i nnov a t i v e ba r r i e r fi l m ge ne r a t e d by ad v a nc e ... n n o va t i ve ba r r i er...
TRANSCRIPT
© 2011 Dai Nippon Printing Co.,Ltd. All Rights Reserved.
http;//www.dnp.co.jphttp;//www.dnp.co.jphttp://www.dnp.co.jp/international/pack/film/film_1.htmlhttp://www.dnp.co.jp/international/pack/film/film_1.html
I nnovative Barrier FilmII nnovative nnovative BBarrier arrier FilmFilm
I nnovative Barrier Film generated by Advanced Clear Coating TechnologiesI nnovative Barrier Film generated by I nnovative Barrier Film generated by Advanced Clear Coating TechnologiesAdvanced Clear Coating Technologies
© 2011 Dai Nippon Printing Co.,Ltd. All Rights Reserved. 11
ConfidentialConfidentialAgenda
Ⅰ. DNP Introduction
Ⅱ. IB (Innovative Barrier) Film feature
© 2011 Dai Nippon Printing Co.,Ltd. All Rights Reserved. 22
ConfidentialConfidential
DNP IntroductionDNP Introduction
© 2011 Dai Nippon Printing Co.,Ltd. All Rights Reserved. 33
ConfidentialConfidential
Established : 1876HQ Location : Tokyo, JAPANCapital (as of March 2010) : ¥ 115 billion Annual Sales (as of March 2010) : ¥ 1,580 billion (Consolidated)
¥ 1,090,billion (Non-Consolidated) Number of Employees (as of March 2010)
39,643 (Consolidated)10,539 (Non-Consolidated)
Operations; Information CommunicationLifestyle & Industrial Supplies (incl. Packaging)Electronics
DNP Company Outline
© 2011 Dai Nippon Printing Co.,Ltd. All Rights Reserved. 44
ConfidentialConfidential
- Books and MagazinesBooks, Magazines, DictionariesTextbooks, Graphic collectionse-books
- Commercial PrintingCatalogs, Calendars, PostersPromotional Publication
- Information Processing ServicesPersonal mail, Business formsCredit/Banking cards, SIM cards Hologram
Information Communication Information Communication
DNP Company Outline
© 2011 Dai Nippon Printing Co.,Ltd. All Rights Reserved. 55
ConfidentialConfidential
- PackagingFoods, Beverages, Personal care,Home care, Pharmaceuticals
- Decorative materialsInterior and Exterior decorative material for houses, buildings
- Optical material, Industrial materialOptical film for Display, Projector screenSublimation/Thermal transfer ribbonSelf print system
Lifestyle and Industrial Supplies Lifestyle and Industrial Supplies
DNP Company Outline
© 2011 Dai Nippon Printing Co.,Ltd. All Rights Reserved. 66
ConfidentialConfidential
- DisplaysColor-filter for LCD Organic light emitting display
- Electronic ComponentsPhoto-mask and Lead flame for Semi-conductors products IC-Tag, MEMS
Electronics Electronics
DNP Company Outline
© 2011 Dai Nippon Printing Co.,Ltd. All Rights Reserved. 77
ConfidentialConfidential
IB (Innovative Barrier) Film feature
(Passive Barrier)(Passive Barrier)
© 2011 Dai Nippon Printing Co.,Ltd. All Rights Reserved. 88
ConfidentialConfidential
IBIB--Film offersFilm offersFunctions and addedFunctions and added--values to packagevalues to package
FunctionsFunctions AddedAdded--ValuesValues
Excellent Gas BarrierExcellent Gas BarrierSterilizabilitySterilizabilityDirect PrintabilityDirect PrintabilityTransparencyTransparency
MicrowaveMicrowave--abilityabilityEasy ConvertingEasy ConvertingSource ReductionSource ReductionEcoEco--FriendlyFriendly
IB-Film Functions & Added-Values
© 2011 Dai Nippon Printing Co.,Ltd. All Rights Reserved. 99
ConfidentialConfidential
IBIB--FILMFILM
CVDCVD SiOxSiOx
AlOxAlOxPVDPVD
OPAOPA
PETPET
PETPET
IBIB--ONON
IBIB--PETPET
IBIB--PETPET--PP
DepositionDeposition LayerLayer SubstrateSubstrate IB SubfamilyIB Subfamily
IBIB--FILMs are classified into 3 subfamilies depending on FILMs are classified into 3 subfamilies depending on deposition methods and substratesdeposition methods and substratesCVDCVD : Chemical Vapor Deposition: Chemical Vapor DepositionPVDPVD : Physical Vapor Deposition: Physical Vapor Deposition
SilicaSilica
AluminaAlumina
IB-Film Classification
© 2011 Dai Nippon Printing Co.,Ltd. All Rights Reserved. 1010
ConfidentialConfidential
PETONy
OSi C
Si
O
OSi
C
COHUnwinderUnwinder
RewinderRewinder
SiSi--PrecursorPrecursorReaction GasReaction GasCarrier GasCarrier Gas
ExhaustExhaust
Highly flexible deposition layerHighly flexible deposition layerDurable against physical and thermal stressesDurable against physical and thermal stressesColorless and clearColorless and clearGood bonding strength with substrateGood bonding strength with substrateProcessable on poor heat resistance substratesProcessable on poor heat resistance substrates
PlasmaPlasma
CVD technology enables to produce CVD technology enables to produce carbon containing SiOxcarbon containing SiOx onto substrate, onto substrate, giving the following beneficial characteristics;giving the following beneficial characteristics;
Covalent Covalent bondbond
SiOxCySiOxCy
Chemical Vapor Deposition Process (CVD)
© 2011 Dai Nippon Printing Co.,Ltd. All Rights Reserved. 1111
ConfidentialConfidential
Colorless and high transparencyColorless and high transparencyLarge volume manufacturingLarge volume manufacturingStability of manufacturedStability of manufactured
UnwinderUnwinder
RewinderRewinder
Electron BeamElectron Beam
OO22
Al + OAl + O22 AlOxAlOxReactive evaporation of aluminiumReactive evaporation of aluminium
Aluminium Aluminium vaporvapor
Physical Vapor Deposition Process (PVD)
PVD technology enables to produce PVD technology enables to produce AlOxAlOx onto substrate, onto substrate, giving the following beneficial characteristics;giving the following beneficial characteristics;
© 2011 Dai Nippon Printing Co.,Ltd. All Rights Reserved. 1212
ConfidentialConfidential
** ○○: Good : Good △△: Poor: Poor ××: Bad or not recommendable: Bad or not recommendable
Direct PrintingDirect Printing (Roto gravia)(Roto gravia)
IBIB--ONON--UBUB
IBIB--PETPET--UBUB
IBIB--PETPET--PXBPXB
○○ ○○ △△
ConvertingConverting& Processing& Processing
SolventSolvent--BaseBaseAdhesive Laminate (approved by FDA)Adhesive Laminate (approved by FDA) ○○ ○○ ○○
Extrusion LaminationExtrusion Lamination--Limit melt temperature or PELimit melt temperature or PE--Limit extrudable PE thicknessLimit extrudable PE thickness
○○300300ººCC2020μμmm
○○320320ººCC2020μμmm
××
Boil TreatmentBoil Treatment ○○9595ººCC ××○○
9595ººCC
Retort TreatmentRetort Treatment ×× ××××
IBIB--PETPET--PIRPIR
○○
○○
○○9595ººCC
○○135135ººCC
○○300300ººCC1515μμmm
Converting & Process-ability Profile
CVD (SiOx) PVD (AlOx)
© 2011 Dai Nippon Printing Co.,Ltd. All Rights Reserved. 1313
ConfidentialConfidential
OXTROXTR :: cc/mcc/m22/day/atm (23/day/atm (23ººC/90%RH)C/90%RH)WVTRWVTR :: g/mg/m22/day (40/day (40ººC/90%RH)C/90%RH)
22--Layer : IBLayer : IB--FILM/adh/PEFILM/adh/PE606033--Layer : IBLayer : IB--FILM/adh/BOPAFILM/adh/BOPA1515/adh/CPP/adh/CPP6060
IB-Film line up & applications ConfidentialConfidential
※These data are based on measurement,but not guaranteed.
Boilable sachetBoilable sachetFlavoring sauce bagFlavoring sauce bag
Laminate TubeLaminate TubePaperboard CartonPaperboard Carton
IBIB--ONON--UBUBIBIB--ONON 1515 0.30.3 1.81.8
IB GradeIB Grade µµmm OXTROXTR WVTRWVTR Typical ApplicationsTypical Applications
IBIB--PETPET--UBUB 1212 0.30.3 0.80.8IBIB--PETPET
IBIB--PETPET--PP
IB SubfamilyIB Subfamily
22--LayerLayer
22--LayerLayer
Retort Retort Medical / Infusion BagMedical / Infusion BagDry Foods, ConfectionaryDry Foods, ConfectionaryIndustrial SuppliesIndustrial SuppliesWaterWater--sensitive product sensitive product
Industrial SuppliesIndustrial SuppliesWaterWater--sensitive product sensitive product IBIB--PETPET--PXBPXB 1212 0.10.1 0.10.1 22--LayerLayer
LaminateLaminateStructureStructure
1212 0.20.2 0.50.5 33--LayerLayerIBIB--PETPET--PIRPIR
CVD(SiOx)
PVD(AlOx)
ForRetort
before retortbefore retort
BOPABOPA
© 2011 Dai Nippon Printing Co.,Ltd. All Rights Reserved. 1414
ConfidentialConfidential
0
1
2
3
4
5
OXTROXTR WVTRWVTR OXTROXTR WVTRWVTR
IBIB--ONON--UBUB 0.30.3 1.81.8 1.21.2 2.82.8ON/SiOx(PVD)ON/SiOx(PVD) 0.40.4 0.50.5 2.82.8 3.63.6
Before BoilBefore Boil After BoilAfter Boil•• General Performance General Performance –– High temperature boil sterilizationHigh temperature boil sterilization
•• Characteristics and promising applicationsCharacteristics and promising applications
““9595ººCC××30min30min””
••Good gelboGood gelbo--flex durabilityflex durability••Good flavor barrierGood flavor barrier••Extrusion coating is availableExtrusion coating is available••Direct printableDirect printable••MicrowaveMicrowave--ableable••ApplicationsApplications
--Sachet Sachet --Cup noodle packagingCup noodle packaging
SauceSauce
JapaneseJapanesedressingdressing
ChineseChinesedressingdressing
DippingDippingsaucesauce
VinegarVinegarsoy saucesoy sauce
GoodGood
BadBad
Sensory test for flavor retention Sensory test for flavor retention (40(40ººC/7days)C/7days)
Structure : BaseStructure : Base--ON15/adhesive/PE60ON15/adhesive/PE60OXTR: 23OXTR: 23ººC/90%RH WVTR: 40C/90%RH WVTR: 40ººC/90%RHC/90%RH
PVD ON-SiOx
IB-ON-UB
((competitivecompetitive))
IBIB--ONON--UBUB
© 2011 Dai Nippon Printing Co.,Ltd. All Rights Reserved. 1515
ConfidentialConfidential
0
2
4
6
8
10
12
14
16
0 10 20 50 100
OXTROXTR WVTRWVTR
IBIB--PETPET--UBUB 2323ººC/90%RHC/90%RH 0.30.3
•• General Performance General Performance -- Low Dependency on Temp. and HumidityLow Dependency on Temp. and Humidity
•• Characteristics and promising applicationsCharacteristics and promising applications••Suitable for liquid packagingSuitable for liquid packaging••Good gelboGood gelbo--flex durabilityflex durability••Extrusion coating is availableExtrusion coating is available••Direct printableDirect printable••MicrowaveMicrowave--ableable••ApplicationsApplications
--Laminate Tube Laminate Tube --Paperboard CartonPaperboard Carton--WetWet--tissue pillow pouchtissue pillow pouch
Temp./HumidityTemp./Humidity
3030ººC/90%RHC/90%RH 0.40.44040ººC/90%RHC/90%RH 0.50.5 0.80.8
0.40.40.20.2
GelboGelbo--CyclesCycles
OX
TR (c
c/m
2/da
y/at
m)
OX
TR (c
c/m
2/da
y/at
m)
At 2
3A
t 23 ºº
C/9
0%R
HC
/90%
RH
PVD PET/SiOx
PVD PET/AlOx
IB-PET-UB
Structure: IBStructure: IB--PETPET--UB12/adhesive/PE60UB12/adhesive/PE60
IBIB--PETPET--UBUB
© 2011 Dai Nippon Printing Co.,Ltd. All Rights Reserved. 1616
ConfidentialConfidential
OXTROXTR WVTRWVTR
IBIB--PETPET--PUBPUB 2323ººC/90%RHC/90%RH 0.30.3
•• General Performance General Performance -- Low Dependency on Temp. and HumidityLow Dependency on Temp. and Humidity
•• Characteristics and promising applicationsCharacteristics and promising applications••Suitable for dry food packagingSuitable for dry food packaging••Excellent moisture barrierExcellent moisture barrier••Extrusion coating is availableExtrusion coating is available••Direct printableDirect printable••MicrowaveMicrowave--ableable••ApplicationsApplications
--Dry foodsDry foods--Water sensitive articlesWater sensitive articles
Temp./HumidityTemp./Humidity
3030ººC/90%RHC/90%RH 0.30.34040ººC/90%RHC/90%RH 0.40.4 0.50.5
0.20.20.10.1
0.000
0.100
0.200
0.300
0 10 20 30 40Time Intervals (Days)Time Intervals (Days)
Wei
ght C
hang
e (g
/pac
kage
)W
eigh
t Cha
nge
(g/p
acka
ge) 90%RH
75%RH
50%RH
Temp.=40ºC constant)
Pouch size: 100mm ×100mContent: Calcium chloride
Structure: IBStructure: IB--PETPET--PUB12/adhesive/PE60PUB12/adhesive/PE60
IBIB--PETPET--PUBPUB
© 2011 Dai Nippon Printing Co.,Ltd. All Rights Reserved. 1717
ConfidentialConfidential
OXTROXTR WVTRWVTR
IBIB--PETPET--PXBPXB 0.10.1
•• General Performance General Performance -- Ultra High Moisture BarrierUltra High Moisture Barrier
•• Characteristics and promising applicationsCharacteristics and promising applications
••Suitable for water sensitive articlesSuitable for water sensitive articles••Excellent moisture barrierExcellent moisture barrier••Direct printableDirect printable••MicrowaveMicrowave--ableable••ApplicationsApplications
--Mouth freshenerMouth freshener--Silicon waferSilicon wafer--Vacuum infusion bagVacuum infusion bag--Price tagPrice tag
Layer #Layer #
0.10.1
0.000
0.100
0.200
0.300
0 10 20 30 40Time Intervals (Days)Time Intervals (Days)
Wei
ght C
hang
e (g
/pac
kage
)W
eigh
t Cha
nge
(g/p
acka
ge)
PXB Double
Pouch size: 100mm ×100mContent: Calcium chloride
Single LayerSingle Layer
OXTR: 23OXTR: 23ººC/90%RH WVTR: 40C/90%RH WVTR: 40ººC/90%RHC/90%RH
PXB12/adh/PE60PXB12/adh/PE60
PXB Single
PUB Single
IBIB--PETPET--PXBPXB
© 2011 Dai Nippon Printing Co.,Ltd. All Rights Reserved. 1818
ConfidentialConfidential
New grade “IB-PET-PIR” for retort
© 2011 Dai Nippon Printing Co.,Ltd. All Rights Reserved. 1919
ConfidentialConfidentialFeature of “IB-PET-PIR”
IBIB--PETPET--PIRPIR consists of AlOx layer using PVD method and wet coating layerconsists of AlOx layer using PVD method and wet coating layeron the PET substrate.on the PET substrate.IBIB--PETPET--PIRPIR has many characteristics which are has many characteristics which are retort treatment resistanceretort treatment resistanceandand high barrier propertieshigh barrier properties..
Colorless and High transparencyColorless and High transparencyLarge volume Large volume manufacturing
● Retort Pouch & Lid● Boil Pouch & Bag● Packaging for microwave● Medical Bag
++
You can use You can use following example!!
© 2011 Dai Nippon Printing Co.,Ltd. All Rights Reserved. 2020
ConfidentialConfidential
• General Performance - Well-balanced gas barrier suitable for retort
OXTR WVTR OXTR WVTR
IB-PET-PIR 0.2 0.5 0.3 0.9
PET/AlOx 0.3 0.5 0.5 0.6
Before Retort After Retort“121ºC×30min”
Structure: Base-PET12/adh/ON15/adh/CPP70 (3-Layer)OXTR(cc/㎡・day・atm): 23ºC/90%RH WVTR (g/㎡・day) : 40ºC/90%RH
(competitive)
OXTR WVTR OXTR WVTR
IB-PET-PIR 0.2 0.5 0.3 1.2
PET/AlOx 0.3 0.5 0.9 1.9
Before Retort After Retort“135ºC×30min”
Structure: Base-PET12/adh/ON15/adh/CPP70 (3-Layer)OXTR(cc/㎡・day・atm): 23ºC/90%RH WVTR (g/㎡・day) : 40ºC/90%RH
(competitive)
※These data are based on measurement,but not guaranteed.
IB-PET-PIR Barrier Property
© 2011 Dai Nippon Printing Co.,Ltd. All Rights Reserved. 2121
ConfidentialConfidential
0.00
0.50
1.00
1.50
2.00
2.50
3.00
3.50
4.00
4.50
5.00
0% 1.50% 2% 2.50% 3%
OXT
R(c
c/m
2 .day
.atm
)
Elongation (%)Elongation (%)
Competitor A: SiOx(P)
Competitor B: AlOx(P)
Competitor C: AlOx(P)
PIR(P)
VM-PET12 (Retort grade)/Ad/ON15/Ad/CPP70/Ad/ON15/Ad/CPP70
(P): PVD
Anti-Elongation Property
• Oxygen barrier property after elongation to specific point
© 2011 Dai Nippon Printing Co.,Ltd. All Rights Reserved. 2222
ConfidentialConfidential
ASTM F392ASTM F3920.00
2.00
4.00
6.00
8.00
10.00
12.00
14.00
OXT
R(c
c/m
OXT
R(c
c/m
22 .day
.atm
).d
ay.a
tm)
Competitor ASiOx(P)
Competitor BAlOx(P)
Competitor CAlOx(P)
PIR(P)
Before gelbo
50 times
10 times20 times
100 times
OX
TR(c
c/m
OX
TR(c
c/m
22 .day
.atm
).d
ay.a
tm)
Oxygen barrierOxygen barrier
Gelbo-Flex Test
(P): PVD
VM-PET12 (Retort grade)/Ad/ON15/Ad/CPP70/Ad/ON15/Ad/CPP70
Twisting and Compress
© 2011 Dai Nippon Printing Co.,Ltd. All Rights Reserved. 2323
ConfidentialConfidential
Retort condition: 30 minLayer structure: VM-PET12 (Retort grade)/Ad/ON15/Ad/CPP70/Ad/ON15/Ad/CPP70
OXTR
Pre-retort
121℃ 125℃ 130℃ 135℃0.00
0.50
1.00
1.50
2.00
2.50
3.00
3.50
0.00
0.25
0.50
0.75
1.00
1.25
1.50
1.75
2.00WVTR
Competitor CAlOx(P)
Competitor ASiOx(P)
Competitor BAlOx(P)
PIR(P)
Pre-retort
121℃ 125℃ 130℃ 135℃
(P): PVD
Retort Temp. and DurabilityO
XTR
(cc/
mO
XTR
(cc/
m22 .d
ay.a
tm)
.day
.atm
)
WV
TR(g
/mW
VTR
(g/m
22 .day
).d
ay)
IB-PET-PIR keeps a goodbarrier properties until 135℃retort treatment conditions.
© 2011 Dai Nippon Printing Co.,Ltd. All Rights Reserved. 2424
ConfidentialConfidential
IBIB--ONON--UBUB
IBIB--PETPET--UBUB
IBIB--PETPET--RBRB
IBIB--PETPET--PUBPUB
IBIB--PETPET--PXBPXB
IBIB--ONON
IBIB--PETPET
IBIB--PETPET--PP
CompliesComplies
CompliesComplies
CompliesComplies
CompliesComplies
under investigationunder investigation
EU Regulations*EU Regulations*
CompliesComplies
CompliesComplies
CompliesComplies
CompliesComplies
FDA RegulationsFDA Regulations
CompliesComplies
IB GradesIB GradesIBIBSubfamilySubfamily
** Framework regulations (EC) No.1935/2004Framework regulations (EC) No.1935/2004Commission Directive 2002/72/EC and its amendmentsCommission Directive 2002/72/EC and its amendmentsEuropean Parliament & Council Directive 94/62/ECEuropean Parliament & Council Directive 94/62/ECGerman Food Contact Regulation German Food Contact Regulation Switzerland Food Contact RegulationSwitzerland Food Contact RegulationItalian Food Contact RegulationItalian Food Contact Regulation
IB-Film Compliance Status EU & FDA
IBIB--PETPET--PIRPIR under investigationunder investigation CompliesComplies★ Brand-new grade
© 2011 Dai Nippon Printing Co.,Ltd. All Rights Reserved. 2525
ConfidentialConfidential
25
confectionery Retort food
BeveragePasteurized rice
General foodsIndustrial supplies
(PET substrate)
TypicalTypical aapplicationspplications 22
© 2011 Dai Nippon Printing Co.,Ltd. All Rights Reserved. 2626
ConfidentialConfidential
Pharmaceutical / Medical Application: Moisture Barrier (IB-PET-PIR, IB-PET-PXB)
- Tablet outer packaging
- Eye drop outer packaging
- Ampoule outer packaging
- Cylinder outer packaging
- Healthcare product packaging (Wet tissue)
- Breath care
- Bath salts
Pharmaceutical / Medical Application: Heat resistance Barrier (IB-PET-PIR)
- Nutritional outer packaging
- Infusion bag
- Pharmaceutical cup lids
- Retort laminated tube
Non Food Application 1
© 2011 Dai Nippon Printing Co.,Ltd. All Rights Reserved. 2727
ConfidentialConfidential
Industrial Material Application: Moisture Barrier (IB-PET-PIR, IB-PET-PXB)
- Ink toner container
- Ink cartridge
- Insulation material
- Flexible display
- Touch panel
- Electric material packaging
- Replacement for thin glass
- E-book
- E-tag
- Inner bag for industrial paper bag
Non Food Application 2