Safety Data Sheet ( Compliant to CLP/GHS Regulation 1272/2008/EEC )

totalCAST Clear Artwork Resin

Revision Date 23-MAR-2016

SECTION 1: Identification of the substance and the company 1.1. Product identifier

Product name totalCAST

Substance name Hybrid Polymeric Blend

CAS number 30583-72-3 ( 55-60% ). Not yet classified ( >40% )

Product Type Polymer Resin

1.2. Relevant identified uses of the substance or mixture and uses advised against

Product use Artwork Coating and Casting

1.3. Details of the supplier of the safety data sheet

Manufacturer / Importer / Supplier : Eli-Chem Resins U.K Ltd Astra House, The Common Cranleigh, Surrey, GU6 8RZ United Kingdom

Contact : sales@elichem.co.uk

Telephone : General Information:

+44 1483 26 66 36 www.elichem.co.uk

1.4. Emergency telephone number +44 (0) 1483 26 66 36

SECTION 2: Hazards identification 2.1. Classification of the substance or mixture Classification according to Regulation (EC) No. 1272/2008 [CLP/GHS] Hazard Class Category Hazard statement Code(s) Skin Sens. Category 1 H317 Aquatic Chronic Category 2 H411 Classification according to Directive 67/548/EEC (DSD) The product is classified as dangerous according to Directive 67/548/EEC and its amendments. Classification : N, R51/53

R43 Adverse effects May cause an allergic skin reaction. Toxic to aquatic life.

See Section 16 for the full text of the H statements and R phrases declared above. 2.2. Label

elements

Hazard pictograms :

Signal word : Warning

Hazard statements : May cause an allergic skin reaction.

Precautionary statements

Prevention Wear protective gloves. Avoid release to the environment. Avoid breathing

vapor. Contaminated work clothing should not be allowed out of the

workplace.

Response Collect spillage. IF ON SKIN: Wash with plenty of soap and water. If

skin irritation or rash occurs, seek medical advice/attention. Wash

contaminated clothing before reuse.

Disposal Dispose of contents and container in accordance with all local, regional,

national and international regulations. 2.3. Other hazards

The data show that the properties of the substance do not meet the specific criteria detailed in

Annex XIII and, consequently, that the substance is not considered a PBT/vPvB.

SECTION 3: Composition/information on ingredients Substance/mixture : Mono-constituent polymeric substance

Ingredient name REG # /CAS Classification % #/EC #

Symbol(s)/Hazard R-Phrases

Class and /Hazard

Category Code(s) statement

Code(s)

Cyclohexanol, Xi; N; Xi; R43 100 4,4'-(1-methylethylidene)bis-, polymer 30583-72-3/ N; R51/53

with 2-(chloromethyl)oxirane

Skin Sens. 1 H317

Aquatic Chronic 2 H411

See Section 16 for the full text of the H statements and R phrases declared above.

SECTION 4: First aid measures 4.1. Description of first aid measures

First aid measures

Inhalation : Move exposed person to fresh air. Keep person warm and

at rest. If not breathing, if breathing is irregular or if

respiratory arrest occurs, provide artificial respiration or

oxygen by trained personnel. It may be dangerous to the

person providing aid to give mouth-to-mouth resuscitation.

Get medical attention if adverse health effects persist or

are severe. If unconscious, place in recovery position and

get medical attention immediately. Maintain an open

airway. Loosen tight clothing such as a collar, tie, belt or waistband.

Ingestion : Wash out mouth with water. Remove dentures if any. Move exposed person to fresh air. Keep person warm and at rest.

If material has been swallowed and the exposed person is

conscious, give small quantities of water to drink. Stop if

the exposed person feels sick as vomiting may be

dangerous.Do not induce vomiting unless directed to do so

by medical personnel. If vomiting occurs, the head should

be kept low so that vomit does not enter the lungs. Get

medical attention if adverse health effects persist or are

severe. Never give anything by mouth to an unconscious person. If

unconscious, place in recovery position and get medical

attention immediately. Maintain an open airway. Loosen

tight clothing such as a collar, tie, belt or waistband.

Skin contact : Flush contaminated skin with plenty of water. Remove

contaminated clothing and shoes. Wash contaminated

clothing thoroughly with water before removing it, or wear

gloves. Continue to rinse for at least 10 minutes. Get

medical attention. In the event of any complaints or

symptoms, avoid further exposure. Wash clothing before

reuse. Clean shoes thoroughly before reuse.

Eye contact : Immediately flush eyes with plenty of water, ccasionally

lifting the upper and lower eyelids. Check for and remove

any contact lenses. Continue to rinse for at least 10min. Get

medical attention if irritation occurs. 4.2. Most important symptoms and effects, both acute and delayed Over-exposure signs/symptoms Inhalation : No known significant effects or critical hazards. Ingestion : No known significant effects or critical hazards. Skin : Once sensitized, a severe allergic reaction may occur when

subsequently exposed to very low levels. Eyes : No known significant effects or critical hazards.

See section 11 for more detailed information on health effects and symptoms. 4.3. Indication

of immediate medical attention and special treatment needed

Notes to physician : No specific treatment. Treat symptomatically. Contact poison treatment specialist

immediately if large quantities have been ingested or

inhaled. Protection of first aid : No action shall be taken involving any personal risk or personnel without suitable training. It may be dangerous to the person

providing aid to give mouth-to-mouth resuscitation. Wash contaminated clothing thoroughly with water.

SECTION 5: Fire-fighting measures 5.1. Extinguishing media Suitable : Use water spray, fog or foam. Not suitable : Do not use water jet. 5.2. Special hazards arising from the substance or mixture Hazards from the substance or : In a fire or if heated, a pressure increase will occur and the mixture container may burst. This material is toxic to aquatic life

with long lasting effects. Fire water contaminated with this material must be contained and prevented from being discharged to any waterway, sewer or drain.

Hazardous thermal : No specific data. decomposition products 5.3. Special protective actions for fire-fighters Special precautions for : Promptly isolate the scene by removing all persons from fire-fighters the vicinity of the incident if there is a fire. No action shall be

taken involving any personal risk or without suitable training.

Special protective equipment : Fire-fighters should wear appropriate protective equipment for fire-fighters and self-contained breathing apparatus (SCBA) with a full

face-piece operated in positive pressure mode.

SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures No action shall be taken involving any personal risk or without suitable training. Evacuate surrounding

areas. Keep unnecessary and unprotected personnel from entering. Do not touch or walk through

spilled material. Provide adequate ventilation. Wear appropriate respirator when ventilation is

inadequate. Put on appropriate personal protective equipment (see section 8). Avoid breathing vapor

or mist. 6.2. Environmental precautions Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers.

Inform the relevant authorities if the product has caused environmental pollution (sewers, waterways,

soil or air). Water polluting material. May be harmful to the environment if released in large

quantities.

6.3. Methods and material for containment and cleaning up Small spill : Move containers from spill area. Dispose of via a licensed

waste disposal contractor. Stop leak if without risk. Dilute with water and mop up if water-soluble. Alternatively, or if water-insoluble, absorb with an inert dry material and place in an appropriate waste disposal container.

Large spill : Move containers from spill area. Approach release from

upwind. Prevent entry into sewers, water courses, basements or confined areas. Dispose of via a licensed waste disposal contractor. Note: see section 1 for emergency contact information and section 13 for waste disposal. Stop leak if without risk. Wash spillages into an effluent treatment plant or proceed as follows. Contain

and collect spillage with non-combustible, absorbent

material e.g. sand, earth, vermiculite or diatomaceous

earth and place in container for disposal according to

local regulations (see section 13). Contaminated

absorbent material may pose the same hazard as the

spilled product.

SECTION 7: Handling and storage 7.1. Precautions for safe handling Put on appropriate personal protective equipment (see section 8). Eating, drinking and smoking should

be prohibited in areas where this material is handled, stored and processed. Workers should wash

hands and face before eating, drinking and smoking. Persons with a history of skin sensitization

problems should not be employed in any process in which this product is used. Do not get in eyes or on

skin or clothing. Do not ingest. Avoid breathing vapor or mist. Avoid release to the environment. Keep

in the original container or an approved alternative made from a compatible material, kept tightly

closed when not in use. Empty containers retain product residue and can be hazardous. Do not reuse

container. 7.2. Conditions for safe storage, including any incompatibilities Store in accordance with local regulations. Store in original container protected from direct sunlight in

a dry, cool and well-ventilated area, away from incompatible materials (see section 10) and food and

drink. Keep container tightly closed and sealed until ready for use. Containers that have been opened

must be carefully resealed and kept upright to prevent leakage. Do not store in unlabeled containers.

Use appropriate containment to avoid environmental contamination.

Packaging materials

Recommended : Use original container.

7.3. Specific end use(s) Not applicable.

SECTION 8: Exposure controls/personal protection 8.1. Control parameters Exposure limit values Ingredient name Occupational exposure limits

Europe No exposure limit value known.

Sweden No exposure limit value known.

Denmark No exposure limit value known.

Norway No exposure limit value known.

France No exposure limit value known.

Netherlands No exposure limit value known.

Germany No exposure limit value known.

Finland No exposure limit value known.

United Kingdom (UK) No exposure limit value known.

Austria No exposure limit value known.

Switzerland No exposure limit value known.

Belgium No exposure limit value known.

Spain No exposure limit value known.

Turkey No exposure limit value known.

Czech Republic No exposure limit value known.

Ireland No exposure limit value known.

Italy No exposure limit value known.

Estonia No exposure limit value known.

Lithuania No exposure limit value known.

Slovakia No exposure limit value known.

Hungary No exposure limit value known.

Poland No exposure limit value known.

Slovenia No exposure limit value known.

Latvia No exposure limit value known.

Greece No exposure limit value known.

Portugal No exposure limit value known.

Bulgaria No exposure limit value known.

Romania No exposure limit value known.

8.2. Exposure controls Recommended monitoring : If this product contains ingredients with exposure limits, procedures personal atmosphere or biological monitoring

may be required to determine the effectiveness of the ventilation or other control measures and/or the necessity

to use respiratory protective equipment. Reference should

be made to European Standard EN 689 for methods for the

assessment of exposure by inhalation to chemical agents

and national guidance documents for methods for the

determination of hazardous substances. If this product

contains ingredients with exposure limits, personal,

workplace atmosphere or biological monitoring may be required to determine the effectiveness of the ventilation

or other control measures and/or the necessity to use

respiratory protective equipment.

Occupational exposure : No special ventilation requirements. Good general controls ventilation should be sufficient to control worker exposure

to airborne contaminants. If this product contains ingredients with exposure limits, use process enclosures,

local exhaust ventilation or other engineering controls to

keep worker exposure below any recommended or statutory

limits. Hygiene measures : Wash hands, forearms and face thoroughly after handling

chemical products, before eating, smoking and using the

lavatory and at the end of the working period. Appropriate

techniques should be used to remove potentially

contaminated clothing. Wash contaminated clothing before

reusing. Ensure that eyewash stations and safety showers are

close to the workstation location.

Respiratory protection : Use a properly fitted, air-purifying or air-fed respirator complying with an approved standard if a risk assessment

indicates this is necessary. Respirator selection must be

based on known or anticipated exposure levels, the hazards

of the product and the safe working limits of the selected

respirator. Hand protection : Chemical-resistant, impervious gloves complying with an

approved standard should be worn at all times when handling chemical products if a risk assessment indicates

this is necessary. Eye protection : Safety eyewear complying with an approved standard

should be used when a risk assessment indicates this is

necessary to avoid exposure to liquid splashes, mists, gases

or dusts. Skin protection : Personal protective equipment for the body should be

selected based on the task being performed and the risks

involved and should be approved by a specialist before

handling this product.

SECTION 9: Physical and chemical properties

9.1. Information on basic physical and chemical properties

Appearance

Physical state : Liquid

Colour : Optically Clear / Colourless

Odour : Odorless

Odour threshold : Not determined

pH : Not determined

Melting Point : Less than 10°C(50 °F)

Initial boiling point and boiling : Not determined

range

Flash point : 115°C (239 °F) Pensky-Martens Closed Cup ASTM D 93

Evaporation rate : Not determined

Vapor pressure : Not determined

Vapor density : Greater than 1

Relative density : Not determined

Solubility : Negligible

Partition coefficient: : Not determined

n-octanol/water

Auto-ignition temperature : Not determined

Decomposition temperature : Not determined

Viscosity : Kinematic-Not determined

Explosive properties : Dynamic- 1.8 - 2.5 Pa·s @25 °C (77 °F)

Not determined

Oxidising properties : Not determined

9.2. Other information Not applicable.

SECTION 10: Stability and reactivity

10.1. Reactivity

Reacts with strong oxidising agents. Reacts exothermically with bases (eg caustic soda),

ammonia, primary and secondary amines, alcohols, water and acids. Polymerises in contact

with caustic soda. Polymerises exothermically with amines, mercaptans and Lewis acids at

ambient temperature and above.

10.2. Chemical stability

The product is stable.

10.3. Possibility of hazardous reactions

Under normal conditions of storage and use, hazardous reactions will not occur.

10.4. Conditions to avoid

Caustic soda (sodium hydroxide) can induce vigorous polymerisation at temperatures around 200

°C. 10.5. Incompatible materials Reactive or incompatible with the following materials: sodium hydroxide, strong oxidizing agents.

10.6. Hazardous decomposition products Under normal conditions of storage and use, hazardous decomposition products should not be

produced.

SECTION 11: Toxicological information 11.1. Information on toxicological effects Cyclohexanol, 4,4'-(1-methylethylidene)bis-, polymer with 2-(chloromethyl)oxirane Acute toxicity

Oral No applicable toxicity data. No known significant effects or critical hazards.

Dermal No applicable toxicity data. No known significant effects or critical hazards.

Inhalation No applicable toxicity data. No known significant effects or critical hazards.

Other routes No applicable toxicity data. No known significant effects or critical hazards.

Skin corrosion/irritation No applicable toxicity data. No known significant effects or critical hazards. Serious eye damage/irritation No applicable toxicity data. No known significant effects or critical hazards. Skin sensitization Expected to be a skin sensitiser. Respiratory sensitization No applicable toxicity data. No known significant effects or critical hazards. Germ cell mutagenicity No applicable toxicity data. No known significant effects or critical hazards. Carcinogenicity No applicable toxicity data. No known significant effects or critical hazards. Reproductive toxicity No applicable toxicity data. No known significant effects or critical hazards.

Developmental / Teratogenicity No applicable toxicity data. No known significant effects or critical hazards. STOT-single exposure No applicable toxicity data. No known significant effects or critical hazards. STOT-repeated exposure No applicable toxicity data. No known significant effects or critical hazards. Aspiration hazard No applicable toxicity data. No known significant effects or critical hazards. Other information No applicable toxicity data. No known significant effects or critical hazards.

SECTION 12: Ecological information 12.1. Toxicity Cyclohexanol, 4,4'-(1-methylethylidene)bis-, polymer with 2-(chloromethyl)oxirane

Expected to be toxic to aquatic organisms.

12.2. Persistence and degradability Cyclohexanol, 4,4'-(1-methylethylidene)bis-, polymer with 2-(chloromethyl)oxirane

Expected to be not readily biodegradable. 12.3. Bioaccumulative potential Cyclohexanol, 4,4'-(1-methylethylidene)bis-, polymer with 2-(chloromethyl)oxirane

Not expected to bio-accumulate. 12.4. Mobility in soil Cyclohexanol, 4,4'-(1-methylethylidene)bis-, polymer with 2-(chloromethyl)oxirane

No data available. 12.5. Results of PBT and vPvB assessment Cyclohexanol, 4,4'-(1-methylethylidene)bis-, polymer with 2-(chloromethyl)oxirane

No data available. 12.6. Other adverse effects Cyclohexanol, 4,4'-(1-methylethylidene)bis-, polymer with 2-(chloromethyl)oxirane

No known adverse effects.

SECTION 13: Disposal considerations 13.1. Waste treatment methods Methods of disposal : The generation of waste should be avoided or minimized

wherever possible. Empty containers or liners may retain some product residues. This material and its container

must be disposed of in a safe way. Dispose of surplus and non-recyclable products via a licensed waste disposal contractor. Disposal of this product, solutions and any

by-products should at all times comply with the requirements of environmental protection and waste disposal legislation and any regional local authority

requirements. Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers. Hazardous waste : The classification of the product may meet the criteria for hazardous waste.

SECTION 14: Transport information

By Land ADR/RID : Not restricted

By sea IMDG : Not restricted

By Air ICAO/IATA : Not restricted

Regulatory 14.1. UN 14.2. UN proper shipping name 14.3. Transport 14.4.

information number hazard class(es) Packing

ADR group

3082 ENVIRONMENTALLY 9 III

HAZARDOUS SUBSTANCE,

LIQUID, N.O.S.

(EPOXIDE DERIVATIVES)

RID 3082 ENVIRONMENTALLY 9 III

HAZARDOUS SUBSTANCE,

LIQUID, N.O.S.

(EPOXIDE DERIVATIVES)

ICAO/IATA 3082 ENVIRONMENTALLY 9 III

HAZARDOUS SUBSTANCE,

LIQUID, N.O.S.

(EPOXIDE DERIVATIVES)

IMO/IMDG 3082 ENVIRONMENTALLY 9 III

HAZARDOUS SUBSTANCE,

LIQUID, N.O.S.

(EPOXIDE DERIVATIVES)

14.6. Special precautions for user Not applicable. 14.7. Transport in bulk according to Annex II of MARPOL73/78 and the IBC Code Not applicable.

SECTION 15: Regulatory information 15.1. Safety, health and environmental regulations/legislation specific for the

substance or mixture EU regulations

SEVESO Directive 96/82/EC : Ingredient name Listed Cyclohexanol, No. 4,4'-(1-methylethylidene)bis-,

polymer with

2-(chloromethyl)oxirane

Biocides - Annex I to Directive : Not listed 98/8/EC

Prior Informed Consent. List of : None required. chemicals subject to the

international PIC procedure

(Part I, II, III)

Integrated pollution prevention : Not listed and control list (IPPC) - Air

Integrated pollution prevention : Not listed and control list (IPPC) – Water

National regulations

Germany

Hazard class for water : WGK 2, Appendix No. 3 15.2. Chemical Safety Assessment

Chemical Safety Assessment not applicable.

SECTION 16: Other information Full text of abbreviated H : H317 - May cause an allergic skin reaction. statements H411 - Toxic to aquatic life with long lasting effects.

Full text of classifications : SKIN SENSITIZATION Category 1 - H317 (CLP) AQUATIC TOXICITY (CHRONIC) Category 2 - H411

Full text of R-Phrases : R43- May cause sensitization by skin contact.

R51/53- Toxic to aquatic organisms.

Conforms to Regulation (EC) No. 1907/2006 (REACH), Annex II

History Date of printing : 23.03.2016 Date of issue/ Date of revision : 23.03.2016 Date of previous issue : First Issue Version : 1.0

Notice to reader The information provided herein was believed by Eli-Chem Resins U.K Ltd ( “ Eli-Chem “ ) to be accurate at the

time of preparation or prepared from sources believed to be reliable, but it is the responsibility of the user to

investigate and understand other pertinent sources of information, to comply with all laws and procedures

applicable to the safe handling and use of the product and to determine the suitability of the product for its

intended use. All products supplied by Eli-Chem are subject to our terms and conditions of sale. Eli-Chem

MAKES NO WARRANTY, EXPRESSED OR IMPLIED, CONCERNING THE PRODUCT OR THE MERCHANTABILITY OR

FITNESS THEREOF FOR ANY PURPOSE OR CONCERNING THE ACCURACY OF ANY INFORMATION PROVIDED BY

Eli-Chem, except that the product shall conform to Eli-Chem's Technical Specifications. Nothing contained

herein constitutes an offer for the sale of any product.

Page 1 of 6

SAFETY DATA SHEET

totalCAST HARDENER

Compilation date: 20.09.2016

Section 1: Identification of the substance/mixture and of the company/undertaking

1.1. Product identifier

Product name: Total Cast FR66A Hardener Component 1.2. Relevant identified uses of the substance or mixture and uses advised against 1.3. Details of the supplier of the safety data sheet

Company name: Eli-Chem Resins U.K Ltd, Astra House, Cranleigh, Surrey GU6 8RZ, United Kingdom

Tel: +44 (0) 1483 26 66 36 Fax: +44 (0) 1483 26 66 50 Email: sales@elichem.co.uk

1.4. Emergency telephone number Emergency tel: +44 (0) 1483 26 66 36

Section 2: Hazards identification

2.1 Classification of the substance or mixture

Classification under CHIP: Sens.: R43 Classification under CLP: Eye Irrit. 2: H319; Skin Irrit. 2: H315; Skin Sens. 1: H317 Most important adverse effects: May cause sensitisation by skin contact.

2.2. Label elements Label Elements under CLP: Hazard statements: H315: Causes skin irritation. H317: May cause an allergic skin reaction. H319: Causes serious eye irritation. Signal words: Warning

Hazard pictograms: GHS07: Exclamation mark GHS09: Environmental

Precautionary statements: P264: Wash hands thoroughly after handling.

P280: Wear protective gloves/protective clothing/eye protection/face protection. P305+351+338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P321: Specific treatment (see instructions on this label). P332+313: If skin irritation occurs: Get medical attention. P362: Take off contaminated clothing and wash before reuse.

Label elements under CHIP: Hazard symbols: Irritant.

Page 2 of 6

Risk phrases: R43: May cause sensitisation by contact. Safety phrases: S24: Avoid contact with skin. S37: Wear suitable gloves.

2.3. Other hazards PBT: This substance is not identified as a PBT substance.

Section 3: Composition/information on ingredients

3.2. Mixtures Hazardous ingredients: MODIFIED AMINE MIXTURE

EINECS CAS CHIP Classification CLP Classification Percent

- 135108-88-2 Xi: R20/21/22/34/36/37/38; Sens.: R43/52/53

H315/317/319; Aquatic Chronic 3: H412

100%

Section 4: First aid measures

4.1. Description of first aid measures

Eye Contact: In cases of contact, immediately flush eyes with plenty of water for at least 15 minutes. Get medical attention if irritation occurs.

Skin Contact: Wash skin thoroughly with soap and water or use recognized skin cleanser. Wash clothing before reuse. Thoroughly clean shoes before reuse. Get medical attention immediately.

Inhalation: If inhaled, remove to fresh air. Get medical attention if symptoms appear. Ingestion: Do not induce vomiting unless directed to do so by medical personnel. Never

give anything by mouth to an unconscious person. If large quantities of this material are swallowed, call a physician immediately.

Notes to Physician: No specific treatment, treat symptomatically. 4.2. Most important symptoms and effects, both acute and delayed Skin contact: There may be irritation and redness at the site of contact. Eye contact: There may be irritation and redness. The eyes may water profusely. Ingestion: There may be soreness and redness of the mouth and throat. Nausea and

stomach pain may occur. Inhalation: Exposure may cause coughing or wheezing. Delayed/immediate effects: Delayed effects can be expected after short-term exposure. 4.3. Indication of any immediate medical attention and special treatment needed Immediate / special treatment: Not applicable.

Section 5: Fire-fighting measures

Flammability of the Product: Combustible at high temperatures Auto-ignition Temperature: The lowest known value is 336.9oC (638.4oF) (Triethylenetetramine). Flash Points: The lowest known value is Closed cup: 98.9oC (210oF). Open cup: 97.9oC

(208oF). (Cleveland). (Diethylenetriamine).

Page 3 of 6

Flammable Limits: Not available Products of Combustion: These products are carbon oxides (CO, CO2), nitrogen oxides (NO, NO2…). Fire Hazards in Presence of Various Substances: Slightly flammable to flammable in presence of open flames, sparks and

static discharge, of heat. Explosion Hazards in Presence of Various Substances: None identified Fire Fighting Media and Instructions: In case of fire, use water spray (fog), foam, dry chemical, or CO2. Special protective Equipment for fire-fighters: Fire-fighters should wear positive pressure self-contained breathing

apparatus (SCBA) and full turnout gear. Special Remarks on Fire Hazards: When heated to decomposition, it emits toxics fumes. (Diethylenetriamine) Special Remarks on Explosion Hazards: No additional remark.

Section 6: Accidental release measures

6.1. Personal precautions, protective equipment and emergency procedures Personal precautions: Do not attempt to take action without suitable protective clothing – see

section 8 of SDS. Turn leaking containers leak-side up to prevent the escape of liquid.

6.2. Environmental precautions Environmental precautions: Do not discharge into drains or rivers. Contain the spillage using bunding. 6.3. Methods and material for containment and cleaning up

Clean-up procedures: Minimize contact of spilled material with soils to prevent runoff to surface waterways. See Section 13 for Waste Disposal Information. If emergency personnel are unavailable, contain spilled material. For small spills add absorbent (soil may be used in the absence of other suitable materials) scoop up material and place in a sealed, liquid-proof container for disposal. For large spills like spilled material or otherwise contain material to ensure runoff does not reach a waterway. Place spilled material in an appropriate container for disposal.

6.4. Reference to other sections Reference to other sections: Refer to section 8 of SDS.

Section 7: Handling and storage

7.1. Precautions for safe handling

Handling requirements: Do not ingest. Avoid contact with eyes, skin and clothing. Wash thoroughly after handling. Use suitable protective equipment (Section 8).

7.2. Conditions for safe storage, including any incompatibilities Storage conditions: Store in cool, well ventilated area. Keep container tightly closed.

Section 8: Exposure controls/personal protection

Exposure Controls Occupational exposure Controls: Provide exhaust ventilation or other engineering controls to keep the

airborne concentrations of vapours below their respective occupational exposure limits. Ensure that eyewash stations and safety showers are proximal to the work-station location.

Page 4 of 6

Respiratory protection: A respirator is not needed under normal and intended conditions of product use. Wear appropriate respirator when ventilation is inadequate.

Hand protection: Rubber gloves. Neoprene gloves. Eye protection: Safety glasses. Goggles, face shield, or other full-face protection if potential

exists for direct exposure to aerosols or splashes. Skin protection: Additional body garments should be used based upon the task being

performed (e.g. sleevelets, apron, gauntlets, disposable suits) to avoid exposed skin surfaces. Appropriate techniques should be used to remove potentially contaminated clothing.

Personal protective Equipment (Pictograms): Occupational exposure limits: n/a

Section 9: Physical and chemical properties

9.1. Information on basic physical and chemical properties State: Liquid Colour: Clear transparent Odour: Mild odour Flash pointoC: 104 9.2. Other information Other information: Not applicable.

Section 10: Stability and reactivity

Stability and Reactivity: The product is stable Conditions of Instability: Heat and cold below 0oC Incompatibility with Various Substances: Reactive with acids. Slightly reactive to reactive with OXIDIZING AGENTS. Hazardous Decomposition Products: These products are carbon oxides (CO, CO2), nitrogen oxides (NO, NO2…) Hazardous Polymerization: Will not occur under normal transport or storage conditions.

Section 11: Toxicological information

Potential Acute Health Effects Inhalation: Harmful by inhalation. Ingestion: Ingestion causes gastrointestinal irritation and diarrhea. Harmful if

swallowed Skin contact: Irritating to skin. May cause sensitisation by skin contact. Eye contact: Irritating to eyes / causes burns. Potential Chronic Health Effects Ingredient Name Carcinogenic Mutagenic Effects Developmental Impairs fertility Effects toxicity Toxic to reproductive Health Categ. 3

Page 5 of 6

Over-exposure signs/symptoms Target Organs: Contains material, which causes damage to the following organs: lungs,

kidneys, liver, gastrointestinal tract, cardiovascular system, skin, eye, lens or cornea.

Other adverse effects: None identified.

Section 12: Ecological information

Ecotoxicity Data Ingredient Name Species Period Result BOD and COD: Not available. Biodegradable/OECD: Not available. Mobility: Readily absorbed into soil. Products of Degradation: These products are carbon oxides (CO, CO2) and water, nitrogen oxides (NO,

NO2…). Toxicity of the Products of Biodegradation: The products of degradation are less toxic than the product itself. Toxic to

aquatic organisms. Special Remarks on the Products of Biodegradation: Not available

Section 13: Disposal considerations

13.1. Waste treatment methods Disposal operations: Transfer to a suitable container and arrange for collection by specialised

disposal company. NB: The user’s attention is drawn to the possible existence of regional or national

regulations regarding disposal.

Section 14: Transport information

Regulatory Information

UN Number Proper shipping name

Class Packing Group

Label Additional information

ADR/RID/SABS 0228 Class

Not regulated

IMDG Class Not regulated

IATA-DGR Class Not regulated

Section 15: Regulatory information

Label elements under CHIP: Hazard symbol(s): H411 Aquatic Chronic Risk phrases: R20/21/22 – Harmful by inhalation, in contact with skin and if swallowed.

Page 6 of 6

R34 – Causes burns. R43 – May cause sensitisation by skin contact.

R50/53 – Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.

R62 – Possible risk of impaired fertility. R63 – Possible risk of harm to the unborn child.. Safety phrases: S25 – Avoid contact with eyes.

S26 – In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. S36/37/39 – Wear suitable protective clothing, gloves and eye/face protection.

Contains: Amines Product Use: Classification and labelling have been performed according to EU directives

67/548/EEC, 1999/45/EC including amended and the intended use. - Industrial applications.

Section 16: Other information

Other information: This safety data sheet is prepared in accordance with Commission Regulation

(EU) No 453/2010. *indicates text in the SDS which has changed since the last revision. Phrases used in s.2 and 3: H312: Harmful in contact with skin. H314: Causes severe skin burns and eye damage. H315: Causes skin irritation. H317: May cause an allergic skin reaction. H319: Causes serious eye irritation. H411: Harmful to aquatic life with long lasting effects. R21: Harmful in contact with skin. R34: Causes burns. R43: May cause sensitisation by skin contact.

R52/53: Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment.

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