hcl, dep. calc. e0,v10,v11

14
dep. Calc. V11 /notendur.hi.is/agust/rannsoknir/rempi/hcl/July12/PPT-130812ak.ppt

Upload: querida-carvalho

Post on 13-Mar-2016

56 views

Category:

Documents


4 download

DESCRIPTION

HCl, dep. Calc. E0,V10,V11 https://notendur.hi.is/agust/rannsoknir/rempi/hcl/July12/PPT-130812ak.ppt. D1. Points for 0 < D1 < 0.001 -for W2 £ W3. W3. W2. Above line: for W2 £ W3 ; below line: W2 > W3. - PowerPoint PPT Presentation

TRANSCRIPT

Page 1: HCl, dep. Calc. E0,V10,V11

HCl, dep. Calc.

E0,V10,V11

https://notendur.hi.is/agust/rannsoknir/rempi/hcl/July12/PPT-130812ak.ppt

Page 2: HCl, dep. Calc. E0,V10,V11

240

220

200

180

160

140

120

100

80

24022020018016014012010080

-0.3

-0.2

-0.1

0.0

0.1

0.2

W3

W2

Points for 0 < D1 < 0.001-for W2 W3

https://notendur.hi.is/agust/rannsoknir/rempi/hcl/July12/PXP-130812ak.pxp Lay:0 Gr:0

Above line: for W2 W3; below line: W2 W3

D1

Page 3: HCl, dep. Calc. E0,V10,V11

210

205

200

195

190

185

200195190185180

-0.3

-0.2

-0.1

0.0

0.1

0.2Points for 0 < D1 < 0.001-for W2 W3

W3

W2

https://notendur.hi.is/agust/rannsoknir/rempi/hcl/July12/PXP-130812ak.pxp Lay:0 Gr:0

186 195

206

192

D1

Page 4: HCl, dep. Calc. E0,V10,V11

240

220

200

180

160

140

120

100

80

24022020018016014012010080

B1

Points for 0 < D1 < 0.001-for W2 W3

W3

W2

https://notendur.hi.is/agust/rannsoknir/rempi/hcl/July12/PXP-130812ak.pxp Lay:1 Gr:1

Above line: for W2 W3; below line: W2 W3

Page 5: HCl, dep. Calc. E0,V10,V11

220

210

200

190

180

205200195190185180175

B1

Points for 0 < D1 < 0.001-for W2 W3

W3

W2

https://notendur.hi.is/agust/rannsoknir/rempi/hcl/July12/PXP-130812ak.pxp Lay:1 Gr:1

B1(max)

Max B1 inside“the red dot circle” is 10.10 ! (for W2,W3= 191,196)=> D1 = +0.0092

Page 6: HCl, dep. Calc. E0,V10,V11

w2 w3 B1186 196 9.08579186 197 9.12887186 198 9.11624186 199 9.06563186 200 8.99954187 194 9.07958187 202 8.97708188 203 9.0112189 192 9.03798189 193 9.13495189 194 9.14774190 193 9.1161190 205 8.99614191 194 9.20785191 195 9.2241192 196 9.26265192 206 9.0676194 200 9.3407194 204 9.33375194 205 9.23704195 203 9.3716 B1(max)

https://notendur.hi.is/agust/rannsoknir/rempi/hcl/July12/XLS-130812ak.xls

B1 range: 9.0 – 9.4

Page 7: HCl, dep. Calc. E0,V10,V11

Try: 0 < D1 < 0.01:

https://notendur.hi.is/agust/rannsoknir/rempi/hcl/July12/PXP-130812ak.pxp

Page 8: HCl, dep. Calc. E0,V10,V11

240

220

200

180

160

140

120

100

80

24022020018016014012010080

-0.3

-0.2

-0.1

0.0

0.1

0.2

W3

W2

Points for 0 < D1 < 0.01-for W2 W3

https://notendur.hi.is/agust/rannsoknir/rempi/hcl/July12/PXP-130812ak.pxp Lay:0 Gr:0

Above line: for W2 W3; below line: W2 W3

D1

Page 9: HCl, dep. Calc. E0,V10,V11

210

205

200

195

190

185

200195190185180

-0.3

-0.2

-0.1

0.0

0.1

0.2Points for 0 < D1 < 0.01-for W2 W3

W3

W2

https://notendur.hi.is/agust/rannsoknir/rempi/hcl/July12/PXP-130812ak.pxp Lay:0 Gr:0

186 195

206

192

D1

Page 10: HCl, dep. Calc. E0,V10,V11

240

220

200

180

160

140

120

100

80

24022020018016014012010080

B1

Points for 0 < D1 < 0.01-for W2 W3

W3

W2

https://notendur.hi.is/agust/rannsoknir/rempi/hcl/July12/PXP-130812ak.pxp Lay:1 Gr:1

Above line: for W2 W3; below line: W2 W3

Page 11: HCl, dep. Calc. E0,V10,V11

220

210

200

190

180

205200195190185180175

B1

Points for 0 < D1 < 0.01-for W2 W3

W3

W2

https://notendur.hi.is/agust/rannsoknir/rempi/hcl/July12/PXP-130812ak.pxp Lay:1 Gr:1

Max B1 inside is 10.10 ! (for W2,W3= 191,196)=> D1 = +0.0092

Page 12: HCl, dep. Calc. E0,V10,V11

https://notendur.hi.is/agust/rannsoknir/rempi/hcl/July12/XLS-130812ak.xls

E(0) E(0) E(0) V(10) V(10) V(10) V(11) V(11) V(11)v1 B1 D1 v2 B2 D2 v3 B3 D3 WL WH83724.8 9,085790.000361879 83583.5 1,83429 -0.0917737 84118.8 3,92633 0.0233574 186 196

83726.9 9,128870.000638181 83582.6 1,80112 -0.0956355 84117.3 3,94721 0.0257223 186 19783729.6 9,116240.000640378 83581.3 1,83681 -0.0975573 84115.7 3,96069 0.0272391 186 198

83732.7 9,065630.000468057 83579.8 1,92055 -0.0981238 84114.1 3,96639 0.0280712 186 199

83735.9 8,999540.000162364 83578.1 0,2018 -0.0982925 84112.3 3,97307 0.0287674 186 20083715.6 9,079580.000896297 83589.7 1,86191 -0.0814714 84122.5 3,86548 0.0176463 187 194

83737.1 8,977080.000439257 83579.4 2,0831 -0.0989326 84109.9 3,97646 0.0298003 187 20283735.1 9,01120.000861352 83582.3 2,05538 -0.0993371 84109.1 3,97575 0.0301505 188 203

83702.3 9,03798 1,65E-01 83600.2 1,89799 -0.0694224 84126.5 3,85507 0.0132783 189 19283703.5 9,134950.000954925 83600 1,77088 -0.0747939 84125.4 3,85445 0.014837 189 193

83706.3 9,147740.000625229 83598.6 1,71326 -0.0799263 84123.9 3,88046 0.0171853 189 194

83699.5 9,11610.000188501 83604.2 1,74195 -0.0732447 84125.9 3,87052 0.014636 190 19383731.2 8,996140.000445844 83588.1 2,04859 -0.0992588 84107.6 4,00041 0.0310658 190 20583695.8 9,207850.00039384 83609.2 1,56589-0.0769761 84125.4 3,888280.0159983 191 19483700.1 9,22410.000783913 83606.3 1,5383 -0.0815887 84123.7 3,89272 0.0177536 191 195

83697.1 9,262650.000447133 83610.8 1,41517 -0.0842921 84123.1 3,91894 0.019094 192 196

83723.2 9,06760.00017991 83596.6 1,89253 -0.10001 84107.9 4,03038 0.031866 192 20683699.9 9,34070.000240379 83613.8 1,19667 -0.0969293 84118.2 4,00563 0.0261251 194 200

83707.8 9,333750.000906039 83609.7 1,3637 -0.102478 84112.7 4,04319 0.0311092 194 20483710.6 9,237040.000122707 83608 1,50426 -0.101762 84111.1 4,05730.0317637 194 205

83701.7 9,37160.000539727 83615.4 1,18551 -0.101847 84114.6 4,04734 0.0299188 195 203

https://notendur.hi.is/agust/rannsoknir/rempi/hcl/July12/PXP-130812ak.pxp

HCl. E(0), V(10) V(11) all red dots in slide 5 above / slide 14 below

Page 13: HCl, dep. Calc. E0,V10,V11

B´(V(11)) = 1.36 – 2.08 cm-1

Page 14: HCl, dep. Calc. E0,V10,V11

210

205

200

195

190

185

WH

/c

m-1

200195190185WL /cm

-1

10

9.8

9.4

9.2

8.6

WH > WL

(187,187)

HX,EvsV state paper-manuscript (Fig. 5b):Give highest B´ for V11:2.06 -2.08 cm-1

B´(V11): 1.6

B´(V11): 1.9