Safety Data Sheet ( Compliant to CLP/GHS Regulation 1272/2008/EEC )
totalCAST Clear Artwork Resin
Revision Date 23-MAR-2016
SECTION 1: Identification of the substance and the company 1.1. Product identifier
Product name totalCAST
Substance name Hybrid Polymeric Blend
CAS number 30583-72-3 ( 55-60% ). Not yet classified ( >40% )
Product Type Polymer Resin
1.2. Relevant identified uses of the substance or mixture and uses advised against
Product use Artwork Coating and Casting
1.3. Details of the supplier of the safety data sheet
Manufacturer / Importer / Supplier : Eli-Chem Resins U.K Ltd Astra House, The Common Cranleigh, Surrey, GU6 8RZ United Kingdom
Contact : [email protected]
Telephone : General Information:
+44 1483 26 66 36 www.elichem.co.uk
1.4. Emergency telephone number +44 (0) 1483 26 66 36
SECTION 2: Hazards identification 2.1. Classification of the substance or mixture Classification according to Regulation (EC) No. 1272/2008 [CLP/GHS] Hazard Class Category Hazard statement Code(s) Skin Sens. Category 1 H317 Aquatic Chronic Category 2 H411 Classification according to Directive 67/548/EEC (DSD) The product is classified as dangerous according to Directive 67/548/EEC and its amendments. Classification : N, R51/53
R43 Adverse effects May cause an allergic skin reaction. Toxic to aquatic life.
See Section 16 for the full text of the H statements and R phrases declared above. 2.2. Label
elements
Hazard pictograms :
Signal word : Warning
Hazard statements : May cause an allergic skin reaction.
Precautionary statements
Prevention Wear protective gloves. Avoid release to the environment. Avoid breathing
vapor. Contaminated work clothing should not be allowed out of the
workplace.
Response Collect spillage. IF ON SKIN: Wash with plenty of soap and water. If
skin irritation or rash occurs, seek medical advice/attention. Wash
contaminated clothing before reuse.
Disposal Dispose of contents and container in accordance with all local, regional,
national and international regulations. 2.3. Other hazards
The data show that the properties of the substance do not meet the specific criteria detailed in
Annex XIII and, consequently, that the substance is not considered a PBT/vPvB.
SECTION 3: Composition/information on ingredients Substance/mixture : Mono-constituent polymeric substance
Ingredient name REG # /CAS Classification % #/EC #
Symbol(s)/Hazard R-Phrases
Class and /Hazard
Category Code(s) statement
Code(s)
Cyclohexanol, Xi; N; Xi; R43 100 4,4'-(1-methylethylidene)bis-, polymer 30583-72-3/ N; R51/53
with 2-(chloromethyl)oxirane
Skin Sens. 1 H317
Aquatic Chronic 2 H411
See Section 16 for the full text of the H statements and R phrases declared above.
SECTION 4: First aid measures 4.1. Description of first aid measures
First aid measures
Inhalation : Move exposed person to fresh air. Keep person warm and
at rest. If not breathing, if breathing is irregular or if
respiratory arrest occurs, provide artificial respiration or
oxygen by trained personnel. It may be dangerous to the
person providing aid to give mouth-to-mouth resuscitation.
Get medical attention if adverse health effects persist or
are severe. If unconscious, place in recovery position and
get medical attention immediately. Maintain an open
airway. Loosen tight clothing such as a collar, tie, belt or waistband.
Ingestion : Wash out mouth with water. Remove dentures if any. Move exposed person to fresh air. Keep person warm and at rest.
If material has been swallowed and the exposed person is
conscious, give small quantities of water to drink. Stop if
the exposed person feels sick as vomiting may be
dangerous.Do not induce vomiting unless directed to do so
by medical personnel. If vomiting occurs, the head should
be kept low so that vomit does not enter the lungs. Get
medical attention if adverse health effects persist or are
severe. Never give anything by mouth to an unconscious person. If
unconscious, place in recovery position and get medical
attention immediately. Maintain an open airway. Loosen
tight clothing such as a collar, tie, belt or waistband.
Skin contact : Flush contaminated skin with plenty of water. Remove
contaminated clothing and shoes. Wash contaminated
clothing thoroughly with water before removing it, or wear
gloves. Continue to rinse for at least 10 minutes. Get
medical attention. In the event of any complaints or
symptoms, avoid further exposure. Wash clothing before
reuse. Clean shoes thoroughly before reuse.
Eye contact : Immediately flush eyes with plenty of water, ccasionally
lifting the upper and lower eyelids. Check for and remove
any contact lenses. Continue to rinse for at least 10min. Get
medical attention if irritation occurs. 4.2. Most important symptoms and effects, both acute and delayed Over-exposure signs/symptoms Inhalation : No known significant effects or critical hazards. Ingestion : No known significant effects or critical hazards. Skin : Once sensitized, a severe allergic reaction may occur when
subsequently exposed to very low levels. Eyes : No known significant effects or critical hazards.
See section 11 for more detailed information on health effects and symptoms. 4.3. Indication
of immediate medical attention and special treatment needed
Notes to physician : No specific treatment. Treat symptomatically. Contact poison treatment specialist
immediately if large quantities have been ingested or
inhaled. Protection of first aid : No action shall be taken involving any personal risk or personnel without suitable training. It may be dangerous to the person
providing aid to give mouth-to-mouth resuscitation. Wash contaminated clothing thoroughly with water.
SECTION 5: Fire-fighting measures 5.1. Extinguishing media Suitable : Use water spray, fog or foam. Not suitable : Do not use water jet. 5.2. Special hazards arising from the substance or mixture Hazards from the substance or : In a fire or if heated, a pressure increase will occur and the mixture container may burst. This material is toxic to aquatic life
with long lasting effects. Fire water contaminated with this material must be contained and prevented from being discharged to any waterway, sewer or drain.
Hazardous thermal : No specific data. decomposition products 5.3. Special protective actions for fire-fighters Special precautions for : Promptly isolate the scene by removing all persons from fire-fighters the vicinity of the incident if there is a fire. No action shall be
taken involving any personal risk or without suitable training.
Special protective equipment : Fire-fighters should wear appropriate protective equipment for fire-fighters and self-contained breathing apparatus (SCBA) with a full
face-piece operated in positive pressure mode.
SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures No action shall be taken involving any personal risk or without suitable training. Evacuate surrounding
areas. Keep unnecessary and unprotected personnel from entering. Do not touch or walk through
spilled material. Provide adequate ventilation. Wear appropriate respirator when ventilation is
inadequate. Put on appropriate personal protective equipment (see section 8). Avoid breathing vapor
or mist. 6.2. Environmental precautions Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers.
Inform the relevant authorities if the product has caused environmental pollution (sewers, waterways,
soil or air). Water polluting material. May be harmful to the environment if released in large
quantities.
6.3. Methods and material for containment and cleaning up Small spill : Move containers from spill area. Dispose of via a licensed
waste disposal contractor. Stop leak if without risk. Dilute with water and mop up if water-soluble. Alternatively, or if water-insoluble, absorb with an inert dry material and place in an appropriate waste disposal container.
Large spill : Move containers from spill area. Approach release from
upwind. Prevent entry into sewers, water courses, basements or confined areas. Dispose of via a licensed waste disposal contractor. Note: see section 1 for emergency contact information and section 13 for waste disposal. Stop leak if without risk. Wash spillages into an effluent treatment plant or proceed as follows. Contain
and collect spillage with non-combustible, absorbent
material e.g. sand, earth, vermiculite or diatomaceous
earth and place in container for disposal according to
local regulations (see section 13). Contaminated
absorbent material may pose the same hazard as the
spilled product.
SECTION 7: Handling and storage 7.1. Precautions for safe handling Put on appropriate personal protective equipment (see section 8). Eating, drinking and smoking should
be prohibited in areas where this material is handled, stored and processed. Workers should wash
hands and face before eating, drinking and smoking. Persons with a history of skin sensitization
problems should not be employed in any process in which this product is used. Do not get in eyes or on
skin or clothing. Do not ingest. Avoid breathing vapor or mist. Avoid release to the environment. Keep
in the original container or an approved alternative made from a compatible material, kept tightly
closed when not in use. Empty containers retain product residue and can be hazardous. Do not reuse
container. 7.2. Conditions for safe storage, including any incompatibilities Store in accordance with local regulations. Store in original container protected from direct sunlight in
a dry, cool and well-ventilated area, away from incompatible materials (see section 10) and food and
drink. Keep container tightly closed and sealed until ready for use. Containers that have been opened
must be carefully resealed and kept upright to prevent leakage. Do not store in unlabeled containers.
Use appropriate containment to avoid environmental contamination.
Packaging materials
Recommended : Use original container.
7.3. Specific end use(s) Not applicable.
SECTION 8: Exposure controls/personal protection 8.1. Control parameters Exposure limit values Ingredient name Occupational exposure limits
Europe No exposure limit value known.
Sweden No exposure limit value known.
Denmark No exposure limit value known.
Norway No exposure limit value known.
France No exposure limit value known.
Netherlands No exposure limit value known.
Germany No exposure limit value known.
Finland No exposure limit value known.
United Kingdom (UK) No exposure limit value known.
Austria No exposure limit value known.
Switzerland No exposure limit value known.
Belgium No exposure limit value known.
Spain No exposure limit value known.
Turkey No exposure limit value known.
Czech Republic No exposure limit value known.
Ireland No exposure limit value known.
Italy No exposure limit value known.
Estonia No exposure limit value known.
Lithuania No exposure limit value known.
Slovakia No exposure limit value known.
Hungary No exposure limit value known.
Poland No exposure limit value known.
Slovenia No exposure limit value known.
Latvia No exposure limit value known.
Greece No exposure limit value known.
Portugal No exposure limit value known.
Bulgaria No exposure limit value known.
Romania No exposure limit value known.
8.2. Exposure controls Recommended monitoring : If this product contains ingredients with exposure limits, procedures personal atmosphere or biological monitoring
may be required to determine the effectiveness of the ventilation or other control measures and/or the necessity
to use respiratory protective equipment. Reference should
be made to European Standard EN 689 for methods for the
assessment of exposure by inhalation to chemical agents
and national guidance documents for methods for the
determination of hazardous substances. If this product
contains ingredients with exposure limits, personal,
workplace atmosphere or biological monitoring may be required to determine the effectiveness of the ventilation
or other control measures and/or the necessity to use
respiratory protective equipment.
Occupational exposure : No special ventilation requirements. Good general controls ventilation should be sufficient to control worker exposure
to airborne contaminants. If this product contains ingredients with exposure limits, use process enclosures,
local exhaust ventilation or other engineering controls to
keep worker exposure below any recommended or statutory
limits. Hygiene measures : Wash hands, forearms and face thoroughly after handling
chemical products, before eating, smoking and using the
lavatory and at the end of the working period. Appropriate
techniques should be used to remove potentially
contaminated clothing. Wash contaminated clothing before
reusing. Ensure that eyewash stations and safety showers are
close to the workstation location.
Respiratory protection : Use a properly fitted, air-purifying or air-fed respirator complying with an approved standard if a risk assessment
indicates this is necessary. Respirator selection must be
based on known or anticipated exposure levels, the hazards
of the product and the safe working limits of the selected
respirator. Hand protection : Chemical-resistant, impervious gloves complying with an
approved standard should be worn at all times when handling chemical products if a risk assessment indicates
this is necessary. Eye protection : Safety eyewear complying with an approved standard
should be used when a risk assessment indicates this is
necessary to avoid exposure to liquid splashes, mists, gases
or dusts. Skin protection : Personal protective equipment for the body should be
selected based on the task being performed and the risks
involved and should be approved by a specialist before
handling this product.
SECTION 9: Physical and chemical properties
9.1. Information on basic physical and chemical properties
Appearance
Physical state : Liquid
Colour : Optically Clear / Colourless
Odour : Odorless
Odour threshold : Not determined
pH : Not determined
Melting Point : Less than 10°C(50 °F)
Initial boiling point and boiling : Not determined
range
Flash point : 115°C (239 °F) Pensky-Martens Closed Cup ASTM D 93
Evaporation rate : Not determined
Vapor pressure : Not determined
Vapor density : Greater than 1
Relative density : Not determined
Solubility : Negligible
Partition coefficient: : Not determined
n-octanol/water
Auto-ignition temperature : Not determined
Decomposition temperature : Not determined
Viscosity : Kinematic-Not determined
Explosive properties : Dynamic- 1.8 - 2.5 Pa·s @25 °C (77 °F)
Not determined
Oxidising properties : Not determined
9.2. Other information Not applicable.
SECTION 10: Stability and reactivity
10.1. Reactivity
Reacts with strong oxidising agents. Reacts exothermically with bases (eg caustic soda),
ammonia, primary and secondary amines, alcohols, water and acids. Polymerises in contact
with caustic soda. Polymerises exothermically with amines, mercaptans and Lewis acids at
ambient temperature and above.
10.2. Chemical stability
The product is stable.
10.3. Possibility of hazardous reactions
Under normal conditions of storage and use, hazardous reactions will not occur.
10.4. Conditions to avoid
Caustic soda (sodium hydroxide) can induce vigorous polymerisation at temperatures around 200
°C. 10.5. Incompatible materials Reactive or incompatible with the following materials: sodium hydroxide, strong oxidizing agents.
10.6. Hazardous decomposition products Under normal conditions of storage and use, hazardous decomposition products should not be
produced.
SECTION 11: Toxicological information 11.1. Information on toxicological effects Cyclohexanol, 4,4'-(1-methylethylidene)bis-, polymer with 2-(chloromethyl)oxirane Acute toxicity
Oral No applicable toxicity data. No known significant effects or critical hazards.
Dermal No applicable toxicity data. No known significant effects or critical hazards.
Inhalation No applicable toxicity data. No known significant effects or critical hazards.
Other routes No applicable toxicity data. No known significant effects or critical hazards.
Skin corrosion/irritation No applicable toxicity data. No known significant effects or critical hazards. Serious eye damage/irritation No applicable toxicity data. No known significant effects or critical hazards. Skin sensitization Expected to be a skin sensitiser. Respiratory sensitization No applicable toxicity data. No known significant effects or critical hazards. Germ cell mutagenicity No applicable toxicity data. No known significant effects or critical hazards. Carcinogenicity No applicable toxicity data. No known significant effects or critical hazards. Reproductive toxicity No applicable toxicity data. No known significant effects or critical hazards.
Developmental / Teratogenicity No applicable toxicity data. No known significant effects or critical hazards. STOT-single exposure No applicable toxicity data. No known significant effects or critical hazards. STOT-repeated exposure No applicable toxicity data. No known significant effects or critical hazards. Aspiration hazard No applicable toxicity data. No known significant effects or critical hazards. Other information No applicable toxicity data. No known significant effects or critical hazards.
SECTION 12: Ecological information 12.1. Toxicity Cyclohexanol, 4,4'-(1-methylethylidene)bis-, polymer with 2-(chloromethyl)oxirane
Expected to be toxic to aquatic organisms.
12.2. Persistence and degradability Cyclohexanol, 4,4'-(1-methylethylidene)bis-, polymer with 2-(chloromethyl)oxirane
Expected to be not readily biodegradable. 12.3. Bioaccumulative potential Cyclohexanol, 4,4'-(1-methylethylidene)bis-, polymer with 2-(chloromethyl)oxirane
Not expected to bio-accumulate. 12.4. Mobility in soil Cyclohexanol, 4,4'-(1-methylethylidene)bis-, polymer with 2-(chloromethyl)oxirane
No data available. 12.5. Results of PBT and vPvB assessment Cyclohexanol, 4,4'-(1-methylethylidene)bis-, polymer with 2-(chloromethyl)oxirane
No data available. 12.6. Other adverse effects Cyclohexanol, 4,4'-(1-methylethylidene)bis-, polymer with 2-(chloromethyl)oxirane
No known adverse effects.
SECTION 13: Disposal considerations 13.1. Waste treatment methods Methods of disposal : The generation of waste should be avoided or minimized
wherever possible. Empty containers or liners may retain some product residues. This material and its container
must be disposed of in a safe way. Dispose of surplus and non-recyclable products via a licensed waste disposal contractor. Disposal of this product, solutions and any
by-products should at all times comply with the requirements of environmental protection and waste disposal legislation and any regional local authority
requirements. Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers. Hazardous waste : The classification of the product may meet the criteria for hazardous waste.
SECTION 14: Transport information
By Land ADR/RID : Not restricted
By sea IMDG : Not restricted
By Air ICAO/IATA : Not restricted
Regulatory 14.1. UN 14.2. UN proper shipping name 14.3. Transport 14.4.
information number hazard class(es) Packing
ADR group
3082 ENVIRONMENTALLY 9 III
HAZARDOUS SUBSTANCE,
LIQUID, N.O.S.
(EPOXIDE DERIVATIVES)
RID 3082 ENVIRONMENTALLY 9 III
HAZARDOUS SUBSTANCE,
LIQUID, N.O.S.
(EPOXIDE DERIVATIVES)
ICAO/IATA 3082 ENVIRONMENTALLY 9 III
HAZARDOUS SUBSTANCE,
LIQUID, N.O.S.
(EPOXIDE DERIVATIVES)
IMO/IMDG 3082 ENVIRONMENTALLY 9 III
HAZARDOUS SUBSTANCE,
LIQUID, N.O.S.
(EPOXIDE DERIVATIVES)
14.6. Special precautions for user Not applicable. 14.7. Transport in bulk according to Annex II of MARPOL73/78 and the IBC Code Not applicable.
SECTION 15: Regulatory information 15.1. Safety, health and environmental regulations/legislation specific for the
substance or mixture EU regulations
SEVESO Directive 96/82/EC : Ingredient name Listed Cyclohexanol, No. 4,4'-(1-methylethylidene)bis-,
polymer with
2-(chloromethyl)oxirane
Biocides - Annex I to Directive : Not listed 98/8/EC
Prior Informed Consent. List of : None required. chemicals subject to the
international PIC procedure
(Part I, II, III)
Integrated pollution prevention : Not listed and control list (IPPC) - Air
Integrated pollution prevention : Not listed and control list (IPPC) – Water
National regulations
Germany
Hazard class for water : WGK 2, Appendix No. 3 15.2. Chemical Safety Assessment
Chemical Safety Assessment not applicable.
SECTION 16: Other information Full text of abbreviated H : H317 - May cause an allergic skin reaction. statements H411 - Toxic to aquatic life with long lasting effects.
Full text of classifications : SKIN SENSITIZATION Category 1 - H317 (CLP) AQUATIC TOXICITY (CHRONIC) Category 2 - H411
Full text of R-Phrases : R43- May cause sensitization by skin contact.
R51/53- Toxic to aquatic organisms.
Conforms to Regulation (EC) No. 1907/2006 (REACH), Annex II
History Date of printing : 23.03.2016 Date of issue/ Date of revision : 23.03.2016 Date of previous issue : First Issue Version : 1.0
Notice to reader The information provided herein was believed by Eli-Chem Resins U.K Ltd ( “ Eli-Chem “ ) to be accurate at the
time of preparation or prepared from sources believed to be reliable, but it is the responsibility of the user to
investigate and understand other pertinent sources of information, to comply with all laws and procedures
applicable to the safe handling and use of the product and to determine the suitability of the product for its
intended use. All products supplied by Eli-Chem are subject to our terms and conditions of sale. Eli-Chem
MAKES NO WARRANTY, EXPRESSED OR IMPLIED, CONCERNING THE PRODUCT OR THE MERCHANTABILITY OR
FITNESS THEREOF FOR ANY PURPOSE OR CONCERNING THE ACCURACY OF ANY INFORMATION PROVIDED BY
Eli-Chem, except that the product shall conform to Eli-Chem's Technical Specifications. Nothing contained
herein constitutes an offer for the sale of any product.
Page 1 of 6
SAFETY DATA SHEET
totalCAST HARDENER
Compilation date: 20.09.2016
Section 1: Identification of the substance/mixture and of the company/undertaking
1.1. Product identifier
Product name: Total Cast FR66A Hardener Component 1.2. Relevant identified uses of the substance or mixture and uses advised against 1.3. Details of the supplier of the safety data sheet
Company name: Eli-Chem Resins U.K Ltd, Astra House, Cranleigh, Surrey GU6 8RZ, United Kingdom
Tel: +44 (0) 1483 26 66 36 Fax: +44 (0) 1483 26 66 50 Email: [email protected]
1.4. Emergency telephone number Emergency tel: +44 (0) 1483 26 66 36
Section 2: Hazards identification
2.1 Classification of the substance or mixture
Classification under CHIP: Sens.: R43 Classification under CLP: Eye Irrit. 2: H319; Skin Irrit. 2: H315; Skin Sens. 1: H317 Most important adverse effects: May cause sensitisation by skin contact.
2.2. Label elements Label Elements under CLP: Hazard statements: H315: Causes skin irritation. H317: May cause an allergic skin reaction. H319: Causes serious eye irritation. Signal words: Warning
Hazard pictograms: GHS07: Exclamation mark GHS09: Environmental
Precautionary statements: P264: Wash hands thoroughly after handling.
P280: Wear protective gloves/protective clothing/eye protection/face protection. P305+351+338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P321: Specific treatment (see instructions on this label). P332+313: If skin irritation occurs: Get medical attention. P362: Take off contaminated clothing and wash before reuse.
Label elements under CHIP: Hazard symbols: Irritant.
Page 2 of 6
Risk phrases: R43: May cause sensitisation by contact. Safety phrases: S24: Avoid contact with skin. S37: Wear suitable gloves.
2.3. Other hazards PBT: This substance is not identified as a PBT substance.
Section 3: Composition/information on ingredients
3.2. Mixtures Hazardous ingredients: MODIFIED AMINE MIXTURE
EINECS CAS CHIP Classification CLP Classification Percent
- 135108-88-2 Xi: R20/21/22/34/36/37/38; Sens.: R43/52/53
H315/317/319; Aquatic Chronic 3: H412
100%
Section 4: First aid measures
4.1. Description of first aid measures
Eye Contact: In cases of contact, immediately flush eyes with plenty of water for at least 15 minutes. Get medical attention if irritation occurs.
Skin Contact: Wash skin thoroughly with soap and water or use recognized skin cleanser. Wash clothing before reuse. Thoroughly clean shoes before reuse. Get medical attention immediately.
Inhalation: If inhaled, remove to fresh air. Get medical attention if symptoms appear. Ingestion: Do not induce vomiting unless directed to do so by medical personnel. Never
give anything by mouth to an unconscious person. If large quantities of this material are swallowed, call a physician immediately.
Notes to Physician: No specific treatment, treat symptomatically. 4.2. Most important symptoms and effects, both acute and delayed Skin contact: There may be irritation and redness at the site of contact. Eye contact: There may be irritation and redness. The eyes may water profusely. Ingestion: There may be soreness and redness of the mouth and throat. Nausea and
stomach pain may occur. Inhalation: Exposure may cause coughing or wheezing. Delayed/immediate effects: Delayed effects can be expected after short-term exposure. 4.3. Indication of any immediate medical attention and special treatment needed Immediate / special treatment: Not applicable.
Section 5: Fire-fighting measures
Flammability of the Product: Combustible at high temperatures Auto-ignition Temperature: The lowest known value is 336.9oC (638.4oF) (Triethylenetetramine). Flash Points: The lowest known value is Closed cup: 98.9oC (210oF). Open cup: 97.9oC
(208oF). (Cleveland). (Diethylenetriamine).
Page 3 of 6
Flammable Limits: Not available Products of Combustion: These products are carbon oxides (CO, CO2), nitrogen oxides (NO, NO2…). Fire Hazards in Presence of Various Substances: Slightly flammable to flammable in presence of open flames, sparks and
static discharge, of heat. Explosion Hazards in Presence of Various Substances: None identified Fire Fighting Media and Instructions: In case of fire, use water spray (fog), foam, dry chemical, or CO2. Special protective Equipment for fire-fighters: Fire-fighters should wear positive pressure self-contained breathing
apparatus (SCBA) and full turnout gear. Special Remarks on Fire Hazards: When heated to decomposition, it emits toxics fumes. (Diethylenetriamine) Special Remarks on Explosion Hazards: No additional remark.
Section 6: Accidental release measures
6.1. Personal precautions, protective equipment and emergency procedures Personal precautions: Do not attempt to take action without suitable protective clothing – see
section 8 of SDS. Turn leaking containers leak-side up to prevent the escape of liquid.
6.2. Environmental precautions Environmental precautions: Do not discharge into drains or rivers. Contain the spillage using bunding. 6.3. Methods and material for containment and cleaning up
Clean-up procedures: Minimize contact of spilled material with soils to prevent runoff to surface waterways. See Section 13 for Waste Disposal Information. If emergency personnel are unavailable, contain spilled material. For small spills add absorbent (soil may be used in the absence of other suitable materials) scoop up material and place in a sealed, liquid-proof container for disposal. For large spills like spilled material or otherwise contain material to ensure runoff does not reach a waterway. Place spilled material in an appropriate container for disposal.
6.4. Reference to other sections Reference to other sections: Refer to section 8 of SDS.
Section 7: Handling and storage
7.1. Precautions for safe handling
Handling requirements: Do not ingest. Avoid contact with eyes, skin and clothing. Wash thoroughly after handling. Use suitable protective equipment (Section 8).
7.2. Conditions for safe storage, including any incompatibilities Storage conditions: Store in cool, well ventilated area. Keep container tightly closed.
Section 8: Exposure controls/personal protection
Exposure Controls Occupational exposure Controls: Provide exhaust ventilation or other engineering controls to keep the
airborne concentrations of vapours below their respective occupational exposure limits. Ensure that eyewash stations and safety showers are proximal to the work-station location.
Page 4 of 6
Respiratory protection: A respirator is not needed under normal and intended conditions of product use. Wear appropriate respirator when ventilation is inadequate.
Hand protection: Rubber gloves. Neoprene gloves. Eye protection: Safety glasses. Goggles, face shield, or other full-face protection if potential
exists for direct exposure to aerosols or splashes. Skin protection: Additional body garments should be used based upon the task being
performed (e.g. sleevelets, apron, gauntlets, disposable suits) to avoid exposed skin surfaces. Appropriate techniques should be used to remove potentially contaminated clothing.
Personal protective Equipment (Pictograms): Occupational exposure limits: n/a
Section 9: Physical and chemical properties
9.1. Information on basic physical and chemical properties State: Liquid Colour: Clear transparent Odour: Mild odour Flash pointoC: 104 9.2. Other information Other information: Not applicable.
Section 10: Stability and reactivity
Stability and Reactivity: The product is stable Conditions of Instability: Heat and cold below 0oC Incompatibility with Various Substances: Reactive with acids. Slightly reactive to reactive with OXIDIZING AGENTS. Hazardous Decomposition Products: These products are carbon oxides (CO, CO2), nitrogen oxides (NO, NO2…) Hazardous Polymerization: Will not occur under normal transport or storage conditions.
Section 11: Toxicological information
Potential Acute Health Effects Inhalation: Harmful by inhalation. Ingestion: Ingestion causes gastrointestinal irritation and diarrhea. Harmful if
swallowed Skin contact: Irritating to skin. May cause sensitisation by skin contact. Eye contact: Irritating to eyes / causes burns. Potential Chronic Health Effects Ingredient Name Carcinogenic Mutagenic Effects Developmental Impairs fertility Effects toxicity Toxic to reproductive Health Categ. 3
Page 5 of 6
Over-exposure signs/symptoms Target Organs: Contains material, which causes damage to the following organs: lungs,
kidneys, liver, gastrointestinal tract, cardiovascular system, skin, eye, lens or cornea.
Other adverse effects: None identified.
Section 12: Ecological information
Ecotoxicity Data Ingredient Name Species Period Result BOD and COD: Not available. Biodegradable/OECD: Not available. Mobility: Readily absorbed into soil. Products of Degradation: These products are carbon oxides (CO, CO2) and water, nitrogen oxides (NO,
NO2…). Toxicity of the Products of Biodegradation: The products of degradation are less toxic than the product itself. Toxic to
aquatic organisms. Special Remarks on the Products of Biodegradation: Not available
Section 13: Disposal considerations
13.1. Waste treatment methods Disposal operations: Transfer to a suitable container and arrange for collection by specialised
disposal company. NB: The user’s attention is drawn to the possible existence of regional or national
regulations regarding disposal.
Section 14: Transport information
Regulatory Information
UN Number Proper shipping name
Class Packing Group
Label Additional information
ADR/RID/SABS 0228 Class
Not regulated
IMDG Class Not regulated
IATA-DGR Class Not regulated
Section 15: Regulatory information
Label elements under CHIP: Hazard symbol(s): H411 Aquatic Chronic Risk phrases: R20/21/22 – Harmful by inhalation, in contact with skin and if swallowed.
Page 6 of 6
R34 – Causes burns. R43 – May cause sensitisation by skin contact.
R50/53 – Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
R62 – Possible risk of impaired fertility. R63 – Possible risk of harm to the unborn child.. Safety phrases: S25 – Avoid contact with eyes.
S26 – In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. S36/37/39 – Wear suitable protective clothing, gloves and eye/face protection.
Contains: Amines Product Use: Classification and labelling have been performed according to EU directives
67/548/EEC, 1999/45/EC including amended and the intended use. - Industrial applications.
Section 16: Other information
Other information: This safety data sheet is prepared in accordance with Commission Regulation
(EU) No 453/2010. *indicates text in the SDS which has changed since the last revision. Phrases used in s.2 and 3: H312: Harmful in contact with skin. H314: Causes severe skin burns and eye damage. H315: Causes skin irritation. H317: May cause an allergic skin reaction. H319: Causes serious eye irritation. H411: Harmful to aquatic life with long lasting effects. R21: Harmful in contact with skin. R34: Causes burns. R43: May cause sensitisation by skin contact.
R52/53: Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
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