engineering report for the kaieie mauka well (state … engineering report for the kaieie mauka well...

[

....

....

.... l1li

,.. ..

....

r Engineering Report for the

Kaieie Mauka Well (State Well No. 4708-03)

Papaikou, South Hiio, Hawaii

Submitta{ to:

Hawaii State Department of Health Safe Drinking Water Branch

Preparei by:

Tom Nance Water Resource Engineering 680 Ala Moana BOLk3vard . Suite 406

Honolulu, Ha~"aii 96813

On '.Beliaif I)f

Department of Water Supply County Of Hawaii

December 2002

;'\ I , • \ .•. ~ l .'

0;'" , .',' ... ,:, '

,,:. 1"l'~I'\')

.' L.c:.' "

E I I I

I I I I I I I I

Engineering Report for the

Kaieie Mauka Well (State Well No. 4708-03)

Papaikou, South Hilo, Hawaii

Suomittaf to:

Hawaii State Department of Health Safe Drinking Water Branch

Preparea oy:

Tom Nance Water Resource Engineering 680 Ala Moana Boulevard - Suite 406

Honolulu. Hawaii 96813

On fJ3eftaif of:

Department of Water Supply County of Hawaii

December 2002

r, I

I Tom Nance Water I Resource Engineering

[

[

[

I I I I I I

Professional Engineer Certification

The undersigned, being a registered professional engineer, certifies that:

1. He J{e/Sfre

has prepared the attached report and the information

contained therein is true to the best of

2. The water

His information and belief; and his/tier

produced by Kaieie Mauka Well (State Well No. 4708-03) , the name of source{s) [State 'Wt{{ 9{p(s).}

potable water system identified in the attached report, will comply with the State primary potable

water regulations contained in Hawaii Administrative Rules, Title 11, Chapter 20, Rules Relating to

Potable Water Systems, and will comply with the Rules and Regulations of the

Department of Water Supply, County of Hawaii , when said 'Department of 'Water supPfiJ, County of / 'lJoart{ of 'Water supPfiJ, City atttf County of !Jionofufu

drinking water system is operated and maintained in accordance with the instructions and information

contained in this report.

This work was prepared by me or under my supervision.

Tom Nance - President Tom Nance Water Resource Engineering

680 Ala Moana Boulevard, Suite 406 • Honolulu, Hawaii 96813-5411 • Phone: (808) 537-1141 • Fax: (808) 538-7757· E-mail: [email protected]

I

c c [

L

I I I I I

Table of Contents

1. General Information ................................................. . A. Project Description .......................................... . B. Name of Owner and Authorized Representative ...................... .

2. Physical and Hydrologic Characteristics of the Area ......................... . A. Location .................................................. . B. Climate ................................................... . C. Topography ................................................ . D. Geology and Foundation Conditions ............................... . E. Earthquake Considerations and Design Parameters ................... . F. Groundwater Conditions ....................................... . G. Flood Problems ............................................. . H. Conformance With Local Land Use Planning and Zoning Regulations ........ . I. Water Rights and Future Use by Others ............................ .

3. Extent of the Water Works System ...................................... . A. Nature and Extent of the Area to be Served ........................ . B. Population Served, Consumption Data, and Forecast Use ............... . C. Future Service Requirements ................................... . D. Provisions for Extending the Water Works System ................... . E. Required Capacity to Meet Fire Protection and Reserve Requirements ..... . F. Alternate Solutions Considered ................................. . G. Environmental and Economic Impact .............................. .

4. Potential Sources of Contamination ...................................... . A. Description of the Well Site .................................... . B. Design Well Draft ............................................. . C. Water Quality Data on Existing Wells in the Area .................... . D. Land Use Classification of the Surrounding Area ..................... . E. Existing or Potential Sources of Contamination in the Recharge Area . . . . . . .

5. Sources of Water Supply .............................................. . A. Nature of Soil Stratum Overlying the Aquifer ....................... . B. Probability of Contaminated Surface or Groundwater Entering

the Deep Aquifer ............................................ . C. Depth to Water Table and Location and Description of Wells in the Vicinity .. . D. Slope of the Water Table ...................................... . E. Potential Flooding or Earthquake Risk ............................. . F. Expected Water Quality or Quantity During Stress Conditions ........... . G. Factors Having the Potential to Contaminate or Reduce the

Quality of the Water Source .................................... . H. Alternative Control Measures to Reduce Contamination . . . . . . . . . . . . . . . . . I. Summary ................................................. .

6. Proposed Treatment Works ............................................ . A. Summary Description ........................................ . B. Site ...................................................... . C. Plant Facilities ............................................. . D. Basis of DeSign ............................................. . E. Water Disposal ............................................. . F. Operation and Maintenance ..................................... .

98-03

1 1 1 1 1 1 1 1 1 4 4 4 4 4 4 4 5 5 5 5 5 5 5 7 7 7 7 8 8

8 8 8 9 9

9 9 9 9 9 9 9 9 9 9

[

I

(

[

(

c

I I I I I

Table of Contents (continued)

7. Pumping Facilities . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . ... A. Purpose of Service .....•..................................... B. Pumping Layout ............................................. . C. Flow Requirements .......................................... . D. Liquid Characteristics ........................................ . E. Electric Power ............................................. . F. Pumping Arrangement ........................................ . G. Selected Pump .............................................. . H. Buildings and Other Structural Improvements ....................... . I. Water Hammer Considerations .................................. . J . Features of Construction ...................................... . K. Electrical Power ............................................ .

8. Finished Water Storage ............................................... . 9. Water Distribution System ............................................ . 1 O. Financing ......................................................... .

Appendix

A Pump Test Data and Interpretations

B

C

o

Montgomery Watson Harza Laboratories Analyses

Data Regarding USGS Monitor Well No. 4708-02

Specifications and Plan for the Well Pump

List of Figures

~ Ti tl e

1 Location Map .................................................... . 2 Site Plan ....................................................... . 3 Past and Projected Water Use in the Upper Areas of DWS' Paukaa-Papaikou

Water System ................................................... . 4 Pump Control Building ............................................. .

ii

~ 11 11 11 11 11 11 11 11 11 11 11 11 11 12 12

2 3

6 10

L I

r, .. , ~

[

[

[

~ I

I I I I I

This report has been prepared to comply with Hawaii Administrative Rules, Title 11 in order to certify the Kaieie Mauka Well (State Well No. 4708-03) as a new source of drinking water. The well will replace Papaikou Spring to supply upper elevation areas of the Hawaii County Department of Water

Supply (DWS) system in Papaikou, South Hilo, Hawaii. The format of this report follows the Department of Health (DOH) Guidelines dated January 2, 1996.

1 . General Information

2.

A. project Description. Construction and pump testing of the Kaieie Mauka well was completed in August 2002. Design to outfit and connect the well to the DWS system is currently in progress. This design work includes the following elements: a 100 GPM,

50-horsepower submersible pump and motor in the well itself; an adjacent 0.10 MG reinforced concrete tank; a perimeter fence and other miscellaneous site work; and

upgrades of the Supervisory Control and Data Acquisition (SCADA) system at DWS' existing Papaikou tank and well sites. Figure 1 shows the location of the well at 1130-foot elevation in upper Papaikou. Figure 2 is a layout of the site showing the well and

new tank in relation to DWS' existing 0.02 MG tank which is presently supplied by Papaikou Spring. When the new well and tank are completed, both the spring and the

0.02 MG tank will be taken out of service.

B. Name of Owner and Authorized Representative. The owner and operator of the well and

its related improvements is the Hawaii County DWS.

Physical and Hydrologic Characteristics of the Area

A.

B.

C.

D.

E.

Location. The Kaieie Mauka well is at 1130-foot elevation on the eastern slope of

Mauna Kea. It is also directly upslope from the community of Papaikou in the South Hilo District.

Climate. Based on the nearest rain gages, mean annual rainfall at the well site is on the order of 200 inches and it is reasonably well distributed throughout the year.

Topography. The site of the well and new tank is relatively level. However, the

overall mauka-to-makai slope in the general vicinity of the well is approximately 10 percent.

Geology and Foundation Conditions. The well site sits on a prehistoric lava flow from the Mauna Kea volcano. Based on the strata penetrated during drilling of the well, the

residual soil is a stiff silty clay on the order of 10 feet thick. Below the soil layer is

about 140 feet of sapprolite followed by relatively unweathered lava flows. Foundation

bearing strength for the well pad and new 0.10 MG storage tank are excellent.

EarthQuake Considerations and Design Parameters. All of the Island of Hawaii is

classified as Seismic Zone 4. This earthquake risk is reflected in the appropriate structural design parameters.

- 1 -

~ ,0002:-" l ::n<tJS HUlON 3ntll

......... 1 i

- - - -

········t-············· .. -··;

.+-I

- -

,-.... ..--

_=,-9 -11 w<o 3;:0

r--(f).,q-

..

.......... -.-+ ............ _-- -.-....... -.. -~ .. . I

- - - - - - -,-....- ; .. ~"

- -

wz a:o :::>eJl-<C LLO

o ...I

- -

I I I I I I I I I I I I I I I I I I I

PROPOSED 100,000 GALLON TAN~ OVERFLOW EL.= 1146.50 FINISH FLOOR EL.= 1132.00

o I"<t f-0::: II 0_ Z -~

W .. :::JW

~<i! () (j)

Tom Nance Water esource Engineering

680 ALA MOANA BLVD., SUITE 406 HONOLULU, HAWAII 96813

(808)537-1141 FAX:(808)538-7757

CLIENT:

DEPARTMENT OF WATER SUPPLY COUNTY OF HAWAII

CLIENT ADDRESS:

345 KEKUANAOA ST., SUITE 20 HILO, HAWAII 96720

JOB TITLE:

DWS JOB NO. 98-711

KAIEIE MAUKA EXPLORA TORY WELL

TMK: 2-7-02:PORTION 3

SHEET TITLE:

SITE PLAN

SCALE:

1" = 40'

JOB NUMBER:

98-03

DRAWN BY:

GS

CHECKED BY:

GF

APPROVED BY:

TN

DATE:

NOV 2002

SHEET NUMBER:

FIGURE 2

I I I I I I I I I

I I I I I I I I I

3 .

F.

G.

H.

I.

Groundwater Conditions. The well is located in the Onomea Aquifer System as

designated by the Commission on Water Resource Management (CWRM). This triangular-shaped, 180-square mile area extends along the shoreline from Hilo to

Pepeekeo Point and its inland end is at the top of Mauna Kea. The CWRM has set the

sustainable yield of this aquifer system at 147 MGD. The only known active well in the

aquifer system is No. 4706-01, DWS' Papaikou well located nominally downslope from

the Kaieie Mauka Well (its location is shown on Figure 1). DWS' present use of Well 4706-01 is on the order of 0.10 MGD.

Groundwater tapped by the Kaieie Mauka Well stands about 27 feet above sea level, is quite cool (660 to 670 F.), and has very low chlorides (less than 3 MG/L). Pump test

data are presented in Appendix A. Based on these data, a lack of a tidal response in

water level recordings, and the well's time-dependent drawdown and recovery, the

groundwater is not basal. Its source of recharge is far upslope where the rainfall is of lower temperature than near the coast.

It should be noted that a shallow, perched aquifer exists in the sapprolite at a depth of about 100 feet. Its potential yield is quite limited. This aquifer has been sealed off by

grouting the well's annulus so that it does not contribute to the water pumped by the well.

Flood Problems. No flooding of any kind at the site is expectable. The upslope area

tributary to the site is less than 5 acres in size. The site's 1130-foot elevation is far

above possible tsunami inundation.

Conformance With Local Land Use Planning and Zoning Regulations. The well is on land

designated Agricultural by the State and County (Zone A-20a). The well and related improvements are allowable uses for both State and County designations.

Water Rights and Future Use by Others. Well Construction and Pump Installation permits have been obtained from the CWRM. Since the Onomea Aquifer System is not a

groundwater management area, a water use permit is not required. The right to use the water accrues from ownership of the land on which the well is located.

Extent of the Water Works System

A.

B.

Nature and Extent of the Area to be Served. As indicated previously, the well will replace Papaikou Spring as the source of supply for upper elevation areas in DWS'

Papaikou System. This part of the service area is comprised of residences and small farms.

Population Served, Consumption Data. and Forecast Use. Water use in the portion of the

service area to be supplied by the Kaieie Mauka Well averaged 0.012 MGD in 1990 and

-4-

I I I I I I I I I

r:.i IW

I I I I I I

4.

C.

D.

E

F.

G.

reached a peak of 0.017 MGD in 1997. A modest growth to about 0.025 MGD in Year 2010 is projected by DWS. Figure 3 depicts past use and DWS' projection of future use.

Future Servjce ReQujrements. Based on the historic trend of water use, only a modest increase in future years is expected. The 100 GPM pump to be installed has more than sufficient capacity for foreseeable service requirements.

Provisions for Extending the Water Works System. There are no plans to extend the

water system at this time.

Required Capacity to Meet Fjre protection and Reserve Requirements. With the new

0.10 MG tank, reservoir storage to provide fire flow rates for required durations for agriculture and single family residences will be met (500 GPM for 0.5- and 2-hour

durations, respectively). An analysis of the hydraulic capacity of DWS' existing distribution system is not a part of this project.

Alternate Solutions Considered. There are two possible alternatives to the Kaieie Mauka well. One is to provide treatment of the Papaikou Spring water. The other is to

booster pump from DWS' lower elevation Papaikou well (No. 4706-01). Costs and dryperiod shortfalls of the spring's supply rule out the first alternative. Costs, operational flexibility, and redundancy make the Kaieie Mauka well more attractive

than the second alternative.

Envjronmental and Economic Impact. There will be only minimal environmental impact. The well, tank, and related improvements will be constructed on previously disturbed land next to DWS' existing 0.02 MG tank. Construction, outfitting, and operation of the

well are obviously far more expensive than continued use of Papaikou Spring without

treatment. However, DWS views the expense as necessary to continue to conform to

DOH's Safe Drinking Water regulations.

Potential Sources of Contamination

A. Description of the WeI! Site.

(1 ) Coordinates (Old Hawaiian Datum):

State Well No. 4708-03 TMK 2-7-02: Portion 3

t9Q 47' 42" 155 0 08' 03"

Latitude / / Longitu~

(2) The well is at elevation 1130 feet. Figure 2 depicts the topography at the well site.

-5-

-

_-------I'!!:I----------

0"1

30000

25000

5' 20000 a.. CJ ........ Q) CJ)

::::> .... 2 15000

~ Q)

~ Q)

~ 10000

5000

o 1990 1995

Figure 3. Past and Projected Water Use in the Upper Areas of DWS' Papaikou Water System

2000 2005

Year

2010

• ACTUAL USE -TREND OF ACTUAL USE -PROJECTED USE I

2015

30000

25000

20000

15000

10000

5000

o 2020

I I I I I I I I

[

[

I I I I I I

B.

C.

D.

E

(3)

(4)

(5)

The catchment area for surface runoff is less than five (5) acres. Perimeter drainage swales will be installed to intercept and direct offsite surface runoff

around the site. The "catchment area" for groundwater tapped by the well

includes the undeveloped upslope area of Mauna Kea. It is impossible to know how much of this upslope area is in the contributing watershed. The mauka-tomakai slope of the ground surface is about 10 percent.

Strata penetrated in drilling the well consisted of: residual soil to a depth of

10 feet; sapprolite (weathered volcanics) for about 140 feet; and relatively unweathered volcanics to the full depth of the well at 1300 feet.

The depth of the well is 1300 feet. The depth to groundwater from the 1130-foot pad elevation is approximately 1103 feet.

Design Well Draft. The well will be used to provide the present and projected supply

requirements shown on Figure 3. It will do this with several pump cycles each day at

100 GPM during each tank infill cycle.

Water Quality Data 00 ExjstjOg Wells jo the Area. Water quality data on the Kaieie Mauka Well, based on samples taken by DWS personnel during the 5-day constant rate test and analyzed by Montgomery Watson Harza Laboratories, can be found in Appendix

B. The only other active well in the near vicinity is State No. 4706-01, DWS' Papaikou well, which is located downslope at elevation 369 feet. Its very low salinity water

(chlorides of 4 MG/L) is similar to the Kaieie Mauka well.

Laod Use Classificatjoo of the Surroyodjng Area. All of the surrounding land is in the

State Agriculture District.

Existjng or Potential Soyrces of Cootaminatjoo jo the Recharge Area.

(1 )

(2)

(3)

(4)

Extent of Contributing Recharge Area: There is no way to determine how far up the slope of Mauna Kea the recharge area extends, although the temperature

of the water suggests it may extend far upslope. Land uses include extensive

grazing, forest reserve, and little or no ground cover at higher elevations in the alpine zone. As far as is known, no one resides in the upslope area.

Type of Contaminants: A modest amount of animal waste is the only known source of contamination.

Distance to the Well: Some grazing by a few cattle takes place within about

500 feet of the well.

Method of "Disposal": Animal wastes deposited on the ground surface.

-7-

I I I I I I I I I I I E

I I I I I I

5 .

(5) Depth from Contaminant Sources to the Groundwater Table: It is about 1100 feet from the ground to the top of the aquifer tapped by the Kaieie Mauka well. However, the shallow, perched groundwater aquifer in the sapprolite at a depth

of about 100 feet provides excellent natural protection. Contaminants

percolating downward would be intercepted by and retained in the shallow aquifer. They are not likely to reach the deep aquifer tapped by the well.

Sources of Water Supply

A. Nature of Soil Stratum Overlying the Aquifer. As described previously in Sections 2.0. and 4.A.(4), the residual soil is about 10 feet thick, the sapprolite (weathered

volcanics) extend to about 140 feet, and relatively unweathered lava flows exist below the sapprolite. Video logging of the borehole showed no fissures or faults. In fact, with

very few exceptions, the formations looked extremely "tight" over the full depth of the borehole and the actual yield of the well was a pleasant surprise.

B.

C.

D.

Probability of Contijminated Surface or Groundwijter Entering the Deep AQuifer. The

thickness of the sapprolite, the existence of a shallow, perched groundwater body

within this sapprolite, the almost complete absence of fractures in the lava layers below, and the 1100-foot vertical travel distance make contamination of the deep

aquifer highly unlikely. The extremely low nitrate value in the well water, for

example, indicates a lack of contamination from animal waste or even natural decomposition of vegetation in the Forest Reserve upslope.

Depth to Wijter Table and Location and Description of Wells in the Vicinity. As stated previously in Sections 4.A.(5) and 4.E.(5), the depth to groundwater tapped by the well

is 1103 feet. There are only two drilled wells in the general vicinity:

(1 )

(2)

No. 4708-02 is a nearby 4-inch diameter USGS monitor well. Due to what appears to be faulty construction of the well, the water level in the well stands 145 feet above sea level and there was no water level response in it during the

pump test of the Kaieie Mauka well (refer to Appendix C for additional information).

No. 4706-01 is an active DWS well which is nominally downslope and 1.9 miles

from the Kaieie Mauka well.

Slope of the Water Table. There are insufficient data to determine a slope of the water

table. The initial static level in Well 4706-01 was 21 feet. Compared to the 27-foot

level in the Kaieie Mauka well, a slope of 3.2 feet per mile is suggested. However,

intervening and as-yet unidentified geologic structural control could make this

computed 'slope" meaningless.

-8-


6 .

E

F.

G.

H.

I.

Potential Flooding or Earthquake Risk. There is absolutely no potential for flooding of the well site due to surface runoff or tsunami. With regard to earthquake risk, all of the island is classified as Seismic Zone 4. This risk is reflected in structural design

parameters.

Expected Water Quality or Quantity During Stress Conditions. Although there is no

operating history with the Kaieie Mauka well, the extensiveness of the recharge area, natural protection of the deep aquifer, and the minimal anticipated draft of the well

suggest that its quality and quantity will not change during stress conditions such as an extended drought.

Factors Having the Potential to Contaminate or Reduce the Quality of the Water Soyrce. As indicated by the previous descriptions in Sections 5.A, 5.B, and 5.F, there are

really no factors which have the potential to contaminate or otherwise reduce the quality of water pumped by the Kaieie Mauka well.

Alternative Control Measures to Reduce Contamination. No such measures are warranted.

Summary. The nature of the groundwater occurrence, the lack of development in the recharge area, and the pristine quality of the aquifer's water as shown by the data in

Appendix B all indicate that this well will continue to provide water meeting drinking water standards for the foreseeable future.

Proposed Treatment Works

A. Summary pescription. The only treatment will be the injection of chlorine into the pipeline from the well pump to the new 0.10 MG tank.

B.

C.

D.

E

F.

~. The chlorination facilities will be located inside the control building. The location of the building is shown on Figure 2. Figure 4 is a layout of the building itself.

Plant Facilities. A gas chlorinator with two 150-pound cylinders and automatic

switch over will be used.

Basis of Design. The chlorination system will be set to produce a chlorine residual of

1.0 PPM in the 100 GPM discharge rate of the pump.

Water Disposal. There is no wastewater stream associated with the chlorination process.

Operation and Maintenance. The feed rate of the chlorinator is manually adjusted.

Maintenance of the system will include regular replacement of the chlorine cylinders,

inspection of the system components, and measuring the chlorine residual.

-9-

.......... - ... ,.-,,-, .. - .............. .. 25'-8"

I~

~ CONTROL ROOM

1= CHLORINATOR

PUMP AND eX)

I STORAGE ROOM eX)

MOTOR CONTROL

I CENTER o

I~

~ = CHLORINATOR CHLORINE ':.t

ROOM STORAGE I eX)

~ If' I 1J II II U AT U dtl

~ 4" CONCRETE

V V I

SIDEWALK~

11' -0" 8'-0" 6'-8"

PUMP CONTROL BUILDING SCALE: 1/4" = 1'-0"

FIGURE 4 PUMP CONTROL BUILDING


7 .

8 .

Pumping Facilities

A.

B.

C.

D.

E

F.

G.

H.

I.

Purpose of Service. The well has been developed to replace Papaikou Spring as the

source of supply for upper areas of DWS' Papaikou system.

Pumping Layout. Layout of the well and related improvements are shown on Figure 2.

The pipeline from the pump to the tank will be 4-inch.

Flow Reguirements. Present and projected supply to be provided by the Kaieie Mauka well are depicted on Figure 3. Both the 100 GPM pump capacity and the 0.10 MG reservoir storage substantially exceed design standards for present and projected use.

Liguid Characteristics. The well pumps extremely fresh and cool (670 F.) water.

Electric Power. Power for the 50 horsepower submersible motor and other

miscellaneous electrical requirements at the site will be provided by extending HELCO's

three-phase power up Kaieie Road to the well site.

Pumping Arrangement. The pump will be automatically started and stopped by a level control switch in the new 0.10 MG tank.

Selected Pump. Pump plan and section drawings, as well as data on the selected pump, can be found in Appendix D.

Buildings and Other Structural Improvements. A 17' x 25.7' control building, 15-foot high reinforced concrete tank, and well pump pad are the structural elements of this

project.

Water Hammer Considerations. Owing to the negligible above ground pressure in the pipeline from the well to the tank, water hammer is not a design consideration for this pipe. Water hammer in the well pump's column pipe is handled by column check valves

installed at locations specified by the pump manufacturer.

J. Features of Construction. All improvements will be completed in a single phase of construction.

K. Electrical power. Power will be provided by HELCO. There are no plans to provide a generator for backup power in the event that HELCO's service is interrupted.

Finished Water Storage

As indicated previously, a new 0.10 MG, reinforced concrete storage tank will be constructed.

When completed, the existing 0.02 MG tank will be taken out of service.

- 11 -


Appendix A

Pump Test Data and Interpretations

I (

I

( No. of pages: ...l.L

Fax#SD.182

Torn Nance Water I Resource Engineering

Original I!f will 0 will not

be mailed to you.

September 3, 2002 02/397 (98-03)

I I I I I I I I I I I I I I I I

MEMORANDUM

TO:

,FROM:

SUBJECT,:

Shari Komata - DWS

TomNance~ ..

FAXED S£P - 3 2DD2

Pump Test Results for the Kaieie Mauka Exploratory Well, DWS Job No. 98-711

This memo and its attachments present and analyze the data compi/ed during the August 22nd step-drawdown test and August 26 to 30 constant rate test of the Kaieie Mauka Well. In general, the well's hydraulic capacity and water quality exceeded expectations.

Data Collection

Water Levels. Water levels were measured in two ways, with an airline and ,with a downhole pressure transducer (Solinst LT-15 Levelogger). Water levels measured with the more accurate

pressure transducer' are used for the analyses herein. In addition to the pumped well, a pressure transducer was installed in the nearby USGS Monitor Well to record its water levels.

Flowrate. Flowrate was determined with a 4-inch, propeller-type Water Specialties meter with an accumulating, gear-driven swing arm.

Temperatyre. Temperature was periodically measured with a HACH Sens/ons 5 meter and was also recorded at 1-minute intervals downhole with the Sotinst LT-15 Levelogger.

Water Quality. Periodically collected samples were measured for conductivity with the HACH

Sensions 5 meter and analyzed for chlorides by mercuric nitrate titration. DWS collected samples for the laboratory analyses required for Department of Health certification of' the well. These results are not yet available.

Step-Drawdown Pump Test on August 22, 2002

The step test was run' at three rates for about 45 minutes at each rate. The water level recorded during, this test is shown on Figure 1. On Figure 2, drawdown at the three rates has been

fitted to a curve which can be, used to predict drawdown at flowrates other than those tested. Data for

the fitted curve are tabulated below.

680 Ala Moana Boulevard, Suite 406 • Honolulu, Hawaii 96813-5411 • Phone: (808) 537 -1141' • Fax: (808) 538-7757· E-mail: [email protected]

A-1


; ,

(

Memo to: Shari Komata September 3, 2002 -- 02/397 Page two

Step Test Data

Flowrate Drawdown (GPM) (Feet)

185 0.36 288 0.69 385 1.02

Fitted Curve

S = AQ2+BQ

where: S = Drawdown in Feet Q = Flowrate in GPM A = 3.526 X 10-6

8 = 1.322 X 10-3

1'2 = 0.98

The initial, step-drawdown test demonstrated the following hydraulic characteristics of the well:

• The static water level stands between 26 and 27 feet above sea level. This is about 117 feet lower than in the nearby USGS Monitor Well.

• Drawdown and recovery were very, rapid and no time-dependent component of drawdown was

evident. These characteristics are typical for a well which taps basal groundwater rather than for wells which draw fr-om a high level groundwater compartment typically have a time

dependent drawdown. • The well is capable of producing water at far greater rates than tested. Drawdown at 700 GPM

would be less than three feet, for example.

• As shown on Table 1, the water pumped is cool (an average of about 67.5° F.) and has a salinity similar to high elevation rainfall (chlorides are less than 3.0 MG/L).

Constant Rate Pump Test From August 26 to 30, 2002

After an initial electrical problem was eliminated, a 96-hour constant rate test was run/from about 2:00 p.m. on August 26th to 2:00 p.m. on August 30th at an average rate of 366 GPM. The

recorded water level prior, during, and following this test is depicted on Figure 3. The recorded downhole temperature is shown on Figure 4 and the coincident water level in the USGS Monitor Well is shown on Figure 5. These data demonstrate the following performance characteristics:

, • Other than the semi-diurnal water level change due to barometric pressure, there was no time

dependent component of drawdown or recovery. As with the step test, this response is more typical of basal rather than hig~ level groundwater.

• Drawdown averaged about 0.9 feet throughout the test.

• • •

The downhole temperature varied between 67.0° and 67.8° F. and averaged 67.5° F. The extremely low salinity of the pumped water did not change throughout the test (Table 1).

There was no water level response in the USGS Monitor Well to pumping of the Kaieie Mauka Well.

A-2

I I I I I 1 1 1 1 1 1 ·1 I I 1 1 1 1 I

(

Memo to: Shari Komata September 3, 2002 -- 02/397 Page three

USGS Monitor Well

(

Water in the USGS Monitor Well is not 1he same as in the aquifer tapped by the Kaieie Mauka

Well. The water level is 117 feet higher in the USGS well; its level did not respond to pumping in the Kaieie Mauka Well; its level response to a passing storm is not indicative of· a true groundwater response (Figure 6); and its water temperature is more than two degrees lower than in the Kaieie

Mauka Well (compare Figures 4 and 7). Based on this, the effort and cost to continue having the USGS monitor the water level in this well would be more appropriately directed elsewhere.

Sizing of the Permanent Pump for the Kaieie Mauka Well

The Septel11ber 1999 engineering report prepared by TNWRE indicates that only a small, 50 GPM pump with a new 0.05 MG tank is needed to meet forecast demands in the immediate service zone.

In view of the well's actual capacity, DWS may want. to reassess the pump capacity and tank size.

Attachments

A-3


( (

Table 1

Temperature, Conductivity, and Chlorides of Pump Test Samples From the Kaieie Mauka Exploratory Well

Step Test Samples:

Day in Sample Flowrate Temperature Conductivity August 2002 Time (GPM) (0 F.) (~S/cm)

22 14:25 185 67.9 115

22 15:10 288 67.2 113

22 15:55 385 66.8 113

Constant Rate Test Samples:

Day in Sample Flowrate Temperature Conductivity August 2002 Time (GPM) (0 F.) (~S/cm)

26 14:00 367 67.7 114

20:00 367 67.6 113

27 02:00 367 67.6 113

14:00 367 67.5 112

20:00 367 67.6 112

28 02:00 367 67.5 112

14:00 367 67.5 112

29 02:00 367 67.4 112

14:00 367 67.4 112

30 02:00 367 67.4 112

14:00 367 67.3 112

A-4

Chlorides (MG/L)

2.7

2.6

2.6

Chlorides (MG/L)

2.6

2.6

2.6

2.6

2.6

2.6

2.6

2.6

2.6

2.6

2.6

::J en

27.50

27.25

27.00

:2 I- 26.75 ill ill l..L. '--'

ill 26.50 > ill ....J a: ill 26.25

~ 26.00

25.75

25.50

I-

I-

I-

13

.~

FIGURE 1. WATER LEVEL RECORDED DURING THE AUG. 22, 2002 STEP TEST

~1l~

~~ l00 ~('M ~"CRM. ..... " ;. t:.f~1!'A.. --. .,.~

". ,.,-

A~ ~~ I~ "

, •

~. rJI.t. I

~ , 'WV' ~

il • ..A~ 1rJ' A

V ' I"~ Y ~

V ~

. . . 13.5 14 14.5 15 15.5 16 16.5

HOUR OF THE DAY ON AUGUST 22, 2002

» I

01

A'

I I I I I I I E m

~ :l

~

~

~ [ "

I I I I I I

3.0 0

2.7 5

2.5 0

2.2 5

2.00

~ 1.75

w !:!:.. z ~ 1.50 Cl

~ Cl 1.25

1.00

0.75'

0.50

0.25 V

•.. ~ 0.00

o 100

( (

FIGURE 2. HYDRAULIC CAPACITY OF THE KAIEIE MAUKA WELL BASED ON THE AUG. 22, 2002 STEP TEST DATA

/

/

/" V

200

y I

/ V

JI'

/ /

300 400

FLOWRATE (GPM)

500

• DATA POINTS --FITTED CURVE I

600

A-6

3.00

2.75

2.50

2.25

! /

V 2.00

1.75

1.50

1.25

1 .00

0 .75

0 .50

0 .25

O. 00

700

FIGURE 3. WATER LEVEL IN THE KAIEIE MAUKA WELL AUGUST 23 TO 30, 2002

27.50 r---T--I---i----r-----r---.,-----...,------.

27.25 r---I---t--~---l-~;-+---+---~---l--~

27.50

27.25

27.00 r---:1;~-:ii-;iA~::--t=-\--t-+---+---+---J--J---3 t 27.00

::::J C/) ~ 26.75 r---I---t----t-tH--+----+~-~+----l--l~ 0> 0>

LL

26.75

'"-"

0» 26.50 r----I---I---+-1H-+--~-+---_+---~---L-J 0> t 26.50

..J .... ~ 26.25 r---~~--T---t--HK-~--'----+---+---~--L~ > t 26.25

26.00 1---j-~--+----4---U---~ 11'--~ 26.00

25.75 r---l---t---t---+---+---+----J---~ t 25.75

25.50 .~.l..U£.WLU.LU.L~wu.u.wu.u.ww.&Jluu.wu.w.wu.w.ww.i.wJu.w.ww.u.u:...uwL.u.u.wJ.IW.U.LLLLU.IJu.w.LLLLU.I.LLW.LIwL.LLW.LI.u.u.w.u.u.wLWWLWJJ.LLuJ 23 24 25 25.50

26 27 28 . 29 30 31

Day in August 2002

» I

.....

_ _ .. r""I r""1 t~":j ..... ~ ~_.)'.MI_- - --- --

FIGURE 4. DOWNHOLE TEMPERATURE IN THE KAIEIE MAUKA WELL

68.5 f ~

68.0 ~ 1

~.5f I~

LL 67.0" I ." l' . (!) w £:) ~ 66.5 r---------~--------i-~------1---------+---------+---------~--------~--------J ::>

~ 66.0 w ~--~~~~~~~~~~-+----~------~----1-----~ a.. :::iE w I- 65.5 r---I---r-----.Jr--ff-t---:--t----+----+---~--L-i

65.0 ~ I. U "-\t4it .. ,,~ .. ·~-t_~,M ~

645 ~ I 1

29.5

29.0

28.5

28.0 @' :::iE I-w

27.5 ~

-' w >

27.0 ~ a: w I-

26.5 ~

26.0

25.5

64.0 ~ ttl t t t t t t t t t , tIt t t t , , t t t , , I , , , , , t , , , t , It,!, , t t , , , , It, , , , , t , t , t I, t"'" I,!" , , ~ 25.0

~ M ~ ~ V ~ 29 30 31

DAY IN AUGUST 2002

I~TEMPERATUR-E u_ .. WATERT-EVEC]

---,

~

,.. I

00

_-----~~~Li~--------

144.5

144.0

......... -1 (J)

~ 143.5 w w 1L --1

~ 143.0 w -1 """" ~ ex: w I-~ 142.5 -1 -1 W ~ (J) 142.0 CD (J) ::>

141.5

141.0 23 24

FIGURE 5. WATER LEVEL IN THE USGS MONITOR WELL DURING THE KAIEIE MAUKA PUMP TEST

.-. - -t~c..:

~-- -- --fO 1'i ff: t9F ~~

~~ ~""

.... , .......... ,a. JI/II\. ....... , .... r"P:".....- .. ~. J'I'III .........

25 26 27 28

DAY IN AUGUST 2002

- ... --- - ~

,..

~~ . ..... . .JJ ..'

29 30

I~USGS MONITOR WELL =-KAIEIE MAUKA WELL I

28.5

28.0

:::J Cf)

~

27.5 tu w !:S -1 W > 27.0 w -1

a: w J-«

26.5 ~

~ ::> « ~

26.0 !:!:! . w « ~

25.5

25.0

31

---."

-.,\

» I

<0

_ _ _ _ _ _ f"'""l r-1 C1 t~~oj t!!J .. .. - - - - - -

160 [

155 t ........ ....I

FIGURE 6. WATER LEVEL AND TEMPERATURE IN THE USGS MONITOR WELL JUNE 14 TO JULY 5,2002

I~

I. .. ::1 ::r-] 66.25

j 66.00

CJ) 150 :2: t 11\ . . II ] 65. 75 ~ f-ill W u.. -....I 145 w > ill ....I a: w ~ 140 s:

ill o .......

~ , , '- . I I I ~ 65.50 ~ ~ 1 ~. . , ~

ill a.. :2:

65.25 I=!

135 t T \ ] 65.00

130 t ' 1 64.75

1~ 1~ 1~ 1M 1~ 100

JULIAN DAY IN YEAR 2002

I-LEVEL -TEMP I

.--..,

-----

» , o

F1P"'1P"'1 ...... P"'I,....,,....,,....,F1,....,r"'1P"'1 ........ P"'I ........

FIGURE 7. WATER LEVEL AND TEMPERATURE IN THE USGS MONITOR WELL AUGUST 26 TO 3D, 2002

144.3 r-------------~--------------r--------------r------------~r-------------~

144.2 r------i------~t----:-----'--+-------~------J 144.1

....... 144 r---~---= ..... --I CJ)

~

ffi 143.9 r---------.:I-------t-------i-------~~~-----J ---~ 143.8 t----------.jf---I:----::----L w -I cr: W

~ 143.7 t-----I-I-UiII.

143.6 r---~~---t---------r-----------~-------~---------J 143.5

143.4 r--------~r-----------t-------+-------~-----------A

65.7

65.6

65.5

65.4 u::-(9

65.3 ~ ......-w a:

65.2 :::> ~ a: w

65.1 a. ~ w I-

65.0

64.9

64.8

64.7

30 31

I--WATER LEVEL -TEMPERATURE I

> , ......

.~

I I I I m

~

~

[

L [

[

[

t &

I I I ~

Appendix B

Montgomery Watson Harza Laboratories Analyses

I I I I I

[

[

[

[

I I I

DEPARTMENT OF WATER SUPPLY • COUNTY OF HAWAII

Mr. William Wo g, P.E., Chief Safe Drinking Water Branch Department of Health State of Hawaii P.O. Box 3378 Honolulu, HI 96801

345 KEKUANAOA STREET, SUITE 20 • HILO, HAWAII 96720

TELEPHONE (808) 961-8050 • FAX (808) 961-8657

November 25, 2002

KAIEIE MAUKA EXPLORATORY WELL LAB RESULTS

The following are the Kaieie Mauka Exploratory Well test results with the corresponding test method to the right (SM stands for Standard Method) for water quality parameters performed by our laboratory perso:QIlel. Mr. Oren Tsunezumi and Mr. Warren Sako conducted testing at the well site on September 25, 2002, at 1545 hours.

Conductivity (Field): pH (Field):

. Temperature (Field):

114.3 j.lS/cm SM2510B 7.98 SM4500-H+B

I8.8°C SM2550B

Please call Mr. Keith Okamoto or Ms. Mae Kise at the Department of Water Supply, Microbiology Laboratory, at (808) 961-8670 for more information if needed. .

Sincerely yours,

e~'E' Manager

MK:sco

copy -k. Greg Fukumitsu, Tom Nance Water Resource Engineering

." ''''', ".""~' or:," .' . ': , •. , ...... te· \ ' •• _ •. " ••.• ' ..... ' ",,·,~\·'O. ',. "'" .-~ .. , .. "-""''''~'''''''''' .,., .. ',-,". , .. -

B-1

r'l r,

DEPARTMENT OF WATER SUPPLY MICROBIOlOGICAllABORAfORY - 889lElLANI ST., HllO, HI 96720

Potable Water Sampling, Processing and Analyses Record Membrane Filtrotlon Ma/t;~ For T!1!J Do:, ;tion of Coliform Bllcteria

Audited by ...!!l.- on

Total Coliform Verification (LTBIBGLB) Total Sample

lab Point J.D. SampJin Number Number I/. Sample location f)/I

~~.2>qA1l"~ ~ 7'lSf ~CRd: .,.,..~ -"N' '7 /"'-tmu-

t:;f)vJ 'Pe'M0I\I 1

5O..,.Jl 1C"--1)N V

/(flC..

~.I""'" / .. c,.. .... 797S"

~iZ; 7'f!7r

tItIA.:;;. "/is-,,...::J .AGNII.:. '$f tI>.-7>to..

Collect {}.. ~-ed by ~ Dale If; Time/f ~

RefinqulShed by c:'~ Date S-/-rt..t.;;me IjI.;;>.s-Recefvedby t!2,~ ~ate tflH'/"LTime ljt";;{; Relinquished by ________ Date Trme __ _

Received by ~ate Time __ ._

Temp. Conlrol: Inilial ~ DC Final ___ DC

Sample Type Codes: RTE - Routine

RPT - Repeal

RPl • Replacement

S·Speciai

Membrane Filter ugend: o - No paat24houn, + - (lu at 241iours

g Residual Sampie Q -No ... at48~, (±) - Gu at 48.bours

Fecal Coliform Verif. Bacteria

Chlorine Type Sheen Non-8heen (BC) (No.lIOOmL)

1 2 3 4 5 6 7 8 9 10 ;Ufw ..s

'-,-v-n:- <9/9 4:1/6) <9/. 6>/1!$) 4>/$ ~

1'P7t:/ 4!9/<p G>/GP +7+ GPAlP $7_ , ~ D 0> 0 .c:!:) 0 c:!!) <£> to ~ cO

. ,/1;>.1,......

I /(,. / I~ I I¥" 7 It.

I~ /11> 1$'/16

-;;:1' v_ r;-/.r7;} 7.iA » 1$.$ ItS~ "~.S" :;"1ee>

f' I$';nil.S1~ 3'f7.7:$ ;~

'., ". .. ,:;;;. .. ".

7

. oale~nme I~()O -"""'F---r'-- Date I) (.. Time~ 3(,J.; 4 5~ 6~

¥l1fr~L!'l':::it S, aureus Ct lCW"M

Reported by_il __ 10.r..I.t '1 Dale .r$~;L. Time ~ ~. -

Verification:

lnocutated~-~..&..c Date -r~ Time /~ Readat24hrs.·by O. ~ . Date ~p..t4-Time "cn.~ Read al48 hrs. bY a· 7tr:Z"I: Date ;f/ • ., £-.L. Time 1~-H#::1' Conlrols: l TB (E. coli) 't l TB (S. aureus) 0

BGlB (E. coli) -I- BGlB (S. aureus) _-",0,--_

EC (E. coli) -I- EC (E. aerogenes) _0 __

No. Samples

Syslem CoUecled Reported by 1o ____ 0ale Time ___ _

Reported bY ____ 10 ____ OaI9 ____ Time __ _

Remarki: ~--------~------------

(MFCOU' 12127(01)

OJ I

I\)

.. r1

COUNTY OF_ HAWf\II DEPARTMENT OF WA"TERSUPPLY

MICROBiOlOGICAL LABORATORY- 889!LEIlANI ST .• HILO. HI 96720 Potable Water Sampling. Processing and Analyses Record

Membrane Filtration Method For The Detection of ColIform Bacteria

S8II1lIe Lab PointlD. SaJTClIIng

Number Nurriler Sample Location Time

~ K/Ttt?lf? ~w7f"'t?.u.y i/S'lFS' t.)¢<.-

2)/.r -==- IJJ./

8""f

p}( So-~ 7. 'f't! gJ

n.w- /'8',1 Cn-P<Jc,,,,,,..,,, .. 114 ~

~'PI7'Y- 0.<3/ ~-..G.s-~~S~ .....

CoIlectecJ by o.~CJ Date 1'/st'".. lime I~ ReI1nqu1shed by o·-,;r " Date 'Ift""- lIme..&L.CL Received by c:f'~""'-<!"'?7'= Date 9br',..... lImeiYL Relinquished by Date lIme __ _

Received by Date lime ___ .

Temp. Control: Initial IJ 6 ·C Anal ~ ·C

Sample Type Codes: RTE - Routine

RPT -Repeat

Rema'*s: pl1 '1..0::; '-/," I f'if ..,. <9 ,.. "7. '" I

,5t.,,.., ... ~2~c>

pu £.t:J.O":.. /0 •• 0

RPL - Replacement

S -Special

Audited by

• Total Colifonn VerifICation (L TBlBGLB) Total

Membrane AHer Lqpd; 0-No .11124....... • + - Goo 1124h0llll Fecal Cofrfonn Residual S,. G-NoPSII<4lhDOl'l, (J) -Goo II 48 hOllll Verif. Bacteria Chlorine Type Sheen Non-Sheen (EC) (NoJlOOmL)

1 2 3 4 5 6 7- 8 9 10 d.,iJ~ S D , I~ -.<'i:£. .:\ None Fauna

'-

!-

1

! i !

~ /

! ,

PreM!p!IYe~ ./ ~ InocuIat~ omeqfffi V" 11me /" .).:~ Inoculated by ________ Date nme __ _

Reedby~ omeo/'/¢~nme Ill;}';) Reedat2<4h1s.by Date nme __ _ Controls: 1 __ 2 __ 3 __ <4 __ 5 __ 6 __ Reed 8148 his. by Date nme __ _

E. coli S. IIU'eUS Controls: LTB (E. coli) L TB (5. aureus) ___ _

Rep(rted by ___ 10 Dale nme BGLB (E. coli) BGLB (5. aureus) __ _

EC (E. coli) EC (E. aerogenes) __ _

No. Samples

Svstem Collected Reported Reported by ___ 10 ___ Date ___ nme __ _

ReportedReportedby ___ 10 ___ Date ___ nme __ _

(MFCOU - 12117/99)

I I I I I I I·' ,.

[

[

[

I I I I

555 East Walnut Street Pasadena. California 91101 Tel: 626 568 6400 Fax: 626 568 6324 1 800 568 LABS (1 800 568 5227)

Laboratory Report

for

Hawaii Department of Water Supply (Hilo) 25 Aupuni St.

DATE OF ISSUE

OCT 1 0 iOOZ

MWH LABORATORIES

Hilo , HI 96720

Attention: Mae Kise Fax: (808) 961-8759

HDS Hillary Strayer Project Manager

~ ,.... 1-~ Q<"

Q,:- ~ (.) -(.) -I

< ~

01114CA

Report#: 100134 PHASEV

L.IIJoratory certifies that the test results meet all NELAC requirements unless ~ed in the Comments section or the Case Narrative. Following the cover page ~re Comments,QC Report,QC Summary,Data Report,Hits Report, totaling 44 page[s].

8-4

1'11\ RtftWhI-h..a~rat~t·i9::"'1 r-1 ~HJ::")J <r:'1 Ct;JTt::JYf'J:ce~A[t?~'1 A '~';"14 I~ .("'00" (3r '\UII MONTGOMERYWATSONHARZA {

~:~~~~~~E:~1101 FGlNCO~~ri" __ """-"""-::-==~::INBY;-""" -~~:=.:I (800) 566-5227 SAMPLES RECEIVED DAY OF <;sALECnON? (check for yes) !

Fax: (626) 568-6324. BLUE ICE: FROZEN \.,/pARTIALLY FROZEN THAWED I ........................................................................................................................................................................................................................................ = ............................................................ = ............................. ;;::::::; ................................. : TO BE COMPLETED BY SAMPLER: (check/or yes)

~"',..c ~AMDII:~ 1"1'" ,_ ... _ •••• ___

ITAT requested: t--STD 1 week 3 day 1 day COMPLIANCE SAMPLES REGULATION: -- -- I--

- Requires state forms (SDWA, PhaseV, NPDES, FDA, ... )

I,..",,~ • ~ll , UTILITY or PROJECT: ip.o.# I PROJECf JOB #: REFER TO ATTACHED BOTTLE ORDER FOR ANALYSES 0 (check for yes)

ANALYSES REQUIRED (mark an 'X' in all tests required for each sample line) :A MPI .F.1t c.u" ..,.J) NAME AND ..,.u,,~. V~.

Warrell ~iak()~ .an Oren Tsunezumi V'1",c-. --z- SAMPLER

~~ r.;l * COMMENTS

~~ SITE NAME or IDENTIFIER or STATE ID # ~ ~ ~ <Q LOCATION U

~ ~

, ·'i· ::~:.

;,,;~ CLIENT: DEPT. OF WATER SUPPLY N(J fE: D ~E ~O I tECE IPl Of j./ l-L_ AMI ~J:R r::IA t<:~ mTTLES FOR COUNTY OF HAWAII

NEW SOURCE TESTING =-= =-= !, ~S!. ~~ I.~[ ,.~! I"'IHI .... ~O~: ,. Fe ~~} ~~ III F, ~~~ BE ADVISED PROJECT: KAI EI E MAUKA .. ,. !, ...... .. ,

SITE NAME: VI • ~ ... ~ .... .' _. rr:v / "T/ ~c.J •

EXPLORATORY WELL . .... - -~ .. .. , ..... ft. " I ..... , .. , ............. ,. .....

, /' 7' roc 801 ITlE • "'j\ ~Du ~ , PI U" ~u ,~ ~UU.L' .LUI1I\L SAMPLE DATE: p'::'; :-;..-

SAMPLE TIME: '·5~ B EXl RA T( BE US ED ~ ADDITIONAl II 1'1::' i:'UI SAMPLER: ,,/. .,c

~ SAMPLE TYPE: GRAB -- -, .-\1 ~'4 L,.

* MATRIX TYPES: Reported b~ YO!llme: sw = Storm Water RepW1~d b~ W ~ight:

RSW = Raw Surface Water FW = Other Finished Water WW = Other Waste Water ~~DNNED RGW = Raw Ground Water CFW = Chlor(am)inated Finished Water CWW = Chlorinated Waste Water

DATE TIME

C-O-C# ____ _ PAGE __ OF __

I I I I I

10-1 S - 02 A 10: 5 4 IN wJI MWH Laboratories

555 E. Walnut St., Pasadena, CA 91101 PHONE: 626-568-6400/FAX: 626-568-6324

ACKNOWLEDGMENT OF SAMPLES RECEIVED

Hawaii Department of Water Supply (Hilo) 25 Aupuni St. Customer Code: Hilo, HI 96720 PO#: Attn: Mae Kise Group#: Phone: (808) 961-8670 Project#:

Proj Mgr: Phone:

HAWAII Contract 98-2,PHASE II/V 100134 PHASEV Hillary Strayer (800) 566-5227

The following samples were received from you on 08/30/02. They have been scheduled for the tests listed beside each sample. If this information is incorrect, please contact your service representative. Thank you for using MWH Laboratories.

lamPle# Sample Id Matrix Sample Date Tests Scheduled

8·6

~~~ __________________________ T_e_s_t __ A_c __ r_O_n_ym ___ D_e_s_c_r_1_'p __ t_i_o_n ____________________________ __

Test Acronym Descriptiori

',' " .::::=::-: : :: ::: :::::::: .,' ........ :.:::

.=-= .. :~:~:.:~r~~~\:/ .;:::::::.:::~t . .... :::.: .. :::.: .. :.:.:.::

ENDOTHAL :\F(:""" GLYPHOS

NI-MS Nickel, Total, ICAP/MS

I - 1 -

~- Hawaii Department of Water Supply (Hilo) I 25 Aupuni St. Customer

Hilo, HI 96720 Attn: Mae Kise

Code: PO#:

Phone: (808) 961-8670 Group#:

Project#: Proj Mgr: I

Phone:

18-13-J2 A1J:54 l~

HAWAII Contract 98-2,PHASE II/V 100134 PHASEV Hillary Strayer (800) 566-5227

I Test Acronym Description

I I I I

Test Acronym Description

' ..

- 2 -

8-7

I I ·1 I I· I I Ii .'

I I I I I I

Report Comments #100134

555 East Walnut Street Pasadana, Galilomia 91101 Tel: 626 568 6400 Fax: 626 568 6324 1 BOO 568 LABS (1 BOO 568 5227)

Group Comments

Analytical results for D1613SUB are submitted by Pace Anallytical, Minneapolis,MN HAWAII #SLD.

(QC Ref#: 180788) Test: 2-Butanone (MEK) (ML/EPA 524.2) QC Type: RPD Les

Trichlorofluoromethane recovered above QC limit in MS and MEK MSD not replicated to required precision. Defaulted to second LCS.

Test: Fluorotrichloromethane-Freon11 (ML/EPA 524.2) QC Type: MS

Trichlorofluoromethane recovered above QC limit in MS and MEK MSD not replicated to required precision. Defaulted to second LCS.

(QC Ref#: 182826) Test: Hexachlorocyclopentadiene (ML/EPA 525.2) QC Type: MS

Recovery low bias.

Comments - Page 1 of 1

8-8

I!" .... ' . Iij

I I I I ralYZed

555 East Walnut Street Pasadena, catlfornia 91101 Tel: 626 568 6400 Fax: 626 568 6324 1 800 568 LABS (1 800 568 5227)

Hawaii Department of Water Supply (Hilo)

Mae Kise 25 Aupuni St. Hilo , HI 96720

Sample# Sample ID

Laboratory Hits Report #100134

Samples Received

30-aug-2002 15:52:15

Result UNITS MRL

8-9

I 220B300156 KAIEIE MAUKA EXPLORATORY WELL

09/14/02

19/03/02 9/05/02

09/12/02

_9/04/02

'. 9/03/02 B/30/02

09/03/02

m

I I I I I I

2,3,7,B-Tcdd 1613 Drinking Wtr Alkalinity in CaC03 units Calcium, Total, ICAP Chromium, Total, ICAP/MS Fluoride Lab pH Nitrate as Nitrogen by IC Specific Conductance

I ~

SUMMARY OF POStTIVE DATA ONLY.

SUB PACE 55 9.B 1.9 0.10 B.1 0.19 11B

None mg/l mg/l ug/l mg/l Units mg/l umho/c

Hits Report - Page 1

1.000 1.000 1.000

.050

.001

.100 4.000

of 1

I 1 I 1

555 East Walnut Street Pasadena, California 91101 Tel: 626 568 6400 Fax: 626 568 6324 1 800 568 lABS (1 800 568 5227)

Hawaii Department of water Supply (Hilo)

Mae Kise 25 Aupuni St. Hilo I HI 96720

~repared Analyzed QC Ref# Method Analyte

1 J-j j -J 2 AI 0 : :5 S • )8·10

IN lJP/v

Laboratory Data Report #100134

Samples Received

08/30/02

Result Units MRL Dilution

~IEIE MAUKA EXPLORATORY WELL (2208300156) Sampled on . 09/03/02 00.00 180164 (SM2320B/E310.1) Alkalinity in CaC03 units 55

08/28/02 14:00 mg/l 1.0 1

1

1

1

1

1

1

1

1

1

1

1

1

1

1

1

1

1

1

1

1

1

1

09/04/02

1 1 I 09/05/02

1/05/02

/05/02

09/05/02

105/02

05/0.2

I I

09/12/02 12.02 180911

09/12/02 12.02 180918

09/12/02 12.02 180915

09/05/02 13.54 180301

09/12/02 12.02 180917

09/09/02 00.00 180539

09/12/02 12.02 180928

09/12/02 12.02 180907

09/14/02 00.00

09/03/02 13.54 180178

09/11/02 00.00 181106

09/04/02 00.00 180336

09/09/02 00.00 180574

09/21/02 15.30 181453

09/12/02 12.02 180906

08/30/02 13.04 180265

08/30/02 13.04 180266

09/12/02 12.02 180921

09/03/02 00.00 180192

09/12/02 12.02 180919

09/12/02 12.02 180912

09/12/02 12:02 180920

10/03/02 00:00 182826

10/03/02 00:00 182826

10/03/02 00:00 182826

10/03/02 00:00 182826

10/03/02 00:00 182826

10/03/02 00:00 182826

EPA/ML 200.8

EPA/ML 200.8

EPA/ML 200.8

ML/EPA 200.7

EPA/ML 200.8

SM4500CN-F

EPA/ML 200.8

EPA/ML 200.8

ML/S2510B

ML/EPA 548.1

SM4500F-C

ML/EPA 547

EPA/ML 245.1

EPA/ML 200.8

ML/EPA 300.0

ML/EPA 300.0

EPA/ML 200.8

Arsenic, Total, XCAP/MS

Barium, Total, XCAP/MS

Beryllium, Total, XCAP/MS

Calcium, Total, XCAP

Cadmium, Total, XCAP/MS

Cyanide

Chromium, Total, XCAP/MS

Copper, Total, XCAP/MS

2,3,7,8-Tcdd 1613 Drinking Wtr

Specific Conductance

Endothall

Fluoride

Glyphosate

Mercury

Nickel, Total, XCAP/MS

Nitrite, Nitrogen by XC

Nitrate as Nitrogen by XC

Lead, Total, XCAP/MS

S4500HB/E150.1) Lab pH

EPA/ML 200.8 ) Antimony, Total, XCAP/MS

EPA/ML 200.8

EPA/ML 200.8

Selenium, Total, XCAP/MS

Thallium, Total, XCAP/MS

525 Semivolatiles by GC/MS ML/EPA 525.2

ML/EPA 525.2

ML/EPA 525.2

ML/EPA 525.2

ML/EPA 525.2

ML/EPA 525.2

2,4-Dinitrotoluene

alpha-Chlordane

Diazinon

Acenaphthylene

Alachlor

Aldrin

NO

NO

NO

9.8

NO

NO

1.9

NO

SUB PACE

118

NO

0.10

NO

NO

NO

NO

0.19

NO

8.1

NO

NO

NO

NO

NO

NO

NO

NO

ND

ug/l

ug/1

ug/l

mg/l

ug/1

mg/1

ug/l

ug/l

None

umbo/cm

ug/l

mg/l

ug/l

ug/l

ug/1

mg/l

mg/l

ug/l

Units

ug/1

ug/1

ug/1

ug/l

ug/l

ug/l

ug/l

ug/l

ug/l

1.0

2.0

1.0

1.0

0.50

0.025

1.0

2.0

0.0000

4.0

5.0

0.050

6.0

0.20

5.0

0.10

0.10

0.50

0.0010

1.0

5.0

1.0

0.10

0.050

0.10

0.10

0.050

0.050

1

1

1

1

1

1

Data Report - Page 1 of 7

,... i...

I I I

Prepared

9/05/02

09/05/02

~9/05/02

~9/05/02 9/05/02

09/05/02

m9/05/02

W9/05/02

09/05/02

m:;::;:: 09/05/02

09/05/02

119/05/02

iW9/05/02

09/05/02

,,/05/02

~/05/02 09/05/02

~/05/02

~;::;:: 09/05/02 n/05/ 02 .

W/05/ 02

09/05/02

1/05/02

;, /05/02

/05/02

09/05/02

1/05/02

/05/02

09/05/02

1/05/02

/05/02

I I

555 East Walnut Street Pasadena, Callfomla 91101 Tel: 626 568 6400 Fax: 626 568 6324 1 800 568 LABS (1 800 568 5227)

Hawaii Department of water Supply (Hilo) (continued)

Analyzed

10/03/02 00:00

10/03/02 00:00

10/03/02 00: 00

10/03/02 00:00

10/03/02 00:00

10/03/02 00:00

10/03/02 00:00

10/03/02 00:00

10/03/02 00:00

10/03/02 00:00

10/03/02 00:00

10/03/02 00:00

10/03/02 00:00

10/03/02 00:00

10/03/02 00:00

10/03/.02 00: 00

10/03/02 00:00

10/03/02 00:00

10/03/02 00:00

10/03/02 00:00

10/03/02 00:00

10/03/02 00:00

10/03/02 00:00

10/03/02 00:00

10/03/02 00:00

10/03/02 00:00

10/03/02 00:00

10/03/02 00:00

10/03/02 00:00

10/03/02 00:00

10/03/02 00:00

10/03/02 00:00

10/03/02 00:00

10/03/02 00:00

10/03/02 00:00

QC Ref!!

182826

182826

182826

182826

182826

182826

182826

182826

182826

182826

182826

182826

182826

182826

182826

182826

182826

182826

182826

182826

182826

182826

182826

182826

182826

182826

182826

182826

182826

182826

182826

182826

182826

182826

182826

Method

ML/EPA 525.2

ML/EPA 525.2

ML/EPA 525.2

ML/EPA 525.2

ML/EPA 525.2

ML/EPA 525.2

ML/EPA 525.2

ML/EPA 525.2

ML/EPA 525.2

ML/EPA 525.2

ML/EPA 525.2

ML/EPA 525.2

ML/EPA 525.2

ML/EPA 525.2

ML/EPA 525.2

ML/EPA 525.2

ML/EPA 525.2

ML/EPA 525.2

ML/EPA 525.2

ML/EPA 525.2

ML/EPA 525.2

ML/EPA 525.2

ML/EPA 525.2

ML/EPA 525.2

ML/EPA 525.2

ML/EPA 525.2

ML/EPA 525.2

ML/SPA 525.2

ML/EPA 525.2

ML/EPA 525.2

ML/EPA 525.2

ML/EPA 525.2

ML/EPA 525.2

ML/EPA 525.2

ML/EPA 525.2

Analyte

Anthracene

Atrazine

Benz (a) Anthracene

Benzo(a)pyrene

Benzo (b) Fluoranthene

Benzo(g,h,i)Perylene

Benzo(k)Fluoranthene

Di(2-Ethylhexyl)phthalate

Butylbenzylphthalate

Bromacil

Butachlor

Caffeine

Chrysene

Dibenz(a,h)Anthracene

Di-(2-Ethylhexyl)adipate

Diethylphthalate

Dieldrin

Dimethylphthalate

Dimethoate

Di-n-Butylphthalate

Endrin

Fluoranthene

Fluorene

gamma-Chlordane

Hexachlorobenzene

Hexachlorocyclopentadiene

Heptachlor

Heptachlor Epoxide

Indeno(1,2,3,c,d)Pyrene

Isophorone

Lindane

Methoxychlor

Metribuzin

Molinate

Metolachlor

1 0-1'3 - J::: A 1 0: 55 I ~1


Result Units MRL

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ug/l

ug/l

ug/l

ug/l

ug/l

ug/l

ug/l

ug/l

ug/l

ug/l

ug/l

ug/l

ug/l

ug/l

ug/l

ug/l

ug/l

ug/l

ug/l

ug/l

ug/l

ug/l

ug/l

ug/l

ug/l

ug/l

ug/l

ug/l

ug/l

ug/l

ug/l

ug/l

ug/l

ug/l

ug/l

0.020

0.050

0.050

0.020

0.020

0.050

0.020

0.60

0.50

0.20

0.050

0.050

0.020

0.050

0.60

0.50

0.20

0.50

10

0.50

0.10

0.10

0.050

0.050

0.050

0.050

0.040

0.020

0.050

0.50

0.020

0.050

0.050

0.20

0.050

8-11

Dilution

1

1

1

1

1

1

1

1

1

1

1

1

1

1

1

1

1

1

1

1

1

1

1

1

1

1

1

1

1

1

1

1

1

1

1

Data Report Page 2 of 7

I I I

555 East Walnut Street Pasadena. California 91101 . Tel: 626 568 6400 Fax: 626 568 6324 1 800 568 LABS (1 600 568 5227)


10-13-02 Al0:56 IN


8-12

(continued)

1-------------------------Prepared

109/05/02

09/05/02

~9/05/02

!~9/05/02 9/05/02

09/05/02

~9/05/02 ~9/05/02

09/05/02

[

[

[

[

E ~8/31/02 08/31/02

1/06/02

09/06/02 1/06/ 02 '

I I

Analyzed

10/03/02 00:00

10/03/02 00:00

10/03/02 00:00

10/03/02 00:00

10/03/02 00:00

10/03/02 00 :00

10/03/02 00:00

10/03/02 00:00

10/03/02 00:00

QC Ref#

182826

182826

182826

182826

182826

182826

182826

182826

182826

Method

ML/EPA 525.2

ML/EPA 525.2

ML/EPA 525.2

ML/EPA 525.2

ML/EPA 525.2

ML/EPA 525.2

ML/EPA 525.2

ML/EPA 525.2

ML/EPA 525.2

Surrogate

Surrogate

Surrogate

Aldicarbs

Analyte

trans-Nonachlor

Pentachlorophenol

Phenanthrene

Prometryn

Propachlor

pyrene

Simazine

Thiobencarb

Trifluralin

l,3-dimethyl-2-nitrobenze

Perylene-d12 (70-130)

Triphenylphosphate

09/13/02 00:00 181018 ML/EPA 531.1 3-Hydroxycarbofuran

09/13/02 00:00 181018 ML/EPA 531.1 Aldicarb (Temik)

09/13/02 00:00 181018 ML/EPA 531.1 Aldicarb sulfone

09/13/02 00:00 181018 ML/EPA 531.1 Aldicarb sulfoxide

09/13/02 00:00 181018

09/13/02 00:00 181018

09/13/02 00:00 181018

09/13/02 00:00 181018

09/13/02 00:00 181018

09/13/02 00:00 181018

09/05/02 00:00

09/05/02 00:00

09/06/02 00:00

09/06/02 00:00

09/06/02 00:00

180689

180689

180572

180572

180572

ML/EPA 531.1

ML/EPA 531.1

ML/EPA 531.1

ML/EPA 531.1

ML/EPA 531.1

ML/EPA 531.1

Surrogate

Baygon

Carbofuran (FUradan)

Carbaryl

Methiocarb

Methomyl

Oxamyl (Vydate)

BDMC (70-130)

Diquat and Paraquat ML/EPA 549.2

( ML/EPA 549.2

Diquat

Paraquat

EDB and DBCP by GC-ECD ML/EPA 504.1

ML/EPA 504.1

ML/EPA 504.1

Surrogate

Dibromochloropropane (DBCP)

Ethylene Dibromide (EDB)

1,2-dibromopropane (surr)

l,2-dibromopropane(60-140)

Result

NO

NO

NO

NO

NO

NO

NO

NO

NO

90

81

103

NO

NO

NO

NO

NO

NO

NO

NO

NO

NO

103

NO

NO

NO

NO

NA

NA

Units

ug/l

ug/l

ug/l

ug/l

ug/l

ug/l

ug/l

ug/l

ug/l

It Rec

It Rec

It Rec

ug/l

ug/l

ug/l

ug/l

ug/l

ug/l

ug/l

ug/l

ug/l

ug/l

, Rec

ug/l

ug/l

ug/l

ug/l

%R

t Rec

MRL

0.050

1.0

0.020

0.50

0.050

0.050

0.050

0.20

0.10

2.0

0.50

0.70

0.50

2.0

0.90

2.0

2.0

1.0

2.0

6.40

2.0

0.010

0.010

0.0000

Dilution

l.

l.

l.

l.

l.

1

1

1

1

1

1

1

1

1

1

1

1

1

1

1

1

1

1

1


I 555 East Walnut Street Pasadena. CaHfornia 91101 Tel: 626 568 6400 Fax: 626 568 6324 1 800 568 LABS (1 800 568 5227)

I Hawaii Department of Water Supply (Hilo)

I (continued)

Prepared Analyzed QC Ref# Method Analyte

I 1It9/10/02 09/14/02 00,00 181471

1t9/10/02 09/14/02 00,00 181471

09/10/02

IU/10/02 i '9/10/02

09/10/02

E:~~:~:: 09/10/02

09/14/02 00,00 181471

09/14/02 00:00 181471

09/14/02 00,00 181471

09/14/02 00,00 181471

09/14/02 00:00 181471

09/14/02 00:00 181471

09/14/02 00:00 181471

09/10/02 09/14/02 00:00

1t99//1100//0022 09/14/02'00:00 I. 09/14/02 00:00

181471

181471

181471

181471

181471

181471

09/10/02 09/14/02 00:00

1(9/10/02' 09/14/02 00:00

~/10/02 09/14/02 00:00

[

I I I

09/10/02 00:00

09/10/02 00:00

180788

180788

09/10/02 00:00 180788

09/10/02 00,00 180788

09/10/02 00:00 180788

09/10/02 00,00 180788

09/10/02 00:00 180788

09/10/02 00:00 180788

09/10/02 00,00 180788

09/10/02 00,00 180788

09/10/02 00,00 180788

09/10/02 00,00 180788

09/10/02 00,00 180788

09/10/02 00,00 180788

Herbicides by 515.3 ( ML/EPA 515.3

ML/EPA 515.3

ML/EPA 515.3

ML/EPA 515.3

ML/EPA 515.3

ML/EPA 515.3

ML/EPA 515.3

ML/EPA 515.3

ML/EPA 515.3

ML/EPA 515.3

ML/EPA 515.3

ML/EPA 515.3

ML/EPA 515.3

ML/EPA 515.3

ML/EPA 515.3

Surrogate

2.4.5-T

2.4.5-TP (Silvex)

2.4-D

2.4-DB

Dichlorprop

Acifluorfen

Bentazon

Dalapon

3.5-Dichlorobenzoic acid

Tot DCPA Mono&Diacid Degradate

Dicarnba

Dinoseb

Pentachlorophenol

Picloram

4-Nitrophenol (qualitative)

24-D(70-130)

Regulated VOCs plus Lists 1&3 (- ML/EPA 524.2

ML/EPA 524.2

ML/EPA 524.2

ML/EPA 524.2

ML/EPA 524.2

ML/EPA 524.2

ML/EPA 524.2

ML/EPA 524.2

ML/EPA 524.2

ML/EPA 524.2

ML/EPA 524.2

ML/EPA 524.2

ML/EPA 524.2

ML/EPA 524.2

1. 1. 1. 2-Tetrachloroethane

1.1.1-Trichloroethane

1. 1. 2. 2-Tetrachloroethane

1, 1, 2-Trichloroethane

1.1-Dichloroethane

1.1-Dichloroethylene

l.l-Dichloropropene

1.2.3-Trichlorobenzene

1. 2. 3-Trichloropropane

1.2.4-Trichlorobenzene

1.2.4-Trimethylbenzene

1.2-Dichloroethane

1.2-Dichloropropane

1. 3. 5-Trimethylbenzene

'/ ()-l J - 0 2~j U: 56 I N


Result Units MRL

NO

NO

NO

NO

NO

NO

NO

NO

NO

NO

NO

NO

NO

NO

NO

98

NO

NO

NO

NO

NO

NO

NO

NO

NO

NO

NO

NO

ND

NO

ug/1

ug/1

ug/1

ug/l

ug/l

ug/l

ug/l

ug/l

ug/l

ug/l

ug/l

ug/l

ug/l

ug/l

ug/l

t Rec

ug/l

ug/l

ug/l

ug/1

ug/l

ug/l

ug/l

ug/l

ug/l

ug/l

ug/l

ug/l

ug/l

ug/l

0.20

0.20

0.10

2.0

0.50

0.20

0.50

1.0

0.50

0.20

0.080

0.20

0.040

0.10

1.0

0.50

0.50

0.50

0.50

0.50

0.50

0.50

0.50

0.50

0.50

0.50

0.50

0.50

0.50

8-13

Dilution

1

1

1

1

1

1

1

1

1

1

1

1

1

1

1

1

1

1

1

1

1

1

1

1

1

1

1

1

1

Data Report Page 4 of 7

I I I

555 East Walnut Street Pasadena, Calilomia 91101 Tel: 626 568 6400 Fax: 626 568 6324 1 800 568 LABS (1 800 568 5227)

Hawaii Department of Water Supply (Hila) ( continued)

Prepared Analyzed QC Ref# Method Analyte Result

[

r: ~

I I I

09/10/02 00:00 180788

09/10/02 00:00 180788

09/10/02 00:00 180788

09/10/02 00:00 180788

09/10/02 00:00 180788

09/10/02 00:00 180788

09/10/02 00:00 180788

09/10/02 00:00 180788

09/10/02 00:00 180788

09/10/02 00:00 180788

09/10/02 00:00 180788

09/10/02 00:00 180788

09/10/02 00:00 180788

09/10/02 00:00 180788

09/10/02 00:00 180788

09/10/02 00:00 180788

09/10/02 00:00 180788

09/10/02 00:00 180788

09/10/02 00:00 180788

09/10/02 00:00 180788

09/10/02 00:00 180788

09/10/02 00:00 180788

09/10/02 00:00 180788

09/10/02 00:00 180788

09/10/02 00,00 180788

09/10/02 00,00 180788

09/10/02 00:00 180788

09/10/02 00:00 180788

09/10/02 00:00 180788

09/10/02 00:00 180788

09/10/02 00:00 180788

09/10/02 00:00 180788

09/10/02 00:00 180788

09/10/02 00:00 180788

09/10/02 00:00 180788

ML/EPA 524.2

ML/EPA 524.2

ML/EPA 524.2

ML/EPA 524.2

ML/EPA 524.2

ML/EPA 524.2

ML/E~A 524.2

ML/EPA 524.2

ML/EPA 524.2

ML/EPA 524.2

ML/EPA 524.2

ML/EPA 524.2

ML/EPA 524.2

ML/EPA 524.2

ML/EPA 524.2

ML/EPA 524.2

ML/EPA 524.2

ML/EPA 524.2

ML/EPA 524.2

ML/EPA 524.2

ML/EPA 524.2

ML/EPA 524.2

ML/EPA 524.2

ML/EPA 524.2

ML/EPA 524.2

ML/EPA 524.2

ML/EPA 524.2

ML/EPA 524.2

ML/EPA 524.2

ML/EPA 524.2

ML/EPA 524.2

ML/EPA 524.2

ML/EPA 524.2

ML/EPA 524.2

ML/EPA 524.2

1.3-0ichloropropane

p-Oichlorobenzene (1.4-DCB)

2,2-0ichloropropane

2-Butanone (MEK)

o-Chlorotoluene

p-Chlorotoluene

4-Methyl-2-Pentanone (MIBK)

Benzene

Bromobenzene

Bromomethane (Methyl Bromide)

Bromoethane

cis-1,2-Dichloroethylene

Chlorobenzene

Carbon Tetrachloride

cis-1.3-Dichloropropene

Bromoform

Chloroform (Trichloromethane)

Bromochloromethane

Chloroethane

Chloromethane(Methyl Chloride)

Chlorodibromomethane

Oibromomethane

Bromodichloromethane

Oichloromethane

Di-isopropyl ether

Ethyl benzene

Oichlorodifluoromethane

Fluorotrichloromethane-Freon11

Hexachlorobutadiene

Isopropylbenzene

m-Oichlorobenzene (1,3-0CB)

m,p-Xylenes

Methyl Tert-butyl ether (MTBE)

Naphthalene

n-Butylbenzene

NO

NO

NO

NO

NO

NO

NO

NO

NO

NO

NO

NO

NO

NO

NO

NO

NO

NO

NO

NO

NO

NO

NO

NO

ND

ND

NO

NO

NO

NO

NO

NO

NO

NO

NO

Data Report


Units

ug/l

ug/l

ug/l

ug/l

ug/l

ug/l

ug/l

ug/l

ug/l

ug/l

ug/l

ug/l

ug/l

ug/l

ug/l

ug/l

ug/l

ug/l

ug/l

ug/l

ug/l

ug/l

ug/l

ug/l

uS/1

uS/l

ug/l

ug/l

ug/l

ug/l

ug/l

ug/l

ug/l

ug/l

ug/l

MRL

0.50

0.50

0.50

5.0

0.50

0.50

5.0

0.50

0.50

0.50

0.50

0.50

0.50

0.50

0.50

0.50

0.50

0.50

0.50

0.50

0.50

0.50

0.50

0.50

3.0

0.50

0.50

0.50

0.50

0.50

0.50

0.50

3.0

0.50

0.50

8-14

Dilution

1

1

1

1

1

1

1

1

1

1

1

1

1

1

1

1

1

1

1

1

1

1

1

1

1

1

1

1

1

1

1

1

1

1

1

Page 5 of 7

I I I

555 East Walnut Street Pasadena, CaliFomia 91101 Tel: 626 566 6400 Fax: 626 566 6324 1 600 566 LABS (1 600 568 5227)

Hawaii Department of Water Supply (Hila) (continued)

J- 1 3 - 0 2 Al 0 : 56 I i~


8-15

I------------------~-----Prepared Analyzed QC Ref# Method Analyte Result Units MRL Dilution

I----------------------~-09/10/02 00:00 180788 ML/EPA 524.2 n-Propylbenzene NO ug/l 0.50 1

I'J ... ". I)

rP/ 04 / 02

~/04/02 09/04/02

1/04/02

/04/02

/04/02

09/04/02

1/04/02

/04/02

09/04/02

1/04/02

/04/02

I I

09/10/02 00:00 180788 ML/EPA 524.2 o-xylene NO ug/l 0.50 1

09/10/02 00:00 180788 ML/EPA 524.2 o-Dichlorobenzene (1,2-DCB) NO ug/l 0.50 1

09/10/02 00:00 180788 ML/EPA 524.2 Tetrachloroethylene (PCE) NO ug/l 0.50 1

09/10/02 00:00 180788 ML/EPA 524.2 p-Isopropyltoluene ND ug/l 0.50 1

09/10/02 00:00 180788

09/10/02 00:00 180788

09/10/02 00:00 180788

09/10/02 00:00 180788

09/10/02 00:00 180788

09/10/02 00:00 180788

09/10/02 00:00 180788

09/10/02 00:00 180788

09/10/02 00:00 180788

09/10/02 00:00 180788

09/10/02 00:00 180788

09/10/02 00:00 180788

09/10/02 00:00 180788

09/06/02 00:00 180522

09/06/02 OO:UO 180522

09/06/02 00:00 180522

09/06/02 00:00 180522

09/06/02 00:00 180522

09/06/02 00:00 180522

09/06/02 00:00 180522

09/06/02 00:00 180522

09/06/02 00:00 180522

09/06/02 00:00 180522

09/06/02 00:00 180522

09/06/02 00:00 180522

ML/EPA 524.2 sec-Butylbenzene NO ug/l 0.50 1

ML/EPA 524.2 Styrene NO ug/l 0.50 1

ML/EPA 524.2 trans-1,2-Dichloroethylene NO ug/l 0.50 1

ML/EPA 524.2 tert-amyl Methyl Ether NO ug/l 3.0 1

ML/EPA 524.2 tert-Butyl Ethyl Ether NO ug/l 3.0 1

ML/EPA 524.2 tert-Butylbenzene NO ug/l 0.50 1

ML/EPA 524.2 Trichloroethylene (TCE) NO ug/l 0.50 1

ML/EPA 524.2 Trichlorotrifluoroethane(Freon NO ug/l 0.50 1

ML/EPA 524.2 trans-1,3-Dichloropropene NO ug/l 0.50 1

ML/EPA 524.2 Toluene NO ug/l 0.501

ML/EPA 524.2 Total THM NO ug/l 0.50 1

ML/EPA 524.2 Total xylenes NO ug/l 0.50 1

ML/EPA 524.2 Vinyl chloride (VC) NO ug/l 0.30 1

Surrogate

Surrogate

Surrogate

1,2-Dichloroethane-d4(70-130) 108 , Rec

4-Bromofluorobenzene(70-130) 102 , Rec

Toluene-d8(70-130) 97' Rec

SDWA Pesticides ML/EPA 508

ML/EPA 508

ML/EPA 508

ML/EPA 508

ML/EPA 508

ML/EPA 508

ML/EPA 508

ML/EPA 508

ML/EPA 508

ML/EPA 508

ML/EPA 508

ML/EPA 508

PCB 1016 Aroclor

PCB 1221 Aroc1or

PCB 1232 Aroclor

PCB 1242 Aroclor

PCB 1248 Aroclor

PCB 1254 Aroclor

PCB 1260 Aroclor

Alpha-BHC

Alachlor (Alanex)

Aldrin

Beta-BHC

Chlordane

NO

ND

ND

ND

ND

ND

NO

ND

NO

NO

ND

ND

Data Report

ug/l

ug/l

ug/l

ug/l

ug/l

ug/l

ug/l

ug/l

ug/l

ug/l

ug/l

ug/l

0.070

0.10

0.10

0.10

0.10

0.10

0.10

0.010

0.050

0.010

0.010

0.10

Page 6

1

1

1

1

1

1

1

1

1

1

1

1

of 7

I I I I

555 East Walnut Street Pasadena. C8t1lomia 91101 Tel: 626 568 6400 Fax: 626 568 6324 1 800 568 LABS (1 800 568 5227)

Hawaii Department of Water Supply (Hilo) (continued)

prepared Analyzed QC Ref# Method Analyte

9/04/02 09/06/02 00:00

09/04/02 09/06/02 00:00

19/04/02 09/06/02 00:00

9/04/02 09/06/02 00:00

9/04/02 09/06/02 00:00

09/04/02 09/06/02 00:00

19/04/02 09/06/02 00:00

9/04/02 09/06/02 00:00

09/04/02 09/06/02 00:00

m9/04/02 09/06/02 00:00

F 9/04/02 09/06/02 00:00

09/04/02 09/06/02 00:00

09/04/02 09/06/02 00:00

[9/04/02 09/06/02 00:00

9/04/02 09/06/02 00:00

09/04/02 09/06/02 00:00

[:/04/02 09/06/02 00:00

,. /04/02 09/06/02 00:00

[ III""

L

I I I I

180522

180522

180522

180522

180522

180522

180522

180522

180522

180522

180522

180522

180522

180522

180522

180522

180522

180522

ML/EPA 508

ML/EPA 508

ML/EPA 508

ML/EPA 508

ML/EPA 508

ML/EPA 508

ML/EPA 50S

ML/EPA 50S

ML/EPA 508

ML/EPA 508

-ML/EPA 50S

ML/EPA 50S

ML/EPA 508

ML/EPA 50S

ML/EPA 50S

ML/EPA 50S

ML/EPA 508

ML/EPA 50S

Surrogate

Surrogate

Chlorthalonil (Draconil,Bravo)

Delta-BHC

P,P' DDD

p,p' DDE

p,p' DDT

Dieldrin

Endrin Aldehyde

Endrin

Endosulfan I (alpha)

Endosulfan II (beta)

Endosulfan sulfate

Heptachlor

Heptachlor Epoxide

Lindane (ganuna-BHC)

Methoxychlor

Tetrachlorometaxylene (surr)

Dibutyl chlorendate (surr)

Toxaphene

Dibutyl Chlorendate(70-130)

Tetrachlorometaxylene(70-130)

: ':, -] 3 -C) 2 Ai ') : 5 5 I N

Result

NO

NO

NO

NO

NO

NO

NO

NO

NO

NO

NO

NO

NO

NO

NO

NO

NO

NO

S4

104


Units MRL

ug/l 0.010

ug/l 0.010

ug/l 0.010

ug/l 0.010

ug/l 0.010

ug/l 0.010

ug/l 0.010

ug/l 0.010

ug/l 0.010

ug/l 0.010

ug/l 0.010

ug/l 0.010

ug/l, 0.010

ug/l 0.010

ug/l 0.050

'R 0.0000

'R 0.0000

ug/l 0.50 , Rec , Rec

8-16

Dilution

l.

l.

l.

1

1

l.

1

l.

1

1

1

1

1

1

1

1

1

1


I I I

555 East Walnut Street Pasadena, California 91101 Tel: 626 568 6400 Fax: 626 568 6324 1 800 568 LABS (1 800 568 5227)


8-17

1:;-18-02 A10:56 IN~J Laboratory

QC Summary #100134

C Ref #180164 - Alkalinity in CaC03 units Analysis Date: 09/03/2002

I 2208300156 KAIEIE MAUKA EXPLORATORY WELL

~C Ref #180178 - Specific Conductance Analysis Date: 09/03/2002

2208300156 KAIEIE MAUKA EXPLORATORY WELL

Ic Ref #180192 - Lab pH Analysis Date: 09/03/2002


I " QC Ref #180265 - Nitrite, Nitrogen by IC Analysis Date: 08/30/2002

D ' ,~


DC Ref #180266 - Nitrate as Nitrogen by IC Analysis Date: 08/30/2002


QC Ref #180301 - Calcium, Total, ICAP Analysis Date: 09/05/2002 !'" ~ 2208300156 KAIEIE MAUKA EXPLORATORY WELL

ic Ref #180336 - Fluoride

2208300156

I

Analysis Date: 09/04/2002

KAIEIE MAUKA EXPLORATORY WELL

QC Ref #180522 - SDWA Pesticides Analysis Date: 09/06/2002


I I B QC Summary - Page 1 of 4

I E

555 East Walnut Street Pasadena, California 91101 Tel: 626 568 6400 Fax: 626 568 6324 1 800 568 LABS (t 800 568 5227)

1 () -I 8 - 0 2 A I !) : 51 1;-.

Laboratory QC Summary

#100134

8-18

I 1-------------------------

Hawaii Department of Water Supply (Hilo) ( continued)

IQC Ref #180539 - Cyanide Analysis Date: 09/09/2002


L ' '

QC Ref #180572 - EDB and DBCP by GC-ECD Analysis Date: 09/06/2002

C 2208300156 KAIEIE MAUKA EXPLORATORY WELL

[bC Ref #180574 - Glyphosate Analysis Date: 09/09/2002'


C QC Ref #180689 - Diquat and Paraquat Analysis Date: 09/05/2002

~ 2208300156 KAIEIE MAUKA EXPLORATORY WELL I

~

Oc Ref #180788 - Regulated VOCs plus Lists 1&3 Analysis Date: 09/10/2002


r '- Ref #180906 - Nickel, QC Total, ICAP/MS Analysis Date: 09/12/2002


Ref #180907 - Copper, Total, ICAP/MS Analysis Date: 09/12/2002


Ref #180911 - Arsenic, Total, ICAP/MS Analysis Date: 09/12/2002


QC Summary - Page 2 of 4

E I I I

555 East Walnut Street Pasadena, Calilomia 91101 Tel: 626 568 6400 Fax: 626 568 6324 1 800 568 LABS (1 800 568 5227)


Ref #180912 - Selenium, Total, ICAP/MS

; ,)- I J - 0 2 Ai,): ~ I i i~

Laboratory QC Swmnary

#100134



QC Ref #180915 - Beryllium, Total, ICAP/MS Analysis Date: 09/12/2002

E 2208300156 KAIEIE MAUKA EXPLORATORY WELL

[bC Ref #180917 - Cadmium, Total, ICAP/MS Analysis Date: 09/12/2002


[ QC Ref #180918 - Barium, Total, ICAP/MS Analysis Date: 09/12/2002

[ 2208300156 KAIEIE MAUKA EXPLORATORY WELL

~c " ~. Re·f #180919 - Antimony, Total, ICAP/MS Analysis Date: 09/12/2002


[ <i

QC Ref #180920 - Thallium, Total, ICAP/MS Analysis Date: 09/12/2002

m L 2208300156 KAIEIE MAUKA EXPLORATORY WELL

IC Ref #180921 - Lead, Total, ICAP/MS Analysis Date: 09/12/2002


We Ref #180928 - Chromium, Total, ICAP/MS Analysis Date: 09/12/2002


I [ QC Summary - Page 3 of 4

8-19

I 1


Laboratory QC Swmnary

#100134

8-20

1 11

-------------------------


IQC Ref #18101~ - Aldicarbs

2208300156

E "

QC Ref #181106 - Endothall

I 2208300156

!pc Ref #181453 - Mercury

2208300156

[







QC Ref #181471 - Herbicides by 515.3 Analysis Date: 09/14/2002

[

Ic [

I I 1 I I


Ref #182826 - 525 Semi volatiles by GC/MS Analysis Date: 10/03/20.02


QC Summary - Page 4 of 4

I I I I

[

[

(

I I I I I

QC

HS

LCS1

LCS2

HBLX

HS

HSD



QC Ref #180164 Alkalinity in CaC03

Analyte Spiked Recovered

Spiked sample Lab # 22 08300156

Alkalinity in CaCOl units 100 99.8

Alkalinity in CaCOl units 100 99.6

Alkalinity in CaCOl units NO <1.00

Alkalinity in CaCOl units 96.2 89,9

Alkalinity in CaCOl units 96.2 90.9

units

Units

HGL

HGL

HGL

HGL

HGL

HGL

1 c)- I 3 - 0 2 A'I 0: 57 . ) 8-21

I N wt'"

Yield ('II)

99.8

99.6

9l.5

94.5

Laboratory QC Report #100134

Limits ('II) RPD ('II)

0-0

90-110

90-110 0.20

80-120

80-120 1.1

RPD_LCS Alkalini ty in CaCOl units 99.800 99.600 HGL 0.2 0-10

RPD_MS Alkalinity in CaCOl units 93.451 94.491 MGL 1.1 0-10

QC Ref #180178 Specific Conductance

QC

DUP

QC

QC

DUP

QC

QC

LCS1

LCS2

MBLK

MS

MSD

Analyte Spiked Recovered Units Yield ('II). Limits ('II) RPD ('II)

Specific Conductance 118 115 UMBO 0-20 2.6

Ref #180192 Lab pH

Analyte Spiked Recovered Units Yield ('II) Limits ('II) RPD ('II)

Lab pH 8.l 8.l UNIT ( 0-20 0.0

Ref #180265 Nitrite, Nitrogen by :IC


Nitrite, Nitrogen by IC 1.0 0.989 MGL 98.9 90-110

Nitrite, Nitrogen by IC 1.0 0.996 MGL 99.6 90-110 0.71

Nitrite, Nitrogen by IC NO <0.10 MGL

Nitrite, Nitrogen by IC 1.0 0.959 MGL 95.9 80-120

Nitrite, Nitrogen by IC 1.0 0.968 MGL 96.8 80-120 0.9l

Spikes which exceed Limits and Method Blanks with positive results are highlighted by Underlining.

Criteria for MS and DUP are advisory only, batch control is based on LCS. Criteria for duplicates

are advisory only, unless otherwise specified in the method.

QC Report - Page 1 of 31

I I I

QC

LCSl

LCS2

HBLX

MS

MSD

QC

LCSl

LCS2

HBLK

HS

MSD

[ QC

MS

LCSl

LCS2

MBLK

MS

MSD

I I I



QC Ref #180266 Nitrate as Nitrogen


Nitrate as Nitrogen by IC 2.5 2.61


Nitrate as Nitrogen by IC NO <0.10



QC Ref #180301 Calcium, Total, I CAP


Calcium, Total, ICAP SO U.8

Calcium, Total, ICAP SO 49.3

Calcium, Total, ICAP NO <1.00



QC Ref #180336 Fluoride


Spiked sample Lab II 22 08290387

Fluoride 1. 00 0.981

Fluoride 1. 00 1.00

Fluoride NO <0.05

Fluoride 1. 00 0.993

Fluoride 1. 00 1. 02

by IC

Units Yield

HaL 104.4

HaL 104.4

HGL

HaL 102.4

HaL 111.6

Units Yield

HaL 99.6

HaL 98.6

HaL

HaL 99.8

MaL 103.4

Units Yield

HGL

MGL 98.1

HGL 100.0

MGL

MGL 99.3

MGL 102.0

1 ',j-I > 02 A'I 0 : 57 1 i':

<'II)

<'II)

<'II)

Laboratory QC Report

#100134

Limits <'II) RPD <'II)

90-110

90-110 0.00

80-120

80-120 8.6

Limits <'II) RPD <'II)

85-115

85-115 1.0

70-130

70-130 3.5

Limits ('II) RPD <'II)

0-0

90-110

90-110 1.9

80-120

80-120 2.7





8-22

I I I I

r ~

[

E [

r ... [

I I I I

QC

MBLK

MBLK

MBLK

LCS1

MBLK

MS

MSD

MBLK

MBLK

MBLK

LCS1

MBLK

MS

MSD

MS

LCS1

MBLK

MS

MSD

LCSl

MBLK

MS

MSD

LCSl

MBLIt

MS

MSD

MB'LIt

LCSl

MBLIt

555 East walnut Street Pasadena, Calilomia 91101 Tel: 626 569 6400 Fax: 626 568 6324 1 800 569 lABS (1 800 569 5227)


QC Ref #180522 SDWA Pesticides

1:)-'13-02 Al():57


#100134

Ii : ~

Analyte Spiked

NO

Recovered Units Yield (%) Limits (%) RPD (%)

PCB 1016 Aroc1or

PCB 1221 Aroc1or

PCB 1232 Aroclor

PCB 1242 Aroclor

PCB 1242 Aroclor

PCB 1242 Aroc1or

PCB 1242 Aroclor

PCB 1248 Aroclor

PCB 1254 Aroclor

PCB 1260 Aroclor

Alpha-BHC

Alpha-BHC

Alpha-SHC

Alpha-BHC

Spiked sample

Alachlor (Alanex)

Alachlor (Alanex)

Alachlor (Alanex)

Alachlor (Alanex)

Aldrin

Aldr:Ln

Aldrin

Aldrin

Beta-BHC

Beta-BHC

Beta-BHC

Beta-BHC

Chlordane



<0.07 UGL

NO

NO

0.500

NO

0.500

0.500

NO

NO

NO

0.050

NO

<0.10

<0.10

0.507

<0.10

0.557

0.608

<0.10

<0.10

<0.10

0.052

<0.01

0.050 0.053

0.050 0.054

Lab • 22 08300156

0.100

NO

0.100

0.100

0.050

ND

0.050

0.050

0.050

NO

0.050

0.050

NO

0.100

NO

0.113

<0.05

0.117

0.123

0.046

<0.01

0.049

0.050

0.053

<0.01

0.058

0.057

<0.10

0.084

<0.01

UGL

UGL

UGL

UGL

UGL

UGL

UGL

UGL

UGL

UGL

UGL

UGL

UGL

NONE

UGL

UGL

UGL

UGL

UGL

UGL

UGL

VGL

VGL

UGL

UGL

VGL

UGL

UGL

UGL

101.4

111.4

121.6

104.0

106.0

108.0

113.0

117.0

123.0

92.0

98.0

100.0

106.0

116.0

114.0

84.0

70-130

65-135

'65-135

62-122 )

57-127

57-127

0-0

70-130

65-135

65-135

56-116

51-121

51-121

65-125

60-130

60-130

( 61-121 )

8.8

1.9

5.0

2.0

1.7

Spikes which exceed Limits and Method Blanks with posi~ive results are highlighted by Underlining.



QC Report Page 3 of 31

8-23

I I E

E [

[

c

I I I I [

MS

MSD

LeS1

MBLK

MS

MSD

LeS1

MBLK

MS

MSD

LeS1

MBLK

MS

MSD

LeS1

MBLK

MS

MSD

LeS1

MBLK

MS

MSD

LeS1

MBLK

MS

MSD

LCS1

MBLK

MS

MSD

LCS1

MBLK

MS

MSD

LCS1

555 East Walnut Street Pasadena. california 91101 Tel: 626 568 6400 Fax: 626 568 6324 1 800 568 LABS (1 800 568 5227)




Delta-BHC

Delta-BHC

Delta-BHC

Delta-BHC

p,p' DOD

p,p' DOD

p,p' DOD

p,p' DOD

p,p' DOE

p,p' DOE

p,p' DOE

p,p' DOE

p,p' DDT

p,p' DDT

p,p' DDT

p,p' DDT

Dieldrin

Dieldrin

Dieldrin

Dieldrin

Endrin Aldehyde

Endrin Aldehyde

Endrin Aldehyde

Endrin Aldehyde

Endrin

Endrin

Endrin

Endrin






0.100

0.100

0.050

NO

0.050

0.050

0.100

NO

0.100

0.100

0.100

NO

0.100

0.100

0.100

NO

0.100

0.100

0.100

NO

0.100

0.100

0.100

NO

0.100

0.100

0.100

NO

0.100

0.100

0.050

NO

0.050

0.050

0.100

0.087

0.090

0.055

<0.01

0.057

0.058

0.113

<0.01

0.115

0.117

0.110

<0.01

0.111

0.116

0.106

<0.01

0.109

0.113

0.110

<0.01

0.111

0.115

0.088

<0.01

0.092

0.091

0.107

<0.01

0.110

0.113

0.054

<0.01

0.054

0.056

0.108

UGL

UGL

UGL

UGL

UGL

UGL

UGL

UGL

UGL

UGL

UGL

UGL

UGL

UGL

UGL

UGL

UGL

UGL

UGL

UGL

UGL

UGL

UGL

UGL

UGL

UGL

UGL

UGL

UGL

UGL

UGL

UGL

UGL

UGL

UGL

I J-I > J:2 i\ 1 0 : 58 I N

87.0

90.0

110.0

114.0

116.0

113.0

115.0

117.0

110.0

111.0

116.0

106.0

109.0

113.0

110.0

111.0

115.0

88.0

92.0

91.0

107.0

110.0

113.0

108.0

108.0

112.0

108.0


#100134

56-126

56-126

72-132

67-137

67-137

77-137

72-142

72-142

69-129

64-134

64-134

82-142

77-147

77-147

57-117

52-122

52-122

58-118

53-123

53-123

58-118

53-123

53-123

57-117

52-122

52-122

62-122

3.4

1.7

1.7

4.4

3.6

3.5

1.1

2.7

3.6


Criteria for MS and DUP are advisory only, batch control is based on Les. Criteria for duplicates



8-24

I I I I I

[

c

I I I

MBLK

MS

MSD

LCS1

MBLK

MS

MSD

LeS1

MBLK

MS

MSD

LCS1

MBLK

MS

MSD

LCS1

MBLK

MS

MSD

LCS1

MBLK

MS

MSD

LCS1

MBLK

KS

MSD

LCS1

MBLK

MS

MSD

MBLK

555 East Walnut Street Pasadena, GaRfomia 91101 Tel: 626 568 6400 Fax: 626 568 6324 1 BOO 568 LABS (1 800 568 5227)





Endosulfan sulfate

Endosulfan sulfate

Endosulfan sul.fate

Endosulfan sulfate

Heptachlor

Heptachlor

Heptachlor

Heptachlor

Heptachlor Epoxide

Heptachlor Epoxide

Heptachlor Epoxide

Heptachlor Epoxide

Lindane (gamma-BHC)

Lindane (gamma-BHC)

Lindane (gamma-BHC)

Lindane (gamma-BHC)

Methoxychlor

Methoxychlor

Methoxychlor

Methoxychlor









Toxaphene

NO

0.100

0.100

0.100

NO

0.100

0.100

0.050

NO

0.050

0.050

0.050

NO

0.050

0.050

0.050

NO

0.050

0.050

0.500

NO

0.500

0.500

100

100

l.00

100

100

100

100

100

NO

0.112

0.114

0.108

<0.01

0.114

0.116

0.048

<0.01

0.051

0.052

0.054

<o.oi 0.054

0.057

0.054

<0.01

0.055

0.057

0.516

<0.05

0.547

0.550

101

92

l.05

111

96

112

116

124

<0.50

UGL

UGL

UGL

UGL

UGL

UGL

UGL

UGL

UGL

UGL

UGL

UGL

UGL

UGL

UGL

UGL

UGL

UGL

UGL

UGL

UGL

UGL

UGL

%R

%R

tR

tR

tR

%R

tR

tR

UGL

:()-1~,-J2 A10:58

112.0

114.0

108.0

114.0

116.0

96.0

102.0

104.0

108.0

108.0

114.0

10.8.0

110.0

114.0

103.2

109.4

110.0

101.0

92.0

l.05.0

111.0

96.0

112.0

116.0

124.0


#100134

57-127

57-127

72-132

67-137

67-137

68-128

63-133

63-133

57-117

52-122

52-122

59-119

54-124

. ( 54-124

75-135

70-140

70-140

70-130

70-l.30

70-130

70-130

70-130

70-130

1.8

1.7

1.9

5.4

3.6

0.55

5.6

6.7




QC Report Page 5

8-25

of 31

I I I I I I

Ed l' "

I I I I I



lJ-lS-JZ ;\'10:5G IN


#100134

QC Ref #180539 Cyanide

QC Analyte Spiked Recovered units Yield (Ik) Limits (Ik) RPD (Ik)

MS Spiked sample Lab It 22 09070018 MGL 0-0

LCSl Cyanide 0.10 0.103 MGL 103.0 80-120

MBLlt Cyanide HD <0.03 MGL

MS Cyanide 0.10 0.093 MGL 93.0 80-120

MSO Cyanide 0.10 0.091 MGL 91.0 80-120 2.2

QCRef #180572 EDB and DBCP by GC-ECD

QC

MS

LCSl

LCB2

MBLlt

MS

MSO

RPO_MS

LCSl

LCS2

MBLlt

MS.

MSD

RPD_MS

LCSl

LCS2

MBLK

MS

MSD

RPD_MS

Analyte spiked Recovered units Yield (Ik) Limits (Ik) RPO (Ik)

Spiked sample Lab * 22 08290312 NONE 0-0 )

Dibromochloropropane (DBCP) 0.02 0.022 UGL 110.0 70-130


Dibromochloropropane (DBCP) HD <0.01 UGL


Oibromoch1oropropane (OBCP) 0.20 0.23 UGL 115.0 65-135 4.4

Dibromochloropropane (OBCP) 110.000 115.000 UGL 4.4 0-2'0

Ethylene Dibromide (BOB) 0.02 0.025 UGL 125.0 70-130

Ethylene Dibromide (EOB) 0.20 0.17 UGL 85.0 70-130

Ethylene Dibromide (BOB) HD <0.01 UGL

Bthylene Dibromide (BOB) 0.20 0.22 UGL 110.0 65-135

Ethylene Dibramide (BOB) 0.20 0.23 UGL 115.0 65-135 4.4

Ethylene Dibramide (EDB) 110.000 115.000 UGL 4.4 0-20

1,2-dibramopropane (surr) 100 106 IIsR 106.0 60-140

1,2-dibromopropane (surr) 100 98 IIsR 98.0 60-140 7.8

1,2-dibromopropane (surr) 100 99 IIsR 99.0

1,2-dibramopropane (surr) 100 137 IkR 137.0 60-140

1,2-dibramopropane (surr) 100 123 IkR 123.0 60-140 11

1,2-dibramopropane (surr) 137.000 123.000 IkR 10.8 0-20

Spikes which exceed Limits and Method Blanks with positive results are highlighted by underlining.


are advisory only. unless otherwise specified in the method.

8-26


I I I I I I

[

I I I I I

QC

MS

LCS1

MBLIC

MS

MSD

QC

MS

MSD

LeS1

MBLIC

MS

MSD

LCS1

MBLIC

MS

MSD

QC

LCS1

MBLK

MS

MSD

555 East Walnut Street Pasadena, Calilornia 91101 Tel: 626566 6400 Fax: 626 566 6324 1 800 566 LABS (1 600 566 5227)


QC Ref #180574 Glyphosate

Ana1yte Spiked Recovered


G1yphosate 10 11.3

G1yphosate ND . <6.00

G1yphosate 10 11.0

G1yphosate 10 11.7

QC Ref #180689 Diquat and Paraquat

Ana1yte Spiked Recovered



Diquat 10.0 8.1

Diquat ND <0.40

Diquat '10.0 8.6

Diquat 10.0 8.3

Paraquat 10.0 9.2

Paraquat ND <2.00

Paraquat 10.0 9.6

Paraquat 10.0 9.3

units

UGL

UGL

UGL

UGL

UGL

Units

NONE

NONE

UGL

UGL

UGL

UGL

UGL

UGL

UGL

UGL

QC Ref #180788 Regulated VOCs plus Lists

Ana1yte Spiked Recovered Units

1,1,1,2-Tetrach1oroethane 4 4.24 UGL

1,1, 1, 2-Tetrach1oroethane ND <0.50 UGL



lO--lS-J2 A1Q:5'J l>J

Yield <'Is)

113.0

110.0

117.0

Yield <'Is)

81.0

86.0

83.0

92.0

96.0

93.0

1&:3

Yield (lis)

106.0

115.0

114.0


#100134

Limits <'Is) RPD <'Is)

0-0

70-130

70-130

70-130 6.2


0-0 )

0-0 ) 0.00

70-130

70-130

70-130 3.6

70-130

70-130

70-130 3.2

Limits <'Is) RPD ('Is)

70-130

84-131

84-131 0.87

RPD_MS 1,1,1,2-Tetrach1oroethane 115.000 114.000 UGL 0.9 0-20





8-27

I I I I

[

[~ . 1

[

[

E I I I I I

LCSl

MBLK

MS

MSD

RPD_MS

LCSl

MBLK

MS

MSD

RPD_MS

LCSl

MBLK

MS

MSD

RPD_MS

LCSl

MBLK

MS

MSD

RPD_MS

LCSl

MBLK

MS

MSD

RPD_MS

LeS1

MBLK

MS

MSD

RPD_MS

LCSl

MBLK

MS

MSD

RPD_MS

1 0-1 ~,-:;2 A 1 0 : 5 :3 I N

555 East walnut Street Pasadena. California 91101 Tel: 626 568 6400 Fax: 626 568 6324 1 BOO 568 LABS (1 BOO 568 5227)


1. 1. 1-Trichloroethane



1. 1, 1-Trichloroethane

l,l,l-Trichloroethane

l,l,2,2-Tetrachloroethane





l,l,2-Trichloroethane





l,l-Dichloroethane

l,l-Dichloroethane

l,l-Dichloroethane

l,l-Dichloroethane

l,l-Dichloroethane

l,l-Dichloroethylene


l,l-Dich1oroethylene



l,l-Dichloropropene

l,l-Dichloropropene

l,l-Dichloropropene

l,l-Dichloropropene

l,l-Dichloropropene

l,2,3-Trichlorobenzene

l,2,3-Trich10robenzene




4

NO

10

10

126.000

4

NO

10

10

115.000

4

NO

10

10

113.000

4

NO

10

10

117.000

4

NO

10

10

104.000

4

NO

10

10

119.000

4

NO

10

10

99.100

4.79

<0.50

12.6

12.0

120.000

4.03

<0.50

11.5

11.5

115.000

4.02

<0.50

11.3

11.2

112.000

4.62

<0.50

11.7

11.5

115.000

4.29

<0.50

10.4

10.5

105.000

4.57

<0.50

11. 9

11.5

115.000

3.99

<0.50

9.91

10.5

105.000

UGL

UGL

UGL

UGL

UGL

UGL

UGL

UGL

UGL

UGL

UGL

UGL

UGL

UGL

UGL

UGL

UGL

UGL

UGL

UGL

UGL

UGL

UGL

UGL

UGL

UGL

UGL

UGL

UGL

UGL

UGL

UGL

UGL

UGL

UGL

119.8

126.0

120.0

4.9

100.8

115.0

115.0

0.0

100.5

113.0

112.0

0.9

115.5

117.0

115.0

1.7

107.2

104.0

105.0

1.0

114.2

119.0

115.0

3.4

99.8

99.1

105.0

5.8


#100134

( 70-130 )

70-130

70-130

0-20

70-130

70-130

70-130

0-20

70-130

70-130

70-130

0-20

70-130

70-130

70-130

0-20

70-130

70-130

70-130

0-20

70-130

81-127

81-127

0-20

70-130

70-130

70-130

0-20

4.9

0.00

0.89

1.7

0.96

3.4

5.8


Criteria for MS and DUP are advisory only. batch control is based on LCS. Criteria for duplicates



8-28

I 555 East Walnut Street Pasadena, GaUfomia 91101 Tel: 626 568 6400 Fax: 626 568 6324 1 800 568 LABS (1 800 568 5227)


iO-13-J2 A'iC):58 IN


#100134

8-29

[-------------------------

c c

[

[

[

I I I I

LCS1

MBLK

MS

MSD

RPD_MS

LCS1

MBLK

MS

MSD

RPD_MS

LCS1

MBLK

MS

MSD

RPD_MS

LCS1

MBLK

MS

MSD

RPD_MS

LCS1

MBLK

MS

MSD

RPD_MS

Lesl.

MBLK

MS

MSD

RPD_MS

LCS1

MBLK

MS

MSD

RPD_MS

1,2 , 3-Trichloropropane

1,2,3-Trichloropropane




1,2,4-Trichlorobenzene





1,2,4-Trimethylbenzene





1,2-Dichloroethane

1,2-Dichloroethane

1,2-Dich1oroethane

1,2-Dichloroethane

1,2-Dichloroethane

1,2-Dichloropropane

1,2-Dichloropropane

1,2-Dichloropropane

1,2-Dichloropropane

1,2-Dichloropropane

1, 3, S-Trimethylbenzene

1,3,5-Trimethy1benzene

1,3,5-Trimethy1benzene



1,3-Dichloropropane

1,3-Dichloropropane

1,3-Dichloropropane

1,3-Dichloropropane

1,3-Dichloropropane

4

ND

10

10

112.000

4

ND

10

10

99.000

4

ND

10

10

110.000

4

ND

10

10

122.000

4

ND

10

10

113.000

4

ND

10

10

111. 000

4

ND

10

10

117.000

4.16

<0.50

11.2

11.2

112.000

4.06

<0.50

9.90

10.0

100.000

4.35

<0.50

11.0

11.1

111.000

4.44

<0.50

12.2

12.0

120.000

4.32

<0.50

11.3

11.1

111. 000

4.50

<0.50

11.1

10.9

109.000

4.35

<0.50

11.7

11.4

114.000

UGL

UGL

UGL

UGL

UGL

UGL

UGL

UGL

UGL

UGL

UGL

UGL

UGL

UGL

UGL

UGL

UGL

UGL

UGL

UGL

UGL

UGL

UGL

UGL

UGL

UGL

UGL

UGL

UGL

UGL

UGL

UGL

UGL

UGL

UGL

104.0

112.0

112.0

0.0

101.5

99.0

100.0

1.0

108.7

110.0

111.0

0.9

111.0

122.0

120.0

1.7

108.0

113.0

111.0

1.8

112.5

111.0

109.0

1.8

108.7

117.0

114.0

2.6

( 70-130 )

70-130

70-130

0-20

70-130

70-130

70-130

0-20

70-130

70-130

70-130

0-20

70-130

80-140

80-140

0-20

70-130

70-130

70-130

0-20

70-130

70-130

70-130

0-20

70-130

70-130

70-130

0-20

0.00

1.0

0.90

1.7

1.8

1.8

2.6





I I I

555 East Walnut Sireel Pasadena. California 91101 Tel: 626 568 6400 Fax: 626 568 6324 1 600 568 LABS (1 600 568 5227)


1 0- 'I 3- J 2 /I. 1 0: :5 giN


#100134

8-30

(continued)

I----------------~~~~~

[

[

[

[

[

r Ii.

c I I I I I

LCS1

MBLK

MS

MSD

RPD_MS

LCS1

MBLK

MS

MSD

RPD_MS

LCS1

LCS2

MBLK

MS

MSD

RPD_LCS

RPD_MS

LCS1

MBLK

MS

MSD

RPD_MS

LCS1

MBLK

MS

MSD

RPD_MS

LeS1

MBLK

MS

MSD

RPD_MS

MS

LCS1

MBLK

p-Dichlorobenzene (l,4-DCB)


p-.Dichlorobenzene (l,4-DCB)



2,2-Dichloropropane

2,2-Dichloropropane

2,2-Dichloropropane

2,2-Dichloropropane

2,2-Dichloropropane

2-Butanone (MEK)

2-Butanone (MEK)

2-Butanone (MEK)

2-Butanone (MEK)

2-Butanone (MEK)

2-Butanone (MEK)

4

ND

10

10

112.000

4

ND

10

10

101.000

40

40

ND

100

100

97.000

68.600

4

ND

10

10

104.000

4

ND

10

10

110.000

40

ND

100

4.11

<0.50

11.2

11.0

110.000

4.37

<0.50

10.1

9.99

99.900

38.8

30.5

<5.00

68.6

72.1

76.250

72.100

4.27

<0.50

10.4

10.1

101. 000

4.42

<0.50

11.0

11.1

111. 000

40.2

<5.00

101

102.8

112.0

110.0

1.8

109.2

101. 0

99.9

1.1

97.0

76.2

68.6

72.1

ll.:.L 5.0

106.7

104.0

101.0

2.9

110.5

110.0

111.0

0.9

100.5

70-130

70-130

70-130

0-20

70-130

84-131

84-131

0-20

70-130

70-130

56-85

56-85

0-20

0-20

70-130

70-UO

70-130

0-20

70-130

70-130

70-130

0-20

70-130

1.8

1.1

24

5.0

2.9

0.90

2-Butanone (MEK)

o-Chlorotoluene

o-Chlorotoluene

o-Chlorotoluene

o-Chlorotoluene

o-Chlorotoluene

p-Chlorotoluene

p-Chlorotoluene

p-Chlorotoluene

p-Ch1oroto1uene

p-Ch1orotoluene






Spiked sample

100 100

UGL

UGL

UGL

UGL

UGL

UGL

UGL

UGL

UGL

UGL

UGL

UGL

UGL

UGL

UGL

UGL

UGL

UGL

UGL

UGL

UGL

UGL

UGL

UGL

UGL

UGL

UGL

UGL

UGL

UGL

UGL

UGL

NONE

UGL

UGL

101. 0

100.0

1.0

70-130

70-130

0-20

0-0

70-130

1.00

Benzene

Benzene

101.000 100.000

Lab # 22 09090028

4

ND

4.77

<0.50

119.2





I

I

E c

r I.

c ,. L.

I I I [

MS

MSD

RPD_MS

LCS1

MBLK

MS

MSD

RPD_MS

LCS1

MBLK

MS

MSD

RPD_MS'

LCS1

MBLK

MS

MSD

RPD_MS

LCS1

MBLK

MS

MSD

RPD_MS

LCS1

MBLK

MS

MSD

RPD_MS

LCS1

MB.LK

MS

MSD

RPD_MS

LCS1

MBLK

1 0-1 3 - J 2 A 1 (J: 58 I ,,;



Benzene

Benzene

Benzene

Bromobenzene

Bromobenzene

Bromobenzene

Bromobenzene

Bromobenzene











Chlorobenzene

Chlorobenzene

Chlorobenzene

Chlorobenzene

Chlorobenzene






cis-l,3-Dichloropropene

cis-1,3-Dichloropropene


ciS-1,3-Dich1oropropene


Bromoform

Bromoform

10

10

113.000

4

NO

10

10

113.000

4

NO

10

10

106.000

4

NO

10

10

105.000

4

NO

10

10

110.000

4

NO

~o

10

125.000

4

NO

10

10

109.000

4

NO

11.3

11.3

l13.000

4.19

<0.50

l1.3

l1.0

l10.000

5.16

<0.50

10.6

10.7

107.000

4.16

<0.50

10.5

10.7

107.000

4.34

<0.50

11.0

10.7

107.000

4.53

<0.50

12.5

12.1

121. 000

4.04

<0.50

10.9

10.8

106.000

4.13

<0.50

UGL

UGL

UGL

UGL

UGL

UGL

.UGL

UGL

UGL

UGL

UGL

UGL

UGL

UGL

UGL

UGL

UGL

UGL

UGL

UGL

UGL

UGL

UGL

UGL

UGL

UGL

UGL

UGL

UGL

UGL

UGL

UGL

UGL

UGL

UGL

113.0

113.0

0.0

104.6

113.0

110.0

2.7

129.0

10B.0

107.0

0.9

.104.0

105.0

107,0

1.9

108.5

110.0

107.0

2.8

113.2

125.0

121.0

3.3

101. 0

109.0

108.0

0.9

103.2


#100134

70-130

70-l30

0-20

70-130

70-130

70-130

0-20.

70-130

74-137

74-137

0-20

70-130

86-129

86-129

0-20

70-130

70-130

70-130

0-20

70-130

70-130

70-130

0-20

70-130

85-120

85-120

0-20

70-130

0.00

2.7

0.93

1.9

2.8

3.3

0.92





8-31

r-III

I I I I

[

c [

E [

I I I I

MS

MSD

RPD_MS

LeS1

MBLK

MS

MSD

RPD_MS

LeS1

MBLK

MS

MSD

RPD_MS

LeS1

MBLK

MS

MSD

RPD_MS

LeS1

MBLK

MS

MSD

RPD_MS

LeS1

MBLK

MS

MSD

RPD_MS

LeS1

MBLK

MS

MSD

RPD_MS

LeS1

MBLK

555 Easl walnut Slreel Pasadena, California 91101 Tel: 626 568 6400 Fax: 626 568 6324 1 800 568 LABS (1 800 568 5227)


Bromoform

Bromoform'

Bromoform






Bromochloromethane

Bromochloromethane

Bromochloromethane

Bromochloromethane

Bromochloromethane

Chloroethane

Chloroethane

Chloroethane

Chloroethane

Chloroethane

Chloromethane(Methyl Chloride}







Ch10rodibromomethane



Dibromomethane

Dibromomethane

Dibromomethane

Dibromomethane

Dibromomethane



10

10

108.000

4

NO

10

10

118.000

4

NO

10

10

112.000

10

NO

10

10

120.000

4

NO

10

10

108.000

4

NO

10

10

123.000

4

NO

10

10

117.000

4

NO

10.8

10.7

107.000

4.60

<0.50

11.B

11.3

113.000

4.09

<0.50

11.2

10.7

107.000

9.82

<0.50

12.0

11.B

118.000

4.52

<0.50

10.8

10.7

107.000

4.09

<0.50

12.3

12.3

123.000

4.19

<0.50

11.7

10.9

109.-000

4.25

<0.50

UGL

UGL

UGL

UGL

UGL

UGL

UGL

UGL

UGL

UGL

UGL

UGL

UGL

UGL

UGL

UGL

UGL

UGL

UGL

UGL

UGL

UGL

UGL

UGL

UGL

UGL

UGL

UGL

UGL

UGL

UGL

UGL

UGL

UGL

UGL

1 n '1' J" ," I 'x- j - :.:. Ale:53

108.0

107.0

0.9

115.0

11B.O

113.0

4.3

102.2

112.0

107.0

4.6

98.2

120.0

118.0

1.7

113.0

108.0

107.0

0.9

102.2

123.0

123.0

0.0

104.8

117.0

109.0

7.1

106.2

Labpratory QC R~ort

#100134

70-130

70-130

0-20

70-130

70-130

70-130

0-20

70-130

70-130

70-130

0-20

70-130

69-151

69-151

0-20

70-130

76-138

76-138

0-20

70-130

70-130

70-130

0-20

70-1'30

70-130

70-130

0-20

70-130

0.93

4.3

4.6

1.7

0.93

0.00

7.1




QC Report Page 12

8-32

IN

of 31

I

I

555 East Walnut Street Pasadena. CalifornIa 91101 Tat: 626 568 6400 Fax: 626 568 6324 1 800 568 LABS (1 800 568 5227)


1 C -I ::; - 0 2 ,A,) 0 : 5 3 IN


#100134

8-33

( continued)

I~-----------------------

c

[

[

[

[

[

I I I I

MS

MSD

RPD_MS

LCS1

~LK

MS

MSD

RPD_MS

LCS1

MBLK

MS

MSD

RPD_MS

LCS1

~LK

MS

MSD

RPD_MS

LCS!

LCS2

~LK

MS

MSD

RPD_LCS

RPD_MS

LeSl.

LCS2

MBLK

MS

MSD

RPD_LCS

RPD_MS

LCS1

MBLK

MS

Bromodich1oromethane

Bromodich1oromethane


Dichloromethane

Dichloromethane

Dichloromethane

Dichloromethane

Dichloromethane

Di-isopropyl ether

Di-isopropyl ether

Di-isopropyl ether

Di-isopropyl ether

Di-isopropyl ether

Ethyl benzene

Ethyl benzene

Ethyl benzene

Ethyl benzene

Ethyl benzene

Dichlorodifluoromethane








Fluorotrichloromethane-Freonl1






Hexachlorobutadiene

Hexachlorobutadiene

Hexachlorobutadiene

10

'10

123.000

4

NO

10

10

104.000

4

NO

10

10

104.000

4

NO

10

10

111.000

4

4

NO

10

10.

105.000

138.000

4

4

NO

10

10

111.000

131. 000

4

NO

10 .

12.3

11.9

119.000

3.95

<0.50

10.4

10.2

102.000

4.27

<3.00

10.4

10.3

103.000

4.58

<0.50

11.1

10.9

109.000

4.20

4.80

<0.50

13.8

13.5

120.000

135.000

4.44

4.99

<0.50

13.1

12.9

124.750

129.000

4.17

<0.50

9.65

UGL

UGL

UGL

UGL

UGL

UGL

UGL

UGL

UGL

UGL

UGL

UGL

UGL

UGL

UGL

UGL

UGL

UGL

UGL

UGL

UGL

UGL

UGL

UGL

UGL

UGL

UGL

UGL

UGL

UGL

UGL

UGL

UGL

UGL

UGL

123.0

119.0

3.3

98.8

104.0

102.0

1.9

106.7

104.0

103.0

1.0

114.5

111.0

109.0

1.8

105.0

120.0

138.0

135.0

13.3

2.2

111.0

124.8

l.ll.:..Q....

129.0

11.7

1.5

104.2

96.5

70-130

70-130

0-20

70-130

70-130

70-130

0-20

70-130

70-130

70-130

0-20

70-130

70-130

70-130

0-20

70-130

70-130

53-168

53-168

0-20

0-20

70-130

70-130

70-130

70-130

0-20

0-20

70-130

( 70-130 )




3.3

1.9

0.97

1.8

13

2.2

12

1.5


I I I

555 East Walnut Street Pasadena. Califomla 91101 Tel: 626 568 6400 Fax: 626 568 6324 1 600 568 LABS (1 600 568 5227)



#100134

8-34

(continued)

I~-----------------------1M ~

~ .. ,;

~

I I

MSD

RPD_MS

LCSI

MBLK

MS

MSD

RPD_MS

LCSI

MBLK

MS

MSD

RPD_MS

LCSI

MBLK

MS

MSD

RPD_MS

LCSI

MBLK

MS

MSD

RPD_MS

LCSI

MBLK

MS

MSD

RPD_MS

LCSI

MBLK

MS

MSD

RPD_MS

LCSI

MBLK

MS

Hexachlorobutadiene

Hexachlorobutadiene

Isopropylbenzene

Isopropylbenzene

Isopropylbenzene

Isopropylbenzene

Isopropylbenzene

m-Dichlorobenzene (l,3-DCB)





m,p-Xylenes

m,p-Xylenes

m,p-Xylenes

m,p-Xylenes

m,p-Xylenes






Naphthalene

Naphthalene

Naphthalene

Naphthalene

Naphthalene

n-Butylbenzene

n-Butylbenzene

n-Butylbenzene

n-Butylbenzene

n-Butylbenzene

'n-Propylbenzene

n-Propylbenzene

n-Propylbenzene

10

96,500

4

NO

10

10

112.000

4

NO

10

10

114.000

8

NO

20

20

111. 000

4

NO

10

10

96.200

4

NO

10

10

95.400

4

ND

10

10

101.000

4

NO

10

10.3

103.000

4.65

<0.50

11.2

11.1

111.000

4.29

<0.50

11.4

11.1

111.000

9.01

<0.50

22.2

21.9

109.500

4.67

<3.00

9.62

9.64

96.400

4.03

<0.50

9.54

10.3

103.000

4.29

<0.50

10.1

10.2

102.000

4.51

<0.50

11.2

UGL

UGL

UGL

UGL

UGL

UGL

UGL

UGL

UGL

UGL

UGL

UGL

UGL

UGL

UGL

UGL

UGL

UGL

UGL

UGL

UGL

UGL

UGL

UGL

UGL

UGL

UGL

UGL

UGL

UGL

UGL

UGL

UGL

UGL

UGL

103.0

6.5

116.3

112.0

111.0

0.9

107.2

114.0

111.0

2.7

112.6

111.0

109.5

1.4

116.8

96.2

96.4

0.2

100.8

95.4

103.0

7.7

107.2

101. 0

102.0

1.0

112.8

112.0

70-130

0-20

70-130

70-130

70-130

0-20

70-130

70-130

70-130

0-20

70-130

70-130

70-130

0-20

60-140

70-130

70-130

0-20

70-130

70-130

70-130

0-20

70-130

70-130

70-130

0-20

70-130

( 70-130 )




6.5

0.90

2.7

1.4

0.21

7.7

0.99


I I I




#100134

8-35

1-------------------------I

c

(

c

I I I

MSD

RPD_MS

LCS1

MBLK

MS

M.SD

RPD_MS

LCS1

MBLK

MS

MSD

RPD_MS

LCS1

MBLK

MS

MSD

RPD_MS

LCS1

MBLK

MS

MSD

RPD_MS

LCSl

MBLK

MS

MSD

RPD_MS

LeSl

MBLK

MS

MSD

RPD_MS

LCSl

MBLK

MS

n-Propylbenzene

n-Propylbenzene

o-Xylene

o-Xylene

o-Xylene

o-Xylene

o-Xylene

o-Dichlorobenzene (l,2-DCB)





Tetrachloroethylene (PCE)





p-Isopropy1toluene

p-Isopropyltoluene

p-Isopropyltoluene

p-Isopropyltoluene

p-Isopropyltoluene

sec-Butylbenzene

sec-Butylbenzene

sec-Butylbenzene

sec-Butylbenzene

sec-Butylbenzene

Styrene

Styrene

Styrene

Styrene

Styrene

trans-l,2-Dichloroethylene



10

112.000

4

ND

10

10

111.000

4

ND

10

10

101.000

4

ND

10

10

113.000

4

ND

10

10

110.000

4

ND

10

10

113.000

4

ND

10

10

107.000

4

ND

10

10.8

108.000

4.34

<0.50

11.1

10.9

109.000

4.00

<0.50

10.1

10.3

103.000

4.45

<0.50

11.3

11.0

110.000

4.29

<0.50

11.0

10.8

108.000

4.47

<0.50

11.3

11.2

112.000

4.25

<0.50

10.7

10.7

107.000

4.32

<0.50

10.5

UGL

UGL

UGL

UGL

UGL

UGL

UGL

UGL

UGL

UGL

UGL

UGL

UGL

UGL

UGL

UGL

UGL

UGL

UGL

UGL

UGL

UGL

UGL

UGL

UGL

UGL

UGL

UGL

UGL

UGL

UGL

UGL

UGL

UGL

UGL

108.0

3.6

108.5

111.0

109.0

1.8

100.0

101.0

103.0

2.0

111.2

113.0

110.0

2.7

107.2

110.0

108.0

1.8

111.8

113.0

112.0

0.9

106.2

107.0

107.0

0.0

108.0

105.0

70-130

0-20

70-130

70-130

70-130

0-20

70-130

70-130

70-130

0-20

70-130

70-130

70-130

0-20

70-130

70-130

70-130

0-20

70-130

70-130

70-130

0-20

70-130

70-130

70-130

0-20

70-130

( 85-129 )

3.6

1.8

2.0

2.7

1.8

0.89

0.00





I I I

555 East Walnut Street Pasadena, california 91101 Tel: 626 568 6400 Fax: 626 568 6324 1 BOO 568 LABS (1 BOO 568 5227)


1 ')- I J - 0 2 1\ 1 r) : 58 I N


#100134

8-36

1-------------------------[

[

E c

c I I I I I

MSD

RPD_MS

LCSl

MBLK

MS

MSD

RPD_MS

LCSl

MBLK

MS

MSD

RPD_MS

LCSl

MBLK

MS

MSD

RPD_MS

LCSl

MBLK

MS

MSD

RPD_MS

LCSl

MBLK

MS MSD

RPD_MS

LCSl

MBLK

MS

MSD

RPD_MS

LCSl

MBLK

MS


tra?s-l,2-Dichloroethylene

tert-amyl Methyl Ether





tert-Butyl Ethyl Ether





tert-Butylbenzene

tert-Butylbenzene

tert-Butylbenzene

tert-Butylbenzene

tert-Butylbenzene

Trichloroethylene (TCE)





Trichlorotrifluoroethane(Freon



Tr1chlorotr1fluoroethane(Freon


trans-1,3-Dichloropropene


trans-l,3-Dichloropropene



Toluene

Toluene

Toluene

10

105.000

4

ND

10

10

107.000

4

ND

10

10

108.000

4

ND

10

10

115.000

4

ND

10

10

111.000

4

ND

10

10

121. 000

4

ND

10

10

109.000

4

ND

10

10.1

101.000

4.39

<3.00

10.7

10.7

107.000

4.13

<3.00

10.8

10.6

106.000

4.52

<0.50

11.5

11.1

111.000

4.52

<0.50

11.1

11.0

110.000

4.12

<0.50

12.1

11.7

117.000

4.00

<0.50

10.9

10.7

107.000

4.73

<0.50

11.5

UGL

UGL

UGL

UGL

UGL

UGL

UGI,.

UGL

UGL

UGL

UGL

UGL

UGL

UGL

UGL

UGL

UGL

UGL

UGL

UGL

UGL

UGL

UGL

UGL

UGL

UGL

UGL

UGL

UGL

UGL

UGL

UGL

UGL

UGL

UGL

101. 0

3.9

109.7

107.0

107.0

0.0

103.2

108.0

106.0

1.9

113.0

115.0

111.0

3.5

113.0

111.0

110.0

0.9

103.0

121.0

117.0

3.4

100.0

109.0

107.0

1.9

118.3

115.0

85-129

0-20

70-130

70-130

70-130

0-20

70-130

70-130

70-130

0-20

70-130

70-130

70-130

0-20

70-130

70-130

70-130

0-20

70-130

70-130

70-130

0-20

70-130

80-131

80-131

0-20

70-130

( 70-130 )

3.9

0.00

1.9

3.5

0.90

3.4

1.9





I

[

555 East Walnut Street Pasadena. Califomla 9t 101 Tel: 626 568 6400 Fax: 626 568 6324 1 800 568 LABS (1 800 568 5227)


10-13-J2 Al0:58 IN


#100134

8-37

~--------------------------------------------------------------~-------------------------------------

[ MSD

RPD_MS

LeSl

[ MBLK

MS

MSD

RPD_MS

[ QC

[ QC

LCSl

LCS2

[ KBLK

KS

KSD

[ QC

[ QC

LCSl

LCS2

c KBLK

MS

MSD

QC

QC

LCBl

LCS2

I KBLK

I I

Toluene 10 ll.3 UGL ll3.0 '( 70-130 1.8

Toluene ll5.000 ll3.000 UGL 1.8 0-20

Vinyl chloride (ve) 4 4.74 UGL ll8.5 70-130

Vinyl chloride (ve) NO <0.30 UGL

Vinyl chloride (Ve) 10 11.3 UGL ll3.0 67-152

Vinyl chloride (Ve) 10 11.5 UGL ll5.0 67-152 1.8

Vinyl chloride (Ve) ll3.000 ll5.000 UGL 1.8 0-20

Ref #180906 Nickel, Total, ICAP/MS

Analyte Spiked Recovered Units Yield ('Is) Limits ''Is) RPD ('Is)

Nickel, Total, ICAP/KS 50 51.5 UGL 103.0 85-115

Nickel, Total, ICAP/KS 50 51.7 UGL 103.4 85-115 0.39

Nickel, Total, ICAP/KS NO <5.00 UGL

Nickel, Total, ICAP/MS 50 50.2 UGL 100.4 70-130

Nickel, Total, ICAP/KS 50 51.2 UGL 102.4 70-130 2.0

Ref #180907 Copper, Total, ICAP/MS

Ana1yte Spiked· Recovered Units Yield ('Is) Limits ('Is) RPD ('Is)

Copper, Total, ICAP/KS 100 102 UGL 102.0 85-115

Copper, Total, ICAP/KS 100 103 UGL 103.0 85-ll5 0.98

Copper, Total, ICAP/KS NO <2.00 UGL

Copper, Tota1, l:CAP/MS 100 '6.5 uaL '6.5 70-130

Copper, Total, ICAP/MS 100 98.3 uaL 98.3 70-130 1.8

Ref #180911 Arsenic, Total, ICAP/MS

Ana1yte Spiked Recovered Units Yield ('Is) Limits ('Is) RPD ('Is)

Arsenic, Total, ICAP/KS 20 19.8 UGL 99.0 85-ll5

Arsenic, Total, ICAP/KS 20 19.9 UGL 99.5 ( 85-ll5 ) 0.50

Arsenic, Total, ICAP/KS NO <1. 00 UGL

Spikes which exceed Limits and Kethod Blanks with positive results are highlighted by Underlining ..




I I I I [ MS

MSD

QC

c LeS l

LCS2

KBLJC

E KS

KSD

c QC

c LCSl

LCS2

KBLIC

KS

MSD

oC

LCSl

LCS2

KBLIC

KS

I KSD

I I I [



Arsenic, Total, ICAP/MS 20

Arsenic, Total, ICAP/MS 20

20.1

20,2

QC Ref #180912 Selenium, Total,

UGL 100.5

UGL 101.0

ICAP/MS


#100134

70-130

70-130 0,50


QC

QC

Selenium, Total, lCAP/KS 20 19.5 UGL 97.5 85-115

Selenium, Total, lCAP/KS 20 19.7 UGL 98.5 85-115 1.0

Selenium, Total, lCAP/KS. NO <5.00 UGL

Selenium, Total, lCAP/KS 20 18.8 UGL 94.0 70-130

Selenium, Total, lCAP/KS 20 18.8 UGL 94.0 70-130 ) 0.00

Ref #180915 Beryllium, Total, ICAP/MS

Analyte Spiked Recovered Units Yield (lis) Limits ('II) RPD ('II)

Beryllium, Total, lCAP/KS 5.00 5.02 UGL 100.4 70-130

Beryllium, Total, ICAP/KS 5.00 5.03 UGL 100.6 85-115 0.20

Beryllium, Total, lCAP/KS NO <1.00 UGL

Beryllium, Total, lCAP/KS 5.00 5.11 UGL 102.2 70-130

Beryllium, Total, lCAP/KS 5.00 5.11 UGL 102.2 70-130 0.00

Ref #180917 Cadmium, Total, ICAP/MS

Analyte Spiked Recovered Units Yield ('II) Limits (lis) RPD ('II)

Cadmium, Total, ICAP/KS 20 20 UGL 100.0 85-115

Cadmium, Total, lCAP/KS 20 20.2 UGL 101. 0 85-115 1.00

Cadmium, Total, lCAP/KS NO <0.50 UGL

Cadmium, Total, lCAP/KS 20 20 UGL 100.0 70~130

Cadmium, Total, lCAP/KS 20 20.2 UGL 101.0 70-130 1.00

Spikes which exceed Limits and Kethod Blanks with positive results are highlighted by Underlining.

Criteria for KS and DUP are advisory only, batch control is based on LCS. Criteria for duplicates



8-38

555 East Walnut Street Pasadena, California 91101 Tel: 626 568 6400 Fax: 626 568 6324 1 800 568 lABS (1 800 568 5227)


:0-'1"-3-;)2 Al0:53 IN


#100134

8-39

i~--------------~-------

[

QC

LCSl

LCS2

MBLK

MS

MSD

"..

L QC

LCSl

LCS2

( MSLK

MS

MSD

(

c QC

LeS1

LeS2

MBLK

MS

MSD

i I I I

QC Ref #180918 Barium, Total, ICAP/MS

QC

QC

Analyte Spiked Recovered Units Yield (!II) Limits ('Is) RPD (!II)

Barium, Total, lCAP/MS 100 97.4 UGL 97.4 85-115

Barium, Total, lCAP/MS 100 97.8 UGL 97.8 85-115 0.41

Barium, Total, lCAP/MS NO <2.00 UGL

Barium., Total, lCAP/MS 100 95.2 UGL 95.2 70-130

Barium, Total. lCAP/MS 100 97.7 VOL 97.7 70-130 2.6

Ref #180919 Antimony, Total, ICAP/MS

Analyte Spiked Recovered Units Yield (!II) Limits ('Is) RPD ('Is)

Antimony. Total, lCAP/MS SO 49.1 UGL 98.2 85-115

Antimony, Total, lCAP/MS SO 49.7 UGL 99.4 85-115 1.2

Antimony. Total, lCAP/MS NO <1.00 UGL

Antimony, Total, lCAP/MS SO 49.2 UGL 98.4 70-130

Antimony, Total. lCAP/MS SO 50.7 UGL 101.4 70-130 3.0

Ref #180920 Thallium, Total, ICAP/MS

.Analyte Spiked Recovered Units Yield ('Is) Limits (!II) RPD ('Is)

Tha11ium, Tota1, ICAP/MS 20.0 20.2 UGL 101.0 85-115

Thallium, Tota1, :rCAP/MS 20.0 20.1 UGL 100.5 85-115 0.50

Thallium, Total, :rCAP/MS NO <1. 00 UGL

Thallium, Total, lCAP/MS 20.0 19.6 UGL 98.0 70-130

Thallium, Total, :reAP/MS 20.0 20 UGL 100.0 70-130 2.0


Criteria for MS and DUP are advisory only. batch control is based on LCB. Criteria for duplicates

are adviSOry only, unless otherwise specified in the method.


I I I I

QC

LCSl

LCS2

HlILlC

KS

KSD

QC

LCS1

LCS2

c MBLlC

KS

KSD

QC

LCSl

HElLlC

KS

KSD

KS

LCS1

MBLK

KS I KSD

I LCS1

I I [

555 East Watnut Street Pasadena, California 9t 101 Tel: 626 568 6400 Fax: 626 568 6324 1 600 568 LABS (1 600 568 5227)


QC Ref #180921 Lead, Total, ICAP/MS


Lead, Total, ZCAP/KS 20 20.1


Lead, Total, ZCAP/KS NO <0.50


Lead, Total, ZCAP/KS 20 20

units

UGL

UGL

UGL

UGL

UGL

10-1J-J2 Al0:58 IN

Yield <'Is)

100.5

102.0

98.0

100.0


#100134


85-115

85-115 1.5

70-130

70-130 2.0

QC Ref #180928 Chromium, Total, ICAP/MS

QC

Analyte Spiked Recovered units Yield ('Is) Limits <'Is) RPD

Chromium, Total, ZCAP/KS 100 100 UGL 100.0 I 85-115 )

Chromium. Total, ZCAP/KS 100 100 UGL 100.0 85-115 0.00

Chromium, Total, ZCAP/KS NO <1.00 UGL

Chromium, Total, ZCAP/KS 100 96.8 UGL 96.8 70-130

Chromium, Total, ZCAP/KS 100 98.2 UGL 98.2 70-130 1.4

Ref #181018 Aldicarbs

Analyte Spiked Recovered units Yield <'II) Limits <'Is) RPD

3-Hydroxycarbofuran 10.0 10.4 UGL 104.0 80-120

3-Hydroxycarbofuran NO <2.00 UGL

3-Hydroxycarbofuran 10.0 10.6 UGL 106.0 65-135

3-Hydroxycarbofuran 10.0 11.0 UGL 110.0 65-135 3.7

Spiked sample Lab II 22 08290062 NONE 0-0

A1dicarb ITemik) 10.0 8.56 UGL 85.6 80-120

A1dicarb ITemik) NO <0.50 UGL

A1dicarb ITemik) 10.0 10.5 UGL 105.0 65-135

A1dicarb ITemik) 10.0 10.4 UGL 104.0 65-135 0.96

A1dicarb sulfone 10.0 10.2 UGL 102.0 80-120

Spikes which exceed Limits and Kethod Blanks with positive results are highlighted by underlining.

Criteria for KS and DUP are advisory only, batch control is based on LCS. Criteria for duplicates


QC Report - Page 20

<'Is)

I'll)

of 31

8-40

I I


Hawaii Department of water Supply (Hila) (continued)


#100134

8-41

1-------------------------

[

[

r iii

I I I

MBLK

MS

MSO

LCS1

MBLK

MS

MSO

LCS1

MBLK

MS

MSO

LCS1

MBLK

MS

MSO

LCS1

MBLK

MS

MSO

LCS1

MBLK

MS

MSO

LCS1

MBLK

MS

MSO

LeSl

MBLK

MS

MSO

LeS1

MBLK

MS

MSO

Aldicarb sulfone

Aldicarb sulfone

Aldicarb sulfone

Aldicarb sulfoxide

Aldicarb sulfoxide

Aldicarb sulfoxide

Aldicarb sulfoxide

Baygon

Baygon

Baygon

Baygon

Carbofuran (Furadan)




Carbaryl

Carbaryl

Carbaryl

Carbaryl

Methiocarb

Methiocarb

Methiocarb

Methiocarb

Methomyl

Methomyl

Methomy1

Methomy1

Oxamy1 (vydate)

Oxamyl (vydate)

Oxamyl (Vydate)

Oxamyl (Vydate)

BOMC

BOMC

BOMC

BOMC

ND

10.0

10.0

10.0

ND

10.0

10.0

10.0

ND

10.0

10.0

10.0

ND

10.0

10.0

10.0

ND

10.0

10.0

10.0

ND

10.0

10.0

10.0

ND

10.0

10.0

10.0

ND

10.0

10.0

100

100

100

100

<0.70

10.6

10.7

9.83

<0.50

10.6

10.8

9.96

<2.00

10.4

10.5

10.6

<0.90

10.9

11.6

8.98

<2.00

8.99

9.12

10.0

<2.00

9.89

10.5

10.2

<1.00

10.6

10.5

10.1

<2.00

10.3

10.4

129

101

85.9

96.5

UGL

UGL

UGL

UGL

UGL

UGL

UGL

UGL

UGL

UGL

UGL

UGL

UGL

UGL

UGL

UGL

UGL

UGL

UGL

UGL

UGL

UGL

UGL

UGL

UGL

UGL

UGL

UGL

UGL

UGL

UGL

%R

%R

%R

%R

106.0

107.0

98.3

106.0

108.0

99.6

104.0

105.0

106.0

109.0

116.0

89.8

89.9

91.2

100.0

98.9

105.0

102.0

106.0

105.0

101. 0

103.0

104.0

129.0

101. 0

85.9

96.5

65-135

65-135

80-120

65-135

65-135

80-120

65-135

65-135

80-120

65-135

65-135

80-120

65-135

65-135

80-120

65-135

65-135

80-120

65-135

65-135

80-120

65-135

65-135

70-130

70-130

70-130

0.94

1.9

0.96

6.2

1.4

6.0

0.95

0.97

12


Criteria for MS and OUP are advisory only. batch control is based on LCS. Criteria for duplicates



~ ...

I I I

555 East Walnut Street Pasadena. caJilomla 91101 Tel: 626 568 6400 falc 626 568 6324 1 BOO 566 LABS (1 BOO 568 5227)

Hawaii Department of Water Supply (Hilo) . (continued)


#100134

8-42

I~-----------------------

[ QC

MS

LCSl

MBLK

MS

MSD

QC

MS

LCSl

LCS2

MBLK

MS

MSD c [ QC

LCSl

I LCS2

MBLK

MSl

MS2

I MSD

LCSl

LCS2

I MBLK

I I

QC Ref #181106 Endotha11

QC

QC

Analyte Spiked Recovered units Yield ('II) Limits (lis) RPD ('II)

Spiked sample Lab • 22 08290059 WI. 0-0

Bndothall 25 24.4 WI. 97.6 60-116

Bndothall NO <5.00 UGL

Bndothall 25 23.5 UCL 94.0 60-116

Bndothall 25 25.1 UGL 100.4 60-116 6.6

Ref #181453 Mercury

Analyte Spiked Recovered units Yield ('II) Limits (lis) RPD ('II)

Spiked sample Lab' 22 09030080 UGL 0-0

Mercury 1.50 1.36 UGL 90.7 85-115

Mercury 1.50 1.34 UGL 89.3 85-115 1.5

Mercury NO <0.20 WI.

Mercury 1.50 1.34 WL 89.3 70-130

Mercury 1.50 1.31 UGL 87.3 70-130 2.3

Ref #181471 Herbicides by 515.3

Analyte Spiked Recovered. Units Yield ('II) Limits ('II) RPD ('II)

2,4,5-T 0.75 0.86 UGL 114.7 70-130

2,4,5-T 3.0 3.00 UGL 100.0 70-130

2,4,5-T NO <0.20 UGL

2,4,5-T 3.00 3.15 UGL 105.0 70-130

2,4,5-T 0.75 0.77 UGL 102.7 70-130

2,4,S-T 3.00 3.20 UGL 106.7 70-130

2,4,5-TP (Silvex) 0.75 0.79 UGL 105.3 70-130

2,4,5-TP (Silvex) 3.0 2.63 UGL 87.7 70-130

2,4,S-TP (Silvex) NO <0.20 UCL





555 East walnut Street Pasadena, Callfomla 91101 Tel: 626 568 6400 Fax: 626 568 6324 1 BOO 568 LABS (1 BOO 568 5227)


10-1'3-)2 A 10 :59 IN


#100134

8-43

[-------------------------

c r .. [

[

[

[

[

[

I I I I

MSl

MS2

MSO

LCSl

LCS2

MBLK

MSl

MS2

MSO

LCSl

LCS2

MBLK

MSl

MS2

MSO

LCSl

LCS2

MBLK

MSl

MS2

MSO

MSl

MS2

MSO

LCSl

LCS2

MBLK

MS1

MS2

MSO

LCSl

LCS2

MBLK

MSl

MS2

2,4,5-TP (Silvex)

2,4,5-TP (Silvex)

2,4,5-TP (Silvex)

2,4-0

2,4-0

2,4-0

2,4-0

2,4-0

2,4-0

2,4-DB

2,4-DB

2,4-DB

2,4-DB

2,4-0B

2,4-DB

Oichlorprop

Dichlorprop

Oichlorprop

Oichlorprop ,

Dichlorprop

Oichlorprop

Spiked sample

Spiked sample

Spiked sample

Acifluorfen

Acifluorfen

Acif1uorfen

Acifluorfen

Acifluorfen

Acifluorfen

Bentazon

Bentazon

Bentazon

Bentazon

Bentazon

3.00

0.75

3.00

0.375

1.5

NO

1.50

0.375

1.50

7.5

30.0

NO

30.0

7.50

30.0

1. 875

7.5

3.03

0.72

3.01

0.36

1.44

<0.10

1. 70

0.40

1. 69

7.13

26.1

<2.00

29.7

6.24

29.2

1. 90

6.69

NO <0.50

7.50 6.44

1. 875 1.66

7.50 6.44

Lab # 22 08290'087

Lab # 22 08290062

Lab # 22 08290087

0.75 0.83

3.0 2.91

NO

3.00

0.75

3.00

1. 875

7.5

NO

7.50

1.875

<0.20

3.27

0.75

3.31

2.09

7.23

<0.50

6.70

1. 93

UGL

UGL

UGL

UGL

UGL

UGL

UGL

UGL

UGL

UGL

UGL

UGL

UGL

UGL

UGL

UGL

UGL

UGL

UGL

UGL

UGL

NONE

NONE

NONE

UGL

lJGL

UGL

UGL

UGL

UGL

UGL

UGL

UGL

UGL

UGL

101. 0

96.0

100.3

96.0

96.0

113.3

106.7

112.7

95.1

87.0

99.0

83.2

97.3

101. 3

89.2

85.9

88.5

85.9

110.7

97.0

109.0

100.0

110.3

111.5

96.4

89.3

102.9

70-130

70-130

70-130

70-130

70-130

70-130

70-130

70-130

70-130

70-130

70-130

70-130

70-130

70-130

70-130

70-130

70-130

70-130

0-0

0-0

0-0

70-130

70-130

70-130

70-130

70-130

70-130

70-130

70-130

70-130


Criteria for MS and OUP are advisory only, batch control is based on LCS. Criteria for duplicates



I I I I

[

[

[

I I I

MSD

LCS1

LCS2

MBLK

MS1

MS2

MSD

LCS1

LCS2

MBLK

MS1

MS2

MSD

LCS1

LCS2

MBLK

MS1

MS2

MSD

LCS1

LCS2

MBLK

MS1

MS2

MSD

LCS1

LCS2

MBLK

MS1

MS2

MSD

LCS1

LCS2

MBLK

MS1

1 0-1 3 - :J 2 AI 0 : 59 1:,1 , '\



Bentazon

Dalapon

Dalapon

Dalapon

Dalapon

Dalapon

Dalapon


3,5-Dichlorobenzoic acid

3,5-Dichlorobenzoic acid










Dicamba

Dicamba

Dicamba

Dicamba

Dicamba

Dicamba

Dinoseb

Dinoseb

Dinoseb

Dinoseb

Dinoseb

Dinoseb

pentachlorophenol

Pentachlorophenol

Pentachlorophenol

Pentachlorophenol

7.50

3.75

15.0

NO

15.0

3.75

15.0

1.875

7.5

NO

7.50

1.875

7.50

0.75

3.0

NO

3.00

0.75

3.00

0.1875

0.75

NO

0.75

0.1875

0.75

0.75

3.0

NO

3.00

0.75

3.00

0.15

0.60

NO

0.60

6.57

3.88

14.4

<1.00

15.4

3.69

15.3

2.08

7.26

<0.50

7.50

1.88

7.60

0.91

3.24

<0.20

3.78

0.91

3.65

0.22

0.79

<0.08

0.97

0.19

0.97

0.8S

3.03

<0.20

3.36

0.79

3.33

0.18

0.58

<0.04

0.62

UGL

UGL

UGL

UGL

UGL

UGL

UGL

UGL

UGL

UGL

UGL

UGL

UGL

UGL

UGL

UGL

UGL

UGL

UGL

UGL

UGL

UGL

UGL

UGL

UGL

UGL

UGL

UGL

UGL

UGL

UGL

UGL

UGL

UGL

UGL

87.6

103.5

96.0

102.7

98.4

102.0

110.9

96.8

100.0

100.3

101.3

121.3

108.0

126.0

121.3

121. 7

117.3

105.3

129.3

101. 3

129.3

117.3

101.0

112.0

105.3

111.0

120.0

96.7

103.3


#100134

70-130

70-130

70-130

70-130

70-130

70-130

70-130

70-130

70-130

70-130

70-130

70-130

70-130

70-13.0

70-130

70-130

70-130

70-130

70-130

70-130

70-130. )

70-130

70-130

70-130

70-130

70-130

70-130

70-130

( 70-130 )





8-44

p" ...

L.

I f·

~

I E m

MS2

MSD

LCSl

LCS2

E MBLK

MSl

MS2

[ MSD

LCSl

LCS2

[ MBLK

MSl

MS2

MSD

[ LCSl

LCS2

MBLK

[ MSl

MS2

MSD

LCSl

r LCS2 ... MBLK

MSD

Ill"" LCSl

L LCS2

MBLK

MSD

I j;

I I I I [

1 () -I :3 - 0 2 A 1 0 : 5 9 I N

555 East Walnut Street Pasadena. Callfomia 91101 Tel: 626 568 6400 Fax: 626 568 6324 1 600 568 LABS (1 800 568 5227)


Pentachlorophenol 0.150 0.17

Pentachlorophenol 0.60 0.62

Picloram 0.375 0.43

Picloram 1.5 1-53

Picloram ND <0.10

Picloram 1. 50 1.85

Picloram 0.375 0.40

Picloram 1.50 1.87

4-Nitrophenol (qualitative) 3.75 4.16


4-Nitrophenol . (qualitati ve) ND <1.00

4-Nitrophenol (qualitative) 15.0 11. 9

4-Nitrophenol (qualitative) .3.75 3.40


2,4-Dichlorophenylacetic acid 100 110






Tot DCPA Mono&Diacid Degradate 0.75 0.91


Tot DCPA Mono&Diacid Degradate ND <1.00



2.4-Dich1orophenylacetic acid 100 98


2,4-Dich10ropheny1acetic acid 100 90

UGL

UGL

UGL

UGL

UGL

UGL

UGL

UGL

UGL

UGL

UGL

UGL

UGL

UGL

tR

tR

tR

tR

tR

tR

UGL

UGL

UGL

UGL

tR

\"R

\"R

tR

113.3

103.3

114.7

102.0

123.3

106.7

124.7

110.9

94.0

79.3

90.7

76.0

110.0

98.0

101.0

94.0

109.0

90.0

121.3

108.3

121. 7

110.0

98.0

101.0

90.0


#100134

70-130

70-130

70-130

70-130

70-130

70-130

70-130

70-130

70-130

70-130

70-130

70-130

70-130

70-130 12

70-130

70-130

70-130 20

70-130

70-130

70-130

70-130

70-130 12

( 70-130) 20





8-45

I 555 East Walnut Street Pasadena. caJilomla 91101 Tel: 626 568 6400 Fax: 626 568 6324 1 800 568 LABS (1 800 568 5227)



#100134

8-46

E~----~-----------------

QC

LCSl [

MBLK

MS

MSD [ MBLK

MS

MSD

LCSl [

MBLK

MS

MSD

LCSl

[ MBLK

MS

MSD

LCSl

MBLK

MS

MaD

LCSl

MBLK [ MS

MSD

LCSl

MBLK

MS

MSD

LCS1

MBLK

I KS

I I [

QC Ref #182826 525 Semivolatiles by GC/MS

Analyte Spiked Recovered Units Yield (%) Limits (%) RPD

alpha-Chlordane 2 1.76 UGL 88.0 ( 70-130 )

alpha-Chlordane NO <0.05 UGL

alpha-Chlordane 5 4.01 UGL 80.2 70-130

alpha-Chlordane 5 4.20 UGL 84.0 70-130 4.6

Diazinon NO <0.10 UGL

Spiked sample Lab " 22 08290076 NONE 0-0

Spiked sample Lab. " 22 08310027 NONE 0-0 0.24

Acenaphthylene 2 2.23 UGL 111.5 70-130

Acenaphthylene NO <0.10 UGL

Acenaphthylene 5 5.15 UGL 103.0 70-130

Acenaphthylene 5 5.45 UGL 109.0 70-130 5.7

Alachlor 2 2.26 UGL 113.0 70-130

Alachlor NO <0.05 UGL

Alachlor 5 5.10 UGL 102.0 70-130

Alachlor 5 5.37 UGL 107.4 70-130 5.2

Aldrin 2 2.09 UGL 104.5 70-130

Aldrin NO <0.05 UGL

Aldrin 5 4.41 UGL 88.2 70-130

Aldrin 5 4.85 UGL 97.0 70-130 9.5

Anthracene 2 1.84 UGL 92.0 70-130

Anthracene NO <0.02 UGL

Anthracene 5 4.37 UGL 87.4 70-130

Anthracene 5 4.68 UGL 93.6 70-130 6.9

Atrazine 2 1.84 UGL 92.0 70-130

Atrazine NO <0.05 UGL

Atrazine 5 4.32 UGL 86.4 70-130

Atrazine 5 4.56 UGL 91.2 70-130 5.4

Benz (a) Anthracene 2 1.92 UGL 96.0 70-130

Benz (a) Anthracene NO <0.05 UGL

Benz (a) Anthracene 5 4.43 UGL 88.6 ( 70-130 )


Criteria for MS and DUP ar·e advisory only. batch control is based on LCS. Criteria for duplicates


QC Report Page 26

(%)

of 31

555 East Walnut Street Pasadena. Galilornla 91101 Tel: 626 568 6400 Fax: 626 568 6324 1 800 568 LABS (1 800 568 5227)


10-'13-02 Al0:S·9 !N


#100134

8-47

1-------------------------

"'" L

[

c

I I I I [

MSD

LCS1

MBLK

MS

MSD

LCS1

MBLK

MS

MSD

LCS1

MBLK

MS

MSD

LeS1

MBLK

MS

MSD

LeS1

MBLK

MS

MSD

LCS1

MBLK

MS

MSD

MBLK

MBLK

LeSl

MBLK

MS

MSD

LCSl

ME!LK

MS

MSD

Benz (a) Anthracene

Benzo(a)pyrene

Benzo(a)pyrene

Benzo(a)pyrene

Benzo(a)pyrene

Benzo(b) Fluoranthene


Benzo (b) Fluoranthene




Benzo(g,h,i)perylene

Benzo(g,h,i)perylene

Benzo(k) Fluoranthene

Benzo (k) Fluoranthene

Benzo(k) Fluoranthene

Benzo (k) Fluoranthene









Bromacil

Butach10r

Caffeine

Caffeine

Caffeine

Caffeine

Chrysene

Chrysene

Chrysene

Chrysene

5

2

ND

5

5

2

ND

5

5

2

ND

5

5

2

ND

5

5

2

ND

5

5

2

ND

5

5

NO

ND

2

ND

5

5

2

ND

5

5

4.66

2.16

cO.02

5.08

5.30

2.23

cO.02

4.95

5.37

2.25

cO.05

5.56

5.69

2.22

cO.02

5.07

5.14

2.02

cO.60

4.28

4.08

1.99

cO.50

4.47

4.91

<0420

cO.05

1. 02

cO.05

3.60

3.97

2.19

cO.02

5.14

5.34

UGL

UGL

UGL

UGL

UGL

UGL

UGL

UGL

UGL

UGL

UGL

UGL

UGL

UGL

UGL

UGL

UGL

UGL

UGL

UGL

UGL

UGL

UGL

UGL

UGL

UGL

UGL

UGL

UGL

UGL

UGL

UGL

UGL

UGL

UGL

93.2

108.0

101. 6

106.0

111.5

99.0

107.4

112.5

111.2

113.8

111.0

101.4

102.8

101.0

85.6

81.6

99.5

89.4

98.2

51.0

72 .0

79.4

109.5

102.8

106.8

70-130

70-130

70-130

70-130

70-130

70-130

70-130

70-130

70-130

70-130

70-130

70-130

70-130

70-130

70-130

70-130

70-130

70-130

70-130

50-110

50-110

50-110

70-130

70-130

70-130

5.1

4.2

8.1

2.3

1.4

4.8

9.4

9.8

3.8






Hawaii Department of water Supply (Hilo) (continued)

OJ Q-1 3 - 0 2 ft, 1 0 : 5 ~' I ~r


#100134

8-48

~-------------

[

[

c

I I I

LCSl

MBLK

MS

MSD

LCSl

MBLK

MS

MSD

LCSl

MBLK

MS

MSD

MBLK

LCSl

MBLK

MS

MSD

MBLK

LCSl

MBLK

MS

MSD

LCSl

MBLK

MS

MSD

LeS1

MBLK

MS

MSD

LeSl

MBLK

MS

MSP

LeSl









Diethylphthalate

Diethylphthalate

Diethylphthalate

Diethylphthalate

Dieldrin

Dimethylphthalate

Dimethylphthalate

Dimethylphthalate

Dimethylphthalate

Dimethoate

Di-n-Butylphthalate

Di-n-Butylphthalate

Di-n-Butylphthalate

Di-n-Butylphthalate

Endrin

Endrin

Endrin

Endrin

Fluoranthene

Fluoranthene

Fluoranthene

Fluoranthene

Fluorene

Fluorene

Fluorene

Fluorene

gamma-Chlordane

2

ND

5

5

2

ND

5

5

2

ND

5

5

ND'

2

ND

5

5

ND

2

ND

5

5

2

ND

5

5

2

ND

5

5

2

ND

5

5

2

2.28

<0.05

5.39

5.44

1. 89

<0.60

4.04

4.93

1. 92

<0.50

4.77

5.01

<0.20

2.08

<0.50

4.80

5.16

<10.00

2.07

<0.50

4.74

5.19

2.11

<0.10

4.56

5.39

2.18

<0.10

5.00

5.28

1.40

<0.05

4.28

4.78

1. 95

UGL

UGL

UGL

UGL

UGL

UGL

UGL

UGL

UGL

UGL

UGL

UGL

UGL

UGL

UGL

UGL

UGL

UGL

UGL

UGL

UGL

UGL

UGL

UGL

UGL

UGL

UGL

UGL

UGL

UGL

UGL

UGL

UGL

UGL

UGL

114.0

107.8

108.8

94.5

80.8

98.6

96.0

95.4

100.2

104.0

96.0

103.2

103.5

94.8

103.8

105.5

91.2

107.S

109.0

100.0

105.6

70.0

85.6

95.6

97.5

( 70-130

70-130

70-130

70-130

70-130

70-130

70-130

70-130

70-130

70-130

70-130

70-130

70-130

70-130

70-130

70-130

70-130

70-130

70-130

70-130

70-130

70-130

70-130

70-130

70-130

0.92

20

4.9

7.2

9.1

17

5.4

11

Spikes which exceed Limits and Method Blanks with positive results are highlighted by Underlininq.

Criteria for MS and DUP are advisory only, batch control is based on LeS. Criteria for duplicates



I 555 East Walnut Street Pasadena. california 91101 Tel: 626 568 6400 Fax: 626 568 6324 1 800 568 LABS (1 800 568 5227)


10-13-J:2 Al0:59 p~


#100134

8-49

E~--------------~-------[

[

[

[

[ ,... L

(

I I I I

MBLK

MS

MSD

LCS1

MBLK

MS

MSD

LCS1

MBLK

MS

MSD

LCSl

MBLK

MS

MSD

LCS1

MBLK

MS

MSD

LCS1

MBLK

MS

MSD

MBLK

LCS1

MBLK

MS

MSD

LCSl

MBLK

MS

MSD

MBLK

LCS1

MBLK

gamma-Chlordane

gamma-Chlordane

gamma-Chlordane

Hexachlorobenzene

Hexachlorobenzene

Hexachlorobenzene

Hexachlorobenzene





Heptachlor

Heptachlor

Heptachlor

Heptachlor

Heptachlor Epoxide

Heptachlor Epoxide

Heptachlor Epoxide

Heptachlor Epoxide

Indeno(l,2,3,c,d)Pyrene



Indeno(1,2,3,c,d)Pyrene

Isophorone

Lindane

Lindane

Lindane

Lindane

Methoxychlor

Methoxychlor

Methoxychlor

Methoxychlor

Metribuzin

Molinate

Molinate

ND

5

5

2

ND

5

5

2

ND

5

5

2

ND

5

5

2

ND

5

5

2

ND

5

5

ND

2

ND

5

5

2

ND

5

5

ND

2

ND

<0.05

4.17

4.39

1.91

<0.05

4.26

4.46

1. 85

<0.05

2.46

4.57

1.94.

<0.04

4.54

4.66

1.94

<0.02

4.38

4.55

2.47

<0.05

5.70

5.84

<0.50

2.12

<0.02

4.88

5.18

2.06

<0.05

4.86

5.38

<0.05

2.10

<0.20

UGL

UGL

UGL

UGL

UGL

UGL

UGL

UGL

UGL

UGL

UGL

UGL

UGL

UGL

UGL

UGL

UGL

UGL

UGL

UGL

UGL

UGL

UGL

UGL

UGL

UGL

UGL

UGL

UGL

UGL

UGL

UGL

UGL

UGL

UGL

83.4

87.8

95.5

85.2

89.2

92.5

~ 91.4

97.0

90.8

93.2

97.0

87.6

91.0

123.5

114.0

116.8

106.0

97.6

103.6

103.0

97.2

107.6

105.0

70-130

70-130

70-130

70-130

70-130

70-130

70-130

70-130

70-130

70-130

70-130

70-130

70-130

70-130

70-130

70-130

70-130

( 70-130

70-130

70-130

70-130

70-130

70-130

( 70-130 )




5.1

4.6

60

2.6

3.8

2.4

6.0

10


I 555 East Walnut Street . Pasadena, Califomla 91101 Tel: 626 568 6400 Fax: 626 568 6324 1 1100 568 LABS (1 800 568 5227)


10-13-J2 A10:59 Ii'l


#100134

8-50

~-------------------------

[

c r .. £ I I I

MS

MSD

LeSl

MBLK

MS

MSD

LeSl

MBLK

MS

MSD

LeSl

MBLK

MS

MSD

LeSl

MBLK

MS

MSD

MBLK

MBLK

LeSl

MBLK

MS

MSD

LeSl

MBLK

MS

MSD

LCSl

MBLK

MS

MSD

LCSl

MBLK

MS.

Molinate

Molinate

Metolachlor

Metolachlor

Metolachlor

Metolachlor

trans-Nonachlor

trans-Nonachlor

trans-Nonachlor

trans-Nonachlor

Pentachlorophenol

Pentachlorophenol

Pentachlorophenol

Pentachlorophenol

Phenanthrene

Phenanthrene

Phenanthrene

Phenanthrene

Prometryn

Propachlor

pyrene

Pyrene

Pyrene

Pyrene

Simazine

Simazine

Simazine

Simazine

Perylene-d12

Perylene-d12

Perylene-d12

Perylene-d12

1,3-dimethyl-2-nitrobenzene



5

5

2

NO

5

5

2

NO

5

5

8

NO

20

20

2

NO

5

5

NO

NO

2

NO

5

5

2

Nt>

5

5

100

100

100

100

100

100

100

5.19

5.25

2.33

<0.05

5.27

5.55

1.87

<0.05

4.16

4.35

9.22

<1.00

21.0

23.2

2.07

<0.02

4.77

5.15

<0.50

<0.05

2.46

<0.05

5.62

5.95

2.08

<0.05

4.72

5.06

107

92

102

102

92

95

90

UGL

UGL

UGL

UGL

UGL

UGL

UGL

UGL

UGL

UGL

UGL

UGL

UGL

UGL

UGL

UGL

UGL

UGL

UGL

UGL

UGL

UGL

'UGL

UGL

UGL

UGL

UGL

UGL

tR

tR

tR

%R

%R

%R

tR

103.8

105.0

116.5

105.4

111.0

93.5

83.2

87.0

115.3

105.0

116.0

103.5

95.4

103.0

123.0

112.4

119.0

104.0

94.4

101.2

107.0

92.0

102.0

102.0

92.0

95.0

90.0

70-130

70-130

70-130

70-130

70-130

70-130

70-130

70-130

70-130

70-130

70-130

70-130

70-130

70-130

70-130

70-130

70-130

70-130

70-130

70-130

70-130

70-130

70-130

70-130

( 70-130 )

1.1

5.2

4.5

10.0

7.7

5.7

7.0

0.00




QC 'Report Page 30 of 31

-. .. ... L.

I ,A~

I I !

MSD

LCSl

MBLK

MS

[ MSD

LCSl

MBLK

L MS

MSD

MBLK

[

[

L [

[

I I I I I [

8-51 lC)-iJ-;2 F\1'):59 !\)

555 East Walnut Street Pasadena, Calilornia 91101 Tel: 626 568 6400 Fax: 626 568 6324 1 600 568 LABS (1 800 568 5227)


1,3-dimethyl-2-nitrobenzene 100

Triphenylphosphate 100




Thiobencarb 2

Thiobencarb NO

Thiobencarb 5

Thiobencarb 5

Trifluralin NO

90

112

115

108

108

2.00

<0.20

4.57

5.29

<0·.10

tR 90.0

tR 112.0

tR 115.0

%R 108.0

%R 108.0

UGL 100.0

UGL

UGL 91.4

UGL 105.8

UGL


#100134

70-130 0.00

70-130

70-130

70-130 0.00

70-130

70-130

70-130 15



are advisory only, unless otherwise specified in t·he method.


..... ~ ,

r., .... II

I I ~

I [

[

[

[

[

C

1J-13-::12 Al0:59 IN~-52

._,/ ace Analyticar~ Pace AnalytIcal Services, Inc. tI J"jtJ{f( / 1100 Elm Street, Suite 200

I 0 I J if.. Minneapolis, MN 55414

.. ' 7I'(f' ~ www.paceJabs.com () / . Phone: 612.601.1100

Fax: 612.601.6444

This report contains..!. pages.

The results reported herein conform to the most current NELAC standards, where applicable, unless otherwise narrated in the body ofthe report.

REPORT OF LABORATORY ANALYSIS This report shall not be reproduced. except in full.

without the written consent of Pace Analytical Services. Inc.

IJ

I I I I ~

[

[

(

[

[

~

I I I £

ace Analytica/® www.pacelabs.com

September 17, 2002

Attn: Martha Frost MWH 555 East Walnut Street Pasadena, CA 91101

Dear Ms. Frost:

'I C- 'I J -:) 2 A 1 ~) : 59 I:~ 8-53

Pace Analytical Services, Inc. 1700 Elm Street, Suite 200

Minneapolis, MN 55414 Phone: 612,601.1700

Fax: 612,607.6444

MWL Project # 100134 MWL Sub PO # 99-8651 Pace Project # 1062106 m State Cert. #: 2155 Expiration Date: 6/30/03

Enclosed are analytical results of one water sample analY.led for 2,3,7,8-TeDD content. This sample was analyzed according to Method 1613B by High Resolution Gas ChromatographylHigh Resolution Mass Spectrometry.

MWL Sample ID Pace Sample ID Date Collected Date Received

2208300156 3824942 08/28/02 09/04/02

The results reported for this sample and the associated quality control samples were all within the criteria described in Method 1613B. If you have any questions or concerns regarding these results, please contact me at (612) 607-6331, by facsimile at (612) 607-6444 or bye-mail [email protected].

Sincerely,

Dan Hoscck, Project Manager High Resolution Mass Spectrometry

Enclosure

REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full,

without the written consent of Pace Analytical Services, Inc.

In:r··era:·· '~:~tC~1~~'i "": , ... .0:: .;¥

[

[

C

L [

[

I ~\;

I I I m [

'ace AnalytfcalM

8·54

10-13-J2 A10:59 I~;

P"oICC AnaIyticaIServiCC$. Inc. 1100 Eltn Sl{eCl- Suite 200

Minneapolis. MN 55414-

Tel: 612·607-1100 Drinking Water Analysis Results Pax: 612.607-6444

2,3,7,8-TCDD - USEPA Method 1613B MWH Laboratories

Sample ID ••••••••••• 2208300156 Source ID ............. Kaieie Mauka Exploratory Well Project # ............... 100134 Sub PO # .............. 99-8651 Lab Sample 10 ..... 103824942

[2,3,7,8-1rCDD]

RL

2,3,7,8-TCDD Recovery

Spike Recovery Limit

RPD

IS Recovery

IS Recovery Limits

CS Recovery

CS Recovery Limits

Filename Analysis Date Analysis Time Analyst Volume Dilution ICALDate CCAL Filename

Sample 2208300156

ND

5 pgIL

86%

31-137%

115%

42-164%

A20913B_13 09/14/2002

00:34 CMP

1.032L NA

08/28/2002 A20913A_2

ND = Outside the Control Limits = Not Detected

RL = Reporting Limit

Date CoIIected .... . 08/28/2002 Spike .................... 200 pg Date Received ...... 09/04/2002 IS Spike ................ 2000 pg Date Extracted .... . 0911212002 CS Spike .............. 200 pg

Method Blank

ND

5 pgIL

76%

31-137%

120%

42-164%

A20913B_3 0911312002

18:42 CMP

1.036L NA

08/28/2002 A209.13A_2

Lab Spike

93%

73-146%

70%

25·141%

112%

37-158%

A20913B_l 09113/2002

17:31 CMP

1.034L NA

08/28/2002 A20913A_2

10.2%

Lab SpikeDup

84%

73-146%

83%

25-141%

118%

37-158%

A20913B_2 0911312002

18:06 CMP

1.035L NA

08/28/2002 A20913A_2

Analyst: ~~ilI=M,-,--__

Limits RPD

= Control Limits from Method 1613 (10/94 Revision), Tables 6A and 7 A = Relative Percent Difference of Lab Spike Recoveries

IS = Internal Standard [2,3,7,8-TCDD· 13CI2] CS = Cleanup Standard [2.3.7,8-TCDD-37CI4]

Project No .............. 1062106

r ..

Appendix C

Data Regarding USGS Monitor Well No. 4708-02

Tom Nance Water ~ Resource Engineering

September 4, 2002 02/403 (98-03)

I: ~

c

·c

[

C [

c [

E I I

[ .. ,

Mr. Gordon Tribble District Chief Water Resources Division U.S. Geological Survey an Ala Moana Boulevard - Suite 415 Honolulu, Hawaii 96813

Dear Mr. Tribble:

Monitoring in USGS Well 4708-02 During 'Pump Testing of DWS' Kaieie Mauka Well, State No. 4708-03

Kalele, Soyth Hilo, Hawaii

Pump testing of DWS' Kaleie Mauka Well was completed on August 30th arid my equipment has now been removed from the USGS' nearby monitoring well. In order to produce useable yield, it was necessary to drill DWS' well to 170 feet below sea level, substantially deeper than the USGS well. There are a number of other differences between the two wells:

•

•

•

Groundwater in the DWS well stands about 27 feet above sea level, some 117 feet lower than the 144-foot level In the USGS well. No water level response to pumping in the USGS well was measured when pumping of the DWS well was conducted (refer to enclosed Figure 1; pumping In the DWS well was at. about 370 GPM). Water in the USGS well is more than 2° F.cooler than in the DWS well (Figure 2).

Also, in response to a rainstorm in June, a water level rise in excess of 10 feet was 'recorded In . the USGS well (Figure 3). This response, along with the other differences noted above, suggest that there may not be much value in continuing to monitor the water level in the USGS well.

Thank you for providing access to your well to enable it to be used for our monitoring purposes. The key to the well is being returned to Dale Nishimoto in your Hilo office along with a copy of this letter.

Sincerely.

Tom Nance

cc: Shari Komata - DWS Dale Nishimoto - USGS Hilo

Attachments

680 Ala Moana Boulevard, Suite 406 • Honolulu, Hawaii 96813-5411 • Phone: (808) 537-1141 • Fax: (808) 538-7757· E-mail: [email protected]

C-1

1""""1 ~ .. _ .. r::I 1-', rI r'1 r'l r1 F1 r1 rl r1 ~ r1 r1 11·

144.5

144.0

........

...I Cf)

~ 143.5 LU LU LL. -...I ~ 143.0 LU

. """-...I

0:: LU J-~ 142.5 ...I ...I LU ~ ~ 142.0 Cf) :::>

141.5

141.0 23

FIGURE 1. WATER LEVEL IN THE USGS MONITOR WELL DURING THE KAIEIE MAUKA PUMP TEST

f:~ ~~ '"('t(C'~ ~~t'2 .' - ... --- .... --- - - ~'-

~al-L- _ - -

- ~6-Utua CO t-!SQAI tz ~~ -. ~ ~~ ~ ...

..... ~ ..... .... , ..... ~ .,.. "'"'..".... ,..... ...... ,.

24 25 26 27 28 29

DAY IN AUGUST 2002

I~USGS MONITOR WELL -KAIEIE MAUKA WELL I

28.5

- ~ - 28.0 "] - .J

...I Cf)

::2: 27.5 tu

LU -.- LL. -...I LU

27.0 Gj ,.. ...I 0:: LU

~ 26.5 ~

';2 :::> ~

~ • .J.I. -.. ' ::2:

26.0 LU ~ w · · ~ \

-J ·

25.5

25.0 30 31

(') I I\)

1"'"1 iJ .. 11ft III!I .. F'1 r1 r1 r1 r1 r-t r1 f""'I ftl .... Ibl I!!I r1

FIGURE 2. COMPARISON OF TEMPERATURES IN THE DWS AND USGS KAIEIE WELLS AUGUST 26 TO 30, 2002

69.0 rl ----r-----,--------,-----,-----.,.....,....-----. I- ~

69.0

68.5 ~ 1 68.0 ~ • . \ j l 1 67.5 I ....

~ .. . .., r ,~ .... "' ...... ' ... ,. .. , ~ ~ 67.0

i 66.5 ~ ~

~ 66.0 ! ~ ~ W I-

65.5 ~ 1 65.0 ~ '0/1 "wry- ..... II ,otII't_ \ 11Op:1 , •• :1 /: "'"" .. ni" ~., I.,,,, •• f" .. ,_..... ~

6~5 l \ . 1 64.0 ~ I I I I I . I I II I I I ~

68.5

68.0

67.5

67.0

66.5

66.0

65.5

65.0

64.5

64.0 26 27 28 29 30 31

DAY IN AUGUST 2002

I~DWS WELC'=-USG8WELL I

.J

"

,~

o I

eN

~~---~~~~~~~~~~~~~~

160

155

::::J (J) 150 :2: IW W LL -m 145 > w ...J a: w ~ 140

135

130 14

~

FIGURE 3. WATER LEVEL AND TEMPERATURE IN THE USGS MONITOR WELL JUNE 14 TO 28, 2002

-W~

~ ~t fl3~ 1;i ~,.n ~

V"'-m ?1:;rdJ ~

J ~~~ ~ -- ~

\ \ ~

fJ~ ~ . 'I( r~ ~ ~ ~ ~ V rw. ~ ~ LII ..... \I~

~ "

--'- ... . .. . . -

15 16 17

~

.

18 19 20 21 22 23

DAY IN JUNE 2002 24 25 26 27 28

I-LEVEL -TEMP I

66.25

66.00

65.75 LL (!J w o -w a:

65.50 ~

a: w a.. :2:

65.25 ~

65.00

64.75

~

,~

(') . .j>.

Appendix 0

Specifications and Plan for the Well Pump

I I

i I I E

TNWRE Goulds Turbine Pump Selection ver: 6.00a 11/18/02

Curve: 1012-5

PUMP DATA SHEET

Goulds Turbine 60 Hz

Design Point: Flow: 100 US gpm Head: 1190 ft

Pump: TURBINE - 3600 Speed: 3450 rpm

Limits: Temperature: -- of Pressure: 430 psig

Specific Speed: Ns: 1290

Size: 7RAHC; (15 stages) Dia: 4.625 in

Sphere size: 0.18 in Power: --- bhp

Nss: ---

Dimensions: Suction: --- in Discharge: -- in

Vertical Turbine: Bowl Dia: 7.5 in Max Lateral: 0.25 in Thrust K Factor: 1.61

Motor: 50 hp Speed: 3600 Frame: 326TS NEMA Standard TEFC Enclosure sized for Max Power on Design Curve

Fluid: Water

NPSHa: --- ft

Piping:

Discharge Sizes-3",4"

--- Data Point --

Flow: 100 US gpm

Head: 1212 ft

Eff: 73.2%

Power: 41.8 bhp

NPSHr: 9.98 ft

ft 2000

1600

1200

800

400

0

~.Il :') .,."

~ [1 17

~'

N 'l

P

Selection file: (untitled)

Catalog: TURB60.MPC v 1.6.1

Temperature: 60 of SG: 1 Viscosity: 1 .122 cP Vapor pressure: 0.2568 psia Atm pressure: 14.7 pSia

System: -Suction: -'-- in Discharge: -- in

.,

I--"'" l---

--

-- Design Curve -

Shutoff Head: 1499 ft

Pressure: 649 psig

Min Flow: - US gpm

BEP: 73.5% eff S 1h e-i--@ 103 US gpm

NOL Pwr: 49.7 bhp @ 151 US gpm

- Max Curve -

Max Pwr: 54.5 bhp @ 156 US gpm

Flow Speed USgpm rpm

120 3450 100 3450 80 3450 60 3450 40 3450

H r n

r- I--

US gpm 20 40 60 80 100 120 140 160 180

-- PERFORMANCE EVALUATION --

Head Pump Power NPSHr Motor Motor Hrslyr Cost ft %eff bhp ft %eff hp IkW

1075 71.7 45.4 12.1 1212 73.2 41.8 9.98 1319 70.2 37.9 9 1397 63.5 33.3 8.98 1442 48.6 30 8

50 b h

25 p

engineering report for the kaieie mauka well (state … engineering report for the kaieie mauka well...

Documents