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EXTERNAL AUDIT REPORT IN FULFILMENT OF THE WASTE
MANAGEMENT LICENSE FOR THE
DECOMISSIONING AND REMEDIATION OF THE
KLIP WASTE SITE
AT
ARCELORMITTAL VEREENIGING WORKS
Report Nr: 194-ZANAMVE-2015
Audit date: 13 May 2015
Report date: 05 June 2015
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External audit report on the WML for Klip waste site at AMSA Vereeniging
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General Information
Report Name: External Audit Report for the Decommissioning and Remediation of the Klip
Waste Site
Environmental Auditor
Zantow Environmental Consulting Services CC
22 Delius Street, SW 5
Vanderbijlpark
PO Box 3858
Vanderbijlpark , 1911
Contact Person:
Trevor Hallatt
Tel: 082 574 6658
Fax: 016 932 4976
Email: [email protected]
Client:
ArcelorMittal South Africa Vereeniging Works
PO Box 48
Vereeniging
1930
Contact Person:
Waste Management Control Officer (WMCO)
Jeremiah Mnisi
Cell: 083 468 1562
Email: [email protected]
Report compiled by: Trevor Hallatt
Audit Date: 13 May 2015
Status: Final
License Nr 12/9/11/L130/3
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EXECUTIVE SUMMARY
Zantow Environmental Consulting Services CC was appointed by ArcelorMittal to conduct an independent
compliance audit on its waste management license (License Nr 12/9/11/L130/3) for the decommissioning of
the Klip Waste Site in terms of condition 7.2.1 of the WML issued on the 10th March 2010.
The methodology followed for conducting the compliance assessment audit included;
Documentation review
Compilation of audit checklist/questionnaire for site visit;
Site Visit (Conducted on the 13th
May 2013); and
Compilation of compliance audit report.
The compliance to each condition of the license was assessed and the details are contained in Table 1.
Compliance to the conditions is categorised in terms of compliance, partial compliance or non-compliance.
In addition to indicating non-compliance or partial compliance, the auditor contextualised the non-compliance
in terms of the intensity. This equates to an objective view of the seriousness of the non-compliance and also
then leads to recommendations where moderate to critical non-compliances have been observed. The non-
compliances are categorised in terms of the following criteria:
Minor Issues
Moderate Issues
Critical Issues
Where an area of improvement has been identified, an observation is raised. This does not constitute a non-
compliance per se, but could lead to improved management systems or controls. ArcelorMittal reserves the
right to implement these at their discretion. The non-compliances raised during the audit mainly relate to
groundwater monitoring requirements and to a lesser extent to some operational controls.
The following findings were raised and recommendations made to improve compliance to the WML;
Monitoring is not undertaken at all of the required boreholes as some of the boreholes have been
damaged and are blocked. It was reported that a contractor started on the 27th of May 2015 to repair
the blocked boreholes, issue each a lockable cap and establish poles to clearly mark the respective
boreholes. Once the boreholes have been repaired, monitoring must commence at the required
frequencies at all of the boreholes (WMCO, June 2015).
At the time of the audit it was reported that monitoring of organic elements commenced in 2014,
however TOC was not monitored in the third quarter (November) of the 2014 reporting period. The
sampling and analysis must be re-assessed in terms of the license and the required elements be
monitored as required until an agreement is reached with the authorities to amend the condition
(WMCO, July 2015).
No gas monitoring is undertaken as required. An amendment application was submitted to remove
this requirement, however until the amendment has been approved the condition is still in force.
Monitoring should therefore proceed as required until the request is formally approved by the
Department (WMCO, July 2015).
The fence on the North-Eastern side of the site has been damaged. The fence should be repaired
before it is completely degraded (WMCO, July 2015).
Further to the legal compliance issues, observations were also raised where there is a possibility to improve
on the environmental practises. These are not legal requirements and ArcelorMittal should investigate the
feasibility of implementation in context with the current situation and available resources. The following
observations were made;
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The amendment application submitted for the new remediation plan and EMP must be followed up
with the department to ensure the remediation process can proceed timeously. It is recommended that
a meeting be set up with DEA in order to present the updated remediation plan and EMP as this is a
substantial amendment (WMCO, July 2015).
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Contents
1. INTRODUCTION .......................................................................................................................................... 6
2. BACKGROUND............................................................................................................................................ 6
3. AMENDMENT APPLICATION FOR TECHNICAL SCOPE ......................................................................... 6
4. PART 1: AUDIT INFORMATION................................................................................................................ 10
4.1. Date of Audit........................................................................................................................................... 10
4.2. Audit Criteria / Scope of Work ................................................................................................................ 10
4.3. Audit Methodology ................................................................................................................................. 10
4.4. Objectives ............................................................................................................................................... 11
4.5. Comments from previous audit reports .................................................................................................. 12
4.6. Declaration ............................................................................................................................................. 13
5. PART 2: AUDIT FINDINGS ........................................................................................................................ 14
5.1. Positive observations/findings ................................................................................................................ 14
5.2. Compliance to the License conditions ................................................................................................... 14
5.3. Authorisation conditions ......................................................................................................................... 15
6. GROUND WATER MONITORING DATA .................................................................................................. 32
7. GAS AND AIR QUALITY MONITORING DATA ........................................................................................ 38
8. CONCLUSION AND RECOMMENDATIONS ............................................................................................ 39
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1. INTRODUCTION
Zantow Environmental Consulting Services CC was appointed by ArcelorMittal to conduct an independent
compliance audit on its WML (License Nr 12/9/11/L130/3) for the decommissioning of the Klip Waste Site in
terms of condition 7.2.1 of the WML issued on the 10th March 2010.
The compliance audit entailed a site visit and a document audit. Compliance was verified with every condition
in the license and the monitoring data assessed and interpreted.
2. BACKGROUND
The Klip Waste Site at ArcelorMittal in Vereeniging is located in the Duncanville Industrial Area close to the
Klip River. The Site was used for the disposal of various waste streams (scrap metal, tar, pitch, oxidised slag,
builder’s rubble, sludge, phenolic effluent and ash) from the early 1950’s to approximately 1990. A phenol dam
was located on top of the Site, which was used to dispose effluent from the Gas Plants at the Klip and Vaal
Works, as well as liquid effluent from the Vanadium Recovery Plant.
Access to the site is restricted by means of a fence and a security gate. The fenced-off area covers
approximately 30 hectares, although the waste body only covers an area of approximately 9 hectares. The
crest of the waste body is some 9 m above natural ground level on the eastern side and the waste body is
located within the floodplain of the Klip River. Existing slopes are typically 1:2.5 and are generally stable,
although one localized area of instability was noted where a gulley has formed towards the Klip River. The
slope at the river side was noted to be very steep.
The site is surrounded by industrial activities and the residential area of Three Rivers is located to the east of
the Site. A building located adjacent to the Site is used by a fishing club for occasional meetings. The
remediation of the Klip waste site commenced in 2012 with the removal of tar waste to an off-site hazardous
landfill site. Since the removal of the hazardous waste the facility re-assessed the remediation plans and
proposes changes to the remediation plan. An amendment application has been submitted in 2013. All
remediation work was placed on hold until such time as the proposed remediation plan can be resolved with
the authorities.
3. AMENDMENT APPLICATION FOR TECHNICAL SCOPE
A detailed baseline site assessment was done of the site to determine the impact in 2001. It was
demonstrated that the subsurface conditions at the site have been impacted by numerous inorganic
constituents that originated from the Vanadium Plant effluent that was stored in the phenol dam between 1990
and 1991.
Following the baseline assessment, various remediation options were investigated and the preferred
remediation option determined. An Environmental Impact Assessment (EIA) was completed in 2006 in terms
of the National Environmental Management Act (No.107 of 1998) for the closure and remediation of the site.
A WML was subsequently issued by the Department of Environmental Affairs (DEA) on the 10th f March 2010.
Since the completion of the baseline assessments (2001) and the EIA (2006), a significant time period has
passed. Subsequent monitoring and additional studies commissioned by ArcelorMittal painted a different
picture of the current status of the site compared to the site conditions found more than a decade ago. The
Tar dumps were also removed from site and disposed at a licensed hazardous waste site in 2012. This
prompted ArcelorMittal to appoint Dr Willie van Niekerk from Infotox (Pty) Ltd to conduct a follow up site
characterization to determine if the initial remediation plans were still relevant and the best possible and
practical solution.
The investigations were conducted on the premise that it was likely that site conditions would have changed
during the last ten years since the Jones & Wagener assessment in 2001. Firstly, some proportion of water-
soluble compounds would have dissolved in rain water and would have been dispersed and diluted in
groundwater and surface water away from the site. Secondly, some of the organic compounds would have
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biodegraded further since 2001 and concentrations in the soil and groundwater were expected to have
decreased.
Analytical data of samples collected by Georem confirmed that organic contaminant concentrations decreased
since the early Jones & Wagener (2001) investigations, which supported the understanding of Infotox. It was
concluded that Phenol had degraded and was no longer of concern in the groundwater. Similarly, it was
confirmed that the alkyl phenols had biodegraded to insignificant levels. Average Naphthalene levels were
found to be low, suggesting significant biodegradation over time. These results placed a new perspective on
the contaminant profile of the phenol dam, as well as other areas associated with coal tar. A ground water
conceptual model was also developed for the first time to better understand the finding’s and is in line with the
conclusions and recommendations made by Infotox during 2012 & 2013.
The latest specialist studies concluded that no in situ capping in the form of a liner is needed. The monitoring
results confirmed that the contamination has over the last decade reduced significantly and is no longer of
concern. From a health and environmental perspective it was argued that the waste site can be left as is.
From a duty of care perspective, ArcelorMittal decided that a minimum liner would be installed on the site after
the shaping is completed in line with NEMA’s precautionary approach principal and from an aesthetic point of view.
The information was consolidated and an updated Remediation Plan and Environmental Management
Program for the remediation of the Klip Waste Disposal Site were developed. ArcelorMittal submitted an
amendment application in July 2013 for the closure of the site. The department acknowledged the receipt of
the application but has not made a final decision.
The facility requested amendment to the following conditions as follows;
Condition
Number
Condition as written in the current
authorisation Proposed condition
1.1.1
The License authorises the
decommissioning and remediation of the
Klip Waste Disposal Site on Portion 68
of the farm Klipplaatdrift 601 IQ in
Vereeniging, Gauteng (hereinafter
referred to as “the Site”) according to the Environmental Impact Report:
Remediation of Klip Waste Site,
Vereeniging (Report Number:
JW176/06/A707) and the Environmental
Management Plan (Report Nr
JW168/07/B461) by Jones and Wagner
Consulting Engineers, dated October
2006 and November 2007 respectively,
and (herein after referred to as “the Reports”) and, the Record of Decision, issued by the Gauteng Department of
Agriculture and Rural Development
dated 8 August 2007, submitted by the
proposed License Holder.
The License authorises the decommissioning and
remediation of the Klip Waste Disposal Site on Portion
68 of the farm Klipplaatdrift 601 IQ in Vereeniging,
Gauteng (hereinafter referred to as “the Site”) according to the amended Remediation Plan and Environmental
Management Plan, dated July 2013 by Zantow
Environmental Consulting Services.”
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Condition
Number
Condition as written in the current
authorisation Proposed condition
1.1.2
The location of the site shall be
according to the co-ordinates indicated
on the permit application Form and
reports submitted by the License Holder
which is defined as follows;
The location of the site shall be according to the co-
ordinates indicated on the permit application Form and
reports submitted by the License Holder which is defined
as follows;
Corner S E
A 26°39’5.25” 27°57’23.95”
B 26°39’2.04” 27°57’15.32”
C 26°39’3.97” 27°57’13.52”
D 26°39’3.32” 27°57’11.03”
E 26°39’23.01” 27°57’55.27”
F 26°39’30.42” 27°57’54.25”
G 26°39’31.14” 27°57’55.04”
H 26°39’26.97” 27°57’14.35”
I 26°39’19.68” 27°57’14.65”
J 26°39’19.83” 27°57’19.50”
3.1
The License and the EMP (Report No.
JW168/07.B461), compiled by Jones
and Wagner dated November 2007, is
binding and must be updated at all
times to ensure it’s relevant. Substantial
changes must be approved by the
Director.
The License and the EMP (Report No. JW168/07.B461),
compiled by Zantow Environmental Consulting Services,
dated July 2013, is binding and must be updated at all
times to ensure it is relevant. Substantial changes must
be approved by the Director
3.3
Closure and rehabilitation must be
carried out under the supervision of a
registered Professional Engineer
appointed by the License Holder and
according to the approved engineering
drawing numbers A720-00-001, A720-
00-002, A720-00-003, A720-00-004,
A720-00-005 and A720-00-006,
prepared by Jones and Wagner
Consulting Engineers dated April 2006.
(Annexure VI hereafter)
Closure and rehabilitation must be carried out under the
supervision of a registered Professional Engineer
appointed by the License Holder and according to the
approved engineering drawing numbers
klip24-06-2013,
0710-07355-100001-001. 0710-07355-100001-002.
0710-07355-100001-003. 0710-07355-100001-004.
(Annexure VI hereafter)
3.7
The license holder must construct
seepage collection trenches between
the site toe and the Klip River to
address movement of pollution plumes
to the river.
Delete
6.6.1
The License Holder must maintain gas
monitoring test pits VOC-01: South
Western boundary of the site
(downwind) and VOC-02: North eastern
boundary of the site (upwind) and the
concentration by volume in air at
Standard Temperature and Pressure, of
flammable gas and carbon dioxide shall
Delete
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Condition
Number
Condition as written in the current
authorisation Proposed condition
not exceed 1% and 0.5% respectively in
the test pits.
6.6.2
Gas monitoring must be conducted
monthly from the date of this license for
a period of two years and thereafter
send the results to the Director for
determination of monitoring frequency if
further required.
Delete
8.3
Records demonstrating compliance with
condition 2.1 and any other records
required by this License must be
maintained and be made available on
request.
Records demonstrating compliance with condition 8.1
and any other records required by this License must be
maintained and be made available on request.
12.1
The site or any portion thereof, including
the surface of the site, must be covered
and the site must be maintained that no
objects or material including facilities
and old machinery which may hamper
the remediation of the site, are present.
The site or any portion thereof, including the surface of
the site, must be remediated according to the final
remediation plan and the site must be maintained that
no objects or material including facilities and old
machinery which may hamper the remediation of the
site, are present.
12.2.3
Operation and maintenance of the
landfill gas control system whereby gas
monitoring by the license holder as
described by condition 6.6 must
continue after closure for a period of two
years or such time longer as determined
by the Director. Should the atmospheric
levels be between 0.1% and 1% during
remediation measures a higher
monitoring frequency should be
installed. Should levels be above 1%
the license holder must submit
contingency plans regarding
occupational safety to the director. This
must be implemented after approval.
Delete
12.4
The temporary lined facility to be used
for dewatering of phenolic waste must
be in use for the period of remediation of
the site which must not exceed three
years.
Delete
12.5
The license holder must not use
condition 12.4 above as a means to
authorise the said facility for other
purposes in future. There shall be no
authorisation for extension of
timeframes and change of use for the
said facility without the license holder
having to start the process of licensing
from the beginning.
Delete
12.7 The License Holder must submit an end
use plan to the Director within six (6)
The end use plan indicate the site will be used in future
as a brown field site with certain portions earmarked for
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Condition
Number
Condition as written in the current
authorisation Proposed condition
months of being issued with this
License.
industrial and or commercial use dependant on the
relevant approval(s) from the municipal council and or
any other department.
13.12
All hazardous material (waste and
contaminated soil) must be treated with
lime and be ash blended prior to being
sent to a licensed H:H landfill for
disposal.
All hazardous material (waste and contaminated soil)
that is to be removed as identified in the amended
rehabilitation plan, must be sent to a licensed H:H
landfill for disposal and treated if so required by that
facilities license.
Annexure III (a) Monitor at bi-annual intervals….
(b) Monitor at quarterly intervals…
(a) Monitor at bi-annual intervals during remediation and annually thereafter ….
(b) Monitor at quarterly intervals during remediation and annually thereafter…
Annexure VI
Reference to site layout plans
A720-00-001, A720-00-002
A720-00-003, A720-00-004
A720-00-005, A720-00-006
Reference to site layout plans
klip24-06-2013,
0710-07355-100001-001. 0710-07355-100001-002.
0710-07355-100001-003. 0710-07355-100001-004.
The remediation efforts on site are currently on hold until the amendment application has been resolved. It is
recommended that ArcelorMittal arrange a meeting with the Department in order to resolve and finalise the
amendment application.
4. PART 1: AUDIT INFORMATION
4.1. Date of Audit
External Audit date: - 13th of May 2015
Report date - 4th of June 2015
4.2. Audit Criteria / Scope of Work
The scope of work entailed conducting a compliance audit to verify compliance to the WML conditions.
The following documents and or information were considered against which compliance to the conditions of
the WML was audited:
WML
Approved Remediation Plan
Approved Environmental Management Plan (EMP)
Amendment application and the updated EMP and Remediation plan
Various database monitoring results made available / presented during the audit
Monitoring reports / data
Procedures and the electronic Environmental Management System (EMS)
Relevant communications between ArcelorMittal, Authorities and I & APs
Applicable South African Environmental Legislation.
4.3. Audit Methodology
The compliance status has been assessed for every condition of the WML and ranked as follows;
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Compliance
Full compliance achieved with documented or audited proof of compliance available. No further actions are
required.
Non-compliance
Non-compliance is the most severe type of finding. A non-compliance will indicate legal non-compliance to the
relevant legislation, license and/or records of decisions conditions. Where appropriate the audit report could
contain recommendations regarding non-compliance and specified/agreed target dates for the
implementation.
Potential or partial non-compliance
A potential or partial non-compliance refers to a deviation from a legal requirement, a standard specification,
or a planned arrangement which does not constitute a non-compliance, but which does not represent Best
Practice. It can also refer to conditions which is partially complied with which the compliance with a condition
is out of the license holders control, for instance where a response is required by an authority etc.
Recommendations could be stated for potential non-compliances. It can also refer to conflicting of nonsensical
conditions in a license that cannot be complied with, but still needs to be resolved.
Observation
An observation refers to a deviation from best practice and includes observations of opportunities for
improvement. Recommendations could be stated for observations but will not have specified target dates.
This has been included for the benefit of management and while not being of immediate priority, can be
included in the self-improvement cycle of environmental management.
It was considered necessary to rank the identified non-compliance in terms of the following criteria:
Critical Issues
There is a critical failure against legal requirements or management response that presents an
immediate or significant risk that could result in prosecution and /or adverse legal finding due to failure
to meet regulatory requirements;
Could result in immediate injury or serious injury or environmental harm;
Could result in prolonged business outage; and/or
Could result in serious damage to the project’s reputation. Critical issues must be addressed immediately and all activities resulting in negative critical findings
must cease until such time as the issue has been rectified.
Moderate Issues
There is a substantial failure to meet the environmental requirements for the project or license
condition,
There is a possibility of substantial environmental degradation and/or pollution and/or
Objective evidence was observed raising doubt as to the integrity of data or records inspected.
Minor Issues
Isolated observations demonstrating that full compliance to the environmental requirements on site
have not been, or will not be, fully achieved.
No physical environmental harm
4.4. Objectives
To carry out an independent compliance audit including:
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Inspection of operations and confirm compliance to the Authorisation
Verify the effectiveness of impact management and mitigation.
Assess allocations of responsibilities and actions.
Report observations for further investigation and action.
Specifically state whether conditions are adhered to.
Make recommendations where appropriate.
Prepare an audit report for submission to the relevant authorities.
4.5. Comments from previous audit reports
Recommendations from previous audits Status or comments
A notice board in three languages has been placed at the entrance to the site. The notice did not stipulate alternative disposal sites.
During the site visit, the notice board was inspected and indicated that the nearest municipal landfill site is the preferred alternative disposal site.
The EC, P-Alkalinity, F-, Phenol & TDS are not
included in the SANAS Schedule of Accreditation
for the Internal ArcelorMittal laboratory. It is
recommended that the use of alternative laboratory
be investigated or alternatively to include the
accreditation of the elements.
No change has occurred since the previous audit.
Tests for organics, including Phenol as scheduled to be done in April 2014, this is to be verified with the next external audit due in 2015.
At time of the audit, it was established that the organisation has started in 2014 to conduct quarterly analysis of organic elements at various boreholes.
ArcelorMittal indicated they had problems in contracting the registered vendor for the repair of the boreholes. The facility is in process to register another vendor to complete the work.
When on site, a contractor was also locating the boreholes to unblock the non-functional units, install lockable caps and put poles to clearly mark the respective boreholes. The contractor started with the repairs on the 27
th of May 2015.
During the site visit the boreholes had lockable caps on.
At the time of the audit not all of the boreholes had lockable installed, indicating that it had been stolen. As stated above, the contractor started to install caps on the 27
th of May 2015.
Organic elements are not monitored at the required frequency. The sampling and analysis must be re-assessed in terms of the license and the required elements be monitored as required until an agreement is reached with the authorities to amend the condition.
At time of the audit, it was established that the organisation started in 2014 to conduct quarterly analysis of organic elements at various boreholes as seen in Appendix B. However, it was established that groundwater quality was not monitored for TOCs for the third quarter of the 2014 reporting period. It is recommended that once the contractor has repaired the boreholes, monitoring of all required elements must continue at the required frequency.
No gas monitoring is undertaken as required. Even though an amendment application has been submitted to remove this requirement, the condition is still in force. Monitoring should therefore proceed as required until the request is formally approved by the department.
No change has occurred since the previous audit
The Tar was not treated with lime of ash before disposed to an H:H facility as required in the WML. ArcelorMittal stated that the contractor, EnviroServ stated they can accept the material as is according to their license. It is recommended that the relevant information be obtained from the contractor and
The information has not been obtained from Enviroserv yet. It should be stated that no hazardous waste was treated or deposed of to an H:H facility during this reporting period.
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Recommendations from previous audits Status or comments
filed as proof.
4.6. Declaration
I, Trevor Hallatt, as an independent consultant compiled this audit report and declare that it correctly reflects
the findings made at the time of the audit. I further declare that I,
Act as an independent consultant; Do not have any financial interest in the undertaking of the activity, other than remuneration for the work performed in terms of the National Environmental Management Act, 1998 (Act107 of 1998) and the National Environmental Management Waste Act; Undertake to disclose, to the competent authority, any material information that has or may have the potential to influence the decision of the competent authority or the objectivity of any report, plan or document required in terms of the National Environmental Management Act, 1998 (Act 107 of 1998); Based on information provided to me by the project proponent, and in addition to information obtained during the course of this study, will present the results and conclusion within the associated document to the best of my professional judgement.
_____________________________
Trevor Hallatt
Environmental Specialist
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5. PART 2: AUDIT FINDINGS
5.1. Positive observations/findings
Overall the site is well managed and it is clear ArcelorMittal environmental management want to solve
problems and mitigate the environmental impacts. It is clear ArcelorMittal has proactively engaged with the
authorities to resolve issues relating to compliance to the authorisation.
Additional studies were instituted to better understand the site and the ground water conceptual model
developed for the first time.
5.2. Compliance to the License conditions
ArcelorMittal is generally compliant to the conditions of the WML (License Nr 12/9/11/L130/3) dated March
2010. The non-compliances observed with the license conditions mainly relate to the borehole monitoring
requirements and to a lesser extent to some operational controls. The remediation efforts have been placed
on hold until the proposed changes in the remediation plan is approved by the department.
Table 1 addresses compliance to each relevant condition in the license.
5.3. Authorisation conditions
Table 1: Audit results
Condition Nr
Condition in WML Observation / Comments Compliance status Intensity of non-compliance
1.1 Site Details
1.1.1
The License authorises the decommissioning and remediation of the Klip Waste Disposal Site on Portion 68 of the farm Klipplaatdrift 601 IQ in Vereeniging, Gauteng (hereinafter referred to as “the Site”) according to the Environmental Impact Report: Remediation of Klip Waste Site, Vereeniging (Report Number: JW176/06/A707) and the Environmental Management Plan (Report Nr JW168/07/B461) by Jones and Wagner Consulting Engineers, dated October 2006 and November 2007 respectively, and (herein after referred to as “the Reports”) and, the Record of Decision, issued by the Gauteng Department of Agriculture and Rural Development dated 8 August 2007, submitted by the proposed License Holder.
The remediation process has been put on hold and the remediation plan was updated. An amendment application was submitted in August 2013 to amend the condition accordingly.
The remediation plans was followed to date.
The amendment application must first be approved by DEA before the implementation of the new plan may commence.
Compliant Observation
1.1.2
The location of the site shall be according to the co-ordinates indicated on the permit application Form and reports submitted by the License Holder which is defined as follows;
The coordinates specified in the Waste License is correct.
ArcelorMittal however requested that the coordinate system be changed to the geographical coordinate system in line with the system used in the final design drawings for ease of reference.
Compliant
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Condition Nr
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1.3. Site management
1.3.1.
The closure and rehabilitation activities must be managed and operated:
(i) In accordance with a site closure and rehabilitation plan that inter alia identifies and minimises risk of pollution, indicating those arising from construction, maintenance, accidents, incidents and non-conformances and those drawn to the attention of the licence holder as a result of compliance.
(ii) By sufficient persons who are compliant in respect to the responsibilities to be undertaken by them in connection with the operation of activities
Activities completed to date were managed in accordance with this condition. ArcelorMittal appointed a third party contractor to excavate and remove the tar. The contractor was supplied with a copy of the EMP and the license.
The remediation process has been put on hold and the remediation plan was updated.
Compliant
1.3.2.
Any persons having duties that are or may be affected by the matters set out in this licence must have access to a copy which must be kept at or near the place where the duties are carried out. A copy of this licence may be published on any website deemed fit by the Department
The license is held at the Environmental Management Department. A copy was supplied to the head of security responsible for safety and access control on site.
Compliant
2. Emergency preparedness plan
2.1.
The licence holder must maintain and implement an n emergency preparedness plan and review it after every two years and after every emergency and/or major accident. The plan must among others include:
(a) Fire
(b) Natural disasters such as floods,
(c) Uncontrolled gas emissions
The procedure is an integrated plan and addresses the items required as well as additional potential emergency conditions.
The revision available at the time of the audit was dated 28/02/2014 and should only be reviewed in 2016.
Compliant
ArcelorMittal Vanderbijlpark
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3. Commissioning and construction of remediation measures
3.1
The licence and the EMP (Report No. JW 168/07/B461, compiled by Jones and Wagener dated November 2007) is binding and must be updated at all times to ensure that it is relevant. Substantial changes must be approved by the Director.
The removal of the tar was in line with the remediation plan prepared by Jones and Wagner plan.
The implementation of the remediation plan was placed on hold. ArcelorMittal updated and changed the remediation plan and EMP and therefore submitted and amendment application to amend this condition.
Implementation of the new updated plans may only commence once the approval has been obtained.
Compliant
3.2
The site or any portion thereof must be maintained in such a way that:
The formation of pools due to rain is prevented Free surface runoff of rain water is ensured Contamination of storm water is prevented No objects or material which may hamper the rehabilitation of the site are present No erosion must occur after rehabilitation Re-vegetating of the area with indigenous plants is achieved
The requirements have been included in the final remediation plans that were submitted to DEA for amendment. The auditor is of the opinion that this condition talks to the desired end state after remediation has been completed. The condition is therefore not currently applicable.
Not yet Applicable
3.3.
Closure and rehabilitation construction must be carried out with supervision of a registered Professional Engineer appointed by the Licence Holder and according to the approved engineered drawings numbered A720-00-001; A720-00-002; A720-00-003; A720-00-004; A720-00-005; A720-00-006, prepared by Jones and Wagener Consulting Engineers dated April 2006.
The implementation of the remediation plan was placed on hold. ArcelorMittal updated and changed the final designs and therefore submitted and amendment application to amend this condition.
Implementation of the new updated plans may only commence once the approval has been obtained.
Not yet applicable
3.4.
Port closure maintenance within the site must be carried out in accordance with recognised civil engineering practice with special consideration to stability under the leadership of a registered Professional Engineer.
The condition is not yet applicable. Not yet applicable
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3.5.
Should any archaeological artifacts be exposed during excavation, the construction in the vicinity of the finding must be stopped. Under no circumstances shall any artifacts be Destroyed. Such an archaeological site must be marked and fenced off and the South African Heritage Resource Agency must be contacted within 48 hours.
The condition is noted. No items were found during the excavation phase. The contractor was made aware of this requirement.
Compliant
3.6.
Drainage systems must be constructed and maintained by the License Holder to ensure that runoff water does not enter the water body during decommissioning.
The condition is not applicable yet. Not yet applicable
3.7. The licence holder must construct seepage collection trenches between the site toe and the Klip River to address movement of pollution plumes to the river.
The implementation of the remediation plan was placed on hold. ArcelorMittal updated and changed the remediation plan and therefore submitted and amendment application to delete this condition.
Not yet applicable
3.8. The Licence Holder shall make provision for sanitation facilities on site in line with the Occupational Health and Safety Act, 1993 (Act S5 of 1993).
No activities currently on site and therefore no sanitation facilities on site.
Not yet applicable
4. Access Control
4.1.
Weatherproof, durable and legible notices in at least three official languages applicable in the area must be displayed at each entrance to the site. These notices must prohibit unauthorized entry, disposal of waste on the site and state the alterative place for disposal. Signs must have the name, address and telephone number of the License Holder and the person responsible for the site.
Site notice boards were noted at the access gate during the site inspection. The board indicated that the nearest municipal waste disposal site is the alternative site for disposal.
Compliant
4.2. The site must be fenced to a minimum height of 1,8 metres with gates of the same height at all entrances, to reasonably prevent unauthorised entry.
The fence was verified on site. However, the fence on the North-Eastern side of the site has been compromised and should be repaired before it is completely degraded.
Partial compliance Minor
5. Health and safety
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5.1. The License Holder must ensure adequate fire breaks and implement fire control measures.
Fire breaks were observed on site. Roads have been established on the site and are used as firebreaks.
Compliant
5.2.
The License Holder must take all reasonable steps to ensure the health and safety of workers and employees on site, in terms of the Occupational Health and Safety Act, 1993 (Act No. 85 of 1993).
A detailed HIRA was completed before the excavation work completed on site.
Compliant
5.3.
In order to curb negative environmental impact, the License Holder must make sure that serviceable ablution facilities are available for personnel who will be responsible for monitoring, maintenance and rehabilitation of the site.
No activities are currently undertaken on site and therefore there are no need for ablution facilities.
Compliant
6. Monitoring
6.1. Monitoring methods and parameters
6.1.1.
The License Holder must carry out all tests required in terms of this license in accordance with methods prescribed by and obtainable from the South African Bureau of Standards (SABS), referred, to in the Standards Act, 1982 (Act 30 of 1982).
The internal laboratory at Vanderbijlpark Works operations is accredited and the external Laboratory, M&L Inspectorate as well.
The internal laboratory is however not accredited for all the required elements.
Partial-compliance Moderate
6.2. Water monitoring
6.2.1.
The Licence Holder must undertake monitoring in accordance with the specified borehole network for the site. The specified monitoring boreholes for the site are geographically located as follows:
At the time of the audit, it was established that some of the monitoring borehole, including KBH 5, was damaged/blocked and the organisation has commissioned a contractor to repair the damaged boreholes. During the audit, a contractor was locating the boreholes to unblock the non-functional units, install lockable caps and put poles to clearly mark the respective boreholes. The contractor started with work on the 27
th of May 2015. However monitoring at all the established
boreholes did not place during the reporting period of 2014. The WMCO indicated that monitoring from the repaired borehole will commence in the 2015 reporting period.
Partial-compliance Minor
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6.2.2.
License Holder must establish three additional sets of shallow, and deep aquifer monitoring boreholes on the south- eastern and southern side of the site and downstream of the tar deposit within 6 month of the date of this license accordingly and to the satisfaction of the Director and the Chief Director RPW so that unobstructed sampling, m required in terms of this license, can be undertaken.
The required boreholes were drilled by Afric Manzi and a report to this effect was made available to the auditor. At the time of the audit it was established that KBH 7D and KBH 8D were blocked. No monitoring took place at KBH 7D for the first, third and fourth quarters of the 2014 reporting period. Additionally, monitoring was not conducted at KBH 8D for the last quarter of the 2014 reporting period. However, the organisation has commissioned a contractor to repair the damaged boreholes and started with work on the 27
th of May
2015. The organisation is partially compliant to the condition because monitoring did not take place at the blocked boreholes at the required frequencies during the 2014 reporting period. The WMCO indicated that they will commence with monitoring in the first quarter of the 2015 reporting period.
Partial-compliance Minor
6.2.3.
Monitoring boreholes must be equipped with lockable caps. The Department of Water Affairs (DWA) reserves the right to take water samples at any time and to analyze these samples, or to have them taken and analyzed
Not all of the boreholes observed during the site visit had lockable caps on. However, the organisation has commissioned a contractor to repair the damaged boreholes and started with the repairs on the 27
th of May 2015.
Partial-compliance Minor
6.2.4.
Groundwater monitoring by the License Holder, in accordance with conditions 6.2.1, must, continue and be maintained for a period of 30 years after closure, or for such a period and/or frequency as approved by the Chief
Noted Partial-compliance
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Director: RPW.
6.2.5. The license holder must establish two upstream boreholes monitoring the shallow and deep aquifers.
The required boreholes were drilled by Afric Manzi and a report to this effect was made available to the auditor.
Compliant
6.2.6. The license holder must ensure that the boreholes referred to in condition 6.2.5 above are hydraulically linked with corresponding downstream boreholes.
The ground water specialist confirmed that the aquifer is linked and the upstream boreholes is indicative to background levels
Compliant
6.3. Background Monitoring
6.3.1.
Samples from the boreholes indicated above, where the groundwater in the borehole is at an expected higher hydraulic pressure level as the hydraulic pressure level of fire groundwater under the site, shall be considered as background monitoring. Background groundwater monitoring must be conducted during each monitoring occasion in terms of condition 6.4 or 6.5 for the water quality variables listed in Annexure II or Annexure III.
At the time of the audit, it was established that monitoring has not been conducted at all of the required boreholes. It is recommended that once the contractor has repaired the boreholes, monitoring of all required elements must continue at all of the boreholes at the required frequency.
Partial-compliance Minor
6.4. Detection Monitoring
6.4.1.
Monitoring must be conducted bi-annually for all water quality variables listed in paragraph (a) of Annexure III and quarterly for the variables listed in paragraph (b) of Annexure III at locations specified in condition 6.2.1 or such frequency as is may be determined by the Chief Director: RPW.
At time of the audit, it was established that the organisation started in 2014 to conduct quarterly analysis of organic elements at various boreholes as seen in Appendix B. However, it was established that groundwater quality has not been monitored for TOCs for the third quarter (November 2014) of the 2014 auditing period. It is recommended that once the contractor has repaired the boreholes, monitoring of all required elements must continue at the required frequency.
Partially compliant Minor
6.5. Investigating Monitoring
6.5.1
lf, in the opinion of Chief Director: RPW, a water quality variable listed under the detection monitoring program, as referred to in condition 6.4.1, shows an increasing trend, the License Holder must initiate monthly monitoring for all
Noted. No such request has been received to date. Compliant
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water quality variables listed in annexure II. l
6.6. Gas Monitoring
6.6.1.
The Licence Holder must maintain gas monitoring test pits VOG01: South western boundary of the site (downwind) and VOC -02 north-eastern boundaries of the site (upwind) and the concentration, by volume in air at Standard Temperature and Pressure, of flammable gas and carbon dioxide shall not exceed 1 % and 0.5 % respectively in the test pits.
The implementation of the remediation plan was placed on hold. ArcelorMittal updated and changed the remediation plan and therefore submitted and amendment application to delete this condition.
The condition is however still in force whilst the amendment application is pending. ArcelorMittal conducted monitoring previously and concluded that the potential impact from gas emissions is negligible. Monitoring was therefore ceased.
Non-Compliance Minor
6.6.2.
Gas monitoring must be conducted monthly from the date of this license for a period of two years and thereafter send the results to the Director for determination of monitoring frequency if further required.
The implementation of the remediation plan was placed on hold. ArcelorMittal updated and changed the remediation plan and therefore submitted and amendment application to delete this condition.
The condition is however still in force whilst the amendment application is pending. ArcelorMittal conducted monitoring previously and concluded that the potential impact from gas emissions is negligible. Monitoring was therefore ceased.
Non-Compliance Minor
6.7. Further Investigation
6.7.1. Water pollution
6.7.1.1.
lf, in the opinion of the Chief Director: RPW, groundwater and surface water pollution have occurred or may possibly occur during remediation the Licence Holder must conduct and/or appoint specialists to conduct the necessary investigations and implement additional
Monitoring and rehabilitation measures to the satisfaction of the Chief Director: RPW.
Noted. No such request has been received to date. Compliant
6.7.2. Environmental pollution
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6.7.2.1.
lf, in the opinion of the Director, environmental pollution, nuisances or health risks may be or is occurring, the License Holder must initiate an investigation into the cause of the of the problem or suspected problem. Such investigation must include the monitoring of the relevant environmental pollution, nuisance and health risk variables, at those monitoring points and such frequency to be determined in consultation with the Director.
Noted. No such request was received to date. Compliant
7. Auditing
7.1. Internal audits
7.1.1.
Internal audits must be conducted quarterly by the License Holder and on each audit occasion an official report must be compiled by the relevant auditor to report the findings of the audits and the report must be forwarded to the Director.
Quarterly audits are being conducted. The last quarterly audit was done in December 2015.
Compliant
7.2. External audits
7.2.1.
The Licence Holder must appoint an independent external auditor to audit the site annually and this auditor must compile an audit report documenting fire findings of his audit, which must be submitted by the Licence Holder according to condition 9.3 below.
The audit report must:
a.) specifically state compliance with regard to each licence condition;
b.) include an interpretation of all available data and test result regarding the operation of the site and all its impacts on the environment!
c.) specify target dates for the implementation of the recommendations by the Licence Holder
to achieve compliance;
d.) contain recommendations regarding noncompliance or
The previous external audit was completed in May 2014 and submitted to the Department. The report contained the required elements and was structured according to the requirements.
Compliant
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potential noncompliance and
must specify target dates for the implementation of the recommendations by the Licence Holder and whether corrective action taken for the previous audit non conformities was adequate;
e.) show monitoring results graphically and conduct trend analysis.
7.3. Audits and inspections
7.3.1.
The Department and the Department of Water Affairs (DWA) reserve the right to audit and/or inspect the site at any time and at such a frequency determined by the Director and Chief Director: RPW, or to have the site audited or inspected.
The Department (DEA) audited the Klip Site in 2012. Access was allowed for the department to conduct the audit. No response or enforcement action received to date
Compliant
7.3.2.
The License Holder must make any records or documentation available to the Director and Chief Director: RPW upon request, as well as any other information the Director and Chief Director RPW may require.
The Department (DEA) audited the Klip Site in 2012. Access was allowed for the department to conduct the audit and the relevant information was provided as requested during the inspection. No response or enforcement action has been received to date
Compliant
7.3.3.
The findings of these audits or inspections shall be made available to the License Holder within 60 days of the end of the audit or inspection. Information from the audits must be treated in accordance with the Promotion of Access to information Act 2010 (Act 2 of 2000).
The Department did not comply with this condition. No response or enforcement action received to date
Not applicable
8. Recording
8.1. The License Folder must keep a record of and update all the information referred to in Annexure V on an annual basis.
The records are attached to this audit report (see appendix B).
Compliant
8.2. The Licence Holder must record all borehole data and chemical analyses in the format depicted in Annexure IV
The ground water data is attached to this audit report (See annexure B and C).
Compliant
ArcelorMittal Vanderbijlpark
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8.3. Records demonstrating compliance with condition 2.1 and any other record required by this. License must be maintained and be made available on request.
An amendment application was submitted to amend the condition. ArcelorMittal is of the opinion that it requires an administrative correction – reference to the relevant section in the license that relates to “records”.
Compliant
9. Reporting
9.1.
The License Holder must, within 24 hours, notify the Director and Chief Director: RPW of the occurrence or detection of any incident on the site, or incidental to the remediation operation of the site, which has the potential to cause, or has caused further environmental pollution, water pollution, health risks or nuisance conditions.
No major incidents were recorded on site Compliant
9.2.
The License Holder must, within 14 days, or a shorter period of time, if specified by the Director and Chief Director: RPW, from the occurrence or detection of any incident refined to in mediation 9.1, submit an action plan, which must include a detailed this schedule, to the
satisfaction of the Director and Chief Director: RPW of measures taken to -
a.) connect the impact resulting from fire incident
b.) prevent the incident from causing any further impact; and
c.) Prevent a recurrence of a similar incident.;
No major incidents were recorded on site Compliant
9.3.
In the event that measures have not been implemented within 21 days of the incident to address impact caused by the incident refined to in condition g,1, or measures which have been implemented are inadequate, the Director and Chief Director: RPW may implement the Necessary measures at the cost and risk of the License Holder.
No major incidents were recorded on site Compliant
9.4. The License Holder must keep an incident report and complaints register, which must be made available to external, Departmental and DWA auditors for the purpose
No external complaints has been received to date Compliant
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of their audits.
9.5.
Records generated in terms of condition 6 above and any other records generated as a result of this Licence must be interpreted and included in the audit reports referred to in condition 7 above.
The ground water monitoring data is included in this report. Refer to attachment C and D.
Compliant
9.6.
Gas monitoring and water monitoring results as per conditions 6.6 and 6.2 respectively, must be recorded and trend analysis conducted and reported to the Director and the. Chief Director:' RPW if there is an indication of an upward trend.
Gas monitoring results are not recorded and therefore trend analysis is not taking place.
Water monitoring results are recorded and trend analysis is taking place (see section 6 of this report). Overall the groundwater is either stable or improving and reporting is therefore not required.
Partial-compliance Minor
10. Leasing and alienation of the site
10.1.
Should the Licence Holder want to alienate or lease the site, he/she must notify the Director in writing of such an intention at least 120 days prior to the said transaction. Should the approval be granted, the subsequent Licence Holder shall remain liable to comply with all licence conditions specified herein.
The license has not been transferred and the major areas where the waste site is located are controlled by AMSA on a daily basis.
Compliant
11. Transfer of waste management licence
11.1.
Should the License Holder want to transfer holder-ship of this license, he/she must apply in terms of Section 52 of the National Environmental Management Waste Act, 2008 (Act No 59 of 2008).
There is no short or medium term plans to transfer the license.
Compliant
11.2. Any subsequent Licence Holder shall be bound by all the conditions specified in this Licence.
Not Applicable Not Applicable
12. Rehabilitation and closure of the site
12.1. The site or any portion thereof, including the surface of the site must be covered and the site must be maintained in such a way that no objects or materials including facility’s
The implementation of the remediation plan was placed on hold. ArcelorMittal updated and changed the remediation plan and therefore submitted an amendment application to
Compliant
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and old machinery which may hamper the rehabilitation of the site are present,
amend this condition.
The illegal scrap metal “miners” was successfully removed from site since the middle of 2012. The digging activities on site disturbed the sites surface. The site was graded flat in anticipation for future remediation work.
12.2. Rehabilitation and closure of the site must entail:
12.2.1. Management of vegetation in terms of species of vegetation planted adjacent to the fill areas and along property boundaries and implementation
This forms part of the remediation plan and is not yet applicable.
Not yet applicable
12.2.2. Protection of the cover from ponding water, drainage challenges, erosion and also providing adequate security to prohibit damage of the cover from settlements.
This forms part of the remediation plan and is not yet applicable.
Not yet applicable
12.2.3.
Operation and maintenance of the landfill gas control system whereby gas monitoring by the License Holder as prescribed in condition 6.6 must continue after closure for a period of two years, or such longer period as may h determined by the Director. Should the atmospheric
Levels be between 0.1% and 1%, during remediation operations, a higher frequency of monitoring must be instituted. Should levels above 1% be detected, the License Holder must submit a contingency plan regarding occupational safety to the Director, which must be implemented on the Site, after written approval by the Director.
The implementation of the remediation plan was placed on hold. ArcelorMittal updated and changed the remediation plan and therefore submitted an amendment application to delete this condition.
Not yet applicable
12.2.4. Assurance by the license holder that the slope is not steeper than 1:4 (VIII).
This forms part of the remediation plan and is not yet applicable.
Not yet applicable
12.3.
The License Holder must rehabilitate the site in accordance with the latest edition of the documents titled: "Minimum Requirements" and closure & rehabilitation plan approved by the Director.
This forms part of the remediation plan and is not yet applicable.
Not yet applicable
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12.4 The temporarily lined facility to be used for the dewatering of phenolic waste must be in use for the period of the remediation of the site which must not exceed three years.
The implementation of the remediation plan was placed on hold. ArcelorMittal updated and changed the remediation plan and therefore submitted an amendment application to delete this condition.
Not yet applicable
12.5.
The license holder must not use condition 12.4 above as a means to authorize the said facility for other purposes in future. There shall be no authorization for extension of timeframes and change of use for the said facility without the license holder having to start the process of licensing from the beginning.
The implementation of the remediation plan was placed on hold. ArcelorMittal updated and changed the remediation plan and therefore submitted an amendment application to delete this condition.
Not yet applicable
12.6. The licence holder must classify waste from the site and dispose them at appropriate facilities,
The tar contaminated material was classified as hazardous waste and disposed therefore at an off-site H:H waste disposal site.
Compliant
12.7. The Licence Holder must submit an end-use plan to the Director within six month (6) months of being issued with this Licence.
An end use plan was submitted in September 2010.
An updated end use plan was submitted to DEA on the 31st
July 2013 that proposes to change the end use plan.
Compliant
12.8. Water from the waste body must be considered waste and the license holder must implement the waste hierarchy in dealing with the all waste streams.
No waste water is generated from the site. Not applicable
13. General
13.1 The commencement of the licensed activity may not begin within thirty (30) days of the date of signature of this licence.
Remediation only commenced in 2012. Compliant
13.2
Should you be notified by the Minister of a suspension of the license pending any appeals decision, you may not commence with the activities licensed unless you arc devised by the Minister in writing.
No appeal or suspension notices have been received. Compliant
13.3. After the appeal period has expired and no good cause to extend the appeal period has been submitted, the activity
A notice was submitted to the department prior to the commencement.
Compliant
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may commence provided a notice has been submitted to the Department. The notice must include a date on which it is anticipated that the activity will commence.
13.4.
The activity must commence within a period of two (2) years from the date of issue. If commencement of the activity does not occur within the said period, the license will lapse and a new application for a licensed must be made in order for the activity to be undertaken.
The remediation commenced in 2012 before the license lapsed.
Compliant
13.5.
lf the License Holder anticipates that the activity would extend beyond the two (21 year period, he / she must apply and show good cause for an extension of the license six (6) months prior to its expiry date.
Noted Compliant
13.6. The license shall not be transferable unless such transfer is suggest to condition 11.1
Noted Compliant
13.7.
This license shall not be construed as exempting the License Holder from compliance with the provisions of the National and Provincial Legislation and any relevant Ordinance, Regulation, By-laws and relevant National Standards and Norms.
Noted. ArcelorMittal receives regular updates on legislation changes and incorporates this into the EMS.
Compliant
13.8. Transgression of any condition. Of this license could result in the validity of the license being terminated by the Department.
Noted Not Applicable
13.9.
Non-compliance with any condition of this license may result in criminal prosecution or other actions provided for in terms of Section 67(1) of the National environmental Management - Waste Act, 2008.
Noted Not Applicable
13.10
Any committees appointed in terms of the application or any other public authority or organization shall not be held responsible for any damages or losses suffered by the License Holder or his/her successor in title in any instance where operations are to be temporary or permanently
No committee appointed Not Applicable
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stopped for reasons of non-compliance.
13.11
In terms of Section 28 and 30 of the National Environmental Management Act No. 107 of 1998, and Section 19 and 20 of the National Water Act No. 36 of 199b, any costs incurred to remedy environmental damage must be borne by the person responsible for the damage. It is therefore imperative that the License Holder reads through and understand the legislative requirements pertaining to the project. It is the License Holder's responsibility to take reasonable measures which include informing and educating contraction and employees about environmental risks of their work and training them to operate in an environmental acceptable manner.
The license holder held a site meeting with the appointed contractor responsible to remove the tar material from site. The contractor was provided with the license and the EMP. Training was provided to the employees. Reasonable measures were therefore taken to inform and educate the responsible people of the requirements.
Compliant
13.12 All hazardous material (water and contaminated soil) must be treated with lime and be ash blended prior to being sent to a licensed H:H landfill for disposal.
The implementation of the remediation plan was placed on hold. ArcelorMittal updated and changed the remediation plan and therefore submitted an amendment application to amend this condition. The proof that the tar was acceptable to the H:H Landfill as is without treatment must be filed.
Compliant Observation
13.13 The Licence Holder shall be responsible for the site or its impacts on the environment post closure of the site.
Noted Not Applicable
14. Appeal of Licence
14.1. The licence holder must notify every registered interested and affected party, in writing and within five (5) days, of receiving the Departments’ decision.
The IAPs was notified on the license on the 24th March 2010.
The license is dated the 10th
March 2013 but ArcelorMittal only received the license later. The timeframe is therefore met.
Compliant
14.2. The notification referred to in 14.1 must:
14.2.1. Specify the date on which the license was issued;
14.2.2. Inform the registered interested and affected party of the appeal procedure provided for in Chapter 7 of the GN No. R385 of 21 April 2006 in terms of National Environmental
The notice contained the relevant information as required in the license
Compliant
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Condition Nr
Condition in WML Observation / Comments Compliance status Intensity of non-compliance
Management Act, 1998, as amended (see Annexure l).
14.2.3. Advise the interested and affected party that a copy of a license and reasons for the decision will be famished on request,
The notice contained the relevant information as required in the license
Compliant
6. GROUND WATER MONITORING DATA
An independent ground water specialist was appointed in 2012 to develop a ground water conceptual
model and also interpret the monitoring data to assess the Sulphate Migration Mechanism in the
groundwater system, and the potential impact thereof on the Klip River, based on existing groundwater-
related studies/data.
The conclusions and recommendations from the study are as follows;
Groundwater flow is predominantly to the east toward the Klip River at a very slow rate.
The sulphate impact on the Klip River is not detected due to the river flow volumes.
The aquifer will naturally attenuate slowly to achieve drinking water standards after approximately
250 years, provided that aquifers to the west of the site are not contaminated.
No groundwater remediation action is recommended.
Regular groundwater monitoring should continue at the Klip Waste Disposal Site.
The figure blow indicates the location of the required monitoring boreholes at the Klip Waste Disposal Site.
KHB-1 represents the “upstream” ground water quality and therefore the upstream borehole of the site.
Figure 1 Location of boreholes
6.1 Inorganic elements
The Infotox “Contaminated Site Investigations for the ArcelorMittal Klip Waste Disposal Site in Vereeniging” (Document No 003-2012 Rev 2.0) concluded that sulphates are the only real element of concern in the
ground water aquifer in terms of inorganic contamination.
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Table 2: Summary of inorganic elements of concern (Infotox, 2012)
As seen in Table 2, sulphate levels exceeded the “limits” at all the downstream boreholes during the infotox
investigation. Ca, Mg, Na, Mn exceeded guideline values at certain boreholes but in varying degrees.
Sulphate is therefore used as the element to track improvement or deterioration in this assessment.
Figure 2 Up and downstream Electric Conductivity
As seen in Figure 2, Electrical Conductivity downstream of the site has increased since September 2013
which correlates with the increase of Sulphate levels measured at borehole KBH 4D. This is what can be
expected and is in line with the conclusion of the ground water specialist report that the sulphates will flush
out over time.
-300.0
200.0
700.0
1200.0
1700.0
2200.0
2700.0
3200.0
3700.0
4200.0
Ele
ctri
cal
con
du
ctiv
ity
Up and Down stream boreholes at Klip Waste Site
(electrical conductivity uS/cm)
KBH5 (upstream) KBH4D (downstream)
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Figure 4 Sulphate Trend up and down stream of the location of the old phenolic dam
KBH 5 is upstream of the location where the phenolic dam was located and KBH-10 is located downstream
of the area. The effluent from the vanadium plant reportedly contained high levels of sulphates. From the
sulphate levels, however, it is clear that the phenolic dam had an impact on the Sulphate levels. The
sulphate levels upstream of the location of the phenolic dam area is on average approximately 560 mg/l
and downstream approximately 5 000 mg/l. It can also be seen in KBH 10 that the trend of the sulphate
level is downwards and therefore improving slowly over time. This confirms the ground water specialist
study’s conclusion that even though the aquifer is contaminated with Sulphate, the fact that the site is no
longer in use and therefore no additional contamination is added to the system; the natural attenuation will
resolve the situation over many years to come naturally.
0.0
1000.0
2000.0
3000.0
4000.0
5000.0
6000.0
7000.0
8000.0
Su
lph
ate
(m
g/L
)
Up and Downstream of the location of the old Phenolic Dam
KBH 5 (up stream) and KBH 10 (downstream) Sulphate
KBH5 KBH10D Linear (KBH10D)
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Figure 5: Sulphate trend downstream of the Klip Waste Site
The monitoring results confirm the movement of the Sulphate contamination plume towards the Klip River.
KBH 3 and 4 is located closest to the River and best represents what reports to the Klip River currently.
The borehole shows an increased sulphate level trend over time. This is what can be expected and in line
with the conclusion of the ground water specialist that the Sulphates will flush out over time. The ground
water will seep into the Klip River system. The ground water specialist concluded that due to the slow
movement of the ground water and therefore the sulphate plume, the impact would be minimal on the
receiving river. The study concluded that the seepage of the sulphate in the Klip River would not impact on
the river quality as the volume of contamination entering the river compared to the volume of water in the
river and the flow would not be picked up.
0.0
500.0
1000.0
1500.0
2000.0
2500.08
-Au
g-0
7
20
-Au
g-0
8
1-J
un
-10
30
-Se
p-1
0
15
-No
v-1
0
13
-Ja
n-1
1
13
-Ja
n-1
1
7-M
ar-
11
25
-Ma
y-1
1
9-J
un
-11
28
-Se
p-1
1
4-O
ct-1
1
1-N
ov-1
1
16
-Ma
r-1
2
25
-Ju
n-1
2
25
-Ju
n-1
2
27
-Au
g-1
3
9-S
ep
-13
08
-No
v-1
3
06
-Fe
b-1
4
04
-Ap
r-1
4
08
-Au
g-1
4
13
-No
v-1
4
10
-Ma
r-1
5
Su
lph
ate
(m
g/l
) "Old" up and down stream boreholes at Klip Waste
Site Sulphate mg/l
KBH5 (up stream) KBH2 (downstream) KBH3D (downstream) KBH4D (downstream)
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Figure 6 Sulphate trend downstream at the new boreholes (KBH 7D and 8D)
Figure 6 Sulphate trend downstream at the new boreholes (KBH 6D and 9D)
KBH 7 KBH 8 is located to the south of the site and it is clear that they are not in direct route of the plume
and therefore not contaminated significantly. These two boreholes are blocked and no monitoring data is
available for KBH 7D for the 1st quarter of 2015 and KBH 8D for end of 2014 and beginning 2015. As seen
0.0
50.0
100.0
150.0
200.0
250.0
300.0
350.0
400.0
450.0
500.0
Su
lph
ate
(m
g/l
)
"New" Up and Down stream boreholes at Klip
Waste Site Sulphate mg/l
KBH7D (upstream) KBH8D (downstream)
0.0
500.0
1000.0
1500.0
2000.0
2500.0
3000.0
3500.0
4000.0
Su
lph
ate
(m
g/l
)
"New" Up and Down stream boreholes at Klip
Waste Site Sulphate mg/l
KBH6D (upstream) KBH9D (downstream)
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in Figure 6, KBH 9 is more contaminated than KBH6D indicating that the sulphates are still moving through
the system.
6.2 Organic ground water monitoring results
At time of the audit, it was established that the organisation has started in 2014 to conduct quarterly
analysis of organic elements in groundwater at various boreholes as seen in Appendix B. However, it was
established that the TOCs were not monitored in the third quarter of the 2014 reporting period and
monitoring did not take place at certain boreholes in the last quarter of the 2014 reporting period (See
Appendix B).
KBH 5 is upstream of the location where the phenolic dam was located and KBH-10 is located downstream
of the area. Additionally, the graph shows TOC results for KBH 6D (upstream) and 9D (downstream) of the
Southern section of the site. The total organic carbon was analysed for these boreholes and trended
below. The downstream boreholes show an increase in TOC.
Figure 7 Total Organic Carbon in groundwater
Table 3: Total organic carbon monitoring results (PPM)
Borehole 25-Apr-14 03-Sep-14 Dec-14 Mar-15
KBH 2 3.2
KBH 3S 25 32 73
KBH 3D 8.5 7.2 19
KBH 4S 22
KBH 4D 9 10 16
KBH 5D 25 19
KBH 6D (upstream) 8.4 9.1
KBH 7D 8.4 9.3
KBH 8D
9.9
0
10
20
30
40
50
60
25-Apr-14 03-Sep-14
TO
C (
PP
M)
Total Organic Carbon (TOC) up and downstream
of the Klip waste site
KBH 6D (up stream)
KBH 9D (downstream)
KBH 5D (upstream)
KBH 10D (downstream)
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Borehole 25-Apr-14 03-Sep-14 Dec-14 Mar-15
KBH 9D (downstream)
10 13 30
KBH 10D (downstream)
49 37 70
KBH 10S 4.4
No volatile organic compounds except for Bis(2-ethylhexyl)phthalate were detected during the reporting
period above the analytical method detection limits. Jones & Wagener (2001) detected trace
concentrations of toluene, ethylbenzene and xylene in 2001, but these compounds are no longer present. It
must be noted that these compounds are common water contaminants associated with petroleum pollution
and Jones & Wagener (2001) also found these in upstream boreholes.
Because of the low guideline concentrations of some of the compounds, the analytical laboratory listed not
only the limits of quantification (LOQ) of the various compounds, but also estimates of the lowest detected
concentrations. Laboratory water blank was also analysed to provide perspectives on the level of
significance of observed concentrations close to the analytical method detection limits.
7. GAS AND AIR QUALITY MONITORING DATA
ArcelorMittal commissioned some external studies historically. A detailed air quality assessment was
conducted by external specialists, Margot Saner & Associates. The specialist concluded based on the
monitoring results that the inhalation exposure to the measured ambient concentrations of the Volatile
organic Compounds (VOC’s) (whether acute or chronic) is very unlikely to cause any adverse health effects – even in particularly sensitive individuals).
The results obtained revealed that ambient concentrations of Benzene, Toluene, Ethylbenzene, Xylene,
Trimethylbenzenes, Phenol and Cresols at all three of the sampling locations were well below the relevant
South African Ambient Air Quality Standard (Benzene) and/or the equivalent UK Environmental
Assessment Levels (UK EALs). Based on the results of this baseline study, the health risks associated with
acute and/or chronic inhalation exposure to the measured ambient contaminant concentrations at the Klip
Site waste site are minimal.
Table 3 Ambient concentrations of priority contaminants as measured by Margot Saner and Associates
Some testing was completed by ArcelorMittal in house in 2011, which confirmed the findings. The data can
however not be presented graphically as the elements were all below the detection limits of the laboratory
analysis methods.
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8. CONCLUSION AND RECOMMENDATIONS
ArcelorMittal appointed Zantow Environmental to conduct an external environmental audit to verify
compliance with the WML for the decommissioning of the Klip Waste Site. This is the fourth external report
in terms of the license condition. The facility addressed some of the recommendations made in the
previous audit but some recommendations made still require intervention by ArcelorMittal. The non-
compliances observed with the license conditions relate to mainly to borehole monitoring requirements and
to a lesser extent to some operational controls.
The following findings were raised and recommendations made to improve compliance to the WML;
Monitoring is not undertaken place at all the required boreholes as some of the boreholes have
been damaged and are blocked. It was reported that a contractor started on the 27th of May 2015
to repair blocked boreholes, issue each a lockable cap and establish poles to clearly mark the
respective boreholes. Once the boreholes have been repaired, monitoring must commence at the
required frequencies at all of the boreholes (WMCO, June 2015).
At the time of the audit it was reported that monitoring of organic elements commenced in 2014,
however TOC was not monitored in the third quarter of the 2014 reporting period. The sampling
and analysis must be re-assessed in terms of the license and the required elements must be
monitored as required until an agreement is reached with the authorities to amend the condition
(WMCO, July 2015).
No gas monitoring is undertaken as required. An amendment application was submitted to remove
this requirement, however until the amendment has been approved the condition is still in force.
Monitoring should therefore proceed as required until the request is formally approved by the
Department (WMCO, July 2015).
The fence on the North-Eastern side of the site has been damaged. The fence should be repaired
before it is completely degraded (WMCO, July 2015).
Further to the legal compliance issues, observations were also raised where there is a possibility to
improve on the environmental practises. These are not legal requirements and ArcelorMittal should
investigate the feasibility of implementation in context with the current situation and available resources.
The following observations were made;
The amendment application submitted for the new remediation plan and EMP must be followed up
with the department to ensure the remediation process can proceed timeously. It is recommended
that a meeting be set up with DEA in order to present the updated remediation plan and EMP as
this is a substantial amendment (WMCO, July 2015).
---End---
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Appendix A
ANNUAL REPORT
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41 Report: 192-ZANAMVE-2015 Zantow Environmental Consulting Services
APPENDIX B
Ground water monitoring results - organics
APPENDIX B1
Ground water monitoring results - organics (April 2014)
M and L Laboratory Services (Pty) Ltd
Registration Number 1974/001476/07 VATNumber 4780103505
P.O. Box 82124
Southdale, 2135
40 Modulus Road
Page 1 of 4
:
:
:
ML2014-0938
8464238
2014-04-25
Ref. No.
Contract No.
Date
Ormonde, 2091
Tel: (011) 661 7900
Fax: (011) 496 2238
0861 467 765
Golden No.Consulting Industrial Chemists, Analysts Samplers
CONFIDENTIAL
Certificate / Report
COMPANY NAME : ARCELOR MITTAL SA
ADDRESS : PO BOX 2 VANDERBIJLPARK 1900
SUBJECT : ANALYSIS OF 9 WATER SAMPLES
PROJECT REFERENCE :
:INSTRUCTED BY J. Mnisi
:ORDER NUMBER N/A
:RECEIVED ON 2014-04-04
:ANALYSIS COMPLETED 2014-04-25
* BDL - Below Detection Limit
* Denotes test method accredited to ISO17025
These tests do not apply to any other samples of a similar nature.
Refer to terms and conditions www.inspml.co.zaoo This report relates to only test items listed herein and analysis on an as received basis.
This certificate cannot be reproduced except in full without the written consent of M and L Laboratory Services (Pty) Ltd.o
:Printed Date 2014-04-25
M and L Laboratory Services (Pty) Ltd
Registration Number 1974/001476/07 VATNumber 4780103505
P.O. Box 82124
Southdale, 2135
40 Modulus Road
Page 2 of 4
:
:
:
ML2014-0938
8464238
2014-04-25
Ref. No.
Contract No.
Date
Ormonde, 2091
Tel: (011) 661 7900
Fax: (011) 496 2238
0861 467 765
Golden No.Consulting Industrial Chemists, Analysts Samplers
CONFIDENTIAL
Certificate / Report
H03575
KBH-4D
H03574
QualityControlResultResult
KBH-6D
QualityControlResultResult
H03573
KBH-3D
Result
QualityControlResult
Lab Number
Sample Marks
Determinant
DetectionLimit
Quanti-fication
LimitQualityControl
Method Total Organic Carbon by Calculation as (C) Reference
Total Organic Carbon as C(mg/l)
9.0 8.48.5
Authorised Signature
Supervisor
Edward Khumalo
* BDL - Below Detection Limit
* Denotes test method accredited to ISO17025
These tests do not apply to any other samples of a similar nature.
Refer to terms and conditions www.inspml.co.zaoo This report relates to only test items listed herein and analysis on an as received basis.
This certificate cannot be reproduced except in full without the written consent of M and L Laboratory Services (Pty) Ltd.o
:Printed Date 2014-04-25
M and L Laboratory Services (Pty) Ltd
Registration Number 1974/001476/07 VATNumber 4780103505
P.O. Box 82124
Southdale, 2135
40 Modulus Road
Page 3 of 4
:
:
:
ML2014-0938
8464238
2014-04-25
Ref. No.
Contract No.
Date
Ormonde, 2091
Tel: (011) 661 7900
Fax: (011) 496 2238
0861 467 765
Golden No.Consulting Industrial Chemists, Analysts Samplers
CONFIDENTIAL
Certificate / Report
H03578
KBH-9D
H03577
QualityControlResultResult
KBH-10D
QualityControlResultResult
H03576
KBH-7D
Result
QualityControlResult
Lab Number
Sample Marks
Determinant
DetectionLimit
Quanti-fication
LimitQualityControl
Method Total Organic Carbon by Calculation as (C) Reference
Total Organic Carbon as C(mg/l)
10 498.4
Authorised Signature
Supervisor
Edward Khumalo
* BDL - Below Detection Limit
* Denotes test method accredited to ISO17025
These tests do not apply to any other samples of a similar nature.
Refer to terms and conditions www.inspml.co.zaoo This report relates to only test items listed herein and analysis on an as received basis.
This certificate cannot be reproduced except in full without the written consent of M and L Laboratory Services (Pty) Ltd.o
:Printed Date 2014-04-25
M and L Laboratory Services (Pty) Ltd
Registration Number 1974/001476/07 VATNumber 4780103505
P.O. Box 82124
Southdale, 2135
40 Modulus Road
Page 4 of 4
:
:
:
ML2014-0938
8464238
2014-04-25
Ref. No.
Contract No.
Date
Ormonde, 2091
Tel: (011) 661 7900
Fax: (011) 496 2238
0861 467 765
Golden No.Consulting Industrial Chemists, Analysts Samplers
CONFIDENTIAL
Certificate / Report
H03581
KBH-10S
H03580
QualityControlResultResult
KBH-5
QualityControlResultResult
H03579
KBH-3S
Result
QualityControlResult
Lab Number
Sample Marks
Determinant
DetectionLimit
Quanti-fication
LimitQualityControl
Method Total Organic Carbon by Calculation as (C) Reference
Total Organic Carbon as C(mg/l)
4.4 2525
Authorised Signature
Supervisor
Edward Khumalo
* BDL - Below Detection Limit
* Denotes test method accredited to ISO17025
These tests do not apply to any other samples of a similar nature.
Refer to terms and conditions www.inspml.co.zaoo This report relates to only test items listed herein and analysis on an as received basis.
This certificate cannot be reproduced except in full without the written consent of M and L Laboratory Services (Pty) Ltd.o
:Printed Date 2014-04-25
P.O. Box 82124,
Southdale, 2135,
South Africa.
TEL. (011) 496-2228
FAX (011) 496-2239
Registration Number 1974/001476/07 Vat Number 4780103505
M and L Laboratory Services (Pty) Ltd Consulting Industrial Chemists, Analysts & Samplers
CONFIDENTIAL
Ref No.
: 8464238
Issued
at
: Johannesburg
Date
: 24/04/2014
Page : 1 of 4
COMPANY NAME : ARCELLOR MITTAL SOUTH AFRICA
ADDRESS : P.O BOX 2, VANDERBILJLPARK 1900
SUBJECT : ANALYSIS OF 5 WATER SAMPLES
MARKED : AS BELOW
INSTRUCTED BY : J.MNISI
ORDER NO : TF
RECEIVED ON : 04/04/2014
LAB NO(S) : H03573-H03577
DATE ANALYSED : 18/04/2014
Analysis on as received basis:
Test: SVOC
Test Ref.: EPA 8270C & EPA 3510
LAB NUMBERS H03573 H03574 H03575 H03576 H03577
SAMPLE MARKS KBH-3D KBH-4D KBH-6D KBH-7D KBH-9D
Acenaphthene BDL BDL BDL BDL BDL Acenaphthylene BDL BDL BDL BDL BDL Anthracene BDL BDL BDL BDL BDL Azobenzene BDL BDL BDL BDL BDL Benzo(a)anthracene BDL BDL BDL BDL BDL Benzo(a)pyrene BDL BDL BDL BDL BDL Benzo(b)fluoranthene BDL BDL BDL BDL BDL Benzo(k)fluoranthene BDL BDL BDL BDL BDL Bis-(2-chloroethoxy)
methane
BDL BDL BDL BDL BDL
Bis-(2-chloroethyl) ether BDL BDL BDL BDL BDL Bis-(2-chloroisopropyl) ether BDL BDL BDL BDL BDL Bis-(2-ethylhexyl) phthalate BDL BDL BDL BDL BDL Butyl benzyl phthalate BDL BDL BDL BDL BDL Carbazole BDL BDL BDL BDL BDL Chrysene BDL BDL BDL BDL BDL Di-n-butyl phthalate BDL BDL BDL BDL BDL Di-n-octyl phthalate BDL BDL BDL BDL BDL Dibenzofuran BDL BDL BDL BDL BDL Diethyl phthalate BDL BDL BDL BDL BDL Dimethyl phthalate BDL BDL BDL BDL BDL Fluoranthene BDL BDL BDL BDL BDL Fluorene BDL BDL BDL BDL BDL
P.O. Box 82124,
Southdale, 2135,
South Africa.
TEL. (011) 496-2228
FAX (011) 496-2239
Registration Number 1974/001476/07 Vat Number 4780103505
M and L Laboratory Services (Pty) Ltd Consulting Industrial Chemists, Analysts & Samplers
CONFIDENTIAL
Ref No.
: 8464238
Issued
at
: Johannesburg
Date
: 24/04/2014
Page : 2 of 4
LAB NUMBERS H03573 H03574 H03575 H03576 H03577
SAMPLE MARKS KBH-3D KBH-4D KBH-6D KBH-7D KBH-9D
Hexachlorobenzene BDL BDL BDL BDL BDL Hexachlorobutadiene BDL BDL BDL BDL BDL Hexachlorocyclopentadiene BDL BDL BDL BDL BDL Hexachloroethane BDL BDL BDL BDL BDL Isophorone BDL BDL BDL BDL BDL N-nitrosodi-n-propylamine BDL BDL BDL BDL BDL Naphthalene BDL BDL BDL BDL BDL Nitrobenzene BDL BDL BDL BDL BDL Pentachlorophenol BDL BDL BDL BDL BDL Phenanthrene BDL BDL BDL BDL BDL Phenol BDL BDL BDL BDL BDL Pyrene BDL BDL BDL BDL BDL 1,2-Dichlorobenzene BDL BDL BDL BDL BDL 1,2,4-Trichlorobenzene BDL BDL BDL BDL BDL 1,3-Dichlorobenzene BDL BDL BDL BDL BDL 1,4-Dichlorobenzene BDL BDL BDL BDL BDL 2-Chloronaphthalene BDL BDL BDL BDL BDL 2-Chlorophenol BDL BDL BDL BDL BDL 2-Methylnaphthalene BDL BDL BDL BDL BDL 2-Methylphenol BDL BDL BDL BDL BDL 2-Nitroaniline BDL BDL BDL BDL BDL 2-Nitrophenol BDL BDL BDL BDL BDL 2,4-Dichlorophenol BDL BDL BDL BDL BDL 2,4-Dimethylphenol BDL BDL BDL BDL BDL 2,4-Dinitrotoluene BDL BDL BDL BDL BDL 2,4,5-Trichlorophenol BDL BDL BDL BDL BDL 2,4,6-Trichlorophenol BDL BDL BDL BDL BDL 2,6-Dinitrotoluene BDL BDL BDL BDL BDL 3-Nitroaniline BDL BDL BDL BDL BDL 4-Bromophenylphenyl
ether
BDL BDL BDL BDL BDL
4-Chloro-3-methylphenol BDL BDL BDL BDL BDL 4-Chloroaniline BDL BDL BDL BDL BDL 4-Chlorophenylphenyl
ether
BDL BDL BDL BDL BDL
4-Methylphenol BDL BDL BDL BDL BDL 4-Nitroaniline BDL BDL BDL BDL BDL
SVOC – GC/MS Following Solvent Extraction Technique.
All Results Reported in (µg/l).
BDL – Below Detection Limit (50µg/l).
P.O. Box 82124,
Southdale, 2135,
South Africa.
TEL. (011) 496-2228
FAX (011) 496-2239
Registration Number 1974/001476/07 Vat Number 4780103505
M and L Laboratory Services (Pty) Ltd Consulting Industrial Chemists, Analysts & Samplers
CONFIDENTIAL
Ref No.
: 8464238
Issued
at
: Johannesburg
Date
: 24/04/2014
Page : 3 of 4
COMPANY NAME : ARCELLOR MITTAL SA
ADDRESS : P.O BOX 2 VANDERBYLPARK SUBJECT
SUBJECT : ANALYSIS OF 5 WATER SAMPLES
MARKED : AS BELOW
INSTRUCTED BY : J. MNISI
ORDER NO : TF
RECEIVED ON : 04/04/2014
LAB NO(S) : H03578-H03581
DATE ANALYSED : 19/04/2014
Analysis on as received basis:
Test: SVOC
Test Ref.: EPA 8270C & EPA 3510
LAB NUMBERS H03578 H03579 H03580 H03581
SAMPLE MARKS KBH-10D KHB-3S KBH-10S KBH5
Acenaphthene BDL BDL BDL BDL Acenaphthylene BDL BDL BDL BDL Anthracene BDL BDL BDL BDL Azobenzene BDL BDL BDL BDL Benzo(a)anthracene BDL BDL BDL BDL Benzo(a)pyrene BDL BDL BDL BDL Benzo(b)fluoranthene BDL BDL BDL BDL Benzo(k)fluoranthene BDL BDL BDL BDL Bis-(2-chloroethoxy)
methane
BDL BDL BDL BDL
Bis-(2-chloroethyl) ether BDL BDL BDL BDL Bis-(2-chloroisopropyl) ether BDL BDL BDL BDL Bis-(2-ethylhexyl) phthalate BDL BDL BDL BDL Butyl benzyl phthalate BDL BDL BDL BDL Carbazole BDL BDL BDL BDL Chrysene BDL BDL BDL BDL Di-n-butyl phthalate BDL BDL BDL BDL Di-n-octyl phthalate BDL BDL BDL BDL Dibenzofuran BDL BDL BDL BDL Diethyl phthalate BDL BDL BDL BDL Dimethyl phthalate BDL BDL BDL BDL Fluoranthene BDL BDL BDL BDL Fluorene BDL BDL BDL BDL
P.O. Box 82124,
Southdale, 2135,
South Africa.
TEL. (011) 496-2228
FAX (011) 496-2239
Registration Number 1974/001476/07 Vat Number 4780103505
M and L Laboratory Services (Pty) Ltd Consulting Industrial Chemists, Analysts & Samplers
CONFIDENTIAL
Ref No.
: 8464238
Issued
at
: Johannesburg
Date
: 24/04/2014
Page : 4 of 4
LAB NUMBERS H03578 H03579 H03580 H03581
SAMPLE MARKS KBH-10D KHB-35 KBH-105 KBH5
Hexachlorobenzene BDL BDL BDL BDL Hexachlorobutadiene BDL BDL BDL BDL Hexachlorocyclopentadiene BDL BDL BDL BDL Hexachloroethane BDL BDL BDL BDL Isophorone BDL BDL BDL BDL N-nitrosodi-n-propylamine BDL BDL BDL BDL Naphthalene BDL BDL BDL BDL Nitrobenzene BDL BDL BDL BDL Pentachlorophenol BDL BDL BDL BDL Phenanthrene BDL BDL BDL BDL Phenol BDL BDL BDL BDL Pyrene BDL BDL BDL BDL 1,2-Dichlorobenzene BDL BDL BDL BDL 1,2,4-Trichlorobenzene BDL BDL BDL BDL 1,3-Dichlorobenzene BDL BDL BDL BDL 1,4-Dichlorobenzene BDL BDL BDL BDL 2-Chloronaphthalene BDL BDL BDL BDL 2-Chlorophenol BDL BDL BDL BDL 2-Methylnaphthalene BDL BDL BDL BDL 2-Methylphenol BDL BDL BDL BDL 2-Nitroaniline BDL BDL BDL BDL 2-Nitrophenol BDL BDL BDL BDL 2,4-Dichlorophenol BDL BDL BDL BDL 2,4-Dimethylphenol BDL BDL BDL BDL 2,4-Dinitrotoluene BDL BDL BDL BDL 2,4,5-Trichlorophenol BDL BDL BDL BDL 2,4,6-Trichlorophenol BDL BDL BDL BDL 2,6-Dinitrotoluene BDL BDL BDL BDL 3-Nitroaniline BDL BDL BDL BDL 4-Bromophenylphenyl ether BDL BDL BDL BDL 4-Chloro-3-methylphenol BDL BDL BDL BDL 4-Chloroaniline BDL BDL BDL BDL 4-Chlorophenylphenyl ether BDL BDL BDL BDL 4-Methylphenol BDL BDL BDL BDL 4-Nitroaniline BDL BDL BDL BDL
SVOC – GC/MS Following Solvent Extraction Technique.
All Results Reported in (µg/l).
BDL – Below Detection Limit (50µg/l).
ArcelorMittal Vanderbijlpark
External audit report on the WML for Klip waste site at AMSA Vereeniging
42 Report: 192-ZANAMVE-2015 Zantow Environmental Consulting Services
ANNEXURE B2
Ground water monitoring results – organics (September 2014)
M and L Laboratory Services (Pty) Ltd
Registration Number 1974/001476/07 VATNumber 4780103505
P.O. Box 82124
Southdale, 2135
40 Modulus Road
Page 1 of 13
:
:
:
ML2014-2336
8555122
2014-09-03
Ref. No.
Contract No.
Date
Ormonde, 2091
Tel: (011) 661 7900
Fax: (011) 496 2238
0861 467 765
Golden No.Consulting Industrial Chemists, Analysts Samplers
CONFIDENTIAL
Certificate / Report
COMPANY NAME : ARCELORMITTAL SOUTH AFRICA
ADDRESS : P O BOX 2 VANDERBIJLPARK 1900
SUBJECT : analysis of 10 water samples
PROJECT REFERENCE :
:INSTRUCTED BY J. Mnisi
:ORDER NUMBER
:RECEIVED ON 2014-08-08
:ANALYSIS COMPLETED 2014-09-03
* BDL - Below Detection Limit
* Denotes test method accredited to ISO17025
These tests do not apply to any other samples of a similar nature.
Refer to terms and conditions www.inspml.co.zaoo This report relates to only test items listed herein and analysis on an as received basis.
This certificate cannot be reproduced except in full without the written consent of M and L Laboratory Services (Pty) Ltd.o
:Printed Date 2014-09-03
M and L Laboratory Services (Pty) Ltd
Registration Number 1974/001476/07 VATNumber 4780103505
P.O. Box 82124
Southdale, 2135
40 Modulus Road
Page 2 of 13
:
:
:
ML2014-2336
8555122
2014-09-03
Ref. No.
Contract No.
Date
Ormonde, 2091
Tel: (011) 661 7900
Fax: (011) 496 2238
0861 467 765
Golden No.Consulting Industrial Chemists, Analysts Samplers
CONFIDENTIAL
Certificate / Report
Method
References
Detection
Limit
E16956 E16957 E16958
Sample Marks KBH -3d KBH-3s KBH-4d
ResultDeterminand Result Result
Lab Number
Sampled Date
Chemical Analysis
Total Organic Carbon as C (mg/l) Subcontracted toAquadoc
1 7.2 32 10
Authorised Signature
Supervisor
Edward Khumalo
* BDL - Below Detection Limit
* Denotes test method accredited to ISO17025
These tests do not apply to any other samples of a similar nature.
Refer to terms and conditions www.inspml.co.zaoo This report relates to only test items listed herein and analysis on an as received basis.
This certificate cannot be reproduced except in full without the written consent of M and L Laboratory Services (Pty) Ltd.o
:Printed Date 2014-09-03
M and L Laboratory Services (Pty) Ltd
Registration Number 1974/001476/07 VATNumber 4780103505
P.O. Box 82124
Southdale, 2135
40 Modulus Road
Page 3 of 13
:
:
:
ML2014-2336
8555122
2014-09-03
Ref. No.
Contract No.
Date
Ormonde, 2091
Tel: (011) 661 7900
Fax: (011) 496 2238
0861 467 765
Golden No.Consulting Industrial Chemists, Analysts Samplers
CONFIDENTIAL
Certificate / Report
Method
References
Detection
Limit
E16956 E16957 E16958
Sample Marks KBH -3d KBH-3s KBH-4d
ResultDeterminand Result Result
Lab Number
Sampled Date
SVOC
Acenaphthene (ug/l) EPA 8270C 50 BDL BDL BDL
Acenaphthylene (ug/l) EPA 8270C 50 BDL BDL BDL
Anthracene (ug/l) EPA 8270C 50 BDL BDL BDL
Azobenzene (ug/l) EPA 8270C 50 BDL BDL BDL
Benzo(a)pyrene (ug/l) EPA 8270C 50 BDL BDL BDL
Carbazole (ug/l) EPA 8270C 50 BDL BDL BDL
Chrysene (ug/l) EPA 8270C 50 BDL BDL BDL
Dibenzofuran (ug/l) EPA 8270C 50 BDL BDL BDL
Fluorene (ug/l) EPA 8270C 50 BDL BDL BDL
Hexachlorobenzene (ug/l) EPA 8270C 50 BDL BDL BDL
Hexachlorobutadiene (ug/l) EPA 8270C 50 BDL BDL BDL
Hexachlorocyclopentadiene (ug/l) EPA 8270C 50 BDL BDL BDL
Hexachloroethane (ug/l) EPA 8270C 50 BDL BDL BDL
Isophorone (ug/l) EPA 8270C 50 BDL BDL BDL
Nitrobenzene (ug/l) EPA 8270C 50 BDL BDL BDL
Phenol (ug/l) EPA 8270C 50 BDL BDL BDL
Pyrene (ug/l) EPA 8270C 50 BDL BDL BDL
2-Chloronaphthalene (ug/l) EPA 8270C 50 BDL BDL BDL
2-Chlorophenol (ug/l) EPA 8270C 50 BDL BDL BDL
2-Methylnaphthalene (ug/l) EPA 8270C 50 BDL BDL BDL
2-Nitrophenol (ug/l) EPA 8270C 50 BDL BDL BDL
2,4-Dichlorophenol (ug/l) EPA 8270C 50 BDL BDL BDL
2,4-Dimethylphenol (ug/l) EPA 8270C 50 BDL BDL BDL
2,4-Dinitrotoluene (ug/l) EPA 8270C 50 BDL BDL BDL
2,4,5-Trichlorophenol (ug/l) EPA 8270C 50 BDL BDL BDL
2,4,6-Trichlorophenol (ug/l) EPA 8270C 50 BDL BDL BDL
* BDL - Below Detection Limit
* Denotes test method accredited to ISO17025
These tests do not apply to any other samples of a similar nature.
Refer to terms and conditions www.inspml.co.zaoo This report relates to only test items listed herein and analysis on an as received basis.
This certificate cannot be reproduced except in full without the written consent of M and L Laboratory Services (Pty) Ltd.o
:Printed Date 2014-09-03
M and L Laboratory Services (Pty) Ltd
Registration Number 1974/001476/07 VATNumber 4780103505
P.O. Box 82124
Southdale, 2135
40 Modulus Road
Page 4 of 13
:
:
:
ML2014-2336
8555122
2014-09-03
Ref. No.
Contract No.
Date
Ormonde, 2091
Tel: (011) 661 7900
Fax: (011) 496 2238
0861 467 765
Golden No.Consulting Industrial Chemists, Analysts Samplers
CONFIDENTIAL
Certificate / Report
Method
References
Detection
Limit
E16956 E16957 E16958
Sample Marks KBH -3d KBH-3s KBH-4d
ResultDeterminand Result Result
Lab Number
Sampled Date
SVOC
4-Methylphenol (ug/l) EPA 8270C 50 BDL BDL BDL
Authorised Signature
Manager M&L Lab Services
Joanne Barton
* BDL - Below Detection Limit
* Denotes test method accredited to ISO17025
These tests do not apply to any other samples of a similar nature.
Refer to terms and conditions www.inspml.co.zaoo This report relates to only test items listed herein and analysis on an as received basis.
This certificate cannot be reproduced except in full without the written consent of M and L Laboratory Services (Pty) Ltd.o
:Printed Date 2014-09-03
M and L Laboratory Services (Pty) Ltd
Registration Number 1974/001476/07 VATNumber 4780103505
P.O. Box 82124
Southdale, 2135
40 Modulus Road
Page 5 of 13
:
:
:
ML2014-2336
8555122
2014-09-03
Ref. No.
Contract No.
Date
Ormonde, 2091
Tel: (011) 661 7900
Fax: (011) 496 2238
0861 467 765
Golden No.Consulting Industrial Chemists, Analysts Samplers
CONFIDENTIAL
Certificate / Report
Method
References
Detection
Limit
E16959 E16960 E16961
Sample Marks KBH-s KBH-5 KBH-6d
ResultDeterminand Result Result
Lab Number
Sampled Date
Chemical Analysis
Total Organic Carbon as C (mg/l) Subcontracted toAquadoc
1 17 19 9.1
Authorised Signature
Supervisor
Edward Khumalo
* BDL - Below Detection Limit
* Denotes test method accredited to ISO17025
These tests do not apply to any other samples of a similar nature.
Refer to terms and conditions www.inspml.co.zaoo This report relates to only test items listed herein and analysis on an as received basis.
This certificate cannot be reproduced except in full without the written consent of M and L Laboratory Services (Pty) Ltd.o
:Printed Date 2014-09-03
M and L Laboratory Services (Pty) Ltd
Registration Number 1974/001476/07 VATNumber 4780103505
P.O. Box 82124
Southdale, 2135
40 Modulus Road
Page 6 of 13
:
:
:
ML2014-2336
8555122
2014-09-03
Ref. No.
Contract No.
Date
Ormonde, 2091
Tel: (011) 661 7900
Fax: (011) 496 2238
0861 467 765
Golden No.Consulting Industrial Chemists, Analysts Samplers
CONFIDENTIAL
Certificate / Report
Method
References
Detection
Limit
E16959 E16960 E16961
Sample Marks KBH-s KBH-5 KBH-6d
ResultDeterminand Result Result
Lab Number
Sampled Date
SVOC
Acenaphthene (ug/l) EPA 8270C 50 BDL BDL BDL
Acenaphthylene (ug/l) EPA 8270C 50 BDL BDL BDL
Anthracene (ug/l) EPA 8270C 50 BDL BDL BDL
Azobenzene (ug/l) EPA 8270C 50 BDL BDL BDL
Benzo(a)pyrene (ug/l) EPA 8270C 50 BDL BDL BDL
Carbazole (ug/l) EPA 8270C 50 BDL BDL BDL
Chrysene (ug/l) EPA 8270C 50 BDL BDL BDL
Dibenzofuran (ug/l) EPA 8270C 50 BDL BDL BDL
Fluorene (ug/l) EPA 8270C 50 BDL BDL BDL
Hexachlorobenzene (ug/l) EPA 8270C 50 BDL BDL BDL
Hexachlorobutadiene (ug/l) EPA 8270C 50 BDL BDL BDL
Hexachlorocyclopentadiene (ug/l) EPA 8270C 50 BDL BDL BDL
Hexachloroethane (ug/l) EPA 8270C 50 BDL BDL BDL
Isophorone (ug/l) EPA 8270C 50 BDL BDL BDL
Nitrobenzene (ug/l) EPA 8270C 50 BDL BDL BDL
Phenol (ug/l) EPA 8270C 50 BDL BDL BDL
Pyrene (ug/l) EPA 8270C 50 BDL BDL BDL
2-Chloronaphthalene (ug/l) EPA 8270C 50 BDL BDL BDL
2-Chlorophenol (ug/l) EPA 8270C 50 BDL BDL BDL
2-Methylnaphthalene (ug/l) EPA 8270C 50 BDL BDL BDL
2-Nitrophenol (ug/l) EPA 8270C 50 BDL BDL BDL
2,4-Dichlorophenol (ug/l) EPA 8270C 50 BDL BDL BDL
2,4-Dimethylphenol (ug/l) EPA 8270C 50 BDL BDL BDL
2,4-Dinitrotoluene (ug/l) EPA 8270C 50 BDL BDL BDL
2,4,5-Trichlorophenol (ug/l) EPA 8270C 50 BDL BDL BDL
2,4,6-Trichlorophenol (ug/l) EPA 8270C 50 BDL BDL BDL
* BDL - Below Detection Limit
* Denotes test method accredited to ISO17025
These tests do not apply to any other samples of a similar nature.
Refer to terms and conditions www.inspml.co.zaoo This report relates to only test items listed herein and analysis on an as received basis.
This certificate cannot be reproduced except in full without the written consent of M and L Laboratory Services (Pty) Ltd.o
:Printed Date 2014-09-03
M and L Laboratory Services (Pty) Ltd
Registration Number 1974/001476/07 VATNumber 4780103505
P.O. Box 82124
Southdale, 2135
40 Modulus Road
Page 7 of 13
:
:
:
ML2014-2336
8555122
2014-09-03
Ref. No.
Contract No.
Date
Ormonde, 2091
Tel: (011) 661 7900
Fax: (011) 496 2238
0861 467 765
Golden No.Consulting Industrial Chemists, Analysts Samplers
CONFIDENTIAL
Certificate / Report
Method
References
Detection
Limit
E16959 E16960 E16961
Sample Marks KBH-s KBH-5 KBH-6d
ResultDeterminand Result Result
Lab Number
Sampled Date
SVOC
4-Methylphenol (ug/l) EPA 8270C 50 BDL BDL BDL
Authorised Signature
Manager M&L Lab Services
Joanne Barton
* BDL - Below Detection Limit
* Denotes test method accredited to ISO17025
These tests do not apply to any other samples of a similar nature.
Refer to terms and conditions www.inspml.co.zaoo This report relates to only test items listed herein and analysis on an as received basis.
This certificate cannot be reproduced except in full without the written consent of M and L Laboratory Services (Pty) Ltd.o
:Printed Date 2014-09-03
M and L Laboratory Services (Pty) Ltd
Registration Number 1974/001476/07 VATNumber 4780103505
P.O. Box 82124
Southdale, 2135
40 Modulus Road
Page 8 of 13
:
:
:
ML2014-2336
8555122
2014-09-03
Ref. No.
Contract No.
Date
Ormonde, 2091
Tel: (011) 661 7900
Fax: (011) 496 2238
0861 467 765
Golden No.Consulting Industrial Chemists, Analysts Samplers
CONFIDENTIAL
Certificate / Report
Method
References
Detection
Limit
E16962 E16963 E16964
Sample Marks KBH-7d KBH-8d KBH-9d
ResultDeterminand Result Result
Lab Number
Sampled Date
Chemical Analysis
Total Organic Carbon as C (mg/l) Subcontracted toAquadoc
1 9.3 9.9 13
Authorised Signature
Supervisor
Edward Khumalo
* BDL - Below Detection Limit
* Denotes test method accredited to ISO17025
These tests do not apply to any other samples of a similar nature.
Refer to terms and conditions www.inspml.co.zaoo This report relates to only test items listed herein and analysis on an as received basis.
This certificate cannot be reproduced except in full without the written consent of M and L Laboratory Services (Pty) Ltd.o
:Printed Date 2014-09-03
M and L Laboratory Services (Pty) Ltd
Registration Number 1974/001476/07 VATNumber 4780103505
P.O. Box 82124
Southdale, 2135
40 Modulus Road
Page 9 of 13
:
:
:
ML2014-2336
8555122
2014-09-03
Ref. No.
Contract No.
Date
Ormonde, 2091
Tel: (011) 661 7900
Fax: (011) 496 2238
0861 467 765
Golden No.Consulting Industrial Chemists, Analysts Samplers
CONFIDENTIAL
Certificate / Report
Method
References
Detection
Limit
E16962 E16963 E16964
Sample Marks KBH-7d KBH-8d KBH-9d
ResultDeterminand Result Result
Lab Number
Sampled Date
SVOC
Acenaphthene (ug/l) EPA 8270C 50 BDL BDL BDL
Acenaphthylene (ug/l) EPA 8270C 50 BDL BDL BDL
Anthracene (ug/l) EPA 8270C 50 BDL BDL BDL
Azobenzene (ug/l) EPA 8270C 50 BDL BDL BDL
Benzo(a)pyrene (ug/l) EPA 8270C 50 BDL BDL BDL
Carbazole (ug/l) EPA 8270C 50 BDL BDL BDL
Chrysene (ug/l) EPA 8270C 50 BDL BDL BDL
Dibenzofuran (ug/l) EPA 8270C 50 BDL BDL BDL
Fluorene (ug/l) EPA 8270C 50 BDL BDL BDL
Hexachlorobenzene (ug/l) EPA 8270C 50 BDL BDL BDL
Hexachlorobutadiene (ug/l) EPA 8270C 50 BDL BDL BDL
Hexachlorocyclopentadiene (ug/l) EPA 8270C 50 BDL BDL BDL
Hexachloroethane (ug/l) EPA 8270C 50 BDL BDL BDL
Isophorone (ug/l) EPA 8270C 50 BDL BDL BDL
Nitrobenzene (ug/l) EPA 8270C 50 BDL BDL BDL
Phenol (ug/l) EPA 8270C 50 BDL BDL BDL
Pyrene (ug/l) EPA 8270C 50 BDL BDL BDL
2-Chloronaphthalene (ug/l) EPA 8270C 50 BDL BDL BDL
2-Chlorophenol (ug/l) EPA 8270C 50 BDL BDL BDL
2-Methylnaphthalene (ug/l) EPA 8270C 50 BDL BDL BDL
2-Nitrophenol (ug/l) EPA 8270C 50 BDL BDL BDL
2,4-Dichlorophenol (ug/l) EPA 8270C 50 BDL BDL BDL
2,4-Dimethylphenol (ug/l) EPA 8270C 50 BDL BDL BDL
2,4-Dinitrotoluene (ug/l) EPA 8270C 50 BDL BDL BDL
2,4,5-Trichlorophenol (ug/l) EPA 8270C 50 BDL BDL BDL
2,4,6-Trichlorophenol (ug/l) EPA 8270C 50 BDL BDL BDL
* BDL - Below Detection Limit
* Denotes test method accredited to ISO17025
These tests do not apply to any other samples of a similar nature.
Refer to terms and conditions www.inspml.co.zaoo This report relates to only test items listed herein and analysis on an as received basis.
This certificate cannot be reproduced except in full without the written consent of M and L Laboratory Services (Pty) Ltd.o
:Printed Date 2014-09-03
M and L Laboratory Services (Pty) Ltd
Registration Number 1974/001476/07 VATNumber 4780103505
P.O. Box 82124
Southdale, 2135
40 Modulus Road
Page 10 of 13
:
:
:
ML2014-2336
8555122
2014-09-03
Ref. No.
Contract No.
Date
Ormonde, 2091
Tel: (011) 661 7900
Fax: (011) 496 2238
0861 467 765
Golden No.Consulting Industrial Chemists, Analysts Samplers
CONFIDENTIAL
Certificate / Report
Method
References
Detection
Limit
E16962 E16963 E16964
Sample Marks KBH-7d KBH-8d KBH-9d
ResultDeterminand Result Result
Lab Number
Sampled Date
SVOC
4-Methylphenol (ug/l) EPA 8270C 50 BDL BDL BDL
Authorised Signature
Manager M&L Lab Services
Joanne Barton
* BDL - Below Detection Limit
* Denotes test method accredited to ISO17025
These tests do not apply to any other samples of a similar nature.
Refer to terms and conditions www.inspml.co.zaoo This report relates to only test items listed herein and analysis on an as received basis.
This certificate cannot be reproduced except in full without the written consent of M and L Laboratory Services (Pty) Ltd.o
:Printed Date 2014-09-03
M and L Laboratory Services (Pty) Ltd
Registration Number 1974/001476/07 VATNumber 4780103505
P.O. Box 82124
Southdale, 2135
40 Modulus Road
Page 11 of 13
:
:
:
ML2014-2336
8555122
2014-09-03
Ref. No.
Contract No.
Date
Ormonde, 2091
Tel: (011) 661 7900
Fax: (011) 496 2238
0861 467 765
Golden No.Consulting Industrial Chemists, Analysts Samplers
CONFIDENTIAL
Certificate / Report
Method
References
Detection
Limit
E16965
Sample Marks KBH-10d
ResultDeterminand
Lab Number
Sampled Date
Chemical Analysis
Total Organic Carbon as C (mg/l) Subcontracted toAquadoc
1 37
Authorised Signature
Supervisor
Edward Khumalo
* BDL - Below Detection Limit
* Denotes test method accredited to ISO17025
These tests do not apply to any other samples of a similar nature.
Refer to terms and conditions www.inspml.co.zaoo This report relates to only test items listed herein and analysis on an as received basis.
This certificate cannot be reproduced except in full without the written consent of M and L Laboratory Services (Pty) Ltd.o
:Printed Date 2014-09-03
M and L Laboratory Services (Pty) Ltd
Registration Number 1974/001476/07 VATNumber 4780103505
P.O. Box 82124
Southdale, 2135
40 Modulus Road
Page 12 of 13
:
:
:
ML2014-2336
8555122
2014-09-03
Ref. No.
Contract No.
Date
Ormonde, 2091
Tel: (011) 661 7900
Fax: (011) 496 2238
0861 467 765
Golden No.Consulting Industrial Chemists, Analysts Samplers
CONFIDENTIAL
Certificate / Report
Method
References
Detection
Limit
E16965
Sample Marks KBH-10d
ResultDeterminand
Lab Number
Sampled Date
SVOC
Acenaphthene (ug/l) EPA 8270C 50 BDL
Acenaphthylene (ug/l) EPA 8270C 50 BDL
Anthracene (ug/l) EPA 8270C 50 BDL
Azobenzene (ug/l) EPA 8270C 50 BDL
Benzo(a)pyrene (ug/l) EPA 8270C 50 BDL
Carbazole (ug/l) EPA 8270C 50 BDL
Chrysene (ug/l) EPA 8270C 50 BDL
Dibenzofuran (ug/l) EPA 8270C 50 BDL
Fluorene (ug/l) EPA 8270C 50 BDL
Hexachlorobenzene (ug/l) EPA 8270C 50 BDL
Hexachlorobutadiene (ug/l) EPA 8270C 50 BDL
Hexachlorocyclopentadiene (ug/l) EPA 8270C 50 BDL
Hexachloroethane (ug/l) EPA 8270C 50 BDL
Isophorone (ug/l) EPA 8270C 50 BDL
Nitrobenzene (ug/l) EPA 8270C 50 BDL
Phenol (ug/l) EPA 8270C 50 BDL
Pyrene (ug/l) EPA 8270C 50 BDL
2-Chloronaphthalene (ug/l) EPA 8270C 50 BDL
2-Chlorophenol (ug/l) EPA 8270C 50 BDL
2-Methylnaphthalene (ug/l) EPA 8270C 50 BDL
2-Nitrophenol (ug/l) EPA 8270C 50 BDL
2,4-Dichlorophenol (ug/l) EPA 8270C 50 BDL
2,4-Dimethylphenol (ug/l) EPA 8270C 50 BDL
2,4-Dinitrotoluene (ug/l) EPA 8270C 50 BDL
2,4,5-Trichlorophenol (ug/l) EPA 8270C 50 BDL
2,4,6-Trichlorophenol (ug/l) EPA 8270C 50 BDL
* BDL - Below Detection Limit
* Denotes test method accredited to ISO17025
These tests do not apply to any other samples of a similar nature.
Refer to terms and conditions www.inspml.co.zaoo This report relates to only test items listed herein and analysis on an as received basis.
This certificate cannot be reproduced except in full without the written consent of M and L Laboratory Services (Pty) Ltd.o
:Printed Date 2014-09-03
M and L Laboratory Services (Pty) Ltd
Registration Number 1974/001476/07 VATNumber 4780103505
P.O. Box 82124
Southdale, 2135
40 Modulus Road
Page 13 of 13
:
:
:
ML2014-2336
8555122
2014-09-03
Ref. No.
Contract No.
Date
Ormonde, 2091
Tel: (011) 661 7900
Fax: (011) 496 2238
0861 467 765
Golden No.Consulting Industrial Chemists, Analysts Samplers
CONFIDENTIAL
Certificate / Report
Method
References
Detection
Limit
E16965
Sample Marks KBH-10d
ResultDeterminand
Lab Number
Sampled Date
SVOC
4-Methylphenol (ug/l) EPA 8270C 50 BDL
Authorised Signature
Manager M&L Lab Services
Joanne Barton
* BDL - Below Detection Limit
* Denotes test method accredited to ISO17025
These tests do not apply to any other samples of a similar nature.
Refer to terms and conditions www.inspml.co.zaoo This report relates to only test items listed herein and analysis on an as received basis.
This certificate cannot be reproduced except in full without the written consent of M and L Laboratory Services (Pty) Ltd.o
:Printed Date 2014-09-03
ArcelorMittal Vanderbijlpark
External audit report on the WML for Klip waste site at AMSA Vereeniging
43 Report: 192-ZANAMVE-2015 Zantow Environmental Consulting Services
ANNEXURE B3
Ground water monitoring results – organics (December 2014)
M and L Laboratory Services (Pty) Ltd
Registration Number 1974/001476/07 VATNumber 4780103505
P.O. Box 82124
Southdale, 2135
40 Modulus Road
Page 1 of 19
:
:
:
ML2014-3556
8621100
2014-12-08
Ref. No.
Contract No.
Date
Ormonde, 2091
Tel: (011) 661 7900
Fax: (011) 496 2238
0861 467 765
Golden No.Consulting Industrial Chemists, Analysts Samplers
CONFIDENTIAL
Certificate / Report
COMPANY NAME : ARCELORMITTAL SOUTH AFRICA
ADDRESS : P O BOX 2 VANDERBIJLPARK 1900
SUBJECT : ANALYSIS OF 16 WATER SAMPLES
PROJECT REFERENCE : 16XWATER SAMPLES
:INSTRUCTED BY J. Mnisi
:ORDER NUMBER
:RECEIVED ON 2014-11-14
:ANALYSIS COMPLETED 2014-12-08
BDL - Below Detection Limit
* Denotes test method accredited to ISO17025
These tests do not apply to any other samples of a similar nature.
Refer to terms and conditions www.inspml.co.zaoo This report relates to only test items listed herein and analysis on an as received basis.
This certificate cannot be reproduced except in full without the written consent of M and L Laboratory Services (Pty) Ltd.o
:Printed Date 2014-12-09
M and L Laboratory Services (Pty) Ltd
Registration Number 1974/001476/07 VATNumber 4780103505
P.O. Box 82124
Southdale, 2135
40 Modulus Road
Page 2 of 19
:
:
:
ML2014-3556
8621100
2014-12-08
Ref. No.
Contract No.
Date
Ormonde, 2091
Tel: (011) 661 7900
Fax: (011) 496 2238
0861 467 765
Golden No.Consulting Industrial Chemists, Analysts Samplers
CONFIDENTIAL
Certificate / Report
H04877
ID-2S
H04876
QualityControlResultResult
ID-3S
QualityControlResultResult
H04875
ID-1S
Result
QualityControlResult
Lab Number
Sample Marks
Determinant
DetectionLimit
Quanti-fication
LimitQualityControl
EPA 8270CMethod SVOC in Water by GC/MS Reference
BDL 50 BDL 5050BDL50Phenol(ug/l)
BDL 55 BDL 5555BDL502-Chlorophenol(ug/l)
BDL 59 BDL 5959BDL50Benzene, 1,3-dichloro-(ug/l)
BDL 55 BDL 5555BDL50Benzene, 1,4-dichloro-(ug/l)
BDL 51 BDL 5151BDL50Benzene, 1,2-dichloro-(ug/l)
BDL 51 BDL 5151BDL502-methylphenol(ug/l)
BDL 51 BDL 5151BDL50Bis(2-chloroisopropyl)ether(ug/l)
BDL 56 BDL 5656BDL504-Methylphenol(ug/l)
BDL 53 BDL 5353BDL50N-Nitrosodi-n-propylamine(ug/l)
BDL 55 BDL 5555BDL50Hexachloroethane(ug/l)
BDL 53 BDL 5353BDL50Nitrobenzene(ug/l)
BDL 52 BDL 5252BDL50Isophorone(ug/l)
BDL 60 BDL 6060BDL502-Nitrophenol(ug/l)
BDL 55 BDL 5555BDL502,4-Dimethylphenol(ug/l)
BDL 56 BDL 5656BDL502,4-Dichlorophenol(ug/l)
BDL 53 BDL 5353BDL50Naphthalene(ug/l)
BDL 53 BDL 5353BDL50p-Chloroaniline(ug/l)
BDL 52 BDL 5252BDL50Hexachlorobutadiene(ug/l)
BDL 55 BDL 5555BDL504-chloro-3-methylphenol(ug/l)
BDL - Below Detection Limit
* Denotes test method accredited to ISO17025
These tests do not apply to any other samples of a similar nature.
Refer to terms and conditions www.inspml.co.zaoo This report relates to only test items listed herein and analysis on an as received basis.
This certificate cannot be reproduced except in full without the written consent of M and L Laboratory Services (Pty) Ltd.o
:Printed Date 2014-12-09
M and L Laboratory Services (Pty) Ltd
Registration Number 1974/001476/07 VATNumber 4780103505
P.O. Box 82124
Southdale, 2135
40 Modulus Road
Page 3 of 19
:
:
:
ML2014-3556
8621100
2014-12-08
Ref. No.
Contract No.
Date
Ormonde, 2091
Tel: (011) 661 7900
Fax: (011) 496 2238
0861 467 765
Golden No.Consulting Industrial Chemists, Analysts Samplers
CONFIDENTIAL
Certificate / Report
H04877
ID-2S
H04876
QualityControlResultResult
ID-3S
QualityControlResultResult
H04875
ID-1S
Result
QualityControlResult
Lab Number
Sample Marks
Determinant
DetectionLimit
Quanti-fication
LimitQualityControl
EPA 8270CMethod SVOC in Water by GC/MS Reference
BDL 50 BDL 5050BDL502-Methylnaphthalene(ug/l)
BDL 54 BDL 5454BDL50Hexachlorocyclopentadiene(ug/l)
BDL 52 BDL 5252BDL502,4,6-Trichlorophenol(ug/l)
BDL 50 BDL 5050BDL502,4,5-Trichlorophenol(ug/l)
BDL 50 BDL 5050BDL502-Chloronaphthalene(ug/l)
BDL 49 BDL 4949BDL50o-Nitroaniline(ug/l)
BDL 49 BDL 4949BDL50Dimethylphthalate(ug/l)
BDL 49 BDL 4949BDL50Acenaphthylene(ug/l)
BDL 54 BDL 5454BDL50m-Nitroaniline(ug/l)
BDL 49 BDL 4949BDL50Acenaphthene(ug/l)
BDL 48 BDL 4848BDL50Dibenzofuran(ug/l)
BDL 49 BDL 4949BDL502,4-Dinitrotoluene(ug/l)
BDL 52 BDL 5252BDL50Diethyl Phthalate(ug/l)
BDL 51 BDL 5151BDL50Fluorene(ug/l)
BDL 48 BDL 4848BDL504-Chlorophenyl-phenylether(ug/l)
BDL 53 BDL 5353BDL50p-Nitroaniline(ug/l)
BDL 49 BDL 4949BDL50Azobenzene(ug/l)
BDL 51 BDL 5151BDL504-Bromophenyl-phenylether(ug/l)
BDL 47 BDL 4747BDL50Hexachlorobenzene(ug/l)
BDL - Below Detection Limit
* Denotes test method accredited to ISO17025
These tests do not apply to any other samples of a similar nature.
Refer to terms and conditions www.inspml.co.zaoo This report relates to only test items listed herein and analysis on an as received basis.
This certificate cannot be reproduced except in full without the written consent of M and L Laboratory Services (Pty) Ltd.o
:Printed Date 2014-12-09
M and L Laboratory Services (Pty) Ltd
Registration Number 1974/001476/07 VATNumber 4780103505
P.O. Box 82124
Southdale, 2135
40 Modulus Road
Page 4 of 19
:
:
:
ML2014-3556
8621100
2014-12-08
Ref. No.
Contract No.
Date
Ormonde, 2091
Tel: (011) 661 7900
Fax: (011) 496 2238
0861 467 765
Golden No.Consulting Industrial Chemists, Analysts Samplers
CONFIDENTIAL
Certificate / Report
H04877
ID-2S
H04876
QualityControlResultResult
ID-3S
QualityControlResultResult
H04875
ID-1S
Result
QualityControlResult
Lab Number
Sample Marks
Determinant
DetectionLimit
Quanti-fication
LimitQualityControl
EPA 8270CMethod SVOC in Water by GC/MS Reference
BDL 49 BDL 4949BDL50Phenathrene(ug/l)
BDL 48 BDL 4848BDL50Anthracene(ug/l)
BDL 49 BDL 4949BDL50Carbazole(ug/l)
BDL 51 BDL 5151BDL50Dibutyl phthalate(ug/l)
BDL 48 BDL 4848BDL50Pyrene(ug/l)
BDL 56 BDL 5656BDL50Benzyl Butyl Phthalate(ug/l)
BDL 53 BDL 5353BDL50Benz[a]anthracene(ug/l)
BDL 51 BDL 5151BDL50Chrysene(ug/l)
BDL 52 BDL 5252BDL50Bis(2-ethylhexyl)phthalate(ug/l)
BDL 61 BDL 6161BDL50Di-n-octylphthalate(ug/l)
BDL 47 BDL 4747BDL50Benzo(b)fluoranthene(ug/l)
BDL 52 BDL 5252BDL50Benzo(k)fluoranthene(ug/l)
BDL 53 BDL 5353BDL50Benzo(a)pyrene(ug/l)
Authorised Signature
Manager M&L Lab Services
Joanne Barton
BDL - Below Detection Limit
* Denotes test method accredited to ISO17025
These tests do not apply to any other samples of a similar nature.
Refer to terms and conditions www.inspml.co.zaoo This report relates to only test items listed herein and analysis on an as received basis.
This certificate cannot be reproduced except in full without the written consent of M and L Laboratory Services (Pty) Ltd.o
:Printed Date 2014-12-09
M and L Laboratory Services (Pty) Ltd
Registration Number 1974/001476/07 VATNumber 4780103505
P.O. Box 82124
Southdale, 2135
40 Modulus Road
Page 5 of 19
:
:
:
ML2014-3556
8621100
2014-12-08
Ref. No.
Contract No.
Date
Ormonde, 2091
Tel: (011) 661 7900
Fax: (011) 496 2238
0861 467 765
Golden No.Consulting Industrial Chemists, Analysts Samplers
CONFIDENTIAL
Certificate / Report
H04880
ID-4S
H04879
QualityControlResultResult
ID-4D
QualityControlResultResult
H04878
ID-3D
Result
QualityControlResult
Lab Number
Sample Marks
Determinant
DetectionLimit
Quanti-fication
LimitQualityControl
EPA 8270CMethod SVOC in Water by GC/MS Reference
BDL 50 BDL 5050BDL50Phenol(ug/l)
BDL 55 BDL 5555BDL502-Chlorophenol(ug/l)
BDL 59 BDL 5959BDL50Benzene, 1,3-dichloro-(ug/l)
BDL 55 BDL 5555BDL50Benzene, 1,4-dichloro-(ug/l)
BDL 51 BDL 5151BDL50Benzene, 1,2-dichloro-(ug/l)
BDL 51 BDL 5151BDL502-methylphenol(ug/l)
BDL 51 BDL 5151BDL50Bis(2-chloroisopropyl)ether(ug/l)
BDL 56 BDL 5656BDL504-Methylphenol(ug/l)
BDL 53 BDL 5353BDL50N-Nitrosodi-n-propylamine(ug/l)
BDL 55 BDL 5555BDL50Hexachloroethane(ug/l)
BDL 53 BDL 5353BDL50Nitrobenzene(ug/l)
BDL 52 BDL 5252BDL50Isophorone(ug/l)
BDL 60 BDL 6060BDL502-Nitrophenol(ug/l)
BDL 55 BDL 5555BDL502,4-Dimethylphenol(ug/l)
BDL 56 BDL 5656BDL502,4-Dichlorophenol(ug/l)
BDL 53 BDL 5353BDL50Naphthalene(ug/l)
BDL 53 BDL 5353BDL50p-Chloroaniline(ug/l)
BDL 52 BDL 5252BDL50Hexachlorobutadiene(ug/l)
BDL 55 BDL 5555BDL504-chloro-3-methylphenol(ug/l)
BDL - Below Detection Limit
* Denotes test method accredited to ISO17025
These tests do not apply to any other samples of a similar nature.
Refer to terms and conditions www.inspml.co.zaoo This report relates to only test items listed herein and analysis on an as received basis.
This certificate cannot be reproduced except in full without the written consent of M and L Laboratory Services (Pty) Ltd.o
:Printed Date 2014-12-09
M and L Laboratory Services (Pty) Ltd
Registration Number 1974/001476/07 VATNumber 4780103505
P.O. Box 82124
Southdale, 2135
40 Modulus Road
Page 6 of 19
:
:
:
ML2014-3556
8621100
2014-12-08
Ref. No.
Contract No.
Date
Ormonde, 2091
Tel: (011) 661 7900
Fax: (011) 496 2238
0861 467 765
Golden No.Consulting Industrial Chemists, Analysts Samplers
CONFIDENTIAL
Certificate / Report
H04880
ID-4S
H04879
QualityControlResultResult
ID-4D
QualityControlResultResult
H04878
ID-3D
Result
QualityControlResult
Lab Number
Sample Marks
Determinant
DetectionLimit
Quanti-fication
LimitQualityControl
EPA 8270CMethod SVOC in Water by GC/MS Reference
BDL 50 BDL 5050BDL502-Methylnaphthalene(ug/l)
BDL 54 BDL 5454BDL50Hexachlorocyclopentadiene(ug/l)
BDL 52 BDL 5252BDL502,4,6-Trichlorophenol(ug/l)
BDL 50 BDL 5050BDL502,4,5-Trichlorophenol(ug/l)
BDL 50 BDL 5050BDL502-Chloronaphthalene(ug/l)
BDL 49 BDL 4949BDL50o-Nitroaniline(ug/l)
BDL 49 BDL 4949BDL50Dimethylphthalate(ug/l)
BDL 49 BDL 4949BDL50Acenaphthylene(ug/l)
BDL 54 BDL 5454BDL50m-Nitroaniline(ug/l)
BDL 49 BDL 4949BDL50Acenaphthene(ug/l)
BDL 48 BDL 4848BDL50Dibenzofuran(ug/l)
BDL 49 BDL 4949BDL502,4-Dinitrotoluene(ug/l)
BDL 52 BDL 5252BDL50Diethyl Phthalate(ug/l)
BDL 51 BDL 5151BDL50Fluorene(ug/l)
BDL 48 BDL 4848BDL504-Chlorophenyl-phenylether(ug/l)
BDL 53 BDL 5353BDL50p-Nitroaniline(ug/l)
BDL 49 BDL 4949BDL50Azobenzene(ug/l)
BDL 51 BDL 5151BDL504-Bromophenyl-phenylether(ug/l)
BDL 47 BDL 4747BDL50Hexachlorobenzene(ug/l)
BDL - Below Detection Limit
* Denotes test method accredited to ISO17025
These tests do not apply to any other samples of a similar nature.
Refer to terms and conditions www.inspml.co.zaoo This report relates to only test items listed herein and analysis on an as received basis.
This certificate cannot be reproduced except in full without the written consent of M and L Laboratory Services (Pty) Ltd.o
:Printed Date 2014-12-09
M and L Laboratory Services (Pty) Ltd
Registration Number 1974/001476/07 VATNumber 4780103505
P.O. Box 82124
Southdale, 2135
40 Modulus Road
Page 7 of 19
:
:
:
ML2014-3556
8621100
2014-12-08
Ref. No.
Contract No.
Date
Ormonde, 2091
Tel: (011) 661 7900
Fax: (011) 496 2238
0861 467 765
Golden No.Consulting Industrial Chemists, Analysts Samplers
CONFIDENTIAL
Certificate / Report
H04880
ID-4S
H04879
QualityControlResultResult
ID-4D
QualityControlResultResult
H04878
ID-3D
Result
QualityControlResult
Lab Number
Sample Marks
Determinant
DetectionLimit
Quanti-fication
LimitQualityControl
EPA 8270CMethod SVOC in Water by GC/MS Reference
BDL 49 BDL 4949BDL50Phenathrene(ug/l)
BDL 48 BDL 4848BDL50Anthracene(ug/l)
BDL 49 BDL 4949BDL50Carbazole(ug/l)
BDL 51 BDL 5151BDL50Dibutyl phthalate(ug/l)
BDL 48 BDL 4848BDL50Pyrene(ug/l)
BDL 56 BDL 5656BDL50Benzyl Butyl Phthalate(ug/l)
BDL 53 BDL 5353BDL50Benz[a]anthracene(ug/l)
BDL 51 BDL 5151BDL50Chrysene(ug/l)
BDL 52 BDL 5252BDL50Bis(2-ethylhexyl)phthalate(ug/l)
BDL 61 BDL 6161BDL50Di-n-octylphthalate(ug/l)
BDL 47 BDL 4747BDL50Benzo(b)fluoranthene(ug/l)
BDL 52 BDL 5252BDL50Benzo(k)fluoranthene(ug/l)
BDL 53 BDL 5353BDL50Benzo(a)pyrene(ug/l)
Authorised Signature
Manager M&L Lab Services
Joanne Barton
BDL - Below Detection Limit
* Denotes test method accredited to ISO17025
These tests do not apply to any other samples of a similar nature.
Refer to terms and conditions www.inspml.co.zaoo This report relates to only test items listed herein and analysis on an as received basis.
This certificate cannot be reproduced except in full without the written consent of M and L Laboratory Services (Pty) Ltd.o
:Printed Date 2014-12-09
M and L Laboratory Services (Pty) Ltd
Registration Number 1974/001476/07 VATNumber 4780103505
P.O. Box 82124
Southdale, 2135
40 Modulus Road
Page 8 of 19
:
:
:
ML2014-3556
8621100
2014-12-08
Ref. No.
Contract No.
Date
Ormonde, 2091
Tel: (011) 661 7900
Fax: (011) 496 2238
0861 467 765
Golden No.Consulting Industrial Chemists, Analysts Samplers
CONFIDENTIAL
Certificate / Report
H04883
KBH-3D
H04882
QualityControlResultResult
KBH-4S
QualityControlResultResult
H04881
KBH-3S
Result
QualityControlResult
Lab Number
Sample Marks
Determinant
DetectionLimit
Quanti-fication
LimitQualityControl
EPA 8270CMethod SVOC in Water by GC/MS Reference
BDL 50 BDL 5050BDL50Phenol(ug/l)
BDL 55 BDL 5555BDL502-Chlorophenol(ug/l)
BDL 59 BDL 5959BDL50Benzene, 1,3-dichloro-(ug/l)
BDL 55 BDL 5555BDL50Benzene, 1,4-dichloro-(ug/l)
BDL 51 BDL 5151BDL50Benzene, 1,2-dichloro-(ug/l)
BDL 51 BDL 5151BDL502-methylphenol(ug/l)
BDL 51 BDL 5151BDL50Bis(2-chloroisopropyl)ether(ug/l)
BDL 56 BDL 5656BDL504-Methylphenol(ug/l)
BDL 53 BDL 5353BDL50N-Nitrosodi-n-propylamine(ug/l)
BDL 55 BDL 5555BDL50Hexachloroethane(ug/l)
BDL 53 BDL 5353BDL50Nitrobenzene(ug/l)
BDL 52 BDL 5252BDL50Isophorone(ug/l)
BDL 60 BDL 6060BDL502-Nitrophenol(ug/l)
BDL 55 BDL 5555BDL502,4-Dimethylphenol(ug/l)
BDL 56 BDL 5656BDL502,4-Dichlorophenol(ug/l)
BDL 53 BDL 5353BDL50Naphthalene(ug/l)
BDL 53 BDL 5353BDL50p-Chloroaniline(ug/l)
BDL 52 BDL 5252BDL50Hexachlorobutadiene(ug/l)
BDL 55 BDL 5555BDL504-chloro-3-methylphenol(ug/l)
BDL - Below Detection Limit
* Denotes test method accredited to ISO17025
These tests do not apply to any other samples of a similar nature.
Refer to terms and conditions www.inspml.co.zaoo This report relates to only test items listed herein and analysis on an as received basis.
This certificate cannot be reproduced except in full without the written consent of M and L Laboratory Services (Pty) Ltd.o
:Printed Date 2014-12-09
M and L Laboratory Services (Pty) Ltd
Registration Number 1974/001476/07 VATNumber 4780103505
P.O. Box 82124
Southdale, 2135
40 Modulus Road
Page 9 of 19
:
:
:
ML2014-3556
8621100
2014-12-08
Ref. No.
Contract No.
Date
Ormonde, 2091
Tel: (011) 661 7900
Fax: (011) 496 2238
0861 467 765
Golden No.Consulting Industrial Chemists, Analysts Samplers
CONFIDENTIAL
Certificate / Report
H04883
KBH-3D
H04882
QualityControlResultResult
KBH-4S
QualityControlResultResult
H04881
KBH-3S
Result
QualityControlResult
Lab Number
Sample Marks
Determinant
DetectionLimit
Quanti-fication
LimitQualityControl
EPA 8270CMethod SVOC in Water by GC/MS Reference
BDL 50 BDL 5050BDL502-Methylnaphthalene(ug/l)
BDL 54 BDL 5454BDL50Hexachlorocyclopentadiene(ug/l)
BDL 52 BDL 5252BDL502,4,6-Trichlorophenol(ug/l)
BDL 50 BDL 5050BDL502,4,5-Trichlorophenol(ug/l)
BDL 50 BDL 5050BDL502-Chloronaphthalene(ug/l)
BDL 49 BDL 4949BDL50o-Nitroaniline(ug/l)
BDL 49 BDL 4949BDL50Dimethylphthalate(ug/l)
BDL 49 BDL 4949BDL50Acenaphthylene(ug/l)
BDL 54 BDL 5454BDL50m-Nitroaniline(ug/l)
BDL 49 BDL 4949BDL50Acenaphthene(ug/l)
BDL 48 BDL 4848BDL50Dibenzofuran(ug/l)
BDL 49 BDL 4949BDL502,4-Dinitrotoluene(ug/l)
BDL 52 BDL 5252BDL50Diethyl Phthalate(ug/l)
BDL 51 BDL 5151BDL50Fluorene(ug/l)
BDL 48 BDL 4848BDL504-Chlorophenyl-phenylether(ug/l)
BDL 53 BDL 5353BDL50p-Nitroaniline(ug/l)
BDL 49 BDL 4949BDL50Azobenzene(ug/l)
BDL 51 BDL 5151BDL504-Bromophenyl-phenylether(ug/l)
BDL 47 BDL 4747BDL50Hexachlorobenzene(ug/l)
BDL - Below Detection Limit
* Denotes test method accredited to ISO17025
These tests do not apply to any other samples of a similar nature.
Refer to terms and conditions www.inspml.co.zaoo This report relates to only test items listed herein and analysis on an as received basis.
This certificate cannot be reproduced except in full without the written consent of M and L Laboratory Services (Pty) Ltd.o
:Printed Date 2014-12-09
M and L Laboratory Services (Pty) Ltd
Registration Number 1974/001476/07 VATNumber 4780103505
P.O. Box 82124
Southdale, 2135
40 Modulus Road
Page 10 of 19
:
:
:
ML2014-3556
8621100
2014-12-08
Ref. No.
Contract No.
Date
Ormonde, 2091
Tel: (011) 661 7900
Fax: (011) 496 2238
0861 467 765
Golden No.Consulting Industrial Chemists, Analysts Samplers
CONFIDENTIAL
Certificate / Report
H04883
KBH-3D
H04882
QualityControlResultResult
KBH-4S
QualityControlResultResult
H04881
KBH-3S
Result
QualityControlResult
Lab Number
Sample Marks
Determinant
DetectionLimit
Quanti-fication
LimitQualityControl
EPA 8270CMethod SVOC in Water by GC/MS Reference
BDL 49 BDL 4949BDL50Phenathrene(ug/l)
BDL 48 BDL 4848BDL50Anthracene(ug/l)
BDL 49 BDL 4949BDL50Carbazole(ug/l)
BDL 51 BDL 5151BDL50Dibutyl phthalate(ug/l)
BDL 48 BDL 4848BDL50Pyrene(ug/l)
BDL 56 BDL 5656BDL50Benzyl Butyl Phthalate(ug/l)
BDL 53 BDL 5353BDL50Benz[a]anthracene(ug/l)
BDL 51 BDL 5151BDL50Chrysene(ug/l)
BDL 52 84 5252BDL50Bis(2-ethylhexyl)phthalate(ug/l)
BDL 61 BDL 6161BDL50Di-n-octylphthalate(ug/l)
BDL 47 BDL 4747BDL50Benzo(b)fluoranthene(ug/l)
BDL 52 BDL 5252BDL50Benzo(k)fluoranthene(ug/l)
BDL 53 BDL 5353BDL50Benzo(a)pyrene(ug/l)
Authorised Signature
Manager M&L Lab Services
Joanne Barton
BDL - Below Detection Limit
* Denotes test method accredited to ISO17025
These tests do not apply to any other samples of a similar nature.
Refer to terms and conditions www.inspml.co.zaoo This report relates to only test items listed herein and analysis on an as received basis.
This certificate cannot be reproduced except in full without the written consent of M and L Laboratory Services (Pty) Ltd.o
:Printed Date 2014-12-09
M and L Laboratory Services (Pty) Ltd
Registration Number 1974/001476/07 VATNumber 4780103505
P.O. Box 82124
Southdale, 2135
40 Modulus Road
Page 11 of 19
:
:
:
ML2014-3556
8621100
2014-12-08
Ref. No.
Contract No.
Date
Ormonde, 2091
Tel: (011) 661 7900
Fax: (011) 496 2238
0861 467 765
Golden No.Consulting Industrial Chemists, Analysts Samplers
CONFIDENTIAL
Certificate / Report
H04886
KBH-5
H04885
QualityControlResultResult
KBH-6S
QualityControlResultResult
H04884
KBH-4D
Result
QualityControlResult
Lab Number
Sample Marks
Determinant
DetectionLimit
Quanti-fication
LimitQualityControl
EPA 8270CMethod SVOC in Water by GC/MS Reference
BDL 50 BDL 5050BDL50Phenol(ug/l)
BDL 55 BDL 5555BDL502-Chlorophenol(ug/l)
BDL 59 BDL 5959BDL50Benzene, 1,3-dichloro-(ug/l)
BDL 55 BDL 5555BDL50Benzene, 1,4-dichloro-(ug/l)
BDL 51 BDL 5151BDL50Benzene, 1,2-dichloro-(ug/l)
BDL 51 BDL 5151BDL502-methylphenol(ug/l)
BDL 51 BDL 5151BDL50Bis(2-chloroisopropyl)ether(ug/l)
BDL 56 BDL 5656BDL504-Methylphenol(ug/l)
BDL 53 BDL 5353BDL50N-Nitrosodi-n-propylamine(ug/l)
BDL 55 BDL 5555BDL50Hexachloroethane(ug/l)
BDL 53 BDL 5353BDL50Nitrobenzene(ug/l)
BDL 52 BDL 5252BDL50Isophorone(ug/l)
BDL 60 BDL 6060BDL502-Nitrophenol(ug/l)
BDL 55 BDL 5555BDL502,4-Dimethylphenol(ug/l)
BDL 56 BDL 5656BDL502,4-Dichlorophenol(ug/l)
BDL 53 BDL 5353BDL50Naphthalene(ug/l)
BDL 53 BDL 5353BDL50p-Chloroaniline(ug/l)
BDL 52 BDL 5252BDL50Hexachlorobutadiene(ug/l)
BDL 55 BDL 5555BDL504-chloro-3-methylphenol(ug/l)
BDL - Below Detection Limit
* Denotes test method accredited to ISO17025
These tests do not apply to any other samples of a similar nature.
Refer to terms and conditions www.inspml.co.zaoo This report relates to only test items listed herein and analysis on an as received basis.
This certificate cannot be reproduced except in full without the written consent of M and L Laboratory Services (Pty) Ltd.o
:Printed Date 2014-12-09
M and L Laboratory Services (Pty) Ltd
Registration Number 1974/001476/07 VATNumber 4780103505
P.O. Box 82124
Southdale, 2135
40 Modulus Road
Page 12 of 19
:
:
:
ML2014-3556
8621100
2014-12-08
Ref. No.
Contract No.
Date
Ormonde, 2091
Tel: (011) 661 7900
Fax: (011) 496 2238
0861 467 765
Golden No.Consulting Industrial Chemists, Analysts Samplers
CONFIDENTIAL
Certificate / Report
H04886
KBH-5
H04885
QualityControlResultResult
KBH-6S
QualityControlResultResult
H04884
KBH-4D
Result
QualityControlResult
Lab Number
Sample Marks
Determinant
DetectionLimit
Quanti-fication
LimitQualityControl
EPA 8270CMethod SVOC in Water by GC/MS Reference
BDL 50 BDL 5050BDL502-Methylnaphthalene(ug/l)
BDL 54 BDL 5454BDL50Hexachlorocyclopentadiene(ug/l)
BDL 52 BDL 5252BDL502,4,6-Trichlorophenol(ug/l)
BDL 50 BDL 5050BDL502,4,5-Trichlorophenol(ug/l)
BDL 50 BDL 5050BDL502-Chloronaphthalene(ug/l)
BDL 49 BDL 4949BDL50o-Nitroaniline(ug/l)
BDL 49 BDL 4949BDL50Dimethylphthalate(ug/l)
BDL 49 BDL 4949BDL50Acenaphthylene(ug/l)
BDL 54 BDL 5454BDL50m-Nitroaniline(ug/l)
BDL 49 BDL 4949BDL50Acenaphthene(ug/l)
BDL 48 BDL 4848BDL50Dibenzofuran(ug/l)
BDL 49 BDL 4949BDL502,4-Dinitrotoluene(ug/l)
BDL 52 BDL 5252BDL50Diethyl Phthalate(ug/l)
BDL 51 BDL 5151BDL50Fluorene(ug/l)
BDL 48 BDL 4848BDL504-Chlorophenyl-phenylether(ug/l)
BDL 53 BDL 5353BDL50p-Nitroaniline(ug/l)
BDL 49 BDL 4949BDL50Azobenzene(ug/l)
BDL 51 BDL 5151BDL504-Bromophenyl-phenylether(ug/l)
BDL 47 BDL 4747BDL50Hexachlorobenzene(ug/l)
BDL - Below Detection Limit
* Denotes test method accredited to ISO17025
These tests do not apply to any other samples of a similar nature.
Refer to terms and conditions www.inspml.co.zaoo This report relates to only test items listed herein and analysis on an as received basis.
This certificate cannot be reproduced except in full without the written consent of M and L Laboratory Services (Pty) Ltd.o
:Printed Date 2014-12-09
M and L Laboratory Services (Pty) Ltd
Registration Number 1974/001476/07 VATNumber 4780103505
P.O. Box 82124
Southdale, 2135
40 Modulus Road
Page 13 of 19
:
:
:
ML2014-3556
8621100
2014-12-08
Ref. No.
Contract No.
Date
Ormonde, 2091
Tel: (011) 661 7900
Fax: (011) 496 2238
0861 467 765
Golden No.Consulting Industrial Chemists, Analysts Samplers
CONFIDENTIAL
Certificate / Report
H04886
KBH-5
H04885
QualityControlResultResult
KBH-6S
QualityControlResultResult
H04884
KBH-4D
Result
QualityControlResult
Lab Number
Sample Marks
Determinant
DetectionLimit
Quanti-fication
LimitQualityControl
EPA 8270CMethod SVOC in Water by GC/MS Reference
BDL 49 BDL 4949BDL50Phenathrene(ug/l)
BDL 48 BDL 4848BDL50Anthracene(ug/l)
BDL 49 BDL 4949BDL50Carbazole(ug/l)
BDL 51 BDL 5151BDL50Dibutyl phthalate(ug/l)
BDL 48 BDL 4848BDL50Pyrene(ug/l)
BDL 56 BDL 5656BDL50Benzyl Butyl Phthalate(ug/l)
BDL 53 BDL 5353BDL50Benz[a]anthracene(ug/l)
BDL 51 BDL 5151BDL50Chrysene(ug/l)
BDL 52 BDL 5252BDL50Bis(2-ethylhexyl)phthalate(ug/l)
BDL 61 BDL 6161BDL50Di-n-octylphthalate(ug/l)
BDL 47 BDL 4747BDL50Benzo(b)fluoranthene(ug/l)
BDL 52 BDL 5252BDL50Benzo(k)fluoranthene(ug/l)
BDL 53 BDL 5353BDL50Benzo(a)pyrene(ug/l)
Authorised Signature
Manager M&L Lab Services
Joanne Barton
BDL - Below Detection Limit
* Denotes test method accredited to ISO17025
These tests do not apply to any other samples of a similar nature.
Refer to terms and conditions www.inspml.co.zaoo This report relates to only test items listed herein and analysis on an as received basis.
This certificate cannot be reproduced except in full without the written consent of M and L Laboratory Services (Pty) Ltd.o
:Printed Date 2014-12-09
M and L Laboratory Services (Pty) Ltd
Registration Number 1974/001476/07 VATNumber 4780103505
P.O. Box 82124
Southdale, 2135
40 Modulus Road
Page 14 of 19
:
:
:
ML2014-3556
8621100
2014-12-08
Ref. No.
Contract No.
Date
Ormonde, 2091
Tel: (011) 661 7900
Fax: (011) 496 2238
0861 467 765
Golden No.Consulting Industrial Chemists, Analysts Samplers
CONFIDENTIAL
Certificate / Report
H04889
KBH7D
H04888
QualityControlResultResult
KBH-10D
QualityControlResultResult
H04887
KBH-6D
Result
QualityControlResult
Lab Number
Sample Marks
Determinant
DetectionLimit
Quanti-fication
LimitQualityControl
EPA 8270CMethod SVOC in Water by GC/MS Reference
BDL 50 BDL 5050BDL50Phenol(ug/l)
BDL 55 BDL 5555BDL502-Chlorophenol(ug/l)
BDL 59 BDL 5959BDL50Benzene, 1,3-dichloro-(ug/l)
BDL 55 BDL 5555BDL50Benzene, 1,4-dichloro-(ug/l)
BDL 51 BDL 5151BDL50Benzene, 1,2-dichloro-(ug/l)
BDL 51 BDL 5151BDL502-methylphenol(ug/l)
BDL 51 BDL 5151BDL50Bis(2-chloroisopropyl)ether(ug/l)
BDL 56 BDL 5656BDL504-Methylphenol(ug/l)
BDL 53 BDL 5353BDL50N-Nitrosodi-n-propylamine(ug/l)
BDL 55 BDL 5555BDL50Hexachloroethane(ug/l)
BDL 53 BDL 5353BDL50Nitrobenzene(ug/l)
BDL 52 BDL 5252BDL50Isophorone(ug/l)
BDL 60 BDL 6060BDL502-Nitrophenol(ug/l)
BDL 55 BDL 5555BDL502,4-Dimethylphenol(ug/l)
BDL 56 BDL 5656BDL502,4-Dichlorophenol(ug/l)
BDL 53 BDL 5353BDL50Naphthalene(ug/l)
BDL 53 BDL 5353BDL50p-Chloroaniline(ug/l)
BDL 52 BDL 5252BDL50Hexachlorobutadiene(ug/l)
BDL 55 BDL 5555BDL504-chloro-3-methylphenol(ug/l)
BDL - Below Detection Limit
* Denotes test method accredited to ISO17025
These tests do not apply to any other samples of a similar nature.
Refer to terms and conditions www.inspml.co.zaoo This report relates to only test items listed herein and analysis on an as received basis.
This certificate cannot be reproduced except in full without the written consent of M and L Laboratory Services (Pty) Ltd.o
:Printed Date 2014-12-09
M and L Laboratory Services (Pty) Ltd
Registration Number 1974/001476/07 VATNumber 4780103505
P.O. Box 82124
Southdale, 2135
40 Modulus Road
Page 15 of 19
:
:
:
ML2014-3556
8621100
2014-12-08
Ref. No.
Contract No.
Date
Ormonde, 2091
Tel: (011) 661 7900
Fax: (011) 496 2238
0861 467 765
Golden No.Consulting Industrial Chemists, Analysts Samplers
CONFIDENTIAL
Certificate / Report
H04889
KBH7D
H04888
QualityControlResultResult
KBH-10D
QualityControlResultResult
H04887
KBH-6D
Result
QualityControlResult
Lab Number
Sample Marks
Determinant
DetectionLimit
Quanti-fication
LimitQualityControl
EPA 8270CMethod SVOC in Water by GC/MS Reference
BDL 50 BDL 5050BDL502-Methylnaphthalene(ug/l)
BDL 54 BDL 5454BDL50Hexachlorocyclopentadiene(ug/l)
BDL 52 BDL 5252BDL502,4,6-Trichlorophenol(ug/l)
BDL 50 BDL 5050BDL502,4,5-Trichlorophenol(ug/l)
BDL 50 BDL 5050BDL502-Chloronaphthalene(ug/l)
BDL 49 BDL 4949BDL50o-Nitroaniline(ug/l)
BDL 49 BDL 4949BDL50Dimethylphthalate(ug/l)
BDL 49 BDL 4949BDL50Acenaphthylene(ug/l)
BDL 54 BDL 5454BDL50m-Nitroaniline(ug/l)
BDL 49 BDL 4949BDL50Acenaphthene(ug/l)
BDL 48 BDL 4848BDL50Dibenzofuran(ug/l)
BDL 49 BDL 4949BDL502,4-Dinitrotoluene(ug/l)
BDL 52 BDL 5252BDL50Diethyl Phthalate(ug/l)
BDL 51 BDL 5151BDL50Fluorene(ug/l)
BDL 48 BDL 4848BDL504-Chlorophenyl-phenylether(ug/l)
BDL 53 BDL 5353BDL50p-Nitroaniline(ug/l)
BDL 49 BDL 4949BDL50Azobenzene(ug/l)
BDL 51 BDL 5151BDL504-Bromophenyl-phenylether(ug/l)
BDL 47 BDL 4747BDL50Hexachlorobenzene(ug/l)
BDL - Below Detection Limit
* Denotes test method accredited to ISO17025
These tests do not apply to any other samples of a similar nature.
Refer to terms and conditions www.inspml.co.zaoo This report relates to only test items listed herein and analysis on an as received basis.
This certificate cannot be reproduced except in full without the written consent of M and L Laboratory Services (Pty) Ltd.o
:Printed Date 2014-12-09
M and L Laboratory Services (Pty) Ltd
Registration Number 1974/001476/07 VATNumber 4780103505
P.O. Box 82124
Southdale, 2135
40 Modulus Road
Page 16 of 19
:
:
:
ML2014-3556
8621100
2014-12-08
Ref. No.
Contract No.
Date
Ormonde, 2091
Tel: (011) 661 7900
Fax: (011) 496 2238
0861 467 765
Golden No.Consulting Industrial Chemists, Analysts Samplers
CONFIDENTIAL
Certificate / Report
H04889
KBH7D
H04888
QualityControlResultResult
KBH-10D
QualityControlResultResult
H04887
KBH-6D
Result
QualityControlResult
Lab Number
Sample Marks
Determinant
DetectionLimit
Quanti-fication
LimitQualityControl
EPA 8270CMethod SVOC in Water by GC/MS Reference
BDL 49 BDL 4949BDL50Phenathrene(ug/l)
BDL 48 BDL 4848BDL50Anthracene(ug/l)
BDL 49 BDL 4949BDL50Carbazole(ug/l)
BDL 51 BDL 5151BDL50Dibutyl phthalate(ug/l)
BDL 48 BDL 4848BDL50Pyrene(ug/l)
BDL 56 BDL 5656BDL50Benzyl Butyl Phthalate(ug/l)
BDL 53 BDL 5353BDL50Benz[a]anthracene(ug/l)
BDL 51 BDL 5151BDL50Chrysene(ug/l)
BDL 52 BDL 5252BDL50Bis(2-ethylhexyl)phthalate(ug/l)
BDL 61 BDL 6161BDL50Di-n-octylphthalate(ug/l)
BDL 47 BDL 4747BDL50Benzo(b)fluoranthene(ug/l)
BDL 52 BDL 5252BDL50Benzo(k)fluoranthene(ug/l)
BDL 53 BDL 5353BDL50Benzo(a)pyrene(ug/l)
Authorised Signature
Manager M&L Lab Services
Joanne Barton
BDL - Below Detection Limit
* Denotes test method accredited to ISO17025
These tests do not apply to any other samples of a similar nature.
Refer to terms and conditions www.inspml.co.zaoo This report relates to only test items listed herein and analysis on an as received basis.
This certificate cannot be reproduced except in full without the written consent of M and L Laboratory Services (Pty) Ltd.o
:Printed Date 2014-12-09
M and L Laboratory Services (Pty) Ltd
Registration Number 1974/001476/07 VATNumber 4780103505
P.O. Box 82124
Southdale, 2135
40 Modulus Road
Page 17 of 19
:
:
:
ML2014-3556
8621100
2014-12-08
Ref. No.
Contract No.
Date
Ormonde, 2091
Tel: (011) 661 7900
Fax: (011) 496 2238
0861 467 765
Golden No.Consulting Industrial Chemists, Analysts Samplers
CONFIDENTIAL
Certificate / Report
QualityControlResultResult
QualityControlResultResult
H04890
KBH-
Result
QualityControlResult
Lab Number
Sample Marks
Determinant
DetectionLimit
Quanti-fication
LimitQualityControl
EPA 8270CMethod SVOC in Water by GC/MS Reference
50BDL50Phenol(ug/l)
55BDL502-Chlorophenol(ug/l)
59BDL50Benzene, 1,3-dichloro-(ug/l)
55BDL50Benzene, 1,4-dichloro-(ug/l)
51BDL50Benzene, 1,2-dichloro-(ug/l)
51BDL502-methylphenol(ug/l)
51BDL50Bis(2-chloroisopropyl)ether(ug/l)
56BDL504-Methylphenol(ug/l)
53BDL50N-Nitrosodi-n-propylamine(ug/l)
55BDL50Hexachloroethane(ug/l)
53BDL50Nitrobenzene(ug/l)
52BDL50Isophorone(ug/l)
60BDL502-Nitrophenol(ug/l)
55BDL502,4-Dimethylphenol(ug/l)
56BDL502,4-Dichlorophenol(ug/l)
53BDL50Naphthalene(ug/l)
53BDL50p-Chloroaniline(ug/l)
52BDL50Hexachlorobutadiene(ug/l)
55BDL504-chloro-3-methylphenol(ug/l)
BDL - Below Detection Limit
* Denotes test method accredited to ISO17025
These tests do not apply to any other samples of a similar nature.
Refer to terms and conditions www.inspml.co.zaoo This report relates to only test items listed herein and analysis on an as received basis.
This certificate cannot be reproduced except in full without the written consent of M and L Laboratory Services (Pty) Ltd.o
:Printed Date 2014-12-09
M and L Laboratory Services (Pty) Ltd
Registration Number 1974/001476/07 VATNumber 4780103505
P.O. Box 82124
Southdale, 2135
40 Modulus Road
Page 18 of 19
:
:
:
ML2014-3556
8621100
2014-12-08
Ref. No.
Contract No.
Date
Ormonde, 2091
Tel: (011) 661 7900
Fax: (011) 496 2238
0861 467 765
Golden No.Consulting Industrial Chemists, Analysts Samplers
CONFIDENTIAL
Certificate / Report
QualityControlResultResult
QualityControlResultResult
H04890
KBH-
Result
QualityControlResult
Lab Number
Sample Marks
Determinant
DetectionLimit
Quanti-fication
LimitQualityControl
EPA 8270CMethod SVOC in Water by GC/MS Reference
50BDL502-Methylnaphthalene(ug/l)
54BDL50Hexachlorocyclopentadiene(ug/l)
52BDL502,4,6-Trichlorophenol(ug/l)
50BDL502,4,5-Trichlorophenol(ug/l)
50BDL502-Chloronaphthalene(ug/l)
49BDL50o-Nitroaniline(ug/l)
49BDL50Dimethylphthalate(ug/l)
49BDL50Acenaphthylene(ug/l)
54BDL50m-Nitroaniline(ug/l)
49BDL50Acenaphthene(ug/l)
48BDL50Dibenzofuran(ug/l)
49BDL502,4-Dinitrotoluene(ug/l)
52BDL50Diethyl Phthalate(ug/l)
51BDL50Fluorene(ug/l)
48BDL504-Chlorophenyl-phenylether(ug/l)
53BDL50p-Nitroaniline(ug/l)
49BDL50Azobenzene(ug/l)
51BDL504-Bromophenyl-phenylether(ug/l)
47BDL50Hexachlorobenzene(ug/l)
BDL - Below Detection Limit
* Denotes test method accredited to ISO17025
These tests do not apply to any other samples of a similar nature.
Refer to terms and conditions www.inspml.co.zaoo This report relates to only test items listed herein and analysis on an as received basis.
This certificate cannot be reproduced except in full without the written consent of M and L Laboratory Services (Pty) Ltd.o
:Printed Date 2014-12-09
M and L Laboratory Services (Pty) Ltd
Registration Number 1974/001476/07 VATNumber 4780103505
P.O. Box 82124
Southdale, 2135
40 Modulus Road
Page 19 of 19
:
:
:
ML2014-3556
8621100
2014-12-08
Ref. No.
Contract No.
Date
Ormonde, 2091
Tel: (011) 661 7900
Fax: (011) 496 2238
0861 467 765
Golden No.Consulting Industrial Chemists, Analysts Samplers
CONFIDENTIAL
Certificate / Report
QualityControlResultResult
QualityControlResultResult
H04890
KBH-
Result
QualityControlResult
Lab Number
Sample Marks
Determinant
DetectionLimit
Quanti-fication
LimitQualityControl
EPA 8270CMethod SVOC in Water by GC/MS Reference
49BDL50Phenathrene(ug/l)
48BDL50Anthracene(ug/l)
49BDL50Carbazole(ug/l)
51BDL50Dibutyl phthalate(ug/l)
48BDL50Pyrene(ug/l)
56BDL50Benzyl Butyl Phthalate(ug/l)
53BDL50Benz[a]anthracene(ug/l)
51BDL50Chrysene(ug/l)
52BDL50Bis(2-ethylhexyl)phthalate(ug/l)
61BDL50Di-n-octylphthalate(ug/l)
47BDL50Benzo(b)fluoranthene(ug/l)
52BDL50Benzo(k)fluoranthene(ug/l)
53BDL50Benzo(a)pyrene(ug/l)
Authorised Signature
Manager M&L Lab Services
Joanne Barton
BDL - Below Detection Limit
* Denotes test method accredited to ISO17025
These tests do not apply to any other samples of a similar nature.
Refer to terms and conditions www.inspml.co.zaoo This report relates to only test items listed herein and analysis on an as received basis.
This certificate cannot be reproduced except in full without the written consent of M and L Laboratory Services (Pty) Ltd.o
:Printed Date 2014-12-09
ArcelorMittal Vanderbijlpark
External audit report on the WML for Klip waste site at AMSA Vereeniging
44 Report: 192-ZANAMVE-2015 Zantow Environmental Consulting Services
ANNEXURE B4
Ground water monitoring results – organics (March 2015)
M and L Laboratory Services (Pty) Ltd
Registration Number 1974/001476/07 VATNumber 4780103505
P.O. Box 82124
Southdale, 2135
40 Modulus Road
Page 1 of 16
:
:
:
ML2015-0981
8677215
2015-04-08
Ref. No.
Contract No.
Date
Ormonde, 2091
Tel: (011) 661 7900
Fax: (011) 496 2238
0861 467 765
Golden No.Consulting Industrial Chemists, Analysts Samplers
CONFIDENTIAL
Certificate / Report
COMPANY NAME : ARCELORMITTAL SOUTH AFRICA
ADDRESS : P O BOX 2 VANDERBIJLPARK 1900
SUBJECT : ANALYSIS OF 8 WATER SAMPLES
PROJECT REFERENCE : 8 BOREHOLES SAMPLES
:INSTRUCTED BY J. Mnisi
:ORDER NUMBER
:RECEIVED ON 2015-03-10
:ANALYSIS COMPLETED 2015-04-08
BDL - Below Detection Limit
* Denotes test method accredited to ISO17025
These tests do not apply to any other samples of a similar nature.
Refer to terms and conditions www.inspml.co.zaoo This report relates to only test items listed herein and analysis on an as received basis.
This certificate cannot be reproduced except in full without the written consent of M and L Laboratory Services (Pty) Ltd.o
:Printed Date 2015-04-08
M and L Laboratory Services (Pty) Ltd
Registration Number 1974/001476/07 VATNumber 4780103505
P.O. Box 82124
Southdale, 2135
40 Modulus Road
Page 2 of 16
:
:
:
ML2015-0981
8677215
2015-04-08
Ref. No.
Contract No.
Date
Ormonde, 2091
Tel: (011) 661 7900
Fax: (011) 496 2238
0861 467 765
Golden No.Consulting Industrial Chemists, Analysts Samplers
CONFIDENTIAL
Certificate / Report
H06094
KBH-3S
H06093
QualityControlResultResult
KBH-3D
QualityControlResultResult
H06092
KBH-2
Result
QualityControlResult
Lab Number
Sample Marks
Determinant
DetectionLimit
Quanti-fication
LimitQualityControl
EPA 8270CMethod SVOC in Water by GC/MS Reference
BDL 55 BDL 5555BDL50Phenol(ug/l)
BDL 45 BDL 4545BDL502-Chlorophenol(ug/l)
BDL 39 BDL 3939BDL50Benzene, 1,3-dichloro-(ug/l)
BDL 40 BDL 4040BDL50Benzene, 1,4-dichloro-(ug/l)
BDL 42 BDL 4242BDL50Benzene, 1,2-dichloro-(ug/l)
BDL 43 BDL 4343BDL502-methylphenol(ug/l)
BDL 42 BDL 4242BDL50Bis(2-chloroisopropyl)ether(ug/l)
BDL 41 BDL 4141BDL504-Methylphenol(ug/l)
BDL 42 BDL 4242BDL50N-Nitrosodi-n-propylamine(ug/l)
BDL 40 BDL 4040BDL50Hexachloroethane(ug/l)
BDL 41 BDL 4141BDL50Nitrobenzene(ug/l)
BDL 41 BDL 4141BDL50Isophorone(ug/l)
BDL 42 BDL 4242BDL502-Nitrophenol(ug/l)
BDL 42 BDL 4242BDL502,4-Dimethylphenol(ug/l)
BDL 41 BDL 4141BDL502,4-Dichlorophenol(ug/l)
BDL 41 BDL 4141BDL50Naphthalene(ug/l)
BDL 43 BDL 4343BDL50p-Chloroaniline(ug/l)
BDL - Below Detection Limit
* Denotes test method accredited to ISO17025
These tests do not apply to any other samples of a similar nature.
Refer to terms and conditions www.inspml.co.zaoo This report relates to only test items listed herein and analysis on an as received basis.
This certificate cannot be reproduced except in full without the written consent of M and L Laboratory Services (Pty) Ltd.o
:Printed Date 2015-04-08
M and L Laboratory Services (Pty) Ltd
Registration Number 1974/001476/07 VATNumber 4780103505
P.O. Box 82124
Southdale, 2135
40 Modulus Road
Page 3 of 16
:
:
:
ML2015-0981
8677215
2015-04-08
Ref. No.
Contract No.
Date
Ormonde, 2091
Tel: (011) 661 7900
Fax: (011) 496 2238
0861 467 765
Golden No.Consulting Industrial Chemists, Analysts Samplers
CONFIDENTIAL
Certificate / Report
H06094
KBH-3S
H06093
QualityControlResultResult
KBH-3D
QualityControlResultResult
H06092
KBH-2
Result
QualityControlResult
Lab Number
Sample Marks
Determinant
DetectionLimit
Quanti-fication
LimitQualityControl
EPA 8270CMethod SVOC in Water by GC/MS Reference
BDL 42 BDL 4242BDL50Hexachlorobutadiene(ug/l)
BDL 43 BDL 4343BDL504-chloro-3-methylphenol(ug/l)
BDL 42 BDL 4242BDL502-Methylnaphthalene(ug/l)
BDL 37 BDL 3737BDL50Hexachlorocyclopentadiene(ug/l)
BDL 43 BDL 4343BDL502,4,6-Trichlorophenol(ug/l)
BDL 43 BDL 4343BDL502,4,5-Trichlorophenol(ug/l)
BDL 42 BDL 4242BDL502-Chloronaphthalene(ug/l)
BDL 44 BDL 4444BDL50o-Nitroaniline(ug/l)
BDL 42 BDL 4242BDL50Dimethylphthalate(ug/l)
BDL 40 BDL 4040BDL50Acenaphthylene(ug/l)
BDL 43 BDL 4343BDL50m-Nitroaniline(ug/l)
BDL 40 BDL 4040BDL50Acenaphthene(ug/l)
BDL 41 BDL 4141BDL50Dibenzofuran(ug/l)
BDL 42 BDL 4242BDL502,4-Dinitrotoluene(ug/l)
BDL 44 BDL 4444BDL50Diethyl Phthalate(ug/l)
BDL 42 BDL 4242BDL50Fluorene(ug/l)
BDL 40 BDL 4040BDL504-Chlorophenyl-phenylether(ug/l)
BDL - Below Detection Limit
* Denotes test method accredited to ISO17025
These tests do not apply to any other samples of a similar nature.
Refer to terms and conditions www.inspml.co.zaoo This report relates to only test items listed herein and analysis on an as received basis.
This certificate cannot be reproduced except in full without the written consent of M and L Laboratory Services (Pty) Ltd.o
:Printed Date 2015-04-08
M and L Laboratory Services (Pty) Ltd
Registration Number 1974/001476/07 VATNumber 4780103505
P.O. Box 82124
Southdale, 2135
40 Modulus Road
Page 4 of 16
:
:
:
ML2015-0981
8677215
2015-04-08
Ref. No.
Contract No.
Date
Ormonde, 2091
Tel: (011) 661 7900
Fax: (011) 496 2238
0861 467 765
Golden No.Consulting Industrial Chemists, Analysts Samplers
CONFIDENTIAL
Certificate / Report
H06094
KBH-3S
H06093
QualityControlResultResult
KBH-3D
QualityControlResultResult
H06092
KBH-2
Result
QualityControlResult
Lab Number
Sample Marks
Determinant
DetectionLimit
Quanti-fication
LimitQualityControl
EPA 8270CMethod SVOC in Water by GC/MS Reference
BDL 46 BDL 4646BDL50p-Nitroaniline(ug/l)
BDL 43 BDL 4343BDL50Azobenzene(ug/l)
BDL 40 BDL 4040BDL504-Bromophenyl-phenylether(ug/l)
BDL 42 BDL 4242BDL50Hexachlorobenzene(ug/l)
BDL 42 BDL 4242BDL50Phenathrene(ug/l)
BDL 41 BDL 4141BDL50Anthracene(ug/l)
BDL 43 BDL 4343BDL50Carbazole(ug/l)
BDL 46 BDL 4646BDL50Dibutyl phthalate(ug/l)
BDL 45 BDL 4545BDL50Pyrene(ug/l)
BDL 49 BDL 4949BDL50Benzyl Butyl Phthalate(ug/l)
BDL 55 BDL 5555BDL50Benz[a]anthracene(ug/l)
BDL 52 BDL 5252BDL50Chrysene(ug/l)
108 51 110 515111050Bis(2-ethylhexyl)phthalate(ug/l)
BDL 56 BDL 5656BDL50Di-n-octylphthalate(ug/l)
BDL 38 BDL 3838BDL50Benzo(b)fluoranthene(ug/l)
BDL 38 BDL 3838BDL50Benzo(k)fluoranthene(ug/l)
BDL - Below Detection Limit
* Denotes test method accredited to ISO17025
These tests do not apply to any other samples of a similar nature.
Refer to terms and conditions www.inspml.co.zaoo This report relates to only test items listed herein and analysis on an as received basis.
This certificate cannot be reproduced except in full without the written consent of M and L Laboratory Services (Pty) Ltd.o
:Printed Date 2015-04-08
M and L Laboratory Services (Pty) Ltd
Registration Number 1974/001476/07 VATNumber 4780103505
P.O. Box 82124
Southdale, 2135
40 Modulus Road
Page 5 of 16
:
:
:
ML2015-0981
8677215
2015-04-08
Ref. No.
Contract No.
Date
Ormonde, 2091
Tel: (011) 661 7900
Fax: (011) 496 2238
0861 467 765
Golden No.Consulting Industrial Chemists, Analysts Samplers
CONFIDENTIAL
Certificate / Report
H06094
KBH-3S
H06093
QualityControlResultResult
KBH-3D
QualityControlResultResult
H06092
KBH-2
Result
QualityControlResult
Lab Number
Sample Marks
Determinant
DetectionLimit
Quanti-fication
LimitQualityControl
EPA 8270CMethod SVOC in Water by GC/MS Reference
BDL 47 BDL 4747BDL50Benzo(a)pyrene(ug/l)
Authorised Signature
Manager M&L Lab Services
Joanne Barton
BDL - Below Detection Limit
* Denotes test method accredited to ISO17025
These tests do not apply to any other samples of a similar nature.
Refer to terms and conditions www.inspml.co.zaoo This report relates to only test items listed herein and analysis on an as received basis.
This certificate cannot be reproduced except in full without the written consent of M and L Laboratory Services (Pty) Ltd.o
:Printed Date 2015-04-08
M and L Laboratory Services (Pty) Ltd
Registration Number 1974/001476/07 VATNumber 4780103505
P.O. Box 82124
Southdale, 2135
40 Modulus Road
Page 6 of 16
:
:
:
ML2015-0981
8677215
2015-04-08
Ref. No.
Contract No.
Date
Ormonde, 2091
Tel: (011) 661 7900
Fax: (011) 496 2238
0861 467 765
Golden No.Consulting Industrial Chemists, Analysts Samplers
CONFIDENTIAL
Certificate / Report
H06094
KBH-3S
H06093
QualityControlResultResult
KBH-3D
QualityControlResultResult
H06092
KBH-2
Result
QualityControlResult
Lab Number
Sample Marks
Determinant
DetectionLimit
Quanti-fication
LimitQualityControl
Method Total Organic Carbon by Calculation as (C) Reference
73 1932Total Organic Carbon as C(mg/l)
Authorised Signature
Supervisor
Edward Khumalo
BDL - Below Detection Limit
* Denotes test method accredited to ISO17025
These tests do not apply to any other samples of a similar nature.
Refer to terms and conditions www.inspml.co.zaoo This report relates to only test items listed herein and analysis on an as received basis.
This certificate cannot be reproduced except in full without the written consent of M and L Laboratory Services (Pty) Ltd.o
:Printed Date 2015-04-08
M and L Laboratory Services (Pty) Ltd
Registration Number 1974/001476/07 VATNumber 4780103505
P.O. Box 82124
Southdale, 2135
40 Modulus Road
Page 7 of 16
:
:
:
ML2015-0981
8677215
2015-04-08
Ref. No.
Contract No.
Date
Ormonde, 2091
Tel: (011) 661 7900
Fax: (011) 496 2238
0861 467 765
Golden No.Consulting Industrial Chemists, Analysts Samplers
CONFIDENTIAL
Certificate / Report
H06097
KBH-4S
H06096
QualityControlResultResult
KBH-6D
QualityControlResultResult
H06095
KBH-4D
Result
QualityControlResult
Lab Number
Sample Marks
Determinant
DetectionLimit
Quanti-fication
LimitQualityControl
EPA 8270CMethod SVOC in Water by GC/MS Reference
BDL 55 BDL 5555BDL50Phenol(ug/l)
BDL 45 BDL 4545BDL502-Chlorophenol(ug/l)
BDL 39 BDL 3939BDL50Benzene, 1,3-dichloro-(ug/l)
BDL 40 BDL 4040BDL50Benzene, 1,4-dichloro-(ug/l)
BDL 42 BDL 4242BDL50Benzene, 1,2-dichloro-(ug/l)
BDL 43 BDL 4343BDL502-methylphenol(ug/l)
BDL 42 BDL 4242BDL50Bis(2-chloroisopropyl)ether(ug/l)
BDL 41 BDL 4141BDL504-Methylphenol(ug/l)
BDL 42 BDL 4242BDL50N-Nitrosodi-n-propylamine(ug/l)
BDL 40 BDL 4040BDL50Hexachloroethane(ug/l)
BDL 41 BDL 4141BDL50Nitrobenzene(ug/l)
BDL 41 BDL 4141BDL50Isophorone(ug/l)
BDL 42 BDL 4242BDL502-Nitrophenol(ug/l)
BDL 42 BDL 4242BDL502,4-Dimethylphenol(ug/l)
BDL 41 BDL 4141BDL502,4-Dichlorophenol(ug/l)
BDL 41 BDL 4141BDL50Naphthalene(ug/l)
BDL 43 BDL 4343BDL50p-Chloroaniline(ug/l)
BDL - Below Detection Limit
* Denotes test method accredited to ISO17025
These tests do not apply to any other samples of a similar nature.
Refer to terms and conditions www.inspml.co.zaoo This report relates to only test items listed herein and analysis on an as received basis.
This certificate cannot be reproduced except in full without the written consent of M and L Laboratory Services (Pty) Ltd.o
:Printed Date 2015-04-08
M and L Laboratory Services (Pty) Ltd
Registration Number 1974/001476/07 VATNumber 4780103505
P.O. Box 82124
Southdale, 2135
40 Modulus Road
Page 8 of 16
:
:
:
ML2015-0981
8677215
2015-04-08
Ref. No.
Contract No.
Date
Ormonde, 2091
Tel: (011) 661 7900
Fax: (011) 496 2238
0861 467 765
Golden No.Consulting Industrial Chemists, Analysts Samplers
CONFIDENTIAL
Certificate / Report
H06097
KBH-4S
H06096
QualityControlResultResult
KBH-6D
QualityControlResultResult
H06095
KBH-4D
Result
QualityControlResult
Lab Number
Sample Marks
Determinant
DetectionLimit
Quanti-fication
LimitQualityControl
EPA 8270CMethod SVOC in Water by GC/MS Reference
BDL 42 BDL 4242BDL50Hexachlorobutadiene(ug/l)
BDL 43 BDL 4343BDL504-chloro-3-methylphenol(ug/l)
BDL 42 BDL 4242BDL502-Methylnaphthalene(ug/l)
BDL 37 BDL 3737BDL50Hexachlorocyclopentadiene(ug/l)
BDL 43 BDL 4343BDL502,4,6-Trichlorophenol(ug/l)
BDL 43 BDL 4343BDL502,4,5-Trichlorophenol(ug/l)
BDL 42 BDL 4242BDL502-Chloronaphthalene(ug/l)
BDL 44 BDL 4444BDL50o-Nitroaniline(ug/l)
BDL 42 BDL 4242BDL50Dimethylphthalate(ug/l)
BDL 40 BDL 4040BDL50Acenaphthylene(ug/l)
BDL 43 BDL 4343BDL50m-Nitroaniline(ug/l)
BDL 40 BDL 4040BDL50Acenaphthene(ug/l)
BDL 41 BDL 4141BDL50Dibenzofuran(ug/l)
BDL 42 BDL 4242BDL502,4-Dinitrotoluene(ug/l)
BDL 44 BDL 4444BDL50Diethyl Phthalate(ug/l)
BDL 42 BDL 4242BDL50Fluorene(ug/l)
BDL 40 BDL 4040BDL504-Chlorophenyl-phenylether(ug/l)
BDL - Below Detection Limit
* Denotes test method accredited to ISO17025
These tests do not apply to any other samples of a similar nature.
Refer to terms and conditions www.inspml.co.zaoo This report relates to only test items listed herein and analysis on an as received basis.
This certificate cannot be reproduced except in full without the written consent of M and L Laboratory Services (Pty) Ltd.o
:Printed Date 2015-04-08
M and L Laboratory Services (Pty) Ltd
Registration Number 1974/001476/07 VATNumber 4780103505
P.O. Box 82124
Southdale, 2135
40 Modulus Road
Page 9 of 16
:
:
:
ML2015-0981
8677215
2015-04-08
Ref. No.
Contract No.
Date
Ormonde, 2091
Tel: (011) 661 7900
Fax: (011) 496 2238
0861 467 765
Golden No.Consulting Industrial Chemists, Analysts Samplers
CONFIDENTIAL
Certificate / Report
H06097
KBH-4S
H06096
QualityControlResultResult
KBH-6D
QualityControlResultResult
H06095
KBH-4D
Result
QualityControlResult
Lab Number
Sample Marks
Determinant
DetectionLimit
Quanti-fication
LimitQualityControl
EPA 8270CMethod SVOC in Water by GC/MS Reference
BDL 46 BDL 4646BDL50p-Nitroaniline(ug/l)
BDL 43 BDL 4343BDL50Azobenzene(ug/l)
BDL 40 BDL 4040BDL504-Bromophenyl-phenylether(ug/l)
BDL 42 BDL 4242BDL50Hexachlorobenzene(ug/l)
BDL 42 BDL 4242BDL50Phenathrene(ug/l)
BDL 41 BDL 4141BDL50Anthracene(ug/l)
BDL 43 BDL 4343BDL50Carbazole(ug/l)
BDL 46 BDL 4646BDL50Dibutyl phthalate(ug/l)
BDL 45 BDL 4545BDL50Pyrene(ug/l)
BDL 49 BDL 4949BDL50Benzyl Butyl Phthalate(ug/l)
BDL 55 BDL 5555BDL50Benz[a]anthracene(ug/l)
BDL 52 BDL 5252BDL50Chrysene(ug/l)
BDL 51 BDL 5151BDL50Bis(2-ethylhexyl)phthalate(ug/l)
BDL 56 BDL 5656BDL50Di-n-octylphthalate(ug/l)
BDL 38 BDL 3838BDL50Benzo(b)fluoranthene(ug/l)
BDL 38 BDL 3838BDL50Benzo(k)fluoranthene(ug/l)
BDL - Below Detection Limit
* Denotes test method accredited to ISO17025
These tests do not apply to any other samples of a similar nature.
Refer to terms and conditions www.inspml.co.zaoo This report relates to only test items listed herein and analysis on an as received basis.
This certificate cannot be reproduced except in full without the written consent of M and L Laboratory Services (Pty) Ltd.o
:Printed Date 2015-04-08
M and L Laboratory Services (Pty) Ltd
Registration Number 1974/001476/07 VATNumber 4780103505
P.O. Box 82124
Southdale, 2135
40 Modulus Road
Page 10 of 16
:
:
:
ML2015-0981
8677215
2015-04-08
Ref. No.
Contract No.
Date
Ormonde, 2091
Tel: (011) 661 7900
Fax: (011) 496 2238
0861 467 765
Golden No.Consulting Industrial Chemists, Analysts Samplers
CONFIDENTIAL
Certificate / Report
H06097
KBH-4S
H06096
QualityControlResultResult
KBH-6D
QualityControlResultResult
H06095
KBH-4D
Result
QualityControlResult
Lab Number
Sample Marks
Determinant
DetectionLimit
Quanti-fication
LimitQualityControl
EPA 8270CMethod SVOC in Water by GC/MS Reference
BDL 47 BDL 4747BDL50Benzo(a)pyrene(ug/l)
Authorised Signature
Manager M&L Lab Services
Joanne Barton
BDL - Below Detection Limit
* Denotes test method accredited to ISO17025
These tests do not apply to any other samples of a similar nature.
Refer to terms and conditions www.inspml.co.zaoo This report relates to only test items listed herein and analysis on an as received basis.
This certificate cannot be reproduced except in full without the written consent of M and L Laboratory Services (Pty) Ltd.o
:Printed Date 2015-04-08
M and L Laboratory Services (Pty) Ltd
Registration Number 1974/001476/07 VATNumber 4780103505
P.O. Box 82124
Southdale, 2135
40 Modulus Road
Page 11 of 16
:
:
:
ML2015-0981
8677215
2015-04-08
Ref. No.
Contract No.
Date
Ormonde, 2091
Tel: (011) 661 7900
Fax: (011) 496 2238
0861 467 765
Golden No.Consulting Industrial Chemists, Analysts Samplers
CONFIDENTIAL
Certificate / Report
H06097
KBH-4S
H06096
QualityControlResultResult
KBH-6D
QualityControlResultResult
H06095
KBH-4D
Result
QualityControlResult
Lab Number
Sample Marks
Determinant
DetectionLimit
Quanti-fication
LimitQualityControl
Method Total Organic Carbon by Calculation as (C) Reference
22 2416Total Organic Carbon as C(mg/l)
Authorised Signature
Supervisor
Edward Khumalo
BDL - Below Detection Limit
* Denotes test method accredited to ISO17025
These tests do not apply to any other samples of a similar nature.
Refer to terms and conditions www.inspml.co.zaoo This report relates to only test items listed herein and analysis on an as received basis.
This certificate cannot be reproduced except in full without the written consent of M and L Laboratory Services (Pty) Ltd.o
:Printed Date 2015-04-08
M and L Laboratory Services (Pty) Ltd
Registration Number 1974/001476/07 VATNumber 4780103505
P.O. Box 82124
Southdale, 2135
40 Modulus Road
Page 12 of 16
:
:
:
ML2015-0981
8677215
2015-04-08
Ref. No.
Contract No.
Date
Ormonde, 2091
Tel: (011) 661 7900
Fax: (011) 496 2238
0861 467 765
Golden No.Consulting Industrial Chemists, Analysts Samplers
CONFIDENTIAL
Certificate / Report
KBH-10
H06099
QualityControlResultResult
QualityControlResultResult
H06098
KBH-9D
Result
QualityControlResult
Lab Number
Sample Marks
Determinant
DetectionLimit
Quanti-fication
LimitQualityControl
EPA 8270CMethod SVOC in Water by GC/MS Reference
BDL 5555BDL50Phenol(ug/l)
BDL 4545BDL502-Chlorophenol(ug/l)
BDL 3939BDL50Benzene, 1,3-dichloro-(ug/l)
BDL 4040BDL50Benzene, 1,4-dichloro-(ug/l)
BDL 4242BDL50Benzene, 1,2-dichloro-(ug/l)
BDL 4343BDL502-methylphenol(ug/l)
BDL 4242BDL50Bis(2-chloroisopropyl)ether(ug/l)
BDL 4141BDL504-Methylphenol(ug/l)
BDL 4242BDL50N-Nitrosodi-n-propylamine(ug/l)
BDL 4040BDL50Hexachloroethane(ug/l)
BDL 4141BDL50Nitrobenzene(ug/l)
BDL 4141BDL50Isophorone(ug/l)
BDL 4242BDL502-Nitrophenol(ug/l)
BDL 4242BDL502,4-Dimethylphenol(ug/l)
BDL 4141BDL502,4-Dichlorophenol(ug/l)
BDL 4141BDL50Naphthalene(ug/l)
BDL 4343BDL50p-Chloroaniline(ug/l)
BDL - Below Detection Limit
* Denotes test method accredited to ISO17025
These tests do not apply to any other samples of a similar nature.
Refer to terms and conditions www.inspml.co.zaoo This report relates to only test items listed herein and analysis on an as received basis.
This certificate cannot be reproduced except in full without the written consent of M and L Laboratory Services (Pty) Ltd.o
:Printed Date 2015-04-08
M and L Laboratory Services (Pty) Ltd
Registration Number 1974/001476/07 VATNumber 4780103505
P.O. Box 82124
Southdale, 2135
40 Modulus Road
Page 13 of 16
:
:
:
ML2015-0981
8677215
2015-04-08
Ref. No.
Contract No.
Date
Ormonde, 2091
Tel: (011) 661 7900
Fax: (011) 496 2238
0861 467 765
Golden No.Consulting Industrial Chemists, Analysts Samplers
CONFIDENTIAL
Certificate / Report
KBH-10
H06099
QualityControlResultResult
QualityControlResultResult
H06098
KBH-9D
Result
QualityControlResult
Lab Number
Sample Marks
Determinant
DetectionLimit
Quanti-fication
LimitQualityControl
EPA 8270CMethod SVOC in Water by GC/MS Reference
BDL 4242BDL50Hexachlorobutadiene(ug/l)
BDL 4343BDL504-chloro-3-methylphenol(ug/l)
BDL 4242BDL502-Methylnaphthalene(ug/l)
BDL 3737BDL50Hexachlorocyclopentadiene(ug/l)
BDL 4343BDL502,4,6-Trichlorophenol(ug/l)
BDL 4343BDL502,4,5-Trichlorophenol(ug/l)
BDL 4242BDL502-Chloronaphthalene(ug/l)
BDL 4444BDL50o-Nitroaniline(ug/l)
BDL 4242BDL50Dimethylphthalate(ug/l)
BDL 4040BDL50Acenaphthylene(ug/l)
BDL 4343BDL50m-Nitroaniline(ug/l)
BDL 4040BDL50Acenaphthene(ug/l)
BDL 4141BDL50Dibenzofuran(ug/l)
BDL 4242BDL502,4-Dinitrotoluene(ug/l)
BDL 4444BDL50Diethyl Phthalate(ug/l)
BDL 4242BDL50Fluorene(ug/l)
BDL 4040BDL504-Chlorophenyl-phenylether(ug/l)
BDL - Below Detection Limit
* Denotes test method accredited to ISO17025
These tests do not apply to any other samples of a similar nature.
Refer to terms and conditions www.inspml.co.zaoo This report relates to only test items listed herein and analysis on an as received basis.
This certificate cannot be reproduced except in full without the written consent of M and L Laboratory Services (Pty) Ltd.o
:Printed Date 2015-04-08
M and L Laboratory Services (Pty) Ltd
Registration Number 1974/001476/07 VATNumber 4780103505
P.O. Box 82124
Southdale, 2135
40 Modulus Road
Page 14 of 16
:
:
:
ML2015-0981
8677215
2015-04-08
Ref. No.
Contract No.
Date
Ormonde, 2091
Tel: (011) 661 7900
Fax: (011) 496 2238
0861 467 765
Golden No.Consulting Industrial Chemists, Analysts Samplers
CONFIDENTIAL
Certificate / Report
KBH-10
H06099
QualityControlResultResult
QualityControlResultResult
H06098
KBH-9D
Result
QualityControlResult
Lab Number
Sample Marks
Determinant
DetectionLimit
Quanti-fication
LimitQualityControl
EPA 8270CMethod SVOC in Water by GC/MS Reference
BDL 4646BDL50p-Nitroaniline(ug/l)
BDL 4343BDL50Azobenzene(ug/l)
BDL 4040BDL504-Bromophenyl-phenylether(ug/l)
BDL 4242BDL50Hexachlorobenzene(ug/l)
BDL 4242BDL50Phenathrene(ug/l)
BDL 4141BDL50Anthracene(ug/l)
BDL 4343BDL50Carbazole(ug/l)
BDL 4646BDL50Dibutyl phthalate(ug/l)
BDL 4545BDL50Pyrene(ug/l)
BDL 4949BDL50Benzyl Butyl Phthalate(ug/l)
BDL 5555BDL50Benz[a]anthracene(ug/l)
BDL 5252BDL50Chrysene(ug/l)
BDL 5151BDL50Bis(2-ethylhexyl)phthalate(ug/l)
BDL 5656BDL50Di-n-octylphthalate(ug/l)
BDL 3838BDL50Benzo(b)fluoranthene(ug/l)
BDL 3838BDL50Benzo(k)fluoranthene(ug/l)
BDL - Below Detection Limit
* Denotes test method accredited to ISO17025
These tests do not apply to any other samples of a similar nature.
Refer to terms and conditions www.inspml.co.zaoo This report relates to only test items listed herein and analysis on an as received basis.
This certificate cannot be reproduced except in full without the written consent of M and L Laboratory Services (Pty) Ltd.o
:Printed Date 2015-04-08
M and L Laboratory Services (Pty) Ltd
Registration Number 1974/001476/07 VATNumber 4780103505
P.O. Box 82124
Southdale, 2135
40 Modulus Road
Page 15 of 16
:
:
:
ML2015-0981
8677215
2015-04-08
Ref. No.
Contract No.
Date
Ormonde, 2091
Tel: (011) 661 7900
Fax: (011) 496 2238
0861 467 765
Golden No.Consulting Industrial Chemists, Analysts Samplers
CONFIDENTIAL
Certificate / Report
KBH-10
H06099
QualityControlResultResult
QualityControlResultResult
H06098
KBH-9D
Result
QualityControlResult
Lab Number
Sample Marks
Determinant
DetectionLimit
Quanti-fication
LimitQualityControl
EPA 8270CMethod SVOC in Water by GC/MS Reference
BDL 4747BDL50Benzo(a)pyrene(ug/l)
Authorised Signature
Manager M&L Lab Services
Joanne Barton
BDL - Below Detection Limit
* Denotes test method accredited to ISO17025
These tests do not apply to any other samples of a similar nature.
Refer to terms and conditions www.inspml.co.zaoo This report relates to only test items listed herein and analysis on an as received basis.
This certificate cannot be reproduced except in full without the written consent of M and L Laboratory Services (Pty) Ltd.o
:Printed Date 2015-04-08
M and L Laboratory Services (Pty) Ltd
Registration Number 1974/001476/07 VATNumber 4780103505
P.O. Box 82124
Southdale, 2135
40 Modulus Road
Page 16 of 16
:
:
:
ML2015-0981
8677215
2015-04-08
Ref. No.
Contract No.
Date
Ormonde, 2091
Tel: (011) 661 7900
Fax: (011) 496 2238
0861 467 765
Golden No.Consulting Industrial Chemists, Analysts Samplers
CONFIDENTIAL
Certificate / Report
KBH-10
H06099
QualityControlResultResult
QualityControlResultResult
H06098
KBH-9D
Result
QualityControlResult
Lab Number
Sample Marks
Determinant
DetectionLimit
Quanti-fication
LimitQualityControl
Method Total Organic Carbon by Calculation as (C) Reference
7030Total Organic Carbon as C(mg/l)
Authorised Signature
Supervisor
Edward Khumalo
BDL - Below Detection Limit
* Denotes test method accredited to ISO17025
These tests do not apply to any other samples of a similar nature.
Refer to terms and conditions www.inspml.co.zaoo This report relates to only test items listed herein and analysis on an as received basis.
This certificate cannot be reproduced except in full without the written consent of M and L Laboratory Services (Pty) Ltd.o
:Printed Date 2015-04-08
ArcelorMittal Vanderbijlpark
External audit report on the WML for Klip waste site at AMSA Vereeniging
45 Report: 192-ZANAMVE-2015 Zantow Environmental Consulting Services
ANNEXURE C
Ground water monitoring results – inorganics
ANNEXURE C1
Ground water monitoring results – inorganics (June 2014)
KBH, VBH & SNS June 14-0169- BH results
SAMPLE ID SAMPLE No. LAB No. Ca K Mg Na S-SO4 Si-SiO2 Al As B Ba Be Bi Cd Co Cr Cu Fe Hg Li Mn Mo Ni P-PO4 Pb Sb Se Sn Sr Ti V ZnPAlk
TOTAlk pH Cond F
-Cl
-NH3-N NO3-N NO2-N E Fact % Cation:Anion Difference (%) TDS, (ppm)
KBH-3D(2014.04.04) 438652 14/0169 63 7.6 56 61 308 15 <0.07 <0.02 0.20 0.28 <0.02 <0.02 <0.01 <0.02 <0.02 <0.02 <0.08 <0.02 <0.02 0.83e-1 <0.02 <0.02 <0.25 <0.02 <0.02 <0.02 <0.07 0.79e-1 <0.01 <0.02 0.12 0 283 7.8 1065 <0.03 8.8 17 <0.37 <0.08 1.011 3.102 680
KBH-3S(2014.04.04) 438653 14/0169 3.1 29 8.5 742 869 <1.11 <0.07 <0.02 0.26 0.25 <0.02 <0.02 <0.01 <0.02 <0.02 <0.02 0.19 <0.02 <0.02 <0.01 <0.02 <0.02 0.27 <0.02 <0.02 <0.02 <0.07 <0.02 <0.01 <0.02 <0.04 255 824 9.7 3161 0.29 50 11 1.4 0.48 0.812 2.304 2141
KBH-4D(2014.04.04) 438654 14/0169 147 12 146 273 1451 18 <0.07 <0.02 0.22 0.16 <0.02 <0.02 <0.01 <0.02 <0.02 <0.02 <0.08 <0.02 0.02 0.18 <0.02 0.02 <0.25 <0.02 <0.02 <0.02 <0.07 0.20 <0.01 <0.02 0.14 0 344 7.5 2993 <0.03 15 51 <0.37 0.13 1.041 4.384 2325
KBH-4S(2014.04.04) 438655 14/0169 225 30 439 1332 6122 13 0.09 <0.02 0.95 0.18 <0.02 <0.02 <0.01 <0.02 <0.02 <0.02 <0.08 <0.02 <0.02 2.4 <0.02 0.04 0.95 <0.02 <0.02 <0.02 <0.07 0.41 <0.01 <0.02 0.29 0 464 7.7 11172 <0.03 47 458 157 0.49 0.983 6.357 9026
KBH-5(2014.04.04) 438656 14/0169 62 4.5 174 90 350 5.4 <0.07 <0.02 1.1 0.33 <0.02 <0.02 <0.01 <0.02 <0.02 <0.02 <0.08 <0.02 <0.02 0.88e-1 <0.02 <0.02 <0.25 <0.02 <0.02 <0.02 <0.07 0.16 <0.01 <0.02 0.11 0 662 7.9 1741 <0.03 52 2.1 <0.37 <0.08 1.168 0.865 1192
KBH-6D(2014.04.04) 438657 14/0169 146 3.9 107 53 614 10 <0.07 <0.02 0.31 0.22 <0.02 <0.02 <0.01 <0.02 <0.02 <0.02 <0.08 <0.02 <0.02 0.49 <0.02 <0.02 <0.25 <0.02 <0.02 <0.02 <0.07 0.15 <0.01 <0.02 0.18 0 294 7.6 1551 <0.03 33 0.24 <0.37 <0.08 1.163 2.771 1261
KBH-7D(2014.04.04) 438658 14/0169 77 5.6 45 32 85 18 <0.07 <0.02 0.54 0.60 <0.02 <0.02 <0.01 <0.02 <0.02 <0.02 <0.08 <0.02 <0.02 0.63e-1 <0.02 <0.02 <0.25 <0.02 <0.02 <0.02 <0.07 0.94e-1 <0.01 <0.02 0.31 0 308 7.5 828 <0.03 43 0.51 3.9 <0.08 1.030 1.712 528
KBH-9D(2014.04.04) 438659 14/0169 424 14 344 245 2616 28 0.16 <0.02 1.5 0.16 <0.02 <0.02 <0.01 <0.02 <0.02 <0.02 <0.08 <0.02 0.03 0.12 <0.02 <0.02 <0.25 <0.02 <0.02 <0.02 <0.07 0.68 0.10e-1 <0.02 0.24 0 405 7.1 4690 <0.03 57 36 44 <0.08 1.256 3.706 4611
KBH-10D(2014.04.04) 438660 14/0169 47 39 195 1002 5488 13 <0.07 <0.02 1.4 0.15 <0.02 <0.02 <0.01 <0.02 <0.02 <0.02 0.22 <0.02 0.07 0.62 <0.02 0.03 <0.25 <0.02 <0.02 <0.02 <0.07 0.17 <0.01 <0.02 0.14 0 1006 8.1 11807 1.9 71 910 <0.37 <0.08 0.879 9.227 7839
KWG-2D(2014.04.04) 438661 14/0169 61 9.3 25 26 20 19 <0.07 <0.02 0.35 1.2 <0.02 <0.02 <0.01 <0.02 <0.02 <0.02 0.23 <0.02 <0.02 1.9 <0.02 <0.02 <0.25 <0.02 <0.02 <0.02 <0.07 0.30 <0.01 <0.02 0.19 0 292 7.7 654 0.24 29 5.3 <0.37 <0.08 0.976 2.293 406
KWG-2S(2014.04.04) 438662 14/0169 86 7.8 36 30 5.7 22 <0.07 <0.02 0.22 0.03 <0.02 <0.02 <0.01 <0.02 <0.02 <0.02 <0.08 <0.02 <0.02 2.9 <0.02 <0.02 <0.25 <0.02 <0.02 <0.02 <0.07 0.40 <0.01 <0.02 0.28 0 379 7.5 796 0.14 45 0.35 <0.37 <0.08 1.046 0.809 496
KWG-3(2014.04.04) 438663 14/0169 98 22 85 73 579 12 <0.07 <0.02 0.34 0.25 <0.02 <0.02 <0.01 <0.02 <0.02 <0.02 <0.08 <0.02 <0.02 0.28 <0.02 <0.02 <0.25 <0.02 <0.02 <0.02 <0.07 0.37 <0.01 <0.02 0.19 0 128 8.2 1428 <0.03 52 2.5 9.2 0.82 1.023 2.968 1095
MF-1(2014.04.04) 438664 14/0169 214 5.9 103 49 596 26 0.08 <0.02 6.2 0.25 <0.02 <0.02 <0.01 <0.02 <0.02 <0.02 <0.08 <0.02 0.05 0.64e-1 <0.02 <0.02 <0.25 <0.02 <0.02 <0.02 <0.07 0.21 <0.01 <0.02 0.47 0 366 7.3 1839 <0.03 96 3.3 5.4 <0.08 1.139 3.806 1821
MF-2(2014.04.04) 438665 14/0169 221 7.9 115 30 683 16 0.08 <0.02 0.43 0.25 <0.02 <0.02 <0.01 <0.02 <0.02 <0.02 <0.08 <0.02 <0.02 0.27 <0.02 <0.02 <0.25 <0.02 <0.02 <0.02 <0.07 0.72 <0.01 <0.02 0.24 0 323 7.4 1786 <0.03 53 <0.18 13 <0.08 1.194 2.594 1881
MF-3(2014.04.04) 438666 14/0169 225 9.5 94 56 625 23 0.08 <0.02 7.9 0.27 <0.02 <0.02 <0.01 <0.02 <0.02 <0.02 <0.08 <0.02 <0.02 0.46 <0.02 0.04 <0.25 <0.02 <0.02 <0.02 <0.07 0.27 <0.01 <0.02 4.8 0 323 7.3 2007 0.21 140 18 15 <0.08 1.065 3.891 1858
TSG-2(2014.04.04) 438667 14/0169 17 36 8.3 1440 86 5.9 0.19 <0.02 787 0.59 <0.02 <0.02 <0.01 <0.02 <0.02 <0.02 0.40 <0.02 3.2 0.04 3.3 0.47e-1 7.0 <0.02 <0.02 <0.02 <0.07 0.10 <0.01 <0.02 0.14 962 2950 8.9 4942 0.61 139 5.6 <0.37 <0.08 0.958 0.552 7071
TSG-4(2014.04.04) 438668 14/0169 53 2.7 45 25 36 3.8 <0.07 <0.02 0.37 0.75 <0.02 <0.02 <0.01 <0.02 <0.02 <0.02 <0.08 <0.02 <0.02 0.61e-1 <0.02 <0.02 <0.25 <0.02 <0.02 <0.02 <0.07 0.37 <0.01 <0.02 0.72e-1 2.2 271 8.4 715 <0.03 57 0.40 <0.37 <0.08 0.990 1.848 493
TSG-6D(2014.04.04) 438669 14/0169 234 2.7 146 54 884 20 0.08 <0.02 0.70 0.22 <0.02 <0.02 <0.01 <0.02 <0.02 <0.02 <0.08 <0.02 0.05 0.09 <0.02 <0.02 0.49 <0.02 <0.02 <0.02 <0.07 0.22 <0.01 <0.02 0.21 0 409 7.6 2077 <0.03 36 0.26 3.0 <0.08 1.241 3.039 1850
TSG-7D(2014.04.04) 438670 14/0169 164 3.5 23 14 439 19 <0.07 <0.02 0.63 0.32 <0.02 <0.02 <0.01 <0.02 <0.02 <0.02 0.15 <0.02 0.11 2.6 <0.02 <0.02 <0.25 <0.02 <0.02 <0.02 <0.07 0.24 <0.01 <0.02 0.67 0 104 7.0 982 <0.03 15 0.67 <0.37 <0.08 1.102 3.679 817
TSG-7S(2014.04.04) 438671 14/0169 28 2.3 6.4 40 23 7.4 0.23 <0.02 0.36e-1 0.84 <0.02 <0.02 <0.01 <0.02 <0.02 <0.02 0.10 <0.02 <0.02 2.8 0.31e-1 <0.02 <0.25 <0.02 <0.02 <0.02 <0.07 0.12 <0.01 <0.02 0.39 0 152 7.5 349 0.28 22 1.4 <0.37 <0.08 0.967 4.100 260
TSG-8S(2014.04.04) 438672 14/0169 68 1.2 34 36 89 15 <0.07 <0.02 0.43 0.56 <0.02 <0.02 <0.01 <0.02 <0.02 <0.02 <0.08 <0.02 <0.02 1.1 <0.02 <0.02 <0.25 0.04 <0.02 <0.02 <0.07 0.18 <0.01 <0.02 1.5 0 290 7.5 748 0.16 29 <0.18 2.7 <0.08 1.014 5.257 462
TSG-9D(2014.04.04) 438673 14/0169 118 0.73 91 69 605 12 <0.07 <0.02 0.27 0.28 <0.02 <0.02 <0.01 <0.02 <0.02 <0.02 1.4 <0.02 0.36e-1 0.86 <0.02 0.44e-1 <0.25 <0.02 <0.02 <0.02 <0.07 0.23 <0.01 <0.02 0.17 0 131 6.9 1475 0.50 93 0.39 0.49 <0.08 1.064 4.366 1234
VBH-1(2014.04.04) 438674 14/0169 40 15 62 247 323 11 <0.07 <0.02 1.3 0.49 <0.02 <0.02 <0.01 <0.02 <0.02 <0.02 <0.08 <0.02 0.34e-1 0.75e-1 0.84 <0.02 <0.25 <0.02 <0.02 <0.02 <0.07 0.42 <0.01 <0.02 0.20 4.7 410 8.4 1679 5.3 117 0.34 <0.37 <0.08 0.876 0.842 1219
VBH-2(2014.04.04) 438675 14/0169 6.6 2.3 9.4 61 3.1 3.1 <0.07 <0.02 0.74 0.68 <0.02 <0.02 <0.01 <0.02 <0.02 <0.02 <0.08 <0.02 <0.02 <0.01 <0.02 <0.02 <0.25 <0.02 <0.02 <0.02 <0.07 0.19 <0.01 <0.02 0.11 13 112 9.0 392 0.30 55 <0.18 <0.37 <0.08 0.739 0.842 225
VBH-4D(2014.04.04) 438676 14/0169 28 3.1 12 99 19 14 <0.07 <0.02 1.5 0.62 <0.02 <0.02 <0.01 <0.02 <0.02 <0.02 <0.08 <0.02 0.49e-1 0.59e-1 <0.02 <0.02 0.31 <0.02 <0.02 <0.02 <0.07 0.41 <0.01 <0.02 0.87e-1 0 249 8.2 681 0.72 59 <0.18 0.76 <0.08 0.812 2.171 421
VBH-4M(2014.04.04) 438677 14/0169 23 1.7 14 62 18 15 <0.07 <0.02 0.29 0.60 <0.02 <0.02 <0.01 <0.02 <0.02 <0.02 <0.08 <0.02 <0.02 0.99 <0.02 <0.02 <0.25 <0.02 <0.02 <0.02 <0.07 0.16 <0.01 <0.02 0.25 0 166 7.8 517 0.18 55 0.22 <0.37 <0.08 0.809 1.918 308
VBH-5D(2014.04.04) 438678 14/0169 9.4 1.7 5.1 145 19 9.3 <0.07 <0.02 1.9 0.67 <0.02 <0.02 <0.01 <0.02 <0.02 <0.02 0.81e-1 <0.02 0.03 0.18e-1 <0.02 0.38e-1 <0.25 <0.02 <0.02 <0.02 <0.07 0.39 <0.01 <0.02 0.12 0 185 7.9 786 1.7 123 0.21 <0.37 <0.08 0.662 2.632 458
VBH-5M(2014.04.04) 438679 14/0169 3.1 3.8 1.6 238 5.4 4.8 <0.07 <0.02 0.39 0.52 <0.02 <0.02 <0.01 <0.02 <0.02 <0.02 <0.08 <0.02 <0.02 <0.01 <0.02 <0.02 0.28 <0.02 <0.02 <0.02 <0.07 0.64e-1 <0.01 <0.02 0.58e-1 42 163 9.5 1285 0.62 289 3.5 <0.37 <0.08 0.558 2.756 673
VWG-1(2014.04.04) 438680 14/0169 23 3.0 14 47 138 3.3 <0.07 <0.02 0.41 0.54e-1 <0.02 <0.02 <0.01 <0.02 <0.02 <0.02 <0.08 <0.02 <0.02 <0.01 <0.02 <0.02 <0.25 <0.02 <0.02 <0.02 <0.07 0.48e-1 <0.01 <0.02 0.12 0 71 8.2 469 <0.03 14 <0.18 <0.37 <0.08 0.827 3.063 287
VWG-2D(2014.04.04) 438681 14/0169 93 4.1 49 39 204 34 <0.07 <0.02 0.56 0.95e-1 <0.02 <0.02 <0.01 <0.02 <0.02 <0.02 <0.08 <0.02 0.70e-1 2.6 <0.02 <0.02 <0.25 <0.02 <0.02 <0.02 <0.07 0.65 <0.01 <0.02 0.26 0 293 7.7 967 <0.03 35 <0.18 <0.37 <0.08 1.045 2.877 674
VWG-2S(2014.04.04) 438682 14/0169 25 2.5 6.4 11 10 5.9 <0.07 <0.02 0.38 0.56 <0.02 <0.02 <0.01 <0.02 <0.02 <0.02 <0.08 <0.02 <0.02 0.18 <0.02 <0.02 <0.25 <0.02 <0.02 <0.02 <0.07 0.82e-1 <0.01 <0.02 0.51e-1 0 109 8.4 224 0.39 1.7 0.67 <0.37 <0.08 1.012 1.704 139
VWG-5(2014.04.04) 438683 14/0169 57 14 81 63 9.9 8.0 <0.07 <0.02 0.47 0.63 <0.02 <0.02 <0.01 <0.02 <0.02 <0.02 <0.08 <0.02 <0.02 1.2 <0.02 <0.02 <0.25 <0.02 <0.02 <0.02 <0.07 0.30 <0.01 <0.02 0.29 0 674 7.9 1199 0.06 15 14 <0.37 <0.08 1.056 2.431 669
VWG-8D(2014.04.04) 438684 14/0169 23 3.1 11 33 41 5.6 <0.07 <0.02 0.33 0.53 <0.02 <0.02 <0.01 <0.02 <0.02 <0.02 <0.08 <0.02 0.03 0.19 <0.02 <0.02 <0.25 <0.02 <0.02 <0.02 <0.07 0.12 <0.01 <0.02 0.16 0 125 7.8 361 0.18 11 <0.18 0.78 <0.08 0.874 2.651 215
VWG-10(2014.04.04) 438685 14/0169 350 7.6 179 107 1421 12 0.86e-1 <0.02 4.6 0.26 <0.02 <0.02 <0.01 <0.02 <0.02 <0.02 <0.08 <0.02 1.0 0.40 <0.02 0.20e-1 0.55 <0.02 <0.02 <0.02 <0.07 1.2 <0.01 <0.02 0.24 0 399 7.9 2845 <0.03 119 <0.18 1.8 0.66 1.288 5.076 2610
ICP-OES:
2014.04.07
2014.04.11
All of the results in this report relate only to the item tested.
Expanded Uncertainties: ICP-MS,
Potensiometric Titrator:
Photometric:
Conductivity Meter:
MAIN LABORATORY; SANAS Accredited Testing Laboratory No TO260 : ANALYTICAL REPORT
Environmental Management (P_BAMBO)
Hattingh, J
E - mail
DATE RECEIVED
DATE COMPLETED
COPIES TO
ORIGIN OF SAMPLES
FORM OF TRANSMISSION
Techniques
Expanded Uncertainties: Metrohm Titrators
Expanded Uncertainties: Aquakem NH3-N, NO3-N, NO2-N & Cl: 3.278%
Al, As, Ba, Be, B, Cd, Co, Cu, Pb, Hg, Mo, Ni, Se, Sn, Sr, V & Zn: (PPM)
Al, Cr, Ca, Fe, K, Mg, Mn, Na, P, S-SO4, Sn, Ti, Zn: 1.31%,
As, Ba, Be, B, Cd, Co, Cu, Pb, Hg, Mo, Ni, Se, Sr, V & Zn: 4.954%
pH: 0.414%, Cl: 4.187%, Alk 4.216%
ICP-MS:
The components indicated in red on this report are not included in the SANAS Schedule of Accreditation for this laboratory: COND,P-Alkalinity,Cl,SUSP,F-, NO2-N,Phenol,CN
-,Al,As,B,Be,Bi,Co,Cu,Li,Mo,Ni,Sb,Si-SiO2,Sn,Sr,Ti,Turb,Oil,COD,Sulphite & TDS
Expanded Uncertainties: ICP-OES,
Analytes & UnitsPAlkalinity (CaCO3 PPM),
TotAlkalinity (CaCO3 PPM), pH @ 25
oC, Cl (PPM)
NH3-N, NO3-N, NO2-N, F, CN-, Phenol, Cl, Cr
6+ (PPM)
Methods
QMMAIN0008, MCSMLQAWP0029,31
MCSMLQAWP0019 & 0020
Conductivity @ 25oC(µS/cm)
Al, Cr, Ca, Fe, K, Mg, Mn, Na, P, S-SO4, Sn, Ti, Zn: (PPM)
QMMAIN0008, MCSMLQAWP0029,31
QMMAIN0008, MCSMLQAWP0022
MCSMLQAWP0016
Technical Manager Tel 016 889 3304
Page 1 of 1
ArcelorMittal Vanderbijlpark
External audit report on the WML for Klip waste site at AMSA Vereeniging
46 Report: 192-ZANAMVE-2015 Zantow Environmental Consulting Services
ANNEXURE C2
Ground water monitoring results – inorganics (September 2014)
September 14-0347- BH results Klip dump
Order No Request
SAMPLE ID SAMPLE No. LAB No. Ca K Mg Na S-SO4 Si-SiO2 Al As B Ba Be Bi Cd Co Cr Cu Fe Hg Li Mn Mo Ni P-PO4 Pb Sb Se Sn Sr Ti V ZnPAlk
TOTAlk pH Cond F
-Cl
-NH3-N NO3-N NO2-N COD TDS, (ppm) E Fact % Cation:Anion Difference (%)
KBH-3D(2014.08.08) 456839 14/0347 59 8.5 54 76 369 12 <0.09 <0.02 0.03 <0.02 <0.02 <0.02 <0.01 <0.02 <0.05 <0.02 <0.16 <0.02 <0.02 0.08 <0.02 <0.02 0.25 <0.02 <0.02 <0.02 <0.12 0.07 <0.04 <0.02 <0.14 0 256 7.7 1093 <0.07 10 19 <0.74 <0.16 25 740 1.012 4.779
KBH-3S(2014.08.08) 456840 14/0347 4.8 28 6.1 889 926 5.5 0.09 <0.02 0.05 <0.02 <0.02 <0.02 <0.01 <0.02 <0.05 <0.02 0.58 <0.02 <0.02 <0.06 <0.02 <0.02 0.28 <0.02 <0.02 <0.02 <0.12 <0.02 <0.04 <0.02 <0.14 276 915 9.7 3294 <0.07 62 9.8 <0.74 <0.16 66 2353 0.871 1.658
KBH-4D(2014.08.08) 456841 14/0347 176 14 172 395 1845 20 <0.09 <0.02 0.08 <0.02 <0.02 <0.02 <0.01 <0.02 <0.05 <0.02 <0.16 <0.02 0.02 0.16 <0.02 0.04 0.25 <0.02 <0.02 <0.02 <0.12 0.23 <0.04 <0.02 <0.14 0 335 7.1 3431 <0.07 18 59 1.8 4.4 38 2851 1.112 2.161
KBH-4S(2014.08.08) 456842 14/0347 242 30 473 1666 6855 16 <0.09 <0.02 0.72 <0.02 <0.02 <0.02 <0.01 <0.02 <0.05 0.04 <0.16 <0.02 <0.02 1.8 <0.02 0.03 0.25 <0.02 <0.02 <0.02 <0.12 0.40 <0.04 <0.02 <0.14 0 477 7.4 11286 <0.07 57 467 138 7.2 97 9589 1.085 4.334
KBH-5(2014.08.08) 456843 14/0347 41 3.5 136 74 255 4.7 <0.09 <0.02 0.74 0.07 <0.02 <0.02 <0.01 <0.02 <0.05 <0.02 <0.16 <0.02 <0.02 <0.06 <0.02 <0.02 0.25 <0.02 <0.02 <0.02 <0.12 0.08 <0.04 <0.02 <0.14 0 563 8.0 1443 0.53 42 0.41 <0.74 <0.16 <7.72 1015 1.109 3.657
KBH-6D(2014.08.08) 456844 14/0347 168 4.0 101 53 618 12 <0.09 <0.02 0.06 0.10 <0.02 <0.02 <0.01 <0.02 <0.05 <0.02 <0.16 <0.02 <0.02 0.47 <0.02 <0.02 0.25 <0.02 <0.02 <0.02 <0.12 0.16 <0.04 <0.02 <0.14 0 334 7.7 1649 0.27 35 <0.37 <0.74 <0.16 <7.72 1372 1.139 3.736
KBH-8D(2014.08.08) 456845 14/0347 100 3.8 69 39 173 22 <0.09 <0.02 0.18 0.08 <0.02 <0.02 <0.01 <0.02 <0.05 <0.02 <0.16 <0.02 <0.02 0.23 <0.02 <0.02 0.25 <0.02 <0.02 <0.02 <0.12 0.10 <0.04 <0.02 <0.14 0 416 7.5 1158 0.70 49 6.1 0.77 <0.16 <7.72 754 1.056 2.235
KBH-9D(2014.08.08) 456846 14/0347 455 13 321 231 2568 25 0.18 <0.02 0.94 0.08 <0.02 <0.02 <0.01 <0.02 <0.05 <0.02 0.62 <0.02 <0.02 0.35 <0.02 <0.02 0.25 <0.02 <0.02 <0.02 <0.12 0.58 <0.04 <0.02 <0.14 0 376 7.1 4251 <0.07 54 27 13 <0.16 9.0 4329 1.351 1.935
KBH-10D(2014.08.08) 456847 14/0347 49 40 195 1042 5543 9.5 0.58 <0.02 1.1 0.07 <0.02 <0.02 <0.01 <0.02 <0.05 0.04 2.6 <0.02 0.06 0.65 <0.02 <0.02 0.25 <0.02 <0.02 <0.02 <0.12 0.18 <0.04 <0.02 <0.14 0 1011 8.2 11673 0.92 77 934 <0.74 <0.16 66 7791 0.820 8.356
KBH-7D(2014.08.08)-Received late 461171 14/0347 74 5.5 43 30 88 20 <0.09 <0.02 0.23 0.06 <0.02 <0.02 <0.01 <0.02 <0.05 <0.02 <0.16 <0.02 <0.02 0.08 <0.02 <0.02 <0.25 <0.02 <0.02 <0.02 <0.12 0.07 <0.04 <0.02 <0.14 0 307 8.1 838 0.38 45 <0.37 4.0 <0.16 <7.72 515 1.006 4.323
QMMAIN0008, MCSMLQAWP0029,31
QMMAIN0008, MCSMLQAWP0022
MCSMLQAWP0016
Methods
QMMAIN0008, MCSMLQAWP0029,31
MCSMLQAWP0019 & 0020
MCSMLQAWP0026COD, O2 (PPM)
Conductivity @ 25oC(µS/cm)
Al, Cr, Ca, Fe, K, Mg, Mn, Na, P, S-SO4, Sn, Ti, Zn: 1.31%,
As, Ba, Be, B, Cd, Co, Cu, Pb, Hg, Mo, Ni, Se, Sr, V & Zn: 4.954%
pH: 0.414%, Cl: 4.187%, Alk 4.216%
Analytes & UnitsPAlkalinity (CaCO3 PPM), TotAlkalinity (CaCO3 PPM), pH @ 25oC, Cl (PPM)
NH3-N, NO3-N, NO2-N, F, CN-, Phenol, Cl, Cr6+ (PPM)
The components indicated in red on this report are not included in the SANAS Schedule of Accreditation for this laboratory: COND,P-Alkalinity,Cl,SUSP,F-, NO2-N,Phenol,CN
-,Al,As,B,Be,Bi,Co,Cu,Li,Mo,Ni,Sb,Si-SiO2,Sn,Sr,Ti,Turb,Oil,COD,Sulphite & TDS
Expanded Uncertainties: ICP-OES,
Techniques
Potensiometric Titrator:
Photometric:
Conductivity Meter:
Al, Cr, Ca, Fe, K, Mg, Mn, Na, P, S-SO4, Sn, Ti, Zn: (PPM)
NH3-N, NO3-N, NO2-N & Cl: 3.278%
Al, As, Ba, Be, B, Cd, Co, Cu, Pb, Hg, Mo, Ni, Se, Sn, Sr, V & Zn: (PPM)
2014.08.12
2014.09.11
All of the results in this report relate only to the item tested.
Expanded Uncertainties: ICP-MS,
Expanded Uncertainties: Metrohm Titrators
Expanded Uncertainties: Aquakem
ICP-OES:
ICP-MS:
DATE RECEIVED
DATE COMPLETED
COPIES TO
ORIGIN OF SAMPLES
FORM OF TRANSMISSION
MAIN LABORATORY; SANAS Accredited Testing Laboratory No TO260 : ANALYTICAL REPORT
Environmental Management (P_BAMBO)
Hattingh, J
E - mail
Technical Manager Tel 016 889 3304
Technical Signatory S Nomntu
Tel 016 889 3304
Page 1 of 1
ArcelorMittal Vanderbijlpark
External audit report on the WML for Klip waste site at AMSA Vereeniging
47 Report: 192-ZANAMVE-2015 Zantow Environmental Consulting Services
ANNEXURE C3
Ground water monitoring results – inorganics (November 2014)
November 14-0510- Klip Dump
Order No Request
SAMPLE ID SAMPLE No. LAB No. Ca K Mg Na S-SO4 Si-SiO2 Al As B Ba Be Bi Cd Co Cr Cu Fe Hg Li Mn Mo Ni P-PO4 Pb Sb Se Sn Sr Ti V ZnPAlk
TOTAlk pH Cond F
-Cl
-NH3-N NO3-N NO2-N COD % Cation:Anion Difference (%) E Fact TDS, (ppm)
KBH-3D(2014.11.13) 471244 14/0510 58 9.9 59 93 420 9.7 <0.09 <0.02 0.05 0.11 <0.02 <0.02 <0.01 <0.02 <0.05 <0.02 <0.16 <0.02 <0.02 0.07 <0.02 <0.03 <0.25 <0.02 <0.02 <0.02 <0.12 0.06 <0.04 <0.02 <0.14 0 238 7.8 1211 <0.24 11 22 <0.92 <0.16 <7.72 2.079 0.976 806
KBH-3S(2014.11.13) 471245 14/0510 1.8 30 4.9 911 922 <1.84 <0.09 <0.02 0.05 0.10 <0.02 <0.02 <0.01 <0.02 <0.05 <0.02 0.40 <0.02 <0.02 <0.06 <0.02 <0.03 <0.25 <0.02 <0.02 <0.02 <0.12 <0.02 <0.04 <0.02 <0.14 271 940 9.6 3453 <0.24 63 9.1 <0.92 <0.16 71 2.004 0.840 2408
KBH-4D(2014.11.13) 471246 14/0510 201 16 204 429 2096 20 <0.09 <0.02 0.07 0.08 <0.02 <0.02 <0.01 <0.02 <0.05 <0.02 <0.16 <0.02 <0.02 0.20 <0.02 <0.03 <0.25 <0.02 <0.02 <0.02 <0.12 0.17 <0.04 <0.02 <0.14 0 361 7.1 3761 <0.24 20 67 6.5 <0.16 <7.72 2.239 1.153 3098
KBH-4S(2014.11.13) 471247 14/0510 278 30 567 1765 6862 14 <0.09 <0.02 0.54 0.08 <0.02 <0.02 <0.01 <0.02 <0.05 <0.02 <0.16 <0.02 <0.02 2.8 <0.02 <0.03 0.55 <0.02 <0.02 <0.02 <0.12 0.33 <0.04 <0.02 0.21 0 474 7.4 12567 <0.24 53 498 323 5.4 31 3.249 1.037 10916
KBH-5(2014.11.13) 471248 14/0510 35 3.5 150 78 204 4.3 <0.09 <0.02 0.59 0.11 <0.02 <0.02 <0.01 <0.02 <0.05 <0.02 <0.16 <0.02 <0.02 <0.06 <0.02 <0.03 <0.25 <0.02 <0.02 <0.02 <0.12 0.06 <0.04 <0.02 <0.14 0 598 7.8 1424 0.56 40 2.0 <0.92 <0.16 <7.72 1.018 1.146 928
KBH-6S(2014.11.13) 471249 14/0510 240 27 154 49 1234 11 <0.09 <0.02 0.03 0.08 <0.02 <0.02 <0.01 <0.02 <0.05 <0.02 <0.16 <0.02 0.04 0.22 <0.02 <0.03 <0.25 <0.02 <0.02 <0.02 <0.12 0.43 <0.04 <0.02 <0.14 0 33 7.8 2043 0.34 18 1.2 16 0.22 18 0.720 1.279 1864
KBH-6D(2014.11.13) 471250 14/0510 200 4.5 122 57 730 13 <0.09 <0.02 0.04 0.11 <0.02 <0.02 <0.01 <0.02 <0.05 <0.02 <0.16 <0.02 <0.02 0.31 <0.02 <0.03 <0.25 <0.02 <0.02 <0.02 <0.12 0.14 <0.04 <0.02 <0.14 0 325 7.6 1708 0.37 33 0.93 1.3 0.88 <7.72 0.022 1.262 1399
KBH-7D(2014.11.13) 471251 14/0510 77 5.6 46 32 74 18 <0.09 <0.02 0.22 0.14 <0.02 <0.02 <0.01 <0.02 <0.05 <0.02 <0.16 <0.02 <0.02 0.14 <0.02 <0.03 <0.25 <0.02 <0.02 <0.02 <0.12 0.06 <0.04 <0.02 <0.14 0 303 7.3 829 0.32 46 0.48 3.6 <0.16 <7.72 0.207 1.023 489
KBH-9D(2014.11.13) 471252 14/0510 474 16 390 292 3013 23 <0.09 <0.02 0.86 0.09 <0.02 <0.02 <0.01 <0.02 <0.05 <0.02 <0.16 <0.02 <0.02 0.24 <0.02 <0.03 <0.25 <0.02 <0.02 <0.02 <0.12 0.51 <0.04 <0.02 <0.14 0 400 6.9 4675 0.30 56 40 9.9 <0.16 <7.72 1.330 1.416 4677
KBH-10D(2014.11.13) 471253 14/0510 53 41 201 1087 5770 11 <0.09 <0.02 0.96 0.07 <0.02 <0.02 <0.01 <0.02 <0.05 <0.02 <0.16 <0.02 0.05 0.31 <0.02 <0.03 <0.25 <0.02 <0.02 <0.02 <0.12 0.13 <0.04 <0.02 <0.14 0 1019 8.1 11361 1.1 72 902 <0.92 <0.16 95 9.611 0.867 7745
ICP-OES:
Gravimetric:
2014.11.17
2015.01.15
All of the results in this report relate only to the item tested.
Potensiometric Titrator:
Photometric:
Conductivity Meter:
MAIN LABORATORY; SANAS Accredited Testing Laboratory No TO260 : ANALYTICAL REPORT
Environmental Management (P_BAMBO)
Hattingh, J
E - mail
DATE RECEIVED
DATE COMPLETED
COPIES TO
ORIGIN OF SAMPLES
FORM OF TRANSMISSION
Techniques
Expanded Uncertainties: ICP-MS,
Expanded Uncertainties: Metrohm Titrators
NH3-N, NO3-N, NO2-N & Cl: 3.278%
Al, As, Ba, Be, B, Cd, Co, Cu, Pb, Hg, Mo, Ni, Se, Sn, Sr, V & Zn: (PPM)
Al, Cr, Ca, Fe, K, Mg, Mn, Na, P, S-SO4, Sn, Ti, Zn: 1.31%,
As, Ba, Be, B, Cd, Co, Cu, Pb, Hg, Mo, Ni, Se, Sr, V & Zn: 4.954%
pH: 0.414%, Cl: 4.187%, Alk 4.216%
ICP-MS:
The components indicated in red on this report are not included in the SANAS Schedule of Accreditation for this laboratory: COND,P-Alkalinity,Cl,SUSP,F-, NO2-N,Phenol,CN
-,Al,As,B,Be,Bi,Co,Cu,Li,Mo,Ni,Sb,Si-SiO2,Sn,Sr,Ti,Turb,Oil,COD,Sulphite & TDS
Expanded Uncertainties: ICP-OES,
Expanded Uncertainties: Aquakem
Analytes & UnitsPAlkalinity (CaCO3 PPM),
TotAlkalinity (CaCO3 PPM), pH @ 25
oC, Cl (PPM)
NH3-N, NO3-N, NO2-N, F, CN-, Phenol, Cl, Cr
6+ (PPM)
Methods
MCSMLQAWP0029,31
MCSMLQAWP0019 & 0020
Conductivity @ 25oC(µS/cm)
Suspension @ 105oC,(PPM), TDS @ 180
oC,(PPM)
Al, Cr, Ca, Fe, K, Mg, Mn, Na, P, S-SO4, Sn, Ti, Zn: (PPM)
MCSMLQAWP0029,31
MCSMLQAWP0028, 24
MCSMLQAWP0022
MCSMLQAWP0016
Technical Manager Tel 016 889 3304
Page 1 of 1
ArcelorMittal Vanderbijlpark
External audit report on the WML for Klip waste site at AMSA Vereeniging
48 Report: 192-ZANAMVE-2015 Zantow Environmental Consulting Services
ANNEXURE C4
Ground water monitoring results – inorganics (March 2015)
KBH, VBD & SNS - March 2015 Results
Order No Request
SAMPLE ID SAMPLE No. LAB No. Ca K Mg Na S-SO4 Si-SiO2 Al As B Ba Be Bi Cd Co Cr Cu Fe Hg Li Mn Mo Ni P-PO4 Pb Sb Se Sn Sr Ti V ZnPAlk
TOTAlk pH Cond F
-Cl
-NH3-N NO3-N NO2-N COD E Fact % Cation:Anion Difference (%) TDS, (ppm)
KBH 2(2015-03-10) 488252 15/0110 6.4 3.4 144 71 38 3.9 <0.09 <0.02 0.67 0.15 <0.02 <0.02 <0.01 <0.02 <0.05 <0.02 <0.16 <0.02 <0.02 <0.06 <0.02 <0.03 <0.25 <0.02 <0.02 <0.02 <0.12 <0.02 <0.04 <0.02 <0.14 0 672 8.3 1242 0.27 40 0.94 <0.92 <0.16 <7.72 1.156 0.273 713
KBH 3D(2015-03-10) 488253 15/0110 20 9.5 35 76 230 4.7 <0.09 <0.02 0.36e-1 0.13 <0.02 <0.02 <0.01 <0.02 <0.05 <0.02 <0.16 <0.02 <0.02 <0.06 <0.02 <0.03 <0.25 <0.02 <0.02 <0.02 <0.12 <0.02 <0.04 <0.02 <0.14 10 216 8.5 869 <0.22 14 19 <0.92 <0.16 <7.72 0.873 5.644 474
KBH 3S(2015-03-10) 488254 15/0110 1.9 30 15 884 1206 <1.84 <0.09 <0.02 0.70e-1 0.14 <0.02 <0.02 <0.01 <0.02 <0.05 <0.02 0.27 <0.02 <0.02 <0.06 <0.02 <0.03 <0.25 <0.02 <0.02 <0.02 <0.12 <0.02 <0.04 <0.02 <0.14 342 1029 9.7 3999 <0.22 72 45 <0.92 <0.16 81 0.833 5.203 2687
KBH 4D(2015-03-10) 488255 15/0110 160 13 171 316 1698 21 <0.09 <0.02 0.78e-1 0.11 <0.02 <0.02 <0.01 <0.02 <0.05 <0.02 <0.16 <0.02 0.26e-1 0.16 <0.02 <0.03 <0.25 <0.02 <0.02 <0.02 <0.12 0.19 <0.04 <0.02 <0.14 0 373 7.2 3395 <0.22 19 60 <0.92 <0.16 <7.72 1.055 4.706 2681
KBH 4S(2015-03-10) 488256 15/0110 207 26 458 1384 5917 16 0.11 <0.02 0.73 0.21 <0.02 <0.02 <0.01 <0.02 <0.05 0.25e-1 <0.16 <0.02 <0.02 1.9 <0.02 <0.03 1.6 <0.02 <0.02 <0.02 <0.12 0.37 <0.04 <0.02 0.15 0 570 7.7 11478 <0.22 54 458 209 1.2 45 0.960 5.856 9332
KBH 6D(2015-03-10) 488257 15/0110 145 4.2 111 55 620 12 <0.09 <0.02 0.65e-1 0.16 <0.02 <0.02 <0.01 <0.02 <0.05 <0.02 <0.16 <0.02 <0.02 0.47 <0.02 <0.03 <0.25 <0.02 <0.02 <0.02 <0.12 0.14 <0.04 <0.02 <0.14 0 292 7.4 1566 <0.22 36 0.77 <0.92 <0.16 <7.72 1.167 2.271 1212
KBH 9D(2015-03-10) 488258 15/0110 440 16 384 285 2959 29 <0.09 <0.02 1.2 0.15 <0.02 <0.02 <0.01 <0.02 <0.05 <0.02 1.3 <0.02 0.22e-1 0.14 <0.02 <0.03 <0.25 <0.02 <0.02 <0.02 <0.12 0.72 <0.04 <0.02 <0.14 0 469 6.9 4655 <0.22 53 42 9.7 <0.16 <7.72 1.400 3.146 4404
KBH 10(2015-03-10) 488259 15/0110 38 38 201 979 5337 12 <0.09 <0.02 1.2 0.11 <0.02 <0.02 <0.01 <0.02 <0.05 <0.02 0.25 <0.02 0.69e-1 0.51 <0.02 <0.03 <0.25 <0.02 <0.02 <0.02 <0.12 0.13 <0.04 <0.02 <0.14 0 1074 8.2 11102 1.3 74 857 <0.92 <0.16 86 0.836 10.325 7201
VBH 1(2015-03-10) 488260 15/0110 44 22 71 338 363 19 <0.09 <0.02 1.2 0.23 <0.02 <0.02 <0.01 <0.02 <0.05 <0.02 <0.16 <0.02 0.40e-1 <0.06 1.1 <0.03 <0.25 <0.02 <0.02 <0.02 <0.12 0.57 <0.04 <0.02 <0.14 4.8 643 8.4 2149 9.3 142 1.8 <0.92 <0.16 0.895 3.038 1462
VBH 2(2015-03-10) 488261 15/0110 5.9 2.6 9.0 63 2.3 3.6 <0.09 <0.02 0.53 0.21 <0.02 <0.02 <0.01 <0.02 <0.05 <0.02 <0.16 <0.02 <0.02 <0.06 <0.02 <0.03 <0.25 <0.02 <0.02 <0.02 <0.12 0.20 <0.04 <0.02 <0.14 14 121 9.0 417 0.40 60 0.82 <0.92 <0.16 0.724 3.808 218
VBH 4D(2015-03-10) 488262 15/0110 46 2.3 24 88 79 21 <0.09 <0.02 0.79 0.41 <0.02 <0.02 <0.01 <0.02 <0.05 <0.02 <0.16 <0.02 0.05 0.15 <0.02 <0.03 <0.25 <0.02 <0.02 <0.02 <0.12 0.66 <0.04 <0.02 <0.14 0 265 8.0 801 0.81 60 <0.43 <0.92 <0.16 0.886 2.751 474
VBH 4M(2015-03-10) 488263 15/0110 20 1.8 13 62 4.6 16 <0.09 <0.02 0.19 0.21 <0.02 <0.02 <0.01 <0.02 <0.05 <0.02 0.71 <0.02 <0.02 0.88 <0.02 <0.03 <0.25 <0.02 <0.02 <0.02 <0.12 0.16 <0.04 <0.02 <0.14 0 160 7.4 513 0.37 74 <0.43 <0.92 <0.16 0.798 5.110 268
VBH 5D(2015-03-10) 488264 15/0110 9.7 1.8 5.8 143 21 11 <0.09 <0.02 1.7 0.32 <0.02 <0.02 <0.01 <0.02 <0.05 <0.02 <0.16 <0.02 0.21e-1 <0.06 <0.02 <0.03 <0.25 <0.02 <0.02 <0.02 <0.12 0.41 <0.04 <0.02 <0.14 0 199 7.8 790 2.0 125 <0.43 <0.92 <0.16 0.684 5.320 440
VBH 5M(2015-03-10) 488265 15/0110 3.4 4.5 2.1 241 2.3 5.2 <0.09 <0.02 0.18 0.16 <0.02 <0.02 <0.01 <0.02 <0.05 <0.02 <0.16 <0.02 <0.02 <0.06 <0.02 <0.03 0.55 <0.02 <0.02 <0.02 <0.12 0.78e-1 <0.04 <0.02 <0.14 48 206 9.3 1319 0.66 295 6.3 <0.92 <0.16 0.587 5.110 684
VWG 10(2015-03-10) 488266 15/0110 361 7.4 186 101 1312 15 <0.09 <0.02 3.6 0.14 <0.02 <0.02 <0.01 <0.02 <0.05 <0.02 <0.16 <0.02 0.81 0.14 <0.02 <0.03 0.40 <0.02 <0.02 <0.02 <0.12 1.1 <0.04 <0.02 <0.14 0 359 7.7 2778 <0.22 117 <0.43 17 0.55 1.288 1.523 2424
SNS BRICS(2015-03-10) 488267 15/0110 144 8.7 84 53 388 22 <0.09 <0.02 1.1 0.14 <0.02 <0.02 <0.01 <0.02 <0.05 <0.02 <0.16 <0.02 0.88e-1 <0.06 <0.02 <0.03 <0.25 <0.02 <0.02 <0.02 <0.12 0.38 <0.04 <0.02 <0.14 0 346 7.4 1373 0.25 60 <0.43 1.5 <0.16 <7.72 1.138 0.485 996
MCSMLQAWP0029,31
MCSMLQAWP0022
MCSMLQAWP0016
Methods
MCSMLQAWP0029,31
MCSMLQAWP0019 & 0020
MCSMLQAWP0026COD, O2 (PPM)
Conductivity @ 25oC(µS/cm)
Al, Cr, Ca, Fe, K, Mg, Mn, Na, P, S-SO4, Sn, Ti, Zn: 1.31%,
As, Ba, Be, B, Cd, Co, Cu, Pb, Hg, Mo, Ni, Se, Sr, V & Zn: 4.954%
pH: 0.414%, Cl: 4.187%, Alk 4.216%
Analytes & UnitsPAlkalinity (CaCO3 PPM),
TotAlkalinity (CaCO3 PPM), pH @ 25
oC, Cl (PPM)
NH3-N, NO3-N, NO2-N, F, CN-, Phenol, Cl, Cr
6+ (PPM)
The components indicated in red on this report are not included in the SANAS Schedule of Accreditation for this laboratory: COND,P-Alkalinity,Cl,SUSP,F-, NO2-N,Phenol,CN
-,Al,As,B,Be,Bi,Co,Cu,Li,Mo,Ni,Sb,Si-SiO2,Sn,Sr,Ti,Turb,Oil,COD,Sulphite & TDS
Expanded Uncertainties: ICP-OES,
Techniques
Potensiometric Titrator:
Photometric:
Conductivity Meter:
Al, Cr, Ca, Fe, K, Mg, Mn, Na, P, S-SO4, Sn, Ti, Zn: (PPM)
NH3-N, NO3-N, NO2-N & Cl: 3.278%
Al, As, Ba, Be, B, Cd, Co, Cu, Pb, Hg, Mo, Ni, Se, Sn, Sr, V & Zn: (PPM)
2015.03.10
2015.03.27
All of the results in this report relate only to the item tested.
Expanded Uncertainties: ICP-MS,
Expanded Uncertainties: Metrohm Titrators
Expanded Uncertainties: Aquakem
ICP-OES:
ICP-MS:
DATE RECEIVED
DATE COMPLETED
COPIES TO
ORIGIN OF SAMPLES
FORM OF TRANSMISSION
MAIN LABORATORY; SANAS Accredited Testing Laboratory No TO260 : ANALYTICAL REPORT
Environmental Management (P_BAMBO)
Hattingh, J
E - mail
Technical Signatory S Nomntu
Tel 016 889 3304
Page 1 of 1