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    Shrinkage and Cracking of Concrete:

    Mechanisms and Impact on Durability

    Bauingenieurwissenschaften Master

    Vertiefung in Werkstoffe und Mechanik

    21.09-14.12.2011

    every Wednesday 10:00-12:00

    3 ECTS points

    Lecturers: Prof. Dr. Pietro Lura

    Dr. Mateusz Wyrzykowski Berlin, Holocaust memorial

    Lecture 1

    Introduction to the course

    Pietro Lura

    Concrete & Construction Chemistry

    Shrinkage and Cracking of Concrete: Mechanisms and Impact on Durability, ETHZ, fall 2011

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    Welcome

    Welcome

    This series of lectures, reading assignments, and afinal exam constitute a 3 ECTS points course

    Participating students receive a DVD with lectures(ppt and movies) of REACCT, a course with similar

    topic held in 2008 at Purdue University

    4

    Reducing Early-age Cracking ofConcrete Today (REACCT 08)

    July 28-29 2008, PurdueUniversity, IN, US

    Graduate course (~30students), series of 16*50minute lectures

    Instructors Jason Weiss, Dale Bentz and Pietro Lura

    All lectures were filmed

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    5

    REACCT 09

    13 July 2009, Empa,Dbendorf, Switzerland

    International PhD Course, 2.5ECTS points, 41 participants,18*50 minute lectures

    Instructors Karen Scrivener,Hans Herrmann, Jason Weiss

    and Pietro Lura

    6

    Contents

    Instructor and students

    Basics of cement and concrete

    Basics of cracking

    Course contents

    Exam

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    About myself

    MSc Civ.Eng., Univ. Brescia, Italy, 1992-1998

    (Final Project, NTNU, Norway, 1997)

    PhD, Delft Univ., The Netherlands, 1999-2003

    Assistant Professor, DTU, Denmark, 2003-2006

    Patent examiner, EPO, Germany, 2006-2008

    Head of Lab, Empa, Switzerland, from 2008

    NIST, Maryland, USA, 2002

    Purdue University, Indiana, USA, 2005TU Kaiserslautern, Germany, 2006

    610-3 km/h

    8

    Empa is an interdisciplinary researchand services institution for materialsciences and technologydevelopment within the ETH domainin Switzerland

    About 30 research laboratories,900 employees

    Concrete / Construction Chemistry

    Laboratory, 25 people

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    Concrete & Construction Chemistry Laboratory

    1E-3 0.01 0.1 1 10 100 1000

    0

    5

    10

    15

    20

    25

    30

    35

    40

    45

    50

    55

    60

    65

    70

    75

    Na2SO

    4

    solution

    unaffected

    core

    hydrotalcite

    gypsum

    ettringite

    monocarbonate

    portlandite

    calcite

    unhyd. clinker

    C-S-Hvolume(cm

    3/100gcement)

    ml Na2SO

    4solution added /cm

    3hydrated mortar

    10

    My main research interests

    Pietro Lura

    (roar!)

    AUTOGENOUS

    SHRINKAGE

    Early-age concrete properties

    Plastic shrinkage

    Autogenous shrinkage

    Internal curing

    Thermal dilation Cracking and microcracking

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    Mateusz Wyrzykowski

    MSc Civ.Eng., Tech. Univ. of Lodz, Poland, 2000-2005

    MSc Thesis at Univ of Padua, Italy, 2005

    Software Engineer, Robobat/Autodesk Poland, 2005-2010

    PhD, Tech. Univ. of Lodz, Poland 2005-2010

    Postdoc researcher, Empa, Switzerland, from 2010

    Main research interests:

    Modelling phenomena in maturing concrete (early age, transport, shrinkage)

    Early age concrete (autogenous shrinkage, properties evolution)

    Curing of conrete

    Thermal dilation

    12

    And what about you?

    What is your background?

    What are your interests?

    Why do you follow this course?

    What do you expect to learn?

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    Concrete

    Sunniberg bridge, photo by M. Romer

    14

    What is concrete?

    Concrete is a heterogeneous system of solid, discrete, gradientlysized, inorganic mineral aggregates, usually plutonic (feldspatho-silicaceous or ferro-magnesian) or sedimentary-calcareous inorigins, embedded in a matrix compound of synthesized poly-basic alkaline and alkaloidal silicates held in aqueous solution andco-precipitate dispersion with other amphoteric oxides, this matrix

    being originally capable of progressive dissolution, hydration,reprecipitation, gelation and solidification through a continuousand coexistent series of crystalline, amorphous, colloidal andcryptocrystalline states and ultimately subject tothermoallotriomorphic alteration, the system when first conjoinedbeing transiently plastic during which state it is impressed to a pre-determined form into which it finally consolidates, thus providing astructure relatively impermeable and with useful capacity totransmit tensile, compressive and shear stresses.

    Source: Portland Cement Association- http://www.cement.org

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    Definitions

    Cement Aggregate Water

    + +

    Fresh concreteHardened concrete

    Mortar:Max aggregate size 4 mm

    Concrete:Max aggregate size 8 mm

    = Binder

    Winnefeld 2008

    16

    Importance for the economy

    Data for Switzerland:

    Cement production 2006 (source: cemsuisse1): 4.2 Mt

    Cement import 0.8 Mt

    3 cement producers with 7 plants (Holcim, Vigier, Jura)

    Market volume of aggregates (source: FSKB2):30 millions m3

    Own production aggregates: 90%

    Concrete production 2006 (source: FSKB): ca. 20 Mt

    Own production concrete: 95%

    1. Association of the Swiss Cement Industry

    2. Fachverband der Schweizerischen Kies- und Betonindustrie Winnefeld 2008

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    A versatile building material

    18

    and the most used one

    10 km3 of concreteor at least 1.5 m3/ personevery year

    ~3 Gt Portland cement

    produced, causing 5% ofman-made CO2 emissions

    (1 t Cement 0.75 t CO2)

    Raw materials for cement andaggregate production

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    Sustainability

    Durable and densesystems

    Cement substitution,alternative binders

    Challenges for the future

    20

    Concretes bad image

    Cracks facilitate transport ofharmful substances

    Durability of concrete is reduced

    Repair needed, often repairof repair

    Costs of repair often exceedcosts of original structure

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    Cracks from alkali-aggregate reaction (1)

    Some types ofaggregates react withthe alkaline poresolution in concrete

    (may take years)

    A silica-rich gel is

    formed within theaggregates

    The aggregates

    expand and causeconcrete crackingPictures by A. Leemann

    22

    Cracks from alkali-aggregate reaction (2)

    Pictures by J.-G. Hammerschlag

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    Cracks from sulfate attack

    Sulfate-containingwater reacts withaluminate phases incement paste to

    produce ettringite

    Production of

    ettringite causesexpansion andcracking within thecement paste

    Pictures by A. Leemann

    24

    Consequences of cracking - steel corrosion

    Cracks are preferredpathways forcarbonation andwater and chlorideions ingress

    Steel bars corrodeand the corrosionproducts expand

    Expansion causescracking and more

    corrosionPicture by R. Loser

    Picture from www.cowi.com

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    Consequences of cracking concrete corrosion

    HCl solutions are used toprepare metal surfaces ingalvanic plants

    HCl solution penetratesthe pre-existing shrinkagecracks and cause deep

    corrosion of the concrete

    Cracks are enlarged bycorrosion and more HCl

    penetrates

    Pictures by R. Loser

    26

    Are all cracks bad?

    Cracks are essentialto reinforced concrete

    Without cracks,tensile stresses

    cannot be transferredto reinforcing bars

    Flexural cracks areneeded, but theirwidth needs to becontrolled by design

    Giuriani et al. J Struct Eng 1991

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    Hardening of concrete

    Hollywood, California, 1953

    Plastic phase Setting Hard concrete

    28

    Solid suspension

    Cryo-nanotomography Zingg et al. CCR 2008

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    Setting and hardening process

    Ye, Lura, van Breugel and Fraaij CCC 2004

    Suspension Threshold of solid percolation Solids fully connected

    30

    Early-age cracks in concrete

    Weiss 2009, after British Cracking Manual

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    Joints vs. random cracking in concrete slabs

    Bill Palmerwww.concretenetwork.com/blogs/bill-palmer/2007/07/cracking-up.html

    There are only two kinds ofconcrete - concrete thats alreadycracked and concrete thats about

    to crack.

    32

    Early-age cracks in concrete (1)

    Photos by A. Leemann, 2008Plastic shrinkage cracking

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    Early-age cracks in concrete (2)

    Photohttp://w

    ww.aggregateresearch.com/caf/file/newdeckcracking.p

    df

    Drying shrinkage cracks, approach to a bridge (pilot project with HPC)

    34

    Early-age cracks in concrete (3)

    Photo by R. Loser, 2008

    Drying shrinkage cracks, top layer on old concrete

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    Early-age cracks in concrete (4)

    Photo by R. Loser, 2009

    Drying shrinkage cracks above a door

    36

    Early-age cracks in concrete (5)

    Tokyo Institute of Technology, 2003

    Photo by O.M. JensenThermal cracking

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    What causes cracking?

    Weiss 1999Cracking

    Unrestrainedlength change

    Initial length

    Restraintstress

    38

    Stress development (1)

    ( ) ( )

    ( ) ( )

    SHRdE

    d

    td +=,

    Initial Specimen

    Shrinkage Effect

    Restraint Effect

    0 7 14 21 28

    Age of Specimen (Days)

    0

    4

    8

    12

    Stress BasedOn Hookes Law

    Stress In

    Specimen

    CalculatedTensileStress(MPa)

    0 7 14 21 28

    Age of Specimen (Days)

    0

    4

    8

    12

    Stress BasedOn Hookes Law

    CalculatedTensileStress(MPa)

    Weiss 1999

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    Stress development (2)

    Creep/Cracking Effect

    Stress Relaxation

    ( ) ( )

    ( ) ( ) ( )

    ( )

    ++=

    28

    ,,

    E

    tdd

    E

    dtd

    SHR

    StressRelaxation( )

    ( )

    ( ) ( )

    SHRd

    E

    dtd +=,

    Initial Specimen

    Shrinkage Effect

    Restraint Effect

    0 7 14 21 28

    Age of Specimen (Days)

    0

    4

    8

    12

    Stress BasedOn Hookes Law

    Stress In

    Specimen

    Calcu

    latedTensileStress(MPa)

    0 7 14 21 28

    Age of Specimen (Days)

    0

    4

    8

    12

    Stress BasedOn Hookes Law

    Calcu

    latedTensileStress(MPa)

    Final Stress State

    Stress In

    Specimen

    Weiss 1999

    40

    Cracking conditions

    Stress that develops tomaintain constant length

    Weiss 1999Age

    Material Resistancei.e., Strength

    Age ofCracking

    StressLevel

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    Common attempts to reduce shrinkage cracking

    Weiss 1999

    Material resistance

    i.e., strength

    Age ofcracking

    Age

    Stresslevel

    ( ) ( )

    ( ) ( )

    SHRd

    E

    dtd +=,

    Initial Specimen

    Shrinkage Effect

    Restraint Effect

    42

    0

    10

    20

    30

    40

    50

    60

    70

    0 24 48 72 96 120 144 168 1 92 216 240

    Time [h]

    Temperature[oC]

    =TT

    Example - Thermal cracking

    Lura and van Breugel 2001

    -4

    -2

    0

    2

    4

    6

    8

    0 24 48 72 96 120 144 168 192 216 240

    Time [hrs]

    Stress,strength[MPa]

    Stress

    Tensile

    strengthyoung concrete

    older concrete

    young concrete

    young concrete

    older concrete

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    High-Strength Concrete in skyscrapers

    Burj Khalifa, 828 m, opened 4.1.2010

    First 156 floors made of high-strengthconcrete (ACI definition of HSC: fc>40MPa)

    Self-compacting pumpable concrete, cooledwith ice and cast at night

    Source of text and figures: Wikipedia, Burj Dubai

    44

    Benefits of High-Strength Concrete

    Higher strength

    Higher stiffness

    Low permeability

    Low shrinkage

    Low creep

    Scaling and freeze-thaw resistance

    Improved abrasion resistance Weiss 1999

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    Misconception #1: HSC has lower shrinkage

    Start time matters!

    Time (Days)

    Shrinkage

    Measuredshrinkage

    0.30 0.40 0.50 0.60 0.70

    Water to Cement Ratio

    0

    250

    500

    750

    1000

    Aggregate volume (70%)

    Shrinkage()

    0.30 0.40 0.50 0.60 0.70

    Water to Cement Ratio

    0

    250

    500

    Aggregate volume (65%)Measured at 24 hours

    Shrinka

    ge()

    Time (Days)

    ActualSh

    rinkage

    MeasuredShrinkage

    Weiss 2008, after Aitcin 1996

    46

    Misconception #2: Higher E is always good (1)

    Initial Specimen

    Shrinkage Effect

    Restraint Effect

    Initial Specimen

    Shrinkage Effect

    Restraint Effect

    E=

    Weiss 1999

    Hookes law

    Ut tensio, sic visRobert Hooke, FRS

    1635 1703

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    Misconception #2: Higher E is always good (2)

    Higher Elastic Modulus

    (if E , for = )

    0 20 40 60 80 100

    Compressive Strength (MPa)

    0

    15

    30

    45

    Te

    nsileStress(MPa)

    0 20 40 60 80 100

    Compressive Strength (MPa)

    0

    15

    30

    45

    Te

    nsileStress(MPa)

    Weiss 1999

    48

    Misconception #3: lower creep is always good (1)

    "We can't prevent creep from happening,but if we slow the rate at which it occurs,

    this will increase concrete's durability andprolong the life of the structures"

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    Misconception #3: lower creep is always good (2)

    Weiss 1999

    Creep/Cracking Effect

    Stress Relaxation

    ( ) ( )

    ( ) ( ) ( )

    ( )

    ++=

    28

    ,,

    E

    tdd

    E

    dtd

    SHR

    StressRelaxation( )

    ( )

    ( ) ( )

    SHRd

    E

    dtd +=,

    Initial Specimen

    Shrinkage Effect

    Restraint Effect

    0 7 14 21 28

    Age of Specimen (Days)

    0

    4

    8

    12

    Stress BasedOn Hookes Law

    Stress In

    Specimen

    CalculatedTensileStress(MPa)

    0 7 14 21 28

    Age of Specimen (Days)

    0

    4

    8

    12

    Stress BasedOn Hookes Law

    CalculatedTensileStress(MPa)

    Final Stress State

    Stress In

    Specimen

    50

    Misconception #3: lower creep is always good (3)

    Weiss 1999

    Specimenstrength

    0 7 14 21 28

    Age of specimen (days)

    0

    4

    8

    12

    Stress basedon Hookes law

    Relaxation

    i.e., creep

    Stress in

    specimen

    Calculatedtensilestress(MPa)

    Specimenstrength

    0 7 14 21 28

    Age of specimen (days)

    0

    4

    8

    12

    Stress basedon Hookes law

    Relaxation

    i.e., creep

    Stress in

    specimen

    Calculatedtensilestress(MPa)

    Specimen with lower creep

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    Misconception #4: High early strength is always good

    Strength

    Reduce rate

    Stressdeveloped

    Reduce magnitude

    Time of drying

    Tensilestress Strength

    Stress

    developed

    Time of drying

    Tensilestress

    Weiss 1999

    Reducing cracking potential: shrinkage rate and magnitude

    52

    Misconception #5: HSC is tougher (1)

    Weiss 2008

    ClintTough

    Toughness

    Strength

    ArnoldStrong

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    aC

    Higher strength is more like glass

    00

    0 20 40 60 80

    Comp. Strength (MPa)

    10

    15

    20

    25

    30

    D-a

    Crac

    kRatio=

    (%)

    aC-a0

    D-a

    Crac

    kRatio=

    (%)

    aC-a0

    Misconception #5: HSC is tougher (2)

    Weiss 1999

    54

    Outline of the course (1)

    21.09: Introduction (2h)

    28.09: Hydration and microstructure development (1h)Powers' model (1h)

    05.10: Plastic shrinkage (1h)Shrinkage mechanisms in hard. concrete (1h)

    12.10: Autogenous shrinkage (1h)

    Drying shrinkage and gradients (1h)

    19.10: Influence of aggregate (1h)Residual stress development (1h)

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    Outline of the course (2)

    26.10: Shrinkage-reducing admixtures (1h)

    Internal curing (1h)

    02.11: Temperature-induced cracking (2h)

    09.11: Residual stresses and cracking practicalcases (1 h)

    Transport and durability of cracked concrete (1h)

    16.11: Visit of the Concrete and ConstructionChemistry Laboratory, Empa

    56

    Outline of the course (3)

    23.11, 30.11 and 7.12: Individual project by students.We will be at ETHZ every Wednesday (or onappointment) for discussion

    14.12: final exam, 15-20 min presentation on topic of

    project plus 5-10 minutes questions

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    Acknowledgements

    J. Weiss, F. Winnefeld and D. Bentz

    (slides, other course material)

    A. Leemann, R. Loser, O.M. Jensen,

    J.-G. Hammerschlag, M. Romer

    (pictures)

    58

    The beauty of cracks

    Doris Salcedo, Shibboleth, Tate Modern, London, 2007