improvements in anerobic digestion
TRANSCRIPT
7/29/2019 Improvements in Anerobic Digestion
http://slidepdf.com/reader/full/improvements-in-anerobic-digestion 1/17
920
ADVANCED ANAEROBIC DIGESTION PERFORMANCE COMPARISONS
Perry L. Schafer, P.E., DEE, Brown and Caldwell
2701 Prospect Park Dr., Rancho Cordova, California 95670Joseph B. Farrell, PhD, P.E., Environmental Consultant
Gary Newman, Brown and CaldwellScott Vandenburgh, Brown and Caldwell
ABSTRACT
Advanced anaerobic digestion processes are being developed and used at more wastewater
treatment facilities in recent years, especially in North America and Europe. These processes are
largely developed to achieve greater performance (i.e., greater volatile solids reduction andincreased digester gas production). This paper reviews the performance data and information
available for several of these advanced digestion processes, especially the ones most commonly
being implemented, evaluated, or proposed in North America. Comparisons are now possible formany of these processes showing the degree of improvement gained by the advanced digestion
process over the previous mesophilic digestion process. The paper also describes volatile solids
reduction calculations and the methods currently used for these calculations. Related issues are
also presented and discussed including product odor, dewatering information, and increasedammonia recycle.
KEYWORDS
Sludge, anaerobic digestion, phased digestion, staged digestion, thermophilic, mesophilic.
INTRODUCTION
Wastewater agencies are under pressure to minimize costs for sludge processing, yet create
improved biosolids products to satisfy users and the public. Since anaerobic digestion continues
to be the dominant municipal sludge stabilization technology in North America, improvementsand advancements in anaerobic digestion are occurring at a significant pace.
The primary objective of this work is to review the actual performance of advanced digestion
processes so that agency staff and engineers are armed with improved data when evaluating theseprocesses. Many authors are providing considerable information within technical papers and
publications about these processes, however, some papers do not provide complete data for
evaluation, and, therefore, the authors have included substantial additional data collected directfrom agency or POTW staff and plant operating data files. Whenever possible, longer-term
average performance data have been used to evaluate these processes (and presented here), rather
than providing results obtained from short-term testing periods. For the most part, full-scalefacility operating and performance data have been used for evaluation purposes. In some cases,
high-quality pilot testing program results are included here since comparative data between
processes can often be best represented by such work.
7/29/2019 Improvements in Anerobic Digestion
http://slidepdf.com/reader/full/improvements-in-anerobic-digestion 2/17
Performance of advanced digestion processes is evaluated primarily in terms of volatile solidsreduction (VSR) since in North America this tends to be one of the most common performance
criteria used and such values are almost always available for each plant’s digestion system.
Indeed VSR is a key parameter in regulatory compliance for most US agencies using anaerobicdigestion of sludge. Other performance criteria for anaerobic digestion processes such as gas
production, gas quality, biosolids product stability, and product odor, are more difficult toevaluate due primarily to infrequent or poor quality data.
PROCESSES EVALUATED
The advanced anaerobic digestion processes evaluated here are grouped into the followingclasses and are schematically represented in Figure 1:
• Thermophilic digestion. Although single stage thermophilic would be the simplest formof thermophilic digestion, several plants have moved to “staged thermophilic” digestion
so that improved pathogen destruction could be assured and, for several plants, Class A
product can be provided.
• Temperature phased digestion. This has been implemented most often with
thermophilic digestion as the first phase, followed by mesophilic digestion as the second
phase. The primary reason for this order is to produce a final product with minimal odorlevel since thermophilic digestion product has been described as odorous by some
authors.
• Acid/gas phased digestion. This category can include either phase (acid or gas) at
mesophilic or thermophilic temperatures, but is most often being implemented with bothphases at mesophilic temperatures due to simplicity in sludge heating and cooling.
• Three-phased digestion. Three-phase digestion (as implemented at the Inland EmpireUtilities Authority in California) is a combination of acid/gas phased digestion and
temperature-phased digestion.
Not included as part of this paper are various pre-digestion processes that are being used or are in
developing stages. These include the following:
• Pre-pasteurization, occurring in various types of tankage and configurations.
• Thermal hydrolysis processes.
• Pre-digestion physical or chemical treatment.
These pre-digestion processes are typically intended to improve digestion or dewatering
performance and/or create Class A biosolids.
7/29/2019 Improvements in Anerobic Digestion
http://slidepdf.com/reader/full/improvements-in-anerobic-digestion 3/17
7/29/2019 Improvements in Anerobic Digestion
http://slidepdf.com/reader/full/improvements-in-anerobic-digestion 4/17
For simplicity, solids retention time (SRT) is used in this paper to describe both hydraulic andsolids retention times, since none of the processes described in this technical paper recycle
process liquor or solids from the digestion reactors, and we assume no significant buildup of
solids within the reactors.
Table 1 presents summary data and information for each of the treatment plant digestion systemsevaluated in this paper. They are grouped according to the process classes described above.Performance data shown are averages from plant operating data. If the performance data are
from a pilot plant, this is noted. Dewatering information is shown if the information is available
since dewatering performance is often a major consideration by agencies considering advanced
digestion systems. However, dewatering information presented here does not included detailson polymer dose and many of the finer details of dewatering needed to make decisions.
Dewatering information is presented to indicate the type of dewatering and general cake solids
performance being achieved.
Thermophilic Digestion
Several agencies have transformed their mesophilic digestion systems to thermophilic digestion
in recent years to improve volatile solids reduction (VSR) and pathogen control. As shown in
Table 1, the North American agency that has led this effort in the last decade has been the
Greater Vancouver Regional District (GVRD) in British Columbia, Canada. In the early 1990s,GVRD began 2-stage thermophilic digestion at the Lions Gate plant, primarily with the objective
of creating pathogen-free biosolids for beneficial use purposes. This experience provided the
impetus for the larger and more definitive 4-stage thermophilic digestion process at the AnnacisIsland plant in the mid-1990s. Both plants have seen significant increases in VSR, as indicated
in the table, as well as providing pathogen-free product for successful biosolids beneficial useprograms.
The OWASA facility (Mason Farm plant) is also showing large increases in VSR improvementby switching to a staged thermophilic process. However, part of this increase is due to longer
solids retention times within the process. This plant had difficulty in consistently meeting the 38
percent VSR regulatory requirement prior to the change to thermophilic digestion. A 22-hour/day batch operation in the second stage reactor of the new system insures meeting the
time/temperature requirements for Class A biosolids.
The single stage thermophilic digestion process at Aalborg, Denmark was reportedly chosen bythe City of Aalborg primarily for increased gas production benefits over the prior mesophilic
digestion system. In Denmark, there are significant financial incentives for agencies to produce
maximum energy from use of digester gas. Increased solids destruction and improveddewatering on belt presses are also significant factors in controlling final biosolids reuse costs for
Aalborg.
Two of these four thermophilic digestion facilities (Aalborg and Annacis Island) currently
recover at least part of the heat through sludge/sludge heat exchangers from thermophilic
digestion, and OWASA is planning to recover this heat to help heat incoming raw sludge.
7/29/2019 Improvements in Anerobic Digestion
http://slidepdf.com/reader/full/improvements-in-anerobic-digestion 5/17
Table 1. Advanced Anaerobic Digestion Process Information
Process/Plant Type of Sludge
HRT (days)
in Each Stage
Temps
(°C)
Reactor
Feeding
Process
VSRa
(%)
VSR for
Mesophilic
Digestion
Staged Thermophilic
Vancouver, Canada
Annacis Island Plant
P+TF/SC 17-Th
2-Th
2-Th2-Th
All stages
55 to 56
Continuous 62 to 63 47
Mason Farm WWTP
OWASA, NC
10% Fermented P
90% WAS
19-Th
10-Th
10-Th
All stages
56 to 57
10 hrs/day
1st stage,
Batch 2nd stage
65 43
Vancouver, Canada
Lions Gate WWTP
P only 22-Th
22-Th
55
Both stages
Continuous 67 to 70 57
SSb Thermophilic with Storage
Aalborg, Denmark
AalborgWest WWTP
P+WAS SS Thermo
15-Th
(plus short
meso storage)
52 to 55 Hourly Feed Sequence “Significantly”
greater than SS
Meso
Unknown
Temp-Phased Thermo/Meso
WLSSD,
Duluth, MN
WAS-only 8-Th
23-M
55-Th
37-M
Continuous 46 40
King Co., WA
Renton (Pilot Scale)
P+WAS 8-Th
16-M
55-Th
37-M
Nearly Continuous 68 58
Neenah-Menasha, WI P+WAS 16-Th
16-M
55-Th
36-M
Nearly Continuous 58 50
Madison, WI Pilot (Lab Scale) P+WAS 5-Th
15-M
55-Th
35-M
Intermittent 64 58
City of Los Angeles Hyperion
WWTP (pilot-scale)
P+WAS 10-Th
7-M
55-Th
35-M
Intermittent 66 48
Cologne, Germany Stammheim
Plant
WAS-only 7-Th
27-M
55-Th
35 to 38-M
Continuous 43 34
Sturgeon Bay, Wisconsin P+WAS ~ 17-Th
> 20-M
55-Th
35-M
Intermittent 65 62 (at much
longer SRT)
Acid/Gas Phased at Meso/Thermo
DuPage Co. Illinois WAS-only 2-Acid
16-Gas
(plus storage of 4 to 10 days)
37-Acid
52-Gas
(38 to 43storage)
Continuous 62 to 63 ~45
Acid/Gas Phased at Meso/Meso
San Bernardino, CA P+WAS 2 to 3 (acid)
25 (gas)
35 acid
35 gas
Continuous 57 53
Elmhurst, Illinois P+WAS 1-Acid
38-Gas
30-Acid
36-Gas
Batch Acid 50 36
DuPage Co., Illinois WAS-only 2 (acid)
16 (gas)
(plus storage of
4 to 8 days)
36 acid
36 gas
Continuous 59 ~45
Madison, WI
(Lab-Scale Pilot)
P+WAS 1 to 2-Acid
15 to 20-Gas
35-Acid
35-Gas
Twice/day 58 57
Acid/Gas Phased at Thermo/Meso
City of Los Angeles Hyperion
WWTP (pilot scale)
P+WAS 2 (acid)
12 (gas)
55-Th
35-M
Intermittent 50 48
Indianapolis, IN
Belmont WWTP
(IDI Pilot Scale)
P+WAS 2 (acid)
10 (gas)
55 & 60-Th
37-M
2 or 4 times a day 55 to 60 Unknown
Three-Phase Digestion
Inland Empire
Utilities Agency, CA
Reg. Plant #1
P+WAS 3-Acid
12/14-Th
14/16-M
33/38-Acid
53/55-Th
39/44-M
Nearly Continuous 56 54
Notes:a VSR = Volatile Solids Reduction Mesophilic = Meso = M P = Primary Sludgeb SS = Single Stage Thermophilic = Thermo= Th WAS = Waste Activated Sludge
TF/SC = Trickling Filter/Solids Contact
7/29/2019 Improvements in Anerobic Digestion
http://slidepdf.com/reader/full/improvements-in-anerobic-digestion 6/17
Table 1. Advanced Anaerobic Digestion Process Information (continued)
Process/Plant
How VSR
Calculated Dewatering Performance
Extent
of Data Ref. Comments
Staged Thermophilic
Vancouver, Canada
Annacis Island Plant
Van Kleeck 32% cake solids content,
high solids centrifuges, 95%
capture.
3 years 1 Extensive data. Consistent long-term
performance. Class A process in British
Columbia.
Mason Farm WWTPOWASA, NC
Mass Balance No dewatering operations. 1 year 2 Meets Class A time/temp Batch Requirement in2nd stage.
Vancouver, Canada
Lions Gate WWTP
Van Kleeck Centrifuges, 37% cake
solids, 95% capture.
8+ years of
operation
1 Steady performance on primary sludge only.
Pathogen data suggest Class A product.
SSb Thermophilic with Storage
Aalborg, Denmark
AalborgWest WWTP
N/A Belt Filter Presses, 25%
cake solids, 10 kg/tonne
polymer
1 year 3 VSR is not calculated, but plant reports
“significant” more gas and power production
from thermophilic over prior mesophilic
operation.
Temp-Phased Thermo/Meso
WLSSD,
Duluth, MN
Mass Balance High-solids centrifuges, 28
to 30% cake solids, 99%
capture.
1 year 4 Large pulp/paper load on WWTP-So, WAS is
less digestible than normal WAS.
King Co., WA
Renton (Pilot Scale)
Mass Balance Lab-scale Belt Press got
16% cake solids – same as
full-scale mesophilic.
Several months 5 Well-run and extensive pilot test.
Neenah-Menasha, WI Van Kleeck 20% cake solids content
Belt Filter Press
2 years 6 Pleased with TPAD. Improved VSR.
Dewatering approved “a few” percentage points
in cake solid.
Madison, WI Pilot (Lab
Scale)
Van Kleeck Thickening tests conducted. Several months 7 Extensive pilot testing of many different
scenarios.
City of Los Angeles
Hyperion WWTP (pilot-
scale)
Mass Balance Not Reported 6 months
operation
8 City reported best results for VSR was obtained
with this process.
Cologne, Germany
Stammheim Plant
Van Kleeck Centrifuges, 33% cake
solids, 8 kg/tonne polymer
3 years average 9 Large plant using egg-shaped digesters. Limited
VSR due to all-WAS feed and long sludge age.
Sturgeon Bay, Wisconsin Mass Balance Belt Filter Press, 13 to 15%
cake solids.
4 years 10 Small plant with very long detention times.
Data 2001.
Acid/Gas Phased at Meso/Thermo
DuPage Co. Illinois Mass Balance 21% cake solids on belt
filter presses.
Several years of
full-scale data.
11,
12
Acid/Gas phasing solved the large foaming
problem and improved performance
significantly with WAS-only sludge.
Acid/Gas Phased at Meso/Meso
San Bernardino, CA Mass Balance Centrifuges 25% cake
solids, Belt Press 19% cake
solids
Several months 13 Poor mixing in acid digester has allowed debris
accumulation.
Elmhurst, Illinois Unknown Belt Filter Press, 20% cake
solids content.
Several months
of data.
14 Batch acid operation causing foam in gas
digesters. Acid reactors are new.
DuPage Co., Illinois Mass Balance Belt Filter Press, 20% cake
solids
Several months
of pilot and full-
scale data
11 Acid gas phased digestion provided
performance improvement and foam control.
Madison, WI
(Lab-Scale Pilot)
Van Kleeck Thickening tests conducted. Few weeks of
data.
7 Part of extensive pilot testing program.
Acid/Gas Phased at Thermo/Meso
City of Los Angeles
Hyperion WWTP (pilot
scale)
Mass Balance Not Reported Several months 8 Process did not appear to stabilize and was
discontinued after several months.
Indianapolis, IN
Belmont WWTP
(IDI Pilot Scale)
Mass Balance Not Reported Several months
at varying
conditions
16 Batch thermophilic acid phase proven as site-
specific PFRP equivalent.
Three-Phase Digestion
Inland Empire
Utilities Agency, CA
Reg. Plant #1
Unknown Belt Filter Presses, 19%
cake solids (with 3-phase)
versus 17% cake solids with
SS Meso.
Several months
of data
15 Temperatures are not consistent. Final phase is
hotter than typical meso systems.
7/29/2019 Improvements in Anerobic Digestion
http://slidepdf.com/reader/full/improvements-in-anerobic-digestion 7/17
At Annacis Island and Aalborg the final product is dewatered at reduced temperature(approximately mesophilic temperature at Aalborg and about 43º C at Annacis Island), after
storage of only 1 or 2 days at these temperatures. This temperature reduction and short-term
storage helps to reduce odor emissions from the dewatering and cake loadout operations, as wellas odor level in the final product. The details of such storage (temperatures, variation in
temperatures, length of storage time, mixing conditions, etc.) are likely to be important indetermining the extent of odor reduction achieved.
At the Lions Gate plant, the digested product is dewatered at 55º C and the cake trucked off-site.
The dewatered cake at Lions Gate is reportedly more odorous than mesophilic digested cake
product, and the centrate is very odorous. At the OWASA plant, the thermophilic digestedsludge has been stored in large storage tanks for 20 days or longer. These tanks lose temperature
to the environment so that the final slurry product trucked to reuse sites is at approximately
mesophilic temperatures. This final reuse product at OWASA has reportedly little odordifference from the previous mesophilic digested slurry product.
Ammonia levels are higher in thermophilic digested sludge (and in dewatering filtrate/centrate)than in the previous mesophilic digested sludge from these plants. This is not a problem at
Vancouver, since ammonia removal is not required at the Vancouver plants. At Aalborg, the
higher ammonia level in the dewatering filtrate is treated within the liquid treatment system at
the Aalborg West plant. Figure 2 displays the performance change identified by agencies havingsufficient data.
Temperature Phased Digestion
About a dozen agencies in the US have now implemented temperature phased digestion, andperformance data for several of these plants are included in Table 1. In addition, data from three
pilot scale programs for temperature-phased digestion are included in the table because of the
availability of comparative performance results. The comparative results are plotted on Figure 3to better display the performance change from prior mesophilic digestion to temperature phased
digestion. These temperature phased digestion facilities are all achieving increased VSR and gas
production.
It is interesting to note the large variety of SRTs being used by these temperature phased
digestion plants. SRTs in each phase are often dictated by the size of digesters available at the
plant since the only temperature-phased plant listed in Table 1 with new digesters is the WesternLake Superior Sanitary District plant at Duluth, Minnesota. In most cases for full-scale
operations, the SRTs are substantially longer than required for stable operation.
Thermophilic sludge heat recovery is practiced at most of the full-scale temperature phased
digestion plants listed in Table 1, however the methods of heat recovery are different. Direct
sludge/sludge heat recovery is practiced at Sturgeon Bay. The Cologne-Stammheim plantutilizes a sludge/water/sludge heat recovery system with concentric tube heat exchangers. At
Duluth, the thermophilic heat is recovered as hot water for building heating.
7/29/2019 Improvements in Anerobic Digestion
http://slidepdf.com/reader/full/improvements-in-anerobic-digestion 8/17
7/29/2019 Improvements in Anerobic Digestion
http://slidepdf.com/reader/full/improvements-in-anerobic-digestion 9/17
7/29/2019 Improvements in Anerobic Digestion
http://slidepdf.com/reader/full/improvements-in-anerobic-digestion 10/17
Agencies operating temperature phased digestion report that the dewatered cake product is well-stabilized and has the typical odor of mesophilic digested biosolids, although a frequent
comment is that ammonia odor from the product is stronger than from the previous mesophilic
digested product. This appears to occur because of the following: (1) higher ammoniaconcentrations in temperature phased digested biosolids, and (2) higher pH of the biosolids,
resulting in a greater percentage of ammonia in the molecular form. The greater ammoniaconcentrations in dewatering centrate/filtrate are causing concern in some of these plants inmeeting current or expected future ammonia discharge limits from the wastewater treatment
plant.
Acid/Gas Phased Digestion
In this process, the acid phase has a short SRT, with pH generally below six, and low methane
content in the digester gas. The methane phase has fully developed methanogens levels withlonger SRT and full methane production. Table 1 includes performance data from plants or pilot
plants utilizing three different temperature configurations:
• Mesophilic acid phase followed by thermophilic gas phase (acid/gas phased at
meso/thermo)
• Mesophilic acid phase followed by mesophilic gas phase (acid/gas phased at meso/meso)
• Thermophilic acid phase followed by mesophilic gas phase (acid/gas phased atthermo/meso)
The wastewater plant with the longest operating experience with acid/gas phased digestion is theWoodridge-Greenevalley plant of DuPage County, Illinois. This plant operated with both phases
at mesophilic temperature many years ago, but has operated under the meso/thermoconfiguration for almost 10 years. There is a reactor following the thermophilic phase that is
primarily a digested sludge storage tank. The temperature of the sludge in this tank is typically
at elevated mesophilic temperatures, but some limited additional biosolids stabilizationreportedly occurs in this tank. The reported performance data for this digestion system does not
take this storage reactor into account.
The acid/gas phased digestion process performance at DuPage County has been extremely
beneficial, resolving a substantial foaming problem in the digesters and providing major
improvement in VSR. The high ammonia recycle in the dewatering filtrate has been a significant
problem for the plant in meeting its ammonia discharge standards.
Several plants are operating in the meso/meso configuration and data from some of the plants
and one pilot program are shown in Table 1. Some of the comparison work is showing relativelylittle VSR improvement from acid/gas phased digestion, while other plants show significant VSR
improvement. No factor or reason has been identified to account for this variation in
performance.
It is clear that the acid phase digester needs to be designed to account for the specific needs of
this process. This includes adequate precautions for grit and debris accumulation or removal. Inaddition, handling of the gas from this phase needs careful consideration since it will probably
7/29/2019 Improvements in Anerobic Digestion
http://slidepdf.com/reader/full/improvements-in-anerobic-digestion 11/17
contain low methane content and perhaps high hydrogen sulfide content. It has been suggestedthat plug-flow movement through this reactor could be beneficial for process performance. In
summary, more detailed development of the operating requirements for the acid phase portion of
this process would be helpful for agencies seeking to implement this process. Figure 4 providesa review of the performance of acid phase digestion systems.
Three-Phase Digestion
The Inland Empire Utilities Authority has implemented three-phase digestion, as depicted on
Figure 1. This process has provided some increase in VSR, and one of the primary benefits
reported by the process has been the improvement in mechanical dewatering of the product. Thethird phase of the system at Inland Empire is not operated at a specific temperature, but is
allowed by seek its own temperature from radiant heat loss to the environment. The result is
that this phase often has temperatures between typical mesophilic and thermophilic temperatures.Biosolids dewatering on belt filter presses is not reported to be an odor problem at Inland
Empire.
PERORMANCE MEASUREMENT BY VSR
Volatile solids reduction calculations are important for proper performance assessment work in
anaerobic digestion. Several methods are available for calculating VSR, as described by theUSEPA (1999). The two most frequent methods used are the Van Kleeck and Mass Blance
methods. These methods often do not provide the same calculated VSR and the reasons for this
are not always clear. However, one of the primary distinctions between these calculationmethods is the assumption by the Van Kleeck method, that fixed solids remain “fixed” through
the digestion process. The discussion below provides understanding on this issue.
At most facilities that utilize anaerobic digestion, volatile solids reduction is calculated and used
as a control parameter for judging the performance of the process. Typically, total and volatilesolids concentration of the feed and product streams are determined and the fraction volatile
solids is determined at inlet and outlet. Then volatile solids reduction is calculated, using the
Van Kleeck equation:
VSRVK = (VSF - VSP) / (VSF – VSF x VSP) (1)
Where VSR is volatile solids reductionVS is fraction of volatile solids to total solids
Subscripts F and P refer to feed and product
Subscripts VK refers to the Van Kleeck equation
7/29/2019 Improvements in Anerobic Digestion
http://slidepdf.com/reader/full/improvements-in-anerobic-digestion 12/17
7/29/2019 Improvements in Anerobic Digestion
http://slidepdf.com/reader/full/improvements-in-anerobic-digestion 13/17
Volatile solids reduction can also be calculated by a mass balance. This calculation is extremelysimple when volumetric flow rate entering and leaving are the same and no decant stream has
been removed from the digester. The relationship is as follows:
VSRMB = (vF – vP) / vF (2)
Where v is concentration of volatile solids, typically in grams / literSubscripts F and P refer to feed and product
Subscripts MB refers to the mass balance equation
Despite the ease of calculation, volatile solids reduction is seldom calculated in this fashion.One reason may be that the volatile solids concentration fluctuates with time more than the
fraction of volatile solids. Actually, when propagation of error in Equations 1 and 2 is examined,
it is found that for the same percentage deviation in fraction of volatile solids and volatile solidsconcentrations, the variation in VSRVK is greater than the variation in VSRMB. Thus, in cases
when the volatile solids concentration is reasonably constant, VSR calculated by either method
will show about the same random variation.
With the advent of federal regulation of biosolids utilization, the volatile solids determination has
become more than a useful control test. The adequacy of the digestion process is evaluated by
many facilities by the volatile solids reduction, which must be at least 38%. Severalinvestigators in the past have observed that the basic assumption of the Van Kleeck equation,
that fixed solids are conserved, is not strictly true. For example, Benefield and Randall (1980)
cite a number of papers by Randall and coworkers that document a decrease in fixed solidsduring aerobic digestion. Thus, it is highly unlikely that VSR calculated by the two methods will
agree. Switzenbaum et al. (2002A), in their evaluation of the protocols used in the Part 503regulation, contacted many facilities practicing aerobic and anaerobic digestion, and found
several of them reporting substantial differences between results of the two methods. This
prompted these investigators to establish the relationship between the two methods. Theydetermined that the two methods are mathematically related by the following equation:
VSRVK / VSRMB = 1 – (1/Rf –1)/ (1/Rv –1) (3)
Where Rf is the ratio of the fixed solids concentration in the product to the feed
Rv is the ratio of volatile solids concentration in the product to the feed
The derivation of this equation is provided in a publication by Switzenbaum et al (2002B). To
illustrate the use of this equation, assume that we have obtained the following data on the feed
and product from a digester:
Feed: vF = 50 g/L, f F = 20 g/L, VSF = 0.7143
Product: vP = 30 g/L, f P = 15 g/L, VSP = 0.6667
Where “f” is the concentration of fixed solids (e.g., in g/L).
7/29/2019 Improvements in Anerobic Digestion
http://slidepdf.com/reader/full/improvements-in-anerobic-digestion 14/17
The percent volatile solids have been calculated from the volatile and fixed solids concentrations.The volatile solids concentrations by the two methods can be calculated:
VSVK = 0.1999, VSMB = 0.400
The ratio, VSVK / VSMB, can also be calculated by Equation 3, whereby:
Rf = 15/20 = 0.750, Rv = 30/50 = 0.600
Substituting these values into Equation 3 gives a ratio of 0.500, which agrees with the ratio of
individual volatile solids reductions for the two methods.
The difference between the two calculation methods is large in this example because the fixed
solids concentration drops so much from the feed to the product. If the fixed solidsconcentration dropped only from 20 g/L to 19 g/L from feed to product, the ratio of the two
calculation methods becomes 0.921 instead of 0.500 in the above example.
It is important to note that the basic information needed to calculate volatile solids concentrations
and percent volatile solids can be used to calculate both VSRs. However, the relationship
between the VSRs cannot be calculated if only volatile solids concentrations are provided or if
only percent volatile solids are provided. Most published data does not provide fixed solidsconcentrations, so the comparison generally cannot be made. It would be very helpful in the
future if data reported on volatile solids reductions in either anaerobic or aerobic digestion
provide this additional information.
FINDINGS AND CONCLUSIONS
The key findings and conclusions from this evaluation of advanced anaerobic digestion processes
are as follows:
1. Advanced anaerobic digestion processes are creating improved digestion performance,
particularly as measured by volatile solids reduction. The degree of improvement isvariable, as seen by the data discussed here.
2. Increased gas production is also occurring from operation of advanced digestion
processes, although confirming the amount or percentage of increased gas production isoften difficult.
3. In most cases, the odor in the final product from advanced digestion processes isconsidered similar to the odor from mesophilic-digested products. However, greater
ammonia odor is sometimes associated with advanced digestion products and a different
odor character is noted at times for thermophilic digested products.
4. The processes involving thermophilic digestion, in particular, are showing high rates of
pathogen destruction. Innovative configurations are occurring to confirm pathogendestruction meeting Class A requirements of EPA’s Part 503 regulations.
7/29/2019 Improvements in Anerobic Digestion
http://slidepdf.com/reader/full/improvements-in-anerobic-digestion 15/17
5. Dewatering improvements are also being identified by many of the plants using advanced
digestion processes. Usually, this is noted as a small improvement in cake solids content.
More work is required to identify the detailed impact on dewatering.
6.
Higher ammonia recycle loads (from dewatering) are occurring with advanced digestion.In some cases, these loads are causing problems in meeting ammonia dischargerequirements for the treatment plant.
7. Calculations for VSR are becoming more important as process performance becomes an
increasingly dominant factor for agencies. More comparison work between VSRcalculation methods is needed.
ACKNOWLEDGEMENTS
We wish to acknowledge all staff from wastewater agencies providing data for this evaluation.
In particular, the following individuals provided important information beyond that available inprior publications: Kevin Buoy (DuPage County, IL), Walter Gottschalk (OWASA, NC), Jim
McQuarrie (GVRD, Canada), Kathy Hamel (WLSSD, MN), Gerald Hernandez, (City of Los
Angeles, CA), Randy Much (Neenah-Menasha, WI) Doug Drury (Inland Empire, CA), Steve
Schultz (City of San Bernardino, CA), and Søren Højsgaard from Krüger (Søborg, Denmark).
REFERENCES
1. Greater Vancouver Regional District, 2001. Operating data and information on digestion
and solids processing system at Lions Gate and Annacis Island Plants in BritishColumbia, Canada.
2. Orange Water and Sewer Authority, 2002. Operating data and information on digestionand solids processing system at Mason Farm WWTP at OWASA, North Carolina.
3. City of Aalborg, 1999. Operating data for digestion and related solids processingfacilities at Aalborg West WWTP in Aalborg, Denmark.
4. Western Lake Superior Sanitary District, 2002. Operating data for solids processing
system at the District WWTP in Duluth, Minnesota.
5. King County, 2001. “Thermophilic-mesophilic Anerobic Digestion: Pilot Testing at
South Treatment Plant”, Draft report published October 2001 by King CountyTechnology Assessment Program, King County, Washington.
6. Neenah-Menasha, 2001. Operating data and information on solids processing system atNeenah-Menasha WWTP, Wisconsin.
7. Reusser, Steve, and G. Zelinka, 2001. “Lab Scale Comparison of Anaerobic DigestionAlternatives,” presented at WEFTEC, Atlanta, October 2001.
7/29/2019 Improvements in Anerobic Digestion
http://slidepdf.com/reader/full/improvements-in-anerobic-digestion 16/17
8. Hernandez, G., et al, 2002. “Hyperion Advanced Digestion Pilot Program,” presented
at the Water Environment Federation’s Residuals and Biosolids Management
Conference, Austin, TX, March 2002.
9.
City of Cologne, Germany. (1999) “Sludge Digestion Operating and Performance Datafrom Stammheim Sewage Treatment Plant over the Period of 1993 to 1996.”
10. Vik, T.E., and C. Olsen. (1997) “Full-Scale Operation of Temperature-Phased
Anaerobic Digestion.” Water Environment Federation Annual Conference, Chicago,
Illinois. October 1997.
11. Buoy, Kevin (1999). Personal communication and operating data review with Kevin
Buoy, Plant Manager for Woodridge-GreenValley WWTP at DuPage County, Illinois.
12. Ghosh, S., K. Buoy, L. Dressel, T. Miller, G. Wilcox, and D. Loos. (1995) “Pilot and
Full-Scale Two Phase Anaerobic Digestion of Municipal Sludge”. Water EnvironmentResearch Vol. 67, No. 2.
13. City of San Bernardino, 2001. Operating data and information on the solids processing
system at the City’s WWTP.
14. Wilson, Tom, and Dennis Streicher, 2001. “Full-scale Application of AG Process:
Update 2001,” presented at WEFTEC, Atlanta, October 2001.
15. Drury, Doug, C. Baker, and C. Berch, 2001. “The Use of Three Stage Digestion toMitigate the Adverse Impacts of Thermophilic Digestion,” presented at the Water
Environment Federation’s Residuals and Biosolids Management Conference, San Diego,
February 2001.
16. Huyard, A. (1998). “A Challenge for the Two Phase Anaerobic Digestion: To Produce
Class A Biosolids and Meet PFRP Equivalency” Presented at Water EnvironmentFederation Annual Conference in Orlando, Florida.
17. Han Y., and R.R. Dague (1996). “Laboratory Studies on the Temperature-Phased
Anaerobic Digestion of Mixtures of Primary and Waste Activated Sludge.” Presented atWater Environment Federation Annual Conference, Dallas, TX, October 1996.
18. Krugel, S. , L. Nemeth, and C. Peddie (1998). “Extended Thermophilic AnaerobicDigestion for Producing Class A Biosolids at the Greater Vancouver Regional District’s
Annacis Island Wastewater Treatment Plant.” Presented at the IAWQ Conference in
Vancouver, Canada. June 1998.
19. US Environmental Protection Agency (1999). Environmental Regulations and
Technology – Control of Pathogens and Vector Attraction in Sewage Sludge,EPA/625/R-92/013, Revised October 1999.
7/29/2019 Improvements in Anerobic Digestion
http://slidepdf.com/reader/full/improvements-in-anerobic-digestion 17/17
20. Benefield, L.D. and Randall, C.W. 1980. “Biological Process Design for Wastewater
Treatment”, p. 484, pub. Prentice-Hall, Englewood Cliffs, N. J.
21. Switzenbaum, M.S., A.B. Pincince, J.F. Donovan, E. Epstein, and J.B. Farrell. 2002A.
“Developing Protocols for Measuring Biosolids Stability”, Project No. 99-PUM-3,submitted to WERF March 2002.
22. Switzenbaum, M.S., J.B. Farrell, and A.B. Pincince. 2002B. Relationship between the
Van Kleeck and mass balance calculation of volatile solids loss. Research note submitted
to Water Environment Research. April 2002.