ecology and environment, inc. · 2018. 5. 9. · ecology and environment, inc. nternationai...

ecology and environment, inc.nternationai Specialists :re Environment

111 West Jackson BouievardChicago, nhnois 60604Tel: i312'663-9415. Fax i2i2'663-0791

March 3. 1995

Gail NabasnyDeputy Project OfficerEmergency and Enforcement Resj- inse BranchU.S. Environmental Protection Agency77 West Jackson BoulevardChicago, Illinois 60604

RE: Petoskey Municipal Well Field - Technical AssistancePetoskey, MichiganTDD No.: T05-9412-006PAN: EMI0209SAA

Dear Ms. Nabasny,

On December 14, 1994, the U.S. Environmental Protection Agency (U.S. EPA) tasked theEcology and Environment, Inc. (E & E), Technical Assistance Team (TAT), under TechnicalDirection Document (TDD) number T05-9412-006, to collect six municipal well water samples fromthe Ingalls Road well of the Petoskey Municipal Well Field in Petoskey, Michigan. The followingletter report describes activities associated with this TDD.

TAT member Sally Imes arrived in Petoskey, Michigan, on January 4, 1995, and met withthe city of Petoskey's consultant, Gary Molchan, of McNamee, Porter & Seeley, Inc., of Ann Arbor.Michigan. The TAT proceeded to generate one field blank using distilled water and one equipmentblank by pouring distilled water into a stainless steel bailer and then filling the sample bottles. Thesesamples were designated as 95TT01R02 and 95TT01R01, respectively. Three volumes of the on-sitewell were purged. The TAT then collected a sample and a duplicate from the on-site well with astainless steel bailer. These samples were numbered 95TT01S01 and 95TT01D01, respectively. Asample and duplicate were then collected from a spigot inside the Petoskey Municipal well house afterpurging the spigot for 15 minutes. These samples were labeled 95TT01S02 and 95TT01D02,respectively. Sample number 95TT01R02, the field blank, was analyzed for volatile organiccompounds (VOCs) only. Sample numbers 95TT01S01, 95TT01D01, 95TT01S02, 95TT01D02, and95TT01R01 were analyzed for VOCs, semivolatile organic compounds, pesticides, metals andcyanide.

EIS Environmental Services, Inc., in South Bend, Indiana, was procured by the TAT toperform VOC analyses under analytical TDD number T05-9412-806 utilizing U.S. EPA SafeDrinking Water method 524.2. Samples to be analyzed for semivolatile organic compounds,

EPA Region 5 Records Ctr.

recycled paper238287

pesticides, metals, and cyanide were shipped to the U.S. EPA Central Regional Laboratory (CRL) inChicago, Illinois. Analyses performed at CRL were arranged by U.S. EPA. Table 1 summarizes theanalytical data. Note that if a parameter was not detected in the sample, then it was not included inTable 1. A copy of the analytical data can be found in Attachment A.

If you should have any questions or require additional information, please contact our office at312-663-9415.

Sincerely,

Lisa GraczykEcology and Environment, Inc.TAT member

Attachments:Attachment A - Analytical Data

cc: Thomas Kouris, TAT LeaderTeresa A. Von Donsel, RPMTDD file

TABLE 1SUMMARY OF DATA RESULTS

January 5, 1995Umls -

Parameter

c-1 ,2-dichloroelhylene"

(eirachloroeihylene*

toluene*

trichloroetbylene*

chlorodibromomethane'

aluminum*

barium*

calcium*

chromium*

cobalt"

copper*

iron*

magnesium*

manganese11

nickel"

potassium*

silver"

sodium"

vanadium"

zinc"

SAMPLE DESIGNATION

95TT01ROI

< 0 5

<0 5

056

< 0 5

<0.5

<80

169

52,000

<10

<6

<6

<80

29,000

<5

25

<5000

<6

21 , (KK)

8

<40

95TTO1R02

< 0 5

< 0 5

062

< 0 5

<0.5

...

...

...

- - -

95TTOIS01

054

0 56

092

86

< 0 5

5180

95

411,000

91

8

43

14.000

106,000

521

115

5000

< 6

52,000

21

157

95TT01D01

0 66

064

073

86

<0.5

2620

73

269,000

67

<6

26

7200

69,000

273

81

< 5000

<6

52,000

17

XX

95TTOIS02

<0 5

<0.5

<() 5

2.5

065

<80

26

60,000

< 10

<6

9

<80

15,000

< 5

< 20

< 5000

v 6

25,000

< X

<: 40

95TT01D02

<() 5

<() 5

<0 5

2 6

0.78

<80

27

60, (MM)

< 10

v 6

< ()

v. 80

15,000

6

<. 20

< 5(M)0

< (>

25,000

V X

- 40

= Noi analy/ed

' Source. ELS Environmental Services, Inc , Smith Bend, Indiana, Analytical TDD No T05 9412-806." Source. US EPA Central Regional Laboratory (CRL), Chicago, Illinois

ATTACHMENT A

ANALYTICAL DATA

ecology and environment, incinternational Sceaahsts m tre Environment

•' i West JacKscn BouievaraChicago. Illinois 60604rei: (312) 663-9415. Fax: (312) 663-0791

M E M O R A N D U M

DATE: February 1, 1995

TO: Sally Imes, Project Manager, E & E, Chicago, IL

FROM: David Hendren, Analytical Services Manager, E & E,Chicago, IL

THROUGH: Mary Jane Ripp, QA Manager, E & E, Chicago, IL

SUBJECT: Volatile Organic Data Quality ReviewPetoskey Municipal Well Field, Petoskey, Emmet County,Michigan

REFERENCE: Project TDD T05-9412-006 Analytical TDD T05-9412-804Project PAN EMI0209VCA Analytical PAN EMI0209AAA

The data quality assurance (QA) review of six drinking watersamples collected from the Petoskey Municipal Well Field site iscomplete. The samples were collected on January 4, 1995, by theTechnical Assistance Team (TAT) contractor, Ecology andEnvironment, Inc. (E & E). The samples were submitted to EISEnvironmental Engineers, South Bend, Indiana for analysesfollowing United States Environmental Agency Method 524.2. Inaddition, certain non-target list compounds, includingcyclohexanone, methyl ethyl ketone, and tetrahydrofuran wererequested for analysis.

Sample Identification

E 6 E LaboratoryIdentification No. Identification No.

95TT01S01 2269395TT01D01 2269495TT01S02 2269595TT01D02 2269695TT01R01 2269795TT01R02 22698

*

Data Qualifications

I. Sample Holding Time; Acceptable

The samples were collected on January 4, 1995, and analyzed

recycled paper

Petoskey Municipal Well FieldProject TDD T05-9412-006Analytical TDD T05-9412-804Page 2

on January 6, 1995. This is within the 14-day limit forpreserved water samples.

II. GC/MS Tuning; Acceptable

GC/MS tuning to meet ion abundance criteria usingbromofluorobenzene (BFB) were acceptable and samples wereanalyzed within 12 hours of BFB tuning.

III. Calibrations;

• Initial Calibration: Acceptable

A five-point initial calibration was performed prior toanalysis. All average response factors were greater than0.05. The percent relative standard deviations (%RSD)between response factors were less than 30% for all targetcompounds.

• Continuing Calibrations: Acceptable

The percent difference between initial and continuingcalibration for all target compounds was less than or equalto 25% for all compounds.

IV. Blanks; Acceptable

A method blank was analyzed with the samples. No targetcompounds or contaminants were detected in the method blank.

V. Internal Standards; Acceptable

The areas of the internal standards in the samples werewithin -50% to +100% of the associated calibration checkstandard. The retention time of the internal standards werewithin the 30-second control limit.

VI. Compound Identification; Acceptable

The retention times and mass spectra of reported targetcompounds were within the allowable limits.

VII. Additional QC Checks; Acceptable

The recoveries of the surrogates used in the samples andblank were within the laboratory established guidelines.

Petoskey Municipal Well FieldProject TDD T05-9412-006Analytical TDD T05-9412-804Page 3

VTII.overall Assessment of Data for Use; Acceptable

The overall usefulness of the data is based on criteria forQA Level II outlined in the Office of Solid Waste andEmergency Response (OSWER) Directive 9360.4-01 (April 1990),Data Validation Procedures, Section 5.0, VOAs by GC/MSAnalysis.

SAMPLE ID: 95TT01S01Wall Point #1

REPORT DATE: 01/12/95EXS LAB NO: 22693

VOLATILE ORGANIC COMPOUNDS (VOC) IN DRINKING WATER

REGULATED VOC PKREGULATim

BanzanaCarbon TatzachloridaQ— Dichlorobanxanam-Dich lorobanzanap— Dichlorobanzana1, 2-Dichloroathana1, 1-Dichloroathylanac-1, 2-Dichloroathylana ....t-1, 2-Dichloroathylana

StyranaTatraehloroathylanaToluanaTotal Trihaloaathanaa (TTBN)1,2, 4-Trichlorobanzana1, 1, 1-Trichloroathana1,1,2 -TrichloroathanaTrichloroathylana . ,Vinyl ChloridaXylanaa (total)

1, 2-Dichloroathana, d4 (SUR)Toluana, d8 (SUR)Bromof luorobanzana (SUR)

ANALTTZCAL COMMENTS1. EPA Mathod: 524.22. Raault ia in ng/13. DL » Dataction Limit at4. MD » Mot Dataetad at thi5. SUR «• Tin i injil a i la^uiuiiil6. A Blank Raault aaana tha7. Sanpla Dilution: Nona8. Othar VOC datactad: Mom

Mathyl Ethyl Katona ....TatrahyArofuran

NDMDMDMDMDMDMD

. 0.54MDMDMDMDMDMD

. 0.5C0.92MDMDMDMD8.6MDMD

90%97%111%

tha diluli DL ahOMwith QC 1analyaia

iNDMD

. ND

— .

0.50.50.50.50.50.50.50.50.50.50.5O.S0.50.50.50.52.00.50.50.50.50.52.0

7C-11481-11086-115

BromobanzanaBroaochloromathanaBroaodichloroaa thanaBromofoza

Q— Butylbanzana•ac-Butylbanzanatart-Butylbanzana

ChloroathanaChloroformChlo r omathanao-Chlorotoluanap-ChlorotoluanaDibroaoaathana&— DichlorobanzanaDichlorodiz'luoroaathana

1, 3 -Dichloropropana2,2 -Dichloropropana1, 1 -Dichloropropana1 , 3 -Dichloropropana (total)riuorotrichloroaathana

_ IHM» AnA

p-IaopropyltoluanaNaphtha lanan-Pr«pvlban«ana1 1 I/ 2— Tatrachloroathana1 1 9 f T^i~T-»<~M fiTfi i" "' — ~

1, 2, 3-Trichlorobanzana

1.2. 4-Triiittthvlb+nxanai1,3, 5-Triaathylbanzana

NDNDMDMDMDMDMDMDNDNDMDNDNDNDNDMDMDMDMDNDNDNDND

NDMDNDNDNDNDNDNDNDMD

~~

0.52.00.50.52.00.50.50.50.52.00.52.00.50.50.50.52.00.50.51.00.51.01.00.50.50.50.50.51.00.50.51.00.50.5

:ion uaadibdaita ahown in tha DL columnwaa not zaquaatad

DL • 20DL • 5DL - 10

Ub Form 20M

SAMPLE ID: 95TTO1DO1Wall Point *2

REPORT DATS: 01/12/9BIS LAB HO: 22694


REGULATED VOC

BanzanaCarbon Tatzachlozidao — D ichloroban zanaB-Dichlorobanzanap-Diehlozobanzana1, 2 -Dichloroathana1, 1-Dichloroathylanac-l,2-Dichloroathylana ....t-1, 2-Dichloroathylana

1, 2-DichlozopzopanaKthyl BanzanaMonochloxobanzanaStyranaTatrachloroathylanaToluanaTotal Trihalomathanaa (TTHM)1,2, 4-Trichlorobanzana1,1, 1-Tzichloroathana1,1, 2-TrichloroathanaTrichloroathylanaVinyl ChloridaXylanaa (total)

1 , 2 -Dichloroathana , d4 ( SUR)Toluana , d8 ( STIR)Bromof luorobanzana (SUR)

ANALYTICAL COMMENTS1. EPA Mathod: 524.22. Raault ia in jig/13. DL m Dataction Limit at4. ND - Not Datactad at th«5. SUR » Surrogata -compound6. A Blank Raault maana tha7. Saapla Dilution: Nona8. Othar VOC datactad: Now

Mathyl Kthyl Katona ....

NDNDNDNDNDNDND0.66NDNDNDNDNDND0.64

. 0.73NDNDNDND8.6NDND

90%9€%

105%

tha dilnti DL ahownwith QC Lanalyaia

tNDNDND

*"**

0.50.50.50.50.50.50.50.50.50.50.50.50.50.50.50.52.00.50.50.50.50.52.0

78-11481-1108C-115

BromobanzanaBromochloromatharia

Bromoform

n-ButvLhanzanaaac-Butylbanzanatart-Butylbanzana

ChloroathanaChloroformChloromathanao-Chlorotoluanap-ChlorotoluanaDibromomathana

DichlorodifluorofDathana1, 1 -Dichloroathana1 r 3 -Dichloropropana

1, 1 -Dichloropropana1 3-Dichlotopropana (total)Fluorotrichloromathana

p-IaopropyltoluanaNaphthalana

1 1 1 j T t"i~B£~hT nr'oafr ***1,1,2,2 -Tatrachloroathana1,2, 3— Trichlorobanzana1,2, 3-Trichloropropana1,2, 4-Trimathylbanzana1,3, 5-Trimathylbanzana

NDNDNDNDNDNDNDNDNDNDNDNDNDNDNDNDNDNDNDNDNDNDNDNDNDNDNDNDNDNDNDNDNDNO-

•"•

0.52.00.50.52.00.50.50.50.52.00.52.00.50.50.50.52.00.50.51.00.51.01.00.50.50.50.50.51.00.50.51.00.50.5

ion uaad

imita ahown in tha DL columnwaa not raquaatad

DL • 20DL • 5DL » 10

I* Form 2Q2i RMta* (M.2M4)

SAMPLE ZD: 95TT01S02PMT Houaa 11

EXPORT DATS: 01/12/9!IIS LAB HO: 22695


REGULATED VOC

BanzanaCarbon Tatrachloridao — D i chlo roban zanan-Diohlorobanxana

1, 2— Dichloroathana1, 1-Dichloroathylanac- 1 , 2 -Dichloroathylanat-1, 2 -Dichloroathylana

1 , 2 -DichloropropanaEthyl BanzanaHonochlorobanzanaStyranaTatrachloroathylanaToluana

1,2, 4-Trichlorobanzana1,1, 1-Trichloroathana1, 1, 2-TrichloroathanaTrichloroathylanaVinyl ChloridaXylanaa (total)

1, 2-Dichloroathana, d4 (SUR)Toluana , d8 ( SUR)Broaofluorobanzana (SUR)

ANALYTICAL COMMENTS1. EPA Nathod: 524.22. Raault ia in ng/13. DL * Dataction Liait at4. MD - Mot Datactad at th«5. SUR • Surrogata -compound6 . A Blank Raault aaana tha7. Saapla Dilution: Nona8. Othar VOC datactad: MOM

Mathyl Ethyl Katona ....

ND 0.5ND 0.5MD 0.5ND 0.5ND 0.5MD 0.5MD 0.5MD 0.5ND 0.5ND 0.5ND 0.5ND 0.5ND 0.5ND 0.5ND 0.5ND 0.5ND 2.0ND 0.5MD 0.5MD 0.52.5 0.5ND 0.5ND 2.0

86% 75-114100% 81-110105% 8C-115

tha dilution uai DL shownvita QC Uaitaanalyaia waa no

i20 DL -5 DL •10 DL •

Broaoban zanaBroittoch loronat hana

Broaofora

Q— Butylbanzanasac-Butylbanzanatart -Butylbanzana

ChloroathanaChlorofora

o-Chlorotoluanap-ChlorotoluanaDibroaoaathanaa-DlchlorobanzanaDichlorodifluoroaathana1, 1-Dichloroathana

2 , 2 -Dichloropropana1, 1 -Dichloropropana

Haxftnh 1 orobut adianaTawpropylbanzanap-IaopropyltoluanaNaphthalanan-P ropylbanzana111 2— Tatrachloroathana1 , 1,2,2 -Tat rachloroathana1,2, 3-Trichlorobanzana1,2, 3 -Trichloropropana1,2, 4-Triaathylbanzana1, 3, 5-Triaathylbanzana

ad

•hown in tha DL coluant raquaatad

20510

NDNDNDNDNDNDNDND0 65NDNDNDNDNDNDNDNDNDNDNDNDNDNDNDNDNDNDNDNDNDNDNDNDND

— ~

0.52.00.50.52.00.50.50.50.52.00.52.00.50.50.50.52.00.50.51.00.51.01.00.50.50.50.50.51.00.50.51.00.50.5

L* Form 2021 (M-2M4)

SAMPLE ZD: 95TTO1DO2Plfll Housa 42

VOLATILE C

REGULATED VOC

BanzanaCarbon Tatzachlozidao— DichlorobanzanaA— D i c h 1 o zoban z anap— D ichlo n?H*i> zana1, 2 -Dichlozoat hana1, 1 -Dichlozoathylanac-1, 2 -Dichlozoathylanat -1 , 2 -Dichlozoathylana

1 , 2 -DichlozopzopanaEthyl Banzana

StyranaTatzachlozoathylana

1,2, 4-Tzichlozobanzana1,1, 1-Tzichlozoathana1,1, 2-TzichlozoathanaTr4 r*hl nroA^hvl AAA

Vinyl ChlozidaXylanaa (total)

1, 2-Dichlozoathana, d4 (SUR)Toluana , dS ( SUR)Bzomof luozobanzana (SUR)

ANALYTICAL COMMENTS1. EPA Mathod: 524.22. Rasult is in M9/13 . DL - Dataction Llait at4. MD - Not Datactad at thi5. SDR • Suzzogata coazaound6 . A Blank Rasult naans tha7. Saapla Dilution: Nona8. Othar VOC datactad: Nont

CyclohaacanonaMathyl Ethyl Katona ....Tatzahydrozuzan ,

REPORT DATE: 01/12/9EIS LAB MO: 22696

JRGANIC

RESULT

NDNDNDNDMDMDMDNDNDNDNDNDMDNDMDMDNDMDMDMD2.6NDND

98%104%117%

tha dilui DL showwith QCanalysis

iMDMDMD

COMPOUNDS (VOC) IN DRINKING WATER

DL UNREGULATED VOC RESULT

0.50.50.50.50.50.50.50.50.50.50.50.50.50.50.50.52.00.50.50.50.50.52.0

76-11488-11086-115

Bromoban zana

Bzoaofoza

tazt -Butylbanzana

ChlozoathanaChlozofomChlozoaathanao-Chlozotoluanap-ChlozotoluanaT\ ..~~*~r+*m*~

Dichlozodifluozonathana1, 1-Dichlozoathana1, 3-Dichlozopzopana2 , 2-Diehlozopzopana

1, 3-Dichlozopzopana (total)riuorotzichlozonathana

Isopzopylbanzanap-IsopzopyltoluanaNapht ha lana

1,2, 3-Trichlozobanzana1,2,3 -Tzichlozopropana1,2, 4-Tziaathylbanzana1,3, 5-Tziaathylbanzana

MDMDMDMDMDMDMDMD

. 0.78MDNDMDMDMDMDMDMDMDMDMDMDNDMDMDMDMDMDMDMDMDMDMDMDMD

DL

0.52.00.50.52.00.50.50.50.52.00.52.00.50.50.50.52.00.50.51.00.51.01.00.50.50.50.30.31.00.50.51.0O.S0.5

tioa uaadnLiaita shown in tha DL coluanwas not zaquaatad

DL » 20DL - 5DL • 10

L*b Form 20M Retort (OM3-W)

SAMPLE ID: 95TTO1RO1EBB

VOLATILE C

Carbon Tatxachloxida

— rnrh lorobanianap— Dichlorobanzana1 2 Dlchloroathana1, 1-Dichloxoathylanac-1, 2-Dichloxoathylanat-1, 2-Dichloxoathylana

1, 2-Dichloxopxopana

MoiuwhlorobanzanaStyxanaTatxachloxoathylana

Total Trihalomathanas(TTHX)1,2, 4— Txichloxobanzana

1,1, 2-TxichloxoathanaTxichloxoathylanaVinyl ChloxidaXylanaa (total)

1, 2-Dichloxoathana, d4 (SUR)Toluana, d8 (SUR)Bxomox'luoxobanzana ( SUR)

REPORT DATE: 01/12/9EXS LAB NO: 22697

JRGANIC

RESULT

MDMDMDNDNDMDNDNDMDNDNDNDMDMDMD

. 0.5$NDNDNDNDMDMDND

90%103%111%

COMPOUNl

_DL_

0.50.50.50.50.50.50.50.50.50.50.50.50.50.50.50.52.00.50.50.50.50.52.0

7«-11411-11086-115

DS (VOC) IN DRINKING WAT!

BxomobanzanaBxomochloxoaathana

Bxomomathana

B«{<-ButYlbanz«nataxt — Butylbanzana

ChloxoathanaChloroform

o -Chlorot oluanap-ChloxotoluanaDibxomomathanam— D ichloxobanzanaDichloxodifluoxoaathana1, 1 -Dichloxeat- h ana1, 3-Dichloxopxopana2 , 2-Dichloxopxopaaa1, 1-Dichloropxopana1, 3-Dichloxopxopana (total)

Ha za ch 1 o robut adi ana!*»• •

p-IsopxopyltoluanaNaDhfha l*nan-Propvlbanzana1,1,1,2 -Tat xachloxoathana

1, 2, 3 -Txichloxobanzana1,2,3 -Txichloropxopana1,2, 4-Txiaathylbanzana1,3, 5-Txiaathylbanzana

1R

RESULT DL

ND 0.5MD 2.0ND 0.5ND 0.5ND 2.0ND 0.5ND 0.5ND 0.5ND 0.5ND 2.0ND 0.5MD 2.0ND 0.5ND 0.5ND 0.5ND 0.5ND 2.0MD 0.5MD 0.5ND 1.0ND 0.5ND 1.0ND 1.0ND 0.5MD 0.5ND 0.5ND 0.5ND 0.5MD 1.0ND 0.5ND 0.5ND 1.0MD 0.5MD 0.5

ANALYTICAL COMOMTS1. EPA Mathod: 524.22. Rasult is in ng/13. DL • Dataetion Limit at tha dilation usad4. ND « Mot Datactad at tha DL shown5. SUR • Suxxogata compound with QC Limits shown in tha DL column6. A, Blank Rasult «T**** tha analysis was not xaquastad7. Sampla Dilution: Nona8. Othax VOC datactad: Nona

t*y~1 **~-mnr * JJD DL • 20

Mathyl Ethyl Katona ND DL » 5Tatxahydxofuxan ND. DL « 10

Ub Form 20M R (Ofr2M4)

SAMPLE ID: 95TTO1R02ra

REPORT DATS: 01/12/9!IIS LAB NO: 22698


VOC UNMGULAT*T> VOC

BanzanaCarbon Tatrachloridao-Dichlorobanzana

1 , 2 -Dichloroathana1, 1-Dichloroathylanac-1, 2-Dichloroathylanat-1 , 2-Dichloroathylana

1, 2-DichloropropanaEthyl BanzanaMonochlo robanzanaStyranaTat rachloroathylanaToluanaTotal Trihalomathanaa (TTHH)1,2, 4-Trichlorobanzana1,1, 1-Trichloroathana1,1, 2-TrichloroathanaTrichloroathylanaVinyl ChloridaXylanaa (total)

1 , 2 -Dichloroathana , d4 ( SUR)Toluana , d8 ( SUR)Brono£luo robanzana (SUR)

ANALYTICAL COMIEMTS1. EPA Nathod: 524.22 . Raault ia in ng/13. DL - Dataction Limit at4. ND - Not Datactad at thi5. SUR • Surrogata cnayound€. A Blank Raault aaana tha7. Saapla Dilution: Nona8. Othar VOC datactad: Noni

CyclohaxanonaMathyl Ethyl Katona .Tatrahydrofuran

NDNDNDNDNDNDNDNDNDNDNDNDNDNDND0.62NDNDNDNDNDNDND

90%97%103%

tha dilui DL ahoiiwith QCanalyaia

INDNDND

•"•

0.50.50.50.50.50.50.50.50.50.50.50.50.50.50.50.52.00.50.50.50.50.52.0

76-11481-11086-115

BronobanzanaBroaochloromathanaBroaodichloroaathananfranf\fnn»

a~f*f**~i* YttTHn— Buty Ibanzanaaac — Buty Ibanzanatart -Buty IbanzanaChlorodibromoawthanaChloroathanaChloroform

o-Chlorotoluanap-Chlorotoluana

a— DichlorobanzanaDichlo*rKiifiuornn»thin*1 1-Dichloroathana1 , 3 -Dichloropropana29 _nl oh 1 nrnnrwnanA1, 1 -Dichloropropana1, 3 -Dichloropropana (total)riuorotrichloronathanaH yj h I orob'u rtiafiaIMvnrnevI h*n**nAawp*wpjf ±Dma*mamp-ZaopropyltoluanaNaphthalanan-Propy Ibanzana1,1,1,2 -Tat rachloroathana1,1,2,2 -Tat rachloroathana1,2, 3-Trichlorobanzana1,2,3 -Trichloropropana1,2, 4— Triaathylbansana1,3, 5-Trimathylbanxana

NDNDNDNDNDNDNDNDNDNDNDNDNDND

NDNDNDNDNDNDNDNDNDNDNDNDNDNDNDNDNDNDND

"H

0.52.00.50.52.00.50.50.50.52.00.52.00.50.50.50.52.00.50.51.00.51.01.00.50.50.50.50.51.00.50.51.00.50.5

tion usadnLimita ahown in tha DL coluanwaa not raquaatad

DL - 20DL - 5DL - 10

Ub fam 303* Ante* (M494»)

UNITED STATES ENVIRONMENTAL PROTECTION AGENCY

£~ 4% ~\ REGION 5 CENTRAL REGIONAL LABORATORY

jf 536 SOUTH CLARK STREET

CfflCAGO, ILLINOIS 60605 *

Date: JAN 2 3 1995

Subject: Review of Region 5 Data for Petoskey Municipal \^ell Field Code:54

From: Charles T. Elly, DirectorRegion 5 Central Regional Laboratory

To: & f <=

Attached are the results for Petoskey Municipal Well Field Code: 54CRL request number 950080for analyses for ICPResults are reported for sample designations: 95TT01S01, 95TT01D01, 95TT01S02,95TT01D02 and 95TT01R01

Results Status:( x ) Acceptable for Use( ) Data Qualified, but Acceptable for use( ) Data Unacceptable for Use

(x) Sewer Disposal Criteria Met; Exceptions: Acid preserved samples must be neutralized priorto disposal. Samples 95TT01S01 and 95TT01D01 contain paniculate matter that may precludedisposal in the sewer. These two samples also exceed the disposal criterion for iron.

Review Record for Petoskey Municipal Well Field Code:54 Page 2i <

Comments on Data Quality by Reviewer

The field blank, 95TT01R01, was found to contain measurable concentrations of barium,calcium, magnesium, nickel, sodium, and vanadium. All these elements except nickel wereconfirmed by also analyzing the undigested field blank. There is some doubt about nickelbecause, due to noise in the detector, nickel was analyzed again in a separate run, and theundigested field blank was not included in that run. Vanadium in this blank is at the detectionlimit (8 Mg/L), and the instrument blank analyzed just after the field blank was 5 uglL, so thisfinding may well be a false positive.

Beryllium, copper and nickel were reanalyzed from the same digestions because of unacceptableinstrument performance. All data were reported from runs with acceptable instrument blanksand control standards, and a valid resweil laboratory control sample.

Chromium had a low matrix spike recovery (74%), outside the 85-115% acceptance window.Because of the large amount of paniculate in the spiked sample, 95TT01S01, it is tempting toattribute this poor recovery to difficulty in obtaining a homogeneous subsampie, but the duplicateresults for the same sample do not support this hypothesis. The relative percent difference forchromium was only 3 %. Chromium may have an error in the measured results.

Sample 95TT01S01 contains visibly more paniculate matter than sample 95TT01D01, whichmay explain the apparent lack of agreement between the two field duplicates.

Comments by Laboratory Director or Quality Control Coordinator

Review Record for Petoskey Municipal Well Field Code:54 Page 3

e^m Leader and Date (ft Reviewed ( ) Unreviewed

PLJUM*Section Chief and Date ( ) Reviewed (^Unreviewed

.,QC Coordinator and Date ( ) Reviewed (^Unreviewed

JAN 2 3 1995

Data Management Coordinator and Date Received

Date Transmitted 2 3 1995

Please sign and date this form below and return it with any comments to:

Sylvia GriffinData Management CoordinatorRegion 5 Central Regional LaboratorySL- IOC

Received by and Date

Comments:

EPA RLIMS CRL - REGION VFINAL RESULTS REPORT

REPORT PRODUCED ON: 18-JAN-95

SAMPLE ORGANIZATION: SUPERFUNDSAMPLE REQUESTOR: SALLY IMES/TATLABORATORY: CRL

SAMPLE BATCH ID:ACCOUNT NO:FACILITY:

SAMPLE: 95TT01D01

COLLECTED: 04-JAN-95

COMPOUND

FIELD: 95TT01D01

950080TFA301PETOSKEYMUNICIPALWELL FIELE

RECEIVED: 06-JAN-95 ANALYZED: ll-JAN-95

AMOUNT (Units) QUALIFIERS CAS NUMBER

AluminumBariumBerylliumCalciumChromiumCobaltCopperIronMagnesiumManganeseNickelPotassiumSilverSodiumVanadiumZinc

ANALYZED BY: "tfe.v*.»

2620732U269000676U26720069000273815000U6U520001788

<v..|iA.- (.. i,

(ug/L)(ug/L)(ug/L) BDL(ug/L)(ug/L)(ug/L) BDL(ug/L)(ug/L)(ug/L)(ug/L)(ug/L)(ug/L) BDL(ug/L) BDL(ug/L)(ug/L)(ug/L)

,u*-

7429-90-57440-39-37440-41-77440-70-27440-47-37440-48-47440-50-87439-89-67439-95-47439-96-57440-02-07440-09-77440-22-47440-23-57440-62-27440-66-6

PAGE NO. 1




SAMPLE: 95TT01D02


FIELD: 95TT01D02

SAMPLE BATCH ID: 950080ACCOUNT NO: TFA301FACILITY: PETOSKEY

MUNICIPALWELL FIEL


COMPOUND


ANALYZED BY: T?TW<o

AMOUNT

SOU272U6000010U6U6USOU15000620U5000U6U250008U40U

,. ».lWr.Al«

(Units)

(ug/L)(ug/L)(ug/L)(ug/L)(ug/L)(ug/L)(ug/L)(ug/L)(ug/L)(ug/L)(ug/L)(ug/L)(ug/L)(ug/L)(ug/L)(ug/L)

•Jurf*

QUALIFIERS

BDL

BDL

BDLBDLBDLBDL

BDLBDLBDL

BDLBDL

I -A

CAS NUMBER

7429-90-57440-39-37440-41-77440-70-27440-47-37440-48-47440-50-87439-89-67439-95-47439-96-57440-02-07440-09-77440-22-47440-23-57440-62-27440-66-6

PAGE NO. 2




SAMPLE BATCH ID: 950080ACCOUNT NO: TFA301FACILITY

SAMPLE: 95TT01R01


FIELD: 95TT01R01

PETOSKEYMUNICIPALWELL FIELT


COMPOUND


ANALYZED BY: rfce

AMOUNT

SOU1692U5200010U6U6USOU290005U255000U6U21000840U

K\*u<v-'M.1\U('8 iaU

(Units)


iii«'h<r v

QUALIFIERS

BDL

BDL

BDLBDLBDLBDL

BDL

BDLBDL

BDL

^ „/

CAS NUMBER

7429-90-57440-39-37440-41-77440-70-27440-47-37440-48-47440-50-87439-89-67439-95-47439-96-57440-02-07440-09-77440-22-47440-23-57440-62-27440-66-6

PAGE NO. 3




SAMPLE: 95TT01S01 FIELD: 95TT01S01

COLLECTED: 04-JAN-95 RECEIVED:

COMPOUND AMOUNT


MUNICIPALWELL FIELD

06-JAN-95 ANALYZED: ll-JAN-95

(Units) QUALIFIERS CAS NUMBER


ANALYZED BY: TOW.

5180952U411000918431400010600052111550006U5200027157

A .-U ruU

(ug/L)(ug/L)(ug/L) BDL(ug/L)(ug/L)(ug/L)(ug/L)(ug/L)(ug/L)(ug/L)(ug/L)(ug/L)(ug/L) BDL(ug/L)(ug/L)(ug/L)

\\ f \./\

7429-90-57440-39-37440-41-77440-70-27440-47-37440-48-47440-50-87439-89-67439-95-47439-96-57440-02-07440-09-77440-22-47440-23-57440-62-27440-66-6

PAGE NO. 4




SAMPLE: 95TT01S02 FIELD: 95TT01S02


MUNICIPALWELL FIELI


COMPOUND


AMOUNT (Units) QUALIFIERS CAS NUMBER


SOU262U6000010U6U9SOU150005U20U5000U6U250008U40U


BDL

BDL

BDLBDL

BDL

BDLBDLBDLBDL

BDLBDL

7429-90-57440-39-37440-41-77440-70-27440-47-37440-48-47440-50-87439-89-67439-95-47439-96-57440-02-07440-09-77440-22-47440-23-57440-62-27440-66-6

ANALYZED BY:

PAGE NO. 5

EPA RLIMS CRL - REGIONFINAL RESULTS REPORTParameter;ABN

Sample organization; SUPERFUNDSample Requestor: SALLY IMES/TATFacility; PETOSKEY MUNICIPAL WELL FIELDMatrix:DRINKING

Date Collected;04-JAN-95Date Extracted;09-DEG-94

Method IA625SWLCS.O

Sample Batch ID; 950080Account No; TFA301Sample ID; 95TT01S01

Units; ug/L

Date Received;06-JAN-95Dare Analyzed;ll-JAN-95

CAS NUMBER

108-95-2111-44-495-57-8541-73-1106-46-7100-51-695-50-195-48-7108-60-1106-44-5621-64-767-72-198-95-378-59-188-75-5105-67-965-85-0111-91-1120-83-2120-82-191-20-3106-47-887-68-359-50-791-57-677-47-488-06-295-95-491-58-788-74-4131-11-3208-96-899-09-283-32-951-28-5100-02-7132-64-9606-20-2121-14-284-66-2

7005-72-386-73-7100-01-6534-52-186-30-6101-55-3118-74-187-86-585-01-8

COMPOUND AMO

Phenolbis(2-Chloroethyl) ether2-Chlorophenol1 , 3 -Dichlorobenzene1 , 4-DichlorobenzeneBenzyl alcohol1 , 2-Dichlorobenzene2 -Methy Iphenolbis ( 2 -Chloroisopropy 1 ) ether4 -Methy IphenolN-Nitroso-di-n-propylamineHexachloroethaneNitrobenzeneIsophorone2-Nitrophenol2 , 4 -Dime thy IphenolBenzoic acidbis ( 2 -Chloroethoxy) methane2 , 4-Dichlorophenol1,2,4 -Tr ichlorobenzeneNaphthalene4-ChloroanilineHexachlorobutadiene4-Chloro-3-methy Iphenol2 -Methy InaphthaleneHexachlorocyclopentadiene2,4, 6-Trichlorophenol2,4, 5-Trichlorophenol2 -Chlor onaphthalene2-NitroanilineDimethylphthalateAcenaphthylene3-NitroanllineAcenaphthene2 , 4-Dinitrophenol4-NitrophenolDibenzofuran2 , 6-Dinitrotoluene2 , 4-DinitrotolueneD i ethy Iphtha 1 ate4-Chlorophenyl-phenyletherFluorene4-Nitroaniline4 , 6-Dinitro-2-methy IphenolN-Nitrosodiphenylamine4-Bromophenyl-phenyletherHexachlorobenzenePentachlorophenolPhenanthrene

UNT QUALIFIERS

5 U5 U5 U5 U5 U5 U5 U5 U5 U5 U5 U5 U5 U5 U5 U5 U20 U5 U5 U5 U5 U4 JB5 U5 U5 U5 U5 U20 U5 U2 JB5 U5 U6 JB5 U20 U20 U5 U5 U5 U5 U5 U5 U8 JB20 U5 U5 U5 U20 U5 U

pg#06lO Page N.7 of 10

EPA RLIMS CRL - REGIONFINAL RESULTS REPORTParameter ;ABN

Sample organization; SUPERFUNDSample Requestor; SALLY IMES/TATFacility; PETOSKEY MUNICIPAL WELL FIELD

Sample Batch ID;Account No;Sample ID;

950080TFA30195TT01S01

Matrix;DRINKING

Date Collected;04-JAN-95Date Extracted;09-&BC-»4

Method ;A6 2 SSWLCS.Q Units; ug/L

Date Received; 06-JAN-95Date Analyzed; ll-JAN-95

CAS NUMBER

120-12-784-74-2206-44-0129-00-085-68-791-94-156-55-3218-01-9117-81-7117-84-0205-99-2207-08-950-32-8193-39-553-70-3191-24-2

COMPOUND AMO

AnthraceneDi-n-butylphthalateFluoranthenePyreneButylbenzylphthalate3,3' -DichlorobenzidineBenzo ( a ) anthraceneChrysenebis ( 2-Ethy Ihexyl) phthalateDi-n-octylphthalateBenzo (b) f luorantheneBenzo (k) f luorantheneBenzo (a) pyreneIndeno (1,2,3 -cd) pyreneDibenzo ( a, h) anthraceneBenzo ( g , h , i ) pery lene

UNT QUALIFIERS

5 U5 U5 U5 U5 U5 U5 U5 U5 U5 U5 U5 U5 U5 U5 U5 U

Analyzed by;

T«am Laad«r:

pgfoeio Page N.8 of 10

EPA RLIMS CRL - REGION VTENTATIVELY IDENTIFIED COMPOUNDSREPORT PRODUCED ON: 24-JAN-95

SAMPLE ORGANIZATION: SUPERFUND SAMPLE BATCH ID: 950080SAMPLE REQUESTOR: SALLY IMES/TAT ACCOUNT NO: TFA301LABORATORY: CRL FACILITY: PETOSKEY

MUNICIPALA625SWLCS.O (ABNa in low level SF Water samples by G WELL FIELD

SAMPLE: 95TT01S01 FIELD: 95TT01S01 CONTROL TYPE: SAM

COLLECTED: 04-JAN-95 RECEIVED: 06-JAN-95 ANALYZED: 11-JAN-9S

COMPOUND EST. CONC. RT Q CAS NUMBER

2H-A2EPIN-2-ONEPHENOL, 2, 4 -BISUNKNOWNUNKNOWNUNKNOWNUNKNOWNUNKNOWNUNKNOWN

, HEXAHYDRO-(1,1-DIMETHYL)-

2305150825272975

JJJJJJJJ

9.4713.2723.1823.6426.3128.7630.9833.12

10560296764

ANALYZED BY: ;

PAGE NO. 4


Sample organization: SUPERFUNDSample Requestor: SALLY IMES/TATFacility: PETOSXEY MUNICIPAL WELL FIELDMatrix;DRINKING

Date Collected;04-JAN-95Date Extracted;09-PBC-94

Method:A625SWLCS.0

Sample Batch ID; 950080Account No: TFA301Sample ID: 95TT01D01

Units; ug/L

Date Received;06-JAN-95Date Analyzed;il-JAN-95

CAS NUMBER

108-95-2111-44-495-57-8541-73-1106-46-7100-51-695-50-195-48-7108-60-1106-44-5621-64-767-72-198-95-378-59-188-75-5105-67-965-85-0111-91-1120-83-2120-82-191-20-3106-47-887-68-359-50-791-57-677-47-488-06-295-95-491-58-788-74-4131-11-3208-96-899-09-283-32-951-28-5100-02-7132-64-9606-20-2121-14-284-66-2

7005-72-386-73-7100-01-6534-52-186-30-6101-55-3118-74-187-86-585-01-8

COMPOUND AMO

Phenolbis (2-Chloroethyl) ether2-Chlorophenol1,3-Dichlorobenzene1 , 4-DichlorobenzeneBenzyl alcohol1 , 2-Dichlorobenzene2-Methylphenolbis (2-Chloroisopropyl) ether4-MethylphenolN-Nitroso-di-n-propylamineHexachloroethaneNitrobenzeneIsophorone2-Nitrophenol2 , 4-DimethylphenolBenzoic acidbis ( 2-Chloroethoxy) methane2 , 4-Dichlorophenol1,2, 4-TrichlorobenzeneNaphthalene4-ChloroanilineHexachlorobutadiene4-Chloro-3-methylphenol2 -Methy InaphthaleneHexachlorocyclopentadiene2,4, 6-Trichlorophenol2,4, 5-Trichlorophenol2-Chloronaphthalene2-NitroanilineDimethylphthalateAcenaphthylene3-NitroanilineAcenaphthene2 , 4-Dinitrophenol4-NitrophenolDibenzofuran2 , 6-Dinitrotoluene2 , 4-DinitrotolueneDiethylphthalate,4-Chlorophenyl-phenyletherFluor ene4-Nitroaniline4 , 6-Dinitro-2-methylphenolN-Nitrosodiphenylamine4-Bromophenyl-phenyletherHexachlorobenzenePentachlorophenolPhenanthrene

UNT QUALIFIERS

5 U5 U5 U5 U5 U5 U5 U5 U5 U5 U5 U5 U5 U5 U5 U5 U20 U5 U5 U5 U5 U5 U5 U5 U5 U5 U5 U20 U5 U20 U5 U5 U20 U5 U20 U20 U5 U5 U5 U5 U5 U5 U20 U20 U5 U5 U5 U20 U5 U

pg/0610 Page N.I of 10

EPA RLIMS CRL - REGIONFINAL RESULTS REPORT

Parameter ;ABNSample organization; SUPERTUNDSample Requestor; SALLY IMES/TATFacility; PETOSKEY MUNICIPAL WELL FIELDMatrix; DRINKING Method; A6 25 SVTLCS . 0

Date Collected; 04-JAN-95Date Extracted; 09-DEC-M

-r

Analyzed by:

Team Leader:

Sample Batch ID; 950080Account No; TFA301Sample ID; 95TT01D01

Units; ug/L

Date Received;06-JAN-95Date Analyzed;ll-JAN-95

CAS NUMBER

120-12-784-74-2206-44-0129-00-085-68-791-94-156-55-3218-01-9117-81-7117-84-0205-99-2207-08-950-32-8193-39-553-70-3191-24-2

COMPOUND AMO

AnthraceneDi-n-butylphthalateFluoranthenePyreneButylbenzylphthalate3,3' -DichlorobenzidineBenzo (a) anthraceneChrysenebis ( 2-Ethylhexyl) phthalateDi-n-octylphthalateBenzo (b) fluorantheneBenzo (k) fluorantheneBenzo (a) pyreneIndeno (1,2, 3-cd) pyreneDibenzo ( a , h) anthraceneBenzo (g,h, ijperylene

UNT QUALIFIERS


pg#0610 Page N.2 of 10



A625SWLCS.O (ABNs in low level SF Water samples by G^ ^ •» ^» ^ •• ^ ^ «* ^ ^ ^ ^

SAMPLE: 95TTQ1D01 FIELD: 95TT01D01 CONTROL TYPE: SAM


MUNICIPALWELL FIELE


COMPOUND


EST. CONG. RT Q CAS NUMBEF

2H-AZEPIN-2-ONE, HEXAHYDRO-UNKNOWNUNKNOWNUNKNOWNUNKNOWNUNKNOWN

2409768680

JJJJJJ

9.42 10560223.0228.7230.9332.9933.11

ANALYZED BY: f.

PAGE NO. 1


Sample organization; SUPERFUNDSample Requestor; SALLY IMES/TATFacility; PETOSKEY MUNICIPAL WELL FIELDMatrix;DRINKING Method;A62SSWLCS.O

Date Collected;04-JAN-95Date Extracted;09-1

Sample Batch ID; 950080Account No; TFA301Sample ID; 95TT01S02

Units; ug/L


CAS NUMBER

108-95-2111-44-495-57-8541-73-1106-46-7100-51-695-50-195-48-7108-60-1106-44-5621-64-767-72-198-95-378-59-188-75-5105-67-965-85-0111-91-1120-83-2120-82-191-20-3106-47-887-68-359-50-791-57-677-47-488-06-295-95-491-58-788-74-4131-11-3208-96-899-09-283-32-951-28-5100-02-7132-64-9606-20-2121-14-284-66-2

7005-72-386-73-7100-01-6534-52-186-30-6101-55-3118-74-187-86-585-01-8

COMPOUND AMO

Phenolbis (2-Chloroethyl) ether2-Chlorophenol1 , 3-Dichlorobenzene1 , 4-DichlorobenzeneBenzyl alcohol1 , 2-Dichlorobenzene2-Methylphenolbis(2-Chloroisopropyl) ether4-MethylphenolN-Nitroso-di-n-propylamineHexachloroethaneNitrobenzeneIsophorone2-Nitrophenol2 , 4-DimethylphenolBenzoic acidbis ( 2-Chloroethoxy ) methane2 , 4-Dichlorophenol1,2, 4-TrichlorobenzeneNaphthalene4-ChloroanilineHexachlorobutadiene4-Chloro-3-methylphenol2 -Me thy Inaphtha leneHexachlorocyclopentadiene2,4, 6-Trichlorophenol2,4, 5-Trichlorophenol2-Chloronaphthalene2-NitroanilineD imethy Iphtha lateAcenaphthylene3-NitroanilineAcenaphthene2 , 4-Dinitrophenol4-NitrophenolDibenzofuran2 , 6-Dinitrotoluene2 , 4-DinitrotolueneDiethylphthalate,4-Chlorophenyl-phenyletherFluorene4-Nitroaniline4 , 6-Dinitro-2-methylphenolN-Nitrosodiphenylamine4-Bromophenyl-phenyletherHexachlorobenzenePentachlorophenolPhenanthrene

UNT QUALIFIERS


pg/0610 Page N.9 of 10

EPA RLIMS CRL - REGIONFINAL RESULTS REPORTParameter:ABN

Sample organization! SUPERFUNDSample Requestor! SALLY IMES/TATFacility! PETOSKEY MUNICIPAL WELL FIELDMatrix;DRINKING Method:A62 SSWLCS.0

Date Collected!04-JAN-95Date Extracted!09-DEe~5-4

Sample Batch ID! 950080Account Noi TFA301Sample IDi 95TT01S02

Unitsi ug/L

Date Received!06-JAN-95Date Analyzed!ll-JAN-95

Analyzed by!

Team Leader !

CAS NUMBER

120-12-784-74-2

206-44-0129-00-085-68-791-94-156-55-3

218-01-9117-81-7117-84-02Q5-99-2207-08-9

50-32-8193-39-553-70-3

191-24-2

COMPOUND AMO

AnthraceneDi-n-butylphthalateFluoranthenePyreneButylbenzylphthalate3 ,3 ' -DichlorobenzidineBenzo( a) anthraceneChrysenebis ( 2-Ethylhexyl) phthalateDi-n-octylphthalateBenzo(b) fluorantheneBenzo(k) fluorantheneBenzo( a) pyreneIndeno (1 ,2 ,3 -cd ) pyreneDibenzo ( a , h) anthraceneBenzo(g,h, ijperylene

UNT QUALIFIERS


i -2 - -

pg#0610 Page N.10 of 10



A625SWLCS.O (ABNs in low level SF Water samples by G

SAMPLE: 95TT01S02 FIELD: 95TT01S02 CONTROL TYPE: SAM

SAMPLE BATCH ID: 950080ACCOUNT NO: TFA301

FACILITY: PETOSKEYMUNICIPALWELL FIELD

COLLECTED: 04-JAN-95 RECEIVED: 06-JAN-95 ANALYZED: ll-JAN-95

COMPOUND

UNKNOWNCYCLOHEXENE, 3-CHLORO-UNKNOWNUNKNOWNUNKNOWNUNKNOWNCYCLOHEXANE, 1, 2-DICHLORO-UNKNOWNUNKNOWNUNKNOWNPHO8PHINE OXIDE, TRIPHENYL-

EST.

212817096229028586

CONG.

JJJJJJJJJJJ

RT Q

2.272.874.934.975.275.335.607.367.9610.6725.62

CAS NUMBER

2441976

822866

791286

ANALYZED BY:

PAGE NO. 5


Sample organization: SUPERFUNDSample Requestor; SALLY IMES/TATFacility: PETOSKEY MUNICIPAL WELL FIELDMatrix:DRINKING Method:A625SWLCS.0

Date Collected;04-JAN-95Date Extracted;09-pge-y<

Sample Batch ID;Account No!Sample ID;

950080TFA30195TT01D02

Units: ug/L


CAS NUMBER

108-95-2111-44-495-57-8541-73-1106-46-7100-51-695-50-195-48-7108-60-1106-44-5621-64-767-72-198-95-378-59-188-75-5105-67-965-85-0111-91-1120-83-2120-82-191-20-3106-47-887-68-359-50-791-57-677-47-488-06-295-95-491-58-788-74-4131-11-3208-96-899-09-283-32-951-28-5100-02-7132-64-9606-20-2121-14-284-66-2

7005-72-386-73-7100-01-6534-52-186-30-6101-55-3118-74-187-86-585-01-8

COMPOUND AMO

Phenolbis ( 2 -Chloroethy 1 ) ether2-Chlorophenol1 , 3-Dichlorobenzene1 , 4-DichlorobenzeneBenzyl alcohol1 , 2-Dichlorobenzene2 -Methy Iphenolbis(2-Chloroisopropyl) ether4 -Methy IphenolN-Nitroso-di-n-propylamineHexachloroethaneNitrobenzeneIsophorone2-Nitrophenol2 , 4 -Dime thy IphenolBenzoic acidbis ( 2-Chloroethoxy ) methane2 , 4-Dichlorophenol1,2, 4-TrichlorobenzeneNaphthalene4-ChloroanilineHexachlorobutadiene4-Chloro-3-methy Iphenol2 -Methy Inaphtha leneHexachlorocyc lopentad iene2,4, 6-Trichlorophenol2,4, 5-Trichlorophenol2-Chloronaphthalene2-NitroanilineD imethy Iphtha lat eAcenaphthy 1 ene3-NitroanilineAcenaphthene2 , 4-Dinitrophenol4-NitrophenolDibenzofuran2 , 6-Dinitrotoluene2 , 4-DinitrotolueneDiethylphthalate^4-Chlorophenyl-phenyletherFluorene4-Nitroaniline4 , 6-Dinitro-2-methy IphenolN-Nitrosodiphenylamine4 -Br omopheny 1-pheny letherHexachlorobenzenePentachlorophenolPhenanthrene

UNT QUALIFIERS




Sample organization: SUPERFUNDSample Requestor: SALLY IMES/TATFacility; PETOSKEY MUNICIPAL WELL FIELDMatrix;DRINKING Method;A62 S SWLCS.0

Date Collected;04-JAN-95Date Extracted;09 BBC 94

Samole Batch ID; 950080Account No: TFA301Sample ID; 95TT01D02

Units: ug/L


CAS NUMBER

120-12-784-74-2206-44-0129-00-085-68-791-94-156-55-3218-01-9117-81-7117-84-0205-99-2207-08-950-32-8193-39-553-70-3191-24-2

COMPOUND AMO

AnthraceneDi-n-butylphthalateFluoranthenePyreneButylbenzylphthalate3,3' -DichlorobenzidineBenzo ( a ) anthraceneChrysenebis (2-Ethylhexyl) phthalateDi-n-octylphthalateBenzo (b) f luorantheneBenzo (k) f luorantheneBenzo (a) pyreneIndeno (1,2,3 -cd) pyreneDibenzo ( a , h) anthraceneBenzo (g,h, ijperylene

UNT QUALIFIERS


Analyzed by:

Team Leader:

- e~




A625SWLCS.O (ABNs in low level SF Water samples by G

SAMPLE: 95TT01D02 FIELD: 95TT01D02 CONTROL TYPE: SAM


MUNICIPALWELL FIELE


COMPOUND


EST. CONG.

ANALYZED BY: r -

RT CAS NUMB El

UNKNOWNCYCLOHEXENE, 3-CHLORO-CYCLOHEZANE , 1 , 3 -DICHLORO-UNKNOWNUNKNOWNUNKNOWNUNKNOWNCYCLOHEXANE, 1, 2-DICHLORO-UNKNOWNUNKNOWN

2828S1201062498299

JJJJJJJJJJ

2.272.893.714.924.985.265.345.607.3510.66

244197655887780

822866

PAGE NO. 2

sr4^ UNITED STATES ENVIRONMENTAL PROTECTION AGENCY- **.

* REGION 5 CENTRAL REGIONAL LABORATORYor

I/ 536 SOUTH CLARK STREET

CHICAGO, ILLINOIS 60605

Date: "^ 2 4 1995

Subject: Review of Region 5 Data for SF 950080 PETOSKY MUNICIPAL WELL FIELD

From: Charles T. Elly, DirectorRegion 5 Central Regional Laboratory

To:

Attached are the results for SF 950080 PETOSKY MUNICIPAL WELL FIELDCRL request number D950080for analyses for PESTICIDESResults are reported for sample designations: 95TT01S01, 95TT01S02, 95TT01D01

95TT01D02, 95TT01R01

Results Status:( X ) Acceptable for Use for samples 95TT01S02. 95TT01D02 & 95TT01R01( X ) Data Qualified, but Acceptable for use for samples 95TT01S01 & 95TT01D01 due to low

surrogate recoveries (see below)( ) Data Unacceptable for Use

( ) Sewer Disposal Criteria Met; Exceptions: noneComments on Data Quality by Reviewer

Instrument performance audits were generally acceptable. MS/MSD were not required for thisdata set. The method blank and instrument blank did not contain target analytes above CRLdetection limits. The LCS/LCS duplicate data associated with this data set were acceptable. ThePE sample data were acceptable except for 1 TCL miss ( Endosulfan 1 ). All other pesticideswere within the acceptance windows. TCMX and DCS recoveries were acceptable for95TT01S02, 95TT01D02, 95TT01R01 but outside QC limits ( low ) in samples 95TT01S01 &95TT01D01. Trie data for these two samples are qualified as U J ( undetected, estimated ). Thelow surrogate recoveries may be attributed to matrix effects. These two samples became turbidwhen shaken and formed a solid layer at the bottom on settling. There were no analytes ofinterest detected in the samples.

Data are acceptable for use for 95TT01S02, 95TT01D02 & 95TT01R01: qualified but acceptablefor use for 95TT01S01 & 95TT01D01.

Comments by Laboratory Director or Quality Control Coordinator

Review Record for SF 950080 PETOSKY MUNICIPAL WELL FIELD

Erlinda Evangelista

ITeam Leader and Date ( X) Reviewed ( ) Unreviewed

Chi M. Tang

Section Chief and Date f (W Reviewed ( ) Unreviewed

QC Coordinator and Date ( ) Reviewed Unreviewed

JAN 2 4 1995

Data Management Coordinator (nd Date Received

Date Transmitted JAN 2 4 1995


Sylvia GriffinData Management CoordinatorRegion 5 Central Regional LaboratorySL- IOC


Comments:

EPA RLIMS CRL - REGION VFINAL RESULTS REPORTParameter! PEST/PCS' "*>"

Sample organization: SUPERFUND Sample Batch ID; 950080Sample Requestor; SALLY IMES/TAT Account Not TFA301Facility; PETOSXEY MUNICIPAL WELL FIELD Sample ID; 95TT01D01Matrix;DRINKING RLIMS Method!608W P/P DNS Units; ug/L

Date Collected;04-JAN-95Date Extracted:09-JAN-95

Analyzed by:

Team Leader: 44

Date Received;06-JAN-95Date Analyzed;10-JAN-95

CAS NUMBER

319846588997644830900210245739599886057172208

331265950293

72-43-5319857419868

5103-74-25103-71-9

7255972548

74219341031078

53494-70-557-74-98001352

COMPOUND AMO

Alpha-BHCLindaneHeptachlorAldrinHeptachlor EpoxideEndosulfan IDieldrinEndrinEndosulfan IIp,p'-DDTMethoxychlorBeta-BHCDelta-BHCGanuna-chlordaneAlpha-Chlordanep,p'-DDEp,p'-DDDEndrin AldehydeEndosulfan SulfateEndrin KetoneChlordane, TechnicalToxaphene

UNT QUALIFIERS

01 U J01 U J01 U J01 U J01 U J01 U J02 U J02 U J02 U J02 U J.1 U J01 U J01 U J01 U J01 U J02 U J02 U J02 U J02 U J02 U J.2 U J1 U J

pg*0610 Page N.I of 5

EPA RLIMS CRL - REGIONFINAL RESULTS REPORTParameter; PEST/PCS

Sample organization; SUPERFUND Sample Batch ID;Sample Requestor; SALLY IMES/TAT Account No;Facility; PETOSKEY MUNICIPAL WELL FIELD Sample ID;Matrix;DRINKING RLIMS Method!608W P/P DNS Units;

950080TFA3 019STT01D02ug/L

DateDate

Collected; 04-JAN-95Extracted; 09-JAN-95

Analyzed by:

Team Leader:


CAS NUMBER

319846588997644830900210245739599886057172208

331265950293

72-43-5319857419868

5103-74-25103-71-9

7255972548

74219341031078

53494-70-557-74-98001352

COMPOUND AMO

Alpha-BHCLindaneHeptachlorAldrinHeptachlor EpoxideEndosulfan IDieldrinEndrinEndosulfan IIp,p'-DDTMethoxychlorBeta-BHCDelta-BHCGamma-ChlordaneAlpha-Chlordanep,p'-DDEp,p'-DDDEndrin AldehydeEndosulfan SulfateEndrin KetoneChlordane, TechnicalToxaphene

UNT QUALIFIERS

01 U01 U01 U01 U01 U01 U02 U02 U02 U02 U.1 U01 U01 U01 U01 U02 U02 U02 U02 U02 U.2 U1 U

pg*0610 Page N.2 of 5

EPA RLIMS CRL - REGIONFINAL RESULTS REPORTParameter;PEST/P€B

Sample organization: SUPERFUNDSample Requestor: SALLY IMES/TATFacility; PETOSKEY MUNICIPAL WELL FIELDMatrix;DRINKING RLIMS Method;6oaw_P/P_DN8

Date Collected;04-JAN-95Date Extracted;09-JAN-95

Sample Batch ID:Account No:Sample ID:

8 Units;

950080TFA30195TT01R01ug/L

DateDate

Received; 06-JAN-9SAnalyzed; 10-JAN-95

Analyzed by:

Team Leader:

CAS NUMBER

319846588997644830900210245739599886057172208

331265950293

72-43-5319857419868

5103-74-25103-71-9

7255972548

74219341031078

53494-70-557-74-98001352

COMPOUND AMO

Alpha-BHCLindaneHeptachlorAldrinHeptachlor EpoxideEndosulfan IDieldrinEndrinEndosulfan IIp,p'-DDTMethoxychlorBeta-BHCDelta-BHCGamma-ChlordaneAlpha-chlordanep,p'-DDEp,p'-DDDEndrin AldehydeEndosulfan SulfateEndrin KetoneChlordane, TechnicalToxaphene

UNT QUALIFIERS


pg#06io Page N.3 of 5

Sample organization: SUPERFUNDSample Requestor: SALLY IMES/TATFacility; PETOSKEY MUNICIPAL WELL FIELD

EPA RLIMS CRL - REGIONFINAL RESULTS REPORTParameter; PEST /Peg

Sample Batch ID;Account No;Sample ID!

950080TFA3019STT01S01

Matrix;DRINKING

Date Collected;04-JAN-9SDate Extracted;09-JAN-95

RLIMS Method:608W P/P DNS

Analyzed by:

Team Leader:

Units: ug/L


CAS NUMBER

319846588997644830900210245739599886057172208

331265950293

72-43-5319857419868

5103-74-25103-71-9

7255972548

74219341031078

53494-70-557-74-98001352

COMPOUND AMO

Alpha-BHCLindaneHeptachlorAldrinHeptachlor EpoxideEndosulfan IDieldrinEndrinEndosulfan IIp,p'-DDTMethoxychlorBeta-BHCDelta-BHCGamma-ChlordaneAlpha-Chlordanep,p'-DDEp,p'-DDDEndrin AldehydeEndosulfan SulfateEndrin KetoneChlordane, TechnicalToxaphene

UNT QUALIFIERS

01 U J01 U J01 U J01 U J01 U J01 U J02 U J02 U J02 U J02 U J.1 U J01 U J01 U J01 U J01 U J02 U J02 U J02 U J02 U J02 U J.2 U J1 U J

pg#06io Page N.4 of 5

EPA RLIMS CRL - REGIONFINAL RESULTS REPORTParameter;

Sample organization; SUPERFUNDSample Requestor; SALLY IMES/TATFacility; PETOSKEY MUNICIPAL WELL FIELD

Sample Batch ID;Account No;Sample ID;

950080TFA30195TT01S02

Matrix:DRINKING

Date Collected;04-JAN-95Date Extracted;09-JAN-95

RLIMS Method:6 0 8W_P/P_DN8

Analyzed by:

Team Leader: a.,

Units; ug/L


CAS NUMBER

319846588997644830900210245739599886057172208

331265950293

72-43-5319857419868

5103-74-25103-71-9

7255972548

74219341031078

53494-70-557-74-98001352

COMPOUND AMO

Alpha-BHCLindaneHeptachlorAldrinHeptachlor EpoxideEndosulfan IDieldrinEndrinEndosulfan IIp,p'-DDTMethoxychlorBeta-BHCDelta-BHCGanuna-ChlordaneAlpha-Chlordanep,p'-DDEp,p'-DDDEndrin AldehydeEndosulfan SulfateEndrin KetoneChlordane, TechnicalToxaphene

UNT QUALIFIERS


pg#06io Page N.5 Of 5

UNITED STATES ENVIRONMENTAL PROTECTION AGENCY

"V, REGION 5 CENTRAL REGIONAL LABORATORY

J 536 SOUTH CLARK STREET&

CHICAGO. ILLINOIS 60605

Date: 'JAN 2 6 1995

Subject: Review of Region 5 Data for PETOSKEY NIUNICIPAL WELL FIELD (950080)

From: Charles T. Elly, Director (Ifa+Afe & /U^Region 5 Central Regional Laboratory

To: E^E

Attached are the results for: Petoskey Municipal Well Field (TFA301)CRL request number: 950080Analyzed for: ABNs OrganicsResults are reported for sample designations: Five water samples (95TT01S01, -S02, -D01,-D02 and -R01)

Results Status:

( X ) Acceptable for Use for most of the compounds. Please see below.( X ) Data Qualified, but Acceptable for Use for some of the compounds. See below.( ) Data Unacceptable for Use.( X ) Sewer Disposal Criteria Met; Exceptions: None.Comments on Data Quality by Reviewer:

• 4-Chloroaniline, 2-nitroaniline, 3-nitrotniline, and 4-oitroaniline were detected at trace levels in theLaboratory Blank sample. Became then were laboratory introduced contaminants, their results areflagged *B" (B - Found in Lab Blank sample) for sample 95TT01S01. These contaminants were notdetected in the rest of the site samples.

• The laboratory's accuracy data for 4-chloroaniline was slightly biased high for the in-house QC sample(Laboratory Control Sample - LCS). Because this compound was detected in the Lab Blank sample andin 95TTOIS01, (heir results are flagged estimated (J).

• No other data quality or QA/QC problems were observed.

Comments bv Laboratory Director or Oualiiv Control Coordinator:,

Review Record for Petoskey MWF - 950080 (TFA301) ABN Organics„ • > - 01-24-95

Team Leader Date ( X ) Reviewed ( ) Unreviewed

_Section Chief Bate ( /) Reviewed ( ) Unreyiewed

QC Coordinator Date ( ) Reviewed (iff Unreviewed

2 6 1995Data Nnagement Coordrtor and Date Received

Date Transmitted IAN 2 6 1995


Sylvia GriffinData Management CoordinatorRegion 5 Central Regional LaboratorySLO - IOC


Comments:

IBSEMIVOLATILE ORGANICS ANALYSIS DATA SHEET

EPA SAMPLE MO,

LAB BLANKLab Name: PETOSKEY MUNICIPAL WELL FIELD Contract: USEPA-IL

Lab Code: 5CRL Case No.: 950080 SAS No.: SDG No.:

Matrix: (soil/water) WATER

Sample wt/vol: 1000 (g/ml) mL

Level: (low/med) LOW

% Moisture: not dec. dec.

Extraction: (Sepf/Cont/Sonc) CONT

GPC Cleanup: (Y/N) Y pH: NA

Lab Sample ID: LAB BLANK

Lab File ID': >B8170

Date Received: 01/06/95

Date Extracted: 01/09/95

Date Analyzed: 01/11/95

Dilution Factor: 1.0

CAS NO. COMPOUND-CONCENTRATION.UNITS:

(ug/L or ug/Kg) ug/L

108-95-2111-44-495-57-8541-73-1106-46-7100-51-695-50-195-48-7108-60-1106-44-5621-64-767-72-198-95-378-59-188-75-5105-67-965-85-0111-91-1120-83-2120-82-191-20-3106-47-887-68-359-50-791-57-677-47-488-06-295-95-491-58-788-74-4131-11-3208-96-8606-20-2

Phenolbis ( 2 -Chloroethy 1 ) ether2-Chlorophenol -".- "-.""1, 3-Dichlorobenzene1 , 4-DichlorobenzeneBenzyl alcohol : - " • • ;1 , 2-Dichlorobenzene2 -Methy Iphenolbis ( 2-Chloroisopropyl ) ether4 -Methy IphenolN-Nitroso-di-n-propylamineHexachloroethaneNitrobenzeneIsophorone2-Nitrophenol2 , 4-DimethylphenolBenzoic acidbis ( 2-Chloroethoxy ) methane2 , 4-Dichlorophenol1,2, 4-TrichlorobenzeneNaphthalene4-ChloroanilineHexachlorobutadiene4-Chloro-3-methylphenol2-MethylnaphthaleneHexachlorocyclopentadiene2,4, 6-Trichlorophenol2,4, 5-Trichlorophenol2-Chloronaphthalene2-NitroanilineDimethylphthalateAcenaphthylene2 , 6-Dinitrotoluene

55555555555555552055556555552052555

UUUUUUUUUUUUUUUUUUUUUJ

UUUUUUUJUUU

FORM I SV-1 1/87 Rev

1CSEMIVOLATILE ORGANICS ANALYSIS DATA SHEET

EPA SAMPLE NO.

LAB BLANKLab Name: PETOSKEY MUNICIPAL WELL FIELD Contract: USEPA-IL

Lab Code: 5CRL Ca

Matrix: (soil/water) WATER Lab Sample ID: LAB BLANK

Sample wt/vol:' 1000

Level: (low/med) LOW

% Moisture: not dec. -

(g/ml) inL Lab File ID.- >B8170

Date Received: 01/06/95

dec. Date Extracted: 01/09/95

Extraction: (Sepf/Cont/Sonc) CONT Date Analyzed: 01/11/95

GPC Cleanup: (Y/N) Y

CAS NO.

99-09-283-32-951-28-5100-02-7132-64-9121-14-284-66-27005-72-386-73-7100-01-6534-52-186-30-6101-55-3118-74-187-86-585-01-8120-12-784-74-2206-44-0129-00-085-68-791-94-156-55-3218-01-9117-81-7117-84-0205-99-2207-08-950-32-8193-39-553-70-3191-24-2

Are there any

pH: NA Dilution Factor: 1.0

CONCENTRATION UNITS:COMPOUND (ug/L or ug/Kg) ug/L Q

3-NitroanilineAcenaphthene2 , 4-Dinitrophenol4-NitrophenolDibenzofuran2,4-Dinitrotoluene :

Diethylphthalate4-Chlorophenyl-phenyletherFluorene4-Nitroaniline4 , 6-Dinitro-2-methylphenolN-Nitrosodiphenylamine4-Bromophenyl-phenyletherHexachlorobenzenePentachlorophenolPhenanthreneAnthraceneDi-n-butylphthalateFluoranthenePyreneButylbenzylphthalate3,3' -DichlorobenzidineBenzo(a) anthraceneChrysenebis ( 2 -Ethylhexyl ) phthalateDi-n-octylphthalateBenzo(b) fluorantheneBenzo(k) fluorantheneBenzo( a) pyreneIndeno (1,2, 3-cd) pyreneDibenzo (a, h) anthraceneBenzo(g,h, ijperylene

135

2020555551120555

2055555555555555555

TICs? YES [ ] NO [X]

JUUUUUUUUJUUUUUUUUUUUUUUUUUUUUUU

. .FORM I SV-2 1/87 Rev


Sample organization: SUPERFUNDSample Requestor; SALLY IMES/TATFacility; PETOSXEY MUNICIPAL WELL FIELDMatrix:DRINKING Method;A62SSWLCS.O

Date Collected:04-JAN-95Date Extracted: 09-PEC-94-

- -

Sample Batch ID: 950080Account No: TFA301Sample ID; 95TT01R01

Units: ug/L

Date Received;06-JAN-95Date Analyzed:ll-JAN-95

CAS NUMBER

108-95-2111-44-495-57-8541-73-1106-46-7100-51-695-50-195-48-7108-60-1106-44-5621-64-767-72-198-95-378-59-188-75-5105-67-965-85-0111-91-1120-83-2120-82-191-20-3106-47-887-68-359-50-791-57-677-47-488-06-295-95-491-58-788-74-4131-11-3208-96-899-09-283-32-951-28-5100-02-7132-64-9606-20-2121-14-284-66-2

7005-72-386-73-7100-01-6534-52-186-30-6101-55-3118-74-187-86-585-01-8

COMPOUND AMG

Phenolbis ( 2-Chloroethyl) ether2-Chlorophenol1 , 3-Dichlorobenzene1 , 4-DichlorobenzeneBenzyl alcohol1 , 2-Dichlorobenzene2-Methylphenolbis ( 2-Chloroisopropyl) ether4-MethylphenolN-Nitroso-di-n-propylamineHexachloroethaneNitrobenzeneIsophorone2-Nitrophenol2 , 4-DimethylphenolBenzoic acidbis ( 2 -Chloroethoxy) methane2 , 4-Dichlorophenol1,2, 4-TrichlorobenzeneNaphthalene4-ChloroanilineHexachlorobutadiene4-Chloro-3-methylphenol2 -Methy InaphthaleneHexachlorocyclopentadiene2,4, 6-Trichlorophenol2,4, 5-Trichlorophenol2-Chloronaphthalene2-NitroanilineD imethy IphthalateAcenaphthylene3-NitroanilineAcenaphthene2 , 4-Dinitrophenol4-NitrophenolDibenzofuran2 , 6-Dinitrotoluene2 , 4-DinitrotolueneDiethylphthalate,4-Chlorophenyl-phenyletherFluorene4-Nitroaniline4 , 6-Dinitro-2-methylphenolN-Nitrosodiphenylamine4 -Br omopheny 1 -pheny 1 etherHexachlorobenzenePentachlorophenolPhenanthrene

UNT QUALIFIERS



EPA RLIMS CRL - REGIONFINAL RESULTS REPORTParameter:ABN

Sample organization: SUPERFUNDSample Requestor: SALLY IMES/TATFacility; PETOSKEY MUNICIPAL WELL FIELDMatrix;DRINKING Method;A62 S SWLCS.0

Date Collected;04-JAN-95Date Extracted;09-BBei»4'

Analyzed by:

Laadcr:

Sample Batch ID; 950080Account No: TFA301Sample ID; 95TT01R01

Units; ug/L


CAS NUMBER

120-12-784-74-2206-44-0129-00-085-68-791-94-156-55-3

218-01-9117-81-7117-84-0205-99-2207-08-950-32-8193-39-553-70-3191-24-2

COMPOUND AMO

AnthraceneDi-n-butylphthalateFluor anthenePyreneButylbenzylphthalate3,3' -DichlorobenzidineBenzo (a) anthraceneChrysenebis ( 2-Ethylhexyl) phthalateDi-n-octylphthalateBenzo (b) fluor antheneBenzo (k) f luorantheneBenzo (a) pyreneIndeno (1,2,3 -cd ) pyreneDibenzo ( a , h) anthraceneBenzo (g, h, i) perylene

UHT QUALIFIERS




SAMPLE ORGANIZATION: SUPERFUKDSAMPLE REQUESTOR: SALLY IMES/TATLABORATORY: CRL

SAMPLE BATCH ID: 950080ACCOUNT NO: TPA301FACILITY: PETOSKEY

MUNICIPALA625SWLCS.O (ABNs in low level SF Water samples by G WELL FIELD

SAMPLE: 95TT01R01 FIELD: 95TT01R01 CONTROL TYPE: SAM

COLLECTED: 04-JAN-95 RECEIVED: 06-JAN-95 ANALYZED: ll-JAN-95

COMPOUND EST. CONC. RT Q CAS NUMBER

UNKNOWNUNKNOWN HYDROCARBONUNKNOWN HYDROCARBONUNKNOWN HYDROCARBONUNKNOWN HYDROCARBON

ANALYZED BY: J***

75955

/fl//-*- "-1

JJJJJ

V: \~-^6r~*'5

2.3123.4225.4726.4327.36

PAGE NO. 3

ecology and environment, inc. · 2018. 5. 9. · ecology and environment, inc. nternationai...

Documents