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Frictional Behavior of bio-based Gp V Base Stocks Presented at Prepared by Matthias Hof, Ph. D. Global Manager Product & Application Development Bio-Lubricants Emery Oleochemicals GmbH Presented by Frank Bongardt, Ph. D. New Business development and Market Manager Bio- Lubricants Emery Oleochemicals GmbH

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Page 1: Frictional Behavior of bio-based Gp V Base Stocks · Global Manager Product & Application Development Bio- Lubricants Emery Oleochemicals GmbH Presented by Frank Bongardt, Ph. D

Frictional Behavior of bio-based

Gp V Base Stocks

Presented at Prepared by Matthias Hof, Ph. D. Global Manager Product & Application Development Bio-Lubricants Emery Oleochemicals GmbH

Presented by Frank Bongardt, Ph. D. New Business development and Market Manager Bio- Lubricants Emery Oleochemicals GmbH

Page 2: Frictional Behavior of bio-based Gp V Base Stocks · Global Manager Product & Application Development Bio- Lubricants Emery Oleochemicals GmbH Presented by Frank Bongardt, Ph. D

Page 2 Presented at UNITI 2016, Copyrights Reserved

1 Trends in the Industry

2 Contribution of Lubricants

3 Test Matrix

4 Test Results

5 Summary

Agenda

Page 3: Frictional Behavior of bio-based Gp V Base Stocks · Global Manager Product & Application Development Bio- Lubricants Emery Oleochemicals GmbH Presented by Frank Bongardt, Ph. D

Page 3 Presented at UNITI 2016, Copyrights Reserved

Trends in the Industry Energy

Source : STLE paper “Trends in Tribology and Lubrication Engineering : 2014 Report on Emerging Issues and Trends”

Page 4: Frictional Behavior of bio-based Gp V Base Stocks · Global Manager Product & Application Development Bio- Lubricants Emery Oleochemicals GmbH Presented by Frank Bongardt, Ph. D

Page 4 Presented at UNITI 2016, Copyrights Reserved

Trends in the Industry Energy

Source : STLE paper “Trends in Tribology and Lubrication Engineering : 2014 Report on Emerging Issues and Trends”

Page 5: Frictional Behavior of bio-based Gp V Base Stocks · Global Manager Product & Application Development Bio- Lubricants Emery Oleochemicals GmbH Presented by Frank Bongardt, Ph. D

Page 5 Presented at UNITI 2016, Copyrights Reserved

Trends in the Industry Safety and the Environment

Source : STLE paper “Trends in Tribology and Lubrication Engineering : 2014 Report on Emerging Issues and Trends”

Page 6: Frictional Behavior of bio-based Gp V Base Stocks · Global Manager Product & Application Development Bio- Lubricants Emery Oleochemicals GmbH Presented by Frank Bongardt, Ph. D

Page 6 Presented at UNITI 2016, Copyrights Reserved

Trends in the Industry Manufacturing

Source : STLE paper “Trends in Tribology and Lubrication Engineering : Industry Leader Predictions Report November 2015”

Page 7: Frictional Behavior of bio-based Gp V Base Stocks · Global Manager Product & Application Development Bio- Lubricants Emery Oleochemicals GmbH Presented by Frank Bongardt, Ph. D

Page 7 Presented at UNITI 2016, Copyrights Reserved

Trends in the Industry Transportation

Source : STLE paper “Trends in Tribology and Lubrication Engineering : Industry Leader Predictions Report November 2015”

Page 8: Frictional Behavior of bio-based Gp V Base Stocks · Global Manager Product & Application Development Bio- Lubricants Emery Oleochemicals GmbH Presented by Frank Bongardt, Ph. D

Page 8 Presented at UNITI 2016, Copyrights Reserved

Trends in the Industry Summary

In various fields one of the major trends is towards Energy Efficiency

The contribution must come from hardware and equipment as well from the fluids need for operation

Lubricants need to further lower the consumption of fuel and energy in all sectors : industrial and automotive and MWF´s

Some minor trends also towards greener solutions but performance requirements are top of the list

Page 9: Frictional Behavior of bio-based Gp V Base Stocks · Global Manager Product & Application Development Bio- Lubricants Emery Oleochemicals GmbH Presented by Frank Bongardt, Ph. D

Page 9 Presented at UNITI 2016, Copyrights Reserved

How can Lubricants contribute ?

Energy and Fuel Efficiency through the use of Lubricants is mostly contributed through the reduction of friction between contact surfaces and within the lubricant

This can be reached with various approaches Advanced formulation technology

Usage of high performance additives

Choice of superior base stock chemistry

Page 10: Frictional Behavior of bio-based Gp V Base Stocks · Global Manager Product & Application Development Bio- Lubricants Emery Oleochemicals GmbH Presented by Frank Bongardt, Ph. D

Page 10 Presented at UNITI 2016, Copyrights Reserved

Lubrication

Ester

PAO Gp III

Gp II

Gp I

PAG very good

poor

Lubrication Effects Comparison of Base Stocks

Page 11: Frictional Behavior of bio-based Gp V Base Stocks · Global Manager Product & Application Development Bio- Lubricants Emery Oleochemicals GmbH Presented by Frank Bongardt, Ph. D

Page 11 Presented at UNITI 2016, Copyrights Reserved

Lube Esters

Polyol Esters

Mono Esters

Di Esters

Complex Esters

Esters for lubricants Categories

Page 12: Frictional Behavior of bio-based Gp V Base Stocks · Global Manager Product & Application Development Bio- Lubricants Emery Oleochemicals GmbH Presented by Frank Bongardt, Ph. D

Page 12 Presented at UNITI 2016, Copyrights Reserved

Basic ester design rules

branched • Low VI, low pourpoint

linear • High VI, high pourpoint

saturated • High oxidation stability, high pourpoint

unsaturated • Poor oxidation stability, low pourpoint

Page 13: Frictional Behavior of bio-based Gp V Base Stocks · Global Manager Product & Application Development Bio- Lubricants Emery Oleochemicals GmbH Presented by Frank Bongardt, Ph. D

Page 13 Presented at UNITI 2016, Copyrights Reserved

Test Matrix Test Methods 3 different test methods and instruments have been used

looking at Frictional Behavior/Wear/Film Thickness

Page 14: Frictional Behavior of bio-based Gp V Base Stocks · Global Manager Product & Application Development Bio- Lubricants Emery Oleochemicals GmbH Presented by Frank Bongardt, Ph. D

Page 14 Presented at UNITI 2016, Copyrights Reserved

Powertrib MTM – test

Page 15: Frictional Behavior of bio-based Gp V Base Stocks · Global Manager Product & Application Development Bio- Lubricants Emery Oleochemicals GmbH Presented by Frank Bongardt, Ph. D

Page 15 Presented at UNITI 2016, Copyrights Reserved

Test Matrix Ester Base Stocks 10 esters have been evaluated in the project grouped by

VG class and chemistry CHEM 1 : Oleates

CHEM 2 : Branched

CHEM 3 : Saturated

Page 16: Frictional Behavior of bio-based Gp V Base Stocks · Global Manager Product & Application Development Bio- Lubricants Emery Oleochemicals GmbH Presented by Frank Bongardt, Ph. D

Page 16 Presented at UNITI 2016, Copyrights Reserved

Test Results Shear Stability

Page 17: Frictional Behavior of bio-based Gp V Base Stocks · Global Manager Product & Application Development Bio- Lubricants Emery Oleochemicals GmbH Presented by Frank Bongardt, Ph. D

Page 17 Presented at UNITI 2016, Copyrights Reserved

Test Results Shear Stability

Page 18: Frictional Behavior of bio-based Gp V Base Stocks · Global Manager Product & Application Development Bio- Lubricants Emery Oleochemicals GmbH Presented by Frank Bongardt, Ph. D

Page 18 Presented at UNITI 2016, Copyrights Reserved

Test Results Shear Stability

Page 19: Frictional Behavior of bio-based Gp V Base Stocks · Global Manager Product & Application Development Bio- Lubricants Emery Oleochemicals GmbH Presented by Frank Bongardt, Ph. D

Page 19 Presented at UNITI 2016, Copyrights Reserved

Test Results Shear Stability

Page 20: Frictional Behavior of bio-based Gp V Base Stocks · Global Manager Product & Application Development Bio- Lubricants Emery Oleochemicals GmbH Presented by Frank Bongardt, Ph. D

Page 20 Presented at UNITI 2016, Copyrights Reserved

Test Results Shear Stability

Page 21: Frictional Behavior of bio-based Gp V Base Stocks · Global Manager Product & Application Development Bio- Lubricants Emery Oleochemicals GmbH Presented by Frank Bongardt, Ph. D

Page 21 Presented at UNITI 2016, Copyrights Reserved

Test Results Film Thickness

Page 22: Frictional Behavior of bio-based Gp V Base Stocks · Global Manager Product & Application Development Bio- Lubricants Emery Oleochemicals GmbH Presented by Frank Bongardt, Ph. D

Page 22 Presented at UNITI 2016, Copyrights Reserved

Test Results Film Thickness

Page 23: Frictional Behavior of bio-based Gp V Base Stocks · Global Manager Product & Application Development Bio- Lubricants Emery Oleochemicals GmbH Presented by Frank Bongardt, Ph. D

Page 23 Presented at UNITI 2016, Copyrights Reserved

Test Results Film Thickness

Page 24: Frictional Behavior of bio-based Gp V Base Stocks · Global Manager Product & Application Development Bio- Lubricants Emery Oleochemicals GmbH Presented by Frank Bongardt, Ph. D

Page 24 Presented at UNITI 2016, Copyrights Reserved

Test Results Film Thickness

Page 25: Frictional Behavior of bio-based Gp V Base Stocks · Global Manager Product & Application Development Bio- Lubricants Emery Oleochemicals GmbH Presented by Frank Bongardt, Ph. D

Page 25 Presented at UNITI 2016, Copyrights Reserved

Test Results Film Thickness

Page 26: Frictional Behavior of bio-based Gp V Base Stocks · Global Manager Product & Application Development Bio- Lubricants Emery Oleochemicals GmbH Presented by Frank Bongardt, Ph. D

Page 26 Presented at UNITI 2016, Copyrights Reserved

Test Results Film Thickness

Page 27: Frictional Behavior of bio-based Gp V Base Stocks · Global Manager Product & Application Development Bio- Lubricants Emery Oleochemicals GmbH Presented by Frank Bongardt, Ph. D

Page 27 Presented at UNITI 2016, Copyrights Reserved

Test Results Film Thickness

Page 28: Frictional Behavior of bio-based Gp V Base Stocks · Global Manager Product & Application Development Bio- Lubricants Emery Oleochemicals GmbH Presented by Frank Bongardt, Ph. D

Page 28 Presented at UNITI 2016, Copyrights Reserved

Test Results Frictional Behavior

Page 29: Frictional Behavior of bio-based Gp V Base Stocks · Global Manager Product & Application Development Bio- Lubricants Emery Oleochemicals GmbH Presented by Frank Bongardt, Ph. D

Page 29 Presented at UNITI 2016, Copyrights Reserved

Test Results Frictional Behavior

Page 30: Frictional Behavior of bio-based Gp V Base Stocks · Global Manager Product & Application Development Bio- Lubricants Emery Oleochemicals GmbH Presented by Frank Bongardt, Ph. D

Page 30 Presented at UNITI 2016, Copyrights Reserved

Test Results Frictional Behavior

Page 31: Frictional Behavior of bio-based Gp V Base Stocks · Global Manager Product & Application Development Bio- Lubricants Emery Oleochemicals GmbH Presented by Frank Bongardt, Ph. D

Page 31 Presented at UNITI 2016, Copyrights Reserved

Test Results Frictional Behavior

Page 32: Frictional Behavior of bio-based Gp V Base Stocks · Global Manager Product & Application Development Bio- Lubricants Emery Oleochemicals GmbH Presented by Frank Bongardt, Ph. D

Page 32 Presented at UNITI 2016, Copyrights Reserved

Test Results Frictional Behavior

Page 33: Frictional Behavior of bio-based Gp V Base Stocks · Global Manager Product & Application Development Bio- Lubricants Emery Oleochemicals GmbH Presented by Frank Bongardt, Ph. D

Page 33 Presented at UNITI 2016, Copyrights Reserved

Test Results Frictional Behavior

Page 34: Frictional Behavior of bio-based Gp V Base Stocks · Global Manager Product & Application Development Bio- Lubricants Emery Oleochemicals GmbH Presented by Frank Bongardt, Ph. D

Page 34 Presented at UNITI 2016, Copyrights Reserved

Test Results Frictional Behavior

Page 35: Frictional Behavior of bio-based Gp V Base Stocks · Global Manager Product & Application Development Bio- Lubricants Emery Oleochemicals GmbH Presented by Frank Bongardt, Ph. D

Page 35 Presented at UNITI 2016, Copyrights Reserved

Test Results Frictional Behavior

Page 36: Frictional Behavior of bio-based Gp V Base Stocks · Global Manager Product & Application Development Bio- Lubricants Emery Oleochemicals GmbH Presented by Frank Bongardt, Ph. D

Page 36 Presented at UNITI 2016, Copyrights Reserved

Summary

Different Chemistries show different behavior and film thickness

All ester base stocks show comparable shear stability Branched and Oleate systems show highest film thickness

especially at low speed conditions Traction and frictional behavior is even more depending on

chemistry Branched systems show higher friction at same VG class

Oleates have lowest friction values

Page 37: Frictional Behavior of bio-based Gp V Base Stocks · Global Manager Product & Application Development Bio- Lubricants Emery Oleochemicals GmbH Presented by Frank Bongardt, Ph. D

Thank You !!!

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