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FEEDING THE WORLD REDUCING OUR DEPENDENCE
ON FOSSIL FUELS
KEEPING PEOPLE AND
THE ENVIRONMENT SAFE
1 © E.I. du Pont de Nemours and Company
Søren Flensborg Iversen Salgs – og Udviklingsansvarlig
DuPont Performance Polymers
En ny æra af plastmaterialer
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DuPont Segments,
Businesses and Core Markets
12/3/2014 DuPont Today 2014
DuPont Industrial Biosciences
Core Markets: Industrial Enzymes | BioBased Materials
DuPont Performance Chemicals Titanium Technologies | Chemicals &
Fluoroproducts
Core Markets: Industrials & Chemicals | Construction |
Specialties | Plastics | Transportation
DuPont Agriculture DuPont Pioneer | Crop Protection
Core Markets: Seeds | Agricultural Chemicals
DuPont Safety & Protection Protection Technologies | Building
Innovations | Sustainable Solutions
Core Markets: Industrial | Construction | Military & Law
Enforcement | Transportation | Consumer
DuPont Performance Materials Performance Polymers | Packaging &
Industrial Polymers
Core Markets: Transportation | Industrial | Packaging |
Electrical/Electronics
DuPont Nutrition & Health
Core Markets: Food & Nutrition Products
DuPont Electronics &
Communications
Core Markets: Photovoltaics | Consumer Electronics |
Advanced Printing | Displays
2
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DuPont Strategy
Building three world-leading, closely related strategic ‘pillars’:
Driving three critical cross-company ‘enablers’ to maximize results:
innovation, geographic expansion, productivity
Ag & Nutrition Seeds
Traits
Crop Protection
Specialty Food Ingredients
Bio-based Industrials
Biofuels
Biomaterials
Biochemicals
Enzymes
Advanced Materials
Electronic Materials
Protective Solutions
Alternative Energy
Advanced Polymers
Advanced Processes
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Use LCA techniques along the product development stages
© E.I. du Pont de Nemours and Company 5
Vision of the development of sustainable solutions
Low footprint Processing
Eco-Design Inclusive
Sustainability Renewable Materials
Enhance customers’ product performance,
improve sustainability and reduce total downstream system cost
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•Develop, manufacture and sell Performance Polymers derived from renewable resources
•Value Proposition: - Performance equal or better than fossil incumbent
- Significant footprint improvement
- 20% up to 100% by weight renewable content
- Cost / performance ratio
DuPont Renewably-Sourced Performance Polymers
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DuPont™ Performance Polymers Worldwide
• Products
– Zytel® Nylon and Zytel® HTN
– Zytel® RS Renewably Sourced Polyamides
– Delrin® Acetal
– Vespel® Polyimide
– Tynex® Filaments
– Rynite® PET
– Crastin® PBT
– Sorona ® EP Renewably Sourced
– Hytrel® TPC-ET
– Hytrel ® RS Renewably Sourced
High
Performance
Engineering
Polymers
Engineering
Polymers
Standard
polymers
AMORPHOUS SEMI-CRYSTALLINE
PES
PEI
PSU
PAR
PEK
PC
MPPO
SMA ABS PMMA
PS SAN PVC
PP LDPE
HDPE
PPS
PI
PET PBT
PA POM
TPC-ET
HTN Zytel®
RS HTN
Sorona® EP
Zytel® RS
Hytrel® RS
DuPont
Renewably Sourced™
LCP
PA66+
Inclusive Sustainability © E.I. du Pont de Nemours and Company
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Properties similar to PBT
37% renewably-sourced Sorona® provides freedom from petroleum dependency - PDO component is Bio- PDO, derived from corn.
Bio-PDO Requires 40% less energy than petrochemical based PDO
HOC
CC
OH C
O
OHC
HO
O+ 1,3-Propanediol
(PDO)
Terephthalic Acid
Polytrimethylene terephthalate
OC
CC
O
O
C
O
CO
CC
C
O
OC
O
DuPont™ Sorona® polymer
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© E.I. du Pont de Nemours and Company
PTT polyester similar to PBT in performance and price.
• Better surface appearance, UV resistance.
• Stronger and stiffer than PBT.
• Lower shrink vs PBT, less warpage.
• Improved hydrolysis resistance and laser weldability. Slightly
better electrical properties
DuPont™ Sorona® polymer
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2012-08-02 © E.I. du Pont de Nemours and Company 10
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Description/Application
Air conditioning register blade
End-user
Toyota Motors
Benefit gained from this development
Cost reduction by eliminating painting process compared with glass reinforced PBT, former material
Design freedom because of higher mechanical property than glass reinforced PBT
Material chosen and Why
Sorona® 2045G, 45% glass filled grade was chosen because of its excellent combination of good appearance and mechanical property. It is also bio-based material.
Sorona® 2045G GF45%-PBT
Tensile strength MPa 170 160
Tensile modulus MPa 15,500 14,500
Mechanical property
45% glass filled Sorona®EP
Sorona®2045G
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SORONA ® EP – cell phone covers
Covers for iphone
- SORONA® EP combines
dimensional stability and
scratch resistance
- Excellent surface finish
- Easy sublimation printing on
demand
- Min 20 up to 37% by weight
renewable content in
SORONA® EP
Taber Scratch result after AOA aging
0
2
4
6
8
10
0 8 16 32 64
AOA aging time / hours
Fo
rce
/ N
Sorona NC010 Sorona Red
Sorona Silver ABS
PC/ABS
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O
OO
OO
O
HO
O
O
OO
O
O
OH
O
YZ
Ether
HARD SEGMENTS SOFT SEGMENTS
Hytrel® RS uses soft segment based on renewable source
The bio renewable content varies Shore D hardness
The basis is non-food biosource
The bio-soft segment is chemically similar to fossil based soft
segment
• DuPont™ Hytrel® polymer
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Air duct applications operate with
design elongation < 50%
Stress versus Strain at different temperatures
Injection molded ISO 5A bars @ 50 mm/min
© E.I. du Pont de Nemours and Company
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Current grade portfolio
• Base Polymers ranging from 40 Shore D to
63 Shore D:
– Hytrel® RS 40F3 NC010
(40D, high flow for injection moulding, >50% renewable content )
– Hytrel® RS 40F5 NC010 (40D, for injection moulding and extrusion, >50% renewable content )
– Hytrel® RS 40F2 NC010 ( 40D, low melting point, >38% renewable content )
– Hytrel® RS 55F5 NC010 ( 55D polymer, >30% renewable content )
– Hytrel® RS 63F5 NC010 ( 63D polymer, >22% renewable content )
DUPONT CONFIDENTIAL
Generation by Knoll®
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© E.I. du Pont de Nemours and Company 16
High performance polyamides that provide high
flexibility, toughness and thermal properties with
superior chemical and hydrolysis resistance.
The product line includes unreinforced and glass
reinforced grades of Polyamide 10.10 and 6.10 with a
renewably sourced content of up to 100%, derived
from castor oil.
Provides lower cost options vs. Polyamide-11 and 12.
Radiator end-tanks
Fluid management Electronic housings
DuPont Zytel® RS High performance Nylon
Industrial
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2012-08-02 © E.I. du Pont de Nemours and Company 17
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ZYTEL® RS Fischer UX-green
Key Benefits Zytel® RS
Min 50% renewable content by weight
Easy Processing
High stiffness and toughness
Similar and better load bearing
Long term properties
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© E.I. du Pont de Nemours and Company 19
Renewable ZYTEL ® RS HTN
Hand Held Device
Inclusive Sustainability
Inclusive Sustainability
Thinner-Lighter-Renewable
ZYTEL® RS HTN - Very high stiffness and strength for
metal replacement
- Flow ability for thinnest wall sections
allows sleek, light designs that
improve performance
- Part weight reduction supports the
footprint reduction
- Min 20 up to 100% renewable content
by weight in ZYTEL® RS
Thinner Lighter
Aesthetical Innovative
Hand Held Device
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20
ZYTEL ® RS – Long Chain LCPA
Hose & Tube
ZYTEL® RS LCPA portfolio for extrusion
- Continued development of the broadest range
of renewably sourced Polyamides
- Commercial Success with ZYTEL RS in Fiat
diesel-fuel lines
- New DuPont™ Zytel® RS LC4000 (PA610)
and Zytel® LC7000 (PA612).
- Chemically modified long chain polyamides
with improved hydrolysis and chemical
resistance
- Min 20 up to 100% renewable content by
weight in ZYTEL® RS
Inclusive Sustainability
Inclusive Sustainability
© E.I. du Pont de Nemours and Company
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Life Cycle Analysis and Carbon Sequestration
CO2
CO
N2O CH4
CO2
recycling
Cradle-to-Gate GHG
Emissions
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2012-08-02 © E.I. du Pont de Nemours and Company 22
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DuPont Renewably Sourced Materials
visit www.renewable.dupont.com
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FEEDING THE WORLD REDUCING OUR DEPENDENCE
ON FOSSIL FUELS
KEEPING PEOPLE AND
THE ENVIRONMENT SAFE
25 © E.I. du Pont de Nemours and Company
Thank you.
Søren Flensborg Iversen
Renewably Sourced Performance Polymers
+45/51430444