Download - Green Chemistry Strategies
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Green Chemistry: Strategies to launch a
program
Green Chemistry: Strategies to launch a
programMegan Murphy,
Green Chemistry Intern, LabRATS University of California, Santa
Barbara
Megan Murphy, Green Chemistry Intern, LabRATS
University of California, Santa Barbara
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12 Principles 12 Principles Prevention Prevent waste rather than treat it or clean it up Inherently Safer Chemistry for Accident Prevention
Reduce Waste Atom Economy Reduce Derivatives Use of Renewable Feedstocks
Reduce Hazards Less Hazardous Chemical Syntheses Designing Safer Chemicals (Minimizing Toxicity) Safer Solvents and Auxiliaries
Prevention Prevent waste rather than treat it or clean it up Inherently Safer Chemistry for Accident Prevention
Reduce Waste Atom Economy Reduce Derivatives Use of Renewable Feedstocks
Reduce Hazards Less Hazardous Chemical Syntheses Designing Safer Chemicals (Minimizing Toxicity) Safer Solvents and Auxiliaries
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12 Principles (continued)12 Principles (continued)
CatalysisCatalytic reagents (as selective as possible) are superior to stoichiometric reagents.
Design for Degradation
Real-time analysis for Pollution Prevention
CatalysisCatalytic reagents (as selective as possible) are superior to stoichiometric reagents.
Design for Degradation
Real-time analysis for Pollution Prevention
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ScopeScope
Assistance to ResearchersReduction of Unneeded ChemicalsChemical ReplacementsCurriculumPublic Education
Assistance to ResearchersReduction of Unneeded ChemicalsChemical ReplacementsCurriculumPublic Education
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Who are we?Who are we?
FacultyGraduate StudentsResearch Staff
Student InternsAnd Intern Advisor
EHS Hazardous Waste ManagerEHS Staff
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Choosing A CampaignChoosing A Campaign
What issues is there already buy in for?
What issues is there already buy in for?
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Choosing A CampaignChoosing A Campaign
What issues is there already buy in for?
What campaigns can you launch and succeed at within a year?
What issues is there already buy in for?
What campaigns can you launch and succeed at within a year?
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Choosing A CampaignChoosing A Campaign
What issues is there already buy in for?
What campaigns can you launch and succeed at within a year?
What chemicals make up the majority of waste produced on the campus?
What issues is there already buy in for?
What campaigns can you launch and succeed at within a year?
What chemicals make up the majority of waste produced on the campus?
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Choosing A CampaignChoosing A Campaign
What issues is there already buy in for?
What campaigns can you launch and succeed at within a year?
What chemicals make up the majority of waste produced on the campus?
What are the worst chemicals on your campus?
What issues is there already buy in for?
What campaigns can you launch and succeed at within a year?
What chemicals make up the majority of waste produced on the campus?
What are the worst chemicals on your campus?
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Choosing A CampaignChoosing A Campaign
What issues is there already buy in for?What campaigns can you launch and
succeed at within a year?What chemicals make up the majority
of waste produced on the campus?What are the worst chemicals on your
campus?What is your team most invested in?
What issues is there already buy in for?What campaigns can you launch and
succeed at within a year?What chemicals make up the majority
of waste produced on the campus?What are the worst chemicals on your
campus?What is your team most invested in?
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Building off existing buy-inBuilding off existing buy-in
Someone on campus already wants tqo see this happen
Champions already identified Ties in with goals outside of
sustainability (safety, cost, quality, etc..)
Someone on campus already wants tqo see this happen
Champions already identified Ties in with goals outside of
sustainability (safety, cost, quality, etc..)
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Room Temperature DNA/RNA Storage
Room Temperature DNA/RNA Storage
ProblemFreezer failure and associated
degradation of precious samples High energy and financial cost of
freezersThe Right Time
Other campuses initiating pilotsHigh incentive for companies to support
pilot programs
ProblemFreezer failure and associated
degradation of precious samples High energy and financial cost of
freezersThe Right Time
Other campuses initiating pilotsHigh incentive for companies to support
pilot programs
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Room TemperatureDNA/RNA Storage
Room TemperatureDNA/RNA Storage
SolutionTable top
storage of samples
Technology inspired by nature
4 labs engaged
SolutionTable top
storage of samples
Technology inspired by nature
4 labs engaged
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Low Hanging FruitWhat campaigns can you launch and
succeed at within a year?
Low Hanging FruitWhat campaigns can you launch and
succeed at within a year?
Easy to accomplish Quick successes Great for publicity in the first few
years
Easy to accomplish Quick successes Great for publicity in the first few
years
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Low Hanging FruitLow Hanging Fruit
Mercury Thermometer ProgramSurplus Chemical Program
Mercury Thermometer ProgramSurplus Chemical Program
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Mercury Thermometer Program
Mercury Thermometer Program
Problem:CostSafety
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Mercury Thermometer Program
Mercury Thermometer Program
•Collected 806 thermometers and 2 barometers•Gave away 387 spirit thermometers
•Saved up to $40,000 (assuming all collected thermometers would have broken at some point in time.)•Total cost: $6,300 including intern support
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Surplus Chemical ProgramSurplus Chemical ProgramWebsite which advertises chemicals188 chemicals exchanged; 38 labs, 5% of
Laboratories on campusSustainability.ucsb.edu/LARS/programs/
adopt
Website which advertises chemicals188 chemicals exchanged; 38 labs, 5% of
Laboratories on campusSustainability.ucsb.edu/LARS/programs/
adopt
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Biggest waste streamBiggest waste stream
Often not the “worst” chemicals, but critical due to the scale of the waste stream
Affects a large number of laboratories across the campus and has the potential to develop a broad support base
Often not the “worst” chemicals, but critical due to the scale of the waste stream
Affects a large number of laboratories across the campus and has the potential to develop a broad support base
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Flammable Solvents Flammable Solvents
Problem35 tons/yr of flammable solvents
treated as wasteNearly $44,000 spent to dispose of
solvent wasteSolution
Switch labs over to solvent free processes where possible
Problem35 tons/yr of flammable solvents
treated as wasteNearly $44,000 spent to dispose of
solvent wasteSolution
Switch labs over to solvent free processes where possible
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Worst ChemicalsWorst Chemicals
Only applicable to a relatively small subset of laboratories
Risk of not being successfulTry combining campaigns where
you know you’ll be successful and riskier ones run simultaneously
Only applicable to a relatively small subset of laboratories
Risk of not being successfulTry combining campaigns where
you know you’ll be successful and riskier ones run simultaneously
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HF AcidHF Acid
Strong support from faculty who would prefer an alternative
Safety and Sustainability motivationsHigh potential for no alternative to be
found, but important to ask the question
Great learning opportunity for student interns performing the research
Strong support from faculty who would prefer an alternative
Safety and Sustainability motivationsHigh potential for no alternative to be
found, but important to ask the question
Great learning opportunity for student interns performing the research
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Team or Personal commitment
Team or Personal commitment
A campaign you or your team is strongly invested in that might be harder to achieve or require long-term planning
A campaign you or your team is strongly invested in that might be harder to achieve or require long-term planning
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Curriculum DevelopmentCurriculum Development
Honors courses as a testing groundStep 1: Identify courses that use a
chemical you want to replace Step 2: Identify a potential alternative
(MIT Green Purchasing Wizard, great start)
Step 3: Test alternative in honors class and use the rest of the class as a control
Honors courses as a testing groundStep 1: Identify courses that use a
chemical you want to replace Step 2: Identify a potential alternative
(MIT Green Purchasing Wizard, great start)
Step 3: Test alternative in honors class and use the rest of the class as a control
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Curriculum DevelopmentCurriculum Development
K-12 Outreach Developing 12 lesson plans for the 12
principles of Green Chemistry
Centered on 5th grade audience because existing chemistry outreach programs are focused on 5th grade
K-12 Outreach Developing 12 lesson plans for the 12
principles of Green Chemistry
Centered on 5th grade audience because existing chemistry outreach programs are focused on 5th grade
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Expanding to larger scaleExpanding to larger scale
Bring in the experts
Utilize every opportunity to develop support of Chairs, Deans, and administration
Engage faculty
Bring in the experts
Utilize every opportunity to develop support of Chairs, Deans, and administration
Engage faculty
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The ChallengeThe Challenge
We challenge you to take on the issue
We challenge you to take on the issue
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Questions?Questions?
Please Contact our group at:(805)893-2003Or [email protected]
Please Contact our group at:(805)893-2003Or [email protected]