L SDMS DocID 2109716

Final Trip Report Removal Site Evaluation

Carr China Site Grafton, Taylor County, West Virginia

TDD: W33-020-08-07-021 Contract: EP-S3-05-03

October 7, 2008

TechLaw Q u a l i t y & I n t e g r i t y

Prepared for: Dominic Ventura, On-Scene Coordinator U.S. Environmental Protection Agency

1650 Arch Street Philadelphia, PA 19103

AR100001

TABLE OF CONTENTS

Section Page

1.0 INTRODUCTION 1-1 1.1 Scope of Work and Purpose 1-1

2.0 SITE BACKGROUND 2-1 2.1 Site Description and Features 2-1 2.2 Site History 2-1

3.0 INVESTIGATION ACTIVITIES 3-1 3.1 Sampling and Analytical Methodology for Soil and Sediment 3-1

3.1.1 Soil Sampling Activities 3-1 3.1.2 Sediment Sampling Activities 3-1 3.1.3 Soil and Sediment Quality Control (QC) Samples 3-2

4.0 ANALYTICAL RESULTS 4-1 4.1 Soil Sample Results 4-1 4.2 Sediment Sample Results 4-2

5.0 FINDINGS/CONCLUSION 5-1

6.0 REFERENCES 6-1

Figure 1 Site Location Map Figure 2 Sample location Map

FIGURES

TABLES

Table 1 Sample Descriptions Table 2 Validated Analytical Results for Metals in Soil and Sediment Samples Table 3 Validated Analytical Results for Organics in Soil and Sediment Samples

APPENDICES

Appendix A Inorganic Data Validation Reports - Soil and Sediment Samples Appendix B Organic Data Validation Reports - Soil and Sediment Samples Appendix C Photographic Documentation

TDD No.: W33-020-08-07-021

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ACRONYM LIST

Acronym Definition

Cj

bgs

CLP

CRQL

CST

EPA

GPS

ICP-AES

mg/kg

MS/MSD

OASQA

OSC

PM

QA

QC

RBC

SOW SQAP

START

TAL

TCL

Below ground surface

EPA Contract Laboratory Program

Contract Required Quantitation Level

Client Services Team United States Environmental Protection Agency

Global Positioning System Inductively Coupled Plasma - Atomic Emission Spectroscopy

Milligrams per kilogram

Matrix Spike/Matrix Spike Duplicate

Office of Analytical Services Quality Assurance

On-Scene Coordinator

Project Manager

Quality Assurance

Quality Control

Risk-based Concentration

Statement of Work

Sampling QA/QC Work Plan

Superfixnd Technical Assessment and Response Team

Target Analyte List

Target Compound List

TDD No.: W33-020-08-07-021

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c

LO INTRODUCTION

1.1 Scope of Work and Purpose

The United States Environmental Protection Agency (EPA) Region III tasked TechLaw,

Inc., (TechLaw) to conduct a removal site evaluation of the Carr China Site (Site), located in

Grafton, Taylor County, West Virginia. Tasking included collecting soil and sediment samples

from the Site and the adjacent Tygart Valley River, which forms the northern site boundary.

TechLaw conducted the sampling event under Technical Direction Document (TDD) No. W23-

014-08-05-003, issued under EPA Region III, Superfiind Technical Assessment and Response

Team (START) Contract No. EP-S3-05-03. This report was prepared under Contract Option

Year No. 3 TDD No. W33-020-08-07-021.

Activities completed by TechLaw as part of the assessment included: prepared a

sampling quality assurance plan (SQAP) to conduct soil and sediment sampling; arranged

analytical services through the U.S. EPA Region III Office of Analytical Services and Quality

Assurance (OASQA) Client Services Team (CST); collected soil and sediment samples;

submitted samples to the assigned Contract Laboratory Program (CLP) laboratories to be

analyzed; reviewed analytical data and the data validation report; compared analytical results

with EPA Region III soil screening levels, prepared site and sample location maps, and prepared

this report.

The primary goal of the sampling activities was to characterize the site for potential

contamination and determine if contaminants have migrated off site.

TDD No.: W33-020-08-07-021

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2.0 SITE BACKGROUND

2.1 Site Description and Features

The Carr China Site is located on the right descending bank of the Tygart Valley River

south of Grafton, Taylor County, West Virginia. The Site area encompasses approximately 9

acres of land. The Site is divided into a eastem and westem portion by an access road to a river

gauging station. The Site is thickly vegetated with trees and underbrush throughout the Site.

Steep banks descend to the Tygart Valley River, which forms the northem boundary of the Site.

Piles of debris from the former manufacture of china ceramics are scattered throughout the

eastem portion of the Site and along the steep river banks on the westem portion of the Site, as

well as in the River. Remnants of the former Carr China facility buildings, foundations, and

roadways remain in the westem portion of the Site. A cluster of electric poles is located near the

edge of the bank on the westem portion of the Site. A dilapidated chain-link fence extends along

portions of the top of the bank on the westem portion of the Site and along the westem boundary

of the Site. The Site can easily be accessed by pedestrians and vehicles from the road to the

gauging station. Trespassers accessed the Site during the sampling event on all terrain vehicles

(ATV) and a pick up tmck. The roadways and paths across the westem portion of the Site

appeared to have frequent traffic. The Site is bordered to the north by the Tygart Valley River, to

the south by a residential area, and to the east and west by wooded areas.

2.2 Site History

The Carr China Site produced commercial grade china at the site from 1916 through 1952

(OTC, 2008). The factory bumed in 1966 (CCCC, 2008).

WVDEP records indicated that historical sampling at the Site by EPA had discovered

high concentrations of lead. TechLaw did not have a copy of this documentation to reference

details in this Trip report.

2-1 TDD No.: W33-020-08-07-021

AR100005

3.0 INVESTIGATION ACTIVITIES

A Draft Sampling QA/QC Work Plan (SQAP) was submitted electronically to EPA On-

Scene Coordinator (OSC) Dominic Ventura on May 21, 2008. The Sampling Plan outlined

methodologies for collecting and analyzing surface soil samples and sediment samples. Analytical

services were requested through the EPA Region III Office of Analytical Services and Quality

Assurance (OASQA) Client Services Team (CST). Laboratory services were provided under

Contract Laboratory Program (CLP) Case No. 37527.

Sampling activities were conducted on May 28 - 29, 2008. All sampling was accomplished

as outlined in the SQAP, except as noted in this report.

3.1 Sampling and Analytical Methodology for Soil and Sediment

3.1.1 Soil Sampling Activities

TechLaw collected a total of 21 surface soil samples, including two duplicate samples.

Geographic coordinates for sample locations were measured using Trimble ProXH® and Garmin

GPS Plus III global position system (GPS) receivers. Refer to Figure 2 for a depiction of sampling

locations and Table 1 for sampling depth intervals and descriptions.

Surface samples were collected using stainless steel trowels or dedicated plastic scoops and

placed into certified pre-cleaned sample jars. All samples were placed into sample coolers and

stored on ice at 4° Celsius until the samples were packaged and shipped to the assigned laboratory

to be analyzed under Contract Laboratory Program (CLP) Case No. 37527. All soil samples were

analyzed for Target Analyte List (TAL) metals by CLP Statement of Work (SOW) ILM05.4

Inductively Coupled Plasma-Atomic Emission Spectroscopy (ICP-AES). Five of the soil samples

(including one duplicate sample) were also analyzed for Target Compound List (TCL) Semi-

volatile organic compounds (SVOC), pesticides, and Aroclors (PCBs).

3.1.2 Sediment Sampling Activities

TechLaw collected a total of seven sediment samples, including one duplicate sample.

Sediment sample SDOl was collected firom the north side of a small pond on the eastern portion of

the property. Sample SD03 was collected fi-om a drainage basin on the eastem portion of the Site

3-1 TDD No.: W33-020-08-07-021

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that drains into the Tygart Valley River. Sample SD05 was collected fi'om a tributary at the westem

end of the west portion of the Site that also drains into the River. The following sediment sample

were collected fi-om the Tygart Valley River, near the river edge: SD04 and duplicate sample SD07

were background samples collected upstream of the Site; SD06 was collected at the approximate

midpoint of the westem portion of the property, downstream of piles of china debris strewn down

the bank/hill side; and SD02 was collected dowTistream of the Site, just beyond the approximate

eastem property boundary.

Sediment samples were collected using stainless steel trowels or dedicated plastic scoops.

Samples were placed into certified pre-cleaned sample jars and placed into a sample cooler and

stored on ice at 4° Celsius until the samples were packaged and shipped to the assigned laboratory.

The sediment samples were shipped to the same CLP laboratory as the soil samples to be analyzed

for TAL metals by CLP SOW ILM05.4 ICP-AES. None of the sediment samples were analyzed

for organics.

3.1.3 Soil and Sediment Quality Control (QC) Samples

Quality control samples collected included two field soil duplicate samples, a field sediment

duplicate sample, and an equipment rinsate blank. Field duplicate samples are identified in Tables

1 through 3, and Appendices A and B. Additionally, one soil and one sediment sample per batch of

up to 20 samples were designated for matrix spike/matrix spike duplicate (MS/MSD) analysis at the

laboratory.

3-2 TDD No.: W33-020-08-07-021

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4.0 ANALYTICAL RESULTS

4.1 Soil Sample Results

Analytical results for soil and sediment samples were compared to soil screening levels

derived from EPA Regional Screening Levels for Chemical Contaminants at Superfund Sites for

residential soil (ORNL, 2008a). The screening levels used for carcinogens were the Screening

Levels for Residential Soil obtained directly firom the Regional Screening Levels for Chemical

Contaminants at Superfund Sites table (ORNL, 2008a). The screening levels used for non-

carcinogens were derived by dividing the respective analyte concentrations obtained fi-om the

Regional Screening Levels for Chemical Contaminants at Superfund Sites table by 10 to represent a

Hazard Quotient (HQ) of 0.1. This is done during the screening process to account for potential

additive effects (EPA, 2008). The resulting screening level concentrations do not necessarily

represent clean up levels and typical background concentrations for some of the metal analytes

exceed the derived screening levels. Analyte concentrations that exceeded the respective screening

levels were also compared to typical Emergency Removal Goals (ERGs). ERG concentrations

were derived by multiplying the derived residential screening levels for soil by 100. The derived

ERG concentration for carcinogens is representative of 10"* cancer risk and the non-carcinogen

concentrations are representative of an HQ = 10. Note that an ERG for lead cannot be calculated in

this manner because the 400 milligram per kilogram (mg/kg) residential soil screening level listed

in the table was calculated differently than the other metal analytes by using the Integrated

Exposure-Uptake Biokinetic Model (lEUBK) (ORNL, 2008b).

Analytical results for the following metal analytes exceeded the residential soil screening

levels in one or more samples: aluminum; antimony; arsenic; cadmium; iron; lead; manganese; and

thallium (all samples exceeding screening level for thallium were qualified with "B", indicating

likely due to lab cross contamination). Lead concentrations exceeded 1,000 mg/kg in eight of the

21 soil samples. The highest lead concentration was detected in sample SSI5 at 21,600 mg/kg.

Sample SSI 5 was collected in a pile of mixed soil and shredded china debris. The samplers

estimated that the china debris constituted approximately 50 percent of the sample submitted for

analysis. None of the detected analyte concentrations exceeded the respective ERGs. Note that an

4-1 TDD No.: W33-020-08-07-021

AR100008

ERG was not calculated for lead. Table 2 presents complete validated analytical results for metals

in soil samples and provides the residential soil screening levels and ERGs for reference. The

complete data validation report for metals is provided in Appendix A.

Analytical results for the following organic compounds exceeded the residential soil

screening levels in one or more samples: benzo(a)anthracene; benzo(b)fluoranthene;

benzo(a)pyrene; indeno(l,2,3-cd)pyrene; and dibenzo(a,h)anthracene. There were no PCBs

detected in any samples. None of the detected organic compound concentrations exceeded the

respective ERGs. Table 3 presents validated analytical results for organic compounds that were

detected in at least one sample and provides the residential soil screening levels and ERGs for

reference. The complete data validation report for metals is provided in Appendix B.

4.2 Sediment Sample Results

Sediment samples were only analyzed for TAL metals. Table 2 presents complete validated

analytical results for sediment samples and provides the residential soil screening levels and ERGs

( for reference. Note that soil screening levels are not directly applicable to sediment samples and

are provided as a general reference only. All the sediment samples exceeded the residential soil

screening levels for arsenic, iron, and manganese. All sediment samples except SD02 and SD03

also exceeded for thallium. Sample SDOl had the most significant concentrations of detected

analytes, including 59,800 milligrams per kilogram (mg/kg) manganese, which also exceeded the

ERG for residential soil.

The primary evaluation for sediment sample results was a comparison with the background

samples (SD04 and duplicate sample SD07), which were collected in the Tygart Valley River

upstream of the Site. Sediment sample SDOl, which was collected fi-om the pond on the eastem

portion of the property, had concentrations for the following analytes that were significantly

elevated above background (approximately > three times background concentration): barium;

cadmium; calcium; cobalt; lead; manganese; and silver. The pond receives drainage via a culvert

firom off site from the direction of a residential area. (Note that the background sample was

collected in the river and may not be a representative background for SDOL SD03, and SD05.)

4-2 TDD No.: W33-020-08-07-021

AR100009

The only analytes detected at concentrations elevated above background in river sediment

samples were lead and manganese in SD06. Lead was detected at 74.5 mg/kg, slightly higher than

two times the background concentration. Manganese was detected at 1,450 mg/kg, slightly greater

than three times the average concentration in the two background samples. The complete data

validation report for metals in sediment samples is provided in Appendix A.

4-3 TDD No.: W33-020-08-07-02I

AR100010

5.0 FINDINGS/CONCLUSION

Analytical results for soil and sediment samples indicate exceedances of soil screening

levels for many metal analytes and some organic compounds. None of the soil analyte

concentrations exceeded the typical ERG values that were calculated. Note that the method for

calculating the ERGs was not applicable to lead.

The primary contaminant in soil was lead. Elevated lead concentrations were found

throughout the Site, with the highest concentrations apparently associated with the presence of

china debris. However, very high lead concentrations were also detected in the following areas: a

dumping area near the westem end of the Site (8,880 mg/kg in SSI 8); in a sump/pit by a brick kibi

(15,100 mg/kg in SSI9); and in a hole beside a concrete roadway near the center of the westem

portion of the Site (5,860 mg/kg in SS20).

The most significant concentrations of metal analytes in sediment samples were detected in

SDOl, which was collected from a pond which receives drainage from nearby residential areas.

The elevated concentrations detected in SDOl may not be attributable to contaminants from the

Site.

Lead was detected in a sediment sample collected fi-om the Tygart Valley River at a

concentration slightly elevated above the river background (74.5 mg/kg in SD06). Manganese was

also detected in sediment sample SD06 at a concentration significantly greater than background.

These results, as well as the visible china debris in the Tygart Valley River, indicate an off-site

release of contaminants from the Site into the River.

^ 5-1 TDD No.: W33-020-08-07-021

AR100011

6.0 REFERENCES

CCCC, 2008. Carr China Collector's Club, website link: http://carrchina.comy wsn/pagel l.html, September 1, 2008.

EPA, 2008. U. S. Environmental Protection Agency Region III, Memorandum - Risk-Based Concentration Table, Philadelphia, Pennsylvania, May 27, 2008.

ORNL, 2008a. Oak Ridge National Laboratory, Regional Screening Levels for Chemical Contaminants at Superfund Sites, Oak Ridge, Tennessee, July 7, 2008.

ORNL, 2008b. Oak Ridge National Laboratory, Screening Levels for Chemical Contaminants - Users Guide, Oak Ridge, Tennessee, July 7, 2008.

OTC, 2008. Olde Tyme Collectibles, website link: http://oldetvmecoliectiblespotterv.com/histories/carrchina.html, September 1, 2008.

6-1 TDD No.: W33-020-08-07-021

AR100012

FIGURES

TDD No.: W33-020-08-^)7-021

AR100013

iTfjfinr'a

< TechLaw i t l i u / l l y ^. I t i t e g r l t y

TDD No. W334)20-08-07.O21 START Contract No. EP-S3.a5.03

Carr China Site Grafton, Taylor County, WV Figure 1 • Site Location Map

1,200

Map By: SG

Date Modif ied: 8/1/2008

Scale: 1:24,000

Topographic Map Name; Grafton Topo Scale: 1:24,000

AR100014

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TDD No. W33.02D-OB4I7421 START Contract No. EP-S3.0543

Carr China Site Grafton, Taylor County, WV

Rgure 2 - Sample Location Map 200 100 200 Feet

Map By: SG

Date Modified: 7/24/2008

Scale: 1:2,091

Aenal Orthophoto Source: WVSAKIB OrttioplMtoFile Name: n-k11.02. and n•*. •<S3 Time Periotl of Comant: Sptinj ai 2003 Note: Sample tocstions collected using a combination o( a Trimble GPS unil, a Garmin GPS Plus II) unit, and a geospatially con^cted aeridJ photograph.

AR100015

TABLES

TDD No.: W33-020-08-07-021

AR100016

Table 1 Sample Descriptions

CarrCliina Site Grafton, Taylor County, West Virginia

Sample No. ("CC-" prefix omitted in table)

... _ .

Depth (bgs) Description/Sample location

Samples Collected from Eastern Portion of Site SS01 SS02 SS03 SS04 SD01 SD02

SD03

0" - 4" 0" - 4" 0" - 6" 0" - 2" 0" - 3" 0" - 3"

0" - 3"

From area with scattered china debris. Banks of drainage basin area in middle of northern portion of Site. From area with china debris near the pond in southeast corner. From area with white sandy material in hole under uprooted tree. North side of pond in the southeast corner of the eastern portion of Site. 11 From edge of Tygart Valley River, just downstream of the Site. Drainage basin area in middle of eastern portion of Site that drains to Tygart Valley River, near sewage outfall pipe.

Samples Collected from Western Portion of Site I SS05 SS06 SS07 SS08 SS09

8810 8811 8812 SSI 3 SS14

8815

8S16

8817

8S18 8819

8820 8830 8D04 SD05

8D06 8D07

0" - 3" 0" - 4" 0" - 4" 0" - 3" 0" - 4"

0" - 4" 0" - 3" 0"-12" 0"-12" 0" - 3"

0"-12"

0"-12"

0" - 4"

0" - 4" 0"-12"

0" - 6" 0" - 4" 0" - 3" 0" - 3"

0" - 2" 0" - 3"

Black-colored soil over layer of bricks. Low area outside western fence in the vicinity of scattered metal debris. Black-colored soil with some white fines/sand intermixed. In vicinity of a cluster of several power poles. White sand beside bag house hopper. Black-colored soil mixed with scrap china debris. Located down the hill side (river bank) from a steel drain pipe. Black-colored soil. From black, coal-like material near northwestern corner of Site. Du^icate of sample 8812. From sandbar at edge of Tygart River, below pile of china srap/debris. From pile of mixed soil and shredded china debris (sample colected consisted of ~ 50% china debris). Collected from under pile of shredded, glazed china. Black soil with white fines and some china debris. From drainage pathway down bank near edge of Tygart Valley River. A pile of plates was at the surface. In the middle of a garbage dumping area near southwestern corner of the Site, near fenceline. From sump/pit beside brick kiln. Near middle of the western portion of Site. Black soil in hole beside concrete roadway. Duplicate of sample 8817. Upstream background sample in Tygart Valley River. From tributary at westem property boundary. From Tygart Valley River, near midpoint of western portion of property, west of 8817. Piles of china debris all over the river banks. Duplicate of sample 8D04.

Key: SS = surface soil sample SD = sediment sample

TDD No.: W33-020-08-07-021

AR100017

Table 2 Validated Analytical Results for Metals in Soil and Sediment Samples

Carr China Site Grafton, Taylor County, West Virginia

May 28-29, 2008 Sampling Event

1 Sample Number:

Sampling Location :

Field QC :

Matrix : Units:

Date Sampled : Time Sampled :

%Solids : Dilution Factor:

A M A L W ^ ALUMINUM ANTIMONY

ARSENIC (C)

BARIUM

BERYLLIUM CADMIUM CALCIUM

CHROMIUM

COBALT COPPER IRON

•LEAD

MAGNESIUM

MANGANESE MERCURY

NICKEL POTASSIUM

SELENIUM

SILVER

SODIUM THALLIUM

VANADIUM ZINC

CR<5L 20

6 1

20

0.5

0.5

500 1

5

2.5 10

1

500 1.5 0.1

4 500

3.5

1

500

2.5

5 6

MC0096

CC.SS01

Soil mg/Kg 5/28C008 12:52

59.8 1.0

kesult 917

0.62 1.7

65.1

0.086

0.92 5000

4.9

6.5

47.5 4390

96B

255 294

0.16 4.0 144

1.2 0.19

37.0

2.5 134

\'\ag

B

J

J

J

J J

J J

J B

J

MC0097

CC-SS02

Soil mg/Kg 5/28«008 13:10

60.7 1.0

l^esult 2880

3.5 62.4

0.37 0.79

3050

5.8 8.8

21.9

10300 303

347 418

0.15 7.6

244 0.74

36.7

0.49

4.8 145

t lag

R

J J

J

J

J J UL

B

B

J

MC0098

CC-SS03

Soil mg/Kg 5/28/2008 13:00

72.8 1.0

Result

1930 1.1

1.3

52.3 0.13

0.85

4280

12.7 21.9

34.2 1200

865 271

160 0.085

2.1

197

0.41

53.8

2.5 139

Flag

B

J

J

J

J J J

J UL

B

J

MC0099 CC-SS04

Soil mg/Kg 5/28/2008 13:29

79.9 1.0

Result

2320 1.8

2.6 86.8

0.20

0.87

2980

4.0

36.7 56.9

2730

: 1390 1220 164

0.046

4.8 197

0.087

52.2

8.3 156

Flag

J

J

J J

J

J

B

MCOOAO CC-SS05

Soil mg/Kg 5/28/2008 14:13

37.6 1.0

Resul:

4390

64.2 ::, 2.9

448 0.27

1.6

19800

8.8

28.4 46.1

5880

1850

1910 . 299

0.11 7.3

953

2.5

0.35

204

11.5 805

Flag

J

J

J

MCQ0A1

CC-SS06

Soil mg/Kg 5/28/2008 14:30

28.8 1.0

Result

1170 3.0

91.3

0.090 3.5

16600

4.1

5.5

46.8 4130

1100

639 165

0.18

4.7

393

2.3

79.5

2.4 466

Flag

J UL

J

J

J

J J J

J UL

B

J

_

MCO0A2

CC-SS07

Soil mg/Kg 5/28/2008 14:23

39.0 1.0

Result

1140 1.9

0.90

87.5 0.11

0.83

12600

3.6

2.9

22.8

•:• 6140 291 649

.: 211 014

4.7

359

2.2

68.7

2.2 231

Flag

B

J

J J

J

J

J J J

J UL

B

J

_

MC00A3

CC.SS08

Soil mg/Kg 5/28/2008 14:35

40.9 1.0

Result

1750

. 695 4.5

144

0.16

2.6

11300

6.3

2.8 78.4

15800

395 588

.271 '

0.12 6.6

290

2.0

51.4

3.7 553

Flag

J

J

J

J

J

J J

J UL

B

J

_

MC00A6

CC-SS09

Soil mg/Kg 5/28/2008 1533

81.6 1.0

Result

127

22.0

0.042

63.6

4.1

1.7

1520

35.6

4.1

2.8

24.4

27.1

0.20 5.6

Flag

R

UL

J

J

J

J

J B

UL

B

J J

Residential

RBC Screening Levels

for Soils ' (mg/kg)

7,700

3.1

0.39

1,500

16

70

NL

12,000 NL

310

5,500 400

NL 180

0.67

14,000

NL

39 39

NL

0.51

39 2,300

ERG

for Soils ^ (mg/kg)

770,000 310

39 150,000

1,600

7,000

NA

1,200,000 NA

31,000

550,000 NA

NA 18,000

67

1,400,000

NA

3,900

3,900

NA

51

3,900 230,000

Key at end of Table.

TDD No,; VV33-02Q-Q8-07-021 AR100018

Table 2 Validated Analytical Results for Metals in Soil and Sediment Samples

Carr China Site Grafton, Taylor County, West Virginia

May 28-29, 2008 Sampling Event

Sample Number:

Sampling Location:

Field QC :

Matrix : Uni ts :

Date Sampled:

Time Sampled :

%Solids : Dilution Factor:

AWALVVe ALUMINUM

ANTIMONY ARSENIC (C) BARIUM

BERYLLIUM CADMIUM

CALCIUM

CHROMIUM COBALT

COPPER IRON

•LEAD MAGNESIUM

MANGANESE MERCURY

NICKEL POTASSIUM

SELENIUM

SILVER

SODIUM THALLIUM

VANADIUM ZINC

CWL 20

6 1

20

0.5 0.5

500

1

5 2.5 10

1

500

1.5

0.1 4

500 3.5

1 500

2.5

5 6

MC00A7

CC.SS10

Soil

mg/Kg

5/28/2008

15:40

28.0 1.0/4.0

Result

1620

22.6

114

77.1

12800 72.6

14.6 260

283000 + 4710

795 1310 0.24

56.6 681

9.2

4.7

166

16000 +

Flag

R

J

J

J

J J

B

UL

MC00A8

CC-SS11

Soil

mg/Kg

5/28/2008

15:45

66.7 1.0

Result

5660

31.3 " 6 . 8

214

0.81

2.2

17600

9.5 2.3

20.1

26300 703

2210

592

0.074

7.9 554

2.1 0.90

138 0.73

4.9 326

Flag

J

J

J

J J

J J

B

J

MCOOBO CC-SS12 Dup. of

CC.SS13

Soil mg/Kg 5/28/2008 16:16

74.5 1.0

Result

5800

4.1

285

0.70 0.26

3140

4.2 4.0

49.8

13100 247

258

46.5

7.6

235

1.1 0.24

199 ; . 0.65

15.8 22.7

Flag

R

J

J

J

J

J

J J B

MC00B1 CC-SS13 Dup. of

CC.SS12

Soil mg/Kg 5/28/2008 16:21

77.8 1.0

Result

5350

• 4.3

232 0.60

0.18

2810

3.1 2.7

36.2

: 6590 : 161

221

37.4

5.5

190 0.44

178 0.49

14.8 16.0

Flag

R

J

J

J

J

J J UL

J B

MC00B3

CC.SS14

Soil

mg/Kg

5/28/2008

17:08

61.6 1.0

Result

6730

. 4.8

122

1.0

0.82

1540 10.2

23.6 21.4

.15900 43.6

648

1730 0.047

26.6

517

0.17

45.2

0.63

103 110

Flag

R

J

J

J B

B

MC00B2

CC.SS15

Soil

mg/Kg

5/28/2008

16:56

75.2 1.0/4.0

Result

6270 1.3

4.6 581

0.83

0.95

4740

8.6 26.6

113

11100 21600 +

605

1660

0.044 34.1

1100

0.51

2110

1.2

29.4 144

Flag

J

J

J

J

J

MC0OA9

CC-SS16

Soil mg/Kg 5/28/2008 16.04

71.3 1.0

Result

675

2.9 0.54

30.1

0.049

095

2020

8.9 17.1

22.7

2040 592

162 74.4

0.021 3.5

111

45.2

6.5

Flag

J J

J

J

J J

J

UL

B

J

MC00A4 CC-SS17 Dup. of

CC.SS30

Soil mg/Kg 5/28/2008 14:43

74.0 1.0

Result

5810

3.5

87.7

0.81

0.82

1390

9.2 28.5

15.3 11400

342 523

1870 0.044

32.0

488

64.6 0.37

7.5 158

Flag

R

J

J

J

UL

B

B

MC00A5 CC-SS30 Dup, of

CC.SS17

Soil mg/Kg 5/28/2008 14:53

75.3 1.0

Result

5160

3.5

87.5

0.86

0.78

1340

9.4

30.3 15.5

11800 341 500

2110

0.051 34.3

413

0.48

37.1

0.70

7.2 167

Flag

UL

J

J

J

B

B

B

Residential

RBC

Screening Levels

for Soils '

(mg/kg)

7,700

3.1

0.39

1,500

16 70

NL 12,000

NL 310

5,500

400 NL

180

0.67

14,000

NL

39

39

NL

0.51

39 2,300

ERG

for Soils ^

(mg/kg)

770,000

310

39 150,000

1,600 7,000

NA 1,200,000

NA

31,000

550,000

NA NA

18,000 67

1,400,000

NA

3,900

3,900

NA

51

3,900 230,000

Key at end of Table.

TPD No,: W33^)20-08-07^)21 AR100019

Table 2 Validated Analytical Results for Metals in Soil and Sediment Samples

Carr China Site Grafton, Taylor County, West Virginia

May 28-29, 2008 Sampling Event

Sample Number: Sampling Location : Field QC :

Matrix : Units:

Date Sampled :

Time Sampled :

%Sol ids: Dilution Factor:

ANALYTE

ALUMINUM ANTIMONY

ARSENIC (C) BARIUM BERYLLIUM

CADMIUM CALCIUM CHROMIUM

COBALT

COPPER IRON

•LEAD

MAGNESIUM MANGANESE MERCURY

NICKEL

POTASSIUM SELENIUM SILVER

SODIUM

THALLIUM

VANADIUM ZINC

CRQL

20 6

1

20 0.5

0.5

500

1 5

2.5 10

1

500 1.5

0.1 4

500 3.5

1 500 2.5

5 6

MC00B4

CC.SS18

Soil mg/Kg

5/28«008

17:37

68.7 1.0

Result

3730 1.6

3.8

901 0.43

2.1 12400

7.7

8.6

108 8880

189

1350 308

0.066 12.7 326

0.71

1.1

84.7

0.48

10.3 664

Flag

J

J

J

J J

B B

MC00B5

CC-SS19

Soil

mg/Kg

5/28/2008

17:45

69.6 1.0

Result

6870

3.8 71.7 0 71

0.32

3040 9.1

7.6 9.4

15100 30.7

844 439

0046

10.6 556

0.58 0.69

60.5

1.0

11.5 46.0

Flag

UL

J J

J

J J B

B J

MCOOBO

CC-SS20

Soil mg/Kg

5/28/2008 17:55

81.5 1.0

Result

3130

6.5

2.3 123

0.29 3.3

10400

7.4 5.3

84.0

5860

645 1120

335: 0.O76

7.0 462

1.3 0.63 86.9

0.22

7.7 798

Flag

J

J

J

J

J

J B B

B

Result Flag Result Flag Result Flag Result Flag Result Flag

Residential

RBC Screening Levels '

for Soils (mg/kg)

7,700

3.1

0.39 1,500

16 70

NL

12,000

NL 310

5,500

400

NL

180 0.67

14,000

NL

39 39

NL 0.51

39 2,300

E R G " for Soils (mg/kg)

770,000

310

39

150,000

1,600

7,000

NA

1,200,000 NA

31,000

550,000

NA NA

18,000 67

1,400,000

NA 3,900

3,900 NA

51

3,900 230,000

Key at end of Table.

TDD No.: W33-020-08-07-021 AR100020

Table 2 Validated Analytical Results for Metals In Soli and Sediment Samples

Carr China Site Grafton, Taylor County, West Virginia

May 28-29, 2008 Sampling Event

Sample Number:

Sampling Location :

Field QC :

Matrix: Units :

Date Sampled : Time Sampled : %Solids :

AhjALVVe ALUMINUM ANTIMONY

ARSENIC (C) BARIUM

BERYLLIUM CADMIUM

CALCIUM CHROMIUM

COBALT

COPPER

IRON

•LEAD

MAGNESIUM

MANGANESE

MERCURY

NICKEL

POTASSIUM

SELENIUM

SILVER

SODIUM

THALLIUM

VANADIUM

ZINC

CWL

20

6

1 20

0.5

0.5

500 1

5

2.5

10

1

500

1.5

0.1

4

500

3.5

1

500

2.5

5

6

MC0088

CC-SD01

Soil mg/Kg

5/28O00S 13:35

20.3

Result

7660

11.2: 1610 0.76

3.5

12500

12.8 93.8

48.5

. 77300

294

1120

•i^saam, 0.16

43.7

1060

4.0

181

3.5

443

Flag

UL

J

J

J

J

J

B

MC0089

CC-SD02

Soil mg/Kg

5/28/2008

13:48

72.8

Result

3070

. : 1.8 33.5 0.39

0.17

117

4.8 7.9

4.7

7740

8.2

399

339

58

356

22.8

0.36

5.0

21.2

Flag

UL

J J

J

J

J

UL

B

B

1

MC0091

CC-SD03

Soil mg/Kg

5/28/2008 13:20

742

Result

5820

• 2:1 60.0

0.57

0.33

821

8.5 7.8

9 5

9380

17.4

724

296

0.028

9.4

551

072

0.18

62.0

050

9.3

51.9

Flag

UL

J J

J

J

J

J

B

B

MC0093 CC-SD04

Dup. of CC.SD07

Soil

mg/Kg 5/28/2008

17:25 59.7

Result

11300

9.2 89.0

2.2 0.78

358 14.2

14.6

38.4

28400

29.9

813

431

0.12

27.1

811

1.5

0.60

38.9

' 1.4

14.0

169

Flag

UL

J J

J

J

J

J

J

B

J

MC0094

CC-SD05

Soil

mg/Kg

5/28/2008

17:15

72.0

Result

4900

4.3 130

0.60

0.52

3140 11.4

9.0

13.6

19500

39.3

888

443

0.031

11.9

581

0.60

0.62

52.5

0.97

106

Flag

UL

J J

J

J

J

B

B

J

MC0092 CC-SD06

Soil

mg/Kg 5/28/2008

15:15 70.8

Result

4110

4.0^ 63.4

0.71

0.87

826

7.8 18.0

11.8

17400

74.5

459

1450

0.025

24.2

474

0.58

0.29

35.9

0.79

6.5

146

Flag

UL

J

J

J

J

J 8

B

MC0095 CC-SD07

Dup. of CC.SD04

Soil mg/Kg

5/28/2008

17:30 59.7

Result

9660

8.3 846

2.1 071

373

12.3 14.1

37.5

26300

29.0

696

520

0.15

27.1

567

1.2

0.69

37.0

1.3

11.6

167

Flag

UL

J J

J

J

J

J

B

B

J

Result Flag

Residential

RBC Screening Levels '

for Soils

7.700 3.1

0.39 1,500

16

70

NL

12,000

NL

310

5,500

400

NL

180

0.67

14,000

NL

39

39

NL

0.51

39

2,300

E R G "

for Soils

770,000 310

39

150,000

1,600

7,000

NA

1,200,000

NA

31,000

550,000

NA

NA

18,000

67

1,400,000

NA

3,900

3,900

NA

51

3,900

230,000

Key: (C) = Carcinogen

CRQL = Contract Required Quantitation Limit

DUP = Duplicate sample

ERG = Emergency Removal Goal

mg/kg = milligrams per kilogram

RBC = EPA Region III Risk-based Concentration

To calculate sample quantitation limits. (CRQL ' Dilution Factor) / (%Solids/100)

-t- = Result reported from diluted analysis.

Notes: Yellow highlighted cells Indicate that the concentration exceeded the soil screening level. Green highlighted cells indicate that the concentration exceeded the Region III ERG.

1. Based upon Regional Screening Levels for Chemical Contamirrants at Superfund Sites, July 7, 2008. Screening levels tor non-carcinogens derived by dividing Table RBC by 10 to give concentration representing a Hazard Quotient (HO) = 0.1, to account for potential additive effects. RBC table values used for screening levels for carcinogens.

2. EPA Region til ERG derived by multiplying the screening RBC by 100. Concentration represents a i d cancer risk for carcinogens and an HQ = 10 for norv-carcinogens.

TDD No.: W33-020-08^7-021 AR100021

Table 3 Validated Analytical Results for Detected Organics in Soil and Sediment Samples

Carr China Site Grafton, Taylor County, West Virginia

Case #: 37527

DATA SUMMARY OF DETECTED SEMIVOLATILE ORGANIC COMPOUNDS

SDG : C0097

1 Sample Number:

Sampling Location:

Field QC

Matrix:

Units :

Date Sampled :

Time Sampled :

%Moisture:

1 Dilution Factor;

1 Semivolatile Compound

1 Naphthalene ( C )

2-Methylnaphthalene

Dibenzofuran

Phenanthrene

1 Anthracene

1 Carbazole(C)

1 Fluoranthene

Pyrene

Benzo(a)anthracene ( C )

Chrysene ( C )

[Bis(2-ethylhexyl)phthalate (C )

1 Benzo(b)fluoranthene ( C )

1 Benzo(k)fluoranthene ( C )

Benzo(a)pyrene ( C )

1 lndeno(1,2,3-cd)pyrene (C )

Dibenzo(a,h)anthracene (C )

1 Benzo(g,h,i)perylene

CRQL

170

170

170

170

170

170

170

170

170

170

170

170

170

170

170

170

170

00097

CC-SS02

Soil

ug/Kg

5/28/2008

13:10

36

0.99

Resul

30

44

50

63

32

51

63

80

33

33 •

Flag

J

J

J

J

J

J

J

J

J

J

C00A3RE

CC-SS08

Soil

ug/Kg

5/28/2008

14:35

65

,0.99

Resul

130

250

95

860

170

150

2000

2900

1400

1500

71

2400

1000

1200

530

170:

370

Flag

J

J

J

J

J

J

J

J

J

J

J

J

J

C00A4

CC-SS17

Dup. of

CC-SS30

Soil

ug/Kg

5/28/2008

14:43

25

0.99

Resul

23

60

110

130

67

85

290

120

52

63

34

31

Flag

J

J

J

J

J

J

J

J

J

J

J

J

C00A5

CC-SS30

Dup. of

CC-SS17

Soil

ug/Kg

5/28/2008

14:53

26

0.99

Result

230

41

41

390

380

190

180

58

280

130

150

60

47

Flag

UL

J

J

J

J

J

J

J

J

J

J

J

COOBO

CC-SS12

Soil

ug/Kg

5/28/2008

16:16

22 1.0

Result

46

96

30

170

81

80

56

88

46

100

31

35

Flag

J

J

J

J

J

J

J

J

J

J

J

J

Residential

RBC

Screening Levels

for Soils'

(ug/kg)

3,900

31,000

NL

NL

1,700,000

24,000

230,000

170,000

150

15,000

35,000

150

1,500

15

150

15

NL

ERG

for Soils ^

(ug/kg)

390,000

3,100,000

NA

NA

170,000,000

2,400,000

23,000,000

17,000,000

15,000

1,500,000

3,500,000

15,000

150,000

1,500

15,000

1,500

NL

CRQL = Contract Required Quantitation Limit SEE NARRATIVE FOR CODE DEFINITIONS

To calculate sample quantitation limits: (CRQL ' Dilution Factor) / [(100 - %Moistur8) /100] . Revised 09/99

* Based upon Regional Screening Levels for Chemical Contaminants at Superfund Sites, July 7, 2008.

TDD No.: W33-020-08-07-021 AR100022

Table 3 Validated Analytical Results for Detected Organics in Soil and Sediment Samples

Carr China Site Grafton, Taylor County, West Virginia

Case #: 37527

DATA SUMMARY O DETECTED ORGANOCHLORINE PESTICIDES

SOG: 00097

(

1 Sample Number:

Sampling Location :

Field QC :

Matrix:

Units:

Date Sampled :

Time Sampled :

%Moisture:

1 Dilution Factor:

1 Pesticide Compound

4,4'-DDD (C )

Endosulfan sulfate

4,4'-DDT ( C )

Endrin ketone

1 Endrin aldehyde

1 gamma-Ohlordane ( 0 )

CRQL

3.3

3.3

3.3

3.3

3 3

1.7

C0097

CC-SS02

Soil

ug/Kg

5/28/2008

13:10

36

,0.99

Resul Flag

1

C00A3

OC-SS08

Soil

ug/Kg

5/28/2008

14:35

65

0.99

Resul

7.0

8.6

6.6

Flag

J

J

J

1

C00A4

CC-SS17

Dup. of

CC-SS30

Soil

ug/Kg

5/28/2008

14:43

25

0.99

Resul

6.0

Flag

J

C00A5

CO-SS30

Dup. of

CC-SS17

Soil

ug/Kg

5/28/2008

14:53

26

1.0

Resul

2.3

2.5

3.1

2.3

Flag

J

J

J

J

1

COOBO

CC-SS12

Soil

ug/Kg

5/28/2008

16:16

22

,0.98

Result

5.3

3.3

2.3

Flag

J

J

J 1

Residential

RBC

Screening Levels

for Soils '

(ug/kg)

2,000

37,000

1,700

1,800

1,800

1,600

ERG

for Soils ^

(ug/kg)

200,000

3,700,000

170,000

180,000

180,000

160,000

CRQL = Contract Required Quantitation Limit To calculate sample quantitation limits: (CRQL * Dilution Factor) / [(100 - %Moisture) /100]

Key: (0) = Carcinogen

CRQL = Contract Required Quantitation Limit DUP = Duplicate sample ERG = Emergency Removal Goal mg/kg = milligrams per kilogram RBC = EPA Region III Risk-based Concentration

To calculate sample quantitation limits: (CRQL * Dilution Factor) / {%Solids/100) + = Result reported from diluted analysis.

SEE NARRATIVE FOR CODE DEFINITIONS

Notes: Yellow highlighted cells indicate that the concentration exceeded the soil screening level.

1. Based upon Regional Screening Levels for Chemic:al Contaminants at Superfund Sites, July 7, 2008. Screening levels for non-carcinogens vtras derived by dividing the Table Screening Level by 10 to give the concentration representing a Hazard Quotient (HQ) = 0.1, to account for potential additive effects. Table values are used for screening levels for carcinigens.

2. EPA Region III ERG derived by multiplying the derived Screening Level by 100. The concentration represents a 10 •* cancer risk for carcinogens and an HQ = 10 for non-carcinogens.

TDD No.: W33-020-08-07-021 AR100023

APPENDIX A

TDD No.: W33-020-08-07-021

AR100024

UNITED STATES ENVIRONMENTAL PROTECTION AGENCY REGION III

ENVIRONMENTAL SCIENCE CENTER 701 MAPES ROAD

FORT MEADE, MARYLAND 20755-5350

DATE : J u l y 16 , 2008

SUBJECT: R e g i o n I I I D a t a QA Review

FROM

TO

Colleen Walling CUiK.(C . t \ ) Region III ESAT RPO {3EA20)

Dominic Ventura Regional Project Manager (3HS32}

Attached is the inorganic data validation report for the Carr China site (Case # 37527; SDG # MC0087, MC0096) completed by the Region III Environmental Services Assistance Team (ESAT) contractor under the direction of Region III EAID,

If you have any questions regarding this review, please call me at (410) 305-2763.

Attachments

cc: Gene Nance (TECH LAW)

TO File #: 0014 TDF#: 0661

OFFICE OF ANALYTICAL SERVICES AND QUALITY ASSURANCE

AR100025

LOCKHEED M A I T T T U T Z We never forget who we 're working for'"

Lockheed Martin Enterprise Solutions & Servioes ESAT Region 3 US EPA Environmental Science Center 701 Mapes Road FL Meade, MD 20755-5350 Telephone 410-305-3037 Facsimile 410-305-3597

DATE: July 10,2008

SUBJECT: Level IM2 Inorganic Data Validation for Case 37527 SDGs: MC0087 & MC0096 Site: Carr China

FROM: ShilpaUdanis^ Inorganic Data Reviewer

Through: Mahboobeh Mecanic **** Senior Data Review Chemist

TO:

(

Colleen Walling ESAT Region 3 Project Officer

OVERVIEW

Case 37527, Sample Delivery Groups (SDGs) MC0087 & MC0096, consisted of twenty-eight (28) soil samples and one (1) rinsate blank submitted to Datachem Laboratories, Inc. (DATAC) for total metals analyses. The sample set included three (3) field duplicate pairs. Samples were analyzed in accordance with Contract Laboratory Program (CLP) Statement of Work (SOW) ILM05.4 through the Routine Analytical Services (RAS) program.

SUMMARY

Data were validated according to the Region III Modifications to the National Fimctional Guidelines for Inorganic Data Review, level IM2. Areas of concern wdth respect to data usability are listed below.

Data in this Case have been impacted by outliers present in laboratory blanks as well as laboratory duplicate and matrix spike analyses. E)etails for these outliers are discussed under "Major and Minor Problems", specific samples affected are outlined in "Table 1 A" and qualified analytical results for all samples are summarized on the Data Summary Forms (DSFs).

Positive results reported in the rinsate blank were used to evaluate field contamination in both SDGs. No data were impacted by the rinsate blank results.

AR100026

Page 2 of 4

MAJOR PROBLEM

The matrix spike recovery was extremely low (< 30%) for antimony (Sb) in SDG MC0096. Positive results reported for this analyte may be biased extremely low. The "L" qualifier for this outlier has been superseded by "J" or "B" on the Data Summary Forms (DSFs), Quantitation limits for this analyte in affected samples were rejected and qualified "R" on the SDGs.

MINOR PROBLEMS

Preparation (PB) and/or Continuing Calibration (CCB) Blanks had reported results greater than the Method Detection Limits (MDLs) for the analytes listed below. Positive results reported for these analytes in affected samples which are less than or equal to five times (i5X) the blank concentrations may be biased high and have been qualified "B" on the DSFs,

SDG MC0087

MC0096

Matrix Soil

Aqueous

Soil

Blank PB CCB PB

PB CCB

Analytes sodium (Na) silver (Ag), thallium (Tl) barium (Ba), calcium (Ca), chromium (Cr), iron (Fe), lead (Pb), Na

potassium (K), Na Sb, thallium (Tl)

PB and/or CCBs had negative results greater than the absolute values of the MDLs for the analytes listed below. Positive results reported for these analytes in affected samples which are less than or equal to two times (< 2X) the absolute values of the blank concentrations may be biased low and have been qualified "L" on the DSFs unless superseded by "J" or "B". Quantitation limits for these analytes in affected samples may be biased low and have been qualified "UL" on the DSFs.

SDG MC0087

MC0096

Matrix Soil Aqueous

Soil

Blank CCB PB

PB CCB

Anglytes Ag arsenic (As), Ag

As, Ag Ag.V

The Relative Percent Difference (RPD) for the laboratory duplicate analysis was outside control limits (35% RPD or ±2CRQL) for Sb in SDG MC0096. Reported results for this analyte are estimated in this SDG and have been qualified "J" unless superseded by "B" on the DSFs. The "UJ" qualifier for this outlier in affected samples is superseded by "R" on he DSFs.

AR100027

(

Page 3 of4

The matrix spike recovery was low (<75% but > 30%) for Sb in SDG MC0087. Low recoveries may be attributed to matrix interferences or analyte lost during the digestion process. Reported results for this ananlyte in affected samples may be biased low. The "L" qualifier has been superseded by "J" on the DSFs. Quantitation limit for this analyte in affected samples may be biased low and have been qualified "UL" on the DSFs.

Positive results which are less than the Contract Required Quantitation Limits (CRQLs) but greater than MDLs have been qualified "J" on the DSFs unless superseded by "B".

The following samples were reanalyzed at dilution in order to bring the concentrations of analytes listed below within the established calibration range. The results for these analytes in these samples are reported from the diluted analysis and annotated with a "+" on the DSFs.

SDG MC0087 MC0096

Sample MC0088 MC00A7 MC00B2

Dilution Factor 2.0 X 4.0 X 4.0 X

Analvte manganese (Mn) Fe, zinc (Zn) Pb

RPDs for the laboratory duplicate analysis were outside contractual control limits (20% RPD or ±CRQL) for Mn in SDG MC0087 and for Cr and Fe in SDG MC0096. However, RPDs for these analytes in this SDG were within Region 3 established control limits (35% RPD, or ±2XCRQL) for soil analysis. No data were qualified for these analytes in these SDGs based on laboratory duplicate imprecision.

Reported results for field duplicate pair MC0093/MC0095 in SDG MC0087 were within 35% RPD, ± 2XCRQL for all analytes.

Reported results for field duplicate pair MC00A4/MC00A5 (SDG MC0096/MC0087) were within 35% RPD, ± 2XCRQL for all analytes.

Reported results for field duplicate pair MCOOBO/MCOOB1 in SDG MC0096 were within 35% RPD, -t 2XCRQL for all analytes except for Fe and Pb.

AR100028

Page 4 of4

Data for Case 37527, SDGs MC0087 & MC0096, were reviewed in accordance with Region III Modifications to the National Functional Guidelines for Evaluating Inorganic Analyses, April 1993.

ATTACHMENTS

INFORMATION REGARDING REPORT CONTENT

TABLES 1A SUMMARY OF QUALIFIERS ON DATA SUMMARY FORMS AFTER DATA VALIDATION

TABLE 1B CODES USED IN COMMENTS COLUMN OF TABLES 1A APPENDIX A GLOSSARY OF DATA QUALIFIER CODES APPENDIX B DATA SUMMARY FORM(S) APPENDIX C CHAIN OF CUSTODY RECORD(S) APPENDIX D LABORATORY CASE NARRATIVE(S)

DCN: 37527 MC0087 & MC0096. IM2

AR100029

Page 1 of3

TABLElA SUMMARY OF QUALIFIERS ON DATA SUMMARY

FORM AFTER DATA VALIDATION

Case 37527, SDG MC0087

Na

Tl

ANALYTE Sb

As

Ba

Ca

Cr

Fe

Pb

Ag

SAMPLES AFFECTED All Samples Except MC00B4, MC00B6 MC0087

MC00B4, MC00B6

MC0087

MC0087

MC0087

MC0087

MC0087

MC0087

MC0087

MC0089

POSITIVE VALUES

J

B

B

B

B

B

NON-DETECTED VALUES

UL

UL

UL

UL

BLAS Low

Low

High

High

High

High

High

Low

Low

COMMENTS* MSL(41%)

>MDL<CRQL MSL(41%)

PBN(-2.906Jug/L)

PB(0.542Jug/L)

PB (34.545 J ug/L)

PB (0.676 J ug/L)

PB (22.809 J ug/L)

PB (L203 J ug/L)

PBN (- 2.020 J ug/L)

PBN(-0.161 J mg/Kg)

MC0091, MC0092 J

MC00A5, MC0OB5, B MC00B6, MC0094, MC0095

All Soil Samples B

MC0087 B

All Soli Samples Except B MC00B5, MC0088, MC0093, MC0094, MC0095. MC0087

>MDL<CRQL PBN (-0.161J mg/Kg)

High CCB (1.509 J ug/L)

High PB (19.825 J mg/Kg)

High PB (309.600 J ug/L)

High CCB (1.180 J ug/L)

See explanation of comments in Table IB

AR100030

Page 2 of 3

TABLE lA SUMMARY OF QUALIFIERS ON DATA SUMMARY

FORM AFTER DATA VALIDATION

Case 37527, SDG MC0096

SAMPLES ANALYTE AFFECTED Sb MC00A2, MC0096,

MC0098

MC00A4, MC00A6, MC00A7, MCOOBO, MC00B1,MC00B3, MC0097

MCOOAO, MCOOA I, MC00A3, MC0OA8, MC00A9, MC0OB2 MC0099

As

K

Ag

MCOOA 1,MC00A6

MC00A2, MC00A9

MC0OA6

MCOOA 1,MC00A2, MC00A3, MC0GA4, MC0OA6, MC00A9, MC00B1,MC0097, MC0098

MCOOAO, MC0096, MC0099

MCOOBO, MC00B3

POSITIVE VALUES

B

B

NON-DETECTED VALUES

UL

UL

BIAS COMMENTS* High CCB (1.977 J ug/L)

MSE (24%) DUP (127%)

Ext. MSE (24%) Low DUP (127%)

>MDL<CRQL MSE (24%) DUP (127%)

Low PBN (- 0.339 J mg/Kg)

>MDL<CRQL PBN (- 0.339 J mg/Kg)

High PB (4.666 J mg/Kg)

Low PBN (- 0.204 J mg/Kg)

>MDL<CRQL CBN (- 2.438 J ug/L)

>MDL<CRQL PBN (- 0.204 J mg/Kg)

* See explanation of comments in Table IB

AR100031

Page 3 of3

TABLE lA SUMMARY OF QUALIFIERS ON DATA SUMMARY

FORM AFTER DATA VALIDATION

Case 37527, SDG MC0096

ANALYTE Na

Tl

V

SAMPLES AFFECTED MCO0ALMCOOA2, MC00A3, MCO0A4, MC00A6, MC00A7, MC00A9, MCO0B3, MC0096, MC0097, MC0098, MC0099

MC00A4. MC00A8

MCOOBO, MCOOBl, MC00B3

MC0097

MC00A7

POSITIVE VALUES

B

B

B

B

NON-DETECTED VALUES

UL

BUS High

High

High

High

Low

COMMENTS* PB (13.387 J mg/Kg)

CCB (1.050 J ug/L)

CCB (1.087 J ug/L)

CCB(L142Jug/L)

CBN( 0.471 J ug/L]

' See explanation of comments in Table IB

AR100032

Page 1 of 1

TABLE IB CODES USED IN COMMENTS COLUMN

MSL - The matrix spike recovery was low (>30 % but < 75%) [%recovery is in parenthesis]. Reported results and quantitation limits may be biased low.

>MDL ~ Reported results are between MDL and CRQL and are considered estimated. <;CRQL

PBN Preparation blanks had reported negative resuhs greater than absolute value of MDLs [results are in parenthesis]. Reported results which are less than or equal to two times (s2X) the absolute value of the blank and quantitation limits may be biased low.

PB - Preparation blanks had reported results greater than the MDLs [results are in parenthesis]. Reported resuhs which are less than or equal to five times (i5X) the blank concentration may be biased high.

CCB = Continuing calibration blanks had reported results greater than the MDLs [results are in parenthesis]. Reported results which are less than or equal to five times (s5X) the blank concentration may be biased high.

MSE = The matrix Spike recovery was extremely Low (<30%) [the %recovery is in parenthesis]. The reported result may be biased extremely low. Quantitation limits are unusable.

DUP = The relative percent difference (RPD) for the laboratory duplicate analysis was outside the control limits (35% RPD or ±2XCRQL) [the RPD is in parenthesis]. Reported results and quantitation limits are estimated.

AR100033

Appendix A

Glossary of Data Qualifier Codes

AR100034

GLOSSARY OF DATA QUALIFIER CODES (INORGANIC)

CODES RELATED TO IDENTIFICATION (confidence concerning presence or absence of analytes):

U = Not detected. The associated number indicates approximate sample concentration necessary to be detected.

(NO CODE) = Confirmed identification.

B = Not detected substantially above the level reported in laboratory or field blanks.

R = Unreliable result. Analyte may or may not be present in the sample. Supporting data necessaty to confirm result

CODES RELATED TO OIJANTITATION (can be used for both positive results and sample quantitation limits):

J - Analyte Present. Reported value may not be accurate or precise.

K ^ Analyte present. Reported value may be biased high. Actual value is expected to be lower.

L = Analyte present. Reported value may be biased low. Actual value is expected to be higher.

UJ = Not detected, quantitation limit may be inaccurate or imprecise.

UL = Not detected, quantitation limit is probably higher.

OTHER CODE

Q = No analytical result.

AR100035

Appendix B

Data Summary Forms (DSFs)

AR100036

DATA SUMMARY FORM: INORGANIC Page 1 of _ _ 8 ^

C a s e * 37527

Si te:

Lab. :

SDG: MC0087

CARR CHINA

DATAC

Number of Soil Samples: 11

Number of Water Samples : 1

Sample Number:

Sampling Location .

Field Q C :

Matrix:

Units:

Date Sampled:

Time Sampled:

%Sollds:

Dilution Factor:

ANALYTE

ALUMINUM

ANTIMONY

ARSENIC

BARIUM,, •;..,!.:,

BERYLLIUM

CADMIUM

CALCIUM

CHROMIUM

COBALT

COPPER

IRON

•LEAD

MAGNESIUM

MANGANESE

MERCURY

NICKEL

POTASSIUM

SELENIUM

SILVER

SODIUM

THAUIUM

VANADIUM

1 ZINC

CRQL

20

• • • \ - . . 8 '

1

' : ' • • 2 0 . -

0.6

iv-: 0.6'"

500

i ; : - ^ ' i ;

5

•• 2 . 5

10

1

500

1.5

0.1

4

500

3.5

1

"'• 500

2.5

• ' • ' . ' 5 '

6

MC00A5

CC-SS30

Dup. of

MC00A4

Soil

ing/Kg

5/28/2008

14:53

: 75.3

1.0

Result

5160

[ 3.5

jry ,87.5

Flag

UL

0.68 1 •\0'78''

1340

":'':,9.4;

30.3

• 15.5-

11800

341

500

2110

0,051

{•'','•34.3'-

413

[ , ' . • • . '

0.48

37.1

0.70

0y^- ' 187

J

J

J

r V

B

B ' ; ' B

MC0OB4

CC-SS18

Soil

mg/Kg

S/28/2008

17:37

68.7

1.0

Result

3730

V • . ; i . 6 '

3.8

90.1

0.43

2.1

12400

7,7-

8.6

108

8880

189

1350

303

0.066

,12.7

326

0.71

1.1

. 8 4 . 7

0,48

10.3

664

Flag

J-.:'

J

J

J

J

> ' • •

B

MC00B5

CC-SS19

Soil

mg/Kg

5/28/2008

17:45

69.6

1,0

Result

6870

3.8

71.7

0.71

0.32

3040

•;••;. 9 , f -

7.6

• • • • • 9 . 4

15100

30.7

844

439

0,048

010 ,8

556

6,58 0.69

j'/;6p.i5;

1,0

; : i i i : 5 •

45,0

flag

UL

J

- J '

J

J

'Ji B

•BL J

'? ' • •

MC00B6

CC-SS20

Soil

mg/Kg

5/28/2008

17:55

81,5

1,0

Result

3130

•.: • • • 6 . 5

2.3

'•,•• I'ZS

0.29

• • ' 3 , 3

10400

' ;••., ; . . 7 . * .

5.3

1 84.0 5860

645

1120

335

0.076

• " • • ' • 7 . 0

462

,13

0.63

-::.M,9:

0,22

• ' • ' . • 7 . T -

798

Flag

I.J. •

J

J

J

J

• j ; . .^

B

'B'-

B

MC0088

CC-SD01

Soil

mg/Kg

5/28/2008

13:35

20,3

1,0/2,0

Result

7880

11,2

: • 1610

0,76

r.:" -'3.6

12500

12:8

93.8

•.• . - • • 4 8 . 5

77300

294

1120

59800 *

0.16

43,7

1060

4.0

/ ' " ' • ; • 1 8 1 •:

3.5

' " ' ' • / V ' • " • •

443

Flag

U'li'

J

J

J

J

J

. 8 -

^^^ CRQL = Contract Required Quantitation Limit SEE

To calculate sample quantitation limits; (CRQL * Dilution Factor) / (%Solids/100)

"+* - Result is reported from diluted analyses.

NARRATIVE FOR CODE DEFINITIONS

Revised 09/99

AR100037

DATA SUMMARY FORM: INORGANIC Page _ 2 _ _ of _ ! i _ _

Case #: 37527

Site:

Lab. :

S D G ; MC0087

CARR CHINA

DATAC

Sample Number:

Sampling Location:

Field Q C :

MatrU:

Units:

Date Sampled :

Time Sampled:

%Solld&:

Dilution Factor:

ANALYTE

ALUMINUM

ANTIMONY

ARSENIC

BARIUM

BERYIiLIUM

CADMIUM

CALaUM

CHROMIUM

COBALT

COPPER

IRON

•LEAD

MAGNESIUM

MANGANESE

MERCURY-

NICKEL

POTASSIUM

SELENIUM

SILVER

SODIUM

' THALLIUM

VANADIUM

ZINC

CRQL

20

6

1 20

P-5 0.5

500

1

5

2.5 10. 1

500 1.5 0.1

4

500

3.5

. : . : • • 1

500

2.5

5 6

MC0089

CC-SD02

Soil

mg/Kg

5/28/2008

13:48

72.6

1.0

Result

3070

18 33,5

0.39

0,17

117

4,8 •-•• • 7 , 9

4.7

7740

8,2

399

339

5,8 :,• 356-

22.8

0,36

5.0 21,2

Flag

UL

J J J

J

J

UL B

B

MC0091

CC-SD03

Soil

mg/Kg

5/28«008

13:20

74,2

1.0 Result

5820

2.1

60,0

0.57

0,33

821

8,5

7.8

9,5

9380

17,4

724

296

0.028

9.4 551

0,72

0.18

62,0

0,50

9,3 51.9

Flag

UL

J J

• • .

A - .

J

J J B

B

MC0092

CC-S006

Soil

mg /Kg

5/28/2008

15:15

70.8

1.0 Result

4110

4.0 83.4

0.71

0.87

826 7,8

18.0

11.8

17400

74.5

459 1450

0.025;

242 474

0.58

0.29

35,9

0.79

6,5 146

Rag

UL

J

J'' •

J J

J B

B

MC0093

CC-SD04

Dup.of

MC0095

Soil

mg/Kg

5/28/2008

17:25

59.7

1.0 Result

11300

9.2

69.0

2.2 0.78

368

14,2

14.6

38.4

28400

29,9

813 431

-••; .•0,12

27,1

811

1.5

0.60

38,9

14 14,0

•••• 1 6 9

Flag

UL

; ' J J

J

•;J:->.

• J - ' J

.J- ' ' " B

j ; . •

- • • - .

MC0094

CC-SD05

Soil mg/Kg 5/28/2008 17:15

72.0 1.0

Result

4900

4:3

130

0,60 0,52

3140 11.4

9.0

13,6

19500 39.3

888 443

J 0.031

11.9 ; ' • • ; • • 5 8 1 -

0.60

0.62

52.5

•.:••;•• 0 . 9 7

10,6

96.8

Flag

UL

J J

J

Jl' J B B

•J'--

' . CRQL = Contract Required Quantitation Limit SEE

To calculate sample quantitation limits: (CRQL * Dilution Factor) / (%Solids/100)

NARRATIVE FOR CODE DEFINITIONS

Revised 09/99

AR100038

DATA SUMMARY FORM: INORGANIC Page _ Z _ ^ of _ 8 _

Case »: 37527

Site;

Lab,:

SDG : MC0087

CARR CHINA

DATAC

1 Sample Number:

Sampling Location:

Field Q C :

Matrix:

Units:

1 Date Sampled:

Time Sampled:

%Solids:

Dilution Factor:

ANALYTE

ALUMINUM

ANTIMONY

ARSENIC

BARIUM

BERYLLIUM

CADMIUM

CALCIUM

CHROMIUM

COBALT

COPPER

IRON

•LEAD

MAGNESIUM

MANGANESE

MERCURY

L N I C K E t . : ••••./• •. ••• :' •-'''•• •-•

POTASSIUM

SELENIUM

SILVER

S C S D I U M H

THALLIUM

VANADIUM

1 ZINC

CRQL

20

6

1

20^

0.5

•, 6.5

500

•' . . • • ' " . l "

5

I-- 2.6

10

' • - • . 1

500

:r.- 1-5^

0.1

:'[-^:A-

50O

1

•;"500:

2.5

• • . • • • . ' 5 j

6

MC0095

CC-SD07

Dup.of

MC0093

Soil

mglKQ

5^8/2008

17:30

59,7

1,0

Resul

9660

8,3

84.6

2.1

0.71

373

[r. 12.3 14.1

1 ••' 37,5^

26300

['•' .28.0•

696

- 520 0.15

-.•:•• • • 2 7 . 1 •

567

• , : 1.2

0.69

L 37.0 1,3

11.6

167

Flag

UL

J •;

J

J

J

J

J

B

• ^ " ' • •

J

Result

• - . • • •

Flag

, • • • .

Result Flag

- t

Result

- . , • • •

Flag

• •

Result

; • • ; • ' . - . • 1

Flag

' ' . ; . ; • • • • •

CRQL = Contract Required Quantitation Limit SEE

To calculate sample quantitation limits: (CRQL * Dilution Factor) / (%Solida/100)

NARRATIVE FOR CODE DEFINITIONS

Revised 09/99

AR100039

DATA SUMMARY FORM: INORGANIC Page 4 of 8_

Case #: 37527 Site:

Lab.:

SDG: MC0087

CARR CHINA

DATAC

Sample Number:

Sampling Location:

Field QC: MaUix;

Units:

Date Sampled : Time Sampled; Dilution Factor

ANALYTE

ALUMINUM ANTIMONY

•ARSENIC BARIUM

BERYLLIUM •CADMIUM

CALCIUM

•CHROMIUM

COBALT COPPER

IRON •LEAD MAGNESIUM

MANGANESE

MERCURY •NICKEL POTASSIUM -

SELENIUM SILVER

SODIUM

THALLIUM VANADIUM ZINC

•CYANIDE

CRQL

200 60 10

200 5 5

5000

10 ; 50.

25 100

10

5000 15

0-2

40 5000^

35

10

5000

25

50 60 10

MC0087

CC-RB01

RInsated

Water

ug/L

5/28/2008 18:20 1.0

Result

0,58

Flag

UL

B

42.0

0,73

8,3

3,5 •; ,

• V • , • - • ' ' " , • •

: • . .

55,7

B B

B B

^ • ' • • • -

ut B

ResuH

••' • : • ' • ? .

Flag

..• • •

ResuH Flag

. ' - . • . .

.__

ResuH

^'^r ' j ' -

Flag

• • •

Result

: • • • • ' " ' . • ,

• ' • . ' J •

Flag

^ • , -

^^^^ CRQL = Contract Required QuantKation Limit 'Action Level Exists

To calculate sample quantitation Umits: (CRQL * Dilution Factor)

SEE NARRATIVE FOR CODE DEFINmONS Revised 09/99

AR100040

DATA SUMMARY FORM: INORGANIC Page _ 5 _ of _ 6 _

Case #: 37527

Si te:

Lab,:

SDG : MC0096

CARR CHINA

DATAC

Number of Soil Samples: 17

Number of Water Samples : 0

Sample Number:

Sampling Location:

Field Q C :

Matrix:

UnHs:

Date Sampled:

Time Sampled:

%Sollds:

Dilution Factor:

ANALYTE

ALUMINUM

ANTIMONY

ARSENIC

BARIUM

BERYLLIUM

CADMIUM

CALCIUM

CHROMIUM

COBALT

COPPER

IRON

•LEAD

IVIAGNESIUM

MANGANESE

MERCURY

NICKEL

POTASSIUM

SELENIUM

SILVER

SODIUM'

THALLIUM

V/VNADiUM

ZINC

CRQL

20

6 1

20

0.5 0,5

500

• ; ^

5 2.6

10

1 500

15 0.1

. , . 4 •

500

3:5 1

500 2.5

•.'. 5

6

MCOOAO ~1 CC^SOS

Soil

mg/Kg

5l2Smm 14:13

37.6

1,0 ResuK

4390

64.2

2,9

448 0,27

1,6 19800

8.8 28,4

46.1

5880

1850

1910

299

0.11

•,.;..7,3:'

953

2.5

0,35

2104

11.5

805

Flag

J

J

V

MCOOA 1

CC-SS06

Soil

mg/Kg

5/28«008

14:30

28.8

1.0 Result

1170

3.0

gi.3

0,090 3.5

16600

4.1 5.5

46.8

4130

1100

639

165 0.18

- [ .y 4 J

393

2.3

79.S .;

2,4 486

Flag

J UL

J

J

J

J

• J •••

J

J UL B; •

J

MC0OA2

CC-SS07

Sou mg/Kg

5/28/2008

14:23

39.0

1.0 Result

1140

1.9 0,90

87,5

0,11

0.83

12600

3^6

2.9 22.6

6140

291 649

• •• 2 M . . 0.14

••'-•• • V

359

2.2

t S.8-'7

'2;2-

231

Flag

B

J

J

J

J

J

J

J J

J UL

• ^ • ^

J-

MC0QA3 "H CC-SS08

Soil

mg/Kg

6/28/2008

14:35

40,9

1.0

Result

1750

: 69,5

4.5 144

0,16

2.6

11300

6,3

2.8

76.4

15B00

39S

588 271

0.12

.' .'• 'S-S 290

2.0

51.4

'.:".•• 3 . 7 ^

553

Flag

J

J

J

J

J

':r J

J

UL B-; •

J

MC00A4

CC-SS17

Dup.of

MC00A5

Soil

mg/Kg

5/28/2008

14:43

74.0

1.0

ResuH

5810

3.5

87.7

0.81

0.82

1390

9.2 28.5

15.3

11400

342

523

;; 1870

0.044

32.0

488

;• 64-6^ 0.37

7.5 158

Flag

R

J

J

J

UL

.8;.

B

CRQL = Contract Required QuantHation LimH

To calculate sample quantitation limits: (CRQL * Dilution

SEE NARRATIVE FOR CODE DEFINITIONS

Factor) / (%So1ids/100) Revised 09/99

AR100041

DATA SUMMARY FORM: INORGANIC Page _ 6 _ _ of _ e ^

Case* , 37527

Site:

Lab,:

SDG: Mcooge

CARR CHINA

DATAC

Sample Number:

Sampling Locat ion:

Field Q C :

Matrix;

UnHs:

Date Sampled:

Tinfie Sampled ;

%Solid5:

Dilution Factor:

ANALYTE

ALUMINUM

ANTIMONY

ARSENIC

BARIUM

BERYLUUM

CADMIUM

CALCIUM

CHROMIUM

COBALT

COPPER

IRON

•LEAD

MAGNESIUM

MANGANESE

MERCURY

NICKEL

POTASSIUM

SELENIUM

SILVER

SODIUM

THALLIUM

VANADIUM

ZINC

CRQL

20 6

: • • . • • . 1 : ' •

20

OS

0,5

500 1

• 5 / '

2.5

10 1

506 1.5

0.1 4

500 3,5 1

500

•.•'.2-5 •

5 .' 8

MC00A6 "H CC-SS09

Son

mg/Kg

5/28/2008

15:33

81.6

1.0 ResuH

127

22.0

0.042

63:8

4.1

1.7

1520

35.6 : • ' •

4.1

2.8 24.4

27,1

0,20

5.6

Flag

R UL J

J J

J

•

i B

UL B

J J

MC0OA7

CC-SS10

Soil

mg/Kg

5/28/2008

15:40

28,0

1.0/4,0

ResuH

1620

22.6

114

77,1

12800

72,6

14.6'

260 283000 +

4710

796

1310

0.24

56.6

681 9,2

4.7

166

16000 +

Flag

R

• • ' • • .

J

• '

J

'j'-

J

J

B

UL

MCOOAS

CC-SS11

Soil

mg/Kg

5/28/2008

15:45

66.7

1.0 ResuH

6660

31,3

6.8 214

0.81

2,2

17600

9.5 2.3

20.1

26300

703 2210

592 0.074

7.9

554

2,1

0.90

138

073 4,9

32iB

Flag

J

J,.',

J

•J - '

J

.J J

^ " •

J

MC00A9

CC-SS16

Soil

mg/Kg

5/28/2008

16:04

71.3

1.0 Result

675

2.9

- 0.54

30.1

0.049

0.95

2raio

8.9 17.1

22.7

2040

592 162

74.4

0.021

3.5 111

45.2

6.5 598

Flag

J "'J'}

. J •• •

J

J J

J

UL B • y ?

J

MCOOBO

CC-SS12

Dup. of

MCOOBl

Soil

mg/Kg

5/26/2008

16:16

74.5

1,0 ResuK

5800

' • • • • • • • • 4 , i . . . :

285

, 0 . 7 0

0.26

3140

4.2

-•:-:,'4.0-

49.8

13100

247

258

46,5

7,6

. .235;

1,1

0-24

199

, 0 . 6 5

15.8

22.7

Flag

- • :

R

J

J

J

: J - •

J y - •

J

k '.•

_ _ CRQL = Contract Required Quantitation Limit

To calculate sample quantitation limtts: ( C R Q L ' Dilution

' + " - ResuHs are reported from diluted analyses.

SEE NARRATIVE FOR

Factor) / (%SoIid$/100)

CODE DEFiNmONS

Revised 09/99

AR100042

DATA SUMMARY FORM: INORGANIC Page _ J _ of 8

Case #: 3 7 5 2 7

S i t e :

L a b , :

S D G : M C 0 0 9 6

C A R R C H I N A

D A T A C

Samp le N u m b e r :

Samp l ing Loca t i on :

Fie ld Q C :

M a t r i x ;

U n i t s :

Da te S a m p l e d :

T ime S a m p l e d :

% S o l l d s :

Di lut ion F a c t o r :

A N A L Y T E

A L U M I N U M

A N T I M O N Y

A R S E N I C

-•BARIUM-::-;"

B E R Y L L I U M

C A D M I U M :

C A L C I U M

C H R O M I I J M ;

C O B A L T

C O P P E R

I R O N

• L E A D

M A G N E S I U M

M A N G A N E S E

M E R C U R Y

NICKEL;•,!••../•••' ' ' ••.~:^-

P O T A S S I U M

S E L E N I U M

S I L V E R

.;s6piUM;::;;K' vj ';';"v.. :'. THAUIUM

;WNAi3IUM^' .;;

ZINC

CRQL

20

:• • -SW •

1

•.- . .20'- ; .

0.5

• 0 . 5

500

[ ' ' ' • \ " ,

5

2.5

10

1

500

1,5

°l ' •^wA'j .

500

; ' , 3 , 5 :

1

'•"sOT;

2.5

•••'^S;^; 6

MC00B1

CC-SS13

Dup.of

MCOOBO

Soil

mg/Kg

5/28/2008

16:21

77.8

1.0

ResuR

5350

4.3

232

0.60

0.18

2810

3.1

2.7

38.2

6590

161

221

3714

^•''•5,5>^

190

0.44

; 178

0,49

'\ J:\AA -16.0

Flag

R

J

J

J

J

J

-i''\

UL

% • •

B

MC00B2

CC-SS15

Soil

mg/Kg

5/28«008

16:58

75.2

1.0/4,0

ResuH

8270

1,3

4,6

581

0.83

0 9 6

4740

: , . ' . 8;6

26,6

113

11100

21600 +

605

18«> 0,044

;-'r^ •• 34.1 •

1100

0.51

\ •• 2 t i p -

1,2

;•!•'.•• 29.4 ••

144

Flag

J

* • •

J

J

J

" • ; . •

J

MC00B3

CC-SS14

Soil

mg/Kg

5/28/2008

17:08

61.6

1.0

ResuK

6730

4.8

122,

1,0

0 82

1540

10.2

23,6

21.4

15900

43.6

848

1730

0.047

28.6

517

0.17

:: 45.2. :

0.63

: la i 110

Flag

R

J

J

J

B'.-

B

MC0096

C C - ^ 0 1

Soil

mg/Kg

5/28/2008

12:52

59.8

1.0

ResuH

917

o!62

1.7

65.1

0.086

0.92

5000

• .• 4 , 9 •••

6.5

47,5

4390

968

255

294

0.16

••!... • •4.p. ; -

144

1.2

0.19

V-'37.P'.,

)y':2.i 134

F lag

B

J

J

J

J

• J .•'•

J

• i l - :

J

-P.

' J - ' •

M C 0 0 9 7

C C - S S 0 2

Son

m g / K g

5 /28 /2006

13 :10

60 ,7

1.0

ResuH

2880

3,5

6 2 . 4 ,

0 .37

0 .79

3 0 5 0

/.'••••S.8^-

8,6

21 .9

10300

303

347

; 4 1 8 ,

0.15

"' r7.6t 244

0-74

•. '3«L7- .

0 .49

'••'.•.4.8:

145

Rag

R

J

• j - :

J

-:. *. , J

' • • :

J

" i r UL

• i ' \ B

. J -

CRQL = Contract Required QuantHation Limtt

To calculate sample quantitation limitB: (CRQL'

"+* = ResuH is reported from diluted analyses.

SEE NARRATIVE FOR

Dilution Factor) / (%Solida/100)

CODE DEFINITIONS

Revised 09/99

AR100043

DATA SUMMARY FORM: INORGANIC Page _ _ 8 _ of 8

Case #: 37527

Site:

U b . :

SDG; MC0096 C/ RR CHINA

DATAC

Sample Number:

Sampling Location:

Field QC: Matrix:

Units:

Date Sampled : Time Sampled: %Sotitis: Dilution Factor:

ANALYTE

ALUMINUM ANTIMONY

Af^ENIC BARIUM

BERYLUUM CADMIUM

CALCIUM

CHROMIUM

COBALT

COPPER

IRON

•LEAD MAGNESIUM

MANGANESE

MERCURY . NICKEL

'POTASSIUM SELENIUM

SILVER SODIUM THALLIUM

VANADIUM ZINC

CRQL

20 6 1

20

0,5 0.5

500 1

.-•• ' 5

2,5

10 1

500 1,5 0.1 4

:;;5o6'--3.5

• 'A'-.

500 • • ; 2 . 5 , .

5 6

MC00B8

CC-SS03

Soil

mg/Kg

5/28/2008 13:00 72.8 1.0

Result

1930 1,1

1,3

52,3

0.13 0,85

4280 12,7

21,9 34,2

1200 865 271

160 0.085

2.1

:|;-,;i97-0,41

53,8

2,5 139

Flag

6

J

J

: •

J

J J

J, J

UL

B

J

MC0099

CC-SS04

Soil

mg/Kg 5/28/2008

13:29 79.9 1.0

ResuH

2320 1.8

. 2,5'. 86,8 0.20

0,87

2980 4.0

36,7

56,9

2730 1390

1220 164

0.046 4.8

' • • ' • ' ' ' 1 9 7 " •

0,087 52.2

6,3 156

Flag

J

J

J

J

J

J B

;V..:'

ResuH

' • '

Flag ResuH

' - . : • ' ; : . . . . ;

Flag

v _

ResuH

1:':y'^<''

• < • •

Flag

U"

^ ^ CRQL • Contract Required Quantitation Limtt To calculate sample quanmation limHs: (CRQL • Dilution Factor) / (%Solld3/100)

SEE N/«RATIVE FOR CODE DEFINITIONS Revised 09/99

AR100044

Appendix C

Chain-of-Custody Records

AR100045

f ^ p p A USEPA Contract Laboratory Program Inorganic Traffic Report & Chain of Custody Record

Region; 3

Praiect Code:

Account Code: OaT03W302DC6CA3LARSO0

CERCUS ID:

SpiBlO: A3LA

Site NameiState: C a n Cl i ina/VW

Project Leader: Gene Nance

Action: Removal Site Evaluation

Sampling Co: TechUaw, Inc.

Date Shipped:

Carrier Nama:

Airbil l:

Shipped to:

5/29/2008

FedEx

8640 6764 5781

Dalachem LaOoratoiles. Inc. 960 West LeVoy Drive Salt 1 ake City UT 84123 (801)266-7700

Case No:

DAS No

Chain of Custody Record

Relinqulshad By (Date/Time)

1

2

3

4

37527 R Sampler S^ialUK

Received By (Date/Time) |

INORGANIC S A M P L E No.

MATRRf SAMPLER

CONQ TYPE

ANA.YSIS/ TURNAROUND

TAGNoi PRESERVATIVE) Bctkra

STATION LOCATION

SAMPUCOlifa DATE/TIME

ORGANIC SAMPLE No. Type

MC0087

MC006&

MC0089

MC0091

MC0092

MC0093

MC0094

MC0095

MCOOAS

MC00B4

Field QC/ Gene Nance

Sediment/ Gerve Nance

Sediment/ Gene Nance

Sediment/ Gene Nance

Sedimeni/ Gene Nance

Sedimejiti' Gene Nance

Sediment/ Gene Nance

Sedimeni/ Gene Nance

Surface Soil (0M2'1/ Cana Nance Surface Soil (O'-IZ")/ Greg Slarkebaum

UG

UG

UG

L/6

UG

L/G

L/G

L/G

UG

L/G

TM+Hg (14)

TM/HgSoiUU)

TM/Hg Soil (14)

TNVHgSoil(14)

TMrtHg Soil (14)

TM,'Hg Soil (14)

TM/Hg Soil (14}

TM/Hg Solid4)

TM/Hg Sou (14)

TM/Hg Soil (14)

3312(HN03){1)

3317 (Ice Only) (1)

3318 (Ice Only) (1)

3320 (Ice Only) (1)

3321 (Ice Only) (1)

3322 (Ice Only) (1)

3323 (Ice Only) (1)

3324 (Ice Only) (1)

3337 (Ice Only) (1)

3348 (Ice Only) (1)

CC-RB01

CC-SD01

CC-SD02

CC-SD03

CC-SD06

CC-SD04

CC-SO05

CC-SD07

CC-SS30

CC-SS18

S;

S

S:

S:

S

S;

S:

S:

S.

S:

5/28C008

5/28«008

5^8/2008

5/2S.'2008

5/2B/2D08

5/28/2008

5/28/2008

S/28/2008

5^8/2008

5/28/2008

18:20 .

13 35,

13:48

13.20

15:15

1/-25

17,15

1730 ,

14-53.

1737 .

C0087 Rirtsate

LabQC

CC0A5

Field Duplicate of CC-SI504

Field Oup l i c of CC-SS17

Shipment forCase Coinplata?Y

Analysis Kev'-

TM+Hg = CLP TAL Tola

Sample|s) to be used for laboratory QC:

MCG088

Cot(c«ntration: L = Low, M = LoWMedium. H = rtgh Typa/DOTlgnate-. Composite = C, Grab • G

1 Metals * Hg (AU), 1 M/Hg Soil = (JLH 1AL 1 ot Metals 4, H Q (Soil)

Chain or Custody Saal Number:

Shlumentleed?

TR Number. 3-174383947-052908-0002 PR providfls praltmlnary rasute. Raqua«tt for pieUmlnaiy results wUI l iKraasa analytical costs.

Send Copy to Sample Management Office, 2000 Edmund Halley D r „ Res lon, VA. 20191-3400 Phone 703/264-9348 Fax 703/264-9222 F2VS.l,04J P a g e t of 2

AR100046

l y p p A USEPA Contract Laboratory Program ^ ^ - ' ' ^ Inorganic Traffic Report & Chain of Custody Record

Region: 3

Project Code:

Account Code: 08T03W302DC6CA3LARSOO

CERCUS \D:

Spa ID: A3LA

Site Name/State: Carr C h i n a A W

Project Leader: Gene Nance

Action: Removal Site Evaluation

Sampling Co: TechLaw, Inc,

Date Shipped: 5/29/2008

Carrier Name: FedEx

Airbil l: 3640 6764 5781

Shipped to: DalBchem Latwralor ies. Inc. 960 w e s t LeVoy Drive Salt Lake City UT 84123 (801) 266-7700

Case No: DAS No

Chain of Custody Record

RelinquUhed By (Date / Time)

1

2

3

4

37527 R Sampler Sgiature:

Received By (Date/Time) |

INORGANIC S A M P L E No,

MAIRIX/ SAMPLB;

CONC/ TYPE

ANA.y9Sr TURNAROUND

TAGNoJ PRESBtVATIVB Betles

STATION LOCATION

SAMPLE o o a E a DAIE/UME

ORGANIC S/UMPLE No.

QC Type

UC0QB5

MCOOB&

Surface Soil (0"-12-)/ Gene Nance Surface Soil {0"-12")/ Greg Slarkebaum

L/G TM/Hg Soil (14) 3349 (Ice Only) (1)

L/G TMflHg Soil (14) 3350 (Ico Only) (1)

CC-SS19 S: 5/28/2008 17:46 ^

CC-SS20 S: 5/28J2008 17:56 /

SNpm o i l for Case Complete? Y

Analysis Key:

TM+Hg = CLP TAL Tola

Samplals) to be used for laboratory QC:

MC0088

AddWoital Sampler Slgnatui«(B):

Concentration: L « Low, M « Low/Medium, H = High TVpe/Oesignite: Con^ioslle » C Grab = G

1 Melals + Hg (A d ) , 1 M/Hg Soil • CLM 1 A L 1 ot Metals * Hg (i joi l) '

Chain of Custody Seal Number:

Shionientlced?

TR Number: 3-174383947-052908-0002 PR provides preliminary results. Requests for prellmlnafy results will increase analytical costs.

Send Copy to: Sample Managenient Office. 2000 Edmund HaUey Or., Reslon, VA. 20191-3400 Phone 703/264-9348 Fax 703/264-9222 F2V&1.043 Page 2 o f 2

AR100047

SEPA Region:

Project Code:

Account Code:

CERCUS ID:

SpilHO:

Site Name/State:

Project Leader:

Action:

Sampling Co:

USEPA Contract Laboratory Program Inorga nic Traffic Report & Chain of Custody Record -

3

08T03W302DC6CA3LARSOO

A3LA

Carr C h i n a W V

Gene Nance Removal Site Evaluation

Tech law , Inc,

Date Shipped: 5/29/2008

Carrier Name: FedEx

A i r t i l : 8640 6764 5781

Shipped to: Datachem Laboratories, Inc. 960 West LoVoy Drive Salt Lake a t y U T 84123 (801) 266-7700

C a s e N o :

DAS No:

Chain of Custody Record

Relinquished By (Date / Time)

1

2

3

4

37527 R Simpler Slgialura:

Received By (Oate/Ttme) |

INORGANIC S A M P L E No.

MATRIX/ SAMaER

CONC/ ANALYSS TYPE TUfMAROUNO

TAGNoJ PRESERVATIVE/ Bottles

SrATION LOCATION

SAMPLE COLLECT DATE/TIME

ORGANIC SAMPLE No.

S: 5/28/2008 1 2 : 5 2 / ^

OC Type

MC0Ofi6

MC0097

MC0098

MC0099

MCOOAO

MC00A1

MCO0A2

Surface Soil (0"-l2")/ Greg Starlcebaum Surface Soil (0--12-)/ Gene Nance Surface Soil (0--12")/ Greg Staitebaum Surface Soil (0--12")/ Greg Slarkebaum Surface Soil (0"-12";/ Greg Slarkebaum Surface Soil (0--12")/ Greg Slarkebaum Surface Soil (0--12")/ Greg Slarkebaum

L/G TM/Hg Soil (14) 3325 (Ice Only) (1)

UG TM/Hg Soil (14)

L/G TM/Hg Soil (14)

UG

3326 (Ice Only) (1)

3328 (Ice Only) (1)

UG TMrtHg Soil (14) 3329 (Ice Only) (1)

L/6 TM/Hg Soli (14) 3330 (Ice Only^ ' i ;

UG TM/Hg Soil (14) 3331 (Ice Only) (1)

TMftHg Soil (14) 3332 (lc« Only) (1J

CC-SS01

CC-SS02 5:5/28/2008 13 1 0 . C0097

CC-SS03 S: 5/26/2008 13.00

CC-SS04 S: 5/26/2008 13:29^

CC-SSOE £ : 5/28/2003 ^<>.•^2/

CC-SS06 5:5/28/2008 14 30

CC-SS07 3: 5/28/2008 14:23'

Shipment for Case CompletB?Y

Analysis Key:

TM/Hg Soil = CLP TAL

$amp|e{s| to be used tor laboratory QC:

MC00A3

ConcentraUon: L = Low. M = LOKrfMedium, H = High

Additional Sampler Signatur«[s|:

Type/Designate: Composite = C. Grab = G

Chain of Custody Seal Number:

Shipment Iced?

01 iMeiais + Hg (soii) . , , . , „ , . .

3-174383947-052908-0001 PR provides praliminar/ results. Requests for preliminary results will Increase analytical costs.

Send Copy to Sample Managemam Office, 2000 Edmund Habey ! > „ Reston, VA, 20191-3400 Phone 703/264-9348 Fax 703/264-9222 F W M J O A I Page 1 of 3

AR100048

4J 'EPA

Region:

Protect Code:

Account Code:

CERCLISID:

Spill 10:

Site Name'Stote:

Project Leader:

Action:

Sampling Co:

USEPA Contract Laboratory Program Inorganic Traffic Report & Chain of Custody Record

3

08T03W3O2DC6CA3LARSO0

A3LA

Carr China/WV

Gene Nance Removal Site Evaluation

TecMLaw, Inc.

Daw Shipped: 5/29/2008

Carrier Name: FedEn

AlrMn: 8640 6764 5781

Shipped to: Datachem Laboratories, Inc. 960 West LeVoy Drive Salt Lake City UT 64123 (801)266-7700

Case No:

DAS No:

Chain of Custody Record

RelinquUhed By (Date/Time)

1

2

3

4

37527 R Sampler | Slffialure:

Received By (Date/Time) |

INORGANIC SAMPLE No.

MATRIX/ SMina i

CONC/ ANALYSE/ TAGNoi TYPE TURNAROUND mESBtVATIVE/ Bottles

STATION LOCATION

SAMPLE OOIIECT-DATE/nUE

ORGANIC SAMPLE No .

QC Type

fJtCOOAS

MC00A4

MC00A6

MCOHA?

MCOOAB

MCOOAO

MCOOBO

Surface Soil (0--12")/ Greg Slarkebaum Surface Soil (0"-l2'> Gene Nance Surface Soil (0"-12")/ Greg Star1<ebaum ou i iace Soil {O'-IZy Greg Slarkebaum Surface Soil (C--12")/ Greg Slarkebaum Surface SoH (0'-12'y Greg Slarkebaum Surface Soil (0"-f2"i/ Greg Slarkebaum

L/G TM/Hg Soil (U) 3333 (Ice Only) (1)

UG TM/Hg Soil (14) 3335 (Ice Only) (1)

UG TM/Hg Soil (14) 3339 (Ice Only) (1)

UG TMflHg Soil (14) 3340 (Ice Only) (1)

UG TM/Hg Soil(14) 3341 (iceOnly) (1)

L/G TM«g Soil (14) 3342 (Ice Oniy) ( i )

UG TM/Hg Soil (14) 3343 (Ice Only) (1)

CC-SS08 S: 5/28«006 14:35^ C00A3

CC-SS17 S: 5/28/2008 1 4 : 4 3 / C00A4

CC-SS09 S: 5/28/2008 15.33 /

CC-SS10 S: 5/28/2008 15:40 •-'

CC-SS11 S: 5/28/2008 15:45

CC ss-,e S: 5/20/2006 1S:04,'

CC-SS12 S: 5/28«008 16:16 / COOBO

LabQC

ShipiRcnt foi Case Coinpltti7Y

Samplalt) to ba used for laboratory QC:

MCO0A3

Additjpnal Sampler Signaturefs): Chain of Custody Seal Number:

Analysis Key: TM/Hg Soil « CLP TAL 1 ol Melals + Hg (Soil)

Concentration: L = Low, M = Low/Medium, H = High Typa/Dealgnato: Convotlle = C Grab = G Shipment iced?

TR Number: 3-174383947-052908-0001 PR provMoA preUntlnary results. Requests for preliminary results wi l l i i taease analytical costs.

Send Copy to: Sample Management Office, 2000 Edmund Halley Or,, Res lon, VA. 20191-3400 Phone 703/264-9348 Fax 703/264-9222 fTJi- iHAi Page 2 of 3

AR100049

£V C p A USEPA Contract Laboratory Program \ f i U . f - r \ ino^anjc Traffic Report & Chain of Custody Record

Region: 3

Project Code:

Account Code: 08T03W302DC6CA3LARSOO

CERCUS ID:

S p l l I D : A3LA

SKe Name/Slate: Carr C h i n a r t W

Project Leader. Gene Nance

Action: Removal Site Evahial ion

Sampling Co: TechLavr, Inc.

Date Shipped: 5/23/2008

Carrier Name: FedEx

AirbilL 8640 6764 5781

Shipped to: Datachem Laboratories, Inc. 960 West LeVoy Drive Salt Lake City UT 84123 (801)266-7700

Case No: 37527 Q DAS No: r X

Chain of Custody Record

Re&iqubhed By (Date / Tmie)

1

2

3

4

StiKpler Sgiatura:

Received By (Date / Time)

INORGANIC S A M P L E No.

UATRIX/ SAMPLER

CONC/ TYPE

AHM.YSS/ TUWAROUNO

J M H a J FRESBIVATIVE/Batlts

STATION LOCAHON

SAHFIE COLLECT OATEmME

ORGANIC SAMPLE No .

QC

Type

MCOOBl

MC00B2

MC00B3

Surface Soil

(0"-ir)/ Greg Slarkebaum Surface Soil (0-.12")/ Greg Slarkebaum Surface Soil (0--12-)/ Greg Slarkebaum

UG TM/Hg Soil (14) 3345 (Ice Only) (1)

UG TMflHg Soil (14) 3346 (Ice Only) (1)

UG TM/Hg Soil (14) 3347 (Ice Only) (1)

CC-SS13

CC-SS15

S: 5/28/2008 16:21 •

S: 5/28/2008 16:56 .

Field Duplic. of CC-SS12

CC-SS14 S 5/26/2008 17 06

SWpmanlforCase Coniplel>7Y

Artaiyais Key:

TM/Hg Soil • CLP TAL

Samplels) to be used tor latMratory QC:

MC00A3

AddHlonal Sampler Signalurett):

Concentration: L = Low. M = Low*ledlum. H = High Typs/De»ignale: Composite = C. Gn* = G

Chain of Custody Saal Number:

Shipment Iced?

Ot Metais + Hg (SOU) • • 1 / 1

PR provides preliminary results. Requests for pretlmlnaiy results wX increase analytical costs. Send Copy to Sample Managemeni Office, 2000 Edmund Halley Dr.. Reston, VA, 20191-3400 Phone 703/264-9348 Fax 703/264-9222 F2V]L1.043 Page 3 o f 3

AR100050

v- >>• ^ i -

UoS, EPA Region III Analytical Request Form Revision 10.06

^ ASOAB USE ONLY RAS# DAS# NSFW

CT4258 Analytical TAT

•34 i**

:A't:lAJt Date: 05.'22/08

Siic K'amt: Cair China

Cii\-: Grafton

Site Activirv- Removal Site E VUIUUIIUI I

State; WV

Street Address:

Latitude:

Acct, #; 2008 T03'^302DC6CA3LARS00

Longitude;

Piogram; Superfund CERCLIS »: UNKNOWN ' ^ j n - ^ J i —

Silt ID: A3LA Spill ID: Operable Unit:

Site SpeciHc QA Plan Submitted; • No glYes 1 Title: Sampling o ,* /oc Work Plan

El'A Piojecl Leader: Dominic Ventura Phone/*: 215-814-2363 Ceil Phoned; 215-756-7977 E-mail: ventura.domijiic@epa.gov

Request Preparer: Gene Nance Phone#: 740-867-0968 Cell Phone #: 304-830-1442 E-mail gnance@techlawinc.coni

Site Leader: Gene Nance- Phone*#: 740-867-0968 Cell Phone #; 304-830-1442 E-mail: giiance@techiawinc.com

CoiUiactor: Techi^aw, Inc.

i/Saniples 20,=- .. + • Matri.x: Soi:

EPA CO/TO: Lorrie Murray' Karen Wodarczyk

Parameter: TAL ICP-AES Total Metals-rHg ^ ^ ^ 6 . Method: 1LM05,4 ICP-AES . 7 ? / ) ^ / }

^/Samples 4 - " . • - ' 'Ai. Matr iv Sol! Parameter: TCL VOA/SVOAyPest/PCB ^ Z j ^ S ^ - ^ j Method: SOiviOi. jnjfi^ %

^Samples Matrix: Sediment Paraiiicici. TAL iCP-A£S Tuiai ivietais+Hg ivictiiod: !LM05,^ !C.f>-AES

:'f Samples Matri.v: Sediment Parameter; TCL VOA/SVOA/Pest/PCB Method; SOMO 1,2

••Samples 2 .Matrix: AQ (field QC sample) Parameter; TAL ICP-AES Total Metals+Hg Method: ILM05.4 ICP-AES

sSamptes iviatrix: AQ (field QC sample) Parameter: TCL VOA/SVOA/Pest/PCB Method: SOMO 1.2

I .^Samples Matrix: AQ (field QC sample) Parameter: TCL VOA only Method; SOMO 1,2

.^Samples Matrix: Parameter: Method:

/?S;imples Malrix: Parameter: ' [fQ^L^ C O ^ ^ u M A ' ^^-JIS- 6 P Method:

Ship Date From: .May 28, 2008 Ship Date To: May 30, 2008 Org. Validation Level M3 Inorg, Validation Level 1M2

Unvalidaied Data Requested: • No ^ Yes If Yes, TAT Needed: ^ \AAzyz D - d a y s Q 72hr5 • 4 8 { u - Q 24hr5 D Other (Specifv) L^.^f^.C^ff ' " ' ~ ~ . — — — - — — ^ " • • • - • • • • • • — • • • F - . .1 . • • - • 1 " * " ' ) fc^'-"—•-^—

Validated Data Package Due; Q 42 days E j 30 days D 21days Q 14 days Q Other (Specify) f M l ^ Electronic Data Deliverables Required: Q No ^ Yes (EDDs will be provided in Region 3 EDD Format)

Special Instructions: Detection Levels - Method CRQLs For SOMOl.2, ILM05.4. TCL and TAL attached to sampling plan. OAPP - Quality Assurance Project Plan (QAPP) For START Sampling Activities Submitted To U S EPA Region ill.

rOK.M A k f - 10,'06 Revision

AR100051

Appendix D

Laboratory Case Narrative

AR100052

SDG MC0087

AR100053

•OSZ??. - CLP

COVE?. F.SiGE

Lab .Name: DATACHEM LABORATORIES

Lab Code : DATAC

SOW N o . ; ILKOS. 4

Case N o . : 37527

C o n t r a c t : EP-W-06-054

NFIAS K'O, :

SPA Sample No. MC0037 MCO086 MCOOeSD Mcooses MC0089 MC0091 MC0092 MCQ093 MC0094 MC0095 MCOOAS MC00B4 t CQOBS MC00B6

SDG No.: MC008 7

Lab Sample 8151012001 8151013001 8151013003 8151013002 8151013004 3151013005 8151013006 8151013007 8151013008 8151013009 8151013010 8151013011 8151013012 8151013013

ID

Were ICP-AES and ICP-MS Interelement corrections applied?

If yes - were raw data generated before application of background corrections?

Comments:

ICP-AES ICP-MS

(Yes/i-io) YES NO

Were ICP-AES and ICP-MS background corrections (Yes/No) applied?

(Yes/No)

YES

NO

NO

NO

I certify that this data package is in compliance with the terrns and conditions of the contract, both technically and for completenes;j, for other than the conditions detailed above. Release of the data contained in this hardcopy data package and in the co.'nputer-readable data submitted on diskette (or via an alternate means of electronic transmission, if approved in advance by USEPA) has been authorized by the Laboratory Manager or the Manager's

rifii designee, as v.

Signature

Date: 06/12/2008

fd by the following signature.

Name: Neil E:dtvard3

Title: Chemist

COVER PAGi ILMOS.M

AR100054

flgg!*j'^,-S."J<.l

^ ^ LABORATORIES, INC.

SDG NARRATIVE

Case #: 37327 SEKi#: MC0087 Contract Ui EP-W-06-054 DCLS«tID#: 8151012,8151013 June 12, 2008

General Inrormation The twelve samples in this SDG were analyzed by methodologies contained in ILM05 4. All concentration, analytical, and method qualifiers are defined in the SOW.

Holding Times All samples were prepared and analyzed within method required holding time:j.

Initiiil and Continuing Calibration All initial and continuing calibration verification and blank analyses were performed within the designated frequency at d recoveries of the verif cations and concentrations of the blanks met metbod acceptance criteria.

Interference Check Sample Analysis Results for the interference check samples met method acceptance criteria.

Preparation Blanlis The absolute values of all analjte concentrations in the preparation blanks were lower than the Contract Required Quantitation Limits.

Laboratory Control Sample Analysis Results for the analysis of the LCS met method acceptance criteria.

Matrix Spike Analysis All matrix spike recoveries were within the limits of 75-125% with the exception of antimony in soil.

Matrix Duplicate Analysis All matrix duplicate results met method criteria with the exception of manganese in soil.

Serial Dilution ICP-AES Serial Dilution results met method acceptance criteria.

Miscellaneous Comments All calibration data is linear, please see raw data. Cooler temps were at 6 'C at time of receipt.

Example Equations

Method HSl: C x D F > i - ^ ^ S = Conceiifrafion{fug/g) = Concentration (mg/Kg) Wi

Method CSl: C x D F x — -f .S = Concern rat ion{iug / g ) = Concentration {mg/Kg) Wi

2

960 Wf.'st LeVoy Drive • Salt Lake City, Utah 34123-2502 • (800) 356-9135 • (801| 266-7700 • Fax (801) 268-9992 www,datachem,com

AR100055

C = Instrument value in pg/L (The average of all replicate integrations), Vf = Final digestion volume (L) Wi = Initial digestion Weight (g) DF = Dilution Factor S = % Solids/100

c

AR100056

_to{ SAMPLE LOG-IN SHEET

tab Name -nr DataChem Laboratories, Inc.

rteoaived By (Print Name) \\^umOj^Ao Log-In Dale

:/fo/b^ Raceived By (Signature)

^a^,f\^e/v-Ls\A\l Case Number

5^5^)1 Sample Delivery Group No, NRAS Numtier umtw

Remarics:

1. Custody Seal (s) fnsahlAaaenC

mtM^roken'

2, Custody Seal Nos. I ^ i l \£L

3. TrafficRapocti/ Chain of Custody Reooids or Packing LMa ((!^9ritrAbsenr

4. Mfbdl

5. AlrtlHNo,

_Q\5

6, Sample Tags

Sample Tag Numbsra

t/Absenr

l ^ l v N o t Ustod on uRabv-of-Custody

/taS^BBroltanV 7. Sample Condition Xealdng*

a. Coder Tamperaturt Indicator BotUe

9. Cooler Temperature

lO.Doesintematloii on custody records. irefllc repodai and

int^Absanr

(V

sample tags agrae? A ^ o '

l lDate Racaivsd at lab

12. Time Recaivad

Sample Tiarsftr

EPA Sample* Aqueous Sample Coiresponding

Sampla Tag #

mtoobl <^ i Jl l

.3A 3i ^a ^ 3

- ^

-35. A5

Br: -&S_

:a^

A7- : 3&^

JQU ^ / n

^ i ^ aeoo

^ ^ \

^ ^ ' - 3 3

Aligned Lab «

Remarks: Conddon of S imple

Shipment, ( « .

IsjOjzdJ

^ 0 1 , 3 3 ^

^ ? 7 ^ - ^

^^-Jli

3^-^!^

3-3^^

_ ^ l

jia a?

Areat AreaO By

. J ^ On

SissiM msk. 3MO^atti<<M»eord of waolullon Contact SMO land atn

IRaviawed Logbook No. NOT APPUCASLE

OatK

^/s^/t^cP-Logbook Page No. NOT APPLtCABUi

FORM OC-1 ILM0S.4

AR100057

SDG MC0096

AR100058

USEPA - CLP

COVER P.a,GE

Lab N'arr.e: DATACKEH L.z BORATORIES

Lab Code: DATAC

SOW No.: ILM05.4

Case No.: 37527

Co.ntract: E?-W-06^054

NRAS No.:

EPA Sample 1-Jo. MC0096 MC0097 MC0098 MC0099 MCOOAO MCOOAl MC00A2 MC00A3 MC00A3D MC00A35 MC00A4 MC00A6 MC00A7 MCOOAS MC00A9 MCOOBO MCOOBl MC00B2 MC00B5

Were ICP-AES and ICP-MS In'ierelement; corrections applied?

Were ICP-AES and ICP-MS background corrections applied?

If yes - were raw data oenerated before application of backgrou.id corrections?

Comments:

SDG No.: MC0096

Lab Sample ID 8151011001 8151011002 8151011003 8151011004 8151011005 8151011006 8151011007 8151011008 8151011010 8151011009 8151011011 8151011012 8151011013 8151011014 8151011015 8151011016 8151011017 8151011018 8151011019

ICP-AES

(Yes/No) YES

(Yes/No) YES

(Yes/No) NO

ICP-MS

NO

NO

NO

I certify that this data package is in compliance with the terms and conditions of the contract, both technically and for completeness, for other than the conditions detailed above. Release of the data contained in this hardcopy data pac)cage and in the computer-readable data submitted on diskette {or via an alternate means of electronic transmission, if approved in advance by USEPA) has been authorized by the Laboratory Manager or the Manager's designee, as v^r^fied byytpe following signature.

Signature: \ L^^^lx_..^ ' ' \ . Name: Neil Edwards

Date: 06/11/2008 Title: Chemist

COVER PAGE ILM05.

AR100059

LABORATORIES, INC.

SDG NARRATIVE

Case #: 37527 SDG#: MC0096 Contract #: EP-W-06-054 DCLS«tID#: 8151011 June 11,2008

General Information The seventeen samples in this SDG were analyzed by methodologies contained in ILM05.4. All concentration, analytical, and n^ethod qualifiers are Jeflned in the SOW.

Holding Times All samples were prepared and analyzed within method required holding times.

Initial and Continuing Calibration All initia] and continuing calibration verification and blank analyses were performed within the designated frequencj' and recoveries of the verifications and corcentrations of the blanks met method acceptance criteria.

Interference Check Sample Analysis Results for the interference check samples met method acceptance criteria.

Preparation Blanks The absolute values of all analyte concentrations in the preparation blanks were lower than the Contract Required Quantitation Limits.

Laboratory Control Sample Analysis Results for the analysis of the LCS met method acceptance criteria,

IVlatrix Spike Anaiy:iis All matrix spike recoveries were within the limits of 75-125% with the exception of antimony.

Matrix Duplicate Analysis All matrix duplicate results met method criteria with the exceptions of antimony, chromium and iron.

Serial Dilution ICP-AES Serial Dilution results met method acceptance criteria.

Miscellaneous Comments All calibration data is linear, please see raw data. Cooler temps were at 6 "C at time of receipt.

Example Equations

Method MSI: Cx OF x - ^ -:- LS = Concentration{}ig/g) = Concentration (mg/Kg) Wi Vf

Method CSl: C x DF x - ^ •- S = Concentraiion(pg/g) = Concentration (mg/Kg) Wi

960 West LeVoy Drive • Salt Lake City, Utoh 84123-2502 • {800} 356-9135 • (801) 266-7700 • Fax (801) 260-9992 vvww.datachem.com

AR100060

C = Instrument value in ug/L (The average of all replicate integrations). Vf= Final digestion volume (L) W.i = Initial digestion Weight (g) DF = Dilution Factor S = %Solids/I00

AR100061

APPENDIX B

TDD No.: W33-020-08-07-021

AR100062

.x*'^^ rtto SJi

' ' %

ul

UNITED STATES ENVIRONMENTAL PROTECTION AGENCY REGION III

Environmental Sciences Center 701 Mapes Road

Fort Meade, Maryland 20755-5350

DATE:

SUBJECT:

FROM:

TO:

July 3, 2008

Region III Data QA Review

Colleen K. Walling i j M ^ ^ | L . \ f J ( P ( ^ ^ _ ^ Region III ESAT RPO (3EA21) \ J

Dominic Ventura Regional Project Manager (3HS32)

Attached is the organic data validation report for the Carr China site (Case# 37527; SDG # C0087 and C0097) completed by the Region III Environmental Services Assistance Team (ESAT) contractor imder the direction of Region III EAID.

If you have any questions regarding this review, please call me at (410) 305-2763.

Attachments

cc: Libby Burns (Techlaw Inc.)

TO File #: 0014 TDF#: 0663

ANALYTICAL SERVICE AND QUALITY ASSURANCE BRANCH OFFICE OF ANALYTICAL SERVICES AND QUALITY ASSURANCE

^I? Printed on 100% recycled/recyclable paper with 100% post-consumer fiber and process chlorine free. Customer Service Hotline: 1-800-438-2474

AR100063

L O C K H E E D M A R T I HI ^^ We never forget who we 're working for"

Lockheed Martin Enterprise Solutions & Services ESAT Region 3 US EPA Environmental Science Center 701 Mapes Road Ft. Meade, MD 20755-5350 Telephone 410-305-3037 Facsimile 410-305-3597

DATE: July 1,2008

SUBJECT: Level M3 Organic Data Validation for Case 37527 SDG: C0087 and C0097 Site: Carr China

FROM:

TO:

OVERVIEW

ShilpaUdani '^ Organic Data Reviewer

Mahboobeh Mecanic Senior Oversight Chemist

Colleen Walling ESAT Region 3 Project Officer

Case 37527, Sample Delivery Groups (SDGs) C0087 and C0097, consisted of one (1) rinsate blank and five (5) soil samples submitted to Mikem, Laboratories, Inc. (MITKEM) for semivolatile, pesticide and aroclor analyses. The sample set included one (I) field duplicate pair. Samples were analyzed according to Contract Laboratory Program (CLP) Statement of Work (SOW) SOMOl.2 through the Routine Analytical Services (RAS) program.

SUMMARY

Data were validated according to the Region in Modifications to the National Functional Guidelines for Organic Data Review, Level M3. Areas that may impact data usability are listed below.

MAJOR PROBLEM

• Semivolatile samples C00A3RE, C0097 reported zero percent (0%) recoveries of Deuterated Monitoring Compound (DMC) 4-chloroaniline-d4. Quantitation limits for compounds associated with this DMC were rejected and qualified "R" on the Data Summary Forms (DSFs).

MINOR PROBLEMS

• Several compounds failed precision criteria [Percent Difference (%D)] in the semivolatile continuing calibrations. Positive results reported for these compounds in affected samples were qualified "J" on the DSFs. Quantitation limits were qualified "UJ" for compounds with %Ds greater than fifty percent (>50%).

AR100064

Page 2 of3

Semivolatile sample C00A5 had recoveries of DMCs dimethyiphthalate-d6 and fluorene-dlO outside the lower Quality Control (QC) limits. The "L" qualifier for positive results associated with these DMCs was superseded by'T' on the DSFs. Quantitation limits for compounds associated with these DMCs were qualified "UL" on the DSFs unless superseded by "UJ".

Internal standards (ISs) area counts for \ ,4-dichlorobenzene-d4, naphthalene-d8, acenaphthene-dlO and phenanthrene-dlO were outside the upper control limits in semivolatile samples C00A3. This sample was reanalyzed with area counts for l,4-dichlorobenzene-d4, naphthalene-d8 and perylene-dl2 outside the QC limits. The reanalyses results for this sample were reported on the DSFs. Reported results and quantitation limits for compounds associated with these internal standards were qualified "J" and "UJ" on the DSFs unless superseded by "R".

Positive results for pesticide and aroclor compounds with percent differences (%Ds) greater than twenty-five percent (>25%) between the two analytical columns were qualified "J" on the DSFs.

NOTES

Compound 4,4'-DDE endosulfan sulfate

C00A4 ND 6.0 J

Non-spiked compounds, were reported in sample C00A4 and the MS/MSD analyses of this sample. Results and precision estimates are listed below.

Concentration f/ig/Kg) C00A4MS C00A4MSD %RSD 1.9 J 2.0 J 5* 4.2 J 5.6 J 18

%RSD = Percent Relative Standard Deviation • = RPD instead of %RSD ND = Non-detect

No positive results were reported in the analyses of rinsate and method blanks associated with this data set.

Reported recoveries for pesticide in Laboratory Control Samples (LCS) and/or Matrix Spike/Matrix Spike Duplicate (MS/MSD) analyses were within QC limits on both columns.

Reported results for field duplicate pairs samples C00A4/C00A5, were not comparable for all compounds in semivolatile and pesticide analyses.

No positive results were reported in the analysis of aroclor field duplicate pair C0OA4/COOA5.

A sample weight other than thirty (30) grams in the semivolatile, pesticide and aroclor analysis was used for samples associated with this case. Dilution factors reported on DSFs reflect actual sample weight used.

Tentatively Identified Compounds (TICs) were reviewed during data validation. Several TICs were identified as the same target compounds at different retention time. Identification for these TICs was changed to "unknown" by the reviewer. TIC Form Is for samples in which TICs were identified are included in Appendix E.

AR100065

Page 3 of3

• Compounds detected below Contract Required Quantitation Limits (CRQLs) were qualified "J" on the DSFs.

All data for Case 37527, SDGs C0087 and C0097, were reviewed in accordance with Region III Modifications to the National Functional Guidelines for Organic Data Review, September 1994.

AllACHMENTS

1) 2) 3) 4) 5)

Appendix A Appendix B Appendix C Appendix D Appendix E

Glossary of Data Qualifier Terms Data Summary Forms Chain-of-Custody Records Laboratory Case Narrative Tentatively Identified Compounds (TICs)

DCN: 37527 - C0087 and C0097

AR100066

Appendix A

Glossary of Data Qualifier Codes

AR100067

GLOSSARY OF DATA QUALIFIER CODES (ORGANIC)

CODES RELATED TO IDENTIFICATION (confidence concerning presence or absence of compoimds)

U = Not detected. The associated number indicates approximate sample concentration necessary to be detected.

NO CODE = Confirmed identification.

B = Not detected substantially above the level reported in laboratory or field blanks.

R = Unusable result. Analyte may or may not be present in the sample. Supporting data necessary to confirm result.

N = Tentative identification. Consider present. Special methods may be needed to confirm its presence or absence in future sampling efforts.

CODES RELATED TO QUANTITATION (can be used for both positive results and sample quantitation limits):

J = Analyte present. Reported value may not be accurate or precise.

K = Analyte present. Reported value may be biased high. Actual value is expected to be lower.

L= Analyte present. Reported value may be biased low. Actual value is expected to be higher.

UJ = Not detected, quantitation limit may be inaccurate or imprecise.

UL = Not detected, quantitation limit is probably higher.

OTHER CODES

NJ = Qualitative identification questionable due to poor resolution. Presumptively present at approximate quantity.

Q = No analytical result.

AR100068

Appendix B

Data Summary Forms

AR100069

DATA SUMMARY FORM: BNA Page_1 o f _ 8 _

Case #: 37527

Site:

Lab,:

SDG : C0087

CARR CHINA

MITKEM

Number of Soil Samples : 0

Number of Water Samples: 1

Sampie Number: Sampiing Location : Field QC: Matrix: Units :

Date Sampled: Time Sampled : Dilution Factor: Semivolatile Compound

^enzaldehyde Phenol

Bk(2-d 2 Chiorophenol

2 2 0)(ybls(1 chloropropane)

4 Methylphenol

Hexachloroethane

Isophorone

WM^iM^^f;-m

2,4-Dlmethylphenol

2,4-Dlchlorophenoi

4-Chloroanlline

'Am

Caprolactam

2-Methylnaphthalene

2,4,6-Trichlorophenol

1,1'-Blphenyl

2-Nitroaniline :

2,6-Dlnitrotoluene

3-Nitroanlline i'*'Arttnarin«»m«v;'•."^l^-"v'^*^?-Hi'>W,»^.p

AR100070

DATA SUMMARY FORM: BNA Page 2 of 8 _

Case *: 37527 Site:

Lab,:

SDG ; C0087

CARR CHINA

MITKEM

CRQL = Contract Required Quantitation Limit 'Action Level Exists SEE NARRATIVE FOR CODE DEFlNmONS

To calculate sample quantitation limits: (CRQL * Dilution Factor) Revised 09/99

AR100071

DATA SUMMARY FORM: BNA Page 3 of _ 8 _ _

Case #: 37527

Site: Lab,;

SDG : C0097

CARR CHINA

MITKEM

Number of Soil Samples : 5 Number of Water Samples : 0

AR100072

DATA SUMMARY FORM: BNA Page __4__ of 8

Case #: 37527

Site:

Lab,:

SDG : C0097

CARR CHINA

MITKEM

Sample Number:

Sampling Location:

Field QC :

Matrix:

Units: Date Sampled: Time Sampled: %Moisture: Dilution Factor:

Semivolatile Compound

2 4 Oinitrophenol 4-Nttrophenol Dibenzofuran

2 4-OtWRTOtoluej3e. ^ Diethylphthalate

Flyoifenei'fe' > ' " Z i ^sM\ 4 Chlorophenyl phenylether

4,6-Dlnitro-2-methylphenol

1,2,4,5-Tetrachlorobenzene

Pentachlorophenol

Anthracene

Oi-n-butylphthalate

Di-n-octylphthalate

Benzo(K}fluoranthene

IndenoO ,2,3-cd)pyrene : jOej g^Qj§ygUWG@BnB«l

Benzo(g,h,i)perylene

CRQL = Contract Required Quantitation Limit SEE NARRATIVE FOR CODE DEFINITIONS

To calculate sample quantitation limits: (CRQL * Dilution Factor) / [(100 - %Moisture) / 1 CO] Revised 09/99

AR100073

DATA SUMMARY FORM: Pesticides Page _ _ 5 _ of _ _ 8 _

Case*: 37527 Site:

Lab.:

SDG: C0087

CARR CHINA

MITKEM

Number of Soil Samples: 0

Number of Water Samples : 1

Sample Number:

Sampling Location:

Field QC :

Matrix:

Units:

Date Sampled: Time Sampled: Dilution Factor:

C0087

CC-RB01

Rinsate Blank

Water

ug/L

5/28/2008 18:20 1,0

Pesticide Compound CRQL Result Flag

S'*" J : :

Result Flag Result Flag Result Flag Result Flag

beta-BHC

&eltf BHC^ . - ' t , ' gamma-BHC (Lindane)

Aldnn

0 050

0 050

0 050

W k ^ ,

Lor,. J

[ A. T-f / \ 4 s^=*i

He/Mtach^tepoxrdfe^^^^^-^l^,^ Q l ^ ? i

• • . , ' . • " (V«; ui.^ 0>" Endosulfan I

4,4'-DDE

Endosulfan II

Endosulfan sulfate

0 050

, r , T:;V, l i t ' - r : .

.3 b^M^'

m 5 nw

mm

-if) L >«; •i?

f t t l ^ if,?'

010

0 10 rf= : wm ll '5.

W T ! "

'•zrfv

^ f

CRQL = Contract Required Quantitation Limit "Action Level Exists SEE NARRATIVE FOR CODE DEFINITIONS

To calculate sample quantitation limits: (CRQL * Dilution Factor) Revised 09/99

AR100074

DATA SUMMARY FORM: Pesticides Page _ 6 ^ of _ _ 8 _

Case #: 37527

Site:

Lab.:

SDG: C0097

CARR CHINA

MITKEM

Number of Soil Samples: 5

Number of Water Samples : 0

CRQL = Contract Required Quantitation Limit SEE NARRATIVE FOR CODE DEFINITIONS

To calculate sample quantitation limits: (CRQL * Dilution Factor) / [(100 - %Moisture) / 100] Revised 09/99

AR100075

DATA SUMMARY FORM: Aroclor Page _ 7 _ _ of _ _ 8 _

Case #: 37527

Site:

Lab.:

SDG : C0087

CARR CHINA

MITKEM

Number of Soil Samples : 0

Number of Water Samples : 1

Sample Number:

Sampling Location :

Field QC:

Matrix:

Units:

Date Sampled : Time Sampled: Dilution Factor:

C0087

CC-RB01

Rinsate Blank

Water

ug/L

5/28/2008 18:20 1.0

Result Flag Aroclor Compound

•Aroclor-1221

'Aroclor-1242

'Aroclor-1254

CRQL Result Flag Result Flag Result Flag Result Flag

•Aroclor-1262

mm 1,0

1,0

1.0

PIP 1.0

W ^

ill

:mM •H^

.........;:-.-.", a>

Iii-iM

ill !li:?^i ifiiai w$ w^

mi^^0S- m ?f[,'-V.;5.-l1Jill.l

SES;;; m Hiil i&^^E

yaStfeai

&^&^

Hi'^^'v^:

CRQL = Contract Required Quantitation Limit 'Action Level Exists SEE NARRATIVE FOR CODE DEFINITIONS To calculate sample quantitation limits: (CRQL * Dilution Factor) Revised 09/99

AR100076

DATA SUMMARY FORM: Aroclor Page 8 of 8_

Case* 37527

S i t e : •

Lab.:

SDG: C0097

CARR CHINA

MITKEM

Number of Soil Samples: 5

Number of Water Samples : 0

Sample Number:

Sampling Location:

Field QC :

Matrix:

Units: Date Sampled: Time Sampled: %Moisture: Dilution Factor:

C0097 CC-SS02

Soil ug/Kg 6/28/2008 13:10 36 0.98

C00A3 CC-SS08

Soil

ug/Kg S/28/2008

14:35

65 1.0

C00A4 CC-SS17 Dup, of CO0A5 Soil ug/Kg 5/28/2008 14:43 25 0.99

C00A5 CC-SS30 Dup. of C00A4 Soil ug/Kg 5/28/2008 14:53 26 0.98

COOBO

CC-SS12

Soil ug/Kg 5/28/2008

16:16

22 1.0

Aroclor Compound CRQL Result Flag Result Flag Result Flag Result Flag Result Flag

Ajrootor-1&16 -Aroclor-1221

Aroclor-1242

Aroclor-1254

Aroclor 1262

33

33

> i « .

M^-M. J

>5t

ft ^

iSK'

33

33 ruu

'i ' l - 1 ^

" t ^

fU K ,fcSrf i

m i m

tA'-J ':f Rfg

CRQL = Contract Required Quantitation Limit SEE NARRATIVE FOR CODE DEFINITIONS

To calculate sample quantitation limits: (CRQL * Dilution Factor) / [(100 - %Moisture) /100] Revised 09/99

AR100077

Appendix C

^ Chain-of-Custody Records

AR100078

i {U.S. EPA Region i n Analytical Request Form Revision 10.06

-¥^ RAS# DAS# NSF#

ASQAB USE ONL\ CT4258 A.na!ytical TAT

14

^^/v).;^^ Date: 05/22/08 Site Activity: Removal Site Evaluation

Site Name: Carr China Street Address:

City: Grafton State: WV Latitude:

Acct. #: 2008 T03V'302DC6CA3LARS00

Longitude:

Program: Superfund CERCLIS #: UNKNOWN -^?vg>-^ Site ID: A3 LA Spill ID: Operable Unit: Site Specific QA Plan Submitted: Q No gjYes Title: Sampling QA/QC Work Plan Date Approved:

EPA Project Leader: Dominic Ventura

Request Preparer: Gene Nance

Phone#: 215-814-2363

Phone#: 740-867-0968

Cell Phone #: 215-756-7977

Cell Phone #: 304-830-1442

E-mail: ventura.dominic(@epa,gov

E-mail: gnance(^techlawinc.com

Site Leader: Gene Nance Phone#: 740-867-0968 Cell Phone #: 304-830-1442 E-mail: gnance@techlawinc.com

Contractor: TechLaw, Inc, EPA CO/PO: Lorrie Murray/ Karen Wodarczyk

#Samples 20^0+2.

^Samples 4 r3 f ' i ' '

Matrix: Soil Parameter; TAL ICP-AES Total Metals+Hg j? ^ ^ ^ ^ Method; ILM05,4 ICP-AES 'p^r^ Matrix: Soil Parameter: TCL VOA/SVOA/Pest/PCB Ji^^S'^ .- ^ / Method; SOMOl.2 f^itKc)^^

#Samples 5 Matrix: Sediment Parameter: TAL ICP-AES Total Metals+Hg Method: ILM05.4 ICP-AES

^Samples 3 Matrix; Sediment Parameter: TCL VOA/SVO/\/Pest/PCB Method: SOMOl.2

#Samples 2 Matrix: AQ (field QC sample) Parameter: TAL ICP-AES Total Metals+Hg Method; ILM05.4 ICP-AES

#Samples 2 Matrix: AQ (field QC sample) Parameter: TCL VOA/SVOA/Pest/PCB Method; SOMO 1,2

#Samples 2 Matrix: AQ (field QC sample) Parameter: TCL VOA only Method: SOMOl.2

^Samples Matrix; Parameter; Method:

#Samples Matrix: Parameter: '/^,^,^ C O A X L ^ M J C . - P ^ . ? - tf P Method:

Ship Date From; May 28, 2008 Ship Date To: May 30,2008 Org, Validation Level M3 Inorg. Validation Level IM2

Unvalidated Data Requested; D No ^ Yes IfYes, TAT Needed: g | 14days D 7days D 72hrs D 48hrs D 24hrs D Other (Specify) L f , . ^ S / f l

Validated Data Package Due: D 42 days ^ 30 days Q 21days Q 14 days D Other (Specify) MlL^ Electronic Data Deliverables Required; D No ^ Yes (EDDs will be provided in Region 3 EDD Format) Special Instructions: Detection Levels - Method CRQLs For SOMOl.2, ILM05.4. TCL and TAL attached to sampling plan. QAPP - Quality Assurance Project Plan (QAPP) For START Sampling Activities Submitted To U S EPA Region III.

FORM ARF- 10/06 Revision

AR100079

^EPA Region:

Project Code:

Account Code:

CERCUS ID:

Spill ID:

Site Name/State:

Project Leader:

Action:

Sampling Co:

USEPA Contract Laboratory Program Organic Traffic Report & Chain of Custody Record

3

68T03VV302DC6CA3LARS00 .

A3LA

Carr China/WV

Gene Nance Removal Site Evaluation

TechLaw, Inc.

Date Shipped: 5/29/2008

Carrier Name: FedEx

Airbil l : 8640 6764 5792

Shipped to: . Mitkem Corporation 175 Metro Center Blvd. Warwick Rl 02886 (401)732-3400

Case No:

DAS No:

Cha in o f Cus tody Record

Relinquished By (Date / Time)

1

2

3

4

37527

Sampler Signature:

Received Sy

R (Date/Time)

ORG.ANIG S A M P L E No .

MATRIX/ SAMPLB;

CONC/ TYPE

ANALYSIS^ rURnAnOUNO

TAGNoJ STATION PRESa\VA7iVc/Boiiies LCPCAIION

SAMPLE 00 ILECr OATBTIME

INORGANIC SAMPLE NO.

QC

Type

C0087

C0097

C00A3

C00A4

C00A5

COOBO

Field QC/ Gene Nance

Surface Soil (0"-12")/ Gene Nance Surface Soil (0"-12")/ Greg Slarkebaum Surface Soil (0"-12")/ Gene Nance Surface Soil (0"-12")/ Gene Nance Surface Soil (0"-12")/ GiBg Slarkebaum

L/G BNA (14), PEST (14)

L/G BNA/PEST (14)

UG BNA/PEST (14)

UG BNA/PEST (14)

UG BNA/PEST (14)

UG BNA/PEST (14)

3313 (Ice Only), 3314 (Ice Only), 3315 (Ice Only), 3316 (Ice Only) (4) 3327 (Ice Only) (1)

3334 (Ice Only) (1)

CC-RB01 S: 5/28/2008 18:20 MC0087

CC-SS02 S: 5/28/2008 13:10 MC0097

CC-SS08 S: 5/28/2008 14:35 MC00A3

Rinsate

LabQC

3336 (Ice Only) (1) CC-SS17 S: 5/28/2008 14:43 MC00A4

3338 (Ice Only) (1) CC-SS30 3:5/28/2008 14:53 MCOOAS Field Duplic. of CC-SS17

3344 (Ice Only) (1) CC-SS12 5:5/28/2008 16:16 MCOOBO

ShlpmentforCase Coniplets?Y

Sample(s) to be used for laboratory QC:

C00A3

Additional Sampler Signatur8(s): Chain of Custody Seal Number:

Analysis Key: ConcentraBon: L = Lew, M = Low/Medium, H = High Type/Designate: Composite = C, Grab = G

BNA = CLP TCL Semivolaliles (AU), UNA/Mti! I = CLh" ICL aemivolatiles and Heshcides/HC;, Pbi? I = ULH ICL I'esiiade/Pl^tls (AU)

Shipment Iced?

TR Number: 3-174383947-052908-0003 PR provides preliminary results. Kequests for prviinitnary reftutte wi l l it«cr«as« enalyiicai coses.

Send Copy to; Sample Management Office. 2000 Edmund Halley Dr., Reston, VA. 20191-3400 Phone 703/264-9348 Fax 703/264-9222 F2V5i1.043 P a g e 1 o f 1

AR100080

Page 1 of 1

Aqnes^Ng

From: "Walsh, Colin" <cwalsh20@fedcsc.com> To: <sng@mitkem.com>; "Agnes Ng" <agnes_ng@mitkem.com> Sent: Thursday, May 29, 2008 12:31 PM Subject: Case 37527

Shirley/Agnes,

All samples for Case 37527 will ship today for delivery tomorrow (5/30). Please note that no VOA samples will ship for the Case.

Please let me know if you need any further information.

Thanks,

Colin

Colin G. Walsh Computer Sciences Corporation (CSC) (703) 818-4544 cwalsh20(afedcsc,com

^§^8 AR100081

M I I K E M LABORATORIES

A Dr/iSiON OF SPECTRUM ANALYTICAL, INC, Featuring HANIBAL TECHNOLOGY

June 12, 2008

Computer Sciences Corporation 2000 Edmund Halley Drive Re«ton,VA 20191-3436

RE: EPA Case # 37527 SDG# C0087 Mitkem Lab Project # G0820

To Document Control Officer:

Enclosed is the data report for the samples associated with the above referenced project. The analyses were performed imder USEPA Contract # EP-W-05-030.

Please call if you have any questions regarding the submittal.

Sincerely,

Agnes R. Ng CLP Project Manager

175 Metro Center Boulevard- Warwick, Rhode Island 02886-1755 • 401-732-3400* Fax 401-732-3499 www.mitkerii.com

AR100082

Appendix D

Laboratory Case Narrative

AR100083

SDG Narrative

Mitkem Corporation submits the enclosed data package in response to USEPA Caise # 37527 and SDG# C0087. Analyses were performed for one aqueous sample that was received on May 30, 2008. The analyses were performed under USEPA Contract # EP-W-05-030. Please note that the sample-shipping cooler received was measured at 2°C.

The case was originally scheduled for VOA, SVOA, Pesticides and Aroclors. Per the Region, no VOA samples will be shipped for this case.

The following sample is submitted in this data package:

Clie,nt ID Lab ID Analysis C0087 G0820-01A S,P,A

S = Semivolatiles P = Pesticides A = Aroclors

,.' The analyses were performed using USEPA CLP Multi-Media, Multi-Concentration V (SOMO 1.2) protocols. The analyses were performed with strict adherence to the SOW

with the following exceptions and observations:

1. Overall Observation:

Where needed, manual integrations were performed to improve data quality. The corrections were reviewed and associated hardcopies generated and reported as required. Manual integrations are coded to provide the data reviewer justification for such action. The codes are labeled on the ion chromatogram signal (GC/MS signal) and chromatogram for GC based analysis as follows:

• Ml peak tailing or fronting. • M2 peak co-elution. • M3 rising or falling baseline. • M4 retention time shift. • M5 miscellaneous - under this category, the justification is explained. • M6 software did not integrate peak • M7 partial peak integration

AR100084

2. Semivolatile Analysis:

GC column: 30 m x 0.25 mm id (0.5 um film thickness) DB-5MS capillary column

The concentration of target analytes were determined for aqueous samples using the following equiition:

Concentration (ug/L) = (AmtXOpXUf f — ][-i-1

where: Amt = on-column amount on raw data DP = Dilution Factor Uf = GPC correction factor Vt = final extract volume (nL) Vi = volume injected (|aL) Vo = initial volume of sample extracted (mL)

The following equation was used to calculate the Amt in the previous equations:

Amt = - ^ M I ^ (A,)(RRF)

where: Ax = area of the characteristic ion for the compound to be measured Ais = area of the characteristic ion for the associated internal standard IS = concentration of internal standard in ug/L RRF = relative response factor

DMC recoveries were within the QC limits.

No manual integrations were performed.

No unusual observation was made for the analysis.

3. Pesticides Analysis:

GC column used: 30 m x 0.53 mm id (0.5 um fihn thickness) CLPPest and 30 m x 0.53 mm id (0.42 um film thickness) CLPPestll megabore columns

The concentration of target analytes were determined using thie following equation for the aqueous samples:

AR100085

Conceu«aUon(; .g/L)=(^5«MMY0 ^ (Vo*Vi)

where: Amt = Lower value of two Cone DF = Dilution Factor UF = Correction Factor Vt = Volume of final extract (\iL) Vi = Volume of sample injected (|aL) Vo = Volume of sample extracted (mL)

SuiTogate recoveries were within the QC limits.

Spike recoveries were within the QC limits in the lab control sample.

Manual integrations were performed on the following: PEMB4: 4,4'-DDE in the rear column due to M7 T0XAPH1B4: toxaphene in the front column due to M3 T0XAPH2B4: toxaphene in the front column due to M3 TOXAPH5B4: toxaphene in the front column due to M3 INDC1B4: tetrachloro-m-xylene in the front column due to M6 PEMBN: alpha-BHC in the rear column due to M7.

No other unusual observation was made for the analysis.

4. Aroclor Analysis

GC column used: 30 m x 0.53 mm id (0.42 um fihn thickness) CLPPestll and 30 m x 0.53 mm id (0.5 um film thickness) CLPPest megabore columns

The concentration of target analytes were determined using the following equation for aqueous samples:

•: C o n c e n t a t t o n ( ^ ) = ( ^ 5 ! M w ) W ^ ^ (Vo*Vi)

where: Amt = Lower value of two Cone DF = Dilution Factor UF = Correction Factor Vt = Volume of final exfract (|iL) Vi = Volume of sample injected (|a.L) Vo = Volume of sample extracted (mL)

AR100086

Surrogate recoveries were within the QC limits.

Spike recoveries were within the QC limits in the lab control sample.

No manual integrations were performed.

No unusual observation was made for the analysis.

All of the submittals to the region are originals other than logbook pages. Photocopies of logbook pages are included, with the originals maintained on file at the laboratory. Tunes, calibration verifications and initial calibrations that are shared among several cases are photocopies indicating the location of the originals.

1 certify that this Sample Data Package is in compliance with the terms and condition of the contract, both technically and for completeness, for other than the conditions detailed above. Release of the data contained in this hardcopy Sample Data Package and in the electronic data deliverable has been authorized by the Laboratory Manager or the Manager's designee, as verified by the following signature.

Agnes Ng CLP Project Manager 06/12/08

. r s , Jr>: B-rfe ? 1

AR100087

SDG Narrative

Mitkem Corporation submits the enclosed data package in response to USEPA Case # 37527 and SDG# C0097. Analyses were performed for five soil samples that were received on May 30, 2008. The analyses were performed under USEPA Contract # EP-W-05-030. The sample-shipping cooler received on was measured at 2°C.

The case was originally scheduled for VO.A, SVOA, Pesticides and Aroclors. Per the Region, no VOA samples will be shipped for this case.

Sample C00A3 is designated as the sample for laboratory QC. The analyses for this sample are SVOA, pesticides and Aroclors. The scheduling notification form notes that laboratoiy QC is not required for SVOA. Per the Region, laboratory QC is only required for the pesticides and Aroclor fractions.

Only one 8oz jar was received for sample COO A3, which is designated as the sample for laboratory QC. The sample was extracted for the pesticides and Aroclor analysis with about 40gram of sample remaining. It is possible to extract lOgram of sample each for the pesticides and Aroclor laboratory QC and adjust the spike and final volume as best as possible. Per the Region, this is acceptable.

During extraction of the pesticides laboratory QC, the incorrect mafrix spike solution was used. There is no remaining sample for pesticides laboratory QC for sample COO A3. If possible, the laboratory would like to perform laboratory QC on a different sample. Per the Region, the laboratory may select a different sample for the pesticides laboratory QC. Laboratory QC for pesticides was performed on sample C00A4.

The following samples are submitted in this data package:

Client ID C0097 C00A3 C00A3MS C0OA3MSD C00A3RE C00A4 C00A4MS C00A4MSD C00A5 COOBO

S = Semivolatiles P = Pesticides A = Aroclors

Lab ID G0821-01A G0821-02A G0821-02AMS G0821-02AMSD G0821-02ARA G0821-03A G0821-03AMS G0821-03AMSD G0821-04A G0821-05A

Analysis S,P,A S,P,A

A A.

S S,P,A

P P

S,P,A S,P,A

AR100088

The analyses were performed using USEPA CLP Multi-Media, Muhi-Concentration (SOMOl.2) protocols. The analyses were performed with strict adherence to the SOW with the following exceptions and observations:

1. Overall Observation:

Where needed, manual integrations were performed to improve data quality. The corrections were reviewed and associated hardcopies generated and reported as required. Manual integrations are coded to provide the data revievi er justification for such action. The codes are labeled on the ion chromatogram signal (GC/MS signal) and chromatogram for GC based analysis as follows:

• Ml peak tailing or fronting. • M2 peak co-elution. • M3 rising or fallmg baseUne. • M4 retention time shift. • M5 miscellaneous - under tljis category, the justification is explained. » M6 software did not integrate peak • M7 partial peak integration

2. Semivolatile Analysis:

GC column: 30 m x 0.25 mm id (0.5 um film thickness) DB-5MS capillary column

The following equation was used to calculate the concentration of target analytes for soil samples:

_1_^ Ws,

( 100 (100-w)j

Concentration (//g/Kg) = (AmtXDFXUf)(—

where: Amt = on-column amount on raw data DF = Dilution factor UF = ng unit correction factor Ws = Weight of sample extracted (g) M = %moisture (not decanted)

The following equation was used to calculate the Amt in the previous equations:

AR100089

Am.-^ '*-^ ' ' '> (,A,)(RRF)

where: Ax = area of the characteristic ion for the compound to be measured Ais = area of the characteristic ion for the associated internal standard IS = concentration of internal standard in ug/L, RRF = relative response factor

Alkanes were determined as part of tentatively identified compounds. The alkanes are reported on the Alkane Narrative Report following the SDG narrative.

DMC recoveries were within the QC limits with the exception of no recovery of 4-chloroaniline-d4 in samples COO A3 and C0097 and low recovery of dimethylphthalate-d6 and fluorene-dIO in sample C00A5. Sample C00A3 was re-analyzed with similar findings.

Internal standard area counts were within QC criteria with the exception of sample C00A3. The sample was re-analyzed with similar findings.

Endmg CCVs, SSTD0202J and SSTD0202N did not meet QC criteria. All the samples in there two analytical sequences were re-analyzed. In the re-analysis, the opening CCV was within QC criteria. After analysis of the samples, the ending CCV did not meet QC criteria.

The re-analysis of sample C00A3 is billable. The re-analysis was performed due to internal standard area counts outside of QC criteria. The re-anfJysis of sample COO A3 exhibited findings similar to the initial analysis.

No manual integrations were performed.

No other unusual observation was made for the analysis.

3.' Pesticides Analysis:

GC column used: 30 m x 0.53 mm id (0.42 um fihn thickness) CLPPestll and 30 m x 0.53 mm id (0.5 um film thickness) CLPPest megabore columns

The following equation was used to calculate the concentration of target analytes for soil samples:

•?a im f s ---s SKI'S* sefc? AR100090

Concentration (ug/Kg) - (AmtXOFXUf ]

(

Vt

(Vi*WS*^^^^-"^ 100 V V

where: Amt = CAL - AMT on ra,w data DF = Dilution factor UF = ng unit correction factor WS = Weight of sample extracted (g) Vt = Volume of fmal extract (uL) Vi = Volume injected (uL) M = %moisture (not decanted)

Surrogate recoveries were within the QC limits.

Spike recoveries were within the QC limits in the lab control samples.

Matrix spike and matrix spike duplicate ^^ere performed on sample C00A4. Spike recoveries and replicate RPDs were within the advisory QC limits.

Manual integrations were performed on the following: PEMB4: 4,4'-DDE in the rear column due to M7 T0XAPH1B4: toxaphene in die front column due to M3 TOXAPH2B4: toxaphene in the front column due to M3 TOXAPH5B4: toxaphene in the front column due to M3 INDC1B4: tetrachloro-m-xylene in the front colunm due to M6 T0XAPH1C4: toxaphene in the front column due to M3 TOXAPH2C4: toxaphene in the front column due to M3 TOXAPH4C4: toxaphene in the front column due to M3.

In CCV, INDC3BS, tetrachloro-m-xylene exceeded QC criteria in the rear column.

Standards PEMBZ and INDC3BA were used for tiie evaluation of the GPC check. Only tfie front column was used. Please note that Form 7 for these two standards only have data from the front coliimn.

No other unusual observation was made for the analysis.

4. Aroclor Analysis

GC column used: 30 m x 0.53 mm id (0.42 um film thickness) CLPPestll and 30 m x 0.53 mm id (0.5 um film thickness) CLPPest megabore columns

•m r ^ . - s , I •-

AR100091

The following equation was used to calculate the concentration of target analytes for soil samples:

Concentration (ug/Kg) = (AmtXOFXUf ] Vt

( V i - W S - ^ ' " " - - " V 100

where: Amt = CAL - AMT on raw data DF = Dilution factor UF = ng unit correction factor WS = Weight of sample extracted (g) Vt = Volume of final exiract (uL) Vi = Volume injected (uL) M = %moisture (not decanted)

Surrogate recoveries were within the QC] limits.

Spike recoveries were within the QC lindts in the lab control samples.

Matrix spike and matrix spike duplicate were performed on sample C00A3. Spike recoveries and replicate RPDs were within the advisory QC limits. Due to limited sample volume, the matrix spike and matrix spike duplicate were extracted using lOgram of sample. The surrogate and matrix spike spike amounts and the final volume were adjusted accordingly.

No manual integrations were performed.

No other unusual observation was made for the analysis.

All of the submittals to the region are originals other than logbook pages. Photocopies of logbook pages are included, with the originals maintained on file at the laboratory. Tunes, calibration verifications and initisd calibrations that are shared among several cases are photocopies indicating the location of the originals.

I certify that this Sample Data Package is in compliance with the terms and condition of the contract, both technically and for completeness, for other than the conditions detailed above. Release of the data contained in this hardcopy Sample Data Package and in the

6"^ -3°^ e'A S ^

AR100092

electronic data deliverable has been authorized by the Laboratory Manager or the Manager's designee, as verified by the following signature.

Agnes Ng CLP Project Manager 06/12/08

AR100093

Appendix C

Tentatively Identified Compounds (TICs)

AR100094

IK - FORM I SV-TIC

SEMIVOLATILE ORGANICS ANALYSIS DATA SHEET

TENTATIVELY IDENTIFIED COMPOUNDS

EPA SAMPLE NO.

C0087

Lab Name: MITKEM LABORATORIES

Lab Code: MITKEM Case No.: 37527

Matrix: (SOIL/SED/WATER) WATER

Sample wt/vol: 1000 (g/mL) ML

LOW

Contract:

Mod. Ref No.:

Lab Sample ID:

Lab File ID:

EP-W-05-030

SDG No, C0087

G0820-01A

S2F7913.D

Level: (TRACE or LOW/MED)

% Moisture: Decanted: (Y/N)

Extraction: (Type) CONT

Date Received: 05/30/2008

Concentrated Extract Volume: 1000 (uL) Date Extracted: 06/02/2008

Injection Volume: 2.0 (uL) GPC Factor: 1.00 Date Analyzed: 06/11/2008

GPC Cleanup: (Y/N) N pH: Dilution Factor: 1.0

01 02 03 04 05 06 07 '08 09 10 11 12 13 14 15

CONCENTRATION UNITS: (ug/L or ug/Kg) UG/L

•EPA-designated Registry Number.

CAS NUMBER COMPOUND NAME

IUnlcnown-01 143-07-7 Dodecanoic acid

82304-66-3 Unk;nown-02 7,9-Di-tert-butyl-l-oxaspiro Unknown-03 Unknown-04 Unknown-05

• ;Unknown-06

7683-64-9

E966796 2

Unknown-07 Unknown-08 Unknown-09 Unknown-10 Squalene Unknown-ll Unknown-12 Total Alkanes

RT

10.858 13.812 15.992 16.282 16.970

L 17.775 17.807 18.656 18.699 19.741 19.794 20.686 20.976 21.212 21.277

N/A

EST. CONC.

10 12 2.2 5.4 3.1 8.7 19 6.0

11 . 3.6 8.2 3.7 2.8 5.1 12

° 1 J NJ .

J NJ J J J J ' J J J J NJ J J

SOMOl.2 (6/2007)

,-s-.-a ,i f

AR100095

IK - FORM I SV-TIC

SEMIVOLATILE ORGANICS ANALYSIS DATA SHEET

TENTATIVELY IDENTIFIED COMPOUNDS

EPA SAMPLE NO.

Lab Name: MITKEM LABORATORIES

Lab Code: MITKEM Case No. 37527

Contract:

Mod. Ref No.

EP-W-05-030

C0097

SDG No.: C0097

Matrix: (SOIL/SED/WATER) SOIL

Sample wt/vol: 30.4 (g/mL)

Lab Sample ID: G0821-01A

Lab File ID: S2F7941.D

Level: (TRACE or LOW/MED) LOW

% Moisture: 36 Decanted: (Y/Nl N

Extraction: (Type) SONC

Date Received: 05/30/2008

Concentrated Extract Volume: 500 (uL) Date Extracted: 06/02/2008

Injection Volume: 2.0 (uL) GPC Factor: 2.00 Date Analyzed:

GPC Cleanup: (Y/N) Y pH:

06/11/2008

6.3 Dilution Factor: 1.0

01 02 03 04 05 06

V J8 09 10 11 12 13 14 15 16 17 18 19 20

CONCENTRATION UNITS: (ug/L or ug/Kg) UG/KG

'EPA-designated Registry Number.

5v, oi53<'^«^

CAS NUMBER

123-08-0 13674-84-5 1002-84-2 112-39-0

b00130-90-8

1 57-10-3

1 112-80-1 57-11-4

i&aa=^£2^ 629-96-9

000131-11-0 [73002-85-4

7494-34-0

83-48-7 83-46-5

L E966796 2

COMPOUND NAME

Benzaldehyde, 4-hydroxY-2-Propanol, 1-chloro-, phosp Pentadecanoic acid Hexadecanoic acid, methyl es Z-7-Hexadecenoic acid Unknown-01 n-Hexadecanoic acid Unknown-02 Oleic Acid Octadecanoic acid l-^Docooono u i'*'* otJ^ •* 1-Eicosanol -1 Doeesftne u'^^-^o*^" ' Z-2-Octadecen-l-ol Decane, 5,6-bis (2,2-dimethyl 26-Nor-5-cholesten-3.beta.-o Unknown-03 Stigmasterol .beta.-Sitosterol Unknown-04 Total Alkanes

RT

12.039 15.519 15.627 16.20/ 16.314 16.357 16.411 16.604 17.270 17.334 18.870 20.052 21.673 23.070 24.026 24.971 26.743 27.130 28.322 29.288

N/A

EST. CONC,

160 180 200 150 380 220 550 160 450 170 400 730

2500 280 810 450

1300 720

5400 490

4100

Q NJ NJ NJ NJ NJ J NJ J NJ NJ NJ NJ NJ NJ NJ NJ J NJ NJ J J

SOM01.2 (6/2007)

r* E"^ ••'ti 'O

AR100096

IK - FORM I SV-TIC

SEMIVOLATILE ORGANICS ANALYSIS DATA SHEET

TENTATIVELY IDENTIFIED COMPOUNDS

EPA SAMPLE NO.

C00A3

Lab Name: MITKEM LABORATORIES

Lab code: MITKEM Case No.: 37527

Contract:

Mod. Ref No.

EP-W-05-030

SDG No.: C0097

Matrix: (SOIL/SED/WATER) SOIL

Sample wt/vol: 30.4 (g/mL)

LOW

Lab Sample ID: G0821-02A

Lab File ID: S2F7916.D

Level: (TRACE or LOW/MED)

% Moisture: 65 Decanted: (Y/N) N

Extraction: (Type) SONC

Date Received: 05/30/2008

Concentrated Extract Volume: 500 (uL) Date Extracted: 06/02/2008

Injection Volume: 2.0'(uL) GPC Factor: 2.00 Date Analyzed: 06/11/2008

pH: GPC Cleanup: (Y/N) Y 6.3 Dilution Factor: 1.0

01 02 03 04 05 06 07 08 09 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26

CONCENTRATION UNITS: (ug/L or ug/Kg) UG/KG

CAS NUMBER COMPOUND NAME

•Unknown-01 515-13-9 ICyclohexane, 1-ethenyl-l-met

Unknown-02

112-39-0 929-79-3

57-10-31

56554-47-3 57-11-41

13187-99-0

1599-67-3 7683-64-9 15594-90-8 67860-04-2 593-50-0

7494-34-0

93-48-7 83-46-5

545-47-1 E9667962

Unknown-03 Unknown-04 Hexadecanoic acid, methyl es trans-2-Hexadecenoic acid Unknown-05 n-Hexadecanoic acid Unknown-06 Unknown-07 13-Octadecenoic acid, methyl Octadecanoic acid 2-Bromo dodecane Unknown-08 1-Docosene Squalene 1-Heneicosanol Oxirane, heptadecyl-l-Triacontanol 26-Nor-5-cholesten-3.beta.-o Unknown-09 Stigmasterol .beta.-Sitosterol Unknown-10 Lupeol Total Alkanes

RT

5,910 12,548 15.694 15.748 16.167 16.254 16.382 16.425 16.489 16.693 17.112 17.155 17.402 18.884 18.927 20.130 20.979 21.784 23.213 24.169 25.157 26.972 27.359 28.572 30.044 30.935

N/A

EST. CONC.

1400 490 970 • _, 400 320 • 800 1300 1300 5300 1300 590 740 1500 960

1100 1300 400

11000 2600 5800 2000 4000 2400 15000 2900 3200 19000

Q

J NJ J J J NJ NJ J NJ J J NJ NJ NJ J NJ NJ NJ NJ NJ NJ J NJ NJ J NJ J

•EPA-designated Registry Number.

SOMOl.2 (6/2007)

00S" AR100097

IK - FORM I SV-TIC

SEMIVOLATILE ORGANICS ANALYSIS DATA SHEET

TENTATIVELY IDENTIFIED COMPOUNDS

EPA SAMPLE NO.

Lab Name:

Lab Code:

MITKEM LABORATORIES

MITKEM Case No. 37527

Contract:

Mod. Ref No.

EP-W-05-030

SDG No, C0097

Matrix: (SOIL/SED/WATER) SOIL

Sample wt/vol: 30.4 (g/mL) G

Lab Sample ID: G0821-02ARA

Lab File ID: S2F7942.D

Level: (TRACE or LOW/MED) LOW

% Moisture: 65 Decanted: (Y/N) N

Extraction: (Type) SONC

Date Received: 05/30/2008

Concentrated Extract Vol'jme: 500 (uL) Date Extracted: 06/02/2008

Injection Volume: 2.0 (uL) GPC Factor: 2.00 Date Analyzed: 06/11/2008

pH: GPC Cleanup: (Y/N) Y 6.3 Dilution Factor: 1.0

01 02 03 04 05 06 ~07 ,08 09 10 11 12 13 14 15 16 17 18 19 20 21

CONCENTRATION UNITS: (ug/L or ug/Kg) UG/KG

CAS NUMBER

1002-84-2 112-39-0

1 2416-20-8 L 57-10-3 1 203-64-5 [

1 56554-48-4 57-11-4

! 1599-67-3 ; 7390-81-0 18835-33-1 53057-53-7 000131-11-8 000210-38-4

83-46-5

1617-70-5

1 E9667962

COMPOUND NAME

Pentadecanoic acid Hexadecanoic acid, methyl es Unknown-01 Hexadecenoic acid, Z-11-n-Hexadecanoic acid 4H-Cyclop=nta[def]phenanthre Unknown-02 Unknown-03 14-Octadecenoic acid, methyl Octadecanoic acid 1-Docosens Oxirane, hexadecyl-1-Hexacosene 1,21-Docosadiene Z-5-Nonadecene 17-{1,5-Dimethylhexyl)-10,13 Unknown-04 .beta.-Sitosterol Unknown-05 Lup-20(29)-en-3-one Unknown-06 Total Alkanes

RT

15.648 16.206 16.324 16.378 16.432

L 16.571 16.636 17.065 17.108 17.355 18.859 21.050 21.662 23.080 22.971 24.938 26.775 28.332 29.320 29.782 30.609

N/A

EST. CONC.

720 640

1200 1300 4000 310 900 460 610

1100 920

2000 9800 4100 4000 2400 3300 17000 2000 3300 4300 13000

Q 1 NJ 1 NJ 1 J j NJ 1

NJ NJ J J NJ NJ NJ NJ NJ j NJ NJ NJ J NJ J NJ J J

SOM01.2 (6/2007)

AR100098

IK - FORM I SV-TIC

SEMIVOLATILE ORGANICS ANALYSIS DATA SHEET

TENTATIVELY IDENTIFIED COMPOUNDS

EPA S.AMPLE NO.

TOAT

Lab Name: MITKEM LABORATORIES

Lab Code: MITKEM Case No.: 37527

Contract:

Mod. Ref No.

EP-W-05-030

SDG No,: C0097

Matrix: (SOIL/SED/WATER) SOIL

Sample wt/vol: 30.0 (g/mL)

Level: (TRACE or LOW/MED) LOW

% Moisture:

Lab Sample ID: G0821-03A

Lab Fi:.e ID: S2F7 94 3.D

Extraction: (Type) SONC

25 Decanted: (Y/N) Date Received: 05/30/2003

Concentrated Extract Volume: 500 (uL) Date Extracted: 06/02/2008

Injection Volume: 2.0 (uL) GPC Factor: 2.00 Date Analyzed: 06/11/2008

GPC Cleanup: (Y/N) Y pH: 5.9 Dilutio.-i Factor: 1.0

CONCENTRATION UNITS: (ug/L or ug/Kg) UG/KG

01 02 03 04 05 06 07 08

•EPA-designated Registry Number.

CAS NUMBER

57-10-3 1599-67-3 124-25-4

I 18535-33-1 1

1 E966796 2

COMPOUND NAME

n-Hexadecanoic acid 1-Docosene Tetradecanal 1-Hexacosene Unknown-01 Unknown-02 Unknown-03 Unknown-04 Total Alkanes

R::

16.380 18.882 21.030 21.718 23.060 26.938 28.312 30.439

N/A

EST. CONC.

97 220 150 630 180 350 380 470

1100

Q

NJ NJ NJ NJ J J J J J

SOMOl.2 (6/2007)

AR100099

( .

IK - FORM I SV-TIC

SEMIVOLATILE ORGANICS ANALYSIS DATA SHEET

TENTATIVELY IDENTIFIED COMPOUNDS

EPA SAMPLE NO. TOAT

Lab Name: MITKEM LABORATORIES

Lab Code: MITKEM Case No.: 37527

Contract:

Mod. Ref No.

EP-W-05-030

SDG No.: C0097

Matrix: (SOIL/SED/WATER) SOIL

Sample wt/vol: 30.4 (g/mL) G

Level: (TRACE or LOW/MED)

% Moisture:

Lab Sample ID: G0821-04A

Lab File ID: S2F7944.D

LOW Extraction: (Type) SONC

26 Decanted: (Y/N) N Date Received: 05/30/2008

5D0 (uL) Date Extracted: 06/02/2008 Concentrated Extract Volume:

Injection Volume: 2.0 (uL) GPC Factor: 2.00 Date Analyzed: 06/11/2008

GPC Cleanup: (Y/N) Y pH: 6.5 D i l u t i o n F a c t o r : 1.0

01 02 03 04 05 06 07

CONCENTRATION UNITS: (ug/L or ug/Kg) UG/KG

EPA-designated Registry Number.

CAS NUMBER COMPOUND NAME

jUnknown-Ol

RT

1 8 . 8 2 7 iUnknown-02 1 8 . 9 0 2

6 9 7 1 - 4 0 - 0

E9667962

Unknown-D3 1 7 - P e n t a t r i a c o n t e n e Unknown-04

1 9 . 9 6 5 2 0 . 1 0 5 2 1 . 7 3 7

Unknown-35 | 2 8 . 3 5 3 Unknown-D6 T o t a l A l k a n e s

3 0 . 4 3 7

EST. CONC.

120 110 110

Q

J J J

130 NJ 430 U 200 ! J

580 iJ N/Ai 7 7 0 J

SOy.01.2 (6/2007)

AR100100

IK - FORM •{ SV-TIC SEMIVOLATILE ORGANICS ANALYSIS DATA SHEET

TENTATIVELY IDENTIFIE.O COMPOUNDS

EPA SAMPLE NO.

:00B0

Lab Name: MITKEM LABORATORIES

Lab Code: MITKEM

EP-W-05-030

Case No.: 37527

Matrix: (SOIL/SED/WATER) SOIL

Sample wt/vol: 30.0 (g/mL) G

LOW

Contract:

Mod. Ref No.:

Lab Sample ID: G0821-05A

Lab File ID: S2F7945.D

Level: (TRACE or LOW/MED)

% Moisture: 22 Decanted: (Y/N) N

Extraction: (Type) SONC

Date Received: 05/30/2008

Concentrated Extract Volume: 500 (uL) Date Extracted: 06/02/2008

Injection Volume: 2.0 (uL) GPC Factor: 2.00 Date Analyzed: 06/12/2008

pH: GPC Cleanup: (Y/N) Y 6.1 Dilution Factor: 1.0

01 02 03 04 05 06 17

CONCENTRATION UNITS: (ug/L or ug/Kg) OG/KG

•EPA-designated Registry Number.

SDG No. : C0097

CAS NUMBER COMPOUND NAME

•Unknown-01 264-09-5 iBenzocycloheptatriene 573-98-8 Naphthalene, 1,2-d.Lmethyl-

Unknown-02 2531-84-2 949-41-7 613-12-7 E9667962

Phenanthrene, 2-methyl-IH-Cyclopropa[1]ph«manthrene Anthracene, 2-methvl-Total Alkanes

RT

11.171 11.869 13.061 15.370 16.455 15.552 15.584

N/A

EST. CONC.

94 110 87 110 150 110 160

2500

Q

J NJ NJ J NJ NJ NJ J

SOM01.2 (6/2007)

^ ^ J!*^ ,^^, rf">

AR100101

APPENDIX C

TDD No.: W33-020-08-07-021

AR100102

Appendix C - Photographic Documentation Carr China Site

Grafton, Taylor County, West Virginia

5/28/2008

DSCN0106JPG

China debris pile.

3/28/2008

DSCN0107,JPG

Pond in southeastern comer of the site.

( . )

5/28/2008

DSCN0108JPG

Tygart River edge near the northeastern comer of property.

5/28/2008

DSCN0109JPG

Former kiln area.

AR100103

Appendix C - Photographic Documentation Carr China Site

Grafton, Taylor County, West Virginia

5/28/2008

DSCN0110JPG

Area with debris near the westem end of property.

5/28/2008

DSCN0111JP6

Collecting soil sample SSO1 in debris pile in eastern portion of the site.

5/28/2008

DSCN0112,JPG

Collecting soil sample SSOl in debris pile in eastem portion of the site.

5/28/2008

DSCN0113.JPG

Collecting soil sample SS03 in debris pile in eastem portion of the site.

AR100104

Appendix C - Photographic Documentation Carr China Site

Grafton, Taylor County, West Virginia

•-.%*svfJ,"yV>'.'*i/

: ' : P ^ - : . ? ••

5/28/2008

DSCN0114JPG

Close up of soil sample location SS03 in debris pile in eastem portion of the site. Dark soil with white fines mixed.

5/28/2008

DSCN0115JPG

Collecting soil sample SS02 in ravine area in eastem portion of the site.

5/28/2008

DSCN0116,JPG 5/28/2008

DSCN0117.JPG

Collecting sediment sample SD03 in ravine drainage basin area in eastem portion of the site.

Collecting soil sample SS04 in hole where a tree uprooted. White sandy material mixed with soil.

AR100105

( .

Appendix C - Photographic Documentation Carr China Site

Grafton, Taylor County, West Virginia

5/28/2008

DSCNOnSJPG

Collecting soil sample SS04 in hole where a tree uprooted. White sandy material mixed with soil.

5/28/2008

DSCN0119JPG

Collecting sediment sample SDOl in pond in southeastern comer of property.

5/28/2008

DSCN0120JPG

Collecting sediment sample SDOl in pond in southeastern comer of property.

5/28/2008

DSCN0121,JPG

Collecting sediment sample SD02 in edge of Tygart Valley River near northeastern comer of property.

AR100106

Appendix C - Photographic Documentation Carr China Site

Grafton, Taylor County, West Virginia

5/28/2008 DSCN0122JPG

5/28/2008 DSCN0123JPG

Collecting soil sample SS05 near kiln on west side of property. Hole under concrete pad near SS05,

5/28/2008 DSCN0124,JPG

5/28/2008

DSCN0125,JPG

Collecting soil sample SS07 outside fence and north of power pole area on westem portion of property.

Collecting soil sample SS07 outside fence and north of power pole area on westem portion of property.

AR100107

Appendix C - Photographic Documentation Carr China Site

Grafton, Taylor County, West Virginia

5/28/2008

DSCN0126JPG

Collecting soil sample SS08 near power pole area on westem portion of property.

( • )

5/28/2008

DSCN0127JPG

Collecting soil sample SS08 near power pole area on westem portion of property.

5/28/2008

DSCN0128,JPG

Collecting soil sample SSI 7 in drainage path to Tygart River in area with china plates on soil surface.

5/28/2008

DSCN0129,JPG

Collecting sediment sample sample SD06 at edge of Tygart River,'

AR100108

Appendix C - Photographic Documentation Carr China Site

Grafton, Taylor County, West Virginia

5/28/2008

DSCN0130JPG

Collecting soil sample SS09 near baghouse equipment in area with white sand/powder on surface.

5/28/2008

DSCN0131JPG

Collecting soil sample SS09 near baghouse equipment in area with white sand/powder on surface.

5/28/2008

DSCN0132JPG 5/28/2008

DSCN0133.JPG

Collecting soil sample SSIO on banks above Tygart River. China debris in vicinity.

Collecting soil sample SSIO on banks above Tygart River. China debris in vicinity. Metal drainage pipe visible at top of the bank.

AR100109

Appendix C - Photographic Documentation Carr China Site

Grafton, Taylor County, West Virginia

5/28/2008

DSCN0134JPG

China debris on the banks and in the Tygart River.

5/28/2008

DSCN0135JPG

Collecting soil sample SSI 1 near kiln in westem portion of site.

5/28/2008

DSCN0136JPG 5/28/2008

DSCN0137.JPG

Collecting soil sample SSI6 from soil under china debris pile. China was glazed and had been shredded.

Collecting soil sample SSI2 and duplicate sample SSI3 from area of what appeared to be coal ash and mixed with soil.

8

AR100110

Appendix C - Photographic Documentation Carr China Site

Grafton, Taylor County, West Virginia

5/28/2008

DSCN0138.JPG

Soil sample location for SS 12 and duplicate sample SS 13.

5/28/2008

DSCN0139JPG

Collecting soil sample SSI 5 from pile of shredded china mixed with soil.

5/28/2008

DSCN0140,JPG 5/28/2008

DSCN0r41JPG

Soil sample SS 15 location. Close up of shredded china and soil where SSI 5 was collected.

AR100111

Appendix C - Photographic Documentation Carr China Site

Grafton, Taylor County, West Virginia

5/28/2008 DSCN0142,JPG

Collecting soil sample SS14 on sandbar at edge of Tygart River.

5/28/2008

DSCN0143JPG

Collecting sediment sample SD05 from tributary at westem property boundary.

5/28/2008

DSCN0144JPG 5/28/2008

DSCN0145.JPG

Collecting sediment sample SD04 and duplicate sample SD07 from edge of Tygart River, upstream of tributary and site boundary.

Collecting soil sample SSI 8 in area of debris pile near southwestern comer of property.

10

AR100112

Appendix C - Photographic Documentation Carr China Site

Grafton, Taylor County, West Virginia

5/28/2008

DSCN0146JPG 5/2S/20O8

DSCN0147JPG

Collecting soil sample SSI 9 from hole at edge of roadway. Collecting soil sample SS19 from hole at edge of roadway.

5/28/2008

DSCN0148JPG 5/29/2008

DSCN0149JPG

Collecting soil sample SS20 from hole at drainage pipe at edge of concrete roadway.

Gaging station and gravel road that separates the eastem and westem portion of property.

11

AR100113

Appendix C - Photographic Documentation Carr China Site

Grafton, Taylor County, West Virginia

5/29/2008

D5CN0150JPG 5/29/2008 DSCN0151JPG

Bricks at entrance to site from Pottery Lane. White sand/silica at entrance to site on westem portion of site.

5/29/20O8

DSCN01S2JPG

•V 1.'VW -'

'.•=...^-:if.'W^ •"•>=i°-', ' . • . • i>3. 'S ' 'Ev- ' - ' ' , ; • • • -•

5/29/2008

DSCN0153JPG

Opening in fence in southern boundary of westem portion of site.

Fence line along Pottery Lane on westem portion of property.

12

AR100114

Appendix C - Photographic Documentation Carr China Site

Grafton, Taylor County, West Virginia

5/29/2008

DSCN0154JPG

Pottery Lane at eastem portion of site, southern side.

13

AR100115