dr. marwa eid 1 chemical bonds - attractive force that holds atoms or ions together - chemical...
TRANSCRIPT
Chemical Bonds
• Chemical Bonds
- attractive force that holds atoms or ions together
- Chemical bonding are classified into 3 types
ionic, covalent, metallic
Chemical Bonding
Electronegativity – the tendency of an atom to attract electrons from a neighboring atom.
Hey! I find your electrons attractive!
Get lost, loser!
Electronegativity increases as you move from left to right.
Electronegativity decreases as you m
ove down each colum
n.
Valence Electrons
– electrons in the outermost occupied energy level.
- Valence electrons can be represented by “dots” drawn around the atom.
7
Electron Shells
a) Atomic number = number of Electrons
b) Electrons vary in the amount of energy they possess, and they occur at certain energy levels or electron shells.
c) Electron shells determine how an atom behaves when it encounters other atoms
8
Electrons are placed in shells according to rules:
The 1st shell can hold up to two electrons, and each shell thereafter can hold up to 8 electrons.
9
Why are electrons important?
Elements have different electron configurations different electron configurations mean
different levels of bonding
10
Octet Rule = atoms tend to gain, lose or share electrons so as to have 8 electrons
C would like to N would like toO would like to
Gain 4 electronsGain 3 electronsGain 2 electrons
11
Bonding
• Elements that do not have a complete octet, tend to react.
• When the elements react bonds are formed.
13
Chemical bonds: an attempt to fill electron shells
1. Ionic bonds
2. Covalent bonds
3. Metallic bonds
15
IONIC BOND
• A bond formed between two oppositely
ions by the transfer of electrons.• Each element (now an ion) will have a
complete octet after the transfer of electrons
When the electronegativities of two atoms are quite different from each other:
One atom loses an electron (or electrons)
The other atom gains an electron (or electrons)
This results in an Ionic Bond.
18
Formation of Ions from Metals
Ionic compounds result when metals react with nonmetals
Metals lose electrons to match the number of valence
electrons of their nearest noble gas
Positive ions form when the number of electrons are
less than the number of protons
Group 1 metals ion 1+
Group 2 metals ion 2+
• Group 13 metals ion 3+
19
Some Typical Ions with Positive Charges (Cations)
Group 1 Group 2 Group 13
H+ Mg2+ Al3+
Li+ Ca2+
Na+ Sr2+
K+ Ba2+
20
Learning Check
A. Number of valence electrons in aluminum1) 1 e- 2) 2 e- 3) 3 e-
B. Change in electrons for octet in aluminum1) lose 3e- 2) gain 3 e- 3) gain 5
e-
C. Ionic charge of aluminum 1) 3- 2) 5- 3) 3+
21
Solution
A. Number of valence electrons in aluminum3) 3 e-
B. Change in aluminum electrons for octet1) lose 3e-
C. Ionic charge of aluminum (13) 3) 3+
35
Covalent Bond
• Between nonmetallic elements of similar electronegativity.
• Formed by sharing electron pairs• Stable non-ionizing particles.• Examples; O2, CO2, C2H6, H2O
38
Cl Cl
circle the electrons foreach atom that completestheir octets
The octet is achieved byeach atom sharing theelectron pair in the middle
39
Cl Cl
circle the electrons foreach atom that completestheir octets
It is a single bondingThis is the bonding pair
41
Oxygen Atom Oxygen Atom
Oxygen Molecule (O2)
44
- water is a polar molecule because oxygen is more electronegative than hydrogen, and therefore electrons are pulled closer to oxygen.
45
1. Define the following:a. Ionic bondb. Covalent bond
Compare between polar and non-polar covalent bond
48
Metallic Bond
• A lattice of positive ions in a sea of electrons
• Formed between atoms of metallic elements• Electron cloud around atoms • Examples; Na, Fe, Al, Au, Co
50
This electrostatic attraction is called metallic bonding and is the reason why the positive metal ions do not repel each other.
The outer shell electrons separate from their atoms and become delocalized, creating a ‘sea of electrons’. The atoms become positive ions and are attracted to these electrons.
metal atoms
sea of free electrons
metal ions
Metallic bonding
51
Properties of Metallic Bonds• Good electrical conductors - free electrons
can move through the lattice carrying charge (GR).
• Conduct heat because of free electrons• Lusterous – absorb and emit light in regular
pattern due to free electrons
52
• Malleable (can be hammered into different shapes) and ductile ( can be drawn into wires) – not in rigid position so ions can be shaped and drawn into wires
Properties of Metallic Bonds