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CognisGreen Chemical Solutions TM
The Greening of Personal Care from Ingredient Classification to High Performing Consumer Products
October 27, 2009
Josef Koester, Director Marketing Care Chemicals NAFTA
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Cognis in Brief
Over 160 years Experience in Oleochemical
Corporate focus: Wellness & Sustainability
Approximately 6,000 employees operating production sites and service centers in about 30 countries
2008 Sales: €3.0 billion ($4.2 billion)
Leading global specialty chemicals company
Headquartered in Germany
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The Green Market Trend
Cognis Green Chemical SolutionsTM
- Portfolio Easy Guide
- Regulation Easy Guide
- Green Formulation Grid
Emollient Selection Criteria and Formulation Challenges
Conclusion
Agenda
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Going “green” is a reality ... In the media
The Green Market Trend
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Going “green” is a reality ... For our customers
The Green Market Trend
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Everybody is talking about it!
The Green Market Trend
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Environment
Waste saving
Natural raw materials
Sustainability
Ethic
Organic
Health
Recycling
Fair trade
Sourcing
Energy saving
Performance
Technology
Does everybody mean the same the same thing?
The Green Market Trend
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Suppliers
Certification bodies
Retailer
Manufacturers
Consumer
Regulations
Where to begin?
The Green Market Trend
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IngredientsCosmetic products
The Green Market Trend
Where to begin?
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It’s your choice how green you want to be !
TM
Cognis´ Approach to meeting the “Green” Trend
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Cognis Product Portfolio
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Co-surfactants
Consistency waxes
Basic emollients
Cationics
Pearlizers
Polymers
Lipid Layer
EnhancersPerformanceDispersions
Botanicals
SpecialEmollients
Natural
Oils
Emulsifiers
Solubilizers
SensorialSurfactants
Biopolymers
Vegetable
Proteins
Emulsion
active ingredients
sensorials
emollient
emulsifier
self-emulsifying base
consistency factor wax
water
Shampoo
active ingredients,perfumes
co surfactants
pearlshine, thickners, auxiliaries
basic surfactants
water
cationic additives silicones,waxy emollients
Sensory Modifiers
DeliverySystemsCapsules
Basic Surfactants
"Actives"
Emulsion
BasesVitamins
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Cognis Product Portfolio Easy Guide
A Systematic Approach…
TM
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Cognis APG® Surfactants—from 100% natural feedstocksTM
Alkyl Polyglucosides (APG ®)
GlucoseCorn, Potato, or Wheat Fatty Alcohols Vegetable Oil
Cognis Product Portfolio Easy Guide TM
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� based on 100% natural renewable raw materials� vegetable origin� produced according to the 12 Principles of
Green Chemistry (1)
� free from preservatives, sulfates and ethylene oxide
� extraordinary environmental footprint� readily biodegradable
� APG® meets the requirements for acceptance according to:
(1) Anastas P.T. & Warner J.C. (1998). Green Chemistry: Theory and Practice, Oxford University Press: New york.
FDA
GRAS
Cognis Product Portfolio Easy Guide
Cognis APG® Surfactants—from 100% natural feedstocks
TM
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Body wash OthersHair Care
Tooth pasteShower gel Shampoo
Foam bath
Liqiud soap
Soap bar
Baby + kidsshampoo
Conditioner
Cleansing wipes
Facial wash
Skin Care emulsions & creams
Cognis APG® Surfactants
For Personal Care Applications
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From natural, renewable & synthetic feedstocks; renewable & synthetic building blocks are combined in a chemical process. Greater share of natural C-atoms
CognisHybrids
CognisEcohybrids
CognisNatural modified
CognisSynthetics
From 100 % natural, renewable feedstocks; physicallypurified by water/alcohol or energy.
From 100 % natural, renewable feedstocks; chemically processed, catalyst or reaction aids used.
From synthetic feedstocks; chemically processed.
From natural, renewable & synthetic feedstocks; renewable& synthetic building blocks are combined in a chemical process. SSmaller share of natural C-atoms
CognisNaturals
Cognis Product Portfolio Easy Guide
Remark: All evaluations do not consider preservations, processing aids, catalysts
TM
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Cognis Product Portfolio Easy Guide TM
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Certification Bodies in North America
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NSF - ‘Made with organic’ standard American National Standard, NSF/ANSI 305
OASIS - Organic and ‘made with organic’ standard
Personal Care Certification Bodies – Cognis Involvement
NPA - Natural standard
NaTrue - Originated in Brussels, Natural and Organic certification seal
BDIH - Originated in Germany, global reach, “natural” standard
Ecocert - Originated in France, global reach, “Bio” and “Eco” standards
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NSF – Approval process under development
OASIS – Approval process under development
NPA – 17 Cognis products approved; 48 products pending
NaTrue – Approval process under development
BDIH – 30 Cognis products approved
Ecocert – 73 Cognis products approved
Personal Care Certification Bodies – Cognis Involvement
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Cognis Green Formulation Grid
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Sustainability vs. performancePerformance is the first priority for premium products
“Greenness”e.g. % of natural, renewable C-atoms (weighted) all ingredients*
PerformanceMarket Benchmark
AdvancedProduct
ClassicProduct
SuperiorProduct
Cognis Green Formulation Grid TM
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EXPLORING GREEN …..I am inspired by green. I expect the fulfillment of performance promises. I decide case by case how green I want to be depending on green claims and performance.> 70 % natural C-atoms in Cognis´green formulations
Eco-Image>50%
Eco-Mind>70%
Eco-Spirit>85%
GREEN IS MY CREDO …. I respect the earth‘s sustainable balance. I seriously consider the choices I make.I am not willing to make any compromise on green.> 95 % natural C-atoms and does not contain the following materials: Petrolatum, Mineral Oil, Silicones, PEG/PPG, DEA/TEA
GREEN COUNTS…. I try to consume products that are as natural, green and genuine as possible. I am honest and authentic in my purchasing decisions. I am a sophisticated consumer with high demands.> 85 % natural C-atoms in Cognis´green formulations
OPPORTUNISTIC GREEN …. I am willing to buy green products that meet expectations and are easily accessible. I do not question every detail. I like easy choices.> 50 % natural C-atoms in Cognis´green formulations
Eco-Passion> 95%
Green Grid Consumer Categories TM
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q. s. ParfumPerfume
Agent, pH adjusting1.4Citric AcidCitric Acid (50 %)
Lipid layer enhancer2.0Coco-Glucoside (and) Glyceryl Oleate
LAMESOFT® PO 65
Agent, pearlescent2.0Lauryl Glucoside (and) Stearyl Citrate
EUPERLAN ® GREEN
~ 6,400
5.0
54.2
1.3
0.5
0.5
13.3
22.8
Weight %(as is )
Viscosity (Brookfield RVT, 23 °C, spindle 4, 10 rpm) mPa.s
pH-value (as is)
AquaWater, demin.
Agent, thickeningSodium ChlorideNaCl
PreservativeSodium BenzoateSodium Benzoate
Active, ingredientHydrolyzed Wheat ProteinGLUADIN® WLM BENZ
Surfactant, cleaningCoco-GlucosidePLANTACARE ® 818 UP
Surfactant, cleaningSodium Coco-SulfateSULFOPON® K 35 UP
FunctionINCIEco status
Ingredients
Naturecare – Pearly Shampoo TM
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% of natural, renewable C-atoms (weighted) all ingredients*
> 85 %
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ShampooPerformance
Market Benchmark
AdvancedProduct
ClassicProduct
SuperiorProduct
Cognis Green Formulation Grid TM
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• Appearance: transparent• Active matter: 46 %• Oil phase: silicone free• pH: 4.0 – 4.5• Use level: 1.5 – 10 % (weight % product)
PlantasilMicro(1%)
Cognis
Natural modified
From 100 % natural, renewable feedstocks; chemically processed, catalyst or reaction aids used.
PLANTASIL ® MICRONew possibilities for ’green’ conditioning shampoo
Dicaprylyl EtherDecyl GlucosideGlyceryl Oleate
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PLANTASIL ® MICRONew possibilities for ’green’ conditioning shampoo
• Formulation B withPlantasil® Micro
• ‘Green‘benchmark
Significantimprovement
Significantimprovement
• Novel microemulsion for high performanceconditioning shampoos
• 100% vegetable-based raw materials
• Free from ethylene oxide
• Ecocert approved, BDIH approval ongoing
• Easy to handle
• Cold processable
• Crystal clear shampoos
Microemulsion technology for ‘performance in green‘
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PLANTASIL ® MICRONew possibilities for ’green’ conditioning shampoo
Formulations
• High compatibility with SLES/CAPB systems• Easy addition to shampoo formula• Cold process
12% SLES/CAPB
1% Plantasil ® Micro
12% SLES/CAPB
5% Plantasil ® Micro
12% SLES/CAPB
10% Plantasil ® Micro
12% SLES/CAPB
25% Plantasil ® Micro
12% SLES/CAPB
50% Plantasil ® Micro
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> 85 %
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Subsegment
Skin Care
PerformanceMarket Benchmark
AdvancedProduct
ClassicProduct
SuperiorProduct
100%
% of natural, renewable C-atoms (weighted) all ingredients*
*All calculations are based on the feedstocks for th e Cognis products; non Cognis raw material calculations are based on public information or best knowledge available; calculations do not consider preservatives, perfume, color and enzymes.
96%
Cognis Green Formulation Grid TM
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Viscosity: Brookfield RVF, 25ºC (spindle T-E, 5 rpm with Helipath): 30,000 cpspH Value: 6.6
Water, preservative
Glycerin
Phase II
Xanthan Gum
Cegesoft®
VP
Cegesoft®
PS 6
Cetiol OE®
Myritol®
331
Lanette®
O
Cutina®
GMS-V
Eumulgin®
SG
Phase ISodium Stearoyl Glutamate
Glyceryl Stearate
Cetearyl Alcohol
Cocglycerides
Dicaprylyl Ether
Vegetable Oil
Vegetable Oil (and) Hydrogenated Vegetable Oil (and) Euphorbia Cerifera (Candelilla) Wax
Xanthan Gum
Glycerin
Aqua
0.25
3.0
2.0
2.0
2.0
2.0
2.0
0.2
5.0
q.s
Emulsifier
Consistency factor
Consistency factor
Emollient
Emollient
Emollient
Emollient
Thickener
Moisturizer
Diluent
Ingredients Eco Status INCI Name wt% Function
Basic Green Lotion Formulation Number: US-291-649-196-33
100%*
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Ingredients Eco Status INCI Name wt% Function
Deep Moisturizing Silky CreamFormulation Number: US 338-654-109-13
I. Emulgade ® PL 68/50
Eumulgin ® SG
Cutina ® GMS-V NA
Monomuls ® 90-O18
Cetiol ® OE
Myritol ® 331
Cegesoft ® PFO
Coviox ® T 70 C
Sphingoceryl ® Veg
LS8712
Veegum Ultra
II. Glycerin
Keltrol CG SFT
Water
III. Geogard 221
Herbalia® Soy
Cetearyl Glucoside (and) Cetearyl Alcohol
Sodium Stearoyl Glutamate
Glyceryl Stearate
Glyceryl Oleate
Dicaprylyl Ether
Cocoglycerides
Passiflora Incarnata Seed Oil
Tocopherol
Octyldodecanol (and) hydrogenated coco-glycerides (and) Helianthus Anuus (sunflower) seed extract
Magnesium Aluminum Silicate
Glycerin
Xanthan Gum
Water
Dehydroacetic Acid (and) Benzyl Alcohol
Soy Isoflavones
2.0
0.5
2.0
0.5
7.0
5.0
2.0
0.5
2.0
0.5
3.0
0.8
q.s.
1.0
0.1
O/W Cream Base SE
Co-Emulsifier
Consistency Factor
Lipid Layer Enhancer
Emollient
Emollient
Emollient
Acitve
Active
Thickener
Moisturizer
Thickener
Preservative
Active
Viscosity: Brookfield RVF, 23C°(spindled TE, 5rpm, Helipath): 200,000 cpspH Value: 6.1
96%*
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Emollient Selection Criteria
and Formulation Challenges
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Cetiol ® B / ABCetiol ® SenSoftCetiol ® SN
Cetiol ® CCCegesoft ® VP/SBE
Cetiol ® OECetiol ® PGLCetiol ® SB 45 / VEutanol ® GFitoderm ®
Cegesoft ® GPO / PFOCegesoft ® SH
CognisSynthetics
From synthetic feedstocks; chemically processed
Cognis Hybrids
From natural, renewable & synthetic feedstocks; natural & synthetic building blocks are combined in a chemical process.
Cognis Ecohybrids
From natural, renewable & synthetic feedstocks; natural & synthetic building blocks are combined in a chemical process. High share of natural C-atoms
Cognis NaturalModified
From 100% natural, renewable feedstocks; chemically processed, catalyst or reaction aids used
Cognis Naturals
From 100% natural, renewable feedstocks; physically purified by water/alcohol or energy
Cognis Emollient Portfolio TM
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0
25
50
75
100
Cetiol O
E
Cetiol C
C
Cetiol S
enSoft
Cyclomethicone
Dimethicone
1600
Spreading value
1600
1900
mm2/10min
Green Aspect by Chemistry
vario
us
>190
0
Natural based carbon / overallcarbon in a molecule (%)
Cognis Emollient Portfolio TM
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Challenges in Applications
Hair Color
Styling
Conditioner
Shampoo
Body Wash
Color Cosmetic
Personal Care Wipes
Sun Care
AP / DEO
Face / Body Emulsion
100 % Natural
Physically processed
100 % NaturalChemical processedNaturally inspiredApplication
Leav
e-on
rinse
-off
hai
r tr
eatm
ent
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Formulating Green is not a miracle !
Challenges in some applications still exist !
The green trend is a driver for innovation !
How green do you want to be?...It’s your choice !
Conclusion
Cognis Green Chemical Solutions TM
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GREEN TRENDGREEN TRENDDonDon’’t wait any longert wait any longer!!
www.cognis.comwww.labserobio.com
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