epa - usabluebook · 2009. 3. 6. · 1310-73-2 yes yes sodium hydroxide 62625-32-5 bromcresol...

ALKALINITY TEST KITMODEL DR-A • CODE 3467

QUANTITY CONTENTS CODE

15 mL *Alkalinity Indicator #1, pH 8.3 *3870-E15 mL Alkalinity Indicator #2, pH 4.5 3869-E60 mL *Alkalinity Titration Reagent B *4493DR-H1 Test Tube, 5-10-15 mL, glass, w/cap 07781 Direct Reading Titrator, 0-200 Range 0382*WARNING: Reagents marked with a * are considered to be potential healthhazards. To view or print a Material Safety Data Sheet (MSDS) for thesereagents see MSDS CD or www.lamotte.com. To obtain a printed copy,contact LaMotte by e-mail, phone or fax.To order a complete set of refill reagents, order as R-3467. To order individualreagents or test kit components, use the specified code number.NOTE: Carefully read the instruction manual for the LaMotte DirectReading Titrator before performing the titration described below. TheTitrator is calibrated in terms of alkalinity expressed as parts per million(ppm) calcium carbonate (CaCO3). Each minor division on the Titratorscale equals 4 ppm CaCO3.

EPA ACCEPTED PROCEDURE

To qualify as an EPA accepted test and to achieve greatest accuracy, thenormality of the *Alkalinity Reagent B should be checked periodically.Standardize *Alkalinity Reagent B by titrating against 0.05N Na2CO3;1 mL = 1.00 mg CaCO3. Should a variance of greater than 0.3 mL of*Alkalinity Reagent B occur, discard and order a fresh bottle of*Alkalinity Reagent B (Code 4493DR-H). A CaCO3 equivalentstandard of 100 ppm is also available (Code 6199-H). Refer to Standard

Methods, 16th edition, 403, 1985.

EPACOMPLIANT

PHENOLPHTHALEIN (P) ALKALINITY PROCEDURE

1. Fill test tube (0778) to 5 mL line with sample water.2 Add two drops of *Alkalinity Indicator # 1 (3870). Cap and mix. If

no red color develops, P alkalinity is zero. If red, proceed to Step 3.3. Fill Direct Reading Titrator with *Alkalinity Reagent B (4493).

Insert Titrator in center hole of test tube cap.4. While gently swirling tube, slowly depress plunger until red color

disappears. Record test result where plunger tip meets titrator scale.Record as P Alkalinity in ppm CaCO3.EXAMPLE: Plunger tip is 3 minor divisions below 80 line. Thetest result is 80 + (3 x 4) = 92 ppm, since each division is equal to4 ppm.

5. If plunger tip reaches the bottom line on the titrator scale (200ppm) before the endpoint color change occurs, refill Titrator andcontinue titration. When recording test result, include originalamount of reagent titrated (200 ppm).NOTE: Do not move the titrator plunger after P Alkalinityendpoint has been obtained.

TOTAL (T) ALKALINITY PROCEDURE

6. Without moving plunger, remove Titrator and test tube cap fromtest tube containing sample from Step 4.

7. Add two drops Alkalinity Indicator #2. Cap and swirl to mix. Ablue color will appear. Insert Titrator in center hole of test tube cap.

8. While gently swirling tube, slowly depress plunger until blue colorchanges to green. Record test result as T Alkalinity in ppm CaCO3.Include total amount of titration reagent added. (See Step 5).

9. If only Total Alkalinity is to be tested, perform Steps 1, 7 and 8only, using a full titrator for Step 8.

CALCULATION OF ALKALINITY RELATIONSHIPS

Results obtained from Phenolphthalein and Total Alkalinitydeterminations offer a means for the stoichiometric classification ofthree principal forms of Alkalinity present in many water supplies.Classification attributes the entire alkalinity to bicarbonate, silica,phosphoric and boric acids. This classification system further assumesincompatilibity of Hydroxide and Bicarbonate Alkalinities in the samesample. Since calculations are on a stoichiometric basis, ionconcentrations in the strictest sense are not represented in the results.According to this scheme:A. Carbonate Alkalinity is present when Phenolphthalein is not zero

but is less than the Total Alkalinity.B. Hydroxide Alkalinity is present if Phenolphthalein Alkalinity is

more than one-half the Total Alkalinity.C. Bicarbonate Alkalinity is present if Phenolphthalein Alkalinity is

less than one-half the Total Alkalinity.Mathematical conversion of the result is shown in the following table:

Relationships Between Phenolphthalein,Total, Carbonate, Bicarbonate and Hydroxide Alkalinity

Result ofTitration

HydroxideAlkalinity as

CaCO3

CarbonateAlkalinity as

CaCO3

BicarbonateAlkalinity as

CaCO3

P = 0 0 0 TP < ½T 0 2P T � 2PP = ½T 0 2P 0P > ½T 2P � T 2(T � P) 0

P = T T 0 0

MATERIAL SAFETY DATA SHEETP.O. Box 329 - 802 Washington Avenue Chestertown, MD 21620 - USATELEPHONE # FOR INFORMATION 410 778-310024 HOUR EMERGENCY NUMBER (CHEM-TEL): USA, Canada, Puerto Rico 800-255-3924;

MSDS

Outside North American Continent 813-248-0585 (call Collect)

1. Product Identification

Alkalinity Indicator pH 4.5

Product Code: 3869Product Description:

Manufactured By: LaMotte Company802 Washington AvenueChestertown, MD 21620

TLVPEL

C 2 mg/cubic m

N/E

%

<0.1

0.1

to 100%

1310-73-2

62625-32-5

7732-18-5

2. Composition/Information On Ingredients

CAS#/Name

Sodium Hydroxide

Bromcresol Green, sodium salt

Water

C 2 mg/cubic m

N/E

Hazard

Yes

Yes

No

3. Hazards Overview

N/A

Primary Route Of Entry: Ingestion

Carcinogenicity: None:

Non-toxic, non-hazardous

Other Health Related Comments:

HMIS HazardScale: 4 = Extreme, 3 = High, 2 = Moderate, 1= Slight, 0 = Least

Health: 0 Flammability: 0 Reactivity: 0

1

3869 Alkalinity Indicator pH 4.5Product Code: Product Description:

4. First Aid Measures

Eye Contact:

Skin Contact:

Inhalation:

Ingestion:

Flush thoroughly with water.

Drink water. Consult physician if symptoms appear.

N/A

Wash with soap and water.

5. Fire Fighting Measures

Extinguishing Media:Special Fire Fighting Procedures:

Flash Point (Method Used): UEL:LEL: N/A N/A

Unusual Fire & Explosion Hazard:

N/A

Not a fire hazard

N/A

N/A

6. Accidental Release Measures

Mop up and flush down drain with excess water.

7. Handling & Storage

Store in cool, dry, place out of direct sunlight.

2


8. Exposure Controls/Personal Protection

Normal

Eye Protection Lab Coat

Ventilation

Protection When Handling

N/AWork/Hygenic Practices:

9. Physical & Chemical Properties

Appearance:Solubility In Water:Odor:pH:

NoneSolubleDark Green Liquid

4.5

Vapor Density: <1 (Air=1)<17 mm Hg @ 20 deg CVapor Pressure:

Boiling Point: ca. 100 degCN/AMelting Point:

10. Stability & Reactivity

Stable: Yes

N/A

N/A

N/AHazardous Decomposition Products:

Incompatibility (Materials To Avoid):

Conditions To Avoid:

11. Toxicological Information

Non-toxic

Target Organs: N/A

3


12. Ecological Information

Information Not Yet Available

13. Disposal ConsiderationsPour down drain with excess water. Dispose according to federal, state and local regulations.

QRLabel5314. Transportation Information

Not Regulated For Transport

15. Regulatory Information

Ingredient--- Canada ---USA

TSCAEurope EC DSL NDSL Australia Japan

Yes Yes1310-73-2Sodium Hydroxide

62625-32-5Bromcresol Green, sodium salt

7732-18-5Distilled Water

Yes No Yes Yes

Yes Yes Yes No No No

YesYes Yes No Yes Yes

Hazard

Yes

Yes

No

Chemical Inventory Status

Federal, State, & International Regulations

Ingredient TPQRQ--------- SARA 313 ---------

Chemical Category--- SARA 302 ---

CERCLARCRA 261.33

TSCA 8(D)

1310-73-2Sodium Hydroxide



No No

No No

No No

No

1000

No No

No No

No No

No No

Listed

No

No

No

No

No

4


Ingredient

--- SARA 311/312 ---Hazard Categories

-------- Australia -------Hazchem Code

Poison Schedule




S6

None Allocated

None Allocated

Yes

No

Yes 2R

None Allocated

None Allocated

No

No

No

No

No

No

No Yes

No No

No No

Acute Chronic Fire Pressure ReactivityThis MSDS Is WHMIS Compliant

3869No No No No No None Allocated None Allocatedproduct

as a whole

Yes

16. Other Information

Prepared By:8/31/2006Revised:

IP, Regulatory Affairs Department

5


MSDS



Alkalinity Indicator pH 8.3



TLVPEL

400 ppm

N/E

%

47

0.5

to 100%

67-63-0

77-09-8

7732-18-5


CAS#/Name

2-propanol

Phenolphthalein

Water

980 mg/cubic m

N/E

Hazard

Yes

Yes

No

3. Hazards Overview

Warning! Flammable liquid and vapor. Harmful if swallowed or inhaled. May be irritating to eyes, skin, and respiratory tract. Affects central nervous system.

Primary Route Of Entry: Eye Skin Ingestion Inhalation

Carcinogenicity: Yes: NTP

Warning This product contains phenolphthalein, a chemical known to the state of California to cause cancer.




1



Eye Contact:

Skin Contact:

Inhalation:

Ingestion:

Flush with water for 15 minutes. Consult a physician.

Drink large amounts of water. Consult physician immediately.

Remove to fresh air.

Flush with water. Wash with soap and water.



Flash Point (Method Used): UEL:LEL: 2% 12%


ca. 13 C--closed cup

Dry chemical, CO2, or water spray

N/A

Vapors may flow along floor to ignition source and flash back.


Eliminate all sources of ignition. Absorb on paper. Evaporate on iron pan in hood.


Store in cool, dry, storage area away from heat, ignition sources, and incompatible materials. Do not use near heat or flame

2



Mechanical

Eye Protection Gloves Lab Coat

Ventilation


Use with adequate ventilation and avoid contact with skin and eyes.Work/Hygenic Practices:



AlcoholSolubleClear Colorless Liquid

N/A

Vapor Density: >1 (Air=1)ca. 30 mm Hg @ 20 CVapor Pressure:

Boiling Point: <100 deg CN/AMelting Point:


Stable: Yes

Heat, sources of ignition

Contact with nitric acid or other strong oxidizers

COxHazardous Decomposition Products:




oral rat LD50: 5840 mg/kg; oral human LD50: 3570 mg/kg for 2-propanol. Investigated as a tumorigen, mutagen, reproductive effector.

Target Organs: Central Nervous System Eyes Lung Skin

3



When released to water or soil, isopropanol is expected to quickly evaporate.Not expected to significantly bioaccumulate.When released into the air, it is expected to be readily degraded or to be removed to a degree by wet deposition (rain,snow)

13. Disposal ConsiderationsSmall quantity: Flush down drain with excess water. Large quantity: Atomize into an incinerator. Dispose according to federal, state and local regulations.

14. Transportation Information

Proper Shipping Name:ISOPROPANOLDOT:

IATA: ISOPROPANOL

Hazard Class/Div:33IATA:

DOT:

UN: 1219

IIPacking Group:




Yes Yes67-63-0Isopropyl Alcohol

77-09-8Phenolphthalein


Yes No Yes Yes

Yes Yes Yes No Yes Yes

YesYes Yes No Yes Yes

Hazard

Yes

Yes

No


4





CERCLARCRA 261.33

TSCA 8(D)

67-63-0Isopropyl Alcohol



No No

No No

No No

No

No

No No

No No

No No

No No

Listed

Yes

No

No

No

No

5


Ingredient



Poison Schedule

67-63-0Isopropyl Alcohol



None Allocated

None Allocated

None Allocated

Yes

No

Yes 2[S]2

None Allocated

None Allocated

Yes

Yes

No

Yes

No

No

No No

No No

No No


3870 Yes Yes Yes No No 2[S]2 None Allocatedproductas a whole

Yes




6


MSDS



Sodium Hydroxide, 1.0 N



TLVPEL

C 2 mg/cubic m

%

4

to 100%

1310-73-2

7732-18-5


CAS#/Name

Sodium Hydroxide

Water

C 2 mg/cubic m

Hazard

Yes

No

3. Hazards Overview

Warning! Corrosive. Can cause severe irritation or burns to all body tissue. Harmful if swallowed.

Primary Route Of Entry: Skin Ingestion





1

4004 Sodium Hydroxide, 1.0 NProduct Code: Product Description:


Eye Contact:

Skin Contact:

Inhalation:

Ingestion:

Immediately flush with water for 15 minutes. Consult a physician.

Do not induce vomiting. Rinse out mouth. Drink plenty of water. Call a doctor immediately.

N/A

Immediately flush with water for 15 minutes. Remove affected clothing and rinse skin thoroughly.





N/A

Not a fire hazard

N/A

N/A


Wear gloves and eye protection. Carefully neutralize with vinegar or other dilute acid (6 M HCl). Mop up and flush to drain with excess water.


Store in cool, dry, storage area away from acids and other incompatible materials.

2



Normal


Ventilation


Avoid contact with eyes, skin and clothing. Wash after handling.Work/Hygenic Practices:



NoneSolubleClear Colorless Liquid

14

Vapor Density: <1 (Air=1)<17 mm Hg @ 20 deg CVapor Pressure:

Boiling Point: 102 deg C (5% soln)(-) 4 deg C (5% soln)Melting Point:


Stable: Yes

N/A

Strong acids, metals

N/AHazardous Decomposition Products:




Sodium hydroxide investigated as a tumorigen, mutagen.

Target Organs: Corrosive to all body parts Skin

3




13. Disposal ConsiderationsNeutralize and flush down drain with excess water. Dispose according to federal, state and local regulations.

14. Transportation Information

Proper Shipping Name:SODIUM HYDROXIDE SOLUTIONDOT:

IATA: SODIUM HYDROXIDE SOLUTION

Hazard Class/Div:

88

IATA:DOT:

UN: 1824

IIPacking Group:




Yes Yes1310-73-2Sodium Hydroxide


Yes No Yes Yes


Hazard

Yes

No





CERCLARCRA 261.33

TSCA 8(D)



No No

No No No

1000 No No

No No

Listed

No

No

No

No

4


Ingredient



Poison Schedule



S6

None AllocatedNo

Yes 2R

None Allocated

No

No

No

No

No Yes

No No


4004Yes No No No No 2R S5product

as a whole

Yes




5


MSDS



Alkalinity Titration Reagent



TLVPEL

1 mg/cubic m

%

0.1

to 100%

7664-93-9

7732-18-5


CAS#/Name

Sulfuric Acid

Water

1 mg/cubic m

Hazard

Yes

No

3. Hazards Overview

May irritate eyes and skin.

Primary Route Of Entry: Skin


Non-toxic




1

4015 Alkalinity Titration ReagentProduct Code: Product Description:


Eye Contact:

Skin Contact:

Inhalation:

Ingestion:

Flush thoroughly with water for 15 minutes. Consult a physician if irritation develops.

Rinse out mouth. Drink 1 - 2 glasses of water. Consult physician if symptoms appear.

N/A

Flush with water. Remove affected clothing and wash skin with soap and water.





N/A

Not a fire hazard

N/A

N/A


Cover spill with sodium bicarbonate. Scoop up slurry and wash down drain with excess water.


Store in cool, dry, place.

2



Normal


Ventilation


Avoid contact with eyes and skin. Wash after handling.Work/Hygenic Practices:




2

Vapor Density: <1(Air=1)<17 mm Hg @ 20 deg CVapor Pressure:

Boiling Point: ca. 100 deg CN/AMelting Point:


Stable: Yes

N/A

N/A

Sulfur OxidesHazardous Decomposition Products:




Oral rat LD50: 2140 mg/kg for sulfuric acid, concentrated. Product 4015 may be irritating to stomach if much is swallfowed because pH is slightly acidic.

Target Organs: Skin

3




13. Disposal ConsiderationsAdd slowly to a solution of sodium bicarbonate or sodium carbonate. Pour neutralized solution down drain with excess water. Dispose according to federal, state and local regulations.






Yes Yes7664-93-9Sulfuric Acid


Yes No Yes Yes


Hazard

Yes

No





CERCLARCRA 261.33

TSCA 8(D)

7664-93-9Sulfuric Acid


1000 1000

No No No

1000 No No

No No

Listed

Yes

No

No

No

4


Ingredient



Poison Schedule



None Allocated

None AllocatedNo

Yes 2P

None Allocated

Yes

No

No

No

No Yes

No No


4015No No No No No None Allocated None Allocatedproduct

as a whole

Yes




5


MSDS



Alkalinity Titration Reagent B



TLVPEL

1 mg/cubic m

%

0.1

to 100%

7664-93-9

7732-18-5


CAS#/Name

Sulfuric Acid

Water

1 mg/cubic m

Hazard

Yes

No

3. Hazards Overview

May be irritating to skin. May be harmful if swallowed.

Primary Route Of Entry: Ingestion Skin

Carcinogenicity: None




1

4493 Alkalinity Titration Reagent BProduct Code: Product Description:


Eye Contact:

Skin Contact:

Inhalation:

Ingestion:

Flush thoroughly with water for 15 minutes. Consult a physician if irritation develops.

Rinse mouth, drink glass of water and consult physician if symptoms appear.

Remove to fresh air.

Flush with water. Remove affected clothing and wash skin with soap and water.





N/A

Not a fire hazard

N/A

N/A


Cover spill with sodium bicarbonate. Scoop up slurry and wash down drain with excess water.


Store in cool, dry, storage area..

2



Normal

Gloves Eye Protection Lab Coat

Ventilation


Avoid contact with eyes, skin and clothing.Work/Hygenic Practices:




2

Vapor Density: <1 (Air=1)<17 mm @ 20 deg CVapor Pressure:

Boiling Point: ca. 100 deg CN/AMelting Point:


Stable: Yes

N/A

N/A

SOxHazardous Decomposition Products:




Oral rat LD50: 2140 mg/kg for sulfuric acid concentrated. Product #4493 is non-toxic but may be irritating to skin or cause GI distress if swallowed because of its sllght acidity (pH2).

Target Organs: Skin

3




13. Disposal ConsiderationsAdd slowly to a solution of sodium carbonate & calcium hydroxide. Pour this neutralized solution down drain with excess water. Dispose according to federal, state and local regulations.






Yes Yes7664-93-9Sulfuric Acid


Yes No Yes Yes


Hazard

Yes

No





CERCLARCRA 261.33

TSCA 8(D)



1000 1000

No No No

1000 No No

No No

Listed

Yes

No

No

No

4


Ingredient



Poison Schedule



None Allocated

None AllocatedNo

Yes 2P

None Allocated

Yes

No

No

No

No Yes

No No


4493 Yes No No No No None Allocated None Allocatedproductas a whole

Yes




5

epa - usabluebook · 2009. 3. 6. · 1310-73-2 yes yes sodium hydroxide 62625-32-5 bromcresol...

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