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R. Digby, FAA/CAA Bonded Structures Workshop Oct 2004 Joining of Thermoplastic Composite Materials Roger Digby Head of Materials & Processes, UK

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Page 1: Joining of Thermoplastic Composite · PDF filetheir ability to meet Airworthiness Authorities’ requirements ... PES PEI LCP PEEK PPS PEKK PA PET PBT POM PU SMA PVC ABS PMMA PC PPO

R. Digby, FAA/CAA Bonded Structures Workshop Oct 2004

Joining of Thermoplastic Composite MaterialsRoger DigbyHead of Materials & Processes, UK

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R. Digby, FAA/CAA Bonded Structures Workshop Oct 2004

Airbus A340-600

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R. Digby, FAA/CAA Bonded Structures Workshop Oct 2004

• An overview of the use of thermoplastic composite components

• Classification of thermoplastic materials

• Thermoplastic material selection

• Welding techniques

• Airbus research programmes

• Adhesive bonding

• Acknowledgments

Contents

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R. Digby, FAA/CAA Bonded Structures Workshop Oct 2004

Reduce structural weight of aircraft

• Improve durability of composite components

• Reduce manufacturing lead-times

• Achieve all of above without incurring cost penalty

Requirements which have to be met:

• All materials and processes used on aircraft must be qualified to the appropriate standards

• Design allowables must be generated to support stress calculations

• Components must be subjected to certification tests to demonstrate their ability to meet Airworthiness Authorities’ requirements

Key design drivers for the introduction of new technology on the A340-500/600

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R. Digby, FAA/CAA Bonded Structures Workshop Oct 2004

• High processing temperatures require special foils and consumable materials. These in themselves tend to be less flexible than those used traditionally

• For PPS inert atmospheres are required during autoclave consolidation cycles

• Tooling must be dimensionally stable and be capable of repeated thermal cycling at temperatures up to 350oC

• Thermal effects such as spring forward are exaggerated and must be considered in the design and tooling phases of the project

• High performance semi-crystalline thermoplastic matrix systems tend to be very stable chemically and may need special surface treatments to promote paint and bonding adhesion.

Some of the challenges of using thermoplastic composites

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R. Digby, FAA/CAA Bonded Structures Workshop Oct 2004

Thermoplastics have all the advantages of thermosets(strength, stiffness, low weight, corrosion resistance, part count reduction,

design flexibility etc), with the additional benefits of:

Thermoplastic Materials

• unlimited storage life, with no need for refrigeration

• faster cycle times

• superior toughness

• improved FST performances

• weldability

• recyclable

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R. Digby, FAA/CAA Bonded Structures Workshop Oct 2004

Classification of Thermoplastic Materials

PBIPAIPESPEI

LCPPEEKPPSPEKK

PAPETPBTPOMPU

SMAPVCABSPMMA

PCPPOPMMA/PC

PPUHMW/PEHDPELDPE

Amorphous Crystalline

Increasing

• Performance• Processing temperature• Maximum use temperature• Material cost

High Performance Thermoplastics

Engineering Thermoplastics

Commodity Thermoplastics

Ternary blendsPEEK/PEI/PSU

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R. Digby, FAA/CAA Bonded Structures Workshop Oct 2004

Classification of Thermoplastic Materials

The engineering thermoplastic materials employed by Airbus are :-

Amorphous

• PEI (polyetherimide)Semi-crystalline

• PPS (polyphenylene sulphide)

• PEEK (polyetherether ketone)Excellent mechanical properties but limited chemical resistance.

Used extensively in cabin due to excellent FST properties

Excellent mechanical properties and excellent resistance to solvents, Skydrol etc.

Used extensively on A340-600 and A380

NOTE: Semi-crystalline materials such as PPS and PEEK are very difficult toadhesively bond due to the inert nature of the material and low surface energy

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R. Digby, FAA/CAA Bonded Structures Workshop Oct 2004

Welding

There are many methods used to weld thermoplastics,

• External heat sources, such as hot plate, flame and lasers

• Friction, such as spin welding, ultrasonic

• Induction welding

• Resistive, such as metallic implant wire or tape or carbon tape

AIRBUS EXPERIENCE

Resistive welding of glass reinforced PPS for the A340-600 J Nose

Carbon implant (resistive and inductive) welding development is being conducted.

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R. Digby, FAA/CAA Bonded Structures Workshop Oct 2004

Schematic of resistance welding

CFR Component

Wire MeshThermoplastic FilmGlass FabricCFR Component

Controlled pressure

Computer controlled pressure, time and energy

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R. Digby, FAA/CAA Bonded Structures Workshop Oct 2004

Resistance welding of A340-600 J Nose riblets

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R. Digby, FAA/CAA Bonded Structures Workshop Oct 2004

Installation of thermoplastic J Nose leading edgeon to wing

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R. Digby, FAA/CAA Bonded Structures Workshop Oct 2004

Details of the welded J-nose assemblies

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R. Digby, FAA/CAA Bonded Structures Workshop Oct 2004

Potential applications for A380

Horizontal Tail Plane

Floor Beamsfor Upper Deck

Rear Pressure Bulkhead

Outer Flaps

Vertical Tail Plane

J-Nose

Center Wing Box

Section 19

GLARE®

Section 19.1

Belly Fairing

Wing Ribs

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R. Digby, FAA/CAA Bonded Structures Workshop Oct 2004

Adhesive Bonding – Semi-crystalline Thermoplastics•Work carried out at Airbus on PPS

Surface preparation

• Alumina blasting

• Corona discharge

• Flame treatment

• Adhesion promoters

Adhesives

• Two part epoxy EA 9394

• Two part polyurethane SW 7838

• Epoxy film adhesive AF 163

None of the adhesives/surface treatments produced results which met the minimum hot/wet lap shear design requirements of

1000psi

Today no adhesive bonding techniques are approved for

manufacture and repair of semi-crystalline thermoplastics

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R. Digby, FAA/CAA Bonded Structures Workshop Oct 2004

Bonding – Amorphous ThermoplasticsBonding – Amorphous Thermoplastics

Amorphous thermoplastics such as PEI can be satisfactorily adhesively bonded using conventional

adhesive systems

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R. Digby, FAA/CAA Bonded Structures Workshop Oct 2004

Acknowledgments

Rafial Avila

Jean-Michel Bergerat

Steve Mason

Christian Rueckert

Fokker BV

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R. Digby, FAA/CAA Bonded Structures Workshop Oct 2004

This document and all information contained herein is the sole property of AIRBUS UK LTD. No intellectual property rights are granted by the delivery of this document or the disclosure of its content. This document shall not be reproduced or disclosed to a third party without the express written consent of AIRBUS UK LTD. This document and its content shall not be used for any purpose other than that for which it is supplied.

The statements made herein do not constitute an offer. They are based on the mentioned assumptions and are expressed in good faith. Where the supporting grounds for these statements are not shown, AIRBUS UK LTD will be pleased to explain the basis thereof.