Sample Prep Vol:

Replicate Data: Calib Blank 1 Net Corrected Calib. Analysis

Repl# Analyte Intensity Intensity Conc. Units Time

Mean Data: Calib Blank 1Mean Corrected Calib

Analyte Intensity Std.Dev. RSD Conc. Units

Sequence No.: 2 Autosampler Location: Sample ID: Std 1a Date Collected: 12/21/2015 12:51:09 PMAnalyst: Data Type: Reprocessed on 12/21/2015 3:52:06 PMLogged In Analyst (Original) : HP Initial Sample Wt: Initial Sample Vol: Dilution: Sample Prep Vol:

Replicate Data: Std 1a Net Corrected Calib. Analysis

Repl# Analyte Intensity Intensity Conc. Units Time

====================================================================================================

----------------------------------------------------------------------------------------------------

1 Cu 324.752 2516.7 2516.7 [0.00] mg/L 12:46:55 PM 1 Cr 283.563 1604.0 1604.0 [0.00] mg/L 12:46:55 PM 1 Fe 259.939 412.9 412.9 [0.00] mg/L 12:46:55 PM 1 K 766.490 68690.7 68690.7 [0.00] mg/L 12:46:49 PM 1 Cd 228.802 131.5 131.5 [0.00] mg/L 12:46:55 PM 1 Pb 283.306 299.5 299.5 [0.00] mg/L 12:46:55 PM 1 Ca 393.366 409940.5 409940.5 [0.00] mg/L 12:46:49 PM 1 Na 588.995 -25164.6 -25164.6 [0.00] mg/L 12:46:49 PM 1 Mg 279.553 90896.4 90896.4 [0.00] mg/L 12:46:49 PM 1 Ni 341.476 -99.1 -99.1 [0.00] mg/L 12:46:55 PM 1 Mn 257.610 325.6 325.6 [0.00] mg/L 12:46:55 PM 1 Zn 213.857 3364.2 3364.2 [0.00] mg/L 12:46:55 PM 1 Co 228.616 3.7 3.7 [0.00] mg/L 12:46:55 PM

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Cu 324.752 2516.7 [0.00] mg/L Cr 283.563 1604.0 [0.00] mg/L Fe 259.939 412.9 [0.00] mg/L K 766.490 68690.7 [0.00] mg/L Cd 228.802 131.5 [0.00] mg/L Pb 283.306 299.5 [0.00] mg/L Ca 393.366 409940.5 [0.00] mg/L Na 588.995 -25164.6 [0.00] mg/L Mg 279.553 90896.4 [0.00] mg/L Ni 341.476 -99.1 [0.00] mg/L Mn 257.610 325.6 [0.00] mg/L Zn 213.857 3364.2 [0.00] mg/L Co 228.616 3.7 [0.00] mg/L

====================================================================================================

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1 Cu 324.752 2820636.4 2818119.7 [10] mg/L 12:51:24 PM 1 Cr 283.563 1495852.2 1494248.1 [10] mg/L 12:51:24 PM 1 Fe 259.939 976.3 563.4 [0] mg/L 12:51:30 PM 1 K 766.490 165323.3 96632.6 [0] mg/L 12:51:24 PM 1 Cd 228.802 161.9 30.4 [0] mg/L 12:51:30 PM 1 Pb 283.306 -136.4 -435.9 [0] mg/L 12:51:30 PM 1 Ca 393.366 6884743.7 6474803.1 [0] mg/L 12:51:23 PM 1 Na 588.995 376896.6 402061.2 [0] mg/L 12:51:24 PM 1 Mg 279.553 543163.4 452266.9 [0] mg/L 12:51:24 PM 1 Ni 341.476 19.9 118.9 [0] mg/L 12:51:30 PM

Method: Pelat Ins 2015 Page 2 Date: 12/21/2015 3:52:13 PM

Mean Data: Std 1aMean Corrected Calib

Analyte Intensity Std.Dev. RSD Conc. Units

Sequence No.: 3 Autosampler Location: Sample ID: Std 1b Date Collected: 12/21/2015 12:52:32 PMAnalyst: Data Type: Reprocessed on 12/21/2015 3:52:06 PMLogged In Analyst (Original) : HP Initial Sample Wt: Initial Sample Vol: Dilution: Sample Prep Vol:

Replicate Data: Std 1b Net Corrected Calib. Analysis

Repl# Analyte Intensity Intensity Conc. Units Time

1 Mn 257.610 4426.2 4100.6 [0] mg/L 12:51:30 PM 1 Zn 213.857 10703.8 7339.7 [0] mg/L 12:51:30 PM 2 Cu 324.752 2848397.9 2845881.2 [10] mg/L 12:51:32 PM 2 Cr 283.563 1510808.8 1509204.8 [10] mg/L 12:51:32 PM 2 Fe 259.939 1047.4 634.5 [0] mg/L 12:51:38 PM 2 K 766.490 167193.4 98502.7 [0] mg/L 12:51:32 PM 2 Cd 228.802 152.2 20.6 [0] mg/L 12:51:38 PM 2 Pb 283.306 -129.3 -428.8 [0] mg/L 12:51:38 PM 2 Ca 393.366 6751088.2 6341147.7 [0] mg/L 12:51:31 PM 2 Na 588.995 387306.5 412471.1 [0] mg/L 12:51:32 PM 2 Mg 279.553 542454.1 451557.7 [0] mg/L 12:51:32 PM 2 Ni 341.476 -48.8 50.2 [0] mg/L 12:51:38 PM 2 Mn 257.610 4260.8 3935.2 [0] mg/L 12:51:38 PM 2 Zn 213.857 10645.3 7281.2 [0] mg/L 12:51:38 PM

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Cu 324.752 2832000.4 19630.33 0.69% [10] mg/L Standard intensity and concentration values are not in the same order.Cr 283.563 1501726.5 10575.95 0.70% [10] mg/L Standard intensity and concentration values are not in the same order.Fe 259.939 599.0 50.28 8.39% [0] mg/L Standard intensity and concentration values are not in the same order.K 766.490 97567.7 1322.38 1.36% [0] mg/L Standard intensity and concentration values are not in the same order.Cd 228.802 25.5 6.89 27.03% [0] mg/L Standard intensity and concentration values are not in the same order.Pb 283.306 -432.4 5.05 1.17% [0] mg/L Standard intensity and concentration values are not in the same order.Ca 393.366 6407975.4 94508.69 1.47% [0] mg/L Standard intensity and concentration values are not in the same order.Na 588.995 407266.1 7360.92 1.81% [0] mg/L Standard intensity and concentration values are not in the same order.Mg 279.553 451912.3 501.52 0.11% [0] mg/L Standard intensity and concentration values are not in the same order.Ni 341.476 84.6 48.57 57.43% [0] mg/L Standard intensity and concentration values are not in the same order.Mn 257.610 4017.9 116.95 2.91% [0] mg/L Standard intensity and concentration values are not in the same order.Zn 213.857 7310.4 41.38 0.57% [0] mg/L Standard intensity and concentration values are not in the same order.

====================================================================================================

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1 Cu 324.752 8428234.9 8425718.2 [30] mg/L 12:52:40 PM 1 Cr 283.563 4636313.3 4634709.2 [30] mg/L 12:52:41 PM 1 Fe 259.939 2472.6 2059.7 [0] mg/L 12:52:49 PM 1 K 766.490 308255.1 239564.4 [0] mg/L 12:52:43 PM 1 Cd 228.802 125.2 -6.3 [0] mg/L 12:52:49 PM 1 Pb 283.306 -1015.5 -1315.0 [0] mg/L 12:52:49 PM 1 Ca 393.366 18986147.9 18576207.4 [0] mg/L 12:52:40 PM 1 Na 588.995 934087.4 959252.0 [0] mg/L 12:52:41 PM 1 Mg 279.553 1689741.8 1598845.4 [0] mg/L 12:52:41 PM 1 Ni 341.476 -13.1 85.9 [0] mg/L 12:52:49 PM 1 Mn 257.610 99716.7 99391.1 [0] mg/L 12:52:43 PM

Method: Pelat Ins 2015 Page 3 Date: 12/21/2015 3:52:13 PM

Mean Data: Std 1bMean Corrected Calib

Analyte Intensity Std.Dev. RSD Conc. Units

Sequence No.: 4 Autosampler Location: Sample ID: Std 1c Date Collected: 12/21/2015 12:54:00 PMAnalyst: Data Type: Reprocessed on 12/21/2015 3:52:06 PMLogged In Analyst (Original) : HP Initial Sample Wt: Initial Sample Vol: Dilution: Sample Prep Vol:

Replicate Data: Std 1c Net Corrected Calib. Analysis

Repl# Analyte Intensity Intensity Conc. Units Time

1 Zn 213.857 39632.9 36268.7 [0] mg/L 12:52:49 PM 2 Cu 324.752 8546047.3 8543530.6 [30] mg/L 12:52:51 PM 2 Cr 283.563 4614877.5 4613273.5 [30] mg/L 12:52:52 PM 2 Fe 259.939 2052.9 1640.1 [0] mg/L 12:52:59 PM 2 K 766.490 286545.3 217854.6 [0] mg/L 12:52:53 PM 2 Cd 228.802 109.8 -21.7 [0] mg/L 12:52:59 PM 2 Pb 283.306 -930.1 -1229.6 [0] mg/L 12:52:59 PM 2 Ca 393.366 19137450.9 18727510.4 [0] mg/L 12:52:51 PM 2 Na 588.995 930926.9 956091.5 [0] mg/L 12:52:52 PM 2 Mg 279.553 1681272.0 1590375.6 [0] mg/L 12:52:52 PM 2 Ni 341.476 -65.4 33.7 [0] mg/L 12:52:59 PM 2 Mn 257.610 98494.1 98168.5 [0] mg/L 12:52:53 PM 2 Zn 213.857 39712.5 36348.4 [0] mg/L 12:52:59 PM

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Cu 324.752 8484624.4 83305.96 0.98% [30] mg/L Standard intensity and concentration values are not in the same order.Cr 283.563 4623991.4 15157.35 0.33% [30] mg/L Standard intensity and concentration values are not in the same order.Fe 259.939 1849.9 296.76 16.04% [0] mg/L Standard intensity and concentration values are not in the same order.K 766.490 228709.5 15351.17 6.71% [0] mg/L Standard intensity and concentration values are not in the same order.Cd 228.802 -14.0 10.93 77.92% [0] mg/L Standard intensity and concentration values are not in the same order.Pb 283.306 -1272.3 60.41 4.75% [0] mg/L Standard intensity and concentration values are not in the same order.Ca 393.366 18651858.9 106987.41 0.57% [0] mg/L Standard intensity and concentration values are not in the same order.Na 588.995 957671.8 2234.76 0.23% [0] mg/L Standard intensity and concentration values are not in the same order.Mg 279.553 1594610.5 5989.05 0.38% [0] mg/L Standard intensity and concentration values are not in the same order.Ni 341.476 59.8 36.98 61.84% [0] mg/L Standard intensity and concentration values are not in the same order.Mn 257.610 98779.8 864.51 0.88% [0] mg/L Standard intensity and concentration values are not in the same order.Zn 213.857 36308.5 56.29 0.16% [0] mg/L Standard intensity and concentration values are not in the same order.

====================================================================================================

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1 Cu 324.752 14330150.0 14327633.3 [50] mg/L 12:54:07 PM 1 Cr 283.563 7484182.7 7482578.7 [50] mg/L 12:54:07 PM 1 Fe 259.939 4561.0 4148.1 [0] mg/L 12:54:14 PM 1 K 766.490 200395.5 131704.8 [0] mg/L 12:54:08 PM 1 Cd 228.802 165.4 33.9 [0] mg/L 12:54:14 PM 1 Pb 283.306 -1848.6 -2148.1 [0] mg/L 12:54:14 PM 1 Ca 393.366 8331728.8 7921788.2 [0] mg/L 12:54:07 PM 1 Na 588.995 527026.8 552191.4 [0] mg/L 12:54:08 PM 1 Mg 279.553 606982.0 516085.6 [0] mg/L 12:54:08 PM 1 Ni 341.476 -117.9 -18.8 [0] mg/L 12:54:14 PM 1 Mn 257.610 15931.6 15606.0 [0] mg/L 12:54:14 PM 1 Zn 213.857 29710.2 26346.0 [0] mg/L 12:54:14 PM

Method: Pelat Ins 2015 Page 4 Date: 12/21/2015 3:52:13 PM

Mean Data: Std 1cMean Corrected Calib

Analyte Intensity Std.Dev. RSD Conc. Units

Sequence No.: 5 Autosampler Location: Sample ID: Std 2a Date Collected: 12/21/2015 12:56:25 PMAnalyst: Data Type: Reprocessed on 12/21/2015 3:52:07 PMLogged In Analyst (Original) : HP Initial Sample Wt: Initial Sample Vol: Dilution: Sample Prep Vol:

Replicate Data: Std 2a Net Corrected Calib. Analysis

Repl# Analyte Intensity Intensity Conc. Units Time

2 Cu 324.752 14370731.0 14368214.3 [50] mg/L 12:54:15 PM 2 Cr 283.563 7497194.7 7495590.7 [50] mg/L 12:54:15 PM 2 Fe 259.939 4627.2 4214.3 [0] mg/L 12:54:22 PM 2 K 766.490 203130.8 134440.1 [0] mg/L 12:54:16 PM 2 Cd 228.802 146.0 14.5 [0] mg/L 12:54:22 PM 2 Pb 283.306 -1840.3 -2139.8 [0] mg/L 12:54:22 PM 2 Ca 393.366 8453751.6 8043811.1 [0] mg/L 12:54:15 PM 2 Na 588.995 553908.4 579073.0 [0] mg/L 12:54:16 PM 2 Mg 279.553 608703.3 517806.9 [0] mg/L 12:54:16 PM 2 Ni 341.476 -12.3 86.8 [0] mg/L 12:54:22 PM 2 Mn 257.610 15948.9 15623.3 [0] mg/L 12:54:22 PM 2 Zn 213.857 29785.9 26421.7 [0] mg/L 12:54:22 PM

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Cu 324.752 14347923.8 28695.09 0.20% [50] mg/L Standard intensity and concentration values are not in the same order.Cr 283.563 7489084.7 9200.90 0.12% [50] mg/L Standard intensity and concentration values are not in the same order.Fe 259.939 4181.2 46.78 1.12% [0] mg/L Standard intensity and concentration values are not in the same order.K 766.490 133072.4 1934.15 1.45% [0] mg/L Standard intensity and concentration values are not in the same order.Cd 228.802 24.2 13.70 56.66% [0] mg/L Standard intensity and concentration values are not in the same order.Pb 283.306 -2144.0 5.88 0.27% [0] mg/L Standard intensity and concentration values are not in the same order.Ca 393.366 7982799.7 86283.18 1.08% [0] mg/L Standard intensity and concentration values are not in the same order.Na 588.995 565632.2 19008.15 3.36% [0] mg/L Standard intensity and concentration values are not in the same order.Mg 279.553 516946.2 1217.17 0.24% [0] mg/L Standard intensity and concentration values are not in the same order.Ni 341.476 34.0 74.67 219.90% [0] mg/L Standard intensity and concentration values are not in the same order.Mn 257.610 15614.6 12.24 0.08% [0] mg/L Standard intensity and concentration values are not in the same order.Zn 213.857 26383.9 53.51 0.20% [0] mg/L Standard intensity and concentration values are not in the same order.

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1 Cu 324.752 44426.4 41909.7 [0] mg/L 12:56:40 PM 1 Cr 283.563 3122271.7 3120667.7 [20] mg/L 12:56:40 PM 1 Fe 259.939 3621416.4 3621003.6 [20] mg/L 12:56:40 PM 1 K 766.490 111479.5 42788.8 [0] mg/L 12:56:40 PM 1 Cd 228.802 137.6 6.0 [0] mg/L 12:56:46 PM 1 Pb 283.306 -389.6 -689.1 [0] mg/L 12:56:46 PM 1 Ca 393.366 9955146.9 9545206.3 [0] mg/L 12:56:39 PM 1 Na 588.995 465163.4 490328.0 [0] mg/L 12:56:40 PM 1 Mg 279.553 694735.6 603839.2 [0] mg/L 12:56:40 PM 1 Ni 341.476 -15.5 83.5 [0] mg/L 12:56:46 PM 1 Mn 257.610 56146.9 55821.2 [0] mg/L 12:56:40 PM 1 Zn 213.857 9961.3 6597.2 [0] mg/L 12:56:46 PM 2 Cu 324.752 27096.2 24579.4 [0] mg/L 12:56:49 PM

Method: Pelat Ins 2015 Page 5 Date: 12/21/2015 3:52:13 PM

Mean Data: Std 2aMean Corrected Calib

Analyte Intensity Std.Dev. RSD Conc. Units

Sequence No.: 6 Autosampler Location: Sample ID: Std 2b Date Collected: 12/21/2015 12:57:45 PMAnalyst: Data Type: Reprocessed on 12/21/2015 3:52:07 PMLogged In Analyst (Original) : HP Initial Sample Wt: Initial Sample Vol: Dilution: Sample Prep Vol:

Replicate Data: Std 2b Net Corrected Calib. Analysis

Repl# Analyte Intensity Intensity Conc. Units Time

2 Cr 283.563 3106863.3 3105259.2 [20] mg/L 12:56:49 PM 2 Fe 259.939 3766926.4 3766513.6 [20] mg/L 12:56:49 PM 2 K 766.490 114844.8 46154.1 [0] mg/L 12:56:49 PM 2 Cd 228.802 192.8 61.2 [0] mg/L 12:56:55 PM 2 Pb 283.306 -402.7 -702.2 [0] mg/L 12:56:55 PM 2 Ca 393.366 9893078.0 9483137.4 [0] mg/L 12:56:48 PM 2 Na 588.995 441078.8 466243.4 [0] mg/L 12:56:49 PM 2 Mg 279.553 686970.2 596073.8 [0] mg/L 12:56:49 PM 2 Ni 341.476 18.9 117.9 [0] mg/L 12:56:55 PM 2 Mn 257.610 55686.3 55360.7 [0] mg/L 12:56:49 PM 2 Zn 213.857 9977.4 6613.2 [0] mg/L 12:56:55 PM

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Cu 324.752 33244.6 12254.34 36.86% [0] mg/L Standard intensity and concentration values are not in the same order.Cr 283.563 3112963.4 10895.40 0.35% [20] mg/L Standard intensity and concentration values are not in the same order.Fe 259.939 3693758.6 102891.11 2.79% [20] mg/L Standard intensity and concentration values are not in the same order.K 766.490 44471.5 2379.60 5.35% [0] mg/L Standard intensity and concentration values are not in the same order.Cd 228.802 33.6 39.03 116.00% [0] mg/L Standard intensity and concentration values are not in the same order.Pb 283.306 -695.6 9.25 1.33% [0] mg/L Standard intensity and concentration values are not in the same order.Ca 393.366 9514171.9 43889.35 0.46% [0] mg/L Standard intensity and concentration values are not in the same order.Na 588.995 478285.7 17030.41 3.56% [0] mg/L Standard intensity and concentration values are not in the same order.Mg 279.553 599956.5 5490.96 0.92% [0] mg/L Standard intensity and concentration values are not in the same order.Ni 341.476 100.7 24.35 24.18% [0] mg/L Standard intensity and concentration values are not in the same order.Mn 257.610 55590.9 325.66 0.59% [0] mg/L Standard intensity and concentration values are not in the same order.Zn 213.857 6605.2 11.32 0.17% [0] mg/L Standard intensity and concentration values are not in the same order.

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1 Cu 324.752 16382.1 13865.4 [0] mg/L 12:58:02 PM 1 Cr 283.563 5999016.3 5997412.3 [40] mg/L 12:57:55 PM 1 Fe 259.939 7618860.3 7618447.4 [40] mg/L 12:57:55 PM 1 K 766.490 126754.8 58064.1 [0] mg/L 12:57:56 PM 1 Cd 228.802 213.0 81.5 [0] mg/L 12:58:02 PM 1 Pb 283.306 -1113.9 -1413.4 [0] mg/L 12:58:02 PM 1 Ca 393.366 11243435.1 10833494.6 [0] mg/L 12:57:54 PM 1 Na 588.995 506692.1 531856.7 [0] mg/L 12:57:55 PM 1 Mg 279.553 900065.1 809168.6 [0] mg/L 12:57:55 PM 1 Ni 341.476 -69.4 29.7 [0] mg/L 12:58:02 PM 1 Mn 257.610 1941.6 1616.0 [0] mg/L 12:57:56 PM 1 Zn 213.857 13591.6 10227.4 [0] mg/L 12:58:02 PM 2 Cu 324.752 9967.2 7450.5 [0] mg/L 12:58:12 PM 2 Cr 283.563 6046425.7 6044821.6 [40] mg/L 12:58:05 PM

Method: Pelat Ins 2015 Page 6 Date: 12/21/2015 3:52:13 PM

Mean Data: Std 2bMean Corrected Calib

Analyte Intensity Std.Dev. RSD Conc. Units

Sequence No.: 7 Autosampler Location: Sample ID: Std 2c Date Collected: 12/21/2015 12:58:57 PMAnalyst: Data Type: Reprocessed on 12/21/2015 3:52:07 PMLogged In Analyst (Original) : HP Initial Sample Wt: Initial Sample Vol: Dilution: Sample Prep Vol:

Replicate Data: Std 2c Net Corrected Calib. Analysis

Repl# Analyte Intensity Intensity Conc. Units Time

2 Fe 259.939 7881738.1 7881325.2 [40] mg/L 12:58:05 PM 2 K 766.490 151207.3 82516.6 [0] mg/L 12:58:06 PM 2 Cd 228.802 180.8 49.2 [0] mg/L 12:58:12 PM 2 Pb 283.306 -1136.9 -1436.4 [0] mg/L 12:58:12 PM 2 Ca 393.366 11181073.7 10771133.2 [0] mg/L 12:58:04 PM 2 Na 588.995 500367.2 525531.8 [0] mg/L 12:58:05 PM 2 Mg 279.553 903829.9 812933.5 [0] mg/L 12:58:05 PM 2 Ni 341.476 -95.8 3.3 [0] mg/L 12:58:12 PM 2 Mn 257.610 1885.4 1559.7 [0] mg/L 12:58:06 PM 2 Zn 213.857 12749.0 9384.8 [0] mg/L 12:58:12 PM

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Cu 324.752 10658.0 4536.00 42.56% [0] mg/L Standard intensity and concentration values are not in the same order.Cr 283.563 6021117.0 33523.50 0.56% [40] mg/L Standard intensity and concentration values are not in the same order.Fe 259.939 7749886.3 185882.64 2.40% [40] mg/L Standard intensity and concentration values are not in the same order.K 766.490 70290.3 17290.52 24.60% [0] mg/L Standard intensity and concentration values are not in the same order.Cd 228.802 65.4 22.82 34.90% [0] mg/L Standard intensity and concentration values are not in the same order.Pb 283.306 -1424.9 16.26 1.14% [0] mg/L Standard intensity and concentration values are not in the same order.Ca 393.366 10802313.9 44096.16 0.41% [0] mg/L Standard intensity and concentration values are not in the same order.Na 588.995 528694.2 4472.38 0.85% [0] mg/L Standard intensity and concentration values are not in the same order.Mg 279.553 811051.1 2662.14 0.33% [0] mg/L Standard intensity and concentration values are not in the same order.Ni 341.476 16.5 18.70 113.42% [0] mg/L Standard intensity and concentration values are not in the same order.Mn 257.610 1587.8 39.77 2.50% [0] mg/L Standard intensity and concentration values are not in the same order.Zn 213.857 9806.1 595.81 6.08% [0] mg/L Standard intensity and concentration values are not in the same order.

====================================================================================================

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1 Cu 324.752 9182.0 6665.3 [0] mg/L 12:59:13 PM 1 Cr 283.563 8633016.1 8631412.1 [60] mg/L 12:59:06 PM 1 Fe 259.939 11096727.7 11096314.8 [60] mg/L 12:59:06 PM 1 K 766.490 150456.1 81765.4 [0] mg/L 12:59:07 PM 1 Cd 228.802 218.1 86.6 [0] mg/L 12:59:13 PM 1 Pb 283.306 -1867.1 -2166.6 [0] mg/L 12:59:13 PM 1 Ca 393.366 47047075.1 46637134.6 [0] mg/L 12:59:06 PM 1 Na 588.995 525017.0 550181.6 [0] mg/L 12:59:07 PM 1 Mg 279.553 984215.3 893318.9 [0] mg/L 12:59:07 PM 1 Ni 341.476 -66.3 32.7 [0] mg/L 12:59:13 PM 1 Mn 257.610 2161.7 1836.1 [0] mg/L 12:59:07 PM 1 Zn 213.857 18075.3 14711.1 [0] mg/L 12:59:13 PM 2 Cu 324.752 8160.1 5643.4 [0] mg/L 12:59:24 PM 2 Cr 283.563 8687973.5 8686369.5 [60] mg/L 12:59:16 PM 2 Fe 259.939 11333690.3 11333277.4 [60] mg/L 12:59:16 PM

Method: Pelat Ins 2015 Page 7 Date: 12/21/2015 3:52:13 PM

Mean Data: Std 2cMean Corrected Calib

Analyte Intensity Std.Dev. RSD Conc. Units

Sequence No.: 8 Autosampler Location: Sample ID: Std 3a Date Collected: 12/21/2015 1:01:13 PMAnalyst: Data Type: Reprocessed on 12/21/2015 3:52:07 PMLogged In Analyst (Original) : HP Initial Sample Wt: Initial Sample Vol: Dilution: Sample Prep Vol:

Replicate Data: Std 3a Net Corrected Calib. Analysis

Repl# Analyte Intensity Intensity Conc. Units Time

2 K 766.490 156778.2 88087.5 [0] mg/L 12:59:18 PM 2 Cd 228.802 232.5 100.9 [0] mg/L 12:59:24 PM 2 Pb 283.306 -1704.8 -2004.3 [0] mg/L 12:59:24 PM 2 Ca 393.366 47352163.3 46942222.8 [0] mg/L 12:59:16 PM 2 Na 588.995 563459.1 588623.7 [0] mg/L 12:59:18 PM 2 Mg 279.553 994455.4 903559.0 [0] mg/L 12:59:18 PM 2 Ni 341.476 -107.6 -8.6 [0] mg/L 12:59:24 PM 2 Mn 257.610 2254.9 1929.3 [0] mg/L 12:59:18 PM 2 Zn 213.857 18172.2 14808.0 [0] mg/L 12:59:24 PM

----------------------------------------------------------------------------------------------------

Cu 324.752 6154.3 722.59 11.74% [0] mg/L Standard intensity and concentration values are not in the same order.Cr 283.563 8658890.8 38860.71 0.45% [60] mg/L Standard intensity and concentration values are not in the same order.Fe 259.939 11214796.1 167557.86 1.49% [60] mg/L Standard intensity and concentration values are not in the same order.K 766.490 84926.5 4470.37 5.26% [0] mg/L Standard intensity and concentration values are not in the same order.Cd 228.802 93.8 10.13 10.81% [0] mg/L Standard intensity and concentration values are not in the same order.Pb 283.306 -2085.5 114.77 5.50% [0] mg/L Standard intensity and concentration values are not in the same order.Ca 393.366 46789678.7 215729.93 0.46% [0] mg/L Standard intensity and concentration values are not in the same order.Na 588.995 569402.7 27182.68 4.77% [0] mg/L Standard intensity and concentration values are not in the same order.Mg 279.553 898438.9 7240.84 0.81% [0] mg/L Standard intensity and concentration values are not in the same order.Ni 341.476 12.1 29.19 241.46% [0] mg/L Standard intensity and concentration values are not in the same order.Mn 257.610 1882.7 65.89 3.50% [0] mg/L Standard intensity and concentration values are not in the same order.Zn 213.857 14759.6 68.51 0.46% [0] mg/L Standard intensity and concentration values are not in the same order.

====================================================================================================

----------------------------------------------------------------------------------------------------

1 Cu 324.752 6091.6 3574.8 [0] mg/L 1:01:28 PM 1 Cr 283.563 5616.1 4012.0 [0] mg/L 1:01:28 PM 1 Fe 259.939 880983.2 880570.3 [10] mg/L 1:01:22 PM 1 K 766.490 3120526.2 3051835.5 [10] mg/L 1:01:22 PM 1 Cd 228.802 143.6 12.1 [0] mg/L 1:01:28 PM 1 Pb 283.306 374.4 74.9 [0] mg/L 1:01:28 PM 1 Ca 393.366 34399921.7 33989981.2 [0] mg/L 1:01:21 PM 1 Na 588.995 1707861.7 1733026.3 [0] mg/L 1:01:22 PM 1 Mg 279.553 1456754.7 1365858.2 [0] mg/L 1:01:22 PM 1 Ni 341.476 142.5 241.5 [0] mg/L 1:01:28 PM 1 Mn 257.610 4405.3 4079.7 [0] mg/L 1:01:28 PM 1 Zn 213.857 10119.9 6755.7 [0] mg/L 1:01:28 PM 2 Cu 324.752 5662.6 3145.9 [0] mg/L 1:01:38 PM 2 Cr 283.563 4808.7 3204.7 [0] mg/L 1:01:38 PM 2 Fe 259.939 878915.3 878502.4 [10] mg/L 1:01:32 PM 2 K 766.490 3199870.6 3131179.9 [10] mg/L 1:01:32 PM

Method: Pelat Ins 2015 Page 8 Date: 12/21/2015 3:52:13 PM

Mean Data: Std 3aMean Corrected Calib

Analyte Intensity Std.Dev. RSD Conc. Units

Sequence No.: 9 Autosampler Location: Sample ID: Std 3b Date Collected: 12/21/2015 1:02:34 PMAnalyst: Data Type: Reprocessed on 12/21/2015 3:52:07 PMLogged In Analyst (Original) : HP Initial Sample Wt: Initial Sample Vol: Dilution: Sample Prep Vol:

Replicate Data: Std 3b Net Corrected Calib. Analysis

Repl# Analyte Intensity Intensity Conc. Units Time

2 Cd 228.802 161.8 30.3 [0] mg/L 1:01:38 PM 2 Pb 283.306 395.6 96.1 [0] mg/L 1:01:38 PM 2 Ca 393.366 34059730.2 33649789.6 [0] mg/L 1:01:30 PM 2 Na 588.995 1714024.4 1739189.0 [0] mg/L 1:01:32 PM 2 Mg 279.553 1450021.6 1359125.2 [0] mg/L 1:01:32 PM 2 Ni 341.476 78.7 177.7 [0] mg/L 1:01:38 PM 2 Mn 257.610 4381.5 4055.8 [0] mg/L 1:01:38 PM 2 Zn 213.857 10407.7 7043.6 [0] mg/L 1:01:38 PM

----------------------------------------------------------------------------------------------------

Cu 324.752 3360.4 303.30 9.03% [0] mg/L Standard intensity and concentration values are not in the same order.Cr 283.563 3608.4 570.86 15.82% [0] mg/L Standard intensity and concentration values are not in the same order.Fe 259.939 879536.4 1462.18 0.17% [10] mg/L Standard intensity and concentration values are not in the same order.K 766.490 3091507.7 56104.97 1.81% [10] mg/L Standard intensity and concentration values are not in the same order.Cd 228.802 21.2 12.84 60.61% [0] mg/L Standard intensity and concentration values are not in the same order.Pb 283.306 85.5 14.95 17.49% [0] mg/L Standard intensity and concentration values are not in the same order.Ca 393.366 33819885.4 240551.76 0.71% [0] mg/L Standard intensity and concentration values are not in the same order.Na 588.995 1736107.6 4357.67 0.25% [0] mg/L Standard intensity and concentration values are not in the same order.Mg 279.553 1362491.7 4761.00 0.35% [0] mg/L Standard intensity and concentration values are not in the same order.Ni 341.476 209.6 45.14 21.53% [0] mg/L Standard intensity and concentration values are not in the same order.Mn 257.610 4067.8 16.89 0.42% [0] mg/L Standard intensity and concentration values are not in the same order.Zn 213.857 6899.6 203.56 2.95% [0] mg/L Standard intensity and concentration values are not in the same order.

====================================================================================================

----------------------------------------------------------------------------------------------------

1 Cu 324.752 6436.2 3919.4 [0] mg/L 1:02:49 PM 1 Cr 283.563 9299.3 7695.2 [0] mg/L 1:02:49 PM 1 Fe 259.939 4156489.4 4156076.5 [30] mg/L 1:02:42 PM 1 K 766.490 8755667.0 8686976.3 [30] mg/L 1:02:41 PM 1 Cd 228.802 190.0 58.5 [0] mg/L 1:02:49 PM 1 Pb 283.306 529.5 230.0 [0] mg/L 1:02:49 PM 1 Ca 393.366 Saturated3 Saturated3 1:02:49 PM Saturated in preshot (code 3) 1 Na 588.995 2316670.7 2341835.3 [0] mg/L 1:02:42 PM 1 Mg 279.553 2210594.1 2119697.7 [0] mg/L 1:02:42 PM 1 Ni 341.476 26.3 125.3 [0] mg/L 1:02:49 PM 1 Mn 257.610 11105.8 10780.1 [0] mg/L 1:02:43 PM 1 Zn 213.857 10801.1 7437.0 [0] mg/L 1:02:49 PM 2 Cu 324.752 5845.3 3328.5 [0] mg/L 1:02:59 PM 2 Cr 283.563 8931.9 7327.8 [0] mg/L 1:02:59 PM 2 Fe 259.939 4260381.2 4259968.4 [30] mg/L 1:02:52 PM 2 K 766.490 9268187.1 9199496.4 [30] mg/L 1:02:51 PM

Method: Pelat Ins 2015 Page 9 Date: 12/21/2015 3:52:13 PM

Mean Data: Std 3bMean Corrected Calib

Analyte Intensity Std.Dev. RSD Conc. Units

Sequence No.: 10 Autosampler Location: Sample ID: Std 3c Date Collected: 12/21/2015 1:03:48 PMAnalyst: Data Type: Reprocessed on 12/21/2015 3:52:07 PMLogged In Analyst (Original) : HP Initial Sample Wt: Initial Sample Vol: Dilution: Sample Prep Vol:

Replicate Data: Std 3c Net Corrected Calib. Analysis

Repl# Analyte Intensity Intensity Conc. Units Time

2 Cd 228.802 180.6 49.0 [0] mg/L 1:02:59 PM 2 Pb 283.306 580.4 280.9 [0] mg/L 1:02:59 PM 2 Ca 393.366 Saturated3 Saturated3 1:02:59 PM Saturated in preshot (code 3) 2 Na 588.995 2348847.1 2374011.7 [0] mg/L 1:02:52 PM 2 Mg 279.553 2199611.4 2108715.0 [0] mg/L 1:02:52 PM 2 Ni 341.476 -38.1 61.0 [0] mg/L 1:02:59 PM 2 Mn 257.610 11257.8 10932.1 [0] mg/L 1:02:53 PM 2 Zn 213.857 11027.7 7663.5 [0] mg/L 1:02:59 PM

----------------------------------------------------------------------------------------------------

Cu 324.752 3624.0 417.82 11.53% [0] mg/L Standard intensity and concentration values are not in the same order.Cr 283.563 7511.5 259.81 3.46% [0] mg/L Standard intensity and concentration values are not in the same order.Fe 259.939 4208022.4 73462.62 1.75% [30] mg/L Standard intensity and concentration values are not in the same order.K 766.490 8943236.3 362406.41 4.05% [30] mg/L Standard intensity and concentration values are not in the same order.Cd 228.802 53.8 6.67 12.41% [0] mg/L Standard intensity and concentration values are not in the same order.Pb 283.306 255.5 36.00 14.09% [0] mg/L Standard intensity and concentration values are not in the same order.Ca 393.366 Saturated3 Na 588.995 2357923.5 22752.15 0.96% [0] mg/L Standard intensity and concentration values are not in the same order.Mg 279.553 2114206.3 7765.95 0.37% [0] mg/L Standard intensity and concentration values are not in the same order.Ni 341.476 93.2 45.50 48.85% [0] mg/L Standard intensity and concentration values are not in the same order.Mn 257.610 10856.1 107.50 0.99% [0] mg/L Standard intensity and concentration values are not in the same order.Zn 213.857 7550.2 160.20 2.12% [0] mg/L Standard intensity and concentration values are not in the same order.

====================================================================================================

----------------------------------------------------------------------------------------------------

1 Cu 324.752 15965.8 13449.1 [0] mg/L 1:04:12 PM 1 Cr 283.563 15219.8 13615.7 [0] mg/L 1:04:12 PM 1 Fe 259.939 8550560.6 8550147.7 [50] mg/L 1:04:04 PM 1 K 766.490 15922366.6 15853675.9 [50] mg/L 1:04:04 PM 1 Cd 228.802 221.2 89.7 [0] mg/L 1:04:12 PM 1 Pb 283.306 733.1 433.6 [0] mg/L 1:04:12 PM 1 Ca 393.366 50107412.1 49697471.6 [0] mg/L 1:04:04 PM 1 Na 588.995 1963380.8 1988545.5 [0] mg/L 1:04:05 PM 1 Mg 279.553 2022366.3 1931469.8 [0] mg/L 1:04:05 PM 1 Ni 341.476 -3.1 96.0 [0] mg/L 1:04:12 PM 1 Mn 257.610 13291.9 12966.2 [0] mg/L 1:04:06 PM 1 Zn 213.857 12342.2 8978.0 [0] mg/L 1:04:12 PM 2 Cu 324.752 15755.0 13238.3 [0] mg/L 1:04:23 PM 2 Cr 283.563 15143.2 13539.1 [0] mg/L 1:04:23 PM 2 Fe 259.939 8616498.2 8616085.3 [50] mg/L 1:04:15 PM 2 K 766.490 16118182.3 16049491.6 [50] mg/L 1:04:15 PM 2 Cd 228.802 184.2 52.6 [0] mg/L 1:04:23 PM

Method: Pelat Ins 2015 Page 10 Date: 12/21/2015 3:52:13 PM

Mean Data: Std 3cMean Corrected Calib

Analyte Intensity Std.Dev. RSD Conc. Units

Sequence No.: 11 Autosampler Location: Sample ID: Std 4a Date Collected: 12/21/2015 1:05:55 PMAnalyst: Data Type: Reprocessed on 12/21/2015 3:52:07 PMLogged In Analyst (Original) : HP Initial Sample Wt: Initial Sample Vol: Dilution: Sample Prep Vol:

Replicate Data: Std 4a Net Corrected Calib. Analysis

Repl# Analyte Intensity Intensity Conc. Units Time

2 Pb 283.306 750.2 450.7 [0] mg/L 1:04:23 PM 2 Ca 393.366 50041207.0 49631266.5 [0] mg/L 1:04:15 PM 2 Na 588.995 2096411.0 2121575.6 [0] mg/L 1:04:16 PM 2 Mg 279.553 2043309.9 1952413.5 [0] mg/L 1:04:16 PM 2 Ni 341.476 -16.7 82.3 [0] mg/L 1:04:23 PM 2 Mn 257.610 13347.3 13021.7 [0] mg/L 1:04:17 PM 2 Zn 213.857 12248.7 8884.6 [0] mg/L 1:04:23 PM

----------------------------------------------------------------------------------------------------

Cu 324.752 13343.7 149.09 1.12% [0] mg/L Standard intensity and concentration values are not in the same order.Cr 283.563 13577.4 54.16 0.40% [0] mg/L Standard intensity and concentration values are not in the same order.Fe 259.939 8583116.5 46624.91 0.54% [50] mg/L Standard intensity and concentration values are not in the same order.K 766.490 15951583.8 138462.58 0.87% [50] mg/L Standard intensity and concentration values are not in the same order.Cd 228.802 71.1 26.19 36.82% [0] mg/L Standard intensity and concentration values are not in the same order.Pb 283.306 442.2 12.07 2.73% [0] mg/L Standard intensity and concentration values are not in the same order.Ca 393.366 49664369.0 46814.09 0.09% [0] mg/L Standard intensity and concentration values are not in the same order.Na 588.995 2055060.5 94066.51 4.58% [0] mg/L Standard intensity and concentration values are not in the same order.Mg 279.553 1941941.6 14809.39 0.76% [0] mg/L Standard intensity and concentration values are not in the same order.Ni 341.476 89.2 9.65 10.82% [0] mg/L Standard intensity and concentration values are not in the same order.Mn 257.610 12994.0 39.21 0.30% [0] mg/L Standard intensity and concentration values are not in the same order.Zn 213.857 8931.3 66.06 0.74% [0] mg/L Standard intensity and concentration values are not in the same order.

====================================================================================================

----------------------------------------------------------------------------------------------------

1 Cu 324.752 3889.8 1373.1 [0] mg/L 1:06:16 PM 1 Cr 283.563 1686.5 82.5 [0] mg/L 1:06:16 PM 1 Fe 259.939 3608.5 3195.6 [0] mg/L 1:06:16 PM 1 K 766.490 5475314.1 5406623.4 [20] mg/L 1:06:09 PM 1 Cd 228.802 129.8 -1.7 [20] mg/L 1:06:16 PM 1 Pb 283.306 24176.3 23876.7 [0] mg/L 1:06:16 PM 1 Ca 393.366 21917325.9 21507385.3 [0] mg/L 1:06:09 PM 1 Na 588.995 1054041.9 1079206.5 [0] mg/L 1:06:10 PM 1 Mg 279.553 1102504.9 1011608.5 [0] mg/L 1:06:10 PM 1 Ni 341.476 38.5 137.6 [0] mg/L 1:06:16 PM 1 Mn 257.610 2542.5 2216.9 [0] mg/L 1:06:16 PM 1 Zn 213.857 13583.3 10219.2 [0] mg/L 1:06:16 PM 2 Cu 324.752 3759.1 1242.4 [0] mg/L 1:06:25 PM 2 Cr 283.563 1616.4 12.3 [0] mg/L 1:06:25 PM 2 Fe 259.939 3164.9 2752.0 [0] mg/L 1:06:25 PM 2 K 766.490 5354874.9 5286184.2 [20] mg/L 1:06:18 PM 2 Cd 228.802 144.7 13.2 [20] mg/L 1:06:25 PM 2 Pb 283.306 25054.0 24754.5 [0] mg/L 1:06:25 PM

Method: Pelat Ins 2015 Page 11 Date: 12/21/2015 3:52:13 PM

Mean Data: Std 4aMean Corrected Calib

Analyte Intensity Std.Dev. RSD Conc. Units

Sequence No.: 12 Autosampler Location: Sample ID: Std 4b Date Collected: 12/21/2015 1:07:44 PMAnalyst: Data Type: Reprocessed on 12/21/2015 3:52:08 PMLogged In Analyst (Original) : HP Initial Sample Wt: Initial Sample Vol: Dilution: Sample Prep Vol:

Replicate Data: Std 4b Net Corrected Calib. Analysis

Repl# Analyte Intensity Intensity Conc. Units Time

2 Ca 393.366 21503001.8 21093061.3 [0] mg/L 1:06:18 PM 2 Na 588.995 1081204.7 1106369.3 [0] mg/L 1:06:19 PM 2 Mg 279.553 1080155.3 989258.9 [0] mg/L 1:06:19 PM 2 Ni 341.476 -70.6 28.5 [0] mg/L 1:06:25 PM 2 Mn 257.610 2514.7 2189.0 [0] mg/L 1:06:25 PM 2 Zn 213.857 13558.4 10194.2 [0] mg/L 1:06:25 PM

----------------------------------------------------------------------------------------------------

Cu 324.752 1307.8 92.40 7.07% [0] mg/L Standard intensity and concentration values are not in the same order.Cr 283.563 47.4 49.60 104.64% [0] mg/L Standard intensity and concentration values are not in the same order.Fe 259.939 2973.8 313.64 10.55% [0] mg/L Standard intensity and concentration values are not in the same order.K 766.490 5346403.8 85163.34 1.59% [20] mg/L Standard intensity and concentration values are not in the same order.Cd 228.802 5.7 10.53 184.70% [20] mg/L Standard intensity and concentration values are not in the same order.Pb 283.306 24315.6 620.69 2.55% [0] mg/L Standard intensity and concentration values are not in the same order.Ca 393.366 21300223.3 292971.36 1.38% [0] mg/L Standard intensity and concentration values are not in the same order.Na 588.995 1092787.9 19206.97 1.76% [0] mg/L Standard intensity and concentration values are not in the same order.Mg 279.553 1000433.7 15803.53 1.58% [0] mg/L Standard intensity and concentration values are not in the same order.Ni 341.476 83.0 77.13 92.92% [0] mg/L Standard intensity and concentration values are not in the same order.Mn 257.610 2203.0 19.70 0.89% [0] mg/L Standard intensity and concentration values are not in the same order.Zn 213.857 10206.7 17.62 0.17% [0] mg/L Standard intensity and concentration values are not in the same order.

====================================================================================================

----------------------------------------------------------------------------------------------------

1 Cu 324.752 4054.9 1538.1 [0] mg/L 1:08:01 PM 1 Cr 283.563 1705.3 101.2 [0] mg/L 1:08:01 PM 1 Fe 259.939 2676.7 2263.9 [0] mg/L 1:08:01 PM 1 K 766.490 10532573.1 10463882.4 [40] mg/L 1:07:53 PM 1 Cd 228.802 118.2 -13.3 [40] mg/L 1:08:01 PM 1 Pb 283.306 89712.1 89412.6 [0] mg/L 1:07:55 PM 1 Ca 393.366 28531681.5 28121741.0 [0] mg/L 1:07:53 PM 1 Na 588.995 1196755.3 1221919.9 [0] mg/L 1:07:54 PM 1 Mg 279.553 1402048.5 1311152.0 [0] mg/L 1:07:54 PM 1 Ni 341.476 -48.1 50.9 [0] mg/L 1:08:01 PM 1 Mn 257.610 3616.1 3290.5 [0] mg/L 1:08:01 PM 1 Zn 213.857 7329.4 3965.2 [0] mg/L 1:08:01 PM 2 Cu 324.752 3793.9 1277.1 [0] mg/L 1:08:12 PM 2 Cr 283.563 1623.8 19.7 [0] mg/L 1:08:12 PM 2 Fe 259.939 2965.7 2552.8 [0] mg/L 1:08:12 PM 2 K 766.490 10802826.6 10734135.9 [40] mg/L 1:08:03 PM 2 Cd 228.802 155.6 24.1 [40] mg/L 1:08:12 PM 2 Pb 283.306 92270.6 91971.0 [0] mg/L 1:08:06 PM 2 Ca 393.366 28516312.4 28106371.9 [0] mg/L 1:08:03 PM

Method: Pelat Ins 2015 Page 12 Date: 12/21/2015 3:52:13 PM

Mean Data: Std 4bMean Corrected Calib

Analyte Intensity Std.Dev. RSD Conc. Units

Sequence No.: 13 Autosampler Location: Sample ID: Std 4c Date Collected: 12/21/2015 1:09:31 PMAnalyst: Data Type: Reprocessed on 12/21/2015 3:52:08 PMLogged In Analyst (Original) : HP Initial Sample Wt: Initial Sample Vol: Dilution: Sample Prep Vol:

Replicate Data: Std 4c Net Corrected Calib. Analysis

Repl# Analyte Intensity Intensity Conc. Units Time

2 Na 588.995 1285579.8 1310744.4 [0] mg/L 1:08:05 PM 2 Mg 279.553 1426725.8 1335829.4 [0] mg/L 1:08:05 PM 2 Ni 341.476 -105.1 -6.1 [0] mg/L 1:08:12 PM 2 Mn 257.610 3538.2 3212.6 [0] mg/L 1:08:12 PM 2 Zn 213.857 7405.5 4041.4 [0] mg/L 1:08:12 PM

----------------------------------------------------------------------------------------------------

Cu 324.752 1407.6 184.55 13.11% [0] mg/L Standard intensity and concentration values are not in the same order.Cr 283.563 60.5 57.63 95.31% [0] mg/L Standard intensity and concentration values are not in the same order.Fe 259.939 2408.3 204.32 8.48% [0] mg/L Standard intensity and concentration values are not in the same order.K 766.490 10599009.1 191098.10 1.80% [40] mg/L Standard intensity and concentration values are not in the same order.Cd 228.802 5.4 26.44 488.87% [40] mg/L Standard intensity and concentration values are not in the same order.Pb 283.306 90691.8 1809.09 1.99% [0] mg/L Standard intensity and concentration values are not in the same order.Ca 393.366 28114056.4 10867.63 0.04% [0] mg/L Standard intensity and concentration values are not in the same order.Na 588.995 1266332.2 62808.40 4.96% [0] mg/L Standard intensity and concentration values are not in the same order.Mg 279.553 1323490.7 17449.52 1.32% [0] mg/L Standard intensity and concentration values are not in the same order.Ni 341.476 22.4 40.30 179.70% [0] mg/L Standard intensity and concentration values are not in the same order.Mn 257.610 3251.5 55.09 1.69% [0] mg/L Standard intensity and concentration values are not in the same order.Zn 213.857 4003.3 53.86 1.35% [0] mg/L Standard intensity and concentration values are not in the same order.

====================================================================================================

----------------------------------------------------------------------------------------------------

1 Cu 324.752 3576.8 1060.0 [0] mg/L 1:09:54 PM 1 Cr 283.563 1598.1 -6.0 [0] mg/L 1:09:54 PM 1 Fe 259.939 2519.3 2106.4 [0] mg/L 1:09:54 PM 1 K 766.490 15543883.3 15475192.6 [60] mg/L 1:09:46 PM 1 Cd 228.802 126.1 -5.4 [60] mg/L 1:09:54 PM 1 Pb 283.306 160223.5 159924.0 [0] mg/L 1:09:48 PM 1 Ca 393.366 33272780.6 32862840.1 [0] mg/L 1:09:46 PM 1 Na 588.995 1498772.0 1523936.6 [0] mg/L 1:09:47 PM 1 Mg 279.553 1579014.3 1488117.9 [0] mg/L 1:09:47 PM 1 Ni 341.476 -30.7 68.3 [0] mg/L 1:09:54 PM 1 Mn 257.610 4315.0 3989.4 [0] mg/L 1:09:54 PM 1 Zn 213.857 9095.6 5731.4 [0] mg/L 1:09:54 PM 2 Cu 324.752 3471.8 955.1 [0] mg/L 1:10:05 PM 2 Cr 283.563 1565.2 -38.8 [0] mg/L 1:10:05 PM 2 Fe 259.939 2291.4 1878.5 [0] mg/L 1:10:05 PM 2 K 766.490 15344801.7 15276111.0 [60] mg/L 1:09:56 PM 2 Cd 228.802 129.1 -2.4 [60] mg/L 1:10:05 PM 2 Pb 283.306 157612.4 157312.9 [0] mg/L 1:09:59 PM 2 Ca 393.366 32934798.1 32524857.6 [0] mg/L 1:09:56 PM 2 Na 588.995 1458245.4 1483410.0 [0] mg/L 1:09:58 PM

Method: Pelat Ins 2015 Page 13 Date: 12/21/2015 3:52:13 PM

Mean Data: Std 4cMean Corrected Calib

Analyte Intensity Std.Dev. RSD Conc. Units

2 Mg 279.553 1557705.1 1466808.7 [0] mg/L 1:09:58 PM 2 Ni 341.476 -41.6 57.5 [0] mg/L 1:10:05 PM 2 Mn 257.610 4235.1 3909.4 [0] mg/L 1:10:05 PM 2 Zn 213.857 9036.5 5672.3 [0] mg/L 1:10:05 PM

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Cu 324.752 1007.6 74.22 7.37% [0] mg/L Standard intensity and concentration values are not in the same order.Cr 283.563 -22.4 23.24 103.73% [0] mg/L Standard intensity and concentration values are not in the same order.Fe 259.939 1992.4 161.12 8.09% [0] mg/L Standard intensity and concentration values are not in the same order.K 766.490 15375651.8 140771.96 0.92% [60] mg/L Standard intensity and concentration values are not in the same order.Cd 228.802 -3.9 2.14 54.37% [60] mg/L Standard intensity and concentration values are not in the same order.Pb 283.306 158618.5 1846.34 1.16% [0] mg/L Standard intensity and concentration values are not in the same order.Ca 393.366 32693848.8 238989.73 0.73% [0] mg/L Standard intensity and concentration values are not in the same order.Na 588.995 1503673.3 28656.63 1.91% [0] mg/L Standard intensity and concentration values are not in the same order.Mg 279.553 1477463.3 15067.87 1.02% [0] mg/L Standard intensity and concentration values are not in the same order.Ni 341.476 62.9 7.67 12.19% [0] mg/L Standard intensity and concentration values are not in the same order.Mn 257.610 3949.4 56.53 1.43% [0] mg/L Standard intensity and concentration values are not in the same order.Zn 213.857 5701.9 41.80 0.73% [0] mg/L Standard intensity and concentration values are not in the same order.