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    Proprietary and Confidential Copyright 2007 Pavilion Technologies

    Ethanol From Corn Process

    Dry Mill Ethanol Process Lina M Rueda

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    Copyright 2007 Pavilion Technologies 2

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    Copyright 2007 Pavilion Technologies 3

    The Distillery Flow Diagram: From Corn to Ethanol Plus Co-products

    1 bushel

    of corn(56 lbs)

    Starch(32 lbs)

    Milling

    Fermentablesugar

    (36 lbs)

    Liquefaction

    Saccharification

    Ethanol

    (17.6 lbs)

    +DDGS

    (17 lbs)

    +Heat

    (7450 BTU)

    +

    CO2(18.4 lbs)

    Fermentation

    Recovery

    Dryhouse

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    Copyright 2007 Pavilion Technologies 4

    Fermentation Fundamentals

    Key Ingredients

    -

    Starch (sugar source)- Enzymes (breakdown of starches)

    - Yeast (conversion of sugar to ethanol)

    Key Process Components- Enzyme addition

    - Yeast propagation

    - Fermentation cycle

    -

    Cooling system

    EnergyCOOHHCOHC 2556126

    22

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    Copyright 2007 Pavilion Technologies 5

    Process Description Milling

    Cooking and mixing

    -Milled corn and cook water

    - a-Amylase to break down long polymer chains (starch), reduce solids

    - Solubilization of sugars

    - Release of bound sugars: starch is bound to protein and fiber which is

    released during cooking

    - Gelatinization: absorb water so enzymes can react with molecules

    Liquefaction

    - Using a-Amylase to break down starches to shorter chain molecules

    Saccharification and Fermentation

    -Batch processs (~ 50-60 hours)

    - Exothermic

    - Glucoamylase is used to break down short chained molecules to glucose

    - Yeast is added to convert glucose to ethanol

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    Copyright 2007 Pavilion Technologies 6

    Water Balance

    Methanator

    Slurry Tank

    Process Water

    Liquefaction

    Backset

    Beer Feed

    Milling

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    Fermentation

    Slurry TankLiquefaction

    Backset

    Beer Feed

    FermenterYeast Propagation

    Enzymes

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    Distillation

    -

    Separate Ethanol from non-fermentable components Dehydration

    - Azeotropic Distillation

    - Molecular Sieves

    Non-Fermentables- Centrifugation

    - Evaporation

    - Drying

    Process Description

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    Distillation

    Beer Feed

    Evap. Steam

    Steam Flow

    Sieve BackPressure

    Rectifier Reflux Sieve Feed

    Vaporizer Temperature

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    Copyright 2007 Pavilion Technologies 10

    Dryer, Evaporator and TO

    Steam Flow

    Centrifuge Feed

    Whole Stillage

    Thin Stillage

    Syrup Tank

    Wet Cake

    Pad

    Evaporators

    Dryers

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    Control Strategy

    Ethanol Plant-Wide Optimizer

    Dryer Evap TOAPC&

    Distill/Sieve APC

    Fermentation APCSlurry/WaterbalanceAPC

    Mv setpointsPlant and constraintMeasurements (CV)

    Energy,feedstock,ProductValues

    $ costs