fischer-tropsch synthesis – development of … · in recent years, fischer-tropsch synthesis has...

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44 Annual Report 2017/18 Dr. Erik Reichelt, Dipl.-Ing. Aniko Walther, M. Sc. Max Schaller, Dipl.-Ing. Gregor Herz, Dr. Matthias Jahn Contact Erik Reichelt • Phone +49 351 2553-7764 • [email protected] In recent years, Fischer-Tropsch synthesis has undergone a renaissance against the background of the use of renewable resources. The possibility of producing several chemicals from different renewable carbon sources (biomass, CO 2 ) via the inter- mediate step of synthesis gas production explains the renewed interest in this nearly 100-year-old process. While research is in many cases focused solely on catalyst development, the focus of Fraunhofer IKTS is on the complete development chain – from catalyst to the overall process. Our research in Fischer-Tropsch synthesis looks mainly at process paths leading to high-quality chemical products. Selectivity for obtaining the desired end products is optimized by developing specific iron- and cobalt-based catalysts. The higher alcohols and waxes thus produced are of particular interest for use in the cosmetics industry. Utilizing sustainable carbon feedstocks means that small-scale decentralized plants are needed. Therefore, novel process and reactor concepts with low capital and operational expenditures have to be developed. Novel ceramic manufacturing technolo- gies available at IKTS allow for the production of catalyst support structures with advantageous mass and heat transfer characte- ristics. In addition, adapted reactor concepts are in development which, among other things, will enable easy replacement of the catalyst structures at the end of their service life. Under the coordination of IKTS, two innovative process con- cepts are currently being demonstrated in pilot plants. For the first time worldwide, the conversion of biogas into wax and the production of higher alcohols from CO 2 and H 2 O via co-electrolysis and Fischer-Tropsch synthesis are realized in one single technical process. The results of both pilot studies not only allow for the validation of the developed process models but also for the evaluation of economic feasibility. 1 Wax produced through Fischer-Tropsch synthesis. 2 Fischer-Tropsch reactor. 2 1 FISCHER-TROPSCH SYNTHESIS – DEVELOPMENT OF SELECTIVE CATALYSTS AND PROCESSES ENVIRONMENTAL AND PROCESS ENGINEERING Composition of the oily product phase for different promoted iron catalysts

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Page 1: FISCHER-TROPSCH SYNTHESIS – DEVELOPMENT OF … · In recent years, Fischer-Tropsch synthesis has undergone a renaissance against the background of the use of renewable resources

44 Annual Report 2017/18

Dr. Er ik Reichelt , Dipl . - Ing. Aniko Walther, M. Sc. Max Schal ler, Dipl . - Ing. Gregor Herz, Dr. Matthias Jahn

Contact Erik Reichelt • Phone +49 351 2553-7764 • [email protected]

In recent years, Fischer-Tropsch synthesis has undergone a

renaissance against the background of the use of renewable

resources. The possibility of producing several chemicals from

different renewable carbon sources (biomass, CO2) via the inter-

mediate step of synthesis gas production explains the renewed

interest in this nearly 100-year-old process. While research is in

many cases focused solely on catalyst development, the focus

of Fraunhofer IKTS is on the complete development chain –

from catalyst to the overall process.

Our research in Fischer-Tropsch synthesis looks mainly at process

paths leading to high-quality chemical products. Selectivity for

obtaining the desired end products is optimized by developing

specific iron- and cobalt-based catalysts. The higher alcohols

and waxes thus produced are of particular interest for use in

the cosmetics industry.

Utilizing sustainable carbon feedstocks means that small-scale

decentralized plants are needed. Therefore, novel process and

reactor concepts with low capital and operational expenditures

have to be developed. Novel ceramic manufacturing technolo-

gies available at IKTS allow for the production of catalyst support

structures with advantageous mass and heat transfer characte-

ristics. In addition, adapted reactor concepts are in development

which, among other things, will enable easy replacement of

the catalyst structures at the end of their service life.

Under the coordination of IKTS, two innovative process con-

cepts are currently being demonstrated in pilot plants. For the

first time worldwide, the conversion of biogas into wax and

the production of higher alcohols from CO2 and H2O via

co-electrolysis and Fischer-Tropsch synthesis are realized in one

single technical process. The results of both pilot studies not

only allow for the validation of the developed process models

but also for the evaluation of economic feasibility.

1 Wax produced through

Fischer-Tropsch synthesis.

2 Fischer-Tropsch reactor.

21

FISCHER-TROPSCH SYNTHESIS – DEVELOPMENT OF SELECTIVE CATALYSTS AND PROCESSES

E N V I R O N M E N T A L A N D P R O C E S S E N G I N E E R I N G

Composition of the oily product phase for different promoted iron catalysts