POPs E l l i.
Pesticides Inventory Report
Enubling Activitie.~~fbr Development of'National Plan fir Implementation of'the Stockholm Cbnvention on POPs: Project no. GF/2732-03-4669
NIP/POPs Coordination Office I@$ p d d l Z m 7 \ ( Y / POP0 Pollution Control Department, 92 Phahoo Yorhin 7. Phayalhai. Bangkok 10400 Thailand Tcl: (662) 298 24.27
nru~7uquuaftu 92 a.mraTu$u 7 n.nnnluiru wqiln n l ~ ~ n n - I i ~ o o in^. (MZ)BE 2457
Acknowledgements
The Pollut ion Control Department (PCD) acknowledges and expresses
their appreciation to all members of the National Coordination Committee (NCC) for
the Project: Enabling Activities for the Development of the National Implementation
Plan (NIP) of the Stockholm Convention on Persistent Organic Pollutants (POPS), for
their contributions over the POPS Pesticides Inventory Report.
A p p r e c i a t i o n i s a l so ex tended t o al l re levant s ta f fs o f PCD for the i r
performing and compi l ing of all available data during the preparat ion process.
Very s p e c i a l a p p r e c i a t i o n g o e s t o the NlP lPOPs Pro jec t Manager a n d a l l
Nationai Technical Experts for their times and efforts throughout the preparation of the
report
Mr. Apichai Chvajarernpun
Director-General of Pollution Control Deoartment
POPS Pesticides Inventory Report
Table of Contents
1. Overview of POPS pesticides production, import, export use and contamination
1 .I Introduction
1.2 Production
1.3 Import
1.4 Export
1.5 Use
1.6 Government programs on pesticide use management
1.6.1 Integrate Pest Management (IPM)
1.6.2 Special programs concerning the use of pestcides in Thailand
2. Status of POPS pesticides stockpiles, related wastes and environmental
contamination in Thailand
2.1 Preliminary inventory of obsolete (POPs) pesticides in Thailand
2.2 Results of the inventory of obsolete (POPs) pesticdes in Thailand
2.2.1 Background information
2.2.2 Prev~ously reported data concerning POPs Pest~cides Inventory
2.2.3 Inventory activtes
2.2.4 Overview of storage cond~tions of sites holding POPs pesticides
2.2.5 Previously reporled env~ronniental contam~nat~on by Obsolete
and POPs pes:cides
2.2.6 Prev~ously reported data about Obsolete and POPs pesticides
2.3 Waste management
3. National infrastructure for POPS pesticides management
3.1 institutional Structure and its mandates for POPs management
3.2 National policies for POPs pesticides management
3.3 Legal rnechan~srns for POPs pesticides management
3.3.1 National legal instrument for the management of POPs pesticides
3.3.2 Regionallinternational legal Instrument for the management
of POPs pesticides
4. Summary of the future production, use and disposal of POPS pesticides
requirement for exemptions
5. Existing programs for monitoring of environmentallhuman health impacts
6. Current level of information, awareness raising and education
Annex : --
Annex 1. Detailed Overview sorted on Site
Annex 2. Detailed Overview sorted on active ingredienr
Annex 3. Detailed Overv~ew soried on manufacturer
Annex 4. Pictures of activities on POPS pesticides during the inventory
1. Overview of POPS pesticides production, import, export use and contamination
1.1 Introduction
Pesticides use in Thailand. especially chemical and synthetic substances, began during the
second World War with the Import of DDT to launch an anti malaria campaign. The aim was to
target mosquitoes and the use as insecticide for health reason. Immediately after the War. DDT
was more widely used to kill mosquitoes and flies. Follow~ng this, more variety of chemicals and
syn!hetics were introduced, particularly those classified as organchlorines, followed by others such
as organophosphates and carbamates.
After 1957, the import of chemicals and synthetic substances increased remarkedly. According to
some reports, imported pesticides into Thailand rose from approximately 2,000 tons of active
ingredients in 1957 to approximately 4,000 tons in 1962 and then 37,039 tons in 2001. In the early
phases of import they were largely limited to types classified as organochlorine, organophosphates
and carbamates. Later on, there was further development in pesticides and other types of
synthetic substances were introduced in Thailand like the pyrethroids and extracts from plants and
microorganisms,
The development of pesticide use in Thailand has increased rapidly. However, the hazardous
effect to human health and env~ronment have been reported as ; direct impact to users or farmer,
toxic residues in agricultural products, impact on environment, impact on natural predator and
ecosystem, and etc. A special adverse effect on env~ronment had been pinpointed to the persistent
organic pollutants (POPS) which prevaile in environment for long time and causes damages to living
and nontarget organisms. Therefore, it is necessary to investigate more details to justify whether
the situation is really risk to human health and ecosystems.
1.2 Production (previous, current, future)
The majority of pesticides (active ingredients) used in Thailand are not produced in the country.
They are imported from foreign countries such as Germany, Switzerland, U.S.A, U.K.. China, India,
etc. The reasons for not being produced in the country might be related to the fact that many
difficulties are exuerienced in obta~ning the permit to produce pesticides irom government
authorities. The imported materials are both technical grades and finished products. The technical
grade materials are forrnulated and packaged in Thailand. Formuialing plants count more than 70
spread all over the country and they belong both to local manufacturers and oversea companies
1.3 Import
Table 1 : Import of pesticides during 1977 - 2003 is shown below :
Source : Department of Agriculture Unit : Quantity = toniai Value=Million Baht
In Thaland, most of pesticides used in the country are Imported and the amount has increased
rap~dly n the past twenty years, Importation of pesticides in the early date was mostly in the form of
f~nshed products. Subsequently, sorne agrochen~ical companies started to formulate locally from
technical grade mported Only tne herblade Paraquat 1s locally manufactured from the
~ntermed~ate by two manufacturing plants whlch account for 6,000 metrlc tons a year Untl 1988,
there were 2 formulators registered in Thailand, the number of registered formulators increased to
77 I I . In 2001 (Agr~cultural Regulatory Division, 2001)
In 2003, Thailand imported pesticides 0.131 million tons, divided into 2 groups, chemical i bio-
pesticides and active ingredient. Che~nical and bio-pesticides imported counted for about 0.0806
rnilon tons while active Ingredient imported counted for about 0.0504 million tons. Imported
pesticides are divided into 11 categories, which are insecticide, fungicide, herbicide, acaricide,
rodent~cde, PGR, molluskicide, fumgants, nematczide, miscellaneous, and bio-pesticide
1.4 Export
Information on export of pesticides to foreign markets is not available. Only reliable sources
report about export of pesticides formulated in Thailand to several neighboring countries such as
Laos, Cambodia Myanmar and Vietnam, but the volume are not recorded since the border trading
has occurred along long border lines without proper administration of quant~ties of material passing
the border.
POPs Pesticides Production, Import and Export
lnformatlon on the importation of the 19 specified POPs chemicals has not really been collected
from the very beginning. The term "toxlc chemicals" was not recognized at that time. The only term
that the people heard and understood in that period was "poison" from plants, snakes, mushrooms
and other living things. Thailand was very conservative in this field and never Introduced any toxlc
chemicals to the country in those days. The first report on the application of chemicals was issued
about after the Second World War. That was in 1949 when [ 1, l - (2,2,2,-trichloroethylidene) - bis
(4-chlorobenzenej] or DDT was first introduced for a malarla control trial in Chiangmai Province.
The Malaria epidemic in 1951 was very serious and killed over 40,000 Thai people at a mortality
rate of 2001100,000. DDT has been widely applied at rate of 2 gm-a.i. I m2 ever since. It proved
capable of decreasing the mortality rate each year until it reached 11100,000 in 1993. During those
days, this toxc angel has not only been used for malaria control but also in agricultural for pest
control. It was first applied to control the epidemic of corn grasshopper (Patanga) in 1953 and
became widely known after 1955 when it was applied to control the cotton ball worm and tobacco
insect pest.
Following DDT, the "drin family" was introduced in 1955. The Shell Company in Thailand imported
dieldrin aldrin and endrin, and also at this rime Yip In Soy, a local company Imported BHC and
Toxaphene. Since 1959 all of these organchlorine pesticides have been widely applied for the pest
control of almost all crops including casawa, fruit and vegetable corps. During 1960-1965, farmers
applied a mixture of DDT + Endrin, DDT + dieldrin and DDT + Toxaphene and even DDT +
Toxaphene + methyl parathion instead of DDT only for the control of cotton pests and other plant
pesrs
In 1971 when Toxaphene DDT and BHC formed the largest volume of 62, I. 968 and 17 metric tons
respectively, the volume of dieldrin, aidrln, endrin, chlorodane and heptachlor were less, as 8, 6, 0.6.
3 and 1 metric tons respectively, The mixtures of DDT + Toxaphene and DDT + Toxaphene + methyl
parathion were also reported. The importation of such POPS increased for years and years. There
were increases and decreases in volumes yearly but in general they increased until they were
banned in specified years for the impact on human health and the env~ronment. Only chlordane
remained in use up until 2000.
Table 2 : Import of POPS Pesticides during 1971 - 1997 (tons)
Year Aldrin Chlordane DDT Dieldrin Endrin Heptachloi Taraphene
Source: Department of Agriculture
1.5 Use
Thailand, a major food producing country, has ga~ned main income from exporting
agr~cultural commodities. In 1998 agr~cultural products were exported to foreign countries w~th
value of 14.642 millon US$, accounted tor 38.4% of the total export. When compared to the earlier
statistics of 1987, the value of exported agricultural products was 6.086 million US$, being 51% of
the total export (Agrcultural Statistics of Thaland Crop Year 1986187, 1997198). Thailand has been
a rnajor rice produc~ng country irom the history until now, but the country's agricultural sector has
becorne more diversified during the last decade,
As hoiticultural crops such as vegetables, fruits and flowers gain a growng importance due
to the demand from foreign countries, their physical appearances are significant for good market
prices. For thls purpose, t is revealed that vegetable and fruit farming are using highest amount of
pesticdes and fertilizers. Pesticides are needed in agricultural because roughly one-thrd of the
production of food and fiber was lost to weed, insect pests and diseased. The reasons for
extensive use of pesticides in Thailand is due to the wide variation in climate and crops and the
great multitude of pests and diseases, etc.
Use of POPs Pesticides (previous)
Aldrin was an insecticide applied to soil for termite control and other soil pests such as corn
rootworm. The chemical was also used to control insects in grain storage and ectoparasites on
cattle.
Chlordane was used extensively for termte and ant control in buildings, nurseres and forest
plantations. Chlordane was a broad-spectrum insecticide used to control pests on a wide range of
crops.
D~eldrin was a very effective pesticide applied against termite in buildings, crops, nurseries
and forest plantations. The main used in the past also focused on locust control as well as grain
storage and ectoparasites on cattle.
DDT the most important POPs chemical, was used widely on control of malaria, typhus and
other diseases spread by insects. It was also applied widely on crops and soil to protect insect pests.
e.g. Lepidoptera.
Endrin was used on several crops such as rice, maize, cotton, sugarcane to control on
Lepdoptera. It is also used to control rodents in house and store.
Heptachlor was used to kill soil insects and termites. The usage was also extended to crop
pests, grasshoppers and mosquitoes.
Toxaphene was used mainly on cotton, and something was m~xed with DDT as Toxaphene -
DDT and then used on cereal grains and fruit trees. It was also used to control ticks and mites in
livestock.
1.6 Government programs on pesticide use management
1.6.1 Integrate Pest Management (IPM):
In the past there were several IPM programs on major crops in Thailand such as cotton, rice.
maize and other field crops. All these programs had incorporated many techniques and uses of bio
pesticides such as plant extracts, bacteria, virus and nematode as the tool to lower down the
problems from pesticides
1.6.2 Special programs concerning the use of pesticides in Thailand
There are recommendations in a Policy and Master Plan of Agricultural Pesticides in Thailand
(2002-2006) on the following policies:
- Policy on Promotion of Pesticide Free Pr~duction of Vegetables and Fruits.
- Policy on Promotion of Proper Use of Pesticides, Adopting Correct and Appropriate
Methods.
- Policy on Promotion of Public Awareness and Public against Pesticides.
- Policy on Extending and Accelerating a study on the Risks of Pesticide Use.
All of these programs are undergoing and has not yet evaluated.
2. Status of POPS pesticides stockpiles, related wastes and environmental contamination in Thailand
2.1 Preliminary inventory of obsolete (POPS) pesticides in Thailand
In Thailand, most of POPS Pest~cides that might be left over were under the ownership of
government offices such as :
Ministry of Agriculture (Department of Agriculture & Department of Agricultural
extens~on)
Forestry Department and 1 Department of Natural Resources
Ministry of Health (Vector Control Depanment)
These owners have obtained and kept pesticides for use against plant pests. for use on
individual farms and plantations; input supply programmes of government farm subsidy: farmers' co-
operatives, for use agairist household pests, etc. lt is also not unusual for private pesticide distributors
to accumulate obsolete slocks but to fail to declare them. Some POPS pesticide remained were
introduced to use in locust control 20 - 30 years ago.
Obsolete stocks of pesticides also include small quantlties of organo-phosphates and
carbamates that have deteriorated as a result of prolonged, inappropriate and substandard storage
These Include pesticides such as malathion, fentrothlon, dimethoate, carbaryi and propoxur, along
with larger quantities of banned highly toxic products such as parathion, methyl-parathion,
monocrotophos and metharnidophos.
During the year 2000-2001, Thailand had started prel~~ninary work to carry out an Inventory
of obsolete and unwanted pesticide stocks in order to assess the magnitude of problems and to
plan appropriate management and arrangement for their disposal and destruction in the future with
the objectives to conduct nationwide surveys of obsolete and unwanted pesticide stocks existlng in
the country.
Data of obsolete pesticide stocks were collected by 2 methods, which were by
questionnaire and direct counting (vslt to the sites),
Questionnaire
Questionnaire was desgned and refined for the purpose of inventory taking. It was simple
and easy to answer. I t contained all parts of nformation needed for the inventory of obsolete
pesticide stocks. Questionnaires were distributed to both government agencies and agrochemical
busness.
For the government agencies, questionnaires were sent to the regonal agriculture offices,
which belong to the department of agriculture extension, in all of 76 provinces. Also, they were sent
to 120 research stationsicenters which belong to the department of agriculture.
For the private sectors, total of 397 questionnaires were sent to pesticide formulators,
distributors, and retailers.
Direct counting
Direct counting surveys were carried out in several pesticide formulation plants, distributor
and retailer stores. Farmlands where pesticides are used extensively such as orange grove and
vegetable plantation, were visited. The processes of data collecting include :
1. Interviewing the owners for background informat~on related to pesticides
2. Visual inspection of the storelsites and areas suspected of contamination
3. Completion of information on the Questionnaire
4. Direct counting on types and quantlties of obsolete pesticides stocks and empty
containers.
Result :
The survey result is completed in the FA0 inventory format using computerized database
program. Total quantities and the number of items of obsolete pesticide stocks are shown in Table
3 It reflects the broaden situation of obsolete pest~c~de stocks in the country. Numbers of Items of
obsolete stocks when grouping by the~r type of actionluse are shown in Table 4, This total amount
of obsolete pesticide stocks when sorted into the sites where they are stored, accord~ng to the
agricultural region, is shown n Table 5.
Table 3 : Obsolete, unwanted andlor banned pesticide stocks in Thailand
1 1 Number of / Quantity 1 Quantity
1 ( Containers 1 (Kgs) (Lts) 1 Total Kgs, Lts and pieces of 24,557 1 12,8717 ' 22,993.6 i
1 P~eces of Containers 1 24,557 1 1 1
containers I
Combined total in Kgs 1 Lts k 1
n tons I I I
36 I
35,865.3
Source: Department of Agriculture
Table 4 : Numbers of obsolete pesticides when grouping by their type of actionsluses
ActionlUse ! Number of obsolete pesticides
Insecticide
Fungicide 7 47
Herbicide I 54
Miscellaneous I 49
Unknown 1 162
Source: Department of Agrculture
Table 5 : Quantity of obsolete pesticide specified per Region where they are stored.
CONCLUSION 8 DISCUSSION
Information obtained from the prel~minary inventory taking during the short periou of 2
months in 2000-2001 revealed that there were about 36 tons of obsolete or abandoned pesticides
left over in several places all over Thailand. Among these obsolete pesticides, the only chemical
in POPS list that could be found was chlordane with total amount 905 kg. However, this data
concerns preliminary data and provdes only an indication. No extensive country wide survey has
been undertaken. This information has to be updated and confirmed to receive coirect data by
undertaking a new inventory of Obsolete & POPs pesticide in the country
Region Number of Quantity Quantity Total
Containers In Kgs + Lts
Central 8,831 4,378.5 17,850.6 22,229.1
The explanation for small figure of obsolete and POPs pesticide in Thailand lies in the narure
of pesticide business in the country that the sale and distribution of pesticides is mainly controlled
by the private sectors and using conservation sale projection. Therefore, the purchase of large,
unecono~nic quantities of pesticides is avoided. The same conservative approach is apparent at
the reformulation and repackaging levels of the pesticide industry by lim~ting the quantities of
pesticide processed in order to meet and not exceed the projected market demand. These
strategies also prevent the buildup of excessive pesticide stocks.
In some Afrlcan and other Asian countries where pesticide disposal problem have been
identified, the public sector was the major importer of pesticides. Pesticide purchases were
pr~marily made through government or donor acquisitions and market forecasts of pesticide
requ~rements were often inaccurate. As a result, excess stocks of pesticides accumulated and
North
North East
East
! ~ e s r
South
Source: Department of Agriculture
1.436
9.020
1 171
33
4,673
356.9
3,865.3
0
179
4,049.7
375.6
2,155.4
6
24
2,492.5
732.5
6,020.7
6 I
6,1422 1
degraded under tropical weather conditions before the pesticides could be used up and often
created serious pesticide disposal problems. Such was not found to be the case in Thailand.
Although there are environmental regulations requiring that obsolete pesticide stocks ana
used pesticide containers be destroyed and disposed of by appropriate technology, these
regulations are rarely enforced. Drum refurbishing also appears to be a profitable business, and,
therefore, the disposal of used pestcide steel drums may not be a serious problem in Thailand.
The lack of a program for the disposal of used pastlc and glass pesticide containers. on the other
hand, does pose a potential environmentai and health problem.
The regonal pesticide warehouses owned and managed by the government agencies rnay
contain an excess of obsolete pesticides for the same reason that these excess stocks exist in
other countries where governments are the main purchasers and distributors of pesticides. An
inventory and inspection of government warehouses would assess if a pesticide disposal problem,
even on a minor scale, might ex~st in the country.
Pesticide waste sites may result from accidental fires or large scale spills involving
pesticides. Two such pesticide waste sltes have been identified. One was a retail pesticide store
where recently destroyed by fire, and another one was a Government warehouse of pestcide stock
where fire damaged all stock In 1982. Only limited details could be found from the second incident
at the government warehouse. where it was estimated that 1.8 million baht (about us 5 72,000 at
that time) worth of pesticides were damaged or destroyed. The resdue from the fire was buried one
meter deep in a 25 square meter plot near the site of the fire. There has been no monitoring of this
site unt~l recently, under NlPIPOPs project of Thaand, the site has been inspected and soil
samples was collected for analysis. The result has not yet been revealed.
Based on a systematic approach to many aspects of pesticides distribution and use in
Thailand, we can provis~onally conclude that it is unlikely that large quantities of abandoned or
obsolete which inciuded POPS pesticides exist in the country. However, since the study tinie was
of short duration, updat~ng the existing information should be undertaken to provlde more
information.
2.2 Results of lhe inventory of obsolete (POPS) pesticides n Thailand
2.2.1 Background information
As had been mentioned many times in the National Implementation Plan Project Report the
Issue of obsolete pesticides stockpiles and storage is very important around the world due to the
concern over environmental and health effects from especially the POPS pesticides. Various factors
have contributed to the accurnuiatlon of obsolete pesticides in many countries. The nialn factors
include: ( 1 ) banning of pestcides w h e they are still kept in store; (2) sub-standard stores and poor
stock managemen:; (3) overstocking as a result of poor assessnient of requirements or difficulties
in forecast~ng outbreaks of mgratory pests; (4) inappropriate formulatons or poor quality containers
In some countrles, a significant part of the obsolete pesticide stocks are leftovers of pesticicles that
countries obtained under direct financ~al aid or through some kind of loan arrangements. Also
excessive donations and lnappropr~ate pestic~des contributed to the huge stockpiles of obsolete
pesticides in many countrles. The problem of obsolete stocks is not limited to few countries or
continents. In fact there are only a few countries that are not affected by deteriorating and leak~ng
obsolete pestic~des. But the problem and the negative effects are much more serious in developing
countries. The reason is lack of basic awareness of the inherent danger of pesticides, lack of
facities to handle or to get rid of the tox~c waste, and lack of resources.
However, there IS a strong need for inventory of obsolete stocks because lnventorles are the
gateway to f n d a solut~on to accumulated stocks and the frst step in mak~ng arrangement for the~r
destruct~on
Normally, a pesticide will be considered obsolete if its use is prohibited due to health
hazards and detrimental effects on environment, or it no longer meets minimum quality requrement.
Th~s definition is valid for banned chemicals under the current Thai regulation which established
guiclelines for banning pesticides in Thailand. As such, the guidelnes set priority on chemicals that
created adversed effects on human and environment as well as sub standard quality. Almost one
hundrecl chemicals had been put under the banned list so far, including all POPS pestcides
The major objective of the POPS pesticides inventory in Thailand is to take inventory of
obsolete pesticides stocks inciuding POPS pest~c~des by physically visitlng stores. All places
reported to contaln obsolete pesticides from the work were visited. The other objective are to
estimate the quantities of POPS wlth pesticides left-over were recommend for further action to be
taken for the environmentaliy sound management of the observed stocks
2.2.2 Previously reported data concerning POPS Pesticides lnventory
Preliminary work for inventory of obsolete stocks had been carried out in 2000-2001 by staff
of Department of Agriculture and Agricultural Extension under the support from FA0 and the
government. The work was done mainly by questionnaires and visiting surveys on the areas
suspected of containing obsolete pesticides, especially organchlorines of the POPS lists. Only
Chlordane could be identified with quantity of 905 kg. A small amount of DDT and dieldrin was
reported as well amongst the total amount of 36 tons of obsolete pesticides.
2.2.3 lnventory activities
A Task team had been formed conlprising the national expert consuitant on POPS
pesticides and staff from the Pollution Control Department. The task team is responsible for field
surveys and slte visits. Based on the first survey report done in 2001, the government storage
houses were not inciuded in the inventory. The explanation could be clarified for the first inventory
about the small figure of obsolete and POPS pesticides in Thailand that the pesticide business in
Thailand is in private hands and avoids the purchase of large, uneconomic quantities of pesticides.
Therefore, this policy prevent the bulldup of excess pesticide stocks in distributors and retailers
warehouses. At the same titne, in the government storage houses, especially the storage under the
responsibility of Department of Agr~culture and Agriculture Extension who had engaged in the use
of pest~cide in research and control of sub-standard pesticides in the markets under the
government regulation might have the chance to contain the large quantities of banned and
unwanted pesticides in the research stations and field areas all over the country.
The Task team was trained during an extensive training session during the month of
December 2004. After that, the task team had drafted the plan and visited the major research
stations and government stores in 2 provinces in the Central Region (Supanburi. Nakorn Pathom), 1
provlnce in the Northern Region (Cniengmai), 2 provinces in the Northeastern Region
(Mahasarakarm, Khon Kaen) and 1 province in the Southern Region (Krabij. All these visiting had
been done within 2 months of December 2004 and January 2005, subsequent the visiting of 2
stores in Bangkok and Prattiumthani with the lnternatlonal Consultant (Mr.Jan Betlem) durlng the
traning course for Task team members. Therefore, there are altogether 11 site visits under this
project. It is not excluded that there are more sites wth obsolete pesticides (and POPS pesticides)
in Tha~land
The details of all visiting had been compiled and computer~zed into the format
recommended by FA0 (as attached). For overall summary, there are 11 site visits, the toial
obsolete pesticides products recorded in these 11 sites are 165, having totai weight 71, 212 kg for
solid products and total volume 63, 414 liters for liquid formulation, including 20 m-or empty
packagings at site 2. Ail of the details are sorted into (1 ) Detailed overview sorted on Site (Annex
1 j , !2) Detailed Overview sorted on Manufacturer iAnnex Z ) , (3) Detailed O v e ~ ~ e w sorted on Active
Ingredient (Annex 3). When sorted from all data available from the countrywide survey, the POPS
pesticdes and other persistent. organochlorines can be arranged in the following manner:
Table 6 : Total amounts and formulations of POPS pesticides and other persistent organochlor~nes.
POPS pesticides' 8 other OC
Chlordane'
DDT'
tieptachlor*
Endosulfan
Endosulfan + BPMC
dicofol
Amounts remained
(kg or L)
30 kg
180 kg
10 kg
20 L
2865 kg
41 L
Formulation
40% WP
75% WG
2.96% dust
35% EC
2.5 + 2.0% G
18.5% EC
Source: Department of Agriculture
Comments
When cornpared w~th the first inventory taken in 2001 the only rnajor POPS was found to be
chlordane at 905 kg. In trying to update thls information the Task team had visited this time rnost of
the places mentioned containing chlordane from the first report and could find only 30 kg left. This
rnight be due to the need to use this chen~lcal in the country to control termites. Therefore, the
figure obtained from other areas of the world that 15 - 20%, or even 30% of obsolete pesticides can
be considered as POPS pesticides is not related to the situaton in Thailand. However, it must be
recognized that the Task tearn did not extensively search for all obsolete pesticides and POPS
quantity of pestlcides could be rnuch higher although this inventory has been shown that only a
reiative sniall aniount of the obsolete pesticides can be considered as POPS pesticides.
The preliminary work on inventory of obsolete and POPS pesrcldes was carried out between 2000-
2001 and could identify 36 tons of such hazardous chemicals, Information from preliminary work
had been used as reference for the updated Inventory by the task team with elaboration for more
information to cover government storage house which did not appear in the first inventory. The
inventory this time contained about 132 tons of obsolete and POPS pesticides. For more accurate
information, POPS pesticides which were recorded (chlordane. DDT and heptachlor) only account
for 220 kg products. We could estimate from this figure that the total POPS in Thailand has a
tendency of going down and are not expected to create any problem in the future. As for other
organochlorines such as endosulfan, dicofol and organophosphates (such as monocrotophos and
methamdophos), the problem is still existing due to the stocks from banning or confiscating which
are kept in many places.
2.2.4 Overview of storage condit~ons of sites holding POPS pesticides
The storage conditions of sites holding POPS pesticides are generally acceptable in term
of facilities such as water and electricity availabity, beng put on shelves, separated from each
formulat~on except the sites such as the government storage house in Bangkok that stored lot of
banned and confiscated pestlcides without good separation and the storage is under poor
condition.
2.2.5 Prevously reported environmental contamination by Obsolete and POPS pest~cides
During the slte visit to 2 storage houses of Department of Agrlculture in Bangkok and
Department of Agr~culture Extension in Patumthani whch IS the b~ggest storage house for obsolete
pesticides, the task team could identify approximately 76 tons of obsolete pesticides. The location
~ources of this storage house is behind the Rlce Research Statlon, without connection to water re-
and rice f~eld. The task team had collected 5 soil samples around the area of storage house by
using core sampler. The samples were sent to a laboratory for analysis of organochlorine and
organophosphate pesticides residues. Result of analysis revealed that there were no detectable
amounts of any resldues of pest~cides remainng in the soil in that area.
Another visit was to the waste site near the head quarter of Department of Agricuiture
Extension which used to be the pest~cides warehouse where fire broke out in 1982 and no report on
ttie amount of pesticides remained had been made since then. The task tear11 had Inspected the
area which has changed to be car park and soil samples were collected at 3 spots for analysis.
The analysis had been done to cover 15 important organophosphorous chemicals, POPS pesticide
which are organochlorine group and 8 carbamates. The result of ttie analysis shows that even after
23 years the chemicals which were buried underground (about 1 metre depth) could be detected:
Table 7 : Pesticide residues found in soil samples under inventory work
Sample no. Pestlcldes -
& so11 depth OC
# 1 150cm) BHC 0.06
Hept & H.E 0.21
aldrin & dieldrin 2 1 4
DDT 2.18
Chlordane 2.99
d 2 150 cm) BHC 0.02
aldrin & dieldr~n 0.10
D DT 0.07
Chlordane 0.15
Detected resdues In riigikg
Sample no. & Pesticides
soil depth OC
# 2 (100 cm) BHC
aldrin & dieldrin
DDT
Chlordane
# 3 (50 cm) aldrin &dieldrin
DDT
Chlordane
8 3 (1 00 cm) BHC
aldrin &dieldrin
DDT
Chlordane
lsoprocarb 0.28
fenobucarb 1.0
ND
ND
ND
N D
N D
N D
N D
N D
N D
Detecied residues in rngikg
Based on the result of analysis, one can conclude that mainly organochlorine pesticides
(POPS) such as BHC, aldrin, dieldrin, DDT and chlordane were detected in each soil sample after
more than twenty years. Traces of carbamate were found in the soil at a depth of 1 metre from
surface in one sample.
Although the levels detecied appear relatively low (several ppni), based on industrial use of
the site aldrin and dieldrin levels are elevated on 3 out of 5 samples with a maximum of 15 times the
industrial PRG level. Based on residential use in 4 out of 5 samples pesticides were detected in
levels given !he fact that it is a car park residential use would not beconsidered, but it is not
industrial use either. If e.g. the car park has a concrete, asphalt or other type of cover there will be
little risk for direct contact.
0 P
The levels detected in soil may pose a risk for groundwater contamination, especially the dieldrin
and BHC levels. Depending on the geology, hydrogeology and the use of groundwater this is a
point of attention. We would need a conceptuai model of the site (description ot geology,
hydrogeology and conraminant situation and use of the site) to assess the groundwater exposure
risks. If the site is covered with an asphalt or concrete layer and groundwater is located at a large
depth current risks will be minimal. Of course we do not know what happened in the past, If the
C A
roundwater 1s shallow, and there is no cover to prevent ~nf~itratlon of raln Into the so11 the
groundwater may be affected.
G~ven the above it was suggested by an env~ronmental expert of Tauw Env~ronmental Consultants
(the Netherlands) to execute a r~sk assessment based on the current use of the s~te before any
defnltve conclusions are drawn on the r~sks of the contamination
2.2.6 Previously revolted data about Obsolete and POPS pesticides residues in fish and other food
products, it- other agricultural products, etc, in Thailand
The suiveys and monitoring of organochlorine resldues in the environment was first initiated in
1976 and went on for ten years t i 1985 (Table 8). The work done was emphasized mainly on water,
sediment, soil, fish and shellfish collected from many sites in the central plain areas of the country.
The analyses showed that organochlor~ne persisted in majority of the samples, roughly 50% in water,
90% in sed~ments and aquatic animals and 90+ in soil samples. Since these surveys and
monitorings were taken during the time that organochlorine was widely used, the maximum
concentration of DDT could be detected as high as 4.0 ppb, whereas the levels in soil were found at
ppm levels. Besides DDT, the other persistent organochlorine insecticides that were frequently found
in environmental samples were KBHC, endrn, aldrin, dieldrin, heptachlor and its metabolites. After
the evidences that all these organochlorines had become widely distributed in food chain
envronment, endrin was banned in 1981 followed by DDT, banned from agriculture used in 1983 and
the rest were all banned in 1988.
During 1987-1989 there was another nationwide monitoring program for residue levels of
organochlorine insecticdes in soil, water, sediment, f~sh and shellfish to observe whether levels of
these chemicals after decreasing use will decline or not (Table 9). The results from extensive studies
revealed that the persistent organochlorine such as KBHC. aldrin, dieidrin, DDT and metabolites,
heptachlor and heptachlor epoxide were found to have been distributed in ail agr~cultural areas and
end up in living organisms such as fish and shelifish, same situation as ten years before, only the
amounts of accumulation were not alarming and had tendency to decline.
Table 8 : Organochlorine residues detected in the analysis of environmental samples, 1976 - 1985
Type of samples Collection sites No. of analyzed Positive samples%
samples
Water 1 Rivers, canals and 1
1 Crop fields and orchards I
Sed~ment
Soil
Fish and shellf~sh
Markets, rivers and canals
Source: Department of Agriculture
reservoirs
Rivers. canals and
reservoirs
Agricultural areas
Table 9 : Organochlorine resldues detected in the analys~s of environmental samples, 1987 - 1989
Type of samples No. of samples Positive samples (%) Max.concentration of total
DDT
< 1 ppb
< 1 ppm
< 1 ppm
< I ppm
Water
Sediment
Soil
Fish and shellfish
Source: Department of Agriculture
220
256
253
402
ORGANOCHLORINE RESIDUES IN FOOD CROPS
The extensive studies on accumulation of organochlorine residues in food commodities were
carried out form 1982 to 1985 on several food conlmodities such as vegetables, fruits, grains, oil
coups, field crops, meat and eggs (Table 10). In these studies the results showed that a relatively
large number of samples were contaminated with residues of organochlorine which were mainly BHC,
heptachlor and its epox~de, adrin, dieldrin, endrin, DDT and metabolites. The levels of accumulation
were rangea from traces which were lower than determination limits to rather high levels such as
res~dues of adrin and dieldrln were found in Chinese kale at 2 ppm, and heptachlor and heptachlor
epoxide were also detected at 2 ppm in cassava.
Table 10 : Organochlorine residues from anayss of food commodities during 1 9 8 2 1985.
Type of samples No. of samples Positive samples
Fruits 38.8
Vegetables 66
Grains
Oil crops
Component
66.7
Field crops
Meat
Egg
Cabbage, cauliflower, Chinese kale,
string
Bean, green mustard, sweet corn,
Grape, rose-apple, jejube, rambutan,
orange,
Water melon, strawberry,
606
225
Rice, mung bean, maize,
Soy bean, sesame.
Cassava, sorghum.
23.8
68.7
253
90
112
Source: Department of Agriculture
54.9
41 .O
72.5
However, when these were compared to the analyses of food commodities in 1988, three
years later, on the same commodities, the accumulation levels of organochlorine residues were
detected in lower concentration, less than 1 ppm in every positve sample.
ORGANOCHLORINE RESIDUES IN BIRDS
The information we have from all the preliminary studies has caused concern over
orgarlochlorine contamination not only in food and abiot~c environment but in living organisms, as well.
A case study that give some information on this was an investigation on pesticide residue levels in
birds from the central areas (Table 11). The birds collected were classified into 30 species and
divided into 5 groups according to their feeding habits. Result form analysis for organochlorine
insecticides in stomach content, livers and tissues showed residues of DDT and dieldrin in every
samples whereas traces of some other organochlorine were also present in some samples. Although
the average levels of the most commonly found DDT and dieldrin rarely exceeded 1 ppm which were
reported in several studies not hazardous to treated birds in laboratory experiments, However, the
combined effects of multiple organochlorine residues on birds and their long term consequences
should be carefully examined.
Table 11 : Average values of DDT and dieldrin (mglkg) In stomach content, livers and tlssues of 5
arouDs of 90 birds. (1982)
Res~dues of DDT Residues of d~eldr~n
Group Number stornacn llver tlssue stomach he r tissue
Carnivorous 35 0.09 0.17 010 0.08 0.09 0.03
Herbivorous 17 0.09 0.16 0.05 0.07 0.12 0.03
Omnivorous 13 0.20 0.1 1 0.05 0.14 0.08 0.03
Insectivorous 16 0.19 0.31 0.13 0.09 0.12 0.06
Blrds of prey 8 0.26 0.30 0.13 1.1 0.03 0.1 6
Source: Department of Agriculture
IMPACT ON HUMAN HEALTH
In order to assess the risk from exposure of organochlorine pesticides or consumption of food
containing their residues, analysis of human blood and breast mlk had been initiated and carry on
during 1980- 1983 and 1980- 1986 (DOA 1980, 1983, 1986). The result of human blood analysis for
organochlorine residues on samples drawn from 127 farmers and 40 unidentified professions showed
that about 20% of the samples from both groups were found contained residues of organochlorine at
ppb levels whch were higher in farmers' group (Table 12). When this compared to 99 blood samples
taken from lactating mothers in 1994 it was revealed that trend of accumulation had decreased to
very low levels with fewer posltive samples. Investigation of organochlorine residues in breast milk
had been conducted during 1980, 1983 and 1986 (Table 13). The samples were collected from
lactating mothers in hospitals and analyzed for residues on a whole milk basis. The first batch of
samples were analyzed only for residues of DDT, whereas the second and third studies included
more organochlorine pesticides. The mean values of pesticide residues in breast milk from the three
surveys remain about the same which consistent with the levels reported on workdone by scientist
from different countres, eg USA, Australla, France. Germany, Japan, India and some Latin American
countries (Curie et al. 1979). Although all the studies worldwide have shown that almost 100% of milk
from lactating mothers contained residues of DDT however, it is contradictory regarding correlation of
age, frequency of pregnancies, de t and living place of the mother (Spicer et al. 1993). Therefore, it
would be appropriate to continue monitoring breast milk samples for residues ot all these
organochlorine Insecticides to see whether the level is still remain the same as before or it has a
downward trend, as well.
Table 12 : Analyses of blood samples for organochlorine residue during 1 9 8 0 1983 and 1994
Number of Positive %
samples
Residues found
1980- 1983
Farmers 127 26 DDT, endrin, aldr~n, d~eldr~n,
Iindane, hept. epox
Unident~f~ed 40 19 DDT, hept epox
professions
1994 99 16 p,p' - DDE
Lactating mothers
Source: Department of Agriculture
Table 13 : Organochlorine residues in breast milk samples from 1980 - 1986 (whole milk basis).
Pesticide residue Mean, ppm Positive Samples, %
N=208 N=229 N=192 N=208 N=229 N=192 -
p,p' - DDE 0.125 0.127 0.198 100 94.7 100
p . p ' DDT 0.036 0.036 11.1 44.8
Dieldrin 0 0.0'14 0.011 18.3 7.3
Hept & H.E. 0.028 0.059 1.3 0.5
Source: Department of Agriculture
The result from all analysis had revealed that several organochlorine such as DDT, aldrin,
dieldrin, heptachlor, hept, epoxide could be detected. All these persistent insecticides have been
banned since many years. However, their persistent residues could be found only at very low levels,
showing that there is probably no alarming situatio~ any more.
2 3 Waste management
Presently the preferred disposal method of obsolete stocks is high temperature inclneratlon
in a dedicated hazardous waste incinerator With the exception of some newly lndustrlalized
countries, there are no safe and environmentally sound hazardous waste incineration fac~llties in
developing countries Small incinerators are generally not suitable for the destruction of bulk
quantities of pesticides due to their low temperature destruction range, the possibility of forming
dioxins and the lack of proper flue gass cleaning. New technologies for destruction of obsolete
stocks might be forthcoming but currently are not wdely available or commercially feasible.
In the absence of local incneraton facilities, the alternative is to ship the waste to an
incinerator in industrialized countries overseas that are willing to accept for destruction. Generally,
the costs of such operations are beyond the f~nancial capacities of developing countries and needs
larger sums of money and technical expertise: All international transport has to be according to the
regulations of international Conventions and international regulations (Basel Convention,
International Maritime Dangerous Goods Code-IMDG). The answer to the problem of obsolete
pesticides therefore lies in awareness ratsing and prevention of accumulation of obsolete
pestic~des. In particular, there is a need for creating greater awareness at various concerned levels
of the country for the development of preventive measures for stock-piling of obsolete pesticides.
3. National infrastructure for POPs pesticides management
3.1 Institutional structure and its mandates for POPS management
Although there is presently no special legislation of POPs, Thailand has established a
number of legal instruments and non-regulatory mechanisms to control the use of chemicals and
reduce risk to human health and the environment originating from chemicals including POPs.
Among these are:
The Enhancement and Conservation of National Environment Quality Act B.E. 2535
(1992): This Act prov~des a legal bass for the management and control of environmental quality,
and emissionleffluent standards, montoring, policy development and requirements for EIA as well
as the pollution control.
With respect to the hazardous wastes and chemicals related to POPs and in case of no
specific law thereto, the Minister shall, with the advice of the Pollution Control Committee, have the
power to issue ministerial regulation spec~fying the types and categories of hazardous wastes
generated from the production and usage of chemicals or hazardous substances in the production
process of industry, agriculture, sanitation and other act~vates whch shall be brought under control
For this purpose, rules, regulations, measures and methods must also be prescribed for rhe control
of collection storage, safety measures, transportation, Import into the Kindom, export out of the
Kingdom, and for proper and techn~cally sound management, treatment and disposal of such
hazardous wastes.
The Factory Act B E . 2535 (1992): Thls Act is to control factory operations regarding
Waste disposal, pollution ernlssion and contamination with the main objective of minimizing the
impact on the environment,
The Minister shall have the power to prescribe the ministerial rules fixing the factory of
any type, kind or size to be the group 1 factory, group 2 factory or group 3 factory as the case
many be by taklng into consideration the necessity for the contro, prevention of nuisance,
prevention of damage and prevention of nuisance, prevention of damage and prevention of danger
n accordance wlth the gravity of impact on the public or environment.
The Customs Act B.E. 2469 (1926) and amendments B.E. 2534 (1991): Is the prlmay
law governing the control of customs duties and the collection of taxes on imported and exported
goods on behalf of other government agencies, sbsh as value added tax, excise tax, and ~nunicipal
tax as well as the prevention and control smuggling of goods and other lieg gal products included
the imported and exported chemical products and hazardous wastes:
The Public Health Act B.E. 2535 (1992): This Act covers the prevention and
management of all aspects of danger and nuisance caused by pollutants. The Act is characterized
as most decentralization for the local administration. Minister of the Public Health Ministry IS
incharge and control of execution of the Act and have powers to appolnt public health offcials and
local governmental authorities all over the country . The Minister also have powers to issue the
Minsterla Regulation as;
(1) Prescribing rules, procedures and measures for controlling or overseeing actvites or
operations on ~natters under ths Act.
(2) Prescribing !iving standards suitable to the livelihood of the population and
procedures for controlling or overseeing or remedying things affecting the living
standard suitable to the livelihood of the population.
Hazardous Substance Act B.E. 2535 (1992) This Act has come into force in 1992 and
replace the other two of 1967 and 1973. The reason for the proclamation of this Act is that at
present a great nurnber of hazardous substance have been used in various business and some of
thern have caused serlous injury to the persons, animals, plants, property and environments.
Althouth at present there exisr some laws which are applicable to the hazardous substance, there
are so niany of thern wnich are under the powers of several ministries, bureaus, departments as a
result of different proclaniations made in different periods of time entailing discrepancies and
incomprehensive-ness of thelr provlsion. It is therefore expedient to revise the law on toxic
substance by expanding the scope of application to cover every kind of hazardous substance as
well as to adopt the criteria and procedures for an even more suitable control of the hazardous
substance and to establish the administrative system to promote coordination among various a
agencies involved in the supervision of the said hazardous
3.2 Natlonal policies for POPS pesticides management
Exlsting pollcy and ~mplementation guidelines
To address the chemical (in general) management in the country, Thailand has set up 4
main policies as 1) Establish an effective system for rnanaging hazardous substances coverllig
import, export, production, transport, trade, use, storage and waste destruction. 2) Establish system
for prevention and mitigation of emergency and serious accident resulting from hazardous
substances 3) Promote reduced utilization of pesticides and 4) Encourage the private sector to
participate in investments for addressing problems related to chem~cal management.
Under these policies, guidelines on law enforcement and management have been
implemented.
Law Enforcement Guidelines
1) Strict and efficient control of hazardous substances according to the law by assigning
unlts other than government agencies and the private sector to monitor these
substances
2) Accelerate the ~mprovement and amend concerned laws and regulations for systematic
management of hazardous substances in all stages: import, export, production, trade,
transport, utllzation, storage and the &struction of wastes.
31 Formuiate standards for hazardous substances contaminating the environment,
agricultural products and consumable items, to cover a greater number of types of
substances.
4) Instruct all industries that use and p~~oduce large quantities of extremely dangerous
substances to prepare an environmental impact assessment report and risk
assessment.
5) Control the storage of hazardous substances by designat~ng areas for establishing
~NarehOUSeS f o ~ hazardous products. Stipulate srandards for warehousing ot
hazardous products, along with systems and insurance system to prevent and mitigate
emergencies 'Nhen an accldent occurs.
6) Consider strictly prohibiting imports and production or restricted uses of hazardous
substances in agriculture, industry and public health that substantially affect heath and
the environment.
7) Control the transport of hazardous substances by stipulating standards for vehicles,
methods of transport, suitable routes for channeling transportation, diiving speed,
qualifications and duties of drivers of transport vehicles and labels giving details of the
hazardous substances.
3.3 Legal mechanisms for POPS pesticides nianagenient
3.3.1 National iegai instrument for the management of POPS pesticdes.
The hazardous substance is classified according to the needs for control as follows:
(1) Type 1 hazardous substance is that of which the production, import, export, or
having in possession must comply with the specified criteria and procedures.
(2) Type 2 hazardous substance is that of which the production, import, export, or
having possession must first be notified to the authority and must also comply with
the specified crteria and procedures.
(3) Type 3 hazardous substance is that of which the production, import, export, or
having possession must obtain a permit.
(4) Type 4 hazardous substance is that of which the production, import, export, or
having in possession is prohibited.
For the purpose of prevention and stop of danger that may be inflicted upon the
persons, animals, plants, property, or environments, the Minister of Industry with the opinions of the
committee, shall have the power to publish in the Government Gazette designating the names or
qualifications of hazardous substance, type of hazardous substance, period of application and
responsble agencies for the control of the said hazardous substance.
There are numerous chemicals considered as severely restricted or banned for
agriculturai and public health use, as well as in foods, cosmetics and household products. A
summary for the POPS gvlng the date of the ban and some of its reasons is shown as the following:
Table 14 ' Banned POPS chemicals in Thailand
Chemicals
Aldrin
Chlordane
DDT
Date of Ban
1988
D~eldrin
Reasons
Persistent, accumulate in living organisms
2000 (AG) 1 environment. many alternatives
Source: Department of Agriculture, AG = agricultural use
1995 (PH) / Possible carcinogen, persistent, high impact. to I
1983 (AG)
1994 (PHI
1988
poisoning, high risk for users
Persistent in agricultural products and in food chain.
I
Heptachior
Hexachlorobenzene
Mirex
PCBs
Toxaphene
PH = public health use
Persistent and accumulation in food chains. possible
carcinogen in tested animais
Persistent, accumulate in living organisms, high acute
Endrin I
All POPs pesticides are classified and listed under the Type 4. It means that the whole
cycle of management from production, import, export and having in possession are prohibited or
banned. It is noted that banned or prohibited measure was applied only importation until the
amended Act after 1992. Therefore at present, all POPS pesticides are totally banned. It must be
noted that Mirex and Hexachlorobenzene (as Type 4 pesticide) have never been imported.
1981
I harm 10 non-target organisms
Responsible agencies and authorities under the Hazardous Substance Act 1992
This Act play an important role in management and control of POPs chemicals and
chemicals in general. All government agencies are able to implement this act in particular
purposes as referred in the Act. For instance, the government agencies have a direct power to
execure the Act as follows.
1) Department of Agriculture, Ministry of Agriculture and Cooperatives iMOAC)
empowered to regulate and control agricultural toxic substances i.e. pesticides, plant
1988
1995
1975
1983
growth regulator etc.
Persistent, accumulate in living organisms
Never imported I I
Never imported i Risk to human health and the environment
Possible carcinogen in tested animals, persistent
I
2) Department of lndustrlal Works, Minstry of lndustry (MOI) empowered to control all
hazardous substances used in industries.
3) Food and Drug Administration Office, Ministry of Public Heath (MOPH) empowered to
control hazardous substances relating household products, daily or public health uses.
The Minister of Industry shall issue the prescription of the announcements the names or
identification of hazardous substances, types of hazardous substances, period of appllcatlon and
responsibiiity agencies for the control of said hazardous substances and also make a list of
hazardous substances of which production process and nature are likely to cause injury.
The hazardous substances are regulated by type as llsted under the Hazardous Substance
Act 1992 which is implemented jointly by main responsible agencies. The Ministry of lndustry has
the power to publish the list in the Government Gazette. Other notification on different matters. i.e.
registration, criteria and procedures of production, Import etc., shall be issued on its own ministeral
notifications.
3.3.2 Regionali~nternat~onal legal instrument for the management of POPS pest~cides.
Thailand has actlvely supported activities and international actions related to chemical's
management, includng the Stockholm Convention on Persistent Organic Pollutants (POPS). Having
recognized the impact of POPS chemicals to human health and the environment, Thailand by
several government agencies has carried out monitoring programs on chem~cal residues in soil,
water and agriculture products includ~ng POPS pest!cides and PCBs. Data and results have been
compiled and the environmental situation evaluated annually. Thailand is an active member of
international organizations and has partic~pated in various programs such as IFCS, IPCS. UNEP.
WHO, FAO, UNIDO, and ILO as well as nternatlonal agreements, such as Agenda 21, UNEP
London Guidelines, FA0 Code of Conduct, Montreal Protocol, Basel Convention, and WTO
agreements.
Thailand has recognized the problem of chemical hazards as a high pr~ority, particularly the
Importance of the chemical management under the chapter 19, Agenda 21. Since the 1960s it has
been tackling health and environmental problems systematically and enacted legislation at the
national ievel. At present, there are many government agencies responsible in the field of chemical
control and management as mentioned earlier.
4. Summary of the future production, use and disposal of POPs pesticides requirement for
exemptions
Some of the POPs pesticdes were never produced nor imported into the country and a!l ot
the remainder pesticides have been banned for all uses since several years. Therefore, it is
antic~pated that the inventory for POPs pesticides will be very less for all chemicals and thls
conformed to lists of chemicals in Annexes A and B of the Convention. As none of the POPS
pesticdes are being used in Thailand as of requirement under the Stockholm Convention, there is
no need to ldenlify needs for country-specific exemptions to further usage of POPs. The Natlonal
Implementaton Plan required under Article 10 on public information , awareness and education has
already existed in Thailand, as well as research, development and monitoring under article 11
However, additional collection of information and cooperation among concerned agencies need to
be strengthened.
5. Existing programs for monitoring of environmental/human health impacts
The programs of monitoring of environmental /human health impacts had been done
intensively during 1970-1990 by many government research institutes. However, the results of
those investigations seemed to show no alarming situation. Therefore, the activities on monitoring of
health and environmental Impacts of POPs pestic~des are becoming on downtrend and finally, not
continue.
6. Current level of information, awareness raising and education
In general, the existing system in Thailand is in compliance with the legislative provisions
and control of hazardous substances including POPS pesticides. However, the knowledge on
disposal of wastes and impacts on health and environment 1s not enough disseminated to relevant
people at all levels.
Annex
Annex 1. Detailed Overview sorted on Site
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35
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lre
168
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Tha
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Annex 3. Detailed Overview sorted on
manufacturer
"ln
veri
toq~
anrl
Dis
posa
1 of
Haz
ardo
us W
aae"
Det
aile
d O
verv
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so
rted
on
man
ufa
ctu
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~-
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20
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mat
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alax
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0 kg
M
etal
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5G
P
01
-03-
1990
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illus
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00
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P
-fl wet
tabl
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~
~
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-
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-
Cya
nam
id
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5.3
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, 1
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iqu
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80
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P
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nam
id T
ha
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nd
U
nkno
wn
23
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' %
1
rm
:
2389
6 kg
G
lyco
side
P
01
-09-
1998
1
- -
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ont
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nula
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-
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Me
tho
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193
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P
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P
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93,
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P
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93
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P
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wet
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24
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11
4/
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lil
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aci
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tiurin
gien
sis
' 17
,600
; I
5 1 A
50
-er
18
0
litre
D
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l ES
P
1
23-0
3-19
97
- -~
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~~
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~~
~
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mu
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trid
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le
24
% W
/G
T-
TA
/
~YE-
i 48
lit
re
Ter
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i P
01
-01-
1997
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9
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-
e 54
0 lit
re
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4E
C
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lv
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8
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93
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Manufacturer Active ingredient Concentration Site number ~ o r m . ~ ~ ~ e ' ~ o t a l quantity Trade name ~ ~ l l ~ a n u f a c t . Arrival
~ I I
I -
May 8 Baker. Dagenham Foselyl A1 8 0 % 1 I I A 6 ~ o r w p - 24 kg Aleate P I I
-~--~ ~ ~
Mitsomboon Ltd. Heptachlor
~ ~~~~~~ ~ ~ ~ ~ ~ - - ~ 1 ~~ ~ --
Milsomboon Ltd Chlordane 4 k g ~ e m o r y : P
~~- ~ ~~~ ~ ~~ ~ .. ~
. ~
-- -- --
Monsanlo Butachlor + Propanil 27.5+27. % wlv e - 264 lilre 'Challenge P
~ -~ ~~~p~ ~~ ~p
~ ~ ~
Monsanto Thailand Ltd. Unknown 1298 lire Lasso P 10-08-1998
~ ~~ ~ - ~ ~
~~-p~- . Parko Parathion methyi 3 grlkg 1 % k g ethyl parathion dust P
- ~ , - ~ ~- ~ ~-~ , ~~ ~. ~~-p~~ ~~ -~ ~~ p~
Pat0 Industrial Chem. Ltd Folpet 4 2 kg ~ o l ~ a n I P ~~ ~ A-
~ -- ~ ~ ~
Pato lnd&trial Chem. Ltd ~imethoate + 12+12 grllitre 5 A 36iEcor e - ! 366 litre Dimethoale + P 10-11-1994'
lsocarbophos ~ - - ~ ~ ~ ~~~ ~~ ~~ - ~ --L ~ 1 1 ;emulsifiable ~~ ~~ Isocarbophos ~~~~
./, ;-~- ~
~~~
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Pato Industrial hem. Ltd Folpet 501 5 A 5 G h o r w p - 234 kg Folpan P
1~J wettablei ~ ~ - - - - ~~~ ~ -- - ~ - ~- ~- ~ ~~ ~
~~ ~ -~ ~-~
Project Field Profenfos + 40+4 % wlv 5 1 A 6 7 ~ c or e - 115 lilre Proper 44 P 10-02-2001 / lemulsifiable I Cypermelhrin --
~-~ ~ ~ ~ ~ ~ - ~ ~ - ~ p ~ ~ ~ ~ ~ ~ ~ ~ - .... ~~
~~ ~- , A , r~ ~.~ ~ ~- - I L~-~~ , ~ ~
Ratchakitpauana LTD. Unknown 7 Liquid 12- Yeast Protein P Hydrolysate
-~ ~ ---- ~~~ - ~ ~ ~ ~
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Rhone Poulenc Ethoprophos l o % [ 4 j ~ - 1201% kg ~lhoprophos I P 06-08-19971 ~ r i l n ~ l l a r , ~~ , ,
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~ h o n e Pouienc Cvoermethrin + 22.50+2 arllitre ! 5 1 A 1 3 3 ~ c or e - 109 litre Panon P ' 11-07-1994 ~ h b s a ~ o n e -~ ~ 8.75: 1 1.- 1 emulsifiable ~~ - ~~
~~ ~~ -- ~
Rhone ~ou lknc lprodione 96' litre Rofral ~ 3 0 - 0 6 - 1 552
~~~ ~~~~ i
~ ~~~ ~ ~- -- ~- -- 7- ~
G o n e ~ou lenc Fipronil 5 % wlv 2 4 litre ~ i p r o n i l 50 SC P 10-03-19971
, ~ ~~~ ~ ~ ~~~~ ' -- ~2
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Annex 4. Pictures of activities on POPS
pesticides during the inventory
Site visit at Chiengmai Province (23-24 December, 2004)
Site visit at Supanburi Province (11 January, 2005)
Site visit at Khonkaen and Mahasarakarm Province ( f c f s January, 2005)
Site visit at Nakorn Pathom Province (17 Januaty, 2005)
Site visit at Krabi Province (27-28 January, 2005)
NIP/POPs Coordination Office p6drz1iwqn NIP I POPS Pollution Control Lkp.rtmeet, 92 P h a h ~otbio 7. mys~bsi BsagkaI~ IW n m i h m d T& (662) 298 2457
C;EF nrum~quurilum ~.mrrru~n 7 o.mwnluLn mq~ln nyinrr* 1~ Inr. w) 2~ 2 4 ~ 7